SAFETY DATA SHEET T-REX solvent based · Product name : T-REX solvent based Product type REACH :...

SAFETY DATA SHEET

Based upon Regulation (EC) No. 1907/2006, as amended by Regulation (EC) No. 453/2010

T-REX solvent based SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1 Product identifier: Product name : T-REX solvent based Product type REACH : Mixture 1.2 Relevant identified uses of the substance or mixture and uses advised against:

1.2.1 Relevant identified uses Adhesive

1.2.2 Uses advised against No uses advised against known

1.3 Details of the supplier of the safety data sheet:

Supplier of the safety data sheet SOUDAL N.V.

Everdongenlaan 18-20 B-2300 Turnhout ☎ +32 14 42 42 31 � +32 14 42 65 14 [email protected]

Manufacturer of the product SOUDAL N.V.

Everdongenlaan 18-20 B-2300 Turnhout ☎ +32 14 42 42 31 � +32 14 42 65 14 [email protected]

1.4 Emergency telephone number: 24h/24h (Telephone advice: English, French, German, Dutch): +32 14 58 45 45 (BIG)

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture:

2.1.1 Classification according to Regulation EC No 1272/2008 Classified as dangerous according to the criteria of Regulation (EC) No 1272/2008 Class Category Hazard statements Flam. Liq. category 2 H225: Highly flammable liquid and vapour. Skin Irrit. category 2 H315: Causes skin irritation. Aquatic Chronic category 3 H412: Harmful to aquatic life with long lasting effects.

2.1.2 Classification according to Directive 67/548/EEC-1999/45/EC Classified as dangerous in accordance with the criteria of Directives 67/548/EEC and 1999/45/EC F; R11 - Highly flammable. R67 - Vapours may cause drowsiness and dizziness. R52-53 - Harmful to aquatic organisms. May cause long-term adverse effects in the aquatic environment. 2.2 Label elements: Labelling according to Regulation EC No 1272/2008 (CLP) Classification and labelling according to the criteria of Regulation (EU) No 487/2013, 4th adaptation of Regulation (EC) No 1272/2008 and after evaluation of

available test data

Signal word Danger

Created by: Brandweerinformatiecentrum voor gevaarlijke stoffen vzw (BIG)Technische Schoolstraat 43 A, B-2440 Geel http://www.big.be © BIG vzw

Publication date: 2013-07-15

134-

1596

0-42

5-en

Date of revision: 2014-02-11

Reason for revision: 2.2

Revision number: 0001 Product number: 54231 1 / 22

T-REX solvent based H-statements H225 Highly flammable liquid and vapour. H315 Causes skin irritation. H412 Harmful to aquatic life with long lasting effects. P-statements P101 If medical advice is needed, have product container or label at hand. P102 Keep out of reach of children. P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P280 Wear protective gloves and eye protection/face protection. P332 + P313 If skin irritation occurs: Get medical advice/attention. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. P403 + P235 Store in a well-ventilated place. Keep cool. P501 Dispose of contents/container in accordance with local/regional/national/international regulation.

Labelling according to Directive 67/548/EEC-1999/45/EC (DSD/DPD) Labels

Highly flammable R-phrases 52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment 67 Vapours may cause drowsiness and dizziness S-phrases (02) (Keep out of the reach of children) 16 Keep away from sources of ignition - No smoking (46) (If swallowed, seek medical advice immediately and show this container or label) 61 Avoid release to the environment. Refer to special instructions/safety data sheets.

2.3 Other hazards:

CLP May be ignited by sparks Gas/vapour spreads at floor level: ignition hazard Slightly irritant to eyes Caution! Substance is absorbed through the skin

DSD/DPD May be ignited by sparks Gas/vapour spreads at floor level: ignition hazard Slightly irritant to eyes Caution! Substance is absorbed through the skin

SECTION 3: Composition/information on ingredients 3.1 Substances: Not applicable

3.2 Mixtures:

Name (REACH Registration No) CAS No

EC No Conc. (C) Classification according to DSD/DPD

Classification according to CLP Note Remark

hydrocarbons, C6-C7, n-alkanes, isoalkanes, cyclics, < 5% n-hexane (01-2119475514-35)

2.5%<C<10%

F; R11Xn; R65 Xi; R38 R67 N; R51-53

Flam. Liq. 2; H225 Asp. Tox. 1; H304 Skin Irrit. 2; H315 STOT SE 3; H336 Aquatic Chronic 2; H411

(1)(10) UVCB

hydrocarbons, C7, n-alkanes, isoalkanes, cyclics (01-2119475514-33)

2.5%<C<10%

F; R11Xn; R65 Xi; R38 R67 N; R51-53

Flam. Liq. 2; H225 Asp. Tox. 1; H304 Skin Irrit. 2; H315 STOT SE 3; H336 Aquatic Chronic 2; H411

(1)(10) UVCB

Reason for revision: 2.2 Publication date: 2013-07-15 Date of revision: 2014-02-11


T-REX solvent based xylene (01-2119488216-32) 1330-20-7

215-535-7 1%<C<12.5%

Xn; R20/21Xi; R38 R10

Flam. Liq. 3; H226 Acute Tox. 4; H332 Acute Tox. 4; H312 Skin Irrit. 2; H315

(1)(2)(8)(10) Constituent

ethylbenzene ( - ) 100-41-4 202-849-4

1%<C<10%

F; R11Xn; R20

Flam. Liq. 2; H225 Acute Tox. 4; H332

(1)(2)(10) Constituent

acetone (01-2119471330-49) 67-64-1 200-662-2

1%<C<10%

F; R11Xi; R36 R66 R67

Flam. Liq. 2; H225 Eye Irrit. 2; H319 STOT SE 3; H336

(1)(2)(10) Constituent

(1) For R-phrases and H-statements in full: see heading 16 (2) Substance with a Community workplace exposure limit (8) Specific concentration limits, see heading 16 (10) Subject to restrictions of Annex XVII of Regulation (EC) No. 1907/2006

SECTION 4: First aid measures

4.1 Description of first aid measures: General: GENERAL. Check the vital functions. Unconscious: maintain adequate airway and respiration. Respiratory arrest: artificial respiration or oxygen. Cardiac arrest:

perform resuscitation. Victim conscious with laboured breathing: half-seated. Victim in shock: on his back with legs slightly raised. Vomiting: prevent asphyxia/aspiration pneumonia. Prevent cooling by covering the victim (no warming up). Keep watching the victim. Give psychological aid. Keep the victim calm, avoid physical strain. Depending on the victim's condition: doctor/hospital.

After inhalation: Remove the victim into fresh air. Respiratory problems: consult a doctor/medical service. After skin contact: Wash immediately with lots of water (15 minutes)/shower. Soap may be used. Take victim to a doctor if irritation persists. After eye contact: Rinse with water. Take victim to an ophthalmologist if irritation persists. After ingestion: Rinse mouth with water. Immediately after ingestion: give lots of water to drink. Do not induce vomiting. Consult a doctor/medical service if you feel unwell.

4.2 Most important symptoms and effects, both acute and delayed: 4.2.1 Acute symptoms After inhalation: EXPOSURE TO HIGH CONCENTRATIONS: Headache. Nausea. After skin contact: Tingling/irritation of the skin. ON CONTINUOUS EXPOSURE/CONTACT: Dry skin. Cracking of the skin. After eye contact: Slight irritation. After ingestion: No effects known. 4.2.2 Delayed symptoms No effects known.

4.3 Indication of any immediate medical attention and special treatment needed: If applicable and available it will be listed below.

