COMPASS DRIVE. SUITE GRAND JUNCTION. COLORADO 970.245 · 1.1 . U_etco Mine..als Co....o .. ation ....
Transcript of COMPASS DRIVE. SUITE GRAND JUNCTION. COLORADO 970.245 · 1.1 . U_etco Mine..als Co....o .. ation ....
1.1 U_etco Mine..als Co....o .. ation 2754 COMPASS DRIVE. SUITE 280 GRAND JUNCTION. COLORADO 81 506 970.245.3700
May 31, 2013
Mr. Ryan Benefield Deputy Director Arkansas Department of Environmental Quality 530 I Northshore Drive North Little Rock, Arkansas 72118-5317
Subject: Data Submittal Umetco Minerals Corporation, Former Wilson Mine Site, Garland County, AR NPDES Permit AR0048950 Consent Administrative Order (CAO) LIS 07-095
Dear Mr. Benefield:
As part ofUmetco's ongoing commitment to proactive communication, enclosed is a CD with analytical data from October 2012 through March 2013. A map showing the sample locations is also provided on the CD.
Data for the following sample locations are included in this submittal:
a. Outfall 001: The permitted outfall to Wilson Creek. Results are reported to ADEQ on the monthly Discharge Monitoring Reports (DMRs).
h. WILL: Surface water sampling location on Wilson Creek downstream of Outfall 00 I and the reclamation area. Note that the WILL results are also provided to ADEQ as an attachment to the monthly DMRs.
c. IC07-A: Surface water sampling location on Indian Springs Creek downstream of Lecroy reclamation area. Note that the IC07-A results are also provided to ADEQ as an attachment to the monthly DMRs.
d. SDP-1: Surface water sample from the South Detention Pond, located in the South Lecroy Area. In addition to storm water, this sample location also includes water that is pumped from the Indian Springs Creek sump as well as seepage from the South Lecroy area, and is representative of the water that is pumped from the South Lecroy area to East Wilson Pond for treatment.
U Vanetco Mine:l'als CO:l'po:l'ation
Mr. Ryan Benefield May 31, 2013 Page 2
e. South I~ecroy Area Groundwater Monitoring Wells: Wells UT-l S, DT-lSR, UT-2S, DT-2S, UT-3S, DT-3S, UM04-21.2, UM04-21.3, and UM04-22. Monitoring well DT-lS was damaged during the South Lecroy reclamation improvements. The damaged well was subsequently abandoned and a new well installed adjacent to the abandoned DT-lS location on February 15,2013. The new well is designated DT -1 SR.
f. Spaulding Area Seep SPRD2: This seep is the source of water for the wetlands pilot test.
g. Spaulding Area Groundwater Monitoring Wells: Wells UM07-1, UM07-2, UM07-3, UM07-4, UM07-5, UM07-6, UM07-7, UM07-8, UM07-9, and UM07-10.
h. Seep05 Area: SEEP05-B. Note that SEEP05-A, SEEP05-C, SEEP05-D, and SEEP05-E were dry during this reporting period, so no samples were collected.
The data from the surface water sampling points on Wilson Creek (location WILL) and Indian Springs Creek (location IC07-A) that are downstream from the site reclamation areas show that the surface water leaving the site meets site-speeific hardness-based metals criteria.
Umetco remains committed to completing technically sound, long-term, sustainable and protective reclamation of the former Wilson Mine. Please feel free to contact me at (215) 7857373 or bye-mail at if you have any questions or would like to arrange a meeting to discuss the submitted materials.
Sincerely,
James F. Strunk, Jr. Remediation Leader Authorized Representative Umetco Minerals Corporation
Enclosures
cc: M. Shafii, Assistant Chief, Water Division, ADEQ 1. Ewing, Counsel, ADEQ A. Eckert, Esquire, Quattlebaum, Grooms, Tull & Burrow
Umetco Former Wilson Mine, Garland County, Arkansas
Semi-Annual Report for Surface Water
October 2012 through March 2013
Analyte
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Umetco Former Wilson Mine, Garland County, Arkansas
Semi-Annual Report for Surface Water
October 2012 through March 2013
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Umetco Former Wilson Mine, Garland County, Arkansas
Semi-Annual Report for Surface Water
October 2012 through March 2013
Analyte
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Semi-Annual Report for Surface Water October 2012 through March 2013
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Semi-Annual Report for Surface Water
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Umetco Former Wilson Mine, Garland County, Arkansas
Semi-Annual Report for Surface Water October 2012 through March 2013
Umetco Former Wilson Mine, Garland County, Arkansas
Semi-Annual Report for Surface Water
October 2012 through March 2013
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Umetco Former Wilson Mine, Garland County, Arkansas
Semi-Annual Report for Surface Water
October 2012 through March 2013
I.ocation Date sample ~_rtx
Ana1vte . ..
TotaJor Dissolved I. Result ••
Re~~~gLimit ~t IsDetf,l~~1
1 11 .>
,; .i
\1. Valldiilttori-Qualifier(s}
OUTFALL 001 12/03/12 SW Chloride Total 15 1 Yes mg/L
OUTFALL 001 12/03/12 SW Field Conductivity Total 661 Yes uS/em
OUTFALL 001 12/03/12 SW Field pH Total 7.09 Yes s.u.
OUTFALL 001 12/03/12 SW Field Temperature Total 14.7 Yes degrees C
OUTFALL 001 12/03/12 SW Sulfate Total 248 10 Yes mg/L
OUTFALL 001 12/03/12 SW Total Dissolved Solids Total 450 10 Yes mg/L
OUTFALL 001 12/03/12 SW Zinc Total 0.036 0.002 Yes mg/L
OUTFALL 001 12/10/12 SW Arsenic Total < 0.0002 0.0002 No mg/L
OUTFALL 001 12/10/12 SW Arsenic Total < 0.0002 0.0002 No mg/L
OUTFALL 001 12/10/12 SW Beryllium Total < 0.00005 0.00005 No mg/L
OUTFALL 001 12/10/12 SW Beryllium Total < 0.00005 0.00005 No mg/L
OUTFALL 001 12/10/12 SW Cadmium Total 0.0003 0.0001 Yes mg/L J OUTFALL 001 12/10/12 SW Cadmium Total 0.0003 0.0001 Yes mg/L J OUTFALL 001 12/10/12 SW Chloride Total 16 1 Yes mg/L
OUTFALL 001 12/10/12 SW Chloride Total 16 1 Yes mg/L
OUTFALL 001 12/10/12 SW Field Conductivity Total 665 Yes uS/em
OUTFALL 001 12/10/12 SW Field pH Total 7.54 Yes S.u.
OUTFALL 001 12/10/12 SW Field Temperature Total 13.9 Yes degrees C
OUTFALL 001 12/10/12 SW Sulfate Total 267 20 Yes mg/L
OUTFALL 001 12/10/12 SW Sulfate Total 268 20 Yes mg/l
OUTFALL 001 12/10/12 SW Total Dissolved Solids Total 450 10 Yes mg/L
OUTFALL 001 12/10/12 SW Total Dissolved Solids Total 440 10 Yes mg/l
OUTFALL 001 12/10/12 SW Zinc Total 0.016 0.002 Yes mg/L
OUTFALL 001 12/10/12 SW Zinc Total 0.016 0.002 Yes mg/L
OUTFALL 001 12/17/12 SW Arsenic Total 0.0003 0.0002 Yes mg/L J
OUTFALL 001 12/17/12 SW Beryllium Total 0.00008 0.00005 Yes mg/L J
OUTFALL 001 12/17/12 SW Cadmium Total 0.0005 0.0001 Yes mg/L J OUTFALL 001 12/17/12 SW Chloride Total 14 1 Yes mg/L
OUTFAll 001 12/17/12 SW Field Conductivity Total 666 Yes uS/em
OUTFALL 001 12/17/12 SW Field pH Total 7.31 Yes S.u.
