E«PH

MATERIAL SAFETY DATA SHEETHOUSTON.

TX. 77252-2180

U . S - A -p.C. BOX 2180

EXXON C O M P A N V . ,

A, IDENTIFICATION AND EMERGENCY INFORMATIONPRODUCT CODE

3U502 - 01502

:»«rfiSnri;.TTS «.<*• " - p e t r o l e u m oOor

,'MERGE-CV TELEPHONE NUMBER" c 5 e - 3 4 2 4

B.COMPONENTS AND HAZARD INFORMATION

COMPONENTS

O U T ' n a t e s (pe t ro l eum) .

CONCENTRATION

r.at.a 647*2-3-6 APpro^m.t.W 70*

Ol5tl l1»t« petroleum), hydrot"eat. . .heavy r tnenlc

Tn1s Dl ,ct. ^ manufac turec cyC,iDn«nyls ( P C B ' s ) .

An cc.ponen<S ,f tM. Product .r, Hs te . cn t h . V l . S .

See S.ct ion E for Heal tn and Hazard Information

.See swrl ion H for .do'r'n^i Envir

HAZARDOUS MATERIALS Tol N . I « 1 C A . : i OS

f r

-,.52-5 Aporc

not contain polycnlor1nated

i

-->,j^£ LIMIT F0« T Q T A ^-o. T.3 for O i l •'•* i t i <i

BASISCSHA Heguie CFR 1910.1COC andr ecomrr<ence2 ^^ , ne American Conferenceof Governmental I n d u s t r i a l M y e l e g i s t s(ACQlH). ACG"'" states that the air 1sto ^e sa-nolec: Cy a methca t h a t dees noicollect vaoor ; ir, a d a p t i o n , n l i s t s a10 mg/m3 S~EL .

C. PRIMARY ROUTES OF ENTRYAND EMERGEIN ' AND FIRST AID PROCEDURES

Coiasneo '.r.i,-"!aMcn sur

the eyes fius th clear water for 15 minutes o-If i r r l t a ; ,n persists, can a physician.

INHALATION --.ror inflation under amoient conditions 1svapor pressure is very low. J^on i n , _ a zi or DrOduct , immefl'atelyn~rmally not a problem. if cvercorre DV -ap^_ ^. « c irreauiar or na

MOT induce vc-.m no; ca'i a pnys'dan irnmeqi atel y.

D FIRE AND EXPLOSION HAZARD INFORMATION

FLASH POINT, (MINIMUM) *£™™^™™™'l 5 7 C ( J ^ v P JA5TM D 92, Cleveianc Open CuC

NATIONAL FIRE PROTECTION ASSOCIATION (NFPA) - HAZARD IDENTIFICATIONHealth r-1 arwab 1 1 1 1 y Reactivity BAS

i i o Rec

HANDLING PRECAUTIONSuse protect w i t h caution around heat, spanKs,electricity, and open flame.

Dy Exxon

MIgnts, Static

FLAMMABLE OR EXPLOSIVE LIMITS (APPROXIMATE PERCENT 8Y VOLUME IN AIR)a values: Lower F ' a-rma,D le f.-n^t 0.9% upper FlarrrnaDie Ll.-nt 7%

EXTINGUISHING WCDIA AND FIRE LIGHTING PROCEDURESFoam, water spray (fog), d"y cnemlca; . carbon dioxide and vaccrizirg iiau'iGtyoe e*t incu i snl ng agents na, all be s-ltacle for ex t lngu'1 sMng fires<rvclving t r, < s tyca of proauct , deoena'ng on size or potential size cf fire:,--r, c < rc'jns t ances related re; the s i t u a t i o n . Plan fire protection ana response•'.•• i. • L%V: tnrougn consul t at 'en w i t h local fire orctection authorities or• -.-3? - • -, .a : e spec 1 a 1 1 S t s .