SECTION 5: Firefighting measures

5.1 Extinguishing media: 5.1.1 Suitable extinguishing media: Polyvalent foam. BC powder. Carbon dioxide. 5.1.2 Unsuitable extinguishing media: No unsuitable extinguishing media known. 5.2 Special hazards arising from the substance or mixture: Upon combustion: CO and CO2 are formed.

5.3 Advice for firefighters: 5.3.1 Instructions: Take account of environmentally hazardous firefighting water. Use water moderately and if possible collect or contain it. 5.3.2 Special protective equipment for fire-fighters: Gloves. Protective clothing. Heat/fire exposure: compressed air/oxygen apparatus.

SECTION 6: Accidental release measures Reason for revision: 2.2 Publication date: 2013-07-15



T-REX solvent based

6.1 Personal precautions, protective equipment and emergency procedures: Stop engines and no smoking. No naked flames or sparks. Spark- and explosionproof appliances and lighting equipment. 6.1.1 Protective equipment for non-emergency personnel See heading 8.2 6.1.2 Protective equipment for emergency responders Gloves. Protective clothing. Suitable protective clothing See heading 8.2

6.2 Environmental precautions: Contain leaking substance. Dam up the solid spill. Try to reduce evaporation. Prevent soil and water pollution. Prevent spreading in sewers. Use appropriate

containment to avoid environmental contamination.

6.3 Methods and material for containment and cleaning up: Scoop solid spill into closing containers. Carefully collect the spill/leftovers. Clean contaminated surfaces with an excess of water. Wash clothing and equipment

after handling. 6.4 Reference to other sections: See heading 13.

SECTION 7: Handling and storage The information in this section is a general description. If applicable and available, exposure scenarios are attached in annex. Always use the relevant exposure

scenarios that correspond to your identified use.

7.1 Precautions for safe handling: Keep away from naked flames/heat. Insufficient ventilation: keep naked flames/sparks away. Gas/vapour heavier than air at 20°C. Observe normal hygiene

standards. Keep container tightly closed. Remove contaminated clothing immediately. Do not discharge the waste into the drain. Insufficient ventilation: use spark-/explosionproof appliances and lighting system.

7.2 Conditions for safe storage, including any incompatibilities: 7.2.1 Safe storage requirements: Storage temperature: 20 °C. Store in a dry area. Ventilation at floor level. Store at room temperature. Meet the legal requirements. Max. storage time: 1

year(s). 7.2.2 Keep away from: Heat sources, ignition sources. 7.2.3 Suitable packaging material: Synthetic material. 7.2.4 Non suitable packaging material: No data available

7.3 Specific end use(s): If applicable and available, exposure scenarios are attached in annex. See information supplied by the manufacturer.

SECTION 8: Exposure controls/personal protection 8.1 Control parameters: 8.1.1 Occupational exposure a) Occupational exposure limit values If limit values are applicable and available these will be listed below.

The Netherlands Aceton Short time value 1002 ppm

2420 mg/m³ Public occupational exposure limit value

Time-weighted average exposure limit 8 h 501 ppm1210 mg/m³

Public occupational exposure limit value

Ethylbenzeen Short time value 97 ppm430 mg/m³




Xyleen (o-,m- en p-isomeren) Short time value 100 ppm442 mg/m³




EU



T-REX solvent based Acetone Time-weighted average exposure limit 8 h 500 ppm

1210 mg/m³ Indicative occupational exposure limit value

Ethylbenzene Short time value 200 ppm884 mg/m³

Indicative occupational exposure limit value



Xylene, mixed isomers, pure Short time value 100 ppm442 mg/m³




Belgium

Acétone Short time value 1000 ppm2420 mg/m³


Ethylbenzène Short time value 125 ppm551 mg/m³


Xylène, isomères mixtes, purs Short time value 100 ppm442 mg/m³


USA (TLV-ACGIH)

Acetone Short time value 750 ppm TLV - Adopted Value Time-weighted average exposure limit 8 h 500 ppm TLV - Adopted Value Ethyl benzene Time-weighted average exposure limit 8 h 20 ppm TLV - Adopted Value Xylene (all isomers) Short time value 150 ppm TLV - Adopted Value Time-weighted average exposure limit 8 h 100 ppm TLV - Adopted Value

Germany Aceton Time-weighted average exposure limit 8 h 500 ppm

1200 mg/m³ TRGS 900

Ethylbenzol Time-weighted average exposure limit 8 h 20 ppm88 mg/m³

TRGS 900

Xylol (alle Isomeren) Time-weighted average exposure limit 8 h 100 ppm440 mg/m³

TRGS 900

France

Acétone Short time value 1000 ppm2420 mg/m³

VRC: Valeur réglementaire contraignante



Ethylbenzène Short time value 100 ppm442 mg/m³


Time-weighted average exposure limit 8 h 20 ppm88.4 mg/m³


Xylènes, isomères mixtes, purs Short time value 100 ppm442 mg/m³




UK

Acetone Short time value 1500 ppm3620 mg/m³

Workplace exposure limit (EH40/2005)



Ethylbenzene Short time value 125 ppm552 mg/m³




Xylene, o-,m-,p- or mixed isomers Short time value 100 ppm441 mg/m³




T-REX solvent based Xylene, o-,m-,p- or mixed isomers Time-weighted average exposure limit 8 h 50 ppm

220 mg/m³ Workplace exposure limit (EH40/2005)

b) National biological limit values If limit values are applicable and available these will be listed below. 8.1.2 Sampling methods Product name Test Number Acetone OSHA 69 Acetone (ketones 1) NIOSH 1300 Acetone (ketones I) NIOSH 2555 Acetone (organic and inorganic gases by Extractive FTIR) NIOSH 3800 Acetone (Volatile Organic compounds) NIOSH 2549 Ethyl Benzene OSHA 7 Ethyl Benzene (Hydrocarbons, Aromatic) NIOSH 1501 No data available Petroleum Distillate (Naphthas) NIOSH 1550 Petroleum Distillates fractions OSHA 48 Xylene (Hydrocarbons, aromatic) NIOSH 1501 Xylene (o-, m-, & p-isomers) OSHA 7 Xylene (Volatile Organic compounds) NIOSH 2549 8.1.3 Applicable limit values when using the substance or mixture as intended If limit values are applicable and available these will be listed below. 8.1.4 DNEL/PNEC values DNEL - Workers hydrocarbons, C6-C7, n-alkanes, isoalkanes, cyclics, < 5% n-hexane Effect level (DNEL/DMEL) Type Value Remark DNEL Long-term systemic effects inhalation 2035 mg/m³ Long-term systemic effects dermal 773 mg/kg bw/day hydrocarbons, C7, n-alkanes, isoalkanes, cyclics Effect level (DNEL/DMEL) Type Value Remark 2085 mg/m³ DNEL Long-term systemic effects dermal 300 mg/kg bw/day xylene Effect level (DNEL/DMEL) Type Value Remark DNEL Acute systemic effects inhalation 289 mg/m³ Acute local effects inhalation 289 mg/m³ Long-term systemic effects dermal 180 mg/kg bw/day Long-term systemic effects inhalation 77 mg/m³ ethylbenzene Effect level (DNEL/DMEL) Type Value Remark DNEL Acute local effects inhalation 293 mg/m³ Long-term systemic effects dermal 180 mg/kg bw/day Long-term systemic effects inhalation 77 mg/m³ acetone Effect level (DNEL/DMEL) Type Value Remark DNEL Acute local effects inhalation 2420 mg/m³ Long-term systemic effects dermal 186 mg/kg bw/day Long-term systemic effects inhalation 1210 mg/m³ DNEL - General population hydrocarbons, C6-C7, n-alkanes, isoalkanes, cyclics, < 5% n-hexane Effect level (DNEL/DMEL) Type Value Remark DNEL Long-term local effects inhalation 608 mg/m³ Long-term systemic effects dermal 699 mg/kg bw/day Long-term systemic effects oral 699 mg/kg bw/day hydrocarbons, C7, n-alkanes, isoalkanes, cyclics Effect level (DNEL/DMEL) Type Value Remark DNEL Long-term local effects inhalation 447 mg/m³ Long-term systemic effects dermal 149 mg/kg bw/day Long-term systemic effects oral 149 mg/kg bw/day



