SAFETY DATA SHEET Revision date: 28/12/2017 Version: 2 ... · SAFETY DATA SHEET according to...

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SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 (REACH) and Regulation (EU) No. 2015/830 Anaerobe Klebstoffe Kategorie D Material number ANAEROB_D1 Revision date: 28/12/2017 Version: 2 Language: en-GB,IE Date of print: 30/1/2018 Page: 1 of 15 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1 Product identifier Trade name: Anaerobe Klebstoffe Kategorie D This safety data sheet pertains to the following products: 02K76.F250/F50, Schraubensicherung 02K76 hochfest, 250ml/50ml 02K77.F250/F50, Schraubensicherung 02K77 hochfest, 250ml/50ml 02K78.F250/F50/Z50, Fügeverbindung, Buchsen- und Lagerbef. 02K78, hochfest, 250ml/50ml 06K40.F250/F50, Fügeverbindung 06K40 hochfest, 250ml/50ml 06K60.Z50, Fügeverbindung 06K60 hochfest, 50ml 1.2 Relevant identified uses of the substance or mixture and uses advised against General use: Anaerobic sealants and adhesives 1.3 Details of the supplier of the safety data sheet Company name: GLUETEC Industrieklebestoffe GmbH & Co. KG Street/POB-No.: Am Biotop 8a Postal Code, city: 97259 Greußenheim Germany WWW: www.gluetec.de E-mail: [email protected] Telephone: +49 (0)9369-98 36-0 Telefax: +49 (0)9369-98 36-10 Dept. responsible for information: Department QS, Telephone: +49 (0)9369-98 36-0, E-mail: [email protected] 1.4 Emergency telephone number GIZ-Nord, Göttingen, Germany, Telephone: +49 551-19240 SECTION 2: Hazards identification 2.1 Classification of the substance or mixture Classification according to EC regulation 1272/2008 (CLP) Skin Irrit. 2; H315 Causes skin irritation. Eye Irrit. 2; H319 Causes serious eye irritation. Skin Sens. 1; H317 May cause an allergic skin reaction. STOT SE 3; H335 May cause respiratory irritation. Aquatic Chronic 4; H413 May cause long lasting harmful effects to aquatic life. 2.2 Label elements Labelling (CLP) Signal word: Warning printed by Gluetec with Qualisys SUMDAT

Transcript of SAFETY DATA SHEET Revision date: 28/12/2017 Version: 2 ... · SAFETY DATA SHEET according to...

Page 1: SAFETY DATA SHEET Revision date: 28/12/2017 Version: 2 ... · SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 (REACH) and Regulation (EU) No. 2015/830 Anaerobe Klebstoffe

SAFETY DATA SHEETaccording to Regulation (EC) No. 1907/2006 (REACH) and Regulation (EU) No. 2015/830

Anaerobe Klebstoffe Kategorie DMaterial number ANAEROB_D1

Revision date: 28/12/2017Version: 2Language: en-GB,IEDate of print: 30/1/2018

Page: 1 of 15

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifierTrade name: Anaerobe Klebstoffe Kategorie D

This safety data sheet pertains to the following products:02K76.F250/F50, Schraubensicherung 02K76 hochfest, 250ml/50ml02K77.F250/F50, Schraubensicherung 02K77 hochfest, 250ml/50ml02K78.F250/F50/Z50, Fügeverbindung, Buchsen- und Lagerbef. 02K78, hochfest, 250ml/50ml06K40.F250/F50, Fügeverbindung 06K40 hochfest, 250ml/50ml06K60.Z50, Fügeverbindung 06K60 hochfest, 50ml

1.2 Relevant identified uses of the substance or mixture and uses advised againstGeneral use: Anaerobic sealants and adhesives

1.3 Details of the supplier of the safety data sheetCompany name: GLUETEC Industrieklebestoffe GmbH & Co. KGStreet/POB-No.: Am Biotop 8aPostal Code, city: 97259 Greußenheim

