Dual Pool Shale Shaker SG3X Motor

DUAL POOL 600 SERIES SHAKER

SG3X MOTOR

Issued 06 Mar 09 Rev. 15 May 11

Maintenance & Operation Manual

Derrick Equipment Company 15630 Export Plaza Drive

Houston, Texas 77032 Phone: 281.590.3003

Toll Free: 1.866.DERRICK Fax: 281.442.6948

www.derrickequipment.com

UNIT NUMBER IS KEY TO DERRICK SERVICE All inquiries to Derrick must include the equipment unit number. The stainless steel unit number tag attached to each piece of Derrick equipment is your key to efficient service and support.

Typical Derrick Unit Number

This unique number gives vital information to Service personnel who use it to identify the correct parts when filling orders, provide accurate responses to service questions, track documentation, and trace the equipments history or configuration. In short, the unit number provides the critical information needed to ensure that Derrick customers receive the best possible service. The unit number consists of a two-character alphabetic prefix that identifies the equipment type and a series of numeric characters that signify the sequence of the machines manufacture. For example, unit number MA000001 would be the first screening machine manufactured by Derrick. Alphabetic prefixes currently in use are:

MA - Screening Machine AD - Desilter and Desander DG - Degasser AG - Mud Agitator CF - Centrifuge SF - Screen Frame

To ensure that it will remain intact over many years of rigorous service, the heavy-gage tag is riveted to a structural member such as the shaker support structure. It is not to be confused with any other identifier on the machine such as a vibrator motor serial number. For convenient availability, the unit number is also recorded in the Operation and Maintenance manual shipped with the equipment. When contacting Derrick for any equipment question or need, always have the unit number in your possession. Its the best way to get the most efficient service from our dedicated Service and Engineering personnel.

ABOUT THIS MANUAL This document is published in both printed and electronic form. In the electronic manual, all sections and paragraphs listed in the CONTENTS are linked to the corresponding text. Navigate the electronic manual as follows: 1. To view any desired information, display the CONTENTS page and move the

cursor to the desired paragraph or section title. 2. To display the desired information, click on the listing when the pointing

finger appears over the text. 3. When finished viewing the text, press Alt + left arrow key to return to the

CONTENTS page. 4. If desired to return to the same information, press Alt + right arrow. To locate

a different item, repeat steps 1 and 2.

The content of this document is subject to change at any time. Information provided does not cover all details or variations possible with DERRICK equipment, nor does it cover every contingency that may be met in conjunction with installation, operation, maintenance, or troubleshooting of the equipment. Should additional information be required, or should situations arise that are not covered by this manual, bring the matter to the attention of your local DERRICK representative or the Service Department at DERRICK Corporation in Buffalo, New York. Copyright 2008 by DERRICK CORPORATION

CONTENTS

15 May 11 TOC-1 DP600Series

Section Page Date

1 - Introduction............................................................................................ 1-1 30 Sep 10 Overview 1-1 Safety ..................................................................................................... 1-1 Equipment Use....................................................................................... 1-2 Equipment Orientation............................................................................ 1-2 Vapor Extraction (VE) Machines ............................................................ 1-2 Description and Operation...................................................................... 1-3 Product Support ..................................................................................... 1-8

2 - Safety ...................................................................................................... 2-1 30 Oct 10 Introduction ............................................................................................ 2-1 Warnings ................................................................................................ 2-1 Material Safety Data Sheets (MSDSs) ................................................... 2-3

3 - Installation.............................................................................................. 3-1 15 Aug 10 General .................................................................................................. 3-1 Safety ..................................................................................................... 3-1 Installation Sequence............................................................................. 3-2 Storage................................................................................................... 3-2 Site Preparation and Clearance Requirements...................................... 3-2 Moving/Positioning the Equipment ......................................................... 3-3 Desilter and Desander Installation ......................................................... 3-5 Equipment Leveling................................................................................ 3-10 Shipping Brackets .................................................................................. 3-10 Feed and Discharge Connections.......................................................... 3-11 Electric Power Connections ................................................................... 3-13 Compressed Air Supply Connection ...................................................... 3-14 Screen Panel Installation........................................................................ 3-15 Machine Startup ..................................................................................... 3-16

CONTENTS

TOC-2 15 May 11 DP600Series

Section Page Date

4 - Operating Instructions........................................................................... 4-1 22 Mar 09 General ................................................................................................... 4-1 Operating Safety..................................................................................... 4-1 Initial Startup........................................................................................... 4-1 Normal Startup........................................................................................ 4-2 Normal Shutdown ................................................................................... 4-2 Emergency Shutdown............................................................................. 4-2 Desilter and Desander Operation ........................................................... 4-3 AWD Operation....................................................................................... 4-6 Screen Compression System Operation................................................. 4-8

5 - Maintenance............................................................................................ 5-1 30 Oct 10 General ................................................................................................... 5-1 Routine Maintenance.............................................................................. 5-1 Vibrator Motors ....................................................................................... 5-2 Screen Frame ......................................................................................... 5-2 Screen Panels ........................................................................................ 5-4 Scalping Deck Screens (DP626/628 Only) ............................................. 5-6 Screen Bed Material ............................................................................... 5-6 Feeder Seal ............................................................................................ 5-7 Adjustable While Drilling (AWD) ............................................................. 5-8 Hydraulic and Pneumatic Parts............................................................... 5-12 Recommended Spare Parts.................................................................... 5-17 Desilter.................................................................................................... 5-18

6 - Screen Retention System ...................................................................... 6-1 06 Mar 09 General ................................................................................................... 6-1 Description and Operation ...................................................................... 6-1 Screen Panel Replacement .................................................................... 6-2 Screen Retention Cylinder Replacement................................................ 6-2 Retention Cylinder Manifold.................................................................... 6-4 Replacement Parts ................................................................................. 6-4

CONTENTS

30 Oct 10 TOC-3 DP600Series

Section Page Date

7 - Vibrator Motors ...................................................................................... 7-1 31 Oct 10 Description ............................................................................................. 7-1 Repair Restrictions................................................................................. 7-2 Safety ..................................................................................................... 7-2 Storage................................................................................................... 7-3 Operating Environment .......................................................................... 7-3 Replacement Parts................................................................................. 7-3 Removal and Installation ........................................................................ 7-6 Electrical Connections............................................................................ 7-9 Preventive Maintenance......................................................................... 7-15 Oil Change Procedure............................................................................ 7-16 Bearing Replacement............................................................................. 7-19 Troubleshooting ..................................................................................... 7-32

8 - Reference Drawings .............................................................................. 8-1 15 May 11

9 - Installation and Maintenance Log ........................................................ 9-1 06 Mar 09

10 - Supplier Data.......................................................................................... 10-1 06 Mar 09

SECTION 1 - INTRODUCTION

OVERVIEW This manual provides instructions for installing, operating and maintaining the Derrick Dual Pool 600 Series Shakers (Figure 1-1). The manual is divided into several sections to assist the user in readily accessing the information.

Both standard and vapor extraction (VE) versions are covered. The DP600VE machine is equipped with covers and a specially designed feeder to prevent the escape of vapors released from process material during the screening process. The VE machine also offers the same features and options (except feeder options) as the standard machine.

Personnel responsible for transporting, installing, operating, or performing maintenance on this equipment are required to read and understand the information and instructions in this manual. One copy of this manual should be available and accessible at the equipment location.

For maximum safety and performance, no additions and/or changes may be made to the equipment without the explicit written permission of Derrick Corporation. Genuine Derrick repair/replacement parts are required.

Figure 1-1 Typical DP600 Series Mud Cleaner

SAFETY Section 2 of this manual contains relevant safety information relating to both operation and maintenance of this equipment. Be sure this information is read and understood by all personnel.

DO NOT operate the equipment if defective or faulty mechanical or electrical components are detected.

30 Sep 10 1-1 DP600

INTRODUCTION

EQUIPMENT USE The DP600 Series Shakers and associated components are designed expressly for removal of drilling solids from drilling fluid. Derrick does not authorize any other use of this equipment. Intended usage of equipment includes compliance with the operating, maintenance and safety instructions provided in this manual.

EQUIPMENT ORIENTATION Throughout this manual, references to front, rear, left, and right are based on viewing the DP600 shaker from the feed end and looking toward the discharge end.

VAPOR EXTRACTION (VE) MACHINES Vapor extraction machines have three hinged covers over the screen bed (Figure 1-2) to limit escape of vapors from the slurry during screening. An exhaust pipe on the rear of the feeder permits attachment of an exhaust duct to extract gases from the feeder. For mud cleaners an exhaust pipe is also provided on the desilter collection pan to limit escape of gases from the feed slurry entering the feeder from the collection pan.

Figure 1-2 DP600 Vapor Extraction (VE) Machine Covers

1-2 30 Sep 10 DP600

INTRODUCTION

30 Sep 10 1-3 DP600

DESCRIPTION AND OPERATION The DP600 Series shakers are dual-motor, high-frequency, linear-motion vibrating screen machines available in six-panel or eight-panel configurations. Available options consist of a scalping deck and desilter/desander package. Major components are shown in Figure 1-2. Following are the available model numbers and configurations:

616 - Six-panel without scalping deck 618 - Eight-panel without scalping deck 626 - Six-panel with scalping deck 628 - Eight-panel with scalping deck

The machines detachable front-mounted operator control panel is used to turn the machine on and off as well as adjust the deck-angle within the adjustment range of 1 to 7. The optional urethane screen scalping deck removes coarse solids in advance of fine screening for extended life of the primary deck screen panels. The low-weir-seal feeder eliminates mud leakage and allows the bell nipple to be set at just 34. And the hinged hood covering the feeder end reduces splashing of process material.

