water reports/ACZ Level 2...BD[ Laboratories, Inc. 2773 Downhill Drive Steamboat Springs, CO 80487...
Transcript of water reports/ACZ Level 2...BD[ Laboratories, Inc. 2773 Downhill Drive Steamboat Springs, CO 80487...
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Analytical
Report
SPF Water Engineering
300 E. Mallard Drive, Suite 350
Boise, ID 83706
ACZ Project ID: L17362
Jason Thompson:
Enclosed are the analytical results for sample(s) submitted to ACZ Laboratories, Inc. (ACZ) on March 21, 2014. This project has been assigned to ACZ's project number, L17362. Please reference this number in all future inquiries.
All analyses were performed according to ACZ's Quality Assurance Plan. The enclosed results relate only to the samples received under L17362. Each section of this report has been reviewed and approved by the appropriate Laboratory Supervisor, or a qualified substitute.
Except as noted, the test results for the methods and parameters listed on ACZ's current NELAC certificate letter (#ACZ) meet all requirements of NELAC.
This report shall be used or copied only in its entirety. ACZ is not responsible for the consequences arising from the use of a partial report.
All samples and sub-samples associated with this project will be disposed of after May 11, 2014. If the samples are determined to be hazardous, additional charges apply for disposal (typically $11/sample). If you would like the samples to be held longer than ACZ's stated policy or to be returned, please contact your Project Manager or Customer Service Representative for further details and associated costs. ACZ retains analytical raw data reports for ten years.
If you have any questions or other needs, please contact your Project Manager.
Jason Thompson
April 11, 2014
Project ID: Calico 1st Quarter 2014 Sampli
SPF Water Engineering
300 E. Mallard Drive, Suite 350
Boise, ID 83706
Crystal Jensen
Report to: Bill to:
Page 1 of 63L17362-1404111040
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Case
Narrative
SPF Water Engineering
ACZ Project ID: L17362
April 11, 2014
Sample Receipt
Sample Analysis
Holding Times
Text10:ACZ Laboratories, Inc. (ACZ) received 8 ground water samples from SPF Water Engineering on March 21, 2014. The samples were received in good condition. Upon receipt, the sample custodian removed the samples from the cooler, inspected the contents, and logged the samples into ACZ's computerized Laboratory Information Management System (LIMS). The samples were assigned ACZ LIMS project number L17362. The custodian verified the sample information entered into the computer against the chain of custody (COC) forms and sample bottle labels.
Text10:These samples were analyzed for inorganic parameters. The individual methods are referenced on both the ACZ invoice and the analytical reports. The extended qualifier reports may contain footnotes qualifying specific elements due to QC failures. In addition the following has been noted with this specific project:
Some of the dissolved Cobalt values exceed the corresponding total values for project L17362. In some cases, RPDs between dissolved and total values exceed the standard acceptance limit of 20%. Samples were re-analyzed for verification, and results for both parameters were confirmed. This is a consistent anomaly with these sample types, and discrepancies may be attributed to a matrix or field sampling issue.
Text10:Any analyses not performed within EPA recommended holding times have been qualified with an "H" flag.
Project ID: Calico 1st Quarter 2014 Sampli
REPAD.03.06.05.01 Page 2 of 63L17362-1404111040
ACZ Sample ID: L17362-01
Sample ID: PW-4
Sample Matrix: Ground Water
SPF Water Engineering
Project ID: Calico 1st Quarter 2014 Sa
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic Analytical
Results
Date Sampled: 03/18/14 10:50
Date Received: 03/21/14
Parameter EPA Method Result Units MDLQual AnalystDatePQL
Inorganic Prep
XQDilution
Cyanide, total M335.4 - Manual Distillation bsu03/28/14 15:31
Cyanide, WAD SM4500-CN I- distillation mss203/27/14 15:12
Phosphorus, total M365.1 - Auto Ascorbic Acid Digestion
bsu04/04/14 12:28
Total Hot Plate Digestion
M200.2 ICP jjc03/27/14 12:01
Total Hot Plate Digestion
M200.2 ICP-MS scp04/07/14 14:38
REPIN.02.06.05.01 * Please refer to Qualifier Reports for details.
Page 3 of 63L17362-1404111040
ACZ Sample ID: L17362-01
Sample ID: PW-4
Sample Matrix: Ground Water
SPF Water Engineering
Project ID: Calico 1st Quarter 2014 Sa
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic Analytical
Results
Date Sampled: 03/18/14 10:50
Date Received: 03/21/14
Parameter EPA Method Result Units MDLQual AnalystDatePQL
Metals Analysis
XQDilution
Aluminum, dissolved M200.7 ICP 0.11 mg/L 0.2B jjc0.03 03/25/14 10:141
Aluminum, total M200.7 ICP 6.11 mg/L 0.2 jjc0.03 03/28/14 11:231
Antimony, dissolved M200.8 ICP-MS mg/L 0.002U las0.0004 04/02/14 0:141
Antimony, total M200.8 ICP-MS mg/L 0.002U las0.0004 04/01/14 20:211
Arsenic, dissolved M200.8 ICP-MS 0.0127 mg/L 0.001 las0.0002 04/02/14 0:141
Arsenic, total M200.8 ICP-MS 0.0148 mg/L 0.001 las0.0002 04/01/14 20:211
Barium, dissolved M200.7 ICP mg/L 0.02U jjc0.003* 03/25/14 10:141
Barium, total M200.7 ICP 0.017 mg/L 0.02B jjc0.003 03/28/14 11:231
Beryllium, dissolved M200.8 ICP-MS mg/L 0.0003U las0.00005 04/02/14 0:141
Beryllium, total M200.8 ICP-MS 0.00032 mg/L 0.0003 las0.00005 04/01/14 20:211
Bismuth, dissolved M200.7 ICP mg/L 0.2U jjc0.04* 03/25/14 10:141
Bismuth, total M200.7 ICP mg/L 0.2U aeb0.04* 03/28/14 15:171
Boron, dissolved M200.7 ICP 0.12 mg/L 0.05 jjc0.01* 03/25/14 10:141
Boron, total M200.7 ICP 0.14 mg/L 0.05 jjc0.01 03/28/14 11:231
Cadmium, dissolved M200.8 ICP-MS mg/L 0.0005U las0.0001 04/02/14 0:141
Cadmium, total M200.8 ICP-MS mg/L 0.0005U las0.0001 04/01/14 20:211
Calcium, dissolved M200.7 ICP 7.3 mg/L 0.5 jjc0.1 03/25/14 10:141
Calcium, total M200.7 ICP 11.6 mg/L 0.5 jjc0.1 03/28/14 11:231
Chromium, dissolved M200.8 ICP-MS mg/L 0.002U las0.0005 04/02/14 0:141
Chromium, total M200.8 ICP-MS mg/L 0.002U las0.0005 04/01/14 20:211
Cobalt, dissolved M200.8 ICP-MS 0.00025 mg/L 0.0003B las0.00005 04/02/14 0:141
Cobalt, total M200.8 ICP-MS 0.00028 mg/L 0.0003B las0.00005 04/01/14 20:211
Copper, dissolved M200.8 ICP-MS mg/L 0.003U las0.0005 04/02/14 0:141
Copper, total M200.8 ICP-MS 0.0007 mg/L 0.003B las0.0005 04/01/14 20:211
Gallium, dissolved M200.7 ICP mg/L 0.5U jjc0.1* 03/25/14 10:141
Gallium, total M200.7 ICP mg/L 0.5U jjc0.1* 03/28/14 11:231
Iron, dissolved M200.7 ICP 0.25 mg/L 0.05 jjc0.02 03/25/14 10:141
Iron, total M200.7 ICP 6.06 mg/L 0.05 jjc0.02 03/28/14 11:231
Lead, dissolved M200.8 ICP-MS mg/L 0.0005U las0.0001 04/02/14 0:141
Lead, total M200.8 ICP-MS 0.0048 mg/L 0.0005 las0.0001 04/01/14 20:211
Lithium, dissolved M200.7 ICP 0.081 mg/L 0.04 jjc0.008* 03/25/14 10:141
Lithium, total M200.7 ICP 0.094 mg/L 0.04 jjc0.008 03/28/14 11:231
Magnesium, dissolved M200.7 ICP 0.3 mg/L 1B jjc0.2 03/25/14 10:141
Magnesium, total M200.7 ICP 1.3 mg/L 1 jjc0.2 03/28/14 11:231
Manganese, dissolved M200.8 ICP-MS 0.0357 mg/L 0.003 las0.0005 04/02/14 0:141
Manganese, total M200.8 ICP-MS 0.0640 mg/L 0.003 las0.0005 04/01/14 20:211
Mercury, dissolved M1631, Atomic Fluorescence ng/L 0.5U las0.2 04/01/14 16:211
Mercury, total M1631, Atomic Fluorescence 4 ng/L 3 las1 03/31/14 12:275
Molybdenum, dissolved M200.8 ICP-MS 0.0105 mg/L 0.003 las0.0005 04/02/14 0:141
Molybdenum, total M200.8 ICP-MS 0.0109 mg/L 0.003 las0.0005 04/01/14 20:211
Nickel, dissolved M200.8 ICP-MS mg/L 0.003U las0.0006 04/02/14 0:141
Nickel, total M200.8 ICP-MS 0.0007 mg/L 0.003B las0.0006 04/01/14 20:211
Potassium, dissolved M200.7 ICP 0.7 mg/L 1B jjc0.2 03/25/14 10:141
REPIN.02.06.05.01 * Please refer to Qualifier Reports for details.
Page 4 of 63L17362-1404111040
ACZ Sample ID: L17362-01
Sample ID: PW-4
Sample Matrix: Ground Water
SPF Water Engineering
Project ID: Calico 1st Quarter 2014 Sa
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic Analytical
Results
Date Sampled: 03/18/14 10:50
Date Received: 03/21/14
Potassium, total M200.7 ICP 1.1 mg/L 1 jjc0.2 03/28/14 11:231
Scandium, dissolved M200.7 ICP mg/L 0.5U jjc0.1* 03/25/14 10:141
Scandium, total M200.7 ICP mg/L 0.5U jjc0.1* 03/28/14 11:231
Selenium, dissolved M200.8 ICP-MS mg/L 0.0003U las0.0001 04/02/14 0:141
Selenium, total M200.8 ICP-MS mg/L 0.0003U las0.0001 04/01/14 20:211
Silver, dissolved M200.8 ICP-MS mg/L 0.0003U las0.00005 04/02/14 0:141
Silver, total M200.8 ICP-MS mg/L 0.0003U las0.00005 04/01/14 20:211
Sodium, dissolved M200.7 ICP 158 mg/L 1 jjc0.2 03/25/14 10:141
Sodium, total M200.7 ICP 177 mg/L 1 jjc0.2 03/28/14 11:231
Strontium, dissolved M200.7 ICP 0.035 mg/L 0.03 jjc0.005 03/25/14 10:141
Strontium, total M200.7 ICP 0.060 mg/L 0.03 jjc0.005 03/28/14 11:231
Thallium, dissolved M200.8 ICP-MS mg/L 0.0005U las0.0001 04/02/14 0:141
Thallium, total M200.8 ICP-MS mg/L 0.0005U las0.0001 04/01/14 20:211
Tin, dissolved M200.8 ICP-MS mg/L 0.0005U las0.0001* 04/02/14 0:141
Tin, total M200.8 ICP-MS 0.0004 mg/L 0.0005B msh0.0001* 04/09/14 19:381
Titanium, dissolved M200.7 ICP mg/L 0.03U jjc0.005 03/25/14 10:141
Titanium, total M200.7 ICP 0.029 mg/L 0.03B jjc0.005 03/28/14 11:231
Uranium, dissolved M200.8 ICP-MS mg/L 0.0005U las0.0001 04/02/14 0:141
Uranium, total M200.8 ICP-MS 0.0019 mg/L 0.0005 las0.0001 04/01/14 20:211
Vanadium, dissolved M200.8 ICP-MS mg/L 0.001U las0.0002 04/02/14 0:141
Vanadium, total M200.8 ICP-MS 0.0007 mg/L 0.001B las0.0002 04/01/14 20:211
Zinc, dissolved M200.7 ICP mg/L 0.05U jjc0.01 03/25/14 10:141
Zinc, total M200.7 ICP 0.01 mg/L 0.05B jjc0.01 03/28/14 11:231
REPIN.02.06.05.01 * Please refer to Qualifier Reports for details.
Page 5 of 63L17362-1404111040
ACZ Sample ID: L17362-01
Sample ID: PW-4
Sample Matrix: Ground Water
SPF Water Engineering
Project ID: Calico 1st Quarter 2014 Sa
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic Analytical
Results
Date Sampled: 03/18/14 10:50
Date Received: 03/21/14
Parameter EPA Method Result Units MDLQual AnalystDatePQL
Wet Chemistry
XQDilution
Alkalinity as CaCO3 SM2320B - Titration
Bicarbonate as CaCO3
177 mg/L 20 dcw2 03/26/14 0:001
Carbonate as CaCO3 4 mg/L 20B dcw2 03/26/14 0:001
Hydroxide as CaCO3 mg/L 20U dcw2 03/26/14 0:001
Total Alkalinity 182 mg/L 20 dcw2* 03/26/14 0:001
Chloride M300.0 - Ion Chromatography 40.0 mg/L 12.5 tcd2.5* 03/26/14 19:185
Conductivity @25C SM2510B 841 umhos/cm 10 dcw1 03/26/14 17:441
Cyanide, total M335.4 - Colorimetric w/ distillation mg/L 0.01U mpb0.003* 03/31/14 15:210.5
Cyanide, WAD SM4500-CN I-Colorimetric w/ distillation
mg/L 0.01U mpb0.003* 03/27/14 16:490.5
Fluoride M300.0 - Ion Chromatography 1.86 mg/L 2.5B tcd0.5* 03/26/14 19:185
Hardness as CaCO3 SM2340B - Calculation 20 mg/L 7 calc1 04/11/14 8:13
Nitrate/Nitrite as N M353.2 - H2SO4 preserved mg/L 0.1U pjb0.02 03/28/14 22:531
Nitrogen, ammonia M350.1 - Automated Phenate 0.10 mg/L 0.5B tcd0.05* 03/27/14 16:051
pH (lab) SM4500H+ B
pH 8.4 units 0.1H dcw0.1 03/26/14 0:001
pH measured at 21 C 0.1 dcw0.1 03/26/14 0:001
Phosphorus, total M365.1 - Auto Ascorbic Acid (digest)
0.05 mg/L 0.05 pjb0.01* 04/05/14 13:461
Residue, Filterable (TDS) @180C
SM2540C 490 mg/L 40 id20* 03/25/14 11:272
Residue, Non-Filterable (TSS) @105C
SM2540D 190 mg/L 80 enb20* 03/25/14 12:064
Sulfate M300.0 - Ion Chromatography 133 mg/L 12.5 tcd2.5 03/26/14 19:185
REPIN.02.06.05.01 * Please refer to Qualifier Reports for details.
Page 6 of 63L17362-1404111040
ACZ Sample ID: L17362-02
Sample ID: GW-4
Sample Matrix: Ground Water
SPF Water Engineering
Project ID: Calico 1st Quarter 2014 Sa
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic Analytical
Results
Date Sampled: 03/18/14 11:40
Date Received: 03/21/14
Parameter EPA Method Result Units MDLQual AnalystDatePQL
Inorganic Prep
XQDilution
Cyanide, total M335.4 - Manual Distillation bsu03/28/14 15:47
Cyanide, WAD SM4500-CN I- distillation mss203/27/14 15:21
Phosphorus, total M365.1 - Auto Ascorbic Acid Digestion
bsu04/04/14 12:43
Total Hot Plate Digestion
M200.2 ICP jjc03/27/14 12:12
Total Hot Plate Digestion
M200.2 ICP-MS las03/27/14 11:58
REPIN.02.06.05.01 * Please refer to Qualifier Reports for details.
Page 7 of 63L17362-1404111040
ACZ Sample ID: L17362-02
Sample ID: GW-4
Sample Matrix: Ground Water
SPF Water Engineering
Project ID: Calico 1st Quarter 2014 Sa
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic Analytical
Results
Date Sampled: 03/18/14 11:40
Date Received: 03/21/14
Parameter EPA Method Result Units MDLQual AnalystDatePQL
Metals Analysis
XQDilution
Aluminum, dissolved M200.7 ICP 0.06 mg/L 0.2B jjc0.03 03/25/14 10:231
Aluminum, total M200.7 ICP 1.09 mg/L 0.2 jjc0.03* 03/28/14 11:261
Antimony, dissolved M200.8 ICP-MS mg/L 0.002U las0.0004 04/02/14 0:241
Antimony, total M200.8 ICP-MS mg/L 0.002U las0.0004 04/01/14 20:251
Arsenic, dissolved M200.8 ICP-MS 0.0109 mg/L 0.001 las0.0002 04/02/14 0:241
Arsenic, total M200.8 ICP-MS 0.0111 mg/L 0.001 las0.0002 04/01/14 20:251
Barium, dissolved M200.7 ICP mg/L 0.02U jjc0.003* 03/25/14 10:231
Barium, total M200.7 ICP 0.009 mg/L 0.02B jjc0.003 03/28/14 11:261
Beryllium, dissolved M200.8 ICP-MS mg/L 0.0003U las0.00005 04/02/14 0:241
Beryllium, total M200.8 ICP-MS 0.00014 mg/L 0.0003B las0.00005 04/01/14 20:251
Bismuth, dissolved M200.7 ICP mg/L 0.2U jjc0.04* 03/25/14 10:231
Bismuth, total M200.7 ICP mg/L 0.2U aeb0.04* 03/28/14 15:201
Boron, dissolved M200.7 ICP 0.12 mg/L 0.05 jjc0.01* 03/25/14 10:231
Boron, total M200.7 ICP 0.14 mg/L 0.05 jjc0.01 03/28/14 11:261
Cadmium, dissolved M200.8 ICP-MS mg/L 0.0005U las0.0001 04/02/14 0:241
Cadmium, total M200.8 ICP-MS mg/L 0.0005U las0.0001 04/01/14 20:251
Calcium, dissolved M200.7 ICP 3.1 mg/L 0.5 jjc0.1 03/25/14 10:231
Calcium, total M200.7 ICP 4.1 mg/L 0.5 jjc0.1 03/28/14 11:261
Chromium, dissolved M200.8 ICP-MS mg/L 0.002U las0.0005 04/02/14 0:241
Chromium, total M200.8 ICP-MS mg/L 0.002U las0.0005 04/01/14 20:251
Cobalt, dissolved M200.8 ICP-MS 0.00047 mg/L 0.0003 las0.00005 04/02/14 0:241
Cobalt, total M200.8 ICP-MS 0.00008 mg/L 0.0003B las0.00005 04/01/14 20:251
Copper, dissolved M200.8 ICP-MS mg/L 0.003U las0.0005 04/02/14 0:241
Copper, total M200.8 ICP-MS mg/L 0.003U las0.0005 04/01/14 20:251
Gallium, dissolved M200.7 ICP mg/L 0.5U jjc0.1* 03/25/14 10:231
Gallium, total M200.7 ICP mg/L 0.5U jjc0.1* 03/28/14 11:261
Iron, dissolved M200.7 ICP mg/L 0.05U jjc0.02 03/25/14 10:231
Iron, total M200.7 ICP 0.41 mg/L 0.05 jjc0.02* 03/28/14 11:261
Lead, dissolved M200.8 ICP-MS mg/L 0.0005U las0.0001 04/02/14 0:241
Lead, total M200.8 ICP-MS 0.0009 mg/L 0.0005 las0.0001 04/01/14 20:251
Lithium, dissolved M200.7 ICP 0.078 mg/L 0.04 jjc0.008* 03/25/14 10:231
Lithium, total M200.7 ICP 0.094 mg/L 0.04 jjc0.008 03/28/14 11:261
Magnesium, dissolved M200.7 ICP mg/L 1U jjc0.2 03/25/14 10:231
Magnesium, total M200.7 ICP mg/L 1U jjc0.2 03/28/14 11:261
Manganese, dissolved M200.8 ICP-MS 0.0055 mg/L 0.003 las0.0005 04/02/14 0:241
Manganese, total M200.8 ICP-MS 0.0101 mg/L 0.003 las0.0005 04/01/14 20:251
Mercury, dissolved M1631, Atomic Fluorescence ng/L 0.5U las0.2 04/01/14 16:361
Mercury, total M1631, Atomic Fluorescence 0.8 ng/L 0.5 las0.2 03/31/14 12:321
Molybdenum, dissolved M200.8 ICP-MS 0.0090 mg/L 0.003 las0.0005 04/02/14 0:241
Molybdenum, total M200.8 ICP-MS 0.0093 mg/L 0.003 las0.0005 04/01/14 20:251
Nickel, dissolved M200.8 ICP-MS mg/L 0.003U las0.0006 04/02/14 0:241
Nickel, total M200.8 ICP-MS mg/L 0.003U las0.0006 04/01/14 20:251
Potassium, dissolved M200.7 ICP 0.4 mg/L 1B jjc0.2 03/25/14 10:231
REPIN.02.06.05.01 * Please refer to Qualifier Reports for details.
Page 8 of 63L17362-1404111040
ACZ Sample ID: L17362-02
Sample ID: GW-4
Sample Matrix: Ground Water
SPF Water Engineering
Project ID: Calico 1st Quarter 2014 Sa
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic Analytical
Results
Date Sampled: 03/18/14 11:40
Date Received: 03/21/14
Potassium, total M200.7 ICP 0.7 mg/L 1B jjc0.2 03/28/14 11:261
Scandium, dissolved M200.7 ICP mg/L 0.5U jjc0.1* 03/25/14 10:231
Scandium, total M200.7 ICP mg/L 0.5U jjc0.1* 03/28/14 11:261
Selenium, dissolved M200.8 ICP-MS mg/L 0.0003U las0.0001 04/02/14 0:241
Selenium, total M200.8 ICP-MS mg/L 0.0003U las0.0001 04/01/14 20:251
Silver, dissolved M200.8 ICP-MS mg/L 0.0003U las0.00005 04/02/14 0:241
Silver, total M200.8 ICP-MS mg/L 0.0003U las0.00005 04/01/14 20:251
Sodium, dissolved M200.7 ICP 129 mg/L 1 jjc0.2 03/25/14 10:231
Sodium, total M200.7 ICP 152 mg/L 1 jjc0.2 03/28/14 11:261
Strontium, dissolved M200.7 ICP 0.019 mg/L 0.03B jjc0.005 03/25/14 10:231
Strontium, total M200.7 ICP 0.029 mg/L 0.03B jjc0.005 03/28/14 11:261
Thallium, dissolved M200.8 ICP-MS mg/L 0.0005U las0.0001 04/02/14 0:241
Thallium, total M200.8 ICP-MS mg/L 0.0005U las0.0001 04/01/14 20:251
Tin, dissolved M200.8 ICP-MS mg/L 0.0005U las0.0001* 04/02/14 0:241
Tin, total M200.8 ICP-MS mg/L 0.0005U las0.0001* 04/01/14 20:251
Titanium, dissolved M200.7 ICP mg/L 0.03U jjc0.005 03/25/14 10:231
Titanium, total M200.7 ICP 0.013 mg/L 0.03B jjc0.005 03/28/14 11:261
Uranium, dissolved M200.8 ICP-MS mg/L 0.0005U las0.0001 04/02/14 0:241
Uranium, total M200.8 ICP-MS 0.0003 mg/L 0.0005B las0.0001 04/01/14 20:251
Vanadium, dissolved M200.8 ICP-MS mg/L 0.001U las0.0002 04/02/14 0:241
Vanadium, total M200.8 ICP-MS 0.0005 mg/L 0.001B las0.0002 04/01/14 20:251
Zinc, dissolved M200.7 ICP mg/L 0.05U jjc0.01 03/25/14 10:231
Zinc, total M200.7 ICP mg/L 0.05U jjc0.01 03/28/14 11:261
REPIN.02.06.05.01 * Please refer to Qualifier Reports for details.
Page 9 of 63L17362-1404111040
ACZ Sample ID: L17362-02
Sample ID: GW-4
Sample Matrix: Ground Water
SPF Water Engineering
Project ID: Calico 1st Quarter 2014 Sa
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic Analytical
Results
Date Sampled: 03/18/14 11:40
Date Received: 03/21/14
Parameter EPA Method Result Units MDLQual AnalystDatePQL
Wet Chemistry
XQDilution
Alkalinity as CaCO3 SM2320B - Titration
Bicarbonate as CaCO3
162 mg/L 20 dcw2 03/26/14 0:001
Carbonate as CaCO3 9 mg/L 20B dcw2 03/26/14 0:001
Hydroxide as CaCO3 mg/L 20U dcw2 03/26/14 0:001
Total Alkalinity 172 mg/L 20 dcw2* 03/26/14 0:001
Chloride M300.0 - Ion Chromatography 26.9 mg/L 2.5 tcd0.5* 03/26/14 20:121
Conductivity @25C SM2510B 696 umhos/cm 10 dcw1 03/26/14 17:531
Cyanide, total M335.4 - Colorimetric w/ distillation mg/L 0.01U mpb0.003* 03/31/14 15:410.5
Cyanide, WAD SM4500-CN I-Colorimetric w/ distillation
mg/L 0.01U mpb0.003* 03/27/14 16:500.5
Fluoride M300.0 - Ion Chromatography 2.23 mg/L 0.5 tcd0.1* 03/26/14 20:121
Hardness as CaCO3 SM2340B - Calculation 8 mg/L 7 calc1 04/11/14 8:14
Nitrate/Nitrite as N M353.2 - H2SO4 preserved mg/L 0.1U pjb0.02 03/28/14 22:541
Nitrogen, ammonia M350.1 - Automated Phenate mg/L 0.5U tcd0.05* 03/27/14 16:061
pH (lab) SM4500H+ B
pH 8.5 units 0.1H dcw0.1 03/26/14 0:001
pH measured at 21 C 0.1 dcw0.1 03/26/14 0:001
Phosphorus, total M365.1 - Auto Ascorbic Acid (digest)
0.07 mg/L 0.05 pjb0.01* 04/05/14 13:491
Residue, Filterable (TDS) @180C
SM2540C 260 mg/L 20 id10* 03/25/14 11:291
Residue, Non-Filterable (TSS) @105C
SM2540D 33 mg/L 20 enb5* 03/25/14 12:101
Sulfate M300.0 - Ion Chromatography 88.3 mg/L 2.5 tcd0.5 03/26/14 20:121
REPIN.02.06.05.01 * Please refer to Qualifier Reports for details.
Page 10 of 63L17362-1404111040
ACZ Sample ID: L17362-03
Sample ID: 59766
Sample Matrix: Ground Water
SPF Water Engineering
Project ID: Calico 1st Quarter 2014 Sa
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic Analytical
Results
Date Sampled: 03/18/14 12:40
Date Received: 03/21/14
Parameter EPA Method Result Units MDLQual AnalystDatePQL
Inorganic Prep
XQDilution
Cyanide, total M335.4 - Manual Distillation bsu03/28/14 16:03
Cyanide, WAD SM4500-CN I- distillation mss203/27/14 15:31
Phosphorus, total M365.1 - Auto Ascorbic Acid Digestion
bsu04/04/14 12:50
Total Hot Plate Digestion
M200.2 ICP-MS scp* 04/07/14 14:48
Total Hot Plate Digestion
M200.2 ICP jjc03/27/14 12:24
REPIN.02.06.05.01 * Please refer to Qualifier Reports for details.
Page 11 of 63L17362-1404111040
ACZ Sample ID: L17362-03
Sample ID: 59766
Sample Matrix: Ground Water
SPF Water Engineering
Project ID: Calico 1st Quarter 2014 Sa
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic Analytical
Results
Date Sampled: 03/18/14 12:40
Date Received: 03/21/14
Parameter EPA Method Result Units MDLQual AnalystDatePQL
Metals Analysis
XQDilution
Aluminum, dissolved M200.7 ICP mg/L 0.2U jjc0.03 03/25/14 10:261
Aluminum, total M200.7 ICP 2.90 mg/L 0.2 jjc0.03* 03/28/14 11:291
Antimony, dissolved M200.8 ICP-MS mg/L 0.002U las0.0004 04/02/14 0:271
Antimony, total M200.8 ICP-MS 0.0006 mg/L 0.002B las0.0004 04/01/14 20:281
Arsenic, dissolved M200.8 ICP-MS 0.1887 mg/L 0.001 las0.0002 04/02/14 0:271
Arsenic, total M200.8 ICP-MS 0.1910 mg/L 0.001 las0.0002 04/01/14 20:281
Barium, dissolved M200.7 ICP 0.014 mg/L 0.02B jjc0.003* 03/25/14 10:261
Barium, total M200.7 ICP 0.057 mg/L 0.02 jjc0.003 03/28/14 11:291
Beryllium, dissolved M200.8 ICP-MS 0.00005 mg/L 0.0003B las0.00005 04/02/14 0:271
Beryllium, total M200.8 ICP-MS 0.00042 mg/L 0.0003 las0.00005 04/01/14 20:281
Bismuth, dissolved M200.7 ICP mg/L 0.2U jjc0.04* 03/25/14 10:261
Bismuth, total M200.7 ICP mg/L 0.2U aeb0.04* 03/28/14 15:231
Boron, dissolved M200.7 ICP 0.12 mg/L 0.05 jjc0.01* 03/25/14 10:261
Boron, total M200.7 ICP 0.14 mg/L 0.05 jjc0.01 03/28/14 11:291
Cadmium, dissolved M200.8 ICP-MS mg/L 0.0005U las0.0001 04/02/14 0:271
Cadmium, total M200.8 ICP-MS 0.0002 mg/L 0.0005B las0.0001 04/01/14 20:281
Calcium, dissolved M200.7 ICP 34.4 mg/L 0.5 jjc0.1 03/25/14 10:261
Calcium, total M200.7 ICP 40.5 mg/L 0.5 jjc0.1 03/28/14 11:291
Chromium, dissolved M200.8 ICP-MS mg/L 0.002U las0.0005 04/02/14 0:271
Chromium, total M200.8 ICP-MS 0.0013 mg/L 0.002B las0.0005 04/01/14 20:281
Cobalt, dissolved M200.8 ICP-MS 0.00086 mg/L 0.0003 las0.00005 04/02/14 0:271
Cobalt, total M200.8 ICP-MS 0.00144 mg/L 0.0003 las0.00005 04/01/14 20:281
Copper, dissolved M200.8 ICP-MS mg/L 0.003U las0.0005 04/02/14 0:271
Copper, total M200.8 ICP-MS 0.0020 mg/L 0.003B las0.0005 04/01/14 20:281
Gallium, dissolved M200.7 ICP mg/L 0.5U jjc0.1* 03/25/14 10:261
Gallium, total M200.7 ICP mg/L 0.5U jjc0.1* 03/28/14 11:291
Iron, dissolved M200.7 ICP 0.89 mg/L 0.05 jjc0.02 03/25/14 10:261
Iron, total M200.7 ICP 3.90 mg/L 0.05 jjc0.02* 03/28/14 11:291
Lead, dissolved M200.8 ICP-MS mg/L 0.0005U las0.0001 04/02/14 0:271
Lead, total M200.8 ICP-MS 0.0024 mg/L 0.0005 las0.0001 04/01/14 20:281
Lithium, dissolved M200.7 ICP 0.477 mg/L 0.04 jjc0.008* 03/25/14 10:261
Lithium, total M200.7 ICP 0.543 mg/L 0.04 jjc0.008 03/28/14 11:291
Magnesium, dissolved M200.7 ICP 2.4 mg/L 1 jjc0.2 03/25/14 10:261
Magnesium, total M200.7 ICP 3.2 mg/L 1 jjc0.2 03/28/14 11:291
Manganese, dissolved M200.8 ICP-MS 0.432 mg/L 0.01 las0.003 04/02/14 16:315
Manganese, total M200.8 ICP-MS 0.490 mg/L 0.01 las0.003 04/02/14 13:395
Mercury, dissolved M1631, Atomic Fluorescence 1 ng/L 0.5 las0.2 04/01/14 16:411
Mercury, total M1631, Atomic Fluorescence 12 ng/L 3 las1 03/31/14 12:375
Molybdenum, dissolved M200.8 ICP-MS 0.0267 mg/L 0.003 las0.0005 04/02/14 0:271
Molybdenum, total M200.8 ICP-MS 0.0266 mg/L 0.003 las0.0005 04/01/14 20:281
Nickel, dissolved M200.8 ICP-MS 0.0035 mg/L 0.003 las0.0006 04/02/14 0:271
Nickel, total M200.8 ICP-MS 0.0049 mg/L 0.003 las0.0006 04/01/14 20:281
Potassium, dissolved M200.7 ICP 8.3 mg/L 1 jjc0.2 03/25/14 10:261
REPIN.02.06.05.01 * Please refer to Qualifier Reports for details.
Page 12 of 63L17362-1404111040
ACZ Sample ID: L17362-03
Sample ID: 59766
Sample Matrix: Ground Water
SPF Water Engineering
Project ID: Calico 1st Quarter 2014 Sa
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic Analytical
Results
Date Sampled: 03/18/14 12:40
Date Received: 03/21/14
Potassium, total M200.7 ICP 10.1 mg/L 1 jjc0.2 03/28/14 11:291
Scandium, dissolved M200.7 ICP mg/L 0.5U jjc0.1* 03/25/14 10:261
Scandium, total M200.7 ICP mg/L 0.5U jjc0.1* 03/28/14 11:291
Selenium, dissolved M200.8 ICP-MS 0.0004 mg/L 0.0003 las0.0001 04/02/14 0:271
Selenium, total M200.8 ICP-MS 0.0005 mg/L 0.0003 las0.0001 04/01/14 20:281
Silver, dissolved M200.8 ICP-MS mg/L 0.0003U las0.00005 04/02/14 0:271
Silver, total M200.8 ICP-MS 0.00006 mg/L 0.0003B las0.00005 04/01/14 20:281
Sodium, dissolved M200.7 ICP 122 mg/L 1 jjc0.2 03/25/14 10:261
Sodium, total M200.7 ICP 138 mg/L 1 jjc0.2 03/28/14 11:291
Strontium, dissolved M200.7 ICP 0.118 mg/L 0.03 jjc0.005 03/25/14 10:261
Strontium, total M200.7 ICP 0.139 mg/L 0.03 jjc0.005 03/28/14 11:291
Thallium, dissolved M200.8 ICP-MS mg/L 0.0005U las0.0001 04/02/14 0:271
Thallium, total M200.8 ICP-MS mg/L 0.0005U las0.0001 04/01/14 20:281
Tin, dissolved M200.8 ICP-MS 0.0001 mg/L 0.0005B las0.0001* 04/02/14 0:271
Tin, total M200.8 ICP-MS 0.0004 mg/L 0.001B msh0.0002* 04/09/14 19:412
Titanium, dissolved M200.7 ICP mg/L 0.03U jjc0.005 03/25/14 10:261
Titanium, total M200.7 ICP 0.112 mg/L 0.03 jjc0.005 03/28/14 11:291
Uranium, dissolved M200.8 ICP-MS 0.0003 mg/L 0.0005B las0.0001 04/02/14 0:271
Uranium, total M200.8 ICP-MS 0.0011 mg/L 0.0005 las0.0001 04/01/14 20:281
Vanadium, dissolved M200.8 ICP-MS 0.0005 mg/L 0.001B las0.0002 04/02/14 0:271
Vanadium, total M200.8 ICP-MS 0.0044 mg/L 0.001 las0.0002 04/01/14 20:281
Zinc, dissolved M200.7 ICP mg/L 0.05U jjc0.01 03/25/14 10:261
Zinc, total M200.7 ICP 0.02 mg/L 0.05B jjc0.01 03/28/14 11:291
REPIN.02.06.05.01 * Please refer to Qualifier Reports for details.
Page 13 of 63L17362-1404111040
ACZ Sample ID: L17362-03
Sample ID: 59766
Sample Matrix: Ground Water
SPF Water Engineering
Project ID: Calico 1st Quarter 2014 Sa
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic Analytical
Results
Date Sampled: 03/18/14 12:40
Date Received: 03/21/14
Parameter EPA Method Result Units MDLQual AnalystDatePQL
Wet Chemistry
XQDilution
Alkalinity as CaCO3 SM2320B - Titration
Bicarbonate as CaCO3
76 mg/L 20 dcw2 03/26/14 0:001
Carbonate as CaCO3 mg/L 20U dcw2 03/26/14 0:001
Hydroxide as CaCO3 mg/L 20U dcw2 03/26/14 0:001
Total Alkalinity 76 mg/L 20 dcw2* 03/26/14 0:001
Chloride M300.0 - Ion Chromatography 12.2 mg/L 2.5 tcd0.5* 03/26/14 20:301
Conductivity @25C SM2510B 893 umhos/cm 10 dcw1 03/26/14 18:021
Cyanide, total M335.4 - Colorimetric w/ distillation mg/L 0.01U mpb0.003* 03/31/14 15:260.5
Cyanide, WAD SM4500-CN I-Colorimetric w/ distillation
mg/L 0.01U mpb0.003* 03/27/14 16:510.5
Fluoride M300.0 - Ion Chromatography 1.65 mg/L 0.5 tcd0.1* 03/26/14 20:301
Hardness as CaCO3 SM2340B - Calculation 96 mg/L 7 calc1 04/11/14 8:14
Nitrate/Nitrite as N M353.2 - H2SO4 preserved 0.06 mg/L 0.1B pjb0.02 03/28/14 22:551
Nitrogen, ammonia M350.1 - Automated Phenate mg/L 0.5U tcd0.05* 03/27/14 16:091
pH (lab) SM4500H+ B
pH 7.7 units 0.1H dcw0.1 03/26/14 0:001
pH measured at 22 C 0.1 dcw0.1 03/26/14 0:001
Phosphorus, total M365.1 - Auto Ascorbic Acid (digest)
0.94 mg/L 0.05 pjb0.01* 04/05/14 13:501
Residue, Filterable (TDS) @180C
SM2540C 650 mg/L 20 id10* 03/25/14 11:311
Residue, Non-Filterable (TSS) @105C
SM2540D 85 mg/L 20 enb5* 03/25/14 12:131
Sulfate M300.0 - Ion Chromatography 305 mg/L 25 tcd5 03/27/14 11:1510
REPIN.02.06.05.01 * Please refer to Qualifier Reports for details.
Page 14 of 63L17362-1404111040
ACZ Sample ID: L17362-04
Sample ID: CYANIDE BLANK
Sample Matrix: Ground Water
SPF Water Engineering
Project ID: Calico 1st Quarter 2014 Sa
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic Analytical
Results
Date Sampled: 03/18/14 00:00
Date Received: 03/21/14
Parameter EPA Method Result Units MDLQual AnalystDatePQL
Inorganic Prep
XQDilution
Cyanide, total M335.4 - Manual Distillation bsu03/28/14 16:10
Cyanide, WAD SM4500-CN I- distillation mpb03/31/14 13:40
Parameter EPA Method Result Units MDLQual AnalystDatePQL
Wet Chemistry
XQDilution
Cyanide, total M335.4 - Colorimetric w/ distillation mg/L 0.01U mpb0.003* 03/31/14 15:270.5
Cyanide, WAD SM4500-CN I-Colorimetric w/ distillation
mg/L 0.01U mpb0.003* 03/31/14 16:090.5
REPIN.02.06.05.01 * Please refer to Qualifier Reports for details.
Page 15 of 63L17362-1404111040
ACZ Sample ID: L17362-05
Sample ID: PW-1
Sample Matrix: Ground Water
SPF Water Engineering
Project ID: Calico 1st Quarter 2014 Sa
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic Analytical
Results
Date Sampled: 03/18/14 14:45
Date Received: 03/21/14
Parameter EPA Method Result Units MDLQual AnalystDatePQL
Inorganic Prep
XQDilution
Cyanide, total M335.4 - Manual Distillation bsu03/28/14 16:18
Cyanide, WAD SM4500-CN I- distillation mpb03/31/14 13:51
Phosphorus, total M365.1 - Auto Ascorbic Acid Digestion
bsu04/04/14 12:57
Total Hot Plate Digestion
M200.2 ICP-MS las03/27/14 12:17
Total Hot Plate Digestion
M200.2 ICP jjc03/27/14 12:59
REPIN.02.06.05.01 * Please refer to Qualifier Reports for details.
Page 16 of 63L17362-1404111040
ACZ Sample ID: L17362-05
Sample ID: PW-1
Sample Matrix: Ground Water
SPF Water Engineering
Project ID: Calico 1st Quarter 2014 Sa
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic Analytical
Results
Date Sampled: 03/18/14 14:45
Date Received: 03/21/14
Parameter EPA Method Result Units MDLQual AnalystDatePQL
Metals Analysis
XQDilution
Aluminum, dissolved M200.7 ICP mg/L 0.2U jjc0.03 03/25/14 10:291
Aluminum, total M200.7 ICP mg/L 0.2U jjc0.03* 03/28/14 11:381
Antimony, dissolved M200.8 ICP-MS mg/L 0.002U las0.0004 04/02/14 0:311
Antimony, total M200.8 ICP-MS mg/L 0.002U las0.0004 04/01/14 20:321
Arsenic, dissolved M200.8 ICP-MS 0.0286 mg/L 0.001 las0.0002 04/02/14 0:311
Arsenic, total M200.8 ICP-MS 0.0282 mg/L 0.001 las0.0002 04/01/14 20:321
Barium, dissolved M200.7 ICP 0.025 mg/L 0.02 jjc0.003* 03/25/14 10:291
Barium, total M200.7 ICP 0.031 mg/L 0.02 jjc0.003 03/28/14 11:381
Beryllium, dissolved M200.8 ICP-MS mg/L 0.0003U las0.00005 04/02/14 0:311
Beryllium, total M200.8 ICP-MS mg/L 0.0003U las0.00005 04/01/14 20:321
Bismuth, dissolved M200.7 ICP mg/L 0.2U jjc0.04* 03/25/14 10:291
Bismuth, total M200.7 ICP mg/L 0.2U aeb0.04* 03/28/14 15:391
Boron, dissolved M200.7 ICP 0.06 mg/L 0.05 jjc0.01* 03/25/14 10:291
Boron, total M200.7 ICP 0.07 mg/L 0.05 jjc0.01 03/28/14 11:381
Cadmium, dissolved M200.8 ICP-MS mg/L 0.0005U las0.0001 04/02/14 0:311
Cadmium, total M200.8 ICP-MS mg/L 0.0005U las0.0001 04/01/14 20:321
Calcium, dissolved M200.7 ICP 26.4 mg/L 0.5 jjc0.1 03/25/14 10:291
Calcium, total M200.7 ICP 30.4 mg/L 0.5 jjc0.1 03/28/14 11:381
Chromium, dissolved M200.8 ICP-MS 0.0006 mg/L 0.002B las0.0005 04/02/14 0:311
Chromium, total M200.8 ICP-MS 0.0007 mg/L 0.002B las0.0005 04/01/14 20:321
Cobalt, dissolved M200.8 ICP-MS 0.00015 mg/L 0.0003B las0.00005 04/02/14 0:311
Cobalt, total M200.8 ICP-MS 0.00008 mg/L 0.0003B las0.00005 04/01/14 20:321
Copper, dissolved M200.8 ICP-MS mg/L 0.003U las0.0005 04/02/14 0:311
Copper, total M200.8 ICP-MS mg/L 0.003U las0.0005 04/01/14 20:321
Gallium, dissolved M200.7 ICP mg/L 0.5U jjc0.1* 03/25/14 10:291
Gallium, total M200.7 ICP mg/L 0.5U jjc0.1* 03/28/14 11:381
Iron, dissolved M200.7 ICP 0.04 mg/L 0.05B jjc0.02 03/25/14 10:291
Iron, total M200.7 ICP 0.16 mg/L 0.05 jjc0.02* 03/28/14 11:381
Lead, dissolved M200.8 ICP-MS mg/L 0.0005U las0.0001 04/02/14 0:311
Lead, total M200.8 ICP-MS mg/L 0.0005U las0.0001 04/01/14 20:321
Lithium, dissolved M200.7 ICP 0.058 mg/L 0.04 jjc0.008* 03/25/14 10:291
Lithium, total M200.7 ICP 0.069 mg/L 0.04 jjc0.008 03/28/14 11:381
Magnesium, dissolved M200.7 ICP 2.8 mg/L 1 jjc0.2 03/25/14 10:291
Magnesium, total M200.7 ICP 3.3 mg/L 1 jjc0.2 03/28/14 11:381
Manganese, dissolved M200.8 ICP-MS 0.0020 mg/L 0.003B las0.0005 04/02/14 0:311
Manganese, total M200.8 ICP-MS 0.0077 mg/L 0.003 las0.0005 04/01/14 20:321
Mercury, dissolved M1631, Atomic Fluorescence ng/L 0.5U las0.2 04/01/14 16:461
Mercury, total M1631, Atomic Fluorescence 0.5 ng/L 0.5 las0.2 03/31/14 13:241
Molybdenum, dissolved M200.8 ICP-MS 0.0044 mg/L 0.003 las0.0005 04/02/14 0:311
Molybdenum, total M200.8 ICP-MS 0.0046 mg/L 0.003 las0.0005 04/01/14 20:321
Nickel, dissolved M200.8 ICP-MS mg/L 0.003U las0.0006 04/02/14 0:311
Nickel, total M200.8 ICP-MS mg/L 0.003U las0.0006 04/01/14 20:321
Potassium, dissolved M200.7 ICP 5.1 mg/L 1 jjc0.2 03/25/14 10:291
REPIN.02.06.05.01 * Please refer to Qualifier Reports for details.
Page 17 of 63L17362-1404111040
ACZ Sample ID: L17362-05
Sample ID: PW-1
Sample Matrix: Ground Water
SPF Water Engineering
Project ID: Calico 1st Quarter 2014 Sa
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic Analytical
Results
Date Sampled: 03/18/14 14:45
Date Received: 03/21/14
Potassium, total M200.7 ICP 5.9 mg/L 1 jjc0.2 03/28/14 11:381
Scandium, dissolved M200.7 ICP mg/L 0.5U jjc0.1* 03/25/14 10:291
Scandium, total M200.7 ICP mg/L 0.5U jjc0.1* 03/28/14 11:381
Selenium, dissolved M200.8 ICP-MS 0.0041 mg/L 0.0003 las0.0001 04/02/14 0:311
Selenium, total M200.8 ICP-MS 0.0040 mg/L 0.0003 las0.0001 04/01/14 20:321
Silver, dissolved M200.8 ICP-MS mg/L 0.0003U las0.00005 04/02/14 0:311
Silver, total M200.8 ICP-MS mg/L 0.0003U las0.00005 04/01/14 20:321
Sodium, dissolved M200.7 ICP 34.6 mg/L 1 jjc0.2 03/25/14 10:291
Sodium, total M200.7 ICP 39 mg/L 1 jjc0.2 03/28/14 11:381
Strontium, dissolved M200.7 ICP 0.109 mg/L 0.03 jjc0.005 03/25/14 10:291
Strontium, total M200.7 ICP 0.121 mg/L 0.03 jjc0.005 03/28/14 11:381
Thallium, dissolved M200.8 ICP-MS mg/L 0.0005U las0.0001 04/02/14 0:311
Thallium, total M200.8 ICP-MS mg/L 0.0005U las0.0001 04/01/14 20:321
Tin, dissolved M200.8 ICP-MS mg/L 0.0005U las0.0001* 04/02/14 0:311
Tin, total M200.8 ICP-MS mg/L 0.0005U las0.0001* 04/01/14 20:321
Titanium, dissolved M200.7 ICP mg/L 0.03U jjc0.005 03/25/14 10:291
Titanium, total M200.7 ICP mg/L 0.03U jjc0.005 03/28/14 11:381
Uranium, dissolved M200.8 ICP-MS 0.0022 mg/L 0.0005 las0.0001 04/02/14 0:311
Uranium, total M200.8 ICP-MS 0.0024 mg/L 0.0005 las0.0001 04/01/14 20:321
Vanadium, dissolved M200.8 ICP-MS 0.0097 mg/L 0.001 las0.0002 04/02/14 0:311
Vanadium, total M200.8 ICP-MS 0.0111 mg/L 0.001 las0.0002 04/01/14 20:321
Zinc, dissolved M200.7 ICP mg/L 0.05U jjc0.01 03/25/14 10:291
Zinc, total M200.7 ICP mg/L 0.05U jjc0.01 03/28/14 11:381
REPIN.02.06.05.01 * Please refer to Qualifier Reports for details.
Page 18 of 63L17362-1404111040
ACZ Sample ID: L17362-05
Sample ID: PW-1
Sample Matrix: Ground Water
SPF Water Engineering
Project ID: Calico 1st Quarter 2014 Sa
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic Analytical
Results
Date Sampled: 03/18/14 14:45
Date Received: 03/21/14
Parameter EPA Method Result Units MDLQual AnalystDatePQL
Wet Chemistry
XQDilution
Alkalinity as CaCO3 SM2320B - Titration
Bicarbonate as CaCO3
110 mg/L 20 dcw2 03/26/14 0:001
Carbonate as CaCO3 mg/L 20U dcw2 03/26/14 0:001
Hydroxide as CaCO3 mg/L 20U dcw2 03/26/14 0:001
Total Alkalinity 110 mg/L 20 dcw2* 03/26/14 0:001
Chloride M300.0 - Ion Chromatography 8.22 mg/L 2.5 tcd0.5* 03/26/14 20:471
Conductivity @25C SM2510B 355 umhos/cm 10 dcw1 03/26/14 18:111
Cyanide, total M335.4 - Colorimetric w/ distillation mg/L 0.01U mpb0.003* 03/31/14 15:280.5
Cyanide, WAD SM4500-CN I-Colorimetric w/ distillation
mg/L 0.01U mpb0.003* 03/31/14 16:100.5
Fluoride M300.0 - Ion Chromatography 0.43 mg/L 0.5B tcd0.1* 03/26/14 20:471
Hardness as CaCO3 SM2340B - Calculation 78 mg/L 7 calc1 04/11/14 8:14
Nitrate/Nitrite as N M353.2 - H2SO4 preserved 0.71 mg/L 0.1 pjb0.02 03/28/14 22:561
Nitrogen, ammonia M350.1 - Automated Phenate mg/L 0.5U tcd0.05* 03/27/14 16:111
pH (lab) SM4500H+ B
pH 8.2 units 0.1H dcw0.1 03/26/14 0:001
pH measured at 22 C 0.1 dcw0.1 03/26/14 0:001
Phosphorus, total M365.1 - Auto Ascorbic Acid (digest)
0.02 mg/L 0.05B pjb0.01* 04/05/14 13:511
Residue, Filterable (TDS) @180C
SM2540C 250 mg/L 20 id10* 03/25/14 11:331
Residue, Non-Filterable (TSS) @105C
SM2540D mg/L 20U enb5* 03/25/14 12:151
Sulfate M300.0 - Ion Chromatography 31.3 mg/L 2.5 tcd0.5 03/26/14 20:471
REPIN.02.06.05.01 * Please refer to Qualifier Reports for details.
Page 19 of 63L17362-1404111040
ACZ Sample ID: L17362-06
Sample ID: GW-1
Sample Matrix: Ground Water
SPF Water Engineering
Project ID: Calico 1st Quarter 2014 Sa
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic Analytical
Results
Date Sampled: 03/18/14 15:20
Date Received: 03/21/14
Parameter EPA Method Result Units MDLQual AnalystDatePQL
Inorganic Prep
XQDilution
Cyanide, total M335.4 - Manual Distillation bsu03/28/14 16:26
Cyanide, WAD SM4500-CN I- distillation mpb03/31/14 14:02
Phosphorus, total M365.1 - Auto Ascorbic Acid Digestion
bsu04/04/14 13:04
Total Hot Plate Digestion
M200.2 ICP-MS las03/27/14 12:27
Total Hot Plate Digestion
M200.2 ICP jjc03/27/14 13:10
REPIN.02.06.05.01 * Please refer to Qualifier Reports for details.
Page 20 of 63L17362-1404111040
ACZ Sample ID: L17362-06
Sample ID: GW-1
Sample Matrix: Ground Water
SPF Water Engineering
Project ID: Calico 1st Quarter 2014 Sa
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic Analytical
Results
Date Sampled: 03/18/14 15:20
Date Received: 03/21/14
Parameter EPA Method Result Units MDLQual AnalystDatePQL
Metals Analysis
XQDilution
Aluminum, dissolved M200.7 ICP mg/L 0.2U jjc0.03 03/25/14 10:321
Aluminum, total M200.7 ICP mg/L 0.2U jjc0.03* 03/28/14 11:421
Antimony, dissolved M200.8 ICP-MS 0.0004 mg/L 0.002B las0.0004 04/02/14 0:341
Antimony, total M200.8 ICP-MS 0.0004 mg/L 0.002B las0.0004 04/01/14 20:421
Arsenic, dissolved M200.8 ICP-MS 0.0294 mg/L 0.001 las0.0002 04/02/14 0:341
Arsenic, total M200.8 ICP-MS 0.0283 mg/L 0.001 las0.0002 04/01/14 20:421
Barium, dissolved M200.7 ICP 0.025 mg/L 0.02 jjc0.003* 03/25/14 10:321
Barium, total M200.7 ICP 0.031 mg/L 0.02 jjc0.003 03/28/14 11:421
Beryllium, dissolved M200.8 ICP-MS mg/L 0.0003U las0.00005 04/02/14 0:341
Beryllium, total M200.8 ICP-MS mg/L 0.0003U las0.00005 04/01/14 20:421
Bismuth, dissolved M200.7 ICP mg/L 0.2U jjc0.04* 03/25/14 10:321
Bismuth, total M200.7 ICP mg/L 0.2U aeb0.04* 03/28/14 15:421
Boron, dissolved M200.7 ICP 0.06 mg/L 0.05 jjc0.01 03/25/14 10:321
Boron, total M200.7 ICP 0.07 mg/L 0.05 jjc0.01 03/28/14 11:421
Cadmium, dissolved M200.8 ICP-MS mg/L 0.0005U las0.0001 04/02/14 0:341
Cadmium, total M200.8 ICP-MS mg/L 0.0005U las0.0001 04/01/14 20:421
Calcium, dissolved M200.7 ICP 39.6 mg/L 0.5 jjc0.1 03/25/14 10:321
Calcium, total M200.7 ICP 47.2 mg/L 0.5 jjc0.1 03/28/14 11:421
Chromium, dissolved M200.8 ICP-MS 0.0007 mg/L 0.002B las0.0005 04/02/14 0:341
Chromium, total M200.8 ICP-MS 0.0007 mg/L 0.002B las0.0005 04/01/14 20:421
Cobalt, dissolved M200.8 ICP-MS 0.00019 mg/L 0.0003B las0.00005 04/02/14 0:341
Cobalt, total M200.8 ICP-MS 0.00021 mg/L 0.0003B las0.00005 04/01/14 20:421
Copper, dissolved M200.8 ICP-MS mg/L 0.003U las0.0005 04/02/14 0:341
Copper, total M200.8 ICP-MS mg/L 0.003U las0.0005 04/01/14 20:421
Gallium, dissolved M200.7 ICP mg/L 0.5U jjc0.1* 03/25/14 10:321
Gallium, total M200.7 ICP mg/L 0.5U jjc0.1* 03/28/14 11:421
Iron, dissolved M200.7 ICP mg/L 0.05U jjc0.02 03/25/14 10:321
Iron, total M200.7 ICP mg/L 0.05U jjc0.02* 03/28/14 11:421
Lead, dissolved M200.8 ICP-MS mg/L 0.0005U las0.0001 04/02/14 0:341
Lead, total M200.8 ICP-MS mg/L 0.0005U las0.0001 04/01/14 20:421
Lithium, dissolved M200.7 ICP 0.040 mg/L 0.04 jjc0.008* 03/25/14 10:321
Lithium, total M200.7 ICP 0.048 mg/L 0.04 jjc0.008 03/28/14 11:421
Magnesium, dissolved M200.7 ICP 7.2 mg/L 1 jjc0.2 03/25/14 10:321
Magnesium, total M200.7 ICP 8.8 mg/L 1 jjc0.2 03/28/14 11:421
Manganese, dissolved M200.8 ICP-MS mg/L 0.003U las0.0005 04/02/14 0:341
Manganese, total M200.8 ICP-MS 0.0010 mg/L 0.003B las0.0005 04/01/14 20:421
Mercury, dissolved M1631, Atomic Fluorescence 0.3 ng/L 0.5B las0.2 04/01/14 16:511
Mercury, total M1631, Atomic Fluorescence 0.8 ng/L 0.5 las0.2 03/31/14 13:291
Molybdenum, dissolved M200.8 ICP-MS 0.0039 mg/L 0.003 las0.0005 04/02/14 0:341
Molybdenum, total M200.8 ICP-MS 0.0040 mg/L 0.003 las0.0005 04/01/14 20:421
Nickel, dissolved M200.8 ICP-MS mg/L 0.003U las0.0006 04/02/14 0:341
Nickel, total M200.8 ICP-MS mg/L 0.003U las0.0006 04/01/14 20:421
Potassium, dissolved M200.7 ICP 5.2 mg/L 1 jjc0.2 03/25/14 10:321
REPIN.02.06.05.01 * Please refer to Qualifier Reports for details.
Page 21 of 63L17362-1404111040
ACZ Sample ID: L17362-06
Sample ID: GW-1
Sample Matrix: Ground Water
SPF Water Engineering
Project ID: Calico 1st Quarter 2014 Sa
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic Analytical
Results
Date Sampled: 03/18/14 15:20
Date Received: 03/21/14
Potassium, total M200.7 ICP 6.1 mg/L 1 jjc0.2 03/28/14 11:421
Scandium, dissolved M200.7 ICP mg/L 0.5U jjc0.1* 03/25/14 10:321
Scandium, total M200.7 ICP mg/L 0.5U jjc0.1* 03/28/14 11:421
Selenium, dissolved M200.8 ICP-MS 0.0032 mg/L 0.0003 las0.0001 04/02/14 0:341
Selenium, total M200.8 ICP-MS 0.0033 mg/L 0.0003 las0.0001 04/01/14 20:421
Silver, dissolved M200.8 ICP-MS mg/L 0.0003U las0.00005 04/02/14 0:341
Silver, total M200.8 ICP-MS mg/L 0.0003U las0.00005 04/01/14 20:421
Sodium, dissolved M200.7 ICP 23.3 mg/L 1 jjc0.2 03/25/14 10:321
Sodium, total M200.7 ICP 27 mg/L 1 jjc0.2 03/28/14 11:421
Strontium, dissolved M200.7 ICP 0.188 mg/L 0.03 jjc0.005 03/25/14 10:321
Strontium, total M200.7 ICP 0.214 mg/L 0.03 jjc0.005 03/28/14 11:421
Thallium, dissolved M200.8 ICP-MS mg/L 0.0005U las0.0001 04/02/14 0:341
Thallium, total M200.8 ICP-MS mg/L 0.0005U las0.0001 04/01/14 20:421
Tin, dissolved M200.8 ICP-MS mg/L 0.0005U las0.0001* 04/02/14 0:341
Tin, total M200.8 ICP-MS mg/L 0.0005U las0.0001* 04/01/14 20:421
Titanium, dissolved M200.7 ICP mg/L 0.03U jjc0.005 03/25/14 10:321
Titanium, total M200.7 ICP mg/L 0.03U jjc0.005 03/28/14 11:421
Uranium, dissolved M200.8 ICP-MS 0.0035 mg/L 0.0005 las0.0001 04/02/14 0:341
Uranium, total M200.8 ICP-MS 0.0036 mg/L 0.0005 las0.0001 04/01/14 20:421
Vanadium, dissolved M200.8 ICP-MS 0.0176 mg/L 0.001 las0.0002 04/02/14 0:341
Vanadium, total M200.8 ICP-MS 0.0188 mg/L 0.001 las0.0002 04/01/14 20:421
Zinc, dissolved M200.7 ICP mg/L 0.05U jjc0.01 03/25/14 10:321
Zinc, total M200.7 ICP mg/L 0.05U jjc0.01 03/28/14 11:421
REPIN.02.06.05.01 * Please refer to Qualifier Reports for details.
Page 22 of 63L17362-1404111040
ACZ Sample ID: L17362-06
Sample ID: GW-1
Sample Matrix: Ground Water
SPF Water Engineering
Project ID: Calico 1st Quarter 2014 Sa
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic Analytical
Results
Date Sampled: 03/18/14 15:20
Date Received: 03/21/14
Parameter EPA Method Result Units MDLQual AnalystDatePQL
Wet Chemistry
XQDilution
Alkalinity as CaCO3 SM2320B - Titration
Bicarbonate as CaCO3
126 mg/L 20 dcw2 03/26/14 0:001
Carbonate as CaCO3 mg/L 20U dcw2 03/26/14 0:001
Hydroxide as CaCO3 mg/L 20U dcw2 03/26/14 0:001
Total Alkalinity 126 mg/L 20 dcw2* 03/26/14 0:001
Chloride M300.0 - Ion Chromatography 11.8 mg/L 2.5 tcd0.5* 03/26/14 21:051
Conductivity @25C SM2510B 419 umhos/cm 10 dcw1 03/26/14 18:201
Cyanide, total M335.4 - Colorimetric w/ distillation mg/L 0.01U mpb0.003* 03/31/14 15:290.5
Cyanide, WAD SM4500-CN I-Colorimetric w/ distillation
mg/L 0.01U mpb0.003* 03/31/14 16:120.5
Fluoride M300.0 - Ion Chromatography 0.45 mg/L 0.5B tcd0.1* 03/26/14 21:051
Hardness as CaCO3 SM2340B - Calculation 129 mg/L 7 calc1 04/11/14 8:15
Nitrate/Nitrite as N M353.2 - H2SO4 preserved 2.44 mg/L 0.1 pjb0.02 03/28/14 22:571
Nitrogen, ammonia M350.1 - Automated Phenate mg/L 0.5U tcd0.05* 03/27/14 16:121
pH (lab) SM4500H+ B
pH 8.1 units 0.1H dcw0.1 03/26/14 0:001
pH measured at 22 C 0.1 dcw0.1 03/26/14 0:001
Phosphorus, total M365.1 - Auto Ascorbic Acid (digest)
0.02 mg/L 0.05B pjb0.01* 04/05/14 13:521
Residue, Filterable (TDS) @180C
SM2540C 290 mg/L 20 id10* 03/25/14 11:351
Residue, Non-Filterable (TSS) @105C
SM2540D mg/L 20U enb5* 03/25/14 12:171
Sulfate M300.0 - Ion Chromatography 34.0 mg/L 2.5 tcd0.5 03/26/14 21:051
REPIN.02.06.05.01 * Please refer to Qualifier Reports for details.
Page 23 of 63L17362-1404111040
ACZ Sample ID: L17362-07
Sample ID: 59761
Sample Matrix: Ground Water
SPF Water Engineering
Project ID: Calico 1st Quarter 2014 Sa
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic Analytical
Results
Date Sampled: 03/18/14 16:30
Date Received: 03/21/14
Parameter EPA Method Result Units MDLQual AnalystDatePQL
Inorganic Prep
XQDilution
Cyanide, total M335.4 - Manual Distillation bsu03/28/14 16:34
Cyanide, WAD SM4500-CN I- distillation mpb03/31/14 14:07
Phosphorus, total M365.1 - Auto Ascorbic Acid Digestion
bsu04/04/14 13:12
Total Hot Plate Digestion
M200.2 ICP-MS las03/27/14 12:37
Total Hot Plate Digestion
M200.2 ICP jjc03/27/14 13:22
REPIN.02.06.05.01 * Please refer to Qualifier Reports for details.
Page 24 of 63L17362-1404111040
ACZ Sample ID: L17362-07
Sample ID: 59761
Sample Matrix: Ground Water
SPF Water Engineering
Project ID: Calico 1st Quarter 2014 Sa
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic Analytical
Results
Date Sampled: 03/18/14 16:30
Date Received: 03/21/14
Parameter EPA Method Result Units MDLQual AnalystDatePQL
Metals Analysis
XQDilution
Aluminum, dissolved M200.7 ICP mg/L 0.2U jjc0.03 03/25/14 10:421
Aluminum, total M200.7 ICP mg/L 0.2U jjc0.03* 03/28/14 11:511
Antimony, dissolved M200.8 ICP-MS mg/L 0.002U las0.0004 04/02/14 0:371
Antimony, total M200.8 ICP-MS mg/L 0.002U las0.0004 04/01/14 20:451
Arsenic, dissolved M200.8 ICP-MS 0.0227 mg/L 0.001 las0.0002 04/02/14 0:371
Arsenic, total M200.8 ICP-MS 0.0219 mg/L 0.001 las0.0002 04/01/14 20:451
Barium, dissolved M200.7 ICP 0.037 mg/L 0.02 jjc0.003* 03/25/14 10:421
Barium, total M200.7 ICP 0.045 mg/L 0.02 jjc0.003 03/28/14 11:511
Beryllium, dissolved M200.8 ICP-MS mg/L 0.0003U las0.00005 04/02/14 0:371
Beryllium, total M200.8 ICP-MS mg/L 0.0003U las0.00005 04/01/14 20:451
Bismuth, dissolved M200.7 ICP mg/L 0.2U jjc0.04* 03/25/14 10:421
Bismuth, total M200.7 ICP mg/L 0.2U aeb0.04* 03/28/14 15:451
Boron, dissolved M200.7 ICP 0.06 mg/L 0.05 jjc0.01 03/25/14 10:421
Boron, total M200.7 ICP 0.07 mg/L 0.05 jjc0.01 03/28/14 11:511
Cadmium, dissolved M200.8 ICP-MS mg/L 0.0005U las0.0001 04/02/14 0:371
Cadmium, total M200.8 ICP-MS mg/L 0.0005U las0.0001 04/01/14 20:451
Calcium, dissolved M200.7 ICP 37.4 mg/L 0.5 jjc0.1 03/25/14 10:421
Calcium, total M200.7 ICP 43.6 mg/L 0.5 jjc0.1 03/28/14 11:511
Chromium, dissolved M200.8 ICP-MS 0.0009 mg/L 0.002B las0.0005 04/02/14 0:371
Chromium, total M200.8 ICP-MS 0.0011 mg/L 0.002B las0.0005 04/01/14 20:451
Cobalt, dissolved M200.8 ICP-MS 0.00017 mg/L 0.0003B las0.00005 04/02/14 0:371
Cobalt, total M200.8 ICP-MS 0.00011 mg/L 0.0003B las0.00005 04/01/14 20:451
Copper, dissolved M200.8 ICP-MS mg/L 0.003U las0.0005 04/02/14 0:371
Copper, total M200.8 ICP-MS mg/L 0.003U las0.0005 04/01/14 20:451
Gallium, dissolved M200.7 ICP mg/L 0.5U jjc0.1* 03/25/14 10:421
Gallium, total M200.7 ICP mg/L 0.5U jjc0.1* 03/28/14 11:511
Iron, dissolved M200.7 ICP mg/L 0.05U jjc0.02 03/25/14 10:421
Iron, total M200.7 ICP mg/L 0.05U jjc0.02* 03/28/14 11:511
Lead, dissolved M200.8 ICP-MS mg/L 0.0005U las0.0001 04/02/14 0:371
Lead, total M200.8 ICP-MS mg/L 0.0005U las0.0001 04/01/14 20:451
Lithium, dissolved M200.7 ICP 0.030 mg/L 0.04B jjc0.008* 03/25/14 10:421
Lithium, total M200.7 ICP 0.037 mg/L 0.04B jjc0.008 03/28/14 11:511
Magnesium, dissolved M200.7 ICP 8.6 mg/L 1 jjc0.2 03/25/14 10:421
Magnesium, total M200.7 ICP 10.4 mg/L 1 jjc0.2 03/28/14 11:511
Manganese, dissolved M200.8 ICP-MS mg/L 0.003U las0.0005 04/02/14 0:371
Manganese, total M200.8 ICP-MS mg/L 0.003U las0.0005 04/01/14 20:451
Mercury, dissolved M1631, Atomic Fluorescence 0.2 ng/L 0.5B las0.2 04/01/14 16:561
Mercury, total M1631, Atomic Fluorescence 0.6 ng/L 0.5 las0.2 03/31/14 13:341
Molybdenum, dissolved M200.8 ICP-MS 0.0026 mg/L 0.003B las0.0005 04/02/14 0:371
Molybdenum, total M200.8 ICP-MS 0.0026 mg/L 0.003B las0.0005 04/01/14 20:451
Nickel, dissolved M200.8 ICP-MS mg/L 0.003U las0.0006 04/02/14 0:371
Nickel, total M200.8 ICP-MS mg/L 0.003U las0.0006 04/01/14 20:451
Potassium, dissolved M200.7 ICP 5.1 mg/L 1 jjc0.2 03/25/14 10:421
REPIN.02.06.05.01 * Please refer to Qualifier Reports for details.