T-REX solvent based xylene Effect level (DNEL/DMEL) Type Value Remark DNEL Acute systemic effects inhalation 174 mg/m³ Acute local effects inhalation 174 mg/m³ Long-term systemic effects dermal 108 mg/kg bw/day Long-term systemic effects inhalation 14.8 mg/m³ Long-term systemic effects oral 1.6 mg/kg bw/day ethylbenzene Effect level (DNEL/DMEL) Type Value Remark DNEL Long-term systemic effects inhalation 15 mg/m³ Long-term systemic effects oral 1.6 mg/kg bw/day acetone Effect level (DNEL/DMEL) Type Value Remark DNEL Long-term systemic effects dermal 62 mg/kg bw/day Long-term systemic effects inhalation 200 mg/m³ Long-term systemic effects oral 62 mg/kg bw/day PNEC xylene Compartments Value Remark Fresh water 0.327 mg/l Marine water 0.327 mg/l Aqua (intermittent releases) 0.327 mg/l STP 6.58 mg/l Fresh water sediment 12.46 mg/kg sediment dw Marine water sediment 12.46 mg/kg sediment dw Soil 2.31 mg/kg soil dw ethylbenzene Compartments Value Remark Fresh water 0.1 mg/l Marine water 0.01 mg/l Aqua (intermittent releases) 0.1 mg/l STP 9.6 mg/l Fresh water sediment 13.7 mg/kg sediment dw Soil 2.68 mg/kg soil dw Oral 0.02 g/kg food acetone Compartments Value Remark Fresh water 10.6 mg/l Marine water 1.06 mg/l Aqua (intermittent releases) 21 mg/l Fresh water sediment 30.4 mg/kg sediment dw Marine water sediment 3.04 mg/kg sediment dw Soil 29.5 mg/kg soil dw STP 100 mg/l 8.1.5 Control banding If applicable and available it will be listed below. 8.2 Exposure controls: The information in this section is a general description. If applicable and available, exposure scenarios are attached in annex. Always use the relevant exposure

scenarios that correspond to your identified use. 8.2.1 Appropriate engineering controls Keep away from naked flames/heat. Insufficient ventilation: keep naked flames/sparks away. Measure the concentration in the air regularly. Work under local

exhaust/ventilation. 8.2.2 Individual protection measures, such as personal protective equipment Observe normal hygiene standards. Keep container tightly closed. Do not eat, drink or smoke during work. a) Respiratory protection: Wear gas mask with filter type A if conc. in air > exposure limit. b) Hand protection: Gloves. c) Eye protection: Protective goggles. d) Skin protection:



T-REX solvent based Protective clothing. 8.2.3 Environmental exposure controls: See headings 6.2, 6.3 and 13

SECTION 9: Physical and chemical properties 9.1 Information on basic physical and chemical properties: Physical form Paste

Odour Characteristic odour

Odour threshold No data available

Colour Variable in colour, depending on the composition Particle size No data available

Explosion limits No data available

Flammability Highly flammable liquid and vapour. Log Kow Not applicable (mixture)

Dynamic viscosity No data available

Kinematic viscosity No data available

Melting point No data available Boiling point No data available

Flash point < 23 °C

Evaporation rate No data available Vapour pressure < 1100 hPa ; 50 °C

Relative vapour density > 1

Solubility water ; insoluble organic solvents ; soluble Relative density 1.36

Decomposition temperature No data available

Auto-ignition temperature No data available Explosive properties No chemical group associated with explosive properties

Oxidising properties No chemical group associated with oxidising properties

pH No data available

Physical hazards

No physical hazard class

9.2 Other information: Absolute density 1360 kg/m³

SECTION 10: Stability and reactivity 10.1 Reactivity: May be ignited by sparks. Gas/vapour spreads at floor level: ignition hazard. No data available.

10.2 Chemical stability: Stable under normal conditions.

10.3 Possibility of hazardous reactions: No data available. 10.4 Conditions to avoid: Keep away from naked flames/heat. Insufficient ventilation: keep naked flames/sparks away.

10.5 Incompatible materials: No data available.

10.6 Hazardous decomposition products: Upon combustion: CO and CO2 are formed.

SECTION 11: Toxicological information

11.1 Information on toxicological effects: 11.1.1 Test results



T-REX solvent based Acute toxicity

T-REX solvent based No (test)data on the mixture available hydrocarbons, C6-C7, n-alkanes, isoalkanes, cyclics, < 5% n-hexane Route of exposure Parameter Method Value Exposure time Species Gender Value

determination Oral LD50 Other >5840 mg/kg bw Rat Male/female Read-across Dermal LD50 Other >2800 mg/kg bw 24 week(s) Rat Male/female Similar product Inhalation (vapours) LC50 Other >25.2 mg/l 4 h Rat Male/female Experimental value hydrocarbons, C7, n-alkanes, isoalkanes, cyclics Route of exposure Parameter Method Value Exposure time Species Gender Value

determination Oral LD50 Other >5840 mg/kg bw Rat Male/female Read-across Dermal LD50 Other >2800 mg/kg bw 24 week(s) Rat Male/female Read-across Inhalation (vapours) LC50 Equivalent to OECD

403 >23.3 mg/l 4 h Rat Male/female Read-across

xylene Route of exposure Parameter Method Value Exposure time Species Gender Value

determination Oral LD50 OECD 401 5627 mg/kg bw Mouse Male Experimental value Dermal LD50 OECD 402 >4200 mg/kg bw 4 h Rabbit Male Experimental value Inhalation LC50 OECD 403 27.57 mg/l 4 h Rat Male Experimental value ethylbenzene Route of exposure Parameter Method Value Exposure time Species Gender Value

determination Oral (one dose) LD50 3500 mg/kg Rat Male/female Experimental value Dermal LD50 Other 15432 mg/kg 24 h Rabbit Male Experimental value Inhalation LC50 Other 4000 ppm 4 h Rat Male Literature study acetone Route of exposure Parameter Method Value Exposure time Species Gender Value

determination Oral LD50 Equivalent to OECD

401 5800 mg/kg Rat Female Experimental value

Dermal LD50 Equivalent to OECD 402

20000 mg/kg Rabbit Male Experimental value

Inhalation (vapours) LC50 Other 76 mg/l 4 h Rat Female Experimental value Inhalation (vapours) LCL0 Other 16000 ppm 4 h Rat Experimental value Judgement is based on the relevant ingredients Conclusion Not classified for acute toxicity

Corrosion/irritation

T-REX solvent based No (test)data on the mixture available hydrocarbons, C6-C7, n-alkanes, isoalkanes, cyclics, < 5% n-hexane Route of exposure Result Method Exposure time Time point Species Value determination Eye Not irritating Other Rabbit Read-across Skin Irritating Equivalent to OECD

404 4 h 24; 48; 72 hours Rabbit Experimental value

hydrocarbons, C7, n-alkanes, isoalkanes, cyclics Route of exposure Result Method Exposure time Time point Species Value determination Eye Not irritating Other Rabbit Read-across Skin Irritating Equivalent to OECD

404 4 h 24; 48; 72 hours Rabbit Read-across

xylene Route of exposure Result Method Exposure time Time point Species Value determination Eye Moderately

irritating OECD 405 24; 48; 72 hours Rabbit Experimental value

Skin Irritating OECD 404 24 h 24; 72 hours Rabbit Experimental value



T-REX solvent based ethylbenzene Route of exposure Result Method Exposure time Time point Species Value determination Eye Slightly irritating Other 7 days Rabbit Experimental value Skin Moderately

irritating Other 24 h Rabbit Experimental value

acetone Route of exposure Result Method Exposure time Time point Species Value determination Eye Irritating OECD 405 24; 48; 72 hours Rabbit Experimental value Skin Not irritating Other 3 day(s) 24; 48; 72 hours Guinea pig Experimental value Inhalation Slightly irritating Human observation

study 20 minutes Human Literature

Classification is based on the relevant ingredients Conclusion Causes skin irritation.