Screen Frame The screen frame is attached to the pivot frame by float mounts that isolate its vibratory motion from the pivot frame. Process material flows onto the primary screen deck either from the scalping deck (Model 626/628) or from the feeder. To receive flow directly from the feeder, the bypass control must be set to bypass the scalping deck.

Dual concave screen beds direct the feed material toward the center of each pool. The unique screen retention system conforms the screens to the concave shape of the screen beds, which are covered with oil-resistant cushions. Screen panels are retained by spring-loaded pins that are retracted by field-replaceable pneumatic retention cylinders powered by 90 psig minimum, 2 cfm air. A single-source manifold connection is used to distribute air to all retention mechanisms. Retention cylinders on each side of the screen frame retain the screen panels by forcing the outer edges of the panels inward, causing them to form the distinctive concave shape that characterizes the dual-pool shaker, and locking them securely to the screen bed. The systems fail-safe design ensures positive screen retention without air pressure. Consequently, machine operation may continue if air pressure is lost. Additionally, screens can be manually released if necessary.

INTRODUCTION

DESCRIPTION AND OPERATION (CONTD)

Figure 1-2 DP600 Series Major Components

Adjustable While Drilling (AWD) The screen frame is mounted in a pivot frame which is attached to the stationary hopper by a pivot block. This arrangement allows the discharge end of the screen frame to be moved up and down by the hydraulic AWD, which is operated by two control buttons (UP - DOWN) on the operator control panel. A self-contained hydraulic package consisting of an electric pump drive motor, hydraulic pump, reservoir, and manifold (Figure 1-3) provides the required hydraulic pressure. Two hydraulic cylinders (one on each side off the machine) drive the screen frame up and down.

By pressing the UP or DOWN button on the control panel, the pump drive motor rotates in the proper direction to either extend or retract the cylinders. In one direction, the pump forces pressurized fluid to the extension side of the cylinders to raise the screen frame; in the opposite direction, fluid is drained from the cylinders to lower the screen frame.

1-4 30 Sep 10 DP600

INTRODUCTION

Hydraulic fluid is drawn from the reservoir (Figure 1-4), pressurized by the motor-driven, bi-directional pump, and directed through the distribution manifold to either extend or retract the cylinders. Cylinder extension raises the screen frame, and retraction lowers the frame throughout its travel range of +1 to +7. For safety, when the screen frame is in the raised position, fluid is locked in the cylinders by a check valve.

Figure 1-3 Hydraulic AWD Major Components

30 Sep 10 1-5 DP600

INTRODUCTION

Figure 1-4 AWD Hydraulic Schematic

Scalping Deck The scalping deck installed on Models 626 and 628 removes large solids from the feed slurry as it flows to the primary screens. Removable urethane screen panels on the scalping deck are retained securely by heavy-duty spring clips. The scalping decks three-dimensional shape allows liquid to flow out the sides, while solids are conveyed along the trough. Unrestricted access is provided to the primary deck screens for inspection, cleaning, and replacement without removing scalping deck panels. If conditions permit, the scalping deck may be bypassed, directing the entire process flow to the primary screens.

1-6 30 Sep 10 DP600

INTRODUCTION

Vibrator Motors Two continuous-duty vibratory motors deliver high G force to the screen frame. Opposing electrical polarities cause the motors to rotate in opposite directions, thereby imparting linear vibrating motion to the screen frame for proper conveyance of solids toward the discharge end of the machine. The vibrating motion of the screen frame is isolated from the surrounding structural members by float mounts.

Desilter and Desander The optional 4 hydrocyclone desilter removes 10- to 74-micron solids from drilling fluid (mud), and the 10 hydrocyclone desander is used to separate solids in the 40- to 100-micron range, The body is the main component of the 4 hydrocyclone (Figure 1-5). A cone tip is threaded into the bottom of the body. The soft apex is positioned in the tapered hole inside the triangular nut, which is threaded onto the cone tip.

The optional 10 desander consists of three main components: Upper, middle, and lower sections (Figure 1-6). The soft orifice bushing (apex) is positioned in the tapered hole inside the orifice nut, which is threaded onto the lower section. The orifice nut is threaded onto the lower section.

By varying the opening of the apex, the hydrocyclone spray pattern may be adjusted during operation. Turning the orifice nut clockwise compresses the apex, thereby reducing the diameter of its opening. Turning the nut counterclockwise releases compression, allowing the apex to return to its original size.

Figure 1-5 4 Hydrocyclone Desilter Components

30 Sep 10 1-7 DP600

INTRODUCTION

Figure 1-6 10 Hydrocyclone Desander Components

Feeders Box and weir feeders are available for the DP600 shaker. For DP600VE machines, the box and weir feeders have an exhaust pipe for connecting vapor extraction equipment.

Box Feeder The box feeder receives and distributes feed slurry either directly from the process stream or from a desilter collection pan. Pipe targets of 8 and 10 (203mm and 254mm) diameters are provided on the rear of the box feeder for locating the customer feed connection. The rear of the VE feeder has a 6 152.4mm) exhaust pipe with Victaulic groove for connecting a gas extraction duct.

Weir Feeder The weir feeder is divided into inlet and outlet tanks. This design allows the inlet slurry to rise in the inlet tank until sufficiently high to overflow into the outlet section. Slurry is evenly distributed across the screen frame, as slurry flows uniformly over the weir. Pipe targets of 8, 10 and 12 (203mm, 254mm, and 305mm) are provided on the rear of the feeder for locating the customer feed connection. A clean-out plug is provided at the bottom of the inlet tank to facilitate removal of accumulated solids. The rear of the VE feeder has a 6 (152.4mm) exhaust pipe with Victaulic groove for connecting a gas extraction duct.

1-8 30 Sep 10 DP600

INTRODUCTION

PRODUCT SUPPORT Derrick offers 24-hour per day, 7-day a week product support. Product support includes screen replacement / ordering information and repair / replacement parts and service for the entire product line. Refer to the following table for the parts / service center nearest you.

PARTS SALES & SERVICE LOCATIONS

Colorado

Grand Junction - 970.241.2417

Louisiana

Broussard - 877.635.3354

New York - Corporate Headquarters

Buffalo - 716.683.9010

Oklahoma

Oklahoma City - 405.208.4070

Texas

Houston (Oilfield Headquarters) - 866.DERRICK (337.7425) 281.590.3003 North Texas (Bridgeport) - 405.208.4070

South Texas (Corpus Christi) - 361.299.6080

West Texas (Midland) - 405.397.4089

East Texas, Arkansas, and Louisiana - 281.546.1166

Wyoming

Casper - 307.265.0445

North Dakota

Williston - 701.572.0722

30 Sep 10 1-9 DP600

SECTION 2 - SAFETY

INTRODUCTION This section contains a summary of WARNINGS used in this manual and a list of material safety data sheets (MSDSs) applicable to the equipment. The DP600 shaker has been designed to perform the stated functions safely.

WARNINGS All persons responsible for operation and maintenance of this equipment must read and understand all safety information in this manual prior to operating and/or maintaining the equipment. The safety warnings listed below are included in applicable procedures throughout this manual.

Sound

WARNING! TO PROTECT AGAINST HEARING LOSS, HEARING PROTECTION SHOULD BE WORN AT ALL TIMES WHEN WORKING ON OR NEAR DERRICK MACHINES.

Electrical Hazards

WARNING! TO AVOID SERIOUS PERSONAL INJURY BE SURE THAT EQUIPMENT IS DE-ENERGIZED, LOCKED OUT, AND TAGGED OUT PRIOR TO PERFORMING MAINTENANCE AND/OR ADJUSTMENTS.

WARNING! MOTORS MUST BE OPERATED AT THE DESIGNATED SUPPLY VOLTAGE.

WARNING! HIGH VOLTAGE MAY BE PRESENT. BE SURE THAT FUSED DISCONNECT SUPPLYING ELECTRIC POWER TO THIS EQUIPMENT IS OPEN. LOCK OUT AND TAG OUT POWER SUPPLY TO PREVENT ACCIDENTAL APPLICATION OF POWER WHILE MAINTENANCE AND/OR ADJUSTMENTS ARE IN PROGRESS.

WARNING! ELECTRICAL CONNECTIONS MUST BE MADE IN ACCORDANCE WITH THE NATIONAL ELECTRICAL CODE (NEC) AND ALL APPLICABLE LOCAL CODES. FAILURE TO COMPLY MAY RESULT IN AN UNSAFE CONDITION THAT COULD INJURE PERSONNEL AND/OR DAMAGE EQUIPMENT. ENSURE THAT ALL ELECTRICAL AND CONDUIT CONNECTIONS ARE SECURE.