GermanyWWW: www.gluetec.deE-mail: [email protected]: +49 (0)9369-98 36-0Telefax: +49 (0)9369-98 36-10Dept. responsible for information:

Department QS, Telephone: +49 (0)9369-98 36-0, E-mail: [email protected]

1.4 Emergency telephone numberGIZ-Nord, Göttingen, Germany,Telephone: +49 551-19240

SECTION 2: Hazards identification2.1 Classification of the substance or mixtureClassification according to EC regulation 1272/2008 (CLP)Skin Irrit. 2; H315 Causes skin irritation.Eye Irrit. 2; H319 Causes serious eye irritation.Skin Sens. 1; H317 May cause an allergic skin reaction.STOT SE 3; H335 May cause respiratory irritation.Aquatic Chronic 4; H413 May cause long lasting harmful effects to aquatic life.

2.2 Label elementsLabelling (CLP)

Signal word: Warning

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SAFETY DATA SHEETaccording to Regulation (EC) No. 1907/2006 (REACH) and Regulation (EU) No. 2015/830

Anaerobe Klebstoffe Kategorie DMaterial number ANAEROB_D1

Revision date: 28/12/2017Version: 2Language: en-GB,IEDate of print: 30/1/2018

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Hazard statements: H315 Causes skin irritation.H317 May cause an allergic skin reaction.H319 Causes serious eye irritation.H335 May cause respiratory irritation.H413 May cause long lasting harmful effects to aquatic life.

Precautionary statements:P102 Keep out of reach of children.

P261 Avoid breathing vapours/spray.P273 Avoid release to the environment.P280 Wear protective gloves/protective clothing/eye protection.

P302+P352 IF ON SKIN: Wash with plenty of water/soap.P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact

lenses, if present and easy to do. Continue rinsing.P312 Call a POISON CENTER/doctor if you feel unwell.

P405 Store locked up.

P501 Dispose of contents/container to hazardous or special waste collection point.

Special labellingText for labelling: Contains: 2-Hydroxyethyl methacrylate, Methacrylic acid, Maleic acid and Cumene

hydroperoxide.

2.3 Other hazardsSpecial danger of slipping by leaking/spilling product.People who suffer from skins problems, asthma, allergies, chronic or recurring respiratory illnesses must not be deployed in processes, which use this substance.

Results of PBT and vPvB assessment:

No data available

SECTION 3: Composition / information on ingredients3.1 Substances: not applicable

3.2 MixturesChemical characterisation: Methacrylate-based adhesive.

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SAFETY DATA SHEETaccording to Regulation (EC) No. 1907/2006 (REACH) and Regulation (EU) No. 2015/830

Anaerobe Klebstoffe Kategorie DMaterial number ANAEROB_D1

Revision date: 28/12/2017Version: 2Language: en-GB,IEDate of print: 30/1/2018

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Hazardous ingredients:

Ingredient Designation Content Classification

REACH 01-2119980659-17-xxxxEC No. 609-946-4CAS 41637-38-1

Esterification products of 4,4'-isopropylidenediphenol, ethoxylated and 2-methylprop-2-enoic acid

65 - 70 % Aquatic Chronic 4; H413.

REACH 01-2119490169-29-xxxxEC No. 212-782-2CAS 868-77-9

2-Hydroxyethyl methacrylate

20 - 25 % Skin Irrit. 2; H315. Eye Irrit. 2; H319. Skin Sens. 1; H317.

REACH 01-2119475796-19-xxxxEC No. 201-254-7CAS 80-15-9

Cumene hydroperoxide 1 - 5 % Org. Perox. EF; H242. Acute Tox. 4; H302. Acute Tox. 4; H312. Acute Tox. 3; H331. Skin Corr. 1B; H314. STOT RE 2; H373. Aquatic Chronic 2; H411.

