COVALENT COMPOUNDS - Tulpehocken Area School … 6 Student Notes PDF3.pdf1) HOW DO COVALENT...
Transcript of COVALENT COMPOUNDS - Tulpehocken Area School … 6 Student Notes PDF3.pdf1) HOW DO COVALENT...
Section 1: Covalent Bonds
l Covalent- electrons are shared. l Simplest covalent bonds are diatomic
molecules. l Always 2 atoms; atoms can be different or
the same (diatomic elements). l Ways to remember diatomic elements:
BrINClHOF, HON & the halogens, #7 l Ex: H2
l Each H atom shares its valence electron so each can have 2.
l Called a shared pair of electrons..
Molecular Orbitals l Where shared electrons are located.
l Region of high probability of finding the shared electrons- recall quantum model.
l Form when covalent bonds occur and atomic orbitals overlap.
Energy and Stability l Non-bonded atoms have high PE and low stability.
l Become more stable when bonded. l E is released when bonds form, PE decreases. l This determines the bond length.
l Ideal length is when the two bonded atoms are at their lowest PE.
Energy and Stability Cont.
l Covalent bonds are flexible. l Bond length is an average distance. l Bond length oscillates like a spring
between the two nuclei. l Bond energy – energy required to
break a bond. l Different from lattice energy!
l More E is needed to break a shorter bond. l Shorter bond length = stronger bond.
Re-visiting Electronegativity l How do we know if atoms will transfer
or share electrons in a bond? l Check electronegativity values! l If the difference is greater than 2.0 it is
considered ionic. l Ex: KCl Electronegativities: K= 0.8 and Cl= 3.2 Subtract: 3.2-0.8 = 2.4, so the bond is ionic.
Re-visiting Electronegativity l If the difference is less than 2.0 it is
considered covalent. l Ex: CO2 Electronegativities: C=2.6 and O=3.4 Subtract: 3.4 – 2.6 = 0.8, so the bond is covalent.
l You do not need to memorize electronegativity values! They will be given to you on tests and quizzes.
Re-visiting Electronegativity
l It is important to note that this cut-off value of 2.0 is somewhat arbitrary! Therefore, it is not 100% accurate.
l Properties of the compound must be investigated for better classification.
l Ex: magnesium chloride Electronegativities: Mg=1.3 and Cl=3.2 Subtract: 3.2 – 1.3 = 1.9 l It looks like it should be a covalent bond,
but properties indicate it is actually ionic.
Polar vs. Nonpolar Covalent
l If the electronegativity difference is less than 0.5 we will consider the bond to be nonpolar covalent. l Means the atoms are essentially sharing
the electrons equally. l If the difference is between 0.5 and 2.0,
we will consider it to be polar covalent. l Means one atom attracts the electrons
more towards itself; there is unequal sharing of electrons.
Practice Classifying Bonds A) Classify the following bonds as ionic, polar covalent, or nonpolar covalent: 1) Li – Cl 2) B – C 3) N – O 4) Mg – Br 5) C – F B) Since F has the highest electronegativity value, can F ever form a nonpolar covalent bond? Why or why not?
2.2 ionic 0.6 polar covalent 0.4 nonpolar covalent
1.7 ionic
1.4 polar covalent
Simple Polar Molecules l Ions have full charges (electrons are
transferred). l Polar molecules have partial charges
(unequally shared electrons). l Use Greek symbol delta δ (and +/-) to
indicate partial charges. l Dipole – molecule that contains both
positive and negative partial charges. l Ex: HCl
Simple Polar Molecules Continued l Use electronegativity values to determine
partial charges. l Atom with larger e-neg value = δ-
l Atom with lower e-neg value = δ+
l Ex: HCl Elecronegativities: H=2.2 and Cl=3.2 So: H is δ+ and Cl is δ- l In other words, the electrons are more likely
to be found at the Cl atom than the H because it has a larger electronegativity; this makes Cl more negative.
Different Properties for Different Bonds
l Besides electronegativity, you can predict bond type by the type of elements involved in the bond. l Metallic = metal atoms (K, Cu, etc.) l Ionic = 1 metal (typically) + 1 nonmetal l Covalent = 2 or more nonmetals
l Properties of these compounds are determined by bond type. l Recall ionic compound properties and
how they stem from the crystal lattice.