30 Oct 10 2-1 DP600Series

SAFETY

Equipment Handling

WARNING! USE SPREADER BARS TO PREVENT DAMAGE WHEN LIFTING THE EQUIPMENT.

WARNING! TO ENSURE PROPER BALANCE AND ORIENTATION WHEN UNIT IS RAISED AND PREVENT DAMAGE TO COMPONENTS, ATTACH LIFTING SLING ONLY AT DESIGNATED LIFT POINTS. DO NOT ATTEMPT LIFTING BY ATTACHMENT TO MOTOR OR ANY OTHER LOCATION.

WARNING! BE SURE THAT HANDLING DEVICES HAVE SUFFICIENT LIFTING CAPACITY TO SAFELY HANDLE THE WEIGHT OF THE EQUIPMENT.

WARNING! DO NOT REMOVE SHIPPING BRACKETS UNTIL EQUIPMENT HAS BEEN POSITIONED AT FINAL INSTALLATION SITE.

Operation

WARNING! MOTOR HOUSING BECOMES HOT DURING OPERATION AND MAY CAUSE SEVERE BURNS. DO NOT TOUCH MOTOR HOUSING DURING OR IMMEDIATELY AFTER MOTOR HAS BEEN OPERATING.

WARNING! ALL OPERATING AND MAINTENANCE PERSONNEL MUST READ AND UNDERSTAND ALL SAFETY INFORMATION IN THIS MANUAL BEFORE WORKING WITH THE EQUIPMENT.

WARNING! BE SURE THAT ALL PERSONNEL ARE CLEAR OF MACHINE BEFORE ADJUSTING ANGLE OF SCREEN BED. HANDS AND FEET CAN BE CRUSHED BY THE MOVING SCREEN FRAME.

WARNING! BE SURE THAT ALL PERSONNEL ARE CLEAR OF SCREEN BED BEFORE MOVING SCREEN OPERATING HANDLES. FINGERS CAN BE CRUSHED BY MOVING PARTS DURING THE COMPRESSION AND RELEASE OF SCREENS.

WARNING! DO NOT ATTEMPT TO OPERATE EQUIPMENT WITH SHIPPING BRACKETS INSTALLED.

Maintenance

WARNING! HIGH VOLTAGE MAY BE PRESENT. ALWAYS OPEN FUSED DISCONNECT SUPPLYING ELECTRIC POWER TO THE EQUIPMENT, AND LOCK OUT AND TAG OUT POWER SUPPLY BEFORE PERFORMING ANY MAINTENANCE AND/OR ADJUSTMENTS OF EQUIPMENT.

2-2 30 Oct 10 DP600Series

SAFETY

Storage

WARNING! MOTOR MAY BE DAMAGED BY STORING IN A HIGH HUMIDITY ENVIRONMENT (GREATER THAN 50% RH). OUT-OF-SERVICE MOTOR(S) MUST BE STORED IN A LOW-HUMIDITY ENVIRONMENT.

MATERIAL SAFETY DATA SHEETS (MSDSs) Material Safety Data Sheets (MSDSs) for exterior finish products are included in this section to advise personnel of the properties and any possible hazards associated with these materials. Emergency first aid procedures, special precautions, emergency telephone number, and other relevant data are contained in the MSDSs. These documents were prepared by the product manufacturers, which have sole responsibility for accuracy of the information.

The MSDSs included are current as of the publication date of this manual and are supplied only for reference. It is the customers responsibility to contact the product manufacturer for the latest documents.

In addition to the finish product documents, MSDSs are listed for other products used in the equipment. To ensure that current information is available, the MSDS should be obtained for the product at the time of purchase. Please note that equivalent products for the listed materials are approved by Derrick for the corresponding applications.

MATERIAL DESCRIPTION - WHERE USED MSDS No. / Date

Paints and Coatings Devoe DEVTHANE 359 - Top Coat1 DEVTHANE 359 / 05-06-08 Devoe DEVRAN 220K - Mid Coat1 DEVRAN 220 / 05-06-08 Devoe CATHACOAT 302H - Prime Coat1 CATHACOAT 302H / 08-11-06 PPG Dimetcote 302H Green 302F0250 Resin - Top Coat1 1302H-5A / 04-11-10 PPG Dimetcote 302H Clear 302G0910 Cure - Top Coat1 1302H-B / 01-21-10 PPG PSX 700 Neutral Tint Resin - Undercoat1 PX700T3 / 02-28-08 PPG PSX 700FD Cure - Undercoat1 PX700FD-B / 01-11-07 Sundur Beige Polyester TGIC - Vibrator Motor P-1609 / 10-30-02

Lubricants and Sealants Chevron GST ISO 68 Turbine Oil - Vibrator Motor Bearings Contact Manufacturer* Loctite 76764 Anti-Seize Lubricant - Fasteners Contact Manufacturer*

Hydraulic Fluid Derrick ISO 32 AW - AWD 60009-22-32-46 / 01-06

30 Oct 10 2-3 DP600Series

1 Exterior finish products were changed during 2010. Refer to specification data sheet supplied with machine to determine exterior finish products used on machine.

* MSDS not included; contact manufacturer for latest revision.

MATERIAL SAFETY DATA SHEET

The information contained herein is based on data available at the time of preparation of this data sheet which ICI Paints believes to be reliable. However, no warranty is expressed or implied regarding the accuracy of thisdata. ICI Paints shall not be responsible for the use of this information, or of any product, method or apparatus mentioned and you must make your own determination of its suitability and completeness for your own use,for the protection of the environment, and the health and safety of your employees and the users of this material.Complies with OSHA hazard communication standard 29CFR1910.1200.

prepared 05/06/08D

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HAZARDS IDENTIFICATION (ANSI Section 3)Primary route(s) of exposure : Inhalation, skin contact, eye contact, ingestion.Effects of overexposure : Inhalation : Irritation of respiratory tract. Prolonged inhalation may lead to. Inhalation of spray mist

may cause irritation of respiratory tract. Mucous membrane irritation, fatigue, drowsiness, dizziness and/or lightheadedness, headache, uncoordination, nausea, vomiting, abdominal pain, chest pain, coughing, apathy, central nervous system depression, intoxication, anesthetic effect or narcosis, difficulty of breathing, allergic response, tremors, severe lung irritation or damage, pulmonary edema, pneumoconiosis, loss of consciousness, respiratory failure, death. Possible sensitization to respiratory tract.

Skin contact : Irritation of skin. Prolonged or repeated contact can cause dermatitis, defatting, severe skin irritation. Possible sensitization to skin.

Eye contact : Irritation of eyes. Prolonged or repeated contact can cause conjunctivitis, blurred vision, tearing of eyes, redness of eyes, severe eye irritation, corneal injury.

Ingestion : Ingestion may cause lung inflammation and damage due to aspiration of material into lungs, mouth and throat irritation, drowsiness, dizziness and/or lightheadedness, headache, uncoordination, nausea, vomiting, diarrhea, gastro-intestinal disturbances, abdominal pain, visual disturbances, apathy, central nervous system depression, intoxication, anesthetic effect or narcosis, burns of the mouth, throat, stomach, pulmonary edema, loss of consciousness, respiratory failure, death.

Medical conditions aggravated by exposure : Eye, skin, respiratory disorders, kidney disorders, liver disorders, nervous system disorders, respiratory disorders.

FIRST-AID MEASURES (ANSI Section 4)Inhalation : Remove to fresh air. Restore and support continued breathing. Get emergency medical

attention. Have trained person give oxygen if necessary. Get medical help for any breathing difficulty. Remove to fresh air if inhalation causes eye watering, headaches, dizziness, or other discomfort.

Skin contact : Wash thoroughly with soap and water. If any product remains, gently rub petroleum jelly, vegetable or mineral/baby oil onto skin. Repeated applications may be needed. Remove contaminated clothing. Wash contaminated clothing before re-use. Dispose of contaminated leather items, such as shoes and belts. If irritation occurs, consult a physician.

Eye contact : Flush immediately with large amounts of water, especially under lids for at least 15 minutes. If irritation or other effects persist, obtain medical treatment.

Ingestion : If swallowed, obtain medical treatment immediately.

FIRE-FIGHTING MEASURES (ANSI Section 5)Fire extinguishing media : Dry chemical or foam water fog. Carbon dioxide. Closed containers may

explode when exposed to extreme heat or fire. Vapors may ignite explosively at ambient temperatures. Vapors are heavier than air and may travel long distances to a source of ignition and flash back. Vapors can form explosive mixtures in air at elevated temperatures. Closed containers may burst if exposed to extreme heat or fire. Dust explosion hazard. May decompose under fire conditions emitting irritant and/or toxic gases.

Fire fighting procedures : Water may be used to cool and protect exposed containers. Firefighters should use full protective clothing, eye protection, and self-contained breathing apparatus. Self-contained breathing apparatus recommended.

Hazardous decomposition or combustion products : Carbon monoxide, carbon dioxide, oxides of nitrogen, oxides of sulfur, ammonia, hydrogen chloride, toxic gases, barium compounds. Cyanides.

