7/22/2019 IEE/CEEM Seminar: Paul Blom and Transport and recombination in polymer:fullerene bulk heterojunction solar cells
1/98
Vrkdspbrt kdf Pnobi`hdkthbd hd
Sbeyinr1Gueenrndn _bekr Onees
Skue @ebi
Ikx Sekdol Hdsthtut gr Sbeyinr Gbrsomudj, Ikhdz
7/22/2019 IEE/CEEM Seminar: Paul Blom and Transport and recombination in polymer:fullerene bulk heterojunction solar cells
2/98
Butehdn
;. Omkrjn trkdspbrt hd Brjkdho _nihobdfuotbrs
-Mben Vrkdspbrt, Nenotrbd Vrkdspbrt
0. Smbtbourrndt Jndnrkthbd hd Brjkdho _bekr Onees
-_pkon Omkrjn, Pnobi`hdkthbd
?. Pnobi`hdkthbd hd brjkdho sbekr onees
-@hibenouekr Pnobi`hdkthbd, Vrkp-ksshstnfcPnobi`hdkthbd
6. Brhjhd bg tmn Pnobi`hdkthbd hd Brjkdho _bekr Onees
-OV nenotrbeuihdnsondon, hfnkehty gkotbr, Nxohtbd Fhggushbd
50
7/22/2019 IEE/CEEM Seminar: Paul Blom and Transport and recombination in polymer:fullerene bulk heterojunction solar cells
3/98
W`hks (W)
3.; ; ;3;3
-6
;3-?
;3-0
;3-;
;33
3.;?i 3.?i 3.: iA
(K/i0
)
A W
E8
=
0
?
KSE 7=, ??3= (;887)
Ourrndt-Wbetkjn omkrkotnrhstho bg k SSW Mben-Bdey Fnvhon
SSW
Ku HVB
Mben Ourrndt hs _pkon Omkrjn (@uel) Ehihtnf !!
Ws
oi0
:;3>
5?
7/22/2019 IEE/CEEM Seminar: Paul Blom and Transport and recombination in polymer:fullerene bulk heterojunction solar cells
4/98
56
_OEO1 SENF kots ks k Okpkohtbr
HVBKuSSW
W93
HVBKu SSW
W4
+ + ++++
++
HVB
KuSSW
+ + ++
+ +
++
W44
++
+
+
++
+
+
A9omkrjn vnebohtyOW W/E
Omkrjn fndshty kdf Nenotrho ghnef ~ W
7/22/2019 IEE/CEEM Seminar: Paul Blom and Transport and recombination in polymer:fullerene bulk heterojunction solar cells
5/98
;3;8
;303
;30;
;300
;30?
;306
;30>
;307
;3-;3
;3-8
;3-=
;3
-:
GNV
m,
GNV(i
0/Ws)
p (i-?)
ENF
BO;O;3-SSW
V908> L
Ib`hehty hs Fndshty Fnpndfndt !
Smys. Pnv. Entt. 8;, 0;773; (033?)
5>
7/22/2019 IEE/CEEM Seminar: Paul Blom and Transport and recombination in polymer:fullerene bulk heterojunction solar cells
6/98
3Vrkdspbrtenvne
Nquheh`rhui
envne
3
Ng
Ebw okrrhnr fndshty Mhjmnr okrrhnr fndshty
Ng
0
;ed
V
V
;ed
Nggnot bg Okrrhnr Fndshty257
7/22/2019 IEE/CEEM Seminar: Paul Blom and Transport and recombination in polymer:fullerene bulk heterojunction solar cells
7/98
; ;3 ;33;3-:
;3-7
;3->
;3-6
;3-?
;3-0
;3-;
;33
;3;
V908= L
V90:0 L
V90>0 L
V90?? L
W (W)
A(K
/i0)
Vmnbrnthoke ibfne gbr (p,V,N) fnvnebpnf
Smys. Pnv. Entt. 86, 03773; (033>)
5:
7/22/2019 IEE/CEEM Seminar: Paul Blom and Transport and recombination in polymer:fullerene bulk heterojunction solar cells
8/98
Nenotrbd Vrkdspbrt hd SSW
Ebw Nenotrbd Ourrndt, _tnnp A-W1 Vrkps 2
Ok OkMbens
Nenotrbds
3.?6 ui
3.00 ui 3.?: ui
3.? ui
KSE 7=, ??3= (;887)
5=
7/22/2019 IEE/CEEM Seminar: Paul Blom and Transport and recombination in polymer:fullerene bulk heterojunction solar cells
9/98
;3->
;3-6
;3-?
;3-0
;3->
;3-6
;3-?
;3-0
;3-;
;33
;3;
0 ? 6 > 7 : = 8;3 03 ?3;3
->
;3-6
;3-?
08> L
0:> L
0>> L
0?> L
0;> L
;8> LOurrndtFnds
hty(K/i)
(k)
(o)
DP_-SSW
E 9 ?03 di
INM-SSW
E 9 0:3 di
08> L0:? L
0>; L
0?3 L
0;; L
OurrndtF
ndshty(K/i)
BO;O
;3-SSW
E 9 ?33 di
(`)
083 L
0:> L
0>> L
0?> L
0;> LOurrndtFndshty(K/i)
W-W`h(W)
Jkusshkd E^IB kdf Jkusshkd Vrkps2
Vrkp-ehihtnf Nenotrbd ourrndts hdSSW fnrhvkthvns kesb fnsorh`nf
`y Jkusshkd trkp fhstrh`uthbd
Dt ~ 0;3;:
oi-?
t9 3.;3 nW
Nt
~ 3.7-3.: nW
Smys. Pnv. @ =?, ;=??3; (03;;)
58
7/22/2019 IEE/CEEM Seminar: Paul Blom and Transport and recombination in polymer:fullerene bulk heterojunction solar cells
10/98
_ebpn vs E^IB pbshthbd
0.7 0.= ?.3 ?.0 ?.6 ?.7 ?.= 6.3 6.0
3
;
0
?
6
>
7
:
=
_
ebpn
E^IB (nW)
DP_-SSW
BO;O;3-SSW
S?MV
G=@VSG;3V@V
SOSFV@V
SO@I
S(DFH0BF-V0)
SG;OWVS
SODNSW
Vrkp-grnn
Nxpekhdnf `y omkdjn bg Jkusshkd Vrkp Fnptm!!!
5;3
7/22/2019 IEE/CEEM Seminar: Paul Blom and Transport and recombination in polymer:fullerene bulk heterojunction solar cells
11/98
-?.=
-?.7
-?.6
-?.0
-?.3
-0.=
-0.7
-0.6
-0.0
Vrkp
DP_-SSWBO
;O
;3-SSW
G=@VSG;3V@V
SOSFV@V
S?MV
E^IB
Nenotrbd Vrkpphdj hd BENFs1
Bdn lhdf bg trkp rnspbdsh`en gbr trkpphdj hd kee BENFs!!!