Covalent Properties l Some are soluble in water and some are
not. l Depends if the bonds are polar or not.
l Poor conductivity. l Covalent compounds can exist as a solid,
liquid, or gas. l Depends upon the polarity of bonds.
l Tend to have low melting and boiling points.
*Remember: covalent compounds are made of molecules, not ions!
Bond type Metallic Ionic Covalent
Model
Example Potassium Potassium chloride
Chlorine
Melting point 63 oC 770 oC -101 oC
Boiling point 760 oC 1500 oC (sublimes)
-34.6 oC
Properties • Soft, grey lustrous • Conductor as solid
• Crystalline white solid • Conductor when molten or in solution
• Green-yellow gas • Insulator
Section 2: Drawing and Naming Molecules
l Lewis structures (electron dot diagrams) use dots and lines to show valence electrons. l Atoms only use dots:
l Each dot represents a valence e-. l Molecules use both dots and dashes:
l Each line represents a bond. l Help to determine and show bonds that will
form in covalent compounds.
Lewis Structures- Atoms
l The 4 sides of the element symbol represent the s and three p orbitals. l s = 2 e- and p = 6 e- so total = 8 l No more than 8 dots per symbol
l Put one dot on each side of the atom before pairing:
l Draw the Lewis structure for the following: Al, Br, N, Ne
Lewis Structures- Molecules
l When drawing Lewis structures for molecules, give each atom an octet. l Except for H! l Looking at the Lewis structures for
each atom can help to determine how many bonds it will form.
l Ex: CH4
Needs 4 e-, so it will form 4 bonds.
Each H needs 1 e-, so they will form 1 bond.
Electron Pairs
• Shared pairs: e- are shared between two atoms, forming a bond. l 1 shared pair = single bond or l 2 shared pairs = double bond l 3 shared pairs = triple bond
• Unshared/lone pairs: e- are not shared between two atoms, and are not involved in a bond.
Steps for Drawing Lewis Structures 1) Find the total # of valence electrons for all atoms in the compound.
Ex: NH3 N: 5e- H: 1e- total: 5 + 1(3) = 8e- 2) Arrange atoms/determine ‘backbone’ of the compound.
l H and halogens tend to be on the end. l They don’t like to share more than 1 pair of e-.
l C is almost always in the center, if present. l Likes to form 4 bonds.
l Except for C, the atom with the lowest electronegativity will be the center. l H will NEVER be in the center! l Ex: NH3 N will be in the center:
3) Keep track of how many e- are used and how many remain.
l Each bond used to build the backbone uses 2 electrons. NH3 has 3 bonds, so 6 e- used. l 8 e- - 6 e- = 2 e- left.
4) Distribute remaining e- by giving each atom an octet.
l Give the most electronegative atoms e- first. l Ex: 2 e- left; N is the only one that needs an octet,
so it gets the remaining 2 e-. 5) Verify the structure! l Make sure all atoms have an octet and check that
all valence electrons have been used.
Steps for Drawing Lewis Structures
Polyatomic Ions 1) The bonds that hold together polyatomic ions are
covalent bonds. 2) When drawing the Lewis structure for a
polyatomic ion, you must take into account its charge when determining the total number of valence electrons you’re working with:
• negative ion: add electrons to the total • positive ion: subtract electrons from the total
3) Finally, put brackets around the ion and include its charge. Ex: Draw the Lewis structure for the sulfate ion.
Practice Problem #4: Multiple Bonds
1) It is possible to run out of remaining electrons to give to atoms as lone pairs.
l But they still need an octet! 2) If this happens, you take lone pairs from a neighboring atom and form another bond to the atom that needs an octet.
l The neighboring atom donates both electrons to be shared in this bond.
l This is how double and triple bonds are formed.
Ex: Draw the Lewis structure for O2.
Practice Problems #5-6: Multiple Bonds
l Draw the Lewis structure for CO2.
l Draw the Lewis structure for N2.
