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    Product Range

    Exhaust System Assembly

    This consists of exhaust manifold, catalyst, center muffler, rear

    muffler and exhaust.

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    Automobiles Part Business

    Contributing To Both Improved Engine Performance and Lower Noise

    1 Role of Product ,Exhaust Pipe

    These parts are mounted beneath the floor of the automobile and their role is to

    cleanse the exhaust gas coming from the engine, mute its sound, and then

    discharge the gas from the rear of the automobile

    2 Required Elements of Products

    The exhaust system products are required to discharge the exhaust gas from the

    engine both smoothly and quietly to satisfy the competing demands for improved

    engine performance and quietness. In addition, these products are exposed to

    high temperatures and a corrosive external environment, so it is also essential

    that they have good heat resistance and corrosion resistance.

    3 Unique Strengths of Our Products

    We make full use of analysis technologies and carry out optimized design to

    reduce the effects of exhaust gas heat and improve the noise reduction.

    4 Direction of Product development

    These products have a large impact on the amount of CO2emissions from the

    automobile and so the performance of these products largely controls the overall

    environmental performance of the automobile as a whole.

    We are advancing and promoting research and development for the purpose of

    reducing CO2emissions even further

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    Exhaust Manifold

    Inautomotive engineering,an exhaust manifold collects theexhaust gases frommultiplecylinders into one pipe. The wordmanifold comes from the Old English

    word manigfeald and refers to the folding together of multiple inputs and

    outputs.

    In contrast, aninlet manifold is the part of an engine that supplies the air to the

    cylinders.

    Exhaust manifolds are generally simplecast iron or stainless steel units which

    collect engine exhaust from multiple cylinders and deliver it to the exhaust pipe.

    For many engines, there are aftermarket tubular exhaust manifolds knownas headers inUS English,asextractor manifolds in British andAustralian

    English,and simply as "tubular manifolds" inUK English.These consist of

    individual exhaust head pipes for each cylinder, which then usually converge into

    one tube called acollector.Headers that do not have collectors are called 'zoomie

    headers'.

    The most common types of aftermarket headers are made of mild steel or

    stainless steel tubing for the primary tubes along with flat flanges and possibly a

    larger diameter collector made of a similar material as the primaries. They may be

    coated with a ceramic-type finish (sometimes both inside and outside), or painted

    with a heat-resistant finish, or bare. Chrome plated headers are available but they

    will tend to blue after use. Polished stainless steel will also color (usually a yellow

    tint), but less than chrome in most cases.

    Another form of modification used is to insulate a standard or aftermarket

    manifold. This decreases the amount of heat given off into the engine bay,

    therefore reducing the intake manifold temperature. There are a few types of

    thermal insulation but three are particularly common:

    Ceramic paint is sprayed or brushed onto the manifold and then cured in an

    oven. These are usually thin, so have little insulatory properties; however, they

    reduce engine bay heating by lessening the heat output via radiation.

    A ceramic mixture is bonded to the manifold viathermal spraying to give a

    tough ceramic coating with very good thermal insulation. This is often used on

    performance production cars and track-only racers.

