Efka® PX 4751
Transcript of Efka® PX 4751
150 years 150 years
Efka® PX 4751
Next generation of high performance solvent based dispersing agents for pigment concentrates
Formulation Additives Dispersions & Pigments Division European Coatings Show 2015
150 years
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Dispersing agents Focus products for solvent-based systems
Inorganic pigments Classic organic pigments High performance pigments HCC black and phthalocyanine
Inorganic pigments Classic organic pigments High performance pigments
Inorganic pigments Classic organic pigments
Efka® PX 4310 1
Efka® PX 4330 1
Efka® PU 4020
Efka® PA 4450 Efka® FA 4608
Efka® PU 4009
solv
ent-b
ased
Efka® PU 4050 Efka® PU 4061 Efka® PU 4046 / 4063
Efka® FA 4620 2 / Efka® FA 4609 2
1 CFRP technology (Controlled Free Radical Polymerization)
Decorative OEM / Refinish / Coil coating General industrial
2 Inorganic pigments and fillers/extenders only
Efka® PX 4751 / Efka® PX 4350 1
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Efka® PX 4751 Benefits
Performance highlights Benchmark performance for a broad variety of pigments
High pigment loading at lower mill base viscosity
Higher color strength
Broad compatibility in a wide range of resin systems:
acrylate/CAB
2-Pack solvent-based PUR
solvent-based alkyd/melamine
2-Pack solvent-based epoxy systems.
Especially developed to achieve best results with Laropal® A 81
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Efka® PX 4751 is an advanced star-shaped polymer
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Acrylic block copolymer based on CFRP Technology
Advanced polymer with pigment affinic groups
Conventional polymeric dispersant with / without synergist
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Advanced Polymeric dispersing agents with core-shell structure
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resin & solvent specific !
pigment specific !
Pigment surface
Stabilizing chain with balanced compatibility to resins and solvents
Pigment affinic core with specific anchoring groups
Dispersing agent adsorb on pigment surface
150 years Positioning overview Efka® PX 4751 shows benchmark performance for a broad variety of pigments
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C.I. Efka PX 4751
Benchmark 1
Efka PX 4751
Benchmark 1
Efka PX 4751
Benchmark 1
Paliotol YellowL 2146 P.Y. 139
Irgazin RedL 3670 HD P.R. 254
Heliogen GreenL 8730 P.G. 7
Heliogen BlauL 7101F P.B. 15:4
Kronos 2310 P.W.6
Special Black 4P.Bk. 7
Mill base viscosity with Laropal A 81
@ 100 1/s
Rel. color strength in a sb
Alkyd/MelamineRel. color strength
in a sb PUR
150 years Positioning overview Efka® PX 4751 shows benchmark performance for a broad variety of pigments
Paliotol Yellow L 2140 Cromophtal
Yellow L 1084 HD
Cromophtal Yellow L 1061 HD
Irgalit Yellow L 1254 HD
Irgazin Yellow L 2060
Irgazin Red L 3670
Bayferrox Red 130 M
Irgazin Scarlet L 3550 HD
Novoperm Red F3RK 70
Irgazin Red L 3660 HD
Cinquasia Red L 4105 HD
Cinquasia Magenta L 4530
Cinquasia Magenta L 4540
Hostaperm Rosa E
Irgazin Orange L 2985 HD
Irgazin Orange L 3250 HD Sicopal
Orange L 2430 Cinquasia
Violet L 5120 Hostaperm
Violet RL spez.
Heliogen Green L 8730
Heliogen Green L 8735
Heliogen Blue L 7101 F
Heliogen Blue L 6700 F
Heliogen Blue L 7085
Heliogen Blue L 6960
Paliogen Blue L 6482
Kronos 2310
Special Black 4
Bayferrox Yellow 3920
Paliotol Yellow L 2146
Sicopal Yellow L 1100
Sicopal Yellow L 1130
Sicotan Yellow L 2110
Paliotol Yellow L 0962 HD
Efka® PX 4751 Laropal® A 81
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Kronos2310
PL= 60%
Paliotol YellowL 2146
PL= 49%
Irgazin OrangeL 3250
PL= 38%
CinquasiaMagenta L 4530
PL= 14%
Irgazin RedL 3670
PL =37%
Cinquasia RedL 4105 HDPL= 15%
Heliogen GreenL 8730
PL= 22%
Heliogen BlueL 7101 FPL= 20%
Paliogen BlueL 6482
PL= 20%
Special Black4
PL= 15%
EFKA PX 4751 Benchmark 1 Benchmark 2
Mill base viscosity @ 100 1/s fresh
Efka® PX 4751 demonstrates benchmark performance in millbase viscosity.