Page 25 of 63L17362-1404111040
ACZ Sample ID: L17362-07
Sample ID: 59761
Sample Matrix: Ground Water
SPF Water Engineering
Project ID: Calico 1st Quarter 2014 Sa
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic Analytical
Results
Date Sampled: 03/18/14 16:30
Date Received: 03/21/14
Potassium, total M200.7 ICP 5.9 mg/L 1 jjc0.2 03/28/14 11:511
Scandium, dissolved M200.7 ICP mg/L 0.5U jjc0.1* 03/25/14 10:421
Scandium, total M200.7 ICP mg/L 0.5U jjc0.1* 03/28/14 11:511
Selenium, dissolved M200.8 ICP-MS 0.0015 mg/L 0.0003 las0.0001 04/02/14 0:371
Selenium, total M200.8 ICP-MS 0.0014 mg/L 0.0003 las0.0001 04/01/14 20:451
Silver, dissolved M200.8 ICP-MS mg/L 0.0003U las0.00005 04/02/14 0:371
Silver, total M200.8 ICP-MS mg/L 0.0003U las0.00005 04/01/14 20:451
Sodium, dissolved M200.7 ICP 21 mg/L 1 jjc0.2 03/25/14 10:421
Sodium, total M200.7 ICP 24.2 mg/L 1 jjc0.2 03/28/14 11:511
Strontium, dissolved M200.7 ICP 0.201 mg/L 0.03 jjc0.005 03/25/14 10:421
Strontium, total M200.7 ICP 0.227 mg/L 0.03 jjc0.005 03/28/14 11:511
Thallium, dissolved M200.8 ICP-MS mg/L 0.0005U las0.0001 04/02/14 0:371
Thallium, total M200.8 ICP-MS mg/L 0.0005U las0.0001 04/01/14 20:451
Tin, dissolved M200.8 ICP-MS mg/L 0.0005U las0.0001* 04/02/14 0:371
Tin, total M200.8 ICP-MS mg/L 0.0005U las0.0001* 04/01/14 20:451
Titanium, dissolved M200.7 ICP mg/L 0.03U jjc0.005 03/25/14 10:421
Titanium, total M200.7 ICP mg/L 0.03U jjc0.005 03/28/14 11:511
Uranium, dissolved M200.8 ICP-MS 0.0027 mg/L 0.0005 las0.0001 04/02/14 0:371
Uranium, total M200.8 ICP-MS 0.0029 mg/L 0.0005 las0.0001 04/01/14 20:451
Vanadium, dissolved M200.8 ICP-MS 0.0195 mg/L 0.001 las0.0002 04/02/14 0:371
Vanadium, total M200.8 ICP-MS 0.0207 mg/L 0.001 las0.0002 04/01/14 20:451
Zinc, dissolved M200.7 ICP mg/L 0.05U jjc0.01 03/25/14 10:421
Zinc, total M200.7 ICP mg/L 0.05U jjc0.01 03/28/14 11:511
REPIN.02.06.05.01 * Please refer to Qualifier Reports for details.
Page 26 of 63L17362-1404111040
ACZ Sample ID: L17362-07
Sample ID: 59761
Sample Matrix: Ground Water
SPF Water Engineering
Project ID: Calico 1st Quarter 2014 Sa
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic Analytical
Results
Date Sampled: 03/18/14 16:30
Date Received: 03/21/14
Parameter EPA Method Result Units MDLQual AnalystDatePQL
Wet Chemistry
XQDilution
Alkalinity as CaCO3 SM2320B - Titration
Bicarbonate as CaCO3
128 mg/L 20 dcw2 03/26/14 0:001
Carbonate as CaCO3 mg/L 20U dcw2 03/26/14 0:001
Hydroxide as CaCO3 mg/L 20U dcw2 03/26/14 0:001
Total Alkalinity 128 mg/L 20 dcw2* 03/26/14 0:001
Chloride M300.0 - Ion Chromatography 13.6 mg/L 2.5 tcd0.5* 03/26/14 21:231
Conductivity @25C SM2510B 410 umhos/cm 10 dcw1 03/26/14 18:291
Cyanide, total M335.4 - Colorimetric w/ distillation mg/L 0.01U mpb0.003* 03/31/14 15:290.5
Cyanide, WAD SM4500-CN I-Colorimetric w/ distillation
mg/L 0.01U mpb0.003* 03/31/14 16:130.5
Fluoride M300.0 - Ion Chromatography 0.52 mg/L 0.5 tcd0.1* 03/26/14 21:231
Hardness as CaCO3 SM2340B - Calculation 129 mg/L 7 calc1 04/11/14 8:15
Nitrate/Nitrite as N M353.2 - H2SO4 preserved 1.92 mg/L 0.1 pjb0.02 03/28/14 22:591
Nitrogen, ammonia M350.1 - Automated Phenate mg/L 0.5U tcd0.05* 03/27/14 16:491
pH (lab) SM4500H+ B
pH 8.1 units 0.1H dcw0.1 03/26/14 0:001
pH measured at 22 C 0.1 dcw0.1 03/26/14 0:001
Phosphorus, total M365.1 - Auto Ascorbic Acid (digest)
0.02 mg/L 0.05B pjb0.01* 04/05/14 13:551
Residue, Filterable (TDS) @180C
SM2540C 280 mg/L 20 id10* 03/25/14 11:371
Residue, Non-Filterable (TSS) @105C
SM2540D mg/L 20U enb5* 03/25/14 12:201
Sulfate M300.0 - Ion Chromatography 27.6 mg/L 2.5 tcd0.5 03/26/14 21:231
REPIN.02.06.05.01 * Please refer to Qualifier Reports for details.
Page 27 of 63L17362-1404111040
ACZ Sample ID: L17362-08
Sample ID: CYANIDE BLANK
Sample Matrix: Ground Water
SPF Water Engineering
Project ID: Calico 1st Quarter 2014 Sa
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic Analytical
Results
Date Sampled: 03/18/14 00:00
Date Received: 03/21/14
Parameter EPA Method Result Units MDLQual AnalystDatePQL
Inorganic Prep
XQDilution
Cyanide, total M335.4 - Manual Distillation bsu03/28/14 16:49
Cyanide, WAD SM4500-CN I- distillation mpb03/31/14 14:13
Parameter EPA Method Result Units MDLQual AnalystDatePQL
Wet Chemistry
XQDilution
Cyanide, total M335.4 - Colorimetric w/ distillation mg/L 0.01U mpb0.003* 03/31/14 15:310.5
Cyanide, WAD SM4500-CN I-Colorimetric w/ distillation
mg/L 0.01U mpb0.003* 03/31/14 16:140.5
REPIN.02.06.05.01 * Please refer to Qualifier Reports for details.
Page 28 of 63L17362-1404111040
ACZ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Report Header Explanations
Batch A distinct set of samples analyzed at a specific time
Found Value of the QC Type of interest
Limit Upper limit for RPD, in %.
Lower Lower Recovery Limit, in % (except for LCSS, mg/Kg)
MDL Method Detection Limit. Same as Minimum Reporting Limit. Allows for instrument and annual fluctuations.
PCN/SCN A number assigned to reagents/standards to trace to the manufacturer's certificate of analysis
PQL Practical Quantitation Limit, typically 5 times the MDL.
QC True Value of the Control Sample or the amount added to the Spike
Rec Recovered amount of the true value or spike added, in % (except for LCSS, mg/Kg)
RPD Relative Percent Difference, calculation used for Duplicate QC Types
Upper Upper Recovery Limit, in % (except for LCSS, mg/Kg)
Sample Value of the Sample of interest
QC Sample Types
AS Analytical Spike (Post Digestion) LCSWD Laboratory Control Sample - Water Duplicate
ASD Analytical Spike (Post Digestion) Duplicate LFB Laboratory Fortified Blank
CCB Continuing Calibration Blank LFM Laboratory Fortified Matrix
CCV Continuing Calibration Verification standard LFMD Laboratory Fortified Matrix Duplicate
DUP Sample Duplicate LRB Laboratory Reagent Blank
ICB Initial Calibration Blank MS Matrix Spike
ICV Initial Calibration Verification standard MSD Matrix Spike Duplicate
ICSAB Inter-element Correction Standard - A plus B solutions PBS Prep Blank - Soil
LCSS Laboratory Control Sample - Soil PBW Prep Blank - Water
LCSSD Laboratory Control Sample - Soil Duplicate PQV Practical Quantitation Verification standard
LCSW Laboratory Control Sample - Water SDL Serial Dilution
QC Sample Type Explanations
Blanks Verifies that there is no or minimal contamination in the prep method or calibration procedure.
Control Samples Verifies the accuracy of the method, including the prep procedure.
Duplicates Verifies the precision of the instrument and/or method.
Spikes/Fortified Matrix Determines sample matrix interferences, if any.
Standard Verifies the validity of the calibration.
ACZ Qualifiers (Qual)
B Analyte concentration detected at a value between MDL and PQL. The associated value is an estimated quantity.
H Analysis exceeded method hold time. pH is a field test with an immediate hold time.
L Target analyte response was below the laboratory defined negative threshold.
U The material was analyzed for, but was not detected above the level of the associated value.
The associated value is either the sample quantitation limit or the sample detection limit.
Method References
(1) EPA 600/4-83-020. Methods for Chemical Analysis of Water and Wastes, March 1983.
(2) EPA 600/R-93-100. Methods for the Determination of Inorganic Substances in Environmental Samples, August 1993.
(3) EPA 600/R-94-111. Methods for the Determination of Metals in Environmental Samples - Supplement I, May 1994.
(4) EPA SW-846. Test Methods for Evaluating Solid Waste.
(5) Standard Methods for the Examination of Water and Wastewater.
Comments
(1) QC results calculated from raw data. Results may vary slightly if the rounded values are used in the calculations.
(2) Soil, Sludge, and Plant matrices for Inorganic analyses are reported on a dry weight basis.
(3) Animal matrices for Inorganic analyses are reported on an "as received" basis.
(4) An asterisk in the "XQ" column indicates there is an extended qualifier and/or certification qualifier
associated with the result.
(5) If the MDL equals the PQL or the MDL column is omitted, the PQL is the reporting limit.
For a complete list of ACZ's Extended Qualifiers, please click: http://www.acz.com/public/extquallist.pdf
REP001.09.12.01
Inorganic
Reference
Page 29 of 63L17362-1404111040
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic QC
Summary
ACZ Project ID: L17362SPF Water Engineering
Alkalinity as CaCO3 SM2320B - Titration
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361281
WG361281PBW1 03/26/14 16:40PBW U -20 20mg/L
WG361281LCSW3 03/26/14 16:59 101.6LCSW WC140313- 833.3 90 110mg/L820.0001
L17364-01DUP1 RA03/26/14 18:38 UDUP U 0mg/L 20
WG361281LCSW6 03/26/14 19:51 102.2LCSW WC140313- 838.3 90 110mg/L820.0001
WG361281PBW2 03/26/14 20:01PBW 2.5 -20 20mg/L
WG361281LCSW9 03/26/14 23:25 102.9LCSW WC140313- 843.4 90 110mg/L820.0001
WG361281PBW3 03/26/14 23:35PBW 2.6 -20 20mg/L
WG361281LCSW12 03/27/14 2:25 101.8LCSW WC140313- 834.8 90 110mg/L820.0001
WG361281PBW4 03/27/14 2:35PBW 2.9 -20 20mg/L
WG361281LCSW15 03/27/14 5:33 103.3LCSW WC140313- 847.2 90 110mg/L820.0001
Aluminum, dissolved M200.7 ICP
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361133
WG361133ICV 03/25/14 9:27 98.4ICV II140220-1 1.968 95 105mg/L2
WG361133ICB 03/25/14 9:33ICB U -0.09 0.09mg/L
WG361133LFB 03/25/14 9:46 92.2LFB II140317-2 .923 85 115mg/L1.0011
L17312-02AS 03/25/14 9:55 U 91.8AS II140317-2 .919 85 115mg/L1.0011
L17312-02ASD 03/25/14 9:58 U 91.8ASD II140317-2 .919 085 115mg/L 201.0011
L17362-06AS 03/25/14 10:36 U 90.3AS II140317-2 .904 85 115mg/L1.0011
L17362-06ASD 03/25/14 10:39 U 90.1ASD II140317-2 .902 0.2285 115mg/L 201.0011
Aluminum, total M200.7 ICP
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361367
WG361367ICV 03/28/14 10:16 96.7ICV II140228-1 1.934 95 105mg/L2
WG361367ICB 03/28/14 10:22ICB U -0.09 0.09mg/L
WG361311LRB 03/28/14 10:35LRB U -0.066 0.066mg/L
WG361311LFB 03/28/14 10:38 102.9LFB II140317-2 1.03 85 115mg/L1.0011
L17343-01LFM 03/28/14 10:57 U 107.5LFM II140317-2 1.076 70 130mg/L1.0011
L17343-01LFMD 03/28/14 11:00 U 106.1LFMD II140317-2 1.062 1.3170 130mg/L 201.0011
L17362-03LFM M103/28/14 11:32 2.9 552.4LFM II140317-2 8.43 70 130mg/L1.0011
L17362-03LFMD M103/28/14 11:35 2.9 542.3LFMD II140317-2 8.329 1.2170 130mg/L 201.0011
Antimony, dissolved M200.8 ICP-MS
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361610
WG361610ICV 04/02/14 0:03 106.3ICV MS140331-9 .02129 90 110mg/L.02002
WG361610ICB 04/02/14 0:07ICB U -0.0012 0.0012mg/L
WG361610LFB 04/02/14 0:10 97.6LFB MS140331-2 .00976 85 115mg/L.01
L17362-01AS 04/02/14 0:17 U 99.6AS MS140331-2 .00996 70 130mg/L.01
L17362-01ASD 04/02/14 0:20 U 101.6ASD MS140331-2 .01016 1.9970 130mg/L 20.01
Page 30 of 63L17362-1404111040
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic QC
Summary
ACZ Project ID: L17362SPF Water Engineering
Antimony, total M200.8 ICP-MS
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361587
WG361587ICV 04/01/14 19:17 100.2ICV MS140331-9 .02006 90 110mg/L.02002
WG361587ICB 04/01/14 19:20ICB U -0.0012 0.0012mg/L
WG361306LRB 04/01/14 19:24LRB U -0.00088 0.00088mg/L
WG361306LFB 04/01/14 19:27 104.1LFB MS140320-2 .01041 85 115mg/L.01
L17362-07LFM 04/01/14 20:49 U 102.6LFM MS140320-2 .01026 70 130mg/L.01
L17362-07LFMD 04/01/14 20:52 U 103.4LFMD MS140320-2 .01034 0.7870 130mg/L 20.01
Arsenic, dissolved M200.8 ICP-MS
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361610
WG361610ICV 04/02/14 0:03 104.6ICV MS140331-9 .05228 90 110mg/L.05
WG361610ICB 04/02/14 0:07ICB U -0.0006 0.0006mg/L
WG361610LFB 04/02/14 0:10 95.7LFB MS140331-2 .04797 85 115mg/L.0501
L17362-01AS 04/02/14 0:17 .0127 102.1AS MS140331-2 .06383 70 130mg/L.0501
L17362-01ASD 04/02/14 0:20 .0127 100.6ASD MS140331-2 .06308 1.1870 130mg/L 20.0501
Arsenic, total M200.8 ICP-MS
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361587
WG361587ICV 04/01/14 19:17 101ICV MS140331-9 .05051 90 110mg/L.05
WG361587ICB 04/01/14 19:20ICB U -0.0006 0.0006mg/L
WG361306LRB 04/01/14 19:24LRB U -0.00044 0.00044mg/L
WG361306LFB 04/01/14 19:27 103.7LFB MS140320-2 .05193 85 115mg/L.0501
L17362-07LFM 04/01/14 20:49 .0219 99.6LFM MS140320-2 .07178 70 130mg/L.0501
L17362-07LFMD 04/01/14 20:52 .0219 100.3LFMD MS140320-2 .07214 0.570 130mg/L 20.0501
Barium, dissolved M200.7 ICP
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361133
WG361133ICV 03/25/14 9:27 96.8ICV II140220-1 1.9352 95 105mg/L2
WG361133ICB 03/25/14 9:33ICB U -0.009 0.009mg/L
WG361133LFB 03/25/14 9:46 87.1LFB II140317-2 .4355 85 115mg/L.5
L17312-02AS M203/25/14 9:55 .04 84.5AS II140317-2 .4624 85 115mg/L.5
L17312-02ASD M203/25/14 9:58 .04 83.9ASD II140317-2 .4594 0.6585 115mg/L 20.5
L17362-06AS M203/25/14 10:36 .025 83AS II140317-2 .4401 85 115mg/L.5
L17362-06ASD M203/25/14 10:39 .025 82.9ASD II140317-2 .4394 0.1685 115mg/L 20.5
Page 31 of 63L17362-1404111040
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic QC
Summary
ACZ Project ID: L17362SPF Water Engineering
Barium, total M200.7 ICP
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361367
WG361367ICV 03/28/14 10:16 96.4ICV II140228-1 1.9285 95 105mg/L2
WG361367ICB 03/28/14 10:22ICB U -0.009 0.009mg/L
WG361311LRB 03/28/14 10:35LRB U -0.0066 0.0066mg/L
WG361311LFB 03/28/14 10:38 98LFB II140317-2 .49 85 115mg/L.5
L17343-01LFM 03/28/14 10:57 .021 99LFM II140317-2 .5158 70 130mg/L.5
L17343-01LFMD 03/28/14 11:00 .021 99.4LFMD II140317-2 .5178 0.3970 130mg/L 20.5
L17362-03LFM 03/28/14 11:32 .057 98.8LFM II140317-2 .5511 70 130mg/L.5
L17362-03LFMD 03/28/14 11:35 .057 98.6LFMD II140317-2 .5502 0.1670 130mg/L 20.5
Beryllium, dissolved M200.8 ICP-MS
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361610
WG361610ICV 04/02/14 0:03 101.1ICV MS140331-9 .05054 90 110mg/L.05
WG361610ICB 04/02/14 0:07ICB U -0.00015 0.00015mg/L
WG361610LFB 04/02/14 0:10 96.8LFB MS140331-2 .04844 85 115mg/L.05005
L17362-01AS 04/02/14 0:17 U 102.1AS MS140331-2 .05112 70 130mg/L.05005
L17362-01ASD 04/02/14 0:20 U 103.5ASD MS140331-2 .05182 1.3670 130mg/L 20.05005
Beryllium, total M200.8 ICP-MS
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361587
WG361587ICV 04/01/14 19:17 98.5ICV MS140331-9 .04926 90 110mg/L.05
WG361587ICB 04/01/14 19:20ICB U -0.00015 0.00015mg/L
WG361306LRB 04/01/14 19:24LRB U -0.00011 0.00011mg/L
WG361306LFB 04/01/14 19:27 99.9LFB MS140320-2 .04999 85 115mg/L.05005
L17362-07LFM 04/01/14 20:49 U 97.8LFM MS140320-2 .04897 70 130mg/L.05005
L17362-07LFMD 04/01/14 20:52 U 97LFMD MS140320-2 .04854 0.8870 130mg/L 20.05005
Bismuth, dissolved M200.7 ICP
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361133
WG361133ICV 03/25/14 9:27 99.4ICV II140220-1 1.987 95 105mg/L2
WG361133ICB 03/25/14 9:33ICB U -0.12 0.12mg/L
WG361133LFB 03/25/14 9:46 89LFB II140317-2 .889 85 115mg/L.999
L17312-02AS 03/25/14 9:55 U 88.8AS II140317-2 .887 85 115mg/L.999
L17312-02ASD 03/25/14 9:58 U 88.1ASD II140317-2 .88 0.7985 115mg/L 20.999
L17362-06AS 03/25/14 10:36 U 87.2AS II140317-2 .871 85 115mg/L.999
L17362-06ASD 03/25/14 10:39 U 87.6ASD II140317-2 .875 0.4685 115mg/L 20.999
Page 32 of 63L17362-1404111040
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic QC
Summary
ACZ Project ID: L17362SPF Water Engineering
Bismuth, total M200.7 ICP
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361427
WG361427ICV 03/28/14 14:42 98ICV II140228-1 1.96 95 105mg/L2
WG361427ICB 03/28/14 14:48ICB U -0.12 0.12mg/L
WG361311LRB 03/28/14 15:01LRB U -0.088 0.088mg/L
WG361311LFB 03/28/14 15:04 94.2LFB II140317-2 .941 85 115mg/L.999
L17343-01LFM 03/28/14 15:11 U 98.6LFM II140317-2 .985 70 130mg/L.999
L17343-01LFMD 03/28/14 15:14 U 100.4LFMD II140317-2 1.003 1.8170 130mg/L 20.999
L17362-03LFM 03/28/14 15:26 U 97.4LFM II140317-2 .973 70 130mg/L.999
L17362-03LFMD 03/28/14 15:30 U 98.8LFMD II140317-2 .987 1.4370 130mg/L 20.999
Boron, dissolved M200.7 ICP
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361133
WG361133ICV 03/25/14 9:27 101.1ICV II140220-1 2.021 95 105mg/L2
WG361133ICB 03/25/14 9:33ICB U -0.03 0.03mg/L
WG361133LFB 03/25/14 9:46 90.1LFB II140317-2 .451 85 115mg/L.5005
L17312-02AS 03/25/14 9:55 .06 85.5AS II140317-2 .488 85 115mg/L.5005
L17312-02ASD MA03/25/14 9:58 .06 84.1ASD II140317-2 .481 1.4485 115mg/L 20.5005
L17362-06AS 03/25/14 10:36 .06 86.5AS II140317-2 .493 85 115mg/L.5005
L17362-06ASD 03/25/14 10:39 .06 85.3ASD II140317-2 .487 1.2285 115mg/L 20.5005
Boron, total M200.7 ICP
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361367
WG361367ICV 03/28/14 10:16 98.1ICV II140228-1 1.962 95 105mg/L2
WG361367ICB 03/28/14 10:22ICB U -0.03 0.03mg/L
WG361311LRB 03/28/14 10:35LRB U -0.022 0.022mg/L
WG361311LFB 03/28/14 10:38 97.1LFB II140317-2 .486 85 115mg/L.5005
L17343-01LFM 03/28/14 10:57 16.5 95.9LFM II140317-2 16.98 70 130mg/L.5005
L17343-01LFMD 03/28/14 11:00 16.5 117.9LFMD II140317-2 17.09 0.6570 130mg/L 20.5005
L17362-03LFM 03/28/14 11:32 .14 95.5LFM II140317-2 .618 70 130mg/L.5005
L17362-03LFMD 03/28/14 11:35 .14 95.3LFMD II140317-2 .617 0.1670 130mg/L 20.5005
Cadmium, dissolved M200.8 ICP-MS
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361610
WG361610ICV 04/02/14 0:03 98.7ICV MS140331-9 .04935 90 110mg/L.05
WG361610ICB 04/02/14 0:07ICB U -0.0003 0.0003mg/L
WG361610LFB 04/02/14 0:10 91.9LFB MS140331-2 .04606 85 115mg/L.0501
L17362-01AS 04/02/14 0:17 U 96.7AS MS140331-2 .04847 70 130mg/L.0501
L17362-01ASD 04/02/14 0:20 U 95.2ASD MS140331-2 .0477 1.670 130mg/L 20.0501
Page 33 of 63L17362-1404111040
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic QC
Summary
ACZ Project ID: L17362SPF Water Engineering
Cadmium, total M200.8 ICP-MS
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361587
WG361587ICV 04/01/14 19:17 98.5ICV MS140331-9 .04925 90 110mg/L.05
WG361587ICB 04/01/14 19:20ICB U -0.0003 0.0003mg/L
WG361306LRB 04/01/14 19:24LRB U -0.00022 0.00022mg/L
WG361306LFB 04/01/14 19:27 100.8LFB MS140320-2 .05051 85 115mg/L.0501
L17362-07LFM 04/01/14 20:49 U 97.3LFM MS140320-2 .04873 70 130mg/L.0501
L17362-07LFMD 04/01/14 20:52 U 97.2LFMD MS140320-2 .04872 0.0270 130mg/L 20.0501
Calcium, dissolved M200.7 ICP
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361133
WG361133ICV 03/25/14 9:27 99.8ICV II140220-1 99.76 95 105mg/L100
WG361133ICB 03/25/14 9:33ICB U -0.3 0.3mg/L
WG361133LFB 03/25/14 9:46 94.6LFB II140317-2 64.3 85 115mg/L67.98099
L17312-02AS 03/25/14 9:55 13.3 92.9AS II140317-2 76.47 85 115mg/L67.98099
L17312-02ASD 03/25/14 9:58 13.3 92.3ASD II140317-2 76.04 0.5685 115mg/L 2067.98099
L17362-06AS 03/25/14 10:36 39.6 92.4AS II140317-2 102.4 85 115mg/L67.98099
L17362-06ASD 03/25/14 10:39 39.6 92.2ASD II140317-2 102.3 0.185 115mg/L 2067.98099
Calcium, total M200.7 ICP
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361367
WG361367ICV 03/28/14 10:16 99.6ICV II140228-1 99.62 95 105mg/L100
WG361367ICB 03/28/14 10:22ICB U -0.3 0.3mg/L
WG361311LRB 03/28/14 10:35LRB U -0.22 0.22mg/L
WG361311LFB 03/28/14 10:38 106.9LFB II140317-2 72.64 85 115mg/L67.98099
L17343-01LFM 03/28/14 10:57 152 105.5LFM II140317-2 223.7 70 130mg/L67.98099
L17343-01LFMD 03/28/14 11:00 152 104LFMD II140317-2 222.7 0.4570 130mg/L 2067.98099
L17362-03LFM 03/28/14 11:32 40.5 106.4LFM II140317-2 112.8 70 130mg/L67.98099
L17362-03LFMD 03/28/14 11:35 40.5 105.3LFMD II140317-2 112.1 0.6270 130mg/L 2067.98099
Chloride M300.0 - Ion Chromatography
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG360290
WG360290ICV 03/06/14 13:49 101.6ICV WI140226-1 20.3 90 110mg/L19.98
WG360290ICB 03/06/14 14:07ICB U -1.5 1.5mg/L
WG361247
WG361247LFB 03/26/14 13:20 102LFB WI140306-2 30.6 90 110mg/L30
L17336-01DUP RA03/26/14 18:06 UDUP U 0mg/L 20
L17360-01AS 03/26/14 18:42 2 101.3AS WI140306-2 32.4 90 110mg/L30
Page 34 of 63L17362-1404111040
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic QC
Summary
ACZ Project ID: L17362SPF Water Engineering
Chromium, dissolved M200.8 ICP-MS
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361610
WG361610ICV 04/02/14 0:03 99ICV MS140331-9 .04952 90 110mg/L.05
WG361610ICB 04/02/14 0:07ICB U -0.0015 0.0015mg/L
WG361610LFB 04/02/14 0:10 92.6LFB MS140331-2 .04636 85 115mg/L.05005
L17362-01AS 04/02/14 0:17 U 93.8AS MS140331-2 .04696 70 130mg/L.05005
L17362-01ASD 04/02/14 0:20 U 92.4ASD MS140331-2 .04624 1.5570 130mg/L 20.05005
Chromium, total M200.8 ICP-MS
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361587
WG361587ICV 04/01/14 19:17 98.5ICV MS140331-9 .04924 90 110mg/L.05
WG361587ICB 04/01/14 19:20ICB U -0.0015 0.0015mg/L
WG361306LRB 04/01/14 19:24LRB U -0.0011 0.0011mg/L
WG361306LFB 04/01/14 19:27 97.5LFB MS140320-2 .04881 85 115mg/L.05005
L17362-07LFM 04/01/14 20:49 .0011 94.9LFM MS140320-2 .04858 70 130mg/L.05005
L17362-07LFMD 04/01/14 20:52 .0011 94.5LFMD MS140320-2 .0484 0.3770 130mg/L 20.05005
Cobalt, dissolved M200.8 ICP-MS
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361610
WG361610ICV 04/02/14 0:03 98.4ICV MS140331-9 .04921 90 110mg/L.05
WG361610ICB 04/02/14 0:07ICB U -0.00015 0.00015mg/L
WG361610LFB 04/02/14 0:10 95.2LFB MS140331-2 .04763 85 115mg/L.05005
L17362-01AS 04/02/14 0:17 .00025 97.7AS MS140331-2 .04916 70 130mg/L.05005
L17362-01ASD 04/02/14 0:20 .00025 97.8ASD MS140331-2 .04922 0.1270 130mg/L 20.05005
Cobalt, total M200.8 ICP-MS
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361587
WG361587ICV 04/01/14 19:17 99.2ICV MS140331-9 .04962 90 110mg/L.05
WG361587ICB 04/01/14 19:20ICB U -0.00015 0.00015mg/L
WG361306LRB 04/01/14 19:24LRB U -0.00011 0.00011mg/L
WG361306LFB 04/01/14 19:27 101LFB MS140320-2 .05056 85 115mg/L.05005
L17362-07LFM 04/01/14 20:49 .00011 99.3LFM MS140320-2 .04979 70 130mg/L.05005
L17362-07LFMD 04/01/14 20:52 .00011 97.5LFMD MS140320-2 .04889 1.8270 130mg/L 20.05005
Conductivity @25C SM2510B
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361281
WG361281LCSW2 03/26/14 16:45 103.4LCSW PCN43577 1456.4 90 110umhos/cm1408.8
L17364-01DUP1 03/26/14 18:38 3550DUP 3570 0.6umhos/cm 20
WG361281LCSW5 03/26/14 19:37 101.8LCSW PCN43577 1434.2 90 110umhos/cm1408.8
WG361281LCSW8 03/26/14 23:11 101LCSW PCN43577 1423.1 90 110umhos/cm1408.8
WG361281LCSW11 03/27/14 2:11 100LCSW PCN43577 1409 90 110umhos/cm1408.8
WG361281LCSW14 03/27/14 5:19 99.1LCSW PCN43577 1395.8 90 110umhos/cm1408.8
Page 35 of 63L17362-1404111040
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic QC
Summary
ACZ Project ID: L17362SPF Water Engineering
Copper, dissolved M200.8 ICP-MS
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361610
WG361610ICV 04/02/14 0:03 99.1ICV MS140331-9 .04953 90 110mg/L.05
WG361610ICB 04/02/14 0:07ICB U -0.0015 0.0015mg/L
WG361610LFB 04/02/14 0:10 92.3LFB MS140331-2 .04618 85 115mg/L.05005
L17362-01AS 04/02/14 0:17 U 91.3AS MS140331-2 .04572 70 130mg/L.05005
L17362-01ASD 04/02/14 0:20 U 89.9ASD MS140331-2 .04498 1.6370 130mg/L 20.05005
Copper, total M200.8 ICP-MS
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361587
WG361587ICV 04/01/14 19:17 97ICV MS140331-9 .04849 90 110mg/L.05
WG361587ICB 04/01/14 19:20ICB U -0.0015 0.0015mg/L
WG361306LRB 04/01/14 19:24LRB U -0.0011 0.0011mg/L
WG361306LFB 04/01/14 19:27 97.9LFB MS140320-2 .04901 85 115mg/L.05005
L17362-07LFM 04/01/14 20:49 U 93.1LFM MS140320-2 .0466 70 130mg/L.05005
L17362-07LFMD 04/01/14 20:52 U 93.2LFMD MS140320-2 .04667 0.1570 130mg/L 20.05005
Cyanide, total M335.4 - Colorimetric w/ distillation
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361515
WG361515ICV 03/31/14 15:14 97.6ICV WI140322-7 .2928 90 110mg/L.3
WG361515ICB 03/31/14 15:15ICB U -0.003 0.003mg/L
WG361445LRB 03/31/14 15:16LRB U -0.003 0.003mg/L
WG361445LFB 03/31/14 15:17 104.5LFB WI140322-4 .209 90 110mg/L.2
L17362-01DUP RA03/31/14 15:22 UDUP U 0mg/L 20
L17362-07DUP RA03/31/14 15:30 UDUP U 0mg/L 20
L17362-08LFM 03/31/14 15:32 U 99.7LFM WI140322-4 .1993 90 110mg/L.2
L17362-02LFM 03/31/14 15:42 U 103.5LFM WI140322-4 .207 90 110mg/L.2
Cyanide, WAD SM4500-CN I-Colorimetric w/ distillation
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361346
WG361346ICV 03/27/14 11:49 98.1ICV WI140322-7 .2942 90 110mg/L.3
WG361346ICB 03/27/14 11:50ICB U -0.003 0.003mg/L
WG361379
WG361349LRB 03/27/14 16:28LRB U -0.003 0.003mg/L
WG361349LFB 03/27/14 16:29 96.3LFB WI140322-6 .1925 90 110mg/L.2
L17332-02LFM 03/27/14 16:43 U 95.2LFM WI140322-6 .1904 90 110mg/L.2
L17333-01DUP RA03/27/14 16:44 UDUP U 0mg/L 20
WG361515
WG361515ICV 03/31/14 15:14 97.6ICV WI140322-7 .2928 90 110mg/L.3
WG361515ICB 03/31/14 15:15ICB U -0.003 0.003mg/L
WG361524
WG361496LRB 03/31/14 16:07LRB U -0.003 0.003mg/L
WG361496LFB 03/31/14 16:08 96.2LFB WI140322-6 .1924 90 110mg/L.2
L17362-04DUP RA03/31/14 16:09 UDUP U 0mg/L 20
L17362-05LFM 03/31/14 16:11 U 95.5LFM WI140322-6 .191 90 110mg/L.2
Page 36 of 63L17362-1404111040
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic QC
Summary
ACZ Project ID: L17362SPF Water Engineering
Fluoride M300.0 - Ion Chromatography
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG360290
WG360290ICV 03/06/14 13:49 103.7ICV WI140226-1 4.17 90 110mg/L4.02
WG360290ICB 03/06/14 14:07ICB U -0.3 0.3mg/L
WG361247
WG361247LFB 03/26/14 13:20 104LFB WI140306-2 1.56 90 110mg/L1.5
L17336-01DUP RA03/26/14 18:06 UDUP U 0mg/L 20
L17360-01AS 03/26/14 18:42 .11 105.3AS WI140306-2 1.69 90 110mg/L1.5
Gallium, dissolved M200.7 ICP
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361133
WG361133ICV 03/25/14 9:27 98ICV II140220-1 1.96 95 105mg/L2
WG361133ICB 03/25/14 9:33ICB U -0.3 0.3mg/L
WG361133LFB 03/25/14 9:46 90.9LFB II140317-2 .91 85 115mg/L1.001
L17312-02AS 03/25/14 9:55 U 88.9AS II140317-2 .89 85 115mg/L1.001
L17312-02ASD 03/25/14 9:58 U 87.9ASD II140317-2 .88 1.1385 115mg/L 201.001
L17362-06AS 03/25/14 10:36 U 90.9AS II140317-2 .91 85 115mg/L1.001
L17362-06ASD 03/25/14 10:39 U 88.9ASD II140317-2 .89 2.2285 115mg/L 201.001
Gallium, total M200.7 ICP
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361367
WG361367ICV 03/28/14 10:16 96.5ICV II140228-1 1.93 95 105mg/L2
WG361367ICB 03/28/14 10:22ICB U -0.3 0.3mg/L
WG361311LRB 03/28/14 10:35LRB U -0.22 0.22mg/L
WG361311LFB 03/28/14 10:38 100.9LFB II140317-2 1.01 85 115mg/L1.001
L17343-01LFM 03/28/14 10:57 U 101.9LFM II140317-2 1.02 70 130mg/L1.001
L17343-01LFMD 03/28/14 11:00 U 104.9LFMD II140317-2 1.05 2.970 130mg/L 201.001
L17362-03LFM 03/28/14 11:32 U 100.9LFM II140317-2 1.01 70 130mg/L1.001
L17362-03LFMD 03/28/14 11:35 U 100.9LFMD II140317-2 1.01 070 130mg/L 201.001
Iron, dissolved M200.7 ICP
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361133
WG361133ICV 03/25/14 9:27 98ICV II140220-1 1.959 95 105mg/L2
WG361133ICB 03/25/14 9:33ICB U -0.06 0.06mg/L
WG361133LFB 03/25/14 9:46 91.7LFB II140317-2 .918 85 115mg/L1.0014
L17312-02AS 03/25/14 9:55 .15 88.7AS II140317-2 1.038 85 115mg/L1.0014
L17312-02ASD 03/25/14 9:58 .15 87ASD II140317-2 1.021 1.6585 115mg/L 201.0014
L17362-06AS 03/25/14 10:36 U 89.7AS II140317-2 .898 85 115mg/L1.0014
L17362-06ASD 03/25/14 10:39 U 88.9ASD II140317-2 .89 0.8985 115mg/L 201.0014
Page 37 of 63L17362-1404111040
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic QC
Summary
ACZ Project ID: L17362SPF Water Engineering
Iron, total M200.7 ICP
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361367
WG361367ICV 03/28/14 10:16 97.1ICV II140228-1 1.941 95 105mg/L2
WG361367ICB 03/28/14 10:22ICB U -0.06 0.06mg/L
WG361311LRB 03/28/14 10:35LRB U -0.044 0.044mg/L
WG361311LFB 03/28/14 10:38 100.9LFB II140317-2 1.01 85 115mg/L1.0014
L17343-01LFM 03/28/14 10:57 U 103.1LFM II140317-2 1.032 70 130mg/L1.0014
L17343-01LFMD 03/28/14 11:00 U 102.5LFMD II140317-2 1.026 0.5870 130mg/L 201.0014
L17362-03LFM M303/28/14 11:32 3.9 215.6LFM II140317-2 6.059 70 130mg/L1.0014
L17362-03LFMD M303/28/14 11:35 3.9 215.3LFMD II140317-2 6.056 0.0570 130mg/L 201.0014
Lead, dissolved M200.8 ICP-MS
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361610
WG361610ICV 04/02/14 0:03 98.2ICV MS140331-9 .0491 90 110mg/L.05
WG361610ICB 04/02/14 0:07ICB U -0.0003 0.0003mg/L
WG361610LFB 04/02/14 0:10 89.8LFB MS140331-2 .04496 85 115mg/L.05005
L17362-01AS 04/02/14 0:17 U 96AS MS140331-2 .04803 70 130mg/L.05005
L17362-01ASD 04/02/14 0:20 U 95.4ASD MS140331-2 .04775 0.5870 130mg/L 20.05005
Lead, total M200.8 ICP-MS
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361587
WG361587ICV 04/01/14 19:17 98.9ICV MS140331-9 .04943 90 110mg/L.05
WG361587ICB 04/01/14 19:20ICB U -0.0003 0.0003mg/L
WG361306LRB 04/01/14 19:24LRB U -0.00022 0.00022mg/L
WG361306LFB 04/01/14 19:27 94.6LFB MS140320-2 .04735 85 115mg/L.05005
L17362-07LFM 04/01/14 20:49 U 95.2LFM MS140320-2 .04766 70 130mg/L.05005
L17362-07LFMD 04/01/14 20:52 U 94.6LFMD MS140320-2 .04733 0.6970 130mg/L 20.05005
Lithium, dissolved M200.7 ICP
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361133
WG361133ICV 03/25/14 9:27 97.8ICV II140220-1 1.955 95 105mg/L2
WG361133ICB 03/25/14 9:33ICB U -0.024 0.024mg/L
WG361133LFB 03/25/14 9:46 86.2LFB II140317-2 .8619 85 115mg/L1
L17312-02AS M203/25/14 9:55 .086 84AS II140317-2 .9264 85 115mg/L1
L17312-02ASD M203/25/14 9:58 .086 83.8ASD II140317-2 .9239 0.2785 115mg/L 201
L17362-06AS M203/25/14 10:36 .04 82.8AS II140317-2 .8682 85 115mg/L1
L17362-06ASD M203/25/14 10:39 .04 82.4ASD II140317-2 .8642 0.4685 115mg/L 201
Page 38 of 63L17362-1404111040
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic QC
Summary
ACZ Project ID: L17362SPF Water Engineering
Lithium, total M200.7 ICP
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361367
WG361367ICV 03/28/14 10:16 97.6ICV II140228-1 1.9512 95 105mg/L2
WG361367ICB 03/28/14 10:22ICB U -0.024 0.024mg/L
WG361311LRB 03/28/14 10:35LRB U -0.0176 0.0176mg/L
WG361311LFB 03/28/14 10:38 96.8LFB II140317-2 .9676 85 115mg/L1
L17343-01LFM 03/28/14 10:57 .778 99.3LFM II140317-2 1.771 70 130mg/L1
L17343-01LFMD 03/28/14 11:00 .778 100.8LFMD II140317-2 1.786 0.8470 130mg/L 201
L17362-03LFM 03/28/14 11:32 .543 96.5LFM II140317-2 1.508 70 130mg/L1
L17362-03LFMD 03/28/14 11:35 .543 97.1LFMD II140317-2 1.514 0.470 130mg/L 201
Magnesium, dissolved M200.7 ICP
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361133
WG361133ICV 03/25/14 9:27 97.8ICV II140220-1 97.8 95 105mg/L100
WG361133ICB 03/25/14 9:33ICB U -0.6 0.6mg/L
WG361133LFB 03/25/14 9:46 88.4LFB II140317-2 44.2 85 115mg/L50.00131
L17312-02AS 03/25/14 9:55 9.3 86.8AS II140317-2 52.7 85 115mg/L50.00131
L17312-02ASD 03/25/14 9:58 9.3 86.4ASD II140317-2 52.52 0.3485 115mg/L 2050.00131
L17362-06AS 03/25/14 10:36 7.2 85.9AS II140317-2 50.15 85 115mg/L50.00131
L17362-06ASD 03/25/14 10:39 7.2 85.7ASD II140317-2 50.05 0.285 115mg/L 2050.00131
Magnesium, total M200.7 ICP
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361367
WG361367ICV 03/28/14 10:16 97.7ICV II140228-1 97.72 95 105mg/L100
WG361367ICB 03/28/14 10:22ICB U -0.6 0.6mg/L
WG361311LRB 03/28/14 10:35LRB U -0.44 0.44mg/L
WG361311LFB 03/28/14 10:38 102.2LFB II140317-2 51.11 85 115mg/L50.00131
L17343-01LFM 03/28/14 10:57 214 104.6LFM II140317-2 266.3 70 130mg/L50.00131
L17343-01LFMD 03/28/14 11:00 214 101.8LFMD II140317-2 264.9 0.5370 130mg/L 2050.00131
L17362-03LFM 03/28/14 11:32 3.2 102.2LFM II140317-2 54.29 70 130mg/L50.00131
L17362-03LFMD 03/28/14 11:35 3.2 100.9LFMD II140317-2 53.66 1.1770 130mg/L 2050.00131
Manganese, dissolved M200.8 ICP-MS
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361610
WG361610ICV 04/02/14 0:03 101.4ICV MS140331-9 .05071 90 110mg/L.05
WG361610ICB 04/02/14 0:07ICB U -0.0015 0.0015mg/L
WG361610LFB 04/02/14 0:10 94.8LFB MS140331-2 .04747 85 115mg/L.0501
L17362-01AS 04/02/14 0:17 .0357 94AS MS140331-2 .08281 70 130mg/L.0501
L17362-01ASD 04/02/14 0:20 .0357 95ASD MS140331-2 .08332 0.6170 130mg/L 20.0501
WG361642
WG361642ICV 04/02/14 16:04 100.8ICV MS140331-9 .05041 90 110mg/L.05
WG361642ICB 04/02/14 16:07ICB U -0.0015 0.0015mg/L
WG361642LFB 04/02/14 16:11 102.7LFB MS140331-2 .05146 85 115mg/L.0501
L17317-01AS 04/02/14 16:17 .7155 125.1AS MS140331-2 .7782 70 130mg/L.0501
L17317-01ASD 04/02/14 16:21 .7155 109ASD MS140331-2 .7701 1.0570 130mg/L 20.0501
Page 39 of 63L17362-1404111040
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic QC
Summary
ACZ Project ID: L17362SPF Water Engineering
Manganese, total M200.8 ICP-MS
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361587
WG361587ICV 04/01/14 19:17 102.9ICV MS140331-9 .05143 90 110mg/L.05
WG361587ICB 04/01/14 19:20ICB U -0.0015 0.0015mg/L
WG361306LRB 04/01/14 19:24LRB U -0.0011 0.0011mg/L
WG361306LFB 04/01/14 19:27 101.2LFB MS140320-2 .05069 85 115mg/L.0501
L17362-07LFM 04/01/14 20:49 U 100.4LFM MS140320-2 .0503 70 130mg/L.0501
L17362-07LFMD 04/01/14 20:52 U 100.8LFMD MS140320-2 .05048 0.3670 130mg/L 20.0501
WG361643
WG361643ICV 04/02/14 13:17 102.6ICV MS140331-9 .05128 90 110mg/L.05
WG361643ICB 04/02/14 13:19ICB U -0.0015 0.0015mg/L
WG361306LRB 04/02/14 13:22LRB U -0.0011 0.0011mg/L
WG361306LFB 04/02/14 13:24 101.9LFB MS140320-2 .05106 85 115mg/L.0501
L17362-07LFM 04/02/14 13:48 U 103.3LFM MS140320-2 .05175 70 130mg/L.0501
L17362-07LFMD 04/02/14 13:50 U 99.9LFMD MS140320-2 .05007 3.370 130mg/L 20.0501
Mercury, dissolved M1631, Atomic Fluorescence
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361393
WG361393ICV 03/28/14 15:59 98.7ICV HG140325-4 9.87 79 121ng/L10
WG361393ICB 03/28/14 16:04ICB U -0.5 0.5ng/L
WG361562
WG361562CCV1 04/01/14 15:50 96.8CCV HG140325-4 9.68 76.5 123.4ng/L10
WG361562CCB1 04/01/14 15:55CCB U -0.5 0.5ng/L
WG361562PQV 04/01/14 16:00 86PQV HG140325-6 .43 70 130ng/L.5
WG361562LFB 04/01/14 16:12 75LFB HG140325-5 1.5 71 125ng/L2
L17362-01MS 04/01/14 16:26 U 76MS HG140325-5 1.52 71 125ng/L2
L17362-01MSD 04/01/14 16:31 U 76.5MSD HG140325-5 1.53 0.6671 125ng/L 242
WG361562CCV2 04/01/14 17:01 94.6CCV HG140325-4 9.46 76.5 123.4ng/L10
WG361562CCB2 04/01/14 17:06CCB U -0.5 0.5ng/L
WG361562CCV3 04/01/14 17:47 91.9CCV HG140325-4 9.19 76.5 123.4ng/L10
WG361562CCB3 04/01/14 17:52CCB U -0.5 0.5ng/L
WG361562CCV4 04/01/14 18:22 97.1CCV HG140325-4 9.71 76.5 123.4ng/L10
WG361562CCB4 04/01/14 18:27CCB U -0.5 0.5ng/L
Page 40 of 63L17362-1404111040
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic QC
Summary
ACZ Project ID: L17362SPF Water Engineering
Mercury, total M1631, Atomic Fluorescence
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361393
WG361393ICV 03/28/14 15:59 98.7ICV HG140325-4 9.87 79 121ng/L10
WG361393ICB 03/28/14 16:04ICB U -0.5 0.5ng/L
WG361470
WG361470CCV1 03/31/14 11:35 99CCV HG140325-4 9.9 76.5 123.4ng/L10
WG361470CCB1 03/31/14 11:40CCB U -0.5 0.5ng/L
WG361470PQV 03/31/14 11:45 102PQV HG140325-6 .51 70 130ng/L.5
WG361470LFB 03/31/14 11:50 89.5LFB HG140325-5 1.79 71 125ng/L2
WG361470CCV2 03/31/14 12:42 77.2CCV HG140325-4 7.72 76.5 123.4ng/L10
WG361470CCB2 03/31/14 12:47CCB U -0.5 0.5ng/L
L17347-01MS 03/31/14 13:09 8 88MS HG10XPRE 25.6 71 125ng/L200
L17347-01MSD 03/31/14 13:14 8 87MSD HG10XPRE 25.4 0.7871 125ng/L 24200
WG361470CCV3 03/31/14 13:50 106CCV HG140325-4 10.6 76.5 123.4ng/L10
WG361470CCB3 03/31/14 13:55CCB U -0.5 0.5ng/L
WG361470CCV4 03/31/14 14:35 104CCV HG140325-4 10.4 76.5 123.4ng/L10
WG361470CCB4 03/31/14 14:40CCB U -0.5 0.5ng/L
WG361470CCV5 03/31/14 15:05 106CCV HG140325-4 10.6 76.5 123.4ng/L10
WG361470CCB5 03/31/14 15:11CCB U -0.5 0.5ng/L
Molybdenum, dissolved M200.8 ICP-MS
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361610
WG361610ICV 04/02/14 0:03 94.5ICV MS140331-9 .01889 90 110mg/L.01998
WG361610ICB 04/02/14 0:07ICB U -0.0015 0.0015mg/L
WG361610LFB 04/02/14 0:10 89.3LFB MS140331-2 .04464 85 115mg/L.05
L17362-01AS 04/02/14 0:17 .0105 97.6AS MS140331-2 .05928 70 130mg/L.05
L17362-01ASD 04/02/14 0:20 .0105 96.8ASD MS140331-2 .05892 0.6170 130mg/L 20.05
Molybdenum, total M200.8 ICP-MS
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361587
WG361587ICV 04/01/14 19:17 93.3ICV MS140331-9 .01865 90 110mg/L.01998
WG361587ICB 04/01/14 19:20ICB U -0.0015 0.0015mg/L
WG361306LRB 04/01/14 19:24LRB U -0.0011 0.0011mg/L
WG361306LFB 04/01/14 19:27 95.1LFB MS140320-2 .04756 85 115mg/L.05
L17362-07LFM 04/01/14 20:49 .0026 96.2LFM MS140320-2 .05069 70 130mg/L.05
L17362-07LFMD 04/01/14 20:52 .0026 95.9LFMD MS140320-2 .05056 0.2670 130mg/L 20.05
Nickel, dissolved M200.8 ICP-MS
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361610
WG361610ICV 04/02/14 0:03 98.5ICV MS140331-9 .04927 90 110mg/L.05
WG361610ICB 04/02/14 0:07ICB U -0.0018 0.0018mg/L
WG361610LFB 04/02/14 0:10 90.1LFB MS140331-2 .04503 85 115mg/L.05
L17362-01AS 04/02/14 0:17 U 88.7AS MS140331-2 .04434 70 130mg/L.05
L17362-01ASD 04/02/14 0:20 U 86.7ASD MS140331-2 .04334 2.2870 130mg/L 20.05
Page 41 of 63L17362-1404111040
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic QC
Summary
ACZ Project ID: L17362SPF Water Engineering
Nickel, total M200.8 ICP-MS
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361587
WG361587ICV 04/01/14 19:17 97.3ICV MS140331-9 .04865 90 110mg/L.05
WG361587ICB 04/01/14 19:20ICB U -0.0018 0.0018mg/L
WG361306LRB 04/01/14 19:24LRB U -0.00132 0.00132mg/L
WG361306LFB 04/01/14 19:27 95.3LFB MS140320-2 .04766 85 115mg/L.05
L17362-07LFM 04/01/14 20:49 U 91.5LFM MS140320-2 .04576 70 130mg/L.05
L17362-07LFMD 04/01/14 20:52 U 92.7LFMD MS140320-2 .04635 1.2870 130mg/L 20.05
Nitrate/Nitrite as N M353.2 - H2SO4 preserved
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361453
WG361453ICV 03/28/14 20:13 106ICV WI140116-3 2.56 90 110mg/L2.416
WG361453ICB 03/28/14 20:14ICB U -0.06 0.06mg/L
WG361455
WG361455LFB1 03/28/14 22:09 109.8LFB WI140215-3 2.195 90 110mg/L2
WG361455LFB2 03/28/14 22:43 107.9LFB WI140215-3 2.158 90 110mg/L2
L17355-01AS 03/28/14 22:45 .26 108.7AS WI140215-3 2.433 90 110mg/L2
L17355-02DUP 03/28/14 22:48 2.19DUP 2.176 0.6mg/L 20
Nitrogen, ammonia M350.1 - Automated Phenate
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361341
WG361341ICV 03/27/14 11:36 105.7ICV WI131021-1 1.06 90 110mg/L1.003
WG361341ICB 03/27/14 11:39ICB U -0.15 0.15mg/L
WG361369
WG361369LFB1 03/27/14 15:50 106.1LFB WI140113-8 1.061 90 110mg/L1
L17248-01AS 03/27/14 15:52 U 100.4AS WI140113-8 1.004 90 110mg/L1
L17248-02DUP RA03/27/14 15:54 UDUP U 0mg/L 20
L17362-02AS M103/27/14 16:07 U 114.4AS WI140113-8 1.144 90 110mg/L1
L17362-03DUP RA03/27/14 16:10 UDUP .058 200mg/L 20
WG361369LFB2 03/27/14 16:56 107.5LFB WI140113-8 1.075 90 110mg/L1
pH (lab) SM4500H+ B
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361281
WG361281LCSW1 03/26/14 16:43 99.2LCSW PCN40852 5.95 units6
L17364-01DUP1 03/26/14 18:38 3.6DUP 3.51 2.5units 20
WG361281LCSW4 03/26/14 19:35 99.5LCSW PCN40852 5.97 units6
WG361281LCSW7 03/26/14 23:09 99.7LCSW PCN40852 5.98 units6
WG361281LCSW10 03/27/14 2:10 99.5LCSW PCN40852 5.97 units6
WG361281LCSW13 03/27/14 5:17 99.3LCSW PCN40852 5.96 units6
Page 42 of 63L17362-1404111040
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic QC
Summary
ACZ Project ID: L17362SPF Water Engineering
Phosphorus, total M365.1 - Auto Ascorbic Acid (digest)
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361833
WG361833ICV 04/05/14 13:38 97.5ICV WI140401-5 .636 90 110mg/L.65228
WG361833ICB 04/05/14 13:41ICB U -0.03 0.03mg/L
WG361801LRB 04/05/14 13:42LRB U -0.03 0.03mg/L
WG361801LFB 04/05/14 13:43 100.2LFB WI140326-3 .501 90 110mg/L.5
L17248-01LFM 04/05/14 13:45 .4 102.4LFM 5XPT 2.961 90 110mg/L2.5
L17362-01DUP RA04/05/14 13:47 .05DUP .049 2mg/L 20
Potassium, dissolved M200.7 ICP
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361133
WG361133ICV 03/25/14 9:27 99.3ICV II140220-1 19.85 95 105mg/L20
WG361133ICB 03/25/14 9:33ICB U -0.6 0.6mg/L
WG361133LFB 03/25/14 9:46 90.7LFB II140317-2 90.65 85 115mg/L99.99364
L17312-02AS 03/25/14 9:55 7.4 89.2AS II140317-2 96.6 85 115mg/L99.99364
L17312-02ASD 03/25/14 9:58 7.4 89.5ASD II140317-2 96.91 0.3285 115mg/L 2099.99364
L17362-06AS 03/25/14 10:36 5.2 88.9AS II140317-2 94.07 85 115mg/L99.99364
L17362-06ASD 03/25/14 10:39 5.2 89ASD II140317-2 94.15 0.0985 115mg/L 2099.99364
Potassium, total M200.7 ICP
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361367
WG361367ICV 03/28/14 10:16 97.8ICV II140228-1 19.55 95 105mg/L20
WG361367ICB 03/28/14 10:22ICB U -0.6 0.6mg/L
WG361311LRB 03/28/14 10:35LRB U -0.44 0.44mg/L
WG361311LFB 03/28/14 10:38 101.8LFB II140317-2 101.8 85 115mg/L99.99364
L17343-01LFM 03/28/14 10:57 29.2 105.2LFM II140317-2 134.4 70 130mg/L99.99364
L17343-01LFMD 03/28/14 11:00 29.2 106LFMD II140317-2 135.2 0.5970 130mg/L 2099.99364
L17362-03LFM 03/28/14 11:32 10.1 101.8LFM II140317-2 111.9 70 130mg/L99.99364
L17362-03LFMD 03/28/14 11:35 10.1 101.5LFMD II140317-2 111.6 0.2770 130mg/L 2099.99364
Residue, Filterable (TDS) @180C SM2540C
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361151
WG361151PBW 03/25/14 11:00PBW U -20 20mg/L
WG361151LCSW 03/25/14 11:01 94.6LCSW PCN45341 246 80 120mg/L260
L17322-05DUP 03/25/14 11:25 2220DUP 2198 1mg/L 10
Residue, Non-Filterable (TSS) @105C SM2540D
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361160
WG361160PBW 03/25/14 11:41PBW U -15 15mg/L
WG361160LCSW 03/25/14 11:43 84.4LCSW PCN45341 135 80 120mg/L160
L17362-01DUP RA03/25/14 12:08 190DUP 188 1.1mg/L 10
L17385-04DUP RA03/25/14 12:31 30DUP 32 6.5mg/L 10
Page 43 of 63L17362-1404111040
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic QC
Summary
ACZ Project ID: L17362SPF Water Engineering
Scandium, dissolved M200.7 ICP
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361133
WG361133ICV 03/25/14 9:27 98.5ICV II140220-1 1.97 95 105mg/L2
WG361133ICB 03/25/14 9:33ICB U -0.3 0.3mg/L
WG361133LFB 03/25/14 9:46 90.9LFB II140317-2 .91 85 115mg/L1.0009
L17312-02AS 03/25/14 9:55 U 88.9AS II140317-2 .89 85 115mg/L1.0009
L17312-02ASD 03/25/14 9:58 U 87.9ASD II140317-2 .88 1.1385 115mg/L 201.0009
L17362-06AS 03/25/14 10:36 U 85.9AS II140317-2 .86 85 115mg/L1.0009
L17362-06ASD 03/25/14 10:39 U 85.9ASD II140317-2 .86 085 115mg/L 201.0009
Scandium, total M200.7 ICP
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361367
WG361367ICV 03/28/14 10:16 98.5ICV II140228-1 1.97 95 105mg/L2
WG361367ICB 03/28/14 10:22ICB U -0.3 0.3mg/L
WG361311LRB 03/28/14 10:35LRB U -0.22 0.22mg/L
WG361311LFB 03/28/14 10:38 105.9LFB II140317-2 1.06 85 115mg/L1.0009
L17343-01LFM 03/28/14 10:57 U 107.9LFM II140317-2 1.08 70 130mg/L1.0009
L17343-01LFMD 03/28/14 11:00 U 107.9LFMD II140317-2 1.08 070 130mg/L 201.0009
L17362-03LFM 03/28/14 11:32 U 105.9LFM II140317-2 1.06 70 130mg/L1.0009
L17362-03LFMD 03/28/14 11:35 U 105.9LFMD II140317-2 1.06 070 130mg/L 201.0009
Selenium, dissolved M200.8 ICP-MS
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361610
WG361610ICV 04/02/14 0:03 101.3ICV MS140331-9 .05063 90 110mg/L.05
WG361610ICB 04/02/14 0:07ICB U -0.0003 0.0003mg/L
WG361610LFB 04/02/14 0:10 90.7LFB MS140331-2 .04542 85 115mg/L.05005
L17362-01AS 04/02/14 0:17 U 99.3AS MS140331-2 .0497 70 130mg/L.05005
L17362-01ASD 04/02/14 0:20 U 98ASD MS140331-2 .04904 1.3470 130mg/L 20.05005
Selenium, total M200.8 ICP-MS
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361587
WG361587ICV 04/01/14 19:17 101.8ICV MS140331-9 .0509 90 110mg/L.05
WG361587ICB 04/01/14 19:20ICB U -0.0003 0.0003mg/L
WG361306LRB 04/01/14 19:24LRB .00017 -0.00022 0.00022mg/L
WG361306LFB 04/01/14 19:27 100.9LFB MS140320-2 .05051 85 115mg/L.05005
L17362-07LFM 04/01/14 20:49 .0014 96.9LFM MS140320-2 .0499 70 130mg/L.05005
L17362-07LFMD 04/01/14 20:52 .0014 95.7LFMD MS140320-2 .04932 1.1770 130mg/L 20.05005
Silver, dissolved M200.8 ICP-MS
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361610
WG361610ICV 04/02/14 0:03 98.6ICV MS140331-9 .01974 90 110mg/L.02002
WG361610ICB 04/02/14 0:07ICB U -0.00015 0.00015mg/L
WG361610LFB 04/02/14 0:10 96.1LFB MS140331-2 .009625 85 115mg/L.01002
L17362-01AS 04/02/14 0:17 U 100.3AS MS140331-2 .01005 70 130mg/L.01002
L17362-01ASD 04/02/14 0:20 U 99.2ASD MS140331-2 .009936 1.1470 130mg/L 20.01002
Page 44 of 63L17362-1404111040
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic QC
Summary
ACZ Project ID: L17362SPF Water Engineering
Silver, total M200.8 ICP-MS
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361587
WG361587ICV 04/01/14 19:17 96.7ICV MS140331-9 .01935 90 110mg/L.02002
WG361587ICB 04/01/14 19:20ICB U -0.00015 0.00015mg/L
WG361306LRB 04/01/14 19:24LRB U -0.00011 0.00011mg/L
WG361306LFB 04/01/14 19:27 99LFB MS140320-2 .009905 85 115mg/L.01001
L17362-07LFM 04/01/14 20:49 U 96.1LFM MS140320-2 .009616 70 130mg/L.01001
L17362-07LFMD 04/01/14 20:52 U 95.7LFMD MS140320-2 .009576 0.4270 130mg/L 20.01001
Sodium, dissolved M200.7 ICP
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361133
WG361133ICV 03/25/14 9:27 99.9ICV II140220-1 99.9 95 105mg/L100
WG361133ICB 03/25/14 9:33ICB U -0.6 0.6mg/L
WG361133LFB 03/25/14 9:46 91.3LFB II140317-2 91.31 85 115mg/L100.0393
L17312-02AS 03/25/14 9:55 86 88.4AS II140317-2 174.4 85 115mg/L100.0393
L17312-02ASD 03/25/14 9:58 86 87ASD II140317-2 173 0.8185 115mg/L 20100.0393
L17362-06AS 03/25/14 10:36 23.3 89.2AS II140317-2 112.5 85 115mg/L100.0393
L17362-06ASD 03/25/14 10:39 23.3 89ASD II140317-2 112.3 0.1885 115mg/L 20100.0393
Sodium, total M200.7 ICP
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361367
WG361367ICV 03/28/14 10:16 98.8ICV II140228-1 98.78 95 105mg/L100
WG361367ICB 03/28/14 10:22ICB U -0.6 0.6mg/L
WG361311LRB 03/28/14 10:35LRB U -0.44 0.44mg/L
WG361311LFB 03/28/14 10:38 100.8LFB II140317-2 100.8 85 115mg/L100.0393
L17343-01LFM 03/28/14 10:57 578 96.4LFM II140317-2 674.4 70 130mg/L100.0393
L17343-01LFMD 03/28/14 11:00 578 102.4LFMD II140317-2 680.4 0.8970 130mg/L 20100.0393
L17362-03LFM 03/28/14 11:32 138 101.8LFM II140317-2 239.8 70 130mg/L100.0393
L17362-03LFMD 03/28/14 11:35 138 99.5LFMD II140317-2 237.5 0.9670 130mg/L 20100.0393
Strontium, dissolved M200.7 ICP
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361133
WG361133ICV 03/25/14 9:27 99.7ICV II140220-1 1.993 95 105mg/L2
WG361133ICB 03/25/14 9:33ICB U -0.015 0.015mg/L
WG361133LFB 03/25/14 9:46 91.2LFB II140317-2 .456 85 115mg/L.5
L17312-02AS 03/25/14 9:55 .337 87.2AS II140317-2 .7729 85 115mg/L.5
L17312-02ASD 03/25/14 9:58 .337 87ASD II140317-2 .7719 0.1385 115mg/L 20.5
L17362-06AS 03/25/14 10:36 .188 88.9AS II140317-2 .6326 85 115mg/L.5
L17362-06ASD 03/25/14 10:39 .188 89ASD II140317-2 .6328 0.0385 115mg/L 20.5
Page 45 of 63L17362-1404111040
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic QC
Summary
ACZ Project ID: L17362SPF Water Engineering
Strontium, total M200.7 ICP
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361367
WG361367ICV 03/28/14 10:16 99ICV II140228-1 1.9792 95 105mg/L2
WG361367ICB 03/28/14 10:22ICB U -0.015 0.015mg/L
WG361311LRB 03/28/14 10:35LRB U -0.011 0.011mg/L
WG361311LFB 03/28/14 10:38 99.6LFB II140317-2 .4978 85 115mg/L.5
L17343-01LFM 03/28/14 10:57 1.96 97.8LFM II140317-2 2.449 70 130mg/L.5
L17343-01LFMD 03/28/14 11:00 1.96 100.2LFMD II140317-2 2.461 0.4970 130mg/L 20.5
L17362-03LFM 03/28/14 11:32 .139 99.9LFM II140317-2 .6386 70 130mg/L.5
L17362-03LFMD 03/28/14 11:35 .139 99.7LFMD II140317-2 .6376 0.1670 130mg/L 20.5
Sulfate M300.0 - Ion Chromatography
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG360290
WG360290ICV 03/06/14 13:49 102.5ICV WI140226-1 51.2 90 110mg/L49.95
WG360290ICB 03/06/14 14:07ICB U -1.5 1.5mg/L
WG361247
WG361247LFB 03/26/14 13:20 102LFB WI140306-2 30.6 90 110mg/L30
L17336-01DUP 03/26/14 18:06 299DUP 299 0mg/L 20
L17360-01AS 03/26/14 18:42 14.3 100AS WI140306-2 44.3 90 110mg/L30
Thallium, dissolved M200.8 ICP-MS
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361610
WG361610ICV 04/02/14 0:03 105.9ICV MS140331-9 .05296 90 110mg/L.05
WG361610ICB 04/02/14 0:07ICB U -0.0003 0.0003mg/L
WG361610LFB 04/02/14 0:10 95.1LFB MS140331-2 .04772 85 115mg/L.0502
L17362-01AS 04/02/14 0:17 U 103.4AS MS140331-2 .05191 70 130mg/L.0502
L17362-01ASD 04/02/14 0:20 U 101ASD MS140331-2 .05071 2.3470 130mg/L 20.0502
Thallium, total M200.8 ICP-MS
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361587
WG361587ICV 04/01/14 19:17 107.3ICV MS140331-9 .05366 90 110mg/L.05
WG361587ICB 04/01/14 19:20ICB U -0.0003 0.0003mg/L
WG361306LRB 04/01/14 19:24LRB U -0.00022 0.00022mg/L
WG361306LFB 04/01/14 19:27 100.4LFB MS140320-2 .05042 85 115mg/L.0502
L17362-07LFM 04/01/14 20:49 U 101.8LFM MS140320-2 .05111 70 130mg/L.0502
L17362-07LFMD 04/01/14 20:52 U 101.4LFMD MS140320-2 .05091 0.3970 130mg/L 20.0502
Tin, dissolved M200.8 ICP-MS
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361610
WG361610ICV 04/02/14 0:03 98.8ICV MS140331-9 .04951 90 110mg/L.0501
WG361610ICB 04/02/14 0:07ICB U -0.0003 0.0003mg/L
WG361610LFB 04/02/14 0:10 90.3LFB MS140331-2 .04518 85 115mg/L.05005
L17362-01AS 04/02/14 0:17 U 96.1AS MS140331-2 .04808 70 130mg/L.05005
L17362-01ASD 04/02/14 0:20 U 95.6ASD MS140331-2 .04783 0.5270 130mg/L 20.05005
Page 46 of 63L17362-1404111040
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic QC
Summary
ACZ Project ID: L17362SPF Water Engineering
Tin, total M200.8 ICP-MS
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361587
WG361587ICV 04/01/14 19:17 98.3ICV MS140331-9 .04927 90 110mg/L.0501
WG361587ICB 04/01/14 19:20ICB U -0.0003 0.0003mg/L
WG361306LRB BF04/01/14 19:24LRB .00034 -0.00022 0.00022mg/L
WG361306LFB 04/01/14 19:27 98LFB MS140320-2 .04907 85 115mg/L.05005
L17362-07LFM 04/01/14 20:49 U 98.5LFM MS140320-2 .0493 70 130mg/L.05005
L17362-07LFMD 04/01/14 20:52 U 98.4LFMD MS140320-2 .04923 0.1470 130mg/L 20.05005
WG362051
WG362051ICV 04/09/14 19:17 102.2ICV MS140331-9 .05122 90 110mg/L.0501
WG362051ICB 04/09/14 19:21ICB U -0.0003 0.0003mg/L
WG361782LRB 04/09/14 19:24LRB U -0.00022 0.00022mg/L
WG361782LFB 04/09/14 19:27 104.5LFB MS140331-2 .05231 85 115mg/L.05005
L17464-02LFM 04/09/14 20:08 U 107.5LFM MS140331-2 .05382 70 130mg/L.05005
L17464-02LFMD 04/09/14 20:12 U 105.8LFMD MS140331-2 .05295 1.6370 130mg/L 20.05005
Titanium, dissolved M200.7 ICP
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361133
WG361133ICV 03/25/14 9:27 96.3ICV II140220-1 1.9255 95 105mg/L2
WG361133ICB 03/25/14 9:33ICB U -0.015 0.015mg/L
WG361133LFB 03/25/14 9:46 88.6LFB II140317-2 .8857 85 115mg/L1
L17312-02AS 03/25/14 9:55 U 88.2AS II140317-2 .8822 85 115mg/L1
L17312-02ASD 03/25/14 9:58 U 87.3ASD II140317-2 .8734 185 115mg/L 201
L17362-06AS 03/25/14 10:36 U 87.6AS II140317-2 .8762 85 115mg/L1
L17362-06ASD 03/25/14 10:39 U 87.5ASD II140317-2 .8746 0.1885 115mg/L 201
Titanium, total M200.7 ICP
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361367
WG361367ICV 03/28/14 10:16 97ICV II140228-1 1.939 95 105mg/L2
WG361367ICB 03/28/14 10:22ICB U -0.015 0.015mg/L
WG361311LRB 03/28/14 10:35LRB U -0.011 0.011mg/L
WG361311LFB 03/28/14 10:38 100.6LFB II140317-2 1.006 85 115mg/L1
L17343-01LFM 03/28/14 10:57 .006 101.2LFM II140317-2 1.018 70 130mg/L1
L17343-01LFMD 03/28/14 11:00 .006 101.1LFMD II140317-2 1.017 0.170 130mg/L 201
L17362-03LFM 03/28/14 11:32 .112 107LFM II140317-2 1.182 70 130mg/L1
L17362-03LFMD 03/28/14 11:35 .112 107LFMD II140317-2 1.182 070 130mg/L 201
Uranium, dissolved M200.8 ICP-MS
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361610
WG361610ICV 04/02/14 0:03 102.8ICV MS140331-9 .05141 90 110mg/L.05
WG361610ICB 04/02/14 0:07ICB U -0.0003 0.0003mg/L
WG361610LFB 04/02/14 0:10 98LFB MS140331-2 .04901 85 115mg/L.05
L17362-01AS 04/02/14 0:17 U 108.2AS MS140331-2 .05409 70 130mg/L.05
L17362-01ASD 04/02/14 0:20 U 108ASD MS140331-2 .05401 0.1570 130mg/L 20.05
Page 47 of 63L17362-1404111040
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic QC
Summary
ACZ Project ID: L17362SPF Water Engineering
Uranium, total M200.8 ICP-MS
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361587
WG361587ICV 04/01/14 19:17 105.3ICV MS140331-9 .05266 90 110mg/L.05
WG361587ICB 04/01/14 19:20ICB U -0.0003 0.0003mg/L
WG361306LRB 04/01/14 19:24LRB U -0.00022 0.00022mg/L
WG361306LFB 04/01/14 19:27 103.8LFB MS140320-2 .05191 85 115mg/L.05
L17362-07LFM 04/01/14 20:49 .0029 107.6LFM MS140320-2 .0567 70 130mg/L.05
L17362-07LFMD 04/01/14 20:52 .0029 107.5LFMD MS140320-2 .05665 0.0970 130mg/L 20.05
Vanadium, dissolved M200.8 ICP-MS
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361610
WG361610ICV 04/02/14 0:03 97.5ICV MS140331-9 .04874 90 110mg/L.05
WG361610ICB 04/02/14 0:07ICB U -0.0006 0.0006mg/L
WG361610LFB 04/02/14 0:10 93.7LFB MS140331-2 .04691 85 115mg/L.05005
L17362-01AS 04/02/14 0:17 U 98.3AS MS140331-2 .04919 70 130mg/L.05005
L17362-01ASD 04/02/14 0:20 U 97ASD MS140331-2 .04855 1.3170 130mg/L 20.05005
Vanadium, total M200.8 ICP-MS
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361587
WG361587ICV 04/01/14 19:17 98.4ICV MS140331-9 .04919 90 110mg/L.05
WG361587ICB 04/01/14 19:20ICB U -0.0006 0.0006mg/L
WG361306LRB 04/01/14 19:24LRB U -0.00044 0.00044mg/L
WG361306LFB 04/01/14 19:27 99.6LFB MS140320-2 .04985 85 115mg/L.05005
L17362-07LFM 04/01/14 20:49 .0207 99.7LFM MS140320-2 .07059 70 130mg/L.05005
L17362-07LFMD 04/01/14 20:52 .0207 98.4LFMD MS140320-2 .06994 0.9370 130mg/L 20.05005
Zinc, dissolved M200.7 ICP
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361133
WG361133ICV 03/25/14 9:27 96.8ICV II140220-1 1.935 95 105mg/L2
WG361133ICB 03/25/14 9:33ICB U -0.03 0.03mg/L
WG361133LFB 03/25/14 9:46 88.5LFB II140317-2 .443 85 115mg/L.5005
L17312-02AS 03/25/14 9:55 U 87.3AS II140317-2 .437 85 115mg/L.5005
L17312-02ASD 03/25/14 9:58 U 87.3ASD II140317-2 .437 085 115mg/L 20.5005
L17362-06AS 03/25/14 10:36 U 85.3AS II140317-2 .427 85 115mg/L.5005
L17362-06ASD 03/25/14 10:39 U 84.9ASD II140317-2 .425 0.4785 115mg/L 20.5005
Page 48 of 63L17362-1404111040
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic QC
Summary
ACZ Project ID: L17362SPF Water Engineering
Zinc, total M200.7 ICP
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361367
WG361367ICV 03/28/14 10:16 97.8ICV II140228-1 1.955 95 105mg/L2
WG361367ICB 03/28/14 10:22ICB U -0.03 0.03mg/L
WG361311LRB 03/28/14 10:35LRB U -0.022 0.022mg/L
WG361311LFB 03/28/14 10:38 103.1LFB II140317-2 .516 85 115mg/L.5005
L17343-01LFM 03/28/14 10:57 U 105.3LFM II140317-2 .527 70 130mg/L.5005
L17343-01LFMD 03/28/14 11:00 U 104.9LFMD II140317-2 .525 0.3870 130mg/L 20.5005
L17362-03LFM 03/28/14 11:32 .02 102.3LFM II140317-2 .532 70 130mg/L.5005
L17362-03LFMD 03/28/14 11:35 .02 101.7LFMD II140317-2 .529 0.5770 130mg/L 20.5005
Page 49 of 63L17362-1404111040
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic Extended
Qualifier Report
ACZ Project ID: L17362SPF Water Engineering
ACZ ID PARAMETER QUAL DESCRIPTIONMETHODWORKNUM
M2 Matrix spike recovery was low, the recovery of the associated control sample (LCS or LFB) was acceptable.
