Documents MSDSVendors 2015 June 02-23-18!33!271 PM

ChemWatch Company Chemwatch Hazard Alert Code: 2

TRIS(ETHYLENEDIAMINE)NICKEL(II) CHLORIDE HYDRATEChemwatch: 4143-99Version No: 5.1.1.1Safety Data Sheet according to WHS and ADG requirements

Issue Date: 05/12/2015Print Date: 06/02/2015

Initial Date: Not AvailableS.GHS.AUS.EN

SECTION 1 IDENTIFICATION OF THE SUBSTANCE / MIXTURE AND OF THE COMPANY / UNDERTAKING

Product IdentifierProduct name TRIS(ETHYLENEDIAMINE)NICKEL(II) CHLORIDE HYDRATE

Chemical Name tris(ethylenediamine)nickel(II) chloride hydrateSynonyms C6-H24-Cl2-Ni, ethane-1,2-diamine - dichloronickel (3:1) hydrate

Other means ofidentification

Not Available

CAS number 699012-90-3

Relevant identified uses of the substance or mixture and uses advised againstRelevant identified

uses

Reagent.Chelating agent [~Regeant ~]

Details of the manufacturer/importerRegistered company

nameSigma-Aldrich

Address 12 Anella Avenue Castle Hill 2154 NSW Australia

Telephone +61 2 9841 0555; 1800 800 097

Fax +61 2 9841 0500

Website www.sigma-aldrich.com

Email [email protected]

Emergency telephone numberAssociation /Organisation

Not Available

Emergency telephonenumbers

1800 448 456

Other emergencytelephone numbers

Not Available

SECTION 2 HAZARDS IDENTIFICATION

Classification of the substance or mixture

HAZARDOUS CHEMICAL. NON-DANGEROUS GOODS. According to the Model WHS Regulations and the ADG Code.

CHEMWATCH HAZARD RATINGSMaxMin

Flammability 1

Toxicity 1

Body Contact 0Reactivity 1

Chronic 2

0 = Minimum1 = Low2 = Moderate3 = High4 = Extreme

Poisons Schedule Not Applicable

GHS Classification [1] Skin Sensitizer Category 1, Carcinogen Category 2, Chronic Aquatic Hazard Category 4

Legend:1. Classified by Chemwatch; 2. Classification drawn from HSIS ; 3. Classification drawn from EC Directive 1272/2008 - AnnexVI

Label elements

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GHS label elements

SIGNAL WORD WARNING

Hazard statement(s)H317 May cause an allergic skin reaction

H351 Suspected of causing cancer

H413 May cause long lasting harmful effects to aquatic life

Precautionary statement(s) PreventionP201 Obtain special instructions before use.

P280 Wear protective gloves/protective clothing/eye protection/face protection.

P281 Use personal protective equipment as required.

P261 Avoid breathing dust/fume/gas/mist/vapours/spray.

Precautionary statement(s) ResponseP308+P313 IF exposed or concerned: Get medical advice/attention.

P363 Wash contaminated clothing before reuse.

P302+P352 IF ON SKIN: Wash with plenty of water and soap

P333+P313 If skin irritation or rash occurs: Get medical advice/attention.

Precautionary statement(s) StorageP405 Store locked up.

Precautionary statement(s) DisposalP501 Dispose of contents/container to authorised chemical landfill or if organic to high temperature incineration

SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS

SubstancesCAS No %[weight] Name699012-90-3 >98

MixturesSee section above for composition of Substances

SECTION 4 FIRST AID MEASURES

Description of first aid measures

Eye Contact

If this product comes in contact with the eyes: Wash out immediately with fresh running water. Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionallylifting the upper and lower lids. Seek medical attention without delay; if pain persists or recurs seek medical attention. Removal of contact lenses after an eye injury should only be undertaken by skilled personnel.

Skin Contact

If skin contact occurs:Immediately remove all contaminated clothing, including footwear. Flush skin and hair with running water (and soap if available). Seek medical attention in event of irritation.

