Section 5: Matter - Study Edge

28
Section 5: Matter The following maps the videos in this section to the Texas Essential Knowledge and Skills for Science TAC §112.35(c). 5.01 Matter Chemistry (4)(C) Chemistry (4)(D) 5.02 Properties of Matter Chemistry (4)(A) Chemistry (4)(B) 5.03 Dalton’s Atomic Theory of Matter Chemistry (6)(A) 5.04 Structure of the Nuclear Atom Chemistry (6)(A) 5.05 Shorthand Notation and Isotopes N/A 5.06 Calculating Atomic Mass Chemistry (6)(D) 5.07 The Periodic Table Chemistry (5)(A) 5.08 Bonding in Elements Chemistry (7)(D) 5.09 Naming Ions Chemistry (7)(A) Chemistry (7)(B) 5.10 Naming Ionic Compounds Chemistry (7)(A) Chemistry (7)(B) 5.11 Naming Covalent Compounds Chemistry (7)(A) Chemistry (7)(B) Copyright 2017 Licensed and Authorized for Use Only by Texas Education Agency 1

Transcript of Section 5: Matter - Study Edge

Page 1: Section 5: Matter - Study Edge

Section5:MatterThefollowingmapsthevideosinthissectiontotheTexasEssentialKnowledgeandSkillsforScienceTAC§112.35(c).5.01Matter

• Chemistry(4)(C)• Chemistry(4)(D)

5.02PropertiesofMatter

• Chemistry(4)(A)• Chemistry(4)(B)

5.03Dalton’sAtomicTheoryofMatter

• Chemistry(6)(A)5.04StructureoftheNuclearAtom

• Chemistry(6)(A)5.05ShorthandNotationandIsotopes

• N/A5.06CalculatingAtomicMass

• Chemistry(6)(D)5.07ThePeriodicTable

• Chemistry(5)(A)5.08BondinginElements

• Chemistry(7)(D)5.09NamingIons

• Chemistry(7)(A)• Chemistry(7)(B)

5.10NamingIonicCompounds

• Chemistry(7)(A)• Chemistry(7)(B)

5.11NamingCovalentCompounds

• Chemistry(7)(A)• Chemistry(7)(B)

Copyright 2017 Licensed and Authorized for Use Only by Texas Education Agency 1

Page 2: Section 5: Matter - Study Edge

5.12NamingAcidsandBases• Chemistry(7)(A)• Chemistry(7)(B)

Note:Unlessstatedotherwise,anysampledataisfictitiousandusedsolelyforthepurposeofinstruction.

SafetyNote:Anychemicalsmentionedinthesevideosarepotentiallyharmfulandshouldbehandledwiththeappropriatesafetyprecautions.

Copyright 2017 Licensed and Authorized for Use Only by Texas Education Agency 2

Page 3: Section 5: Matter - Study Edge

5.01

Matter

Matterisanythingthatoccupiesspaceandhasmass.

• Themassofanobjectisameasureoftheamountofmattertheobjectcontains.

• Thevolumeofanobjectisameasureoftheamountofspacetheobjectoccupies.

Matterhasthreestates:

• Asolidisaformofmatterthathasafixedshapeandvolume,whichmakesitalmostincompressible.

• Aliquidisaformofmatterthathasavariableshapewithafixedvolume.Liquidsarealmostincompressible,buttheytendtoexpandslightlywhenheated.

• Agasisaformofmatterthattakesboththeshapeandthevolumeofitscontainer.

o Gasparticlesaremuchfartherawayfromeachotherthantheparticlesinaliquid.Thisspacebetweentheparticlesiswhatmakesgasescompressible.

o Vapordescribesthegaseousstateofasubstancethatisgenerallyaliquidorsolidatroomtemperature.

1. Matterintheliquidstateis__________andhasa__________shape.A. incompressible;fixedB. compressible;variableC. incompressible;variableD. compressible;fixed

Copyright 2017 Licensed and Authorized for Use Only by Texas Education Agency 3

Page 4: Section 5: Matter - Study Edge

CompositionofMatter

• Matterthathasauniformanddefinitecompositioniscalledapuresubstance.

o Anelementisthesimplestformofmatterthathasauniquesetofproperties.

o Acompoundisasubstancethatcontainstwoormoreelementschemicallycombinedinafixedproportion.

