ChemWatch Company Chemwatch Hazard Alert Code: 2
TRIS(ETHYLENEDIAMINE)NICKEL(II) CHLORIDE HYDRATEChemwatch: 4143-99Version No: 5.1.1.1Safety Data Sheet according to WHS and ADG requirements
Issue Date: 05/12/2015Print Date: 06/02/2015
Initial Date: Not AvailableS.GHS.AUS.EN
SECTION 1 IDENTIFICATION OF THE SUBSTANCE / MIXTURE AND OF THE COMPANY / UNDERTAKING
Product IdentifierProduct name TRIS(ETHYLENEDIAMINE)NICKEL(II) CHLORIDE HYDRATE
Chemical Name tris(ethylenediamine)nickel(II) chloride hydrateSynonyms C6-H24-Cl2-Ni, ethane-1,2-diamine - dichloronickel (3:1) hydrate
Other means ofidentification
Not Available
CAS number 699012-90-3
Relevant identified uses of the substance or mixture and uses advised againstRelevant identified
uses
Reagent.Chelating agent [~Regeant ~]
Details of the manufacturer/importerRegistered company
nameSigma-Aldrich
Address 12 Anella Avenue Castle Hill 2154 NSW Australia
Telephone +61 2 9841 0555; 1800 800 097
Fax +61 2 9841 0500
Website www.sigma-aldrich.com
Email [email protected]
Emergency telephone numberAssociation /Organisation
Not Available
Emergency telephonenumbers
1800 448 456
Other emergencytelephone numbers
Not Available
SECTION 2 HAZARDS IDENTIFICATION
Classification of the substance or mixture
HAZARDOUS CHEMICAL. NON-DANGEROUS GOODS. According to the Model WHS Regulations and the ADG Code.
CHEMWATCH HAZARD RATINGSMaxMin
Flammability 1
Toxicity 1
Body Contact 0Reactivity 1
Chronic 2
0 = Minimum1 = Low2 = Moderate3 = High4 = Extreme
Poisons Schedule Not Applicable
GHS Classification [1] Skin Sensitizer Category 1, Carcinogen Category 2, Chronic Aquatic Hazard Category 4
Legend:1. Classified by Chemwatch; 2. Classification drawn from HSIS ; 3. Classification drawn from EC Directive 1272/2008 - AnnexVI
Label elements
Continued...
GHS label elements
SIGNAL WORD WARNING
Hazard statement(s)H317 May cause an allergic skin reaction
H351 Suspected of causing cancer
H413 May cause long lasting harmful effects to aquatic life
Precautionary statement(s) PreventionP201 Obtain special instructions before use.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P281 Use personal protective equipment as required.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
Precautionary statement(s) ResponseP308+P313 IF exposed or concerned: Get medical advice/attention.
P363 Wash contaminated clothing before reuse.
P302+P352 IF ON SKIN: Wash with plenty of water and soap
P333+P313 If skin irritation or rash occurs: Get medical advice/attention.
Precautionary statement(s) StorageP405 Store locked up.
Precautionary statement(s) DisposalP501 Dispose of contents/container to authorised chemical landfill or if organic to high temperature incineration
SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS
SubstancesCAS No %[weight] Name699012-90-3 >98
MixturesSee section above for composition of Substances
SECTION 4 FIRST AID MEASURES
Description of first aid measures
Eye Contact
If this product comes in contact with the eyes: Wash out immediately with fresh running water. Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionallylifting the upper and lower lids. Seek medical attention without delay; if pain persists or recurs seek medical attention. Removal of contact lenses after an eye injury should only be undertaken by skilled personnel.
Skin Contact
If skin contact occurs:Immediately remove all contaminated clothing, including footwear. Flush skin and hair with running water (and soap if available). Seek medical attention in event of irritation.
InhalationIf fumes, aerosols or combustion products are inhaled remove from contaminated area. Other measures are usually unnecessary.
IngestionIf swallowed do NOT induce vomiting. If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain open airway andprevent aspiration.
tris(ethylenediamine)nickel(II) chloride hydrate
Chemwatch: 4143-99Version No: 5.1.1.1
Page 2 of 8
TRIS(ETHYLENEDIAMINE)NICKEL(II) CHLORIDE HYDRATEIssue Date: 05/12/2015Print Date: 06/02/2015
Continued...
