SAFETY DATA SHEET Araldite GY 6010 GY 250 · Araldite_GY 6010_GY 250 2.1. Classification of the...

18
Revision date: 06/07/2020 Revision: 02 Supersedes date: 01/11/2018 SAFETY DATA SHEET Araldite_GY 6010_GY 250 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product name Araldite_GY 6010_GY 250 Chemical name 100% 2,2'-[(1-methylethylidene)bis(4,1-phenyleneoxymethylene)]bisoxirane REACH registration number 01-2119456619-26-0012 CAS number 1675-54-3 EU index number 603-073-00-2 EC number 216-823-5 1.2. Relevant identified uses of the substance or mixture and uses advised against Identified uses Manufacturing of the substance. Formulation Industrial in closed systems. Industrial use as intermediate. Industrial use as monomer. Use on industrial site. Use by professional workers. DIY Consumer Applications. Sector of Use Refer to Annexes (after Section 16) Process category Refer to Annexes (after Section 16) Environmental release category Refer to Annexes (after Section 16) Application of the substance / the mixture Epoxy Resin liquid 1.3. Details of the supplier of the safety data sheet Manufacturer Jubail Chemical Industries Company (JANA) Tareeq 263, Jubail 1, Jubail Industrial City, 31961 Kingdom of Saudi Arabia, (PO Box 10661) Tel. +966 13 3585002 Fax. +966 13 3583192 [email protected] Only Representative REACH 1907/2006/EC Article 8 NAMA Germany Teichstrasse 38 D-79539 Lörrach Tel. + 49 762 1940 5410 Fax. + 49 762 1940 5420 1.4. Emergency telephone number Emergency telephone Emergency CONTACT (24-Hour-Number):GBK GmbH +49 (0)6132-84463 SECTION 2: Hazards identification 1/ 10

Transcript of SAFETY DATA SHEET Araldite GY 6010 GY 250 · Araldite_GY 6010_GY 250 2.1. Classification of the...

Page 1: SAFETY DATA SHEET Araldite GY 6010 GY 250 · Araldite_GY 6010_GY 250 2.1. Classification of the substance or mixture Classification (EC 1272/2008) Physical hazards Not Classified

Revision date: 06/07/2020 Revision: 02 Supersedes date: 01/11/2018

SAFETY DATA SHEETAraldite_GY 6010_GY 250

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

Product name Araldite_GY 6010_GY 250

Chemical name 100% 2,2'-[(1-methylethylidene)bis(4,1-phenyleneoxymethylene)]bisoxirane

REACH registration number 01-2119456619-26-0012

CAS number 1675-54-3

EU index number 603-073-00-2

EC number 216-823-5

1.2. Relevant identified uses of the substance or mixture and uses advised against

Identified uses Manufacturing of the substance.Formulation Industrial in closed systems.Industrial use as intermediate.Industrial use as monomer.Use on industrial site.Use by professional workers.DIY Consumer Applications.

Sector of Use Refer to Annexes (after Section 16)

Process category Refer to Annexes (after Section 16)

Environmental releasecategory

Refer to Annexes (after Section 16)

Application of the substance /the mixture

Epoxy Resin liquid

1.3. Details of the supplier of the safety data sheet

Manufacturer Jubail Chemical Industries Company (JANA)Tareeq 263, Jubail 1, Jubail Industrial City, 31961Kingdom of Saudi Arabia, (PO Box 10661)Tel. +966 13 3585002Fax. +966 13 [email protected]

Only Representative REACH1907/2006/EC Article 8

NAMA GermanyTeichstrasse 38D-79539 LörrachTel. + 49 762 1940 5410Fax. + 49 762 1940 5420

1.4. Emergency telephone number

Emergency telephone Emergency CONTACT (24-Hour-Number):GBK GmbH +49 (0)6132-84463

SECTION 2: Hazards identification

1/10

Page 2: SAFETY DATA SHEET Araldite GY 6010 GY 250 · Araldite_GY 6010_GY 250 2.1. Classification of the substance or mixture Classification (EC 1272/2008) Physical hazards Not Classified

Revision date: 06/07/2020 Revision: 02 Supersedes date: 01/11/2018

Araldite_GY 6010_GY 250

2.1. Classification of the substance or mixtureClassification (EC 1272/2008)Physical hazards Not Classified

Health hazards Skin Irrit. 2 - H315 Eye Irrit. 2 - H319 Skin Sens. 1 - H317

Environmental hazards Aquatic Chronic 2 - H411

2.2. Label elements

EC number 216-823-5

Hazard pictograms

Signal word Warning

Hazard-determiningcomponents of labelling

2,2'-[(1-methylethylidene)bis(4,1-phenyleneoxymethylene)]bisoxirane

Hazard statements H315 Causes skin irritation.H317 May cause an allergic skin reaction.H319 Causes serious eye irritation.H411 Toxic to aquatic life with long lasting effects.

Precautionary statements P261 Avoid breathing vapour/ spray.P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Removecontact lenses, if present and easy to do. Continue rinsing.P501 Dispose of contents/ container in accordance with national regulations.P273 Avoid release to the environment.P264 Wash … thoroughly after handling.

2.3. Other hazards

Results of PBT and vPvBassessment:

Not applicable.

SECTION 3: Composition/information on ingredients

3.1. Substances

Product name Araldite_GY 6010_GY 250

Chemical name 100% 2,2'-[(1-methylethylidene)bis(4,1-phenyleneoxymethylene)]bisoxirane

REACH registration number 01-2119456619-26-0012

EU index number 603-073-00-2

CAS number 1675-54-3

EC number 216-823-5

Chemical formula C21H24O4

SECTION 4: First aid measures

4.1. Description of first aid measures

General information Promptly remove any clothing that becomes wet or contaminated.