• Asubstancecomposedoftwoormoredifferenttypesofatomsormoleculesthatcanbecombinedinvariableproportionsisamixture.

o Amixtureinwhichthecompositionisnotuniformthroughoutisaheterogeneousmixture.

o Amixtureinwhichthecompositionisuniformthroughoutisahomogeneousmixture.

o Asolutionisanothernameforahomogeneousmixture.

TechniquesforSeparatingMixtures

• Infiltration,weseparateasolidandaliquidbypouringthemixturethroughafilterthatallowstheliquidtopass,butnotthesolid.

• Indistillation,weseparatemiscibleliquids(forexample,liquidsthatmixtogetherequallyinallproportions)byboilingofftheonewithalowerboilingpoint.

2. Whichofthefollowingis/aretrue?i. Airisaheterogeneousmixture.ii. Contactlenssolutionisahomogeneousmixture.iii. Chromeisanelement.iv. Magnesiumisanelement.

A. iandiiB. iiandiiiC. ivonlyD. iiandiv

Copyright 2017 Licensed and Authorized for Use Only by Texas Education Agency 4

Page 5: Section 5: Matter - Study Edge

5.02

PropertiesofMatter

Physicalproperty–Aqualityorconditionofasubstancethatcanbeobservedormeasuredwithoutchangingthesubstance’scomposition

• Anextensivepropertydependsontheamountofmatterinasample.

o Mass

o Volume

• Anintensivepropertydependsonthetypeofmatterinasample,nottheamount.

o Absorbency

o Density

Aphysicalchangeoccurswhenthereisachangeinthestateofthesubstanceandnotthecompositionofthematerial.Physicalchangesareeitherreversibleorirreversible.

• Meltingiceisareversiblephysicalchange.

• Crackinganeggisanirreversiblephysicalchange.

Chemicalproperty–Apropertythatasubstancedisplaysonlybychangingitscompositionviaachemicalchange

Achemicalchangeisachangethatproducesmatterwithadifferentcompositionfromtheoriginalmatter.

Copyright 2017 Licensed and Authorized for Use Only by Texas Education Agency 5

Page 6: Section 5: Matter - Study Edge

1. Identifyeachofthefollowingaseitherachemicalorphysicalchange.i. Hammeringcopper(Cu)intowire:_______________

ii. Rustformingonametalbench:_______________

iii. Makingasolidhotenoughtogostraighttothegasphase:_______________

iv. Hydrogengasandoxygengascombiningtomakewater:_______________

2. Fourimportantpropertiesofaninorganiccompoundare(i)meltingpoint,(ii)corrosiveness,(iii)length,and(iv)reactivitywithacids.Whichchoicebelowcorrectlyclassifiesthesepropertiesasextensivephysical(EP),intensivephysical(IP),orchemical(C)?A. i=EP,ii=C,iii=IP,iv=CB. i=IP,ii=IP,iii=EP,iv=CC. i=C,ii=C,iii=EP,iv=CD. i=IP,ii=C,iii=EP,iv=C

Copyright 2017 Licensed and Authorized for Use Only by Texas Education Agency 6

Page 7: Section 5: Matter - Study Edge

5.03

Dalton’sAtomicTheoryofMatter

TheEnglishchemistJohnDalton(1766–1844)madeconclusionsaboutthenatureofmatterthatbecameknownasDalton’satomictheory,orDalton’spostulates.

1. Allmatterismadeofatoms.Atomsareindivisibleandindestructible.

2. Allatomsofagivenelementareidenticalbothinmassandinchemicalproperties.Theatomsofanyoneelementaredifferentfromthoseofanyotherelement.

3. Atomscombineinsimple,fixed,whole-numberratiostoformcompounds.

4. Chemicalreactionsoccurwhenatomsareseparatedfromeachother,joined,orrearrangedinadifferentcombination.Atomsofoneelement,however,areneverchangedintoatomsofanotherelementthroughachemicalreaction.

Dalton’satomictheoryledtothreelawsthathelpedexplaincompoundformationandchemicalreactions.

• Lawofdefiniteproportions–Samplesofanychemicalcompoundmaintainthesameproportionsoftheirconstituentelements.