Observe the patient carefully. Never give liquid to a person showing signs of being sleepy or with reduced awareness; i.e. becoming unconscious. Give water to rinse out mouth, then provide liquid slowly and as much as casualty can comfortably drink. Seek medical advice.
Indication of any immediate medical attention and special treatment neededTreat symptomatically.
In cases of nickel poisoning, dimercaptol delivered by deep intramuscular injection may be a suitable antidote. (Patients should not exhibit renal orhepatic dysfunction.) The use of diethyldithiocarbamate is the subject of ongoing research. Irritant contact dermatoses or eczemas may respond to applications of weak antiseptic packs, antibiotic ointments (tetracycline or erythromycin) or inertpastes and ointments. Systemic antibiotics are advisable in the presence of lymphangitis or lymphadenitis.
SECTION 5 FIREFIGHTING MEASURES
Extinguishing mediaWater spray or fog. Foam. Dry chemical powder. BCF (where regulations permit).
Special hazards arising from the substrate or mixture
Fire IncompatibilityAvoid contamination with oxidising agents i.e. nitrates, oxidising acids, chlorine bleaches, pool chlorine etc. as ignition mayresult
Advice for firefighters
Fire Fighting
Alert Fire Brigade and tell them location and nature of hazard. Wear breathing apparatus plus protective gloves. Prevent, by any means available, spillage from entering drains or water courses. Use water delivered as a fine spray to control fire and cool adjacent area.
Fire/Explosion Hazard
Combustible solid which burns but propagates flame with difficulty; it is estimated that most organic dusts are combustible(circa 70%) - according to the circumstances under which the combustion process occurs, such materials may cause firesand / or dust explosions.Organic powders when finely divided over a range of concentrations regardless of particulate size or shape and suspendedin air or some other oxidizing medium may form explosive dust-air mixtures and result in a fire or dust explosion (includingsecondary explosions).Avoid generating dust, particularly clouds of dust in a confined or unventilated space as dusts may form an explosivemixture with air, and any source of ignition, i.e. flame or spark, will cause fire or explosion. Dust clouds generated by thefine grinding of the solid are a particular hazard; accumulations of fine dust (420 micron or less) may burn rapidly andfiercely if ignited - particles exceeding this limit will generally not form flammable dust clouds; once initiated, however,larger particles up to 1400 microns diameter will contribute to the propagation of an explosion.
SECTION 6 ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Minor Spills
Clean up waste regularly and abnormal spills immediately. Avoid breathing dust and contact with skin and eyes. Wear protective clothing, gloves, safety glasses and dust respirator. Use dry clean up procedures and avoid generating dust.
Major SpillsModerate hazard.
CAUTION: Advise personnel in area. Alert Emergency Services and tell them location and nature of hazard. Control personal contact by wearing protective clothing.
Personal Protective Equipment advice is contained in Section 8 of the MSDS.
SECTION 7 HANDLING AND STORAGE
Precautions for safe handling
Safe handling
Avoid all personal contact, including inhalation. Wear protective clothing when risk of exposure occurs. Use in a well-ventilated area. Prevent concentration in hollows and sumps.
Chemwatch: 4143-99Version No: 5.1.1.1
Page 3 of 8
TRIS(ETHYLENEDIAMINE)NICKEL(II) CHLORIDE HYDRATEIssue Date: 05/12/2015Print Date: 06/02/2015
Continued...
Other information
Store in original containers. Keep containers securely sealed. Store in a cool, dry area protected from environmental extremes. Store away from incompatible materials and foodstuff containers.
Conditions for safe storage, including any incompatibilities
Suitable containerGlass container is suitable for laboratory quantities Polyethylene or polypropylene container. Check all containers are clearly labelled and free from leaks.