2/10

Page 3: SAFETY DATA SHEET Araldite GY 6010 GY 250 · Araldite_GY 6010_GY 250 2.1. Classification of the substance or mixture Classification (EC 1272/2008) Physical hazards Not Classified

Revision date: 06/07/2020 Revision: 02 Supersedes date: 01/11/2018

Araldite_GY 6010_GY 250

Inhalation IF INHALED: Move affected person to fresh air at once. Place unconscious person on theirside in the recovery position and ensure breathing can take place. Get medical attention.

Ingestion IF SWALLOWED: Administer medicinal carbon. Get medical attention immediately.

Skin contact IF ON SKIN: Wash skin thoroughly with soap and water or use an approved skin cleanser. Donot use organic solvents. Get medical attention immediately.

Eye contact IF IN EYES: Rinse with water. Remove any contact lenses and open eyelids wide apart. Getmedical attention immediately.

4.2. Most important symptoms and effects, both acute and delayed4.3. Indication of any immediate medical attention and special treatment needed

Notes for the doctor No information available.

SECTION 5: Firefighting measures

5.1. Extinguishing media

Suitable extinguishing media Use fire-extinguishing media suitable for the surrounding fire.

Unsuitable extinguishingmedia

Do not use water jet as an extinguisher, as this will spread the fire.

5.2. Special hazards arising from the substance or mixture

Specific hazards Vapours may form explosive mixtures with air. Oxides of carbon. In case of fire and/orexplosion do not breathe fumes.

Hazardous combustionproducts

Thermal decomposition or combustion products may include the following substances: Oxidesof carbon. Toxic gases or vapours.

5.3. Advice for firefighters

Special protective equipmentfor firefighters

Wear positive-pressure self-contained breathing apparatus (SCBA) and appropriate protectiveclothing. Wear chemical protective suit.

Additional information Dispose of fire debris and contaminated fire fighting water in accordance with officialregulations.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

Personal precautions Wear protective clothing, gloves, eye and face protection.

6.2. Environmental precautions

Environmental precautions Dispose of waste to licensed waste disposal site in accordance with the requirements of thelocal Waste Disposal Authority. Do not discharge into drains or watercourses or onto theground. Avoid the spillage or runoff entering drains, sewers or watercourses. Inform therelevant authorities if environmental pollution occurs (sewers, waterways, soil or air).

6.3. Methods and material for containment and cleaning up

Methods for cleaning up Contain and absorb spillage with sand, earth or other non-combustible material. This can beeased by using warm soapy water. Alternatively, or if it is not water-soluble, absorb thespillage with an inert, dry material and place it in a suitable waste disposal container.

6.4. Reference to other sections

Reference to other sections Follow precautions for safe handling described in this safety data sheet. For personalprotection, see Section 8. For waste disposal, see Section 13.

SECTION 7: Handling and storage

3/10

Page 4: SAFETY DATA SHEET Araldite GY 6010 GY 250 · Araldite_GY 6010_GY 250 2.1. Classification of the substance or mixture Classification (EC 1272/2008) Physical hazards Not Classified

Revision date: 06/07/2020 Revision: 02 Supersedes date: 01/11/2018

Araldite_GY 6010_GY 250

7.1. Precautions for safe handling

Usage precautions No specific requirements are anticipated under normal conditions of use.

7.2. Conditions for safe storage, including any incompatibilities

Requirements to be met bystorerooms and receptacles

None.

Storage precautions Keep away from food, drink and animal feeding stuffs. Keep container tightly closed and dry.Store at temperatures between 2°C and 43°C.

Storage class 10 (TRGS 510) The product is non-combustible.

7.3. Specific end use(s)

Specific end use(s) No information available.

SECTION 8: Exposure controls/Personal protection

8.1. Control parameters

Ingredient comments No exposure limits known for ingredient(s).

DNEL Workers - Dermal; Long term : 8.33 mg/kg bw/TagWorkers - Dermal; Short term Acute: 8,33 mg/kg bw/TagWorkers - Inhalation; Short term Acute: 12.25 mg/m³Workers - Inhalation; Long term : 12.25 mg/m³

PNEC - STP; 10 mg/l- Fresh water; 0.006 mg/l- Sediment (Freshwater); 0.341 mg/kg/dwt- marine water; 0.001 mg/l- Sediment (Marinewater); 0.034 mg/kg/dwt- Soil; 0.065 mg/kg/dwt

Additional information: The lists valid during the making were used as basis

8.2. Exposure controls

Protective equipment

Appropriate engineeringcontrols

Provide adequate general and local exhaust ventilation.

Personal protection Keep away from food, drink and animal feeding stuffs. Remove contaminated clothing andwash the skin thoroughly with soap and water after work. Avoid contact with skin, eyes andclothing. Use appropriate skin cream to prevent drying of skin.

Eye/face protection Wear tight-fitting, chemical splash goggles or face shield. Personal protective equipment foreye and face protection should comply with European Standard EN166.

4/10

Page 5: SAFETY DATA SHEET Araldite GY 6010 GY 250 · Araldite_GY 6010_GY 250 2.1. Classification of the substance or mixture Classification (EC 1272/2008) Physical hazards Not Classified

Revision date: 06/07/2020 Revision: 02 Supersedes date: 01/11/2018

Araldite_GY 6010_GY 250

Hand protection It is recommended that chemical-resistant, impervious gloves are worn. (EN 374). For userswith sensitive skin, it is recommended that suitable protective gloves are worn. It isrecommended that gloves are made of the following material: Rubber (natural, latex).Chloroprene rubber. Nitrile rubber. Viton rubber (fluoro rubber). Butyl rubber. Polyvinylchloride (PVC). Considering the data specified by the glove manufacturer, check during usethat the gloves are retaining their protective properties and change them as soon as anydeterioration is detected. The most suitable glove should be chosen in consultation with theglove supplier/manufacturer, who can provide information about the breakthrough time of theglove material.

