ChemInform Abstract: Thermal Reduction of 7H-Benz[d,e]anthracen-7-one and Related Ketones under...

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2002 reduction, hydrogenation reduction, hydrogenation O 0220 11 - 045 Thermal Reduction of 7H-Benz[d,e]anthracen-7-one and Related Ketones under Hydrogen-Transfer Conditions. In the presence of hydrogen donors aromatic ketones undergo selective deoxygenation to the corresponding hydroaromatic compounds via reverse radical disproportionation. The kinetics for reduction of ketone (I) are studied in detail. — (MULDER, PETER; HEMMINK, SVEN; DE HEER, MARTINE I.; LUPO, MARCO; SANTORO, DANILO; KORTH, HANS-GERT; J. Org. Chem. 66 (2001) 20, 6611-6619; Leiden Inst. Chem., Leiden Univ., NL-2300 RA Leiden, Neth.; EN) 1

Transcript of ChemInform Abstract: Thermal Reduction of 7H-Benz[d,e]anthracen-7-one and Related Ketones under...

Page 1: ChemInform Abstract: Thermal Reduction of 7H-Benz[d,e]anthracen-7-one and Related Ketones under Hydrogen-Transfer Conditions.

2002 reduction, hydrogenation

reduction, hydrogenationO 0220

11 - 045Thermal Reduction of 7H-Benz[d,e]anthracen-7-one and RelatedKetones under Hydrogen-Transfer Conditions. — In the presenceof hydrogen donors aromatic ketones undergo selective deoxygenation to thecorresponding hydroaromatic compounds via reverse radical disproportionation.The kinetics for reduction of ketone (I) are studied in detail. — (MULDER,PETER; HEMMINK, SVEN; DE HEER, MARTINE I.; LUPO, MARCO;SANTORO, DANILO; KORTH, HANS-GERT; J. Org. Chem. 66 (2001) 20,6611-6619; Leiden Inst. Chem., Leiden Univ., NL-2300 RA Leiden, Neth.; EN)

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