Materials for Femtospin Project Colin Forbes [email protected].

15
Materials for Femtospin Project Colin Forbes [email protected]

Transcript of Materials for Femtospin Project Colin Forbes [email protected].

Page 1: Materials for Femtospin Project Colin Forbes cforbes628@qub.ac.uk.

Materials for Femtospin Project

Colin Forbes

[email protected]

Page 2: Materials for Femtospin Project Colin Forbes cforbes628@qub.ac.uk.

Introduction

• Brief Overview of Key materials

• Material sequencing

• Overview of experimental results

• Future

Page 3: Materials for Femtospin Project Colin Forbes cforbes628@qub.ac.uk.

Materials of interest

• GdFeCo ternary alloys with 20-25% Gd & Co = 10%

• Gd/(FeCo) multilayers– 20-25% volume fraction of Gd

• FePt(5nm)/Co(5,10-20nm) bilayers

• FeRh

• FeTb – TbFe2 and TbFe3 ordered phases

• Elemental RE– GdFe2 ordered phases

Page 4: Materials for Femtospin Project Colin Forbes cforbes628@qub.ac.uk.

Material Sequencing

1. GdFeCo ternary alloy

2. Gd/(FeCo) multilayers

3. FePt(5nm)/Co(5,10-20nm) bilayers

4.= FeTb, FeTb2, FeTb3

4.= FeRh4.= Gd & GdFe2

Page 5: Materials for Femtospin Project Colin Forbes cforbes628@qub.ac.uk.

Experimental Analysis

Page 6: Materials for Femtospin Project Colin Forbes cforbes628@qub.ac.uk.

• Ternary Alloy Depositions– GdFeCo

• Gd – 15 - 30%• Fe – 60 – 75% 50nm• Co – 10%

• SiO2 wafers used as substrates

• Depositions done at ambient temperatures

• Samples sent to Seagate

Ternary Alloy Samples

SiO2

Ta

GdxFe90-xCo10

Ta 5nm

50nm

5nm

Where x = 15 - 30

Page 7: Materials for Femtospin Project Colin Forbes cforbes628@qub.ac.uk.

XRD Analysis Gd20Fe70Co10 (50nm)

• No crystalline structure• Amorphous surface

Page 8: Materials for Femtospin Project Colin Forbes cforbes628@qub.ac.uk.

Heated VSM GdFeCo alloys

Page 9: Materials for Femtospin Project Colin Forbes cforbes628@qub.ac.uk.

Heated VSM

• 20% Gd has perpendicular anisotropy at room temperature while 25% Gd has in plane anisotropy

• Magnetic properties change with temperature• 25% Gd switches from in plane to perpendicular anisotropy at

≈300°C

Page 10: Materials for Femtospin Project Colin Forbes cforbes628@qub.ac.uk.

• Multilayers of Gd and Fe90Co10 - (40nm)

• Volume factor of Gd was either 20 or 25%• Single bilayer• Double bilayer• Quadruple bilayer

• Depositions at room temperature

• Samples sent to Seagate

Gd/(FeCo) Multilayer Samples

SiO2

Ta

Gd

Fe90Co10

Ta

SiO2

Ta

Gd

Fe90Co10

Ta

Gd

Fe90Co10

SiO2

Ta

Gd

Fe90Co10

Ta

Gd

Fe90Co10

Gd

Fe90Co10

5nm

40nm

5nm

Gd

Fe90Co10

Page 11: Materials for Femtospin Project Colin Forbes cforbes628@qub.ac.uk.

BH Looper AnalysisTa(5nm)/[Gd(20%)/Fe90Co10](40nm)/Ta(5nm) in

Plane

Ta(5nm)/[Gd(25%)/Fe90Co10](40nm)/Ta(5nm) in Plane

Page 12: Materials for Femtospin Project Colin Forbes cforbes628@qub.ac.uk.

VSM Analysis of Gd/FeCo multilayers

Page 13: Materials for Femtospin Project Colin Forbes cforbes628@qub.ac.uk.

Ta(5nm)/[Gd(4nm)FeCo(16nm)]2(40nm)/Ta(5nm) in Plane

Temp / °C Temp / °C

Temp / °C

Temp / °C

Heated VSM Measurements

Ta(5nm)/[Gd(5nm)FeCo(15nm)]2(40nm)/Ta(5nm) in Plane

Page 14: Materials for Femtospin Project Colin Forbes cforbes628@qub.ac.uk.

• Decrease in both saturation & coercivity general trend• Not what was expected – in plane to perpendicular

anisotropy switching expected at compositional temp

Page 15: Materials for Femtospin Project Colin Forbes cforbes628@qub.ac.uk.

Future

• Improve multilayer structures of Gd/(FeCo)– Vary Volume fraction– Magnetic Properties– Crystal structure– Temperature analysis

• Investigate FePt/Co – FePt(5nm)Co(5,10-20nm) bilayers

• FeRh

• FeTb, FeTb2, FeTb3

• Gd & GdFe2