InhalationIf fumes, aerosols or combustion products are inhaled remove from contaminated area. Other measures are usually unnecessary.

IngestionIf swallowed do NOT induce vomiting. If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain open airway andprevent aspiration.

tris(ethylenediamine)nickel(II) chloride hydrate

Chemwatch: 4143-99Version No: 5.1.1.1

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TRIS(ETHYLENEDIAMINE)NICKEL(II) CHLORIDE HYDRATEIssue Date: 05/12/2015Print Date: 06/02/2015

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Observe the patient carefully. Never give liquid to a person showing signs of being sleepy or with reduced awareness; i.e. becoming unconscious. Give water to rinse out mouth, then provide liquid slowly and as much as casualty can comfortably drink. Seek medical advice.

Indication of any immediate medical attention and special treatment neededTreat symptomatically.

In cases of nickel poisoning, dimercaptol delivered by deep intramuscular injection may be a suitable antidote. (Patients should not exhibit renal orhepatic dysfunction.) The use of diethyldithiocarbamate is the subject of ongoing research. Irritant contact dermatoses or eczemas may respond to applications of weak antiseptic packs, antibiotic ointments (tetracycline or erythromycin) or inertpastes and ointments. Systemic antibiotics are advisable in the presence of lymphangitis or lymphadenitis.

SECTION 5 FIREFIGHTING MEASURES

Extinguishing mediaWater spray or fog. Foam. Dry chemical powder. BCF (where regulations permit).

Special hazards arising from the substrate or mixture

Fire IncompatibilityAvoid contamination with oxidising agents i.e. nitrates, oxidising acids, chlorine bleaches, pool chlorine etc. as ignition mayresult

Advice for firefighters

Fire Fighting

Alert Fire Brigade and tell them location and nature of hazard. Wear breathing apparatus plus protective gloves. Prevent, by any means available, spillage from entering drains or water courses. Use water delivered as a fine spray to control fire and cool adjacent area.

Fire/Explosion Hazard

Combustible solid which burns but propagates flame with difficulty; it is estimated that most organic dusts are combustible(circa 70%) - according to the circumstances under which the combustion process occurs, such materials may cause firesand / or dust explosions.Organic powders when finely divided over a range of concentrations regardless of particulate size or shape and suspendedin air or some other oxidizing medium may form explosive dust-air mixtures and result in a fire or dust explosion (includingsecondary explosions).Avoid generating dust, particularly clouds of dust in a confined or unventilated space as dusts may form an explosivemixture with air, and any source of ignition, i.e. flame or spark, will cause fire or explosion. Dust clouds generated by thefine grinding of the solid are a particular hazard; accumulations of fine dust (420 micron or less) may burn rapidly andfiercely if ignited - particles exceeding this limit will generally not form flammable dust clouds; once initiated, however,larger particles up to 1400 microns diameter will contribute to the propagation of an explosion.

SECTION 6 ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures

Minor Spills

Clean up waste regularly and abnormal spills immediately. Avoid breathing dust and contact with skin and eyes. Wear protective clothing, gloves, safety glasses and dust respirator. Use dry clean up procedures and avoid generating dust.

Major SpillsModerate hazard.

CAUTION: Advise personnel in area. Alert Emergency Services and tell them location and nature of hazard. Control personal contact by wearing protective clothing.

Personal Protective Equipment advice is contained in Section 8 of the MSDS.

SECTION 7 HANDLING AND STORAGE

Precautions for safe handling

Safe handling

Avoid all personal contact, including inhalation. Wear protective clothing when risk of exposure occurs. Use in a well-ventilated area. Prevent concentration in hollows and sumps.


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Other information

Store in original containers. Keep containers securely sealed. Store in a cool, dry area protected from environmental extremes. Store away from incompatible materials and foodstuff containers.

Conditions for safe storage, including any incompatibilities

Suitable containerGlass container is suitable for laboratory quantities Polyethylene or polypropylene container. Check all containers are clearly labelled and free from leaks.