REACH 01-2119463884-26-xxxxEC No. 201-204-4CAS 79-41-4

Methacrylic acid 1 - 5 % Acute Tox. 4; H302. Acute Tox. 3; H311. Acute Tox. 4; H332. Skin Corr. 1A; H314. Eye Dam. 1; H318. STOT SE 3; H335.

EC No. 204-055-3CAS 114-83-0

2'-phenylacetohydrazide < 1 % Acute Tox. 3; H301.

EC No. 203-742-5CAS 110-16-7

Maleic acid < 1 % Acute Tox. 4; H302. Skin Irrit. 2; H315. Eye Irrit. 2; H319. Skin Sens. 1; H317. STOT SE 3; H335.

EC No. 210-199-8CAS 609-72-3

N,N-Dimethyl-o-toluidine < 1 % Acute Tox. 3; H301. Acute Tox. 3; H311. Acute Tox. 3; H331. STOT RE 2; H373. Aquatic Chronic 3; H412.

Full text of H- and EUH-statements: see section 16.

SECTION 4: First aid measures4.1 Description of first aid measuresGeneral information: If medical advice is needed, have product container or label at hand.

Take off immediately all contaminated clothing and wash it before reuse.In case of inhalation: Move victim to fresh air.

In case of respiratory tract irritation, consult a physician.Following skin contact: After contact with skin, wash immediately with soap and plenty of water.

In case of skin reactions, consult a physician.

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SAFETY DATA SHEETaccording to Regulation (EC) No. 1907/2006 (REACH) and Regulation (EU) No. 2015/830

Anaerobe Klebstoffe Kategorie DMaterial number ANAEROB_D1

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After eye contact: Immediately flush eyes with plenty of flowing water for 10 to 15 minutes holding eyelids apart. Remove contact lenses, if present and easy to do. Continue rinsing. Subsequently consult an ophthalmologist.

After swallowing: Rinse mouth immediately and drink plenty of water. Never give anything by mouth to an unconscious person.Do not induce vomiting. Consult physician.

4.2 Most important symptoms and effects, both acute and delayedMay cause respiratory irritation. Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation.

4.3 Indication of any immediate medical attention and special treatment neededTreat symptomatically.

SECTION 5: Firefighting measures5.1 Extinguishing mediaSuitable extinguishing media:

extinguishing powder, foam, Carbon dioxideExtinguishing media which must not be used for safety reasons:

full water jet5.2 Special hazards arising from the substance or mixture

In case of fire may be liberated: Nitrogen oxides (NOx), carbon monoxide and carbon dioxide.

5.3 Advice for firefightersSpecial protective equipment for firefighters:

Wear self-contained positive pressure breathing apparatus and full firefighting protective clothing.

Additional information: Hazchem-Code: -Move container away or cool with water from a protected position.Do not allow fire water to penetrate into surface or ground water.

SECTION 6: Accidental release measures6.1 Personal precautions, protective equipment and emergency procedures

Provide adequate ventilation. Do not breathe vapour/aerosol. Avoid contact with skin, eyes, and clothing.Wear appropriate protective equipment. Take off immediately all contaminated clothing and wash it before reuse.Keep unprotected people away.

6.2 Environmental precautionsDo not allow to enter into ground-water, surface water or drains.

6.3 Methods and material for containment and cleaning upAbsorb with liquid-binding material (e.g. sand, diatomaceous earth, acid- or universal binding agents) and place in closed containers for disposal. Dispose of waste according to applicable legislation.Clean the floor and all object contaminated by this material.

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Additional information: Special danger of slipping by leaking/spilling product.6.4 Reference to other sections

Refer additionally to section 8 and 13.

SECTION 7: Handling and storage7.1 Precautions for safe handlingAdvices on safe handling: Provide adequate ventilation, and local exhaust as needed. Do not breathe vapour/aerosol.