Dt ~ 0-?;3;:oi-?
t9 3.;3 nW
Nenotrbd ourrndt okd `n prnfhotnf wmnd E^IB hs ldbwd
5;;
Dkturn Iktnrhkes ;; , p.==0 (03;0)
7/22/2019 IEE/CEEM Seminar: Paul Blom and Transport and recombination in polymer:fullerene bulk heterojunction solar cells
12/98
Brhjhd bg Vrkp2
Smbtb-bxhfkthbd2
Zktnr-pbeyinr obipenxns2
Myfrktnf-bxyjnd obipenxns B0(M0B)0
Vrkp-fnptm 3.;-3.0 nW
Sbtndthke Fnnp Vrkp
Sntnr Mb nt ke., Kfv. Ikt. 0;, 6:6: (0338)
O. Okip`nee, O. Phslb, A. E. @rfks, Jnbrjhk Vnom
5;0
B eh
7/22/2019 IEE/CEEM Seminar: Paul Blom and Transport and recombination in polymer:fullerene bulk heterojunction solar cells
13/98
Butehdn
;. Omkrjn trkdspbrt hd Brjkdho _nihobdfuotbrs
-Mben Vrkdspbrt, Nenotrbd Vrkdspbrt
0. Smbtbourrndt Jndnrkthbd hd Brjkdho _bekr Onees
-_pkon Omkrjn, Pnobi`hdkthbd
?. Pnobi`hdkthbd hd brjkdho sbekr onees
-@hibenouekr Pnobi`hdkthbd, Vrkp-ksshstnfcPnobi`hdkthbd
6. Brhjhd bg tmn Pnobi`hdkthbd hd Brjkdho _bekr Onees
-OV nenotrbeuihdnsondon, hfnkehty gkotbr, Nohtbd Fhggushbd
5;?
7/22/2019 IEE/CEEM Seminar: Paul Blom and Transport and recombination in polymer:fullerene bulk heterojunction solar cells
14/98
Jbbfikd kdf Pbsn1 A. Kppe. Smys. 60, ;8:;, 0=0?
Ndnrjy
x
E
NO
NW
@ngbrn ehjmt nxohtkthbd
ghnef1N9W/E
inkd okrrhnr frhgt endjtms1
wd9 dtdNwp9 ptpN
Kssuipthbds1
udhgbri jndnrkthbd bg n-mpkhrs tmrbujmbut tmn vbeuin bg tmn kothvn ekynr
dbd hdanothbd obdtkots gbr `btm nenotrbds kdf mbens
bdn fhindshbdke oksn
fhggushbd hjdbrnf
Smbtbourrndt hd k snihobdfuotbr15;6
7/22/2019 IEE/CEEM Seminar: Paul Blom and Transport and recombination in polymer:fullerene bulk heterojunction solar cells
15/98
@uhet-hd Wbetkjn1
W93
W9W`h
EhG SNFBV
W`h
EhGW`h
SNFBV
W93
Jbbfikd kdf Pbsn1
@MA _bekr Onee1
Wngg9W-W`h
5;>
7/22/2019 IEE/CEEM Seminar: Paul Blom and Transport and recombination in polymer:fullerene bulk heterojunction solar cells
16/98
ikhd okrrhnr frhgt endjtm wd9dtdN kdf wp9ptpN 55E ,N9W/E9obdstkdt.
+
Rmd
W9WBO-W`hks
E
A-W omkrkotnrhstho (Bmiho rnjhin)1
Kgtnr ehjmt nxohtkthbd
E
WnJA ppdd tt
A
W
W
_ikee kppehnf vbetkjn15;7
7/22/2019 IEE/CEEM Seminar: Paul Blom and Transport and recombination in polymer:fullerene bulk heterojunction solar cells
17/98
dtd 4 ptp , wd44 E, wp5 E
Pnobi`hdkthbd (t Ehihtnf rnjhin1 0/;0/;0/; < JWAWnJA dd t
A
W
W
W;/0+R
md
E;
W9WBO-`hks
Hdtnrinfhktn vbetkjn15;:
;=
7/22/2019 IEE/CEEM Seminar: Paul Blom and Transport and recombination in polymer:fullerene bulk heterojunction solar cells
18/98
skturkthbd rnjhin1
wd4 E, wp4 E, N9W/E9obdstkdtnquke nenotrbd kdf mben ourrndt.
A-W omkrkotnrhstho hs1
nJEA
+R
md
W9WBO-`hks
E
A
W
W
W;/0
Obdstkdt
Mhjm Wbetkjn Pnjhin15;=
_ Om Eh h f Sm;8
7/22/2019 IEE/CEEM Seminar: Paul Blom and Transport and recombination in polymer:fullerene bulk heterojunction solar cells
19/98
_OE Smbtbourrndt1
A
W
W;/0+R
md
E;
W9WBO-`hks
_pkon-Omkrjn Ehihtnf Smbtbourrndt1
0/;6/?0/;6/?
6/;
.0 nv
Oktmbfn
EhG/Ke
?.= nv
Ehjmt
Nenotrbd trkdspbrt
Mben trkdspbrt
Omkrjn trkdsgnr
OV-stktn
OV-stktn1Hg r39; di kdf r9?, tmnd
`hdfhdj ndnrjy hs 3.> nW !!
Smbtbourrndt hd k Sbeyinr1Gueenrndn _bekr Onee503
J. Xu, A. Jkb, A. O. Muiinend, G.
Zufe, K. A. Mnnjnr, _ohndon ;88>,
0:3, ;:=8.
K e JP I f e t @MA _ e O ee 5 0;
7/22/2019 IEE/CEEM Seminar: Paul Blom and Transport and recombination in polymer:fullerene bulk heterojunction solar cells
21/98
Kppey JP Ibfne tb @MA _bekr Onee1
MBIBSSW
MBIB O73
E^IB O73
0.8 nW
?.: nW
>.; nW
7.; nW
SNFBV1S__
I>.0 nW
E^IBSSW
EhG/Ke
I?.3 nW
E^IB9E^IBSO@IMBIB9MBIBSSW
Nggnothvn Infhui1
50;
Sm h SSW SO@I (; 6 %) e ee5 00
7/22/2019 IEE/CEEM Seminar: Paul Blom and Transport and recombination in polymer:fullerene bulk heterojunction solar cells
22/98
3.3; 3.; ; ;3
;
;3
Apm9AE-AF
\K/i0Y
W3-W \WY
frhgtfhggushbd
Smbtbourrndt hd SSW1SO@I (;16 wt.%) sbekr onees
fnvhkthbd kt mhjm (rnvnrsn) vbetkjns fun tb ghnef-fnpndfndon bg J2
3.3 3.0 3.6 3.7 3.= ;.3
-?3
-03
-;3
3
;3
03
WBO
W3
AF
AE
Apm9A
E-A
F
A\K/i
0 Y
W \WYA W
A9qJE
E9;03 di
V908> L
500
_ t th P h5 0?
7/22/2019 IEE/CEEM Seminar: Paul Blom and Transport and recombination in polymer:fullerene bulk heterojunction solar cells
23/98
_kturkthbd Pnjhin1
IFIB-SSW1SO@I
_kturktnf rnjhin1 pmbtbourrndt A9n J(N,V) Efun tb fhssbohkthbd bg
`budf nenotrbd-mben pkhrs
@rkud1 A. Omni. Smys. =3, ;8=6, 6;>:
3.; ; ;3;
;3
08> L0:3 L0>3 L0?3 L
0;3 L
Apm
\K/i
0Y
WBO
-W \WY
Smys. Pnv. Entt.,8?, 0;773; (0336)
73% Aso
Kt Asobdey 73% bg `budf
n-m pkhrs hs fhssbohktnf !!
nJIK]E
50?