    http://en.wikipedia.org/wiki/Automotive_engineeringhttp://en.wikipedia.org/wiki/Exhaust_gashttp://en.wikipedia.org/wiki/Cylinder_(engine)http://en.wikipedia.org/wiki/Manifold_(engineering)http://en.wikipedia.org/wiki/Inlet_manifoldhttp://en.wikipedia.org/wiki/Cast_ironhttp://en.wikipedia.org/wiki/US_Englishhttp://en.wikipedia.org/wiki/Extractor_manifoldhttp://en.wikipedia.org/wiki/Australian_Englishhttp://en.wikipedia.org/wiki/Australian_Englishhttp://en.wikipedia.org/wiki/UK_Englishhttp://en.wikipedia.org/w/index.php?title=Collector_(automotive)&action=edit&redlink=1http://en.wikipedia.org/wiki/Zoomie_headerhttp://en.wikipedia.org/wiki/Zoomie_headerhttp://en.wikipedia.org/wiki/Thermal_sprayinghttp://en.wikipedia.org/wiki/Thermal_sprayinghttp://en.wikipedia.org/wiki/Zoomie_headerhttp://en.wikipedia.org/wiki/Zoomie_headerhttp://en.wikipedia.org/w/index.php?title=Collector_(automotive)&action=edit&redlink=1http://en.wikipedia.org/wiki/UK_Englishhttp://en.wikipedia.org/wiki/Australian_Englishhttp://en.wikipedia.org/wiki/Australian_Englishhttp://en.wikipedia.org/wiki/Extractor_manifoldhttp://en.wikipedia.org/wiki/US_Englishhttp://en.wikipedia.org/wiki/Cast_ironhttp://en.wikipedia.org/wiki/Inlet_manifoldhttp://en.wikipedia.org/wiki/Manifold_(engineering)http://en.wikipedia.org/wiki/Cylinder_(engine)http://en.wikipedia.org/wiki/Exhaust_gashttp://en.wikipedia.org/wiki/Automotive_engineering
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    Exhaust wrap is wrapped completely around the manifold. Although this is

    cheap and fairly simple, it can lead to premature degradation of the manifold.

    The goal of performance exhaust headers is mainly to decrease flow resistance

    (back pressure), and to increase the volumetric efficiency of an engine, resulting

    in a gain in power output. The processes occurring can be explained by thegaslaws,specifically theideal gas law and thecombined gas law.

    The role of the exhaust manifold is to send the high-temperature exhaust gas

    from the engine onto the exhaust system (catalyst). In the past this part was

    made from cast iron, but here at Futaba we began producing exhaust

    manifolds made from stainless steel pipe and sheet metal in the spring of 1989,

    long before any of our competitors, and now it has become the mainstream

    material for this product.

    http://en.wikipedia.org/wiki/Back_pressurehttp://en.wikipedia.org/wiki/Gas_lawhttp://en.wikipedia.org/wiki/Gas_lawhttp://en.wikipedia.org/wiki/Ideal_gas_lawhttp://en.wikipedia.org/wiki/Combined_gas_lawhttp://en.wikipedia.org/wiki/Combined_gas_lawhttp://en.wikipedia.org/wiki/Ideal_gas_lawhttp://en.wikipedia.org/wiki/Gas_lawhttp://en.wikipedia.org/wiki/Gas_lawhttp://en.wikipedia.org/wiki/Back_pressure
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    Exhaust System

    An exhaust system is usuallypiping used to guide reactionexhaust gases away

    from a controlledcombustion inside anengine orstove.The entire systemconveys burnt gases from the engine and includes one or more exhaust pipes.

    Depending on the overall system design, the exhaust gas may flow through one or

    more of:

    Cylinder head andexhaust manifold

    Aturbocharger to increase engine power.

    Acatalytic converter to reduceair pollution.

    Amuffler (North America) /silencer (Europe), to reducenoise.

    This system is composed of parts such as the exhaust manifold, catalyst, center

    muffler, rear muffler, and the exhaust pipes that connect these parts together.

    The role of the exhaust system is to reduce both the temperature and the noise

    of the exhaust gas, as well as to remove any harmful components of the gas.