Avoid contact with skin, eyes, and clothing. Wear appropriate protective equipment. Take off immediately all contaminated clothing and wash it before reuse. Do not eat, drink or smoke when using this product. Wash hands thoroughly after handling.Have eye wash bottle or eye rinse ready at work place.

7.2 Conditions for safe storage, including any incompatibilitiesRequirements for storerooms and containers:

Keep container dry, tightly closed and store at cool and aired place.Protect from exposure to heat, direct sunlight, and cold.

Hints on joint storage: Do not store together with oxidizing agents.Do not store together with food.

7.3 Specific end use(s)No information available.

SECTION 8: Exposure controls/personal protection8.1 Control parametersOccupational exposure limit values:

CAS No. Designation Type Limit value

79-41-4 Methacrylic acid Great Britain: WEL-STEL 143 mg/m³; 40 ppmGreat Britain: WEL-TWA 72 mg/m³; 20 ppmIreland: 15 minutes 140 mg/m³; 40 ppmIreland: 8 hours 70 mg/m³; 20 ppm

DNEL/DMEL: Information about 2-Hydroxyethyl methacrylate:DNEL long-term, workers, inhalative, systemic: 4.9 mg/m³DNEL long-term, workers, dermal, systemic: 1.3 mg/kg bw/dDNEL long-term, consumers, inhalative, systemic: 2.9 mg/m³DNEL long-term, consumers, oral, systemic: 0.83 mg/kg bw/dDNEL long-term, consumers, dermal, systemic: 0.83 mg/kgInformation about Cumene hydroperoxide:DNEL long-term, workers, inhalative, systemic: 6 mg/m³Information about Methacrylic acid:DNEL long-term, workers, inhalative, systemic: 29.6 mg/m³DNEL long-term, workers, inhalative, local: 88 mg/m³DNEL long-term, workers, dermal, systemic: 4.25 mg/kg bw/dDNEL long-term, consumers, inhalative, systemic: 6.3 mg/m³DNEL long-term, consumers, inhalative, local: 6.55 mg/m³DNEL long-term, consumers, dermal, systemic: 2.55 mg/kg

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SAFETY DATA SHEETaccording to Regulation (EC) No. 1907/2006 (REACH) and Regulation (EU) No. 2015/830

Anaerobe Klebstoffe Kategorie DMaterial number ANAEROB_D1

Revision date: 28/12/2017Version: 2Language: en-GB,IEDate of print: 30/1/2018

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PNEC: Information about 2-Hydroxyethyl methacrylate:PNEC Water (freshwater): 0.482 mg/LPNEC Water (marine water): 0.482 mg/LPNEC Water (intermittent release): 1 mg/LPNEC sewage treatment plant: 10 mg/LPNEC sediment (freshwater): 3.79 mg/kg dwPNEC sediment (marine water): 3.79 mg/kg dwPNEC soil: 0.476 mg/kg dwInformation about Cumene hydroperoxide:PNEC Water (freshwater): 0.003 mg/LPNEC Water (marine water): 0.003 mg/LPNEC sediment (freshwater): 0.023 mg/kg dwPNEC sediment (marine water): 0.002 mg/kg dwPNEC sewage treatment plant: 0.35 mg/LPNEC soil: 0.003 mg/kgInformation about Methacrylic acid:PNEC Water (freshwater): 0.82 mg/LPNEC Water (marine water): 0.82 mg/LPNEC Water (intermittent release): 0.82 mg/LPNEC sewage treatment plant: 10 mg/LPNEC soil: 1.2 mg/kg

8.2 Exposure controlsProvide adequate ventilation, and local exhaust as needed.

Personal protection equipmentOccupational exposure controlsRespiratory protection: Respiratory protection must be worn whenever the WEL levels have been exceeded. Use

filter type A / P2/P3 according to EN 14387.Hand protection: Protective gloves according to EN 374.