• Lawofmultipleproportions–Wheneverthesametwoelementscombinetoformmorethanonecompound,thedifferentmassesofoneelementthatcombinewiththesamemassoftheotherelementareintheratioofsmallwholenumbers.

• Lawofconservationofmass–Inachemicalprocess,atomscannotbecreated,destroyed,orchanged—onlyrearrangedintodifferentcombinations.

1. WhichofthefollowingstatementsisnotapartofJohnDalton’satomictheory?A. Allatomsofagivenelementhavethesamemassandotherpropertiesthatdistinguish

themfromtheotherelements.B. Atomscombineinsimple,whole-numberratiostoformcompounds.C. Theatomhasanucleussurroundedbyelectrons.D. Eachelementiscomposedoftinyindestructibleparticlescalledatoms.

Copyright 2017 Licensed and Authorized for Use Only by Texas Education Agency 7

Page 8: Section 5: Matter - Study Edge

5.04

StructureoftheNuclearAtom

Dalton’satomictheoryiswidelyacceptedtoday,withoneimportantchange.Wenowknowthatatomscanbedividedintosmallerparticles.Thethreekindsofsubatomicparticlesareelectrons,protons,andneutrons.

• Electronsarenegativelychargedsubatomicparticles.

• Protonsarepositivelychargedsubatomicparticles.

• Neutronsaresubatomicparticleswithnochargebutwithamassnearlyequaltothatofprotons.

Eachelementhasitsownuniqueproperties.However,onanatomicscale,elementsareessentiallythesame.

• Everyatomisanelectricallyneutral,sphericalentity.

• Anatomiscomposedofacentralcoreofprotonsandneutrons,calledthenucleus,thatissurroundedbyelectrons.

• Aneutralatomcontainsequalnumbersofelectronsandprotons,butthisratiochangeswhenatomsbecomeions.

NuclearAtomDiscoveries

In1897,J.J.Thomson(1856–1940)discoveredthefirstsubatomicparticle,thenegativelychargedelectron,withthehelpofamodifiedcathoderaytube.Asaresult,Thomsonproposedthe“plum-puddingmodel”oftheatom.Inthismodel,electronswereevenlydistributedthroughoutanatomthatwasfilleduniformlywithpositivelychargedmaterial.

• Acathoderaytubeconsistsoftwoelectrodessealedinaglasscontainerwithgasatlowpressure.

o Whenavoltageisappliedtothecathode,aglowingbeam,orcathoderay,travelsfromthecathodetotheanode.

o Inhisexperiment,Thomsonplacedapositivelychargedplateononesideofthecathoderayandanegativelychargedplateontheotherside.

o Thecathoderaywasattractedtothepositivelychargedplate.Thomsonhypothesizedthatthecathoderaywasastreamofnegativelychargedparticlesmovingathighspeed.

o Aftertestinghishypothesis,heconcludedthatelectronsareacomponentoftheatomsofallelements.

Copyright 2017 Licensed and Authorized for Use Only by Texas Education Agency 8

Page 9: Section 5: Matter - Study Edge

Theplum-puddingmodelwasshort-lived.In1911,ErnestRutherford(1871–1937)discoveredapositivelychargedsubatomicparticle,theproton.Heusedthegold-foilexperimenttoprovehisconclusions.

• Thegold-foilexperimentusedanarrowbeamofalphaparticles(i.e.,particleswithadoublepositivecharge)directedataverythinsheetofgoldfoil.

o Mostofthealphaparticleswentstraightthroughthegoldfoilorwereslightlydeflected.

o Asmallfractionofthealphaparticlesbouncedoffthegoldfoilatverylargeangles.

• Rutherfordusedtheresultsofhisgold-foilexperimenttodeterminethattheatomwasmostlyemptyspace,sincemostofthealphaparticlespassedstraightthroughthegoldfoil,butthatithadaverydensenucleus,whichdeflectedsomeofthealphaparticles.

In1932,JamesChadwick(1891–1974)confirmedtheexistenceofanothersubatomicparticle,theneutron.

1. Selectthetruestatementfromthechoicesbelow.A. Thechargeofaprotonisequalinmagnitudebutoppositeinsigntothatofaneutron.B. Thegold-foilexperimentledtothediscoverythateachatomcontainsatiny,positively

charged,massivecentercalledthenucleus.C. Themassofaprotonisclosetothatofanelectron.D. Thegold-foilexperimentledtothediscoveryoftheelectron.