    This system is one of the most critical parts of the automobile because it has a

    large effect on the tone of the exhaust noise and the power performance

    http://en.wikipedia.org/wiki/Pipe_(fluid_conveyance)http://en.wikipedia.org/wiki/Exhaust_gashttp://en.wikipedia.org/wiki/Combustionhttp://en.wikipedia.org/wiki/Enginehttp://en.wikipedia.org/wiki/Stovehttp://en.wikipedia.org/wiki/Cylinder_headhttp://en.wikipedia.org/wiki/Exhaust_manifoldhttp://en.wikipedia.org/wiki/Turbochargerhttp://en.wikipedia.org/wiki/Catalytic_converterhttp://en.wikipedia.org/wiki/Air_pollutionhttp://en.wikipedia.org/wiki/Mufflerhttp://en.wikipedia.org/wiki/Mufflerhttp://en.wikipedia.org/wiki/Noise_(environmental)http://en.wikipedia.org/wiki/Noise_(environmental)http://en.wikipedia.org/wiki/Mufflerhttp://en.wikipedia.org/wiki/Mufflerhttp://en.wikipedia.org/wiki/Air_pollutionhttp://en.wikipedia.org/wiki/Catalytic_converterhttp://en.wikipedia.org/wiki/Turbochargerhttp://en.wikipedia.org/wiki/Exhaust_manifoldhttp://en.wikipedia.org/wiki/Cylinder_headhttp://en.wikipedia.org/wiki/Stovehttp://en.wikipedia.org/wiki/Enginehttp://en.wikipedia.org/wiki/Combustionhttp://en.wikipedia.org/wiki/Exhaust_gashttp://en.wikipedia.org/wiki/Pipe_(fluid_conveyance)
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    Truthfully, an individual car's emissions are relatively low, compared to other

    sources of pollution. But when hundreds of thousands of people are each sitting

    in a car, packing a highway to capacity, the cumulative effects are enormous. As

    you're sitting in a traffic jam, gazing at the smoke coming out of the tailpipe in

    front of you and rising to join the smog in the sky, think for a moment about what

    that smoke is. It might not look like much, but that smoke has come a long way

    since it was pushed through the car's engine just moments before.

    Concern about our automobiles' effect on the environment is nothing new. The

    1970 version of the Clean Air Act gave the EPA its sweeping authority to regulate

    automotive emissions. As technology advanced, the EPA pushed for more strict

    standards. And while new cars are much cleaner than those of 40 years ago,

    people tend to drive greater distances and a lot more often today, contributing toa lot more pollution. The Clean Air Act was revamped and increased in scope in

    1977, and then again in 1990.

    Automotive manufacturers and parts suppliers have had to keep pace with these

    changes, and as you can imagine, a car's exhaust system has had to evolve

    considerably, too.

    Components of an Exhaust -- Smokin' Pipes

    The exhaust system is comprised mainly of pipes in several different shapes, each

    designed to connect to one another, and each shaped to conform to a specificpart of the underside of the car. (The pipes are often bent to wrap around or

    otherwise accommodate other nearby components of the car, such as the axles.)

    Each pipe is responsible for moving the exhaust gases toward the back, but many

    of the segments are specialized. In other words, from the exterior, the system

    simply looks like a bunch of connected pipe segments that run from the engine

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    bay to the back bumper, though some serve an additional purpose as the exhaust

    flows through that particular pipe.

    For example, the Y pipe (which is simply, well, a Y-shaped pipe) might be installed

    so the end with two openings bolts up to two corresponding openings in theexhaust manifold, combining the engine's waste to progress through the system.

    Or, when installed at the back end of the car, a Y pipe can help create a dual

    exhaust system with a tailpipe on each side of the car (for an often sought-after

    sporty look). Intermediate pipes might be attached to the muffler or resonator,

    which are other important system components (we'll get to these on the next

    page). Balance pipes, found in dual exhaust systems, help equalize the exhaust

    pulses traveling under the driver and passenger sides of the car. Air gap pipes are

    specialized nested pipes that act as a heat shield and insulator by providing anextra layer for airflow. And the tail pipe, which is typically peeking out from

    underneath the rear bumper, usually has a larger opening and might be made of

    more substantial-looking metal, to give the appearance of a performance exhaust

    that's a common feature of high-end cars.

    Though it might seem inefficient to have a ton of pipes instead of just one, really,

    all those segments serve a purpose. For one, bending pipes is hard work, and it's

    easier to connect small angled segments to straight pipes than it is to shape onelong, expensive, heavy pipe to fit every contour of a car. Also, exhaust system

    components wear out at regular intervals (depending, of course, on the

    manufacturer, its materials, driving conditions and environmental factors). It's

    easier and less expensive to replace one rusted-out segment of pipe, banged-up

    muffler, or worn-out catalytic converter than it would be to install a whole new

    system.

