Efka® PX 4751

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150 years Efka ® PX 4751 Next generation of high performance solvent based dispersing agents for pigment concentrates Formulation Additives Dispersions & Pigments Division European Coatings Show 2015

Transcript of Efka® PX 4751

Page 1: Efka® PX 4751

150 years 150 years

Efka® PX 4751

Next generation of high performance solvent based dispersing agents for pigment concentrates

Formulation Additives Dispersions & Pigments Division European Coatings Show 2015

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Dispersing agents Focus products for solvent-based systems

Inorganic pigments Classic organic pigments High performance pigments HCC black and phthalocyanine

Inorganic pigments Classic organic pigments High performance pigments

Inorganic pigments Classic organic pigments

Efka® PX 4310 1

Efka® PX 4330 1

Efka® PU 4020

Efka® PA 4450 Efka® FA 4608

Efka® PU 4009

solv

ent-b

ased

Efka® PU 4050 Efka® PU 4061 Efka® PU 4046 / 4063

Efka® FA 4620 2 / Efka® FA 4609 2

1 CFRP technology (Controlled Free Radical Polymerization)

Decorative OEM / Refinish / Coil coating General industrial

2 Inorganic pigments and fillers/extenders only

Efka® PX 4751 / Efka® PX 4350 1

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Efka® PX 4751 Benefits

Performance highlights Benchmark performance for a broad variety of pigments

High pigment loading at lower mill base viscosity

Higher color strength

Broad compatibility in a wide range of resin systems:

acrylate/CAB

2-Pack solvent-based PUR

solvent-based alkyd/melamine

2-Pack solvent-based epoxy systems.

Especially developed to achieve best results with Laropal® A 81

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Efka® PX 4751 is an advanced star-shaped polymer

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Acrylic block copolymer based on CFRP Technology

Advanced polymer with pigment affinic groups

Conventional polymeric dispersant with / without synergist

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Advanced Polymeric dispersing agents with core-shell structure

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resin & solvent specific !

pigment specific !

Pigment surface

Stabilizing chain with balanced compatibility to resins and solvents

Pigment affinic core with specific anchoring groups

Dispersing agent adsorb on pigment surface

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150 years Positioning overview Efka® PX 4751 shows benchmark performance for a broad variety of pigments

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C.I. Efka PX 4751

Benchmark 1

Efka PX 4751

Benchmark 1

Efka PX 4751

Benchmark 1

Paliotol YellowL 2146 P.Y. 139

Irgazin RedL 3670 HD P.R. 254

Heliogen GreenL 8730 P.G. 7

Heliogen BlauL 7101F P.B. 15:4

Kronos 2310 P.W.6

Special Black 4P.Bk. 7

Mill base viscosity with Laropal A 81

@ 100 1/s

Rel. color strength in a sb

Alkyd/MelamineRel. color strength

in a sb PUR

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150 years Positioning overview Efka® PX 4751 shows benchmark performance for a broad variety of pigments

Paliotol Yellow L 2140 Cromophtal

Yellow L 1084 HD

Cromophtal Yellow L 1061 HD

Irgalit Yellow L 1254 HD

Irgazin Yellow L 2060

Irgazin Red L 3670

Bayferrox Red 130 M

Irgazin Scarlet L 3550 HD

Novoperm Red F3RK 70

Irgazin Red L 3660 HD

Cinquasia Red L 4105 HD

Cinquasia Magenta L 4530

Cinquasia Magenta L 4540

Hostaperm Rosa E

Irgazin Orange L 2985 HD

Irgazin Orange L 3250 HD Sicopal

Orange L 2430 Cinquasia

Violet L 5120 Hostaperm

Violet RL spez.