ACCIDENTAL RELEASE MEASURES (ANSI Section 6)Steps to be taken in case material is released or spilled : Comply with all applicable health and

environmental regulations. Eliminate all sources of ignition. Ventilate area. Ventilate area with explosion-proof equipment. Spills may be collected with absorbent materials. Use non-sparking tools. Evacuate all unnecessary personnel. Place collected material in proper container. Complete personal protective equipment must be used during cleanup. Large spills - shut off leak if safe to do so. Dike and contain spill. Pump to storage or salvage vessels. Use absorbent to pick up excess residue. Keep salvageable material and rinse water out of sewers and water courses. Small spills - use absorbent to pick up residue and dispose of properly.

HANDLING AND STORAGE (ANSI Section 7)Handling and storage : Store below 80f. Store below 100f (38c). Keep away from heat, sparks and

open flame. Store in original container. Keep away from direct sunlight, heat and all sources of ignition. Keep container tightly closed in a well-ventilated area.

Other precautions : Use only with adequate ventilation. Do not take internally. Keep out of reach of children. Avoid contact with skin and eyes, and breathing of vapors. Wash hands thoroughly after handling, especially before eating or smoking. Keep containers tightly closed and upright when not in use. Empty containers may contain hazardous residues. Ground equipment when transferring to prevent accumulation of static charge.

EXPOSURE CONTROLS/PERSONAL PROTECTION (ANSI Section 8)Respiratory protection : Respiratory protection is required for use in isocyanate containing

environments. Consider type of application and environmental concentrations when selecting respiratory protection. Observe governmental regulations for respirator use. (29 CFR 1910.134(OSHA))(Canadian z94.4) The use of positive pressure supplied air respirator is mandatory when the airborne isocyanate concentrations are not known. Note: isocyanate based materials have been determined to cause allergic sensitization in humans. Avoid inhalation and dermal (skin) contact with the uncured material.

Ventilation : Provide dilution ventilation or local exhaust to prevent build-up of vapors. Use explosion-proof equipment. Use non-sparking equipment.

Personal protective equipment : Eye wash, safety shower, safety glasses or goggles. Impervious gloves, impervious clothing, face shield, apron, boots.

STABILITY AND REACTIVITY (ANSI Section 10)Under normal conditions : Stable see section 5 fire fighting measuresMaterials to avoid : Oxidizers, acids, reducing agents, bases, aldehydes, halogens, amines, alkalis,

water, peroxides, nitric acid, alcohols, combustible materials, caustics, mineral acids. Nitrates.Conditions to avoid : Sunlight, elevated temperatures, moisture, contact with oxidizing agent, storage

near acids, sparks, open flame, ignition sources.Hazardous polymerization : Will not occur

Form: 359D, Page 2 of 3, prepared 05/06/08

TOXICOLOGICAL INFORMATION (ANSI Section 11)Supplemental health information : Contains a chemical that is moderately toxic by ingestion. Contains a

chemical that is toxic by inhalation. Contains a chemical that may be absorbed through skin. Free diisocyanate may cause allergic reaction in susceptible persons. Notice - reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal. Contains iron oxide, repeated or prolonged exposure to iron oxide dust may cause siderosis, a benign pneumoconiosis. Other effects of overexposure may include toxicity to liver, kidney, central nervous system, blood.

Carcinogenicity : Contains formaldehyde, a potential cancer hazard. Rats exposed to formaldehyde via inhalation developed cancer of the nasal cavity. Evidence in humans is limited (nasal and nasopharyngeal cancer). Formaldehyde is listed as a carcinogen by OSHA, probable human carcinogen (group 2a) by IARC, and anticipated human carcinogen by NTP. Overexposure can cause eye, skin, and respiratory tract irritation, and skin and respiratory sensitization. In a lifetime inhalation study, exposure to 250 mg/m3 titanium dioxide resulted in the development of lung tumors in rats. These tumors occurred only at dust levels that overwhelmed the animals' lung clearance mechanisms and were different from common human lung tumors in both type and location. The relevance of these findings to humans is unknown but questionable. The international agency for research on cancer (IARC) has classified titanium dioxide as possibly carcinogenic to humans (group 2b) based on inadequate evidence of carcinogenicity in humans and sufficient evidence of carcinogenicity in experimental animals.

Reproductive effects : High exposures to xylene in some animal studies, often at maternally toxic levels, have affected embryo/fetal development. The significance of this finding to humans is not known.

Mutagenicity : No mutagenic effects are anticipatedTeratogenicity : No teratogenic effects are anticipated

ECOLOGICAL INFORMATION (ANSI Section 12)No ecological testing has been done by ICI paints on this product as a whole.

DISPOSAL CONSIDERATIONS (ANSI Section 13)Waste disposal : Dispose in accordance with all applicable regulations. Avoid discharge to natural waters.

REGULATORY INFORMATION (ANSI Section 15)As of the date of this MSDS, all of the components in this product are listed (or are otherwise exempt from

listing) on the TSCA inventory. This product has been classified in accordance with the hazard criteria of the CPR (controlled products regulations) and the MSDS contains all the information required by the CPR.

Physical Data (ANSI Sections 1, 9, and 14)Product

Code Description Wt. / Gal.VOC

gr. / ltr.% Volatileby Volume

FlashPoint

BoilingRange HMIS DOT, proper shipping name

359F65DGF devthane 359h (no organic haps) derrick green 9.02 291.43 34.96 80 f 208-595 *330 UN1263, paint, 3, PGIII379C0910 devthane 379 hs converter 9.40 112.85 13.00 135 f 293-293 *321 UN1866, resin solution, combustible liquid, PGIII

Ingredients Product Codes with % by Weight (ANSI Section 2)Chemical Name Common Name CAS. No. 359F65DGF 379C0910

4-heptanone, 2,6-dimethyl- diisobutyl ketone 108-83-8 1-5ethane, 1,1',1''-methylidenetris(oxy)-tris- ethyl orthoformate 122-51-0 1-5acetic acid, butyl ester butyl acetate 123-86-4 5-10 5-10c.i. pigment green 7 phthalo green pigment 1328-53-6 1-5benzene, dimethyl- xylene 1330-20-7 .1-1.0 .1-1.0titanium oxide titanium dioxide 13463-67-7 1-52-propenoic acid, 2-methyl-, 2-hydroxyethyl ester, polymer with ethenylbenzene, 2-ethylhexyl 2-propeno and methyl 2-methyl-2-propenoate

acrylic polymer 26916-05-2 40-50

hexane, 1,6-diisocyanato-, homopolymer aliphatic polyisocyanate 28182-81-2 90-95formaldehyde formaldehyde 50-00-0 LT .01c.i. pigment yellow 42 yellow iron oxide 51274-00-1 1-5acetic acid, 1,1-dimethylethyl ester tert-butyl acetate 540-88-5 1-5butanamide, 2-((2-methoxy-4-nitrophenyl)azo) -n-(2-methoxyphenyl)-3-oxo- pigment yellow 74 6358-31-2 1-5solvent naphtha (petroleum), light aromatic light aromatic solvent naphtha 64742-95-6 1-51-butanol n-butanol 71-36-3 1-5propanoic acid, 3-ethoxy-, ethyl ester ethyl 3-ethoxypropionate 763-69-9 5-10sulfuric acid, barium salt barium sulfate 7727-43-7 1-5castor oil castor oil, raw 8001-79-4 10-20hexane, 1,6-diisocyanato- hexamethylene diisocyanate 822-06-0 .1-1.0acetic acid, c6-8-branched alkyl esters oxo-heptyl acetate 90438-79-2 1-5benzene,1,2,4-trimethyl- pseudocumene 95-63-6 .1-1.0 1-5anti-settling agent anti-settling agent Sup. Conf. 1-5polyamide rheological additive Sup. Conf. 1-5


Chemical Hazard Data (ANSI Sections 2, 8, 11, and 15)ACGIH-TLV OSHA-PEL S.R.