Storageincompatibility

Avoid reaction with oxidising agents

PACKAGE MATERIAL INCOMPATIBILITIESNot Available

SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION

Control parameters

OCCUPATIONAL EXPOSURE LIMITS (OEL)INGREDIENT DATA

Not Available

EMERGENCY LIMITS

Ingredient Material name TEEL-1 TEEL-2 TEEL-3

TRIS(ETHYLENEDIAMINE)NICKEL(II)CHLORIDE HYDRATE Not Available Not Available Not Available Not Available

Ingredient Original IDLH Revised IDLH

tris(ethylenediamine)nickel(II)chloride hydrate Not Available Not Available

Exposure controls

Appropriateengineering controls

Engineering controls are used to remove a hazard or place a barrier between the worker and the hazard. Well-designedengineering controls can be highly effective in protecting workers and will typically be independent of worker interactions toprovide this high level of protection.The basic types of engineering controls are:Process controls which involve changing the way a job activity or process is done to reduce the risk.Enclosure and/or isolation of emission source which keeps a selected hazard "physically" away from the worker andventilation that strategically "adds" and "removes" air in the work environment.

Personal protection

Eye and faceprotection

Safety glasses with side shields.Chemical goggles.Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written policydocument, describing the wearing of lenses or restrictions on use, should be created for each workplace or task.

Skin protection See Hand protection below

Hands/feet protection

NOTE:The material may produce skin sensitisation in predisposed individuals. Care must be taken, when removing gloves andother protective equipment, to avoid all possible skin contact. Contaminated leather items, such as shoes, belts and watch-bands should be removed and destroyed.

The selection of suitable gloves does not only depend on the material, but also on further marks of quality which vary frommanufacturer to manufacturer.

Body protection See Other protection below

Other protectionOveralls. P.V.C. apron. Barrier cream.

Thermal hazards Not Available

Recommended material(s) Respiratory protection


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GLOVE SELECTION INDEXGlove selection is based on a modified presentation of the: "Forsberg Clothing Performance Index". The effect(s) of the following substance(s) are taken into account in the computer-generated selection: TRIS(ETHYLENEDIAMINE)NICKEL(II) CHLORIDE HYDRATE NotAvailable

Material CPI

* CPI - Chemwatch Performance IndexA: Best SelectionB: Satisfactory; may degrade after 4 hours continuous immersionC: Poor to Dangerous Choice for other than short term immersionNOTE: As a series of factors will influence the actual performance of theglove, a final selection must be based on detailed observation. -* Where the glove is to be used on a short term, casual or infrequentbasis, factors such as "feel" or convenience (e.g. disposability), maydictate a choice of gloves which might otherwise be unsuitable followinglong-term or frequent use. A qualified practitioner should be consulted.

Particulate. (AS/NZS 1716 & 1715, EN 143:000 & 149:001, ANSI Z88 ornational equivalent)

Required MinimumProtection Factor

Half-FaceRespirator

Full-FaceRespirator

Powered AirRespirator

up to 10 x ES P1Air-line*-

-

PAPR-P1-

up to 50 x ES Air-line** P2 PAPR-P2

up to 100 x ES - P3 -

Air-line* -

100+ x ES - Air-line** PAPR-P3

* - Negative pressure demand ** - Continuous flowA(All classes) = Organic vapours, B AUS or B1 = Acid gasses, B2 = Acidgas or hydrogen cyanide(HCN), B3 = Acid gas or hydrogen cyanide(HCN),E = Sulfur dioxide(SO2), G = Agricultural chemicals, K = Ammonia(NH3),Hg = Mercury, NO = Oxides of nitrogen, MB = Methyl bromide, AX = Lowboiling point organic compounds(below 65 degC)

SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical propertiesAppearance Solid; mixes with water.

