2000 gadolinium, Gd

gadolinium, GdI 3500

31 - 022Electrodeposition of Gd–Co Film in Organic Bath. — AmorphousGd–Co films are deposited on Cu by potentiostatic electrolysis of DMF solutionscontaining (TosO)3Gd, CoCl2, and Bu4NBF4. The electroreduction of Gd(III)is irreversible; transfer coefficient and diffusion coefficient of Gd(III) are given.The films are homogeneous, dense, and exhibit high adhesion on the Cusubstrate. Heat treatment at 500 ◦C (1 h) results in crystallization of the filmand formation of the alloy Co3Gd. — (LIU, PENG; YANG, QIQIN; TONG,YEXIANG; YANG, YANSHENG; Electrochim. Acta 45 (2000) 13, 2147-2152;MOCVD Lab., South China Norm. Univ., Guangzhou, Guangzhou 510631,Peop. Rep. China; EN)

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