Respiratory or skin sensitisation

T-REX solvent based No (test)data on the mixture available hydrocarbons, C6-C7, n-alkanes, isoalkanes, cyclics, < 5% n-hexane Route of exposure Result Method Exposure time Observation time

point Species Gender Value

determination Skin Not sensitizing Equivalent to OECD

406 24; 48 hours Guinea pig Male/female Read-across

hydrocarbons, C7, n-alkanes, isoalkanes, cyclics Route of exposure Result Method Exposure time Observation time


determination Skin Not sensitizing Equivalent to OECD

406 24; 48 hours Guinea pig Male/female Read-across

xylene Route of exposure Result Method Exposure time Observation time


determination Skin Not sensitizing OECD 429 Mouse Experimental value ethylbenzene Route of exposure Result Method Exposure time Observation time


determination Skin Not sensitizing Other Human Inconclusive,

insufficient data acetone Route of exposure Result Method Exposure time Observation time


determination Skin Not sensitizing Human observation Human Literature Judgement is based on the relevant ingredients Conclusion Not sensitizing for skin

Specific target organ toxicity

T-REX solvent based No (test)data on the mixture available hydrocarbons, C6-C7, n-alkanes, isoalkanes, cyclics, < 5% n-hexane Route of exposure Parameter Method Value Organ Effect Exposure time Species Gender Value

determination Inhalation

(vapours) NOAEC Other 4200 mg/m³

air No effect 3 days (8h/day) Rat Male Experimental

value Inhalation

(vapours) NOAEC Equivalent to

OECD 413 6646 ppm No effect 13 weeks (6h/day, 5

days/week) Rat Male/femal

e Read-across

Inhalation (vapours)

NOAEC Equivalent to OECD 413

2220 ppm No effect 13 weeks (6h/day, 5 days/week)

Rat Male/female

Read-across


LOAEC Other 14 g/m³ Central nervous system

Behavioural disturbances

3 days (8h/day) Rat Male Experimental value



T-REX solvent based hydrocarbons, C7, n-alkanes, isoalkanes, cyclics Route of exposure Parameter Method Value Organ Effect Exposure time Species Gender Value

determination Inhalation

(vapours) NOAEC Other 12470 mg/m³

air Central nervous system

No effect 16 weeks (daily) Rat Male Read-across


LOAEL Equivalent to OECD 413

1650 mg/m³ air

Central nervous system

CNS depression 26 weeks (6h/day, 5 days/week)

Rat Male/female

Read-across

xylene Route of exposure Parameter Method Value Organ Effect Exposure time Species Gender Value

determination Oral LOAEL Equivalent to

OECD 408 150 mg/kg bw/day

Liver Weight gain 90 day(s) Rat Male/female

Experimental value


NOAEC >=3515 mg/m³

No effect 13 weeks (6h/day, 5 days/week)

Rat Male Experimental value

ethylbenzene Route of exposure Parameter Method Value Organ Effect Exposure time Species Gender Value

determination Oral NOAEL OECD 407 75 mg/kg

bw/day No effect 28 day(s) Rat Male/femal

e Experimental value

Oral NOAEL OECD 408 75 mg/kg bw/day

No effect 13 week(s) Rat Male/female

Experimental value

Oral LOAEL OECD 408 250 mg/kg bw/day

Liver Enlargement/affection of the liver

13 week(s) Rat Male/female

Experimental value

Oral NOAEL Equivalent to OECD 424

500 mg/kg bw/day

No effect 90 day(s) Rat Male/female

Experimental value

Inhalation NOAEL Equivalent to OECD 453


Rat Male/female

Experimental value

Inhalation NOAEL Equivalent to OECD 413


Rat Male/female

Experimental value

acetone Route of exposure Parameter Method Value Organ Effect Exposure time Species Gender Value

determination Oral NOAEL Equivalent to

OECD 408 20 mg/l No effect 13 week(s) Mouse Male/femal

e Experimental value

Dermal Not relevant, expert judgement


NOAEC Other 19000 ppm No effect 8 week(s) Rat Male Literature


Human observation study

361 ppm Central nervous system

neurotoxic effects

2 day(s) Human Inconclusive, insufficient data

Judgement is based on the relevant ingredients Conclusion Not classified for subchronic toxicity

Mutagenicity (in vitro)

T-REX solvent based No (test)data on the mixture available hydrocarbons, C6-C7, n-alkanes, isoalkanes, cyclics, < 5% n-hexane Result Method Test substrate Effect Value determination Negative Equivalent to OECD 473 Rat liver cells No effect Read-across Negative Equivalent to OECD 471 Bacteria (S.typhimurium) No effect Read-across Negative OECD 476 No effect Read-across hydrocarbons, C7, n-alkanes, isoalkanes, cyclics Result Method Test substrate Effect Value determination Negative Equivalent to OECD 473 Rat liver cells No effect Read-across Negative Equivalent to OECD 471 Bacteria (S.typhimurium) No effect Read-across Negative OECD 476 No effect Read-across xylene Result Method Test substrate Effect Value determination Negative Other Chinese hamster ovary (CHO) No effect Experimental value



T-REX solvent based ethylbenzene Result Method Test substrate Effect Value determination Negative with metabolic

activation, negative without metabolic activation

OECD 476 Mouse (lymphoma L5178Y cells)

No effect Experimental value

Negative with metabolic activation, negative without metabolic activation

Equivalent to OECD 473 Chinese hamster ovary (CHO) No effect Experimental value

acetone Result Method Test substrate Effect Value determination Negative Equivalent to OECD 471 Bacteria (S.typhimurium) No effect Experimental value Negative Equivalent to OECD 473 Chinese hamster ovary (CHO) No effect Experimental value

Mutagenicity (in vivo)

T-REX solvent based No (test)data on the mixture available xylene Result Method Exposure time Test substrate Gender Organ Value determination Negative Equivalent to OECD

478 Mouse Male/female Experimental value

ethylbenzene Result Method Exposure time Test substrate Gender Organ Value determination Negative OECD 486 6 h Mouse Male/female Experimental value Negative OECD 474 48 h Mouse Male Experimental value acetone Result Method Exposure time Test substrate Gender Organ Value determination Negative 13 week(s) Mouse Male/female Literature

Carcinogenicity

T-REX solvent based No (test)data on the mixture available xylene Route of

exposure Parameter Method Value Exposure time Species Gender Value

determination Organ Effect

Oral NOAEC Other >=500 mg/kg bw/day

103 weeks (5 days/week)

Rat Male/female Experimental value

No effect

ethylbenzene Route of




NOAEC Equivalent to OECD 453

250 ppm 104 weeks (6h/day, 5 days/week)