OUTFALL 001 12/17/12 SW Field Temperature Total 12.7 Yes degrees C
OUTFALL 001 12/17/12 SW Sulfate Total 245 20 Yes mg/L
OUTFALL 001 12/17/12 SW Total Dissolved Solids Total 430 10 Yes mg/L
OUTFALL 001 12/17/12 SW Zinc Total 0.035 0.002 Yes mg/L
OUTFALL 001 01/09/13 SW Arsenic Total 0.0003 0.0002 Yes mg/L J OUTFALL 001 01/09/13 SW Beryllium Total 0.00018 0.00005 Yes mg/L J OUTFALL 001 01/09/13 SW Cadmium Total 0.0008 0.0001 Yes mg/L OUTFALL 001 01/09/13 SW Chloride Total 13 1 Yes mg/L OUTFALL 001 01/09/13 SW Field Conductivity Total 564 Yes uS/em OUTFALL 001 01/09/13 SW Field pH Total 6.82 Yes S.u.
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Umetco Former Wilson Mine, Garland County, Arkansas
Semi-Annual Report for Surface Water
October 2012 through March 2013
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Semi-Annual Report for Surface Water
October 2012 through March 2013
\tt . i, ..
~rll!',' rOGatiOn . Date
OUTFALL 001 02/04/13 SW
OUTFALL 001 02/04/13 SW
OUTFALL 001 02/04/13 SW
OUTFALL 001 02/04/13 SW
OUTFAll 001 02/04/13 SW
OUTFAll 001 02/04/13 SW
OUTFALL 001 02/04/13 SW
OUTFALL 001 02/04/13 SW
OUTFAll 001 02/04/13 SW
OUTFALL 001 02/12/13 SW
OUTFALL 001 02/12/13 SW
OUTFALL 001 02/12/13 SW
OUTFALL 001 02/12/13 SW
OUTFALL 001 02/12/13 SW
OUTFALL 001 02/12/13 SW
OUTFALL 001 02/12/13 SW
OUTFALL 001 02/12/13 SW
OUTFALL 001 02/12/13 SW
OUTFALL 001 02/12/13 SW
OUTFALL 001 02/18/13 SW
OUTFALL 001 02/18/13 SW
OUTFALL 001 02/18/13 SW
OUTFALL 001 02/18/13 SW
OUTFALL 001 02/18/13 SW
OUTFALL 001 02/18/13 SW
OUTFALL 001 02/18/13 SW
OUTFALL 001 02/18/13 SW
OUTFALL 001 02/18/13 SW
OUTFALL 001 02/18/13 SW
OUTFALL 001 03/05/13 SW
OUTFALL 001 03/05/13 SW
OUTFAll 001 03/05/13 SW
OUTFAll 001 03/05/13 SW
OUTFALL 001 03/05/13 SW
OUTFALL 001 03/05/13 SW
OUTFALL 001 03/05/13 SW
OUTFALL 001 03/05/13 SW
OUTFALL 001 03/05/13 SW
OUTFALL 001 03/05/13 SW
OUTFALL 001 03/05/13 SW
II Ii !\,"'~;~£~~t:" Anal~e ~. I··jli~~l !!;\; r:';;;}~S41~'!' .••. Field Conductivity Total 569
Field pH Total 7.1
Field Temperature Total 12.1
Sulfate Total 226
Sulfate Total 229
Total Dissolved Solids Total 410
Total Dissolved Solids Total 410
Zinc Total 0.069
Zinc Total 0.069
Arsenic Total 0.0003
Beryllium Total 0.00007
Cadmium Total 0.0005
Chloride Total 14
Field Conductivity Total 596
Field pH Total 7.44
Field Temperature Total 10.2
Sulfate Total 227
Total Dissolved Solids Total 390
Zinc Total 0.03
Arsenic Total < 0.0002
Beryllium Total < 0.00005
Cadmium Total 0.0004
Chloride Total 16
Field Conductivity Total 556
Field pH Total 7.32
Field Temperature Total 10.6
Sulfate Total 236
Total Dissolved Solids Total 420
Zinc Total 0.029
Arsenic Total 0.0002
Arsenic Total < 0.0002
Beryllium Total 0.00012
Beryllium Total 0.00012
Cadmium Total 0.0007
Cadmium Total 0.0007
Chloride Total 11 Chloride Total 12
Field Conductivity Total 593
Field pH Total 7.07
Field Temperature Total 8.4
t;;I~IJ:!l_' J:i~j;;~~~~d? "~.'.y~ .;!.\i,·'·;·;Llr".. C',." " Yes uS/cm
Yes s.u.
Yes degrees C
20 Yes mg/L
20 Yes mg/l
10 Yes mg/L
10 Yes mg/l
0.002 Yes mg/l
0.002 Yes mg/l
0.0002 Yes mg/L J 0.00005 Yes mg/l J 0.0001 Yes mg/l J
1 Yes mg/l
Yes US/em
Yes s.u.
Yes degrees C
20 Yes mg/L
10 Yes mg/L
0.002 Yes mg/L
0.0002 No mg/L
0.00005 No mg/L
0.0001 Yes mg/L J 1 Yes mg/L
Yes uS/cm
Yes s.u.
Yes degrees C
10 Yes mg/L
10 Yes mg/L
0.002 Yes mg/L
0.0002 Yes mg/L J 0.0002 No mg/L
0.00005 Yes mg/L J 0.00005 Yes mg/L J !
0.0001 Yes mg/L !
0.0001 Yes mg/L
1 Yes mg/L .
1 Yes mg/L
Yes uS/cm
Yes s.U.
Yes degrees C
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Semi-Annual Report for Surface Water
October 2012 through March 2013
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October 2012 through March 2013
_._"""'f"";;~alyte .......~?".?;; ,) ii Retutt 1'= llm)tf "i;;, ~~';;!!i<;;Units Vali~ation
location Date MatriK
"
0V~~ Dlssolve.Ol 'ii iii;;. ; ., ' I'leteete:'d 1.: qualifier(s} SDP-1 01/17/13 SW Lead Total 0.0002 0.0001 Yes mg/L J SDP-1 01/17/13 SW Magnesium Dissolved 41.9 0.2 Yes
SDP-1 01/17/13 SW Manganese Dissolved 44.3 0.005 Yes
SDP-1 01/17/13 SW Manganese Total 45.4 0.005 Yes
SDP-1 01/17/13 SW Nickel Dissolved 0.157 0.0006 Yes
SDP-1 01/17/13 SW Nickel Total 0.174 0.0006 Yes
SDP-1 01/17/13 SW Potassium Dissolved 7.7 0.3 Yes mg/L
SDP-1 01/17/13 SW Silica Dissolved 17.1 0.4 Yes mg/L
SDP-1 01/17/13 SW Silica Total 16.4 0.4 Yes mg/L
SDP-1 01/17/13 SW Sodium Dissolved 11.4 0.3 Yes mg/L
SDP-1 01/17/13 SW Sulfate Total 686 5 Yes mg/L
SDP-1 01/17/13 SW Total Dissolved Solids Total 1110 10 Yes mg/L
SDP-1 01/17/13 SW Total Suspended Solids Total 37 5 Yes mg/L
SDP-1 01/17/13 SW Zinc Dissolved 0.63 0.Q1 Yes mg/L
SDP-1 01/17/13 SW Zinc Total 0.65 0.01 Yes mg/L
SDP-1 02/25/13 SW Acidity (as CaC03) Total 190 10 Yes mg/L
SDP-1 02/25/13 SW Alkalinity, Bicarbonate (as CaC03) Total 6 2 Yes mg/L
SDP-1 02/25/13 SW Alkalinity, Carbonate (as CaC03) Total <2 2 No mg/L
SDP-1 02/25/13 SW Alkalinity, Total (as CaC03) Total 6 2 Yes mg/L