_ e O ee F h I f e5 06
7/22/2019 IEE/CEEM Seminar: Paul Blom and Transport and recombination in polymer:fullerene bulk heterojunction solar cells
24/98
_bekr Onee Fnvhon Ibfne
Hdoeushbd bg (Ekdjnvhd) rnobi`hdkthbd kdf J(N,V) rnquhrns duinrhoke
ibfnehdj
;3-0
;3-;
;33
;3;
;33
;3;
fktk 08> L
fktk 0>3 L
q J(W) E 08> L
q J(W) E 0>3 L
shiuekthbd 08> Lshiuekthbd 0>3 L
Aehjmt-Afkrl\K/i
0
Y
Wbo-W \WY
Smys. Pnv. @ :0, 3=>03> (033>)
IFIB-SSW1SO@I
506
V t h @NM @I@ SSW/ SO@I `e f5 0>
7/22/2019 IEE/CEEM Seminar: Paul Blom and Transport and recombination in polymer:fullerene bulk heterojunction solar cells
25/98
?.6 ?.7 ?.= 6.3 6.0 6.6 6.7 6.=
;3-;;
;3-;3
;3-8
;3-=
;3-:
B
B
*
B
B
* ;
? rkd
B
B
*
B
B
* ;
? rkd
E;E
W;
J
E;E
W;
J\i
0/WsY
;333/V \L-;Y
Nenotrbds
Mbens
Kt V90;3 L gkotbr ;3?fhggnrndon hd n/m ib`hehthns
Vrkdspbrt hd k @NM-@I@ SSW/ SO@I `endf
;16 wt. %
50>
Sm h m @NM @I@ SSW/ SO@I `e f
7/22/2019 IEE/CEEM Seminar: Paul Blom and Transport and recombination in polymer:fullerene bulk heterojunction solar cells
26/98
3.3; 3.; ; ;3
;33
;3;
08> L
0:3 L
0>3 L0?3 L
0;3 LA pm9A E-AF
\K/i
0Y
W3-W \WY
Apm
W;/0
Ehjmt-hdtndshty (J) fnpndfndon 2
Smbtbourrndt hd tmn @NM-@I@ SSW/ SO@I `endf
B` th g _OE m t t5 0:
7/22/2019 IEE/CEEM Seminar: Paul Blom and Transport and recombination in polymer:fullerene bulk heterojunction solar cells
27/98
B`snrvkthbd bg _OE pmbtbourrndt
3.3; 3.; ; ;3
3.;
;
;3
A pm\K/i
0 Y
W3-W \WY
E90:> di
V90;3 L
Wskt
;3
;
;3
;3 ;33
;
0
?
6
Apm
C W3-W9;3 W
_9 3.:7
Apm
\K/
i0Y
_ 9 3.8>
Apm
C W3-W93.; W
_9 3.>; W
skt
\W
Y
Hdohfndt Ehjmt Sbwnr \iZ/oi0Y
Ehjmt-hdtndshty fnpndfndon1
=3 iZ/oi
0
7 iZ/oi0
Kt Asoebssns fun tb `hibenouekr rnobi`hdkthbd wnkl (6%)
Smys. Pnv. Entt.86, ;07730 (033>)
50:
Ebw @kdfjkp Sbeyinr SOSFV@V (Lbdkrlk) 50=
7/22/2019 IEE/CEEM Seminar: Paul Blom and Transport and recombination in polymer:fullerene bulk heterojunction solar cells
28/98
|0=
Ebw @kdfjkp Sbeyinr SOSFV@V (Lbdkrlk)
Wbo 9 3.7> W
Aso 9 83 K/i0(SO 7;@I)
9 ;;3 K/i0(SO:;
@I)
GG 6:%
SON 9 0.7: % (SO7;@I)
9 ?.;7 % (SO:;@I)
Ime`komnr nt ke, Kfv. Iktnr., ;=, 0==60==8 (0337)
Sbey \0,7-(6,6-`hs-(0-ntmyemnxye)-6M-
oyoebpndtk\0,;-`
7/22/2019 IEE/CEEM Seminar: Paul Blom and Transport and recombination in polymer:fullerene bulk heterojunction solar cells
29/98
SOSFV@V1SO@I _bekr Onees
-3.0 -3.; 3.3 3.; 3.0 3.? 3.6 3.> 3.7 3.:
-73
->3
-63
-?3
-03
-;3
3
;3
08>
0:3
0>3
0?3
0;3
AE\K/i
0Y
W \WY
Ebw Ghee Gkotbr (~63-6>%) obi`hdnf whtmsqukrn rbbt rnjhin hd pmbtbourrndt1
_pkon-Omkrjn Ehihtnf222
3.; ;
;3
;33
V \LY
08>
0:3
0>3
0?30;3
Apm
\K/i0Y
W3-W \WY
_hdjen Okrrhnr Fnvhons 5?3
7/22/2019 IEE/CEEM Seminar: Paul Blom and Transport and recombination in polymer:fullerene bulk heterojunction solar cells
30/98
|?3
_hdjen Okrrhnr Fnvhons
3.3 3.6 3.= ;.0 ;.7 0.3
;3
;33
;333
;3333
A\K/i
0Y
W-Wrns
-W`h\WY
n9:x;3
-=i
0/Ws
3.3 3.: ;.6
;
;3
;33
;333
A\K/i
0Y
W-W`h-W
rs
m9?x;3
-=i
0/Ws
E^IB
MBIB
E^IB
MBIB
Mben/Nenotrbd ib`hehty keibst `kekdonf1 _O Ehiht ^dehlney!!!
Sbeyinr1Gueenrndn @endf
Hdtndshty fnpndfndon bg Smbtbourrndt1 5?;
7/22/2019 IEE/CEEM Seminar: Paul Blom and Transport and recombination in polymer:fullerene bulk heterojunction solar cells
31/98
Hdtndshty fnpndfndon bg Smbtbourrndt1
3.; ; ;3
;3
;33
A
pm
\K/i
0Y
W3-W \WY
Apm W;/0
Apm J
Wskt9 obdstkdt
Wskt
Ghdjnrprhdt bg rnobi`hdkthbd ehihtnf ourrndt!!!
Kfv. Gudot. Iktnr. 0338, ;8, ;;37;;;;
_qukrn Pbbt Fnpndfndon< vs so ehihtnf 5?0
7/22/2019 IEE/CEEM Seminar: Paul Blom and Transport and recombination in polymer:fullerene bulk heterojunction solar cells
32/98
|?0
_qukrn Pbbt Fnpndfndon< vs so ehihtnf
Vwb fhggnrndt brhjhds gbr k squkrn rbbt fnpndfndon bg Apm
_pkon Omkrjn Ehihtnf1 n 44 m
WqJA mrpm
0>.3
3
:>.3
=
8)(
Apm W;/0
Apm J?/6
WsktJ;/0
W. F. Ihmkhentomh nt ke.,Smys. Pnv. Entt. 86, ;07730 (033>)
K. I. Jbbfikd kdf K. Pbsn, A. Kppe. Smys. 60, 0=0? (;8:;)
-ehihtnf1 wd,p9 tN5E
7/22/2019 IEE/CEEM Seminar: Paul Blom and Transport and recombination in polymer:fullerene bulk heterojunction solar cells
33/98
Butehdn
;. Omkrjn trkdspbrt hd Brjkdho _nihobdfuotbrs
-Mben Vrkdspbrt, Nenotrbd Vrkdspbrt
0. Smbtbourrndt Jndnrkthbd hd Brjkdho _bekr Onees
-_pkon Omkrjn, Pnobi`hdkthbd
?. Pnobi`hdkthbd hd brjkdho sbekr onees
-@hibenouekr Pnobi`hdkthbd, Vrkp-ksshstnfcPnobi`hdkthbd
6. Brhjhd bg tmn Pnobi`hdkthbd hd Brjkdho _bekr Onees
-OV nenotrbeuihdnsondon, hfnkehty gkotbr
5?6@hibenouekr Ekdjnvhd rnobi`hdkthbd
7/22/2019 IEE/CEEM Seminar: Paul Blom and Transport and recombination in polymer:fullerene bulk heterojunction solar cells
34/98
Ehihtnf `y Fhggushbd bg Nenotrbds kdf Mbens tbwkrfs nkom btmnr
Orhthoke Obuebi` Pkfhus1 hdfhdj ndnrjy mben-nenotrbd 9 lV
q0/6lV (03 di) 44 inkd grnn pktm hd SSW (;-? di)
03di
;-? di
@hibenouekr Ekdjnvhd rnobi`hdkthbd
^. Ke`rnomt kdf M. @ssenr, Smys. _tktus _behfh @ ;8;, 6>> (;88>)
S. Ekdjnvhd, Kdd. Omni. Smys. 0=, 0=8 (;83?)
Mbw tb omkrkotnrhzn rnobi`hdkthbd25?>
7/22/2019 IEE/CEEM Seminar: Paul Blom and Transport and recombination in polymer:fullerene bulk heterojunction solar cells
35/98
_tufy Pnobi`hdkthbd kt Wbo !!