No effect

acetone Route of



Dermal NOEL Other 79 mg 51 week(s) Mouse Female Literature No effect

Reproductive toxicity

T-REX solvent based No (test)data on the mixture available



T-REX solvent based hydrocarbons, C6-C7, n-alkanes, isoalkanes, cyclics, < 5% n-hexane Parameter Method Value Exposure

time Species Gender Effect Organ Value

determination Developmental toxicity NOAEC Other ≥1200 ppm 10 days

(6h/day) Rat No effect Read-across

NOAEL Equivalent to OECD 414

3000 ppm 10 days (6h/day)

Mouse No effect Read-across



Mouse Minor skeletal variations

Skeleton Read-across

Maternal toxicity NOAEC 1200 ppm Rat Female No effect Read-across NOAEL Equivalent to

OECD 414 900 ppm 10 days

(6h/day) Rat Female No effect Read-across



Rat Female Lung tissue affection/degeneration

Lungs Read-across

Effects on fertility NOAEL (P/F1) Equivalent to OECD 416

9000 ppm Rat Male/female No effect Read-across

hydrocarbons, C7, n-alkanes, isoalkanes, cyclics Parameter Method Value Exposure


determination Developmental toxicity NOAEC Other ≥1200 ppm 10 days

(6h/day) Rat No effect Read-across

NOAEL Equivalent to OECD 414


Mouse No effect Read-across


9000 ppm 10 days(6h/day)

Mouse Minor skeletal variations

Skeleton Read-across

Maternal toxicity NOAEC 1200 ppm Rat Female No effect Read-across NOAEL Equivalent to

OECD 414 900 ppm 10 days

(6h/day) Rat Female No effect Read-across



Rat Female Lung tissue affection/degeneration

Lungs Read-across

Effects on fertility NOAEL (P/F1) Equivalent to OECD 416

9000 ppm Rat Male/female No effect Read-across

xylene Parameter Method Value Exposure


determination Developmental toxicity NOAEC (P) Equivalent to

OECD 414 >=500 ppm 21 days

(6h/day) Rat Male/female No effect Experimental

value Effects on fertility NOAEC (P) EPA OPPTS

870.3800 >=500 ppm 70 days


value NOAEC (F1) EPA OPPTS

870.3800 >=500 ppm 70 days


value NOAEC (F2) EPA OPPTS

870.3800 >=500 ppm Rat Male/female No effect Experimental

value ethylbenzene Parameter Method Value Exposure


determination Developmental toxicity NOAEC OECD 414 500 ppm 15 days

(gestation, daily)

Rat Female No effect Experimental value

NOAEC OECD 426 500 ppm 70 days (6h/day)

Rat Male/female No effect Experimental value

Effects on fertility NOAEC (P/F1/F2)

OECD 416 500 ppm 70 days (6h/day)

Rat Male/female No effect Experimental value

NOAEC (P) Equivalent to OECD 415

1000 ppm 2 week(s) Rat Male/female No effect Experimental value

NOEC (F1) Equivalent to OECD 415

100 ppm Rat Male/female No effect Experimental value

NOAEL Other 750 ppm 104 weeks (6h/day, 5 days/week)

Mouse Male/female No effect Experimental value

NOEC OECD 408 750 ppm 13 week(s) Rat Male/female No effect Experimental value



T-REX solvent based acetone Parameter Method Value Exposure


determination Developmental toxicity NOAEC Equivalent to

OECD 414 11000 ppm 6-19 days

(gestation, daily)


Effects on fertility NOAEL Other 900 mg/kg bw/day

13 week(s) Rat Male No effect Literature

Judgement is based on the relevant ingredients Conclusion CMR Not classified for carcinogenicity Not classified for mutagenic or genotoxic toxicity Not classified for reprotoxic or developmental toxicity

Toxicity other effects

T-REX solvent based No (test)data on the mixture available acetone Parameter Method Value Organ Effect Exposure time Species Gender Value

determination Skin Skin dryness or

cracking Literature study

Chronic effects from short and long-term exposure

No effects known.

SECTION 12: Ecological information 12.1 Toxicity:

T-REX solvent based No (test)data on the mixture available hydrocarbons, C6-C7, n-alkanes, isoalkanes, cyclics, < 5% n-hexane Parameter Method Value Duration Species Test design Fresh/salt

water Value determination

Acute toxicity fishes LC50 OECD 203 11.4 mg/l WAF

96 h Oncorhynchus mykiss

Semi-static Fresh water Experimental value; GLP

Acute toxicity invertebrates EC50 OECD 202 3.0 mg/l WAF 48 h Daphnia magna Static system Fresh water Experimental value; GLP

Toxicity algae and other aquatic plants

ErC50 OECD 201 30 - 100 mg/l WAF

72 h Pseudokirchneriella subcapitata

Static system Fresh water Experimental value; GLP

Long-term toxicity fish NOEL 2.045 mg/l 28 Oncorhynchus mykiss

Fresh water QSAR

Long-term toxicity aquatic invertebrates

NOEC 0.17 mg/l 21 day(s) Daphnia magna Literature

LOEC 0.32 mg/l 21 day(s) Daphnia magna Literature

Toxicity aquatic micro-organisms

EC50 35.57 mg/l 48 h Tetrahymena pyriformis

Fresh water QSAR; Growth rate



T-REX solvent based hydrocarbons, C7, n-alkanes, isoalkanes, cyclics Parameter Method Value Duration Species Test design Fresh/salt


Acute toxicity fishes LL50 OECD 203 >13.4 mg/l WAF

96 h Oncorhynchus mykiss

Semi-static Fresh water Experimental value; GLP

Acute toxicity invertebrates EL50 OECD 202 3.0 mg/l WAF 48 h Daphnia magna Static system Fresh water Experimental value; GLP


ErC50 OECD 201 30 - 100 mg/l WAF

72 h Pseudokirchneriella subcapitata

Static system Fresh water Experimental value;GLP

ErC50 OECD 201 13 mg/l WAF 72 h Pseudokirchneriella subcapitata

Static system Fresh water Read-across; GLP

Long-term toxicity fish NOELR 1.534 mg/l 28 Oncorhynchus mykiss

Fresh water QSAR


NOEC 0.17 mg/l 21 day(s) Daphnia magna Literature

LOEC 0.32 mg/l 21 day(s) Daphnia magna Literature

Toxicity aquatic micro-organisms

EL50 26.81 mg/l 48 h Tetrahymena pyriformis

Fresh water QSAR; Growth rate

xylene Parameter Method Value Duration Species Test design Fresh/salt


Acute toxicity fishes LC50 OECD 203 2.6 mg/l 96 h Oncorhynchus mykiss

Static system Fresh water Read-across; Lethal

Acute toxicity invertebrates EC50 3.82 mg/l 48 h Daphnia magna Flow-through system

Fresh water Read-across


EC50 OECD 201 4.36 mg/l 73 h Pseudokirchneriella subcapitata

Static system Fresh water Experimental value; Growth rate

Long-term toxicity fish NOEC > 1.3 mg/l 56 day(s) Oncorhynchus mykiss

Flow-through system

Fresh water Experimental value; Lethal


NOEC US EPA 1.17 mg/l 7 day(s) Ceriodaphnia dubia

Fresh water Read-across; Reproduction

ethylbenzene Parameter Method Value Duration Species Test design Fresh/salt


Acute toxicity fishes LC50 OECD 203 4.2 mg/l 96 h Salmo gairdneri (Oncorhynchus mykiss)