Heliogen Green L 8730

Heliogen Green L 8735

Heliogen Blue L 7101 F

Heliogen Blue L 6700 F

Heliogen Blue L 7085

Heliogen Blue L 6960

Paliogen Blue L 6482

Kronos 2310

Special Black 4

Bayferrox Yellow 3920

Paliotol Yellow L 2146

Sicopal Yellow L 1100

Sicopal Yellow L 1130

Sicotan Yellow L 2110

Paliotol Yellow L 0962 HD

Efka® PX 4751 Laropal® A 81

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Kronos2310

PL= 60%

Paliotol YellowL 2146

PL= 49%

Irgazin OrangeL 3250

PL= 38%

CinquasiaMagenta L 4530

PL= 14%

Irgazin RedL 3670

PL =37%

Cinquasia RedL 4105 HDPL= 15%

Heliogen GreenL 8730

PL= 22%

Heliogen BlueL 7101 FPL= 20%

Paliogen BlueL 6482

PL= 20%

Special Black4

PL= 15%

EFKA PX 4751 Benchmark 1 Benchmark 2

Mill base viscosity @ 100 1/s fresh

Efka® PX 4751 demonstrates benchmark performance in millbase viscosity.

Mill base viscosity with Laropal® A 81 x% pigment load

Visc

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[mPa

.s]

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Kronos2310

PL= 60%

Paliotol YellowL 2146

PL= 49%

Irgazin OrangeL 3250

PL= 38%

CinquasiaMagenta L 4530

PL= 14%

Irgazin RedL 3670

PL =37%

Cinquasia RedL 4105 HDPL= 15%

Heliogen GreenL 8730

PL= 22%

Heliogen BlueL 7101 FPL= 20%

Paliogen BlueL 6482

PL= 20%

Special Black4

PL= 15%

EFKA PX 4751 Benchmark 1 Benchmark 2

Efka® PX 4751 demonstrates excellent color strength at typical DOP.

Rel. color strength in a sb Alkyd/Melamine system at a typical DOP with Laropal® A81

Rel. Color strength in a sb Alkyd/melamine system

Rel

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Heliogen Green L 8730 Special Black 4

Paliogen Blue L 6482 Cinquasia Magenta L 4530

Irgazin Red L 3670 Heliogen Blue L 7101

Cinquasia Red L 4105 Paliotol Yellow L 2146

Benchmark 1 EFKA PX 4751 Benchmark 2 Benchmark 1 EFKA PX 4751 Benchmark 2

Rel. color strength in a sb Alkyd/Melamine system at a typical DOP with Laropal® A81

Efka® PX 4751 demonstrates excellent color strength at typical DOP.

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Disclaimer

Safety When handling the mentioned products, please comply with the advice and information given in the safety data sheets and

observe protective and workplace hygiene measures adequate for handling chemicals.

Note The data contained in this publication are based on our current knowledge and experience. In view of the many factors that may

affect processing and application of our products, these data do not relieve processors from carrying out their own investigations and tests; neither do these data imply any guarantee of certain properties, nor the suitability of the product for a specific purpose. Any descriptions, drawings, photographs, data, proportions, weights, etc. given herein may change withou prior information and do not constitute the agreed contractual quality of the product. The agreed contractual quality of the product results exclusively from the statements made in the product specification. It is the responsibility of the recipient of our product to ensure that any proprietary rights and existing laws and legislation are observed.

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Kronos 2360

Paliotol Yellow

L 0962 HD P.Y. 138

Cromophtal Yellow

L 1061 HD P.Y. 151

Cromophtal Yellow

L 1084 HD P.Y. 154

Sicopal Yellow L 1100

P.Y. 184

Sicopal Yellow

(L 1130) P.Y. 184

Paliotan Yellow L 1145

Irgalite Yellow

L 1254 HD P.Y. 74

Paliotan Yellow L 1945

Bayferrox Yellow 3920

P.Y. 42 Laropal A81 (63,5%ig in MPA) 21,3 43,4 37,8 35,9 27,9 27,9 24,1 59,5 23,6 23,2

Methoxypropylacetate 5,2 10,1 17,6 12 4,8 4,8 11,3 8,5 9,8 8,2 Efka PX 4751 5 8,4 12,6 9,1 6,3 6,3 5,6 14 5,6 8,3 Aerosil 200 0,5 -- -- -- 1 1 1 -- 1 0,3 Pigment 68 38 32 43 60 60 58 18 60 60