SDP-1 02/25/13 SW Aluminum Dissolved 3.44 0.03 Yes mg/L
SDP-1 02/25/13 SW Aluminum Total 3.68 0.06 Yes mg/L
SDP-1 02/25/13 SW Cadmium Dissolved 0.0059 0.0001 Yes mg/L
SDP-1 02/25/13 SW Cadmium Total 0.0063 0.0001 Yes mg/L
SDP-1 02/25/13 SW Calcium Dissolved 227 0.2 Yes mg/L
SDP-1 02/25/13 SW Chloride Total 25 2.5 Yes me:IL
SDP-1 02/25/13 SW Copper Dissolved 0.0079 0.0005 Yes
SDP-1 02/25/13 SW Copper Total 0.0083 0.0005 Yes
SDP-1 02/25/13 SW Field Conductivity Total 1515 Yes
SDP-1 02/25/13 SW Field pH Total 5.66 Yes
SDP-1 02/25/13 SW Field Temperature Total 9 Yes
02/25/13 SW Hardness (as CaC03) Total 794 1
02/25/13 SW Iron Dissolved 27.1 0.02
02/25/13 SW Iron Total 30 0.02
SDP-1 02/25/13 SW Lead Dissolved < 0.0001 0.0001
SDP-1 02/25/13 SW Lead Total 0.0003 0.0001 Yes
SDP-1 02/25/13 SW Magnesium Dissolved 55.1 0.2 Yes mg/L SDP-1 02/25/13 SW Manganese Dissolved 63.6 0.005 Yes mg/L SDP-1 02/25/13 SW Manganese Total 63.8 0.01 Yes mg/L SDP-1 02/25/13 SW Nickel Dissolved 0.240 0.0006 Yes mg/L SDP-l 02/25/13 SW Nickel Total 0.231 0.0006 Yes mg/L
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Semi-Annual Report for Surface Water
October 2012 through March 2013
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Umetco Former Wilson Mine, Garland County, Arkansas
Semi-Annual Report for Surface Water
October 2012 through March 2013
location D"~e,i
Sample .. ,
Ma~ri~ .. :llil:[. "
Analyte .,. ~=:::V:d~ [lli{~~Ult ", I'· p~~~;;;,;~ II!l~ ~~~lt·'1jWI!~Vnl~f. Validation Qualifier(s)
WILL 02/11/13 SW Zinc Dissolved 0.02 0.01 Yes mg/L J WILL 03/11/13 SW Cadmium Dissolved 0.0004 0.0001 Yes mg/L J WILL 03/11/13 SW Calcium Dissolved 86.7 0.2 Yes mg/L
WILL 03/11/13 SW Chloride Total 15 1 Yes mg/L
WILL 03/11/13 SW Chromium Dissolved < 0.0005 0.0005 No mg/L
WILL 03/11/13 SW Copper Dissolved < 0.0005 0.0005 No mg/L
WILL 03/11/13 SW Field Conductivity Total 578 Yes uS/cm
WILL 03/11/13 SW Field pH Total 7.23 Yes s.u.
WILL 03/11/13 SW Field Temperature Total 11.5 Yes degrees C
WILL 03/11/13 SW Hardness (as CaC03) Total 266 1 Yes mg/l
WILL 03/11/13 SW Iron Dissolved < 0.02 0.02 No mg/l
WILL 03/11/13 SW Lead Dissolved < 0.0001 0.0001 No mg/l
WILL 03/11/13 SW Magnesium Dissolved 12.1 0.2 Yes mg/L
WILL 03/11/13 SW Nickel Dissolved 0.0289 0.0006 Yes mg/l
WILL 03/11/13 SW Sulfate Total 230 20 Yes mg/l
WilL 03/11/13 SW Total Dissolved Solids Total 410 10 Yes mg/L
WILL 03/11/13 SW Total Suspended Solids Total <2 2 No mg/L
WilL 03/11/13 SW Zinc Dissolved 0.03 0.01 Yes mg/L J Notes: SW =surface water; mg/L = milligrams per liter; uS/cm = microSeimens per centimeter; s.u. standard units; degrees C degrees Centigrade; < =less than; J = estimated result
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Umetco Former Wilson Mine, Garland County, Arkansas
Semi-Annual Report for Groundwater
October 2012 through March 2013
, '" !-ocation :Iii D~t~i "
,', Sample Matrix ;, ,Analyte .y
' " Qi~=L!It'!:iml; ',Result " '11111~'t"
15 Detected?
i{~~.? ,iii:ji ~i~~_:t~;lL;;Unlu. .:.f. ";'}!ifl): ,;M(:Yij
DT-1SR 03/21/13 GW Acidity (as CaC03) Total 400 10 Yes mg/L
DT-1SR 03/21/13 GW Alkalinity, Bicarbonate (as CaC03) Total 237 2 Yes mg/L
DT-1SR 03/21/13 GW Alkalinity, Carbonate (as CaC03) Total <2 2 No mg/L
DT-1SR 03/21/13 GW Alkalinity, Total (as CaC03) Total 237 2 Yes mg/L
DT-1SR 03/21/13 GW Aluminum Dissolved 0.05 0.03 Yes mg/L
DT-1SR 03/21/13 GW Aluminum Total 1.78 0.06 Yes mg/L
DT-1SR 03/21/13 GW Cadmium Dissolved < 0.0002 0.0002 No mg/L
DT-1SR 03/21/13 GW Cadmium Total < 0.0002 0.0002 No mg/L
DT-1SR 03/21/13 GW Calcium Dissolved 528 0.2 Yes mg/L
DT-1SR 03/21/13 GW Chloride Total 221 25 Yes mg/L
DT-1SR 03/21/13 GW Copper Dissolved < 0.001 0.001 No mg/L
DT-1SR 03/21/13 GW Copper Total 0.001 0.001 Yes mg/L
DT-lSR 03/21/13 GW Field Conductivity Total 3620 Yes uS/cm
DT-1SR 03/21/13 GW Field pH Tota! 6.04 Yes s.u.
DT-1SR 03/21/13 GW Field Temperature Tota! 15.5 Yes degrees C
DT-1SR 03/21/13 GW Hardness (as CaC03) Total 1740 1 Yes mg/L
DT-1SR 03/21/13 GW Iron Dissolved 98.1 0.02 Yes mg/L
DT-1SR 03/21/13 GW Iron Total 99.3 0.04 Yes mg/L
DT-1SR 03/21/13 GW Magnesium Dissolved 102 0.2 Yes mg/L
DT-lSR 03/21/13 GW Manganese Dissolved 176 0.03 Yes mg/L
DT-1SR 03/21/13 GW Manganese Total 170 0.01 Yes mg/L
DT-1SR 03/21/13 GW Nickel Dissolved 0.005 0.001 Yes mg/l
DT-1SR 03/21/13 GW Nickel Total 0.008 0.001 Yes mg/L
DT-lSR 03/21/13 GW Potassium Dissolved 8.3 0.3 Yes mg/L
DT-lSR 03/21/13 GW Silica Dissolved 10.9 0.4 Yes mg/L
DT-lSR 03/21/13 GW Silica Total 13.5 0.9 Yes mg/L
DT-lSR 03/21/13 GW Sodium Dissolved 74.2 0.3 Yes mg/L
DT-1SR 03/21/13 GW Sulfate Total 1855 25 Yes mg/L
DT-1SR 03/21/13 GW Total Dissolved Solids Total 3270 10 Yes mg/L DT-1SR 03/21/13 GW Zinc Dissolved 0.05 0.01 Yes mg/L
DT-1SR 03/21/13 GW Zinc Total 0.05 0.02 Yes mg/L DT-2S 10/03/12 GW Field Conductivity Total 2875 Yes uS/cm DT-2S 10/03/12 GW Field pH Total 6.2 Yes s.u.