Copyright 2017 Licensed and Authorized for Use Only by Texas Education Agency 9

Page 10: Section 5: Matter - Study Edge

5.05

ShorthandNotationandIsotopes

ShorthandNotation

Elementsaredifferentfromoneanotherbecausetheycontaindifferentnumbersofprotons.Anelement’satomicnumberisthenumberofprotonsinthenucleusofanatomofthatelement.

Mostofanatom’smassisconcentratedinthenucleus.Themassdependsonthenumberofprotonsandelectrons.Thetotalnumberofprotonsandneutronsinanatomiscalledthemassnumber.

Thecompositionofanyatomcanberepresentedinshorthandnotationusingthemassnumberandtheatomicnumber.

!"#

Intheexampleabove,Xistheelementsymbol,Aisthemassnumber,andZistheatomicnumber.

Isotopes

Anisotopeisavariationofanelementthathasthesamenumberofprotonsandelectronsbutadifferentnumberofneutrons.

Isotopeshavevaryingnumbersofneutrons,whichmeanstheyhavedifferentmassnumbers.14Nand15Narebothisotopesofnitrogenbecausetheyhavethesameatomicnumberbutdifferentmassnumbers.

Copyright 2017 Licensed and Authorized for Use Only by Texas Education Agency 10

Page 11: Section 5: Matter - Study Edge

1. Completethefollowingtable:

!"# AtomicNumber NumberofNeutrons

$%&'('

45 59

2. Howmanyprotons(p+1),neutrons(n0),andelectrons(e-1)doestheisotope55Mnhave?A. 30p+1,25n0,25e-1B. 24p+1,33n0,22e-1C. 25p+1,30n0,25e-1D. 25p+1,25n0,30e-1

Copyright 2017 Licensed and Authorized for Use Only by Texas Education Agency 11

Page 12: Section 5: Matter - Study Edge

5.06

CalculatingAtomicMass

Calculatingthemassofelementsisdifficultbecausetheirmassesareverysmall.

RelativeMassesofSubatomicParticles

Themassofanatomismeasuredfromthenucleus.

• Protonsandneutronshaveapproximatelythesamemassof1atomicmassunit(amu).1amuequals1.67×10-24g.

• Electronshaverelativelynomass—about0.00055amuor9.109×10-28g.

Chemistshavedevisedasystemtocomparerelativemassesofatomsusingcarbon-12asareferenceisotope.Carbonhasbeenassignedamassofexactly12atomicmassunits.Anatomicmassunitisdefinedas1/12ofthemassofacarbon-12atom.

Sincemostofthemassofanatomisinthenucleus,therelativesystemabovewouldseemtoindicatethattheatomicmassofanelementshouldbeawholenumber,butthisisnotusuallythecase.

Innature,mostelementsoccurasamixtureoftwoormoreisotopes.Theatomicmass,sometimescalledtheaverageatomicmass,ofanelementisaweightedaveragemassoftheatomsinanaturallyoccurringsampleoftheelement.

Tocalculatetheatomicmassofanelement,multiplythemassofeachisotopebyitsnaturalabundance,expressedasadecimal,andthenaddtheproducts.

)*+,-.0122 = 15672+*+8%0122 91*:;1<)=:>?1>.%+ 2BC72+*+8%0122 91*:;1<)=:>?1>.% …

Copyright 2017 Licensed and Authorized for Use Only by Texas Education Agency 12

Page 13: Section 5: Matter - Study Edge

1. ElementZhasthreeisotopes:Z-31,Z-32,andZ-29.Z-29hasamassof28.98amuandis24.44%abundantinnature.Z-32hasamassof32.12amuandis32.65%abundantinnature.Z-31hasamassof31.23amu.CalculatetheatomicmassofelementZ.

Copyright 2017 Licensed and Authorized for Use Only by Texas Education Agency 13

Page 14: Section 5: Matter - Study Edge

5.07

ThePeriodicTable

Elementsarethefundamentalbuildingblocksthatmakeupallmatter.