Sicotan Yellow L 2110

Irgazin Yellow L 2060

P.Y. 110

Paliotan Yellow

L 2140 HD P.Y. 139

Paliotan Yellow

L 2146 HD P.Y. 139

Sicopal Orange L 2430 P.O. 82

Irgazin Orange

L 3250 HD

Bayferrox Red

130 M P.R. 101

Irgazin Scarlet

L 3550 HD P.R. 255

Irgazin Red

L 3660 HD P.R. 254

Irgazin Red

L 3670 HD P.R. 254

Laropal A81 (63,5%ig in MPA) 20,2 37,8 27,1 27,1 20,3 34,1 21,8 33,1 36 35

Methoxypropylacetate 7,5 18,2 6,9 7,5 5,4 17,9 ---- 24,9 9,5 10,5 Efka PX 4751 2,8 14 17 16,4 2,8 10 11,7 14 17,5 17,5 Aerosil 200 1,5 -- -- -- 1,5 -- 1,5 -- -- -- Pigment 68 30 49 49 70 38 65 28 37 37

Paliogen

Red L 3885

Cinquasia Red

L 4105 HD

Novoperm Red

F3RK 70

Hostaperm Rosa

E

Cinquasia Magenta L 4530

Cinquasia Magenta L 4540

Cinquasia Violet L 5120 P.V. 19

Hostaperm Violet

RL specia P.V. 23l

Heliogen Blue

L 6700 F P.B. 15:6

Heliogen Blue

L 6960 F P.B. 15: 2

Laropal A81 (63,5%ig in MPA) 36,4 58,6 23,4 37,8 60 58,6 43,5 62,4 37,8 42,5

Methoxypropylacetate 17 12,6 21,6 22,2 14 12,6 22,5 18,4 31,2 30,5 Efka PX 4751 16,6 13,8 10 15 12 13,8 14 11,2 9 10 Pigment 30 15 45 25 14 15 20 8 22 17

Heliogen Blue

L 7085 P.B. 15.3

Heliogen Blue

L 7101 F P.B. 15 : 4

Paliogen Blue

L 6482 P.B. 60

Heliogen Green L 8730 P.G. 7

Heliogen Green L 8735 P.G. 7

Ruß FW 200

Special Black 4

Laropal A81 (63,5%ig in MPA) 45,4 59,5 37,8 54,1 54,1 41 54,8

Methoxypropylacetate 24,6 12,5 32,2 16,2 16,2 36,5 16,2

Efka PX 4751 14 8 10 7,7 7,7 12,5 14

Pigment 16 20 20 22 22 10 15

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Kronos2310

PL= 60%

PaliotolYellowL 2146

PL= 49%

IrgazinOrange

L 2990 HDPL= 27%

IrgazinOrangeL 3250

PL= 38%

CinquasiaMagentaL 4530

PL= 14%

IrgazinRed

L 3670PL =37%

CinquasiaRed

L 4105 HDPL= 15%

BayferroxRed

130MPL= 60%

HeliogenGreenL 8730

PL= 22%

HeliogenBlue

L 7101 FPL= 20%

PaliogenBlue

L 6482PL= 20%

SpecialBlack

4PL= 15%

EFKA PX 4751 EFKA PX 4330 Benchmark 1 Benchmark 2

Mill base viscosity @ 100 1/s fresh

Efka® PX 4751 demonstrates benchmark performance in millbase viscosity.

Mill base viscosity with Laropal® A 81 x% pigment load

Visc

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[mPa

.s]

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Kronos2310

PL= 60%

PaliotolYellowL 2146

PL= 49%

IrgazinOrange

L 2990 HDPL = 27%

IrgazinOrangeL 3250

PL= 38%

CinquasiaMagentaL 4530

PL= 14%

IrgazinRed

L 3670PL =37%

CinquasiaRed

L 4105 HDPL= 15%

BayferroxRed

130 MPL =60%

HeliogenGreenL 8730

PL= 22%

HeliogenBlue

L 7101 FPL= 20%

PaliogenBlue

L 6482PL= 20%

SpecialBlack

4PL= 15%

Benchmark 1 EFKA PX 4751 EFKA PX 4330

Efka® PX 4751 demonstrates excellent color strength at typical DOP.