Storageincompatibility
Avoid reaction with oxidising agents
PACKAGE MATERIAL INCOMPATIBILITIESNot Available
SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION
Control parameters
OCCUPATIONAL EXPOSURE LIMITS (OEL)INGREDIENT DATA
Not Available
EMERGENCY LIMITS
Ingredient Material name TEEL-1 TEEL-2 TEEL-3
TRIS(ETHYLENEDIAMINE)NICKEL(II)CHLORIDE HYDRATE Not Available Not Available Not Available Not Available
Ingredient Original IDLH Revised IDLH
tris(ethylenediamine)nickel(II)chloride hydrate Not Available Not Available
Exposure controls
Appropriateengineering controls
Engineering controls are used to remove a hazard or place a barrier between the worker and the hazard. Well-designedengineering controls can be highly effective in protecting workers and will typically be independent of worker interactions toprovide this high level of protection.The basic types of engineering controls are:Process controls which involve changing the way a job activity or process is done to reduce the risk.Enclosure and/or isolation of emission source which keeps a selected hazard "physically" away from the worker andventilation that strategically "adds" and "removes" air in the work environment.
Personal protection
Eye and faceprotection
Safety glasses with side shields.Chemical goggles.Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written policydocument, describing the wearing of lenses or restrictions on use, should be created for each workplace or task.
Skin protection See Hand protection below
Hands/feet protection
NOTE:The material may produce skin sensitisation in predisposed individuals. Care must be taken, when removing gloves andother protective equipment, to avoid all possible skin contact. Contaminated leather items, such as shoes, belts and watch-bands should be removed and destroyed.
The selection of suitable gloves does not only depend on the material, but also on further marks of quality which vary frommanufacturer to manufacturer.
Body protection See Other protection below
Other protectionOveralls. P.V.C. apron. Barrier cream.
Thermal hazards Not Available
Recommended material(s) Respiratory protection
Chemwatch: 4143-99Version No: 5.1.1.1
Page 4 of 8
TRIS(ETHYLENEDIAMINE)NICKEL(II) CHLORIDE HYDRATEIssue Date: 05/12/2015Print Date: 06/02/2015
Continued...
GLOVE SELECTION INDEXGlove selection is based on a modified presentation of the: "Forsberg Clothing Performance Index". The effect(s) of the following substance(s) are taken into account in the computer-generated selection: TRIS(ETHYLENEDIAMINE)NICKEL(II) CHLORIDE HYDRATE NotAvailable
Material CPI
* CPI - Chemwatch Performance IndexA: Best SelectionB: Satisfactory; may degrade after 4 hours continuous immersionC: Poor to Dangerous Choice for other than short term immersionNOTE: As a series of factors will influence the actual performance of theglove, a final selection must be based on detailed observation. -* Where the glove is to be used on a short term, casual or infrequentbasis, factors such as "feel" or convenience (e.g. disposability), maydictate a choice of gloves which might otherwise be unsuitable followinglong-term or frequent use. A qualified practitioner should be consulted.
Particulate. (AS/NZS 1716 & 1715, EN 143:000 & 149:001, ANSI Z88 ornational equivalent)
Required MinimumProtection Factor
Half-FaceRespirator
Full-FaceRespirator
Powered AirRespirator
up to 10 x ES P1Air-line*-
-
PAPR-P1-
up to 50 x ES Air-line** P2 PAPR-P2
up to 100 x ES - P3 -
Air-line* -
100+ x ES - Air-line** PAPR-P3
* - Negative pressure demand ** - Continuous flowA(All classes) = Organic vapours, B AUS or B1 = Acid gasses, B2 = Acidgas or hydrogen cyanide(HCN), B3 = Acid gas or hydrogen cyanide(HCN),E = Sulfur dioxide(SO2), G = Agricultural chemicals, K = Ammonia(NH3),Hg = Mercury, NO = Oxides of nitrogen, MB = Methyl bromide, AX = Lowboiling point organic compounds(below 65 degC)
SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical propertiesAppearance Solid; mixes with water.
Physical state Divided Solid Relative density(Water = 1) Not Available
Odour Not Available Partition coefficientn-octanol / water
Not Available
Odour threshold Not Available Auto-ignitiontemperature (C) Not Available
pH (as supplied) Not Applicable Decompositiontemperature
Not Available
Melting point /freezing point (C) Not Available Viscosity (cSt) Not Applicable
Initial boiling pointand boiling range (C) 170
Molecular weight(g/mol) 309.9
Flash point (C) Not Available Taste Not AvailableEvaporation rate Not Applicable Explosive properties Not Available
Flammability Not Available Oxidising properties Not Available
Upper Explosive Limit(%) Not Available
Surface Tension(dyn/cm or mN/m) Not Applicable
Lower Explosive Limit(%) Not Available
Volatile Component(%vol) Negligible
Vapour pressure (kPa) Negligible Gas group Not AvailableSolubility in water
(g/L) Miscible pH as a solution (1%) Not Available
Vapour density (Air =1) Not Applicable VOC g/L Not Available
SECTION 10 STABILITY AND REACTIVITY
Reactivity See section 7
Chemical stabilityUnstable in the presence of incompatible materials.Product is considered stable.Hazardous polymerisation will not occur.