• Theperiodictableisacompilationofallthediscoveredelements.

o Therowsinaperiodictablearereferredtoasperiods.

o Columnsoftheperiodictablearecalledgroups.

• Scientistshavediscoveredover116elements.Eachelementhasitsownuniquechemicalandphysicalproperties.

• Earlychemistsusedthechemicalandphysicalpropertiesofelementstosortthemintogroups.

Inthemid-19thcentury,theRussianchemistDmitriMendeleevnoticedthatcertaingroupsofelementshadsimilarproperties.Mendeleevproposedatablethatarrangedelementsperiodically—thatis,insetswithrepeatingpatterns—inorderofincreasingatomicmass.

Inthemodernperiodictable,elementsarearrangedinorderofincreasingatomicnumberbecausetherewereinconsistencieswithMendeleev’speriodictable.Whenelementsarearrangedinorderofincreasingatomicnumber,movinglefttorightacrossaperiod,theelementshavedifferentchemicalandphysicalproperties.However,thepatternofpropertieswithinaperiodrepeatsasyoumovefromoneperiodtothenext.Thisisreferredtoastheperiodiclaw.

BroadClassesofElements

• Metalsaregenerallygoodconductorsofheatandelectriccurrent.Mostmetalshaveahighlusterandareductileandmalleable.

• Nonmetalsarepoorconductorsofheatandelectriccurrent.Mostnonmetalsarebrittle,butingeneral,physicalpropertiesvarymoreamongnonmetalsthanamongmetals.

• Metalloidshavepropertiesofbothmetalsandnonmetals.Thebehaviorofmetalloidsdependsontheconditions.

1. Classifyeachofthefollowingaseitherametal(M)oranonmetal(N).

i.Bromine(Br) ii.Cobalt(Co) iii.Boron(B) iv.Potassium(K)

Copyright 2017 Licensed and Authorized for Use Only by Texas Education Agency 14

Page 15: Section 5: Matter - Study Edge

ClassifyingElementsinthePeriodicTable

Becauseoftheperiodiclaw,elementsthathavesimilarpropertiesendupinthesamecolumnintheperiodictable.Thesecolumnshavespecialnames,listedbelow,becauseofthesimilarityofthechemicalpropertiesofthoseelementswithinthecolumn.

• Elementsingroups1Athrough7Aarecalledrepresentativeelementsbecausetheydisplayawiderangeofchemicalandphysicalproperties.

• Themetallicelementsingroups1Athrough7Aoftheperiodictablearecalledmaingroupmetals.

• TheelementsingroupBarecalledtransitionelements.

o ThetransitionmetalsarethegroupBelementsthatareusuallydisplayedinthemainbodyofaperiodictable.Theseincludecopper,silver,andiron.

o TheinnertransitionmetalsarethegroupBelementsthatappearbelowthemainbodyoftheperiodictable.Theseincludeuraniumandplutonium.

Group Name Elements Properties

1A AlkaliMetalsLi,Na,K,Rb,Cs,

andFrSolidsatroomtemperatureandreactviolently

withwater

2AAlkalineEarth

MetalsBe,Mg,Ca,Sr,Ba,

andRaSolidsatroomtemperatureandreact

vigorouslywithoxygen

7A Halogens F,Cl,Br,I,andAtMostlygasesatroomtemperatureandform

saltswhenbondedtoametal

8A NobleGasesHe,Ne,Ar,Kr,Xe,

andRnInertmonatomicgasesatroomtemperature

2. Whichofthefollowingelementsbelongtothealkalineearthmetals?A. F,Cl,Br,I,AtB. He,Ne,Ar,Kr,Xe,RnC. Li,Na,K,Rb,Cs,FrD. Be,Mg,Ca,Sr,Ba,Ra

Copyright 2017 Licensed and Authorized for Use Only by Texas Education Agency 15

Page 16: Section 5: Matter - Study Edge

5.08

BondinginElements

Elementsbondtoformcompoundswhentheirouterelectronsinteract.Thebondingbetweenthethreebroadclassesofelementsoccursinthreegeneralways.

1. Whenametaldonatesitsouterelectronstoanonmetal,thiscreatesanionicbond.

• Theresultingcompoundiscalledanioniccompound.