Semi-static Fresh water Experimental value

Acute toxicity invertebrates EC50 US EPA 1.8 - 2.4 mg/l 48 h Daphnia magna Static system Fresh water Experimental value Toxicity algae and other aquatic

plants EC50 OECD 201 4.6 mg/l 72 h Selenastrum

capricornutum Experimental value;

Growth rate Long-term toxicity aquatic

invertebrates NOEC US EPA 1 mg/l 7 day(s) Ceriodaphnia

dubia Semi-static Fresh water Experimental value;

Reproduction acetone Parameter Method Value Duration Species Test design Fresh/salt


Acute toxicity fishes LC50 EU Method C.1

5540 mg/l 96 h Salmo gairdneri (Oncorhynchus mykiss)

Static system Fresh water Experimental value; Nominal concentration

Acute toxicity invertebrates LC50 Other 12600 mg/l 48 h Daphnia magna Static system Fresh water Experimental value; Nominal concentration


EC50 >7000 mg/l 96 h Selenastrum capricornutum

Static system Fresh water Experimental value; Nominal concentration

Classification of the mixture is based on the relevant ingredients and on application of the summation method

Conclusion Harmful to aquatic organisms May cause long-term adverse effects in the aquatic environment 12.2 Persistence and degradability: hydrocarbons, C6-C7, n-alkanes, isoalkanes, cyclics, < 5% n-hexane Biodegradation water Method Value Duration Value determination OECD 301F: Manometric Respirometry Test 98 % 28 day(s) Experimental value Reason for revision: 2.2 Publication date: 2013-07-15



T-REX solvent based hydrocarbons, C7, n-alkanes, isoalkanes, cyclics Biodegradation water Method Value Duration Value determination OECD 301F: Manometric Respirometry Test 98 % 28 day(s) Experimental value xylene Biodegradation water Method Value Duration Value determination OECD 301: Ready Biodegradability 100 % 12 day(s) Experimental value OECD 301F: Manometric Respirometry Test 87.8 % 28 day(s) Read-across ethylbenzene Biodegradation water Method Value Duration Value determination OECD 301C: Modified MITI Test (I) > = 81 % = 14 day(s) Experimental value ISO 14593 70 - 80 % 28 day(s) Experimental value Half-life soil (t1/2 soil) Method Value Primary

degradation/mineralisation Value determination

3-10 day(s) Literature study acetone Biodegradation water Method Value Duration Value determination OECD 301B: CO2 Evolution Test 90.9 % 28 day(s) Experimental value

Conclusion

Contains readily biodegradable component(s)

12.3 Bioaccumulative potential: T-REX solvent based Log Kow Method Remark Value Temperature Value determination Not applicable (mixture)

hydrocarbons, C6-C7, n-alkanes, isoalkanes, cyclics, < 5% n-hexane Log Kow Method Remark Value Temperature Value determination > 3 hydrocarbons, C7, n-alkanes, isoalkanes, cyclics Log Kow Method Remark Value Temperature Value determination > 3 xylene BCF fishes Parameter Method Value Duration Species Value determination BCF 7 - 26 8 week(s) Oncorhynchus mykiss Experimental value Log Kow Method Remark Value Temperature Value determination 3.2 20 °C Conclusion by analogy ethylbenzene BCF fishes Parameter Method Value Duration Species Value determination BCF Other 1 6 week(s) Oncorhynchus kisutch Literature study 15 - 79 Carassius auratus Literature study BCF other aquatic organisms Parameter Method Value Duration Species Value determination BCF 4.68 Lamellibranchiata Literature study Log Kow Method Remark Value Temperature Value determination 3.15 Experimental value EU Method A.8 3.6 20 °C Experimental value



T-REX solvent based acetone BCF fishes Parameter Method Value Duration Species Value determination BCF 0.69 Pisces BCF other aquatic organisms Parameter Method Value Duration Species Value determination BCF BCFWIN 3 Calculated value Log Kow Method Remark Value Temperature Value determination -0.24 Test data Conclusion No straightforward conclusion can be drawn based upon the available numerical values

12.4 Mobility in soil: hydrocarbons, C6-C7, n-alkanes, isoalkanes, cyclics, < 5% n-hexane Percent distribution Method Fraction air Fraction biota Fraction

sediment Fraction soil Fraction water Value determination

Mackay level III 98 % 0 % 0.9 % 0 % 1.3 % Calculated value hydrocarbons, C7, n-alkanes, isoalkanes, cyclics Percent distribution Method Fraction air Fraction biota Fraction

sediment Fraction soil Fraction water Value determination

Mackay level III 96 % 0 % 1.8 % 0.55 % 1.4 % Calculated value ethylbenzene (log) Koc Parameter Method Value Value determination log Koc PCKOCWIN v1.66 2.71 Calculated value Koc PCKOCWIN v1.66 517.8 Calculated value

Conclusion

Contains component(s) with potential for mobility in the soil 12.5 Results of PBT and vPvB assessment: Due to insufficient data no statement can be made whether the component(s) fulfil(s) the criteria of PBT and vPvB according to Annex XIII of Regulation

(EC) No 1907/2006.

12.6 Other adverse effects: T-REX solvent based Global warming potential (GWP) None of the known components is included in the list of substances which may contribute to the greenhouse effect (Regulation (EC) No 842/2006) Ozone-depleting potential (ODP) Not classified as dangerous for the ozone layer (Regulation (EC) No 1005/2009)

xylene

Ground water Ground water pollutant

SECTION 13: Disposal considerations The information in this section is a general description. If applicable and available, exposure scenarios are attached in annex. Always use the relevant exposure

scenarios that correspond to your identified use.

13.1 Waste treatment methods: 13.1.1 Provisions relating to waste Waste material code (Directive 2008/98/EC, Decision 2000/0532/EC).

08 04 09* (wastes from MFSU of adhesives and sealants (including waterproofing products): waste adhesives and sealants containing organic solvents or other dangerous substances). Depending on branch of industry and production process, also other waste codes may be applicable. Hazardous waste according to Directive 2008/98/EC.

13.1.2 Disposal methods Remove waste in accordance with local and/or national regulations. Hazardous waste shall not be mixed together with other waste. Different types of

hazardous waste shall not be mixed together if this may entail a risk of pollution or create problems for the further management of the waste. Hazardous waste shall be managed responsibly. All entities that store, transport or handle hazardous waste shall take the necessary measures to prevent risks of pollution or damage to people or animals. Do not discharge into drains or the environment. Dispose of at authorized waste collection point.

13.1.3 Packaging/Container



T-REX solvent based Waste material code packaging (Directive 2008/98/EC).

15 01 10* (packaging containing residues of or contaminated by dangerous substances).