Other skin and bodyprotection

Wear protective clothing.

Respiratory protection If ventilation is inadequate, suitable respiratory protection must be worn.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

Appearance Clear liquid.

Colour Colourless to pale yellow.

Odour Characteristic.

Odour threshold Not determined.

pH Not determined.

Melting point -16°C

Initial boiling point and range Not determined.

Flash point 264 - 268°C

Flammability (solid, gas) Not applicable.

Upper/lower flammability orexplosive limits

Not determined.

Vapour pressure Not determined.

Vapour density Not determined.

Density 1.15 - 1.17 g/cm3 @ 25°C

Solubility(ies) Slightly soluble in water.

Auto-ignition temperature Not determined.

Decomposition Temperature 320°C

Viscosity 8000 - 24000 mPa s @ 25°C

Explosive properties None.

Organic solvents 0.0%

VOC (EC) 0.00%

VOC (CH) 0,00%

Volatile by Wt:

9.2. Other information

Other information No information available.

5/10

Page 6: SAFETY DATA SHEET Araldite GY 6010 GY 250 · Araldite_GY 6010_GY 250 2.1. Classification of the substance or mixture Classification (EC 1272/2008) Physical hazards Not Classified

Revision date: 06/07/2020 Revision: 02 Supersedes date: 01/11/2018

Araldite_GY 6010_GY 250

SECTION 10: Stability and reactivity

10.1. Reactivity

Reactivity No information available.

10.2. Chemical stability

Stability Stable under the prescribed storage conditions.

Thermal decomposition /conditions to be avoided

Take precautionary measures against static discharge. Stable under the prescribed storageconditions.

10.3. Possibility of hazardous reactions

Possibility of hazardousreactions

Polymerization will not occur by itself. Masses of more than one pound (0.5 kg) of productplus an aliphatic amine will cause irreversible polymerization with considerable heat build-up.

10.4. Conditions to avoid

Conditions to avoid Keep at temperature not exceeding 300°C.

10.5. Incompatible materials

Materials to avoid Avoid contact with oxidising agents. Avoid contact with acids. Amines.

10.6. Hazardous decomposition products

Hazardous decompositionproducts

Thermal decomposition or combustion products may include the following substances:Aldehydes. Carbon monoxide (CO). Carbon dioxide (CO2). Oxides of carbon. Toxic gases orvapours.

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Toxicological effects Based on available data the classification criteria are not met.

Acute toxicity - oralAcute toxicity oral (LD₅₀mg/kg)

15,000.0

Species Rat

Acute toxicity - dermalAcute toxicity dermal (LD₅₀mg/kg)

23,000.0

Species Rabbit

ATE dermal (mg/kg) 23,000.0

Skin corrosion/irritationSkin corrosion/irritation Causes skin irritation.

Serious eye damage/irritationSerious eye damage/irritation Causes eye irritation.

Respiratory sensitisationRespiratory sensitisation Not available.

Skin sensitisationSkin sensitisation Sensitising.

Germ cell mutagenicityGenotoxicity - in vitro Based on available data the classification criteria are not met.

6/10

Page 7: SAFETY DATA SHEET Araldite GY 6010 GY 250 · Araldite_GY 6010_GY 250 2.1. Classification of the substance or mixture Classification (EC 1272/2008) Physical hazards Not Classified

Revision date: 06/07/2020 Revision: 02 Supersedes date: 01/11/2018

Araldite_GY 6010_GY 250

CarcinogenicityCarcinogenicity Based on available data the classification criteria are not met.

Reproductive toxicityReproductive toxicity - fertility Fertility - NOAEL 750 mg/Kg bw/day, Subcutaneous, Rat

Reproductive toxicity -development

Developmental toxicity: - NOAEL: 180 mg/Kg bw/day, Dermal, Rabbit

Specific target organ toxicity - single exposureSTOT - single exposure Based on available data the classification criteria are not met.

Specific target organ toxicity - repeated exposureSTOT - repeated exposure Based on available data the classification criteria are not met.

Aspiration hazardAspiration hazard Based on available data the classification criteria are not met.

Toxicological information of the main substances found in the product:

SECTION 12: Ecological information

General Notes The product contains a substance which is toxic to aquatic organisms. Water hazard class 2(German Regulation) (Self-assessment): hazardous for water Do not allow product to reachground water, water course or sewage system. Danger to drinking water if even smallquantities leak into the ground.

Ecotoxicity Toxic for fish.

12.1. Toxicity

Toxicity Adopt good working practices, so that the product is not released into the environment.

Acute aquatic toxicityAcute toxicity - fish LC₅₀, 96 hours: 2 mg/l, Oncorhynchus mykiss

Acute toxicity - aquaticinvertebrates

EC₅₀, 48 hours: 1.8 mg/l, Daphnia magna

Acute toxicity - aquatic plants EC₅₀, 72 hours: 11 mg/l, Freshwater algae

Acute toxicity -microorganisms

EC₅₀, 3 hours: 100 mg/l, Notes: micro-organism

12.2. Persistence and degradability

Biodegradation Not readily biodegradable.

12.3. Bioaccumulative potential

Bioaccumulative potential Bioaccumulation is unlikely.