M200.7 ICPBarium, dissolvedL17362-01 WG361133
MA Recovery for either the spike or spike duplicate was outside of the acceptance limits; the RPD was within the acceptance limits.
M200.7 ICPBoron, dissolved
M2 Matrix spike recovery was low, the recovery of the associated control sample (LCS or LFB) was acceptable.
M200.7 ICPLithium, dissolved
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
M300.0 - Ion ChromatographyChlorideWG361247
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
M335.4 - Colorimetric w/ distillation
Cyanide, totalWG361515
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
SM4500-CN I-Colorimetric w/ distillation
Cyanide, WADWG361379
DC Sample required dilution. Non-target analyte exceeded calibration range.
M300.0 - Ion ChromatographyFluorideWG361247
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
M300.0 - Ion Chromatography
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
M350.1 - Automated PhenateNitrogen, ammoniaWG361369
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
M365.1 - Auto Ascorbic Acid (digest)
Phosphorus, totalWG361833
RO The duplicate originally assigned to this sample was not used for precision assessment because residue density exceeded the method limits. Another duplicate in the batch was used to assess precision. Method required duplicate frequency was not met.
SM2540CResidue, Filterable (TDS) @180CWG361151
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
SM2540DResidue, Non-Filterable (TSS) @105CWG361160
RA Relative Percent Difference (RPD) was not used for data
validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
SM2320B - TitrationTotal AlkalinityWG361281
REPAD.15.06.05.01
Page 50 of 63L17362-1404111040
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic Extended
Qualifier Report
ACZ Project ID: L17362SPF Water Engineering
ACZ ID PARAMETER QUAL DESCRIPTIONMETHODWORKNUM
M1 Matrix spike recovery was high, the recovery of the associated control sample (LCS or LFB) was acceptable.
M200.7 ICPAluminum, totalL17362-02 WG361367
M2 Matrix spike recovery was low, the recovery of the associated control sample (LCS or LFB) was acceptable.
M200.7 ICPBarium, dissolvedWG361133
MA Recovery for either the spike or spike duplicate was outside of the acceptance limits; the RPD was within the acceptance limits.
M200.7 ICPBoron, dissolved
M3 The spike recovery value is unusable since the analyte concentration in the sample is disproportionate to the spike level. The recovery of the associated control sample (LCS or LFB) was acceptable.
M200.7 ICPIron, totalWG361367
M2 Matrix spike recovery was low, the recovery of the associated control sample (LCS or LFB) was acceptable.
M200.7 ICPLithium, dissolvedWG361133
BF Target analyte in prep / method blank at or above the acceptance criteria. Target analyte was not detected in the sample [< MDL].
M200.8 ICP-MSTin, totalWG361587
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
M300.0 - Ion ChromatographyChlorideWG361247
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
M335.4 - Colorimetric w/ distillation
Cyanide, totalWG361515
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
SM4500-CN I-Colorimetric w/ distillation
Cyanide, WADWG361379
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
M300.0 - Ion ChromatographyFluorideWG361247
M1 Matrix spike recovery was high, the recovery of the associated control sample (LCS or LFB) was acceptable.
M350.1 - Automated PhenateNitrogen, ammoniaWG361369
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
M350.1 - Automated Phenate
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
M365.1 - Auto Ascorbic Acid (digest)
Phosphorus, totalWG361833
RO The duplicate originally assigned to this sample was not used for precision assessment because residue density exceeded the method limits. Another duplicate in the batch was used to assess precision. Method required duplicate frequency was not met.
SM2540CResidue, Filterable (TDS) @180CWG361151
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
SM2540DResidue, Non-Filterable (TSS) @105CWG361160
RA Relative Percent Difference (RPD) was not used for data
validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
SM2320B - TitrationTotal AlkalinityWG361281
REPAD.15.06.05.01
Page 51 of 63L17362-1404111040
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic Extended
Qualifier Report
ACZ Project ID: L17362SPF Water Engineering
ACZ ID PARAMETER QUAL DESCRIPTIONMETHODWORKNUM
DJ Sample dilution required due to insufficient sample.M200.2 ICP-MSTotal Hot Plate DigestionL17362-03 WG361782
M1 Matrix spike recovery was high, the recovery of the associated control sample (LCS or LFB) was acceptable.
M200.7 ICPAluminum, totalWG361367
M2 Matrix spike recovery was low, the recovery of the associated control sample (LCS or LFB) was acceptable.
M200.7 ICPBarium, dissolvedWG361133
MA Recovery for either the spike or spike duplicate was outside of the acceptance limits; the RPD was within the acceptance limits.
M200.7 ICPBoron, dissolved
M3 The spike recovery value is unusable since the analyte
concentration in the sample is disproportionate to the spike level. The recovery of the associated control sample (LCS or LFB) was acceptable.
M200.7 ICPIron, totalWG361367
M2 Matrix spike recovery was low, the recovery of the associated control sample (LCS or LFB) was acceptable.
M200.7 ICPLithium, dissolvedWG361133
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
M300.0 - Ion ChromatographyChlorideWG361247
RA Relative Percent Difference (RPD) was not used for data
validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
M335.4 - Colorimetric w/
distillation
Cyanide, totalWG361515
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
SM4500-CN I-Colorimetric w/ distillation
Cyanide, WADWG361379
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
M300.0 - Ion ChromatographyFluorideWG361247
M1 Matrix spike recovery was high, the recovery of the
associated control sample (LCS or LFB) was acceptable.
M350.1 - Automated PhenateNitrogen, ammoniaWG361369
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
M350.1 - Automated Phenate
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
M365.1 - Auto Ascorbic Acid (digest)
Phosphorus, totalWG361833
RO The duplicate originally assigned to this sample was not used for precision assessment because residue density exceeded the method limits. Another duplicate in the batch was used to assess precision. Method required duplicate frequency was not met.
SM2540CResidue, Filterable (TDS) @180CWG361151
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
SM2540DResidue, Non-Filterable (TSS) @105CWG361160
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
SM2320B - TitrationTotal AlkalinityWG361281
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
M335.4 - Colorimetric w/ distillation
Cyanide, totalL17362-04 WG361515
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
SM4500-CN I-Colorimetric w/ distillation
Cyanide, WADWG361524
REPAD.15.06.05.01
Page 52 of 63L17362-1404111040
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic Extended
Qualifier Report
ACZ Project ID: L17362SPF Water Engineering
ACZ ID PARAMETER QUAL DESCRIPTIONMETHODWORKNUM
M1 Matrix spike recovery was high, the recovery of the associated control sample (LCS or LFB) was acceptable.
M200.7 ICPAluminum, totalL17362-05 WG361367
M2 Matrix spike recovery was low, the recovery of the associated control sample (LCS or LFB) was acceptable.
M200.7 ICPBarium, dissolvedWG361133
MA Recovery for either the spike or spike duplicate was outside of the acceptance limits; the RPD was within the acceptance limits.
M200.7 ICPBoron, dissolved
M3 The spike recovery value is unusable since the analyte concentration in the sample is disproportionate to the spike level. The recovery of the associated control sample (LCS or LFB) was acceptable.
M200.7 ICPIron, totalWG361367
M2 Matrix spike recovery was low, the recovery of the associated control sample (LCS or LFB) was acceptable.
M200.7 ICPLithium, dissolvedWG361133
BF Target analyte in prep / method blank at or above the acceptance criteria. Target analyte was not detected in the sample [< MDL].
M200.8 ICP-MSTin, totalWG361587
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
M300.0 - Ion ChromatographyChlorideWG361247
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
M335.4 - Colorimetric w/ distillation
Cyanide, totalWG361515
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
SM4500-CN I-Colorimetric w/ distillation
Cyanide, WADWG361524
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
M300.0 - Ion ChromatographyFluorideWG361247
M1 Matrix spike recovery was high, the recovery of the associated control sample (LCS or LFB) was acceptable.
M350.1 - Automated PhenateNitrogen, ammoniaWG361369
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
M350.1 - Automated Phenate
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
M365.1 - Auto Ascorbic Acid (digest)
Phosphorus, totalWG361833
RO The duplicate originally assigned to this sample was not used for precision assessment because residue density exceeded the method limits. Another duplicate in the batch was used to assess precision. Method required duplicate frequency was not met.
SM2540CResidue, Filterable (TDS) @180CWG361151
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
SM2540DResidue, Non-Filterable (TSS) @105CWG361160
RA Relative Percent Difference (RPD) was not used for data
validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
SM2320B - TitrationTotal AlkalinityWG361281
REPAD.15.06.05.01
Page 53 of 63L17362-1404111040
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic Extended
Qualifier Report
ACZ Project ID: L17362SPF Water Engineering
ACZ ID PARAMETER QUAL DESCRIPTIONMETHODWORKNUM
M1 Matrix spike recovery was high, the recovery of the associated control sample (LCS or LFB) was acceptable.
M200.7 ICPAluminum, totalL17362-06 WG361367
M2 Matrix spike recovery was low, the recovery of the associated control sample (LCS or LFB) was acceptable.
M200.7 ICPBarium, dissolvedWG361133
M3 The spike recovery value is unusable since the analyte concentration in the sample is disproportionate to the spike level. The recovery of the associated control sample (LCS or LFB) was acceptable.
M200.7 ICPIron, totalWG361367
M2 Matrix spike recovery was low, the recovery of the associated control sample (LCS or LFB) was acceptable.
M200.7 ICPLithium, dissolvedWG361133
BF Target analyte in prep / method blank at or above the acceptance criteria. Target analyte was not detected in the sample [< MDL].
M200.8 ICP-MSTin, totalWG361587
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
M300.0 - Ion ChromatographyChlorideWG361247
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
M335.4 - Colorimetric w/ distillation
Cyanide, totalWG361515
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
SM4500-CN I-Colorimetric w/ distillation
Cyanide, WADWG361524
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
M300.0 - Ion ChromatographyFluorideWG361247
M1 Matrix spike recovery was high, the recovery of the associated control sample (LCS or LFB) was acceptable.
M350.1 - Automated PhenateNitrogen, ammoniaWG361369
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
M350.1 - Automated Phenate
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
M365.1 - Auto Ascorbic Acid (digest)
Phosphorus, totalWG361833
RO The duplicate originally assigned to this sample was not used for precision assessment because residue density exceeded the method limits. Another duplicate in the batch was used to assess precision. Method required duplicate frequency was not met.
SM2540CResidue, Filterable (TDS) @180CWG361151
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
SM2540DResidue, Non-Filterable (TSS) @105CWG361160
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
SM2320B - TitrationTotal AlkalinityWG361281
REPAD.15.06.05.01
Page 54 of 63L17362-1404111040
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic Extended
Qualifier Report
ACZ Project ID: L17362SPF Water Engineering
ACZ ID PARAMETER QUAL DESCRIPTIONMETHODWORKNUM
M1 Matrix spike recovery was high, the recovery of the associated control sample (LCS or LFB) was acceptable.
M200.7 ICPAluminum, totalL17362-07 WG361367
M2 Matrix spike recovery was low, the recovery of the associated control sample (LCS or LFB) was acceptable.
M200.7 ICPBarium, dissolvedWG361133
M3 The spike recovery value is unusable since the analyte concentration in the sample is disproportionate to the spike level. The recovery of the associated control sample (LCS or LFB) was acceptable.
M200.7 ICPIron, totalWG361367
M2 Matrix spike recovery was low, the recovery of the associated control sample (LCS or LFB) was acceptable.
M200.7 ICPLithium, dissolvedWG361133
BF Target analyte in prep / method blank at or above the acceptance criteria. Target analyte was not detected in the sample [< MDL].
M200.8 ICP-MSTin, totalWG361587
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
M300.0 - Ion ChromatographyChlorideWG361247
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
M335.4 - Colorimetric w/ distillation
Cyanide, totalWG361515
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
SM4500-CN I-Colorimetric w/ distillation
Cyanide, WADWG361524
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
M300.0 - Ion ChromatographyFluorideWG361247
M1 Matrix spike recovery was high, the recovery of the associated control sample (LCS or LFB) was acceptable.
M350.1 - Automated PhenateNitrogen, ammoniaWG361369
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
M350.1 - Automated Phenate
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
M365.1 - Auto Ascorbic Acid (digest)
Phosphorus, totalWG361833
RO The duplicate originally assigned to this sample was not used for precision assessment because residue density exceeded the method limits. Another duplicate in the batch was used to assess precision. Method required duplicate frequency was not met.
SM2540CResidue, Filterable (TDS) @180CWG361151
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
SM2540DResidue, Non-Filterable (TSS) @105CWG361160
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
SM2320B - TitrationTotal AlkalinityWG361281
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
M335.4 - Colorimetric w/ distillation
Cyanide, totalL17362-08 WG361515
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
SM4500-CN I-Colorimetric w/ distillation
Cyanide, WADWG361524
REPAD.15.06.05.01
Page 55 of 63L17362-1404111040
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Certification
Qualifiers
ACZ Project ID: L17362SPF Water Engineering
Metals Analysis
The following parameters are not offered for certification or are not covered by NELAC certificate #ACZ.
Bismuth, dissolved M200.7 ICP
Bismuth, total M200.7 ICP
Gallium, dissolved M200.7 ICP
Gallium, total M200.7 ICP
Scandium, dissolved M200.7 ICP
Scandium, total M200.7 ICP
Tin, dissolved M200.8 ICP-MS
Tin, total M200.8 ICP-MS
REPAD.05.06.05.01
Page 56 of 63L17362-1404111040
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Sample
Receipt
SPF Water EngineeringCalico 1st Quarter 2014 Sampling
ACZ Project ID:
Date Received:
Received By: mtb
03/21/2014 08:44
L17362
Date Printed: 3/21/2014
Chain of Custody Related Remarks
Client Contact Remarks
NANOYES
X
X
X
X
X
X
1) Is a foreign soil permit included for applicable samples?
2) Is the Chain of Custody or other directive shipping papers present?
3) Does this project require special handling procedures such as CLP protocol?
4) Are any samples NRC licensable material?
5) If samples are received past hold time, proceed with requested short hold time analyses?
6) Is the Chain of Custody complete and accurate?
7) Were any changes made to the Chain of Custody prior to ACZ receiving the samples?
Receipt Verification
NANOYES
X
X
X
X
X
X
X
X
X8) Are all containers intact and with no leaks?
9) Are all labels on containers and are they intact and legible?
10) Do the sample labels and Chain of Custody match for Sample ID, Date, and Time?
11) For preserved bottle types, was the pH checked and within limits?
12) Is there sufficient sample volume to perform all requested work?
13) Is the custody seal intact on all containers?
14) Are samples that require zero headspace acceptable?
15) Are all sample containers appropriate for analytical requirements?
16) Is there an Hg-1631 trip blank present?
17) Is there a VOA trip blank present?
18) Were all samples received within hold time?
Samples/Containers
X
X
Shipping Containers
Client must contact an ACZ Project Manager if analysis should not proceed for samples received outside of their thermal preservation acceptance criteria.
Cooler Id Temp (°C) Rad (µR/Hr) Custody Seal Intact?--------- --------- ----------- ------- -------------NA19328 0.5 16 Yes
X
Was ice present in the shipment container(s)?
Yes - Wet ice was present in the shipment container (s).
REPAD LPII 2012-03
Page 57 of 63L17362-1404111040
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Analytical
Report
SPF Water Engineering
300 E. Mallard Drive, Suite 350
Boise, ID 83706
ACZ Project ID: L17433
Jason Thompson:
Enclosed are the analytical results for sample(s) submitted to ACZ Laboratories, Inc. (ACZ) on March 26, 2014. This project has been assigned to ACZ's project number, L17433. Please reference this number in all future inquiries.
All analyses were performed according to ACZ's Quality Assurance Plan. The enclosed results relate only to the samples received under L17433. Each section of this report has been reviewed and approved by the appropriate Laboratory Supervisor, or a qualified substitute.
Except as noted, the test results for the methods and parameters listed on ACZ's current NELAC certificate letter (#ACZ) meet all requirements of NELAC.
This report shall be used or copied only in its entirety. ACZ is not responsible for the consequences arising from the use of a partial report.
All samples and sub-samples associated with this project will be disposed of after May 14, 2014. If the samples are determined to be hazardous, additional charges apply for disposal (typically $11/sample). If you would like the samples to be held longer than ACZ's stated policy or to be returned, please contact your Project Manager or Customer Service Representative for further details and associated costs. ACZ retains analytical raw data reports for ten years.
If you have any questions or other needs, please contact your Project Manager.
Jason Thompson
April 14, 2014
Project ID: Calico 1st Quarter 2014 Sampli
SPF Water Engineering
300 E. Mallard Drive, Suite 350
Boise, ID 83706
Crystal Jensen
Report to: Bill to:
Page 1 of 60L17433-1404141323
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Case
Narrative
SPF Water Engineering
ACZ Project ID: L17433
April 14, 2014
Sample Receipt
Sample Analysis
Holding Times
Text10:ACZ Laboratories, Inc. (ACZ) received 9 ground water samples from SPF Water Engineering on March 26, 2014. The samples were received in good condition. Upon receipt, the sample custodian removed the samples from the cooler, inspected the contents, and logged the samples into ACZ's computerized Laboratory Information Management System (LIMS). The samples were assigned ACZ LIMS project number L17433. The custodian verified the sample information entered into the computer against the chain of custody (COC) forms and sample bottle labels.
Text10:These samples were analyzed for inorganic parameters. The individual methods are referenced on both the ACZ invoice and the analytical reports. The extended qualifier reports may contain footnotes qualifying specific elements due to QC failures. In addition the following has been noted with this specific project:
Some of the dissolved Cobalt values exceed the corresponding total values for project L17433. In some cases, RPDs between dissolved and total values exceed the standard acceptance limit of 20%. Samples were re-analyzed for verification, and results for both parameters were confirmed. This is a consistent anomaly with these sample types, and discrepancies may be attributed to a matrix or field sampling issue.
Text10:Any analyses not performed within EPA recommended holding times have been qualified with an "H" flag.
Project ID: Calico 1st Quarter 2014 Sampli
REPAD.03.06.05.01 Page 2 of 60L17433-1404141323
ACZ Sample ID: L17433-01
Sample ID: 59772
Sample Matrix: Ground Water
SPF Water Engineering
Project ID: Calico 1st Quarter 2014 Sa
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic Analytical
Results
Date Sampled: 03/24/14 11:05
Date Received: 03/26/14
Parameter EPA Method Result Units MDLQual AnalystDatePQL
Inorganic Prep
XQDilution
Cyanide, total M335.4 - Manual Distillation tcd04/01/14 15:31
Cyanide, WAD SM4500-CN I- distillation mpb03/31/14 15:23
Phosphorus, total M365.1 - Auto Ascorbic Acid Digestion
bsu04/01/14 15:30
Total Hot Plate Digestion
M200.2 ICP jjc03/31/14 11:54
Total Hot Plate Digestion
M200.2 ICP-MS las04/02/14 11:13
REPIN.02.06.05.01 * Please refer to Qualifier Reports for details.
Page 3 of 60L17433-1404141323
ACZ Sample ID: L17433-01
Sample ID: 59772
Sample Matrix: Ground Water
SPF Water Engineering
Project ID: Calico 1st Quarter 2014 Sa
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic Analytical
Results
Date Sampled: 03/24/14 11:05
Date Received: 03/26/14
Parameter EPA Method Result Units MDLQual AnalystDatePQL
Metals Analysis
XQDilution
Aluminum, dissolved M200.7 ICP mg/L 0.2U aeb0.03 03/27/14 16:411
Aluminum, total M200.7 ICP mg/L 0.2U jjc0.03* 04/01/14 10:301
Antimony, dissolved M200.8 ICP-MS 0.0006 mg/L 0.002B msh0.0004 04/07/14 15:431
Antimony, total M200.8 ICP-MS 0.0007 mg/L 0.002B msh0.0004 04/03/14 22:071
Arsenic, dissolved M200.8 ICP-MS 0.0372 mg/L 0.001 msh0.0002 04/07/14 15:431
Arsenic, total M200.8 ICP-MS 0.0348 mg/L 0.001 msh0.0002 04/03/14 22:071
Barium, dissolved M200.7 ICP 0.024 mg/L 0.02 aeb0.003 03/27/14 16:411
Barium, total M200.7 ICP 0.030 mg/L 0.02 jjc0.003 04/01/14 16:201
Beryllium, dissolved M200.8 ICP-MS mg/L 0.0003U pmc0.00005 04/09/14 4:331
Beryllium, total M200.8 ICP-MS mg/L 0.0003U msh0.00005 04/03/14 22:071
Bismuth, dissolved M200.7 ICP mg/L 0.2U aeb0.04* 03/27/14 16:411
Bismuth, total M200.7 ICP mg/L 0.2U jjc0.04* 04/01/14 10:301
Boron, dissolved M200.7 ICP 0.08 mg/L 0.05 aeb0.01 03/27/14 16:411
Boron, total M200.7 ICP 0.07 mg/L 0.05 jjc0.01 04/01/14 10:301
Cadmium, dissolved M200.8 ICP-MS mg/L 0.0005U pmc0.0001 04/09/14 4:331
Cadmium, total M200.8 ICP-MS mg/L 0.0005U msh0.0001 04/03/14 22:071
Calcium, dissolved M200.7 ICP 37.9 mg/L 0.5 aeb0.1 03/27/14 16:411
Calcium, total M200.7 ICP 37.6 mg/L 0.5 jjc0.1 04/01/14 10:301
Chromium, dissolved M200.8 ICP-MS 0.0007 mg/L 0.002B msh0.0005 04/07/14 15:431
Chromium, total M200.8 ICP-MS 0.0008 mg/L 0.002B msh0.0005 04/03/14 22:071
Cobalt, dissolved M200.8 ICP-MS 0.00016 mg/L 0.0003B msh0.00005 04/07/14 15:431
Cobalt, total M200.8 ICP-MS 0.00008 mg/L 0.0003B msh0.00005 04/03/14 22:071
Copper, dissolved M200.8 ICP-MS mg/L 0.003U msh0.0005 04/07/14 15:431
Copper, total M200.8 ICP-MS mg/L 0.003U msh0.0005 04/03/14 22:071
Gallium, dissolved M200.7 ICP mg/L 0.5U aeb0.1* 03/27/14 16:411
Gallium, total M200.7 ICP mg/L 0.5U jjc0.1* 04/01/14 10:301
Iron, dissolved M200.7 ICP mg/L 0.05U aeb0.02 03/27/14 16:411
Iron, total M200.7 ICP mg/L 0.05U jjc0.02 04/01/14 10:301
Lead, dissolved M200.8 ICP-MS mg/L 0.0005U msh0.0001 04/07/14 15:431
Lead, total M200.8 ICP-MS mg/L 0.0005U msh0.0001 04/03/14 22:071
Lithium, dissolved M200.7 ICP 0.038 mg/L 0.04B aeb0.008 03/27/14 16:411
Lithium, total M200.7 ICP 0.046 mg/L 0.04 jjc0.008 04/01/14 10:301
Magnesium, dissolved M200.7 ICP 6.8 mg/L 1 aeb0.2 03/27/14 16:411
Magnesium, total M200.7 ICP 6.8 mg/L 1 jjc0.2 04/01/14 10:301
Manganese, dissolved M200.8 ICP-MS mg/L 0.003U msh0.0005 04/07/14 15:431
Manganese, total M200.8 ICP-MS mg/L 0.003U msh0.0005 04/03/14 22:071
Mercury, dissolved M1631, Atomic Fluorescence ng/L 0.5U las0.2 04/01/14 17:261
Mercury, total M1631, Atomic Fluorescence ng/L 0.5U las0.2 04/03/14 10:171
Molybdenum, dissolved M200.8 ICP-MS 0.0034 mg/L 0.003 msh0.0005 04/07/14 15:431
Molybdenum, total M200.8 ICP-MS 0.0038 mg/L 0.003 msh0.0005 04/03/14 22:071
Nickel, dissolved M200.8 ICP-MS mg/L 0.003U msh0.0006 04/07/14 15:431
Nickel, total M200.8 ICP-MS mg/L 0.003U msh0.0006 04/03/14 22:071
Potassium, dissolved M200.7 ICP 5.8 mg/L 1 aeb0.2 03/27/14 16:411
REPIN.02.06.05.01 * Please refer to Qualifier Reports for details.
Page 4 of 60L17433-1404141323
ACZ Sample ID: L17433-01
Sample ID: 59772
Sample Matrix: Ground Water
SPF Water Engineering
Project ID: Calico 1st Quarter 2014 Sa
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic Analytical
Results
Date Sampled: 03/24/14 11:05
Date Received: 03/26/14
Potassium, total M200.7 ICP 5.9 mg/L 1 jjc0.2 04/01/14 10:301
Scandium, dissolved M200.7 ICP mg/L 0.5U aeb0.1* 03/27/14 16:411
Scandium, total M200.7 ICP mg/L 0.5U jjc0.1* 04/01/14 10:301
Selenium, dissolved M200.8 ICP-MS 0.0030 mg/L 0.0003 pmc0.0001 04/09/14 4:331
Selenium, total M200.8 ICP-MS 0.0025 mg/L 0.0003 msh0.0001 04/03/14 22:071
Silver, dissolved M200.8 ICP-MS mg/L 0.0003U msh0.00005 04/07/14 15:431
Silver, total M200.8 ICP-MS mg/L 0.0003U msh0.00005 04/03/14 22:071
Sodium, dissolved M200.7 ICP 25.3 mg/L 1 aeb0.2 03/27/14 16:411
Sodium, total M200.7 ICP 25.4 mg/L 1 jjc0.2 04/01/14 10:301
Strontium, dissolved M200.7 ICP 0.196 mg/L 0.03 aeb0.005 03/27/14 16:411
Strontium, total M200.7 ICP 0.202 mg/L 0.03 jjc0.005 04/01/14 10:301
Thallium, dissolved M200.8 ICP-MS mg/L 0.0005U msh0.0001 04/07/14 15:431
Thallium, total M200.8 ICP-MS mg/L 0.0005U msh0.0001 04/03/14 22:071
Tin, dissolved M200.8 ICP-MS mg/L 0.0005U msh0.0001* 04/07/14 15:431
Tin, total M200.8 ICP-MS mg/L 0.0005U msh0.0001* 04/03/14 22:071
Titanium, dissolved M200.7 ICP mg/L 0.03U aeb0.005 03/27/14 16:411
Titanium, total M200.7 ICP mg/L 0.03U jjc0.005 04/01/14 10:301
Uranium, dissolved M200.8 ICP-MS 0.0015 mg/L 0.0005 msh0.0001 04/07/14 15:431
Uranium, total M200.8 ICP-MS 0.0017 mg/L 0.0005 msh0.0001 04/03/14 22:071
Vanadium, dissolved M200.8 ICP-MS 0.0168 mg/L 0.001 msh0.0002 04/07/14 15:431
Vanadium, total M200.8 ICP-MS 0.0181 mg/L 0.001 msh0.0002 04/03/14 22:071
Zinc, dissolved M200.7 ICP mg/L 0.05U aeb0.01 03/27/14 16:411
Zinc, total M200.7 ICP mg/L 0.05U jjc0.01 04/01/14 10:301
REPIN.02.06.05.01 * Please refer to Qualifier Reports for details.
Page 5 of 60L17433-1404141323
ACZ Sample ID: L17433-01
Sample ID: 59772
Sample Matrix: Ground Water
SPF Water Engineering
Project ID: Calico 1st Quarter 2014 Sa
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic Analytical
Results
Date Sampled: 03/24/14 11:05
Date Received: 03/26/14
Parameter EPA Method Result Units MDLQual AnalystDatePQL
Wet Chemistry
XQDilution
Alkalinity as CaCO3 SM2320B - Titration
Bicarbonate as CaCO3
102 mg/L 20 dcw2 03/27/14 0:001
Carbonate as CaCO3 mg/L 20U dcw2 03/27/14 0:001
Hydroxide as CaCO3 mg/L 20U dcw2 03/27/14 0:001
Total Alkalinity 102 mg/L 20 dcw2 03/27/14 0:001
Chloride M300.0 - Ion Chromatography 10.5 mg/L 2.5 tcd0.5* 04/03/14 19:301
Conductivity @25C SM2510B 351 umhos/cm 10 dcw1 03/27/14 4:201
Cyanide, total M335.4 - Colorimetric w/ distillation mg/L 0.01U tcd0.003* 04/02/14 13:530.5
Cyanide, WAD SM4500-CN I-Colorimetric w/ distillation
mg/L 0.01U mpb0.003* 03/31/14 16:280.5
Fluoride M300.0 - Ion Chromatography 0.45 mg/L 0.5B tcd0.1* 04/03/14 19:301
Hardness as CaCO3 SM2340B - Calculation 123 mg/L 7 calc1 04/14/14 8:40
Nitrate/Nitrite as N M353.2 - H2SO4 preserved 1.28 mg/L 0.1 pjb0.02* 04/05/14 14:541
Nitrogen, ammonia M350.1 - Automated Phenate mg/L 0.5U tcd0.05* 04/02/14 12:501
pH (lab) SM4500H+ B
pH 8.2 units 0.1H dcw0.1 03/27/14 0:001
pH measured at 23 C 0.1 dcw0.1 03/27/14 0:001
Phosphorus, total M365.1 - Auto Ascorbic Acid (digest)
0.03 mg/L 0.05B pjb0.01* 04/02/14 23:491
Residue, Filterable (TDS) @180C
SM2540C 280 mg/L 20 enb10 03/28/14 14:521
Residue, Non-Filterable (TSS) @105C
SM2540D mg/L 20U dcw5* 03/28/14 15:151
Sulfate M300.0 - Ion Chromatography 36.6 mg/L 2.5 tcd0.5* 04/03/14 19:301
REPIN.02.06.05.01 * Please refer to Qualifier Reports for details.
Page 6 of 60L17433-1404141323
ACZ Sample ID: L17433-02
Sample ID: 59760
Sample Matrix: Ground Water
SPF Water Engineering
Project ID: Calico 1st Quarter 2014 Sa
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic Analytical
Results
Date Sampled: 03/24/14 12:35
Date Received: 03/26/14
Parameter EPA Method Result Units MDLQual AnalystDatePQL
Inorganic Prep
XQDilution
Cyanide, total M335.4 - Manual Distillation tcd04/01/14 15:31
Cyanide, WAD SM4500-CN I- distillation mss204/02/14 9:46
Phosphorus, total M365.1 - Auto Ascorbic Acid Digestion
bsu04/01/14 15:39
Total Hot Plate Digestion
M200.2 ICP-MS las04/02/14 11:23
Total Hot Plate Digestion
M200.2 ICP jjc03/31/14 12:05
REPIN.02.06.05.01 * Please refer to Qualifier Reports for details.
Page 7 of 60L17433-1404141323
ACZ Sample ID: L17433-02
Sample ID: 59760
Sample Matrix: Ground Water
SPF Water Engineering
Project ID: Calico 1st Quarter 2014 Sa
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic Analytical
Results
Date Sampled: 03/24/14 12:35
Date Received: 03/26/14
Parameter EPA Method Result Units MDLQual AnalystDatePQL
Metals Analysis
XQDilution
Aluminum, dissolved M200.7 ICP mg/L 0.2U aeb0.03 03/27/14 16:561
Aluminum, total M200.7 ICP 0.59 mg/L 0.2 jjc0.03* 04/01/14 10:331
Antimony, dissolved M200.8 ICP-MS 0.0005 mg/L 0.002B msh0.0004 04/07/14 15:461
Antimony, total M200.8 ICP-MS 0.0006 mg/L 0.002B msh0.0004 04/03/14 22:101
Arsenic, dissolved M200.8 ICP-MS 0.0282 mg/L 0.001 msh0.0002 04/07/14 15:461
Arsenic, total M200.8 ICP-MS 0.0245 mg/L 0.001 msh0.0002 04/03/14 22:101
Barium, dissolved M200.7 ICP 0.046 mg/L 0.02 aeb0.003 03/27/14 16:561
Barium, total M200.7 ICP 0.055 mg/L 0.02 jjc0.003 04/01/14 16:231
Beryllium, dissolved M200.8 ICP-MS mg/L 0.0003U pmc0.00005 04/09/14 4:361
Beryllium, total M200.8 ICP-MS mg/L 0.0003U msh0.00005 04/03/14 22:101
Bismuth, dissolved M200.7 ICP mg/L 0.2U aeb0.04* 03/27/14 16:561
Bismuth, total M200.7 ICP mg/L 0.2U jjc0.04* 04/01/14 10:331
Boron, dissolved M200.7 ICP 0.08 mg/L 0.05 aeb0.01 03/27/14 16:561
Boron, total M200.7 ICP 0.07 mg/L 0.05 jjc0.01 04/01/14 10:331
Cadmium, dissolved M200.8 ICP-MS mg/L 0.0005U pmc0.0001 04/09/14 4:361
Cadmium, total M200.8 ICP-MS mg/L 0.0005U msh0.0001 04/03/14 22:101
Calcium, dissolved M200.7 ICP 38.8 mg/L 0.5 aeb0.1 03/27/14 16:561
Calcium, total M200.7 ICP 39 mg/L 0.5 jjc0.1 04/01/14 10:331
Chromium, dissolved M200.8 ICP-MS 0.0007 mg/L 0.002B msh0.0005 04/07/14 15:461
Chromium, total M200.8 ICP-MS 0.0007 mg/L 0.002B msh0.0005 04/03/14 22:101
Cobalt, dissolved M200.8 ICP-MS 0.00017 mg/L 0.0003B msh0.00005 04/07/14 15:461
Cobalt, total M200.8 ICP-MS 0.00017 mg/L 0.0003B msh0.00005 04/03/14 22:101
Copper, dissolved M200.8 ICP-MS 0.0062 mg/L 0.003 msh0.0005 04/07/14 15:461
Copper, total M200.8 ICP-MS 0.0115 mg/L 0.003 msh0.0005 04/03/14 22:101
Gallium, dissolved M200.7 ICP mg/L 0.5U aeb0.1* 03/27/14 16:561
Gallium, total M200.7 ICP mg/L 0.5U jjc0.1* 04/01/14 10:331
Iron, dissolved M200.7 ICP mg/L 0.05U aeb0.02 03/27/14 16:561
Iron, total M200.7 ICP 0.20 mg/L 0.05 jjc0.02 04/01/14 10:331
Lead, dissolved M200.8 ICP-MS mg/L 0.0005U msh0.0001 04/07/14 15:461
Lead, total M200.8 ICP-MS 0.0007 mg/L 0.0005 msh0.0001 04/03/14 22:101
Lithium, dissolved M200.7 ICP 0.047 mg/L 0.04 aeb0.008 03/27/14 16:561
Lithium, total M200.7 ICP 0.055 mg/L 0.04 jjc0.008 04/01/14 10:331
Magnesium, dissolved M200.7 ICP 6.5 mg/L 1 aeb0.2 03/27/14 16:561
Magnesium, total M200.7 ICP 6.6 mg/L 1 jjc0.2 04/01/14 10:331
Manganese, dissolved M200.8 ICP-MS mg/L 0.003U msh0.0005 04/07/14 15:461
Manganese, total M200.8 ICP-MS 0.0061 mg/L 0.003 msh0.0005 04/03/14 22:101
Mercury, dissolved M1631, Atomic Fluorescence ng/L 0.5U las0.2 04/01/14 17:321
Mercury, total M1631, Atomic Fluorescence 0.5 ng/L 0.5 las0.2 04/03/14 10:321
Molybdenum, dissolved M200.8 ICP-MS 0.0029 mg/L 0.003B msh0.0005 04/07/14 15:461
Molybdenum, total M200.8 ICP-MS 0.0030 mg/L 0.003 msh0.0005 04/03/14 22:101
Nickel, dissolved M200.8 ICP-MS mg/L 0.003U msh0.0006 04/07/14 15:461
Nickel, total M200.8 ICP-MS mg/L 0.003U msh0.0006 04/03/14 22:101
Potassium, dissolved M200.7 ICP 7.2 mg/L 1 aeb0.2 03/27/14 16:561
REPIN.02.06.05.01 * Please refer to Qualifier Reports for details.
Page 8 of 60L17433-1404141323
ACZ Sample ID: L17433-02
Sample ID: 59760
Sample Matrix: Ground Water
SPF Water Engineering
Project ID: Calico 1st Quarter 2014 Sa
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic Analytical
Results
Date Sampled: 03/24/14 12:35
Date Received: 03/26/14
Potassium, total M200.7 ICP 7.3 mg/L 1 jjc0.2 04/01/14 10:331
Scandium, dissolved M200.7 ICP mg/L 0.5U aeb0.1* 03/27/14 16:561
Scandium, total M200.7 ICP mg/L 0.5U jjc0.1* 04/01/14 10:331
Selenium, dissolved M200.8 ICP-MS 0.0022 mg/L 0.0003 pmc0.0001 04/09/14 4:361
Selenium, total M200.8 ICP-MS 0.0018 mg/L 0.0003 msh0.0001 04/03/14 22:101
Silver, dissolved M200.8 ICP-MS mg/L 0.0003U msh0.00005 04/07/14 15:461
Silver, total M200.8 ICP-MS mg/L 0.0003U msh0.00005 04/03/14 22:101
Sodium, dissolved M200.7 ICP 25.8 mg/L 1 aeb0.2 03/27/14 16:561
Sodium, total M200.7 ICP 25.7 mg/L 1 jjc0.2 04/01/14 10:331
Strontium, dissolved M200.7 ICP 0.243 mg/L 0.03 aeb0.005 03/27/14 16:561
Strontium, total M200.7 ICP 0.250 mg/L 0.03 jjc0.005 04/01/14 10:331
Thallium, dissolved M200.8 ICP-MS mg/L 0.0005U msh0.0001 04/07/14 15:461
Thallium, total M200.8 ICP-MS mg/L 0.0005U msh0.0001 04/03/14 22:101
Tin, dissolved M200.8 ICP-MS mg/L 0.0005U msh0.0001* 04/07/14 15:461
Tin, total M200.8 ICP-MS mg/L 0.0005U msh0.0001* 04/03/14 22:101
Titanium, dissolved M200.7 ICP mg/L 0.03U aeb0.005 03/27/14 16:561
Titanium, total M200.7 ICP 0.005 mg/L 0.03B jjc0.005 04/01/14 10:331
Uranium, dissolved M200.8 ICP-MS 0.0025 mg/L 0.0005 msh0.0001 04/07/14 15:461
Uranium, total M200.8 ICP-MS 0.0030 mg/L 0.0005 msh0.0001 04/03/14 22:101
Vanadium, dissolved M200.8 ICP-MS 0.0157 mg/L 0.001 msh0.0002 04/07/14 15:461
Vanadium, total M200.8 ICP-MS 0.0155 mg/L 0.001 msh0.0002 04/03/14 22:101
Zinc, dissolved M200.7 ICP mg/L 0.05U aeb0.01 03/27/14 16:561
Zinc, total M200.7 ICP 0.01 mg/L 0.05B jjc0.01 04/01/14 10:331
REPIN.02.06.05.01 * Please refer to Qualifier Reports for details.
Page 9 of 60L17433-1404141323
ACZ Sample ID: L17433-02
Sample ID: 59760
Sample Matrix: Ground Water
SPF Water Engineering
Project ID: Calico 1st Quarter 2014 Sa
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic Analytical
Results
Date Sampled: 03/24/14 12:35
Date Received: 03/26/14
Parameter EPA Method Result Units MDLQual AnalystDatePQL
Wet Chemistry
XQDilution
Alkalinity as CaCO3 SM2320B - Titration
Bicarbonate as CaCO3
132 mg/L 20 dcw2 03/27/14 0:001
Carbonate as CaCO3 mg/L 20U dcw2 03/27/14 0:001
Hydroxide as CaCO3 mg/L 20U dcw2 03/27/14 0:001
Total Alkalinity 132 mg/L 20 dcw2 03/27/14 0:001
Chloride M300.0 - Ion Chromatography 9.57 mg/L 2.5 tcd0.5* 04/03/14 20:241
Conductivity @25C SM2510B 380 umhos/cm 10 dcw1 03/27/14 4:311
Cyanide, total M335.4 - Colorimetric w/ distillation mg/L 0.01U tcd0.003* 04/02/14 13:540.5
Cyanide, WAD SM4500-CN I-Colorimetric w/ distillation
mg/L 0.01U tcd0.003* 04/02/14 14:590.5
Fluoride M300.0 - Ion Chromatography 0.50 mg/L 0.5 tcd0.1* 04/03/14 20:241
Hardness as CaCO3 SM2340B - Calculation 124 mg/L 7 calc1 04/14/14 8:40
Nitrate/Nitrite as N M353.2 - H2SO4 preserved 0.78 mg/L 0.1 pjb0.02* 04/05/14 14:171
Nitrogen, ammonia M350.1 - Automated Phenate mg/L 0.5U tcd0.05* 04/02/14 12:551
pH (lab) SM4500H+ B
pH 8.2 units 0.1H dcw0.1 03/27/14 0:001
pH measured at 24 C 0.1 dcw0.1 03/27/14 0:001
Phosphorus, total M365.1 - Auto Ascorbic Acid (digest)
0.02 mg/L 0.05B pjb0.01* 04/02/14 23:501
Residue, Filterable (TDS) @180C
SM2540C 280 mg/L 20 enb10 03/28/14 14:551
Residue, Non-Filterable (TSS) @105C
SM2540D 22 mg/L 20 dcw5* 03/28/14 15:181
Sulfate M300.0 - Ion Chromatography 30.4 mg/L 2.5 tcd0.5* 04/03/14 20:241
REPIN.02.06.05.01 * Please refer to Qualifier Reports for details.
Page 10 of 60L17433-1404141323
ACZ Sample ID: L17433-03
Sample ID: 59760-DUP
Sample Matrix: Ground Water
SPF Water Engineering
Project ID: Calico 1st Quarter 2014 Sa
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic Analytical
Results
Date Sampled: 03/24/14 12:40
Date Received: 03/26/14
Parameter EPA Method Result Units MDLQual AnalystDatePQL
Inorganic Prep
XQDilution
Cyanide, total M335.4 - Manual Distillation tcd04/01/14 15:31
Cyanide, WAD SM4500-CN I- distillation mss204/02/14 10:03
Phosphorus, total M365.1 - Auto Ascorbic Acid Digestion
bsu04/01/14 15:48
Total Hot Plate Digestion
M200.2 ICP-MS las04/02/14 11:32
Total Hot Plate Digestion
M200.2 ICP jjc03/31/14 12:17
REPIN.02.06.05.01 * Please refer to Qualifier Reports for details.
Page 11 of 60L17433-1404141323
ACZ Sample ID: L17433-03
Sample ID: 59760-DUP
Sample Matrix: Ground Water
SPF Water Engineering
Project ID: Calico 1st Quarter 2014 Sa
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic Analytical
Results
Date Sampled: 03/24/14 12:40
Date Received: 03/26/14
Parameter EPA Method Result Units MDLQual AnalystDatePQL
Metals Analysis
XQDilution
Aluminum, dissolved M200.7 ICP mg/L 0.2U aeb0.03 03/27/14 16:591
Aluminum, total M200.7 ICP 0.37 mg/L 0.2 jjc0.03* 04/01/14 10:371
Antimony, dissolved M200.8 ICP-MS 0.0005 mg/L 0.002B msh0.0004 04/07/14 15:501
Antimony, total M200.8 ICP-MS 0.0005 mg/L 0.002B msh0.0004 04/03/14 22:141
Arsenic, dissolved M200.8 ICP-MS 0.0221 mg/L 0.001 msh0.0002 04/07/14 15:501
Arsenic, total M200.8 ICP-MS 0.0251 mg/L 0.001 msh0.0002 04/03/14 22:141
Barium, dissolved M200.7 ICP 0.048 mg/L 0.02 aeb0.003 03/27/14 16:591
Barium, total M200.7 ICP 0.056 mg/L 0.02 jjc0.003 04/01/14 16:261
Beryllium, dissolved M200.8 ICP-MS mg/L 0.0003U pmc0.00005 04/09/14 4:391
Beryllium, total M200.8 ICP-MS mg/L 0.0003U msh0.00005 04/03/14 22:141
Bismuth, dissolved M200.7 ICP mg/L 0.2U aeb0.04* 03/27/14 16:591
Bismuth, total M200.7 ICP mg/L 0.2U jjc0.04* 04/01/14 10:371
Boron, dissolved M200.7 ICP 0.07 mg/L 0.05 aeb0.01 03/27/14 16:591
Boron, total M200.7 ICP 0.07 mg/L 0.05 jjc0.01 04/01/14 10:371
Cadmium, dissolved M200.8 ICP-MS mg/L 0.0005U pmc0.0001 04/09/14 4:391
Cadmium, total M200.8 ICP-MS mg/L 0.0005U msh0.0001 04/03/14 22:141
Calcium, dissolved M200.7 ICP 38.4 mg/L 0.5 aeb0.1 03/27/14 16:591
Calcium, total M200.7 ICP 38.5 mg/L 0.5 jjc0.1 04/01/14 10:371
Chromium, dissolved M200.8 ICP-MS 0.0006 mg/L 0.002B msh0.0005 04/07/14 15:501
Chromium, total M200.8 ICP-MS 0.0008 mg/L 0.002B msh0.0005 04/03/14 22:141
Cobalt, dissolved M200.8 ICP-MS 0.00011 mg/L 0.0003B msh0.00005 04/07/14 15:501
Cobalt, total M200.8 ICP-MS 0.00016 mg/L 0.0003B msh0.00005 04/03/14 22:141
Copper, dissolved M200.8 ICP-MS 0.0040 mg/L 0.003 msh0.0005 04/07/14 15:501
Copper, total M200.8 ICP-MS 0.0080 mg/L 0.003 msh0.0005 04/03/14 22:141
Gallium, dissolved M200.7 ICP mg/L 0.5U aeb0.1* 03/27/14 16:591
Gallium, total M200.7 ICP mg/L 0.5U jjc0.1* 04/01/14 10:371
Iron, dissolved M200.7 ICP mg/L 0.05U aeb0.02 03/27/14 16:591
Iron, total M200.7 ICP 0.12 mg/L 0.05 jjc0.02 04/01/14 10:371
Lead, dissolved M200.8 ICP-MS mg/L 0.0005U msh0.0001 04/07/14 15:501
Lead, total M200.8 ICP-MS 0.0004 mg/L 0.0005B msh0.0001 04/03/14 22:141
Lithium, dissolved M200.7 ICP 0.046 mg/L 0.04 aeb0.008 03/27/14 16:591
Lithium, total M200.7 ICP 0.055 mg/L 0.04 jjc0.008 04/01/14 10:371
Magnesium, dissolved M200.7 ICP 6.4 mg/L 1 aeb0.2 03/27/14 16:591
Magnesium, total M200.7 ICP 6.5 mg/L 1 jjc0.2 04/01/14 10:371
Manganese, dissolved M200.8 ICP-MS mg/L 0.003U msh0.0005 04/07/14 15:501
Manganese, total M200.8 ICP-MS 0.0042 mg/L 0.003 msh0.0005 04/03/14 22:141
Mercury, dissolved M1631, Atomic Fluorescence ng/L 0.5U las0.2* 04/01/14 17:371
Mercury, total M1631, Atomic Fluorescence 0.2 ng/L 0.5B las0.2 04/03/14 10:371
Molybdenum, dissolved M200.8 ICP-MS 0.0029 mg/L 0.003B msh0.0005 04/07/14 15:501
Molybdenum, total M200.8 ICP-MS 0.0030 mg/L 0.003 msh0.0005 04/03/14 22:141
Nickel, dissolved M200.8 ICP-MS mg/L 0.003U msh0.0006 04/07/14 15:501
Nickel, total M200.8 ICP-MS mg/L 0.003U msh0.0006 04/03/14 22:141
Potassium, dissolved M200.7 ICP 7.1 mg/L 1 aeb0.2 03/27/14 16:591
REPIN.02.06.05.01 * Please refer to Qualifier Reports for details.
Page 12 of 60L17433-1404141323
ACZ Sample ID: L17433-03
Sample ID: 59760-DUP
Sample Matrix: Ground Water
SPF Water Engineering
Project ID: Calico 1st Quarter 2014 Sa
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic Analytical
Results
Date Sampled: 03/24/14 12:40
Date Received: 03/26/14
Potassium, total M200.7 ICP 7.2 mg/L 1 jjc0.2 04/01/14 10:371
Scandium, dissolved M200.7 ICP mg/L 0.5U aeb0.1* 03/27/14 16:591
Scandium, total M200.7 ICP mg/L 0.5U jjc0.1* 04/01/14 10:371
Selenium, dissolved M200.8 ICP-MS 0.0019 mg/L 0.0003 pmc0.0001 04/09/14 4:391
Selenium, total M200.8 ICP-MS 0.0017 mg/L 0.0003 msh0.0001 04/03/14 22:141
Silver, dissolved M200.8 ICP-MS mg/L 0.0003U msh0.00005 04/07/14 15:501
Silver, total M200.8 ICP-MS 0.00005 mg/L 0.0003B msh0.00005 04/03/14 22:141
Sodium, dissolved M200.7 ICP 25.3 mg/L 1 aeb0.2 03/27/14 16:591
Sodium, total M200.7 ICP 25.6 mg/L 1 jjc0.2 04/01/14 10:371
Strontium, dissolved M200.7 ICP 0.246 mg/L 0.03 aeb0.005 03/27/14 16:591
Strontium, total M200.7 ICP 0.253 mg/L 0.03 jjc0.005 04/01/14 10:371
Thallium, dissolved M200.8 ICP-MS mg/L 0.0005U msh0.0001 04/07/14 15:501
Thallium, total M200.8 ICP-MS mg/L 0.0005U msh0.0001 04/03/14 22:141
Tin, dissolved M200.8 ICP-MS mg/L 0.0005U msh0.0001* 04/07/14 15:501
Tin, total M200.8 ICP-MS 0.0001 mg/L 0.0005B msh0.0001* 04/03/14 22:141
Titanium, dissolved M200.7 ICP mg/L 0.03U aeb0.005 03/27/14 16:591
Titanium, total M200.7 ICP mg/L 0.03U jjc0.005 04/01/14 10:371
Uranium, dissolved M200.8 ICP-MS 0.0025 mg/L 0.0005 msh0.0001 04/07/14 15:501
Uranium, total M200.8 ICP-MS 0.0029 mg/L 0.0005 msh0.0001 04/03/14 22:141
Vanadium, dissolved M200.8 ICP-MS 0.0115 mg/L 0.001 msh0.0002 04/07/14 15:501
Vanadium, total M200.8 ICP-MS 0.0156 mg/L 0.001 msh0.0002 04/03/14 22:141
Zinc, dissolved M200.7 ICP mg/L 0.05U aeb0.01 03/27/14 16:591
Zinc, total M200.7 ICP 0.01 mg/L 0.05B jjc0.01 04/01/14 10:371
REPIN.02.06.05.01 * Please refer to Qualifier Reports for details.
Page 13 of 60L17433-1404141323
ACZ Sample ID: L17433-03
Sample ID: 59760-DUP
Sample Matrix: Ground Water
SPF Water Engineering
Project ID: Calico 1st Quarter 2014 Sa
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic Analytical
Results
Date Sampled: 03/24/14 12:40
Date Received: 03/26/14
Parameter EPA Method Result Units MDLQual AnalystDatePQL
Wet Chemistry
XQDilution
Alkalinity as CaCO3 SM2320B - Titration
Bicarbonate as CaCO3
116 mg/L 20 dcw2 03/27/14 0:001
Carbonate as CaCO3 mg/L 20U dcw2 03/27/14 0:001
Hydroxide as CaCO3 mg/L 20U dcw2 03/27/14 0:001
Total Alkalinity 116 mg/L 20 dcw2 03/27/14 0:001
Chloride M300.0 - Ion Chromatography 9.13 mg/L 2.5 tcd0.5* 04/03/14 20:421
Conductivity @25C SM2510B 371 umhos/cm 10 dcw1 03/27/14 4:401
Cyanide, total M335.4 - Colorimetric w/ distillation mg/L 0.01U tcd0.003* 04/02/14 13:540.5
Cyanide, WAD SM4500-CN I-Colorimetric w/ distillation
mg/L 0.01U tcd0.003* 04/02/14 15:010.5
Fluoride M300.0 - Ion Chromatography 0.48 mg/L 0.5B tcd0.1* 04/03/14 20:421
Hardness as CaCO3 SM2340B - Calculation 122 mg/L 7 calc1 04/14/14 8:40
Nitrate/Nitrite as N M353.2 - H2SO4 preserved 0.83 mg/L 0.1 pjb0.02* 04/05/14 14:181
Nitrogen, ammonia M350.1 - Automated Phenate mg/L 0.5U tcd0.05* 04/02/14 12:561
pH (lab) SM4500H+ B
pH 8.2 units 0.1H dcw0.1 03/27/14 0:001
pH measured at 24 C 0.1 dcw0.1 03/27/14 0:001
Phosphorus, total M365.1 - Auto Ascorbic Acid (digest)
0.02 mg/L 0.05B pjb0.01* 04/02/14 23:511
Residue, Filterable (TDS) @180C
SM2540C 270 mg/L 20 enb10* 03/28/14 15:021
Residue, Non-Filterable (TSS) @105C
SM2540D 13 mg/L 20B dcw5* 03/28/14 15:201
Sulfate M300.0 - Ion Chromatography 29.6 mg/L 2.5 tcd0.5* 04/03/14 20:421
REPIN.02.06.05.01 * Please refer to Qualifier Reports for details.
Page 14 of 60L17433-1404141323
ACZ Sample ID: L17433-04
Sample ID: CYANIDE BLANK
Sample Matrix: Ground Water
SPF Water Engineering
Project ID: Calico 1st Quarter 2014 Sa
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic Analytical
Results
Date Sampled: 03/24/14 00:00
Date Received: 03/26/14
Parameter EPA Method Result Units MDLQual AnalystDatePQL
Inorganic Prep
XQDilution
Cyanide, total M335.4 - Manual Distillation tcd04/01/14 15:31
Cyanide, WAD SM4500-CN I- distillation mss204/02/14 10:20
Parameter EPA Method Result Units MDLQual AnalystDatePQL
Wet Chemistry
XQDilution
Cyanide, total M335.4 - Colorimetric w/ distillation mg/L 0.01U tcd0.003* 04/02/14 13:550.5
Cyanide, WAD SM4500-CN I-Colorimetric w/ distillation
mg/L 0.01U tcd0.003* 04/02/14 15:020.5
REPIN.02.06.05.01 * Please refer to Qualifier Reports for details.
Page 15 of 60L17433-1404141323
ACZ Sample ID: L17433-05
Sample ID: DEPOSIT RE-SAMPLE
Sample Matrix: Ground Water
SPF Water Engineering
Project ID: Calico 1st Quarter 2014 Sa
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic Analytical
Results
Date Sampled: 03/16/14 12:35
Date Received: 03/26/14
Parameter EPA Method Result Units MDLQual AnalystDatePQL
Metals Analysis
XQDilution
Mercury, dissolved M1631, Atomic Fluorescence 0.4 ng/L 0.5B las0.2* 04/01/14 17:421
Mercury, total M1631, Atomic Fluorescence 0.3 ng/L 0.5B las0.2 04/03/14 10:421
REPIN.02.06.05.01 * Please refer to Qualifier Reports for details.
Page 16 of 60L17433-1404141323
ACZ Sample ID: L17433-06
Sample ID: BLM
Sample Matrix: Ground Water
SPF Water Engineering
Project ID: Calico 1st Quarter 2014 Sa
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic Analytical
Results
Date Sampled: 03/24/14 13:45
Date Received: 03/26/14
Parameter EPA Method Result Units MDLQual AnalystDatePQL
Inorganic Prep
XQDilution
Cyanide, total M335.4 - Manual Distillation tcd04/01/14 15:32
Cyanide, WAD SM4500-CN I- distillation tcd04/04/14 11:00
Phosphorus, total M365.1 - Auto Ascorbic Acid Digestion
bsu04/01/14 15:57
Total Hot Plate Digestion
M200.2 ICP jjc03/31/14 12:52
Total Hot Plate Digestion
M200.2 ICP-MS las04/02/14 11:42
REPIN.02.06.05.01 * Please refer to Qualifier Reports for details.
Page 17 of 60L17433-1404141323
ACZ Sample ID: L17433-06
Sample ID: BLM
Sample Matrix: Ground Water
SPF Water Engineering
Project ID: Calico 1st Quarter 2014 Sa
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic Analytical
Results
Date Sampled: 03/24/14 13:45
Date Received: 03/26/14
Parameter EPA Method Result Units MDLQual AnalystDatePQL
Metals Analysis
XQDilution
Aluminum, dissolved M200.7 ICP mg/L 0.2U aeb0.03 03/27/14 17:031
Aluminum, total M200.7 ICP mg/L 0.2U jjc0.03* 04/01/14 10:461
Antimony, dissolved M200.8 ICP-MS 0.0005 mg/L 0.002B msh0.0004 04/07/14 15:531
Antimony, total M200.8 ICP-MS 0.0006 mg/L 0.002B msh0.0004 04/03/14 22:241
Arsenic, dissolved M200.8 ICP-MS 3.630 mg/L 0.04 pmc0.008 04/10/14 6:2540
Arsenic, total M200.8 ICP-MS 3.750 mg/L 0.04 pmc0.008 04/09/14 22:0940
Barium, dissolved M200.7 ICP 0.062 mg/L 0.02 aeb0.003 03/27/14 17:031
Barium, total M200.7 ICP 0.067 mg/L 0.02 jjc0.003 04/01/14 16:361
Beryllium, dissolved M200.8 ICP-MS mg/L 0.0003U pmc0.00005 04/09/14 4:421
Beryllium, total M200.8 ICP-MS mg/L 0.01U pmc0.002 04/09/14 22:0940
Bismuth, dissolved M200.7 ICP mg/L 0.2U aeb0.04* 03/27/14 17:031
Bismuth, total M200.7 ICP mg/L 0.2U jjc0.04* 04/01/14 10:461
Boron, dissolved M200.7 ICP 0.61 mg/L 0.05 aeb0.01 03/27/14 17:031
Boron, total M200.7 ICP 0.60 mg/L 0.05 jjc0.01 04/01/14 10:461
Cadmium, dissolved M200.8 ICP-MS mg/L 0.0005U pmc0.0001 04/09/14 4:421
Cadmium, total M200.8 ICP-MS mg/L 0.0005U msh0.0001 04/03/14 22:241
Calcium, dissolved M200.7 ICP 157 mg/L 0.5 aeb0.1 03/27/14 17:031
Calcium, total M200.7 ICP 150 mg/L 0.5 jjc0.1 04/01/14 10:461
Chromium, dissolved M200.8 ICP-MS mg/L 0.002U msh0.0005 04/07/14 15:531
Chromium, total M200.8 ICP-MS mg/L 0.002U msh0.0005 04/03/14 22:241
Cobalt, dissolved M200.8 ICP-MS 0.08330 mg/L 0.0003 msh0.00005 04/07/14 15:531
Cobalt, total M200.8 ICP-MS 0.08309 mg/L 0.0003 msh0.00005 04/03/14 22:241
Copper, dissolved M200.8 ICP-MS mg/L 0.003U msh0.0005 04/07/14 15:531
Copper, total M200.8 ICP-MS mg/L 0.003U msh0.0005 04/03/14 22:241
Gallium, dissolved M200.7 ICP mg/L 0.5U aeb0.1* 03/27/14 17:031
Gallium, total M200.7 ICP mg/L 0.5U jjc0.1* 04/01/14 10:461
Iron, dissolved M200.7 ICP 163 mg/L 0.05 aeb0.02 03/27/14 17:031
Iron, total M200.7 ICP 156 mg/L 0.05 jjc0.02 04/01/14 10:461
Lead, dissolved M200.8 ICP-MS mg/L 0.0005U msh0.0001 04/07/14 15:531
Lead, total M200.8 ICP-MS mg/L 0.0005U msh0.0001 04/03/14 22:241
Lithium, dissolved M200.7 ICP 0.709 mg/L 0.04 aeb0.008 03/27/14 17:031
Lithium, total M200.7 ICP 0.700 mg/L 0.04 jjc0.008 04/01/14 10:461
Magnesium, dissolved M200.7 ICP 8.2 mg/L 1 aeb0.2 03/27/14 17:031
Magnesium, total M200.7 ICP 7.9 mg/L 1 jjc0.2 04/01/14 10:461
Manganese, dissolved M200.8 ICP-MS 1.31 mg/L 0.1 pmc0.02 04/10/14 6:2540
Manganese, total M200.8 ICP-MS 1.34 mg/L 0.1 pmc0.02 04/09/14 22:0940
Mercury, dissolved M1631, Atomic Fluorescence 0.5 ng/L 0.5 las0.2* 04/01/14 17:571
Mercury, total M1631, Atomic Fluorescence 4 ng/L 3 las1 04/03/14 10:595
Molybdenum, dissolved M200.8 ICP-MS 0.0014 mg/L 0.003B msh0.0005 04/07/14 15:531
Molybdenum, total M200.8 ICP-MS 0.0015 mg/L 0.003B msh0.0005 04/03/14 22:241
Nickel, dissolved M200.8 ICP-MS 0.0844 mg/L 0.003 msh0.0006 04/07/14 15:531
Nickel, total M200.8 ICP-MS 0.0831 mg/L 0.003 msh0.0006 04/03/14 22:241
Potassium, dissolved M200.7 ICP 6 mg/L 1 aeb0.2 03/27/14 17:031
REPIN.02.06.05.01 * Please refer to Qualifier Reports for details.
Page 18 of 60L17433-1404141323
ACZ Sample ID: L17433-06
Sample ID: BLM
Sample Matrix: Ground Water
SPF Water Engineering
Project ID: Calico 1st Quarter 2014 Sa
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic Analytical
Results
Date Sampled: 03/24/14 13:45
Date Received: 03/26/14
Potassium, total M200.7 ICP 5.9 mg/L 1 jjc0.2 04/01/14 10:461
Scandium, dissolved M200.7 ICP mg/L 0.5U aeb0.1* 03/27/14 17:031
Scandium, total M200.7 ICP mg/L 0.5U jjc0.1* 04/01/14 10:461
Selenium, dissolved M200.8 ICP-MS mg/L 0.0003U pmc0.0001 04/09/14 4:421
Selenium, total M200.8 ICP-MS mg/L 0.0003U msh0.0001* 04/03/14 22:241
Silver, dissolved M200.8 ICP-MS mg/L 0.0003U msh0.00005 04/07/14 15:531
Silver, total M200.8 ICP-MS mg/L 0.0003U msh0.00005 04/03/14 22:241
Sodium, dissolved M200.7 ICP 275 mg/L 1 aeb0.2 03/27/14 17:031
Sodium, total M200.7 ICP 271 mg/L 1 jjc0.2 04/01/14 10:461
Strontium, dissolved M200.7 ICP 3.610 mg/L 0.03 aeb0.005 03/27/14 17:031
Strontium, total M200.7 ICP 3.420 mg/L 0.03 jjc0.005 04/01/14 10:461
Thallium, dissolved M200.8 ICP-MS mg/L 0.0005U msh0.0001 04/07/14 15:531
Thallium, total M200.8 ICP-MS mg/L 0.0005U msh0.0001 04/03/14 22:241
Tin, dissolved M200.8 ICP-MS mg/L 0.0005U msh0.0001* 04/07/14 15:531
Tin, total M200.8 ICP-MS mg/L 0.0005U msh0.0001* 04/03/14 22:241
Titanium, dissolved M200.7 ICP mg/L 0.03U aeb0.005 03/27/14 17:031
Titanium, total M200.7 ICP mg/L 0.03U jjc0.005 04/01/14 10:461
Uranium, dissolved M200.8 ICP-MS 0.0002 mg/L 0.0005B msh0.0001 04/07/14 15:531
Uranium, total M200.8 ICP-MS 0.0002 mg/L 0.0005B msh0.0001 04/03/14 22:241
Vanadium, dissolved M200.8 ICP-MS mg/L 0.001U msh0.0002 04/07/14 15:531
Vanadium, total M200.8 ICP-MS mg/L 0.001U msh0.0002 04/03/14 22:241
Zinc, dissolved M200.7 ICP 0.60 mg/L 0.05 aeb0.01 03/27/14 17:031
Zinc, total M200.7 ICP 0.58 mg/L 0.05 jjc0.01 04/01/14 10:461
REPIN.02.06.05.01 * Please refer to Qualifier Reports for details.
Page 19 of 60L17433-1404141323
ACZ Sample ID: L17433-06
Sample ID: BLM
Sample Matrix: Ground Water
SPF Water Engineering
Project ID: Calico 1st Quarter 2014 Sa
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic Analytical
Results
Date Sampled: 03/24/14 13:45
Date Received: 03/26/14
Parameter EPA Method Result Units MDLQual AnalystDatePQL
Wet Chemistry
XQDilution
Alkalinity as CaCO3 SM2320B - Titration
Bicarbonate as CaCO3
28 mg/L 20 dcw2 03/27/14 0:001
Carbonate as CaCO3 mg/L 20U dcw2 03/27/14 0:001
Hydroxide as CaCO3 mg/L 20U dcw2 03/27/14 0:001
Total Alkalinity 28 mg/L 20 dcw2 03/27/14 0:001
Chloride M300.0 - Ion Chromatography 22.5 mg/L 2.5 tcd0.5* 04/03/14 20:591
Conductivity @25C SM2510B 2100 umhos/cm 10 dcw1 03/27/14 4:471
Cyanide, total M335.4 - Colorimetric w/ distillation mg/L 0.01U tcd0.003* 04/02/14 13:580.5
Cyanide, WAD SM4500-CN I-Colorimetric w/ distillation
mg/L 0.01U tcd0.003* 04/04/14 15:420.5
Fluoride M300.0 - Ion Chromatography 0.83 mg/L 0.5 tcd0.1* 04/03/14 20:591
Hardness as CaCO3 SM2340B - Calculation 426 mg/L 7 calc1 04/14/14 8:41
Nitrate/Nitrite as N M353.2 - H2SO4 preserved mg/L 0.1U pjb0.02* 04/05/14 14:211
Nitrogen, ammonia M350.1 - Automated Phenate 0.72 mg/L 0.5 tcd0.05* 04/02/14 13:041
pH (lab) SM4500H+ B
pH 6.6 units 0.1H dcw0.1 03/27/14 0:001
pH measured at 23 C 0.1 dcw0.1 03/27/14 0:001
Phosphorus, total M365.1 - Auto Ascorbic Acid (digest)
0.35 mg/L 0.05 pjb0.01* 04/02/14 23:521
Residue, Filterable (TDS) @180C
SM2540C 1640 mg/L 20 enb10* 03/28/14 15:051
Residue, Non-Filterable (TSS) @105C
SM2540D 116 mg/L 20 dcw5* 03/28/14 15:231
Sulfate M300.0 - Ion Chromatography 1070 mg/L 50 tcd10* 04/04/14 11:3620
REPIN.02.06.05.01 * Please refer to Qualifier Reports for details.