Physical state Divided Solid Relative density(Water = 1) Not Available

Odour Not Available Partition coefficientn-octanol / water

Not Available

Odour threshold Not Available Auto-ignitiontemperature (C) Not Available

pH (as supplied) Not Applicable Decompositiontemperature

Not Available

Melting point /freezing point (C) Not Available Viscosity (cSt) Not Applicable

Initial boiling pointand boiling range (C) 170

Molecular weight(g/mol) 309.9

Flash point (C) Not Available Taste Not AvailableEvaporation rate Not Applicable Explosive properties Not Available

Flammability Not Available Oxidising properties Not Available

Upper Explosive Limit(%) Not Available

Surface Tension(dyn/cm or mN/m) Not Applicable

Lower Explosive Limit(%) Not Available

Volatile Component(%vol) Negligible

Vapour pressure (kPa) Negligible Gas group Not AvailableSolubility in water

(g/L) Miscible pH as a solution (1%) Not Available

Vapour density (Air =1) Not Applicable VOC g/L Not Available

SECTION 10 STABILITY AND REACTIVITY

Reactivity See section 7

Chemical stabilityUnstable in the presence of incompatible materials.Product is considered stable.Hazardous polymerisation will not occur.

Possibility ofhazardous reactions

See section 7

Conditions to avoid See section 7

Incompatible materials See section 7


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Legend: Data required to make classification available Data available but does not fill the criteria for classification Data Not Available to make classification

Hazardousdecomposition

productsSee section 5

SECTION 11 TOXICOLOGICAL INFORMATION

Information on toxicological effects

Inhaled

The material is not thought to produce either adverse health effects or irritation of the respiratory tract following inhalation (asclassified by EC Directives using animal models). Nevertheless, adverse systemic effects have been produced followingexposure of animals by at least one other route and good hygiene practice requires that exposure be kept to a minimum andthat suitable control measures be used in an occupational setting.Persons with impaired respiratory function, airway diseases and conditions such as emphysema or chronic bronchitis, mayincur further disability if excessive concentrations of particulate are inhaled.If prior damage to the circulatory or nervous systems has occurred or if kidney damage has been sustained, properscreenings should be conducted on individuals who may be exposed to further risk if handling and use of the material resultin excessive exposures.

IngestionAccidental ingestion of the material may be damaging to the health of the individual.Nickel is not well absorbed orally. Excretion in the urine is complete after about 4-5 days.Nickel salts cause vomiting, following ingestion as a result of the irritant effects.

Skin Contact

The material is not thought to produce adverse health effects or skin irritation following contact (as classified by ECDirectives using animal models). Nevertheless, good hygiene practice requires that exposure be kept to a minimum and thatsuitable gloves be used in an occupational setting.Open cuts, abraded or irritated skin should not be exposed to this materialEntry into the blood-stream, through, for example, cuts, abrasions or lesions, may produce systemic injury with harmfuleffects. Examine the skin prior to the use of the material and ensure that any external damage is suitably protected.

EyeAlthough the material is not thought to be an irritant (as classified by EC Directives), direct contact with the eye may causetransient discomfort characterised by tearing or conjunctival redness (as with windburn). Slight abrasive damage may alsoresult.

Chronic

There has been concern that this material can cause cancer or mutations, but there is not enough data to make anassessment.Skin contact with the material is more likely to cause a sensitisation reaction in some persons compared to the generalpopulation.There is some evidence that inhaling this product is more likely to cause a sensitisation reaction in some persons comparedto the general population.Nickel causes a skin sensitisation which may produce a chronic eczema.

tris(ethylenediamine)nickel(II)chloride hydrate

TOXICITY IRRITATION

Not Available Not Available

Legend: 1. Value obtained from Europe ECHA Registered Substances - Acute toxicity 2.* Value obtained from manufacturer's msds. Unless otherwise specified data extracted from RTECS - Register of Toxic Effect of chemical Substances

TRIS(ETHYLENEDIAMINE)NICKEL(II)CHLORIDE HYDRATE

The following information refers to contact allergens as a group and may not be specific to this product. Contact allergies quickly manifest themselves as contact eczema, more rarely as urticaria or Quincke'soedema. The pathogenesis of contact eczema involves a cell-mediated (T lymphocytes) immune reaction ofthe delayed type. Other allergic skin reactions, e.g. contact urticaria, involve antibody-mediated immunereactions.

