Figure 1.1 Charges of unlike sign attact each other, those of like sign repel.

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Electrochemical Science and Technology: Fundamentals and Applications, Keith B. Oldham, Jan C. Myland and Alan M. Bond. © 2011 John Wiley & Sons, Ltd. Published 2011 by John Wiley & Sons, Ltd. Figure 1.1 Charges of unlike sign attact each other, those of like sign repel.

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Figure 1.1 Charges of unlike sign attact each other, those of like sign repel. Figure 1.2 The architecture of the dipolar water molecule. The red and blue surface regions are charged positively and negatively respectively. - PowerPoint PPT Presentation

Transcript of Figure 1.1 Charges of unlike sign attact each other, those of like sign repel.

Page 1: Figure 1.1  Charges of unlike sign attact each other, those of like sign repel.

Electrochemical Science and Technology: Fundamentals and Applications,Keith B. Oldham, Jan C. Myland and Alan M. Bond.© 2011 John Wiley & Sons, Ltd. Published 2011 by John Wiley & Sons, Ltd.

Figure 1.1 Charges of unlike sign attact each other, those of like sign repel.

Page 2: Figure 1.1  Charges of unlike sign attact each other, those of like sign repel.

Electrochemical Science and Technology: Fundamentals and Applications,Keith B. Oldham, Jan C. Myland and Alan M. Bond.© 2011 John Wiley & Sons, Ltd. Published 2011 by John Wiley & Sons, Ltd.

Figure 1.2 The architecture of the dipolar water molecule. The red and blue surface regions are charged positively and negatively respectively.

Page 3: Figure 1.1  Charges of unlike sign attact each other, those of like sign repel.

Electrochemical Science and Technology: Fundamentals and Applications,Keith B. Oldham, Jan C. Myland and Alan M. Bond.© 2011 John Wiley & Sons, Ltd. Published 2011 by John Wiley & Sons, Ltd.

Figure 1.3 The field created by a positive charge is directed away from the charge in all three-dimensional directions, the converse being true for negative charges.

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Electrochemical Science and Technology: Fundamentals and Applications,Keith B. Oldham, Jan C. Myland and Alan M. Bond.© 2011 John Wiley & Sons, Ltd. Published 2011 by John Wiley & Sons, Ltd.

Figure 1.4 In a spherically symmetrical geometry, all properties are uniform on spheres such as r = R. Here a charge Q resides at the r = 0 origin.

Page 5: Figure 1.1  Charges of unlike sign attact each other, those of like sign repel.

Electrochemical Science and Technology: Fundamentals and Applications,Keith B. Oldham, Jan C. Myland and Alan M. Bond.© 2011 John Wiley & Sons, Ltd. Published 2011 by John Wiley & Sons, Ltd.

Figure 1.5 The test charge experiences a repulsive force of magnitude Qtestq/2ε from the positively charged sheet, independent of l, and an attractive force of the same

magnitude from the negatively charged sheet.

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Electrochemical Science and Technology: Fundamentals and Applications,Keith B. Oldham, Jan C. Myland and Alan M. Bond.© 2011 John Wiley & Sons, Ltd. Published 2011 by John Wiley & Sons, Ltd.

Figure 1.6 A test charge moves a short distance δr from point A to point B towards the source of an electric field. It experiences a field of strength X acting in the direction of

increasing r.

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Electrochemical Science and Technology: Fundamentals and Applications,Keith B. Oldham, Jan C. Myland and Alan M. Bond.© 2011 John Wiley & Sons, Ltd. Published 2011 by John Wiley & Sons, Ltd.

Figure 1.7 A test charge journeying by the direct A → B route encounters a field that is constantly changing in both strength and direction. However, the work involved is the

same as via the route A → C → B. No work accompanies the A → C journey along the circular arc.

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Electrochemical Science and Technology: Fundamentals and Applications,Keith B. Oldham, Jan C. Myland and Alan M. Bond.© 2011 John Wiley & Sons, Ltd. Published 2011 by John Wiley & Sons, Ltd.

Figure 1.8 Parallel plates store electric charge, and retain the charge when the switch is opened.

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Electrochemical Science and Technology: Fundamentals and Applications,Keith B. Oldham, Jan C. Myland and Alan M. Bond.© 2011 John Wiley & Sons, Ltd. Published 2011 by John Wiley & Sons, Ltd.

Figure 1.9 Measurable potential differences exist within the dielectric and between the metal phases, but not between points in dissimilar phases.

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Electrochemical Science and Technology: Fundamentals and Applications,Keith B. Oldham, Jan C. Myland and Alan M. Bond.© 2011 John Wiley & Sons, Ltd. Published 2011 by John Wiley & Sons, Ltd.

Figure 1.10 In an electric field, dipoles become aligned, to some extent, so that the dipole field opposes the field applied by the plates.