Std. S2 S3 CCCommon Name CAS. No. 8-Hour TWA STEL C S 8-Hour TWA STEL C S H M N I Odiisobutyl ketone 108-83-8 25 ppm not est. not est. not est. 50 ppm not est. not est. not est. not est. n n n n n n n nethyl orthoformate 122-51-0 not est. not est. not est. not est. not est. not est. not est. not est. not est. n n n n n n n nbutyl acetate 123-86-4 150 ppm 200 ppm not est. not est. 150 ppm not est. not est. not est. not est. n n y n n n n nphthalo green pigment 1328-53-6 not est. not est. not est. not est. not est. not est. not est. not est. not est. n n n n n n n nxylene 1330-20-7 100 ppm 150 ppm not est. not est. 100 ppm not est. not est. not est. not est. n y y y n n n ntitanium dioxide 13463-67-7 10 mg/m3 not est. not est. not est. 10 mg/m3 not est. not est. not est. not est. n n n n n y y nacrylic polymer 26916-05-2 not est. not est. not est. not est. not est. not est. not est. not est. not est. n n n n n n n naliphatic polyisocyanate 28182-81-2 not est. not est. not est. not est. not est. not est. not est. not est. not est. n n n n n n n nformaldehyde 50-00-0 not est. not est. 0.3 ppm not est. 0.75 ppm 2 ppm not est. not est. not est. y y y y n y y yyellow iron oxide 51274-00-1 5 mg/m3 not est. not est. not est. 10 mg/m3 not est. not est. not est. not est. n n n n n n n ntert-butyl acetate 540-88-5 200 ppm not est. not est. not est. 200 ppm not est. not est. not est. not est. n n y n n n n npigment yellow 74 6358-31-2 not est. not est. not est. not est. not est. not est. not est. not est. not est. n n n n n n n nlight aromatic solvent naphtha 64742-95-6 not est. not est. not est. not est. 500x ppm not est. not est. not est. not est. n n n n n n n nn-butanol 71-36-3 20 ppm not est. not est. not est. 100 ppm not est. not est. not est. not est. n y y n n n n nethyl 3-ethoxypropionate 763-69-9 not est. not est. not est. not est. not est. not est. not est. not est. not est. n n n n n n n nbarium sulfate 7727-43-7 10 mg/m3 not est. not est. not est. 5 mg/m3 not est. not est. not est. not est. n n n n n n n ncastor oil, raw 8001-79-4 not est. not est. not est. not est. not est. not est. not est. not est. not est. n n n n n n n nhexamethylene diisocyanate 822-06-0 0.005 ppm not est. not est. not est. not est. not est. not est. not est. not est. n y y y n n n noxo-heptyl acetate 90438-79-2 not est. not est. not est. not est. not est. not est. not est. not est. not est. n n n n n n n npseudocumene 95-63-6 25 ppm not est. not est. not est. not est. not est. not est. not est. not est. n y n n n n n nanti-settling agent Sup. Conf. not est. not est. not est. not est. not est. not est. not est. not est. not est. n n n n n n n nrheological additive Sup. Conf. 10 mg/m3 not est. not est. not est. 5 mg/m3 not est. not est. not est. not est. n n n n n n n n

Footnotes: H=Hazardous Air Pollutant, M=Marine PollutantC=Ceiling - Concentration that S=Skin - Additional exposure, n/a=not applicable ppm=parts per million S2=Sara Section 302 EHS P=Pollutant, S=Severe Pollutantshould not be exceeded, over and above airborn exposure, not est=not established mg/m3=milligrams per cubic meter S3=Sara Section 313 Chemical Carcinogenicity Listed By:even instantaneously. may result from skin absorption. CC=CERCLA Chemical Sup Conf=Supplier Confidential S.R.Std.=Supplier Recommended Standard N=NTP, I=IARC, O=OSHA, y=yes, n=no



prepared 05/06/08D

EVRA

N 220 D

ERR

ICK

GR

EEN220D

ICI Paints N

orth Am

erica 15885 Sprague Road Strongsville, O

hio 44136 EMER

GEN

CY

TELEPHO

NE N

O. (800) 545-2643

HAZARDS IDENTIFICATION (ANSI Section 3)Primary route(s) of exposure : Inhalation, skin contact, eye contact, ingestion.Effects of overexposure : Inhalation : Irritation of respiratory tract. Prolonged inhalation may lead to mucous membrane

irritation, fatigue, drowsiness, dizziness and/or lightheadedness, headache, uncoordination, nausea, vomiting, diarrhea, abdominal pain, chest pain, coughing, apathy, central nervous system depression, intoxication, metallic taste, anesthetic effect or narcosis, difficulty of breathing, allergic response, fever and chills, dehydration, tremors, pulmonary edema, pneumoconiosis, loss of consciousness, respiratory failure, death. Possible sensitization to respiratory tract.

Skin contact : Irritation of skin. Prolonged or repeated contact can cause dermatitis, defatting, severe skin irritation, severe skin irritation or burns. Possible sensitization to skin.

Eye contact : Irritation of eyes. Prolonged or repeated contact can cause conjunctivitis, tearing of eyes, redness of eyes, severe eye irritation, severe eye irritation or burns, corneal injury.

Ingestion : Ingestion may cause lung inflammation and damage due to aspiration of material into lungs, mouth and throat irritation, mucous membrane irritation, drowsiness, dizziness and/or lightheadedness, headache, uncoordination, nausea, vomiting, diarrhea, gastro-intestinal disturbances, abdominal pain, visual disturbances, apathy, central nervous system depression, anesthetic effect or narcosis, difficulty of breathing, burns of the mouth, throat, stomach, pulmonary edema, convulsions, loss of consciousness, respiratory failure, death.

Medical conditions aggravated by exposure : Eye, skin, respiratory disorders, kidney disorders, liver disorders, allergies.


attention. Have trained person give oxygen if necessary. Get medical help for any breathing difficulty.





explode when exposed to extreme heat or fire. Vapors may ignite explosively at ambient temperatures. Vapors are heavier than air and may travel long distances to a source of ignition and flash back. Vapors can form explosive mixtures in air at elevated temperatures. Closed containers may burst if exposed to extreme heat or fire. Dust explosion hazard. May decompose under fire conditions emitting irritant and/or toxic gases.


Hazardous decomposition or combustion products : Carbon monoxide, carbon dioxide, oxides of nitrogen, acrid fumes, formaldehyde, oxides of sulfur, ammonia, hydrogen cyanide, hydrogen chloride, aldehydes, toxic gases, barium compounds, smoke and soot. Cyanides.


environmental regulations. Eliminate all sources of ignition. Ventilate area with explosion-proof equipment. Spills may be collected with absorbent materials. Use non-sparking tools. Evacuate all unnecessary personnel. Place collected material in proper container. Complete personal protective equipment must be used during cleanup. Large spills - shut off leak if safe to do so. Dike and contain spill. Pump to storage or salvage vessels. Use absorbent to pick up excess residue. Keep salvageable material and rinse water out of sewers and water courses. Small spills - use absorbent to pick up residue and dispose of properly.

HANDLING AND STORAGE (ANSI Section 7)Handling and storage : Store below 80f. Keep away from heat, sparks and open flame. Keep away

from direct sunlight, heat and all sources of ignition.Other precautions : Use only with adequate ventilation. Do not take internally. Keep out of reach of

children. Avoid contact with skin and eyes, and breathing of vapors. Wash hands thoroughly after handling, especially before eating or smoking. Keep containers tightly closed and upright when not in use. Avoid conditions which result in formation of inhalable particles such as spraying or abrading (sanding) painted surfaces. If such conditions cannot be avoided, use appropriate respiratory protection as directed under exposure controls/personal protection. Empty containers may contain hazardous residues. Ground equipment when transferring to prevent accumulation of static charge.

EXPOSURE CONTROLS/PERSONAL PROTECTION (ANSI Section 8)Respiratory protection : Control environmental concentrations below applicable exposure standards

when using this material. When respiratory protection is determined to be necessary, use a NIOSH/MSHA (Canadian z94.4) Approved elastomeric sealing- surface facepiece respirator outfitted with organic vapor cartridges and paint spray (dust/mist) prefilters. Determine the proper level of protection by conducting appropriate air monitoring. Consult 29CFR1910.134 For selection of respirators (Canadian z94.4).


Personal protective equipment : Eye wash, safety shower, safety glasses or goggles. Impervious gloves, impervious clothing, face shield, apron.

STABILITY AND REACTIVITY (ANSI Section 10)Under normal conditions : Stable see section 5 fire fighting measuresMaterials to avoid : Oxidizers, acids, reducing agents, bases, aldehydes, halogens, amines, nitric

acid, combustible materials, lewis acids, mineral acids.Conditions to avoid : Elevated temperatures, contact with oxidizing agent, storage near acids, sparks,

open flame, ignition sources.Hazardous polymerization : Will not occur

TOXICOLOGICAL INFORMATION (ANSI Section 11)Supplemental health information : Contains a chemical that is moderately toxic by ingestion.

Contains a chemical that may be absorbed through skin. Notice - reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal. Contains iron oxide, repeated or prolonged exposure to iron oxide dust may cause siderosis, a benign pneumoconiosis. Other effects of overexposure may include toxicity to liver, kidney, central nervous system, blood.


Carcinogenicity : Inhalation of non-asbestiform cosmetic grade talc for 2 years at 6 and 18 mg/m3 produced clear evidence of carcinogenicity in female rats (lung and adrenal tumors) and some evidence of carcinogenicity in male rats (adrenal tumors). No evidence of carcinogenicity was demonstrated in male and female mice exposed under the same conditions. Microscopic examination of the lungs of rats and mice exposed to talc revealed additional exposure related effects primarily associated with the inflammatory response. Contains formaldehyde, a potential cancer hazard. Rats exposed to formaldehyde via inhalation developed cancer of the nasal cavity. Evidence in humans is limited (nasal and nasopharyngeal cancer). Formaldehyde is listed as a carcinogen by OSHA, probable human carcinogen (group 2a) by IARC, and anticipated human carcinogen by NTP. Overexposure can cause eye, skin, and respiratory tract irritation, and skin and respiratory sensitization. Contains crystalline silica which is considered a hazard by inhalation. IARC has classified crystalline silica as carcinogenic to humans (group 1). Crystalline silica is also a known cause of silicosis, a noncancerous lung disease. The national toxicology program (NTP) has classified crystalline silica as a known human carcinogen. In a lifetime inhalation study, exposure to 250 mg/m3 titanium dioxide resulted in the development of lung tumors in rats. These tumors occurred only at dust levels that overwhelmed the animals' lung clearance mechanisms and were different from common human lung tumors in both type and location. The relevance of these findings to humans is unknown but questionable. The international agency for research on cancer (IARC) has classified titanium dioxide as possibly carcinogenic to humans (group 2b) based on inadequate evidence of carcinogenicity in humans and sufficient evidence of carcinogenicity in experimental animals.