Inksurn Wbo~ Ehjmt Hdtndshty!!
_bekr onee whtm `hibenouekr rnobi`hdkthbd1
SJ
DS
q
lV
q
N
W
ojkp
bo
0
;ed
KSE =7, ;0?>38 (033>)
N. K. _omhgg, _be. Ndj. Iktnr. _be. Onees 033?, :=, >7:.
Mbw tb omkrkotnrhzn rnobi`hdkthbd2
Ehjmt hdtndshty fnpndfndon bg W 5?7
7/22/2019 IEE/CEEM Seminar: Paul Blom and Transport and recombination in polymer:fullerene bulk heterojunction solar cells
36/98
Ehjmt hdtndshty fnpndfndon bg Wbo
Ehdnkr fnpndfndon bg Wbobd ed(H) whtm sebpn lV/q, d9; !
; 0 ? 6 >
3.7>
3.:3
3.:>
3.=3
3.=>
3.83
Wbo
\WY
Ed (hdtndshty) \k.u.Y
08> L
0>3 L
0;3 L
KSE =7, ;0?>38 (033>)
IFIB-SSW1SO@I
Bdey hibenouekr Pnobi`hdkthbd!!!!!
Kee pbeyinr sbekr onees1 Nenotrbd trkps
5?:
7/22/2019 IEE/CEEM Seminar: Paul Blom and Transport and recombination in polymer:fullerene bulk heterojunction solar cells
37/98
Kee-pbeyinr sbekr onees1 Nenotrbd trkps
Pnobi`hdkthbd
;. Ekdjnvhd
0. _mboleny-Pnkf-Mkee
-
+
-
+
- - -
+ + +
-
--
-;0
Skrkintnrs1
Dt, Vt, Od, Op
;;;; / ppOddOdppdDOOP pdtpd_PM
)( 0
hEkdjnvhd ddpP )(
3
pd
r
q
W ehjmt hdtndshty fnpndfndon5?=
7/22/2019 IEE/CEEM Seminar: Paul Blom and Transport and recombination in polymer:fullerene bulk heterojunction solar cells
38/98
Wboehjmt hdtndshty fnpndfndon
;3 ;33 ;333
;.0>
;.?3
;.?>
;.63
;.6>
;.>3
Ehjmt hdtndshty (Z/i0)
Wbo
(W)
Bdey Ekdjnvhd rnobi`hdkthbd hdoeufnf
_\lV/qY9;
Kt Wbobdey ebssns vhk Pnobi`hdkthbd!!!!!
IFIB-SSW1SODNSW
Kee-pbeyinr1 _PM rnobi`hdkthbd nggnots bd Wbo5?8
7/22/2019 IEE/CEEM Seminar: Paul Blom and Transport and recombination in polymer:fullerene bulk heterojunction solar cells
39/98
Kee-pbeyinr1 _PM rnobi`hdkthbd nggnots bd Wbo
;3 ;33 ;333
;.0>
;.?3
;.?>
;.63
;.6>
;.>3
Ehjmt hdtndshty (Z/i0)
W
bo(W) Od,p9 ;.6;3
-;=i?s-;
>.3;3-;:
i?
s-;
>.3;3-03i?s-;
Smbtbourrndt bg IFIB-SSW1SODNSW563
7/22/2019 IEE/CEEM Seminar: Paul Blom and Transport and recombination in polymer:fullerene bulk heterojunction solar cells
40/98
Smbtbourrndt bg IFIB-SSW1SODNSW
-;3 -= -7 -6 -0 3 0->3
-63
-?3
-03
-;3
3
;3
03
Wbetkjn (W)
A(K
/i0)
AF
AE
Jikx9 8.6 ;30: i-?s-;
Lg9 7.: ;30s -;
k 9 3.70 di
5r4 9 0.7
Dt9 8.7 ;300
i-?
Vt9 0>33 L
Od,p9 ;.= ;3-;=i ?s-;
@btm Ekdjnvhd kdf _PM rnobi`hdkthbd hdoeufnf
Kfv. Gudot. Ikt. ;:, 0;7: (033:)
Zmkt fbns ht inkd2
Inksurn SENF ks k sbekr onee1 56;
7/22/2019 IEE/CEEM Seminar: Paul Blom and Transport and recombination in polymer:fullerene bulk heterojunction solar cells
41/98
Inksurn SENF ks k sbekr onee1
INM-SSWOd9Op9;;3
-;= i?/s
lV/q
I.I. Ikdfbo nt ke. Kpp. Smys. Entt. 8;, 07?>3> (033:)
I.I. Ikdfbo nt ke. Kfv. Gudot. Iktnr. ;:, 0;7:-0;:? (033:)
Brhjhd bg _PM Okpturn Obngghohndt1560
7/22/2019 IEE/CEEM Seminar: Paul Blom and Transport and recombination in polymer:fullerene bulk heterojunction solar cells
42/98
Brhjhd bg _PM Okpturn Obngghohndt1
?.0 ?.6 ?.7 ?.= 6.3 6.0 6.6 6.7 6.=
;3-0;
;3-03
;3-;8
;3-;=
p
q
O 9 sbekr onee
O 9 - mben-bdey fnvhon
OkpturnObngghohndts
(i?/s)
V-;(;3
-?L)
pDq
pDOl tptp_PM
Dt9nenotrbd trkp
Smys. Pnv. Entt. ;3:, 0>7=3> (03;;)
Brhjhd bg _PM Okpturn Obngghohndt156?
7/22/2019 IEE/CEEM Seminar: Paul Blom and Transport and recombination in polymer:fullerene bulk heterojunction solar cells
43/98
Brhjhd bg _PM Okpturn Obngghohndt1
03di
;-? di
pDlr t_ P M
)3( p_ P Mq
l
Vrkpphdj
Hfni ks Ekdjnvhd whtm hiib`hen nenotrbd!
566
Fhggushbd Ourrndt W5W`h
7/22/2019 IEE/CEEM Seminar: Paul Blom and Transport and recombination in polymer:fullerene bulk heterojunction solar cells
44/98
W93
Ok HVB
W`h
W9W`h
OkW`h
HVB
W4W`h
Ok
W
HVB
Fhggushbd Ourrndt W W`h
Frhgt Fhggushbd
FrhgtFhggushbd Fhggushbd
fx
fpnFNnpA
)/nxp(~ dlVqWA
v9N
BENF Ourrndt-vbetkjn omkrkotnrhsthos156>
7/22/2019 IEE/CEEM Seminar: Paul Blom and Transport and recombination in polymer:fullerene bulk heterojunction solar cells
45/98
BENF Ourrndt vbetkjn omkrkotnrhsthos1
Vmrnn rnjhins1
;. Enklkjn ourrndt
0. Fhggushbd rnjhin
?. Frhgt rnjhin
;.3 ;.> 0.3 0.> ?.3 ?.> 6.3 6.>;3
-7
;3->
;3-6
;3-?
;3-0
;3-;
;33
;3;
;3
0
;3?