SECTION 14: Transport information

Road (ADR) 14.1 UN number: UN number 1133 14.2 UN proper shipping name: Proper shipping name Adhesives 14.3 Transport hazard class(es): Hazard identification number 33 Class 3 Classification code F1 14.4 Packing group: Packing group III Labels 3 14.5 Environmental hazards: Environmentally hazardous substance mark no 14.6 Special precautions for user: Special provisions 640H Limited quantities Combination packagings: not more than 5 liters per inner packaging for

liquids. A package shall not weigh more than 30 kg. (gross mass) Specific mention Viscous liquid with a flash point lower than 23°C, which meets the

conditions indicated in 2.2.3.1.4 of ADR Rail (RID) 14.1 UN number: UN number 1133 14.2 UN proper shipping name: Proper shipping name Adhesives 14.3 Transport hazard class(es): Hazard identification number 33 Class 3 Classification code F1 14.4 Packing group: Packing group III Labels 3 14.5 Environmental hazards: Environmentally hazardous substance mark no 14.6 Special precautions for user: Special provisions 640H Limited quantities Combination packagings: not more than 5 liters per inner packaging for


conditions indicated in 2.2.3.1.4 of RID Inland waterways (ADN) 14.1 UN number: UN number 1133 14.2 UN proper shipping name: Proper shipping name Adhesives 14.3 Transport hazard class(es): Class 3 Classification code F1 14.4 Packing group: Packing group III Labels 3 14.5 Environmental hazards: Environmentally hazardous substance mark no 14.6 Special precautions for user: Special provisions 640H



T-REX solvent based Limited quantities Combination packagings: not more than 5 liters per inner packaging for


conditions indicated in 2.2.3.1.4 of ADN Sea (IMDG/IMSBC) 14.1 UN number: UN number 1133 14.2 UN proper shipping name: Proper shipping name Adhesives 14.3 Transport hazard class(es): Class 3 14.4 Packing group: Packing group III Labels 3 14.5 Environmental hazards: Marine pollutant - Environmentally hazardous substance mark no 14.6 Special precautions for user: Special provisions 223 Special provisions 955 Limited quantities Combination packagings: not more than 5 liters per inner packaging for


conditions indicated in 2.3.2.3 of IMDG 14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code: Annex II of MARPOL 73/78 Not applicable, based on available data Air (ICAO-TI/IATA-DGR) 14.1 UN number: UN number 1133 14.2 UN proper shipping name: Proper shipping name Adhesives 14.3 Transport hazard class(es): Class 3 14.4 Packing group: Packing group III Labels 3 14.5 Environmental hazards: Environmentally hazardous substance mark no 14.6 Special precautions for user: Special provisions A3 Passenger and cargo transport: limited quantities: maximum net quantity

per packaging 10 L

Specific mention Viscous liquid with a flash point lower than 23°C, which meets the conditions indicated in 3.3.3.1 of ICAO

SECTION 15: Regulatory information 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture: European legislation: REACH Annex XVII - Restriction Contains component(s) subject to restrictions of Annex XVII of Regulation (EC) No 1907/2006: restrictions on the manufacture, placing on the market

and use of certain dangerous substances, mixtures and articles. Designation of the substance, of the group of

substances or of the mixture Conditions of restriction

· hydrocarbons, C6-C7, n-alkanes, isoalkanes, cyclics, < 5% n-hexane · hydrocarbons, C7, n-alkanes, isoalkanes, cyclics · xylene · ethylbenzene · acetone

Liquid substances or mixtures which are regarded as dangerous in accordance with Directive 1999/45/EC or are fulfilling the criteria for any of the following hazard classes or categories set out in Annex I to Regulation (EC) No 1272/2008: (a) hazard classes 2.1 to 2.4, 2.6 and 2.7, 2.8 types A and B, 2.9, 2.10, 2.12, 2.13 categories 1 and 2, 2.14 categories 1 and 2, 2.15 types A to F; (b) hazard classes 3.1 to 3.6, 3.7 adverse

1. Shall not be used in: � ornamental articles intended to produce light or colour effects by means of different phases, for example in ornamental lamps and ashtrays, � tricks and jokes, � games for one or more participants, or any article intended to be used as such, even with ornamental aspects,2. Articles not complying with paragraph 1 shall not be placed on the market.3. Shall not be placed on the market if they contain a colouring agent, unless required for fiscal reasons, or perfume, or both, if they: � can be used as fuel in decorative oil lamps for supply to the general public, and, � present an aspiration hazard and are labelled with R65 or H304,4. Decorative oil lamps for supply to the general public shall not be placed on the market unless they conform to the



T-REX solvent based effects on sexual function and fertility or on

development, 3.8 effects other than narcotic effects, 3.9 and 3.10; (c) hazard class 4.1; (d) hazard class 5.1.

European Standard on Decorative oil lamps (EN 14059) adopted by the European Committee for Standardisation (CEN).5. Without prejudice to the implementation of other Community provisions relating to the classification, packaging and labelling of dangerous substances and mixtures, suppliers shall ensure, before the placing on the market, that the following requirements are met: a) lamp oils, labelled with R65 or H304, intended for supply to the general public are visibly, legibly and indelibly marked as follows: �Keep lamps filled with this liquid out of the reach of children�; and, by 1 December 2010, �Just a sip of lamp oil � or even sucking the wick of lamps � may lead to life- threatening lung damage�; b) grill lighter fluids, labelled with R65 or H304, intended for supply to the general public are legibly and indelibly marked by 1 December 2010 as follows: �Just a sip of grill lighter may lead to life threatening lung damage�; c) lamp oils and grill lighters, labelled with R65 or H304, intended for supply to the general public are packaged in black opaque containers not exceeding 1 litre by 1 December 2010.6. No later than 1 June 2014, the Commission shall request the European Chemicals Agency to prepare a dossier, in accordance with Article 69 of the present Regulation with a view to ban, if appropriate, grill lighter fluids and fuel for decorative lamps, labelled R65 or H304, intended for supply to the general public.7. Natural or legal persons placing on the market for the first time lamp oils and grill lighter fluids, labelled with R65 or H304, shall by 1 December 2011, and annually thereafter, provide data on alternatives to lamp oils and grill lighter fluids labelled R65 or H304 to the competent authority in the Member State concerned. Member States shall make those data available to the Commission.�

· hydrocarbons, C7, n-alkanes, isoalkanes, cyclics · xylene · ethylbenzene · acetone

Substances classified as flammable gases category 1 or 2, flammable liquids categories 1, 2 or 3, flammable solids category 1 or 2, substances and mixtures which, in contact with water, emit flammable gases, category 1, 2 or 3, pyrophoric liquids category 1 or pyrophoric solids category 1, regardless of whether they appear in Part 3 of Annex VI to that Regulation or not.

1. Shall not be used, as substance or as mixtures in aerosol dispensers where these aerosol dispensers are intended for supply to the general public for entertainment and decorative purposes such as the following: � metallic glitter intended mainly for decoration, � artificial snow and frost, � �whoopee� cushions, � silly string aerosols, � imitation excrement, � horns for parties, � decorative flakes and foams, � artificial cobwebs, � stink bombs.2. Without prejudice to the application of other Community provisions on the classification, packaging and labelling of substances, suppliers shall ensure before the placing on the market that the packaging of aerosol dispensers referred to above is marked visibly, legibly and indelibly with: �For professional users only�.3. By way of derogation, paragraphs 1 and 2 shall not apply to the aerosol dispensers referred to Article 8 (1a) of Council Directive 75/ 324/EEC.4. The aerosol dispensers referred to in paragraphs 1 and 2 shall not be placed on the market unless they conform to the requirements indicated.