DT-2S 10/03/12 GW Field Temperature Total 23.7 Yes degrees C
DT-2S 10/05/12 GW Aluminum Dissolved < 0.018 0.018 No mg/L DT-2S 10/05/12 GW Aluminum Total < 0.018 0.018 No mg/L DT-2S 10/05/12 GW Cadmium Dissolved < 0.0001 0.0001 No mg/L
DT-2S 10/05/12 GW Cadmium Total 0.00013 0.0001 Yes mg/l J DT-2S 10/05/12 GW Calcium Dissolved 560 0.035 Yes mg/L
DT-2S 10/05/12 GW Copper Dissolved < 0.00056 0.00056 No mg/l
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Umetco Former Wilson Mine, Garland County, Arkansas Semi-Annual Report for Groundwater
October 2012 through March 2013
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October 2012 through March 2013
Location Date
DT-2S
DT-2S
DT-2S
DT-2S
DT-2S
DT-2S
DT-2S
DT-2S
DT-2S DT-2S
DT-2S
DT-2S
DT-2S
DT-2S
DT-2S
DT-2S
DT-2S
DT-2S
DT-2S
DT-2S
DT-2S
DT-2S
DT-2S
DT-2S
DT-2S
DT-2S
DT-2S /13 DT-2S 3/13 DT-2S 23/13 DT-2S 01/23/13 DT-2S 01/23/13 DT-2S 01/23/13 DT-2S 01/23/13 DT-2S 01/23/13 DT-2S 01/23/13 DT-2S 01/23/13 DT-2S 01/23/13 DT-2S 01/23/13 DT-2S 01/23/13 DT-2S 01/23/13
Sample M~tri)(
GW
GW GW
Anal~e
erature
s CaC03)
Totalory,:, Dis50Ivl!~r;;%··
Total
Total
GW Iron Total 0.49 0.04 Yes GW Magnesium Dissolved 85.6 0.2 Yes _.
GW Manganese Dissolved 1.53 0.005 Yes mg/l
GW Manganese Total 1.71 0.01 Yes mg/l
GW Nickel Dissolved 0.003 0.001 Yes mg/l
GW INickel Total 0.004 0.001 Yes mg/l
GW IPotassium Dissolved 9.7 0.3 Yes mg/l
GW ISilica Dissolved 57.5 0.4 Yes mg/l
GW ISilica Total 51.2 0.9 Yes mg/l
GW ISodium Dissolved 23.3 0.3 Yes mg/l
GW ISulfate Total 1580 25 Yes mg/l
GW ITotal Dissolved Solids Total 2830 10 Yes mg/L
GW Zinc Dissolved 0.02 0.01 Yes mg/l
Zinc Total < 0.02 0.02 No mg/l
Acidity (as CaC03) Total < 10 10 No mg/L
Alkalinity, Bicarbonate (as CaC03) Total 390 2 Yes mg/L
Alkalinity, Carbonate (as CaC03) Total < 2 2 No mg/L
Total (as CaC03) Total 390 2 Yes mg/l
Yes mg/l GW Aluminum Yes mg/l GW Cadmium No mg/L GW Cadmium No mg/L GW Calcium Yes mg/L GW Chloride Yes GW Copper No GW Copper No GW Field Conductivity Yes GW Field pH Yes GW Field Temperature Yes GW Hardness (as CaC03) Total 2020 1 Yes
GW Iron Dissolved < 0.02 0.02 No GW Iron Total 0.23 0.04 Yes GW Magnesium Dissolved 93.1 0.2 Yes GW Manganese Dissolved 2.29 0.005 Yes GW Manganese Total 1.5 0.01 Yes mg/l GW Nickel Dissolved 0.014 0.001 Yes mg/l GW Nickel Total 0.005 0.001 Yes mg/L
;\f<llidation ~u~lffie~s)
Umetco Former Wilson Mine, Garland County, Arkansas
Semi-Annual Report for Groundwater October 2012 through March 2013
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Semi-Annual Report for Groundwater
October 2012 through March 2013
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October 2012 through March 2013
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Umetco Former Wilson Mine, Garland County, Arkansas
Semi-Annual Report for Groundwater
October 2012 through March 2013
Location Date Sample
Matrix Analyte
Total or Dissolved
Result Reporting
Limit .•.. I$;.
DetEicted? Units
Validation
Qualifler{s)
UM04-21.3 01/17/13 GW Cadmium Dissolved < 0.0001 0.0001 No mg/L
UM04-21.3 01/17/13 GW Cadmium Total < 0.0001 0.0001 No mg/L
UM04-21.3 01/17/13 GW Cadmium Total < 0.0001 0.0001 No mg/L
UM04-21.3 01/17/13 GW Calcium Dissolved 322 0.2 Yes mg/L
UM04-21.3 01/17/13 GW Calcium Dissolved 323 0.2 Yes mg/L
UM04-21.3 01/17/13 GW Chloride Total 143 10 Yes mg/L
UM04-21.3 01/17/13 GW Chloride Total 143 5 Yes mg/L
UM04-21.3 01/17/13 GW Copper Dissolved < 0.01 0.01 No mg/L
UM04-21.3 01/17/13 GW Copper Dissolved < 0.01 0.01 No mg/L
UM04-21.3 01/17/13 GW Copper Total < 0.01 0.01 No mg/L
UM04-21.3 01/17/13 GW Copper Total < 0.01 0.01 No mg/L
UM04-21.3 01/17/13 GW Field Conductivity Total 1482 Yes uS/cm
UM04-21.3 01/17/13 GW Field pH Total 6.96 Yes s.u.
UM04-21.3 01/17/13 GW Field Temperature Total 16 Yes degrees C
UM04-21.3 01/17/13 GW Iron Dissolved 3.29 0.02 Yes mg/L
UM04-21.3 01/17/13 GW Iron Dissolved 3.27 0.02 Yes mg/L
UM04-21.3 01/17/13 GW Iron Total 3.33 0.02 Yes mg/L
UM04-21.3 01/17/13 GW Iron Total 3.28 0.02 Yes mg/L
UM04-21.3 01/17/13 GW Magnesium Dissolved 47.6 0.2 Yes mg/L
UM04-21.3 01/17/13 GW Magnesium Dissolved 47.6 0.2 Yes mg/L
UM04-21.3 01/17/13 GW Manganese Dissolved 0.273 0.005 Yes mg/L
UM04-21.3 01/17/13 GW Manganese Dissolved 0.272 0.005 Yes mg/L
UM04-21.3 01/17/13 GW Manganese Total 0.267 0.005 Yes mg/L
UM04-21.3 01/17/13 GW Manganese Total 0.274 0.005 Yes mg/L
UM04-21.3 01/17/13 GW Nickel Dissolved < 0.01 0.01 No mg/L
UM04-21.3 01/17/13 GW Nickel Dissolved < 0.01 0.01 No mg/L
UM04-21.3 01/17/13 GW Nickel Total <0.01 0.01 No mg/L
UM04-21.3 01/17/13 GW Nickel Total < 0.01 0.01 No mg/L
UM04-21.3 01/17/13 GW Potassium Dissolved 8.1 0.3 Yes mg/L UM04-21.3 01/17/13 GW Potassium Dissolved 8.1 0.3 Yes mg/L UM04-21.3 01/17/13 GW Silica Dissolved 33.6 0.4 Yes mg/L
UM04-21.3 01/17/13 GW Silica Dissolved 33.6 0.4 Yes mg/L UM04-21.3 01/17/13 GW Silica Total 30.1 0.4 Yes mg/L UM04-21.3 01/17/13 GW Silica Total 30 0.4 Yes mg/L UM04-21.3 01/17/13 GW Sodium Dissolved 28 0.3 Yes mg/L UM04-21.3 01/17/13 GW Sodium Dissolved 28 0.3 Yes mg/L UM04-21.3 01/17/13 GW Sulfate Total 524 10 Yes mg/L UM04-21.3 01/17/13 GW Sulfate Total 530 5 Yes mg/L UM04-21.3 01/17/13 GW Total Dissolved Solids Total 1320 10 Yes mg/L UM04-21.3 01/17/13 GW Total Dissolved Solids Total 1330 10 Yes mg/L
Umetco Former Wilson Mine, Garland County, Arkansas
Semi-Annual Report for Groundwater
October 2012 through March 2013
Page 10 of 37
Umetco Former Wilson Mine, Garland County, Arkansas
Semi-Annual Report for Groundwater
October 2012 through March 2013
.' 'ii 111
~O\l~tiOl1dl i &a~e ,. Sample
Matti" ' .. I >.: i;rr;U AoalytT Totator
Dissolved Res~~~i~1 ;, Reporting
Limit 11~1',Is~, \.i~" .i,y~I~'i:i :ilyalid~],o~ ;t!A~alifier(s)
UM04-22 01/17/13 GW Cadmium Dissolved < 0.0001 0.0001 No mg/L
UM04-22 01/17/13 GW Cadmium Total < 0.0001 0.0001 No mg/L UM04-22 01/17/13 GW Calcium Dissolved 572 0.2 Yes mg/L
UM04-22 01/17/13 GW Chloride Total 196 10 Yes mg/L
UM04-22 01/17/13 GW Copper Dissolved <0.01 0.01 No mg/L
UM04-22 01/17/13 GW Copper Total <0.02 0.02 No mg/L
UM04-22 01/17/13 GW Field Conductivity Total 3140 Yes uS/cm
UM04-22 01/17/13 GW Field pH Total 5.95 Yes s.u.