Glove material:butyl caoutchouc (butyl rubber) - layer thickness: 0.5 mmFluororubber (Viton) - layer thickness: 0.4 mmchloroprene rubber - layer thickness: 0.5 mmBreakthrough time: >= 480 min.Observe glove manufacturer's instructions concerning penetrability and breakthrough time.

Eye protection: Tightly sealed goggles according to EN 166.Body protection: Wear suitable protective clothing.General protection and hygiene measures:

Take off immediately all contaminated clothing and wash it before reuse.Avoid breathing vapours/spray. Avoid contact with skin and eyes.When using do not eat or drink.Have eye wash bottle or eye rinse ready at work place.Wash hands before breaks and after work.

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SECTION 9: Physical and chemical properties9.1 Information on basic physical and chemical propertiesAppearance: Physical state at 20 °C and 101.3 kPa: liquid

Colour: Varying coloursOdour: characteristicOdour threshold: No data available

pH value: No data availableMelting point/freezing point: not determined Initial boiling point and boiling range: not determined Flash point/flash point range: not determined Evaporation rate: No data availableFlammability: No data availableExplosion limits: LEL (Lower Explosion Limit): not determined

UEL (Upper Explosive Limit): not determinedVapour pressure: No data availableVapour density: No data availableDensity: No data availableSolubility: No data availablePartition coefficient: n-octanol/water: 0.93 log P(o/w) (Methacrylic acid)

Based on the n-octanol/water partition coefficient accumulation in organisms is not expected.0.47 log P(o/w) (2-Hydroxyethyl methacrylate)Based on the n-octanol/water partition coefficient accumulation in organisms is not expected.5.30 - 5.62 log P(o/w) (Esterification products of 4,4'-isopropylidenediphenol, ethoxylated and 2-methylprop-2-enoic acid)Based on the n-octanol/water partition coefficient accumulation in organisms is not expected.2.16 log P(o/w) (Cumene hydroperoxide)Based on the n-octanol/water partition coefficient accumulation in organisms is not expected.-0.79 log P(o/w) (Maleic acid)Based on the n-octanol/water partition coefficient accumulation in organisms is not expected.

Auto-ignition temperature: No data availableDecomposition temperature: No data availableViscosity, kinematic: No data availableExplosive properties: No data availableOxidizing characteristics: No data available

9.2 Other informationIgnition temperature: not determined

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SAFETY DATA SHEETaccording to Regulation (EC) No. 1907/2006 (REACH) and Regulation (EU) No. 2015/830

Anaerobe Klebstoffe Kategorie DMaterial number ANAEROB_D1

Revision date: 28/12/2017Version: 2Language: en-GB,IEDate of print: 30/1/2018

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SECTION 10: Stability and reactivity10.1 Reactivity

refer to section 10.3

10.2 Chemical stabilityStable under recommended storage conditions.

10.3 Possibility of hazardous reactionsReacts with strong acids, strong alkalis and oxidizing agents.

10.4 Conditions to avoidProtect from exposure to heat, direct sunlight, and cold. Protect from moisture contamination.

10.5 Incompatible materialsAvoid contact with strong acids, strong bases and strong oxidizing agents.

10.6 Hazardous decomposition productsNo hazardous decomposition products when regulations for storage and handling are observed.

Thermal decomposition: No data available

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SECTION 11: Toxicological information11.1 Information on toxicological effectsToxicological effects: The statements are derived from the properties of the single components. No toxicological