Mutagenicity : No mutagenic effects are anticipatedTeratogenicity : No teratogenic effects are anticipated








FlashPoint


220B65DGF devran 220 heavy duty epoxy coating derrick green 10.06 343.38 41.86 80 f 244-244 *330 UN1263, paint, 3, PGIII220C0903H devran 220 heavy duty epoxy coating converter 12.99 425.04 49.53 80 f 243-355 *330 UN1263, paint, 3, PGIII

Ingredients Product Codes with % by Weight (ANSI Section 2)Chemical Name Common Name CAS. No. 220B65DGF 220C0903H

1,3,5-trimethylbenzene 1,3,5-trimethylbenzene 108-67-8 1-52-heptanone methyl amyl ketone 110-43-0 20-301,2,-ethanediamine, n,n'-bis(2-aminoethyl)- triethylenetetramine 112-24-3 .1-1.0antigorite antigorite 12135-86-3 5-10quaternary ammonium compounds, benzyl(hydrogenated tallow alkyl)dimethyl, stearates, salts with bentonite rheological additive 121888-68-4 1-5c.i. pigment green 7 phthalo green pigment 1328-53-6 1-5benzene, dimethyl- xylene 1330-20-7 .1-1.0titanium oxide titanium dioxide 13463-67-7 1-5tremolite, nonasbestiform tremolite 14567-73-8 10-20talc talc 14807-96-6 5-10quartz quartz 14808-60-7 .1-1.0anthophyllite, nonasbestiform anthophyllite 17068-78-9 1-5phenol, 4,4'-(1-methylethylidene)bis-, polymer with 2,2'-((1-methylethylidene)bis (4,1-phenyleneoxymethylene))bis(oxirane) epoxy resin 25036-25-3 40-50formaldehyde formaldehyde 50-00-0 .01-.1c.i. pigment yellow 42 yellow iron oxide 51274-00-1 1-5butanamide, 2-((2-methoxy-4-nitrophenyl)azo) -n-(2-methoxyphenyl)-3-oxo- pigment yellow 74 6358-31-2 1-5solvent naphtha (petroleum), light aromatic light aromatic solvent naphtha 64742-95-6 5-10urea, polymer with formaldehyde, butylated urea-formaldehyde resin 68002-19-7 1-5fatty acids, c18-unsatd., dimers, reaction products with polyethylenepolyamines polyamide resin 68410-23-1 10-201-butanol n-butanol 71-36-3 1-5 5-10sulfuric acid, barium salt barium sulfate 7727-43-7 10-20 20-30benzene,1,2,4-trimethyl- pseudocumene 95-63-6 .1-1.0 5-10



Std. S2 S3 CCCommon Name CAS. No. 8-Hour TWA STEL C S 8-Hour TWA STEL C S H M N I O1,3,5-trimethylbenzene 108-67-8 25 ppm 35 ppm not est. not est. not est. not est. not est. not est. not est. n n n n n n n nmethyl amyl ketone 110-43-0 50 ppm not est. not est. not est. 100 ppm not est. not est. not est. not est. n n n n n n n ntriethylenetetramine 112-24-3 not est. not est. not est. not est. not est. not est. not est. not est. not est. n n n n n n n nantigorite 12135-86-3 not est. not est. not est. not est. not est. not est. not est. not est. not est. n n n n n n n nrheological additive 121888-68-4 10 mg/m3 not est. not est. not est. 15 mg/m3 not est. not est. not est. not est. n n n n n n n nphthalo green pigment 1328-53-6 not est. not est. not est. not est. not est. not est. not est. not est. not est. n n n n n n n nxylene 1330-20-7 100 ppm 150 ppm not est. not est. 100 ppm not est. not est. not est. not est. n y y y n n n ntitanium dioxide 13463-67-7 10 mg/m3 not est. not est. not est. 10 mg/m3 not est. not est. not est. not est. n n n n n y y ntremolite 14567-73-8 not est. not est. not est. not est. not est. not est. not est. not est. not est. n n n n n n n ntalc 14807-96-6 2 mg/m3 not est. not est. not est. not est. not est. not est. not est. not est. n n n n n n n nquartz 14808-60-7 .025 mg/m3 not est. not est. not est. 0.1 mg/m3 not est. not est. not est. not est. n n n n n y y nanthophyllite 17068-78-9 not est. not est. not est. not est. not est. not est. not est. not est. not est. n n n n n n n nepoxy resin 25036-25-3 not est. not est. not est. not est. not est. not est. not est. not est. not est. n n n n n n n nformaldehyde 50-00-0 not est. not est. 0.3 ppm not est. 0.75 ppm 2 ppm not est. not est. not est. y y y y n y y yyellow iron oxide 51274-00-1 5 mg/m3 not est. not est. not est. 10 mg/m3 not est. not est. not est. not est. n n n n n n n npigment yellow 74 6358-31-2 not est. not est. not est. not est. not est. not est. not est. not est. not est. n n n n n n n nlight aromatic solvent naphtha 64742-95-6 not est. not est. not est. not est. 500x ppm not est. not est. not est. not est. n n n n n n n nurea-formaldehyde resin 68002-19-7 not est. not est. not est. not est. not est. not est. not est. not est. not est. n n n n n n n npolyamide resin 68410-23-1 not est. not est. not est. not est. not est. not est. not est. not est. not est. n n n n n n n nn-butanol 71-36-3 20 ppm not est. not est. not est. 100 ppm not est. not est. not est. not est. n y y n n n n nbarium sulfate 7727-43-7 10 mg/m3 not est. not est. not est. 5 mg/m3 not est. not est. not est. not est. n n n n n n n npseudocumene 95-63-6 25 ppm not est. not est. not est. not est. not est. not est. not est. not est. n y n n n n n n




prepared 08/02/04O

RG

AN

IC Z

INC

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PO

XY

PR

IME

R313K

ICI Paints N

orth Am

erica 925 Euclid A

venue Cleveland, O

hio 44115 EM

ER

GE

NC

Y T

EL

EPHO

NE N

O. (800) 545-2643

HAZARDS IDENTIFICATION (ANSI Section 3)Primary route(s) of exposure : Inhalation, skin contact, eye contact, ingestion.Effects of overexposure : Inhalation : Irritation of respiratory tract. Prolonged inhalation may lead to mucous membrane

irritation, fatigue, drowsiness, dizziness and/or lightheadedness, headache, uncoordination, nausea, vomiting, diarrhea, abdominal pain, chest pain, blurred vision, flu-like symptoms, coughing, sneezing, difficulty with speech, apathy, central nervous system depression, anesthetic effect or narcosis, difficulty of breathing, allergic response, fever and chills, tremors, abnormal blood pressure, severe lung irritation or damage, liver damage, kidney damage, pulmonary edema, pneumoconiosis, loss of consciousness, respiratory failure, asphyxiation, death. Possible sensitization to respiratory tract.

Skin contact : Irritation of skin. Prolonged or repeated contact can cause dermatitis, defatting, blistering, allergic response, severe skin irritation, severe skin irritation or burns. Possible sensitization to skin.

Eye contact : Irritation of eyes. Prolonged or repeated contact can cause conjunctivitis, blurred vision, tearing of eyes, redness of eyes, severe eye irritation, severe eye irritation or burns, corneal injury.

Ingestion : Ingestion may cause lung inflammation and damage due to aspiration of material into lungs, mouth and throat irritation, drowsiness, dizziness and/or lightheadedness, headache, uncoordination, nausea, vomiting, diarrhea, gastro-intestinal disturbances, abdominal pain, visual disturbances, apathy, central nervous system depression, anesthetic effect or narcosis, burns of the mouth, throat, stomach, liver damage, kidney damage, pulmonary edema, loss of consciousness, respiratory failure, death.

Medical conditions aggravated by exposure : Eye, skin, respiratory disorders, lung disorders, asthma-like conditions, respiratory disorders.


attention. Have trained person give oxygen if necessary. Get medical help for any breathing difficulty.





explode when exposed to extreme heat or fire. Vapors may ignite explosively at ambient temperatures. Vapors are heavier than air and may travel long distances to a source of ignition and flash back. Vapors can form explosive mixtures in air at elevated temperatures. Closed containers may burst if exposed to extreme heat or fire. May decompose under fire conditions emitting irritant and/or toxic gases.


Hazardous decomposition or combustion products : Carbon monoxide, carbon dioxide, oxides of nitrogen, oxides of sulfur, ammonia, aldehydes, toxic gases, barium compounds. Cyanides.


environmental regulations. Eliminate all sources of ignition. Ventilate area. Ventilate area with explosion-proof equipment. Spills may be collected with absorbent materials. Use non-sparking tools. Evacuate all unnecessary personnel. Place collected material in proper container. Complete personal protective equipment must be used during cleanup. Large spills - shut off leak if safe to do so. Dike and contain spill. Pump to storage or salvage vessels. Use absorbent to pick up excess residue. Keep salvageable material and rinse water out of sewers and water courses. Small spills - use absorbent to pick up residue and dispose of properly.