"'lcv.1ng procedures fc" t n l s type of are based en tnereccrrvTianaa t ions i n the National F i r e =-otection Association's "Fire ProtectionGuide on Haza.racu£ M a t e r i a l s , le-nth Eciticn (1991):

use water spray, dry cneiv.iea', foam o- caroon d'cxide to extinguish tne fire.use water to Keep f1re-e*r'isa containers cool. If i leaK or s c i l l has notignited, use water spray t •_. cisuerse t e vapors and t cro^lae protection forpersons attempting to stop a ifraK *ater spray may be used to flush, s p i l l saway from exposures win —-zt- breatr'^g c* gases, vaaor fumes or

con?S USceror^^ctr.t-!^^rlllll^ &reath1ns pment ^or enclosed or

DECOMPOSITION PRODUCTS UNDER ^IRE CONDITIONSFumes, smoke, careen monc^-de. sulfur oMces. a-dehyaes and otherdecomposition products, m the case o' incorrclete comc'st'on

"EMPTY" CONTAINER WARNING:Emoty" conta iner , ^ e T a . n -es^due ( ' • 5j ;,a__ ar.0/C5r vaoor ; anfl Cfln te aar,oeroys .i-uik; t y i - u . i . a ine r - ^ r e " a . n ""SldUB ( i "_/ •'OO^NOT P R E S S U R I Z E , CUT, v^E.5, 3RAZE. SC^

resi

in accordance w i t h Oovernrrent a 1Occ.uDat^nn.al S a f e t y and Mea' th AamTi FO" wcnk en

' " a t ions, ANSI 245 .

to

anc

E HEALTH AND HAZARD INFORMATION

»»IABILITY AMONG INDIVIDUALS;,.,-,.. r.^.Aes nave shown tr.at many pet-oleum hydrocarbons and synthetic

.7 ~~re cctential j-.an healt^ MSK.S which may vary from person toon. exccsure to liquids, vanors, mists or fumes snou'd

EFFECTS OF OvEREXPOSURE (Signs and symptoms of exposure)Prolonged or repeated sKln contact may cause sKln i r r i t a t i o n .

NATURfc OF HAZARD AND TOXICITY INFORMATIONRepeated ana oroloneea ove-e*oosure to on m is t s may resu l t in d rcp .e*deposition, on uranuloma formation, inflammation ano increased Incidence ofin fect 'on.

In accordance *itn the cur-e^t OSHA Hazard Communication Standard criteria.this prociuCt does not reau"9 a cancer hazard warning, Tms 1s Because ". : ,&product is formulated frorr. case stocks yihich are severely hyarotreatea .severely solvent extractea. ana/or orocessea oy mild nydrotreaiment andeAfaction Alternatively, 't may cc~s',st of comoonants not otherwiseaf fee-tea Dy IARC criteria, sjch as ati^cspherlc di s t i l l a t e s or syntheticallyderived materials, ana as sucn 1s not characterized oy current IARCclassification c r i t e r i a ,

Prolonoed or repeated skin contact w'tn this product tenas to r-emove SKlnoils. ocsslDly lead^na to 'r-ltatlon and dermatitis; however, based on humanexcellence &nd avallaole t c* icol og ica1 data, this oroauct 1s Judsed to ceneither a "corrosive" nor a* " I r r i t a n t " Dy OS^A criteria.

Product cpntacMr-3 the eyes may cause eye irritation.

--r-'-^rt has a lew order of acute era' and dermal to*lcity, but minute amounts:-:~:K.~. -nto the lungs a^Mna Ingestlon or vomiting may cause mile to severe

• -UTV ana ooss' '.y death.

we

;_dcea to -ave an acute oral LD50 (rat) oreater than 5 Q/KQ ofan acute cermal LD50 (raoblt) greater than 3.16 O/KQ of cody

PRE-EXISTING M^uICAL CONDITIONS WHICH MAY BE AGGRAVATED BY EXPOSUREreccon 1 zea

F PHYSICAL DATA

ASTM D 2887 2.rc (WP' VAPOR PRESSURELess than c-01 H9

SPfcClFIC GRAVITY (15 6'r/ic0.89 W15.