data is available for the product as such.Acute toxicity (oral): Lack of data.Acute toxicity (dermal): Lack of data.Acute toxicity (inhalative): Lack of data.Skin corrosion/irritation: Skin Irrit. 2; H315 = Causes skin irritation.Serious eye damage/irritation: Eye Irrit. 2; H319 = Causes serious eye irritation.Sensitisation to the respiratory tract: Lack of data.Skin sensitisation: Skin Sens. 1; H317 = May cause an allergic skin reaction.Germ cell mutagenicity/Genotoxicity: Based on available data, the classification criteria are not met.Information about 2-Hydroxyethyl methacrylatein vivo mutagenicity negative (OECD 471)Information about CumeneIn vitro mutagenicity negativeInformation about Cumene hydroperoxidein vivo mutagenicity negative (ECHA-Dossier)Information about Methacrylic acidIn vitro mutagenicity negativeCarcinogenicity: Based on available data, the classification criteria are not met.Information about CumeneLOAEC = 205 ppm/105 weeks (OECD 451)Reproductive toxicity: Based on available data, the classification criteria are not met.Information about CumeneNOAEL Rat = 1200 ppm/13 weeks (OECD 413)Information about 2-Hydroxyethyl methacrylateNOAEL Rat >= 1000 mg/kg/d (OECD 422)Information about Methacrylic acidNOAEL Rabbit, 29d = 450 mg/kg/d (ECHA-Dossier)Effects on or via lactation: Lack of data.Specific target organ toxicity (single exposure): STOT SE 3; H335 = May cause respiratory irritation.Specific target organ toxicity (repeated exposure): Based on available data, the classification criteria are not met.Information about CumeneNOAEC Rat, oral (90 d): 125 ppm (OECD 413)Information about 2-Hydroxyethyl methacrylateNOAEL Rat, oral (90 d): 30 mg/kg/d (OECD 422)Information about Cumene hydroperoxideNOAEL Rat, inhalative (90d): 5 ppm (OECD 408)Aspiration hazard: Based on available data, the classification criteria are not met.

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Other information: Information about Esterification products of 4,4'-isopropylidenediphenol, ethoxylated and 2-methylprop-2-enoic acid:LD50 Rat, oral: >2000 mg/kg LD50 Rat, dermal: >2000 mg/kg Information about 2-Hydroxyethyl methacrylate:LD50 Rat, oral: >5000 mg/kgLD50 Rabbit, dermal: >5000 mg/kgInformation about Cumene hydroperoxide:LD50 oral, Rat: 382 mg/kg (IUCLID)LD50 Rat, dermal: 500 mg/kg (RTECS)LC50 Mouse, inhalative (vapour): 200 mg/L/4h (IUCLID)ATE inhalative (Aerosol): 0.5 mg/LInformation about Methacrylic acid:LD50 Rat, oral: 1320 mg/kg (ECHA-Dossier)LD50 Rabbit, dermal: 500-1000 mg/kg (ECHA-Dossier)LC50 Rat, inhalative (Aerosol): 7.1 mg/L/4h (ECHA-Dossier)ATE inhalative: 11 mg/L (Aerosol)Information about 2'-phenylacetohydrazide:LD50 Mouse, oral: 270 mg/kg (RTECS)Information about Maleic acid:LD50 Rat, oral: 2870 mg/kg (ECHA-Dossier)Information about N,N-Dimethyl-o-toluidine:ATE, oral: 100 mg/kgATE, dermal: 300 mg/kgATE, inhalative (vapour): 3 mg/LATE, inhalative (Aerosol): 0.5 mg/L

SymptomsIn case of inhalation: Vapours irritate mucous membranes and respiratory tracts.

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SECTION 12: Ecological information12.1 ToxicityAquatic toxicity: May cause long lasting harmful effects to aquatic life.