Mill base viscosity with Laropal® A 81 x% pigment load
Visc
osity
[mPa
.s]
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Kronos2310
PL= 60%
Paliotol YellowL 2146
PL= 49%
Irgazin OrangeL 3250
PL= 38%
CinquasiaMagenta L 4530
PL= 14%
Irgazin RedL 3670
PL =37%
Cinquasia RedL 4105 HDPL= 15%
Heliogen GreenL 8730
PL= 22%
Heliogen BlueL 7101 FPL= 20%
Paliogen BlueL 6482
PL= 20%
Special Black4
PL= 15%
EFKA PX 4751 Benchmark 1 Benchmark 2
Efka® PX 4751 demonstrates excellent color strength at typical DOP.
Rel. color strength in a sb Alkyd/Melamine system at a typical DOP with Laropal® A81
Rel. Color strength in a sb Alkyd/melamine system
Rel
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Heliogen Green L 8730 Special Black 4
Paliogen Blue L 6482 Cinquasia Magenta L 4530
Irgazin Red L 3670 Heliogen Blue L 7101
Cinquasia Red L 4105 Paliotol Yellow L 2146
Benchmark 1 EFKA PX 4751 Benchmark 2 Benchmark 1 EFKA PX 4751 Benchmark 2
Rel. color strength in a sb Alkyd/Melamine system at a typical DOP with Laropal® A81
Efka® PX 4751 demonstrates excellent color strength at typical DOP.
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Disclaimer
Safety When handling the mentioned products, please comply with the advice and information given in the safety data sheets and
observe protective and workplace hygiene measures adequate for handling chemicals.
Note The data contained in this publication are based on our current knowledge and experience. In view of the many factors that may
affect processing and application of our products, these data do not relieve processors from carrying out their own investigations and tests; neither do these data imply any guarantee of certain properties, nor the suitability of the product for a specific purpose. Any descriptions, drawings, photographs, data, proportions, weights, etc. given herein may change withou prior information and do not constitute the agreed contractual quality of the product. The agreed contractual quality of the product results exclusively from the statements made in the product specification. It is the responsibility of the recipient of our product to ensure that any proprietary rights and existing laws and legislation are observed.
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Kronos 2360
Paliotol Yellow
L 0962 HD P.Y. 138
Cromophtal Yellow
L 1061 HD P.Y. 151
Cromophtal Yellow
L 1084 HD P.Y. 154
Sicopal Yellow L 1100
P.Y. 184
Sicopal Yellow
(L 1130) P.Y. 184
Paliotan Yellow L 1145
Irgalite Yellow
L 1254 HD P.Y. 74
Paliotan Yellow L 1945
Bayferrox Yellow 3920
P.Y. 42 Laropal A81 (63,5%ig in MPA) 21,3 43,4 37,8 35,9 27,9 27,9 24,1 59,5 23,6 23,2