A\K/i0Y
W \WY
;.
0.
?.
W`h
;nxp3
lV
qWAA
?
0
=
8
E
WA
enklkjnPWH
Hfnkehty Gkotbr
Brhjhd bg Hfnkehty Gkotbr2 567
7/22/2019 IEE/CEEM Seminar: Paul Blom and Transport and recombination in polymer:fullerene bulk heterojunction solar cells
46/98
Brhjhd bg Hfnkehty Gkotbr2
Hfnkehty gkotbr nqukes 0 hd tmn oksn bg trkp-ksshstnf
rnobi`hdkthbd hd k oeksshoke p-daudothbd
;0
nxp3lV
qWAA
O. V. _km nt ke., Srbo. HPN 6>, ;00= (;8>:)
_upnr Xneebw SSW ENF56:
7/22/2019 IEE/CEEM Seminar: Paul Blom and Transport and recombination in polymer:fullerene bulk heterojunction solar cells
47/98
_upnr Xneebw SSW ENF
Vmn hfnkehty gkotbr gbr k _upnr
Xneebw ENF wks fntnrihdnftb mkvn k vkeun bg 0 kt rbbi
tnipnrkturn.
Vmhs obrrnspbdfs tb _PM
rnobi`hdkthbd grbi trkpphdj
shtns1
;
0nxp3
lV
qWAA
;
ed
W
A
q
lV
Zmhtn BENFs1 Nihsshvn _PM rnobi`hdkthbd256=
7/22/2019 IEE/CEEM Seminar: Paul Blom and Transport and recombination in polymer:fullerene bulk heterojunction solar cells
48/98
Zmhtn BENFs1 Nihsshvn _PM rnobi`hdkthbd2
Vrkp-ksshstnf rnobi`hdkthbd hd obdvndthbdke pbeyinrs
kppnkrs tb `n dbd-rkfhkthvn.
Hd k wmhtn nihtthdj pbeyinr, rnf fyns hd tmn `eun `kol`bdn
gudothbd ks nihsshvn trkps.
MBIB
E^IB
Ekdjnvhd & _PM rnobi`hdkthbd!568
7/22/2019 IEE/CEEM Seminar: Paul Blom and Transport and recombination in polymer:fullerene bulk heterojunction solar cells
49/98
Ekdjnvhd & _PM rnobi`hdkthbd!
-3.0 -3.; 3.3 3.;
;
0
?
6Ourrndt
Ehjmt>>3 di Ebdjpkss Ghetnr
Ehjmt
@eun Fhomrbho Ghetnr
(lV/q
edA/W)-;
W-W`h\WY
0.3 0.> ?.3 ?.>;3
-;?
;3-;0
;3-;;
;3-;3
;3-8
;3-=
;3-:
;3-7
633 >33 733 :333
03
63
73
=3
;33
N
EHdtndshty\k.u.Y
Zkvnendjtm \diY
>>3 di Ebdjpkss Ghetnr
@eun Fhomrbho Ghetnr
Euihdkdon\k.u.Y
W \WY
Euihdkdon bg rnf fyns gbeebws _PM rnobi`hdkthbd,
wmnrnks tmn `eun ehjmt gbeebws Ekdjnvhd rnobi`hdkthbd.
Butehdn 5>3
7/22/2019 IEE/CEEM Seminar: Paul Blom and Transport and recombination in polymer:fullerene bulk heterojunction solar cells
50/98
Butehdn
;. Omkrjn trkdspbrt hd Brjkdho _nihobdfuotbrs
-Mben Vrkdspbrt, Nenotrbd Vrkdspbrt
0. Smbtbourrndt Jndnrkthbd hd Brjkdho _bekr Onees
-_pkon Omkrjn, Pnobi`hdkthbd
?. Pnobi`hdkthbd hd brjkdho sbekr onees
-@hibenouekr Pnobi`hdkthbd, Vrkp-ksshstnf Pnobi`hdkthbd
6. Brhjhd bg tmn Pnobi`hdkthbd hd Brjkdho _bekr Onees
-OV nenotrbeuihdnsondon, hfnkehty gkotbr
Omkrjn trkdspbrt hd @AM _bekr Onee5>;
7/22/2019 IEE/CEEM Seminar: Paul Blom and Transport and recombination in polymer:fullerene bulk heterojunction solar cells
51/98
j p
3.; ;;3
3
;3;
;30
;3?
;36
V 9 086 L
;:3 di83 di
A\K/i
0 Y
W-WPs
-W`h\WY
?
0
3
=
8
E
WA
nr
n0.3x;3-:i0/Ws
Kfv. Gudot. Iktnr. 033?, ;?,
Nenotrbd trkdspbrt hd SO@I kdf Mben trkdspbrt hd FbdbrSbeyinrs krn trkp-grnn1 Db _PM rnobi`hdkthbdnxpnotnf
Btmnr Sbeyinr1gueenrndn sbekr onees1 5>0
7/22/2019 IEE/CEEM Seminar: Paul Blom and Transport and recombination in polymer:fullerene bulk heterojunction solar cells
52/98
_ebpn9lV/q1 Bdey @hibenouekr Pnobi`hdkthbd
OV stktn nenotrbeuihdnsondon hd BSW 5>?
7/22/2019 IEE/CEEM Seminar: Paul Blom and Transport and recombination in polymer:fullerene bulk heterojunction solar cells
53/98
Znkl nenotrbeuihdnsondon grbi tmn omkrjn-trkdsgnr stktn
hs b`snrvnf hd brjkdho sbekr onees
Oktmbfn
Kdbfn
Koonptbr
Fbdbr
NE Hfnkehty gkotbr2 5>6
7/22/2019 IEE/CEEM Seminar: Paul Blom and Transport and recombination in polymer:fullerene bulk heterojunction solar cells
54/98
y
Hfnkehty gkotbr bg ; hs
inksurnf gbr tmn OV
nenotrbeuihdnsondon
Nihsshbd brhjhdktns grbi k
grnn-okrrhnr `hibenouekr
rnobi`hdkthbd prbonss!
Wbovs Ehjmt hdtndshty5>>
7/22/2019 IEE/CEEM Seminar: Paul Blom and Transport and recombination in polymer:fullerene bulk heterojunction solar cells
55/98
bo
K obdtrh`uthbd bg trkp-ksshstnf rnobi`hdkthbd hs b`snrvnf gbr
S?MV1SO@I
Pnobi`hdkthbd hs `hibenouekr gbr btmnr sbekr onees
Dbdrkfhkthvn _PM rnobi`hdkthbd2 5>7
7/22/2019 IEE/CEEM Seminar: Paul Blom and Transport and recombination in polymer:fullerene bulk heterojunction solar cells
56/98
Okd `n nxpbsnf `y ebblhdj kt tmn vbetkjn fnpndfndon bg
tmn NE qukdtui ngghohndoy
S?MV1SO@I
Obipnththbd_PM kdf
@hibenouekr!
S?MV1SO@I sbekr onees5>:
7/22/2019 IEE/CEEM Seminar: Paul Blom and Transport and recombination in polymer:fullerene bulk heterojunction solar cells
57/98
St5 0;3;>oi-? 2 _PM sikee
Mben trkps hd S?MV2
S?MV1SO@I sbekr onees5>=
7/22/2019 IEE/CEEM Seminar: Paul Blom and Transport and recombination in polymer:fullerene bulk heterojunction solar cells
58/98
Hd S?MV1SO@I sbekr onees tmn Ekdjnvhd rnobi`hdkthbd
hs strbdjey rnfuonf ~;3? (ONEHW)
Shvrhlks, Bstnr`kolk, Auslk nt ke., Smys. Pnv. Entt. 86, ;:7=37 (033>)
Vwb fhindshbdke Ekdjnvhd rnobi`hdkthbd hd tmn
ekineekr struoturn bg PP-S?MV
Auslk, Bstnr`kolk nt ke., Kppe. Smys. Entt. 8>, 3;??3? (0338)
S?MV1SO@I sbekr onees5>8
7/22/2019 IEE/CEEM Seminar: Paul Blom and Transport and recombination in polymer:fullerene bulk heterojunction solar cells
59/98
;30 ;3?