• Themetalbecomesapositiveion(cation)andthenonmetalbecomesanegativeion(anion).

o Acationisproducedwhenanatomlosesoneormoreouterelectrons.

o Ananionisproducedwhenanatomgainsoneormoreouterelectrons.

• Althoughtheyarecomposedofions,ioniccompoundsareelectricallyneutral.

• Anioniccompoundisheldtogetherbytheelectrostaticforcesbetweentheoppositelychargedcationsandanions,whichattractoneanother.

• Aformulaunitisthelowestwhole-numberratioofionsinanioniccompound.

2. Whenanatomsharesitsouterelectronswithanotheratom’souterelectrons,thiscreatesacovalentbond.

• Amoleculeisaneutralgroupofatomsjoinedtogetherbycovalentbonds.

• Adiatomicmoleculeisamoleculethatcontainstwoatoms.

• Acompoundcomposedofmoleculesiscalledamolecularcompound.

3. Metalsbondinaspecialwaybecausetheirouterelectronsaremobileanddriftfreelyfromonepartofthemetaltoanother.

• Thiscreatesa“sea”ofelectronsthatarenottieddowntoanyatom.

• Metallicbondsaretheforcesofattractionbetweenthefree-floatingouterelectronsandthepositivelychargedmetalions.

Metallicbondingexplainsmanyofthedifferentmetallicpropertiesinametal.

• Ductility–Apropertyofametalthatenablesittobedrawnintoawire

• Malleability–Theabilityofametaltobehammeredorpressedintoshapes

• Electricalconductivity–Apropertythatenablesasubstancetoconductanelectriccurrentthroughtheflowofelectrons

• Thermalconductivity–Apropertythatenablesasubstancetotransferheat

Copyright 2017 Licensed and Authorized for Use Only by Texas Education Agency 16

Page 17: Section 5: Matter - Study Edge

1. Whichofthefollowingpropertiesofmetalsisnotexplainedbythe“electron-sea”modelofmetallicbonding?A. MalleabilityB. Metallicluster(shine)C. ElectricalconductivityD. ThermalconductivityE. Ductility

Copyright 2017 Licensed and Authorized for Use Only by Texas Education Agency 17

Page 18: Section 5: Matter - Study Edge

5.09

NamingIons

Ioniccompoundsconsistofpositivelychargedionsandnegativelychargedionscombinedinaproportionsothattheirchargesadduptoanetchargeofzero.

Monatomicion–Asingleatomwithapositiveornegativechargeresultingfromthelossorgain,respectively,ofoneormoreouterelectrons,calledvalenceelectrons

Whenthemetalsofgroups1A,2A,and3Aloseelectrons,theyformcationswithpositivechargesequaltotheirgroupnumber.Thenamesofthecationsarethesameasthenameofthemetal,followedbythewordionorcation.

• Al3+isthealuminumion

• Na+isthesodiumion

Nonmetalstendtogainelectronstoformanions,sothechargeofanonmetallicionisnegative.ThechargeofanyionofagroupAnonmetalisdeterminedbysubtracting8fromthegroupnumber.

• S2-isthesulfurion

• N3-isthenitrogenion

Thenameofananionisnotthesameastheelement’sname.Anionnamesstartwiththestemoftheelementnameandendin-ide.

1. Nametheionsformedbythefollowingelements.i. Barium

ii. Oxygen

iii. Chlorine

Copyright 2017 Licensed and Authorized for Use Only by Texas Education Agency 18

Page 19: Section 5: Matter - Study Edge

Manyofthetransitionmetals(groups1B–8B)formmultiplecationsthathavedifferentioniccharges.Thechargesofthecationsofmanytransitionmetalionsmustbedeterminedfromthenumberofelectronslost.

Therearetwomethodstonametransitionmetalswithdifferentioniccharges.

• Stocksystem–ARomannumeralinparenthesesafterthenameoftheelementindicatesthenumericalvalueofthecharge.

• Classicalsystem–Oneoftwosuffixes,attachedtotherootoftheLatinnamefortheion,indicateswhethertheionhasahigherorlowerioniccharge.

o Thesuffix-ousisusedtonamethecationwiththelowerofthetwoioniccharges.

o Thesuffix-icisusedtonamethecationwiththehigherofthetwoioniccharges.

