8 Air Polution Ozone

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    Air PollutionBeijing,chinaJanuary2013

    Why we care:

    Smog, acid rain, health hazards, global climate change

    1. What is air pollution?2. Where does pollution come from?3.Air hazard events and pollution meteorology4.Air pollution and climate change5. The Ozone Hole

    Todays Lecture: Air Pollution

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    Pollution Meteorology

    Meteorological conditions can make thepollution issue better or worse

    The solution to pollution is dilution Meteorological conditions that inhibit the

    dispersion of air pollution will create apollution problem

    Air hazard events and pollution meteorology

    Topography

    At night, cold, dense surface air drainsdownhill into low-lying areas, making them

    susceptible to strong temperature

    inversions

    Hills and mountains can trap air Sea breezes can provide cold air masses

    Air hazard events and pollution meteorology

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    Inversions inhibit vertical convection, trapping pollutants close

    to the surface. Strong, persistent, inversions over urban areas

    lead to much greater concentrations of pollutants.

    Inversions

    5 C warmer

    Air hazard events and pollution meteorology

    Los Angeles smog

    29 January 2004.

    The top of the

    inversion layer is

    easily seen against

    hills

    a thick brown or

    slightly orange haze

    -inversion is belowthe top of the highest

    buildings.

    --The exhaust frommore than a million

    cars driven in the

    morning rush hour istrapped below this

    level.

    Air hazard events and pollution meteorology

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    Air hazard events and pollution meteorology

    Air hazard events and pollution meteorology

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    Jan14,2013

    Other Meteorological Factors

    Sunlight/clear skies increases production of

    photochemical smog

    Air hazard events and pollution meteorology

    Rain will scrub the atmosphere because

    many of the pollutants are condensation

    nuclei or dissolve easily in water

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    Air hazard events and pollution meteorology

    CloudSeeding

    Air hazard events and pollution meteorology

    Chinausedcloudseeding

    inBeijingjustbeforethe

    2008OlympicGamesin

    ordertocleartheairof

    polluon.

    CloudSeeding

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    InFebruary2009,Chinaalso

    blastediodidescksover

    Beijingtoarficiallyinduce

    snowfallaQerfourmonthsof

    drought,andblastediodide

    scksoverotherareasof

    northernChinatoincrease

    snowfall.Thesnowfallin

    Beijinglastedforapproximately

    threedaysandledtothe

    closureof12mainroads

    aroundBeijing

    CloudSeeding

    1. What is air pollution?2. Where does pollution come from?3.Air hazard events and pollution meteorology4.Air pollution and climate change5. The Ozone Hole

    Todays Lecture: Air Pollution

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    Air pollution and climate change

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    RadiaveBudgetofAerosols

    Air pollution and climate change

    Mainpoint:MostaerosolsCOOLthesurfacetemperature!

    Air pollution and climate change

    Anyrolein

    global

    warming?

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    Air pollution and climate change

    Anyrolein

    global

    warming?

    VanillicAcid

    Sourcesofblackcarbon

    (soot)?

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    Air pollution and climate change

    Anyrolein

    global

    warming?

    GlobalDimming

    Air pollution and climate change

    Conceptthathumanaerosolscooledtheclimate,andhelptooffsetglobalwarming.

    Thedecreaseofglobaldimmingagentspromoteswarming.

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    1. What is air pollution?2. Where does pollution come from?3.Air hazard events and pollution meteorology4.Air pollution and climate change5. The Ozone Hole

    Todays Lecture: Air Pollution

    Darkestblueareas

    representregionsof

    maximumozone

    depleon

    1979

    19821984 1986

    1988 1990

    19921994

    1997

    1999

    2004

    The Ozone Hole

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    What is the ozone hole?

    Media confuses it with global warming Over the poles (especially Antarctica),

    stratospheric ozone depleted over past 30years

    Hole presently size Antarctica Ozone (O3) contributes to the greenhouse

    effect

    And of course O3 creation at the ground levelis bad bad bad.

    The Ozone Hole

    OzoneintheAtmosphere

    The Ozone Hole

    90%in

    Stratosphere

    10%in

    Troposphere

    recall:

    goodup

    high,bad

    nearby

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    How is ozone formed?

    UVradiaonstrikestheO2moleculeandsplitsit,

    atomicoxygenassociatesitselfwithanotherO2

    moleculetomakeOzone(O3)

    O2+sunlight>O+O

    O+O2>O3

    The Ozone Hole

    The Ozone Hole

    Sunburn

    DNAdamage(cancer)

    NoDamage

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    Why do we like Ozone?

    Too much UV:

    Eye damage, cataracts,Skin cancers

    photoagingDamage to land species

    Damage to aquaticspecies (plankton)

    The Ozone Hole

    Short answer: it protects us fromUV radiation!

    What causes the depletion?

    Release of man-made chemicals- CFCs (Chlorofluorocarbons) - refrigerants,aerosol sprays, solvents and foam-blowing agents

    - halogen compounds (F, Cl, Br) - Fire fightersused bromine-containing halogens to put out fires

    - Nox

    The Ozone Hole

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    The Ozone Hole

    Sources that harm ozone layerThe Ozone Hole

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    One chlorine atom on average - destroys one thousand ozonemolecules before converted into form harmless to ozone

    The Ozone Hole

    The Ozone Hole

    Why over the poles?

    Isolatedair

    Chemical

    breakdownis

    favoredincold

    airandbypolar

    stratosphericclouds

    Ozonehole

    changesseasonally

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    Arctic ozone hole?

    2004

    Antarctic ozone hole?

    The Ozone Hole

    Why over the poles?

    2000

    What does this look like on population

    density map?

    The Ozone Hole

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    October Antarctic Ozone

    Ozoneisnolongerdecreasing(1ststepintherecoveryprocess)

    The Ozone Hole

    TheFuture?

    The Ozone Hole