12.4. Mobility in soil

Mobility No information available.

12.5. Results of PBT and vPvB assessment

Results of PBT and vPvBassessment

Not applicable.

12.6. Other adverse effects

7/10

Page 8: SAFETY DATA SHEET Araldite GY 6010 GY 250 · Araldite_GY 6010_GY 250 2.1. Classification of the substance or mixture Classification (EC 1272/2008) Physical hazards Not Classified

Revision date: 06/07/2020 Revision: 02 Supersedes date: 01/11/2018

Araldite_GY 6010_GY 250

Other adverse effects No information available.

SECTION 13: Disposal considerations

13.1. Waste treatment methods

General information External recovery, treatment, recycling and disposal of waste should comply with allapplicable local and/or national regulations.

European waste catalogue: 08 04 09: waste adhesives and sealants containing organic solvents or other hazardoussubstances

SECTION 14: Transport information

14.1. UN number

UN No. (ADR/RID) 3082

UN No. (IMDG) 3082

UN No. (ICAO) 3082

14.2. UN proper shipping name

Proper shipping name(ADR/RID)

ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Epoxy Resin)

Proper shipping name (IMDG) ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Epoxy Resin), MARINEPOLLUTANT

Proper shipping name (ICAO) ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Epoxy Resin)

14.3. Transport hazard class(es)

ADR/RID class 9

ADR/RID classification code M6

ADR/RID label 9

IMDG class 9

ICAO class/division 9

Transport labels

14.4. Packing group

ADR/RID packing group III

IMDG packing group III

ICAO packing group III

14.5. Environmental hazards

Environmentally hazardous substance/marine pollutant

14.6. Special precautions for user

8/10

Page 9: SAFETY DATA SHEET Araldite GY 6010 GY 250 · Araldite_GY 6010_GY 250 2.1. Classification of the substance or mixture Classification (EC 1272/2008) Physical hazards Not Classified

Revision date: 06/07/2020 Revision: 02 Supersedes date: 01/11/2018

Araldite_GY 6010_GY 250

EmS F-A, S-F

ADR transport category 3

Emergency Action Code •3Z

Hazard Identification Number(ADR/RID)

90

Tunnel restriction code (-)

Transportation AdditionalInformation: ADR/IMDG

Excepted Quantities (EQ): Code:E1

Limited Quantities (LQ): 5 L

Maximum Net Quantity perInner Packaging:

30 ml

Maximum Net Quantity perOuter Packaging:

1000 ml

14.7. Transport in bulk according to Annex II of MARPOL and the IBC Code

Transport in bulk according toAnnex II of MARPOL 73/78and the IBC Code

Not applicable.

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

EU legislation Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16December 2008 on classification, labelling and packaging of substances and mixtures (asamended).

Qualifying quantity forapplication of lower-tierrequirements (2012/18/EU):

200MT

Qualifying quantity forapplication of upper-tierrequirements(2012/18/EU):

500MT

15.2. Chemical safety assessment

A chemical safety assessment has been carried out.

SECTION 16: Other information

9/10

Page 10: SAFETY DATA SHEET Araldite GY 6010 GY 250 · Araldite_GY 6010_GY 250 2.1. Classification of the substance or mixture Classification (EC 1272/2008) Physical hazards Not Classified

Revision date: 06/07/2020 Revision: 02 Supersedes date: 01/11/2018

Araldite_GY 6010_GY 250

Abbreviations and acronymsused in the safety data sheet

RID: European Agreement concerning the International Carriage of Dangerous Goods byRail.ICAO: International Civil Aviation OrganisationADR: European Agreement concerning the International Carriage of Dangerous Goods byRoad.IMDG: International Maritime Dangerous Goods.IATA: International Air Transport Association.GHS: Globally Harmonized System.EINECSCAS: Chemical Abstracts Service.VOCV: Lengkungsabgabe auf fluchtingen organischen Verbindungen, Schweiz (SwissOrdinance on volatile organic compounds)VOC: Volatile Organic Compounds (USA,EU)OECD: Organization for Economic Cooperation and DevelopmentDNEL: Derived No Effect Level.PNEC: Predicted No Effect Concentration.LC₅₀: Lethal Concentration to 50 % of a test population.LD₅₀: Lethal Dose to 50% of a test population (Median Lethal Dose).PBT: Persistent, Bioaccumulative and Toxic substance.vPvB: Very Persistent and Very Bioaccumulative.Skin Irrit. 2 - H315Skin Irrit. = Skin irritationSkin Sens. = Skin sensitisationSkin Sens. 1 - H317Eye Irrit. = Eye irritationEye Irrit. 2 - H319Aquatic Chronic 2 - H411

Revision comments SECTION 01: Identification of the substance/mixture and of the company/undertakingSECTION 03: Composition/information on ingredients SECTION 02: Hazards IdentifcationSECTION 03: Composition/information on ingredients SECTION 07: Handling and StorageSECTION 08: Exposure Controls/Personal Protection SECTION 09: Physical and ChemicalProperties SECTION 10: Stability and Reactivity SECTION 11: Toxicological InformationSECTION 12: Ecological Information SECTION 14: Transportation Information SECTION 16:Other Information

Revision date 06/07/2020

Revision 02

Supersedes date 01/11/2018

SDS number 4640

Hazard statements in full H315 Causes skin irritation.H317 May cause an allergic skin reaction.H319 Causes serious eye irritation.H411 Toxic to aquatic life with long lasting effects.