Information about Esterification products of 4,4'-isopropylidenediphenol, ethoxylated and 2-methylprop-2-enoic acidDaphnia toxicity:EC50 Daphnia magna (Big water flea): > 100 mg/L/48h (ECHA Dossier)Information about 2-Hydroxyethyl methacrylateFish toxicity:LC50 Oryzias latipes: > 100 mg/L/96h (ECHA Dossier)Algae toxicity:ErC50 Selenastrum capricornutum: 836 mg/L/72h (ECHA Dossier)Daphnia toxicity:EC50 Daphnia magna (Big water flea): 380 mg/L/48h (ECHA Dossier) Daphnia toxicity:NOEC Daphnia magna (Big water flea): 24.1 mg/L/21d (ECHA Dossier)Information about Methacrylic acidFish toxicity:LC50 Oncorhynchus mykiss: 85 mg/L/96h (ECHA Dossier)Fish toxicity:NOEC Brachydanio rerio (zebra-fish): 10 mg/L/35d (ECHA Dossier)Algae toxicity:ErC50 Pseudokirchneriella subcapitata (green algae): 45 mg/L/72h (ECHA Dossier)Daphnia toxicity:EC50 Daphnia magna (Big water flea): > 130 mg/L/48h (ECHA Dossier) Daphnia toxicity:NOEC Daphnia magna (Big water flea): 53 mg/L/21d (ECHA Dossier)Information about Maleic acidAlgae toxicity:ErC50 Pseudokirchnerella subcapitata: 74.35 mg/L/96h (ECHA Dossier)Daphnia toxicity:EC50 Daphnia magna (Big water flea): 42.81 mg/L/48h (ECHA Dossier)Information about Cumene hydroperoxideFish toxicity:LC50 Oncorhynchus mykiss: 3.9 mg/L/96h (ECHA Dossier)Algae toxicity:ErC50 Selenastrum capricornutum: 3.1 mg/L/72h (ECHA Dossier)Daphnia toxicity:EC50 Daphnia magna (Big water flea): 18.84 mg/L/48h (ECHA Dossier)

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12.2 Persistence and degradabilityFurther details: Information about Esterification products of 4,4'-isopropylidenediphenol, ethoxylated and

2-methylprop-2-enoic acidBiodegradation: 24 %/28d (not readily biodegradable (according to OECD criteria)) (ECHA Dossier)Information about 2-Hydroxyethyl methacrylateBiodegradation: > 92 %/14d (readily biodegradable (according to OECD criteria)) (ECHA Dossier)Information about Methacrylic acidBiodegradation: 86 %/28d (readily biodegradable (according to OECD criteria))Information about Maleic acidBiodegradation: 97.08 %/28d (readily biodegradable (according to OECD criteria))Information about Cumene hydroperoxideBiodegradation: 3 %/28d (not readily biodegradable (according to OECD criteria)) (ECHA Dossier)

12.3 Bioaccumulative potentialPartition coefficient: n-octanol/water:

0.93 log P(o/w) (Methacrylic acid)Based on the n-octanol/water partition coefficient accumulation in organisms is not expected.0.47 log P(o/w) (2-Hydroxyethyl methacrylate)Based on the n-octanol/water partition coefficient accumulation in organisms is not expected.5.30 - 5.62 log P(o/w) (Esterification products of 4,4'-isopropylidenediphenol, ethoxylated and 2-methylprop-2-enoic acid)Based on the n-octanol/water partition coefficient accumulation in organisms is not expected.2.16 log P(o/w) (Cumene hydroperoxide)Based on the n-octanol/water partition coefficient accumulation in organisms is not expected.-0.79 log P(o/w) (Maleic acid)Based on the n-octanol/water partition coefficient accumulation in organisms is not expected.

12.4 Mobility in soilNo data available

12.5 Results of PBT and vPvB assessmentNo data available

12.6 Other adverse effectsGeneral information: Do not allow to penetrate into soil, waterbodies or drains.

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SAFETY DATA SHEETaccording to Regulation (EC) No. 1907/2006 (REACH) and Regulation (EU) No. 2015/830

Anaerobe Klebstoffe Kategorie DMaterial number ANAEROB_D1

Revision date: 28/12/2017Version: 2Language: en-GB,IEDate of print: 30/1/2018

Page: 13 of 15

SECTION 13: Disposal considerations13.1 Waste treatment methodsProductWaste key number: 08 04 09* = Waste adhesives and sealants containing organic solvents or other

dangerous substances.MFSU = manufacture, formulation, supply and use* = Evidence for disposal must be provided.