    You might wonder how all those pipes fit together. Well, some ends overlap,

    while others are mated end-to-end; but not without a little bit of assistance.

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    Other Exhaust Components -- Headers,

    Hangers and More

    We discussed the various pipes first, because they're the most visible and

    prevalent components of the exhaust system, and because they're all over the

    place. But the exhaust system really starts at the exhaust header (also known as

    the exhaust manifold). The header looks like a series of adjacent tubes stuck

    together (though it's often made of heavy-duty cast metal). It collects the exhaust

    directly from the engine, so it's designed so each opening mates up with one of

    the engine's exhaust ports, with flanges that form a tight seal to prevent exhaust

    from escaping. From here, the exhaust begins its flow through the various pipesand other components.

    The gaskets that are fitted between each pipe play a very important role. It's

    difficult, if not impossible, to form a flawless metal-to-metal seal, so gaskets are

    sandwiched between each connection to prevent the poisonous gases from

    escaping prematurely. They're made of fiberAd by save net or other heavy-duty,

    heat resistant materials, which have just enough flexibility to compress slightly

    when the pipes are clamped tightly together. This helps form a tight seal.

    The muffler is another key part of the exhaust system. It looks like a large round

    or oval chamber (usually, but not always, found near the back of the car). That

    chamber has a very complex design, though -- it's responsible for silencing most

    of the engine's noise, even though it has to allow the exhaust to continue flowing

    smoothly. A series of chambers and tubes, filled with rock, wool, or synthetic

    fibers, absorbs and controls the noise. And that's not all -- the muffler must be

    reasonably resistant to damage, corrosion and heat retention. The resonator is a

    secondary or substitute sound elimination component, used to augment the

    muffler, or in cases where space is at a premium it might even be used instead of

    a muffler.

    Catalytic converters, which became commonplace in the 1970s, are the primary

    and most efficient means of reducing the level of toxins in a car's exhaust. The

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    innards of a catalytic converter (or "cat") are coated with metals. Different types

    of catalytic converters use different combinations of platinum, palladium and

    rhodium. Before the exhaust reaches the cat, it contains a potent, super-toxic

    combination of carbon monoxide, nitrogen oxide and hydrocarbons. (When you

    take your car for its emissions test, these are the chemical levels that are being

    tested.) When these poisons come into contact with the metals coating the inside

    of the cat, a chemical reaction takes place that makes the exhaust gases less

    harmful. As the exhaust passes through the cat, the level of chemicals should be

    reduced enough to comply with government regulations.

    We already talked about gaskets, but the exhaust system requires other basic

    pieces of hardware. Flanges generally serve the same purpose as gaskets, but

    these are made of metal (and are sometimes formed right onto the end of apipe). Assorted clamps and brackets mount the exhaust pieces together and hold

    them to the vehicle, and exhaust hangers literally hang the pipes from the

    underbody of the car, with enough strength to keep them in place but also

    enough flexibility to withstand movement caused by driving. And last, but not

    least are the heat shields: Metal (sometimes insulated) plates that are used as an

    extra barrier whenever hot exhaust parts are particularly close to another part of

    the car or directly below the passenger compartment.

    The Exit Route

    If an engine ran perfectly, it would combust all its available fuel as it ran through

    its cycles, converting all the dirty bits to a source of power. However, leftovers

    exist as pollutants because an engine simply cannot be engineered to run

    perfectly -- there are far too many variables. Some amount of fuel will always

    remain unburned or partially burned, and these remnants must be quickly

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    processed out of the vehicle, in the form of exhaust, to make room for the next

    cycle of engine combustion.