Disclaimer This information relates only to the specific material designated and may not be valid for suchmaterial used in combination with any other materials or in any process. Such information is,to the best of the company's knowledge and belief, accurate and reliable as of the dateindicated. However, no warranty, guarantee or representation is made to its accuracy,reliability or completeness. It is the user's responsibility to satisfy himself as to the suitability ofsuch information for his own particular use.

10/10

Page 11: SAFETY DATA SHEET Araldite GY 6010 GY 250 · Araldite_GY 6010_GY 250 2.1. Classification of the substance or mixture Classification (EC 1272/2008) Physical hazards Not Classified

11/18

Annex: Exposure scenario 1

Short title of the exposure scenario M-1 Manufacture

· Process category

PROC2 Chemical production or refinery in closed continuous process with occasional controlled exposure

or processes with equivalent containment conditions

PROC15 Use as laboratory reagent

PROC8b Transfer of substance or mixture (charging and discharging) at dedicated facilities

· Environmental release category ERC1 Manufacture of the substance

· Description of the activities / processes covered in the Exposure Scenario

See section 1 of the annex to the Safety Data Sheet.

· Conditions of use

· Duration and frequency 5 workdays/week.

· Worker Regular use with exposure up to 8 hrs. per workday.

· Environment The product must not be released into the environment.

· Physical parameters

The data on the physical - chemical properties in the Exposure Scenario is based on the properties of the

preparation.

· Physical state Fluid

· Concentration of the substance in the mixture The substance is main component.

· Used amount per time or activity

12000 tons per year

40 tons per day

· Other operational conditions Observe the general safety regulations when handling chemicals.

· Other operational conditions affecting environmental exposure

Observe section 6 of the Safety Data Sheet (Accidental release measures).

Use only on hard ground.

· Other operational conditions affecting worker exposure

Avoid contact with eyes

Avoid contact with the skin.

Avoid long-term or repeated skin contact.

· Other operational conditions affecting consumer exposure Keep out of the reach of children.

· Other operational conditions affecting consumer exposure during the use of the product Not applicable.

· Risk management measures

· Worker protection

· Organizational protective measures

Handling procedures must be well documented.

Ensure that activities are executed by specialists or authorised personnel only.

· Technical protective measures

Use product only in enclosed systems.

Ensure that suitable extractors are available on processing machines

· Personal protective measures

Do not inhale gases / fumes / aerosols.

Avoid contact with the eyes.

Tightly sealed goggles

Chemical resistant gloves (EN 374)

Protective gloves

The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.

Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/

the chemical mixture.

Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation

Avoid contact with the skin.

· Measures for consumer protection

Ensure adequate labelling.

Keep locked up and out of the reach of children.

Environmental protection measures

Avoid release to the environment. Obtain special instructions / refer to Safety Data Sheet.

· Air Exhaust air is introduced into the gas scrubber.

· Water Do not allow to reach sewage system.

· Soil Prevent contamination of soil.

· Notes In case of unintended release of the product: See section 6 of the Safety Data Sheet.

· Disposal measures

Disposal must be made according to official regulations.

Ensure that waste is collected and contained.

Page 12: SAFETY DATA SHEET Araldite GY 6010 GY 250 · Araldite_GY 6010_GY 250 2.1. Classification of the substance or mixture Classification (EC 1272/2008) Physical hazards Not Classified

12/18

· Disposal procedures

Must not be disposed together with household garbage. Do not allow product to reach sewage system.

· Waste type Partially emptied and uncleaned packaging

· Exposure estimation

· Consumer Not relevant for this Exposure Scenario.

· Guidance for downstream users No further relevant information available

Annex: Exposure scenario 2

. Short title of the exposure scenario F-2 Formulation Industrial in closed systems

· Process category

PROC9 Transfer of substance or mixture into small containers (dedicated filling line, including weighing)

PROC8b Transfer of substance or mixture (charging and discharging) at dedicated facilities

PROC4 Chemical production where opportunity for exposure arises

PROC3 Manufacture or formulation in the chemical industry in closed batch processes with occasional controlled

exposure or processes with equivalent containment condition

· Environmental release category ERC2 Formulation into mixture

· Description of the activities / processes covered in the Exposure Scenario

See section 1 of the annex to the Safety Data Sheet.

· Conditions of use

· Duration and frequency 5 workdays/week.

· Worker Regular use with exposure up to 8 hrs. per workday.

· Environment The product must not be released into the environment.

· Physical parameters

· Concentration of the substance in the mixture Raw material.

· Used amount per time or activity 14000 tons per year

· Other operational conditions

· Other operational conditions affecting environmental exposure

Observe section 6 of the Safety Data Sheet (Accidental release measures).

Use only on hard ground.

Other operational conditions affecting worker exposure

Avoid contact with eyes.

Avoid contact with the skin.

Avoid long-term or repeated skin contact.

Other operational conditions affecting consumer exposure Keep out of the reach of children.

Other operational conditions affecting consumer exposure during the use of the product Not applicable.

· Risk management measures

· Worker protection

· Organisational protective measures

Ensure that activities are executed by specialists or authorised personnel only.

Handling procedures must be well documented.

· Technical protective measures

The work process has to be performed under closed conditions.

Ensure that suitable extractors are available on processing machines

Use product only in enclosed systems.

· Personal protective measures

Do not inhale gases / fumes / aerosols.

Avoid contact with the skin. Avoid contact with the eyes. Tightly sealed goggles Protective gloves

The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.

Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/

the chemical mixture.

Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation

· Measures for consumer protection

Keep locked up and out of the reach of children.

Ensure adequate labelling.

· Environmental protection measures

Avoid release to the environment. Obtain special instructions / refer to Safety Data Sheet.