Element IonFormula StockName ClassicalName

Chromium Cr2+ chromium(II) chromous

Cr3+ chromium(III) chromic

Copper Cu+ copper(I) cuprous

Cu2+ copper(II) cupric

Iron Fe2+ iron(II) ferrous

Fe3+ iron(III) ferric

Mercury Hg22+ mercury(I) mercurous

Hg2+ mercury(II) mercuric

Tin Sn2+ tin(II) stannous

Sn4+ tin(IV) stannic

2. Howmanyelectronswerelostorgainedtoformtheseions?i. Mn4+

ii. Zn2+

iii. As3-

Copyright 2017 Licensed and Authorized for Use Only by Texas Education Agency 19

Page 20: Section 5: Matter - Study Edge

Polyatomicion–Anioncomposedofmorethanoneatom,whichbehavesasaunitandcarriesacharge

Namingpolyatomicionsrequiressomememorizationofthenumberofatomsinandtheoverallchargeofeachion.

• ClO-ishypo–chlor–ite.

• ClO2-ischlor–ite.

• ClO3-ischlor–ate.

• ClO4-isper–chlor–ate.

Remembertheionswithan-ateending.Theseionsareverycommoninioniccompoundsandofferasystematicwaytonameotherions.

Somepolyatomicionshavedifferentendingsthatdonotfitthepatternabove:

• CN-isthecyanideanion.

• OH-isthehydroxideanion.

• NH4+istheammoniumcation.

WhentheformulaforapolyatomicionbeginswithH(hydrogen),youcanthinkoftheHasrepresentingahydrogenion(H+)combinedwithanotherpolyatomicion.

• HCO3-ishydrogencarbonate.

• H2PO4-isdihydrogenphosphate.

Copyright 2017 Licensed and Authorized for Use Only by Texas Education Agency 20

Page 21: Section 5: Matter - Study Edge

Name Formula

ammonium NH4+

hydroxide OH-cyanide CN-nitrate NO3

-ethanoate CH3COO

-orC2H3O2-

chlorate ClO3-

bromate BrO3-

iodate IO3-

sulfate SO42-

hydrogensulfate HSO4-

carbonate CO32-

hydrogencarbonate HCO3-

phosphate PO43-

hydrogenphosphate HPO42-

dihydrogenphosphate H2PO4-

permanganate MnO4-

chromate CrO42-

dichromate Cr2O72-

oxalate C2O42-

silicate SiO32-

3. Writethesymbolorchemicalformula(includingcharge)foreachofthefollowingions.i. Nitriteion

ii. Hydrogensulfiteion

iii. Perbromateion

Copyright 2017 Licensed and Authorized for Use Only by Texas Education Agency 21

Page 22: Section 5: Matter - Study Edge

5.10

NamingIonicCompounds

Binarycompound–Acompoundcomposedoftwoelements.Binarycompoundscanbeioniccompoundsormolecularcompounds.

Towritetheformulaofabinaryioniccompound,firstwritethesymbolofthecationandthenthatoftheanion.Then,addsubscriptsasneededtobalancethecharges.

Anothermethodisthe“crisscross”method:

• Crossoutthechargeofeachionandmakeitthesubscriptfortheotherion.

• Dropthecharges.

• Theformulaiscorrectbecausetheoverallchargeoftheformulaiszero,andthesubscriptsareexpressedasthelowestwhole-numberratio.

1. Writethechemicalformulasforthecompoundsformedbythefollowingpairsofions.i. Al3+andCl-

ii. Mg2+andSO42-

iii. Cr6+andN3-

2. Writethechemicalformulaforeachofthefollowingioniccompounds.i. Sodiumsulfide

ii. Aluminumphosphate

Copyright 2017 Licensed and Authorized for Use Only by Texas Education Agency 22

Page 23: Section 5: Matter - Study Edge

TipsforNamingIonicCompounds

• Placethecationnamefirst,followedbytheanionname.

• Ifthemetallicelementinthecompoundhasmorethanonecommonioniccharge,aRomannumeralmustbeincludedinthecationname.

• Whenevermorethanonepolyatomicionisneededtobalancethechargesinanioniccompound,useparenthesestosetoffthepolyatomicionintheformula.