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Electrochemical Science and Technology: Fundamentals and Applications,Keith B. Oldham, Jan C. Myland and Alan M. Bond.© 2011 John Wiley & Sons, Ltd. Published 2011 by John Wiley & Sons, Ltd.

Figure 1.11 Arrangement for measuring the conductivity of an electronic conductor. The method is sometimes called the 4-terminal method because there are four connections

to the conductor. The sample of conductor is of length L and cross-sectional area A.

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Electrochemical Science and Technology: Fundamentals and Applications,Keith B. Oldham, Jan C. Myland and Alan M. Bond.© 2011 John Wiley & Sons, Ltd. Published 2011 by John Wiley & Sons, Ltd.

Figure 1.12 In the absence of chemical reaction, current flows transiently when a field is applied to an ionic conductor.

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Electrochemical Science and Technology: Fundamentals and Applications,Keith B. Oldham, Jan C. Myland and Alan M. Bond.© 2011 John Wiley & Sons, Ltd. Published 2011 by John Wiley & Sons, Ltd.

Figure 1.13 How the charge passed varies with time following the imposition of an electric field on three classes of material. For the insulator, a charge of magnitude

AεΔE/L passes almost immediately. For the electronic conductor, the charge passed increases linearly as AκtΔE/L. For the ionic conductor, the charge accumulates at an

ever-decreasing rate.

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Electrochemical Science and Technology: Fundamentals and Applications,Keith B. Oldham, Jan C. Myland and Alan M. Bond.© 2011 John Wiley & Sons, Ltd. Published 2011 by John Wiley & Sons, Ltd.

Figure 1.14 In the absence of chemical reaction, ions move and accumulate at the interfaces when a field is applied to an ionic conductor.

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Electrochemical Science and Technology: Fundamentals and Applications,Keith B. Oldham, Jan C. Myland and Alan M. Bond.© 2011 John Wiley & Sons, Ltd. Published 2011 by John Wiley & Sons, Ltd.

Figure 1.15 Positive charge carriers move in response to a field, leading to the flow of current I.

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Electrochemical Science and Technology: Fundamentals and Applications,Keith B. Oldham, Jan C. Myland and Alan M. Bond.© 2011 John Wiley & Sons, Ltd. Published 2011 by John Wiley & Sons, Ltd.

Figure 1.16 Cations, moving to the right with the field, and anions, moving leftwards against the field, both contribute to the current.

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Electrochemical Science and Technology: Fundamentals and Applications,Keith B. Oldham, Jan C. Myland and Alan M. Bond.© 2011 John Wiley & Sons, Ltd. Published 2011 by John Wiley & Sons, Ltd.

Figure 1.17 Circuits to evaluate the effect of a voltage step on a resistor and a capacitor in parallel (left) and series (right). In the parallel case, ΔEC and ΔER are identical; when

the components are in series, the same current I flows through R and C.

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Electrochemical Science and Technology: Fundamentals and Applications,Keith B. Oldham, Jan C. Myland and Alan M. Bond.© 2011 John Wiley & Sons, Ltd. Published 2011 by John Wiley & Sons, Ltd.

Figure 1.18 How the current changes following the imposition of a constant voltage on a series arrangement of a resistor and a capacitor.

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Electrochemical Science and Technology: Fundamentals and Applications,Keith B. Oldham, Jan C. Myland and Alan M. Bond.© 2011 John Wiley & Sons, Ltd. Published 2011 by John Wiley & Sons, Ltd.

Figure 1.19 Waveforms of the domestic electricity supply: the green and violet curves respectively illustrate 120 V, 60 Hz and 240 V, 50 Hz supplies.

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Electrochemical Science and Technology: Fundamentals and Applications,Keith B. Oldham, Jan C. Myland and Alan M. Bond.© 2011 John Wiley & Sons, Ltd. Published 2011 by John Wiley & Sons, Ltd.

Figure 1.20 An a.c. circuit for measuring the impedance of five alternative loads.

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Electrochemical Science and Technology: Fundamentals and Applications,Keith B. Oldham, Jan C. Myland and Alan M. Bond.© 2011 John Wiley & Sons, Ltd. Published 2011 by John Wiley & Sons, Ltd.

Figure 1.21 A typical Fourier spectrum. In this example, harmonics are present at frequencies of 3ω, 5ω, 7ω, …, in addition to the fundamental of frequency ω. Here,

ω = 2π/P.

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Electrochemical Science and Technology: Fundamentals and Applications,Keith B. Oldham, Jan C. Myland and Alan M. Bond.© 2011 John Wiley & Sons, Ltd. Published 2011 by John Wiley & Sons, Ltd.

Figure 1.22 A square wave of amplitude |E|, period P and frequency 2π/P.