Reference legislation See column 1: 3. See column 1: 40. Volatile organic compounds (VOC) 27 % National legislation The Netherlands T-REX solvent based Waste identification (the

Netherlands) LWCA (the Netherlands): KGA category 03

Waterbezwaarlijkheid 1 xylene SZW - List of reprotoxic

substances (development) Possibly hazardous to the foetus

National legislation Germany T-REX solvent based WGK 2; Classification water polluting based on the components in compliance with Verwaltungsvorschrift wassergefährdender

Stoffe (VwVwS) of 27 July 2005 (Anhang 4) xylene TA-Luft TA-Luft Klasse 5.2.5/I Schwangerschaft Gruppe D MAK 8-Stunden-Mittelwert

ppm Xylol (alle Isomeren); 100 ppm

MAK 8-Stunden-Mittelwert mg/m³

Xylol (alle Isomeren); 440 mg/m³



T-REX solvent based ethylbenzene MAK - Krebserzeugend

Kategorie 4

TA-Luft TA-Luft Klasse 5.2.5/I Schwangerschaft Gruppe C MAK 8-Stunden-Mittelwert

ppm Ethylbenzol; 20 ppm


Ethylbenzol; 88 mg/m³

acetone TA-Luft TA-Luft Klasse 5.2.5 Schwangerschaft Gruppe D MAK 8-Stunden-Mittelwert

ppm Aceton; 500 ppm


Aceton; 1200 mg/m³

National legislation France T-REX solvent based No data available National legislation Belgium T-REX solvent based No data available

15.2 Chemical safety assessment: No chemical safety assessment is required.

SECTION 16: Other information Information based on classification according to CLP Full text of any R-phrases referred to under headings 2 and 3: R10 Flammable

R20 Harmful by inhalation R20/21 Harmful by inhalation and in contact with skin R36 Irritating to eyes R38 Irritating to skin R51 Toxic to aquatic organisms R52 Harmful to aquatic organisms R53 May cause long-term adverse effects in the aquatic environment R65 Harmful: may cause lung damage if swallowed R66 Repeated exposure may cause skin dryness or cracking R67 Vapours may cause drowsiness and dizziness

Full text of any H-statements referred to under headings 2 and 3: H225 Highly flammable liquid and vapour.

H226 Flammable liquid and vapour. H304 May be fatal if swallowed and enters airways. H312 Harmful in contact with skin. H315 Causes skin irritation. H319 Causes serious eye irritation. H332 Harmful if inhaled. H336 May cause drowsiness or dizziness. H411 Toxic to aquatic life with long lasting effects. H412 Harmful to aquatic life with long lasting effects.

(*) = INTERNAL CLASSIFICATION BY BIG PBT-substances = persistent, bioaccumulative and toxic substances DSD Dangerous Substance Directive

DPD Dangerous Preparation Directive CLP (EU-GHS) Classification, labelling and packaging (Globally Harmonised System in Europe)

Specific concentration limits DSD xylene C ≥ 12,5 % Xn; R20/21 Annex VI

The information in this safety data sheet is based on data and samples provided to BIG. The sheet was written to the best of our ability and according to the state of knowledge at that time. The safety data sheet only constitutes a guideline for the safe handling, use, consumption, storage, transport and disposal of the substances/preparations/mixtures mentioned under point 1. New safety data sheets are written from time to time. Only the most recent versions may be used. Old versions must be destroyed. Unless indicated otherwise word for word on the safety data sheet, the information does not apply to substances/preparations/mixtures in purer form, mixed with other substances or in processes. The safety data sheet offers no quality specification for the substances/preparations/mixtures in question. Compliance with the instructions in this safety data sheet does not release the user from the obligation to take all measures dictated by common sense, regulations and recommendations or which are necessary and/or useful based on the real applicable circumstances. BIG does not guarantee



T-REX solvent based the accuracy or exhaustiveness of the information provided and cannot be held liable for any changes by third parties. This safety data sheet is only to be used

within the European Union, Switzerland, Iceland, Norway and Liechtenstein. Any use outside of this area is at your own risk. Use of this safety data sheet is subject to the licence and liability limiting conditions as stated in your BIG licence agreement or when this is failing the general conditions of BIG. All intellectual property rights to this sheet are the property of BIG and its distribution and reproduction are limited. Consult the mentioned agreement/conditions for details.



S

Technical Data Sheet

T-REX SOLVENT BASED

Revision: 10/02/2014 Page 1 of 2

Remark: The directives contained in this documentation are the result of our experiments and of our experience and have been submitted in good faith. Because of the diversity of the materials and substrates and the great number of possible applications which are out of our control, we cannot accept any responsibility for the results obtained. In every case it is recommended to carry out preliminary experiments.

Soudal NV Everdongenlaan 18-20 2300 Turnhout, Belgium Tel.: +32 (0)14-42.42.31 Fax: +32 (0)14-42.65.14 www.soudal.com

Technical data: Base Synthetic rubber Consistency Paste Curing System Physical drying and crystallization Specific Gravity Ca. 1.35 g/cm³ Temperature resistance -20°C until +70°C Open Time (*) 5 min. Initial grab At least 125kg/m² End strength wood-wood Ca. 13 kg/cm² End strength wood- aluminium Ca. 13 kg/cm² End strength wood- PVC Ca. 12 kg/cm² Application Temperature +5°C until +30°C

* This varies according to ambient conditions such as temperature, humidity, substrate etc. Product: T-Rex Solvent based is a fibre reinforced high strength construction adhesive with high initial grab (over 125kg/m²) and high bond strength. Compatible with most building materials (porous and non-porous). Characteristics: - Fibre reinforced - Excellent initial grab (at least 125kg/m², full

surface bonding) for fast and direct bonding - Very fast powerful bonding - Direct application onto one substrate - Replaces nails and screws - Suitable for bonding on uneven surfaces - Excellent adhesion on a wide range of

construction materials both in interior and exterior applications

Applications: - Suitable for the bonding of decorative

materials, skirting boards, gypsum panels in vertical, horizontal and overhead applications.

- Bonding of carpet grippers, edge strips and aluminium and uPVC stair nosing

- Bonding of wall and floor boards, window frames and partitions

- Suitable for direct bonding of many materials such as wood, many plastics, bricks, stone, tiles, metal to porous surfaces such as concrete, plaster, MDF, OSB, timber panels, chipboard etc.

Packaging: Colour: beige/brown Packaging: Cartridge xxx gr Surfaces: Type: All substrates except PE,PP and bituminous surfaces. State of Surface: The substrates should be dry, clean and free of dust, grease and loose particles. Porous surfaces such as plaster and fibre cement board should be primed. We recommend a preliminary compatibility test. Applying the adhesive: Method: Apply the adhesive by means of a caulking gun onto one surface in strips or dabs. Always apply adhesive to the edges and corners of panels. Press the surfaces together immediately and tamp down with a rubber hammer. Support may be required on a vertical fixing or for heavy components. For the bonding of impervious or heavy materials use the transfer method: press components together and release for max. 5 min. Return parts together and batten down with a rubber hammer. If necessary support until adhesive is completely cured (approx. 24-48 hours).The bond can be loaded after 24-48 hours Application temperature: +5°C to +35°C Clean: Soudal Adhesive Cleaner 90A, mechanically if cured Repair: with same material

S

Technical Data Sheet

T-REX SOLVENT BASED

Revision: 10/02/2014 Page 2 of 2

Remark: The directives contained in this documentation are the result of our experiments and of our experience and have been submitted in good faith. Because of the diversity of the materials and substrates and the great number of possible applications which are out of our control, we cannot accept any responsibility for the results obtained. In every case it is recommended to carry out preliminary experiments.

Soudal NV Everdongenlaan 18-20 2300 Turnhout, Belgium Tel.: +32 (0)14-42.42.31 Fax: +32 (0)14-42.65.14 www.soudal.com

Shelf-life: At least 12 months in unopened packaging in a cool and dry storage place at temperatures between +5°C and +25°C. Health- and safety recommendations: Apply the usual industrial hygiene. Work in a well-ventilated place. Do not smoke. If the area is not sufficiently ventilated, wear breathing equipment. Consult the label for more information.

Remarks:

When bonding, the pressure applied determines the initial grab and the final bonding strength. The duration during which pressure is applied is less important.

In case of overhead applications a combination with mechanical fixing is required.

Do not use as a mirror adhesive. Do not use in applications where continuous

immersion is possible.

SAFETY DATA SHEET T-REX solvent based · Product name : T-REX solvent based Product type REACH :...

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