Page 20 of 60L17433-1404141323
ACZ Sample ID: L17433-07
Sample ID: 59763
Sample Matrix: Ground Water
SPF Water Engineering
Project ID: Calico 1st Quarter 2014 Sa
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic Analytical
Results
Date Sampled: 03/24/14 15:15
Date Received: 03/26/14
Parameter EPA Method Result Units MDLQual AnalystDatePQL
Inorganic Prep
XQDilution
Cyanide, total M335.4 - Manual Distillation tcd04/01/14 15:32
Cyanide, WAD SM4500-CN I- distillation mss204/02/14 10:37
Phosphorus, total M365.1 - Auto Ascorbic Acid Digestion
bsu04/01/14 16:06
Total Hot Plate Digestion
M200.2 ICP-MS las04/02/14 11:52
Total Hot Plate Digestion
M200.2 ICP jjc03/31/14 13:03
REPIN.02.06.05.01 * Please refer to Qualifier Reports for details.
Page 21 of 60L17433-1404141323
ACZ Sample ID: L17433-07
Sample ID: 59763
Sample Matrix: Ground Water
SPF Water Engineering
Project ID: Calico 1st Quarter 2014 Sa
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic Analytical
Results
Date Sampled: 03/24/14 15:15
Date Received: 03/26/14
Parameter EPA Method Result Units MDLQual AnalystDatePQL
Metals Analysis
XQDilution
Aluminum, dissolved M200.7 ICP mg/L 0.2U aeb0.03 03/27/14 17:061
Aluminum, total M200.7 ICP 0.12 mg/L 0.2B jjc0.03* 04/01/14 10:491
Antimony, dissolved M200.8 ICP-MS 0.0005 mg/L 0.002B msh0.0004 04/07/14 15:571
Antimony, total M200.8 ICP-MS 0.0006 mg/L 0.002B msh0.0004 04/03/14 22:271
Arsenic, dissolved M200.8 ICP-MS 0.0688 mg/L 0.001 msh0.0002 04/07/14 15:571
Arsenic, total M200.8 ICP-MS 0.0614 mg/L 0.001 msh0.0002 04/03/14 22:271
Barium, dissolved M200.7 ICP 0.020 mg/L 0.02 aeb0.003 03/27/14 17:061
Barium, total M200.7 ICP 0.028 mg/L 0.02 jjc0.003 04/01/14 16:391
Beryllium, dissolved M200.8 ICP-MS mg/L 0.0003U pmc0.00005 04/09/14 4:461
Beryllium, total M200.8 ICP-MS mg/L 0.0003U msh0.00005* 04/03/14 22:271
Bismuth, dissolved M200.7 ICP mg/L 0.2U aeb0.04* 03/27/14 17:061
Bismuth, total M200.7 ICP mg/L 0.2U jjc0.04* 04/01/14 10:491
Boron, dissolved M200.7 ICP 0.17 mg/L 0.05 aeb0.01 03/27/14 17:061
Boron, total M200.7 ICP 0.16 mg/L 0.05 jjc0.01 04/01/14 10:491
Cadmium, dissolved M200.8 ICP-MS mg/L 0.0005U pmc0.0001 04/09/14 4:461
Cadmium, total M200.8 ICP-MS mg/L 0.0005U msh0.0001 04/03/14 22:271
Calcium, dissolved M200.7 ICP 51.1 mg/L 0.5 aeb0.1 03/27/14 17:061
Calcium, total M200.7 ICP 51.4 mg/L 0.5 jjc0.1 04/01/14 10:491
Chromium, dissolved M200.8 ICP-MS mg/L 0.002U msh0.0005 04/07/14 15:571
Chromium, total M200.8 ICP-MS mg/L 0.002U msh0.0005 04/03/14 22:271
Cobalt, dissolved M200.8 ICP-MS 0.00024 mg/L 0.0003B msh0.00005 04/07/14 15:571
Cobalt, total M200.8 ICP-MS 0.00020 mg/L 0.0003B msh0.00005 04/03/14 22:271
Copper, dissolved M200.8 ICP-MS mg/L 0.003U msh0.0005 04/07/14 15:571
Copper, total M200.8 ICP-MS mg/L 0.003U msh0.0005 04/03/14 22:271
Gallium, dissolved M200.7 ICP mg/L 0.5U aeb0.1* 03/27/14 17:061
Gallium, total M200.7 ICP mg/L 0.5U jjc0.1* 04/01/14 10:491
Iron, dissolved M200.7 ICP 0.09 mg/L 0.05 aeb0.02 03/27/14 17:061
Iron, total M200.7 ICP 0.14 mg/L 0.05 jjc0.02 04/01/14 10:491
Lead, dissolved M200.8 ICP-MS mg/L 0.0005U msh0.0001 04/07/14 15:571
Lead, total M200.8 ICP-MS 0.0001 mg/L 0.0005B msh0.0001 04/03/14 22:271
Lithium, dissolved M200.7 ICP 0.187 mg/L 0.04 aeb0.008 03/27/14 17:061
Lithium, total M200.7 ICP 0.200 mg/L 0.04 jjc0.008 04/01/14 10:491
Magnesium, dissolved M200.7 ICP 5.5 mg/L 1 aeb0.2 03/27/14 17:061
Magnesium, total M200.7 ICP 5.6 mg/L 1 jjc0.2 04/01/14 10:491
Manganese, dissolved M200.8 ICP-MS 0.0838 mg/L 0.003 msh0.0005 04/07/14 15:571
Manganese, total M200.8 ICP-MS 0.1029 mg/L 0.003 msh0.0005 04/03/14 22:271
Mercury, dissolved M1631, Atomic Fluorescence 0.4 ng/L 0.5B las0.2* 04/01/14 18:121
Mercury, total M1631, Atomic Fluorescence 0.9 ng/L 0.5 las0.2 04/03/14 10:531
Molybdenum, dissolved M200.8 ICP-MS 0.0110 mg/L 0.003 msh0.0005 04/07/14 15:571
Molybdenum, total M200.8 ICP-MS 0.0114 mg/L 0.003 msh0.0005 04/03/14 22:271
Nickel, dissolved M200.8 ICP-MS mg/L 0.003U msh0.0006 04/07/14 15:571
Nickel, total M200.8 ICP-MS mg/L 0.003U msh0.0006 04/03/14 22:271
Potassium, dissolved M200.7 ICP 25.6 mg/L 1 aeb0.2 03/27/14 17:061
REPIN.02.06.05.01 * Please refer to Qualifier Reports for details.
Page 22 of 60L17433-1404141323
ACZ Sample ID: L17433-07
Sample ID: 59763
Sample Matrix: Ground Water
SPF Water Engineering
Project ID: Calico 1st Quarter 2014 Sa
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic Analytical
Results
Date Sampled: 03/24/14 15:15
Date Received: 03/26/14
Potassium, total M200.7 ICP 26.3 mg/L 1 jjc0.2 04/01/14 10:491
Scandium, dissolved M200.7 ICP mg/L 0.5U aeb0.1* 03/27/14 17:061
Scandium, total M200.7 ICP mg/L 0.5U jjc0.1* 04/01/14 10:491
Selenium, dissolved M200.8 ICP-MS 0.0003 mg/L 0.0003 pmc0.0001 04/09/14 4:461
Selenium, total M200.8 ICP-MS 0.0004 mg/L 0.0003 pmc0.0001 04/09/14 22:121
Silver, dissolved M200.8 ICP-MS mg/L 0.0003U msh0.00005 04/07/14 15:571
Silver, total M200.8 ICP-MS mg/L 0.0003U msh0.00005 04/03/14 22:271
Sodium, dissolved M200.7 ICP 291 mg/L 1 aeb0.2 03/27/14 17:061
Sodium, total M200.7 ICP 295 mg/L 1 jjc0.2 04/01/14 10:491
Strontium, dissolved M200.7 ICP 0.166 mg/L 0.03 aeb0.005 03/27/14 17:061
Strontium, total M200.7 ICP 0.173 mg/L 0.03 jjc0.005 04/01/14 10:491
Thallium, dissolved M200.8 ICP-MS mg/L 0.0005U msh0.0001 04/07/14 15:571
Thallium, total M200.8 ICP-MS mg/L 0.0005U msh0.0001 04/03/14 22:271
Tin, dissolved M200.8 ICP-MS mg/L 0.0005U msh0.0001* 04/07/14 15:571
Tin, total M200.8 ICP-MS mg/L 0.0005U msh0.0001* 04/03/14 22:271
Titanium, dissolved M200.7 ICP mg/L 0.03U aeb0.005 03/27/14 17:061
Titanium, total M200.7 ICP 0.005 mg/L 0.03B jjc0.005 04/01/14 10:491
Uranium, dissolved M200.8 ICP-MS 0.0017 mg/L 0.0005 msh0.0001 04/07/14 15:571
Uranium, total M200.8 ICP-MS 0.0019 mg/L 0.0005 msh0.0001 04/03/14 22:271
Vanadium, dissolved M200.8 ICP-MS 0.0018 mg/L 0.001 msh0.0002 04/07/14 15:571
Vanadium, total M200.8 ICP-MS 0.0024 mg/L 0.001 msh0.0002 04/03/14 22:271
Zinc, dissolved M200.7 ICP mg/L 0.05U aeb0.01 03/27/14 17:061
Zinc, total M200.7 ICP mg/L 0.05U jjc0.01 04/01/14 10:491
REPIN.02.06.05.01 * Please refer to Qualifier Reports for details.
Page 23 of 60L17433-1404141323
ACZ Sample ID: L17433-07
Sample ID: 59763
Sample Matrix: Ground Water
SPF Water Engineering
Project ID: Calico 1st Quarter 2014 Sa
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic Analytical
Results
Date Sampled: 03/24/14 15:15
Date Received: 03/26/14
Parameter EPA Method Result Units MDLQual AnalystDatePQL
Wet Chemistry
XQDilution
Alkalinity as CaCO3 SM2320B - Titration
Bicarbonate as CaCO3
166 mg/L 20 dcw2 03/27/14 0:001
Carbonate as CaCO3 mg/L 20U dcw2 03/27/14 0:001
Hydroxide as CaCO3 mg/L 20U dcw2 03/27/14 0:001
Total Alkalinity 166 mg/L 20 dcw2 03/27/14 0:001
Chloride M300.0 - Ion Chromatography 19.6 mg/L 25B tcd5* 04/03/14 21:1710
Conductivity @25C SM2510B 1720 umhos/cm 10 dcw1 03/27/14 4:561
Cyanide, total M335.4 - Colorimetric w/ distillation mg/L 0.01U tcd0.003* 04/02/14 13:590.5
Cyanide, WAD SM4500-CN I-Colorimetric w/ distillation
mg/L 0.01U tcd0.003* 04/02/14 15:030.5
Fluoride M300.0 - Ion Chromatography mg/L 5U tcd1* 04/03/14 21:1710
Hardness as CaCO3 SM2340B - Calculation 150 mg/L 7 calc1 04/14/14 8:41
Nitrate/Nitrite as N M353.2 - H2SO4 preserved mg/L 0.1U pjb0.02* 04/05/14 14:231
Nitrogen, ammonia M350.1 - Automated Phenate mg/L 0.5U tcd0.05* 04/02/14 12:581
pH (lab) SM4500H+ B
pH 8.2 units 0.1H dcw0.1 03/27/14 0:001
pH measured at 23 C 0.1 dcw0.1 03/27/14 0:001
Phosphorus, total M365.1 - Auto Ascorbic Acid (digest)
0.05 mg/L 0.05 pjb0.01* 04/02/14 23:531
Residue, Filterable (TDS) @180C
SM2540C 1170 mg/L 20 enb10* 03/28/14 15:081
Residue, Non-Filterable (TSS) @105C
SM2540D mg/L 20U dcw5* 03/28/14 15:261
Sulfate M300.0 - Ion Chromatography 580 mg/L 25 tcd5* 04/03/14 21:1710
REPIN.02.06.05.01 * Please refer to Qualifier Reports for details.
Page 24 of 60L17433-1404141323
ACZ Sample ID: L17433-08
Sample ID: BISHOP
Sample Matrix: Ground Water
SPF Water Engineering
Project ID: Calico 1st Quarter 2014 Sa
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic Analytical
Results
Date Sampled: 03/24/14 17:50
Date Received: 03/26/14
Parameter EPA Method Result Units MDLQual AnalystDatePQL
Inorganic Prep
XQDilution
Cyanide, total M335.4 - Manual Distillation tcd04/01/14 15:32
Cyanide, WAD SM4500-CN I- distillation mss204/02/14 10:45
Phosphorus, total M365.1 - Auto Ascorbic Acid Digestion
bsu04/01/14 16:15
Total Hot Plate Digestion
M200.2 ICP jjc03/31/14 13:15
Total Hot Plate Digestion
M200.2 ICP-MS las04/02/14 12:01
REPIN.02.06.05.01 * Please refer to Qualifier Reports for details.
Page 25 of 60L17433-1404141323
ACZ Sample ID: L17433-08
Sample ID: BISHOP
Sample Matrix: Ground Water
SPF Water Engineering
Project ID: Calico 1st Quarter 2014 Sa
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic Analytical
Results
Date Sampled: 03/24/14 17:50
Date Received: 03/26/14
Parameter EPA Method Result Units MDLQual AnalystDatePQL
Metals Analysis
XQDilution
Aluminum, dissolved M200.7 ICP mg/L 0.2U aeb0.03 03/27/14 17:091
Aluminum, total M200.7 ICP mg/L 0.2U jjc0.03* 04/01/14 10:521
Antimony, dissolved M200.8 ICP-MS mg/L 0.002U msh0.0004 04/07/14 16:001
Antimony, total M200.8 ICP-MS mg/L 0.002U msh0.0004 04/03/14 22:311
Arsenic, dissolved M200.8 ICP-MS 0.0086 mg/L 0.001 msh0.0002 04/07/14 16:001
Arsenic, total M200.8 ICP-MS 0.0078 mg/L 0.001 msh0.0002 04/03/14 22:311
Barium, dissolved M200.7 ICP 0.015 mg/L 0.02B aeb0.003 03/27/14 17:091
Barium, total M200.7 ICP 0.022 mg/L 0.02 jjc0.003 04/01/14 16:421
Beryllium, dissolved M200.8 ICP-MS mg/L 0.0003U pmc0.00005 04/09/14 4:491
Beryllium, total M200.8 ICP-MS mg/L 0.0003U msh0.00005* 04/03/14 22:311
Bismuth, dissolved M200.7 ICP mg/L 0.2U aeb0.04* 03/27/14 17:091
Bismuth, total M200.7 ICP mg/L 0.2U jjc0.04* 04/01/14 10:521
Boron, dissolved M200.7 ICP 0.20 mg/L 0.05 aeb0.01 03/27/14 17:091
Boron, total M200.7 ICP 0.20 mg/L 0.05 jjc0.01 04/01/14 10:521
Cadmium, dissolved M200.8 ICP-MS mg/L 0.0005U pmc0.0001 04/09/14 4:491
Cadmium, total M200.8 ICP-MS mg/L 0.0005U msh0.0001 04/03/14 22:311
Calcium, dissolved M200.7 ICP 4.7 mg/L 0.5 aeb0.1 03/27/14 17:091
Calcium, total M200.7 ICP 4.8 mg/L 0.5 jjc0.1 04/01/14 10:521
Chromium, dissolved M200.8 ICP-MS mg/L 0.002U msh0.0005 04/07/14 16:001
Chromium, total M200.8 ICP-MS mg/L 0.002U msh0.0005 04/03/14 22:311
Cobalt, dissolved M200.8 ICP-MS 0.00017 mg/L 0.0003B msh0.00005 04/07/14 16:001
Cobalt, total M200.8 ICP-MS 0.00008 mg/L 0.0003B msh0.00005 04/03/14 22:311
Copper, dissolved M200.8 ICP-MS mg/L 0.003U msh0.0005 04/07/14 16:001
Copper, total M200.8 ICP-MS mg/L 0.003U msh0.0005 04/03/14 22:311
Gallium, dissolved M200.7 ICP mg/L 0.5U aeb0.1* 03/27/14 17:091
Gallium, total M200.7 ICP mg/L 0.5U jjc0.1* 04/01/14 10:521
Iron, dissolved M200.7 ICP mg/L 0.05U aeb0.02 03/27/14 17:091
Iron, total M200.7 ICP 0.04 mg/L 0.05B jjc0.02 04/01/14 10:521
Lead, dissolved M200.8 ICP-MS 0.0002 mg/L 0.0005B msh0.0001 04/07/14 16:001
Lead, total M200.8 ICP-MS 0.0002 mg/L 0.0005B msh0.0001 04/03/14 22:311
Lithium, dissolved M200.7 ICP 0.013 mg/L 0.04B aeb0.008 03/27/14 17:091
Lithium, total M200.7 ICP 0.022 mg/L 0.04B jjc0.008 04/01/14 10:521
Magnesium, dissolved M200.7 ICP 1.1 mg/L 1 aeb0.2 03/27/14 17:091
Magnesium, total M200.7 ICP 1.1 mg/L 1 jjc0.2 04/01/14 10:521
Manganese, dissolved M200.8 ICP-MS 0.0060 mg/L 0.003 msh0.0005 04/07/14 16:001
Manganese, total M200.8 ICP-MS 0.0067 mg/L 0.003 msh0.0005 04/03/14 22:311
Mercury, dissolved M1631, Atomic Fluorescence 0.4 ng/L 0.5B las0.2* 04/01/14 18:171
Mercury, total M1631, Atomic Fluorescence 0.2 ng/L 0.5B las0.2 04/03/14 11:151
Molybdenum, dissolved M200.8 ICP-MS 0.0083 mg/L 0.003 msh0.0005 04/07/14 16:001
Molybdenum, total M200.8 ICP-MS 0.0090 mg/L 0.003 msh0.0005 04/03/14 22:311
Nickel, dissolved M200.8 ICP-MS mg/L 0.003U msh0.0006 04/07/14 16:001
Nickel, total M200.8 ICP-MS mg/L 0.003U msh0.0006 04/03/14 22:311
Potassium, dissolved M200.7 ICP 4.2 mg/L 1 aeb0.2 03/27/14 17:091
REPIN.02.06.05.01 * Please refer to Qualifier Reports for details.
Page 26 of 60L17433-1404141323
ACZ Sample ID: L17433-08
Sample ID: BISHOP
Sample Matrix: Ground Water
SPF Water Engineering
Project ID: Calico 1st Quarter 2014 Sa
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic Analytical
Results
Date Sampled: 03/24/14 17:50
Date Received: 03/26/14
Potassium, total M200.7 ICP 4.1 mg/L 1 jjc0.2 04/01/14 10:521
Scandium, dissolved M200.7 ICP mg/L 0.5U aeb0.1* 03/27/14 17:091
Scandium, total M200.7 ICP mg/L 0.5U jjc0.1* 04/01/14 10:521
Selenium, dissolved M200.8 ICP-MS 0.0004 mg/L 0.0003 pmc0.0001 04/09/14 4:491
Selenium, total M200.8 ICP-MS 0.0004 mg/L 0.0003 pmc0.0001 04/09/14 22:151
Silver, dissolved M200.8 ICP-MS mg/L 0.0003U msh0.00005 04/07/14 16:001
Silver, total M200.8 ICP-MS mg/L 0.0003U msh0.00005 04/03/14 22:311
Sodium, dissolved M200.7 ICP 81.6 mg/L 1 aeb0.2 03/27/14 17:091
Sodium, total M200.7 ICP 81.2 mg/L 1 jjc0.2 04/01/14 10:521
Strontium, dissolved M200.7 ICP 0.035 mg/L 0.03 aeb0.005 03/27/14 17:091
Strontium, total M200.7 ICP 0.042 mg/L 0.03 jjc0.005 04/01/14 10:521
Thallium, dissolved M200.8 ICP-MS mg/L 0.0005U msh0.0001 04/07/14 16:001
Thallium, total M200.8 ICP-MS mg/L 0.0005U msh0.0001 04/03/14 22:311
Tin, dissolved M200.8 ICP-MS mg/L 0.0005U msh0.0001* 04/07/14 16:001
Tin, total M200.8 ICP-MS mg/L 0.0005U msh0.0001* 04/03/14 22:311
Titanium, dissolved M200.7 ICP mg/L 0.03U aeb0.005 03/27/14 17:091
Titanium, total M200.7 ICP mg/L 0.03U jjc0.005 04/01/14 10:521
Uranium, dissolved M200.8 ICP-MS 0.0006 mg/L 0.0005 msh0.0001 04/07/14 16:001
Uranium, total M200.8 ICP-MS 0.0007 mg/L 0.0005 msh0.0001 04/03/14 22:311
Vanadium, dissolved M200.8 ICP-MS 0.0026 mg/L 0.001 msh0.0002 04/07/14 16:001
Vanadium, total M200.8 ICP-MS 0.0033 mg/L 0.001 msh0.0002 04/03/14 22:311
Zinc, dissolved M200.7 ICP mg/L 0.05U aeb0.01 03/27/14 17:091
Zinc, total M200.7 ICP 0.02 mg/L 0.05B jjc0.01 04/01/14 10:521
REPIN.02.06.05.01 * Please refer to Qualifier Reports for details.
Page 27 of 60L17433-1404141323
ACZ Sample ID: L17433-08
Sample ID: BISHOP
Sample Matrix: Ground Water
SPF Water Engineering
Project ID: Calico 1st Quarter 2014 Sa
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic Analytical
Results
Date Sampled: 03/24/14 17:50
Date Received: 03/26/14
Parameter EPA Method Result Units MDLQual AnalystDatePQL
Wet Chemistry
XQDilution
Alkalinity as CaCO3 SM2320B - Titration
Bicarbonate as CaCO3
120 mg/L 20 dcw2 03/27/14 0:001
Carbonate as CaCO3 4 mg/L 20B dcw2 03/27/14 0:001
Hydroxide as CaCO3 mg/L 20U dcw2 03/27/14 0:001
Total Alkalinity 123 mg/L 20 dcw2 03/27/14 0:001
Chloride M300.0 - Ion Chromatography 8.60 mg/L 2.5 tcd0.5* 04/03/14 21:351
Conductivity @25C SM2510B 374 umhos/cm 10 dcw1 03/27/14 5:051
Cyanide, total M335.4 - Colorimetric w/ distillation mg/L 0.01U tcd0.003* 04/02/14 14:000.5
Cyanide, WAD SM4500-CN I-Colorimetric w/ distillation
mg/L 0.01U tcd0.003* 04/02/14 15:040.5
Fluoride M300.0 - Ion Chromatography 0.69 mg/L 0.5 tcd0.1* 04/03/14 21:351
Hardness as CaCO3 SM2340B - Calculation 16 mg/L 7 calc1 04/14/14 8:42
Nitrate/Nitrite as N M353.2 - H2SO4 preserved 0.35 mg/L 0.1 pjb0.02* 04/05/14 14:241
Nitrogen, ammonia M350.1 - Automated Phenate mg/L 0.5U tcd0.05* 04/02/14 12:591
pH (lab) SM4500H+ B
pH 8.4 units 0.1H dcw0.1 03/27/14 0:001
pH measured at 23 C 0.1 dcw0.1 03/27/14 0:001
Phosphorus, total M365.1 - Auto Ascorbic Acid (digest)
0.12 mg/L 0.05 pjb0.01* 04/02/14 23:541
Residue, Filterable (TDS) @180C
SM2540C 260 mg/L 20 enb10* 03/28/14 15:111
Residue, Non-Filterable (TSS) @105C
SM2540D mg/L 20U dcw5* 03/28/14 15:281
Sulfate M300.0 - Ion Chromatography 25.8 mg/L 2.5 tcd0.5* 04/03/14 21:351
REPIN.02.06.05.01 * Please refer to Qualifier Reports for details.
Page 28 of 60L17433-1404141323
ACZ Sample ID: L17433-09
Sample ID: MERCURY TRIP BLANK
Sample Matrix: Ground Water
SPF Water Engineering
Project ID: Calico 1st Quarter 2014 Sa
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic Analytical
Results
Date Sampled: 03/24/14 17:40
Date Received: 03/26/14
Parameter EPA Method Result Units MDLQual AnalystDatePQL
Metals Analysis
XQDilution
Mercury, total M1631, Atomic Fluorescence ng/L 0.5U las0.2 04/03/14 11:201
REPIN.02.06.05.01
Page 29 of 60L17433-1404141323
ACZ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Report Header Explanations
Batch A distinct set of samples analyzed at a specific time
Found Value of the QC Type of interest
Limit Upper limit for RPD, in %.
Lower Lower Recovery Limit, in % (except for LCSS, mg/Kg)
MDL Method Detection Limit. Same as Minimum Reporting Limit. Allows for instrument and annual fluctuations.
PCN/SCN A number assigned to reagents/standards to trace to the manufacturer's certificate of analysis
PQL Practical Quantitation Limit, typically 5 times the MDL.
QC True Value of the Control Sample or the amount added to the Spike
Rec Recovered amount of the true value or spike added, in % (except for LCSS, mg/Kg)
RPD Relative Percent Difference, calculation used for Duplicate QC Types
Upper Upper Recovery Limit, in % (except for LCSS, mg/Kg)
Sample Value of the Sample of interest
QC Sample Types
AS Analytical Spike (Post Digestion) LCSWD Laboratory Control Sample - Water Duplicate
ASD Analytical Spike (Post Digestion) Duplicate LFB Laboratory Fortified Blank
CCB Continuing Calibration Blank LFM Laboratory Fortified Matrix
CCV Continuing Calibration Verification standard LFMD Laboratory Fortified Matrix Duplicate
DUP Sample Duplicate LRB Laboratory Reagent Blank
ICB Initial Calibration Blank MS Matrix Spike
ICV Initial Calibration Verification standard MSD Matrix Spike Duplicate
ICSAB Inter-element Correction Standard - A plus B solutions PBS Prep Blank - Soil
LCSS Laboratory Control Sample - Soil PBW Prep Blank - Water
LCSSD Laboratory Control Sample - Soil Duplicate PQV Practical Quantitation Verification standard
LCSW Laboratory Control Sample - Water SDL Serial Dilution
QC Sample Type Explanations
Blanks Verifies that there is no or minimal contamination in the prep method or calibration procedure.
Control Samples Verifies the accuracy of the method, including the prep procedure.
Duplicates Verifies the precision of the instrument and/or method.
Spikes/Fortified Matrix Determines sample matrix interferences, if any.
Standard Verifies the validity of the calibration.
ACZ Qualifiers (Qual)
B Analyte concentration detected at a value between MDL and PQL. The associated value is an estimated quantity.
H Analysis exceeded method hold time. pH is a field test with an immediate hold time.
L Target analyte response was below the laboratory defined negative threshold.
U The material was analyzed for, but was not detected above the level of the associated value.
The associated value is either the sample quantitation limit or the sample detection limit.
Method References
(1) EPA 600/4-83-020. Methods for Chemical Analysis of Water and Wastes, March 1983.
(2) EPA 600/R-93-100. Methods for the Determination of Inorganic Substances in Environmental Samples, August 1993.
(3) EPA 600/R-94-111. Methods for the Determination of Metals in Environmental Samples - Supplement I, May 1994.
(4) EPA SW-846. Test Methods for Evaluating Solid Waste.
(5) Standard Methods for the Examination of Water and Wastewater.
Comments
(1) QC results calculated from raw data. Results may vary slightly if the rounded values are used in the calculations.
(2) Soil, Sludge, and Plant matrices for Inorganic analyses are reported on a dry weight basis.
(3) Animal matrices for Inorganic analyses are reported on an "as received" basis.
(4) An asterisk in the "XQ" column indicates there is an extended qualifier and/or certification qualifier
associated with the result.
(5) If the MDL equals the PQL or the MDL column is omitted, the PQL is the reporting limit.
For a complete list of ACZ's Extended Qualifiers, please click: http://www.acz.com/public/extquallist.pdf
REP001.09.12.01
Inorganic
Reference
Page 30 of 60L17433-1404141323
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic QC
Summary
ACZ Project ID: L17433SPF Water Engineering
Alkalinity as CaCO3 SM2320B - Titration
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361281
WG361281PBW1 03/26/14 16:40PBW U -20 20mg/L
WG361281LCSW3 03/26/14 16:59 101.6LCSW WC140313- 833.3 90 110mg/L820.0001
WG361281LCSW6 03/26/14 19:51 102.2LCSW WC140313- 838.3 90 110mg/L820.0001
WG361281PBW2 03/26/14 20:01PBW 2.5 -20 20mg/L
WG361281LCSW9 03/26/14 23:25 102.9LCSW WC140313- 843.4 90 110mg/L820.0001
WG361281PBW3 03/26/14 23:35PBW 2.6 -20 20mg/L
WG361281LCSW12 03/27/14 2:25 101.8LCSW WC140313- 834.8 90 110mg/L820.0001
WG361281PBW4 03/27/14 2:35PBW 2.9 -20 20mg/L
L17433-08DUP 03/27/14 5:14 123DUP 125.4 1.9mg/L 20
WG361281LCSW15 03/27/14 5:33 103.3LCSW WC140313- 847.2 90 110mg/L820.0001
Aluminum, dissolved M200.7 ICP
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361340
WG361340ICV 03/27/14 15:22 96.5ICV II140220-1 1.929 95 105mg/L2
WG361340ICB 03/27/14 15:28ICB U -0.09 0.09mg/L
WG361340LFB 03/27/14 15:41 99.5LFB II140317-2 .996 85 115mg/L1.0011
L17433-01AS 03/27/14 16:44 U 98.7AS II140317-2 .988 85 115mg/L1.0011
L17433-01ASD 03/27/14 16:47 U 99ASD II140317-2 .991 0.385 115mg/L 201.0011
Aluminum, total M200.7 ICP
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361527
WG361527ICV 04/01/14 9:28 98.1ICV II140228-1 1.961 95 105mg/L2
WG361527ICB 04/01/14 9:34ICB U -0.09 0.09mg/L
WG361468LRB 04/01/14 9:47LRB U -0.066 0.066mg/L
WG361468LFB 04/01/14 9:50 102.5LFB II140317-2 1.026 85 115mg/L1.0011
L17381-01LFM 04/01/14 9:56 19.9 123.9LFM II140317-2 21.14 70 130mg/L1.0011
L17381-01LFMD M304/01/14 9:59 19.9 136.8LFMD II140317-2 21.27 0.6170 130mg/L 201.0011
L17433-03LFM M104/01/14 10:40 .37 172.3LFM II140317-2 2.095 70 130mg/L1.0011
L17433-03LFMD M104/01/14 10:43 .37 177.5LFMD II140317-2 2.147 2.4570 130mg/L 201.0011
Antimony, dissolved M200.8 ICP-MS
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361845
WG361845ICV 04/07/14 14:18 109.5ICV MS140331-9 .02192 90 110mg/L.02002
WG361845ICB 04/07/14 14:21ICB U -0.0012 0.0012mg/L
WG361845LFB 04/07/14 14:24 94.1LFB MS140331-2 .00941 85 115mg/L.01
L17399-08AS 04/07/14 15:23 U 87.5AS MS140331-2 .00875 70 130mg/L.01
L17399-08ASD 04/07/14 15:26 U 89.4ASD MS140331-2 .00894 2.1570 130mg/L 20.01
Page 31 of 60L17433-1404141323
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic QC
Summary
ACZ Project ID: L17433SPF Water Engineering
Antimony, total M200.8 ICP-MS
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361760
WG361760ICV 04/03/14 20:59 107.2ICV MS140331-9 .02146 90 110mg/L.02002
WG361760ICB 04/03/14 21:02ICB U -0.0012 0.0012mg/L
WG361557LRB 04/03/14 21:06LRB U -0.00088 0.00088mg/L
WG361557LFB 04/03/14 21:09 103.2LFB MS140331-2 .01032 85 115mg/L.01
L17433-08LFM 04/03/14 22:34 U 101.7LFM MS140331-2 .01017 70 130mg/L.01
L17433-08LFMD 04/03/14 22:37 U 101.7LFMD MS140331-2 .01017 070 130mg/L 20.01
Arsenic, dissolved M200.8 ICP-MS
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361845
WG361845ICV 04/07/14 14:18 98.7ICV MS140331-9 .04934 90 110mg/L.05
WG361845ICB 04/07/14 14:21ICB U -0.0006 0.0006mg/L
WG361845LFB 04/07/14 14:24 103.7LFB MS140331-2 .05197 85 115mg/L.0501
L17399-08AS 04/07/14 15:23 .0011 101.1AS MS140331-2 .05177 70 130mg/L.0501
L17399-08ASD 04/07/14 15:26 .0011 98.2ASD MS140331-2 .05029 2.970 130mg/L 20.0501
WG362063
WG362063ICV 04/10/14 5:36 101ICV MS140331-9 .05049 90 110mg/L.05
WG362063ICB 04/10/14 5:39ICB U -0.0006 0.0006mg/L
WG362063LFB 04/10/14 5:43 88.9LFB MS140331-2 .04454 85 115mg/L.0501
L17282-01AS 04/10/14 5:49 .0042 97AS MS140331-2 .05282 70 130mg/L.0501
L17282-01ASD 04/10/14 5:52 .0042 101.8ASD MS140331-2 .05521 4.4270 130mg/L 20.0501
Arsenic, total M200.8 ICP-MS
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361760
WG361760ICV 04/03/14 20:59 101ICV MS140331-9 .0505 90 110mg/L.05
WG361760ICB 04/03/14 21:02ICB U -0.0006 0.0006mg/L
WG361557LRB 04/03/14 21:06LRB U -0.00044 0.00044mg/L
WG361557LFB 04/03/14 21:09 104.6LFB MS140331-2 .0524 85 115mg/L.0501
L17433-08LFM 04/03/14 22:34 .0078 95.9LFM MS140331-2 .05586 70 130mg/L.0501
L17433-08LFMD 04/03/14 22:37 .0078 95.3LFMD MS140331-2 .05554 0.5770 130mg/L 20.0501
WG361975
WG361975ICV 04/09/14 21:56 101.6ICV MS140331-9 .05079 90 110mg/L.05
WG361975ICB 04/09/14 21:59ICB U -0.0006 0.0006mg/L
WG361557LRB 04/09/14 22:02LRB U -0.00044 0.00044mg/L
WG361557LFB 04/09/14 22:05 109LFB MS140331-2 .05462 85 115mg/L.0501
L17433-08LFM 04/09/14 22:18 .008 98.6LFM MS140331-2 .05742 70 130mg/L.0501
L17433-08LFMD 04/09/14 22:21 .008 99.1LFMD MS140331-2 .05763 0.3770 130mg/L 20.0501
Page 32 of 60L17433-1404141323
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic QC
Summary
ACZ Project ID: L17433SPF Water Engineering
Barium, dissolved M200.7 ICP
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361340
WG361340ICV 03/27/14 15:22 97.7ICV II140220-1 1.9548 95 105mg/L2
WG361340ICB 03/27/14 15:28ICB U -0.009 0.009mg/L
WG361340LFB 03/27/14 15:41 96.8LFB II140317-2 .4842 85 115mg/L.5
L17433-01AS 03/27/14 16:44 .024 98AS II140317-2 .5138 85 115mg/L.5
L17433-01ASD 03/27/14 16:47 .024 98.4ASD II140317-2 .5161 0.4585 115mg/L 20.5
Barium, total M200.7 ICP
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361574
WG361574ICV 04/01/14 15:18 98.4ICV II140228-1 1.9688 95 105mg/L2
WG361574ICB 04/01/14 15:24ICB U -0.009 0.009mg/L
WG361468LRB 04/01/14 15:37LRB U -0.0066 0.0066mg/L
WG361468LFB 04/01/14 15:40 101LFB II140317-2 .5051 85 115mg/L.5
L17381-01LFM 04/01/14 15:46 .024 99.6LFM II140317-2 .5221 70 130mg/L.5
L17381-01LFMD 04/01/14 15:49 .024 99.3LFMD II140317-2 .5206 0.2970 130mg/L 20.5
L17433-03LFM 04/01/14 16:30 .056 101.8LFM II140317-2 .565 70 130mg/L.5
L17433-03LFMD 04/01/14 16:33 .056 101.9LFMD II140317-2 .5655 0.0970 130mg/L 20.5
Beryllium, dissolved M200.8 ICP-MS
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361971
WG361971ICV 04/09/14 3:41 94.5ICV MS140331-9 .04727 90 110mg/L.05
WG361971ICB 04/09/14 3:44ICB U -0.00015 0.00015mg/L
WG361971LFB 04/09/14 3:47 90.8LFB MS140331-2 .04547 85 115mg/L.05005
L17399-08AS 04/09/14 4:03 U 100.7AS MS140331-2 .05038 70 130mg/L.05005
L17399-08ASD 04/09/14 4:07 U 100.6ASD MS140331-2 .05034 0.0870 130mg/L 20.05005
L17475-03AS 04/09/14 5:08 .00058 98.2AS MS140331-2 .04971 70 130mg/L.05005
L17475-03ASD 04/09/14 5:12 .00058 98.8ASD MS140331-2 .05002 0.6270 130mg/L 20.05005
Beryllium, total M200.8 ICP-MS
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361760
WG361760ICV 04/03/14 20:59 96.5ICV MS140331-9 .04824 90 110mg/L.05
WG361760ICB 04/03/14 21:02ICB U -0.00015 0.00015mg/L
WG361557LRB 04/03/14 21:06LRB U -0.00011 0.00011mg/L
WG361557LFB 04/03/14 21:09 98.4LFB MS140331-2 .04925 85 115mg/L.05005
L17433-08LFM 04/03/14 22:34 U 100.5LFM MS140331-2 .05031 70 130mg/L.05005
L17433-08LFMD 04/03/14 22:37 U 100.7LFMD MS140331-2 .05041 0.270 130mg/L 20.05005
WG361975
WG361975ICV 04/09/14 21:56 91.3ICV MS140331-9 .04566 90 110mg/L.05
WG361975ICB 04/09/14 21:59ICB U -0.00015 0.00015mg/L
WG361557LRB 04/09/14 22:02LRB U -0.00011 0.00011mg/L
WG361557LFB 04/09/14 22:05 96.5LFB MS140331-2 .04832 85 115mg/L.05005
L17433-08LFM 04/09/14 22:18 U 94.5LFM MS140331-2 .0473 70 130mg/L.05005
L17433-08LFMD 04/09/14 22:21 U 95LFMD MS140331-2 .04756 0.5570 130mg/L 20.05005
Page 33 of 60L17433-1404141323
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic QC
Summary
ACZ Project ID: L17433SPF Water Engineering
Bismuth, dissolved M200.7 ICP
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361340
WG361340ICV 03/27/14 15:22 98.8ICV II140220-1 1.976 95 105mg/L2
WG361340ICB 03/27/14 15:28ICB U -0.12 0.12mg/L
WG361340LFB 03/27/14 15:41 98.9LFB II140317-2 .988 85 115mg/L.999
L17433-01AS 03/27/14 16:44 U 100.2AS II140317-2 1.001 85 115mg/L.999
L17433-01ASD 03/27/14 16:47 U 99.1ASD II140317-2 .99 1.185 115mg/L 20.999
Bismuth, total M200.7 ICP
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361527
WG361527ICV 04/01/14 9:28 100ICV II140228-1 1.999 95 105mg/L2
WG361527ICB 04/01/14 9:34ICB U -0.12 0.12mg/L
WG361468LRB 04/01/14 9:47LRB U -0.088 0.088mg/L
WG361468LFB 04/01/14 9:50 102.4LFB II140317-2 1.023 85 115mg/L.999
L17381-01LFM 04/01/14 9:56 U 96.4LFM II140317-2 .963 70 130mg/L.999
L17381-01LFMD 04/01/14 9:59 U 98.7LFMD II140317-2 .986 2.3670 130mg/L 20.999
L17433-03LFM 04/01/14 10:40 U 101.9LFM II140317-2 1.018 70 130mg/L.999
L17433-03LFMD 04/01/14 10:43 U 102.4LFMD II140317-2 1.023 0.4970 130mg/L 20.999
Boron, dissolved M200.7 ICP
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361340
WG361340ICV 03/27/14 15:22 99.6ICV II140220-1 1.992 95 105mg/L2
WG361340ICB 03/27/14 15:28ICB U -0.03 0.03mg/L
WG361340LFB 03/27/14 15:41 98.5LFB II140317-2 .493 85 115mg/L.5005
L17433-01AS 03/27/14 16:44 .08 98.3AS II140317-2 .572 85 115mg/L.5005
L17433-01ASD 03/27/14 16:47 .08 98.5ASD II140317-2 .573 0.1785 115mg/L 20.5005
Boron, total M200.7 ICP
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361527
WG361527ICV 04/01/14 9:28 98.4ICV II140228-1 1.967 95 105mg/L2
WG361527ICB 04/01/14 9:34ICB U -0.03 0.03mg/L
WG361468LRB 04/01/14 9:47LRB U -0.022 0.022mg/L
WG361468LFB 04/01/14 9:50 100.1LFB II140317-2 .501 85 115mg/L.5005
L17381-01LFM 04/01/14 9:56 .07 99.7LFM II140317-2 .569 70 130mg/L.5005
L17381-01LFMD 04/01/14 9:59 .07 100.5LFMD II140317-2 .573 0.770 130mg/L 20.5005
L17433-03LFM 04/01/14 10:40 .07 99.1LFM II140317-2 .566 70 130mg/L.5005
L17433-03LFMD 04/01/14 10:43 .07 97.3LFMD II140317-2 .557 1.670 130mg/L 20.5005
Page 34 of 60L17433-1404141323
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic QC
Summary
ACZ Project ID: L17433SPF Water Engineering
Cadmium, dissolved M200.8 ICP-MS
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361971
WG361971ICV 04/09/14 3:41 97.7ICV MS140331-9 .04887 90 110mg/L.05
WG361971ICB 04/09/14 3:44ICB U -0.0003 0.0003mg/L
WG361971LFB 04/09/14 3:47 93LFB MS140331-2 .04657 85 115mg/L.0501
L17399-08AS 04/09/14 4:03 .0001 98.4AS MS140331-2 .04939 70 130mg/L.0501
L17399-08ASD 04/09/14 4:07 .0001 97.9ASD MS140331-2 .04913 0.5370 130mg/L 20.0501
L17475-03AS 04/09/14 5:08 U 98.2AS MS140331-2 .04922 70 130mg/L.0501
L17475-03ASD 04/09/14 5:12 U 100.5ASD MS140331-2 .05036 2.2970 130mg/L 20.0501
Cadmium, total M200.8 ICP-MS
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361760
WG361760ICV 04/03/14 20:59 98.4ICV MS140331-9 .04922 90 110mg/L.05
WG361760ICB 04/03/14 21:02ICB U -0.0003 0.0003mg/L
WG361557LRB 04/03/14 21:06LRB U -0.00022 0.00022mg/L
WG361557LFB 04/03/14 21:09 99.7LFB MS140331-2 .04993 85 115mg/L.0501
L17433-08LFM 04/03/14 22:34 U 97.3LFM MS140331-2 .04877 70 130mg/L.0501
L17433-08LFMD 04/03/14 22:37 U 97.2LFMD MS140331-2 .04872 0.170 130mg/L 20.0501
Calcium, dissolved M200.7 ICP
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361340
WG361340ICV 03/27/14 15:22 98.3ICV II140220-1 98.28 95 105mg/L100
WG361340ICB 03/27/14 15:28ICB U -0.3 0.3mg/L
WG361340LFB 03/27/14 15:41 101LFB II140317-2 68.64 85 115mg/L67.98099
L17433-01AS 03/27/14 16:44 37.9 98AS II140317-2 104.5 85 115mg/L67.98099
L17433-01ASD 03/27/14 16:47 37.9 99.4ASD II140317-2 105.5 0.9585 115mg/L 2067.98099
Calcium, total M200.7 ICP
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361527
WG361527ICV 04/01/14 9:28 97.7ICV II140228-1 97.69 95 105mg/L100
WG361527ICB 04/01/14 9:34ICB U -0.3 0.3mg/L
WG361468LRB 04/01/14 9:47LRB U -0.22 0.22mg/L
WG361468LFB 04/01/14 9:50 101.7LFB II140317-2 69.12 85 115mg/L67.98099
L17381-01LFM 04/01/14 9:56 117 100LFM II140317-2 185 70 130mg/L67.98099
L17381-01LFMD 04/01/14 9:59 117 99.7LFMD II140317-2 184.8 0.1170 130mg/L 2067.98099
L17433-03LFM 04/01/14 10:40 38.5 100.5LFM II140317-2 106.8 70 130mg/L67.98099
L17433-03LFMD 04/01/14 10:43 38.5 101.4LFMD II140317-2 107.4 0.5670 130mg/L 2067.98099
Page 35 of 60L17433-1404141323
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic QC
Summary
ACZ Project ID: L17433SPF Water Engineering
Chloride M300.0 - Ion Chromatography
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG360290
WG360290ICV 03/06/14 13:49 101.6ICV WI140226-1 20.3 90 110mg/L19.98
WG360290ICB 03/06/14 14:07ICB U -1.5 1.5mg/L
WG361726
WG361726LFB1 04/03/14 13:31 100.3LFB WI140306-2 30.1 90 110mg/L30
L17370-02DUP RA04/03/14 18:18 94.2DUP 96.7 2.6mg/L 20
L17380-01AS 04/03/14 18:54 1600 101.3AS WI140306-2 4640 90 110mg/L3000
WG361726LFB2 04/03/14 22:11 100.3LFB WI140306-2 30.1 90 110mg/L30
Chromium, dissolved M200.8 ICP-MS
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361845
WG361845ICV 04/07/14 14:18 92.8ICV MS140331-9 .04641 90 110mg/L.05
WG361845ICB 04/07/14 14:21ICB U -0.0015 0.0015mg/L
WG361845LFB 04/07/14 14:24 98.4LFB MS140331-2 .04924 85 115mg/L.05005
L17399-08AS 04/07/14 15:23 U 89.5AS MS140331-2 .04479 70 130mg/L.05005
L17399-08ASD 04/07/14 15:26 U 89.5ASD MS140331-2 .04478 0.0270 130mg/L 20.05005
Chromium, total M200.8 ICP-MS
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361760
WG361760ICV 04/03/14 20:59 98.1ICV MS140331-9 .04907 90 110mg/L.05
WG361760ICB 04/03/14 21:02ICB U -0.0015 0.0015mg/L
WG361557LRB 04/03/14 21:06LRB U -0.0011 0.0011mg/L
WG361557LFB 04/03/14 21:09 97.6LFB MS140331-2 .04887 85 115mg/L.05005
L17433-08LFM 04/03/14 22:34 U 91.8LFM MS140331-2 .04594 70 130mg/L.05005
L17433-08LFMD 04/03/14 22:37 U 91.9LFMD MS140331-2 .04602 0.1770 130mg/L 20.05005
Cobalt, dissolved M200.8 ICP-MS
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361845
WG361845ICV 04/07/14 14:18 97.6ICV MS140331-9 .04881 90 110mg/L.05
WG361845ICB 04/07/14 14:21ICB U -0.00015 0.00015mg/L
WG361845LFB 04/07/14 14:24 99LFB MS140331-2 .04955 85 115mg/L.05005
L17399-08AS 04/07/14 15:23 .00027 94.2AS MS140331-2 .04744 70 130mg/L.05005
L17399-08ASD 04/07/14 15:26 .00027 95.4ASD MS140331-2 .04802 1.2270 130mg/L 20.05005
Cobalt, total M200.8 ICP-MS
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361760
WG361760ICV 04/03/14 20:59 98.1ICV MS140331-9 .04905 90 110mg/L.05
WG361760ICB 04/03/14 21:02ICB U -0.00015 0.00015mg/L
WG361557LRB 04/03/14 21:06LRB U -0.00011 0.00011mg/L
WG361557LFB 04/03/14 21:09 98.5LFB MS140331-2 .04929 85 115mg/L.05005
L17433-08LFM 04/03/14 22:34 .00008 97.5LFM MS140331-2 .04886 70 130mg/L.05005
L17433-08LFMD 04/03/14 22:37 .00008 98.2LFMD MS140331-2 .04923 0.7570 130mg/L 20.05005
Page 36 of 60L17433-1404141323
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic QC
Summary
ACZ Project ID: L17433SPF Water Engineering
Conductivity @25C SM2510B
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361281
WG361281LCSW2 03/26/14 16:45 103.4LCSW PCN43577 1456.4 90 110umhos/cm1408.8
WG361281LCSW5 03/26/14 19:37 101.8LCSW PCN43577 1434.2 90 110umhos/cm1408.8
WG361281LCSW8 03/26/14 23:11 101LCSW PCN43577 1423.1 90 110umhos/cm1408.8
WG361281LCSW11 03/27/14 2:11 100LCSW PCN43577 1409 90 110umhos/cm1408.8
L17433-08DUP 03/27/14 5:14 374DUP 381 1.9umhos/cm 20
WG361281LCSW14 03/27/14 5:19 99.1LCSW PCN43577 1395.8 90 110umhos/cm1408.8
Copper, dissolved M200.8 ICP-MS
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361845
WG361845ICV 04/07/14 14:18 91.9ICV MS140331-9 .04595 90 110mg/L.05
WG361845ICB 04/07/14 14:21ICB U -0.0015 0.0015mg/L
WG361845LFB 04/07/14 14:24 97.6LFB MS140331-2 .04884 85 115mg/L.05005
L17399-08AS 04/07/14 15:23 U 86.2AS MS140331-2 .04315 70 130mg/L.05005
L17399-08ASD 04/07/14 15:26 U 86.1ASD MS140331-2 .04308 0.1670 130mg/L 20.05005
Copper, total M200.8 ICP-MS
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361760
WG361760ICV 04/03/14 20:59 97.1ICV MS140331-9 .04855 90 110mg/L.05
WG361760ICB 04/03/14 21:02ICB U -0.0015 0.0015mg/L
WG361557LRB 04/03/14 21:06LRB U -0.0011 0.0011mg/L
WG361557LFB 04/03/14 21:09 98.4LFB MS140331-2 .04923 85 115mg/L.05005
L17433-08LFM 04/03/14 22:34 U 88.7LFM MS140331-2 .0444 70 130mg/L.05005
L17433-08LFMD 04/03/14 22:37 U 89.6LFMD MS140331-2 .04483 0.9670 130mg/L 20.05005
Cyanide, total M335.4 - Colorimetric w/ distillation
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361653
WG361653ICV 04/02/14 13:09 98.6ICV WI140322-7 .2957 90 110mg/L.3
WG361653ICB 04/02/14 13:10ICB U -0.003 0.003mg/L
WG361655
WG361602LRB 04/02/14 13:47LRB U -0.003 0.003mg/L
WG361602LFB 04/02/14 13:48 107.5LFB WI140322-4 .215 90 110mg/L.2
L17386-01DUP RA04/02/14 13:50 UDUP U 0mg/L 20
L17392-01LFM 04/02/14 13:52 .064 102.1LFM WI140322-4 .2682 90 110mg/L.2
Page 37 of 60L17433-1404141323
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic QC
Summary
ACZ Project ID: L17433SPF Water Engineering
Cyanide, WAD SM4500-CN I-Colorimetric w/ distillation
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361515
WG361515ICV 03/31/14 15:14 97.6ICV WI140322-7 .2928 90 110mg/L.3
WG361515ICB 03/31/14 15:15ICB U -0.003 0.003mg/L
WG361524
WG361496LRB 03/31/14 16:07LRB U -0.003 0.003mg/L
WG361496LFB 03/31/14 16:08 96.2LFB WI140322-6 .1924 90 110mg/L.2
L17387-01DUP RA03/31/14 16:21 .026DUP .0282 8.1mg/L 20
L17388-01LFM 03/31/14 16:23 U 92.7LFM WI140322-6 .1854 90 110mg/L.2
WG361653
WG361653ICV 04/02/14 13:09 98.6ICV WI140322-7 .2957 90 110mg/L.3
WG361653ICB 04/02/14 13:10ICB U -0.003 0.003mg/L
WG361673
WG361626LRB 04/02/14 14:57LRB U -0.003 0.003mg/L
WG361626LFB 04/02/14 14:58 101.8LFB WI140322-6 .2036 90 110mg/L.2
L17433-02LFM 04/02/14 15:00 U 101LFM WI140322-6 .202 90 110mg/L.2
L17433-03DUP RA04/02/14 15:01 UDUP U 0mg/L 20
WG361810
WG361810ICV 04/04/14 15:38 97.8ICV WI140322-7 .2935 90 110mg/L.3
WG361810ICB 04/04/14 15:39ICB U -0.003 0.003mg/L
WG361798LRB 04/04/14 15:40LRB U -0.003 0.003mg/L
WG361798LFB 04/04/14 15:41 95.1LFB WI140322-6 .1902 90 110mg/L.2
L17433-06DUP RA04/04/14 15:43 UDUP U 0mg/L 20
L17466-01LFM 04/04/14 15:44 U 92.7LFM WI140322-6 .1853 90 110mg/L.2
Fluoride M300.0 - Ion Chromatography
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG360290
WG360290ICV 03/06/14 13:49 103.7ICV WI140226-1 4.17 90 110mg/L4.02
WG360290ICB 03/06/14 14:07ICB U -0.3 0.3mg/L
WG361726
WG361726LFB1 04/03/14 13:31 101.3LFB WI140306-2 1.52 90 110mg/L1.5
L17370-02DUP RA04/03/14 18:18 UDUP U 0mg/L 20
L17380-01AS 04/03/14 18:54 57 103.3AS WI140306-2 212 90 110mg/L150
WG361726LFB2 04/03/14 22:11 100.7LFB WI140306-2 1.51 90 110mg/L1.5
Gallium, dissolved M200.7 ICP
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361340
WG361340ICV 03/27/14 15:22 98ICV II140220-1 1.96 95 105mg/L2
WG361340ICB 03/27/14 15:28ICB U -0.3 0.3mg/L
WG361340LFB 03/27/14 15:41 100.9LFB II140317-2 1.01 85 115mg/L1.001
L17433-01AS 03/27/14 16:44 U 95.9AS II140317-2 .96 85 115mg/L1.001
L17433-01ASD 03/27/14 16:47 U 104.9ASD II140317-2 1.05 8.9685 115mg/L 201.001
Page 38 of 60L17433-1404141323
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic QC
Summary
ACZ Project ID: L17433SPF Water Engineering
Gallium, total M200.7 ICP
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361527
WG361527ICV 04/01/14 9:28 99ICV II140228-1 1.98 95 105mg/L2
WG361527ICB 04/01/14 9:34ICB U -0.3 0.3mg/L
WG361468LRB 04/01/14 9:47LRB U -0.22 0.22mg/L
WG361468LFB 04/01/14 9:50 102.9LFB II140317-2 1.03 85 115mg/L1.001
L17381-01LFM 04/01/14 9:56 U 102.9LFM II140317-2 1.03 70 130mg/L1.001
L17381-01LFMD 04/01/14 9:59 U 100.9LFMD II140317-2 1.01 1.9670 130mg/L 201.001
L17433-03LFM 04/01/14 10:40 U 103.9LFM II140317-2 1.04 70 130mg/L1.001
L17433-03LFMD 04/01/14 10:43 U 101.9LFMD II140317-2 1.02 1.9470 130mg/L 201.001
Iron, dissolved M200.7 ICP
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361340
WG361340ICV 03/27/14 15:22 98.3ICV II140220-1 1.965 95 105mg/L2
WG361340ICB 03/27/14 15:28ICB U -0.06 0.06mg/L
WG361340LFB 03/27/14 15:41 98.6LFB II140317-2 .987 85 115mg/L1.0014
L17433-01AS 03/27/14 16:44 U 98AS II140317-2 .981 85 115mg/L1.0014
L17433-01ASD 03/27/14 16:47 U 99.3ASD II140317-2 .994 1.3285 115mg/L 201.0014
Iron, total M200.7 ICP
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361527
WG361527ICV 04/01/14 9:28 97.3ICV II140228-1 1.946 95 105mg/L2
WG361527ICB 04/01/14 9:34ICB U -0.06 0.06mg/L
WG361468LRB 04/01/14 9:47LRB U -0.044 0.044mg/L
WG361468LFB 04/01/14 9:50 102.4LFB II140317-2 1.025 85 115mg/L1.0014
L17381-01LFM 04/01/14 9:56 .36 96.1LFM II140317-2 1.322 70 130mg/L1.0014
L17381-01LFMD 04/01/14 9:59 .36 96.5LFMD II140317-2 1.326 0.370 130mg/L 201.0014
L17433-03LFM 04/01/14 10:40 .13 116.3LFM II140317-2 1.285 70 130mg/L1.0014
L17433-03LFMD 04/01/14 10:43 .13 117.6LFMD II140317-2 1.298 1.0170 130mg/L 201.0014
Lead, dissolved M200.8 ICP-MS
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361845
WG361845ICV 04/07/14 14:18 93.2ICV MS140331-9 .04661 90 110mg/L.05
WG361845ICB 04/07/14 14:21ICB U -0.0003 0.0003mg/L
WG361845LFB 04/07/14 14:24 90.2LFB MS140331-2 .04516 85 115mg/L.05005
L17399-08AS 04/07/14 15:23 U 88.6AS MS140331-2 .04432 70 130mg/L.05005
L17399-08ASD 04/07/14 15:26 U 89.1ASD MS140331-2 .0446 0.6370 130mg/L 20.05005
Page 39 of 60L17433-1404141323
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic QC
Summary
ACZ Project ID: L17433SPF Water Engineering
Lead, total M200.8 ICP-MS
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361760
WG361760ICV 04/03/14 20:59 101ICV MS140331-9 .05052 90 110mg/L.05
WG361760ICB 04/03/14 21:02ICB U -0.0003 0.0003mg/L
WG361557LRB 04/03/14 21:06LRB U -0.00022 0.00022mg/L
WG361557LFB 04/03/14 21:09 96.1LFB MS140331-2 .04808 85 115mg/L.05005
L17433-08LFM 04/03/14 22:34 .0002 97.3LFM MS140331-2 .0489 70 130mg/L.05005
L17433-08LFMD 04/03/14 22:37 .0002 97LFMD MS140331-2 .04873 0.3570 130mg/L 20.05005
Lithium, dissolved M200.7 ICP
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361340
WG361340ICV 03/27/14 15:22 97.7ICV II140220-1 1.9542 95 105mg/L2
WG361340ICB 03/27/14 15:28ICB U -0.024 0.024mg/L
WG361340LFB 03/27/14 15:41 95.6LFB II140317-2 .9555 85 115mg/L1
L17433-01AS 03/27/14 16:44 .038 96.5AS II140317-2 1.003 85 115mg/L1
L17433-01ASD 03/27/14 16:47 .038 97.4ASD II140317-2 1.012 0.8985 115mg/L 201
Lithium, total M200.7 ICP
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361527
WG361527ICV 04/01/14 9:28 97.9ICV II140228-1 1.9588 95 105mg/L2
WG361527ICB 04/01/14 9:34ICB U -0.024 0.024mg/L
WG361468LRB 04/01/14 9:47LRB U -0.0176 0.0176mg/L
WG361468LFB 04/01/14 9:50 98.3LFB II140317-2 .9826 85 115mg/L1
L17381-01LFM 04/01/14 9:56 .141 98LFM II140317-2 1.121 70 130mg/L1
L17381-01LFMD 04/01/14 9:59 .141 98.9LFMD II140317-2 1.13 0.870 130mg/L 201
L17433-03LFM 04/01/14 10:40 .055 100.6LFM II140317-2 1.061 70 130mg/L1
L17433-03LFMD 04/01/14 10:43 .055 100.2LFMD II140317-2 1.057 0.3870 130mg/L 201
Magnesium, dissolved M200.7 ICP
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361340
WG361340ICV 03/27/14 15:22 96.6ICV II140220-1 96.64 95 105mg/L100
WG361340ICB 03/27/14 15:28ICB U -0.6 0.6mg/L
WG361340LFB 03/27/14 15:41 96.9LFB II140317-2 48.44 85 115mg/L50.00131
L17433-01AS 03/27/14 16:44 6.8 96.2AS II140317-2 54.9 85 115mg/L50.00131
L17433-01ASD 03/27/14 16:47 6.8 97.2ASD II140317-2 55.38 0.8785 115mg/L 2050.00131
Page 40 of 60L17433-1404141323
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic QC
Summary
ACZ Project ID: L17433SPF Water Engineering
Magnesium, total M200.7 ICP
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361527
WG361527ICV 04/01/14 9:28 96ICV II140228-1 95.98 95 105mg/L100
WG361527ICB 04/01/14 9:34ICB U -0.6 0.6mg/L
WG361468LRB 04/01/14 9:47LRB U -0.44 0.44mg/L
WG361468LFB 04/01/14 9:50 97.2LFB II140317-2 48.6 85 115mg/L50.00131
L17381-01LFM 04/01/14 9:56 52 96.6LFM II140317-2 100.3 70 130mg/L50.00131
L17381-01LFMD 04/01/14 9:59 52 97.2LFMD II140317-2 100.6 0.370 130mg/L 2050.00131
L17433-03LFM 04/01/14 10:40 6.5 97.4LFM II140317-2 55.21 70 130mg/L50.00131
L17433-03LFMD 04/01/14 10:43 6.5 97.7LFMD II140317-2 55.34 0.2470 130mg/L 2050.00131
Manganese, dissolved M200.8 ICP-MS
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361845
WG361845ICV 04/07/14 14:18 101.9ICV MS140331-9 .05095 90 110mg/L.05
WG361845ICB 04/07/14 14:21ICB U -0.0015 0.0015mg/L
WG361845LFB 04/07/14 14:24 99.7LFB MS140331-2 .04996 85 115mg/L.0501
L17399-08AS 04/07/14 15:23 .0026 96.5AS MS140331-2 .05095 70 130mg/L.0501
L17399-08ASD 04/07/14 15:26 .0026 97.4ASD MS140331-2 .05138 0.8470 130mg/L 20.0501
WG362063
WG362063ICV 04/10/14 5:36 99.2ICV MS140331-9 .0496 90 110mg/L.05
WG362063ICB 04/10/14 5:39ICB U -0.0015 0.0015mg/L
WG362063LFB 04/10/14 5:43 88LFB MS140331-2 .0441 85 115mg/L.0501
L17282-01AS 04/10/14 5:49 .2043 92.2AS MS140331-2 .2505 70 130mg/L.0501
L17282-01ASD 04/10/14 5:52 .2043 92.6ASD MS140331-2 .2507 0.0870 130mg/L 20.0501
Manganese, total M200.8 ICP-MS
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361760
WG361760ICV 04/03/14 20:59 102.8ICV MS140331-9 .05138 90 110mg/L.05
WG361760ICB 04/03/14 21:02ICB U -0.0015 0.0015mg/L
WG361557LRB 04/03/14 21:06LRB U -0.0011 0.0011mg/L
WG361557LFB 04/03/14 21:09 97.2LFB MS140331-2 .04872 85 115mg/L.0501
L17433-08LFM 04/03/14 22:34 .0067 97.2LFM MS140331-2 .05542 70 130mg/L.0501
L17433-08LFMD 04/03/14 22:37 .0067 97.7LFMD MS140331-2 .05567 0.4570 130mg/L 20.0501
WG361975
WG361975ICV 04/09/14 21:56 98.8ICV MS140331-9 .04939 90 110mg/L.05
WG361975ICB 04/09/14 21:59ICB U -0.0015 0.0015mg/L
WG361557LRB 04/09/14 22:02LRB U -0.0011 0.0011mg/L
WG361557LFB 04/09/14 22:05 98.4LFB MS140331-2 .04931 85 115mg/L.0501
L17433-08LFM 04/09/14 22:18 .0068 97.8LFM MS140331-2 .0558 70 130mg/L.0501
L17433-08LFMD 04/09/14 22:21 .0068 96.8LFMD MS140331-2 .05532 0.8670 130mg/L 20.0501
Page 41 of 60L17433-1404141323
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic QC
Summary
ACZ Project ID: L17433SPF Water Engineering
Mercury, dissolved M1631, Atomic Fluorescence
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361393
WG361393ICV 03/28/14 15:59 98.7ICV HG140325-4 9.87 79 121ng/L10
WG361393ICB 03/28/14 16:04ICB U -0.5 0.5ng/L
WG361562
WG361562CCV1 04/01/14 15:50 96.8CCV HG140325-4 9.68 76.5 123.4ng/L10
WG361562CCB1 04/01/14 15:55CCB U -0.5 0.5ng/L
WG361562PQV 04/01/14 16:00 86PQV HG140325-6 .43 70 130ng/L.5
WG361562LFB 04/01/14 16:12 75LFB HG140325-5 1.5 71 125ng/L2
L17362-01MS 04/01/14 16:26 U 76MS HG140325-5 1.52 71 125ng/L2
L17362-01MSD 04/01/14 16:31 U 76.5MSD HG140325-5 1.53 0.6671 125ng/L 242
WG361562CCV2 04/01/14 17:01 94.6CCV HG140325-4 9.46 76.5 123.4ng/L10
WG361562CCB2 04/01/14 17:06CCB U -0.5 0.5ng/L
WG361562CCV3 04/01/14 17:47 91.9CCV HG140325-4 9.19 76.5 123.4ng/L10
WG361562CCB3 04/01/14 17:52CCB U -0.5 0.5ng/L
L17433-06MS M204/01/14 18:02 .5 66.5MS HG140325-5 1.83 71 125ng/L2
L17433-06MSD M204/01/14 18:07 .5 66MSD HG140325-5 1.82 0.5571 125ng/L 242
WG361562CCV4 04/01/14 18:22 97.1CCV HG140325-4 9.71 76.5 123.4ng/L10
WG361562CCB4 04/01/14 18:27CCB U -0.5 0.5ng/L
Mercury, total M1631, Atomic Fluorescence
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361393
WG361393ICV 03/28/14 15:59 98.7ICV HG140325-4 9.87 79 121ng/L10
WG361393ICB 03/28/14 16:04ICB U -0.5 0.5ng/L
WG361711
WG361711CCV1 04/03/14 9:54 95.6CCV HG140403-3 9.56 76.5 123.4ng/L10
WG361711CCB1 04/03/14 9:59CCB U -0.5 0.5ng/L
WG361711PQV 04/03/14 10:04 112PQV HG140403-5 .56 70 130ng/L.5
WG361711LFB 04/03/14 10:09 97.5LFB HG140403-4 1.95 71 125ng/L2
L17433-01MS 04/03/14 10:22 U 95MS HG140403-4 1.9 71 125ng/L2
L17433-01MSD 04/03/14 10:27 U 90.5MSD HG140403-4 1.81 4.8571 125ng/L 242
WG361711CCV2 04/03/14 11:05 94CCV HG140403-3 9.4 76.5 123.4ng/L10
WG361711CCB2 04/03/14 11:10CCB .22 -0.5 0.5ng/L
WG361711CCV3 04/03/14 11:55 94.9CCV HG140403-3 9.49 76.5 123.4ng/L10
WG361711CCB3 04/03/14 12:00CCB .21 -0.5 0.5ng/L
WG361711CCV4 04/03/14 12:48 102CCV HG140403-3 10.2 76.5 123.4ng/L10
WG361711CCB4 04/03/14 12:53CCB U -0.5 0.5ng/L
Molybdenum, dissolved M200.8 ICP-MS
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361845
WG361845ICV 04/07/14 14:18 95ICV MS140331-9 .01898 90 110mg/L.01998
WG361845ICB 04/07/14 14:21ICB U -0.0015 0.0015mg/L
WG361845LFB 04/07/14 14:24 94.9LFB MS140331-2 .04743 85 115mg/L.05
L17399-08AS 04/07/14 15:23 .0007 91.6AS MS140331-2 .04651 70 130mg/L.05
L17399-08ASD 04/07/14 15:26 .0007 92.4ASD MS140331-2 .04691 0.8670 130mg/L 20.05
Page 42 of 60L17433-1404141323
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic QC
Summary
ACZ Project ID: L17433SPF Water Engineering
Molybdenum, total M200.8 ICP-MS
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361760
WG361760ICV 04/03/14 20:59 95.6ICV MS140331-9 .0191 90 110mg/L.01998
WG361760ICB 04/03/14 21:02ICB U -0.0015 0.0015mg/L
WG361557LRB 04/03/14 21:06LRB U -0.0011 0.0011mg/L
WG361557LFB 04/03/14 21:09 95.8LFB MS140331-2 .0479 85 115mg/L.05
L17433-08LFM 04/03/14 22:34 .009 96.6LFM MS140331-2 .05728 70 130mg/L.05
L17433-08LFMD 04/03/14 22:37 .009 98.2LFMD MS140331-2 .05812 1.4670 130mg/L 20.05
Nickel, dissolved M200.8 ICP-MS
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361845
WG361845ICV 04/07/14 14:18 92.2ICV MS140331-9 .04612 90 110mg/L.05
WG361845ICB 04/07/14 14:21ICB U -0.0018 0.0018mg/L
WG361845LFB 04/07/14 14:24 95.8LFB MS140331-2 .04789 85 115mg/L.05
L17399-08AS 04/07/14 15:23 U 83.1AS MS140331-2 .04156 70 130mg/L.05
L17399-08ASD 04/07/14 15:26 U 82.3ASD MS140331-2 .04115 0.9970 130mg/L 20.05
Nickel, total M200.8 ICP-MS
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361760
WG361760ICV 04/03/14 20:59 96.2ICV MS140331-9 .0481 90 110mg/L.05
WG361760ICB 04/03/14 21:02ICB U -0.0018 0.0018mg/L
WG361557LRB 04/03/14 21:06LRB U -0.00132 0.00132mg/L
WG361557LFB 04/03/14 21:09 95.8LFB MS140331-2 .04792 85 115mg/L.05
L17433-08LFM 04/03/14 22:34 U 87.2LFM MS140331-2 .04361 70 130mg/L.05
L17433-08LFMD 04/03/14 22:37 U 87.9LFMD MS140331-2 .04393 0.7370 130mg/L 20.05
Nitrate/Nitrite as N M353.2 - H2SO4 preserved
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361832
WG361832ICV 04/05/14 13:27 98.8ICV WI140116-3 2.386 90 110mg/L2.416
WG361832ICB 04/05/14 13:28ICB U -0.06 0.06mg/L
WG361834
WG361834LFB1 04/05/14 14:01 101.2LFB WI140215-3 2.024 90 110mg/L2
L17225-02AS 04/05/14 14:03 .04 99.6AS WI140215-3 2.032 90 110mg/L2
L17305-01DUP RA04/05/14 14:05 UDUP U 0mg/L 20
L17433-03AS 04/05/14 14:20 .83 108.3AS WI140215-3 2.996 90 110mg/L2
L17433-06DUP RA04/05/14 14:22 UDUP U 0mg/L 20
WG361834LFB2 04/05/14 14:35 102.5LFB WI140215-3 2.05 90 110mg/L2
Page 43 of 60L17433-1404141323
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic QC
Summary
ACZ Project ID: L17433SPF Water Engineering
Nitrogen, ammonia M350.1 - Automated Phenate
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361628
WG361628ICV 04/02/14 10:37 98.2ICV WI131021-1 .985 90 110mg/L1.003
WG361628ICB 04/02/14 10:40ICB U -0.15 0.15mg/L
WG361637
WG361637LFB1 04/02/14 11:42 99.9LFB WI140113-8 .999 90 110mg/L1
WG361637LFB2 04/02/14 12:47 99.4LFB WI140113-8 .994 90 110mg/L1
L17414-19AS 04/02/14 12:49 U 98.8AS WI140113-8 .988 90 110mg/L1
L17433-01DUP RA04/02/14 12:51 UDUP U 0mg/L 20
pH (lab) SM4500H+ B
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361281
WG361281LCSW1 03/26/14 16:43 99.2LCSW PCN40852 5.95 units6
WG361281LCSW4 03/26/14 19:35 99.5LCSW PCN40852 5.97 units6
WG361281LCSW7 03/26/14 23:09 99.7LCSW PCN40852 5.98 units6
WG361281LCSW10 03/27/14 2:10 99.5LCSW PCN40852 5.97 units6
L17433-08DUP 03/27/14 5:14 8.4DUP 8.38 0.2units 20
WG361281LCSW13 03/27/14 5:17 99.3LCSW PCN40852 5.96 units6
Phosphorus, total M365.1 - Auto Ascorbic Acid (digest)
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361685
WG361685ICV 04/02/14 18:57 98.1ICV WI140401-5 .64 90 110mg/L.65228
WG361685ICB 04/02/14 18:59ICB U -0.03 0.03mg/L
WG361691
WG361579LRB 04/02/14 23:22LRB U -0.03 0.03mg/L
WG361579LFB 04/02/14 23:23 99.8LFB WI140326-3 .499 90 110mg/L.5
L17305-11LFM M104/02/14 23:41 .07 128.4LFM WI140326-3 .712 90 110mg/L.5
L17305-12DUP 04/02/14 23:43 .1DUP .098 2mg/L 20
Potassium, dissolved M200.7 ICP
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361340
WG361340ICV 03/27/14 15:22 96.8ICV II140220-1 19.36 95 105mg/L20
WG361340ICB 03/27/14 15:28ICB U -0.6 0.6mg/L
WG361340LFB 03/27/14 15:41 99.1LFB II140317-2 99.14 85 115mg/L99.99364
L17433-01AS 03/27/14 16:44 5.8 99.4AS II140317-2 105.2 85 115mg/L99.99364
L17433-01ASD 03/27/14 16:47 5.8 99.9ASD II140317-2 105.7 0.4785 115mg/L 2099.99364
Page 44 of 60L17433-1404141323
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic QC
Summary
ACZ Project ID: L17433SPF Water Engineering
Potassium, total M200.7 ICP
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361527
WG361527ICV 04/01/14 9:28 97.2ICV II140228-1 19.44 95 105mg/L20
WG361527ICB 04/01/14 9:34ICB U -0.6 0.6mg/L
WG361468LRB 04/01/14 9:47LRB U -0.44 0.44mg/L
WG361468LFB 04/01/14 9:50 100.4LFB II140317-2 100.4 85 115mg/L99.99364
L17381-01LFM 04/01/14 9:56 8.6 100.9LFM II140317-2 109.5 70 130mg/L99.99364