· Water Do not allow to reach sewage system.

· Soil Prevent contamination of soil.

· Notes In case of unintended release of the product: See section 6 of the Safety Data Sheet.

Disposal measures

Disposal must be made according to official regulations.

Ensure that waste is collected and contained.

· Disposal procedures

Must not be disposed together with household garbage. Do not allow product to reach sewage system

Page 13: SAFETY DATA SHEET Araldite GY 6010 GY 250 · Araldite_GY 6010_GY 250 2.1. Classification of the substance or mixture Classification (EC 1272/2008) Physical hazards Not Classified

13/18

Waste type Partially emptied and uncleaned packaging

· Exposure estimation

· Worker (oral) The calculated value is smaller than the DNEL.

· Worker (dermal) The calculated value is smaller than the DNEL.

· Worker (inhalation) The calculated value is smaller than the DNEL.

· Consumer Not relevant for this Exposure Scenario.

· Guidance for downstream users No further relevant information available.

Annex: Exposure scenario 3

Short title of the exposure scenario IW-4 Industrial use as intermediate

· Product category PC19 Intermediate

· Process category

PROC8b Transfer of substance or mixture (charging and discharging) at dedicated facilities

PROC3 Manufacture or formulation in the chemical industry in closed batch processes with occasional controlled

exposure or processes with equivalent containment condition

PROC2 Chemical production or refinery in closed continuous process with occasional controlled exposure or

processes with equivalent containment conditions

PROC1 Chemical production or refinery in closed process without likelihood of exposure or processes with equivalent

containment conditions.

· Environmental release category ERC6a Use of intermediate

· Description of the activities / processes covered in the Exposure Scenario

See section 1 of the annex to the Safety Data Sheet.

· Conditions of use

· Duration and frequency 5 workdays/week.

· Worker Regular use with exposure up to 8 hrs. per workday.

· Environment The product must not be released into the environment.

· Physical parameters

· Concentration of the substance in the mixture Raw material.

· Used amount per time or activity 1200 tons per year

· Other operational conditions

· Other operational conditions affecting environmental exposure

Observe section 6 of the Safety Data Sheet (Accidental release measures).

Use only on hard ground.

Other operational conditions affecting worker exposure

Avoid contact with eyes.

Avoid contact with the skin.

Avoid long-term or repeated skin contact.

· Other operational conditions affecting consumer exposure Keep out of the reach of children.

· Other operational conditions affecting consumer exposure during the use of the product Not applicable.

· Risk management measures

· Worker protection

· Organisational protective measures

Ensure that activities are executed by specialists or authorised personnel only.

Handling procedures must be well documented.

· Technical protective measures

The work process has to be performed under closed conditions.

Ensure that suitable extractors are available on processing machines

Use product only in enclosed systems.

· Personal protective measures

Do not inhale gases / fumes / aerosols.

Avoid contact with the skin. Avoid contact with the eyes. Tightly sealed goggles Protective gloves

The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.

Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/

the chemical mixture.

Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation

· Measures for consumer protection

Keep locked up and out of the reach of children.

Ensure adequate labelling.

· Environmental protection measures

Avoid release to the environment. Obtain special instructions / refer to Safety Data Sheet.

· Water Do not allow to reach sewage system.

· Soil Prevent contamination of soil.

· Notes In case of unintended release of the product: See section 6 of the Safety Data Sheet.

· Disposal measures

Page 14: SAFETY DATA SHEET Araldite GY 6010 GY 250 · Araldite_GY 6010_GY 250 2.1. Classification of the substance or mixture Classification (EC 1272/2008) Physical hazards Not Classified

14/18

Disposal must be made according to official regulations.

Ensure that waste is collected and contained.

Disposal procedures

Must not be disposed together with household garbage. Do not allow product to reach sewage system.

· Waste type Partially emptied and uncleaned packaging

· Exposure estimation

· Worker (oral) The calculated value is smaller than the DNEL.

· Worker (dermal) The calculated value is smaller than the DNEL.

· Worker (inhalation) The calculated value is smaller than the DNEL.

· Consumer Not relevant for this Exposure Scenario.

· Guidance for downstream users No further relevant information available.

Annex: Exposure scenario 4

Short title of the exposure scenario IW-3 Industrial use as monomer

· Process category

PROC8b Transfer of substance or mixture (charging and discharging) at dedicated facilities

PROC3 Manufacture or formulation in the chemical industry in closed batch processes with occasional

controlled exposure or processes with equivalent containment condition

PROC2 Chemical production or refinery in closed continuous process with occasional controlled exposure or

processes with equivalent containment conditions

PROC1 Chemical production or refinery in closed process without likelihood of exposure or processes with

equivalent containment conditions.

· Environmental release category

ERC4 Use of non-reactive processing aid at industrial site (no inclusion into or onto article)

· Description of the activities / processes covered in the Exposure Scenario

See section 1 of the annex to the Safety Data Sheet.

· Conditions of use

· Duration and frequency 5 workdays/week.

· Worker Regular use with exposure up to 8 hrs. per workday.

· Environment The product must not be released into the environment.

· Physical parameters

· Concentration of the substance in the mixture Raw material.

· Used amount per time or activity 900 tons per year

· Other operational conditions

· Other operational conditions affecting environmental exposure

Observe section 6 of the Safety Data Sheet (Accidental release measures).

Use only on hard ground.

Other operational conditions affecting worker exposure

Avoid contact with eyes.

Avoid contact with the skin.

Avoid long-term or repeated skin contact.

· Other operational conditions affecting consumer exposure Keep out of the reach of children.

· Other operational conditions affecting consumer exposure during the use of the product Not applicable.