UM04-22 01/17/13 GW Field Temperature Total 17.5 Yes degrees C
UM04-22 01/17/13 GW Iron Dissolved 10.7 0.02 Yes mg/L
UM04-22 01/17/13 GW Iron Total 16.1 0.04 Yes mg/L
UM04-22 01/17/13 GW Magnesium Dissolved 70.8 0.2 Yes mg/L
UM04-22 01/17/13 GW Manganese Dissolved 5.86 0.005 Yes mg/l UM04-22 01/17/13 GW Manganese Total 6.21 0.01 Yes mg/L UM04-22 01/17/13 GW Nickel Dissolved 0.01 0.01 Yes mg/L UM04-22 01/17/13 GW Nickel Total < 0.02 0.02 No mg/L UM04-22 01/17/13 GW Potassium Dissolved 9.4 0.3 Yes mg/L UM04-22 01/17/13 GW Silica Dissolved 49.9 0.4 Yes mg/l
UM04-22 01/17/13 GW Silica Total 48.2 0.9 Yes mg/L UM04-22 01/17/13 GW Sodium Dissolved 32.9 0.3 Yes mg/L UM04-22 01/17/13 GW Sulfate Total 1377 10 Yes mg/l UM04-22 01/17/13 GW Total Dissolved Solids Total 2580 10 Yes mg/L UM04-22 01/17/13 GW Zinc Dissolved < 0.01 0.01 No mg/L UM04-22 01/17/13 GW Zinc Total < 0.02 0.02 No mg/L UM07-1 11/08/12 GW Acidity (as CaC03) Total < 10 10 No mg/L UM07-1 11/08/12 GW Acidity (as CaC03) Total < 10 10 No mg/L UM07-1 11/08/12 GW Alkalinity, Bicarbonate (as CaC03) Total 54 2 Yes mg/L UM07-1 11/08/12 GW Alkalinity, Bicarbonate (as CaC03) Total 52 2 Yes mg/L UM07-1 11/08/12 GW Alkalinity, Carbonate (as CaC03) Total <2 2 No mg/L UM07-1 11/08/12 GW Alkalinity, Carbonate (as CaC03) Total <2 2 No mg/l UM07-1 11/08/12 GW Alkalinity, Total (as CaC03) Total 54 2 Yes mg/L UM07-1 11/08/12 GW Alkalinity, Total (as CaC03) Total 52 2 Yes mg/l UM07-1 11/08/12 GW Aluminum Dissolved <0.03 0.03 No mg/L UM07-1 11/08/12 GW Aluminum Dissolved <0.03 0.03 No mg/L UM07-1 11/08/12 GW Aluminum Total 1.6 0.03 Yes mg/L J UM07-1 11/08/12 GW Aluminum Total 1.66 0.03 Yes mg/l J UM07-1 11/08/12 GW Cadmium Dissolved < 0.0001 0.0001 No mg/L UM07-1 11/08/12 GW Cadmium Dissolved < 0.0001 0.0001 No mg/l UM07-1 11/08/12 GW Cadmium Total 0.0002 0.0001 Yes mg/l J UM07-1 11/08/12 GW Cadmium Total 0.0002 0.0001 Yes mg/L J
Page 11 of 37
Umetco Former Wilson Mine, Garland County, Arkansas Semi-Annual Report for Groundwater
October 2012 through March 2013
Page 12 of 37
Umetco Former Wilson Mine, Garland County, Arkansas
Semi-Annual Report for Groundwater
October 2012 through March 2013
Page 13 of 37
Umetco Former Wilson Mine, Garland County, Arkansas
Semi-Annual Report for Groundwater
October 2012 through March 2013
II, '""en ~'::i: :t ,'; ::<.~,J I'.:i'o.::w,,:,,,:',"':, ':':~tl1i::
UM07-1 03/25/13 GW
UM07-1 03/25/13 GW
UM07-1 03/25/13 GW
UM07-1 03/25/13 GW
UM07-l 03/25/13 GW
UM07-l 03/25/13 GW
UM07-l 03/25/13 GW
UM07-l 03/25/13 GW
UM07-l 03/25/13 GW
UM07-l 03/25/13 GW
UM07-l 03/25/13 GW
UM07-l 03/25/13 GW UM07-l 03/25/13 GW
UM07-l 03/25/13 GW
UM07-l 03/25/13 GW
UM07-l 03/25/13 GW
UM07-l 03/25/13 GW
UM07-1 03/25/13 GW
UM07-1 03/25/13 GW
UM07-1 03/25/13 GW
UM07-1 03/25/13 GW
UM07-1 03/25/13 GW
UM07·1 03/25/13 GW
UM07·1 03/25/13 GW
UM07·1 03/25/13 GW UM07-l 03/25/13 GW
UM07·1 03/25/13 GW
UM07·1 03/25/13 GW
UM07·1 03/25/13 GW
UM07-1 03/25/13 GW
UM07·10 11/08/12 GW
UM07·1Q 11/08/12 GW
UM07·10 11/08/12 GW
UM07·10 11/08/12 GW
UM07·10 11/08/12 GW
UM07-10 11/08/12 GW
UM07-1O 11/08/12 GW
UM07-10 11/08/12 GW
UM07·10 11/08/12 GW
UM07·1O 11/08/12 GW
~:m~~I' .1Jl')Y'!#lI',' Total or 'LII~~lt. ·fey :.:", Dissolved
Lead Dissolved < 0.0001
Lead Dissolved < 0.0001
Lead Total 0.002
Lead Total 0.001
Magnesium Dissolved 2.4
Magnesium Dissolved 2.6
Manganese Dissolved 1.34 Manganese Dissolved 1.93 Manganese Total 1.42 Manganese Total 1.47
Nickel Dissolved 0.0019
Nickel Dissolved 0.002
Nickel Total 0.0051
Nickel Total 0.0035
Potassium Dissolved 6.2
Potassium Dissolved 6.1
Silica Dissolved 36.1
Silica Dissolved 36.6
Silica Total 34.8
Silica Total 35.7
Sodium Dissolved 4.9
Sodium Dissolved 4.8
Sulfate Total 14.4
Sulfate Total 14.4
Total Dissolved Solids Total 130
Total Dissolved Solids Total 120
Zinc Dissolved 0.028
Zinc Dissolved 0.036
Zinc Total 0.062
Zinc Total 0.073
Acidity (as CaC03) Total 570
Alkalinity, Bicarbonate (as CaC03) Total <2
Alkalinity, Carbonate (as CaC03) Total <2
Alkalinity, Total (as CaC03) Total <2
Aluminum Dissolved 72.5
Aluminum Total 80.3
Cadmium Dissolved 0.0288
Cadmium Total 0,0294
Calcium Dissolved 50
Chloride Total <5
Rep~rting >,15 Validation limitS:: ,'Pet.cted? •. Units,
Qualjf:i~~ts) :,,: 0.0001 No mg/L 0.0001 No mg/L 0.0001 Yes mg/L 0.0001 Yes mg/L
0.2 Yes mg/L 0.2 Yes mg/L
0.005 Yes mg/L
0.005 Yes mg/L 0.005 Yes mg/L 0.005 Yes mg/L 0.0006 Yes mg/L 0.0006 Yes mg/L 0.0006 Yes mg/L 0.0006 Yes mg/L
0.3 Yes mg/L 0.3 Yes mg/L
0.4 Yes mg/L
0.4 Yes mg/L
0.4 Yes mg/L
0.4 Yes mg/L
0.3 Yes mg/L 0.3 Yes mg/L
0.5 Yes mg/L 0.5 Yes mg/L
10 Yes mg/L
10 Yes mg/L
0.002 Yes mg/L
0.002 Yes mg/L 0.002 Yes mg/L
0.002 Yes mg/L
10 Yes mg/L 2 No mg/L 2 No mg/L 2 No mg/L
0.3 Yes mg/L
0.3 Yes mg/L J 0.0001 Yes mg/L 0.0001 Yes mg/L
2 Yes mg/L 5 No mg/L