L17381-01LFMD 04/01/14 9:59 8.6 100.9LFMD II140317-2 109.5 070 130mg/L 2099.99364
L17433-03LFM 04/01/14 10:40 7.2 100.9LFM II140317-2 108.1 70 130mg/L99.99364
L17433-03LFMD 04/01/14 10:43 7.2 101.2LFMD II140317-2 108.4 0.2870 130mg/L 2099.99364
Residue, Filterable (TDS) @180C SM2540C
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361441
WG361441PBW 03/28/14 14:22PBW U -20 20mg/L
WG361441LCSW 03/28/14 14:25 96.9LCSW PCN45344 252 80 120mg/L260
L17433-02DUP 03/28/14 14:59 280DUP 280 0mg/L 10
Residue, Non-Filterable (TSS) @105C SM2540D
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361444
WG361444PBW 03/28/14 15:00PBW U -15 15mg/L
WG361444LCSW 03/28/14 15:02 101.3LCSW PCN45344 162 80 120mg/L160
L17433-08DUP RA03/28/14 15:31 UDUP U 0mg/L 10
Scandium, dissolved M200.7 ICP
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361340
WG361340ICV 03/27/14 15:22 99.5ICV II140220-1 1.99 95 105mg/L2
WG361340ICB 03/27/14 15:28ICB U -0.3 0.3mg/L
WG361340LFB 03/27/14 15:41 103.9LFB II140317-2 1.04 85 115mg/L1.0009
L17433-01AS 03/27/14 16:44 U 103.9AS II140317-2 1.04 85 115mg/L1.0009
L17433-01ASD 03/27/14 16:47 U 104.9ASD II140317-2 1.05 0.9685 115mg/L 201.0009
Scandium, total M200.7 ICP
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361527
WG361527ICV 04/01/14 9:28 99ICV II140228-1 1.98 95 105mg/L2
WG361527ICB 04/01/14 9:34ICB U -0.3 0.3mg/L
WG361468LRB 04/01/14 9:47LRB U -0.22 0.22mg/L
WG361468LFB 04/01/14 9:50 102.9LFB II140317-2 1.03 85 115mg/L1.0009
L17381-01LFM 04/01/14 9:56 U 100.9LFM II140317-2 1.01 70 130mg/L1.0009
L17381-01LFMD 04/01/14 9:59 U 102.9LFMD II140317-2 1.03 1.9670 130mg/L 201.0009
L17433-03LFM 04/01/14 10:40 U 105.9LFM II140317-2 1.06 70 130mg/L1.0009
L17433-03LFMD 04/01/14 10:43 U 104.9LFMD II140317-2 1.05 0.9570 130mg/L 201.0009
Page 45 of 60L17433-1404141323
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic QC
Summary
ACZ Project ID: L17433SPF Water Engineering
Selenium, dissolved M200.8 ICP-MS
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361971
WG361971ICV 04/09/14 3:41 101.4ICV MS140331-9 .05071 90 110mg/L.05
WG361971ICB 04/09/14 3:44ICB U -0.0003 0.0003mg/L
WG361971LFB 04/09/14 3:47 95.4LFB MS140331-2 .04774 85 115mg/L.05005
L17399-08AS 04/09/14 4:03 .0009 107.4AS MS140331-2 .05465 70 130mg/L.05005
L17399-08ASD 04/09/14 4:07 .0009 106.9ASD MS140331-2 .05438 0.570 130mg/L 20.05005
L17475-03AS 04/09/14 5:08 U 109.9AS MS140331-2 .05501 70 130mg/L.05005
L17475-03ASD 04/09/14 5:12 U 110.8ASD MS140331-2 .05545 0.870 130mg/L 20.05005
Selenium, total M200.8 ICP-MS
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361760
WG361760ICV 04/03/14 20:59 101.5ICV MS140331-9 .05073 90 110mg/L.05
WG361760ICB 04/03/14 21:02ICB U -0.0003 0.0003mg/L
WG361557LRB 04/03/14 21:06LRB .00019 -0.00022 0.00022mg/L
WG361557LFB 04/03/14 21:09 102.2LFB MS140331-2 .05113 85 115mg/L.05005
L17433-08LFM 04/03/14 22:34 .0004 92.4LFM MS140331-2 .04666 70 130mg/L.05005
L17433-08LFMD 04/03/14 22:37 .0004 94.2LFMD MS140331-2 .04755 1.8970 130mg/L 20.05005
WG361975
WG361975ICV 04/09/14 21:56 100.5ICV MS140331-9 .05023 90 110mg/L.05
WG361975ICB 04/09/14 21:59ICB U -0.0003 0.0003mg/L
WG361557LRB 04/09/14 22:02LRB U -0.00022 0.00022mg/L
WG361557LFB 04/09/14 22:05 108.1LFB MS140331-2 .05411 85 115mg/L.05005
L17433-08LFM 04/09/14 22:18 .0004 94.5LFM MS140331-2 .04771 70 130mg/L.05005
L17433-08LFMD 04/09/14 22:21 .0004 95.4LFMD MS140331-2 .04816 0.9470 130mg/L 20.05005
Silver, dissolved M200.8 ICP-MS
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361845
WG361845ICV 04/07/14 14:18 97ICV MS140331-9 .01942 90 110mg/L.02002
WG361845ICB 04/07/14 14:21ICB U -0.00015 0.00015mg/L
WG361845LFB 04/07/14 14:24 94.4LFB MS140331-2 .009461 85 115mg/L.01002
L17399-08AS 04/07/14 15:23 U 88.4AS MS140331-2 .00886 70 130mg/L.01002
L17399-08ASD 04/07/14 15:26 U 89ASD MS140331-2 .008921 0.6970 130mg/L 20.01002
Silver, total M200.8 ICP-MS
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361760
WG361760ICV 04/03/14 20:59 99.3ICV MS140331-9 .01988 90 110mg/L.02002
WG361760ICB 04/03/14 21:02ICB U -0.00015 0.00015mg/L
WG361557LRB 04/03/14 21:06LRB U -0.00011 0.00011mg/L
WG361557LFB 04/03/14 21:09 96.7LFB MS140331-2 .009693 85 115mg/L.01002
L17433-08LFM 04/03/14 22:34 U 95LFM MS140331-2 .009514 70 130mg/L.01002
L17433-08LFMD 04/03/14 22:37 U 95.1LFMD MS140331-2 .009532 0.1970 130mg/L 20.01002
Page 46 of 60L17433-1404141323
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic QC
Summary
ACZ Project ID: L17433SPF Water Engineering
Sodium, dissolved M200.7 ICP
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361340
WG361340ICV 03/27/14 15:22 98.6ICV II140220-1 98.6 95 105mg/L100
WG361340ICB 03/27/14 15:28ICB U -0.6 0.6mg/L
WG361340LFB 03/27/14 15:41 99.2LFB II140317-2 99.21 85 115mg/L100.0393
L17433-01AS 03/27/14 16:44 25.3 98.3AS II140317-2 123.6 85 115mg/L100.0393
L17433-01ASD 03/27/14 16:47 25.3 98.9ASD II140317-2 124.2 0.4885 115mg/L 20100.0393
Sodium, total M200.7 ICP
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361527
WG361527ICV 04/01/14 9:28 98.2ICV II140228-1 98.2 95 105mg/L100
WG361527ICB 04/01/14 9:34ICB U -0.6 0.6mg/L
WG361468LRB 04/01/14 9:47LRB U -0.44 0.44mg/L
WG361468LFB 04/01/14 9:50 98.6LFB II140317-2 98.68 85 115mg/L100.0393
L17381-01LFM 04/01/14 9:56 48.7 98.8LFM II140317-2 147.5 70 130mg/L100.0393
L17381-01LFMD 04/01/14 9:59 48.7 99.5LFMD II140317-2 148.2 0.4770 130mg/L 20100.0393
L17433-03LFM 04/01/14 10:40 25.6 100.7LFM II140317-2 126.3 70 130mg/L100.0393
L17433-03LFMD 04/01/14 10:43 25.6 101LFMD II140317-2 126.6 0.2470 130mg/L 20100.0393
Strontium, dissolved M200.7 ICP
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361340
WG361340ICV 03/27/14 15:22 99.4ICV II140220-1 1.9875 95 105mg/L2
WG361340ICB 03/27/14 15:28ICB U -0.015 0.015mg/L
WG361340LFB 03/27/14 15:41 97.7LFB II140317-2 .4885 85 115mg/L.5
L17433-01AS 03/27/14 16:44 .196 97.4AS II140317-2 .683 85 115mg/L.5
L17433-01ASD 03/27/14 16:47 .196 98.2ASD II140317-2 .687 0.5885 115mg/L 20.5
Strontium, total M200.7 ICP
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361527
WG361527ICV 04/01/14 9:28 98.9ICV II140228-1 1.9775 95 105mg/L2
WG361527ICB 04/01/14 9:34ICB U -0.015 0.015mg/L
WG361468LRB 04/01/14 9:47LRB U -0.011 0.011mg/L
WG361468LFB 04/01/14 9:50 98.4LFB II140317-2 .492 85 115mg/L.5
L17381-01LFM 04/01/14 9:56 .803 97.6LFM II140317-2 1.291 70 130mg/L.5
L17381-01LFMD 04/01/14 9:59 .803 98.8LFMD II140317-2 1.297 0.4670 130mg/L 20.5
L17433-03LFM 04/01/14 10:40 .253 98.6LFM II140317-2 .7458 70 130mg/L.5
L17433-03LFMD 04/01/14 10:43 .253 98.8LFMD II140317-2 .7472 0.1970 130mg/L 20.5
Page 47 of 60L17433-1404141323
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic QC
Summary
ACZ Project ID: L17433SPF Water Engineering
Sulfate M300.0 - Ion Chromatography
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG360290
WG360290ICV 03/06/14 13:49 102.5ICV WI140226-1 51.2 90 110mg/L49.95
WG360290ICB 03/06/14 14:07ICB U -1.5 1.5mg/L
WG361726
WG361726LFB1 04/03/14 13:31 101.3LFB WI140306-2 30.4 90 110mg/L30
L17370-02DUP RA04/03/14 18:18 10.4DUP U 200mg/L 20
L17380-01AS 04/03/14 18:54 376 100.8AS WI140306-2 3400 90 110mg/L3000
WG361726LFB2 04/03/14 22:11 100LFB WI140306-2 30 90 110mg/L30
Thallium, dissolved M200.8 ICP-MS
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361845
WG361845ICV 04/07/14 14:18 102.8ICV MS140331-9 .0514 90 110mg/L.05
WG361845ICB 04/07/14 14:21ICB U -0.0003 0.0003mg/L
WG361845LFB 04/07/14 14:24 98.7LFB MS140331-2 .04954 85 115mg/L.0502
L17399-08AS 04/07/14 15:23 U 91.7AS MS140331-2 .04603 70 130mg/L.0502
L17399-08ASD 04/07/14 15:26 U 92.3ASD MS140331-2 .04632 0.6370 130mg/L 20.0502
Thallium, total M200.8 ICP-MS
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361760
WG361760ICV 04/03/14 20:59 106.7ICV MS140331-9 .05333 90 110mg/L.05
WG361760ICB 04/03/14 21:02ICB U -0.0003 0.0003mg/L
WG361557LRB 04/03/14 21:06LRB U -0.00022 0.00022mg/L
WG361557LFB 04/03/14 21:09 99.3LFB MS140331-2 .04983 85 115mg/L.0502
L17433-08LFM 04/03/14 22:34 U 101.8LFM MS140331-2 .05108 70 130mg/L.0502
L17433-08LFMD 04/03/14 22:37 U 101.3LFMD MS140331-2 .05085 0.4570 130mg/L 20.0502
Tin, dissolved M200.8 ICP-MS
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361845
WG361845ICV 04/07/14 14:18 99ICV MS140331-9 .04958 90 110mg/L.0501
WG361845ICB 04/07/14 14:21ICB U -0.0003 0.0003mg/L
WG361845LFB 04/07/14 14:24 94.7LFB MS140331-2 .0474 85 115mg/L.05005
L17399-08AS 04/07/14 15:23 U 90.7AS MS140331-2 .04539 70 130mg/L.05005
L17399-08ASD 04/07/14 15:26 U 91.6ASD MS140331-2 .04585 1.0170 130mg/L 20.05005
Tin, total M200.8 ICP-MS
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361760
WG361760ICV 04/03/14 20:59 100.3ICV MS140331-9 .05027 90 110mg/L.0501
WG361760ICB 04/03/14 21:02ICB U -0.0003 0.0003mg/L
WG361557LRB 04/03/14 21:06LRB U -0.00022 0.00022mg/L
WG361557LFB 04/03/14 21:09 101LFB MS140331-2 .05057 85 115mg/L.05005
L17433-08LFM 04/03/14 22:34 U 97.2LFM MS140331-2 .04863 70 130mg/L.05005
L17433-08LFMD 04/03/14 22:37 U 101.5LFMD MS140331-2 .0508 4.3670 130mg/L 20.05005
Page 48 of 60L17433-1404141323
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic QC
Summary
ACZ Project ID: L17433SPF Water Engineering
Titanium, dissolved M200.7 ICP
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361340
WG361340ICV 03/27/14 15:22 96.3ICV II140220-1 1.9268 95 105mg/L2
WG361340ICB 03/27/14 15:28ICB U -0.015 0.015mg/L
WG361340LFB 03/27/14 15:41 96.2LFB II140317-2 .9621 85 115mg/L1
L17433-01AS 03/27/14 16:44 U 96.9AS II140317-2 .9693 85 115mg/L1
L17433-01ASD 03/27/14 16:47 U 97.6ASD II140317-2 .9757 0.6685 115mg/L 201
Titanium, total M200.7 ICP
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361527
WG361527ICV 04/01/14 9:28 97ICV II140228-1 1.9402 95 105mg/L2
WG361527ICB 04/01/14 9:34ICB U -0.015 0.015mg/L
WG361468LRB 04/01/14 9:47LRB U -0.011 0.011mg/L
WG361468LFB 04/01/14 9:50 100.3LFB II140317-2 1.003 85 115mg/L1
L17381-01LFM 04/01/14 9:56 U 98.3LFM II140317-2 .9828 70 130mg/L1
L17381-01LFMD 04/01/14 9:59 U 98.8LFMD II140317-2 .9884 0.5770 130mg/L 201
L17433-03LFM 04/01/14 10:40 U 101LFM II140317-2 1.01 70 130mg/L1
L17433-03LFMD 04/01/14 10:43 U 100.9LFMD II140317-2 1.009 0.170 130mg/L 201
Uranium, dissolved M200.8 ICP-MS
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361845
WG361845ICV 04/07/14 14:18 100.3ICV MS140331-9 .05016 90 110mg/L.05
WG361845ICB 04/07/14 14:21ICB U -0.0003 0.0003mg/L
WG361845LFB 04/07/14 14:24 100LFB MS140331-2 .04998 85 115mg/L.05
L17399-08AS 04/07/14 15:23 .0012 100.4AS MS140331-2 .05141 70 130mg/L.05
L17399-08ASD 04/07/14 15:26 .0012 100.7ASD MS140331-2 .05153 0.2370 130mg/L 20.05
Uranium, total M200.8 ICP-MS
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361760
WG361760ICV 04/03/14 20:59 104.4ICV MS140331-9 .05219 90 110mg/L.05
WG361760ICB 04/03/14 21:02ICB U -0.0003 0.0003mg/L
WG361557LRB 04/03/14 21:06LRB U -0.00022 0.00022mg/L
WG361557LFB 04/03/14 21:09 102.4LFB MS140331-2 .05122 85 115mg/L.05
L17433-08LFM 04/03/14 22:34 .0007 104.9LFM MS140331-2 .05317 70 130mg/L.05
L17433-08LFMD 04/03/14 22:37 .0007 104.9LFMD MS140331-2 .05313 0.0870 130mg/L 20.05
Vanadium, dissolved M200.8 ICP-MS
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361845
WG361845ICV 04/07/14 14:18 90.4ICV MS140331-9 .04521 90 110mg/L.05
WG361845ICB 04/07/14 14:21ICB U -0.0006 0.0006mg/L
WG361845LFB 04/07/14 14:24 99.2LFB MS140331-2 .04963 85 115mg/L.05005
L17399-08AS 04/07/14 15:23 .002 93.9AS MS140331-2 .049 70 130mg/L.05005
L17399-08ASD 04/07/14 15:26 .002 92.7ASD MS140331-2 .04841 1.2170 130mg/L 20.05005
Page 49 of 60L17433-1404141323
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic QC
Summary
ACZ Project ID: L17433SPF Water Engineering
Vanadium, total M200.8 ICP-MS
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361760
WG361760ICV 04/03/14 20:59 97.3ICV MS140331-9 .04863 90 110mg/L.05
WG361760ICB 04/03/14 21:02ICB U -0.0006 0.0006mg/L
WG361557LRB 04/03/14 21:06LRB U -0.00044 0.00044mg/L
WG361557LFB 04/03/14 21:09 100.2LFB MS140331-2 .05016 85 115mg/L.05005
L17433-08LFM 04/03/14 22:34 .0033 96.3LFM MS140331-2 .0515 70 130mg/L.05005
L17433-08LFMD 04/03/14 22:37 .0033 96.8LFMD MS140331-2 .05176 0.570 130mg/L 20.05005
Zinc, dissolved M200.7 ICP
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361340
WG361340ICV 03/27/14 15:22 97.7ICV II140220-1 1.954 95 105mg/L2
WG361340ICB 03/27/14 15:28ICB U -0.03 0.03mg/L
WG361340LFB 03/27/14 15:41 99.9LFB II140317-2 .5 85 115mg/L.5005
L17433-01AS 03/27/14 16:44 U 99.7AS II140317-2 .499 85 115mg/L.5005
L17433-01ASD 03/27/14 16:47 U 100.3ASD II140317-2 .502 0.685 115mg/L 20.5005
Zinc, total M200.7 ICP
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361527
WG361527ICV 04/01/14 9:28 95.7ICV II140228-1 1.913 95 105mg/L2
WG361527ICB 04/01/14 9:34ICB U -0.03 0.03mg/L
WG361468LRB 04/01/14 9:47LRB U -0.022 0.022mg/L
WG361468LFB 04/01/14 9:50 100.1LFB II140317-2 .501 85 115mg/L.5005
L17381-01LFM 04/01/14 9:56 .95 88.7LFM II140317-2 1.374 70 130mg/L.5005
L17381-01LFMD 04/01/14 9:59 .95 89.3LFMD II140317-2 1.377 0.2270 130mg/L 20.5005
L17433-03LFM 04/01/14 10:40 .01 97.5LFM II140317-2 .498 70 130mg/L.5005
L17433-03LFMD 04/01/14 10:43 .01 97.7LFMD II140317-2 .499 0.270 130mg/L 20.5005
Page 50 of 60L17433-1404141323
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic Extended
Qualifier Report
ACZ Project ID: L17433SPF Water Engineering
ACZ ID PARAMETER QUAL DESCRIPTIONMETHODWORKNUM
M3 The spike recovery value is unusable since the analyte concentration in the sample is disproportionate to the spike level. The recovery of the associated control sample (LCS or LFB) was acceptable.
M200.7 ICPAluminum, totalL17433-01 WG361527
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
M300.0 - Ion ChromatographyChlorideWG361726
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
M335.4 - Colorimetric w/ distillation
Cyanide, totalWG361655
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
SM4500-CN I-Colorimetric w/ distillation
Cyanide, WADWG361524
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
M300.0 - Ion ChromatographyFluorideWG361726
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
M353.2 - H2SO4 preservedNitrate/Nitrite as NWG361834
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
M350.1 - Automated PhenateNitrogen, ammoniaWG361637
M1 Matrix spike recovery was high, the recovery of the associated control sample (LCS or LFB) was acceptable.
M365.1 - Auto Ascorbic Acid (digest)
Phosphorus, totalWG361691
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
SM2540DResidue, Non-Filterable (TSS) @105CWG361444
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
M300.0 - Ion ChromatographySulfateWG361726
M3 The spike recovery value is unusable since the analyte concentration in the sample is disproportionate to the spike level. The recovery of the associated control sample (LCS or LFB) was acceptable.
M200.7 ICPAluminum, totalL17433-02 WG361527
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
M300.0 - Ion ChromatographyChlorideWG361726
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
M335.4 - Colorimetric w/ distillation
Cyanide, totalWG361655
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
SM4500-CN I-Colorimetric w/ distillation
Cyanide, WADWG361673
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
M300.0 - Ion ChromatographyFluorideWG361726
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
M353.2 - H2SO4 preservedNitrate/Nitrite as NWG361834
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
M350.1 - Automated PhenateNitrogen, ammoniaWG361637
M1 Matrix spike recovery was high, the recovery of the associated control sample (LCS or LFB) was acceptable.
M365.1 - Auto Ascorbic Acid (digest)
Phosphorus, totalWG361691
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
SM2540DResidue, Non-Filterable (TSS) @105CWG361444
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
M300.0 - Ion ChromatographySulfateWG361726
REPAD.15.06.05.01
Page 51 of 60L17433-1404141323
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic Extended
Qualifier Report
ACZ Project ID: L17433SPF Water Engineering
ACZ ID PARAMETER QUAL DESCRIPTIONMETHODWORKNUM
M1 Matrix spike recovery was high, the recovery of the associated control sample (LCS or LFB) was acceptable.
M200.7 ICPAluminum, totalL17433-03 WG361527
M2 Matrix spike recovery was low, the recovery of the associated control sample (LCS or LFB) was acceptable.
M1631, Atomic FluorescenceMercury, dissolvedWG361562
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
M300.0 - Ion ChromatographyChlorideWG361726
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
M335.4 - Colorimetric w/ distillation
Cyanide, totalWG361655
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
SM4500-CN I-Colorimetric w/ distillation
Cyanide, WADWG361673
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
M300.0 - Ion ChromatographyFluorideWG361726
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
M353.2 - H2SO4 preservedNitrate/Nitrite as NWG361834
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
M350.1 - Automated PhenateNitrogen, ammoniaWG361637
M1 Matrix spike recovery was high, the recovery of the associated control sample (LCS or LFB) was acceptable.
M365.1 - Auto Ascorbic Acid (digest)
Phosphorus, totalWG361691
RO The duplicate originally assigned to this sample was not used for precision assessment because residue density exceeded the method limits. Another duplicate in the batch was used to assess precision. Method required duplicate frequency was not met.
SM2540CResidue, Filterable (TDS) @180CWG361441
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
SM2540DResidue, Non-Filterable (TSS) @105CWG361444
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
M300.0 - Ion ChromatographySulfateWG361726
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
M335.4 - Colorimetric w/ distillation
Cyanide, totalL17433-04 WG361655
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
SM4500-CN I-Colorimetric w/ distillation
Cyanide, WADWG361673
M2 Matrix spike recovery was low, the recovery of the associated control sample (LCS or LFB) was acceptable.
M1631, Atomic FluorescenceMercury, dissolvedL17433-05 WG361562
REPAD.15.06.05.01
Page 52 of 60L17433-1404141323
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic Extended
Qualifier Report
ACZ Project ID: L17433SPF Water Engineering
ACZ ID PARAMETER QUAL DESCRIPTIONMETHODWORKNUM
M1 Matrix spike recovery was high, the recovery of the associated control sample (LCS or LFB) was acceptable.
M200.7 ICPAluminum, totalL17433-06 WG361527
M2 Matrix spike recovery was low, the recovery of the associated control sample (LCS or LFB) was acceptable.
M1631, Atomic FluorescenceMercury, dissolvedWG361562
BE Target analyte in continuing calibration blank (CCB) at or above the acceptance criteria. Target analyte was not detected in the sample [< MDL].
M200.8 ICP-MSSelenium, totalWG361760
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
M300.0 - Ion ChromatographyChlorideWG361726
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
M335.4 - Colorimetric w/ distillation
Cyanide, totalWG361655
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
SM4500-CN I-Colorimetric w/ distillation
Cyanide, WADWG361810
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
M300.0 - Ion ChromatographyFluorideWG361726
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
M353.2 - H2SO4 preservedNitrate/Nitrite as NWG361834
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
M350.1 - Automated PhenateNitrogen, ammoniaWG361637
M1 Matrix spike recovery was high, the recovery of the associated control sample (LCS or LFB) was acceptable.
M365.1 - Auto Ascorbic Acid (digest)
Phosphorus, totalWG361691
RO The duplicate originally assigned to this sample was not used for precision assessment because residue density exceeded the method limits. Another duplicate in the batch was used to assess precision. Method required duplicate frequency was not met.
SM2540CResidue, Filterable (TDS) @180CWG361441
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
SM2540DResidue, Non-Filterable (TSS) @105CWG361444
RA Relative Percent Difference (RPD) was not used for data
validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
M300.0 - Ion ChromatographySulfateWG361726
REPAD.15.06.05.01
Page 53 of 60L17433-1404141323
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic Extended
Qualifier Report
ACZ Project ID: L17433SPF Water Engineering
ACZ ID PARAMETER QUAL DESCRIPTIONMETHODWORKNUM
M1 Matrix spike recovery was high, the recovery of the associated control sample (LCS or LFB) was acceptable.
M200.7 ICPAluminum, totalL17433-07 WG361527
VC CCV recovery was above the acceptance limits. Target analyte was not detected in the sample [< MDL].
M200.8 ICP-MSBeryllium, totalWG361760
M2 Matrix spike recovery was low, the recovery of the associated control sample (LCS or LFB) was acceptable.
M1631, Atomic FluorescenceMercury, dissolvedWG361562
DC Sample required dilution. Non-target analyte exceeded calibration range.
M300.0 - Ion ChromatographyChlorideWG361726
RA Relative Percent Difference (RPD) was not used for data
validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
M300.0 - Ion Chromatography
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
M335.4 - Colorimetric w/ distillation
Cyanide, totalWG361655
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
SM4500-CN I-Colorimetric w/ distillation
Cyanide, WADWG361673
DC Sample required dilution. Non-target analyte exceeded
calibration range.
M300.0 - Ion ChromatographyFluorideWG361726
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
M300.0 - Ion Chromatography
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
M353.2 - H2SO4 preservedNitrate/Nitrite as NWG361834
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
M350.1 - Automated PhenateNitrogen, ammoniaWG361637
M1 Matrix spike recovery was high, the recovery of the associated control sample (LCS or LFB) was acceptable.
M365.1 - Auto Ascorbic Acid (digest)
Phosphorus, totalWG361691
RO The duplicate originally assigned to this sample was not used for precision assessment because residue density exceeded the method limits. Another duplicate in the batch was used to assess precision. Method required duplicate frequency was not met.
SM2540CResidue, Filterable (TDS) @180CWG361441
RA Relative Percent Difference (RPD) was not used for data
validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
SM2540DResidue, Non-Filterable (TSS) @105CWG361444
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
M300.0 - Ion ChromatographySulfateWG361726
REPAD.15.06.05.01
Page 54 of 60L17433-1404141323
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic Extended
Qualifier Report
ACZ Project ID: L17433SPF Water Engineering
ACZ ID PARAMETER QUAL DESCRIPTIONMETHODWORKNUM
M1 Matrix spike recovery was high, the recovery of the associated control sample (LCS or LFB) was acceptable.
M200.7 ICPAluminum, totalL17433-08 WG361527
VC CCV recovery was above the acceptance limits. Target analyte was not detected in the sample [< MDL].
M200.8 ICP-MSBeryllium, totalWG361760
M2 Matrix spike recovery was low, the recovery of the associated control sample (LCS or LFB) was acceptable.
M1631, Atomic FluorescenceMercury, dissolvedWG361562
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
M300.0 - Ion ChromatographyChlorideWG361726
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
M335.4 - Colorimetric w/ distillation
Cyanide, totalWG361655
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
SM4500-CN I-Colorimetric w/ distillation
Cyanide, WADWG361673
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
M300.0 - Ion ChromatographyFluorideWG361726
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
M353.2 - H2SO4 preservedNitrate/Nitrite as NWG361834
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
M350.1 - Automated PhenateNitrogen, ammoniaWG361637
M1 Matrix spike recovery was high, the recovery of the associated control sample (LCS or LFB) was acceptable.
M365.1 - Auto Ascorbic Acid (digest)
Phosphorus, totalWG361691
RO The duplicate originally assigned to this sample was not
used for precision assessment because residue density exceeded the method limits. Another duplicate in the batch was used to assess precision. Method required duplicate frequency was not met.
SM2540CResidue, Filterable (TDS) @180CWG361441
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
SM2540DResidue, Non-Filterable (TSS) @105CWG361444
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
M300.0 - Ion ChromatographySulfateWG361726
REPAD.15.06.05.01
Page 55 of 60L17433-1404141323
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Certification
Qualifiers
ACZ Project ID: L17433SPF Water Engineering
Metals Analysis
The following parameters are not offered for certification or are not covered by NELAC certificate #ACZ.
Bismuth, dissolved M200.7 ICP
Bismuth, total M200.7 ICP
Gallium, dissolved M200.7 ICP
Gallium, total M200.7 ICP
Scandium, dissolved M200.7 ICP
Scandium, total M200.7 ICP
Tin, dissolved M200.8 ICP-MS
Tin, total M200.8 ICP-MS
REPAD.05.06.05.01
Page 56 of 60L17433-1404141323
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Sample
Receipt
SPF Water EngineeringCalico 1st Quarter 2014 Sampling
ACZ Project ID:
Date Received:
Received By: mtb
03/26/2014 09:38
L17433
Date Printed: 3/26/2014
Chain of Custody Related Remarks
Client Contact Remarks
NANOYES
X
X
X
X
X
X
1) Is a foreign soil permit included for applicable samples?
2) Is the Chain of Custody or other directive shipping papers present?
3) Does this project require special handling procedures such as CLP protocol?
4) Are any samples NRC licensable material?
5) If samples are received past hold time, proceed with requested short hold time analyses?
6) Is the Chain of Custody complete and accurate?
7) Were any changes made to the Chain of Custody prior to ACZ receiving the samples?
Receipt Verification
NANOYES
X
X
X
X
X
X
X
X
X8) Are all containers intact and with no leaks?
9) Are all labels on containers and are they intact and legible?
10) Do the sample labels and Chain of Custody match for Sample ID, Date, and Time?
11) For preserved bottle types, was the pH checked and within limits?
12) Is there sufficient sample volume to perform all requested work?
13) Is the custody seal intact on all containers?
14) Are samples that require zero headspace acceptable?
15) Are all sample containers appropriate for analytical requirements?
16) Is there an Hg-1631 trip blank present?
17) Is there a VOA trip blank present?
18) Were all samples received within hold time?
Samples/Containers
X
X
Shipping Containers
Client must contact an ACZ Project Manager if analysis should not proceed for samples received outside of their thermal preservation acceptance criteria.
Cooler Id Temp (°C) Rad (µR/Hr) Custody Seal Intact?--------- --------- ----------- ------- -------------NA19354 0.5 13 YesNA19355 0.3 13 Yes
X
Was ice present in the shipment container(s)?
Yes - Wet ice was present in the shipment container (s).
REPAD LPII 2012-03
Page 57 of 60L17433-1404141323
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Analytical
Report
SPF Water Engineering
300 E. Mallard Drive, Suite 350
Boise, ID 83706
ACZ Project ID: L17275
Erik Boe:
Enclosed are the analytical results for sample(s) submitted to ACZ Laboratories, Inc. (ACZ) on March 19, 2014. This project has been assigned to ACZ's project number, L17275. Please reference this number in all future inquiries.
All analyses were performed according to ACZ's Quality Assurance Plan. The enclosed results relate only to the samples received under L17275. Each section of this report has been reviewed and approved by the appropriate Laboratory Supervisor, or a qualified substitute.
Except as noted, the test results for the methods and parameters listed on ACZ's current NELAC certificate letter (#ACZ) meet all requirements of NELAC.
This report shall be used or copied only in its entirety. ACZ is not responsible for the consequences arising from the use of a partial report.
All samples and sub-samples associated with this project will be disposed of after May 01, 2014. If the samples are determined to be hazardous, additional charges apply for disposal (typically $11/sample). If you would like the samples to be held longer than ACZ's stated policy or to be returned, please contact your Project Manager or Customer Service Representative for further details and associated costs. ACZ retains analytical raw data reports for ten years.
If you have any questions or other needs, please contact your Project Manager.
Erik Boe
April 01, 2014
Project ID: Calico 1st Quarter 2
SPF Water Engineering
300 E. Mallard Drive, Suite 350
Boise, ID 83706
Crystal Jensen
Report to: Bill to:
Page 1 of 90L17275-1404011436
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Case
Narrative
SPF Water Engineering
ACZ Project ID: L17275
April 01, 2014
Sample Receipt
Sample Analysis
Holding Times
Text10:ACZ Laboratories, Inc. (ACZ) received 15 ground water samples from SPF Water Engineering on March 19, 2014. The samples were received in good condition. Upon receipt, the sample custodian removed the samples from the cooler, inspected the contents, and logged the samples into ACZ's computerized Laboratory Information Management System (LIMS). The samples were assigned ACZ LIMS project number L17275. The custodian verified the sample information entered into the computer against the chain of custody (COC) forms and sample bottle labels.
Text10:These samples were analyzed for inorganic parameters. The individual methods are referenced on both the ACZ invoice and the analytical reports. The extended qualifier reports may contain footnotes qualifying specific elements due to QC failures. In addition the following has been noted with this specific project:
Some of the dissolved Cobalt values exceed the corresponding total values for project L17275. In some cases, RPDs between dissolved and total values exceed the standard acceptance limit of 20%. Samples were re-analyzed for verification, and results for both parameters were confirmed. This is a consistent anomaly with these sample types, and discrepancies may be attributed to a matrix or field sampling issue.
Text10:Any analyses not performed within EPA recommended holding times have been qualified with an "H" flag.
Project ID: Calico 1st Quarter 2
REPAD.03.06.05.01 Page 2 of 90L17275-1404011436
ACZ Sample ID: L17275-01
Sample ID: SAGEBRUSH SPRING
Sample Matrix: Ground Water
SPF Water Engineering
Project ID: Calico 1st Quarter 2
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic Analytical
Results
Date Sampled: 03/16/14 09:30
Date Received: 03/19/14
Parameter EPA Method Result Units MDLQual AnalystDatePQL
Inorganic Prep
XQDilution
Cyanide, total M335.4 - Manual Distillation bsu03/24/14 12:49
Cyanide, WAD SM4500-CN I- distillation mss203/26/14 8:38
Phosphorus, total M365.1 - Auto Ascorbic Acid Digestion
mpb03/27/14 14:36
Total Hot Plate Digestion
M200.2 ICP-MS las03/26/14 9:08
Total Hot Plate Digestion
M200.2 ICP jjc03/25/14 9:11
REPIN.02.06.05.01 * Please refer to Qualifier Reports for details.
Page 3 of 90L17275-1404011436
ACZ Sample ID: L17275-01
Sample ID: SAGEBRUSH SPRING
Sample Matrix: Ground Water
SPF Water Engineering
Project ID: Calico 1st Quarter 2
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic Analytical
Results
Date Sampled: 03/16/14 09:30
Date Received: 03/19/14
Parameter EPA Method Result Units MDLQual AnalystDatePQL
Metals Analysis
XQDilution
Aluminum, dissolved M200.7 ICP mg/L 0.2U aeb0.03 03/21/14 11:551
Aluminum, total M200.7 ICP mg/L 0.2U jjc0.03 03/26/14 10:151
Antimony, dissolved M200.8 ICP-MS mg/L 0.002U las0.0004 03/27/14 15:321
Antimony, total M200.8 ICP-MS mg/L 0.002U pmc0.0004 03/28/14 0:281
Arsenic, dissolved M200.8 ICP-MS 0.0080 mg/L 0.001 las0.0002 03/27/14 15:321
Arsenic, total M200.8 ICP-MS 0.0071 mg/L 0.001 pmc0.0002 03/28/14 0:281
Barium, dissolved M200.7 ICP 0.003 mg/L 0.02B aeb0.003 03/21/14 11:551
Barium, total M200.7 ICP 0.004 mg/L 0.02B jjc0.003 03/26/14 10:151
Beryllium, dissolved M200.8 ICP-MS mg/L 0.0003U las0.00005 03/27/14 15:321
Beryllium, total M200.8 ICP-MS mg/L 0.0003U pmc0.00005 03/28/14 0:281
Bismuth, dissolved M200.7 ICP mg/L 0.2U aeb0.04* 03/21/14 11:551
Bismuth, total M200.7 ICP mg/L 0.2U jjc0.04* 03/26/14 10:151
Boron, dissolved M200.7 ICP 0.05 mg/L 0.05 aeb0.01 03/21/14 11:551
Boron, total M200.7 ICP 0.06 mg/L 0.05 jjc0.01 03/26/14 10:151
Cadmium, dissolved M200.8 ICP-MS mg/L 0.0005U las0.0001 03/27/14 15:321
Cadmium, total M200.8 ICP-MS mg/L 0.0005U pmc0.0001 03/28/14 0:281
Calcium, dissolved M200.7 ICP 45.2 mg/L 0.5 aeb0.1* 03/21/14 11:551
Calcium, total M200.7 ICP 46 mg/L 0.5 jjc0.1 03/26/14 10:151
Chromium, dissolved M200.8 ICP-MS 0.0013 mg/L 0.002B las0.0005 03/27/14 15:321
Chromium, total M200.8 ICP-MS 0.0012 mg/L 0.002B pmc0.0005 03/28/14 0:281
Cobalt, dissolved M200.8 ICP-MS 0.00053 mg/L 0.0003 las0.00005 03/27/14 15:321
Cobalt, total M200.8 ICP-MS 0.00008 mg/L 0.0003B pmc0.00005 03/28/14 0:281
Copper, dissolved M200.8 ICP-MS mg/L 0.003U las0.0005 03/27/14 15:321
Copper, total M200.8 ICP-MS mg/L 0.003U pmc0.0005 03/28/14 0:281
Gallium, dissolved M200.7 ICP mg/L 0.5U aeb0.1* 03/21/14 11:551
Gallium, total M200.7 ICP mg/L 0.5U jjc0.1* 03/26/14 10:151
Iron, dissolved M200.7 ICP mg/L 0.05U aeb0.02 03/21/14 11:551
Iron, total M200.7 ICP mg/L 0.05U jjc0.02 03/26/14 10:151
Lead, dissolved M200.8 ICP-MS mg/L 0.0005U las0.0001 03/27/14 15:321
Lead, total M200.8 ICP-MS mg/L 0.0005U pmc0.0001 03/28/14 0:281
Lithium, dissolved M200.7 ICP 0.018 mg/L 0.04B aeb0.008 03/21/14 11:551
Lithium, total M200.7 ICP 0.021 mg/L 0.04B jjc0.008 03/26/14 10:151
Magnesium, dissolved M200.7 ICP 9.7 mg/L 1 aeb0.2 03/21/14 11:551
Magnesium, total M200.7 ICP 9.8 mg/L 1 jjc0.2 03/26/14 10:151
Manganese, dissolved M200.8 ICP-MS 0.0007 mg/L 0.003B las0.0005 03/27/14 15:321
Manganese, total M200.8 ICP-MS mg/L 0.003U pmc0.0005 03/28/14 0:281
Mercury, dissolved M1631, Atomic Fluorescence ng/L 0.5U las0.2 03/27/14 12:551
Mercury, total M1631, Atomic Fluorescence 0.6 ng/L 0.5 las0.2 03/28/14 16:191
Molybdenum, dissolved M200.8 ICP-MS 0.0017 mg/L 0.003B las0.0005 03/27/14 15:321
Molybdenum, total M200.8 ICP-MS 0.0017 mg/L 0.003B pmc0.0005 03/28/14 0:281
Nickel, dissolved M200.8 ICP-MS mg/L 0.003U las0.0006 03/27/14 15:321
Nickel, total M200.8 ICP-MS mg/L 0.003U pmc0.0006 03/28/14 0:281
Potassium, dissolved M200.7 ICP 4.8 mg/L 1 aeb0.2 03/21/14 11:551
REPIN.02.06.05.01 * Please refer to Qualifier Reports for details.
Page 4 of 90L17275-1404011436
ACZ Sample ID: L17275-01
Sample ID: SAGEBRUSH SPRING
Sample Matrix: Ground Water
SPF Water Engineering
Project ID: Calico 1st Quarter 2
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic Analytical
Results
Date Sampled: 03/16/14 09:30
Date Received: 03/19/14
Potassium, total M200.7 ICP 4.7 mg/L 1 jjc0.2 03/26/14 10:151
Scandium, dissolved M200.7 ICP mg/L 0.5U aeb0.1* 03/21/14 11:551
Scandium, total M200.7 ICP mg/L 0.5U jjc0.1* 03/26/14 10:151
Selenium, dissolved M200.8 ICP-MS 0.0011 mg/L 0.0003 las0.0001 03/27/14 15:321
Selenium, total M200.8 ICP-MS 0.0010 mg/L 0.0003 pmc0.0001 03/28/14 0:281
Silver, dissolved M200.8 ICP-MS mg/L 0.0003U las0.00005 03/27/14 15:321
Silver, total M200.8 ICP-MS mg/L 0.0003U pmc0.00005 03/28/14 0:281
Sodium, dissolved M200.7 ICP 19.9 mg/L 1 aeb0.2 03/21/14 11:551
Sodium, total M200.7 ICP 20.5 mg/L 1 jjc0.2 03/26/14 10:151
Strontium, dissolved M200.7 ICP 0.201 mg/L 0.03 aeb0.005 03/21/14 11:551
Strontium, total M200.7 ICP 0.202 mg/L 0.03 jjc0.005 03/26/14 10:151
Thallium, dissolved M200.8 ICP-MS mg/L 0.0005U las0.0001 03/27/14 15:321
Thallium, total M200.8 ICP-MS mg/L 0.0005U pmc0.0001 03/28/14 0:281
Tin, dissolved M200.8 ICP-MS mg/L 0.0005U las0.0001* 03/27/14 15:321
Tin, total M200.8 ICP-MS mg/L 0.0005U pmc0.0001* 03/28/14 0:281
Titanium, dissolved M200.7 ICP mg/L 0.03U aeb0.005 03/21/14 11:551
Titanium, total M200.7 ICP 0.009 mg/L 0.03B jjc0.005 03/26/14 10:151
Uranium, dissolved M200.8 ICP-MS 0.0037 mg/L 0.0005 las0.0001 03/27/14 15:321
Uranium, total M200.8 ICP-MS 0.0040 mg/L 0.0005 pmc0.0001 03/28/14 0:281
Vanadium, dissolved M200.8 ICP-MS 0.0201 mg/L 0.001 las0.0002 03/27/14 15:321
Vanadium, total M200.8 ICP-MS 0.0197 mg/L 0.001 pmc0.0002 03/28/14 0:281
Zinc, dissolved M200.7 ICP mg/L 0.05U aeb0.01 03/21/14 11:551
Zinc, total M200.7 ICP mg/L 0.05U jjc0.01 03/26/14 10:151
REPIN.02.06.05.01 * Please refer to Qualifier Reports for details.
Page 5 of 90L17275-1404011436
ACZ Sample ID: L17275-01
Sample ID: SAGEBRUSH SPRING
Sample Matrix: Ground Water
SPF Water Engineering
Project ID: Calico 1st Quarter 2
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic Analytical
Results
Date Sampled: 03/16/14 09:30
Date Received: 03/19/14
Parameter EPA Method Result Units MDLQual AnalystDatePQL
Wet Chemistry
XQDilution
Alkalinity as CaCO3 SM2320B - Titration
Bicarbonate as CaCO3
128 mg/L 20 abd2 03/24/14 0:001
Carbonate as CaCO3 mg/L 20U abd2 03/24/14 0:001
Hydroxide as CaCO3 mg/L 20U abd2 03/24/14 0:001
Total Alkalinity 128 mg/L 20 abd2 03/24/14 0:001
Chloride M300.0 - Ion Chromatography 9.71 mg/L 2.5 tcd0.5* 03/25/14 20:401
Conductivity @25C SM2510B 383 umhos/cm 10 abd1 03/24/14 17:051
Cyanide, total M335.4 - Colorimetric w/ distillation mg/L 0.01U bsu0.003* 03/24/14 18:100.5
Cyanide, WAD SM4500-CN I-Colorimetric w/ distillation
mg/L 0.01U mpb0.003* 03/27/14 13:320.5
Fluoride M300.0 - Ion Chromatography 0.32 mg/L 0.5B tcd0.1* 03/25/14 20:401
Hardness as CaCO3 SM2340B - Calculation 153 mg/L 7 calc1 04/01/14 12:21
Nitrate/Nitrite as N M353.2 - H2SO4 preserved 3.48 mg/L 0.1 pjb0.02 03/27/14 23:341
Nitrogen, ammonia M350.1 - Automated Phenate mg/L 0.5U tcd0.05* 03/27/14 12:371
pH (lab) SM4500H+ B
pH 8.2 units 0.1H abd0.1 03/24/14 0:001
pH measured at 19 C 0.1 abd0.1 03/24/14 0:001
Phosphorus, total M365.1 - Auto Ascorbic Acid (digest)
mg/L 0.05U pjb0.01* 03/28/14 0:111
Residue, Filterable (TDS) @180C
SM2540C 270 mg/L 20 id10 03/20/14 12:431
Residue, Non-Filterable (TSS) @105C
SM2540D mg/L 20U enb5* 03/21/14 12:451
Sulfate M300.0 - Ion Chromatography 15.6 mg/L 2.5 tcd0.5 03/25/14 20:401
REPIN.02.06.05.01 * Please refer to Qualifier Reports for details.
Page 6 of 90L17275-1404011436
ACZ Sample ID: L17275-02
Sample ID: GOVERNMENT CORRAL SPRING
Sample Matrix: Ground Water
SPF Water Engineering
Project ID: Calico 1st Quarter 2014 Sa
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic Analytical
Results
Date Sampled: 03/16/14 10:30
Date Received: 03/19/14
Parameter EPA Method Result Units MDLQual AnalystDatePQL
Inorganic Prep
XQDilution
Cyanide, total M335.4 - Manual Distillation bsu03/24/14 13:08
Cyanide, WAD SM4500-CN I- distillation mss203/26/14 8:57
Phosphorus, total M365.1 - Auto Ascorbic Acid Digestion
mpb03/27/14 14:51
Total Hot Plate Digestion
M200.2 ICP-MS las03/26/14 9:18
Total Hot Plate Digestion
M200.2 ICP jjc03/25/14 9:46
REPIN.02.06.05.01 * Please refer to Qualifier Reports for details.
Page 7 of 90L17275-1404011436
ACZ Sample ID: L17275-02
Sample ID: GOVERNMENT CORRAL SPRING
Sample Matrix: Ground Water
SPF Water Engineering
Project ID: Calico 1st Quarter 2014 Sa
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic Analytical
Results
Date Sampled: 03/16/14 10:30
Date Received: 03/19/14
Parameter EPA Method Result Units MDLQual AnalystDatePQL
Metals Analysis
XQDilution
Aluminum, dissolved M200.7 ICP mg/L 0.2U aeb0.03 03/21/14 11:591
Aluminum, total M200.7 ICP 0.05 mg/L 0.2B jjc0.03 03/26/14 10:241
Antimony, dissolved M200.8 ICP-MS mg/L 0.002U las0.0004 03/27/14 15:361
Antimony, total M200.8 ICP-MS mg/L 0.002U pmc0.0004 03/28/14 0:311
Arsenic, dissolved M200.8 ICP-MS 0.0084 mg/L 0.001 las0.0002 03/27/14 15:361
Arsenic, total M200.8 ICP-MS 0.0073 mg/L 0.001 pmc0.0002 03/28/14 0:311
Barium, dissolved M200.7 ICP 0.028 mg/L 0.02 aeb0.003 03/21/14 11:591
Barium, total M200.7 ICP 0.030 mg/L 0.02 jjc0.003 03/26/14 10:241
Beryllium, dissolved M200.8 ICP-MS mg/L 0.0003U las0.00005 03/27/14 15:361
Beryllium, total M200.8 ICP-MS mg/L 0.0003U pmc0.00005 03/28/14 0:311
Bismuth, dissolved M200.7 ICP mg/L 0.2U aeb0.04* 03/21/14 11:591
Bismuth, total M200.7 ICP 0.04 mg/L 0.2B jjc0.04* 03/26/14 10:241
Boron, dissolved M200.7 ICP 0.05 mg/L 0.05 aeb0.01 03/21/14 11:591
Boron, total M200.7 ICP 0.05 mg/L 0.05 jjc0.01 03/26/14 10:241
Cadmium, dissolved M200.8 ICP-MS mg/L 0.0005U las0.0001 03/27/14 15:361
Cadmium, total M200.8 ICP-MS mg/L 0.0005U pmc0.0001 03/28/14 0:311
Calcium, dissolved M200.7 ICP 46.3 mg/L 0.5 aeb0.1* 03/21/14 11:591
Calcium, total M200.7 ICP 48 mg/L 0.5 jjc0.1 03/26/14 10:241
Chromium, dissolved M200.8 ICP-MS 0.0013 mg/L 0.002B las0.0005 03/27/14 15:361
Chromium, total M200.8 ICP-MS 0.0016 mg/L 0.002B pmc0.0005 03/28/14 0:311
Cobalt, dissolved M200.8 ICP-MS 0.00012 mg/L 0.0003B las0.00005 03/27/14 15:361
Cobalt, total M200.8 ICP-MS 0.00012 mg/L 0.0003B pmc0.00005 03/28/14 0:311
Copper, dissolved M200.8 ICP-MS mg/L 0.003U las0.0005 03/27/14 15:361
Copper, total M200.8 ICP-MS mg/L 0.003U pmc0.0005 03/28/14 0:311
Gallium, dissolved M200.7 ICP mg/L 0.5U aeb0.1* 03/21/14 11:591
Gallium, total M200.7 ICP mg/L 0.5U jjc0.1* 03/26/14 10:241
Iron, dissolved M200.7 ICP mg/L 0.05U aeb0.02 03/21/14 11:591
Iron, total M200.7 ICP 0.06 mg/L 0.05 jjc0.02 03/26/14 10:241
Lead, dissolved M200.8 ICP-MS mg/L 0.0005U las0.0001 03/27/14 15:361
Lead, total M200.8 ICP-MS mg/L 0.0005U pmc0.0001 03/28/14 0:311
Lithium, dissolved M200.7 ICP 0.017 mg/L 0.04B aeb0.008 03/21/14 11:591
Lithium, total M200.7 ICP 0.021 mg/L 0.04B jjc0.008 03/26/14 10:241
Magnesium, dissolved M200.7 ICP 13.7 mg/L 1 aeb0.2 03/21/14 11:591
Magnesium, total M200.7 ICP 14 mg/L 1 jjc0.2 03/26/14 10:241
Manganese, dissolved M200.8 ICP-MS mg/L 0.003U las0.0005 03/27/14 15:361
Manganese, total M200.8 ICP-MS 0.0035 mg/L 0.003 pmc0.0005 03/28/14 0:311
Mercury, dissolved M1631, Atomic Fluorescence ng/L 0.5U las0.2 03/27/14 13:001
Mercury, total M1631, Atomic Fluorescence 0.5 ng/L 0.5 las0.2 03/28/14 16:241
Molybdenum, dissolved M200.8 ICP-MS 0.0016 mg/L 0.003B las0.0005 03/27/14 15:361
Molybdenum, total M200.8 ICP-MS 0.0017 mg/L 0.003B pmc0.0005 03/28/14 0:311
Nickel, dissolved M200.8 ICP-MS mg/L 0.003U las0.0006 03/27/14 15:361
Nickel, total M200.8 ICP-MS mg/L 0.003U pmc0.0006 03/28/14 0:311
Potassium, dissolved M200.7 ICP 4 mg/L 1 aeb0.2 03/21/14 11:591
REPIN.02.06.05.01 * Please refer to Qualifier Reports for details.
Page 8 of 90L17275-1404011436
ACZ Sample ID: L17275-02
Sample ID: GOVERNMENT CORRAL SPRING
Sample Matrix: Ground Water
SPF Water Engineering
Project ID: Calico 1st Quarter 2014 Sa
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic Analytical
Results
Date Sampled: 03/16/14 10:30
Date Received: 03/19/14
Potassium, total M200.7 ICP 4 mg/L 1 jjc0.2 03/26/14 10:241
Scandium, dissolved M200.7 ICP mg/L 0.5U aeb0.1* 03/21/14 11:591
Scandium, total M200.7 ICP mg/L 0.5U jjc0.1* 03/26/14 10:241
Selenium, dissolved M200.8 ICP-MS 0.0018 mg/L 0.0003 las0.0001 03/27/14 15:361
Selenium, total M200.8 ICP-MS 0.0016 mg/L 0.0003 pmc0.0001 03/28/14 0:311
Silver, dissolved M200.8 ICP-MS mg/L 0.0003U las0.00005 03/27/14 15:361
Silver, total M200.8 ICP-MS mg/L 0.0003U pmc0.00005 03/28/14 0:311
Sodium, dissolved M200.7 ICP 18.1 mg/L 1 aeb0.2 03/21/14 11:591
Sodium, total M200.7 ICP 18.7 mg/L 1 jjc0.2 03/26/14 10:241
Strontium, dissolved M200.7 ICP 0.244 mg/L 0.03 aeb0.005 03/21/14 11:591
Strontium, total M200.7 ICP 0.245 mg/L 0.03 jjc0.005 03/26/14 10:241
Thallium, dissolved M200.8 ICP-MS mg/L 0.0005U las0.0001 03/27/14 15:361
Thallium, total M200.8 ICP-MS mg/L 0.0005U pmc0.0001 03/28/14 0:311
Tin, dissolved M200.8 ICP-MS mg/L 0.0005U las0.0001* 03/27/14 15:361
Tin, total M200.8 ICP-MS mg/L 0.0005U pmc0.0001* 03/28/14 0:311
Titanium, dissolved M200.7 ICP mg/L 0.03U aeb0.005 03/21/14 11:591
Titanium, total M200.7 ICP 0.011 mg/L 0.03B jjc0.005 03/26/14 10:241
Uranium, dissolved M200.8 ICP-MS 0.0020 mg/L 0.0005 las0.0001 03/27/14 15:361
Uranium, total M200.8 ICP-MS 0.0021 mg/L 0.0005 pmc0.0001 03/28/14 0:311
Vanadium, dissolved M200.8 ICP-MS 0.0204 mg/L 0.001 las0.0002 03/27/14 15:361
Vanadium, total M200.8 ICP-MS 0.0195 mg/L 0.001 pmc0.0002 03/28/14 0:311
Zinc, dissolved M200.7 ICP mg/L 0.05U aeb0.01 03/21/14 11:591
Zinc, total M200.7 ICP mg/L 0.05U jjc0.01 03/26/14 10:241
REPIN.02.06.05.01 * Please refer to Qualifier Reports for details.
Page 9 of 90L17275-1404011436
ACZ Sample ID: L17275-02
Sample ID: GOVERNMENT CORRAL SPRING
Sample Matrix: Ground Water
SPF Water Engineering
Project ID: Calico 1st Quarter 2014 Sa
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic Analytical
Results
Date Sampled: 03/16/14 10:30
Date Received: 03/19/14
Parameter EPA Method Result Units MDLQual AnalystDatePQL
Wet Chemistry
XQDilution
Alkalinity as CaCO3 SM2320B - Titration
Bicarbonate as CaCO3
138 mg/L 20 abd2 03/24/14 0:001
Carbonate as CaCO3 mg/L 20U abd2 03/24/14 0:001
Hydroxide as CaCO3 mg/L 20U abd2 03/24/14 0:001
Total Alkalinity 138 mg/L 20 abd2 03/24/14 0:001
Chloride M300.0 - Ion Chromatography 13.2 mg/L 2.5 tcd0.5* 03/25/14 20:581
Conductivity @25C SM2510B 423 umhos/cm 10 abd1 03/24/14 17:141
Cyanide, total M335.4 - Colorimetric w/ distillation mg/L 0.01U bsu0.003* 03/24/14 18:120.5
Cyanide, WAD SM4500-CN I-Colorimetric w/ distillation
mg/L 0.01U mpb0.003* 03/27/14 13:340.5
Fluoride M300.0 - Ion Chromatography 0.38 mg/L 0.5B tcd0.1* 03/25/14 20:581
Hardness as CaCO3 SM2340B - Calculation 172 mg/L 7 calc1 04/01/14 12:22
Nitrate/Nitrite as N M353.2 - H2SO4 preserved 2.99 mg/L 0.1 pjb0.02 03/27/14 23:351
Nitrogen, ammonia M350.1 - Automated Phenate mg/L 0.5U tcd0.05* 03/27/14 12:381
pH (lab) SM4500H+ B
pH 8.2 units 0.1H abd0.1 03/24/14 0:001
pH measured at 20 C 0.1 abd0.1 03/24/14 0:001
Phosphorus, total M365.1 - Auto Ascorbic Acid (digest)
0.01 mg/L 0.05B pjb0.01* 03/28/14 0:141
Residue, Filterable (TDS) @180C
SM2540C 280 mg/L 20 id10 03/21/14 9:311
Residue, Non-Filterable (TSS) @105C
SM2540D mg/L 20U enb5* 03/21/14 12:461
Sulfate M300.0 - Ion Chromatography 24.0 mg/L 2.5 tcd0.5 03/25/14 20:581
REPIN.02.06.05.01 * Please refer to Qualifier Reports for details.
Page 10 of 90L17275-1404011436
ACZ Sample ID: L17275-03
Sample ID: POISON SPRING
Sample Matrix: Ground Water
SPF Water Engineering
Project ID: Calico 1st Quarter 2014 Sa
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic Analytical
Results
Date Sampled: 03/16/14 11:45
Date Received: 03/19/14
Parameter EPA Method Result Units MDLQual AnalystDatePQL
Inorganic Prep
XQDilution
Cyanide, total M335.4 - Manual Distillation bsu03/24/14 13:27
Cyanide, WAD SM4500-CN I- distillation mss203/26/14 9:07
Phosphorus, total M365.1 - Auto Ascorbic Acid Digestion
mpb03/27/14 15:06
Total Hot Plate Digestion
M200.2 ICP jjc03/25/14 9:57
Total Hot Plate Digestion
M200.2 ICP-MS las03/26/14 9:27
REPIN.02.06.05.01 * Please refer to Qualifier Reports for details.
Page 11 of 90L17275-1404011436
ACZ Sample ID: L17275-03
Sample ID: POISON SPRING
Sample Matrix: Ground Water
SPF Water Engineering
Project ID: Calico 1st Quarter 2014 Sa
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic Analytical
Results
Date Sampled: 03/16/14 11:45
Date Received: 03/19/14
Parameter EPA Method Result Units MDLQual AnalystDatePQL
Metals Analysis
XQDilution
Aluminum, dissolved M200.7 ICP mg/L 0.2U aeb0.03 03/21/14 12:021
Aluminum, total M200.7 ICP mg/L 0.2U jjc0.03 03/26/14 10:271
Antimony, dissolved M200.8 ICP-MS mg/L 0.002U las0.0004 03/27/14 15:391
Antimony, total M200.8 ICP-MS mg/L 0.002U pmc0.0004 03/28/14 0:351
Arsenic, dissolved M200.8 ICP-MS 0.0396 mg/L 0.001 las0.0002 03/27/14 15:391
Arsenic, total M200.8 ICP-MS 0.0337 mg/L 0.001 pmc0.0002 03/28/14 0:351
Barium, dissolved M200.7 ICP 0.004 mg/L 0.02B aeb0.003 03/21/14 12:021
Barium, total M200.7 ICP 0.004 mg/L 0.02B jjc0.003 03/26/14 10:271
Beryllium, dissolved M200.8 ICP-MS mg/L 0.0003U las0.00005 03/27/14 15:391
Beryllium, total M200.8 ICP-MS mg/L 0.0003U pmc0.00005 03/28/14 0:351
Bismuth, dissolved M200.7 ICP mg/L 0.2U aeb0.04* 03/21/14 12:021
Bismuth, total M200.7 ICP 0.06 mg/L 0.2B jjc0.04* 03/26/14 10:271
Boron, dissolved M200.7 ICP 0.13 mg/L 0.05 aeb0.01 03/21/14 12:021
Boron, total M200.7 ICP 0.12 mg/L 0.05 jjc0.01 03/26/14 10:271
Cadmium, dissolved M200.8 ICP-MS mg/L 0.0005U las0.0001 03/27/14 15:391
Cadmium, total M200.8 ICP-MS mg/L 0.0005U pmc0.0001 03/28/14 0:351
Calcium, dissolved M200.7 ICP 1 mg/L 0.5 aeb0.1* 03/21/14 12:021
Calcium, total M200.7 ICP 1.1 mg/L 0.5 jjc0.1 03/26/14 10:271
Chromium, dissolved M200.8 ICP-MS mg/L 0.002U las0.0005 03/27/14 15:391
Chromium, total M200.8 ICP-MS mg/L 0.002U pmc0.0005 03/28/14 0:351
Cobalt, dissolved M200.8 ICP-MS mg/L 0.0003U las0.00005 03/27/14 15:391
Cobalt, total M200.8 ICP-MS mg/L 0.0003U pmc0.00005 03/28/14 0:351
Copper, dissolved M200.8 ICP-MS mg/L 0.003U las0.0005 03/27/14 15:391
Copper, total M200.8 ICP-MS mg/L 0.003U pmc0.0005 03/28/14 0:351
Gallium, dissolved M200.7 ICP mg/L 0.5U aeb0.1* 03/21/14 12:021
Gallium, total M200.7 ICP mg/L 0.5U jjc0.1* 03/26/14 10:271
Iron, dissolved M200.7 ICP mg/L 0.05U aeb0.02 03/21/14 12:021
Iron, total M200.7 ICP mg/L 0.05U jjc0.02 03/26/14 10:271
Lead, dissolved M200.8 ICP-MS mg/L 0.0005U las0.0001 03/27/14 15:391
Lead, total M200.8 ICP-MS mg/L 0.0005U pmc0.0001 03/28/14 0:351
Lithium, dissolved M200.7 ICP mg/L 0.04U aeb0.008 03/21/14 12:021
Lithium, total M200.7 ICP 0.009 mg/L 0.04B jjc0.008 03/26/14 10:271
Magnesium, dissolved M200.7 ICP mg/L 1U aeb0.2 03/21/14 12:021
Magnesium, total M200.7 ICP mg/L 1U jjc0.2 03/26/14 10:271
Manganese, dissolved M200.8 ICP-MS 0.0009 mg/L 0.003B las0.0005 03/27/14 15:391
Manganese, total M200.8 ICP-MS 0.0008 mg/L 0.003B pmc0.0005 03/28/14 0:351
Mercury, dissolved M1631, Atomic Fluorescence ng/L 0.5U las0.2 03/27/14 13:051
Mercury, total M1631, Atomic Fluorescence 0.5 ng/L 0.5 las0.2 03/28/14 16:391
Molybdenum, dissolved M200.8 ICP-MS 0.0154 mg/L 0.003 las0.0005 03/27/14 15:391
Molybdenum, total M200.8 ICP-MS 0.0155 mg/L 0.003 pmc0.0005 03/28/14 0:351
Nickel, dissolved M200.8 ICP-MS mg/L 0.003U las0.0006 03/27/14 15:391
Nickel, total M200.8 ICP-MS mg/L 0.003U pmc0.0006 03/28/14 0:351
Potassium, dissolved M200.7 ICP 5.5 mg/L 1 aeb0.2 03/21/14 12:021
REPIN.02.06.05.01 * Please refer to Qualifier Reports for details.
Page 12 of 90L17275-1404011436
ACZ Sample ID: L17275-03
Sample ID: POISON SPRING
Sample Matrix: Ground Water
SPF Water Engineering
Project ID: Calico 1st Quarter 2014 Sa
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic Analytical
Results
Date Sampled: 03/16/14 11:45
Date Received: 03/19/14
Potassium, total M200.7 ICP 5.5 mg/L 1 jjc0.2 03/26/14 10:271
Scandium, dissolved M200.7 ICP mg/L 0.5U aeb0.1* 03/21/14 12:021
Scandium, total M200.7 ICP mg/L 0.5U jjc0.1* 03/26/14 10:271
Selenium, dissolved M200.8 ICP-MS mg/L 0.0003U las0.0001 03/27/14 15:391
Selenium, total M200.8 ICP-MS mg/L 0.0003U pmc0.0001 03/28/14 0:351
Silver, dissolved M200.8 ICP-MS mg/L 0.0003U las0.00005 03/27/14 15:391
Silver, total M200.8 ICP-MS mg/L 0.0003U pmc0.00005 03/28/14 0:351
Sodium, dissolved M200.7 ICP 105 mg/L 1 aeb0.2 03/21/14 12:021
Sodium, total M200.7 ICP 111 mg/L 1 jjc0.2 03/26/14 10:271
Strontium, dissolved M200.7 ICP mg/L 0.03U aeb0.005 03/21/14 12:021
Strontium, total M200.7 ICP 0.005 mg/L 0.03B jjc0.005 03/26/14 10:271
Thallium, dissolved M200.8 ICP-MS mg/L 0.0005U las0.0001 03/27/14 15:391
Thallium, total M200.8 ICP-MS mg/L 0.0005U pmc0.0001 03/28/14 0:351
Tin, dissolved M200.8 ICP-MS mg/L 0.0005U las0.0001* 03/27/14 15:391
Tin, total M200.8 ICP-MS mg/L 0.0005U pmc0.0001* 03/28/14 0:351
Titanium, dissolved M200.7 ICP mg/L 0.03U aeb0.005 03/21/14 12:021
Titanium, total M200.7 ICP mg/L 0.03U jjc0.005 03/26/14 10:271
Uranium, dissolved M200.8 ICP-MS mg/L 0.0005U las0.0001 03/27/14 15:391
Uranium, total M200.8 ICP-MS mg/L 0.0005U pmc0.0001 03/28/14 0:351
Vanadium, dissolved M200.8 ICP-MS mg/L 0.001U las0.0002 03/27/14 15:391
Vanadium, total M200.8 ICP-MS 0.0004 mg/L 0.001B pmc0.0002 03/28/14 0:351
Zinc, dissolved M200.7 ICP mg/L 0.05U aeb0.01 03/21/14 12:021
Zinc, total M200.7 ICP mg/L 0.05U jjc0.01 03/26/14 10:271
REPIN.02.06.05.01 * Please refer to Qualifier Reports for details.