Methoxypropylacetate 5,2 10,1 17,6 12 4,8 4,8 11,3 8,5 9,8 8,2 Efka PX 4751 5 8,4 12,6 9,1 6,3 6,3 5,6 14 5,6 8,3 Aerosil 200 0,5 -- -- -- 1 1 1 -- 1 0,3 Pigment 68 38 32 43 60 60 58 18 60 60
Sicotan Yellow L 2110
Irgazin Yellow L 2060
P.Y. 110
Paliotan Yellow
L 2140 HD P.Y. 139
Paliotan Yellow
L 2146 HD P.Y. 139
Sicopal Orange L 2430 P.O. 82
Irgazin Orange
L 3250 HD
Bayferrox Red
130 M P.R. 101
Irgazin Scarlet
L 3550 HD P.R. 255
Irgazin Red
L 3660 HD P.R. 254
Irgazin Red
L 3670 HD P.R. 254
Laropal A81 (63,5%ig in MPA) 20,2 37,8 27,1 27,1 20,3 34,1 21,8 33,1 36 35
Methoxypropylacetate 7,5 18,2 6,9 7,5 5,4 17,9 ---- 24,9 9,5 10,5 Efka PX 4751 2,8 14 17 16,4 2,8 10 11,7 14 17,5 17,5 Aerosil 200 1,5 -- -- -- 1,5 -- 1,5 -- -- -- Pigment 68 30 49 49 70 38 65 28 37 37
Paliogen
Red L 3885
Cinquasia Red
L 4105 HD
Novoperm Red
F3RK 70
Hostaperm Rosa
E
Cinquasia Magenta L 4530
Cinquasia Magenta L 4540
Cinquasia Violet L 5120 P.V. 19
Hostaperm Violet
RL specia P.V. 23l
Heliogen Blue
L 6700 F P.B. 15:6
Heliogen Blue
L 6960 F P.B. 15: 2
Laropal A81 (63,5%ig in MPA) 36,4 58,6 23,4 37,8 60 58,6 43,5 62,4 37,8 42,5
Methoxypropylacetate 17 12,6 21,6 22,2 14 12,6 22,5 18,4 31,2 30,5 Efka PX 4751 16,6 13,8 10 15 12 13,8 14 11,2 9 10 Pigment 30 15 45 25 14 15 20 8 22 17
Heliogen Blue
L 7085 P.B. 15.3
Heliogen Blue
L 7101 F P.B. 15 : 4
Paliogen Blue
L 6482 P.B. 60
Heliogen Green L 8730 P.G. 7
Heliogen Green L 8735 P.G. 7
Ruß FW 200
Special Black 4
Laropal A81 (63,5%ig in MPA) 45,4 59,5 37,8 54,1 54,1 41 54,8
Methoxypropylacetate 24,6 12,5 32,2 16,2 16,2 36,5 16,2
Efka PX 4751 14 8 10 7,7 7,7 12,5 14
Pigment 16 20 20 22 22 10 15
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Kronos2310
PL= 60%
PaliotolYellowL 2146
PL= 49%
IrgazinOrange
L 2990 HDPL= 27%
IrgazinOrangeL 3250
PL= 38%
CinquasiaMagentaL 4530
PL= 14%
IrgazinRed
L 3670PL =37%
CinquasiaRed
L 4105 HDPL= 15%
BayferroxRed
130MPL= 60%
HeliogenGreenL 8730
PL= 22%
HeliogenBlue
L 7101 FPL= 20%
PaliogenBlue
L 6482PL= 20%
SpecialBlack
4PL= 15%
EFKA PX 4751 EFKA PX 4330 Benchmark 1 Benchmark 2
Mill base viscosity @ 100 1/s fresh
Efka® PX 4751 demonstrates benchmark performance in millbase viscosity.
Mill base viscosity with Laropal® A 81 x% pigment load
Visc
osity
[mPa
.s]
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50556065707580859095
100105110115120125130135140
Kronos2310
PL= 60%
PaliotolYellowL 2146
PL= 49%
IrgazinOrange
L 2990 HDPL = 27%
IrgazinOrangeL 3250
PL= 38%
CinquasiaMagentaL 4530
PL= 14%
IrgazinRed
L 3670PL =37%
CinquasiaRed
L 4105 HDPL= 15%
BayferroxRed
130 MPL =60%
HeliogenGreenL 8730
PL= 22%
HeliogenBlue
L 7101 FPL= 20%
PaliogenBlue
L 6482PL= 20%
SpecialBlack
4PL= 15%
Benchmark 1 EFKA PX 4751 EFKA PX 4330
Efka® PX 4751 demonstrates excellent color strength at typical DOP.