Recommendation: Dispose of waste according to applicable legislation.

Contaminated packagingWaste key number: 15 01 10 = packaging containing residues of or contaminated by dangerous substancesRecommendation: Dispose of waste according to applicable legislation.

Handle contaminated packages in the same way as the substance itself.Non-contaminated packages may be recycled.

SECTION 14: Transport information14.1 UN numberADR/RID, IMDG, IATA-DGR:

not applicable

14.2 UN proper shipping nameADR/RID, IMDG, IATA-DGR:

Not restricted

14.3 Transport hazard class(es)ADR/RID, IMDG, IATA-DGR:

not applicable

14.4 Packing groupADR/RID, IMDG, IATA-DGR:

not applicable

14.5 Environmental hazardsMarine pollutant: no

14.6 Special precautions for userNo dangerous good in sense of these transport regulations.

14.7 Transport in bulk according to Annex II of Marpol and the IBC CodeNo data available

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SAFETY DATA SHEETaccording to Regulation (EC) No. 1907/2006 (REACH) and Regulation (EU) No. 2015/830

Anaerobe Klebstoffe Kategorie DMaterial number ANAEROB_D1

Revision date: 28/12/2017Version: 2Language: en-GB,IEDate of print: 30/1/2018

Page: 14 of 15

SECTION 15: Regulatory information15.1 Safety, health and environmental regulations/legislation specific for the substance or mixtureNational regulations - Great BritainHazchem-Code: -

No data available

National regulations - EC member statesLabelling of packaging with <= 125mL content

Signal word: WarningHazard statements: H317 May cause an allergic skin reaction.

H335 May cause respiratory irritation.H413 May cause long lasting harmful effects to aquatic life.

Precautionary statements:P102 Keep out of reach of children.P261 Avoid breathing vapours/spray.P280 Wear protective gloves/protective clothing/eye protection.P302+P352 IF ON SKIN: Wash with plenty of water/soap.P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.P312 Call a POISON CENTER/doctor if you feel unwell.P405 Store locked up.

Further regulations, limitations and legal requirements:

Use restriction according to REACH annex XVII, no.: 3

15.2 Chemical Safety AssessmentFor this mixture a chemical safety assessment is not required.

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SAFETY DATA SHEETaccording to Regulation (EC) No. 1907/2006 (REACH) and Regulation (EU) No. 2015/830

Anaerobe Klebstoffe Kategorie DMaterial number ANAEROB_D1

Revision date: 28/12/2017Version: 2Language: en-GB,IEDate of print: 30/1/2018

Page: 15 of 15

SECTION 16: Other informationFurther informationWording of the H-phrases under paragraph 2 and 3:

H242 = Heating may cause a fire.H301 = Toxic if swallowed.H302 = Harmful if swallowed.H311 = Toxic in contact with skin.H312 = Harmful in contact with skin.H314 = Causes severe skin burns and eye damage.H315 = Causes skin irritation.H317 = May cause an allergic skin reaction.H318 = Causes serious eye damage.H319 = Causes serious eye irritation.H331 = Toxic if inhaled.H332 = Harmful if inhaled.H335 = May cause respiratory irritation.H373 = May cause damage to organs through prolonged or repeated exposure.H411 = Toxic to aquatic life with long lasting effects.H412 = Harmful to aquatic life with long lasting effects.H413 = May cause long lasting harmful effects to aquatic life.

Reason of change: Changes in section 1: Changes of product listChanges in section 2: classification, labellingChanges in section 3: Change of compositonGeneral revision

Date of first version: 28/12/2017Department issuing data sheetContact person: see section 1: Dept. responsible for information

For abbreviations and acronyms, see: ECHA Guidance on information requirements and chemical safety assessment, chapter R.20 (Table of terms and abbreviations).The information in this data sheet has been established to our best knowledge and was up-to-date at time of revision. It does not represent a guarantee for the properties of the product described in terms of the legal warranty regulations.

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