HANDLING AND STORAGE (ANSI Section 7)Handling and storage : Store below 80f. Store below 100f (38c). Keep away from heat, sparks and

open flame. Keep away from direct sunlight, heat and all sources of ignition.Other precautions : Use only with adequate ventilation. Do not take internally. Keep out of reach of

children. Avoid contact with skin and eyes, and breathing of vapors. Wash hands thoroughly after handling, especially before eating or smoking. Keep containers tightly closed and upright when not in use. Empty containers may contain hazardous residues. Ground equipment when transferring to prevent accumulation of static charge.

EXPOSURE CONTROLS/PERSONAL PROTECTION (ANSI Section 8)Respiratory protection : Control environmental concentrations below applicable exposure standards

when using this material. When respiratory protection is determined to be necessary, use a NIOSH/MSHA (Canadian z94.4) Approved elastomeric sealing- surface facepiece respirator outfitted with organic vapor cartridges and paint spray (dust/mist) prefilters. Determine the proper level of protection by conducting appropriate air monitoring. Consult 29CFR1910.134 For selection of respirators (Canadian z94.4).


Personal protective equipment : Eye wash, safety shower, safety glasses or goggles. Impervious gloves, impervious clothing, face shield, apron.

STABILITY AND REACTIVITY (ANSI Section 10)Under normal conditions : Stable see section 5 fire fighting measuresMaterials to avoid : Oxidizers, acids, reducing agents, bases, aldehydes, ketones, halogens, amines,

carbon tetrachloride (at elevated temperatures), aluminum, nitric acid, metal compounds, lewis acids, mineral acids.

Conditions to avoid : Elevated temperatures, moisture, contact with oxidizing agent, storage near acids, sparks, open flame, ignition sources.

Hazardous polymerization : Will not occur may polymerize in presence of aliphatic amines.

TOXICOLOGICAL INFORMATION (ANSI Section 11)Supplemental health information : Contains a chemical that is moderately toxic by ingestion.

Contains a chemical that may be absorbed through skin. Excessive inhalation of fumes may lead to metal fume fever characterized by a metallic taste in mouth, excessive thirst, coughing, weakness, fatigue, muscular pain, nausea, chills and fever. Notice - reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal. Other effects of overexposure may include toxicity to liver, kidney, central nervous system, blood.

Form: 313K, Page 2 of 2, prepared 08/02/04

Carcinogenicity : The international agency for research on cancer (IARC) has evaluated ethylbenzene and classified it as a possible human carcinogen (group 2b) based on sufficient evidence for carcinogenicity in experimental animals, but inadequate evidence for cancer in exposed humans. In a 2 year inhalation study conducted by the national toxicology program (NTP), ethylbenzene vapor at 750 ppm produced kidney and testicular tumors in rats and lung and liver tumors in mice. Genetic toxicity studies showed no genotoxic effects. The relevance of these results to humans is not known.


Mutagenicity : Triethylenetetramine has demonstrated weak mutagenic activity in standard in vitro tests, and has caused embryo- fetal toxicity and fetal malformations when fed to rats. Triethylenetetramine did not exhibit carcinogenic potential in life-time mouse skin painting studies.

Teratogenicity : No teratogenic effects are anticipated








FlashPoint


313B0250 do not use, use dc313b0250d instead 24.77 334.95 41.44 90 f 244-304 *231 paint, 3, UN1263, PGIII313C0910 catha coat 313 organic zinc-rich epoxy primer clear converter 7.54 338.66 41.11 110 f 243-304 *320 paint, combustible liquid, UN 1263, PGIII

Ingredients Product Codes with % by Weight (ANSI Section 2)Chemical Name Common Name CAS. No. 313B0250 313C0910

benzene, ethyl- ethylbenzene 100-41-4 .1-1.02-heptanone methyl amyl ketone 110-43-0 5-10 20-301,2,-ethanediamine, n,n'-bis(2-aminoethyl)- triethylenetetramine 112-24-3 1-5zinc oxide zinc oxide 1314-13-2 1-5benzene, dimethyl- xylene 1330-20-7 1-5oxirane,2,2'-(( (1-methylethylidene) bis (4,1-phenyleneoxymethylene) )) bis- diglycidyl ether of bisphenol a 1675-54-3 1-5phenol, 4,4'-(1-methylethylidene)bis-, polymer with 2,2'-((1-methylethylidene)bis (4,1-phenyleneoxymethylene))bis(oxirane) epoxy resin 25036-25-3 1-5fatty acids, c18-unsatd., dimers, reaction products with polyethylenepolyamines polyamide resin 68410-23-1 40-501-butanol n-butanol 71-36-3 10-20zinc zinc 7440-66-6 70-80sulfuric acid, barium salt barium sulfate 7727-43-7 1-5amine adduct amine adduct Sup. Conf. 10-20


Std. S2 S3 CCCommon Name CAS. No. 8-Hour TWA STEL C S 8-Hour TWA STEL C S H M N I Oethylbenzene 100-41-4 100 ppm 125 ppm not est. not est. 100 ppm not est. not est. not est. not est. n y y y n n y nmethyl amyl ketone 110-43-0 50 ppm not est. not est. not est. 100 ppm not est. not est. not est. not est. n n n n n n n ntriethylenetetramine 112-24-3 not est. not est. not est. not est. not est. not est. not est. not est. not est. n n n n n n n nzinc oxide 1314-13-2 2 mg/m3 10 mg/m3 not est. not est. 5 mg/m3 not est. not est. not est. not est. n y n n n n n nxylene 1330-20-7 100 ppm 150 ppm not est. not est. 100 ppm not est. not est. not est. not est. n y y y n n n ndiglycidyl ether of bisphenol a 1675-54-3 not est. not est. not est. not est. not est. not est. not est. not est. not est. n n n n n n n nepoxy resin 25036-25-3 not est. not est. not est. not est. not est. not est. not est. not est. not est. n n n n n n n npolyamide resin 68410-23-1 not est. not est. not est. not est. not est. not est. not est. not est. not est. n n n n n n n nn-butanol 71-36-3 20 ppm not est. not est. not est. 100 ppm not est. not est. not est. not est. n y y n n n n nzinc 7440-66-6 not est. not est. not est. not est. not est. not est. not est. not est. not est. n y y n n n n nbarium sulfate 7727-43-7 10 mg/m3 not est. not est. not est. 5 mg/m3 not est. not est. not est. not est. n n n n n n n namine adduct Sup. Conf. not est. not est. not est. not est. not est. not est. not est. not est. not est. n n n n n n n n


DIMETCOTE 302H GREEN 302F0250 RESINProduct name

Product and company identification:

1 .

DI302H-5APPG Industries, Inc.One PPG PlacePittsburgh, PA 15272(412) 434-4515 (U.S.)(514) 645-1320 (Canada)01-800-00-21-400 (Mexico)

SupplierCode

Emergency telephonenumber

:

:

:

Technical Phone Number : (412) 492-5200 (ALLISON PARK, PA) 8:00 a.m. - 5:00 p.m. EST

Material Safety Data Sheet

Date of issue 7 July 2010Version 11

Emergency overview

Hazards identification

Potential acute health effects

May be harmful if swallowed.

EyesSkin

Inhalation

Ingestion

See toxicological information (section 11)

WARNING!:

::

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:

Medical conditionsaggravated by over-exposure

Pre-existing skin disorders and disorders involving any other target organs mentioned inthis MSDS as being at risk may be aggravated by over-exposure to this product.

:

2 .

Over-exposure signs/symptomsRepeated exposure to high vapor concentrations may cause irritation of the respiratory system and permanent brain andnervous system damage. Inhalation of vapor/aerosol concentrations above the recommended exposure limits causesheadaches, drowsiness and nausea and may lead to unconsciousness or death. There is some evidence that repeatedexposure to organic solvent vapors in combination with constant loud noise can cause greater hearing loss than expectedfrom exposure to noise alone.

Keep away from flames, such as a pilot light, and any object that sparks, such as anelectric motor. Keep away from heat. Do not smoke. Do not breathe vapor or mist. Donot swallow. Do not get on skin or clothing. Avoid contact with eyes. Use only withadequate ventilation. Keep container tightly closed and sealed until ready for use. Washthoroughly after handling.

FLAMMABLE LIQUID AND VAPOR. HARMFUL IF INHALED. CAUSESRESPIRATORY TRACT IRRITATION. MAY CAUSE ALLERGIC SKIN REACTION.MAY BE HARMFUL IF SWALLOWED. SANDING AND GRINDING DUSTS MAY BEHARMFUL IF INHALED. MAY CAUSE EYE IRRITATION. PROLONGED ORREPEATED CONTACT MAY DRY SKIN AND CAUSE IRRITATION. CONTAINSMATERIAL THAT CAN CAUSE TARGET ORGAN DAMAGE.

Harmful if inhaled. Irritating to respiratory system. Can irritate eyes, nose, mouth andthroat.

Moderately irritating to eyes.May cause skin dryness and irritation. May cause an allergic skin reaction.