Rel. color strength in a sb Alkyd/Melamine system at a typical DOP with Laropal® A81

Rel. Color strength in a sb Alkyd/melamine system [ 21% White -Pigment ]

Rel

. col

or s

treng

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Fs

Rel

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Alkyd/Melamin system white 20 parts Pigmentpreparations 1 parts

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Relative Color Strength with Efka® PX 4751 vs. Benchmark

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100105110115120

Spezialschwarz4 Kronos 2310 Heliogenblau L 7101 F Heliogengrün L 8730 Irgazin Rot L 3670 Paliotol Gelb L 2146

EFKA PX 4751 EFKA PX 4330 EFKA PX 4340 Disperbyk 2150 Disperbyk 2155 Disperbyk 163

Letdown: Alkyd/Melamin - Weisslack ( 30% Pigment ) + 5% Farbpaste Auftrag auf Karton: 100µ Trocknung: 15 Min 140°C

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150 years Viscosity Comparison of pigment concentrates with Efka® PX 4751 vs. Benchmark

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Spezialschwarz4 Kronos 2310 Heliogenblau L 7101 F Heliogengrün L 8730 Irgazin Rot L 3670

EFKA PX 4751 EFKA PX 4330 EFKA PX 4340 Disperbyk 2150 Disperbyk 2155 Disperbyk 163

m.P

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s-1

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Receipe of Lacquer EL2 Clear 57,5g Setal 84 ( 70% in Xylol ) 27,7g Luwipal 012 ( 58% in But/Xyl. 3: 2) 1,0g Byketol OK 1,5g Solvesso 150 0,1g Baysilon-Öl A (1% in Xylol ) 12,2g Xylol/Butanol 4: 1

Receipe of lacquer EL2 White 70,0g EL2 Clear coat diluted with Xylol / But. 4: 1 to 45% solids 30,0g Kronos 2310 Milling beads: Glass 3mm Dispersion time: 1h Skantex

Tinting: 20g White lacquer EL2 1g Pigment concentrate mixing in Speedmixer Speed Mixer 2 Min. at 2700 rpm

Application: 100µ wet on black & white carton Drying: 15 Min. 120°C.

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Benchmark 1DOP 47,0%

EFKA PX 4751DOP 47,0%

Benchmark 2DOP 47,0%

1 2 3 Laropal A 81 63,5%ig 54,8 54,8 54,8

MPA 16,2 16,2 16,2

Benchmark 1 14,0

EFKA PX 4751 14,0

Benchmark 2 15,6

Spezialschwarz 4 15,0 15,0 15,0

DOP % 47 47 47

Pigment preparations of Base Laropal A 81 Dispersing agent: Efka® PX 4751 vs. Benchmark

Color strength

mPa

.s

Seiberth

Benchmark 1 EFKA PX 4751 Benchmark 2

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Benchmark 1DOP 43,0%

EFKA PX 4751DOP 43,0%

Benchmark 2DOP 43,0%

1 2 3 Laropal A 81 63,5%ig 60,0 60,0 60,0

MPA 14,0 14,0 14,0

Benchmark 1 12,0

EFKA PX 4751 12,0

Benchmark 2 13,2

Cinquasia Magenta L 4530 14,0 14,0 14,0

DOP % 43 43 43

Color strength

mPa

.s

Seiberth

Benchmark 1 EFKA PX 4751 Benchmark 2

Pigment preparations of Base Laropal® A 81 Dispersing agent: Efka® PX 4751 vs. Benchmark

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Benchmark 1DOP 25,0%

EFKA PX 4751DOP 25,0%

Benchmark 2DOP 25,0%

1 2 3 Laropal A 81 63,5%ig 37,8 37,8 37,9

MPA 32,2 32,2 31,1

Benchmark 1 10,0

EFKA PX 4751 10,0

Benchmark 2 11,1

Paliotan Blau L 6482 20,0 20,0 20,0

DOP % 25 25 25

mPa

.s

Benchmark 1 EFKA PX 4751 Benchmark 2

Pigment preparations of Base Laropal® A 81 Dispersing agent: Efka® PX 4751 vs. Benchmark

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Benchmark 1DOP 17,5%

EFKA PX 4751DOP 17,5%

Benchmark 2DOP 17,5%

1 2 3 Laropal A 81 63,5%ig 54,1 54,1 54,1

MPA 16,2 16,2 15,1

Benchmark 1 7,7

EFKA PX 4751 7,7

Benchmark 2 8,8

Heliogengrün L 8730 22 22 22

DOP % 17,5 17,5 17,5

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.s

Benchmark 1 EFKA PX 4751 Benchmark 2

Pigment preparations of Base Laropal® A 81 Dispersing agent: Efka® PX 4751 vs. Benchmark