Possibility ofhazardous reactions
See section 7
Conditions to avoid See section 7
Incompatible materials See section 7
Chemwatch: 4143-99Version No: 5.1.1.1
Page 5 of 8
TRIS(ETHYLENEDIAMINE)NICKEL(II) CHLORIDE HYDRATEIssue Date: 05/12/2015Print Date: 06/02/2015
Continued...
Legend: Data required to make classification available Data available but does not fill the criteria for classification Data Not Available to make classification
Hazardousdecomposition
productsSee section 5
SECTION 11 TOXICOLOGICAL INFORMATION
Information on toxicological effects
Inhaled
The material is not thought to produce either adverse health effects or irritation of the respiratory tract following inhalation (asclassified by EC Directives using animal models). Nevertheless, adverse systemic effects have been produced followingexposure of animals by at least one other route and good hygiene practice requires that exposure be kept to a minimum andthat suitable control measures be used in an occupational setting.Persons with impaired respiratory function, airway diseases and conditions such as emphysema or chronic bronchitis, mayincur further disability if excessive concentrations of particulate are inhaled.If prior damage to the circulatory or nervous systems has occurred or if kidney damage has been sustained, properscreenings should be conducted on individuals who may be exposed to further risk if handling and use of the material resultin excessive exposures.
IngestionAccidental ingestion of the material may be damaging to the health of the individual.Nickel is not well absorbed orally. Excretion in the urine is complete after about 4-5 days.Nickel salts cause vomiting, following ingestion as a result of the irritant effects.
Skin Contact
The material is not thought to produce adverse health effects or skin irritation following contact (as classified by ECDirectives using animal models). Nevertheless, good hygiene practice requires that exposure be kept to a minimum and thatsuitable gloves be used in an occupational setting.Open cuts, abraded or irritated skin should not be exposed to this materialEntry into the blood-stream, through, for example, cuts, abrasions or lesions, may produce systemic injury with harmfuleffects. Examine the skin prior to the use of the material and ensure that any external damage is suitably protected.
EyeAlthough the material is not thought to be an irritant (as classified by EC Directives), direct contact with the eye may causetransient discomfort characterised by tearing or conjunctival redness (as with windburn). Slight abrasive damage may alsoresult.
Chronic
There has been concern that this material can cause cancer or mutations, but there is not enough data to make anassessment.Skin contact with the material is more likely to cause a sensitisation reaction in some persons compared to the generalpopulation.There is some evidence that inhaling this product is more likely to cause a sensitisation reaction in some persons comparedto the general population.Nickel causes a skin sensitisation which may produce a chronic eczema.
tris(ethylenediamine)nickel(II)chloride hydrate
TOXICITY IRRITATION
Not Available Not Available
Legend: 1. Value obtained from Europe ECHA Registered Substances - Acute toxicity 2.* Value obtained from manufacturer's msds. Unless otherwise specified data extracted from RTECS - Register of Toxic Effect of chemical Substances
TRIS(ETHYLENEDIAMINE)NICKEL(II)CHLORIDE HYDRATE
The following information refers to contact allergens as a group and may not be specific to this product. Contact allergies quickly manifest themselves as contact eczema, more rarely as urticaria or Quincke'soedema. The pathogenesis of contact eczema involves a cell-mediated (T lymphocytes) immune reaction ofthe delayed type. Other allergic skin reactions, e.g. contact urticaria, involve antibody-mediated immunereactions.