This Material Safety Data Sheet has been prepared in accordance with Canada's Workplace Hazardous MaterialsInformation System (WHMIS) and the OSHA Hazard Communication Standard (29 CFR 1910.1200).

Page: 1/8United States - Canada - Mexico

DIMETCOTE 302H GREEN 302F0250 RESINProduct name11Product code Date of issue VersionDI302H-5A 7 July 2010

Composition/information on ingredients3 .

There are no additional ingredients present which, within the current knowledge of the supplier and in theconcentrations applicable, are classified as hazardous to health or the environment and hence require reporting inthis section.

Zinc powder - zinc dust (stabilized) 7440-66-6 30 - 60Cement, portland, chemicals 65997-15-1 10 - 30heptan-2-one 110-43-0 7 - 13Phenol, 4,4'-(1-methylethylidene)bis-, polymer with 2,2'-[(1-methylethylidene)bis(4,1-phenyleneoxymethylene)]bis[oxirane]

25036-25-3 5 - 10

Phenol, 4-(1,1-dimethylethyl)-, polymer with 2-(chloromethyl)oxirane and 4,4'-(1-methylethylidene)bis[phenol] Average Molecular Weight


No action shall be taken involving any personal risk or without suitable training.Evacuate surrounding areas. Keep unnecessary and unprotected personnel fromentering. Do not touch or walk through spilled material. Shut off all ignition sources. Noflares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provideadequate ventilation. Wear appropriate respirator when ventilation is inadequate. Puton appropriate personal protective equipment (see section 8).

Stop leak if without risk. Move containers from spill area. Approach release fromupwind. Use spark-proof tools and explosion-proof equipment. Prevent entry intosewers, water courses, basements or confined areas. Wash spillages into an effluenttreatment plant or proceed as follows. Contain and collect spillage with non-combustible,absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place incontainer for disposal according to local regulations (see section 13). Dispose of via alicensed waste disposal contractor. Contaminated absorbent material may pose thesame hazard as the spilled product. Note: see section 1 for emergency contactinformation and section 13 for waste disposal.

Environmental precautions

Accidental release measures

: Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains andsewers. Inform the relevant authorities if the product has caused environmental pollution(sewers, waterways, soil or air). Water polluting material. May be harmful to theenvironment if released in large quantities.

Personal precautions :

Large spill :

6 .

Stop leak if without risk. Move containers from spill area. Use spark-proof tools andexplosion-proof equipment. Dilute with water and mop up if water-soluble or absorb withan inert dry material and place in an appropriate waste disposal container. Dispose ofvia a licensed waste disposal contractor.

Small spill :

Store in accordance with local regulations. Store in a segregated and approved area.Store in original container protected from direct sunlight in a dry, cool and well-ventilatedarea, away from incompatible materials (see section 10) and food and drink. Eliminateall ignition sources. Separate from oxidizing materials. Keep container tightly closedand sealed until ready for use. Containers that have been opened must be carefullyresealed and kept upright to prevent leakage. Do not store in unlabeled containers. Useappropriate containment to avoid environmental contamination.

Put on appropriate personal protective equipment (see section 8). Eating, drinking andsmoking should be prohibited in areas where this material is handled, stored andprocessed. Persons with a history of skin sensitization problems should not be employedin any process in which this product is used. Do not breathe vapor or mist. Do notswallow. Do not get on skin or clothing. Avoid contact with eyes. Avoid release to theenvironment. Use only with adequate ventilation. Wear appropriate respirator whenventilation is inadequate. Do not enter storage areas and confined spaces unlessadequately ventilated. Keep in the original container or an approved alternative madefrom a compatible material, kept tightly closed when not in use. Store and use awayfrom heat, sparks, open flame or any other ignition source. Use explosion-proofelectrical (ventilating, lighting and material handling) equipment. Use non-sparking tools.Take precautionary measures against electrostatic discharges. To avoid fire orexplosion, dissipate static electricity during transfer by grounding and bonding containersand equipment before transferring material. Empty containers retain product residue andcan be hazardous. Do not reuse container.

Handling and storageHandling

Storage

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Exposure controls/personal protection8 .

Cement, portland, chemicals TWA 10 mg/m 5 mg/m R15 mg/m TD

10 mg/m TD 10 mg/m Notestablished

STEL Notestablished

Notestablished

Notestablished

20 mg/m Notestablished

____________________________ ___________ ___________ ___________ ___________ ___________ ___________heptan-2-one TWA 50 ppm 100 ppm 25 ppm 50 ppm Not

established

Name Result ACGIH OSHA Ontario Mexico PPG



Exposure controls/personal protection8 .

Acceptable Maximum PeakA =ACGIH = American Conference of Governmental Industrial Hygienists.

C = Ceiling Limit

Potential skin absorptionSSR = Respiratory sensitization

= Skin sensitizationSS

TD = Total dust

Key to abbreviations

If workers are exposed to concentrations above the exposure limit, they must useappropriate, certified respirators. Use a properly fitted, air-purifying or air-fed respiratorcomplying with an approved standard if a risk assessment indicates this is necessary.Respirator selection must be based on known or anticipated exposure levels, thehazards of the product and the safe working limits of the selected respirator.

Safety glasses with side shields.

Personal protective equipment for the body should be selected based on the task beingperformed and the risks involved and should be approved by a specialist before handlingthis product.

Personal protectionEyes

Skin

Respiratory

Consult local authorities for acceptable exposure limits.

:

:

:butyl rubberGloves :

Engineering measures : Use only with adequate ventilation. Use process enclosures, local exhaust ventilation orother engineering controls to keep worker exposure to airborne contaminants below anyrecommended or statutory limits. The engineering controls also need to keep gas, vaporor dust concentrations below any lower explosive limits. Use explosion-proof ventilationequipment.

Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, beforeeating, smoking and using the lavatory and at the end of the working period. Appropriatetechniques should be used to remove potentially contaminated clothing. Washcontaminated clothing before reusing. Ensure that eyewash stations and safety showersare close to the workstation location.

Recommended monitoringprocedures

: If this product contains ingredients with exposure limits, personal, workplace atmosphereor biological monitoring may be required to determine the effectiveness of the ventilationor other control measures and/or the necessity to use respiratory protective equipment.

Environmental exposurecontrols

: Emissions from ventilation or work process equipment should be checked to ensure theycomply with the requirements of environmental protection legislation. In some cases,fume scrubbers, filters or engineering modifications to the process equipment will benecessary to reduce emissions to acceptable levels.

= Threshold Limit ValueTLVTWA = Time Weighted Average

Hands : Chemical-resistant, impervious gloves complying with an approved standard should beworn at all times when handling chemical products if a risk assessment indicates this isnecessary.

Fume=FIPEL = Internal Permissible Exposure Limit

= Occupational Safety and Health Administration.OSHAR = Respirable

OSHA 29CFR 1910.1200 Subpart Z - Toxic and Hazardous Substances=Z

STEL Notestablished

Notestablished

Notestablished

100 ppm Notestablished

____________________________ ___________ ___________ ___________ ___________ ___________ ___________Barium sulfate TWA 10 mg/m 5 mg/m R

15 mg/m TD10 mg/m TD 0.5 mg/m

(as Ba)Notestablished

____________________________ ___________ ___________ ___________ ___________ ___________ ___________n-Butyl acetate TWA 150 ppm 150 ppm 150 ppm 150 ppm Not

establishedSTEL 200 ppm Not

established200 ppm 200 ppm Not

established____________________________ ___________ ___________ ___________ ___________ ___________ ___________

STEL =

=

Short term Exposure limit values



>37.78C (>100F)

Liquid.

39% (v/v), 12.88% (w/w)

Not available.

Not available.2.48

Not available.0.4 kPa (3 mm Hg)

Not available.

Not available.Not available.

Boiling/condensation pointMelting/freezing point

46 (butyl acetate = 1)

Physical and chemical propertiesPhysical state

pH

Specific gravity

Vapor pressureVapor densityVolatilityOdor thresholdEvaporation rate

OdorColor

:

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Flash point : Closed cup: 37.22C (99F)Explosion limits : Lower: 1.2%

9 .

Octanol/water partitioncoefficient

: Not available.

% Solid. (w/w) : 87.12

Density ( lbs / gal ) : 20.7

The product may not be stable under certain conditions of storage or use.

Reactive or incompatible with the following materials:,water,acids,oxidizingmaterials,strong alkalis

Under normal conditions of storage and use, hazardous polymerization will not occur.

Under normal conditions of storage and use, hazardous decomposition products shouldnot be produced.

Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld,braze, solder, drill, grind or expose containers to heat or sources of ignition. Avoidincreased storage temperature. Pressure hazard

Stability and reactivityStabilityConditions to avoid

Materials to avoid

Hazardous decompositionproductsHazardous polymerization

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10 .

Toxicological information11 .

Conclusion/Summary : Not available.Chronic toxicity

Conclusion/Summary : Not available.

Carcinogenicity

Defatting irritant? : Prolonged or repeated contact can defat the skin and lead to irritation, cracking and/ordermatitis.

Target organs : Contains material which causes damage to the following organs: brain.Contains material which may cause damage to the following organs: peripheral nervoussystem, upper respiratory tract, skin, eyes, central nervous system (CNS), nose/sinuses,throat.

heptan-2-one

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