Page 13 of 90L17275-1404011436
ACZ Sample ID: L17275-03
Sample ID: POISON SPRING
Sample Matrix: Ground Water
SPF Water Engineering
Project ID: Calico 1st Quarter 2014 Sa
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic Analytical
Results
Date Sampled: 03/16/14 11:45
Date Received: 03/19/14
Parameter EPA Method Result Units MDLQual AnalystDatePQL
Wet Chemistry
XQDilution
Alkalinity as CaCO3 SM2320B - Titration
Bicarbonate as CaCO3
98 mg/L 20 abd2 03/24/14 0:001
Carbonate as CaCO3 43 mg/L 20 abd2 03/24/14 0:001
Hydroxide as CaCO3 mg/L 20U abd2 03/24/14 0:001
Total Alkalinity 141 mg/L 20 abd2 03/24/14 0:001
Chloride M300.0 - Ion Chromatography 9.12 mg/L 2.5 tcd0.5* 03/25/14 21:161
Conductivity @25C SM2510B 496 umhos/cm 10 abd1 03/24/14 17:231
Cyanide, total M335.4 - Colorimetric w/ distillation mg/L 0.01U bsu0.003* 03/24/14 18:140.5
Cyanide, WAD SM4500-CN I-Colorimetric w/ distillation
mg/L 0.01U mpb0.003* 03/27/14 13:350.5
Fluoride M300.0 - Ion Chromatography 0.74 mg/L 0.5 tcd0.1* 03/25/14 21:161
Hardness as CaCO3 SM2340B - Calculation 3 mg/L 7B calc1 04/01/14 12:22
Nitrate/Nitrite as N M353.2 - H2SO4 preserved mg/L 0.1U pjb0.02 03/27/14 23:361
Nitrogen, ammonia M350.1 - Automated Phenate mg/L 0.5U tcd0.05* 03/27/14 12:391
pH (lab) SM4500H+ B
pH 9.1 units 0.1H abd0.1 03/24/14 0:001
pH measured at 20 C 0.1 abd0.1 03/24/14 0:001
Phosphorus, total M365.1 - Auto Ascorbic Acid (digest)
0.02 mg/L 0.05B pjb0.01* 03/28/14 0:161
Residue, Filterable (TDS) @180C
SM2540C 350 mg/L 20 id10 03/21/14 9:331
Residue, Non-Filterable (TSS) @105C
SM2540D mg/L 20U dcw5* 03/22/14 11:101
Sulfate M300.0 - Ion Chromatography 59.2 mg/L 2.5 tcd0.5 03/25/14 21:161
REPIN.02.06.05.01 * Please refer to Qualifier Reports for details.
Page 14 of 90L17275-1404011436
ACZ Sample ID: L17275-04
Sample ID: DEPOSIT STOCK TANK
Sample Matrix: Ground Water
SPF Water Engineering
Project ID: Calico 1st Quarter 2014 Sa
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic Analytical
Results
Date Sampled: 03/16/14 12:35
Date Received: 03/19/14
Parameter EPA Method Result Units MDLQual AnalystDatePQL
Inorganic Prep
XQDilution
Cyanide, total M335.4 - Manual Distillation bsu03/24/14 13:37
Cyanide, WAD SM4500-CN I- distillation mss203/26/14 9:16
Phosphorus, total M365.1 - Auto Ascorbic Acid Digestion
mpb03/27/14 15:14
Total Hot Plate Digestion
M200.2 ICP-MS las03/26/14 9:37
Total Hot Plate Digestion
M200.2 ICP jjc03/25/14 10:09
REPIN.02.06.05.01 * Please refer to Qualifier Reports for details.
Page 15 of 90L17275-1404011436
ACZ Sample ID: L17275-04
Sample ID: DEPOSIT STOCK TANK
Sample Matrix: Ground Water
SPF Water Engineering
Project ID: Calico 1st Quarter 2014 Sa
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic Analytical
Results
Date Sampled: 03/16/14 12:35
Date Received: 03/19/14
Parameter EPA Method Result Units MDLQual AnalystDatePQL
Metals Analysis
XQDilution
Aluminum, dissolved M200.7 ICP mg/L 0.2U aeb0.03 03/21/14 12:051
Aluminum, total M200.7 ICP mg/L 0.2U jjc0.03 03/26/14 10:301
Antimony, dissolved M200.8 ICP-MS mg/L 0.002U las0.0004 03/27/14 15:421
Antimony, total M200.8 ICP-MS mg/L 0.002U pmc0.0004 03/28/14 0:381
Arsenic, dissolved M200.8 ICP-MS 0.0301 mg/L 0.001 las0.0002 03/27/14 15:421
Arsenic, total M200.8 ICP-MS 0.0257 mg/L 0.001 pmc0.0002 03/28/14 0:381
Barium, dissolved M200.7 ICP 0.049 mg/L 0.02 aeb0.003 03/21/14 12:051
Barium, total M200.7 ICP 0.051 mg/L 0.02 jjc0.003 03/26/14 10:301
Beryllium, dissolved M200.8 ICP-MS mg/L 0.0003U las0.00005 03/27/14 15:421
Beryllium, total M200.8 ICP-MS mg/L 0.0003U pmc0.00005 03/28/14 0:381
Bismuth, dissolved M200.7 ICP mg/L 0.2U aeb0.04* 03/21/14 12:051
Bismuth, total M200.7 ICP mg/L 0.2U jjc0.04* 03/26/14 10:301
Boron, dissolved M200.7 ICP 0.07 mg/L 0.05 aeb0.01 03/21/14 12:051
Boron, total M200.7 ICP 0.07 mg/L 0.05 jjc0.01 03/26/14 10:301
Cadmium, dissolved M200.8 ICP-MS mg/L 0.0005U las0.0001 03/27/14 15:421
Cadmium, total M200.8 ICP-MS mg/L 0.0005U pmc0.0001 03/28/14 0:381
Calcium, dissolved M200.7 ICP 53.6 mg/L 0.5 aeb0.1* 03/21/14 12:051
Calcium, total M200.7 ICP 55.7 mg/L 0.5 jjc0.1 03/26/14 10:301
Chromium, dissolved M200.8 ICP-MS mg/L 0.002U las0.0005 03/27/14 15:421
Chromium, total M200.8 ICP-MS mg/L 0.002U pmc0.0005 03/28/14 0:381
Cobalt, dissolved M200.8 ICP-MS 0.00026 mg/L 0.0003B las0.00005 03/27/14 15:421
Cobalt, total M200.8 ICP-MS 0.00012 mg/L 0.0003B pmc0.00005 03/28/14 0:381
Copper, dissolved M200.8 ICP-MS mg/L 0.003U las0.0005 03/27/14 15:421
Copper, total M200.8 ICP-MS mg/L 0.003U pmc0.0005 03/28/14 0:381
Gallium, dissolved M200.7 ICP mg/L 0.5U aeb0.1* 03/21/14 12:051
Gallium, total M200.7 ICP mg/L 0.5U jjc0.1* 03/26/14 10:301
Iron, dissolved M200.7 ICP mg/L 0.05U aeb0.02 03/21/14 12:051
Iron, total M200.7 ICP mg/L 0.05U jjc0.02 03/26/14 10:301
Lead, dissolved M200.8 ICP-MS mg/L 0.0005U las0.0001 03/27/14 15:421
Lead, total M200.8 ICP-MS mg/L 0.0005U pmc0.0001 03/28/14 0:381
Lithium, dissolved M200.7 ICP 0.040 mg/L 0.04 aeb0.008 03/21/14 12:051
Lithium, total M200.7 ICP 0.046 mg/L 0.04 jjc0.008 03/26/14 10:301
Magnesium, dissolved M200.7 ICP 11.8 mg/L 1 aeb0.2 03/21/14 12:051
Magnesium, total M200.7 ICP 12 mg/L 1 jjc0.2 03/26/14 10:301
Manganese, dissolved M200.8 ICP-MS 0.0033 mg/L 0.003 las0.0005 03/27/14 15:421
Manganese, total M200.8 ICP-MS 0.0030 mg/L 0.003 pmc0.0005 03/28/14 0:381
Mercury, total M1631, Atomic Fluorescence 0.9 ng/L 0.5 las0.2 03/28/14 16:441
Molybdenum, dissolved M200.8 ICP-MS 0.0035 mg/L 0.003 las0.0005 03/27/14 15:421
Molybdenum, total M200.8 ICP-MS 0.0036 mg/L 0.003 pmc0.0005 03/28/14 0:381
Nickel, dissolved M200.8 ICP-MS mg/L 0.003U las0.0006 03/27/14 15:421
Nickel, total M200.8 ICP-MS mg/L 0.003U pmc0.0006 03/28/14 0:381
Potassium, dissolved M200.7 ICP 4.3 mg/L 1 aeb0.2 03/21/14 12:051
Potassium, total M200.7 ICP 4.3 mg/L 1 jjc0.2 03/26/14 10:301
REPIN.02.06.05.01 * Please refer to Qualifier Reports for details.
Page 16 of 90L17275-1404011436
ACZ Sample ID: L17275-04
Sample ID: DEPOSIT STOCK TANK
Sample Matrix: Ground Water
SPF Water Engineering
Project ID: Calico 1st Quarter 2014 Sa
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic Analytical
Results
Date Sampled: 03/16/14 12:35
Date Received: 03/19/14
Scandium, dissolved M200.7 ICP mg/L 0.5U aeb0.1* 03/21/14 12:051
Scandium, total M200.7 ICP mg/L 0.5U jjc0.1* 03/26/14 10:301
Selenium, dissolved M200.8 ICP-MS 0.0060 mg/L 0.0003 las0.0001 03/27/14 15:421
Selenium, total M200.8 ICP-MS 0.0051 mg/L 0.0003 pmc0.0001 03/28/14 0:381
Silver, dissolved M200.8 ICP-MS mg/L 0.0003U las0.00005 03/27/14 15:421
Silver, total M200.8 ICP-MS mg/L 0.0003U pmc0.00005 03/28/14 0:381
Sodium, dissolved M200.7 ICP 35.2 mg/L 1 aeb0.2 03/21/14 12:051
Sodium, total M200.7 ICP 37.1 mg/L 1 jjc0.2 03/26/14 10:301
Strontium, dissolved M200.7 ICP 0.251 mg/L 0.03 aeb0.005 03/21/14 12:051
Strontium, total M200.7 ICP 0.255 mg/L 0.03 jjc0.005 03/26/14 10:301
Thallium, dissolved M200.8 ICP-MS mg/L 0.0005U las0.0001 03/27/14 15:421
Thallium, total M200.8 ICP-MS mg/L 0.0005U pmc0.0001 03/28/14 0:381
Tin, dissolved M200.8 ICP-MS mg/L 0.0005U las0.0001* 03/27/14 15:421
Tin, total M200.8 ICP-MS mg/L 0.0005U pmc0.0001* 03/28/14 0:381
Titanium, dissolved M200.7 ICP mg/L 0.03U aeb0.005 03/21/14 12:051
Titanium, total M200.7 ICP 0.009 mg/L 0.03B jjc0.005 03/26/14 10:301
Uranium, dissolved M200.8 ICP-MS 0.0046 mg/L 0.0005 las0.0001 03/27/14 15:421
Uranium, total M200.8 ICP-MS 0.0049 mg/L 0.0005 pmc0.0001 03/28/14 0:381
Vanadium, dissolved M200.8 ICP-MS 0.0332 mg/L 0.001 las0.0002 03/27/14 15:421
Vanadium, total M200.8 ICP-MS 0.0309 mg/L 0.001 pmc0.0002 03/28/14 0:381
Zinc, dissolved M200.7 ICP 0.01 mg/L 0.05B aeb0.01 03/21/14 12:051
Zinc, total M200.7 ICP 0.02 mg/L 0.05B jjc0.01 03/26/14 10:301
REPIN.02.06.05.01 * Please refer to Qualifier Reports for details.
Page 17 of 90L17275-1404011436
ACZ Sample ID: L17275-04
Sample ID: DEPOSIT STOCK TANK
Sample Matrix: Ground Water
SPF Water Engineering
Project ID: Calico 1st Quarter 2014 Sa
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic Analytical
Results
Date Sampled: 03/16/14 12:35
Date Received: 03/19/14
Parameter EPA Method Result Units MDLQual AnalystDatePQL
Wet Chemistry
XQDilution
Alkalinity as CaCO3 SM2320B - Titration
Bicarbonate as CaCO3
178 mg/L 20 abd2 03/24/14 0:001
Carbonate as CaCO3 mg/L 20U abd2 03/24/14 0:001
Hydroxide as CaCO3 mg/L 20U abd2 03/24/14 0:001
Total Alkalinity 178 mg/L 20 abd2 03/24/14 0:001
Chloride M300.0 - Ion Chromatography 16.9 mg/L 2.5 tcd0.5 03/25/14 21:521
Conductivity @25C SM2510B 519 umhos/cm 10 abd1 03/24/14 17:331
Cyanide, total M335.4 - Colorimetric w/ distillation mg/L 0.01U bsu0.003* 03/24/14 18:150.5
Cyanide, WAD SM4500-CN I-Colorimetric w/ distillation
mg/L 0.01U mpb0.003* 03/27/14 13:350.5
Fluoride M300.0 - Ion Chromatography 0.44 mg/L 0.5B tcd0.1* 03/25/14 21:521
Hardness as CaCO3 SM2340B - Calculation 182 mg/L 7 calc1 04/01/14 12:23
Nitrate/Nitrite as N M353.2 - H2SO4 preserved 0.07 mg/L 0.1B pjb0.02 03/27/14 23:381
Nitrogen, ammonia M350.1 - Automated Phenate mg/L 0.5U tcd0.05* 03/27/14 12:411
pH (lab) SM4500H+ B
pH 8.2 units 0.1H abd0.1 03/24/14 0:001
pH measured at 21 C 0.1 abd0.1 03/24/14 0:001
Phosphorus, total M365.1 - Auto Ascorbic Acid (digest)
0.02 mg/L 0.05B pjb0.01* 03/28/14 0:171
Residue, Filterable (TDS) @180C
SM2540C 340 mg/L 20 id10 03/21/14 9:351
Residue, Non-Filterable (TSS) @105C
SM2540D mg/L 20U dcw5* 03/22/14 11:131
Sulfate M300.0 - Ion Chromatography 47.0 mg/L 2.5 tcd0.5 03/25/14 21:521
REPIN.02.06.05.01 * Please refer to Qualifier Reports for details.
Page 18 of 90L17275-1404011436
ACZ Sample ID: L17275-05
Sample ID: DEPOSIT DUPLICATE
Sample Matrix: Ground Water
SPF Water Engineering
Project ID: Calico 1st Quarter 2014 Sa
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic Analytical
Results
Date Sampled: 03/16/14 12:45
Date Received: 03/19/14
Parameter EPA Method Result Units MDLQual AnalystDatePQL
Inorganic Prep
XQDilution
Cyanide, total M335.4 - Manual Distillation bsu03/24/14 13:46
Cyanide, WAD SM4500-CN I- distillation mss203/26/14 9:26
Phosphorus, total M365.1 - Auto Ascorbic Acid Digestion
mpb03/27/14 15:22
Total Hot Plate Digestion
M200.2 ICP jjc03/25/14 10:20
Total Hot Plate Digestion
M200.2 ICP-MS las03/26/14 9:46
REPIN.02.06.05.01 * Please refer to Qualifier Reports for details.
Page 19 of 90L17275-1404011436
ACZ Sample ID: L17275-05
Sample ID: DEPOSIT DUPLICATE
Sample Matrix: Ground Water
SPF Water Engineering
Project ID: Calico 1st Quarter 2014 Sa
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic Analytical
Results
Date Sampled: 03/16/14 12:45
Date Received: 03/19/14
Parameter EPA Method Result Units MDLQual AnalystDatePQL
Metals Analysis
XQDilution
Aluminum, dissolved M200.7 ICP mg/L 0.2U aeb0.03 03/21/14 12:081
Aluminum, total M200.7 ICP mg/L 0.2U jjc0.03 03/26/14 10:341
Antimony, dissolved M200.8 ICP-MS mg/L 0.002U las0.0004 03/27/14 15:461
Antimony, total M200.8 ICP-MS mg/L 0.002U pmc0.0004 03/28/14 0:411
Arsenic, dissolved M200.8 ICP-MS 0.0299 mg/L 0.001 las0.0002 03/27/14 15:461
Arsenic, total M200.8 ICP-MS 0.0252 mg/L 0.001 pmc0.0002 03/28/14 0:411
Barium, dissolved M200.7 ICP 0.039 mg/L 0.02 aeb0.003 03/21/14 12:081
Barium, total M200.7 ICP 0.050 mg/L 0.02 jjc0.003 03/26/14 10:341
Beryllium, dissolved M200.8 ICP-MS mg/L 0.0003U las0.00005 03/27/14 15:461
Beryllium, total M200.8 ICP-MS mg/L 0.0003U pmc0.00005 03/28/14 0:411
Bismuth, dissolved M200.7 ICP mg/L 0.2U aeb0.04* 03/21/14 12:081
Bismuth, total M200.7 ICP mg/L 0.2U jjc0.04* 03/26/14 10:341
Boron, dissolved M200.7 ICP 0.05 mg/L 0.05 aeb0.01 03/21/14 12:081
Boron, total M200.7 ICP 0.07 mg/L 0.05 jjc0.01 03/26/14 10:341
Cadmium, dissolved M200.8 ICP-MS mg/L 0.0005U las0.0001 03/27/14 15:461
Cadmium, total M200.8 ICP-MS mg/L 0.0005U pmc0.0001 03/28/14 0:411
Calcium, dissolved M200.7 ICP 42.6 mg/L 0.5 aeb0.1* 03/21/14 12:081
Calcium, total M200.7 ICP 54.6 mg/L 0.5 jjc0.1 03/26/14 10:341
Chromium, dissolved M200.8 ICP-MS mg/L 0.002U las0.0005 03/27/14 15:461
Chromium, total M200.8 ICP-MS mg/L 0.002U pmc0.0005 03/28/14 0:411
Cobalt, dissolved M200.8 ICP-MS 0.00016 mg/L 0.0003B las0.00005 03/27/14 15:461
Cobalt, total M200.8 ICP-MS 0.00011 mg/L 0.0003B pmc0.00005 03/28/14 0:411
Copper, dissolved M200.8 ICP-MS mg/L 0.003U las0.0005 03/27/14 15:461
Copper, total M200.8 ICP-MS mg/L 0.003U pmc0.0005 03/28/14 0:411
Gallium, dissolved M200.7 ICP mg/L 0.5U aeb0.1* 03/21/14 12:081
Gallium, total M200.7 ICP mg/L 0.5U jjc0.1* 03/26/14 10:341
Iron, dissolved M200.7 ICP mg/L 0.05U aeb0.02 03/21/14 12:081
Iron, total M200.7 ICP mg/L 0.05U jjc0.02 03/26/14 10:341
Lead, dissolved M200.8 ICP-MS mg/L 0.0005U las0.0001 03/27/14 15:461
Lead, total M200.8 ICP-MS mg/L 0.0005U pmc0.0001 03/28/14 0:411
Lithium, dissolved M200.7 ICP 0.032 mg/L 0.04B aeb0.008 03/21/14 12:081
Lithium, total M200.7 ICP 0.044 mg/L 0.04 jjc0.008 03/26/14 10:341
Magnesium, dissolved M200.7 ICP 9.3 mg/L 1 aeb0.2 03/21/14 12:081
Magnesium, total M200.7 ICP 11.8 mg/L 1 jjc0.2 03/26/14 10:341
Manganese, dissolved M200.8 ICP-MS 0.0032 mg/L 0.003 las0.0005 03/27/14 15:461
Manganese, total M200.8 ICP-MS 0.0030 mg/L 0.003 pmc0.0005 03/28/14 0:411
Mercury, dissolved M1631, Atomic Fluorescence 0.4 ng/L 0.5B las0.2 03/27/14 13:101
Mercury, total M1631, Atomic Fluorescence 1 ng/L 0.5 las0.2* 03/28/14 16:491
Molybdenum, dissolved M200.8 ICP-MS 0.0036 mg/L 0.003 las0.0005 03/27/14 15:461
Molybdenum, total M200.8 ICP-MS 0.0035 mg/L 0.003 pmc0.0005 03/28/14 0:411
Nickel, dissolved M200.8 ICP-MS mg/L 0.003U las0.0006 03/27/14 15:461
Nickel, total M200.8 ICP-MS mg/L 0.003U pmc0.0006 03/28/14 0:411
Potassium, dissolved M200.7 ICP 3.5 mg/L 1 aeb0.2 03/21/14 12:081
REPIN.02.06.05.01 * Please refer to Qualifier Reports for details.
Page 20 of 90L17275-1404011436
ACZ Sample ID: L17275-05
Sample ID: DEPOSIT DUPLICATE
Sample Matrix: Ground Water
SPF Water Engineering
Project ID: Calico 1st Quarter 2014 Sa
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic Analytical
Results
Date Sampled: 03/16/14 12:45
Date Received: 03/19/14
Potassium, total M200.7 ICP 4.2 mg/L 1 jjc0.2 03/26/14 10:341
Scandium, dissolved M200.7 ICP mg/L 0.5U aeb0.1* 03/21/14 12:081
Scandium, total M200.7 ICP mg/L 0.5U jjc0.1* 03/26/14 10:341
Selenium, dissolved M200.8 ICP-MS 0.0059 mg/L 0.0003 las0.0001 03/27/14 15:461
Selenium, total M200.8 ICP-MS 0.0050 mg/L 0.0003 pmc0.0001 03/28/14 0:411
Silver, dissolved M200.8 ICP-MS mg/L 0.0003U las0.00005 03/27/14 15:461
Silver, total M200.8 ICP-MS mg/L 0.0003U pmc0.00005 03/28/14 0:411
Sodium, dissolved M200.7 ICP 28 mg/L 1 aeb0.2 03/21/14 12:081
Sodium, total M200.7 ICP 36.1 mg/L 1 jjc0.2 03/26/14 10:341
Strontium, dissolved M200.7 ICP 0.198 mg/L 0.03 aeb0.005 03/21/14 12:081
Strontium, total M200.7 ICP 0.250 mg/L 0.03 jjc0.005 03/26/14 10:341
Thallium, dissolved M200.8 ICP-MS mg/L 0.0005U las0.0001 03/27/14 15:461
Thallium, total M200.8 ICP-MS mg/L 0.0005U pmc0.0001 03/28/14 0:411
Tin, dissolved M200.8 ICP-MS mg/L 0.0005U las0.0001* 03/27/14 15:461
Tin, total M200.8 ICP-MS mg/L 0.0005U pmc0.0001* 03/28/14 0:411
Titanium, dissolved M200.7 ICP mg/L 0.03U aeb0.005 03/21/14 12:081
Titanium, total M200.7 ICP 0.009 mg/L 0.03B jjc0.005 03/26/14 10:341
Uranium, dissolved M200.8 ICP-MS 0.0047 mg/L 0.0005 las0.0001 03/27/14 15:461
Uranium, total M200.8 ICP-MS 0.0048 mg/L 0.0005 pmc0.0001 03/28/14 0:411
Vanadium, dissolved M200.8 ICP-MS 0.0328 mg/L 0.001 las0.0002 03/27/14 15:461
Vanadium, total M200.8 ICP-MS 0.0309 mg/L 0.001 pmc0.0002 03/28/14 0:411
Zinc, dissolved M200.7 ICP mg/L 0.05U aeb0.01 03/21/14 12:081
Zinc, total M200.7 ICP 0.02 mg/L 0.05B jjc0.01 03/26/14 10:341
REPIN.02.06.05.01 * Please refer to Qualifier Reports for details.
Page 21 of 90L17275-1404011436
ACZ Sample ID: L17275-05
Sample ID: DEPOSIT DUPLICATE
Sample Matrix: Ground Water
SPF Water Engineering
Project ID: Calico 1st Quarter 2014 Sa
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic Analytical
Results
Date Sampled: 03/16/14 12:45
Date Received: 03/19/14
Parameter EPA Method Result Units MDLQual AnalystDatePQL
Wet Chemistry
XQDilution
Alkalinity as CaCO3 SM2320B - Titration
Bicarbonate as CaCO3
166 mg/L 20 abd2 03/24/14 0:001
Carbonate as CaCO3 mg/L 20U abd2 03/24/14 0:001
Hydroxide as CaCO3 mg/L 20U abd2 03/24/14 0:001
Total Alkalinity 166 mg/L 20 abd2 03/24/14 0:001
Chloride M300.0 - Ion Chromatography 16.9 mg/L 2.5 tcd0.5 03/25/14 22:271
Conductivity @25C SM2510B 513 umhos/cm 10 abd1 03/24/14 17:421
Cyanide, total M335.4 - Colorimetric w/ distillation mg/L 0.01U bsu0.003* 03/24/14 18:160.5
Cyanide, WAD SM4500-CN I-Colorimetric w/ distillation
mg/L 0.01U mpb0.003* 03/27/14 13:360.5
Fluoride M300.0 - Ion Chromatography 0.45 mg/L 0.5B tcd0.1* 03/25/14 22:271
Hardness as CaCO3 SM2340B - Calculation 145 mg/L 7 calc1 04/01/14 12:23
Nitrate/Nitrite as N M353.2 - H2SO4 preserved 0.07 mg/L 0.1B pjb0.02 03/27/14 23:401
Nitrogen, ammonia M350.1 - Automated Phenate mg/L 0.5U tcd0.05* 03/27/14 12:421
pH (lab) SM4500H+ B
pH 8.1 units 0.1H abd0.1 03/24/14 0:001
pH measured at 21 C 0.1 abd0.1 03/24/14 0:001
Phosphorus, total M365.1 - Auto Ascorbic Acid (digest)
0.02 mg/L 0.05B pjb0.01* 03/28/14 0:211
Residue, Filterable (TDS) @180C
SM2540C 340 mg/L 20 id10 03/21/14 9:371
Residue, Non-Filterable (TSS) @105C
SM2540D mg/L 20U dcw5* 03/22/14 11:151
Sulfate M300.0 - Ion Chromatography 47.1 mg/L 2.5 tcd0.5 03/25/14 22:271
REPIN.02.06.05.01 * Please refer to Qualifier Reports for details.
Page 22 of 90L17275-1404011436
ACZ Sample ID: L17275-06
Sample ID: WHISKEY SPRING
Sample Matrix: Ground Water
SPF Water Engineering
Project ID: Calico 1st Quarter 2014 Sa
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic Analytical
Results
Date Sampled: 03/16/14 15:25
Date Received: 03/19/14
Parameter EPA Method Result Units MDLQual AnalystDatePQL
Inorganic Prep
XQDilution
Cyanide, total M335.4 - Manual Distillation bsu03/24/14 13:56
Cyanide, WAD SM4500-CN I- distillation mss203/26/14 9:36
Phosphorus, total M365.1 - Auto Ascorbic Acid Digestion
mpb03/27/14 15:29
Total Hot Plate Digestion
M200.2 ICP-MS las03/26/14 9:56
Total Hot Plate Digestion
M200.2 ICP jjc03/25/14 10:32
REPIN.02.06.05.01 * Please refer to Qualifier Reports for details.
Page 23 of 90L17275-1404011436
ACZ Sample ID: L17275-06
Sample ID: WHISKEY SPRING
Sample Matrix: Ground Water
SPF Water Engineering
Project ID: Calico 1st Quarter 2014 Sa
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic Analytical
Results
Date Sampled: 03/16/14 15:25
Date Received: 03/19/14
Parameter EPA Method Result Units MDLQual AnalystDatePQL
Metals Analysis
XQDilution
Aluminum, dissolved M200.7 ICP mg/L 0.2U aeb0.03 03/21/14 12:111
Aluminum, total M200.7 ICP mg/L 0.2U jjc0.03 03/26/14 10:371
Antimony, dissolved M200.8 ICP-MS 0.0008 mg/L 0.002B las0.0004 03/27/14 15:561
Antimony, total M200.8 ICP-MS 0.0007 mg/L 0.002B pmc0.0004 03/28/14 0:511
Arsenic, dissolved M200.8 ICP-MS 0.1039 mg/L 0.001 las0.0002 03/27/14 15:561
Arsenic, total M200.8 ICP-MS 0.0867 mg/L 0.001 pmc0.0002 03/28/14 0:511
Barium, dissolved M200.7 ICP 0.045 mg/L 0.02 aeb0.003 03/21/14 12:111
Barium, total M200.7 ICP 0.047 mg/L 0.02 jjc0.003 03/26/14 10:371
Beryllium, dissolved M200.8 ICP-MS mg/L 0.0003U las0.00005 03/27/14 15:561
Beryllium, total M200.8 ICP-MS mg/L 0.0003U pmc0.00005 03/28/14 0:511
Bismuth, dissolved M200.7 ICP mg/L 0.2U aeb0.04* 03/21/14 12:111
Bismuth, total M200.7 ICP 0.05 mg/L 0.2B jjc0.04* 03/26/14 10:371
Boron, dissolved M200.7 ICP 0.17 mg/L 0.05 aeb0.01 03/21/14 12:111
Boron, total M200.7 ICP 0.18 mg/L 0.05 jjc0.01 03/26/14 10:371
Cadmium, dissolved M200.8 ICP-MS mg/L 0.0005U las0.0001 03/27/14 15:561
Cadmium, total M200.8 ICP-MS mg/L 0.0005U pmc0.0001 03/28/14 0:511
Calcium, dissolved M200.7 ICP 34.8 mg/L 0.5 aeb0.1* 03/21/14 12:111
Calcium, total M200.7 ICP 35.9 mg/L 0.5 jjc0.1 03/26/14 10:371
Chromium, dissolved M200.8 ICP-MS mg/L 0.002U las0.0005 03/27/14 15:561
Chromium, total M200.8 ICP-MS mg/L 0.002U pmc0.0005 03/28/14 0:511
Cobalt, dissolved M200.8 ICP-MS 0.00011 mg/L 0.0003B las0.00005 03/27/14 15:561
Cobalt, total M200.8 ICP-MS 0.00006 mg/L 0.0003B pmc0.00005 03/28/14 0:511
Copper, dissolved M200.8 ICP-MS mg/L 0.003U las0.0005 03/27/14 15:561
Copper, total M200.8 ICP-MS mg/L 0.003U pmc0.0005 03/28/14 0:511
Gallium, dissolved M200.7 ICP mg/L 0.5U aeb0.1* 03/21/14 12:111
Gallium, total M200.7 ICP mg/L 0.5U jjc0.1* 03/26/14 10:371
Iron, dissolved M200.7 ICP mg/L 0.05U aeb0.02 03/21/14 12:111
Iron, total M200.7 ICP mg/L 0.05U jjc0.02 03/26/14 10:371
Lead, dissolved M200.8 ICP-MS mg/L 0.0005U las0.0001 03/27/14 15:561
Lead, total M200.8 ICP-MS mg/L 0.0005U pmc0.0001 03/28/14 0:511
Lithium, dissolved M200.7 ICP 0.100 mg/L 0.04 aeb0.008 03/21/14 12:111
Lithium, total M200.7 ICP 0.103 mg/L 0.04 jjc0.008 03/26/14 10:371
Magnesium, dissolved M200.7 ICP 5.8 mg/L 1 aeb0.2 03/21/14 12:111
Magnesium, total M200.7 ICP 5.8 mg/L 1 jjc0.2 03/26/14 10:371
Manganese, dissolved M200.8 ICP-MS mg/L 0.003U las0.0005 03/27/14 15:561
Manganese, total M200.8 ICP-MS mg/L 0.003U pmc0.0005 03/28/14 0:511
Mercury, dissolved M1631, Atomic Fluorescence ng/L 0.5U las0.2 03/27/14 13:151
Mercury, total M1631, Atomic Fluorescence 0.5 ng/L 0.5 las0.2 03/28/14 16:541
Molybdenum, dissolved M200.8 ICP-MS 0.0211 mg/L 0.003 las0.0005 03/27/14 15:561
Molybdenum, total M200.8 ICP-MS 0.0214 mg/L 0.003 pmc0.0005 03/28/14 0:511
Nickel, dissolved M200.8 ICP-MS mg/L 0.003U las0.0006 03/27/14 15:561
Nickel, total M200.8 ICP-MS mg/L 0.003U pmc0.0006 03/28/14 0:511
Potassium, dissolved M200.7 ICP 5.5 mg/L 1 aeb0.2 03/21/14 12:111
REPIN.02.06.05.01 * Please refer to Qualifier Reports for details.
Page 24 of 90L17275-1404011436
ACZ Sample ID: L17275-06
Sample ID: WHISKEY SPRING
Sample Matrix: Ground Water
SPF Water Engineering
Project ID: Calico 1st Quarter 2014 Sa
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic Analytical
Results
Date Sampled: 03/16/14 15:25
Date Received: 03/19/14
Potassium, total M200.7 ICP 5.5 mg/L 1 jjc0.2 03/26/14 10:371
Scandium, dissolved M200.7 ICP mg/L 0.5U aeb0.1* 03/21/14 12:111
Scandium, total M200.7 ICP mg/L 0.5U jjc0.1* 03/26/14 10:371
Selenium, dissolved M200.8 ICP-MS 0.0023 mg/L 0.0003 las0.0001 03/27/14 15:561
Selenium, total M200.8 ICP-MS 0.0019 mg/L 0.0003 pmc0.0001 03/28/14 0:511
Silver, dissolved M200.8 ICP-MS mg/L 0.0003U las0.00005 03/27/14 15:561
Silver, total M200.8 ICP-MS mg/L 0.0003U pmc0.00005 03/28/14 0:511
Sodium, dissolved M200.7 ICP 67.4 mg/L 1 aeb0.2 03/21/14 12:111
Sodium, total M200.7 ICP 70 mg/L 1 jjc0.2 03/26/14 10:371
Strontium, dissolved M200.7 ICP 0.151 mg/L 0.03 aeb0.005 03/21/14 12:111
Strontium, total M200.7 ICP 0.153 mg/L 0.03 jjc0.005 03/26/14 10:371
Thallium, dissolved M200.8 ICP-MS mg/L 0.0005U las0.0001 03/27/14 15:561
Thallium, total M200.8 ICP-MS mg/L 0.0005U pmc0.0001 03/28/14 0:511
Tin, dissolved M200.8 ICP-MS 0.0002 mg/L 0.0005B las0.0001* 03/27/14 15:561
Tin, total M200.8 ICP-MS mg/L 0.0005U pmc0.0001* 03/28/14 0:511
Titanium, dissolved M200.7 ICP mg/L 0.03U aeb0.005 03/21/14 12:111
Titanium, total M200.7 ICP 0.007 mg/L 0.03B jjc0.005 03/26/14 10:371
Uranium, dissolved M200.8 ICP-MS 0.0057 mg/L 0.0005 las0.0001 03/27/14 15:561
Uranium, total M200.8 ICP-MS 0.0059 mg/L 0.0005 pmc0.0001 03/28/14 0:511
Vanadium, dissolved M200.8 ICP-MS 0.0243 mg/L 0.001 las0.0002 03/27/14 15:561
Vanadium, total M200.8 ICP-MS 0.0218 mg/L 0.001 pmc0.0002 03/28/14 0:511
Zinc, dissolved M200.7 ICP mg/L 0.05U aeb0.01 03/21/14 12:111
Zinc, total M200.7 ICP 0.01 mg/L 0.05B jjc0.01 03/26/14 10:371
REPIN.02.06.05.01 * Please refer to Qualifier Reports for details.
Page 25 of 90L17275-1404011436
ACZ Sample ID: L17275-06
Sample ID: WHISKEY SPRING
Sample Matrix: Ground Water
SPF Water Engineering
Project ID: Calico 1st Quarter 2014 Sa
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic Analytical
Results
Date Sampled: 03/16/14 15:25
Date Received: 03/19/14
Parameter EPA Method Result Units MDLQual AnalystDatePQL
Wet Chemistry
XQDilution
Alkalinity as CaCO3 SM2320B - Titration
Bicarbonate as CaCO3
114 mg/L 20 abd2 03/24/14 0:001
Carbonate as CaCO3 mg/L 20U abd2 03/24/14 0:001
Hydroxide as CaCO3 mg/L 20U abd2 03/24/14 0:001
Total Alkalinity 114 mg/L 20 abd2 03/24/14 0:001
Chloride M300.0 - Ion Chromatography 6.53 mg/L 12.5B tcd2.5* 03/25/14 23:395
Conductivity @25C SM2510B 536 umhos/cm 10 abd1 03/24/14 17:511
Cyanide, total M335.4 - Colorimetric w/ distillation mg/L 0.01U bsu0.003* 03/24/14 18:160.5
Cyanide, WAD SM4500-CN I-Colorimetric w/ distillation
mg/L 0.01U mpb0.003* 03/27/14 13:390.5
Fluoride M300.0 - Ion Chromatography mg/L 2.5U tcd0.5* 03/25/14 23:395
Hardness as CaCO3 SM2340B - Calculation 111 mg/L 7 calc1 04/01/14 12:23
Nitrate/Nitrite as N M353.2 - H2SO4 preserved 0.28 mg/L 0.1 pjb0.02 03/27/14 23:421
Nitrogen, ammonia M350.1 - Automated Phenate mg/L 0.5U tcd0.05* 03/27/14 12:431
pH (lab) SM4500H+ B
pH 8.2 units 0.1H abd0.1 03/24/14 0:001
pH measured at 20 C 0.1 abd0.1 03/24/14 0:001
Phosphorus, total M365.1 - Auto Ascorbic Acid (digest)
0.03 mg/L 0.05B pjb0.01* 03/28/14 0:221
Residue, Filterable (TDS) @180C
SM2540C 390 mg/L 20 id10 03/21/14 9:391
Residue, Non-Filterable (TSS) @105C
SM2540D mg/L 20U dcw5* 03/22/14 11:181
Sulfate M300.0 - Ion Chromatography 119 mg/L 12.5 tcd2.5 03/25/14 23:395
REPIN.02.06.05.01 * Please refer to Qualifier Reports for details.
Page 26 of 90L17275-1404011436
ACZ Sample ID: L17275-07
Sample ID: MERC TRANSFER/TRIP BLANK
Sample Matrix: Ground Water
SPF Water Engineering
Project ID: Calico 1st Quarter 2014 Sa
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic Analytical
Results
Date Sampled: 03/16/14 17:25
Date Received: 03/19/14
Parameter EPA Method Result Units MDLQual AnalystDatePQL
Metals Analysis
XQDilution
Mercury, dissolved M1631, Atomic Fluorescence ng/L 0.5U las0.2 03/27/14 13:401
Mercury, total M1631, Atomic Fluorescence ng/L 0.5U las0.2 03/28/14 17:091
REPIN.02.06.05.01
Page 27 of 90L17275-1404011436
ACZ Sample ID: L17275-08
Sample ID: TWIN SPRINGS NORTH
Sample Matrix: Ground Water
SPF Water Engineering
Project ID: Calico 1st Quarter 2014 Sa
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic Analytical
Results
Date Sampled: 03/16/14 16:10
Date Received: 03/19/14
Parameter EPA Method Result Units MDLQual AnalystDatePQL
Inorganic Prep
XQDilution
Cyanide, total M335.4 - Manual Distillation bsu03/24/14 14:06
Cyanide, WAD SM4500-CN I- distillation mss203/26/14 9:45
Phosphorus, total M365.1 - Auto Ascorbic Acid Digestion
mpb03/27/14 15:37
Total Hot Plate Digestion
M200.2 ICP jjc03/25/14 10:44
Total Hot Plate Digestion
M200.2 ICP-MS las03/26/14 10:06
REPIN.02.06.05.01 * Please refer to Qualifier Reports for details.
Page 28 of 90L17275-1404011436
ACZ Sample ID: L17275-08
Sample ID: TWIN SPRINGS NORTH
Sample Matrix: Ground Water
SPF Water Engineering
Project ID: Calico 1st Quarter 2014 Sa
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic Analytical
Results
Date Sampled: 03/16/14 16:10
Date Received: 03/19/14
Parameter EPA Method Result Units MDLQual AnalystDatePQL
Metals Analysis
XQDilution
Aluminum, dissolved M200.7 ICP mg/L 0.2U aeb0.03 03/21/14 12:211
Aluminum, total M200.7 ICP mg/L 0.2U jjc0.03 03/26/14 10:461
Antimony, dissolved M200.8 ICP-MS mg/L 0.002U las0.0004 03/27/14 16:061
Antimony, total M200.8 ICP-MS mg/L 0.002U pmc0.0004 03/28/14 0:551
Arsenic, dissolved M200.8 ICP-MS 0.0522 mg/L 0.001 las0.0002 03/27/14 16:061
Arsenic, total M200.8 ICP-MS 0.0444 mg/L 0.001 pmc0.0002 03/28/14 0:551
Barium, dissolved M200.7 ICP 0.010 mg/L 0.02B aeb0.003 03/21/14 12:211
Barium, total M200.7 ICP 0.010 mg/L 0.02B jjc0.003 03/26/14 10:461
Beryllium, dissolved M200.8 ICP-MS mg/L 0.0003U las0.00005 03/27/14 16:061
Beryllium, total M200.8 ICP-MS mg/L 0.0003U pmc0.00005 03/28/14 0:551
Bismuth, dissolved M200.7 ICP mg/L 0.2U aeb0.04* 03/21/14 12:211
Bismuth, total M200.7 ICP mg/L 0.2U jjc0.04* 03/26/14 10:461
Boron, dissolved M200.7 ICP 0.11 mg/L 0.05 aeb0.01 03/21/14 12:211
Boron, total M200.7 ICP 0.10 mg/L 0.05 jjc0.01 03/26/14 10:461
Cadmium, dissolved M200.8 ICP-MS mg/L 0.0005U las0.0001 03/27/14 16:061
Cadmium, total M200.8 ICP-MS mg/L 0.0005U pmc0.0001 03/28/14 0:551
Calcium, dissolved M200.7 ICP 24.3 mg/L 0.5 aeb0.1* 03/21/14 12:211
Calcium, total M200.7 ICP 25 mg/L 0.5 jjc0.1 03/26/14 10:461
Chromium, dissolved M200.8 ICP-MS 0.0005 mg/L 0.002B las0.0005 03/27/14 16:061
Chromium, total M200.8 ICP-MS 0.0007 mg/L 0.002B pmc0.0005 03/28/14 0:551
Cobalt, dissolved M200.8 ICP-MS 0.00008 mg/L 0.0003B las0.00005 03/27/14 16:061
Cobalt, total M200.8 ICP-MS 0.00010 mg/L 0.0003B pmc0.00005 03/28/14 0:551
Copper, dissolved M200.8 ICP-MS mg/L 0.003U las0.0005 03/27/14 16:061
Copper, total M200.8 ICP-MS mg/L 0.003U pmc0.0005 03/28/14 0:551
Gallium, dissolved M200.7 ICP mg/L 0.5U aeb0.1* 03/21/14 12:211
Gallium, total M200.7 ICP mg/L 0.5U jjc0.1* 03/26/14 10:461
Iron, dissolved M200.7 ICP mg/L 0.05U aeb0.02 03/21/14 12:211
Iron, total M200.7 ICP mg/L 0.05U jjc0.02 03/26/14 10:461
Lead, dissolved M200.8 ICP-MS mg/L 0.0005U las0.0001 03/27/14 16:061
Lead, total M200.8 ICP-MS mg/L 0.0005U pmc0.0001 03/28/14 0:551
Lithium, dissolved M200.7 ICP 0.013 mg/L 0.04B aeb0.008 03/21/14 12:211
Lithium, total M200.7 ICP 0.017 mg/L 0.04B jjc0.008 03/26/14 10:461
Magnesium, dissolved M200.7 ICP 14.2 mg/L 1 aeb0.2 03/21/14 12:211
Magnesium, total M200.7 ICP 14.4 mg/L 1 jjc0.2 03/26/14 10:461
Manganese, dissolved M200.8 ICP-MS 0.0090 mg/L 0.003 las0.0005 03/27/14 16:061
Manganese, total M200.8 ICP-MS 0.0200 mg/L 0.003 pmc0.0005 03/28/14 0:551
Mercury, dissolved M1631, Atomic Fluorescence 0.3 ng/L 0.5B las0.2 03/27/14 13:461
Mercury, total M1631, Atomic Fluorescence 0.7 ng/L 0.5 las0.2 03/28/14 17:141
Molybdenum, dissolved M200.8 ICP-MS 0.0110 mg/L 0.003 las0.0005 03/27/14 16:061
Molybdenum, total M200.8 ICP-MS 0.0108 mg/L 0.003 pmc0.0005 03/28/14 0:551
Nickel, dissolved M200.8 ICP-MS mg/L 0.003U las0.0006 03/27/14 16:061
Nickel, total M200.8 ICP-MS mg/L 0.003U pmc0.0006 03/28/14 0:551
Potassium, dissolved M200.7 ICP 8.5 mg/L 1 aeb0.2 03/21/14 12:211
REPIN.02.06.05.01 * Please refer to Qualifier Reports for details.
Page 29 of 90L17275-1404011436
ACZ Sample ID: L17275-08
Sample ID: TWIN SPRINGS NORTH
Sample Matrix: Ground Water
SPF Water Engineering
Project ID: Calico 1st Quarter 2014 Sa
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic Analytical
Results
Date Sampled: 03/16/14 16:10
Date Received: 03/19/14
Potassium, total M200.7 ICP 8.5 mg/L 1 jjc0.2 03/26/14 10:461
Scandium, dissolved M200.7 ICP mg/L 0.5U aeb0.1* 03/21/14 12:211
Scandium, total M200.7 ICP mg/L 0.5U jjc0.1* 03/26/14 10:461
Selenium, dissolved M200.8 ICP-MS 0.0044 mg/L 0.0003 las0.0001 03/27/14 16:061
Selenium, total M200.8 ICP-MS 0.0039 mg/L 0.0003 pmc0.0001 03/28/14 0:551
Silver, dissolved M200.8 ICP-MS mg/L 0.0003U las0.00005 03/27/14 16:061
Silver, total M200.8 ICP-MS mg/L 0.0003U pmc0.00005 03/28/14 0:551
Sodium, dissolved M200.7 ICP 43.9 mg/L 1 aeb0.2 03/21/14 12:211
Sodium, total M200.7 ICP 45.9 mg/L 1 jjc0.2 03/26/14 10:461
Strontium, dissolved M200.7 ICP 0.134 mg/L 0.03 aeb0.005 03/21/14 12:211
Strontium, total M200.7 ICP 0.135 mg/L 0.03 jjc0.005 03/26/14 10:461
Thallium, dissolved M200.8 ICP-MS mg/L 0.0005U las0.0001 03/27/14 16:061
Thallium, total M200.8 ICP-MS mg/L 0.0005U pmc0.0001 03/28/14 0:551
Tin, dissolved M200.8 ICP-MS mg/L 0.0005U las0.0001* 03/27/14 16:061
Tin, total M200.8 ICP-MS 0.0002 mg/L 0.0005B pmc0.0001* 03/28/14 0:551
Titanium, dissolved M200.7 ICP mg/L 0.03U aeb0.005 03/21/14 12:211
Titanium, total M200.7 ICP 0.006 mg/L 0.03B jjc0.005 03/26/14 10:461
Uranium, dissolved M200.8 ICP-MS 0.0044 mg/L 0.0005 las0.0001 03/27/14 16:061
Uranium, total M200.8 ICP-MS 0.0045 mg/L 0.0005 pmc0.0001 03/28/14 0:551
Vanadium, dissolved M200.8 ICP-MS 0.0443 mg/L 0.001 las0.0002 03/27/14 16:061
Vanadium, total M200.8 ICP-MS 0.0422 mg/L 0.001 pmc0.0002 03/28/14 0:551
Zinc, dissolved M200.7 ICP mg/L 0.05U aeb0.01 03/21/14 12:211
Zinc, total M200.7 ICP 0.01 mg/L 0.05B jjc0.01 03/26/14 10:461
REPIN.02.06.05.01 * Please refer to Qualifier Reports for details.
Page 30 of 90L17275-1404011436
ACZ Sample ID: L17275-08
Sample ID: TWIN SPRINGS NORTH
Sample Matrix: Ground Water
SPF Water Engineering
Project ID: Calico 1st Quarter 2014 Sa
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic Analytical
Results
Date Sampled: 03/16/14 16:10
Date Received: 03/19/14
Parameter EPA Method Result Units MDLQual AnalystDatePQL
Wet Chemistry
XQDilution
Alkalinity as CaCO3 SM2320B - Titration
Bicarbonate as CaCO3
140 mg/L 20 abd2 03/24/14 0:001
Carbonate as CaCO3 mg/L 20U abd2 03/24/14 0:001
Hydroxide as CaCO3 mg/L 20U abd2 03/24/14 0:001
Total Alkalinity 140 mg/L 20 abd2 03/24/14 0:001
Chloride M300.0 - Ion Chromatography 8.82 mg/L 2.5 tcd0.5 03/25/14 23:571
Conductivity @25C SM2510B 442 umhos/cm 10 abd1 03/24/14 18:001
Cyanide, total M335.4 - Colorimetric w/ distillation mg/L 0.01U bsu0.003* 03/24/14 18:190.5
Cyanide, WAD SM4500-CN I-Colorimetric w/ distillation
mg/L 0.01U mpb0.003* 03/27/14 13:400.5
Fluoride M300.0 - Ion Chromatography 0.61 mg/L 0.5 tcd0.1* 03/25/14 23:571
Hardness as CaCO3 SM2340B - Calculation 119 mg/L 7 calc1 04/01/14 12:24
Nitrate/Nitrite as N M353.2 - H2SO4 preserved 1.28 mg/L 0.1 pjb0.02 03/27/14 23:471
Nitrogen, ammonia M350.1 - Automated Phenate mg/L 0.5U tcd0.05* 03/27/14 12:441
pH (lab) SM4500H+ B
pH 8.2 units 0.1H abd0.1 03/24/14 0:001
pH measured at 20 C 0.1 abd0.1 03/24/14 0:001
Phosphorus, total M365.1 - Auto Ascorbic Acid (digest)
0.05 mg/L 0.05 pjb0.01* 03/28/14 0:231
Residue, Filterable (TDS) @180C
SM2540C 300 mg/L 20 id10 03/21/14 9:401
Residue, Non-Filterable (TSS) @105C
SM2540D mg/L 20U dcw5* 03/22/14 11:201
Sulfate M300.0 - Ion Chromatography 44.3 mg/L 2.5 tcd0.5 03/25/14 23:571
REPIN.02.06.05.01 * Please refer to Qualifier Reports for details.
Page 31 of 90L17275-1404011436
ACZ Sample ID: L17275-09
Sample ID: TWIN SPRINGS SOUTH
Sample Matrix: Ground Water
SPF Water Engineering
Project ID: Calico 1st Quarter 2014 Sa
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic Analytical
Results
Date Sampled: 03/16/14 17:05
Date Received: 03/19/14
Parameter EPA Method Result Units MDLQual AnalystDatePQL
Inorganic Prep
XQDilution
Cyanide, total M335.4 - Manual Distillation bsu03/24/14 14:15
Cyanide, WAD SM4500-CN I- distillation mss203/26/14 9:55
Phosphorus, total M365.1 - Auto Ascorbic Acid Digestion
mpb03/27/14 15:44
Total Hot Plate Digestion
M200.2 ICP-MS las03/26/14 10:34
Total Hot Plate Digestion
M200.2 ICP jjc03/25/14 10:55
REPIN.02.06.05.01 * Please refer to Qualifier Reports for details.
Page 32 of 90L17275-1404011436
ACZ Sample ID: L17275-09
Sample ID: TWIN SPRINGS SOUTH
Sample Matrix: Ground Water
SPF Water Engineering
Project ID: Calico 1st Quarter 2014 Sa
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic Analytical
Results
Date Sampled: 03/16/14 17:05
Date Received: 03/19/14
Parameter EPA Method Result Units MDLQual AnalystDatePQL
Metals Analysis
XQDilution
Aluminum, dissolved M200.7 ICP mg/L 0.2U aeb0.03 03/21/14 12:241
Aluminum, total M200.7 ICP mg/L 0.2U jjc0.03 03/26/14 10:491
Antimony, dissolved M200.8 ICP-MS mg/L 0.002U las0.0004 03/27/14 16:101
Antimony, total M200.8 ICP-MS mg/L 0.002U pmc0.0004 03/28/14 1:051
Arsenic, dissolved M200.8 ICP-MS 0.0489 mg/L 0.001 las0.0002 03/27/14 16:101
Arsenic, total M200.8 ICP-MS 0.0422 mg/L 0.001 pmc0.0002 03/28/14 1:051
Barium, dissolved M200.7 ICP 0.006 mg/L 0.02B aeb0.003 03/21/14 12:241
Barium, total M200.7 ICP 0.006 mg/L 0.02B jjc0.003 03/26/14 10:491
Beryllium, dissolved M200.8 ICP-MS mg/L 0.0003U las0.00005 03/27/14 16:101
Beryllium, total M200.8 ICP-MS mg/L 0.0003U pmc0.00005 03/28/14 1:051
Bismuth, dissolved M200.7 ICP mg/L 0.2U aeb0.04* 03/21/14 12:241
Bismuth, total M200.7 ICP mg/L 0.2U jjc0.04* 03/26/14 10:491
Boron, dissolved M200.7 ICP 0.11 mg/L 0.05 aeb0.01 03/21/14 12:241
Boron, total M200.7 ICP 0.11 mg/L 0.05 jjc0.01 03/26/14 10:491
Cadmium, dissolved M200.8 ICP-MS mg/L 0.0005U las0.0001 03/27/14 16:101
Cadmium, total M200.8 ICP-MS mg/L 0.0005U pmc0.0001 03/28/14 1:051
Calcium, dissolved M200.7 ICP 25.3 mg/L 0.5 aeb0.1* 03/21/14 12:241
Calcium, total M200.7 ICP 26.4 mg/L 0.5 jjc0.1 03/26/14 10:491
Chromium, dissolved M200.8 ICP-MS 0.0008 mg/L 0.002B las0.0005 03/27/14 16:101
Chromium, total M200.8 ICP-MS 0.0008 mg/L 0.002B pmc0.0005 03/28/14 1:051
Cobalt, dissolved M200.8 ICP-MS 0.00010 mg/L 0.0003B las0.00005 03/27/14 16:101
Cobalt, total M200.8 ICP-MS 0.00007 mg/L 0.0003B pmc0.00005 03/28/14 1:051
Copper, dissolved M200.8 ICP-MS mg/L 0.003U las0.0005 03/27/14 16:101
Copper, total M200.8 ICP-MS mg/L 0.003U pmc0.0005 03/28/14 1:051
Gallium, dissolved M200.7 ICP mg/L 0.5U aeb0.1* 03/21/14 12:241
Gallium, total M200.7 ICP mg/L 0.5U jjc0.1* 03/26/14 10:491
Iron, dissolved M200.7 ICP mg/L 0.05U aeb0.02 03/21/14 12:241
Iron, total M200.7 ICP mg/L 0.05U jjc0.02 03/26/14 10:491
Lead, dissolved M200.8 ICP-MS mg/L 0.0005U las0.0001 03/27/14 16:101
Lead, total M200.8 ICP-MS mg/L 0.0005U pmc0.0001 03/28/14 1:051
Lithium, dissolved M200.7 ICP 0.011 mg/L 0.04B aeb0.008 03/21/14 12:241
Lithium, total M200.7 ICP 0.016 mg/L 0.04B jjc0.008 03/26/14 10:491
Magnesium, dissolved M200.7 ICP 14.3 mg/L 1 aeb0.2 03/21/14 12:241
Magnesium, total M200.7 ICP 14.6 mg/L 1 jjc0.2 03/26/14 10:491
Manganese, dissolved M200.8 ICP-MS 0.0034 mg/L 0.003 las0.0005 03/27/14 16:101
Manganese, total M200.8 ICP-MS 0.0083 mg/L 0.003 pmc0.0005 03/28/14 1:051
Mercury, dissolved M1631, Atomic Fluorescence 0.3 ng/L 0.5B las0.2 03/27/14 13:511
Mercury, total M1631, Atomic Fluorescence 0.7 ng/L 0.5 las0.2 03/28/14 17:201
Molybdenum, dissolved M200.8 ICP-MS 0.0098 mg/L 0.003 las0.0005 03/27/14 16:101
Molybdenum, total M200.8 ICP-MS 0.0099 mg/L 0.003 pmc0.0005 03/28/14 1:051
Nickel, dissolved M200.8 ICP-MS mg/L 0.003U las0.0006 03/27/14 16:101
Nickel, total M200.8 ICP-MS mg/L 0.003U pmc0.0006 03/28/14 1:051
Potassium, dissolved M200.7 ICP 8.4 mg/L 1 aeb0.2 03/21/14 12:241
REPIN.02.06.05.01 * Please refer to Qualifier Reports for details.
Page 33 of 90L17275-1404011436
ACZ Sample ID: L17275-09
Sample ID: TWIN SPRINGS SOUTH
Sample Matrix: Ground Water
SPF Water Engineering
Project ID: Calico 1st Quarter 2014 Sa
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic Analytical
Results
Date Sampled: 03/16/14 17:05
Date Received: 03/19/14
Potassium, total M200.7 ICP 8.6 mg/L 1 jjc0.2 03/26/14 10:491
Scandium, dissolved M200.7 ICP mg/L 0.5U aeb0.1* 03/21/14 12:241
Scandium, total M200.7 ICP mg/L 0.5U jjc0.1* 03/26/14 10:491
Selenium, dissolved M200.8 ICP-MS 0.0046 mg/L 0.0003 las0.0001 03/27/14 16:101
Selenium, total M200.8 ICP-MS 0.0040 mg/L 0.0003 pmc0.0001 03/28/14 1:051
Silver, dissolved M200.8 ICP-MS mg/L 0.0003U las0.00005 03/27/14 16:101
Silver, total M200.8 ICP-MS mg/L 0.0003U pmc0.00005 03/28/14 1:051
Sodium, dissolved M200.7 ICP 41.1 mg/L 1 aeb0.2 03/21/14 12:241
Sodium, total M200.7 ICP 43.4 mg/L 1 jjc0.2 03/26/14 10:491
Strontium, dissolved M200.7 ICP 0.145 mg/L 0.03 aeb0.005 03/21/14 12:241
Strontium, total M200.7 ICP 0.149 mg/L 0.03 jjc0.005 03/26/14 10:491
Thallium, dissolved M200.8 ICP-MS mg/L 0.0005U las0.0001 03/27/14 16:101
Thallium, total M200.8 ICP-MS mg/L 0.0005U pmc0.0001 03/28/14 1:051
Tin, dissolved M200.8 ICP-MS mg/L 0.0005U las0.0001* 03/27/14 16:101
Tin, total M200.8 ICP-MS mg/L 0.0005U pmc0.0001* 03/28/14 1:051
Titanium, dissolved M200.7 ICP mg/L 0.03U aeb0.005 03/21/14 12:241
Titanium, total M200.7 ICP mg/L 0.03U jjc0.005 03/26/14 10:491
Uranium, dissolved M200.8 ICP-MS 0.0034 mg/L 0.0005 las0.0001 03/27/14 16:101
Uranium, total M200.8 ICP-MS 0.0035 mg/L 0.0005 pmc0.0001 03/28/14 1:051
Vanadium, dissolved M200.8 ICP-MS 0.0483 mg/L 0.001 las0.0002 03/27/14 16:101
Vanadium, total M200.8 ICP-MS 0.0452 mg/L 0.001 pmc0.0002 03/28/14 1:051
Zinc, dissolved M200.7 ICP mg/L 0.05U aeb0.01 03/21/14 12:241
Zinc, total M200.7 ICP mg/L 0.05U jjc0.01 03/26/14 10:491
REPIN.02.06.05.01 * Please refer to Qualifier Reports for details.
Page 34 of 90L17275-1404011436
ACZ Sample ID: L17275-09
Sample ID: TWIN SPRINGS SOUTH
Sample Matrix: Ground Water
SPF Water Engineering
Project ID: Calico 1st Quarter 2014 Sa
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic Analytical
Results
Date Sampled: 03/16/14 17:05
Date Received: 03/19/14
Parameter EPA Method Result Units MDLQual AnalystDatePQL
Wet Chemistry
XQDilution
Alkalinity as CaCO3 SM2320B - Titration
Bicarbonate as CaCO3
136 mg/L 20 abd2 03/24/14 0:001
Carbonate as CaCO3 mg/L 20U abd2 03/24/14 0:001
Hydroxide as CaCO3 mg/L 20U abd2 03/24/14 0:001
Total Alkalinity 136 mg/L 20 abd2 03/24/14 0:001
Chloride M300.0 - Ion Chromatography 10.6 mg/L 2.5 tcd0.5 03/26/14 0:151
Conductivity @25C SM2510B 445 umhos/cm 10 abd1 03/24/14 18:091
Cyanide, total M335.4 - Colorimetric w/ distillation mg/L 0.01U bsu0.003* 03/24/14 18:200.5
Cyanide, WAD SM4500-CN I-Colorimetric w/ distillation
mg/L 0.01U mpb0.003* 03/27/14 13:410.5
Fluoride M300.0 - Ion Chromatography 0.62 mg/L 0.5 tcd0.1* 03/26/14 0:151
Hardness as CaCO3 SM2340B - Calculation 122 mg/L 7 calc1 04/01/14 12:24
Nitrate/Nitrite as N M353.2 - H2SO4 preserved 2.32 mg/L 0.1 pjb0.02 03/27/14 23:481
Nitrogen, ammonia M350.1 - Automated Phenate mg/L 0.5U tcd0.05* 03/27/14 12:451
pH (lab) SM4500H+ B
pH 8.2 units 0.1H abd0.1 03/24/14 0:001
pH measured at 19 C 0.1 abd0.1 03/24/14 0:001
Phosphorus, total M365.1 - Auto Ascorbic Acid (digest)
0.02 mg/L 0.05B pjb0.01* 03/28/14 0:241
Residue, Filterable (TDS) @180C
SM2540C 340 mg/L 20 enb10 03/21/14 16:141
Residue, Non-Filterable (TSS) @105C
SM2540D mg/L 20U dcw5* 03/22/14 11:231
Sulfate M300.0 - Ion Chromatography 43.7 mg/L 2.5 tcd0.5 03/26/14 0:151
REPIN.02.06.05.01 * Please refer to Qualifier Reports for details.
Page 35 of 90L17275-1404011436
ACZ Sample ID: L17275-10
Sample ID: SOURDOUGH UPPER
Sample Matrix: Ground Water
SPF Water Engineering
Project ID: Calico 1st Quarter 2014 Sa
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic Analytical
Results
Date Sampled: 03/17/14 11:10
Date Received: 03/19/14
Parameter EPA Method Result Units MDLQual AnalystDatePQL
Inorganic Prep
XQDilution
Cyanide, total M335.4 - Manual Distillation bsu03/24/14 14:25
Cyanide, WAD SM4500-CN I- distillation mss203/26/14 10:04
Phosphorus, total M365.1 - Auto Ascorbic Acid Digestion
mpb03/27/14 15:52
Total Hot Plate Digestion
M200.2 ICP-MS las03/26/14 10:44
Total Hot Plate Digestion
M200.2 ICP jjc03/25/14 11:07
REPIN.02.06.05.01 * Please refer to Qualifier Reports for details.
Page 36 of 90L17275-1404011436
ACZ Sample ID: L17275-10
Sample ID: SOURDOUGH UPPER
Sample Matrix: Ground Water
SPF Water Engineering
Project ID: Calico 1st Quarter 2014 Sa
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic Analytical
Results
Date Sampled: 03/17/14 11:10
Date Received: 03/19/14
Parameter EPA Method Result Units MDLQual AnalystDatePQL
Metals Analysis
XQDilution
Aluminum, dissolved M200.7 ICP mg/L 0.2U aeb0.03 03/21/14 12:271
Aluminum, total M200.7 ICP mg/L 0.2U jjc0.03 03/26/14 10:531
Antimony, dissolved M200.8 ICP-MS mg/L 0.002U las0.0004 03/27/14 16:131
Antimony, total M200.8 ICP-MS mg/L 0.002U pmc0.0004 03/28/14 1:081
Arsenic, dissolved M200.8 ICP-MS 0.0319 mg/L 0.001 las0.0002 03/27/14 16:131
Arsenic, total M200.8 ICP-MS 0.0278 mg/L 0.001 pmc0.0002 03/28/14 1:081
Barium, dissolved M200.7 ICP 0.064 mg/L 0.02 aeb0.003 03/21/14 12:271
Barium, total M200.7 ICP 0.067 mg/L 0.02 jjc0.003 03/26/14 10:531
Beryllium, dissolved M200.8 ICP-MS mg/L 0.0003U las0.00005 03/27/14 16:131
Beryllium, total M200.8 ICP-MS mg/L 0.0003U pmc0.00005 03/28/14 1:081
Bismuth, dissolved M200.7 ICP mg/L 0.2U aeb0.04* 03/21/14 12:271
Bismuth, total M200.7 ICP mg/L 0.2U jjc0.04* 03/26/14 10:531
Boron, dissolved M200.7 ICP 0.12 mg/L 0.05 aeb0.01 03/21/14 12:271
Boron, total M200.7 ICP 0.11 mg/L 0.05 jjc0.01 03/26/14 10:531
Cadmium, dissolved M200.8 ICP-MS mg/L 0.0005U las0.0001 03/27/14 16:131
Cadmium, total M200.8 ICP-MS mg/L 0.0005U pmc0.0001 03/28/14 1:081
Calcium, dissolved M200.7 ICP 34.6 mg/L 0.5 aeb0.1* 03/21/14 12:271
Calcium, total M200.7 ICP 35.2 mg/L 0.5 jjc0.1 03/26/14 10:531
Chromium, dissolved M200.8 ICP-MS mg/L 0.002U las0.0005 03/27/14 16:131
Chromium, total M200.8 ICP-MS mg/L 0.002U pmc0.0005 03/28/14 1:081
Cobalt, dissolved M200.8 ICP-MS 0.00013 mg/L 0.0003B las0.00005 03/27/14 16:131
Cobalt, total M200.8 ICP-MS 0.00009 mg/L 0.0003B pmc0.00005 03/28/14 1:081
Copper, dissolved M200.8 ICP-MS 0.0009 mg/L 0.003B las0.0005 03/27/14 16:131
Copper, total M200.8 ICP-MS 0.0008 mg/L 0.003B pmc0.0005 03/28/14 1:081
Gallium, dissolved M200.7 ICP mg/L 0.5U aeb0.1* 03/21/14 12:271
Gallium, total M200.7 ICP mg/L 0.5U jjc0.1* 03/26/14 10:531
Iron, dissolved M200.7 ICP mg/L 0.05U aeb0.02 03/21/14 12:271
Iron, total M200.7 ICP mg/L 0.05U jjc0.02 03/26/14 10:531
Lead, dissolved M200.8 ICP-MS mg/L 0.0005U las0.0001 03/27/14 16:131
Lead, total M200.8 ICP-MS mg/L 0.0005U pmc0.0001 03/28/14 1:081
Lithium, dissolved M200.7 ICP 0.017 mg/L 0.04B aeb0.008 03/21/14 12:271
Lithium, total M200.7 ICP 0.020 mg/L 0.04B jjc0.008 03/26/14 10:531
Magnesium, dissolved M200.7 ICP 9 mg/L 1 aeb0.2 03/21/14 12:271
Magnesium, total M200.7 ICP 9 mg/L 1 jjc0.2 03/26/14 10:531
Manganese, dissolved M200.8 ICP-MS mg/L 0.003U las0.0005 03/27/14 16:131
Manganese, total M200.8 ICP-MS mg/L 0.003U pmc0.0005* 03/28/14 1:081
Mercury, dissolved M1631, Atomic Fluorescence 1 ng/L 0.5 las0.2 03/27/14 13:561
Mercury, total M1631, Atomic Fluorescence 1.4 ng/L 0.5 las0.2 03/28/14 17:251
Molybdenum, dissolved M200.8 ICP-MS 0.0039 mg/L 0.003 las0.0005 03/27/14 16:131
Molybdenum, total M200.8 ICP-MS 0.0038 mg/L 0.003 pmc0.0005 03/28/14 1:081
Nickel, dissolved M200.8 ICP-MS 0.0006 mg/L 0.003B las0.0006 03/27/14 16:131
Nickel, total M200.8 ICP-MS 0.0006 mg/L 0.003B pmc0.0006 03/28/14 1:081
Potassium, dissolved M200.7 ICP 3.8 mg/L 1 aeb0.2 03/21/14 12:271
REPIN.02.06.05.01 * Please refer to Qualifier Reports for details.