Acute Toxicity Carcinogenicity
SkinIrritation/Corrosion Reproductivity
Serious EyeDamage/Irritation
STOT - SingleExposure
Respiratory or Skinsensitisation
STOT - RepeatedExposure
Mutagenicity Aspiration Hazard
CMR STATUSNot Applicable
Chemwatch: 4143-99Version No: 5.1.1.1
Page 6 of 8
TRIS(ETHYLENEDIAMINE)NICKEL(II) CHLORIDE HYDRATEIssue Date: 05/12/2015Print Date: 06/02/2015
Continued...
SECTION 12 ECOLOGICAL INFORMATION
ToxicityMay cause long-term adverse effects in the aquatic environment. Do NOT allow product to come in contact with surface waters or to intertidal areas below the mean high water mark. Do not contaminate water whencleaning equipment or disposing of equipment wash-waters.Wastes resulting from use of the product must be disposed of on site or at approved waste sites.
Persistence and degradabilityIngredient Persistence: Water/Soil Persistence: Air
No Data available for all ingredients No Data available for all ingredients
Bioaccumulative potentialIngredient Bioaccumulation
No Data available for all ingredients
Mobility in soilIngredient Mobility
No Data available for all ingredients
SECTION 13 DISPOSAL CONSIDERATIONS
Waste treatment methods
Product / Packagingdisposal
Containers may still present a chemical hazard/ danger when empty. Return to supplier for reuse/ recycling if possible.
Otherwise:If container can not be cleaned sufficiently well to ensure that residuals do not remain or if the container cannot be used tostore the same product, then puncture containers, to prevent re-use, and bury at an authorised landfill. Where possible retain label warnings and MSDS and observe all notices pertaining to the product.
SECTION 14 TRANSPORT INFORMATION
Labels RequiredMarine Pollutant NO
HAZCHEM Not Applicable
Land transport (ADG): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODSAir transport (ICAO-IATA / DGR): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODSSea transport (IMDG-Code / GGVSee): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS
SECTION 15 REGULATORY INFORMATION
Safety, health and environmental regulations / legislation specific for the substance or mixturetris(ethylenediamine)nickel(II)chloride hydrate(699012-90-3)
is found on the followingregulatory lists
"Not Applicable"
National Inventory Status
Australia - AICS N (tris(ethylenediamine)nickel(II) chloride hydrate)Canada - DSL N (tris(ethylenediamine)nickel(II) chloride hydrate)China - IECSC N (tris(ethylenediamine)nickel(II) chloride hydrate)Europe - EINEC /ELINCS / NLP N (tris(ethylenediamine)nickel(II) chloride hydrate)
Japan - ENCS N (tris(ethylenediamine)nickel(II) chloride hydrate)Korea - KECI N (tris(ethylenediamine)nickel(II) chloride hydrate)New Zealand - NZIoC N (tris(ethylenediamine)nickel(II) chloride hydrate)
Chemwatch: 4143-99Version No: 5.1.1.1
Page 7 of 8
TRIS(ETHYLENEDIAMINE)NICKEL(II) CHLORIDE HYDRATEIssue Date: 05/12/2015Print Date: 06/02/2015
Continued...
Philippines - PICCS N (tris(ethylenediamine)nickel(II) chloride hydrate)USA - TSCA N (tris(ethylenediamine)nickel(II) chloride hydrate)
Legend:Y = All ingredients are on the inventory N = Not determined or one or more ingredients are not on the inventory and are notexempt from listing(see specific ingredients in brackets)
SECTION 16 OTHER INFORMATION
Other informationClassification of the preparation and its individual components has drawn on official and authoritative sources as well as independent review by theChemwatch Classification committee using available literature references.A list of reference resources used to assist the committee may be found at: www.chemwatch.net
The (M)SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whether the reported Hazardsare Risks in the workplace or other settings. Risks may be determined by reference to Exposures Scenarios. Scale of use, frequency of use and currentor available engineering controls must be considered.
This document is copyright.Apart from any fair dealing for the purposes of private study, research, review or criticism, as permitted under the Copyright Act, no part may bereproduced by any process without written permission from CHEMWATCH.TEL (+61 3) 9572 4700.
Chemwatch: 4143-99Version No: 5.1.1.1
Page 8 of 8
TRIS(ETHYLENEDIAMINE)NICKEL(II) CHLORIDE HYDRATEIssue Date: 05/12/2015Print Date: 06/02/2015
end of SDS
Top Related