Sedimentary Mineral Associations

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    The Rock Cycle

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    Sedimentary Processes1

    2) & 3)

    Sediments aretransported and

    deposited

    4

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    Products of weather ing

    Primary Residual Dissolved

    Minerals Minerals Ions

    Feldspar Clay minerals K+, Ca+2, Na+

    Aluminum hydroxide

    Fe-Mg minerals Hematite & Mg+2

    Limonite

    Quartz Quartz Silica

    Primary Solids that Ions that are carried

    Minerals remain in soil away in water

    ----------Detrital sediments------------------ Chemical & biochemical sediments

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    Types o f sediment

    Detritalmineral & rock fragments Chemicalhalite (NaCl)crystalsthat precipitate from water

    Biochemicalshells made ofcalcite (CaCO3) by organisms

    that extract the ions from water

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    Detrital sedimentary rocks- classified by

    grain size differences

    Conglomerate

    Breccia

    Sandstone

    Shale

    All these rocks have clast ictexturesthe rocks are composed ofparticles (fragments) that are cemented together

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    Detr i tal sediments are so rted by the pro cesses of

    transportat ion and deposi t ion

    Well sorted Poorly sorted

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    Sands and sandstones can be used to interpret the erosional

    history of an area and the kinds of rocks that were eroded

    Well-

    sorted

    Poorly

    sorted

    Mature sediments have little feldspar. This means that the sediment was

    derived from weathered rocks or that the feldspar decomposed during

    transportation in water.

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    The same

    diagram is

    used to

    interpret the

    provenance(source rocks)

    of sediments

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    Placer depositaccumulation of sand or gravel containing minerals that are

    highly resistant to chemical attack and economically valuable - gold, platinum,

    ilmenite, rutile, zircon, diamond, garnet, magnetite, corundum, monazite.

    These and other chemically resistant minerals are widely used to indicate theprovenanceof sediments, e.g. kyanite, sillimanite, staurolite

    indicate that metamorphic rocks were eroded. Diamonds indicate kimberlite;gold indicates hydrothermal veins, etc.

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    Chemical and biochemical sedimentary rocks

    Limestonescomposed of calcite

    Travertine Coquina

    Chalk

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    Deep ocean sedimentsare mainly fine-grained biochemical

    sediment called oozes, with some hydrogenous(chemical)

    and terr igenous (wind or water borne) detrital sediment

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    Calcareous & siliceous ooze

    Manganese nodules are

    hydrogenous - they

    precipitate from deep ocean

    water when the Mn oxidizes:

    Mn+2(dissolved) + O2+ 2e- =

    MnO2(pyrolusite)

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    Banded Iron Format ionsancient (>2.5 billion year old) sedimentary deposits of iron-

    bearing minerals. These indicate that Earths early atmosphere was too poor in oxygen to

    oxidize iron at the site of weathering. Dissolved iron was transported in water:

    4Fe+2(dissolved) + 3O2= 2Fe2O3(hematite)

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    Phosphates form in shallow marine environments where dissolved PO4-3

    is carried by upwelling of deep ocean water. These areas are biologically

    productive - many fossils are found, especially bone material.

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    Phosphate Mining of the Bone Valley Formation in Florida

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    Evapori tes

    Gypsum

    Halite

    Seawater evaporation:

    1) Calcite

    2) Gypsum

    3) Anhydrite

    4) Halite (95% evaporation)

    5) Sylvite

    6) Other rare minerals

    Dolomite may form afterward by

    reaction of Mg+2with calcite

    Continental waters:Borax & borates

    Nitrates

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    Salt

    dome

    Sulfur is

    produced by

    sulfate

    reducingbacteria

    which

    consume the

    oxygen in

    gypsum oranhydrite