Sensory in Food : A Virtual Molecular Meal

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by Neil Wiltshire Senior Flavourist FlavourCraft - part of Kerry Ingredients & Flavours 11 July 2012 presented to the SAAFoST Sensory Forum Winter Warmer Sensory in Food : A Virtual Molecular Meal

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Sensory in Food : A Virtual Molecular Meal. presented to the SAAFoST Sensory Forum Winter Warmer. by Neil Wiltshire Senior Flavourist FlavourCraft - part of Kerry Ingredients & Flavours 11 July 2012. Starter 1 : Mushrooms. linoleic acid. enzyme. 1-octen-3-ol / "mushroom alcohol". - PowerPoint PPT Presentation

Transcript of Sensory in Food : A Virtual Molecular Meal

Page 1: Sensory in Food : A Virtual Molecular Meal

by Neil WiltshireSenior Flavourist

FlavourCraft - part of Kerry Ingredients & Flavours11 July 2012

presented to theSAAFoST Sensory Forum Winter Warmer

Sensory in Food :A Virtual Molecular Meal

Page 2: Sensory in Food : A Virtual Molecular Meal

Starter 1 : Mushrooms

OH

1-octen-3-ol / "mushroom alcohol"

linoleic acid

enzyme

disodium guanylate / GMP = umami / savoury taste

monosodium glutamate / MSG = umami / savoury taste

UMAMIindicates the presence of PROTEIN

HO

O

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Starter 2 : Peri-peri (chicken livers)- chillies, and other hot stuff...

NH

OO

HO

capsaicin = pungent / hot!

O

O O

N

piperine

OO

HO

OH

gingerol

OO

HO shogaol

trigeminal sense= sensory confusion!!

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Starter 3 : Garlic

cysteine (amino acid)

SO NH2

OH

O

SNH2

OH

O

OHOH

O

NH3

OH2O

OS SS S

NH2

OH

O

HS

alliin

alliinase(enzyme)

2-propenesulfenic acid

X 2

ammonia &pyruvic acid

allicin = antibacterial & antifungaldiallyl disulfide

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Main Course : Meat & Fish

lipids / fats > lipolysis > lipid oxidation=> fatty acids, aldehydes, esters, lactones- chicken = 2,4-alkadienals- beef = lactones & alkanals- lamb / mutton = 4-methyloctanoic acid & 4-methylnonanoic acid- pork = 2-alkenals

proteins / amino acids + sugars (+ lipids + thiamine / vitamin B1) > Maillard reaction=> very complex group of reactions> aldehydes, sulfur compounds, pyrazines, pyridines, thiazoles, thiazines, thiophenes, furans, etc., etc. > chicken & pork : cysteine NB. > beef : thiamine NB.

SSO

O

bis-(2-methyl-3-furyl) disulfide> odour = cooked meat / beefy- OT ~ 0.02 ppt => 1 drop / 500 Olympic pools

O

OH4-methyloctanoic acid

4-methylnonanoic acid

odour of both = fatty, goaty

NO

trimethylamine oxide

trimethylamine > odour = fishyN

OH

O

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Main Course : Curry / Spices

OH NH2

O

OHOH

HO O

NH2

O O

OH

coriander - linalool

OH

thyme - thymol

OH

cardamom - terpinyl acetate

O

O

ginger - zingiberene

OOHclove - eugenol

basil - eugenol & estragole

star-anise- anethole

cinnamon - cinnamaldehyde

O

O

O

fenugreek / methie

4-hydroxy-isoleucine (amino acid) 3-hydroxy-4,5-dimethyl-2(5H)-furanone / Sotolone > odour = burnt sugar / curry

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Dessert : Chocolate Mousse- sweet => sugar => carbohydrates / energy

ie. Lots of reasons to crave chocolate!!

- creamy, smooth, rich mouthfeel => source of fats = energy + building blocks- bitter => at high level = possible toxin BUT at low level = possible medicine... &/ psychoactive drug!

theobromine = Greek for "food of the gods"- present in the cacao seeds as a defense- bitter- stimulant and various therapeutic effects- at high levels, it becomes toxic- toxic to cats and dogs at even low levels

phenylalanine- amino acid

O

OHNH2

phenylethylamine- produced in the brain- especially associated with happiness and "falling in love"...

NH2

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Dessert : Chocolate Mousse

leucine - amino acid

NH2

O

OH

O

OHNH2

phenylalanine - amino acid

NH2H

NH2

H

NH3

NH3

O

O

O

O

CO2

CO2

O

O

O

5-methyl-2-phenyl-2-hexenal / cocoa aldehyde > char. cocoa odour

ammonia

ammonia

carbon dioxide

carbon dioxide

oxygen

* all reactions "catalyzed" by sugars and requiring heat (pH also important)

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Thank you very much for your attention,enjoy the meal

and have a wonderful evening...

Digesting the "Meal"...

- flavours from compounds already in foods (eg. spices)- flavours derived from precursors in foods - formed automatically in the food (eg. garlic) - formed by human or other outside influence on the food (eg. cooking)

=> result : lots of delicious flavours & foods to choose from!!