HFO Process

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    Classification and mainClassification and maincharacteristics of heavy fuel oilscharacteristics of heavy fuel oils

    Ronan JzquelRonan Jzquel

    CedreCedre

    Very Heavy Fuel OilWorkshop29-30 November 2006-Brest-France

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    HEAVY FUEL OILS:HEAVY FUEL OILS:

    WHAT THEY ARE ?WHAT THEY ARE ?

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    Crude(s)oil(s)

    FIOULFIOULFIOULFIOUL

    LOURDLOURDLOURDLOURD

    HFOHFOHFOHFO

    Atmosphericdistillation

    distillate

    Gases+

    Naphta

    Gas oil

    Atmosphericresidue

    Visbreaking Visbreakergas oil

    Gases Visbreakerdistillate

    Visbreaker residue

    FluidCatalyticCracking

    Gases

    FCC distillate

    Light Cycle Oil

    Heavy Cycle Oil

    Lubricants unit

    asphalt

    Waxes

    Lubricants

    Vacuumdistillation

    Gase

    s

    Vacuum residue

    He

    avyVacuum

    gasoil

    HFO blend variousHFO blend various residuesresidues

    Distillation process = Straight Run

    Conversion process = Cracking

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    HFO blend variousHFO blend various residuesresidues withwith variousvarious distillatesdistillates

    Distillation process = Straight Run

    Conversion process = Cracking

    FIOULFIOULFIOULFIOUL

    LOURDLOURDLOURDLOURD

    HFOHFOHFOHFO

    Atmosphericdistillation

    distillate

    Gases+

    Naphta

    Gas oil

    Atmosphericresidue

    Visbreakergas oil

    Gases Visbreakerdistillate

    Visbreaker residue

    Gases

    FCC distillate

    Light Cycle Oil

    Heavy Cycle Oil

    Lubricants unit

    asphalt

    Waxes

    Lubricants

    Vacuumdistillation

    Gase

    s

    Vacuum residue

    He

    avyVacuum

    gasoil

    FluidCatalyticCracking

    Visbreaking

    Crude(s)oil(s)

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    Residues

    from distillation processes

    from conversion processes

    Distillates (cutter stock)

    from distillation processes

    from conversion processes

    Small Amount of cutter stock add to residues in order to achievSmall Amount of cutter stock add to residues in order to achieve thee the

    commercial requirements:commercial requirements:

    viscosity mainlyviscosity mainly

    Heavy Fuel Oil

    Chemical composition of HFO depend on:Chemical composition of HFO depend on:

    chemical composition of crude(s) oil(s)chemical composition of crude(s) oil(s)

    nature and number of refinery processnature and number of refinery process

    commercial requirementscommercial requirements

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    Properties of Heavy Fuel OilProperties of Heavy Fuel Oil

    Rather than typical values, HFO properties have to achieve maxima

    values principally for :

    other properties (needed for the purchaser)

    density

    viscosity (cSt) @ 50C or 100C

    flash point

    sulfur content

    pour point ash, asphaltene, vanadium, aluminium content

    calorific value

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    HFOAtmosphericdistillation

    distillate

    Gases+

    Naphta

    Gas oil

    Atmosphericresidue

    Visbreakergas oil

    Gases Visbreakerdistillate

    Visbreaker residue

    Gases

    FCCdistillate

    Light Cycle Oil

    Heavy Cycle Oil

    Lubricants unit

    asphalt

    Waxes

    Lubricants

    Vacuumdistillation

    Gases

    Vacuum residue

    HeavyVacuum

    gasoil

    FluidCatalyticCracking

    Visbreaking

    Atmosphericdistillation

    distillate

    Gases+

    Naphta

    Gas oil

    Atmosphericresidue

    Visbreakergas oil

    Gases Visbreakerdistillate

    Visbreaker residue

    Gases

    FCCdistillate

    Light Cycle Oil

    Heavy Cycle Oil

    Lubricants unit

    asphalt

    Waxes

    Lubricants

    Vacuumdistillation

    Gases

    Vacuum residue

    HeavyVacuum

    gasoil

    FluidCatalyticCracking

    Visbreaking

    HEAVY FUEL OILS:HEAVY FUEL OILS:

    Different classifications for different usesDifferent classifications for different uses

    Residual Burner Fuel OilsResidual Burner Fuel Oils

    (RFO)(RFO)

    Thermal and Power Plant

    Marine Bunker Fuel OilsMarine Bunker Fuel Oils

    Ships

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    Residual Burner Fuel Oils classificationsResidual Burner Fuel Oils classifications

    British classification (BS 2869):

    Light Fuel Oil (E)

    Medium Fuel Oil (F) Heavy Fuel Oil (G)

    Main parameter of classification

    viscosity

    Russian classification (GOST- 10585-99): M-40

    M-100viscosity

    US classification (ASTM D396-80): N5 Fuel Oil N6 Fuel Oil

    viscosity

    French classification (AFNOR): Fioul Lourd TBTS Fioul Lourd BTS

    Fioul Lourd HTS

    Sulfur content

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    Marine Bunker Fuel Oils classificationsMarine Bunker Fuel Oils classifications

    IFO (Intermediate Fuel Oil) grades

    Based on Viscosity (Based on Viscosity (cStcSt) at 50C) at 50C

    14 grades from IFO14 grades from IFO--30 to IFO30 to IFO--460 available (IFO460 available (IFO--500; IFO 700)500; IFO 700)

    Most popular are IFOMost popular are IFO--180 and IFO180 and IFO--380380

    International (ISO) bunker fuel oil grades (ISO 8217:2005)

    Based on Viscosity (Based on Viscosity (cStcSt) at 50C) at 50C (instead of 100C)(instead of 100C)

    10 grades from RM10 grades from RM--30 to RM30 to RM--700 available700 available (instead of 15 grades)(instead of 15 grades)

    Additional letter is added to differentiate HFO with same viscosAdditional letter is added to differentiate HFO with same viscosityity

    according to various parameteraccording to various parameter (density, vanadium content, carbon residue, ...)(density, vanadium content, carbon residue, ...)

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    ProspectsProspects

    4 different Simulated distillation chromatograms of 4 different HFOsnevertheless classified in the same category.

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    THANK YOU FORTHANK YOU FOR

    YOUR ATTENTION !!YOUR ATTENTION !!

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    Classification and mainClassification and maincharacteristics of heavy fuel oilscharacteristics of heavy fuel oils

    Ronan JzquelRonan Jzquel

    CedreCedre

    Very Heavy Fuel OilWorkshop29-30 November 2006 - Brest France