3.>3
3.>0
3.>6
3.>7
3.>=
3.73
Pnfuonf Ekdjnvhd + _PM
W
bo
\WY
Ehjmt Hdtndshty \Z/i0Y
Ekdjnvhd + _PM
lV/q
Kfvkdonf Ndnrjy Iktnrhkes, koonptnf
Nxohtbd Vrkdspbrt2
7/22/2019 IEE/CEEM Seminar: Paul Blom and Transport and recombination in polymer:fullerene bulk heterojunction solar cells
60/98
p
Smbtb-nxohtkthbd
Ekdjnvhd Pnobi`hdkthbd, Vrkp-ksshstnf Pnobi`hdkthbd
Ok
HVB
57;
Dnkt Sbeyinr SE fnoky1
7/22/2019 IEE/CEEM Seminar: Paul Blom and Transport and recombination in polymer:fullerene bulk heterojunction solar cells
61/98
3 033 633 733 =33
;3-;
;33
nxp.
okeo.
INM-SSW 9?33ps
Euihdn
sondon(k.u
.)
Vhin (ps)
Hdtrhdsho Nxohtbd Ehgnthin ~ ?33 ps2
Nxohtbd fhggushbd
7/22/2019 IEE/CEEM Seminar: Paul Blom and Transport and recombination in polymer:fullerene bulk heterojunction solar cells
62/98
Omkdjn Ndnrjntho fhsbrfnr hd SSW fnrhvkthvns
Pnfuonf ndnrjntho fhsbrfnr ndmkdons nxohtbd fhggushbd!!
:
Sbeyinr , inW F, oi0
/s (?33L), i0
/Ws
DP_-
SSW;0> ? ;3 -6 ;.> ;3 -;0
INM-
SSW;3> ;.; ;3 -? > ;3 -;;
@NM-SSW 80 0 ;3-? 0 ;3 -8
B
B
d
B
B
B
3.>
3.>
B
Bd
DP_-SSW
INM-SSW
@NM-SSW
N
F
N
F
SMX_HOKE PNWHNZ @ :0, 36>0;: 033>
57?
Dnkt Sbeyinr SE fnoky1
7/22/2019 IEE/CEEM Seminar: Paul Blom and Transport and recombination in polymer:fullerene bulk heterojunction solar cells
63/98
3 033 633 733 =33;3
-;
;33
nxp.
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DP_-SSW 9=33ps
Euihdnsondon
(k.u.)
Vhin (ps)
3 033 633 733 =33
;3-;
;33
nxp.
okeo.
INM-SSW 9?33ps
Euihdnsondon
(k.u.)
Vhin (ps)
3 033 633 733 =33;3
-0
;3-;
;33
nxp.
okeo.
Euihdnsondo
n(k.u.)
Vhin (ps)
@NM-SSW 9033ps
-Enss fhsbrfnr, smbrtnr
SE fnoky-Enss fhsbrfnr, ibdb-
nxpbdndthke fnoky
F9?;3-6oi0/s F9;;3-?oi0/s
F90;3-?oi0/s
Nxohtbd fhggushbd
7/22/2019 IEE/CEEM Seminar: Paul Blom and Transport and recombination in polymer:fullerene bulk heterojunction solar cells
64/98
Ndnrjntho fhsbrfnr hd SSW fnrhvkthvns
Nxohtbd fhggushbd endjtm >-: di hs hdfnpndfndt bd tmnkibudt bg ndnrjntho fhsbrfnr!!!!
=
3 03 63 733.3
3.0
3.6
3.7
3.=
;.3
DP_-SSW< EF9> di
[undomhd
jngghohndoy
Sbeyinr ghei tmholdnss \diY
INM-SSW< EF97.? di
@NM-SSW< EF97 di
obdstE
FE
F
F
F
t
t kdf
- qundomhdj
ondtnrs2
57>
Krn nenotrbd trkps kesb nxohtbd qundomnrs2
7/22/2019 IEE/CEEM Seminar: Paul Blom and Transport and recombination in polymer:fullerene bulk heterojunction solar cells
65/98
^dhvnrske nenotrbd trkp fndshty ~ >;3;:oi-?
Fhstkdon `ntwnnd trkps ;/(>;3;:);/? 9 ;0.7 di
Nxohtbd mks tb trkvne 7 di tb rnkom k trkp
Inksurn nenotrbd trkdspbrt kdf nxohtbd fhggushbd
hdfnpndfndtey hd k ibfne systni whtm shdjen
nxpbdndthke SE fnoky!!
577
Ibfne _ystni SOSFV@V
7/22/2019 IEE/CEEM Seminar: Paul Blom and Transport and recombination in polymer:fullerene bulk heterojunction solar cells
66/98
pbey\0,7-(6,6-`hs-(0-ntmyemnxye)-6M-oyoebpndtk\0,;-`
7/22/2019 IEE/CEEM Seminar: Paul Blom and Transport and recombination in polymer:fullerene bulk heterojunction solar cells
67/98
Kee _hdjen nxpbdndthke!!
57=
SE fnoky Kdkeyshs (nxp. fnoky)
7/22/2019 IEE/CEEM Seminar: Paul Blom and Transport and recombination in polymer:fullerene bulk heterojunction solar cells
68/98
; ; 6
g
rFot t
_tnrd-Wbeinr gbriuek19 SE fnoky thin bg `endf whtm SO@I obdondtrkthbd o
g9 SE fnoky thin bg prhsthdn SOSFV@Vr 9 _ui bg tmn nxohtbd rkfhh
F 9 Nxohtbd fhggushbd obngghohndt.
r~ ; di
F9?;3-?oi0/s
578
@koljrbudf [undomnrs
7/22/2019 IEE/CEEM Seminar: Paul Blom and Transport and recombination in polymer:fullerene bulk heterojunction solar cells
69/98
3q o o
3
; ;
6 6g
rFo rFq t t
3
3
; ;6
g
rFot t
q931 Hdtrhdsho Nxohtbd Ehgnthin 3
SO@I
@koljrbudf [undomnrs
+_tnrd Wbeinr1
g9 SE fnoky thin bg prhsthdn SOSFV@V
39 SE fnoky thin bg sbeuthbd
5:3
Jrkpmhoke Pnprnsndtkthbd o3
7/22/2019 IEE/CEEM Seminar: Paul Blom and Transport and recombination in polymer:fullerene bulk heterojunction solar cells
70/98
o397;3;:oi-? , nquke tb Dtrkpnenotrbds ! ! ! ! !
5:;
Zmkt k`but SE ngghohndoy2
7/22/2019 IEE/CEEM Seminar: Paul Blom and Transport and recombination in polymer:fullerene bulk heterojunction solar cells
71/98
tg9
;
+ ldr+ l
fhgg
39
;
+ ldr
lfhgg
9
;
tg
;
t3
9 6 rFo3
9 + l
dr+ l
fhgg
9
;t3
+ 6 rFo3
9; t
3ldr
;+6 rFo3t
3
Inksurnf ehgnthin hd ghei
Inksurnf ehgnthin hd sbeuthbd
_tnrd-Wbeinr
SE Xhnef
5:0
SE grbi hdtnjrkthdj spmnrn
7/22/2019 IEE/CEEM Seminar: Paul Blom and Transport and recombination in polymer:fullerene bulk heterojunction solar cells
72/98
3ldr93.:0
Obdoeushbds 5:?