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Color strength

Seiberth

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Benchmark 1DOP 46,0%

EFKA PX 4751DOP 46,0%

Benchmark 2DOP 46,0%

1 2 3 Laropal A 81 63,5%ig 58,6 58,6 58,6

MPA 12,6 12,6 11,1

Benchmark 1 13,8

EFKA PX 4751 13,8

Benchmark 2 15,3

Cinquasia Rot L 4105 HD 15 15 15

DOP % 46 46 46

mPa

.s

Benchmark 1 EFKA PX 4751 Benchmark 2

Pigment preparations of Base Laropal® A 81 Dispersing agent: Efka® PX 4751 vs. Benchmark

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Color strength

Seiberth

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Benchmark 1DOP 9,2%

EFKA PX 4751DOP 9,2%

Benchmark 2DOP 9,2%

1 2 3 Laropal A 81 63,5%ig 34,1 34,1 34,1

MPA 20,9 20,9 20,9

Benchmark 1 7,0

EFKA PX 4751 7,0

Benchmark 2 7,0

Irgazin Orange L 3250 38 38 38

DOP % 9,2 9,2 9,2

mPa

.s

Benchmark 1 EFKA PX 4751 Benchmark 2

Pigment preparations of Base Laropal® A 81 Dispersing agent: Efka® PX 4751 vs. Benchmark

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Color strength

Seiberth

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Benchmark 1DOP 23,6%

EFKA PX 4751DOP 23,6%

Benchmark 2DOP 23,6%

1 2 3 Laropal A 81 63,5%ig 35,0 35,0 35,0

MPA 10,5 10,5 8,6

Benchmark 1 17,5

EFKA PX 4751 17,5

Benchmark 2 19,4

Irgazin Rot L 3670 37,0 37,0 37,0

DOP % 23,6 23,6 23,6

mPa

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Benchmark 1 EFKA PX 4751 Benchmark 2

Pigment preparations of Base Laropal® A 81 Dispersing agent: Efka® PX 4751 vs. Benchmark

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Color strength

Seiberth

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Benchmark 1DOP 16,7%

EFKA PX 4751DOP 16,7%

Benchmark 2DOP 16,7%

1 2 3 Laropal A 81 63,5%ig 27,1 27,1 27,1

MPA 7,5 7,5 5,7

Benchmark 1 16,4

EFKA PX 4751 16,4

Benchmark 2 18,2

Paliotol Gelb L 2146 49 49 49

DOP % 16,7 16,7 16,7

mPa

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Benchmark 1 EFKA PX 4751 Benchmark 2

Pigment preparations of Base Laropal® A 81 Dispersing agent: Efka® PX 4751 vs. Benchmark

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Seiberth

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Benchmark 1DOP 25,0%

EFKA PX 4751DOP25,0%

Benchmark 2DOP 25,0%

1 2 3 Laropal A 81 63,5%ig 59,5 59,5 59,5

MPA 12,5 12,5 11,6

Benchmark 1 8,0

EFKA PX 4751 8,0

Benchmark 2 8,9

Heliogen Blue L 7101 F 20,0 20,0 20,0

DOP % 25,0 25,0 25,0

mPa

.s

Benchmark 1 EFKA PX 4751 Benchmark 2

Pigment preparations of Base Laropal® A 81 Dispersing agent: Efka® PX 4751 vs. Benchmark

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Color strength

Seiberth

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Benchmark 1DOP 3,7%

EFKA PX 4751DOP 3,7%

Benchmark 2DOP 3,7%

1 2 3 Laropal A 81 63,5%ig 21,3 21,3 21,3

MPA 5,2 5,2 5,2

Benchmark 1 5,0

EFKA PX 4751 5,0

Benchmark 2 5,6

Kronos 2310 68,0 68,0 68,0

DOP % 3,7 3,7 3,7

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Seiberth

Pigment preparations of Base Laropal® A 81 Dispersing agent: Efka® PX 4751 vs. Benchmark

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