WEIGHTDetermined

VAPOR DENSITY (AIR - 1)Greater man 5

PERCENT VOLATILE BY VOLUMENesiigif. e from ocen contai.-erm 4 hours 9 38' C ( 100'F )

EVAPORATION RATE » 1 ATM AND(77'F) (n-BUTYL ACETATE I 1)Less than 0.01

TC

Pour Point Gy ASTM D 97 Neg i 1g 1 1 ' e ; ess tr ar C.",%

"••C=

AV010 proonoeorPERSONAL HYGIhNr. vacor, mist Or^mmis^^-^

t ransccr t a" 'ionEmerge'icy Respwr

Not

OSHA REQUIRED LABEL INFORMATION „-,-!,ran'ain compliance w 1 1 r, hazara and rignt-tc-know requirements, where a^Ka^eOSMA Hazarfl warnings may be found on the l a b e l , b i l l of lading C^ .nvuiceaccorr'Oany Ing this

U . S . DOT HAZARDOUS MATERIALS SHIPPING DESCRIPTION

Not Proaur may contain non-CSHA relates information a 1

J

>r->Tormat ion and recormehdat 1 ons contained herein are, to the best ofi s Knowledge and belief, accurate and reliable as of the date issued

„ ,, fioes not warrant or guarantee their accuracy or r e l i a b i l i t y , and Exxonsnan not be l i a b l e for any loss o- damaoe arising out of the use thereof

forThe Information and reconrnendat Ions are offeredand examination, ana it 1s the user's 'esponsiDI 1 1 t y tothey ar-e :,u:taDle and cor^lete for its oartlcularthis product, legal counsel should be consultedand other necessary information 1s

user's considerationsatisfy Itself that

use- If buyer repackagesto insure proper health, safety

or, the container.

The Environmental information Included unaer SectionHazardous Materials Identification System (HMIS)Association (NFPA) ratinas have been includedto provide additional health and hazard "reconrnendea are based upon the criteriarating systems, together with Exxon's

H hereof as well as theand National Fire Protection

by Exxon Comoany, U.S.A. m or0erclassification Information. The rat'ngssupplied by the developers of these

interpretation of the available data

FOR LUBRICANTS TECHNICAL ASSISTANCE CALL:

FOR FUELS TECHNICAL ASSISTANCE CALL

1-8OO-443-9966

713-656-4955

ASSISTANCE *ITH AN °™ECT INQUIRIES TO THE ADDRESS

H. ENVIRONMENTAL INFORMATION

ACT ^^ s§ , ,P. c

^-. >»r p-eOO-424-8602) .

r TAKEN IS CASE MATERIAL IS RELEASED OR JELLED aDSQr&ent t o ,p1l1

. - - ae proauct. Add sand, ear!*, o ro^* rju 'e*grs anfl w a terccurses Dy

. : , •'.i'-,^ns'!;s.scs55ni iss^f. !0 ; ' " .ss/.; s s,' - wate-coorses. o r extensive ^and areas.

v - -a conformity w l t n applicable gcvernmentai

8 ""r egu la t i ons .

'ND

TMRESHOUO PLANNING QUANTITY (TPO). EPA REGULATION 4O CFR 355

ny constituent 3 r e a t e - tnan i« or 0.1% (carcinogen,

TOXIC CHEMICAL RELEASE REPORTING, EPA REGULATION 40 CFR 372 (SARA Section 313)NO toxic cnem-icai is present areate- than 1% or o.iv. ( car c inoaen ) ,

HAZARDOUS CHtVlCAl. REPORTING, EPA REGULATION 4Q CFR 370 (SARA Sections 311-312)

NotlicA A A

EPA HAZARD Acute Cnronic Fire Pressure ReactiveCLASSIFICATION CODE: Hazard Hazard Hazard Hazard Hazard

PROTECTION AND PRECAUTIONS

VENTILATION\o & t L J r e . -aonr. T> • s t s o" Curries. i c n e c e s s a r y . P rov ide

to c . re \ -enc e^csea'ng 'ecomrercJed e x p o s u r e l imi t orc o n c e n t r a t i o n s of vapc^ in a i r . NO sTioKi^.g, c^ use o

-.--.« cr cThe r i g n i t i o n sources.

- _ _ : _ ...,.^,., PROTECTION(_.~.e suoo! ',f.n- a 1 r r e s c ^ r a t c r y p ro tec t i on in co " f i neC or enc 'osec s c a c e s , 1f

PROTECTIVE GLOVES

J£* t<*m 1 c a - " r e s 1 a f* n tC w n i p-oionsed or r e peat e c

EYE PROTECTIONUse srjiasn goasles cr face shield w-e- eye co-:act pay occu

OTHER PROTECTIVE EQUIPMENTuse Chemical-resistant aorcn Cr c"-e' mce-^--^ rl ___ mo •

" '