Resonance Structures
• 1) Some compounds can be represented with more than one Lewis structure.
l All Lewis structures are drawn. l A double-headed arrow is put between them
to indicate all possibilities. • 2) Compound is an average of the possible Lewis structures (resonance hybrid).
Naming Binary Covalent Compounds
1) Name the first element listed in the formula.
l The name does not change. 2) Second element always has ‘-ide’ ending. 3) Prefixes are used to indicate numbers of atoms of both elements.
l Exception: do not use ‘mono-’ for the first element listed if there is only one.
Naming Binary Covalent Compounds Take off the ‘a’ at the end of the prefix if the element begins with a vowel. Ex: pentoxide, not pentaoxide.
Ex #1: CCl4
Ex #2: P2O5
Ex #3: H2O
Ex #4: CO
carbon tetrachloride
diphosphorus pentoxide
dihydrogen monoxide
carbon monoxide
HOW CAN THE THREE DIMENSIONAL SHAPE OF A MOLECULE BE DETERMINED? WHY ARE THE SHAPES OF MOLECULES USEFUL?
Lesson Essential Question:
Section 3: Molecule Shapes
1) VSEPR theory: Valence Shell Electron Pair Repulsion l Predicts shape based on electron repulsion. l e- want to be as far apart as possible! l Look at the central atom to determine the shape. 2) Unshared pairs repel more than shared pairs. l All electrons repel each other, whether
they are bonded or lone pairs. 3) In addition to bond polarity, shape also plays a role in determining the properties of a substance.
Predicting Shapes l Count the number of shared and unshared regions
on the central atom in the Lewis structure. l Count double/triple bonds as 1 shared pair.
Total pairs Shared regions
Unshared pairs Shape name
4 4 0 Tetrahedral
4 3 1 Trigonal pyramidal
4 2 2 Bent
3 2 1 Bent
2 2 0 Linear
3 3 0 Trigonal planar
Angles l Bond angles also show repulsion of electrons
in molecules. l Tetrahedral angles = 109.5o l Base all other angles off of this.
l From here, we can predict >, < , or = 109.5o
l Depends upon shared vs. lone pairs. (Additional factors that affect bond angles: atom size, multiple bonds take up more space. We won’t worry about these.)
Angles Cont. l Trigonal Pyramidal: <109.5o
l Remember- tetrahedral was 109.5, now we’ve replaced a shared pair with a lone pair that repels more! So angles decrease!
l Linear: > 109.5o (180o is much bigger!)
l Trigonal Planar: >109.5o (120o is bigger!)
l Bent – depends on # of lone pairs l Bent with one lone pair is like taking trigonal
planar and replacing a shared pair with a lone pair, so angle is <120 but >109.5.
l Bent with two lone pairs is like taking tetrahedral and replacing two shared pairs with two lone pairs, so angles are much <109.5. This is most common!
Polarity l Tetrahedral, trigonal planar, and
linear molecules can be nonpolar. l Polar bonds can ‘cancel’ out other polar
bonds because of the ‘symmetrical’ shape.
l This happens if the bonds are all the same. l Ex: CH4 & CO2
l They can also be polar if the bonds are not all the same. l Bonds do not completely cancel out.
l Ex: CH3F
Polarity & Properties l Let’s relate polarity back to covalent
compound properties from section 1. l Melting/boiling points
l Lower than ionic compounds l Vary from covalent compound to covalent
compound. l The more polar the molecule, the higher
its melting & boiling point. Why??
l Solubility in water l Polar molecules are soluble in water. l Nonpolar molecules are not. Why??
Polarity & Properties Cont.
l Solid, liquid, or gas at room temp. l More polar molecules will be solid or liquid at
room temperature. Why??
l Key point: It all comes down to the presence of partial charges! l If a molecule is polar, partial charges will
attract and hold molecules together. l If a molecule is nonpolar, no partial
charges are present to hold them together.
Properties: Practice l Ethane (C2H6) and water (H2O) are
covalent compounds. Ethane’s boiling point is -128°C and water’s boiling point is 100°C. Why?
l Would you expect an ionic compound to have a higher or lower boiling point than water? Why?
l Which of the following substances would be a liquid at room temp. and which would be a gas: C2H6 and CH3OH.