· Risk management measures

· Worker protection

· Organisational protective measures

Ensure that activities are executed by specialists or authorised personnel only.

Handling procedures must be well documented.

· Technical protective measures

The work process has to be performed under closed conditions.

Ensure that suitable extractors are available on processing machines

Use product only in enclosed systems.

· Personal protective measures

Do not inhale gases / fumes / aerosols.

Avoid contact with the skin. Avoid contact with the eyes. Tightly sealed goggles Protective gloves

The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.

Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/

the chemical mixture.

Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation

· Measures for consumer protection

Keep locked up and out of the reach of children.

Ensure adequate labelling.

· Environmental protection measures

Avoid release to the environment. Obtain special instructions / refer to Safety Data Sheet.

Page 15: SAFETY DATA SHEET Araldite GY 6010 GY 250 · Araldite_GY 6010_GY 250 2.1. Classification of the substance or mixture Classification (EC 1272/2008) Physical hazards Not Classified

15/18

. Water Do not allow to reach sewage system.

· Soil Prevent contamination of soil.

· Notes In case of unintended release of the product: See section 6 of the Safety Data Sheet.

· Disposal measures

Disposal must be made according to official regulations.

Ensure that waste is collected and contained.

. Disposal procedures

Must not be disposed together with household garbage. Do not allow product to reach sewage system

. Waste type Partially emptied and uncleaned packaging

· Exposure estimation

· Worker (oral) The calculated value is smaller than the DNEL.

· Worker (dermal) The calculated value is smaller than the DNEL.

· Worker (inhalation) The calculated value is smaller than the DNEL.

· Consumer Not relevant for this Exposure Scenario.

· Guidance for downstream users No further relevant information available.

Annex: Exposure scenario 5

· Short title of the exposure scenario IW6 Use on industrial site

· Process category

PROC15 Use as laboratory reagent

PROC13 Treatment of articles by dipping and pouring

PROC10 Roller application or brushing

PROC8b Transfer of substance or mixture (charging and discharging) at dedicated facilities

PROC7 Industrial spraying

· Environmental release category ERC5 Use at industrial site leading to inclusion into/onto article

· Description of the activities / processes covered in the Exposure Scenario

See section 1 of the annex to the Safety Data Sheet.

· Conditions of use

· Duration and frequency 5 workdays/week.

· Worker Regular use with exposure up to 8 hrs. per workday.

· Environment The product must not be released into the environment.

· Physical parameters

· Concentration of the substance in the mixture Raw material.

· Used amount per time or activity 600 tons per year

· Other operational conditions

· Other operational conditions affecting environmental exposure

Observe section 6 of the Safety Data Sheet (Accidental release measures).

Use only on hard ground.

· Other operational conditions affecting worker exposure

Avoid contact with eyes.

Avoid contact with the skin.

Avoid long-term or repeated skin contact.

· Other operational conditions affecting consumer exposure Keep out of the reach of children.

· Other operational conditions affecting consumer exposure during the use of the product Not applicable.

· Risk management measures

Worker protection

· Organisational protective measures

Ensure that activities are executed by specialists or authorised personnel only.

Handling procedures must be well documented.

· Technical protective measures

The work process has to be performed under closed conditions.

Ensure that suitable extractors are available on processing machines

Use product only in enclosed systems.

· Personal protective measures

Do not inhale gases / fumes / aerosols.

Avoid contact with the skin. Avoid

contact with the eyes. Tightly

sealed goggles Protective gloves

The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.

Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/

the chemical mixture.

Selection of the glove material on consideration of the penetration times, rates of diffusion and the

degradation

· Measures for consumer protection

Page 16: SAFETY DATA SHEET Araldite GY 6010 GY 250 · Araldite_GY 6010_GY 250 2.1. Classification of the substance or mixture Classification (EC 1272/2008) Physical hazards Not Classified

16/18

Keep locked up and out of the reach of children.

Ensure adequate labelling.

· Environmental protection measures

Avoid release to the environment. Obtain special instructions / refer to Safety Data Sheet.

· Water Do not allow to reach sewage system.

· Soil Prevent contamination of soil.

· Notes In case of unintended release of the product: See section 6 of the Safety Data Sheet.

· Disposal measures

Disposal must be made according to official regulations.

Ensure that waste is collected and contained.

. Disposal procedures

Must not be disposed together with household garbage. Do not allow product to reach sewage system.

. Waste type Partially emptied and uncleaned packaging

· Exposure estimation

· Worker (oral) The calculated value is smaller than the DNEL.

· Worker (dermal) The calculated value is smaller than the DNEL.

· Worker (inhalation) The calculated value is smaller than the DNEL.

· Consumer Not relevant for this Exposure Scenario.

· Guidance for downstream users No further relevant information available.

Annex: Exposure scenario 6

· Short title of the exposure scenario PW-5 Professional use

· Process category

PROC24 High (mechanical) energy work-up of substances bound in /on materials and/or articles

PROC11 Non industrial spraying

PROC13 Treatment of articles by dipping and pouring

PROC19 Manual activities involving hand contact

PROC8b Transfer of substance or mixture (charging and discharging) at dedicated facilities

PROC10 Roller application or brushing

PROC8a Transfer of substance or mixture (charging and discharging) at non-dedicated facilities

· Environmental release category

ERC8c Widespread use leading to inclusion into/onto article (indoor)

ERC8f Widespread use leading to inclusion into/onto article (outdoor)

· Description of the activities / processes covered in the Exposure Scenario

See section 1 of the annex to the Safety Data Sheet.

· Conditions of use

· Duration and frequency 5 workdays/week.

