ChemInform Abstract: Thermal Reduction of 7H-Benz[d,e]anthracen-7-one and Related Ketones under...

2002 reduction, hydrogenation reduction, hydrogenation O 0220 11 - 045 Thermal Reduction of 7H-Benz[d,e]anthracen-7-one and Related Ketones under Hydrogen-Transfer Conditions. — In the presence of hydrogen donors aromatic ketones undergo selective deoxygenation to the corresponding hydroaromatic compounds via reverse radical disproportionation. The kinetics for reduction of ketone (I) are studied in detail. — (MULDER, PETER; HEMMINK, SVEN; DE HEER, MARTINE I.; LUPO, MARCO; SANTORO, DANILO; KORTH, HANS-GERT; J. Org. Chem. 66 (2001) 20, 6611-6619; Leiden Inst. Chem., Leiden Univ., NL-2300 RA Leiden, Neth.; EN) 1

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Transcript of ChemInform Abstract: Thermal Reduction of 7H-Benz[d,e]anthracen-7-one and Related Ketones under...

Page 1: ChemInform Abstract: Thermal Reduction of 7H-Benz[d,e]anthracen-7-one and Related Ketones under Hydrogen-Transfer Conditions.

2002 reduction, hydrogenation

reduction, hydrogenationO 0220

11 - 045Thermal Reduction of 7H-Benz[d,e]anthracen-7-one and RelatedKetones under Hydrogen-Transfer Conditions. — In the presenceof hydrogen donors aromatic ketones undergo selective deoxygenation to thecorresponding hydroaromatic compounds via reverse radical disproportionation.The kinetics for reduction of ketone (I) are studied in detail. — (MULDER,PETER; HEMMINK, SVEN; DE HEER, MARTINE I.; LUPO, MARCO;SANTORO, DANILO; KORTH, HANS-GERT; J. Org. Chem. 66 (2001) 20,6611-6619; Leiden Inst. Chem., Leiden Univ., NL-2300 RA Leiden, Neth.; EN)