Acute Toxicity Carcinogenicity

SkinIrritation/Corrosion Reproductivity

Serious EyeDamage/Irritation

STOT - SingleExposure

Respiratory or Skinsensitisation

STOT - RepeatedExposure

Mutagenicity Aspiration Hazard

CMR STATUSNot Applicable


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SECTION 12 ECOLOGICAL INFORMATION

ToxicityMay cause long-term adverse effects in the aquatic environment. Do NOT allow product to come in contact with surface waters or to intertidal areas below the mean high water mark. Do not contaminate water whencleaning equipment or disposing of equipment wash-waters.Wastes resulting from use of the product must be disposed of on site or at approved waste sites.

Persistence and degradabilityIngredient Persistence: Water/Soil Persistence: Air

No Data available for all ingredients No Data available for all ingredients

Bioaccumulative potentialIngredient Bioaccumulation

No Data available for all ingredients

Mobility in soilIngredient Mobility

No Data available for all ingredients

SECTION 13 DISPOSAL CONSIDERATIONS

Waste treatment methods

Product / Packagingdisposal

Containers may still present a chemical hazard/ danger when empty. Return to supplier for reuse/ recycling if possible.

Otherwise:If container can not be cleaned sufficiently well to ensure that residuals do not remain or if the container cannot be used tostore the same product, then puncture containers, to prevent re-use, and bury at an authorised landfill. Where possible retain label warnings and MSDS and observe all notices pertaining to the product.

SECTION 14 TRANSPORT INFORMATION

Labels RequiredMarine Pollutant NO

HAZCHEM Not Applicable

Land transport (ADG): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODSAir transport (ICAO-IATA / DGR): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODSSea transport (IMDG-Code / GGVSee): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS

SECTION 15 REGULATORY INFORMATION

Safety, health and environmental regulations / legislation specific for the substance or mixturetris(ethylenediamine)nickel(II)chloride hydrate(699012-90-3)

is found on the followingregulatory lists

"Not Applicable"

National Inventory Status

Australia - AICS N (tris(ethylenediamine)nickel(II) chloride hydrate)Canada - DSL N (tris(ethylenediamine)nickel(II) chloride hydrate)China - IECSC N (tris(ethylenediamine)nickel(II) chloride hydrate)Europe - EINEC /ELINCS / NLP N (tris(ethylenediamine)nickel(II) chloride hydrate)

Japan - ENCS N (tris(ethylenediamine)nickel(II) chloride hydrate)Korea - KECI N (tris(ethylenediamine)nickel(II) chloride hydrate)New Zealand - NZIoC N (tris(ethylenediamine)nickel(II) chloride hydrate)


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Philippines - PICCS N (tris(ethylenediamine)nickel(II) chloride hydrate)USA - TSCA N (tris(ethylenediamine)nickel(II) chloride hydrate)

Legend:Y = All ingredients are on the inventory N = Not determined or one or more ingredients are not on the inventory and are notexempt from listing(see specific ingredients in brackets)

SECTION 16 OTHER INFORMATION

Other informationClassification of the preparation and its individual components has drawn on official and authoritative sources as well as independent review by theChemwatch Classification committee using available literature references.A list of reference resources used to assist the committee may be found at: www.chemwatch.net

The (M)SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whether the reported Hazardsare Risks in the workplace or other settings. Risks may be determined by reference to Exposures Scenarios. Scale of use, frequency of use and currentor available engineering controls must be considered.

This document is copyright.Apart from any fair dealing for the purposes of private study, research, review or criticism, as permitted under the Copyright Act, no part may bereproduced by any process without written permission from CHEMWATCH.TEL (+61 3) 9572 4700.


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end of SDS

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