Rel. color strength in a sb Alkyd/Melamine system at a typical DOP with Laropal® A81
Rel. Color strength in a sb Alkyd/melamine system [ 21% White -Pigment ]
Rel
. col
or s
treng
th [
Fs
Rel
. ]
Alkyd/Melamin system white 20 parts Pigmentpreparations 1 parts
150 years
Relative Color Strength with Efka® PX 4751 vs. Benchmark
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404550556065707580859095
100105110115120
Spezialschwarz4 Kronos 2310 Heliogenblau L 7101 F Heliogengrün L 8730 Irgazin Rot L 3670 Paliotol Gelb L 2146
EFKA PX 4751 EFKA PX 4330 EFKA PX 4340 Disperbyk 2150 Disperbyk 2155 Disperbyk 163
Letdown: Alkyd/Melamin - Weisslack ( 30% Pigment ) + 5% Farbpaste Auftrag auf Karton: 100µ Trocknung: 15 Min 140°C
150 years Viscosity Comparison of pigment concentrates with Efka® PX 4751 vs. Benchmark
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Spezialschwarz4 Kronos 2310 Heliogenblau L 7101 F Heliogengrün L 8730 Irgazin Rot L 3670
EFKA PX 4751 EFKA PX 4330 EFKA PX 4340 Disperbyk 2150 Disperbyk 2155 Disperbyk 163
m.P
a.s
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s-1
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Receipe of Lacquer EL2 Clear 57,5g Setal 84 ( 70% in Xylol ) 27,7g Luwipal 012 ( 58% in But/Xyl. 3: 2) 1,0g Byketol OK 1,5g Solvesso 150 0,1g Baysilon-Öl A (1% in Xylol ) 12,2g Xylol/Butanol 4: 1
Receipe of lacquer EL2 White 70,0g EL2 Clear coat diluted with Xylol / But. 4: 1 to 45% solids 30,0g Kronos 2310 Milling beads: Glass 3mm Dispersion time: 1h Skantex
Tinting: 20g White lacquer EL2 1g Pigment concentrate mixing in Speedmixer Speed Mixer 2 Min. at 2700 rpm
Application: 100µ wet on black & white carton Drying: 15 Min. 120°C.
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Benchmark 1DOP 47,0%
EFKA PX 4751DOP 47,0%
Benchmark 2DOP 47,0%
1 2 3 Laropal A 81 63,5%ig 54,8 54,8 54,8
MPA 16,2 16,2 16,2
Benchmark 1 14,0
EFKA PX 4751 14,0
Benchmark 2 15,6
Spezialschwarz 4 15,0 15,0 15,0
DOP % 47 47 47
Pigment preparations of Base Laropal A 81 Dispersing agent: Efka® PX 4751 vs. Benchmark
Color strength
mPa
.s
Seiberth
Benchmark 1 EFKA PX 4751 Benchmark 2
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194196198200202204206208210212
Benchmark 1DOP 43,0%
EFKA PX 4751DOP 43,0%
Benchmark 2DOP 43,0%
1 2 3 Laropal A 81 63,5%ig 60,0 60,0 60,0
MPA 14,0 14,0 14,0
Benchmark 1 12,0
EFKA PX 4751 12,0
Benchmark 2 13,2
Cinquasia Magenta L 4530 14,0 14,0 14,0
DOP % 43 43 43
Color strength
mPa
.s
Seiberth
Benchmark 1 EFKA PX 4751 Benchmark 2
Pigment preparations of Base Laropal® A 81 Dispersing agent: Efka® PX 4751 vs. Benchmark
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Benchmark 1DOP 25,0%
EFKA PX 4751DOP 25,0%
Benchmark 2DOP 25,0%
1 2 3 Laropal A 81 63,5%ig 37,8 37,8 37,9
MPA 32,2 32,2 31,1
Benchmark 1 10,0
EFKA PX 4751 10,0
Benchmark 2 11,1
Paliotan Blau L 6482 20,0 20,0 20,0
DOP % 25 25 25
mPa
.s
Benchmark 1 EFKA PX 4751 Benchmark 2
Pigment preparations of Base Laropal® A 81 Dispersing agent: Efka® PX 4751 vs. Benchmark
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Color strength
Seiberth
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Benchmark 1DOP 17,5%
EFKA PX 4751DOP 17,5%
Benchmark 2DOP 17,5%
1 2 3 Laropal A 81 63,5%ig 54,1 54,1 54,1