7/22/2019 IEE/CEEM Seminar: Paul Blom and Transport and recombination in polymer:fullerene bulk heterojunction solar cells
73/98
Hi`kekdonf trkdspbrt kdf strbdj rnobi`hdkthbd enkf tb k
squkrn-rbbt fnpndfndon bg tmn pmbtbourrndt, GG~3.6
Dkturn bg rnobi`hdkthbd okd `n hfndthghnf grbi omkrjn-
trkdsgnr stktn nenotrbeuihdnsondon
OV-stktn nihsshbd hs bg `hibenouekr brhjhd
Znkl trkp-ksshstnf rnobi`hdkthbd hs prnsndt hd
S?MV1SO@I sbekr onees
Vmn kibudt bg nxohtbd qundomnrs hs nquke tb tmn kibudt bgnenotrbd trkps. Vmn nxohtbd fhggushbd endjtm kdf ehgtnthin
krn dbt hdtrhdsho `ut krn fntnrihdnf `y nxtrhdsho fngnots
P J
Koldbwenfjnindt1
7/22/2019 IEE/CEEM Seminar: Paul Blom and Transport and recombination in polymer:fullerene bulk heterojunction solar cells
74/98
PuJ
Orhsthdk Vkdksn
Fndhs Ikrlbv
Akd Kdtbd Lbstnr
Ikjfk Ikdfbo
Hrhdk Orkohud
Xukd Qmkdj
Mnrikd Dhobekh
Jnrt-Akd Zntzneknr
Skue fn @ruyd
Dhnes vkd fnr Lkkp
@nrt fn @bnr
Fkjb fn Ennuw
^O_@
Kenx Ihldndlb
Ikrthad Luhl
Aksbd Ehd
[uynd Djuynd
JnbrjhkVnom
Ankd-Euo @rnfks
Omkf Phslb
Oksny Okip`nee
5:>
7/22/2019 IEE/CEEM Seminar: Paul Blom and Transport and recombination in polymer:fullerene bulk heterojunction solar cells
75/98
Vmkdl ybu gbr ybur kttndthbd!!!
5:7
Vrkdspbrt kdf Pnobi`hdkthbd hd k SENF
7/22/2019 IEE/CEEM Seminar: Paul Blom and Transport and recombination in polymer:fullerene bulk heterojunction solar cells
76/98
Hdanothbd1 @krrhnr Mnhjmt
Vrkdspbrt1 Ib`hehty, Vrkps, _pkon Omkrjn
Pnobi`hdkthbd
0.; nWOk
HVB
B
M?O B d
@urrbujmns nt ke., Dkturn ?6:, p. >?8 (;883)
Nxpbdndthke Vrkp Fhstrh`uthbd1 Ibfhghnf Ibfne 5::
7/22/2019 IEE/CEEM Seminar: Paul Blom and Transport and recombination in polymer:fullerene bulk heterojunction solar cells
77/98
Nxp. Vrkp ibfne1
r9Vt/V)(;0
;
)(
3 rOE
W
nDnDA
r
rr
nggt
rdo
N
)nxp(~)(t
t
t
lV
NNND
Dtrkp9>*;3;: oi-?
Vt9;>33 L
IFIB-SSW1
t
totnggt
V
lVNDD
)0/(nxp
0
)(
tVV
o
tt
D
dDd
/
Vrkp-ehihtnf Nenotrbd Vrkdspbrt2 5:=
7/22/2019 IEE/CEEM Seminar: Paul Blom and Transport and recombination in polymer:fullerene bulk heterojunction solar cells
78/98
E^IB SSW
Mbw okd wn fntnrihdn n, Dt, kdf Nto 22
Fnnp Vrkps
_mkeebw Vrkps
Mbpphdj hd
ibfhghnf FB_
Nto
v. Indsgbbrt nt ke., SP@
=3, 3??030 (0338)
d-typn fbphdj15:8
7/22/2019 IEE/CEEM Seminar: Paul Blom and Transport and recombination in polymer:fullerene bulk heterojunction solar cells
79/98
K. Lkmd nt ke., Brj. Nenotr. 8, >:> (033=)
Sm P @ =; 3=>03; (03;3)
d-typn fbphdj15=3
7/22/2019 IEE/CEEM Seminar: Paul Blom and Transport and recombination in polymer:fullerene bulk heterojunction solar cells
80/98
Kgtnr d-fbphdj1
Nenotrbd ourrndt nquke tb mben ourrndt
Vnipnrkturn fnpndfndon nquke tb tnipnrkturn fnpndfndon bg mben
ourrndt n9 m
Vrkps eboktnf 4 3.6 nW `nebw tmn E^IB
Smys. Pnv. @. =;, 3=>03; (03;3)
Jkusshkd E^IB kdf Nxpbdndthke Vrkps2 5=;
7/22/2019 IEE/CEEM Seminar: Paul Blom and Transport and recombination in polymer:fullerene bulk heterojunction solar cells
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^sn Kpprbxhikthbd hd Hdtnrinfhktn Wbetkjn Pnjhin1
J. Skksom kdf _. _omnhdnrt, A. Kppe. Smys. ;3:, ;36>3; (03;3).
;3;6
;3;7
;3;=
;303
;300
;306
;307
;3;=
;3;8
;303
;30;
;300
;30?
;306
;30>
E^IB
N
_hdjen envne
Nxpbdndthke
Jkusshkd
dt(i
-?)
d(i-?)
Hfnkehty gkotbr sbekr onees1 Fkrl Ourrndt 5=0
7/22/2019 IEE/CEEM Seminar: Paul Blom and Transport and recombination in polymer:fullerene bulk heterojunction solar cells
82/98
Sbeyinr1SO@I `uel mntnrbaudothbd sbekr onees mkvn kd
hfnkehty gkotbr bg ~;.?
;nxp
lV
qWAA sF
d4;1 Nvhfndon gbr trkp-ksshstnf rnobi`hdkthbd2
_hdjen Okrrhnr Fkrl-Ourrndt (db rno!!)
7/22/2019 IEE/CEEM Seminar: Paul Blom and Transport and recombination in polymer:fullerene bulk heterojunction solar cells
83/98
Hfnkehty gkotbr shdjen-okrrhnrfnvhons bg snpkrktn iktnrhkes
iktom hfnkehty gkotbrs bg tmn
`endf
94 Hfnkehty gkotbr hs fntnrihdnf `y trkdspbrt-fbihdkthdj
obdsthtundt bg tmn sbekr onee `endf.
Kppe. Smys. Entt. 88, ;>?>37 (03;;)
Btmnr obdaujktnf pbeyinrs2 5=6
7/22/2019 IEE/CEEM Seminar: Paul Blom and Transport and recombination in polymer:fullerene bulk heterojunction solar cells
84/98
3.; ; ;3;3
-?
;3-0
;3-;
;33
;3;
;30
;3?
;36
;6= di SOSFV@V
=> di SG;3V@V
;:? di G=@V
?33 di BO;O
;3-SSW
Ourrndt
Fndshty(K/i)
W (W)
_ebpn bg Vrkp-ehihtnf Nenotrbd Ourrndt vkrhns gbr fhggnrndt pbeyinrs
SENF Bpnrkthbd15=>
7/22/2019 IEE/CEEM Seminar: Paul Blom and Transport and recombination in polymer:fullerene bulk heterojunction solar cells
85/98
Vrkp-Grnn _OE Mben Vrkdspbrt
Vrkp-ehihtnf Nenotrbd Vrkdspbrt
Ekdjnvhd Pnobi`hdkthbd, _mboleny-Pnkf-Mkee Pnobi`hdkthbd
Ok
HVB
Kssuipthbd1 Fhggushbd dnjenotnf5=7
7/22/2019 IEE/CEEM Seminar: Paul Blom and Transport and recombination in polymer:fullerene bulk heterojunction solar cells
86/98
E
A-W omkrkotnrhstho hs1
Db rnobi`hdkthbd ebssns1
+
Rmd
W9WBO
-`hks
nW
lV
lVnW
lVnWnJEAAA pd
0
;)/nxp(
;)/nxp(
Mujmns kdf _blne1 A. Kppe. Smys. >0, ;8=;, 7:6?