Page 14 of 37
Umetco Former Wilson Mine, Garland County, Arkansas
Semi-Annual Report for Groundwater
October 2012 through March 2013
Umetco Former Wilson Mine, Garland County, Arkansas Semi-Annual Report for Groundwater
October 2012 through March 2013
Page 16 of 37
Umetco Former Wilson Mine, Garland County, Arkansas
Semi-Annual Report for Groundwater
October 2012 through March 2013
Page 17 of 37
Umetco Former Wilson Mine, Garland County, Arkansas
Semi·Annual Report for Groundwater
October 2012 through March 2013
Page 18 of 37
Umetco Former Wilson Mine, Garland County, Arkansas
Semi-Annual Report for Groundwater October 2012 through March 2013
. " . vciiitfationH
Location Units Qualifier{s) UM07-2 11/08/12 Calcium Dissolved 20.2 0.2 Yes mg/L
UM07-2 11/08/12 GW Chloride Total 2.3 1 Yes mg/L
11/08/12 GW Copper Dissolved 0.0008 0.0005 Yes mg/l
11/08/12 GW Copper Total < 0.0005 0.0005 No mg
UM07-2 I 11/08/12 I GW IField Conductivity Total 322 Yes u UM07-2 Field pH Total 6.11 Yes s.u.
UM07-2 Field Temperature Total 17.3 Yes d
UM07-2 I 11/08/12 I GW IHardness (as CaC03) Total 87 1 Yes mg/L
UM07-2 I 11/08/12 I GW IIron Dissolved 26.5 0.02 Yes mg/L
UM07-2 I 11/08/12 I GW Ilron Total 32.1 0.02 Yes mg/L UM07-2 11/08/12 GW Lead Dissolved < 0.0001 0.0001 No mg/L
UM07-2 11/08/12 GW Lead Total < 0.0001 0.0001 No mg/L
UM07-2 11/08/12 GW Magnesium Dissolved 8.9 0.2 Yes mg/l
UM07-2 11/08/12 GW Manganese Dissolved 6.09 0.005 Yes mg/l I I UM07-2 11/08/12 GW Manganese Total 6.63 0.005 Yes
UM07-2 11/08/12 GW Nickel Dissolved 0.0291 0.0006 Yes
UM07-2 11/08/12 GW Nickel Total 0.0289 0.0006 Yes
UM07-2 11/08/12 GW Potassium Dissolved 9.2 0.3 Yes l UM07-2 11/08/12 GW Silica Dissolved 48.9 0.4 Yes L UM07-2 11/08/12 GW Silica Total 44.7 0.4 L UM07-2 11/08/12 GW Sodium Dissolved 7.2 0.3 I Yes
UM07-2 I 11/08/12 I GW ISulfate Total 117 1 Yes mg/L
UM07-2 I 11/08/12 I GW ITotal Dissolved Solids Total 260 10 Yes mg/L
UM07-2 I 11/08/12 I GW IZinc Dissolved 0.052 0.002 Yes mg/L
UM07-2 I 11/08/12 I GW IZinc Total 0.048 0.002 Yes mg/L
UM07-2 I 03/26/13 I GW IAcidity (as CaC03) Total 30 10 Yes mg/l
UM07-2 I 03/26/13 I GW IAlkalinity, Bicarbonate (as CaC03) Total 31 2 Yes mg/l
UM07-2 Alkalinity, Carbonate (as CaC03) Total < 2 2 No mg/l
UM07-2 Alkalinity, Total (as CaC03) Total 31 2 Yes mg/l
UM07-2 I 03/26/13 I GW IAluminum Dissolved < 0.03 0.03 No mg/l
UM07-2 03/26/13 GW Aluminum Total 0.25 0.03 Yes mg/l UM07-2 03/26/13 GW Cadmium Dissolved 0.0002 0.0001 Yes mg/l
UM07-2 03/26/13 GW Cadmium Total 0.0004 0.0001 Yes mg/L
UM07-2 03/26/13 GW Calcium Dissolved 19.4 0.2 Yes mg/l
UM07-2 03/26/13 GW Chloride Total 3.5 1 Yes mg/l UM07-2 03/26/13 GW Copper Dissolved < 0.0005 0.0005 No mg/l
UM07-2 03/26/13 GW Copper Total 0.001 0.0005 Yes mg/L
UM07-2 03/26/13 GW Field Conductivity Total 340 Yes uS/cm I I UM07-2 03/26/13 GW Field pH Total 6.17 Yes s.u.
UM07-2 I 03/26/13 I GW IField Temperature Total 17.3 Yes I degrees C
Page 19 of 37
Umetco Former Wilson Mine, Garland County, Arkansas
Semi-Annual Report for Groundwater
October 2012 through March 2013
Page 20 of 37
Umetco Former Wilson Mine, Garland County, Arkansas
Semi-Annual Report for Groundwater
October 2012 through March 2013
Page 21 of 37
Umetco Former Wilson Mine, Garland County, Arkansas
Semi-Annual Report for Groundwater
October 2012 through March 2013
Page 22 of 37
Umetco Former Wilson Mine, Garland County, Arkansas Semi-Annual Report for Groundwater
October 2012 through March 2013
Page 23 of37
Umetco Former Wilson Mine, Garland County, Arkansas
Semi-Annual Report for Groundwater
October 2012 through March 2013
Page 24 of 37
Umetco Former Wilson Mine, Garland County, Arkansas
Semi-Annual Report for Groundwater
October 2012 through March 2013
Page 25 of 37
Umetco Former Wilson Mine, Garland County, Arkansas Semi-Annual Report for Groundwater
October 2012 through March 2013
my I_~~+l_~,;~ "'::~~1~;!ic ~;i;;~',i?;;:)'i··U!H!m:)n;;t iT,
UM07-6 11/08/12 GW UM07-6 11/08/12 GW UM07-6 11/08/12 GW UM07-6 11/08/12 GW UM07-6 11/08/12 GW UM07-6 11/08/12 GW UM07-6 11/08/12 GW UM07-6 11/08/12 GW UM07-6 11/08/12 GW UM07-6 03/26/13 GW UM07-6 03/26/13 GW UM07-6 03/26/13 GW UM07-6 03/26/13 GW UM07·6 03/26/13 GW UM07-6 03/26/13 GW UM07-6 03/26/13 GW UM07-6 03/26/13 GW UM07-6 03/26/13 GW UM07-6 03/26/13 GW UM07-6 03/26/13 GW UM07-6 03/26/13 GW UM07-6 03/26/13 GW UM07-6 03/26/13 GW UM07-6 03/26/13 GW UM07-6 03/26/13 GW UM07-6 03/26/13 GW UM07-6 03/26/13 GW UM07-6 03/26/13 GW UM07-6 03/26/13 GW UM07-6 03/26/13 GW UM07·6 03/26/13 GW UM07-6 03/26/13 GW UM07-6 03/26/13 GW UM07-6 03/26/13 GW UM07-6 03/26/13 GW UM07-6 03/26/13 GW UM07·6 03/26/13 GW UM07-6 03/26/13 GW UM07-6 03/26/13 GW UM07-6 03/26/13 GW
1!nilUl~l~jlmifmW' A~~,~~lillnmN,fi;mi ::' . 1;,;£'Jrm!Im~; !tllW Result....