3. Namethefollowingioniccompounds.i. ZnO

ii. Ag2Se

iii. Al2(SO4)3

4. Writechemicalformulasforthefollowingcompounds.i. Sodiumhydrogensulfate

ii. Nickel(II)sulfite

Copyright 2017 Licensed and Authorized for Use Only by Texas Education Agency 23

Page 24: Section 5: Matter - Study Edge

5.11

NamingMolecularCompounds

Molecularcompounds,orcovalentcompounds,arecomposedofmolecules,notions,soionicchargescannotbeusedtowritetheirformulasortonamethem.

Theprefixesbelowareusedinthenamesofmolecularcompoundstohelpdistinguishcompoundscontainingdifferentnumbersofatoms.Theprefixestellhowmanyatomsofanelementarepresentineachmoleculeofthecompound.

Prefix Number

mono- 1di- 2tri- 3

tetra- 4penta- 5hexa- 6hepta- 7octa- 8nona- 9deca- 10

Tonameamolecularcompound:

1. Writethenamesoftheelementsintheorderlistedintheformula.

2. Useprefixesappropriatelytoindicatethenumberofeachkindofatom.

• Omittheprefix“mono-”ifjustoneatomofthefirstelementispresent.

• Thevowelattheendofaprefixissometimesdroppedwhenthenameoftheelementbeginswithavowel.

3. Endthenameofthesecondelementwiththesuffix-ide.

Copyright 2017 Licensed and Authorized for Use Only by Texas Education Agency 24

Page 25: Section 5: Matter - Study Edge

1. Namethefollowingmolecularcompounds.i. Cl2O7

ii. SO3

iii. CO

2. Writetheformulasforthesemolecularcompounds.i. Oxygendifluoride

ii. Tetraphosphorousdecoxide

Copyright 2017 Licensed and Authorized for Use Only by Texas Education Agency 25

Page 26: Section 5: Matter - Study Edge

5.12

NamingAcidsandBasesAnacidisacompoundthatcontainsoneormorehydrogenatomsandproduceshydrogenionswhendissolvedinwater.

Whennaminganacid,considerittobeananionwithasmanyhydrogenionsneededtomakethecompoundelectricallyneutral.ThechemicalformulasofacidsareinthegeneralformHnX,whereXisamonatomicorpolyatomicanionandnisasubscriptindicatingthenumberofhydrogenionsthatarecombinedwiththeanion.

Acidnomenclaturedependsonthesuffixanionhas:

• Iftheanionnameendsin-ide,theacidnamebeginswiththeprefixhydro-.Thisprefixisattachedtothestemoftheanionwiththesuffix-ic,followedbythewordacid.

• Iftheanionnameendsin-ite,theacidnameisthestemoftheanionwiththesuffix-ous,followedbythewordacid.

• Iftheanionnameendsin-ate,theacidnameisthestemoftheanionwiththesuffix-ic,followedbythewordacid.

Whenwritingthechemicalformulaforanacid,usetheruleforwritingthenameoftheacidsinreverse.Besuretobalancetheionicchargesjustasyouwouldforanyioniccompound.

CommonAcids

AnionFormula AnionName AcidName AcidFormula

Br- Bromide Hydrobromicacid HBr

ClO31- Chlorate Chloricacid HClO3

SO32- Sulfite Sulfurousacid H2SO3

Copyright 2017 Licensed and Authorized for Use Only by Texas Education Agency 26

Page 27: Section 5: Matter - Study Edge

Abaseisgenerallyanioniccompoundthatproduceshydroxideionswhendissolvedinwater.

• Usetherulesfornamingioniccompoundstonamebases.

• Whenwritingthechemicalformulaforabase,writethemetalcationfirst,followedbytheformulaforthehydroxideion.

• Balancetheionicchargesasyouwouldforanyioniccompound.

1. Nameeachacidorbasebelow.

i. HCl

ii. HNO3

iii. Sr(OH)2

iv. CsOH

2. Writeformulasforthefollowingacidsandbases.i. Hydrosulfuricacid

ii. Perchloricacid

iii. Aluminumhydroxide

iv. Iron(II)hydroxide

Copyright 2017 Licensed and Authorized for Use Only by Texas Education Agency 27

Page 28: Section 5: Matter - Study Edge

Copyright 2017 Licensed and Authorized for Use Only by Texas Education Agency 28