· Worker Regular use with exposure up to 8 hrs. per workday.

· Environment The product must not be released into the environment.

· Physical parameters

· Concentration of the substance in the mixture Raw material.

· Used amount per time or activity 4000 tons per year

· Other operational conditions

· Other operational conditions affecting environmental exposure

Observe section 6 of the Safety Data Sheet (Accidental release measures).

Use only on hard ground.

. Other operational conditions affecting worker exposure

Avoid contact with eyes.

Avoid contact with the skin.

Avoid long-term or repeated skin contact. Indoor

application.

Outdoor application.

· Other operational conditions affecting consumer exposure Keep out of the reach of children.

· Other operational conditions affecting consumer exposure during the use of the product Not applicable.

· Risk management measures

· Worker protection

· Organisational protective measures

Ensure that activities are executed by specialists or authorised personnel only.

Handling procedures must be well documented.

· Technical protective measures

The work process has to be performed under closed conditions.

Ensure that suitable extractors are available on processing machines

Use product only in enclosed systems.

· Personal protective measures

Page 17: SAFETY DATA SHEET Araldite GY 6010 GY 250 · Araldite_GY 6010_GY 250 2.1. Classification of the substance or mixture Classification (EC 1272/2008) Physical hazards Not Classified

17/18

Do not inhale gases / fumes / aerosols.

Avoid contact with the skin. Avoid

contact with the eyes. Tightly

sealed goggles Protective gloves

The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.

Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/

the chemical mixture.

Selection of the glove material on consideration of the penetration times, rates of diffusion and the

degradation

· Measures for consumer protection

Keep locked up and out of the reach of children.

Ensure adequate labelling.

· Environmental protection measures

Avoid release to the environment. Obtain special instructions / refer to Safety Data Sheet.

· Water Do not allow to reach sewage system.

· Soil Prevent contamination of soil.

· Notes In case of unintended release of the product: See section 6 of the Safety Data Sheet.

· Disposal measures

Disposal must be made according to official regulations.

Ensure that waste is collected and contained.

· Disposal procedures

Must not be disposed together with household garbage. Do not allow product to reach sewage system.

· Waste type Partially emptied and uncleaned packaging

· Exposure estimation

· Worker (oral) The calculated value is smaller than the DNEL.

· Worker (dermal) The calculated value is smaller than the DNEL.

· Worker (inhalation) The calculated value is smaller than the DNEL.

· Consumer Not relevant for this Exposure Scenario.

· Guidance for downstream users No further relevant information available.

Annex: Exposure scenario 7

Short title of the exposure scenario

· Sector of Use C-7 DIY Consumer Applications

· Product category

PC9b Fillers, putties, plasters, modelling clay

PC9a Coatings and paints, thinners, paint removers

PC1 Adhesives, sealants

· Environmental release category

ERC8c Widespread use leading to inclusion into/onto article (indoor)

ERC8f Widespread use leading to inclusion into/onto article (outdoor)

· Description of the activities / processes covered in the Exposure Scenario

See section 1 of the annex to the Safety Data Sheet.

· Conditions of use

· Duration and frequency

Frequency of use:

1-3 applications per year: 1-3/year. Applikation pro Jahr : 1-3/year

· Environment The product must not be released into the environment.

· Physical parameters

· Concentration of the substance in the mixture Raw material.

· Used amount per time or activity 30 annual tons per plant

· Other operational conditions

· Other operational conditions affecting environmental exposure

Observe section 6 of the Safety Data Sheet (Accidental release measures).

Use only on hard ground.

· Other operational conditions affecting worker exposure

Avoid contact with eyes.

Avoid contact with the skin.

Avoid long-term or repeated skin contact. Indoor

application.

Outdoor application.

· Other operational conditions affecting consumer exposure Keep out of the reach of children.

· Other operational conditions affecting consumer exposure during the use of the product Not applicable.

· Risk management measures

· Worker protection

Page 18: SAFETY DATA SHEET Araldite GY 6010 GY 250 · Araldite_GY 6010_GY 250 2.1. Classification of the substance or mixture Classification (EC 1272/2008) Physical hazards Not Classified

18/18

· Organisational protective measures

Ensure that activities are executed by specialists or authorised personnel only.

Handling procedures must be well documented.

· Technical protective measures

The work process has to be performed under closed conditions.

Ensure that suitable extractors are available on processing machines

Use product only in enclosed systems.

· Personal protective measures

Do not inhale gases / fumes / aerosols.

Avoid contact with the skin. Avoid

contact with the eyes. Tightly

sealed goggles Protective gloves

The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.

Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/

the chemical mixture.

Selection of the glove material on consideration of the penetration times, rates of diffusion and the

degradation

· Measures for consumer protection

Keep locked up and out of the reach of children.

Ensure adequate labelling.

· Environmental protection measures

Avoid release to the environment. Obtain special instructions / refer to Safety Data Sheet.

· Water Do not allow to reach sewage system.

· Soil Prevent contamination of soil.

· Notes In case of unintended release of the product: See section 6 of the Safety Data Sheet.

· Disposal measures

Disposal must be made according to official regulations.

Ensure that waste is collected and contained

. Disposal procedures

Must not be disposed together with household garbage. Do not allow product to reach sewage system.

· Waste type Partially emptied and uncleaned packaging

· Exposure estimation

· Worker (oral) The calculated value is smaller than the DNEL.

· Worker (dermal) The calculated value is smaller than the DNEL.

· Worker (inhalation) The calculated value is smaller than the DNEL.

· Consumer Not relevant for this Exposure Scenario.

· Guidance for downstream users No further relevant information available.