    As we mentioned earlier, the exhaust first exits the engine and enters the system

    through the exhaust manifold. From there, it travels down the system throughinterconnected pipes until it exits through the tailpipe, near the back bumper. The

    pipes themselves actually help cool the exhaust, but they're mostly a way for the

    exhaust to travel to (and through) the catalytic converter and muffler.

    The cat has to be as close to the engine as possible, because it isn't fully

    functional until it rises to operating temperature. In many cases, the

    manufacturer places the cat shortly after the manifold, so heat from the engine

    helps warm the cat and quickly bring it up to temp.

    After the gases pass through the cat, which will burn off and remove up to 90

    percent of the exhaust's toxins, the next priority is to filter the engine sound

    [source: Allen]. The muffler and resonator are usually situated right beyond the

    cat. There are many variations on this combination -- some will soothe the

    exhaust as much as possible, while others are specifically tuned for aggressive

    tones. From there, the exhaust moves through the remainder of the pipes until it

    exits the car.

    With all those chemicals swirling around, it's quite a feat that the exhaust system

    actually works as well as it does. A well-maintained exhaust system should last

    two to three years, but the pipes incur damage both inside and out. On the

    outside, they're susceptible to road conditions, such as impact from debris and

    environmental factors, such as snow, ice and road salt.

    However, a more substantial cause of exhaust system degradation is internal, and

    it can't be seen until the pipes have corroded through with rust. We know that as

    the engine combusts fuel to make power, byproducts of this process are left over

    -- that's why the exhaust system is needed. One of these byproducts is acidic

    moisture, and it's really damaging to metal. Unfortunately, there's really no way

    to keep the insides of the pipes clean.

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    When an exhaust pipe rots through or a connection comes loose, an exhaust leak

    occurs. A leak is almost always immediately apparent with a loud, obnoxious

    sound and, possibly, drivability issues like an intermittent fluctuation in power.

    But, believe it or not, these aren't the real problems. It gets a little more serious if

    the leak occurs before the catalytic converter, which means the exhaust isn't

    being properly processed and all those hot chemicals are spilling everywhere into

    the atmosphere. It's always a good idea to get leaks fixed as soon as possible to

    avoid subjecting yourself, your passengers and your surroundings to unfiltered

    exhaust fumes.

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    Muffler

    If you've ever heard a car engine running without a muffler, you know what a

    huge difference a muffler can make to the noise level. Inside a muffler, you'll find

    a deceptively simple set of tubes with some holes in them. These tubes and

    chambers are actually as finely tuned as a musical instrument. They are designed

    to reflect the sound waves produced by the engine in such a way that they

    partially cancel themselves out.

    Mufflers use some pretty neat technology to cancel out the noise. In this article,

    we'll take a look inside a real car muffler and learn about the principles that makeit work.

    But first, we need to know a little about sound.

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    Where Does the Sound Come From?

    Sound is a pressure wave formed from pulses of alternating high and low air

    pressure. These pulses makes their way through the air at -- you guessed it -- thespeed of sound.

    In an engine, pulses are created when an exhaust valve opens and a burst of high-

    pressure gas suddenly enters the exhaust system. The molecules in this gas collide

    with the lower-pressure molecules in the pipe, causing them to stack up on each

    other. They in turn stack up on the molecules a little further down the pipe,

    leaving an area of low pressure behind. In this way, the sound wave makes its way

    down the pipe much faster than the actual gases do.

    When these pressure pulses reach your ear, the eardrum vibrates back and forth.

    Your brain interprets this motion as sound. Two main characteristics of the wave

    determine how we perceive the sound:

    Sound wave frequency - A higher wave frequency simply means that the air

    pressure fluctuates faster. The faster an engine runs, the higher the pitch we

    hear. Slower fluctuations sound like a lower pitch.

    Air pressure level - The wave's amplitude determines how loud the sound is.

    Sound waves with greater amplitudes move our eardrums more, and we register

    this sensation as a higher volume.

    It turns out that it is possible to add two or more sound waves together and get

    less sound. Let's see how.

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    How Can You Cancel Out Sound?