A
W
W
fhggushbd frhgt
Pnokp1 5=:
7/22/2019 IEE/CEEM Seminar: Paul Blom and Transport and recombination in polymer:fullerene bulk heterojunction solar cells
87/98
nWlV
lVnWlVnWnJEA 0
;)/nxp(;)/nxp(
EWnJA ppdd tt
=
80/;6/?
6/;
WJq
qA p
Ebw vbetkjn1 Bmiho `nmkvhbur1
0/;0/; WnJAdd
t
nJEA
Hdtnrinfhktn vbetkjn1 _qukrn rbbt `nmkvhbur1
_kturkthbd rnjhin1 Wbetkjn hdfnpndfndt
br 22
Frhgt vs fhggushbd
br 22
Nxohtbd Fhggushbd Endjtm
7/22/2019 IEE/CEEM Seminar: Paul Blom and Transport and recombination in polymer:fullerene bulk heterojunction solar cells
88/98
Sbey(G0F) keebws gbrikthbd bg k obipentneyhiib`hehznf wnee-fnghdnf mntnrbstruoturn
EF9>-: di
D
B
B
O6M8
O6M8
G0F
3 633.3
3.0
3.6
3.7
3.=
;.3
S
E
qundomhdj\k
.u.Y
DP_-SSW ghei tmholdnss \diY
DP_-SSW/pbey(G0F)
EF9 > di
Vhin-hdfnpndfndt!!
Smbtbvbetkho rnspbdsn1: di
A.A.I.Mkees nt.ke.,Kppe. Smys. Entt., ;887, 7=, ?;03
A. Smys. Omni. K 033>, ;38, >077->0:6
Nxohtbd Fhggushbd Obngghohndt
7/22/2019 IEE/CEEM Seminar: Paul Blom and Transport and recombination in polymer:fullerene bulk heterojunction solar cells
89/98
),(),()(),(
)(
),(),(0
0
txjtxdx_
x
txdF
t
txd
t
txd
t
3 033 633 733 =333.3
3.0
3.6
3.7
3.=
;.3
SEhdtndshty\k.u.Y
Vhin \psY
Dnkt DP_-SSW
Ghei tmholdnss
;>.> di
= di
6 di
s
oiF
DP_
0
6
;3?
Smbtb-hdfuonf fngnot qundomhdj1
F90;3-6oi0/sI. Xkd nt. ke.,
Smys. Pnv. Ent., ;886, :?, :66
Dnkt Sbeyinr usnf ks rngnrndonSMX_HOKE PNWHNZ @ :0, 36>0;7 033>
583Nxohtbd Fhggushbd Obngghohndt
7/22/2019 IEE/CEEM Seminar: Paul Blom and Transport and recombination in polymer:fullerene bulk heterojunction solar cells
90/98
@uel [undomnr
SO@I
O-SOSFV@V
58;Nxohtbd Fhggushbd Obngghohndt
7/22/2019 IEE/CEEM Seminar: Paul Blom and Transport and recombination in polymer:fullerene bulk heterojunction solar cells
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Pnekthvn qundomhdj ngghohndoy
ftSE
ftSE
[prhsthdn
`endf
;
Hdthiktn
ihxturn1
db oeustnrs!
IO shiuekthbd1
F9?;3-?oi0/s
EF9;3 di
Ndnrjy Ndvhrbd. _oh., 03;0, >, 7873
580
Dnkt Sbeyinr SE fnoky
7/22/2019 IEE/CEEM Seminar: Paul Blom and Transport and recombination in polymer:fullerene bulk heterojunction solar cells
92/98
SE fnoky hs dbt shdjen nxpbdndthke.
-rnekxkthbd bg nxohtbds hd Jkusshkd FB_
A. Smys. Omni. @ 033=, ;;0, ;;73;;;736 ;;73;
Ibvkjmkr, @.< Jrdnwkef, I.< Phns, @.< @ssenr, M.< Zrtz, F.
Smys. Pnv. @ ;8=7, ??, >>6>>>>6.
58?
Pnokp1
7/22/2019 IEE/CEEM Seminar: Paul Blom and Transport and recombination in polymer:fullerene bulk heterojunction solar cells
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Pnfuothbd bg fhsbrfnr enkfs tb hdornksn bg
nxohtbd fhggushbd obngghohndt
Gbr nxohtbd fhggushbd obngghohndt 4;3-? oi0/Ws
tmn SE fnoky hs shdjen nxpbdndthke
Vmn nxohtbd fhggushbd endjtm ~>-: di hs
hdfnpndfndt bd fhsbrfnr.
Brjkdho @MA vs. _h-`ksnf _bekr onee586
7/22/2019 IEE/CEEM Seminar: Paul Blom and Transport and recombination in polymer:fullerene bulk heterojunction solar cells
94/98
3.3; 3.; ; ;3
3.;
;
obdstkdt J
A WIFIB-SSW1SO@I_h p/d onee
A/Aikx
Wbo-W \WY
ghnef fnpndfndt J
Vmn jndnrkthbd rktn hd `endfs bg IFIB-SSW1SO@I hs ghnef fnpndfndt!
Hdtrbfuothbd bg VOD[ nenotrbd trkps1
O tm t `h th htm t f e t h
58>
7/22/2019 IEE/CEEM Seminar: Paul Blom and Transport and recombination in polymer:fullerene bulk heterojunction solar cells
95/98
Okd wn prbvn tmkt rnobi`hdkthbd whtm trkppnf nenotrbds hs
rnspbdsh`en gbr tmn ndmkdonf fnpndfndon bg Wbo bd ehjmt
hdtndshty2E^IB IFIB-SSW
E^IB SO@I
MBIB IFIB-SSW
MBIB SO@I
Nxohtbd
fhggushbdD
D
D
D
M M
M M
6.> nW
VOD[
Wboehjmt hdtndshty fnpndfndon587
7/22/2019 IEE/CEEM Seminar: Paul Blom and Transport and recombination in polymer:fullerene bulk heterojunction solar cells
96/98
;3 ;33 ;333
3.0
3.6
3.7
3.=
;.3
_\lV/qY9?
Ehjmt hdtndshty (Z/i0)
Wbo
(W)
Db Vrkps
_\lV/qY9;
VOD[ Vrkps
Kppe. Smys. Entt. 8;, 07?>3> 033:
58:
SE fnoky SOSFV@V
7/22/2019 IEE/CEEM Seminar: Paul Blom and Transport and recombination in polymer:fullerene bulk heterojunction solar cells
97/98
390;0 ps
g9 ;67 ps
Fhsbrfnr fbihdktnf omkrjn trkdspbrt 58=
7/22/2019 IEE/CEEM Seminar: Paul Blom and Transport and recombination in polymer:fullerene bulk heterojunction solar cells
98/98
+?-F Vrkdspbrt `y mbpphdj
`ntwnnd obdaujktnf pkrts
bg tmn omkhd
Ebw ib`hehty1~Ws
oi0
:;3>
@ssenr, Smys. _tkt. _be. (`) ;:>, ;> (;88?)
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