Page 37 of 90L17275-1404011436
ACZ Sample ID: L17275-10
Sample ID: SOURDOUGH UPPER
Sample Matrix: Ground Water
SPF Water Engineering
Project ID: Calico 1st Quarter 2014 Sa
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic Analytical
Results
Date Sampled: 03/17/14 11:10
Date Received: 03/19/14
Potassium, total M200.7 ICP 3.7 mg/L 1 jjc0.2 03/26/14 10:531
Scandium, dissolved M200.7 ICP mg/L 0.5U aeb0.1* 03/21/14 12:271
Scandium, total M200.7 ICP mg/L 0.5U jjc0.1* 03/26/14 10:531
Selenium, dissolved M200.8 ICP-MS 0.0019 mg/L 0.0003 las0.0001 03/27/14 16:131
Selenium, total M200.8 ICP-MS 0.0016 mg/L 0.0003 pmc0.0001 03/28/14 1:081
Silver, dissolved M200.8 ICP-MS mg/L 0.0003U las0.00005 03/27/14 16:131
Silver, total M200.8 ICP-MS mg/L 0.0003U pmc0.00005 03/28/14 1:081
Sodium, dissolved M200.7 ICP 40.9 mg/L 1 aeb0.2 03/21/14 12:271
Sodium, total M200.7 ICP 42 mg/L 1 jjc0.2 03/26/14 10:531
Strontium, dissolved M200.7 ICP 0.239 mg/L 0.03 aeb0.005 03/21/14 12:271
Strontium, total M200.7 ICP 0.237 mg/L 0.03 jjc0.005 03/26/14 10:531
Thallium, dissolved M200.8 ICP-MS mg/L 0.0005U las0.0001 03/27/14 16:131
Thallium, total M200.8 ICP-MS mg/L 0.0005U pmc0.0001 03/28/14 1:081
Tin, dissolved M200.8 ICP-MS mg/L 0.0005U las0.0001* 03/27/14 16:131
Tin, total M200.8 ICP-MS mg/L 0.0005U pmc0.0001* 03/28/14 1:081
Titanium, dissolved M200.7 ICP mg/L 0.03U aeb0.005 03/21/14 12:271
Titanium, total M200.7 ICP 0.007 mg/L 0.03B jjc0.005 03/26/14 10:531
Uranium, dissolved M200.8 ICP-MS 0.0039 mg/L 0.0005 las0.0001 03/27/14 16:131
Uranium, total M200.8 ICP-MS 0.0039 mg/L 0.0005 pmc0.0001 03/28/14 1:081
Vanadium, dissolved M200.8 ICP-MS 0.0337 mg/L 0.001 las0.0002 03/27/14 16:131
Vanadium, total M200.8 ICP-MS 0.0315 mg/L 0.001 pmc0.0002 03/28/14 1:081
Zinc, dissolved M200.7 ICP 0.10 mg/L 0.05 aeb0.01 03/21/14 12:271
Zinc, total M200.7 ICP 0.10 mg/L 0.05 jjc0.01 03/26/14 10:531
REPIN.02.06.05.01 * Please refer to Qualifier Reports for details.
Page 38 of 90L17275-1404011436
ACZ Sample ID: L17275-10
Sample ID: SOURDOUGH UPPER
Sample Matrix: Ground Water
SPF Water Engineering
Project ID: Calico 1st Quarter 2014 Sa
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic Analytical
Results
Date Sampled: 03/17/14 11:10
Date Received: 03/19/14
Parameter EPA Method Result Units MDLQual AnalystDatePQL
Wet Chemistry
XQDilution
Alkalinity as CaCO3 SM2320B - Titration
Bicarbonate as CaCO3
131 mg/L 20 abd2 03/24/14 0:001
Carbonate as CaCO3 mg/L 20U abd2 03/24/14 0:001
Hydroxide as CaCO3 mg/L 20U abd2 03/24/14 0:001
Total Alkalinity 131 mg/L 20 abd2 03/24/14 0:001
Chloride M300.0 - Ion Chromatography 14.4 mg/L 2.5 tcd0.5 03/26/14 0:331
Conductivity @25C SM2510B 427 umhos/cm 10 abd1 03/24/14 18:181
Cyanide, total M335.4 - Colorimetric w/ distillation mg/L 0.01U bsu0.003* 03/24/14 18:210.5
Cyanide, WAD SM4500-CN I-Colorimetric w/ distillation
mg/L 0.01U mpb0.003* 03/27/14 13:410.5
Fluoride M300.0 - Ion Chromatography 0.45 mg/L 0.5B tcd0.1* 03/26/14 0:331
Hardness as CaCO3 SM2340B - Calculation 123 mg/L 7 calc1 04/01/14 12:24
Nitrate/Nitrite as N M353.2 - H2SO4 preserved 0.05 mg/L 0.1B pjb0.02 03/27/14 23:501
Nitrogen, ammonia M350.1 - Automated Phenate mg/L 0.5U tcd0.05* 03/27/14 13:111
pH (lab) SM4500H+ B
pH 8.1 units 0.1H abd0.1 03/24/14 0:001
pH measured at 19 C 0.1 abd0.1 03/24/14 0:001
Phosphorus, total M365.1 - Auto Ascorbic Acid (digest)
0.03 mg/L 0.05B pjb0.01* 03/28/14 0:251
Residue, Filterable (TDS) @180C
SM2540C 310 mg/L 20 enb10 03/21/14 16:171
Residue, Non-Filterable (TSS) @105C
SM2540D mg/L 20U dcw5* 03/22/14 11:261
Sulfate M300.0 - Ion Chromatography 42.0 mg/L 2.5 tcd0.5 03/26/14 0:331
REPIN.02.06.05.01 * Please refer to Qualifier Reports for details.
Page 39 of 90L17275-1404011436
ACZ Sample ID: L17275-11
Sample ID: SOURDOUGH LOWER
Sample Matrix: Ground Water
SPF Water Engineering
Project ID: Calico 1st Quarter 2014 Sa
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic Analytical
Results
Date Sampled: 03/17/14 12:30
Date Received: 03/19/14
Parameter EPA Method Result Units MDLQual AnalystDatePQL
Inorganic Prep
XQDilution
Cyanide, total M335.4 - Manual Distillation bsu03/24/14 14:34
Cyanide, WAD SM4500-CN I- distillation mss203/26/14 10:14
Phosphorus, total M365.1 - Auto Ascorbic Acid Digestion
mpb03/27/14 16:00
Total Hot Plate Digestion
M200.2 ICP jjc03/25/14 11:18
Total Hot Plate Digestion
M200.2 ICP-MS las03/26/14 10:54
REPIN.02.06.05.01 * Please refer to Qualifier Reports for details.
Page 40 of 90L17275-1404011436
ACZ Sample ID: L17275-11
Sample ID: SOURDOUGH LOWER
Sample Matrix: Ground Water
SPF Water Engineering
Project ID: Calico 1st Quarter 2014 Sa
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic Analytical
Results
Date Sampled: 03/17/14 12:30
Date Received: 03/19/14
Parameter EPA Method Result Units MDLQual AnalystDatePQL
Metals Analysis
XQDilution
Aluminum, dissolved M200.7 ICP mg/L 0.2U aeb0.03 03/21/14 12:301
Aluminum, total M200.7 ICP mg/L 0.2U jjc0.03 03/26/14 10:561
Antimony, dissolved M200.8 ICP-MS mg/L 0.002U las0.0004 03/27/14 16:171
Antimony, total M200.8 ICP-MS mg/L 0.002U pmc0.0004 03/28/14 1:121
Arsenic, dissolved M200.8 ICP-MS 0.0264 mg/L 0.001 las0.0002 03/27/14 16:171
Arsenic, total M200.8 ICP-MS 0.0229 mg/L 0.001 pmc0.0002 03/28/14 1:121
Barium, dissolved M200.7 ICP 0.088 mg/L 0.02 aeb0.003 03/21/14 12:301
Barium, total M200.7 ICP 0.092 mg/L 0.02 jjc0.003 03/26/14 10:561
Beryllium, dissolved M200.8 ICP-MS mg/L 0.0003U las0.00005 03/27/14 16:171
Beryllium, total M200.8 ICP-MS mg/L 0.0003U pmc0.00005 03/28/14 1:121
Bismuth, dissolved M200.7 ICP mg/L 0.2U aeb0.04* 03/21/14 12:301
Bismuth, total M200.7 ICP mg/L 0.2U jjc0.04* 03/26/14 10:561
Boron, dissolved M200.7 ICP 0.09 mg/L 0.05 aeb0.01 03/21/14 12:301
Boron, total M200.7 ICP 0.09 mg/L 0.05 jjc0.01 03/26/14 10:561
Cadmium, dissolved M200.8 ICP-MS mg/L 0.0005U las0.0001 03/27/14 16:171
Cadmium, total M200.8 ICP-MS mg/L 0.0005U pmc0.0001 03/28/14 1:121
Calcium, dissolved M200.7 ICP 25.4 mg/L 0.5 aeb0.1 03/21/14 12:301
Calcium, total M200.7 ICP 26.4 mg/L 0.5 jjc0.1 03/26/14 10:561
Chromium, dissolved M200.8 ICP-MS mg/L 0.002U las0.0005 03/27/14 16:171
Chromium, total M200.8 ICP-MS 0.0007 mg/L 0.002B pmc0.0005 03/28/14 1:121
Cobalt, dissolved M200.8 ICP-MS 0.00008 mg/L 0.0003B las0.00005 03/27/14 16:171
Cobalt, total M200.8 ICP-MS 0.00006 mg/L 0.0003B pmc0.00005 03/28/14 1:121
Copper, dissolved M200.8 ICP-MS mg/L 0.003U las0.0005 03/27/14 16:171
Copper, total M200.8 ICP-MS mg/L 0.003U pmc0.0005 03/28/14 1:121
Gallium, dissolved M200.7 ICP mg/L 0.5U aeb0.1* 03/21/14 12:301
Gallium, total M200.7 ICP mg/L 0.5U jjc0.1* 03/26/14 10:561
Iron, dissolved M200.7 ICP mg/L 0.05U aeb0.02 03/21/14 12:301
Iron, total M200.7 ICP mg/L 0.05U jjc0.02 03/26/14 10:561
Lead, dissolved M200.8 ICP-MS mg/L 0.0005U las0.0001 03/27/14 16:171
Lead, total M200.8 ICP-MS mg/L 0.0005U pmc0.0001 03/28/14 1:121
Lithium, dissolved M200.7 ICP 0.014 mg/L 0.04B aeb0.008 03/21/14 12:301
Lithium, total M200.7 ICP 0.019 mg/L 0.04B jjc0.008 03/26/14 10:561
Magnesium, dissolved M200.7 ICP 5.7 mg/L 1 aeb0.2 03/21/14 12:301
Magnesium, total M200.7 ICP 5.8 mg/L 1 jjc0.2 03/26/14 10:561
Manganese, dissolved M200.8 ICP-MS 0.0038 mg/L 0.003 las0.0005 03/27/14 16:171
Manganese, total M200.8 ICP-MS 0.0038 mg/L 0.003 pmc0.0005* 03/28/14 1:121
Mercury, dissolved M1631, Atomic Fluorescence 0.7 ng/L 0.5 las0.2 03/27/14 14:011
Mercury, total M1631, Atomic Fluorescence 1 ng/L 0.5 las0.2 03/28/14 17:301
Molybdenum, dissolved M200.8 ICP-MS 0.0045 mg/L 0.003 las0.0005 03/27/14 16:171
Molybdenum, total M200.8 ICP-MS 0.0043 mg/L 0.003 pmc0.0005 03/28/14 1:121
Nickel, dissolved M200.8 ICP-MS mg/L 0.003U las0.0006 03/27/14 16:171
Nickel, total M200.8 ICP-MS mg/L 0.003U pmc0.0006 03/28/14 1:121
Potassium, dissolved M200.7 ICP 2.7 mg/L 1 aeb0.2 03/21/14 12:301
REPIN.02.06.05.01 * Please refer to Qualifier Reports for details.
Page 41 of 90L17275-1404011436
ACZ Sample ID: L17275-11
Sample ID: SOURDOUGH LOWER
Sample Matrix: Ground Water
SPF Water Engineering
Project ID: Calico 1st Quarter 2014 Sa
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic Analytical
Results
Date Sampled: 03/17/14 12:30
Date Received: 03/19/14
Potassium, total M200.7 ICP 2.6 mg/L 1 jjc0.2 03/26/14 10:561
Scandium, dissolved M200.7 ICP mg/L 0.5U aeb0.1* 03/21/14 12:301
Scandium, total M200.7 ICP mg/L 0.5U jjc0.1* 03/26/14 10:561
Selenium, dissolved M200.8 ICP-MS 0.0023 mg/L 0.0003 las0.0001 03/27/14 16:171
Selenium, total M200.8 ICP-MS 0.0020 mg/L 0.0003 pmc0.0001 03/28/14 1:121
Silver, dissolved M200.8 ICP-MS mg/L 0.0003U las0.00005 03/27/14 16:171
Silver, total M200.8 ICP-MS mg/L 0.0003U pmc0.00005 03/28/14 1:121
Sodium, dissolved M200.7 ICP 39.8 mg/L 1 aeb0.2 03/21/14 12:301
Sodium, total M200.7 ICP 41.5 mg/L 1 jjc0.2 03/26/14 10:561
Strontium, dissolved M200.7 ICP 0.195 mg/L 0.03 aeb0.005 03/21/14 12:301
Strontium, total M200.7 ICP 0.197 mg/L 0.03 jjc0.005 03/26/14 10:561
Thallium, dissolved M200.8 ICP-MS mg/L 0.0005U las0.0001 03/27/14 16:171
Thallium, total M200.8 ICP-MS mg/L 0.0005U pmc0.0001 03/28/14 1:121
Tin, dissolved M200.8 ICP-MS mg/L 0.0005U las0.0001* 03/27/14 16:171
Tin, total M200.8 ICP-MS mg/L 0.0005U pmc0.0001* 03/28/14 1:121
Titanium, dissolved M200.7 ICP mg/L 0.03U aeb0.005 03/21/14 12:301
Titanium, total M200.7 ICP 0.006 mg/L 0.03B jjc0.005 03/26/14 10:561
Uranium, dissolved M200.8 ICP-MS 0.0069 mg/L 0.0005 las0.0001 03/27/14 16:171
Uranium, total M200.8 ICP-MS 0.0069 mg/L 0.0005 pmc0.0001 03/28/14 1:121
Vanadium, dissolved M200.8 ICP-MS 0.0186 mg/L 0.001 las0.0002 03/27/14 16:171
Vanadium, total M200.8 ICP-MS 0.0169 mg/L 0.001 pmc0.0002 03/28/14 1:121
Zinc, dissolved M200.7 ICP 0.01 mg/L 0.05B aeb0.01 03/21/14 12:301
Zinc, total M200.7 ICP 0.02 mg/L 0.05B jjc0.01 03/26/14 10:561
REPIN.02.06.05.01 * Please refer to Qualifier Reports for details.
Page 42 of 90L17275-1404011436
ACZ Sample ID: L17275-11
Sample ID: SOURDOUGH LOWER
Sample Matrix: Ground Water
SPF Water Engineering
Project ID: Calico 1st Quarter 2014 Sa
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic Analytical
Results
Date Sampled: 03/17/14 12:30
Date Received: 03/19/14
Parameter EPA Method Result Units MDLQual AnalystDatePQL
Wet Chemistry
XQDilution
Alkalinity as CaCO3 SM2320B - Titration
Bicarbonate as CaCO3
112 mg/L 20 abd2 03/24/14 0:001
Carbonate as CaCO3 mg/L 20U abd2 03/24/14 0:001
Hydroxide as CaCO3 mg/L 20U abd2 03/24/14 0:001
Total Alkalinity 112 mg/L 20 abd2 03/24/14 0:001
Chloride M300.0 - Ion Chromatography 9.21 mg/L 2.5 tcd0.5 03/26/14 0:511
Conductivity @25C SM2510B 352 umhos/cm 10 abd1 03/24/14 18:271
Cyanide, total M335.4 - Colorimetric w/ distillation mg/L 0.01U bsu0.003* 03/24/14 18:220.5
Cyanide, WAD SM4500-CN I-Colorimetric w/ distillation
mg/L 0.01U mpb0.003* 03/27/14 13:420.5
Fluoride M300.0 - Ion Chromatography 0.33 mg/L 0.5B tcd0.1* 03/26/14 0:511
Hardness as CaCO3 SM2340B - Calculation 87 mg/L 7 calc1 04/01/14 12:25
Nitrate/Nitrite as N M353.2 - H2SO4 preserved 0.76 mg/L 0.1 pjb0.02 03/27/14 23:511
Nitrogen, ammonia M350.1 - Automated Phenate mg/L 0.5U tcd0.05* 03/27/14 13:131
pH (lab) SM4500H+ B
pH 8.2 units 0.1H abd0.1 03/24/14 0:001
pH measured at 20 C 0.1 abd0.1 03/24/14 0:001
Phosphorus, total M365.1 - Auto Ascorbic Acid (digest)
0.01 mg/L 0.05B pjb0.01* 03/28/14 0:261
Residue, Filterable (TDS) @180C
SM2540C 260 mg/L 20 enb10 03/21/14 16:191
Residue, Non-Filterable (TSS) @105C
SM2540D mg/L 20U dcw5* 03/22/14 11:281
Sulfate M300.0 - Ion Chromatography 30.7 mg/L 2.5 tcd0.5 03/26/14 0:511
REPIN.02.06.05.01 * Please refer to Qualifier Reports for details.
Page 43 of 90L17275-1404011436
ACZ Sample ID: L17275-12
Sample ID: EQUIPMENT BLANK
Sample Matrix: Ground Water
SPF Water Engineering
Project ID: Calico 1st Quarter 2014 Sa
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic Analytical
Results
Date Sampled: 03/17/14 13:00
Date Received: 03/19/14
Parameter EPA Method Result Units MDLQual AnalystDatePQL
Inorganic Prep
XQDilution
Cyanide, total M335.4 - Manual Distillation bsu03/24/14 14:44
Cyanide, WAD SM4500-CN I- distillation mss203/26/14 10:33
Phosphorus, total M365.1 - Auto Ascorbic Acid Digestion
bsu03/28/14 12:50
Total Hot Plate Digestion
M200.2 ICP-MS las03/26/14 11:03
Total Hot Plate Digestion
M200.2 ICP jjc03/25/14 11:30
REPIN.02.06.05.01 * Please refer to Qualifier Reports for details.
Page 44 of 90L17275-1404011436
ACZ Sample ID: L17275-12
Sample ID: EQUIPMENT BLANK
Sample Matrix: Ground Water
SPF Water Engineering
Project ID: Calico 1st Quarter 2014 Sa
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic Analytical
Results
Date Sampled: 03/17/14 13:00
Date Received: 03/19/14
Parameter EPA Method Result Units MDLQual AnalystDatePQL
Metals Analysis
XQDilution
Aluminum, dissolved M200.7 ICP mg/L 0.2U aeb0.03 03/21/14 12:331
Aluminum, total M200.7 ICP mg/L 0.2U jjc0.03 03/26/14 10:591
Antimony, dissolved M200.8 ICP-MS mg/L 0.002U las0.0004 03/27/14 16:201
Antimony, total M200.8 ICP-MS mg/L 0.002U pmc0.0004 03/28/14 1:151
Arsenic, dissolved M200.8 ICP-MS mg/L 0.001U las0.0002 03/27/14 16:201
Arsenic, total M200.8 ICP-MS mg/L 0.001U pmc0.0002 03/28/14 1:151
Barium, dissolved M200.7 ICP mg/L 0.02U aeb0.003 03/21/14 12:331
Barium, total M200.7 ICP mg/L 0.02U jjc0.003 03/26/14 10:591
Beryllium, dissolved M200.8 ICP-MS mg/L 0.0003U las0.00005 03/27/14 16:201
Beryllium, total M200.8 ICP-MS mg/L 0.0003U pmc0.00005 03/28/14 1:151
Bismuth, dissolved M200.7 ICP mg/L 0.2U aeb0.04* 03/21/14 12:331
Bismuth, total M200.7 ICP mg/L 0.2U jjc0.04* 03/26/14 10:591
Boron, dissolved M200.7 ICP mg/L 0.05U aeb0.01 03/21/14 12:331
Boron, total M200.7 ICP 0.01 mg/L 0.05B jjc0.01 03/26/14 10:591
Cadmium, dissolved M200.8 ICP-MS mg/L 0.0005U las0.0001 03/27/14 16:201
Cadmium, total M200.8 ICP-MS mg/L 0.0005U pmc0.0001 03/28/14 1:151
Calcium, dissolved M200.7 ICP mg/L 0.5U aeb0.1 03/21/14 12:331
Calcium, total M200.7 ICP mg/L 0.5U jjc0.1 03/26/14 10:591
Chromium, dissolved M200.8 ICP-MS mg/L 0.002U las0.0005 03/27/14 16:201
Chromium, total M200.8 ICP-MS mg/L 0.002U pmc0.0005 03/28/14 1:151
Cobalt, dissolved M200.8 ICP-MS mg/L 0.0003U las0.00005 03/27/14 16:201
Cobalt, total M200.8 ICP-MS mg/L 0.0003U pmc0.00005 03/28/14 1:151
Copper, dissolved M200.8 ICP-MS mg/L 0.003U las0.0005 03/27/14 16:201
Copper, total M200.8 ICP-MS mg/L 0.003U pmc0.0005 03/28/14 1:151
Gallium, dissolved M200.7 ICP mg/L 0.5U aeb0.1* 03/21/14 12:331
Gallium, total M200.7 ICP mg/L 0.5U jjc0.1* 03/26/14 10:591
Iron, dissolved M200.7 ICP mg/L 0.05U aeb0.02 03/21/14 12:331
Iron, total M200.7 ICP mg/L 0.05U jjc0.02 03/26/14 10:591
Lead, dissolved M200.8 ICP-MS mg/L 0.0005U las0.0001 03/27/14 16:201
Lead, total M200.8 ICP-MS mg/L 0.0005U pmc0.0001 03/28/14 1:151
Lithium, dissolved M200.7 ICP mg/L 0.04U aeb0.008 03/21/14 12:331
Lithium, total M200.7 ICP mg/L 0.04U jjc0.008 03/26/14 10:591
Magnesium, dissolved M200.7 ICP mg/L 1U aeb0.2 03/21/14 12:331
Magnesium, total M200.7 ICP mg/L 1U jjc0.2 03/26/14 10:591
Manganese, dissolved M200.8 ICP-MS mg/L 0.003U las0.0005 03/27/14 16:201
Manganese, total M200.8 ICP-MS 0.0008 mg/L 0.003B pmc0.0005* 03/28/14 1:151
Mercury, dissolved M1631, Atomic Fluorescence ng/L 0.5U las0.2 03/27/14 14:061
Mercury, total M1631, Atomic Fluorescence ng/L 0.5U las0.2 03/28/14 17:351
Molybdenum, dissolved M200.8 ICP-MS mg/L 0.003U las0.0005 03/27/14 16:201
Molybdenum, total M200.8 ICP-MS mg/L 0.003U pmc0.0005 03/28/14 1:151
Nickel, dissolved M200.8 ICP-MS mg/L 0.003U las0.0006 03/27/14 16:201
Nickel, total M200.8 ICP-MS mg/L 0.003U pmc0.0006 03/28/14 1:151
Potassium, dissolved M200.7 ICP mg/L 1U aeb0.2 03/21/14 12:331
REPIN.02.06.05.01 * Please refer to Qualifier Reports for details.
Page 45 of 90L17275-1404011436
ACZ Sample ID: L17275-12
Sample ID: EQUIPMENT BLANK
Sample Matrix: Ground Water
SPF Water Engineering
Project ID: Calico 1st Quarter 2014 Sa
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic Analytical
Results
Date Sampled: 03/17/14 13:00
Date Received: 03/19/14
Potassium, total M200.7 ICP mg/L 1U jjc0.2 03/26/14 10:591
Scandium, dissolved M200.7 ICP mg/L 0.5U aeb0.1* 03/21/14 12:331
Scandium, total M200.7 ICP mg/L 0.5U jjc0.1* 03/26/14 10:591
Selenium, dissolved M200.8 ICP-MS mg/L 0.0003U las0.0001 03/27/14 16:201
Selenium, total M200.8 ICP-MS mg/L 0.0003U pmc0.0001 03/28/14 1:151
Silver, dissolved M200.8 ICP-MS mg/L 0.0003U las0.00005 03/27/14 16:201
Silver, total M200.8 ICP-MS mg/L 0.0003U pmc0.00005 03/28/14 1:151
Sodium, dissolved M200.7 ICP mg/L 1U aeb0.2 03/21/14 12:331
Sodium, total M200.7 ICP mg/L 1U jjc0.2 03/26/14 10:591
Strontium, dissolved M200.7 ICP mg/L 0.03U aeb0.005 03/21/14 12:331
Strontium, total M200.7 ICP mg/L 0.03U jjc0.005 03/26/14 10:591
Thallium, dissolved M200.8 ICP-MS mg/L 0.0005U las0.0001 03/27/14 16:201
Thallium, total M200.8 ICP-MS mg/L 0.0005U pmc0.0001 03/28/14 1:151
Tin, dissolved M200.8 ICP-MS mg/L 0.0005U las0.0001* 03/27/14 16:201
Tin, total M200.8 ICP-MS mg/L 0.0005U pmc0.0001* 03/28/14 1:151
Titanium, dissolved M200.7 ICP mg/L 0.03U aeb0.005 03/21/14 12:331
Titanium, total M200.7 ICP mg/L 0.03U jjc0.005 03/26/14 10:591
Uranium, dissolved M200.8 ICP-MS mg/L 0.0005U las0.0001 03/27/14 16:201
Uranium, total M200.8 ICP-MS mg/L 0.0005U pmc0.0001 03/28/14 1:151
Vanadium, dissolved M200.8 ICP-MS mg/L 0.001U las0.0002 03/27/14 16:201
Vanadium, total M200.8 ICP-MS mg/L 0.001U pmc0.0002 03/28/14 1:151
Zinc, dissolved M200.7 ICP mg/L 0.05U aeb0.01 03/21/14 12:331
Zinc, total M200.7 ICP mg/L 0.05U jjc0.01 03/26/14 10:591
REPIN.02.06.05.01 * Please refer to Qualifier Reports for details.
Page 46 of 90L17275-1404011436
ACZ Sample ID: L17275-12
Sample ID: EQUIPMENT BLANK
Sample Matrix: Ground Water
SPF Water Engineering
Project ID: Calico 1st Quarter 2014 Sa
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic Analytical
Results
Date Sampled: 03/17/14 13:00
Date Received: 03/19/14
Parameter EPA Method Result Units MDLQual AnalystDatePQL
Wet Chemistry
XQDilution
Alkalinity as CaCO3 SM2320B - Titration
Bicarbonate as CaCO3
mg/L 20U abd2 03/24/14 0:001
Carbonate as CaCO3 mg/L 20U abd2 03/24/14 0:001
Hydroxide as CaCO3 mg/L 20U abd2 03/24/14 0:001
Total Alkalinity mg/L 20U abd2 03/24/14 0:001
Chloride M300.0 - Ion Chromatography mg/L 2.5U tcd0.5 03/26/14 1:091
Conductivity @25C SM2510B 1 umhos/cm 10B abd1 03/24/14 18:441
Cyanide, total M335.4 - Colorimetric w/ distillation mg/L 0.01U bsu0.003* 03/24/14 18:220.5
Cyanide, WAD SM4500-CN I-Colorimetric w/ distillation
mg/L 0.01U mpb0.003* 03/27/14 13:440.5
Fluoride M300.0 - Ion Chromatography mg/L 0.5U tcd0.1* 03/26/14 1:091
Hardness as CaCO3 SM2340B - Calculation mg/L 7U calc1 04/01/14 12:25
Nitrate/Nitrite as N M353.2 - H2SO4 preserved mg/L 0.1U pjb0.02 03/27/14 23:521
Nitrogen, ammonia M350.1 - Automated Phenate mg/L 0.5U tcd0.05* 03/27/14 13:151
pH (lab) SM4500H+ B
pH 6.1 units 0.1H abd0.1 03/24/14 0:001
pH measured at 21 C 0.1 abd0.1 03/24/14 0:001
Phosphorus, total M365.1 - Auto Ascorbic Acid (digest)
mg/L 0.05U pjb0.01* 03/28/14 22:001
Residue, Filterable (TDS) @180C
SM2540C mg/L 20U enb10 03/21/14 16:211
Residue, Non-Filterable (TSS) @105C
SM2540D mg/L 20U dcw5* 03/22/14 11:341
Sulfate M300.0 - Ion Chromatography mg/L 2.5U tcd0.5 03/26/14 1:091
REPIN.02.06.05.01 * Please refer to Qualifier Reports for details.
Page 47 of 90L17275-1404011436
ACZ Sample ID: L17275-13
Sample ID: TRANSFER BLANK
Sample Matrix: Ground Water
SPF Water Engineering
Project ID: Calico 1st Quarter 2014 Sa
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic Analytical
Results
Date Sampled: 03/17/14 13:20
Date Received: 03/19/14
Parameter EPA Method Result Units MDLQual AnalystDatePQL
Inorganic Prep
XQDilution
Cyanide, total M335.4 - Manual Distillation bsu03/24/14 15:03
Cyanide, WAD SM4500-CN I- distillation mss203/26/14 10:52
Phosphorus, total M365.1 - Auto Ascorbic Acid Digestion
bsu03/28/14 13:10
Total Hot Plate Digestion
M200.2 ICP-MS las03/26/14 11:13
Total Hot Plate Digestion
M200.2 ICP jjc03/25/14 11:42
Parameter EPA Method Result Units MDLQual AnalystDatePQL
Metals Analysis
XQDilution
Aluminum, total M200.7 ICP mg/L 0.2U jjc0.03 03/26/14 11:021
Antimony, total M200.8 ICP-MS mg/L 0.002U pmc0.0004 03/28/14 1:191
Arsenic, total M200.8 ICP-MS mg/L 0.001U pmc0.0002 03/28/14 1:191
Barium, total M200.7 ICP mg/L 0.02U jjc0.003 03/26/14 11:021
Beryllium, total M200.8 ICP-MS mg/L 0.0003U pmc0.00005 03/28/14 1:191
Bismuth, total M200.7 ICP mg/L 0.2U jjc0.04* 03/26/14 11:021
Boron, total M200.7 ICP mg/L 0.05U jjc0.01 03/26/14 11:021
Cadmium, total M200.8 ICP-MS mg/L 0.0005U pmc0.0001 03/28/14 1:191
Calcium, total M200.7 ICP mg/L 0.5U jjc0.1 03/26/14 11:021
Chromium, total M200.8 ICP-MS mg/L 0.002U pmc0.0005 03/28/14 1:191
Cobalt, total M200.8 ICP-MS mg/L 0.0003U pmc0.00005 03/28/14 1:191
Copper, total M200.8 ICP-MS mg/L 0.003U pmc0.0005 03/28/14 1:191
Gallium, total M200.7 ICP mg/L 0.5U jjc0.1* 03/26/14 11:021
Iron, total M200.7 ICP mg/L 0.05U jjc0.02 03/26/14 11:021
Lead, total M200.8 ICP-MS mg/L 0.0005U pmc0.0001 03/28/14 1:191
Lithium, total M200.7 ICP mg/L 0.04U jjc0.008 03/26/14 11:021
Magnesium, total M200.7 ICP mg/L 1U jjc0.2 03/26/14 11:021
Manganese, total M200.8 ICP-MS 0.0006 mg/L 0.003B pmc0.0005* 03/28/14 1:191
Mercury, total M1631, Atomic Fluorescence ng/L 0.5U las0.2 03/28/14 17:401
Molybdenum, total M200.8 ICP-MS mg/L 0.003U pmc0.0005 03/28/14 1:191
Nickel, total M200.8 ICP-MS mg/L 0.003U pmc0.0006 03/28/14 1:191
Potassium, total M200.7 ICP mg/L 1U jjc0.2 03/26/14 11:021
Scandium, total M200.7 ICP mg/L 0.5U jjc0.1* 03/26/14 11:021
Selenium, total M200.8 ICP-MS mg/L 0.0003U pmc0.0001 03/28/14 1:191
Silver, total M200.8 ICP-MS mg/L 0.0003U pmc0.00005 03/28/14 1:191
Sodium, total M200.7 ICP mg/L 1U jjc0.2 03/26/14 11:021
Strontium, total M200.7 ICP mg/L 0.03U jjc0.005 03/26/14 11:021
Thallium, total M200.8 ICP-MS mg/L 0.0005U pmc0.0001 03/28/14 1:191
Tin, total M200.8 ICP-MS mg/L 0.0005U pmc0.0001* 03/28/14 1:191
Titanium, total M200.7 ICP mg/L 0.03U jjc0.005 03/26/14 11:021
Uranium, total M200.8 ICP-MS mg/L 0.0005U pmc0.0001 03/28/14 1:191
Vanadium, total M200.8 ICP-MS mg/L 0.001U pmc0.0002 03/28/14 1:191
Zinc, total M200.7 ICP mg/L 0.05U jjc0.01 03/26/14 11:021
REPIN.02.06.05.01 * Please refer to Qualifier Reports for details.
Page 48 of 90L17275-1404011436
ACZ Sample ID: L17275-13
Sample ID: TRANSFER BLANK
Sample Matrix: Ground Water
SPF Water Engineering
Project ID: Calico 1st Quarter 2014 Sa
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic Analytical
Results
Date Sampled: 03/17/14 13:20
Date Received: 03/19/14
Parameter EPA Method Result Units MDLQual AnalystDatePQL
Wet Chemistry
XQDilution
Alkalinity as CaCO3 SM2320B - Titration
Bicarbonate as CaCO3
mg/L 20U abd2 03/24/14 0:001
Carbonate as CaCO3 mg/L 20U abd2 03/24/14 0:001
Hydroxide as CaCO3 mg/L 20U abd2 03/24/14 0:001
Total Alkalinity mg/L 20U abd2 03/24/14 0:001
Chloride M300.0 - Ion Chromatography mg/L 2.5U tcd0.5 03/26/14 1:271
Conductivity @25C SM2510B umhos/cm 10U abd1 03/24/14 18:511
Cyanide, total M335.4 - Colorimetric w/ distillation mg/L 0.01U bsu0.003* 03/24/14 18:240.5
Cyanide, WAD SM4500-CN I-Colorimetric w/ distillation
mg/L 0.01U mpb0.003* 03/27/14 13:460.5
Fluoride M300.0 - Ion Chromatography mg/L 0.5U tcd0.1* 03/26/14 1:271
Nitrate/Nitrite as N M353.2 - H2SO4 preserved mg/L 0.1U pjb0.02 03/27/14 23:531
Nitrogen, ammonia M350.1 - Automated Phenate mg/L 0.5U tcd0.05* 03/27/14 13:161
pH (lab) SM4500H+ B
pH 5.9 units 0.1H abd0.1 03/24/14 0:001
pH measured at 22 C 0.1 abd0.1 03/24/14 0:001
Phosphorus, total M365.1 - Auto Ascorbic Acid (digest)
mg/L 0.05U pjb0.01* 03/28/14 22:021
Residue, Filterable (TDS) @180C
SM2540C mg/L 20U enb10 03/21/14 16:231
Residue, Non-Filterable (TSS) @105C
SM2540D mg/L 20U dcw5* 03/22/14 11:361
Sulfate M300.0 - Ion Chromatography mg/L 2.5U tcd0.5 03/26/14 1:271
REPIN.02.06.05.01 * Please refer to Qualifier Reports for details.
Page 49 of 90L17275-1404011436
ACZ Sample ID: L17275-14
Sample ID: PROD-1
Sample Matrix: Ground Water
SPF Water Engineering
Project ID: Calico 1st Quarter 2014 Sa
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic Analytical
Results
Date Sampled: 03/16/14 13:20
Date Received: 03/19/14
Parameter EPA Method Result Units MDLQual AnalystDatePQL
Inorganic Prep
XQDilution
Cyanide, total M335.4 - Manual Distillation bsu03/24/14 15:22
Cyanide, WAD SM4500-CN I- distillation mss203/26/14 11:02
Phosphorus, total M365.1 - Auto Ascorbic Acid Digestion
bsu03/28/14 13:31
Total Hot Plate Digestion
M200.2 ICP jjc03/25/14 11:53
Total Hot Plate Digestion
M200.2 ICP-MS las03/26/14 11:22
REPIN.02.06.05.01 * Please refer to Qualifier Reports for details.
Page 50 of 90L17275-1404011436
ACZ Sample ID: L17275-14
Sample ID: PROD-1
Sample Matrix: Ground Water
SPF Water Engineering
Project ID: Calico 1st Quarter 2014 Sa
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic Analytical
Results
Date Sampled: 03/16/14 13:20
Date Received: 03/19/14
Parameter EPA Method Result Units MDLQual AnalystDatePQL
Metals Analysis
XQDilution
Aluminum, dissolved M200.7 ICP mg/L 0.2U aeb0.03 03/21/14 12:361
Aluminum, total M200.7 ICP mg/L 0.2U jjc0.03 03/26/14 11:051
Antimony, dissolved M200.8 ICP-MS mg/L 0.002U las0.0004 03/27/14 16:241
Antimony, total M200.8 ICP-MS mg/L 0.002U pmc0.0004 03/28/14 1:221
Arsenic, dissolved M200.8 ICP-MS 0.0710 mg/L 0.001 las0.0002 03/27/14 16:241
Arsenic, total M200.8 ICP-MS 0.0589 mg/L 0.001 pmc0.0002 03/28/14 1:221
Barium, dissolved M200.7 ICP mg/L 0.02U aeb0.003 03/21/14 12:361
Barium, total M200.7 ICP mg/L 0.02U jjc0.003 03/26/14 11:051
Beryllium, dissolved M200.8 ICP-MS mg/L 0.0003U las0.00005 03/27/14 16:241
Beryllium, total M200.8 ICP-MS mg/L 0.0003U pmc0.00005 03/28/14 1:221
Bismuth, dissolved M200.7 ICP mg/L 0.2U aeb0.04* 03/21/14 12:361
Bismuth, total M200.7 ICP mg/L 0.2U jjc0.04* 03/26/14 11:051
Boron, dissolved M200.7 ICP 0.11 mg/L 0.05 aeb0.01 03/21/14 12:361
Boron, total M200.7 ICP 0.10 mg/L 0.05 jjc0.01 03/26/14 11:051
Cadmium, dissolved M200.8 ICP-MS mg/L 0.0005U las0.0001 03/27/14 16:241
Cadmium, total M200.8 ICP-MS mg/L 0.0005U pmc0.0001 03/28/14 1:221
Calcium, dissolved M200.7 ICP 11.4 mg/L 0.5 aeb0.1 03/21/14 12:361
Calcium, total M200.7 ICP 11.7 mg/L 0.5 jjc0.1 03/26/14 11:051
Chromium, dissolved M200.8 ICP-MS mg/L 0.002U las0.0005 03/27/14 16:241
Chromium, total M200.8 ICP-MS mg/L 0.002U pmc0.0005 03/28/14 1:221
Cobalt, dissolved M200.8 ICP-MS 0.00009 mg/L 0.0003B las0.00005 03/27/14 16:241
Cobalt, total M200.8 ICP-MS mg/L 0.0003U pmc0.00005 03/28/14 1:221
Copper, dissolved M200.8 ICP-MS mg/L 0.003U las0.0005 03/27/14 16:241
Copper, total M200.8 ICP-MS mg/L 0.003U pmc0.0005 03/28/14 1:221
Gallium, dissolved M200.7 ICP mg/L 0.5U aeb0.1* 03/21/14 12:361
Gallium, total M200.7 ICP mg/L 0.5U jjc0.1* 03/26/14 11:051
Iron, dissolved M200.7 ICP 0.06 mg/L 0.05 aeb0.02 03/21/14 12:361
Iron, total M200.7 ICP 0.04 mg/L 0.05B jjc0.02 03/26/14 11:051
Lead, dissolved M200.8 ICP-MS mg/L 0.0005U las0.0001 03/27/14 16:241
Lead, total M200.8 ICP-MS mg/L 0.0005U pmc0.0001 03/28/14 1:221
Lithium, dissolved M200.7 ICP 0.154 mg/L 0.04 aeb0.008 03/21/14 12:361
Lithium, total M200.7 ICP 0.156 mg/L 0.04 jjc0.008 03/26/14 11:051
Magnesium, dissolved M200.7 ICP 0.2 mg/L 1B aeb0.2 03/21/14 12:361
Magnesium, total M200.7 ICP mg/L 1U jjc0.2 03/26/14 11:051
Manganese, dissolved M200.8 ICP-MS 0.0513 mg/L 0.003 las0.0005 03/27/14 16:241
Manganese, total M200.8 ICP-MS 0.0471 mg/L 0.003 pmc0.0005* 03/28/14 1:221
Mercury, dissolved M1631, Atomic Fluorescence 0.5 ng/L 0.5 las0.2 03/27/14 14:111
Mercury, total M1631, Atomic Fluorescence 1.2 ng/L 0.5 las0.2 03/28/14 17:451
Molybdenum, dissolved M200.8 ICP-MS 0.0077 mg/L 0.003 las0.0005 03/27/14 16:241
Molybdenum, total M200.8 ICP-MS 0.0073 mg/L 0.003 pmc0.0005 03/28/14 1:221
Nickel, dissolved M200.8 ICP-MS mg/L 0.003U las0.0006 03/27/14 16:241
Nickel, total M200.8 ICP-MS mg/L 0.003U pmc0.0006 03/28/14 1:221
Potassium, dissolved M200.7 ICP 0.5 mg/L 1B aeb0.2 03/21/14 12:361
REPIN.02.06.05.01 * Please refer to Qualifier Reports for details.
Page 51 of 90L17275-1404011436
ACZ Sample ID: L17275-14
Sample ID: PROD-1
Sample Matrix: Ground Water
SPF Water Engineering
Project ID: Calico 1st Quarter 2014 Sa
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic Analytical
Results
Date Sampled: 03/16/14 13:20
Date Received: 03/19/14
Potassium, total M200.7 ICP 0.4 mg/L 1B jjc0.2 03/26/14 11:051
Scandium, dissolved M200.7 ICP mg/L 0.5U aeb0.1* 03/21/14 12:361
Scandium, total M200.7 ICP mg/L 0.5U jjc0.1* 03/26/14 11:051
Selenium, dissolved M200.8 ICP-MS mg/L 0.0003U las0.0001 03/27/14 16:241
Selenium, total M200.8 ICP-MS mg/L 0.0003U pmc0.0001 03/28/14 1:221
Silver, dissolved M200.8 ICP-MS mg/L 0.0003U las0.00005 03/27/14 16:241
Silver, total M200.8 ICP-MS mg/L 0.0003U pmc0.00005 03/28/14 1:221
Sodium, dissolved M200.7 ICP 129 mg/L 1 aeb0.2 03/21/14 12:361
Sodium, total M200.7 ICP 134 mg/L 1 jjc0.2 03/26/14 11:051
Strontium, dissolved M200.7 ICP 0.038 mg/L 0.03 aeb0.005 03/21/14 12:361
Strontium, total M200.7 ICP 0.039 mg/L 0.03 jjc0.005 03/26/14 11:051
Thallium, dissolved M200.8 ICP-MS mg/L 0.0005U las0.0001 03/27/14 16:241
Thallium, total M200.8 ICP-MS mg/L 0.0005U pmc0.0001 03/28/14 1:221
Tin, dissolved M200.8 ICP-MS mg/L 0.0005U las0.0001* 03/27/14 16:241
Tin, total M200.8 ICP-MS mg/L 0.0005U pmc0.0001* 03/28/14 1:221
Titanium, dissolved M200.7 ICP mg/L 0.03U aeb0.005 03/21/14 12:361
Titanium, total M200.7 ICP mg/L 0.03U jjc0.005 03/26/14 11:051
Uranium, dissolved M200.8 ICP-MS mg/L 0.0005U las0.0001 03/27/14 16:241
Uranium, total M200.8 ICP-MS mg/L 0.0005U pmc0.0001 03/28/14 1:221
Vanadium, dissolved M200.8 ICP-MS mg/L 0.001U las0.0002 03/27/14 16:241
Vanadium, total M200.8 ICP-MS mg/L 0.001U pmc0.0002 03/28/14 1:221
Zinc, dissolved M200.7 ICP mg/L 0.05U aeb0.01 03/21/14 12:361
Zinc, total M200.7 ICP 0.01 mg/L 0.05B jjc0.01 03/26/14 11:051
REPIN.02.06.05.01 * Please refer to Qualifier Reports for details.
Page 52 of 90L17275-1404011436
ACZ Sample ID: L17275-14
Sample ID: PROD-1
Sample Matrix: Ground Water
SPF Water Engineering
Project ID: Calico 1st Quarter 2014 Sa
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic Analytical
Results
Date Sampled: 03/16/14 13:20
Date Received: 03/19/14
Parameter EPA Method Result Units MDLQual AnalystDatePQL
Wet Chemistry
XQDilution
Alkalinity as CaCO3 SM2320B - Titration
Bicarbonate as CaCO3
162 mg/L 20 abd2 03/24/14 0:001
Carbonate as CaCO3 6 mg/L 20B abd2 03/24/14 0:001
Hydroxide as CaCO3 mg/L 20U abd2 03/24/14 0:001
Total Alkalinity 168 mg/L 20 abd2 03/24/14 0:001
Chloride M300.0 - Ion Chromatography 22.2 mg/L 2.5 tcd0.5 03/26/14 1:451
Conductivity @25C SM2510B 625 umhos/cm 10 abd1 03/24/14 19:011
Cyanide, total M335.4 - Colorimetric w/ distillation mg/L 0.01U bsu0.003* 03/24/14 18:260.5
Cyanide, WAD SM4500-CN I-Colorimetric w/ distillation
mg/L 0.01U mpb0.003* 03/27/14 13:470.5
Fluoride M300.0 - Ion Chromatography 1.07 mg/L 0.5 tcd0.1* 03/26/14 1:451
Hardness as CaCO3 SM2340B - Calculation 29 mg/L 7 calc1 04/01/14 12:26
Nitrate/Nitrite as N M353.2 - H2SO4 preserved mg/L 0.1U pjb0.02 03/27/14 23:541
Nitrogen, ammonia M350.1 - Automated Phenate 0.06 mg/L 0.5B tcd0.05* 03/27/14 13:181
pH (lab) SM4500H+ B
pH 8.4 units 0.1H abd0.1 03/24/14 0:001
pH measured at 21 C 0.1 abd0.1 03/24/14 0:001
Phosphorus, total M365.1 - Auto Ascorbic Acid (digest)
0.04 mg/L 0.05B pjb0.01* 03/28/14 22:051
Residue, Filterable (TDS) @180C
SM2540C 380 mg/L 20 enb10 03/21/14 16:251
Residue, Non-Filterable (TSS) @105C
SM2540D mg/L 20U dcw5* 03/22/14 11:391
Sulfate M300.0 - Ion Chromatography 80.6 mg/L 2.5 tcd0.5 03/26/14 1:451
REPIN.02.06.05.01 * Please refer to Qualifier Reports for details.
Page 53 of 90L17275-1404011436
ACZ Sample ID: L17275-15
Sample ID: MERC. TRANSFER/TRIP BLANK
Sample Matrix: Ground Water
SPF Water Engineering
Project ID: Calico 1st Quarter 2014 Sa
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic Analytical
Results
Date Sampled: 03/17/14 12:45
Date Received: 03/19/14
Parameter EPA Method Result Units MDLQual AnalystDatePQL
Metals Analysis
XQDilution
Mercury, dissolved M1631, Atomic Fluorescence ng/L 0.5U las0.2 03/27/14 14:161
Mercury, total M1631, Atomic Fluorescence ng/L 0.5U las0.2 03/28/14 17:501
REPIN.02.06.05.01
Page 54 of 90L17275-1404011436
ACZ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Report Header Explanations
Batch A distinct set of samples analyzed at a specific time
Found Value of the QC Type of interest
Limit Upper limit for RPD, in %.
Lower Lower Recovery Limit, in % (except for LCSS, mg/Kg)
MDL Method Detection Limit. Same as Minimum Reporting Limit. Allows for instrument and annual fluctuations.
PCN/SCN A number assigned to reagents/standards to trace to the manufacturer's certificate of analysis
PQL Practical Quantitation Limit, typically 5 times the MDL.
QC True Value of the Control Sample or the amount added to the Spike
Rec Recovered amount of the true value or spike added, in % (except for LCSS, mg/Kg)
RPD Relative Percent Difference, calculation used for Duplicate QC Types
Upper Upper Recovery Limit, in % (except for LCSS, mg/Kg)
Sample Value of the Sample of interest
QC Sample Types
AS Analytical Spike (Post Digestion) LCSWD Laboratory Control Sample - Water Duplicate
ASD Analytical Spike (Post Digestion) Duplicate LFB Laboratory Fortified Blank
CCB Continuing Calibration Blank LFM Laboratory Fortified Matrix
CCV Continuing Calibration Verification standard LFMD Laboratory Fortified Matrix Duplicate
DUP Sample Duplicate LRB Laboratory Reagent Blank
ICB Initial Calibration Blank MS Matrix Spike
ICV Initial Calibration Verification standard MSD Matrix Spike Duplicate
ICSAB Inter-element Correction Standard - A plus B solutions PBS Prep Blank - Soil
LCSS Laboratory Control Sample - Soil PBW Prep Blank - Water
LCSSD Laboratory Control Sample - Soil Duplicate PQV Practical Quantitation Verification standard
LCSW Laboratory Control Sample - Water SDL Serial Dilution
QC Sample Type Explanations
Blanks Verifies that there is no or minimal contamination in the prep method or calibration procedure.
Control Samples Verifies the accuracy of the method, including the prep procedure.
Duplicates Verifies the precision of the instrument and/or method.
Spikes/Fortified Matrix Determines sample matrix interferences, if any.
Standard Verifies the validity of the calibration.
ACZ Qualifiers (Qual)
B Analyte concentration detected at a value between MDL and PQL. The associated value is an estimated quantity.
H Analysis exceeded method hold time. pH is a field test with an immediate hold time.
L Target analyte response was below the laboratory defined negative threshold.
U The material was analyzed for, but was not detected above the level of the associated value.
The associated value is either the sample quantitation limit or the sample detection limit.
Method References
(1) EPA 600/4-83-020. Methods for Chemical Analysis of Water and Wastes, March 1983.
(2) EPA 600/R-93-100. Methods for the Determination of Inorganic Substances in Environmental Samples, August 1993.
(3) EPA 600/R-94-111. Methods for the Determination of Metals in Environmental Samples - Supplement I, May 1994.
(4) EPA SW-846. Test Methods for Evaluating Solid Waste.
(5) Standard Methods for the Examination of Water and Wastewater.
Comments
(1) QC results calculated from raw data. Results may vary slightly if the rounded values are used in the calculations.
(2) Soil, Sludge, and Plant matrices for Inorganic analyses are reported on a dry weight basis.
(3) Animal matrices for Inorganic analyses are reported on an "as received" basis.
(4) An asterisk in the "XQ" column indicates there is an extended qualifier and/or certification qualifier
associated with the result.
(5) If the MDL equals the PQL or the MDL column is omitted, the PQL is the reporting limit.