    The key thing about sound waves is that the result at your ear is the sum of all the

    sound waves hitting your ear at that time. If you are listening to a band, eventhough you may hear several distinct sources of sound, the pressure waves hitting

    your ear drum all add together, so your ear drum only feels one pressure at any

    given moment.

    Now comes the cool part: It is possible to produce a sound wave that is exactly

    the opposite of another wave. This is the basis for those noise-canceling

    headphones you may have seen. Take a look at the figure below. The wave on top

    and the second wave are both pure tones. If the two waves are in phase, they add

    up to a wave with the same frequency but twice the amplitude. This is called

    constructive interference. But, if they are exactly out of phase, they add up to

    zero. This is called destructive interference. At the time when the first wave is at

    its maximum pressure, the second wave is at its minimum. If both of these waves

    hit your ear drum at the same time, you would not hear anything because the two

    waves always add up to zero.

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    Inside a Muffler

    Located inside the muffler is a set of tubes. These tubes are designed to create

    reflected waves that interfere with each other or cancel each other out. Take a

    look at the inside of this muffler:

    The exhaust gases and the sound waves enter through the center tube. They

    bounce off the back wall of the muffler and are reflected through a hole into the

    main body of the muffler. They pass through a set of holes into another chamber,

    where they turn and go out the last pipe and leave the muffler.

    A chamber called a resonator is connected to the first chamber by a hole. The

    resonator contains a specific volume of air and has a specific length that is

    calculated to produce a wave that cancels out a certain frequency of sound. Howdoes this happen? Let's take a closer look ...

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    The Resonator

    When a wave hits the hole, part of it continues into the chamber and part of it is

    reflected. The wave travels through the chamber, hits the back wall of the mufflerand bounces back out of the hole. The length of this chamber is calculated so that

    this wave leaves the resonator chamber just after the next wave reflects off the

    outside of the chamber. Ideally, the high-pressure part of the wave that came

    from the chamber will line up with the low-pressure part of the wave that was

    reflected off the outside of the chamber wall, and the two waves will cancel each

    other out.

    The animation below shows how the resonator works in a simplified muffler.

    Waves canceling inside a simplified muffler

    In reality, the sound coming from the engine is a mixture of many different

    frequencies of sound, and since many of those frequencies depend on the engine

    speed, the sound is almost never at exactly the right frequency for this to happen.

    The resonator is designed to work best in the frequency range where the engine

    makes the most noise; but even if the frequency is not exactly what the resonator

    was tuned for, it will still produce some destructive interference.

    Some cars, especially luxury cars where quiet operation is a key feature, have

    another component in the exhaust that looks like a muffler, but is called a

    resonator. This device works just like the resonator chamber in the muffler -- the

    dimensions are calculated so that the waves reflected by the resonator helpcancel out certain frequencies of sound in the exhaust.

    There are other features inside this muffler that help it reduce the sound level in

    different ways. The body of the muffler is constructed in three layers: Two thin

    layers of metal with a thicker, slightly insulated layer between them. This allows

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    the body of the muffler to absorb some of the pressure pulses. Also, the inlet and

    outlet pipes going into the main chamber are perforated with holes. This allows

    thousands of tiny pressure pulses to bounce around in the main chamber,

    canceling each other out to some extent in addition to being absorbed by the

    muffler's housing.

    Backpressure and Other Types of Mufflers

    One important characteristic of mufflers is how much backpressure they produce.

    Because of all of the turns and holes the exhaust has to go through, mufflers like

    those in the previous section produce a fairly high backpressure. This subtracts a

    little from the power of the engine.

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    There are other types of mufflers that can reduce backpressure. One type,

    sometimes called a glass pack or a cherry bomb, uses only absorption to reduce

    the sound. On a muffler like this, the exhaust goes straight through a pipe that is

    perforated with holes. Surrounding this pipe is a layer of glass insulation that

    absorbs some of the pressure pulses. A steel housing surrounds the insulation.