Nickel Total 0.014
Potassium Dissolved 5.5
Silica Dissolved 33.3
Silica Total 30.9 Sodium Dissolved 2.4
Sulfate Total 4.0 Total Dissolved Solids Total 40
Zinc Dissolved 0.043
Zinc Total 0.044
Acidity (as CaC03) Total 10 Alkalinity, Bicarbonate (as CaC03) Total 9
Alkalinity, Carbonate (as CaC03) Total <2
Alkalinity, Total (as CaC03) Total 9
Aluminum Dissolved 0,05
Aluminum Total 1.26
Cadmium Dissolved 0.0003
Cadmium Total 0.0003
Calcium Dissolved 0.3
Chloride Total 2.5
Copper Dissolved < 0.0005
Copper Total 0.0019
Field Conductivity Total 114
Field pH Total 5.47
Field Temperature Total 17
Hardness (as CaC03) Total 10
Iron Dissolved 1.15
Iron Total 29.2
Lead Dissolved < 0.0001
Lead Total 0.0047
Magnesium Dissolved 2.3
Manganese Dissolved 0.132
Manganese Total 0.159
Nickel Dissolved 0.0121
Nickel Total 0.0141
Potassium Dissolved 5.2
Silica Dissolved 30.7
Silica Total 36.9
Sodium Dissolved 2.3
Sulfate Total 2.8
Total Dissolved Solids Total 60
'''·~;;r~~~i; ,'dk:dfr U~it5Iil!li Validation I
! Q~UfierrsV 0.0006 Yes mg/L
0.3 Yes mg/L 0.4 Yes mg/L 0.4 Yes mg/L J 0.3 Yes mg/L 0.5 Yes mg/L 10 Yes mg/L
0.002 Yes mg/L 0.002 Yes mg/L
10 Yes mg/L 2 Yes mg/L
2 No mg/L 2 Yes mg/L
0.03 Yes mg/L
0.03 Yes mg/L 0.0001 Yes mg/L
0.0001 Yes mg/L 0.2 Yes mg/L 0.5 Yes mg/L
0.0005 No mg/L 0.0005 Yes mg/L
Yes uS/cm Yes S.u.
Yes degrees C
1 Yes mg/L 0.02 Yes mg/L 0.02 Yes mg/L
0.0001 No mg/L
0.0001 Yes mg/L
0.2 Yes mg/L
0.005 Yes mg/L 0.005 Yes mg/L
0.0006 Yes mg/L
0.0006 Yes mg/L 0.3 Yes mg/L 0.4 Yes mg/L
0.4 Yes mg/L 0.3 Yes mg/L 0.5 Yes mg/L
10 Yes mg/L
Page 26 of 37
Umetco Former Wilson Mine, Garland County, Arkansas Semi-Annual Report for Groundwater
October 2012 through March 2013
Location salWPlt;Validatlon
Date .• . . . Matrix Qu"bfler{s)
UM07-6 03/26/13 GW Zinc 0.03 Yes UM07-6 03/26/13 I GW IZine Total 0.042 0.002 Yes mg/L UM07-7 11/07/12 I GW IAcidity (as CaC03) Total < 10 10 No mg/L UM07-7 11/07/12 GW Alkalinity, Bicarbonate (as (aC03) Total < 20 10 No mg/L
UM07-7 11/07/12 GW Alkalinity, Carbonate (as (aC03) Total < 2 2 No mg/L
UM07-7 11/07/12 GW Alkalinity, Total (as (a(03) Total < 20 10 No mg/L I UM07-7 11/07/12 GW Aluminum Dissolved 0.07 0.03 Yes mg/L J UM07-7 11/07/12 GW Aluminum Total 1.49 0.03 Yes mg/L J UM07-7 11/07/12 GW Cadmium Dissolved < 0.0001 0.0001 No mg/L
UM07-7 11/07/12 GW Cadmium Total 0.0001 0.0001 Yes mg/L UM07-7 11/07/12 GW Calcium Dissolved 1.4 0.2 Yes mg/L
UM07-7 I 11/07/12 I GW IChloride Total 2.2 0.5 Yes mg/L
UM07-7 I 11/07/12 I GW ICopper Dissolved 0.0009 0.0005 Yes mg/L
UM07-7 I 11/07/12 I GW ICopper Total 0.0032 0.0005 Yes mg/L
UM07-7 I 11/07/12 I GW IField Conductivity Total 110 Yes uS/em
UM07-7 I 11/07/12 I GW IField pH Total 5.6 Yes s.u. UM07-7 11/07/12 GW Field Temperature Total 15.3 Yes degrees C
UM07-7 11/07/12 GW Hardness (as CaC03) Total 13 1 Yes mg/L
UM07-7 11/07/12 GW Iron Dissolved 4.8 0.02 Yes mg/L
UM07-7 11/07/12 GW Iron Total 22.1 0.02 Yes mg/L
UM07-7 I 11/07/12 I GW ILead Dissolved < 0.0001 0.0001 No mg/L
UM07-7 I 11/07/12 I GW ILead Total 0.0029 0.0001 Yes mg/L UM07-7 I 11/07/12 I GW IMagnesium Dissolved 2.4 0.2 Yes mg/L
UM07-7 I 11/07/12 I GW IManganese Dissolved 1.78 0.005 Yes mg/L
UM07-7 I 11/07/12 I GW IManganese Total 2.08 0.005 Yes mg/L
UM07-7 I 11/07/12 I GW INickel Dissolved 0.0215 0.0006 Yes mg/L
UM07-7 11/07/12 GW Nickel Total 0.0263 0.0006 Yes mg/L
UM07-7 11/07/12 GW Potassium Dissolved 4.1 0.3 Yes mg/L
UM07-7 11/07/12 GW Silica Dissolved 20.7 0.4 Yes mg/L
UM07-7 11/07/12 GW Silica Total 21.7 0.4 Yes mg/L J
UM07-7 11/07/12 GW Sodium Dissolved 3.2 0.3 Yes mg/L UM07-7 11/07/12 GW Sulfate Total 17.3 0.5 Yes mg/L
UM07-7 11/07/12 GW Total Dissolved Solids Total 60 10 Yes mg/L
UM07-7 11/07/12 GW Zinc Dissolved 0.059 0.002 Yes mg/L
UM07-7 I 11/07/12 I GW IZinc Total 0.065 0.002 Yes mg/L
UM07-7 I 03/25/13 I GW IAcidity (as CaC03) Total < 10 10 No mg/L
UM07-7 I 03/25/13 I GW IAlkalinity, Bicarbonate (as CaC03) Total 27 2 Yes mg/L
UM07-7 03/25/13 GW Alkalinity, Carbonate (as CaC03) Total < 2 2 No mg/L
UM07-7 03/25/13 GW Alkalinity, Total (as CaC03) Total 27 2 Yes mg/L
UM07-7 03/25/13 GW Aluminum Dissolved 0.04 0.03 Yes mg/L
Page 27 of 37
Umetco Former Wilson Mine, Garland County, Arkansas Semi-Annual Report for Groundwater
October 2012 through March 2013
" ,}!iJ~M~j;]'lt}
i.:r'v:L ':?bY '"
UM07-7
••••
iT .'15! 03/25/13
~!iii 'M~tli~'ii GW
i!!'~.::,i!lil·!·I[i!Wi·.,.··.·Ei;;:!~ unt"'~~i~ll!llitll:ijl.lrrrrHlII,,;;Jiii·;i:.,;;r'7 ilL,. . Aluminum
;;gD~::::~:d:··i · Total
I.Lfi·;R~~I.t\. 0.14
Reporting' 1.< Umit' JH
0.03
tiliite ._Il$~ 'I'~i[!: Yes
I,illl!\, . mg/L
v~lida~~!l o.Ullliflef($)
