2002 reduction, hydrogenation

reduction, hydrogenationO 0220

11 - 045Thermal Reduction of 7H-Benz[d,e]anthracen-7-one and RelatedKetones under Hydrogen-Transfer Conditions. — In the presenceof hydrogen donors aromatic ketones undergo selective deoxygenation to thecorresponding hydroaromatic compounds via reverse radical disproportionation.The kinetics for reduction of ketone (I) are studied in detail. — (MULDER,PETER; HEMMINK, SVEN; DE HEER, MARTINE I.; LUPO, MARCO;SANTORO, DANILO; KORTH, HANS-GERT; J. Org. Chem. 66 (2001) 20,6611-6619; Leiden Inst. Chem., Leiden Univ., NL-2300 RA Leiden, Neth.; EN)

1