    Diagram of glass pack muffler

    These mufflers produce much less restriction, but don't reduce the sound level asmuch as conventional mufflers.

    Active Noise-Canceling Mufflers

    There have been a few experiments with active noise-canceling mufflers,

    especially on industrial generators. These systems incorporate a set of

    microphones and a speaker.

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    The speaker is positioned in a pipe, which wraps around the exhaust pipe so that

    the sound from the exhaust comes out in the same direction as the sound from

    the speaker. A computer monitors a microphone positioned before the speaker

    and one positioned after the speaker. By knowing some things about the length

    and shape of the pipes, the computer can generate a signal to drive the speaker.

    This can cancel out much of the sound coming from the generator. The

    downstream microphone lets the computer know how well it is doing so it can

    make adjustments if needed.

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    How Catalytic Converters Work

    There are millions of cars on the road in the United States, and each one is a

    source of air pollution. Especially in large cities, the amount of pollution that all

    the cars produce together can create big problems.

    To solve those problems, cities, states and the federal government create clean-

    air laws that restrict the amount of pollution that cars can produce. Over the

    years, automakers have made many refinements to car engines and fuel systems

    to keep up with these laws. One of these changes came about in 1975 with an

    interesting device called a catalytic converter. The job of the catalytic converter is

    to convert harmful pollutants into less harmful emissions before they ever leave

    the car's exhaust system.

    Catalytic converters are amazingly simple devices, so it is incredible to see howbig an impact they have. In this article, you will learn which pollutants are

    produced by an engine and how a catalytic converter deals with each of these

    pollutants to help reduce vehicle emissions.

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    Pollutants Produced by a Car Engine

    In order to reduce emissions, modern car engines carefully control the amount of

    fuel they burn. They try to keep the air-to-fuel ratio very close to thestoichiometric point, which is the ideal ratio of air to fuel. Theoretically, at this

    ratio, all of the fuel will be burned using all of the oxygen in the air. For gasoline,

    the stoichiometric ratio is about 14.7:1, meaning that for each pound of gasoline,

    14.7 pounds of air will be burned. The fuel mixture actually varies from the ideal

    ratio quite a bit during driving. Sometimes the mixture can be lean (an air-to-fuel

    ratio higher than 14.7), and other times the mixture can be rich (an air-to-fuel

    ratio lower than 14.7).

    The main emissions of a car engine are:

    Nitrogen gas (N2) - Air is 78-percent nitrogen gas, and most of this passes right

    through the car engine.

    Carbon dioxide (CO2) - This is one product of combustion. The carbon in the fuel

    bonds with the oxygen in the air.

    Water vapor (H2O) - This is another product of combustion. The hydrogen in the

    fuel bonds with the oxygen in the air.

    These emissions are mostly benign, although carbon dioxide emissions are

    believed to contribute to global warming. Because the combustion process is

    never perfect, some smaller amounts of more harmful emissions are also

    produced in car engines. Catalytic converters are designed to reduce all three:

    Carbon monoxide (CO) is a poisonous gas that is colorless and odorless.

    Hydrocarbons or volatile organic compounds (VOCs) are a major component of

    smog produced mostly from evaporated, unburned .fuel.

    Nitrogen oxides (NO and NO2, together called NOx) are a contributor to smog and

    acid rain, which also causes irritation to human mucus membranes.

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    How Catalytic Converters Reduce PollutionIn chemistry, a catalyst is a substance that causes or accelerates a chemical

    reaction without itself being affected. Catalysts participate in the reactions, but

    are neither reactants nor products of the reaction they catalyze. In the human

    body, enzymes are naturally occurring catalysts responsible for many essential

    biochemical reactions.

    In the catalytic converter, there are two different types of catalyst at work, a

    reduction catalyst and an oxidation catalyst. Both types consist of a ceramic

    structure coated with a metal catalyst, usually platinum, rhodium and/or

    palladium. The idea is to create a structure that exposes the maximum surface

    area of catalyst to the exhaust stream, while also minimizing the amount of

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    catalyst required, as the materials are extremely expensive. Some of the newest

    converters have even started to use gold mixed with the more traditional

    catalysts. Gold is cheaper than the other materials and could increase oxidation,

    the chemical reaction that reduces pollutants, by up to 40 percent.