For a complete list of ACZ's Extended Qualifiers, please click: http://www.acz.com/public/extquallist.pdf
REP001.09.12.01
Inorganic
Reference
Page 55 of 90L17275-1404011436
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic QC
Summary
ACZ Project ID: L17275SPF Water Engineering
Alkalinity as CaCO3 SM2320B - Titration
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361080
WG361080PBW1 03/24/14 13:06PBW 5.8 -20 20mg/L
WG361080LCSW3 03/24/14 13:25 98.2LCSW WC140313- 805.1 90 110mg/L820.0001
WG361080LCSW6 03/24/14 16:46 101.4LCSW WC140313- 831.4 90 110mg/L820.0001
WG361080PBW2 03/24/14 16:55PBW 2.6 -20 20mg/L
L17275-11DUP 03/24/14 18:37 112DUP 123.6 9.8mg/L 20
L17282-01DUP 03/24/14 20:12 207DUP 205.7 0.6mg/L 20
WG361080LCSW9 03/24/14 20:32 102.2LCSW WC140313- 838.2 90 110mg/L820.0001
WG361080PBW3 03/24/14 20:41PBW 2.8 -20 20mg/L
WG361080LCSW12 03/25/14 0:28 103LCSW WC140313- 844.6 90 110mg/L820.0001
WG361080PBW4 03/25/14 0:38PBW 2.5 -20 20mg/L
WG361080LCSW15 03/25/14 3:51 103.7LCSW WC140313- 850.4 90 110mg/L820.0001
Aluminum, dissolved M200.7 ICP
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG360973
WG360973ICV 03/21/14 11:24 97.1ICV II140220-1 1.941 95 105mg/L2
WG360973ICB 03/21/14 11:30ICB U -0.09 0.09mg/L
WG360973LFB 03/21/14 11:43 102.1LFB II140317-2 1.022 85 115mg/L1.0011
L17261-01AS 03/21/14 11:49 U 106AS II140317-2 2.122 85 115mg/L2.0022
L17261-01ASD 03/21/14 11:52 U 107.7ASD II140317-2 2.156 1.5985 115mg/L 202.0022
L17332-01AS 03/21/14 13:01 U 101.4AS II140317-2 1.015 85 115mg/L1.0011
L17332-01ASD 03/21/14 13:04 U 106.2ASD II140317-2 1.063 4.6285 115mg/L 201.0011
Aluminum, total M200.7 ICP
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361188
WG361188ICV 03/26/14 9:50 94.8ICV II140228-1 1.896 95 105mg/L2
WG361188ICB 03/26/14 9:56ICB U -0.09 0.09mg/L
WG361129LRB 03/26/14 10:09LRB U -0.066 0.066mg/L
WG361129LFB 03/26/14 10:12 98.9LFB II140317-2 .99 85 115mg/L1.0011
L17275-01LFM 03/26/14 10:18 U 100.7LFM II140317-2 1.008 70 130mg/L1.0011
L17275-01LFMD 03/26/14 10:21 U 100.2LFMD II140317-2 1.003 0.570 130mg/L 201.0011
L17304-01LFM 03/26/14 11:24 U 97.3LFM II140317-2 .974 70 130mg/L1.0011
L17304-01LFMD 03/26/14 11:27 U 98.7LFMD II140317-2 .988 1.4370 130mg/L 201.0011
Antimony, dissolved M200.8 ICP-MS
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361239
WG361239ICV 03/27/14 15:22 106.5ICV MS140218-2 .02134 90 110mg/L.02004
WG361239ICB 03/27/14 15:25ICB U -0.0012 0.0012mg/L
WG361239LFB 03/27/14 15:29 99.6LFB MS140320-2 .00996 85 115mg/L.01
L17275-05AS 03/27/14 15:49 U 109.9AS MS140320-2 .01099 70 130mg/L.01
L17275-05ASD 03/27/14 15:53 U 107.8ASD MS140320-2 .01078 1.9370 130mg/L 20.01
L17320-01AS 03/27/14 16:37 U 101.9AS MS140320-2 .01019 70 130mg/L.01
L17320-01ASD 03/27/14 16:47 U 103.9ASD MS140320-2 .01039 1.9470 130mg/L 20.01
Page 56 of 90L17275-1404011436
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic QC
Summary
ACZ Project ID: L17275SPF Water Engineering
Antimony, total M200.8 ICP-MS
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361380
WG361380ICV 03/28/14 0:07 102.2ICV MS140218-2 .02049 90 110mg/L.02004
WG361380ICB 03/28/14 0:11ICB U -0.0012 0.0012mg/L
WG361214LRB 03/28/14 0:14LRB U -0.00088 0.00088mg/L
WG361214LFB 03/28/14 0:18 108.5LFB MS140320-2 .01085 85 115mg/L.01
L17275-08LFM 03/28/14 0:58 U 104.1LFM MS140320-2 .01041 70 130mg/L.01
L17275-08LFMD 03/28/14 1:02 U 102.9LFMD MS140320-2 .01029 1.1670 130mg/L 20.01
L17321-02LFM 03/28/14 1:43 U 109.5LFM MS140320-2 .01095 70 130mg/L.01
L17321-02LFMD 03/28/14 1:46 U 107.5LFMD MS140320-2 .01075 1.8470 130mg/L 20.01
Arsenic, dissolved M200.8 ICP-MS
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361239
WG361239ICV 03/27/14 15:22 105.1ICV MS140218-2 .05254 90 110mg/L.05
WG361239ICB 03/27/14 15:25ICB U -0.0006 0.0006mg/L
WG361239LFB 03/27/14 15:29 98.5LFB MS140320-2 .04934 85 115mg/L.0501
L17275-05AS 03/27/14 15:49 .0299 128.2AS MS140320-2 .09414 70 130mg/L.0501
L17275-05ASD 03/27/14 15:53 .0299 128.6ASD MS140320-2 .09433 0.270 130mg/L 20.0501
L17320-01AS 03/27/14 16:37 .0003 122AS MS140320-2 .06141 70 130mg/L.0501
L17320-01ASD 03/27/14 16:47 .0003 121.8ASD MS140320-2 .06132 0.1570 130mg/L 20.0501
Arsenic, total M200.8 ICP-MS
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361380
WG361380ICV 03/28/14 0:07 102.8ICV MS140218-2 .05142 90 110mg/L.05
WG361380ICB 03/28/14 0:11ICB U -0.0006 0.0006mg/L
WG361214LRB 03/28/14 0:14LRB U -0.00044 0.00044mg/L
WG361214LFB 03/28/14 0:18 112.2LFB MS140320-2 .05622 85 115mg/L.0501
L17275-08LFM 03/28/14 0:58 .0444 101.8LFM MS140320-2 .0954 70 130mg/L.0501
L17275-08LFMD 03/28/14 1:02 .0444 105.2LFMD MS140320-2 .09711 1.7870 130mg/L 20.0501
L17321-02LFM 03/28/14 1:43 .0011 112.4LFM MS140320-2 .0574 70 130mg/L.0501
L17321-02LFMD 03/28/14 1:46 .0011 114.9LFMD MS140320-2 .05866 2.1770 130mg/L 20.0501
Barium, dissolved M200.7 ICP
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG360973
WG360973ICV 03/21/14 11:24 97.3ICV II140220-1 1.9458 95 105mg/L2
WG360973ICB 03/21/14 11:30ICB .0031 -0.009 0.009mg/L
WG360973LFB 03/21/14 11:43 97.4LFB II140317-2 .4869 85 115mg/L.5
L17261-01AS 03/21/14 11:49 .014 98AS II140317-2 .9942 85 115mg/L1
L17261-01ASD 03/21/14 11:52 .014 98.3ASD II140317-2 .9968 0.2685 115mg/L 201
L17332-01AS 03/21/14 13:01 .023 96.9AS II140317-2 .5073 85 115mg/L.5
L17332-01ASD 03/21/14 13:04 .023 99.3ASD II140317-2 .5193 2.3485 115mg/L 20.5
Page 57 of 90L17275-1404011436
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic QC
Summary
ACZ Project ID: L17275SPF Water Engineering
Barium, total M200.7 ICP
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361188
WG361188ICV 03/26/14 9:50 96.5ICV II140228-1 1.9302 95 105mg/L2
WG361188ICB 03/26/14 9:56ICB .0031 -0.009 0.009mg/L
WG361129LRB 03/26/14 10:09LRB U -0.0066 0.0066mg/L
WG361129LFB 03/26/14 10:12 99.4LFB II140317-2 .4971 85 115mg/L.5
L17275-01LFM 03/26/14 10:18 .004 99.5LFM II140317-2 .5014 70 130mg/L.5
L17275-01LFMD 03/26/14 10:21 .004 99.3LFMD II140317-2 .5004 0.270 130mg/L 20.5
L17304-01LFM 03/26/14 11:24 .118 98.3LFM II140317-2 .6093 70 130mg/L.5
L17304-01LFMD 03/26/14 11:27 .118 100.1LFMD II140317-2 .6186 1.5170 130mg/L 20.5
Beryllium, dissolved M200.8 ICP-MS
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361239
WG361239ICV 03/27/14 15:22 97ICV MS140218-2 .04848 90 110mg/L.05
WG361239ICB 03/27/14 15:25ICB U -0.00015 0.00015mg/L
WG361239LFB 03/27/14 15:29 94.4LFB MS140320-2 .04726 85 115mg/L.05005
L17275-05AS 03/27/14 15:49 U 109.5AS MS140320-2 .0548 70 130mg/L.05005
L17275-05ASD 03/27/14 15:53 U 106.2ASD MS140320-2 .05317 3.0270 130mg/L 20.05005
L17320-01AS 03/27/14 16:37 U 111.8AS MS140320-2 .05598 70 130mg/L.05005
L17320-01ASD 03/27/14 16:47 U 107ASD MS140320-2 .05353 4.4770 130mg/L 20.05005
Beryllium, total M200.8 ICP-MS
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361380
WG361380ICV 03/28/14 0:07 95.4ICV MS140218-2 .04771 90 110mg/L.05
WG361380ICB 03/28/14 0:11ICB U -0.00015 0.00015mg/L
WG361214LRB 03/28/14 0:14LRB U -0.00011 0.00011mg/L
WG361214LFB 03/28/14 0:18 104.1LFB MS140320-2 .05211 85 115mg/L.05005
L17275-08LFM 03/28/14 0:58 U 103.1LFM MS140320-2 .05159 70 130mg/L.05005
L17275-08LFMD 03/28/14 1:02 U 102.5LFMD MS140320-2 .05132 0.5270 130mg/L 20.05005
L17321-02LFM 03/28/14 1:43 .0057 96.2LFM MS140320-2 .05386 70 130mg/L.05005
L17321-02LFMD 03/28/14 1:46 .0057 94.8LFMD MS140320-2 .05316 1.3170 130mg/L 20.05005
Bismuth, dissolved M200.7 ICP
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG360973
WG360973ICV 03/21/14 11:24 97.9ICV II140220-1 1.957 95 105mg/L2
WG360973ICB 03/21/14 11:30ICB U -0.12 0.12mg/L
WG360973LFB 03/21/14 11:43 99.6LFB II140317-2 .995 85 115mg/L.999
L17261-01AS 03/21/14 11:49 U 102.3AS II140317-2 2.044 85 115mg/L1.998
L17261-01ASD 03/21/14 11:52 U 103.7ASD II140317-2 2.072 1.3685 115mg/L 201.998
L17332-01AS 03/21/14 13:01 U 98.8AS II140317-2 .987 85 115mg/L.999
L17332-01ASD 03/21/14 13:04 U 105ASD II140317-2 1.049 6.0985 115mg/L 20.999
Page 58 of 90L17275-1404011436
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic QC
Summary
ACZ Project ID: L17275SPF Water Engineering
Bismuth, total M200.7 ICP
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361188
WG361188ICV 03/26/14 9:50 96.7ICV II140228-1 1.934 95 105mg/L2
WG361188ICB 03/26/14 9:56ICB U -0.12 0.12mg/L
WG361129LRB 03/26/14 10:09LRB U -0.088 0.088mg/L
WG361129LFB 03/26/14 10:12 107.6LFB II140317-2 1.075 85 115mg/L.999
L17275-01LFM 03/26/14 10:18 U 104.1LFM II140317-2 1.04 70 130mg/L.999
L17275-01LFMD 03/26/14 10:21 U 102.1LFMD II140317-2 1.02 1.9470 130mg/L 20.999
L17304-01LFM 03/26/14 11:24 .05 102.1LFM II140317-2 1.07 70 130mg/L.999
L17304-01LFMD 03/26/14 11:27 .05 102.8LFMD II140317-2 1.077 0.6570 130mg/L 20.999
Boron, dissolved M200.7 ICP
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG360973
WG360973ICV 03/21/14 11:24 97.1ICV II140220-1 1.941 95 105mg/L2
WG360973ICB 03/21/14 11:30ICB U -0.03 0.03mg/L
WG360973LFB 03/21/14 11:43 99.9LFB II140317-2 .5 85 115mg/L.5005
L17261-01AS 03/21/14 11:49 .11 99.7AS II140317-2 1.108 85 115mg/L1.001
L17261-01ASD 03/21/14 11:52 .11 100.4ASD II140317-2 1.115 0.6385 115mg/L 201.001
L17332-01AS 03/21/14 13:01 .11 97.1AS II140317-2 .596 85 115mg/L.5005
L17332-01ASD 03/21/14 13:04 .11 101.3ASD II140317-2 .617 3.4685 115mg/L 20.5005
Boron, total M200.7 ICP
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361188
WG361188ICV 03/26/14 9:50 95.7ICV II140228-1 1.914 95 105mg/L2
WG361188ICB 03/26/14 9:56ICB .013 -0.03 0.03mg/L
WG361129LRB 03/26/14 10:09LRB .012 -0.022 0.022mg/L
WG361129LFB 03/26/14 10:12 97.5LFB II140317-2 .488 85 115mg/L.5005
L17275-01LFM 03/26/14 10:18 .06 95.3LFM II140317-2 .537 70 130mg/L.5005
L17275-01LFMD 03/26/14 10:21 .06 96.3LFMD II140317-2 .542 0.9370 130mg/L 20.5005
L17304-01LFM 03/26/14 11:24 .01 92.1LFM II140317-2 .471 70 130mg/L.5005
L17304-01LFMD 03/26/14 11:27 .01 93.7LFMD II140317-2 .479 1.6870 130mg/L 20.5005
Cadmium, dissolved M200.8 ICP-MS
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361239
WG361239ICV 03/27/14 15:22 96.3ICV MS140218-2 .04814 90 110mg/L.05
WG361239ICB 03/27/14 15:25ICB U -0.0003 0.0003mg/L
WG361239LFB 03/27/14 15:29 94LFB MS140320-2 .04708 85 115mg/L.0501
L17275-05AS 03/27/14 15:49 U 103.8AS MS140320-2 .05202 70 130mg/L.0501
L17275-05ASD 03/27/14 15:53 U 102.6ASD MS140320-2 .05138 1.2470 130mg/L 20.0501
L17320-01AS 03/27/14 16:37 U 101.1AS MS140320-2 .05063 70 130mg/L.0501
L17320-01ASD 03/27/14 16:47 U 101.4ASD MS140320-2 .05079 0.3270 130mg/L 20.0501
Page 59 of 90L17275-1404011436
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic QC
Summary
ACZ Project ID: L17275SPF Water Engineering
Cadmium, total M200.8 ICP-MS
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361380
WG361380ICV 03/28/14 0:07 97.7ICV MS140218-2 .04885 90 110mg/L.05
WG361380ICB 03/28/14 0:11ICB U -0.0003 0.0003mg/L
WG361214LRB 03/28/14 0:14LRB U -0.00022 0.00022mg/L
WG361214LFB 03/28/14 0:18 104.5LFB MS140320-2 .05237 85 115mg/L.0501
L17275-08LFM 03/28/14 0:58 U 98.7LFM MS140320-2 .04944 70 130mg/L.0501
L17275-08LFMD 03/28/14 1:02 U 98.1LFMD MS140320-2 .04914 0.6170 130mg/L 20.0501
L17321-02LFM 03/28/14 1:43 .0022 98.6LFM MS140320-2 .05158 70 130mg/L.0501
L17321-02LFMD 03/28/14 1:46 .0022 98.9LFMD MS140320-2 .05176 0.3570 130mg/L 20.0501
Calcium, dissolved M200.7 ICP
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG360973
WG360973ICV 03/21/14 11:24 97.4ICV II140220-1 97.43 95 105mg/L100
WG360973ICB 03/21/14 11:30ICB U -0.3 0.3mg/L
WG360973LFB 03/21/14 11:43 101.7LFB II140317-2 69.16 85 115mg/L67.98099
L17261-01AS M303/21/14 11:49 959 69.9AS II140317-2 1054 85 115mg/L135.96198
L17261-01ASD M303/21/14 11:52 959 81.8ASD II140317-2 1070.2 1.5385 115mg/L 20135.96198
L17332-01AS 03/21/14 13:01 182 89.9AS II140317-2 243.1 85 115mg/L67.98099
L17332-01ASD 03/21/14 13:04 182 101.6ASD II140317-2 251.1 3.2485 115mg/L 2067.98099
Calcium, total M200.7 ICP
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361188
WG361188ICV 03/26/14 9:50 98.3ICV II140228-1 98.32 95 105mg/L100
WG361188ICB 03/26/14 9:56ICB U -0.3 0.3mg/L
WG361129LRB 03/26/14 10:09LRB U -0.22 0.22mg/L
WG361129LFB 03/26/14 10:12 103.7LFB II140317-2 70.5 85 115mg/L67.98099
L17275-01LFM 03/26/14 10:18 46 103.7LFM II140317-2 116.5 70 130mg/L67.98099
L17275-01LFMD 03/26/14 10:21 46 103.6LFMD II140317-2 116.4 0.0970 130mg/L 2067.98099
L17304-01LFM 03/26/14 11:24 29.6 102.1LFM II140317-2 99.02 70 130mg/L67.98099
L17304-01LFMD 03/26/14 11:27 29.6 104.9LFMD II140317-2 100.9 1.8870 130mg/L 2067.98099
Chloride M300.0 - Ion Chromatography
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG360290
WG360290ICV 03/06/14 13:49 101.6ICV WI140226-1 20.3 90 110mg/L19.98
WG360290ICB 03/06/14 14:07ICB U -1.5 1.5mg/L
WG361148
WG361148LFB1 03/25/14 12:54 101.3LFB WI140306-2 30.4 90 110mg/L30
L17232-03DUP RA03/25/14 17:41 1.7DUP 1.72 1.2mg/L 20
L17232-04AS 03/25/14 18:17 1.48 101.4AS WI140306-2 31.9 90 110mg/L30
WG361148LFB2 03/25/14 21:34 101.7LFB WI140306-2 30.5 90 110mg/L30
L17275-04DUP 03/25/14 22:10 16.9DUP 16.9 0mg/L 20
L17275-05AS 03/25/14 23:21 16.9 100AS WI140306-2 46.9 90 110mg/L30
Page 60 of 90L17275-1404011436
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic QC
Summary
ACZ Project ID: L17275SPF Water Engineering
Chromium, dissolved M200.8 ICP-MS
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361239
WG361239ICV 03/27/14 15:22 98.5ICV MS140218-2 .04923 90 110mg/L.05
WG361239ICB 03/27/14 15:25ICB U -0.0015 0.0015mg/L
WG361239LFB 03/27/14 15:29 96.9LFB MS140320-2 .04848 85 115mg/L.05005
L17275-05AS 03/27/14 15:49 U 108.1AS MS140320-2 .05412 70 130mg/L.05005
L17275-05ASD 03/27/14 15:53 U 108.5ASD MS140320-2 .05429 0.3170 130mg/L 20.05005
L17320-01AS 03/27/14 16:37 U 105.8AS MS140320-2 .05297 70 130mg/L.05005
L17320-01ASD 03/27/14 16:47 U 105.5ASD MS140320-2 .05281 0.370 130mg/L 20.05005
Chromium, total M200.8 ICP-MS
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361380
WG361380ICV 03/28/14 0:07 99ICV MS140218-2 .04952 90 110mg/L.05
WG361380ICB 03/28/14 0:11ICB U -0.0015 0.0015mg/L
WG361214LRB 03/28/14 0:14LRB U -0.0011 0.0011mg/L
WG361214LFB 03/28/14 0:18 99.5LFB MS140320-2 .04979 85 115mg/L.05005
L17275-08LFM 03/28/14 0:58 .0007 94.7LFM MS140320-2 .04808 70 130mg/L.05005
L17275-08LFMD 03/28/14 1:02 .0007 96.3LFMD MS140320-2 .04891 1.7170 130mg/L 20.05005
L17321-02LFM 03/28/14 1:43 .009 79.7LFM MS140320-2 .0489 70 130mg/L.05005
L17321-02LFMD 03/28/14 1:46 .009 82.1LFMD MS140320-2 .0501 2.4270 130mg/L 20.05005
Cobalt, dissolved M200.8 ICP-MS
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361239
WG361239ICV 03/27/14 15:22 98.1ICV MS140218-2 .04904 90 110mg/L.05
WG361239ICB 03/27/14 15:25ICB U -0.00015 0.00015mg/L
WG361239LFB 03/27/14 15:29 98LFB MS140320-2 .04906 85 115mg/L.05005
L17275-05AS 03/27/14 15:49 .00016 112.8AS MS140320-2 .05662 70 130mg/L.05005
L17275-05ASD 03/27/14 15:53 .00016 109.9ASD MS140320-2 .05515 2.6370 130mg/L 20.05005
L17320-01AS 03/27/14 16:37 .00055 114.5AS MS140320-2 .05785 70 130mg/L.05005
L17320-01ASD 03/27/14 16:47 .00055 111.8ASD MS140320-2 .05653 2.3170 130mg/L 20.05005
Cobalt, total M200.8 ICP-MS
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361380
WG361380ICV 03/28/14 0:07 96.7ICV MS140218-2 .04833 90 110mg/L.05
WG361380ICB 03/28/14 0:11ICB U -0.00015 0.00015mg/L
WG361214LRB 03/28/14 0:14LRB U -0.00011 0.00011mg/L
WG361214LFB 03/28/14 0:18 100.5LFB MS140320-2 .05028 85 115mg/L.05005
L17275-08LFM 03/28/14 0:58 .0001 100.6LFM MS140320-2 .05043 70 130mg/L.05005
L17275-08LFMD 03/28/14 1:02 .0001 99.7LFMD MS140320-2 .05001 0.8470 130mg/L 20.05005
L17321-02LFM 03/28/14 1:43 .306 98.7LFM MS140320-2 .3554 70 130mg/L.05005
L17321-02LFMD 03/28/14 1:46 .306 95.9LFMD MS140320-2 .354 0.3970 130mg/L 20.05005
Page 61 of 90L17275-1404011436
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic QC
Summary
ACZ Project ID: L17275SPF Water Engineering
Conductivity @25C SM2510B
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361080
WG361080LCSW2 03/24/14 13:11 102.2LCSW PCN43577 1439.5 90 110umhos/cm1408.8
WG361080LCSW5 03/24/14 16:31 101.1LCSW PCN43577 1424.2 90 110umhos/cm1408.8
L17275-11DUP 03/24/14 18:37 352DUP 352 0umhos/cm 20
L17282-01DUP 03/24/14 20:12 583DUP 585 0.3umhos/cm 20
WG361080LCSW8 03/24/14 20:17 100.4LCSW PCN43577 1415 90 110umhos/cm1408.8
WG361080LCSW11 03/25/14 0:13 99.6LCSW PCN43577 1402.8 90 110umhos/cm1408.8
WG361080LCSW14 03/25/14 3:36 99LCSW PCN43577 1394.7 90 110umhos/cm1408.8
Copper, dissolved M200.8 ICP-MS
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361239
WG361239ICV 03/27/14 15:22 98.8ICV MS140218-2 .04939 90 110mg/L.05
WG361239ICB 03/27/14 15:25ICB U -0.0015 0.0015mg/L
WG361239LFB 03/27/14 15:29 96.8LFB MS140320-2 .04843 85 115mg/L.05005
L17275-05AS 03/27/14 15:49 U 105.3AS MS140320-2 .05268 70 130mg/L.05005
L17275-05ASD 03/27/14 15:53 U 104.2ASD MS140320-2 .05215 1.0170 130mg/L 20.05005
L17320-01AS 03/27/14 16:37 .0008 99.3AS MS140320-2 .05052 70 130mg/L.05005
L17320-01ASD 03/27/14 16:47 .0008 99ASD MS140320-2 .05035 0.3470 130mg/L 20.05005
Copper, total M200.8 ICP-MS
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361380
WG361380ICV 03/28/14 0:07 97.5ICV MS140218-2 .04876 90 110mg/L.05
WG361380ICB 03/28/14 0:11ICB U -0.0015 0.0015mg/L
WG361214LRB 03/28/14 0:14LRB U -0.0011 0.0011mg/L
WG361214LFB 03/28/14 0:18 98.5LFB MS140320-2 .04928 85 115mg/L.05005
L17275-08LFM 03/28/14 0:58 U 91.3LFM MS140320-2 .04568 70 130mg/L.05005
L17275-08LFMD 03/28/14 1:02 U 91.5LFMD MS140320-2 .0458 0.2670 130mg/L 20.05005
L17321-02LFM 03/28/14 1:43 .003 92.5LFM MS140320-2 .0493 70 130mg/L.05005
L17321-02LFMD 03/28/14 1:46 .003 94.5LFMD MS140320-2 .0503 2.0170 130mg/L 20.05005
Cyanide, total M335.4 - Colorimetric w/ distillation
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361114
WG361114ICV 03/24/14 18:07 97.8ICV WI140322-7 .2934 90 110mg/L.3
WG361114ICB 03/24/14 18:08ICB U -0.003 0.003mg/L
WG361087LRB 03/24/14 18:09LRB U -0.003 0.003mg/L
WG361087LFB 03/24/14 18:09 100.8LFB WI140322-4 .2015 90 110mg/L.2
L17275-01DUP RA03/24/14 18:11 UDUP U 0mg/L 20
L17275-02LFM 03/24/14 18:13 U 101.7LFM WI140322-4 .2033 90 110mg/L.2
L17275-12DUP RA03/24/14 18:23 UDUP U 0mg/L 20
L17275-13LFM 03/24/14 18:25 U 105.1LFM WI140322-4 .2102 90 110mg/L.2
Page 62 of 90L17275-1404011436
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic QC
Summary
ACZ Project ID: L17275SPF Water Engineering
Cyanide, WAD SM4500-CN I-Colorimetric w/ distillation
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361346
WG361346ICV 03/27/14 11:49 98.1ICV WI140322-7 .2942 90 110mg/L.3
WG361346ICB 03/27/14 11:50ICB U -0.003 0.003mg/L
WG361357
WG361218LRB 03/27/14 13:28LRB U -0.003 0.003mg/L
WG361218LFB 03/27/14 13:29 95.1LFB WI140322-6 .1902 90 110mg/L.2
L17264-03LFM 03/27/14 13:31 U 95.1LFM WI140322-6 .1901 90 110mg/L.2
L17275-01DUP RA03/27/14 13:33 UDUP U 0mg/L 20
L17275-11LFM 03/27/14 13:43 U 95.2LFM WI140322-6 .1903 90 110mg/L.2
L17275-12DUP RA03/27/14 13:45 UDUP U 0mg/L 20
Fluoride M300.0 - Ion Chromatography
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG360290
WG360290ICV 03/06/14 13:49 103.7ICV WI140226-1 4.17 90 110mg/L4.02
WG360290ICB 03/06/14 14:07ICB U -0.3 0.3mg/L
WG361148
WG361148LFB1 03/25/14 12:54 102LFB WI140306-2 1.53 90 110mg/L1.5
L17232-03DUP RA03/25/14 17:41 UDUP U 0mg/L 20
L17232-04AS 03/25/14 18:17 U 106AS WI140306-2 1.59 90 110mg/L1.5
WG361148LFB2 03/25/14 21:34 102.7LFB WI140306-2 1.54 90 110mg/L1.5
L17275-04DUP RA03/25/14 22:10 .44DUP .45 2.2mg/L 20
L17275-05AS 03/25/14 23:21 .45 103.3AS WI140306-2 2 90 110mg/L1.5
Gallium, dissolved M200.7 ICP
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG360973
WG360973ICV 03/21/14 11:24 98ICV II140220-1 1.96 95 105mg/L2
WG360973ICB 03/21/14 11:30ICB U -0.3 0.3mg/L
WG360973LFB 03/21/14 11:43 97.9LFB II140317-2 .98 85 115mg/L1.001
L17261-01AS 03/21/14 11:49 U 100.4AS II140317-2 2.01 85 115mg/L2.002
L17261-01ASD 03/21/14 11:52 U 103.4ASD II140317-2 2.07 2.9485 115mg/L 202.002
L17332-01AS 03/21/14 13:01 U 98.9AS II140317-2 .99 85 115mg/L1.001
L17332-01ASD 03/21/14 13:04 U 104.9ASD II140317-2 1.05 5.8885 115mg/L 201.001
Gallium, total M200.7 ICP
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361188
WG361188ICV 03/26/14 9:50 96ICV II140228-1 1.92 95 105mg/L2
WG361188ICB 03/26/14 9:56ICB U -0.3 0.3mg/L
WG361129LRB 03/26/14 10:09LRB U -0.22 0.22mg/L
WG361129LFB 03/26/14 10:12 100.9LFB II140317-2 1.01 85 115mg/L1.001
L17275-01LFM 03/26/14 10:18 U 98.9LFM II140317-2 .99 70 130mg/L1.001
L17275-01LFMD 03/26/14 10:21 U 101.9LFMD II140317-2 1.02 2.9970 130mg/L 201.001
L17304-01LFM 03/26/14 11:24 U 99.9LFM II140317-2 1 70 130mg/L1.001
L17304-01LFMD 03/26/14 11:27 U 101.9LFMD II140317-2 1.02 1.9870 130mg/L 201.001
Page 63 of 90L17275-1404011436
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic QC
Summary
ACZ Project ID: L17275SPF Water Engineering
Iron, dissolved M200.7 ICP
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG360973
WG360973ICV 03/21/14 11:24 97.8ICV II140220-1 1.955 95 105mg/L2
WG360973ICB 03/21/14 11:30ICB U -0.06 0.06mg/L
WG360973LFB 03/21/14 11:43 100.9LFB II140317-2 1.01 85 115mg/L1.0014
L17261-01AS 03/21/14 11:49 U 98.3AS II140317-2 1.969 85 115mg/L2.0028
L17261-01ASD 03/21/14 11:52 U 99.1ASD II140317-2 1.985 0.8185 115mg/L 202.0028
L17332-01AS 03/21/14 13:01 2.03 91AS II140317-2 2.931 85 115mg/L1.0014
L17332-01ASD 03/21/14 13:04 2.03 99.3ASD II140317-2 3.014 2.7985 115mg/L 201.0014
Iron, total M200.7 ICP
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361188
WG361188ICV 03/26/14 9:50 97.7ICV II140228-1 1.953 95 105mg/L2
WG361188ICB 03/26/14 9:56ICB U -0.06 0.06mg/L
WG361129LRB 03/26/14 10:09LRB U -0.044 0.044mg/L
WG361129LFB 03/26/14 10:12 102.7LFB II140317-2 1.028 85 115mg/L1.0014
L17275-01LFM 03/26/14 10:18 U 102.7LFM II140317-2 1.028 70 130mg/L1.0014
L17275-01LFMD 03/26/14 10:21 U 102.2LFMD II140317-2 1.023 0.4970 130mg/L 201.0014
L17304-01LFM 03/26/14 11:24 U 100.8LFM II140317-2 1.009 70 130mg/L1.0014
L17304-01LFMD 03/26/14 11:27 U 102.6LFMD II140317-2 1.027 1.7770 130mg/L 201.0014
Lead, dissolved M200.8 ICP-MS
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361239
WG361239ICV 03/27/14 15:22 101.7ICV MS140218-2 .05084 90 110mg/L.05
WG361239ICB 03/27/14 15:25ICB U -0.0003 0.0003mg/L
WG361239LFB 03/27/14 15:29 96.6LFB MS140320-2 .04833 85 115mg/L.05005
L17275-05AS 03/27/14 15:49 U 105.7AS MS140320-2 .05292 70 130mg/L.05005
L17275-05ASD 03/27/14 15:53 U 103.7ASD MS140320-2 .0519 1.9570 130mg/L 20.05005
L17320-01AS 03/27/14 16:37 U 105.3AS MS140320-2 .05271 70 130mg/L.05005
L17320-01ASD 03/27/14 16:47 U 106ASD MS140320-2 .05303 0.6170 130mg/L 20.05005
Lead, total M200.8 ICP-MS
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361380
WG361380ICV 03/28/14 0:07 101.1ICV MS140218-2 .05053 90 110mg/L.05
WG361380ICB 03/28/14 0:11ICB U -0.0003 0.0003mg/L
WG361214LRB 03/28/14 0:14LRB U -0.00022 0.00022mg/L
WG361214LFB 03/28/14 0:18 98.6LFB MS140320-2 .04937 85 115mg/L.05005
L17275-08LFM 03/28/14 0:58 U 101.2LFM MS140320-2 .05063 70 130mg/L.05005
L17275-08LFMD 03/28/14 1:02 U 99.4LFMD MS140320-2 .04976 1.7370 130mg/L 20.05005
L17321-02LFM 03/28/14 1:43 U 99.3LFM MS140320-2 .04968 70 130mg/L.05005
L17321-02LFMD 03/28/14 1:46 U 99.6LFMD MS140320-2 .04986 0.3670 130mg/L 20.05005
Page 64 of 90L17275-1404011436
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic QC
Summary
ACZ Project ID: L17275SPF Water Engineering
Lithium, dissolved M200.7 ICP
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG360973
WG360973ICV 03/21/14 11:24 97.5ICV II140220-1 1.9495 95 105mg/L2
WG360973ICB 03/21/14 11:30ICB U -0.024 0.024mg/L
WG360973LFB 03/21/14 11:43 96.5LFB II140317-2 .9651 85 115mg/L1
L17261-01AS 03/21/14 11:49 .52 97.6AS II140317-2 2.472 85 115mg/L2
L17261-01ASD 03/21/14 11:52 .52 97.9ASD II140317-2 2.478 0.2485 115mg/L 202
L17332-01AS 03/21/14 13:01 .088 96.4AS II140317-2 1.052 85 115mg/L1
L17332-01ASD 03/21/14 13:04 .088 100ASD II140317-2 1.088 3.3685 115mg/L 201
Lithium, total M200.7 ICP
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361188
WG361188ICV 03/26/14 9:50 96ICV II140228-1 1.9192 95 105mg/L2
WG361188ICB 03/26/14 9:56ICB U -0.024 0.024mg/L
WG361129LRB 03/26/14 10:09LRB U -0.0176 0.0176mg/L
WG361129LFB 03/26/14 10:12 96.3LFB II140317-2 .9627 85 115mg/L1
L17275-01LFM 03/26/14 10:18 .021 96.8LFM II140317-2 .989 70 130mg/L1
L17275-01LFMD 03/26/14 10:21 .021 96.1LFMD II140317-2 .9816 0.7570 130mg/L 201
L17304-01LFM 03/26/14 11:24 .011 93.7LFM II140317-2 .9477 70 130mg/L1
L17304-01LFMD 03/26/14 11:27 .011 95.2LFMD II140317-2 .9631 1.6170 130mg/L 201
Magnesium, dissolved M200.7 ICP
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG360973
WG360973ICV 03/21/14 11:24 96ICV II140220-1 95.96 95 105mg/L100
WG360973ICB 03/21/14 11:30ICB U -0.6 0.6mg/L
WG360973LFB 03/21/14 11:43 97.7LFB II140317-2 48.86 85 115mg/L50.00131
L17261-01AS 03/21/14 11:49 162 92.6AS II140317-2 254.6 85 115mg/L100.00262
L17261-01ASD 03/21/14 11:52 162 96.8ASD II140317-2 258.8 1.6485 115mg/L 20100.00262
L17332-01AS 03/21/14 13:01 33.2 93.1AS II140317-2 79.77 85 115mg/L50.00131
L17332-01ASD 03/21/14 13:04 33.2 99.5ASD II140317-2 82.97 3.9385 115mg/L 2050.00131
Magnesium, total M200.7 ICP
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361188
WG361188ICV 03/26/14 9:50 96.3ICV II140228-1 96.26 95 105mg/L100
WG361188ICB 03/26/14 9:56ICB U -0.6 0.6mg/L
WG361129LRB 03/26/14 10:09LRB U -0.44 0.44mg/L
WG361129LFB 03/26/14 10:12 98.9LFB II140317-2 49.46 85 115mg/L50.00131
L17275-01LFM 03/26/14 10:18 9.8 99.1LFM II140317-2 59.37 70 130mg/L50.00131
L17275-01LFMD 03/26/14 10:21 9.8 98.4LFMD II140317-2 59.01 0.6170 130mg/L 2050.00131
L17304-01LFM 03/26/14 11:24 15.6 97LFM II140317-2 64.1 70 130mg/L50.00131
L17304-01LFMD 03/26/14 11:27 15.6 99.2LFMD II140317-2 65.21 1.7270 130mg/L 2050.00131
Page 65 of 90L17275-1404011436
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic QC
Summary
ACZ Project ID: L17275SPF Water Engineering
Manganese, dissolved M200.8 ICP-MS
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361239
WG361239ICV 03/27/14 15:22 102.3ICV MS140218-2 .05113 90 110mg/L.05
WG361239ICB 03/27/14 15:25ICB U -0.0015 0.0015mg/L
WG361239LFB 03/27/14 15:29 99.2LFB MS140320-2 .04971 85 115mg/L.0501
L17275-05AS 03/27/14 15:49 .0032 112.7AS MS140320-2 .05968 70 130mg/L.0501
L17275-05ASD 03/27/14 15:53 .0032 110.7ASD MS140320-2 .05866 1.7270 130mg/L 20.0501
L17320-01AS 03/27/14 16:37 .0114 113.6AS MS140320-2 .06829 70 130mg/L.0501
L17320-01ASD 03/27/14 16:47 .0114 110.9ASD MS140320-2 .06698 1.9470 130mg/L 20.0501
Manganese, total M200.8 ICP-MS
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361380
WG361380ICV 03/28/14 0:07 102.3ICV MS140218-2 .05117 90 110mg/L.05
WG361380ICB 03/28/14 0:11ICB U -0.0015 0.0015mg/L
WG361214LRB 03/28/14 0:14LRB U -0.0011 0.0011mg/L
WG361214LFB 03/28/14 0:18 100.1LFB MS140320-2 .05014 85 115mg/L.0501
L17275-08LFM 03/28/14 0:58 .02 100.3LFM MS140320-2 .07024 70 130mg/L.0501
L17275-08LFMD 03/28/14 1:02 .02 104.5LFMD MS140320-2 .07237 2.9970 130mg/L 20.0501
L17321-02LFM M303/28/14 1:43 106 2275.4LFM MS140320-2 107.14 70 130mg/L.0501
L17321-02LFMD M303/28/14 1:46 106 1477LFMD MS140320-2 106.74 0.3770 130mg/L 20.0501
Mercury, dissolved M1631, Atomic Fluorescence
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361308
WG361308ICV 03/27/14 12:34 101ICV HG140325-4 10.1 79 121ng/L10
WG361308ICB 03/27/14 12:39ICB U -0.5 0.5ng/L
WG361308PQV 03/27/14 12:44 104PQV HG140325-6 .52 70 130ng/L.5
WG361308LFB 03/27/14 12:49 99LFB HG140325-5 1.98 71 125ng/L2
L17275-06MS 03/27/14 13:20 U 108MS HG140325-5 2.16 71 125ng/L2
L17275-06MSD 03/27/14 13:25 U 108MSD HG140325-5 2.16 071 125ng/L 242
WG361308CCV1 03/27/14 13:30 103CCV HG140325-4 10.3 76.5 123.4ng/L10
WG361308CCB1 03/27/14 13:35CCB U -0.5 0.5ng/L
WG361308CCV2 03/27/14 14:21 105CCV HG140325-4 10.5 76.5 123.4ng/L10
WG361308CCB2 03/27/14 14:26CCB U -0.5 0.5ng/L
L17284-02MS 03/27/14 14:41 1 104.9MS HG5XPREP 11.8 71 125ng/L50
L17284-02MSD 03/27/14 14:46 1 102.9MSD HG5XPREP 11.6 1.7171 125ng/L 2450
WG361308CCV3 03/27/14 15:17 104CCV HG140325-4 10.4 76.5 123.4ng/L10
WG361308CCB3 03/27/14 15:22CCB U -0.5 0.5ng/L
Page 66 of 90L17275-1404011436
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic QC
Summary
ACZ Project ID: L17275SPF Water Engineering
Mercury, total M1631, Atomic Fluorescence
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361393
WG361393ICV 03/28/14 15:59 98.7ICV HG140325-4 9.87 79 121ng/L10
WG361393ICB 03/28/14 16:04ICB U -0.5 0.5ng/L
WG361393PQV 03/28/14 16:09 112PQV HG140325-6 .56 70 130ng/L.5
WG361393LFB 03/28/14 16:14 100LFB HG140325-5 2 71 125ng/L2
L17275-02MS 03/28/14 16:29 .5 104MS HG140325-5 2.58 71 125ng/L2
L17275-02MSD 03/28/14 16:34 .5 105.5MSD HG140325-5 2.61 1.1671 125ng/L 242
WG361393CCV1 03/28/14 16:59 106CCV HG140325-4 10.6 76.5 123.4ng/L10
WG361393CCB1 03/28/14 17:04CCB U -0.5 0.5ng/L
WG361393CCV2 03/28/14 17:55 104CCV HG140325-4 10.4 76.5 123.4ng/L10
WG361393CCB2 03/28/14 18:00CCB U -0.5 0.5ng/L
L17348-01MS 03/28/14 18:10 9.1 90.5MS HG140325-5 10.9 71 125ng/L2
L17348-01MSD 03/28/14 18:15 9.1 90MSD HG140325-5 10.9 071 125ng/L 242
WG361393CCV3 03/28/14 18:40 104CCV HG140325-4 10.4 76.5 123.4ng/L10
WG361393CCB3 03/28/14 18:46CCB U -0.5 0.5ng/L
Molybdenum, dissolved M200.8 ICP-MS
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361239
WG361239ICV 03/27/14 15:22 96.8ICV MS140218-2 .01941 90 110mg/L.02006
WG361239ICB 03/27/14 15:25ICB U -0.0015 0.0015mg/L
WG361239LFB 03/27/14 15:29 91.1LFB MS140320-2 .04556 85 115mg/L.05
L17275-05AS 03/27/14 15:49 .0036 102.7AS MS140320-2 .05495 70 130mg/L.05
L17275-05ASD 03/27/14 15:53 .0036 100.9ASD MS140320-2 .05405 1.6570 130mg/L 20.05
L17320-01AS 03/27/14 16:37 .002 108.1AS MS140320-2 .05604 70 130mg/L.05
L17320-01ASD 03/27/14 16:47 .002 101.7ASD MS140320-2 .05286 5.8470 130mg/L 20.05
Molybdenum, total M200.8 ICP-MS
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361380
WG361380ICV 03/28/14 0:07 93.9ICV MS140218-2 .01883 90 110mg/L.02006
WG361380ICB 03/28/14 0:11ICB U -0.0015 0.0015mg/L
WG361214LRB 03/28/14 0:14LRB U -0.0011 0.0011mg/L
WG361214LFB 03/28/14 0:18 92.9LFB MS140320-2 .04644 85 115mg/L.05
L17275-08LFM 03/28/14 0:58 .0108 96.9LFM MS140320-2 .05923 70 130mg/L.05
L17275-08LFMD 03/28/14 1:02 .0108 95.4LFMD MS140320-2 .0585 1.2470 130mg/L 20.05
L17321-02LFM 03/28/14 1:43 U 96.8LFM MS140320-2 .0484 70 130mg/L.05
L17321-02LFMD 03/28/14 1:46 U 95.8LFMD MS140320-2 .0479 1.0470 130mg/L 20.05
Page 67 of 90L17275-1404011436
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic QC
Summary
ACZ Project ID: L17275SPF Water Engineering
Nickel, dissolved M200.8 ICP-MS
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361239
WG361239ICV 03/27/14 15:22 97.1ICV MS140218-2 .04856 90 110mg/L.05
WG361239ICB 03/27/14 15:25ICB U -0.0018 0.0018mg/L
WG361239LFB 03/27/14 15:29 93.6LFB MS140320-2 .04679 85 115mg/L.05
L17275-05AS 03/27/14 15:49 U 101.4AS MS140320-2 .0507 70 130mg/L.05
L17275-05ASD 03/27/14 15:53 U 101ASD MS140320-2 .05048 0.4370 130mg/L 20.05
L17320-01AS 03/27/14 16:37 .0018 97.3AS MS140320-2 .05047 70 130mg/L.05
L17320-01ASD 03/27/14 16:47 .0018 97.1ASD MS140320-2 .05033 0.2870 130mg/L 20.05
Nickel, total M200.8 ICP-MS
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361380
WG361380ICV 03/28/14 0:07 97.7ICV MS140218-2 .04883 90 110mg/L.05
WG361380ICB 03/28/14 0:11ICB U -0.0018 0.0018mg/L
WG361214LRB 03/28/14 0:14LRB U -0.00132 0.00132mg/L
WG361214LFB 03/28/14 0:18 96.2LFB MS140320-2 .04811 85 115mg/L.05
L17275-08LFM 03/28/14 0:58 U 90LFM MS140320-2 .04499 70 130mg/L.05
L17275-08LFMD 03/28/14 1:02 U 90.8LFMD MS140320-2 .04539 0.8970 130mg/L 20.05
L17321-02LFM 03/28/14 1:43 .345 106.4LFM MS140320-2 .3982 70 130mg/L.05
L17321-02LFMD 03/28/14 1:46 .345 127.2LFMD MS140320-2 .4086 2.5870 130mg/L 20.05
Nitrate/Nitrite as N M353.2 - H2SO4 preserved
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361383
WG361383ICV 03/27/14 20:57 104.9ICV WI140116-3 2.535 90 110mg/L2.416
WG361383ICB 03/27/14 20:59ICB U -0.06 0.06mg/L
WG361387
WG361387LFB1 03/27/14 23:04 105.6LFB WI140215-3 2.112 90 110mg/L2
L17273-08AS 03/27/14 23:23 .05 109AS WI140215-3 2.23 90 110mg/L2
L17273-09DUP 03/27/14 23:26 .64DUP .644 0.6mg/L 20
WG361387LFB2 03/27/14 23:39 104.6LFB WI140215-3 2.092 90 110mg/L2
L17275-05AS 03/27/14 23:41 .07 110.4AS WI140215-3 2.277 90 110mg/L2
L17275-06DUP 03/27/14 23:44 .28DUP .274 2.2mg/L 20
Page 68 of 90L17275-1404011436
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic QC
Summary
ACZ Project ID: L17275SPF Water Engineering
Nitrogen, ammonia M350.1 - Automated Phenate
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361341
WG361341ICV 03/27/14 11:36 105.7ICV WI131021-1 1.06 90 110mg/L1.003
WG361341ICB 03/27/14 11:39ICB U -0.15 0.15mg/L
WG361347
WG361347LFB1 03/27/14 11:58 101.7LFB WI140113-8 1.017 90 110mg/L1
WG361347LFB2 03/27/14 12:30 103LFB WI140113-8 1.03 90 110mg/L1
L17274-13AS 03/27/14 12:32 .48 101.1AS WI140113-8 1.491 90 110mg/L1
L17274-14DUP RA03/27/14 12:34 UDUP U 0mg/L 20
WG361354
WG361354LFB1 03/27/14 13:10 108.8LFB WI140113-8 1.088 90 110mg/L1
L17275-10AS 03/27/14 13:12 U 99.5AS WI140113-8 .995 90 110mg/L1
L17275-11DUP RA03/27/14 13:14 UDUP U 0mg/L 20
WG361354LFB2 03/27/14 13:42 109.4LFB WI140113-8 1.094 90 110mg/L1
pH (lab) SM4500H+ B
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361080
WG361080LCSW1 03/24/14 13:10 99.3LCSW PCN40852 5.96 units6
WG361080LCSW4 03/24/14 16:30 99.3LCSW PCN40852 5.96 units6
L17275-11DUP 03/24/14 18:37 8.2DUP 8.19 0.1units 20
L17282-01DUP 03/24/14 20:12 8.2DUP 8.19 0.1units 20
WG361080LCSW7 03/24/14 20:15 99.7LCSW PCN40852 5.98 units6
WG361080LCSW10 03/25/14 0:11 99.8LCSW PCN40852 5.99 units6
WG361080LCSW13 03/25/14 3:35 99.7LCSW PCN40852 5.98 units6
Phosphorus, total M365.1 - Auto Ascorbic Acid (digest)
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361388
WG361388ICV 03/27/14 23:01 105.3ICV WI140224-3 .687 90 110mg/L.65228
WG361388ICB 03/27/14 23:04ICB U -0.03 0.03mg/L
WG361389
WG361328LRB 03/27/14 23:53LRB U -0.03 0.03mg/L
WG361328LFB 03/27/14 23:54 103LFB WI140326-3 .515 90 110mg/L.5
L17275-01LFM 03/28/14 0:13 U 105.4LFM WI140326-3 .527 90 110mg/L.5
L17275-02DUP RA03/28/14 0:15 .01DUP U 200mg/L 20
WG361457
WG361457ICV 03/28/14 21:54 107.9ICV WI140224-3 .704 90 110mg/L.65228
WG361457ICB 03/28/14 21:57ICB U -0.03 0.03mg/L
WG361423LRB 03/28/14 21:58LRB U -0.03 0.03mg/L
WG361423LFB 03/28/14 21:59 105.4LFB WI140326-3 .527 90 110mg/L.5
L17275-12LFM 03/28/14 22:01 U 102.2LFM WI140326-3 .511 90 110mg/L.5
L17275-13DUP RA03/28/14 22:03 UDUP U 0mg/L 20
Page 69 of 90L17275-1404011436
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic QC
Summary
ACZ Project ID: L17275SPF Water Engineering
Potassium, dissolved M200.7 ICP
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG360973
WG360973ICV 03/21/14 11:24 96.9ICV II140220-1 19.37 95 105mg/L20
WG360973ICB 03/21/14 11:30ICB U -0.6 0.6mg/L
WG360973LFB 03/21/14 11:43 99.5LFB II140317-2 99.5 85 115mg/L99.99364
L17261-01AS 03/21/14 11:49 21.4 103.1AS II140317-2 227.6 85 115mg/L199.98728
L17261-01ASD 03/21/14 11:52 21.4 104.8ASD II140317-2 231 1.4885 115mg/L 20199.98728
L17332-01AS 03/21/14 13:01 4.4 99AS II140317-2 103.4 85 115mg/L99.99364
L17332-01ASD 03/21/14 13:04 4.4 104ASD II140317-2 108.4 4.7285 115mg/L 2099.99364
Potassium, total M200.7 ICP
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361188
WG361188ICV 03/26/14 9:50 96.2ICV II140228-1 19.24 95 105mg/L20
WG361188ICB 03/26/14 9:56ICB U -0.6 0.6mg/L
WG361129LRB 03/26/14 10:09LRB U -0.44 0.44mg/L
WG361129LFB 03/26/14 10:12 99.2LFB II140317-2 99.15 85 115mg/L99.99364
L17275-01LFM 03/26/14 10:18 4.7 100.3LFM II140317-2 105 70 130mg/L99.99364
L17275-01LFMD 03/26/14 10:21 4.7 99.5LFMD II140317-2 104.2 0.7670 130mg/L 2099.99364
L17304-01LFM 03/26/14 11:24 .9 97.5LFM II140317-2 98.36 70 130mg/L99.99364
L17304-01LFMD 03/26/14 11:27 .9 99.1LFMD II140317-2 99.99 1.6470 130mg/L 2099.99364
Residue, Filterable (TDS) @180C SM2540C
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG360922
WG360922PBW 03/20/14 11:46PBW U -20 20mg/L
WG360922LCSW 03/20/14 11:48 93.8LCSW PCN45339 244 80 120mg/L260
L17253-02DUP 03/20/14 12:17 790DUP 798 1mg/L 10
WG360981
WG360981PBW 03/21/14 9:00PBW U -20 20mg/L
WG360981LCSW 03/21/14 9:01 102.3LCSW PCN45339 266 80 120mg/L260
L17354-01DUP 03/21/14 9:44 160DUP 158 1.3mg/L 10
WG361035
WG361035PBW 03/21/14 15:38PBW U -20 20mg/L
WG361035LCSW 03/21/14 15:40 97.7LCSW PCN45340 254 80 120mg/L260
L17275-14DUP 03/21/14 16:27 380DUP 384 1mg/L 10
Residue, Non-Filterable (TSS) @105C SM2540D
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361016
WG361016PBW 03/21/14 12:18PBW U -15 15mg/L
WG361016LCSW 03/21/14 12:19 83.8LCSW PCN45339 134 80 120mg/L160
L17354-01DUP RA03/21/14 12:49 UDUP 5 200mg/L 10
WG361048
WG361048PBW 03/22/14 11:00PBW U -15 15mg/L
WG361048LCSW 03/22/14 11:02 95LCSW PCN45340 152 80 120mg/L160
L17275-11DUP RA03/22/14 11:31 UDUP U 0mg/L 10
L17282-01DUP RA03/22/14 12:00 20DUP 19 5.1mg/L 10
Page 70 of 90L17275-1404011436
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic QC
Summary
ACZ Project ID: L17275SPF Water Engineering
Scandium, dissolved M200.7 ICP
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG360973
WG360973ICV 03/21/14 11:24 99ICV II140220-1 1.98 95 105mg/L2
WG360973ICB 03/21/14 11:30ICB U -0.3 0.3mg/L
WG360973LFB 03/21/14 11:43 104.9LFB II140317-2 1.05 85 115mg/L1.0009
L17261-01AS 03/21/14 11:49 U 104.4AS II140317-2 2.09 85 115mg/L2.0018
L17261-01ASD 03/21/14 11:52 U 104.9ASD II140317-2 2.1 0.4885 115mg/L 202.0018
L17332-01AS 03/21/14 13:01 U 103.9AS II140317-2 1.04 85 115mg/L1.0009
L17332-01ASD 03/21/14 13:04 U 106.9ASD II140317-2 1.07 2.8485 115mg/L 201.0009
Scandium, total M200.7 ICP
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361188
WG361188ICV 03/26/14 9:50 98.5ICV II140228-1 1.97 95 105mg/L2
WG361188ICB 03/26/14 9:56ICB U -0.3 0.3mg/L
WG361129LRB 03/26/14 10:09LRB U -0.22 0.22mg/L
WG361129LFB 03/26/14 10:12 106.9LFB II140317-2 1.07 85 115mg/L1.0009
L17275-01LFM 03/26/14 10:18 U 107.9LFM II140317-2 1.08 70 130mg/L1.0009
L17275-01LFMD 03/26/14 10:21 U 106.9LFMD II140317-2 1.07 0.9370 130mg/L 201.0009
L17304-01LFM 03/26/14 11:24 U 106.9LFM II140317-2 1.07 70 130mg/L1.0009
L17304-01LFMD 03/26/14 11:27 U 108.9LFMD II140317-2 1.09 1.8570 130mg/L 201.0009
Selenium, dissolved M200.8 ICP-MS
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361239
WG361239ICV 03/27/14 15:22 100.7ICV MS140218-2 .05036 90 110mg/L.05
WG361239ICB 03/27/14 15:25ICB U -0.0003 0.0003mg/L
WG361239LFB 03/27/14 15:29 94.4LFB MS140320-2 .04724 85 115mg/L.05005
L17275-05AS 03/27/14 15:49 .0059 115.9AS MS140320-2 .06393 70 130mg/L.05005
L17275-05ASD 03/27/14 15:53 .0059 112.4ASD MS140320-2 .06217 2.7970 130mg/L 20.05005
L17320-01AS 03/27/14 16:37 U 112.2AS MS140320-2 .05615 70 130mg/L.05005
L17320-01ASD 03/27/14 16:47 U 110.6ASD MS140320-2 .05537 1.470 130mg/L 20.05005
Selenium, total M200.8 ICP-MS
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361380
WG361380ICV 03/28/14 0:07 99.4ICV MS140218-2 .04968 90 110mg/L.05
WG361380ICB 03/28/14 0:11ICB U -0.0003 0.0003mg/L
WG361214LRB 03/28/14 0:14LRB U -0.00022 0.00022mg/L
WG361214LFB 03/28/14 0:18 112LFB MS140320-2 .05604 85 115mg/L.05005
L17275-08LFM 03/28/14 0:58 .0039 88.6LFM MS140320-2 .04826 70 130mg/L.05005
L17275-08LFMD 03/28/14 1:02 .0039 90.1LFMD MS140320-2 .04899 1.570 130mg/L 20.05005
L17321-02LFM 03/28/14 1:43 U 105.1LFM MS140320-2 .05262 70 130mg/L.05005
L17321-02LFMD 03/28/14 1:46 U 107LFMD MS140320-2 .05356 1.7770 130mg/L 20.05005
Page 71 of 90L17275-1404011436
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic QC
Summary
ACZ Project ID: L17275SPF Water Engineering
Silver, dissolved M200.8 ICP-MS
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361239
WG361239ICV 03/27/14 15:22 99.2ICV MS140218-2 .01986 90 110mg/L.02002
WG361239ICB 03/27/14 15:25ICB U -0.00015 0.00015mg/L
WG361239LFB 03/27/14 15:29 94.8LFB MS140320-2 .009486 85 115mg/L.01001
L17275-05AS 03/27/14 15:49 U 96.2AS MS140320-2 .009627 70 130mg/L.01001
L17275-05ASD 03/27/14 15:53 U 93.5ASD MS140320-2 .009356 2.8670 130mg/L 20.01001
L17320-01AS 03/27/14 16:37 U 89.5AS MS140320-2 .008961 70 130mg/L.01001
L17320-01ASD 03/27/14 16:47 U 88.1ASD MS140320-2 .008818 1.6170 130mg/L 20.01001
Silver, total M200.8 ICP-MS
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361380
WG361380ICV 03/28/14 0:07 97.3ICV MS140218-2 .01947 90 110mg/L.02002
WG361380ICB 03/28/14 0:11ICB U -0.00015 0.00015mg/L
WG361214LRB 03/28/14 0:14LRB U -0.00011 0.00011mg/L
WG361214LFB 03/28/14 0:18 98.1LFB MS140320-2 .009822 85 115mg/L.01001
L17275-08LFM 03/28/14 0:58 U 96.4LFM MS140320-2 .00965 70 130mg/L.01001
L17275-08LFMD 03/28/14 1:02 U 94.6LFMD MS140320-2 .00947 1.8870 130mg/L 20.01001
L17321-02LFM 03/28/14 1:43 U 93.9LFM MS140320-2 .0094 70 130mg/L.01001
L17321-02LFMD 03/28/14 1:46 U 92.8LFMD MS140320-2 .00929 1.1870 130mg/L 20.01001
Sodium, dissolved M200.7 ICP
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG360973
WG360973ICV 03/21/14 11:24 98.1ICV II140220-1 98.09 95 105mg/L100
WG360973ICB 03/21/14 11:30ICB U -0.6 0.6mg/L
WG360973LFB 03/21/14 11:43 99.6LFB II140317-2 99.63 85 115mg/L100.0393
L17261-01AS 03/21/14 11:49 85.4 101.1AS II140317-2 287.6 85 115mg/L200.0786
L17261-01ASD 03/21/14 11:52 85.4 103.1ASD II140317-2 291.6 1.3885 115mg/L 20200.0786
L17332-01AS 03/21/14 13:01 44.8 97.4AS II140317-2 142.2 85 115mg/L100.0393
L17332-01ASD 03/21/14 13:04 44.8 103.5ASD II140317-2 148.3 4.285 115mg/L 20100.0393
Sodium, total M200.7 ICP
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361188
WG361188ICV 03/26/14 9:50 98.2ICV II140228-1 98.22 95 105mg/L100
WG361188ICB 03/26/14 9:56ICB U -0.6 0.6mg/L
WG361129LRB 03/26/14 10:09LRB U -0.44 0.44mg/L
WG361129LFB 03/26/14 10:12 101LFB II140317-2 101 85 115mg/L100.0393
L17275-01LFM 03/26/14 10:18 20.5 101.9LFM II140317-2 122.4 70 130mg/L100.0393
L17275-01LFMD 03/26/14 10:21 20.5 101.4LFMD II140317-2 121.9 0.4170 130mg/L 20100.0393
L17304-01LFM 03/26/14 11:24 41.6 100.5LFM II140317-2 142.1 70 130mg/L100.0393
L17304-01LFMD 03/26/14 11:27 41.6 103.3LFMD II140317-2 144.9 1.9570 130mg/L 20100.0393
Page 72 of 90L17275-1404011436
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic QC
Summary
ACZ Project ID: L17275SPF Water Engineering
Strontium, dissolved M200.7 ICP
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG360973
WG360973ICV 03/21/14 11:24 99.1ICV II140220-1 1.9822 95 105mg/L2
WG360973ICB 03/21/14 11:30ICB U -0.015 0.015mg/L
WG360973LFB 03/21/14 11:43 99.3LFB II140317-2 .4966 85 115mg/L.5
L17261-01AS 03/21/14 11:49 1.62 93.6AS II140317-2 2.556 85 115mg/L1
L17261-01ASD 03/21/14 11:52 1.62 96.2ASD II140317-2 2.582 1.0185 115mg/L 201
L17332-01AS 03/21/14 13:01 1.81 87.2AS II140317-2 2.246 85 115mg/L.5
L17332-01ASD 03/21/14 13:04 1.81 103ASD II140317-2 2.325 3.4685 115mg/L 20.5
Strontium, total M200.7 ICP
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361188
WG361188ICV 03/26/14 9:50 98.3ICV II140228-1 1.9658 95 105mg/L2
WG361188ICB 03/26/14 9:56ICB U -0.015 0.015mg/L
WG361129LRB 03/26/14 10:09LRB U -0.011 0.011mg/L
WG361129LFB 03/26/14 10:12 97.6LFB II140317-2 .4879 85 115mg/L.5
L17275-01LFM 03/26/14 10:18 .202 97.9LFM II140317-2 .6917 70 130mg/L.5
L17275-01LFMD 03/26/14 10:21 .202 97.3LFMD II140317-2 .6885 0.4670 130mg/L 20.5
L17304-01LFM 03/26/14 11:24 .391 95.2LFM II140317-2 .8672 70 130mg/L.5
L17304-01LFMD 03/26/14 11:27 .391 98.3LFMD II140317-2 .8823 1.7370 130mg/L 20.5
Sulfate M300.0 - Ion Chromatography
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG360290
WG360290ICV 03/06/14 13:49 102.5ICV WI140226-1 51.2 90 110mg/L49.95
WG360290ICB 03/06/14 14:07ICB U -1.5 1.5mg/L
WG361148
WG361148LFB1 03/25/14 12:54 100.7LFB WI140306-2 30.2 90 110mg/L30
L17232-03DUP 03/25/14 17:41 23.1DUP 23.1 0mg/L 20
L17232-04AS 03/25/14 18:17 19.7 99.7AS WI140306-2 49.6 90 110mg/L30
WG361148LFB2 03/25/14 21:34 100.7LFB WI140306-2 30.2 90 110mg/L30
L17275-04DUP 03/25/14 22:10 47DUP 47 0mg/L 20
L17275-05AS 03/25/14 23:21 47.1 97.7AS WI140306-2 76.4 90 110mg/L30
Thallium, dissolved M200.8 ICP-MS
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361239
WG361239ICV 03/27/14 15:22 106.3ICV MS140218-2 .05316 90 110mg/L.05
WG361239ICB 03/27/14 15:25ICB U -0.0003 0.0003mg/L
WG361239LFB 03/27/14 15:29 98.9LFB MS140320-2 .04965 85 115mg/L.0502
L17275-05AS 03/27/14 15:49 U 111AS MS140320-2 .05571 70 130mg/L.0502
L17275-05ASD 03/27/14 15:53 U 108.8ASD MS140320-2 .0546 2.0170 130mg/L 20.0502
L17320-01AS 03/27/14 16:37 U 110.9AS MS140320-2 .05566 70 130mg/L.0502
L17320-01ASD 03/27/14 16:47 U 110.6ASD MS140320-2 .05551 0.2770 130mg/L 20.0502
Page 73 of 90L17275-1404011436
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic QC
Summary
ACZ Project ID: L17275SPF Water Engineering
Thallium, total M200.8 ICP-MS
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361380
WG361380ICV 03/28/14 0:07 106.4ICV MS140218-2 .05319 90 110mg/L.05
WG361380ICB 03/28/14 0:11ICB U -0.0003 0.0003mg/L
WG361214LRB 03/28/14 0:14LRB U -0.00022 0.00022mg/L
WG361214LFB 03/28/14 0:18 101.4LFB MS140320-2 .0509 85 115mg/L.0502
L17275-08LFM 03/28/14 0:58 U 105.5LFM MS140320-2 .05296 70 130mg/L.0502
L17275-08LFMD 03/28/14 1:02 U 103.5LFMD MS140320-2 .05198 1.8770 130mg/L 20.0502
L17321-02LFM 03/28/14 1:43 .0003 101.9LFM MS140320-2 .05146 70 130mg/L.0502
L17321-02LFMD 03/28/14 1:46 .0003 103LFMD MS140320-2 .052 1.0470 130mg/L 20.0502
Tin, dissolved M200.8 ICP-MS
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361239
WG361239ICV 03/27/14 15:22 103.5ICV MS140218-2 .05192 90 110mg/L.05015
WG361239ICB 03/27/14 15:25ICB U -0.0003 0.0003mg/L
WG361239LFB 03/27/14 15:29 94.3LFB MS140320-2 .04721 85 115mg/L.05005
L17275-05AS 03/27/14 15:49 U 101.4AS MS140320-2 .05077 70 130mg/L.05005
L17275-05ASD 03/27/14 15:53 U 99.7ASD MS140320-2 .04988 1.7770 130mg/L 20.05005
L17320-01AS 03/27/14 16:37 .0007 103.6AS MS140320-2 .05255 70 130mg/L.05005
L17320-01ASD 03/27/14 16:47 .0007 99.7ASD MS140320-2 .0506 3.7870 130mg/L 20.05005
Tin, total M200.8 ICP-MS
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361380
WG361380ICV 03/28/14 0:07 100.5ICV MS140218-2 .0504 90 110mg/L.05015
WG361380ICB 03/28/14 0:11ICB U -0.0003 0.0003mg/L
WG361214LRB 03/28/14 0:14LRB U -0.00022 0.00022mg/L
WG361214LFB 03/28/14 0:18 96.5LFB MS140320-2 .04829 85 115mg/L.05005
L17275-08LFM 03/28/14 0:58 .0002 96.8LFM MS140320-2 .04867 70 130mg/L.05005
L17275-08LFMD 03/28/14 1:02 .0002 95.7LFMD MS140320-2 .04811 1.1670 130mg/L 20.05005
L17321-02LFM 03/28/14 1:43 U 98.1LFM MS140320-2 .0491 70 130mg/L.05005
L17321-02LFMD 03/28/14 1:46 U 97.5LFMD MS140320-2 .0488 0.6170 130mg/L 20.05005
Titanium, dissolved M200.7 ICP
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG360973
WG360973ICV 03/21/14 11:24 95.2ICV II140220-1 1.9045 95 105mg/L2
WG360973ICB 03/21/14 11:30ICB U -0.015 0.015mg/L
WG360973LFB 03/21/14 11:43 96.6LFB II140317-2 .9658 85 115mg/L1
L17261-01AS 03/21/14 11:49 U 96AS II140317-2 1.919 85 115mg/L2
L17261-01ASD 03/21/14 11:52 U 96.6ASD II140317-2 1.931 0.6285 115mg/L 202
L17332-01AS 03/21/14 13:01 .005 95.6AS II140317-2 .9614 85 115mg/L1
L17332-01ASD 03/21/14 13:04 .005 98.8ASD II140317-2 .9926 3.1985 115mg/L 201
Page 74 of 90L17275-1404011436
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic QC
Summary
ACZ Project ID: L17275SPF Water Engineering
Titanium, total M200.7 ICP
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361188
WG361188ICV 03/26/14 9:50 96.6ICV II140228-1 1.9312 95 105mg/L2
WG361188ICB 03/26/14 9:56ICB U -0.015 0.015mg/L
WG361129LRB 03/26/14 10:09LRB U -0.011 0.011mg/L
WG361129LFB 03/26/14 10:12 98.8LFB II140317-2 .9875 85 115mg/L1
L17275-01LFM 03/26/14 10:18 .009 98.9LFM II140317-2 .9982 70 130mg/L1
L17275-01LFMD 03/26/14 10:21 .009 98.3LFMD II140317-2 .9919 0.6370 130mg/L 201
L17304-01LFM 03/26/14 11:24 .007 96.6LFM II140317-2 .9726 70 130mg/L1
L17304-01LFMD 03/26/14 11:27 .007 97.8LFMD II140317-2 .9853 1.370 130mg/L 201
Uranium, dissolved M200.8 ICP-MS
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361239
WG361239ICV 03/27/14 15:22 102.3ICV MS140218-2 .05115 90 110mg/L.05
WG361239ICB 03/27/14 15:25ICB U -0.0003 0.0003mg/L
WG361239LFB 03/27/14 15:29 101.3LFB MS140320-2 .05064 85 115mg/L.05
L17275-05AS 03/27/14 15:49 .0047 111AS MS140320-2 .0602 70 130mg/L.05
L17275-05ASD 03/27/14 15:53 .0047 109.3ASD MS140320-2 .05935 1.4270 130mg/L 20.05
L17320-01AS 03/27/14 16:37 .0062 112.3AS MS140320-2 .06234 70 130mg/L.05
L17320-01ASD 03/27/14 16:47 .0062 112.3ASD MS140320-2 .06237 0.0570 130mg/L 20.05
Uranium, total M200.8 ICP-MS
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361380
WG361380ICV 03/28/14 0:07 101.6ICV MS140218-2 .0508 90 110mg/L.05
WG361380ICB 03/28/14 0:11ICB U -0.0003 0.0003mg/L
WG361214LRB 03/28/14 0:14LRB U -0.00022 0.00022mg/L
WG361214LFB 03/28/14 0:18 102.5LFB MS140320-2 .05127 85 115mg/L.05
L17275-08LFM 03/28/14 0:58 .0045 107.8LFM MS140320-2 .05841 70 130mg/L.05
L17275-08LFMD 03/28/14 1:02 .0045 107.1LFMD MS140320-2 .05807 0.5870 130mg/L 20.05
L17321-02LFM 03/28/14 1:43 .004 106LFM MS140320-2 .057 70 130mg/L.05
L17321-02LFMD 03/28/14 1:46 .004 107.8LFMD MS140320-2 .05792 1.670 130mg/L 20.05
Vanadium, dissolved M200.8 ICP-MS
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361239
WG361239ICV 03/27/14 15:22 97.7ICV MS140218-2 .04883 90 110mg/L.05
WG361239ICB 03/27/14 15:25ICB U -0.0006 0.0006mg/L
WG361239LFB 03/27/14 15:29 99.4LFB MS140320-2 .04976 85 115mg/L.05005
L17275-05AS 03/27/14 15:49 .0328 113.6AS MS140320-2 .08965 70 130mg/L.05005
L17275-05ASD 03/27/14 15:53 .0328 113.3ASD MS140320-2 .0895 0.1770 130mg/L 20.05005
L17320-01AS 03/27/14 16:37 U 113.9AS MS140320-2 .057 70 130mg/L.05005
L17320-01ASD 03/27/14 16:47 U 113.1ASD MS140320-2 .05662 0.6770 130mg/L 20.05005
Page 75 of 90L17275-1404011436
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic QC
Summary
ACZ Project ID: L17275SPF Water Engineering
Vanadium, total M200.8 ICP-MS
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361380
WG361380ICV 03/28/14 0:07 97.6ICV MS140218-2 .04882 90 110mg/L.05
WG361380ICB 03/28/14 0:11ICB U -0.0006 0.0006mg/L
WG361214LRB 03/28/14 0:14LRB U -0.00044 0.00044mg/L
WG361214LFB 03/28/14 0:18 101.5LFB MS140320-2 .05078 85 115mg/L.05005
L17275-08LFM 03/28/14 0:58 .0422 98.1LFM MS140320-2 .09132 70 130mg/L.05005
L17275-08LFMD 03/28/14 1:02 .0422 99.7LFMD MS140320-2 .09208 0.8370 130mg/L 20.05005
L17321-02LFM 03/28/14 1:43 .0019 102.6LFM MS140320-2 .05324 70 130mg/L.05005
L17321-02LFMD 03/28/14 1:46 .0019 103.5LFMD MS140320-2 .05372 0.970 130mg/L 20.05005
Zinc, dissolved M200.7 ICP
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG360973
WG360973ICV 03/21/14 11:24 97.1ICV II140220-1 1.942 95 105mg/L2
WG360973ICB 03/21/14 11:30ICB U -0.03 0.03mg/L
WG360973LFB 03/21/14 11:43 99.1LFB II140317-2 .496 85 115mg/L.5005
L17261-01AS 03/21/14 11:49 .06 101.1AS II140317-2 1.072 85 115mg/L1.001
L17261-01ASD 03/21/14 11:52 .06 103.7ASD II140317-2 1.098 2.485 115mg/L 201.001
L17332-01AS 03/21/14 13:01 U 99.1AS II140317-2 .496 85 115mg/L.5005
L17332-01ASD 03/21/14 13:04 U 104.1ASD II140317-2 .521 4.9285 115mg/L 20.5005
Zinc, total M200.7 ICP
ACZ ID Analyzed RecSample QualLower Upper RPDFoundType UnitsPCN/SCN LimitQC
WG361188
WG361188ICV 03/26/14 9:50 96.7ICV II140228-1 1.933 95 105mg/L2
WG361188ICB 03/26/14 9:56ICB U -0.03 0.03mg/L
WG361129LRB 03/26/14 10:09LRB U -0.022 0.022mg/L
WG361129LFB 03/26/14 10:12 102.1LFB II140317-2 .511 85 115mg/L.5005
L17275-01LFM 03/26/14 10:18 U 103.3LFM II140317-2 .517 70 130mg/L.5005
L17275-01LFMD 03/26/14 10:21 U 102.1LFMD II140317-2 .511 1.1770 130mg/L 20.5005
L17304-01LFM 03/26/14 11:24 .03 103.1LFM II140317-2 .546 70 130mg/L.5005
L17304-01LFMD 03/26/14 11:27 .03 101.9LFMD II140317-2 .54 1.170 130mg/L 20.5005
Page 76 of 90L17275-1404011436
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic Extended
Qualifier Report
ACZ Project ID: L17275SPF Water Engineering
ACZ ID PARAMETER QUAL DESCRIPTIONMETHODWORKNUM
M3 The spike recovery value is unusable since the analyte concentration in the sample is disproportionate to the spike level. The recovery of the associated control sample (LCS or LFB) was acceptable.
M200.7 ICPCalcium, dissolvedL17275-01 WG360973
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
M300.0 - Ion ChromatographyChlorideWG361148
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
M335.4 - Colorimetric w/ distillation
Cyanide, totalWG361114
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
SM4500-CN I-Colorimetric w/ distillation
Cyanide, WADWG361357
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
M300.0 - Ion ChromatographyFluorideWG361148
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
M350.1 - Automated PhenateNitrogen, ammoniaWG361347
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
M365.1 - Auto Ascorbic Acid (digest)
Phosphorus, totalWG361389
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
SM2540DResidue, Non-Filterable (TSS) @105CWG361016
M3 The spike recovery value is unusable since the analyte concentration in the sample is disproportionate to the spike level. The recovery of the associated control sample (LCS or LFB) was acceptable.
M200.7 ICPCalcium, dissolvedL17275-02 WG360973
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
M300.0 - Ion ChromatographyChlorideWG361148
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
M335.4 - Colorimetric w/ distillation
Cyanide, totalWG361114
RA Relative Percent Difference (RPD) was not used for data
validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
SM4500-CN I-Colorimetric w/
distillation
Cyanide, WADWG361357
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
M300.0 - Ion ChromatographyFluorideWG361148
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
M350.1 - Automated PhenateNitrogen, ammoniaWG361347
RA Relative Percent Difference (RPD) was not used for data
validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
M365.1 - Auto Ascorbic Acid
(digest)
Phosphorus, totalWG361389
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
SM2540DResidue, Non-Filterable (TSS) @105CWG361016
REPAD.15.06.05.01
Page 77 of 90L17275-1404011436
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic Extended
Qualifier Report
ACZ Project ID: L17275SPF Water Engineering
ACZ ID PARAMETER QUAL DESCRIPTIONMETHODWORKNUM
M3 The spike recovery value is unusable since the analyte concentration in the sample is disproportionate to the spike level. The recovery of the associated control sample (LCS or LFB) was acceptable.
M200.7 ICPCalcium, dissolvedL17275-03 WG360973
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
M300.0 - Ion ChromatographyChlorideWG361148
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
M335.4 - Colorimetric w/ distillation
Cyanide, totalWG361114
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
SM4500-CN I-Colorimetric w/ distillation
Cyanide, WADWG361357
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
M300.0 - Ion ChromatographyFluorideWG361148
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
M350.1 - Automated PhenateNitrogen, ammoniaWG361347
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
M365.1 - Auto Ascorbic Acid (digest)
Phosphorus, totalWG361389
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
SM2540DResidue, Non-Filterable (TSS) @105CWG361048
M3 The spike recovery value is unusable since the analyte concentration in the sample is disproportionate to the spike level. The recovery of the associated control sample (LCS or LFB) was acceptable.
M200.7 ICPCalcium, dissolvedL17275-04 WG360973
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
M335.4 - Colorimetric w/ distillation
Cyanide, totalWG361114
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
SM4500-CN I-Colorimetric w/ distillation
Cyanide, WADWG361357
RA Relative Percent Difference (RPD) was not used for data
validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
M300.0 - Ion ChromatographyFluorideWG361148
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
M350.1 - Automated PhenateNitrogen, ammoniaWG361347
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
M365.1 - Auto Ascorbic Acid (digest)
Phosphorus, totalWG361389
RA Relative Percent Difference (RPD) was not used for data
validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
SM2540DResidue, Non-Filterable (TSS) @105CWG361048
REPAD.15.06.05.01
Page 78 of 90L17275-1404011436
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic Extended
Qualifier Report
ACZ Project ID: L17275SPF Water Engineering
ACZ ID PARAMETER QUAL DESCRIPTIONMETHODWORKNUM
M3 The spike recovery value is unusable since the analyte concentration in the sample is disproportionate to the spike level. The recovery of the associated control sample (LCS or LFB) was acceptable.
M200.7 ICPCalcium, dissolvedL17275-05 WG360973
Q5 Sample received with inadequate chemical preservation. Additional preservation performed by the laboratory.
M1631, Atomic FluorescenceMercury, totalWG361393
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
M335.4 - Colorimetric w/ distillation
Cyanide, totalWG361114
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
SM4500-CN I-Colorimetric w/ distillation
Cyanide, WADWG361357
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
M300.0 - Ion ChromatographyFluorideWG361148
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
M350.1 - Automated PhenateNitrogen, ammoniaWG361347
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
M365.1 - Auto Ascorbic Acid (digest)
Phosphorus, totalWG361389
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
SM2540DResidue, Non-Filterable (TSS) @105CWG361048
M3 The spike recovery value is unusable since the analyte concentration in the sample is disproportionate to the spike level. The recovery of the associated control sample (LCS or LFB) was acceptable.
M200.7 ICPCalcium, dissolvedL17275-06 WG360973
DC Sample required dilution. Non-target analyte exceeded calibration range.
M300.0 - Ion ChromatographyChlorideWG361148
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
M335.4 - Colorimetric w/ distillation
Cyanide, totalWG361114
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
SM4500-CN I-Colorimetric w/ distillation
Cyanide, WADWG361357
DC Sample required dilution. Non-target analyte exceeded calibration range.
M300.0 - Ion ChromatographyFluorideWG361148
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
M300.0 - Ion Chromatography
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
M350.1 - Automated PhenateNitrogen, ammoniaWG361347
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
M365.1 - Auto Ascorbic Acid (digest)
Phosphorus, totalWG361389
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
SM2540DResidue, Non-Filterable (TSS) @105CWG361048
REPAD.15.06.05.01
Page 79 of 90L17275-1404011436
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic Extended
Qualifier Report
ACZ Project ID: L17275SPF Water Engineering
ACZ ID PARAMETER QUAL DESCRIPTIONMETHODWORKNUM
M3 The spike recovery value is unusable since the analyte concentration in the sample is disproportionate to the spike level. The recovery of the associated control sample (LCS or LFB) was acceptable.
M200.7 ICPCalcium, dissolvedL17275-08 WG360973
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
M335.4 - Colorimetric w/ distillation
Cyanide, totalWG361114
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
SM4500-CN I-Colorimetric w/ distillation
Cyanide, WADWG361357
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
M300.0 - Ion ChromatographyFluorideWG361148
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
M350.1 - Automated PhenateNitrogen, ammoniaWG361347
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
M365.1 - Auto Ascorbic Acid (digest)
Phosphorus, totalWG361389
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
SM2540DResidue, Non-Filterable (TSS) @105CWG361048
M3 The spike recovery value is unusable since the analyte concentration in the sample is disproportionate to the spike level. The recovery of the associated control sample (LCS or LFB) was acceptable.
M200.7 ICPCalcium, dissolvedL17275-09 WG360973
RA Relative Percent Difference (RPD) was not used for data
validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
M335.4 - Colorimetric w/
distillation
Cyanide, totalWG361114
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
SM4500-CN I-Colorimetric w/ distillation
Cyanide, WADWG361357
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
M300.0 - Ion ChromatographyFluorideWG361148
RA Relative Percent Difference (RPD) was not used for data
validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
M350.1 - Automated PhenateNitrogen, ammoniaWG361347
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
M365.1 - Auto Ascorbic Acid (digest)
Phosphorus, totalWG361389
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
SM2540DResidue, Non-Filterable (TSS) @105CWG361048
REPAD.15.06.05.01
Page 80 of 90L17275-1404011436
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic Extended
Qualifier Report
ACZ Project ID: L17275SPF Water Engineering
ACZ ID PARAMETER QUAL DESCRIPTIONMETHODWORKNUM
M3 The spike recovery value is unusable since the analyte concentration in the sample is disproportionate to the spike level. The recovery of the associated control sample (LCS or LFB) was acceptable.
M200.7 ICPCalcium, dissolvedL17275-10 WG360973
M3 The spike recovery value is unusable since the analyte concentration in the sample is disproportionate to the spike level. The recovery of the associated control sample (LCS or LFB) was acceptable.
M200.8 ICP-MSManganese, totalWG361380
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
M335.4 - Colorimetric w/ distillation
Cyanide, totalWG361114
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
SM4500-CN I-Colorimetric w/ distillation
Cyanide, WADWG361357
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
M300.0 - Ion ChromatographyFluorideWG361148
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
M350.1 - Automated PhenateNitrogen, ammoniaWG361354
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
M365.1 - Auto Ascorbic Acid (digest)
Phosphorus, totalWG361389
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
SM2540DResidue, Non-Filterable (TSS) @105CWG361048
M3 The spike recovery value is unusable since the analyte
concentration in the sample is disproportionate to the spike level. The recovery of the associated control sample (LCS or LFB) was acceptable.
M200.8 ICP-MSManganese, totalL17275-11 WG361380
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
M335.4 - Colorimetric w/ distillation
Cyanide, totalWG361114
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
SM4500-CN I-Colorimetric w/ distillation
Cyanide, WADWG361357
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
M300.0 - Ion ChromatographyFluorideWG361148
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
M350.1 - Automated PhenateNitrogen, ammoniaWG361354
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
M365.1 - Auto Ascorbic Acid (digest)
Phosphorus, totalWG361389
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
SM2540DResidue, Non-Filterable (TSS) @105CWG361048
REPAD.15.06.05.01
Page 81 of 90L17275-1404011436
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic Extended
Qualifier Report
ACZ Project ID: L17275SPF Water Engineering
ACZ ID PARAMETER QUAL DESCRIPTIONMETHODWORKNUM
M3 The spike recovery value is unusable since the analyte concentration in the sample is disproportionate to the spike level. The recovery of the associated control sample (LCS or LFB) was acceptable.
M200.8 ICP-MSManganese, totalL17275-12 WG361380
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
M335.4 - Colorimetric w/ distillation
Cyanide, totalWG361114
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
SM4500-CN I-Colorimetric w/ distillation
Cyanide, WADWG361357
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
M300.0 - Ion ChromatographyFluorideWG361148
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
M350.1 - Automated PhenateNitrogen, ammoniaWG361354
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
M365.1 - Auto Ascorbic Acid (digest)
Phosphorus, totalWG361457
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
SM2540DResidue, Non-Filterable (TSS) @105CWG361048
M3 The spike recovery value is unusable since the analyte concentration in the sample is disproportionate to the spike level. The recovery of the associated control sample (LCS or LFB) was acceptable.
M200.8 ICP-MSManganese, totalL17275-13 WG361380
RA Relative Percent Difference (RPD) was not used for data
validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
M335.4 - Colorimetric w/
distillation
Cyanide, totalWG361114
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
SM4500-CN I-Colorimetric w/ distillation
Cyanide, WADWG361357
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
M300.0 - Ion ChromatographyFluorideWG361148
RA Relative Percent Difference (RPD) was not used for data
validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
M350.1 - Automated PhenateNitrogen, ammoniaWG361354
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
M365.1 - Auto Ascorbic Acid (digest)
Phosphorus, totalWG361457
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
SM2540DResidue, Non-Filterable (TSS) @105CWG361048
REPAD.15.06.05.01
Page 82 of 90L17275-1404011436
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic Extended
Qualifier Report
ACZ Project ID: L17275SPF Water Engineering
ACZ ID PARAMETER QUAL DESCRIPTIONMETHODWORKNUM
M3 The spike recovery value is unusable since the analyte concentration in the sample is disproportionate to the spike level. The recovery of the associated control sample (LCS or LFB) was acceptable.
M200.8 ICP-MSManganese, totalL17275-14 WG361380
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
M335.4 - Colorimetric w/ distillation
Cyanide, totalWG361114
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
SM4500-CN I-Colorimetric w/ distillation
Cyanide, WADWG361357
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
M300.0 - Ion ChromatographyFluorideWG361148
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
M350.1 - Automated PhenateNitrogen, ammoniaWG361354
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
M365.1 - Auto Ascorbic Acid (digest)
Phosphorus, totalWG361457
RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL).
SM2540DResidue, Non-Filterable (TSS) @105CWG361048
REPAD.15.06.05.01
Page 83 of 90L17275-1404011436
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Certification
Qualifiers
ACZ Project ID: L17275SPF Water Engineering
Metals Analysis
The following parameters are not offered for certification or are not covered by NELAC certificate #ACZ.
Bismuth, dissolved M200.7 ICP
Bismuth, total M200.7 ICP
Gallium, dissolved M200.7 ICP
Gallium, total M200.7 ICP
Scandium, dissolved M200.7 ICP
Scandium, total M200.7 ICP
Tin, dissolved M200.8 ICP-MS
Tin, total M200.8 ICP-MS
REPAD.05.06.05.01
Page 84 of 90L17275-1404011436
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Sample
Receipt
SPF Water EngineeringCalico 1st Quarter 2014 Sampling
ACZ Project ID:
Date Received:
Received By: mtb
03/19/2014 10:05
L17275
Date Printed: 3/19/2014
Chain of Custody Related Remarks
Client Contact Remarks
NANOYES
X
X
X
X
X
X
1) Is a foreign soil permit included for applicable samples?
2) Is the Chain of Custody or other directive shipping papers present?
3) Does this project require special handling procedures such as CLP protocol?
4) Are any samples NRC licensable material?
5) If samples are received past hold time, proceed with requested short hold time analyses?
6) Is the Chain of Custody complete and accurate?
7) Were any changes made to the Chain of Custody prior to ACZ receiving the samples?
Receipt Verification
NANOYES
X
X
X
X
X
X
X
X
X
8) Are all containers intact and with no leaks?
9) Are all labels on containers and are they intact and legible?
10) Do the sample labels and Chain of Custody match for Sample ID, Date, and Time?
11) For preserved bottle types, was the pH checked and within limits?
12) Is there sufficient sample volume to perform all requested work?
13) Is the custody seal intact on all containers?
14) Are samples that require zero headspace acceptable?
15) Are all sample containers appropriate for analytical requirements?
16) Is there an Hg-1631 trip blank present?
17) Is there a VOA trip blank present?
18) Were all samples received within hold time?
Samples/Containers
X
X
Shipping Containers
L17275-04 Container B1443090 (HG-1631 D): This cont ainer was received broken and the associated analysis were re moved from the project.
Cooler Id Temp (°C) Rad (µR/Hr) Custody Seal Intact?--------- --------- ----------- ------- -------------NA19306 0.2 13 YesNA19307 0.9 13 YesNA19308 1.4 13 YesNA19309 0.9 13 Yes
X
Was ice present in the shipment container(s)?
Yes - Wet ice was present in the shipment container (s).
REPAD LPII 2012-03
Page 85 of 90L17275-1404011436
BD[ Laboratories, Inc.2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Sample
Receipt
SPF Water EngineeringCalico 1st Quarter 2014 Sampling
ACZ Project ID:
Date Received:
Received By: mtb
03/19/2014 10:05
L17275
Date Printed: 3/19/2014
Client must contact an ACZ Project Manager if analysis should not proceed for samples received outside of their thermal preservation acceptance criteria.
REPAD LPII 2012-03
Page 86 of 90L17275-1404011436