MPA 16,2 16,2 15,1
Benchmark 1 7,7
EFKA PX 4751 7,7
Benchmark 2 8,8
Heliogengrün L 8730 22 22 22
DOP % 17,5 17,5 17,5
mPa
.s
Benchmark 1 EFKA PX 4751 Benchmark 2
Pigment preparations of Base Laropal® A 81 Dispersing agent: Efka® PX 4751 vs. Benchmark
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Color strength
Seiberth
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Benchmark 1DOP 46,0%
EFKA PX 4751DOP 46,0%
Benchmark 2DOP 46,0%
1 2 3 Laropal A 81 63,5%ig 58,6 58,6 58,6
MPA 12,6 12,6 11,1
Benchmark 1 13,8
EFKA PX 4751 13,8
Benchmark 2 15,3
Cinquasia Rot L 4105 HD 15 15 15
DOP % 46 46 46
mPa
.s
Benchmark 1 EFKA PX 4751 Benchmark 2
Pigment preparations of Base Laropal® A 81 Dispersing agent: Efka® PX 4751 vs. Benchmark
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Color strength
Seiberth
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Benchmark 1DOP 9,2%
EFKA PX 4751DOP 9,2%
Benchmark 2DOP 9,2%
1 2 3 Laropal A 81 63,5%ig 34,1 34,1 34,1
MPA 20,9 20,9 20,9
Benchmark 1 7,0
EFKA PX 4751 7,0
Benchmark 2 7,0
Irgazin Orange L 3250 38 38 38
DOP % 9,2 9,2 9,2
mPa
.s
Benchmark 1 EFKA PX 4751 Benchmark 2
Pigment preparations of Base Laropal® A 81 Dispersing agent: Efka® PX 4751 vs. Benchmark
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Color strength
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Benchmark 1DOP 23,6%
EFKA PX 4751DOP 23,6%
Benchmark 2DOP 23,6%
1 2 3 Laropal A 81 63,5%ig 35,0 35,0 35,0
MPA 10,5 10,5 8,6
Benchmark 1 17,5
EFKA PX 4751 17,5
Benchmark 2 19,4
Irgazin Rot L 3670 37,0 37,0 37,0
DOP % 23,6 23,6 23,6
mPa
.s
Benchmark 1 EFKA PX 4751 Benchmark 2
Pigment preparations of Base Laropal® A 81 Dispersing agent: Efka® PX 4751 vs. Benchmark
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Color strength
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Benchmark 1DOP 16,7%
EFKA PX 4751DOP 16,7%
Benchmark 2DOP 16,7%
1 2 3 Laropal A 81 63,5%ig 27,1 27,1 27,1
MPA 7,5 7,5 5,7
Benchmark 1 16,4
EFKA PX 4751 16,4
Benchmark 2 18,2
Paliotol Gelb L 2146 49 49 49
DOP % 16,7 16,7 16,7
mPa
.s
Benchmark 1 EFKA PX 4751 Benchmark 2
Pigment preparations of Base Laropal® A 81 Dispersing agent: Efka® PX 4751 vs. Benchmark
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Color strength
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Benchmark 1DOP 25,0%
EFKA PX 4751DOP25,0%
Benchmark 2DOP 25,0%
1 2 3 Laropal A 81 63,5%ig 59,5 59,5 59,5
MPA 12,5 12,5 11,6
Benchmark 1 8,0
EFKA PX 4751 8,0
Benchmark 2 8,9
Heliogen Blue L 7101 F 20,0 20,0 20,0
DOP % 25,0 25,0 25,0
mPa
.s
Benchmark 1 EFKA PX 4751 Benchmark 2
Pigment preparations of Base Laropal® A 81 Dispersing agent: Efka® PX 4751 vs. Benchmark
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Color strength
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Benchmark 1DOP 3,7%
EFKA PX 4751DOP 3,7%
Benchmark 2DOP 3,7%
1 2 3 Laropal A 81 63,5%ig 21,3 21,3 21,3
MPA 5,2 5,2 5,2
Benchmark 1 5,0
EFKA PX 4751 5,0
Benchmark 2 5,6
Kronos 2310 68,0 68,0 68,0
DOP % 3,7 3,7 3,7
mPa
.s
Seiberth
Pigment preparations of Base Laropal® A 81 Dispersing agent: Efka® PX 4751 vs. Benchmark
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150 years
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150 years
150 years