    Most modern cars are equipped with three-way catalytic converters. This refers

    to the three regulated emissions it helps to reduce.

    The reduction catalyst is the first stage of the catalytic converter. It uses platinum

    and rhodium to help reduce the NOx emissions. When an NO or NO2 molecule

    contacts the catalyst, the catalyst rips the nitrogen atom out of the molecule and

    holds on to it, freeing the oxygen in the form of O2. The nitrogen atoms bond

    with other nitrogen atoms that are also stuck to the catalyst, forming N2. For

    example:

    2NO => N2 + O2 or 2NO2 => N2 + 2O2

    2NO => N2 + O2 or 2NO2 => N2 + 2O2

    Ceramic honeycomb catalyst structure.

    The oxidation catalyst is the second stage of the catalytic converter. It reduces the

    unburned hydrocarbons and carbon monoxide by burning (oxidizing) them over a

    platinum and palladium catalyst. This catalyst aids the reaction of the CO and

    hydrocarbons with the remaining oxygen in the exhaust gas. For example:

    2CO + O2 => 2CO2

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    There are two main types of structures used in catalytic converters -- honeycomb

    and ceramic beads. Most cars today use a honeycomb structure.

    In the next section, we'll look at the third stage of the conversion process and

    how you can get the most from your catalytic converter.

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    Controlling Pollution and Improving

    Performance

    The third stage of conversion is a control system that monitors the exhaust

    stream, and uses this information to control the fuel injection system. There is an

    oxygen sensor mounted upstream of the catalytic converter, meaning it is closer

    to the engine than the converter. This sensor tells the engine computer how

    much oxygen is in the exhaust. The engine computer can increase or decrease the

    amount of oxygen in the exhaust by adjusting the air-to-fuel ratio. This control

    scheme allows the engine computer to make sure that the engine is running at

    close to the stoichiometric point, and also to make sure that there is enoughoxygen in the exhaust to allow the oxidization catalyst to burn the unburned

    hydrocarbons and CO.

    The catalytic converter does a great job at reducing the pollution, but it can still

    be improved substantially. One of its biggest shortcomings is that it only works at

    a fairly high temperature. When you start your car cold, the catalytic converter

    does almost nothing to reduce the pollution in your exhaust.

    One simple solution to this problem is to move the catalytic converter closer tothe engine. This means that hotter exhaust gases reach the converter and it heats

    up faster, but this may also reduce the life of the converter by exposing it to

    extremely high temperatures. Most carmakers position the converter under the

    front passenger seat, far enough from the engine to keep the temperature down

    to levels that will not harm it.

    Preheating the catalytic converter is a good way to reduce emissions. The easiest

    way to preheat the converter is to use electric resistance heaters. Unfortunately,the 12-volt electrical systems on most cars don't provide enough energy or power

    to heat the catalytic converter fast enough. Most people would not wait several

    minutes for the catalytic converter to heat up before starting their car. Hybrid

    cars that have big, high-voltage battery packs can provide enough power to heat

    up the catalytic converter very quickly.

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    Catalytic converters in diesel engines do not work as well in reducing NOx. One

    reason is that diesel engines run cooler than standard engines, and the converters

    work better as they heat up. Some of the leading environmental auto experts

    have come up with a new system that helps to combat this. They inject a urea

    solution in the exhaust pipe, before it gets to the converter, to evaporate and mix

    with the exhaust and create a chemical reaction that will reduce NOx. Urea, also

    known as carbamide, is an organic compound made of carbon, nitrogen, oxygen

    and hydrogen. It's found in the urine of mammals and amphibians. Urea reacts

    with NOx to produce nitrogen and water vapor, disposing more than 90 percent

    of the nitrogen oxides in exhaust gases.