UM07-7 03/25/13 GW Cadmium Dissolved 0.0004 0.0001 Yes mg/L UM07-7 03/25/13 GW Cadmium Total 0.0004 0.0001 Yes mg/L UM07-7 03/25/13 GW Calcium Dissolved 1.4 0.2 Yes mg/L UM07-7 03/25/13 GW Chloride Total 2.6 0.5 Yes mg/l UM07-7 03/25/13 GW Copper Dissolved < 0.0005 0.0005 No mg/l UM07-7 03/25/13 GW Copper Total 0.0008 0.0005 Yes mg/L UM07-7 03/25/13 GW Field Conductivity Total 118 Yes uS/cm UM07-7 03/25/13 GW Field pH Total 5.65 Yes s.u. UM07-7 03/25/13 GW Field Temperature Total 15.6 Yes degrees C
UM07-7 03/25/13 GW Hardness (as CaC03) Total 11 1 Yes mg/L UM07-7 03/25/13 GW Iron Dissolved 0.15 0.02 Yes mg/L
UM07-7 03/25/13 GW Iron Total 8.38 0.02 Yes mg/L UM07-7 03/25/13 GW Lead Dissolved < 0.0001 0.0001 No mg/L UM07-7 03/25/13 GW Lead Total 0.0001 0.0001 Yes mg/L UM07-7 03/25/13 GW Magnesium Dissolved 1.8 0.2 Yes mg/L UM07-7 03/25/13 GW Manganese Dissolved 1.27 0.005 Yes mg/L
UM07·7 03/25/13 GW Manganese Total 1.4 0.005 Yes mg/L
UM07·7 03/25/13 GW Nickel Dissolved 0.0155 0.0006 Yes mg/L
UM07-7 03/25/13 GW Nickel Total 0.0173 0.0006 Yes mg/L UM07-7 03/25/13 GW Potassium Dissolved 3.9 0.3 Yes mg/L UM07-7 03/25/13 GW Silica Dissolved 18 0.4 Yes mg/L UM07-7 03/25/13 GW Silica Total 19.6 0.4 Yes mg/l UM07-7 03/25/13 GW Sodium Dissolved 3.5 0.3 Yes mg/L UM07-7 03/25/13 GW Sulfate Total 17.5 0.5 Yes mg/L
UM07-7 03/25/13 GW Total Dissolved Solids Total SO 10 Yes mg/L
UM07-7 03/25/13 GW Zinc Dissolved 0.052 0.002 Yes mg/L
UM07-7 03/25/13 GW Zinc Total 0.049 0.002 Yes mg/L
UM07-8 11/07/12 GW Acidity (as CaC03) Total 10 10 Yes mg/L J
UM07-8 11/07/12 GW Alkalinity, Bicarbonate (as CaC03) Total < 20 3 No mg/L
UM07·8 11/07/12 GW Alkalinity, Carbonate (as CaC03) Total <2 2 No mg/l
UM07·8 11/07/12 GW Alkalinity, Total (as CaC03) Total < 20 3 No mg/L
UM07·8 11/07/12 GW Aluminum Dissolved 0.06 0.03 Yes mg/L J UM07-8 11/07/12 GW Aluminum Total 2.91 0.03 Yes mg/L J
UM07·8 11/07/12 GW Cadmium Dissolved 0.0002 0.0001 Yes mg/L J
UM07-8 11/07/12 GW Cadmium Total 0.0003 0.0001 Yes mg/L J UM07-8 11/07/12 GW Calcium Dissolved 0.6 0.2 Yes mg/L J
UM07-8 11/07/12 GW Chloride Total 1.7 0.5 Yes mg/L J
UM07-8 11/07/12 GW Copper Dissolved 0.0263 0.0005 Yes mg/L
UM07-8 11/07/12 GW Copper Total 0.0452 0.0005 Yes mg/l
Page 28 of 37
Umetco Former Wilson Mine, Garland County, Arkansas
Semi-Annual Report for Groundwater
October 2012 through March 2013
Page 29 of 37
Umetco Former Wilson Mine, Garland County, Arkansas
Semi-Annual Report for Groundwater
October 2012 through March 2013
Page 30 of 37
Umetco Former Wilson Mine, Garland County, Arkansas
Semi-Annual Report for Groundwater
October 2012 through March 2013
Page 31 of 37
Umetco Former Wilson Mine, Garland County, Arkansas
Semi-Annual Report for Groundwater
October 2012 through March 2013
Page 32 of 37
Umetco Former Wilson Mine, Garland County, Arkansas
Semi-Annual Report for Groundwater
October 2012 through March 2013
Page 33 of 37
Umetco Former Wilson Mine, Garland County, Arkansas
Semi-Annual Report for Groundwater
October 2012 through March 2013
Page 34 of 37
Umetco Former Wilson Mine, Garland County, Arkansas Semi·Annual Report for Groundwater
October 2012 through March 2013
Page 35 of 37
Umetco Former Wilson Mine, Garland County, Arkansas Semi-Annual Report for Groundwater
October 2012 through March 2013
Page 36 of 37
Umetco Former Wilson Mine, Garland County, Arkansas
Semi-Annual Report for Groundwater
October 2012 through March 2013
,
:; Location nIlli!r)ff~e 01/23/13
SUmp!1\!; ; M~1Nll1U
GW
"0,,'
I i'lf(;I:ii ,':' ,.ji Y>',<Ylii'llll'l!!I"'Analyt',,!V",, "I.""'"X>,~" .
Field Temperature
!,
Total
HJIIll:f 0,;:;1711':' Re~il1g,;:
Limit) li,iN~t.·;il~
Yes
',,'"",~ 1~1!!!!••• :8'111~{
degrees C
i~arrdation ;!",<!W~¢i <t1,l~UI~ii~l
UT-3S 17.1
UT-3S 01/23/13 GW Hardness (as CaC03) Total 641 1 Yes mg/L
UT-3S 01/23/13 GW Iron Dissolved 13.8 0.02 Yes mg/L
UT-3S 01/23/13 GW Iron Total 32.4 0.02 Yes mg/L
UT-3S 01/23/13 GW Magnesium Dissolved 43.5 0.2 Yes mg/L
UT-3S 01/23/13 GW Manganese Dissolved 57.1 0.005 Yes mg/L
UT-3S 01/23/13 GW Manganese Total 75.2 0.005 Yes mg/L
UT-3S 01/23/13 GW Nickel Dissolved 0.2096 0.0006 Yes mg/L
UT-3S 01/23/13 GW Nickel Total 0.2898 0.0006 Yes mg/L
UT-3S 01/23/13 GW PotaSSium Dissolved 9.9 0.3 Yes mg/L
UT-3S 01/23/13 GW Silica Dissolved 22.6 0.4 Yes mg/L
UT-3S 01/23/13 GW Silica Total 23.3 0.4 Yes mg/L
UT-3S 01/23/13 GW Sodium Dissolved 5.2 0.3 Yes mg/L
UT-3S 01/23/13 GW Sulfate Total 753 10 Yes mg/L
UT-3S 01/23/13 GW Total Dissolved Solids Total 1220 10 Yes mg/L
UT-3S 01/23/13 GW linc Dissolved 0.51 0.01 Yes mg/L
UT-3S 01/23/13 GW linc Total 0.68 0.01 Yes mg/L
Notes: GW =groundwater; mg/L" milligrams per liter; uS/em = mieroSeimens per centimeter; s.u. " standard units; degrees C = degrees Centigrade; < =less than; J " estimated result. Monitoring well OT-15
was damaged during the South Lecroy reclamation improvements. The damaged well was subsequently abandoned and a new well installed adjacent to the abandoned OT-15 location on February 15, 2013.
The new well is designated OT-1SR.
Page 37 of 37