University Based Innovation on PEMFC in Turkey Assoc. Prof. Dr. Süleyman Kaytakoğlu Anadolu...

University Based Innovation on PEMFC in Turkey

Assoc. Prof. Dr. Süleyman Kaytakoğlu

Anadolu UniversityFaculty of Engineering and Architecture

Department of Chemical EngineeringEskişehir, Turkey

February 26-28, 2007Ana

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GeT Univation!GeT Univation!

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I. Part

Presentation of Dept. of Chemical Engineering

Anadolu UniversityDepartment of Chemical Engineering

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itesi Education

BSc Programme - Since 1970

MSc Programme - Since 1981

PhD Programme - Since 1984


Academic StaffA

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Professor 4 Assoc. Professor 1 Assist. Professor 8 Research Assist.

10 Technicians 2


Research StatisticsA

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International Journal Articles 7 National Journal Articles 5 Conference Proceeding Articles 9


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• 5000 square meter closed area

• 2 million € worth of equipment

• One of the well equipped student and

research laboratories in Turkey


Research Infrastructureat Department of Chemical Engineering

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Full Electrochemical System – SolartronFuel Cell Test FacilitiesGCGC-MSElemental AnalyzerAtomic Absorption AnalyzerHPLCFuel Test LabFTIRUV-VIS


Research Infrastructureat Faculty of Engineering and Architecture

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TEMSEMs (low vac. 0.6nm, EDX,WDX)AFMXRDs (Theta-Theta, up to 2000ºC, Rietveld) XRF TG-DTA/DSC BET FTIR ICP Mercury Porosimeter Rapid prototyping facilitiesWell equipped workshop GeT Univation!GeT Univation!

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II. Part

Presentation of University Based Innovation on PEMFC

PEM Fuel CellA

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Operating Temperature 20-80ºC

Power Output Upto 250 kW

Applications Portable, Transport, Military, Space

Required Power Cars(75 kW), Buses (250 kW)

H2 2H+ + 2e-, U0 =0 V ½ O2 + 2H+ + 2e- H2O, U0 = 1,229 V

Anode Cathode


Research Milestones

H2 production studies began in 1997.

PEMFC activities in Dept. of Chem. Eng. started in 2002.

Since then, our PEMFC cell activities have made a peak due

to collaborations with Juelich research institute,

Germany.

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• 2000 $218 million

• 2005 $2.4 billion (The Freedonia Group, Inc.)

• 2009 $7 billion (Business Com. Company, Inc.)

• 2020 $1.7 trillion (Price Waterhouse-Coopers)

• 2030 750,000 jobs (U.S. Dept. of Energy)

High cost of PEMFC components

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Material costs for a present-day fuel cell stackMaterial mass Material cost(kg/kW) (US$/kW)

Membrane 0.025 120Electrode 0.082 31.16Catalyst 0.016 243.2Bipolar plate 3.3 825End plate 0.12 0.24Plastic frame 0.105 0.105Total 3.684 1219.705

Lack of fueling infrastructure

Efficient, affordable hydrogen production and storage


Kwi Seong Jeong and Byeong Soo Oh Fuel economy and life-cycle cost analysis of a fuel cell hybrid vehicleJournal of Power Sources Volume 105, Issue 1 , 5 March 2002, Pages 58-65

http://www.sciencedirect.com/science?_ob=JournalURL&_cdi=5269&_auth=y&_acct=C000040859&_version=1&_urlVersion=0&_userid=736614&md5=0d9996411146cde5c7e99db53794b08c






http://www.sciencedirect.com/science?_ob=IssueURL&_tockey=%23TOC%235269%232002%23998949998%23289154%23FLA%23&_auth=y&view=c&_acct=C000040859&_version=1&_urlVersion=0&_userid=736614&md5=2ed520bd6d92e20924b257ed551aa42f




http://www.buchmann.ca/Article1-Page1.aspEnergySource

Investment of equipment to generate 1kW

Lifespan of equipment before major overhaul or replacement

Cost of fuelper kWh

Total Costper kWh, incl. fuel, maintenance and equipment replacement.

NiCdFor portable use

$7,000based on 7.2V, 1000mAh at $50/pack

1500 h based on 1C discharge

$0.15electricity for charging

$7.50

Gasoline EngineFor mobile use

$30based on $3,000/100kW (134HP)

4000 h $0.10 $0.14

Diesel Engine For stationary use

$40based on $4,000/100kW (134HP)

5000 h $0.07 $0.10

Fuel Cell $3,000 – 7,500 $0.35

For portable use 2000 h $0.35 $1.85 – 4.10

For mobile use 4000 h $0.35 $1.10 – 2.25

For stationary use 40,000 h $0.35 $0.45 – 0.55

Electricity From electric grid

All inclusive All inclusive 0.10 0.10

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1. Manufacture of Gas Diffusion Layer

2. MEA production by both conventional and sputter methods

3. Building up a FC test station upto 5 kW –hardware and software-

4. PEMFC stack manufacturing – 1 kW

5. Micro size -both active and passive- DMFC production


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Thickness : 300 μmCarbon content : 3-5 mg/cm2

PTFE content : 1-2 mg/cm2


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Conventional(Pt loading range: 0.1-5 mg Pt/cm2)

Sputtered(Pt loading range: 0.01-0.1 mg Pt/cm2)


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4 barg

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Current Density, mA/cm2

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E-TEK

PEM001

PEM002


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Current Density, mA/cm 2

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SP001

SP005

SP010

SP020


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Current Density, mA/cm 2

mW

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Pt

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SP005

SP001

SP010

SP020

SEM Image


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120 s

”The Europe of Knowledge 2020: A vision for university based research and

innovation” Liege 25-28 April’04

• Interdisiplinary Approach

• Relationship between Higher Education and Research

• University – Industry Relationship

• The effect of universities in the development of regional development

• Mobility of Researchers including between University and Industry

• Commercialisation of university based innovationAna

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•DAAD (Germany)

•Jülich Research Center (Germany)

•Technical University of Karlsruhe (Germany)

•Solitem Group (Germany)

•Louisiana State University (USA)

•NTNU, SINTEF and IFE (Norway)

•KTH (Sweden)

•UNIDO-ICHET (Turkey)


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Industrial Collaborations

• Arıkan Machinery Industry GmbH

• Demirdöküm DD Heating GmbH

• Savronik Defense Industry GmbH

On Going ProjectsA

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•Development of a 1 kW PEMFC stack

•Maximization of Pt Utilization at PEMFC Electrodes

using sputtering method

•Optimization of MEA Components

•Optimization of operating parameters of PEMFC

•Design and Testing of DMFC

•Design and Testing of Passive DMFC


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• High purity hydrogen production via steam reforming

of natural gas


• Combined Heat and Power (CHP) System for household application

• Transportation application of a PEMFC stack

• Capture, storage and electrochemical reduction of CO2 to CO

•Membrane for High Temperature PEMFC applications

•Non-Pt based electrocatalyst development for FCs

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If you have a problem for which our expertise could be of use, we would like to become your partner - please do not hesitate to contact us!

Contact Point

Assoc. Prof. Dr. Süleyman Kaytakoğlu Anadolu University

Dept. Of Chemical Engineering26555 - Eskişehir/Turkey

Phone: +90-222-3213550/Ext. 6306

Fax: +90-222-3239501E-mail: [email protected]

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Thank you for your attention


University Based Innovation on PEMFC in Turkey Assoc. Prof. Dr. Süleyman Kaytakoğlu Anadolu...

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Transcript of University Based Innovation on PEMFC in Turkey Assoc. Prof. Dr. Süleyman Kaytakoğlu Anadolu...