REGION m ' 201 DEFENSE HIGHWAY SUITE 200 DATE : April 11, … · TO: Cynthia E. Caporale ESAT...

lr"~\UNITED STATES ENVIRONMENTAL PROTECTION AGENCY"' J< I

REGION m ' "CENTRAL REGIONAL LABORAT &fr:

201 DEFENSE HIGHWAYSUITE 200

ANNAPOLIS, MARYLAND 21401

ASSUHAWCE

DATE : April 11, 1995

SUBJECT: Region III Data QA Review

FROM : Cynthia E. Caporale1-Region III ESAT RPO (3ES30)

TO : Chris CorbettRegional Project Manager (3HW24)

Attached is the organic data validation report for the KeystoneSanitation Site (Case 23274) completed by the Region IIIEnvironmental Services Assistance Team (ESAT) contractor under thedirection of Region III BSD.

If you have any questions regarding this review, please call me at(410) 573-6832.

Attachment

cc:; Russ Sloboda/Patricia Armstrong, Halliburton NUS, Wayne, PA

TID File: 03950350

a Q o I I Q i -j Printed on Recycled Papt« n J I 4 5.. I /

Environmental Services Assistance Teams Phone:(410)268-7705Regions Fax:(410)268-84721419 Forest Drive, Suite 104 • .Annapolis, Maryland 21403

DATE: April 04, 1995SUBJECT: Organic Data Validation for Case 23274

Site: Keystone Sanitation-••--- - • c^ *FROM: Douglas S. Buf f ington VoP Mahboobeh,Mecanic

* Organic Data Reviewer Senior Oversight Chemist

TO: Cynthia E. CaporaleESAT Regional Project Officer

THROUGH: /Dale S. Boshart Jj ESAT Team Manager

OVERVIEW

Case 23274 consisted of five (5) soil samples submitted toCompuchem Corp. (COMPU) for semivolatile and pesticide/PCBanalyses. One (1) field blank (CCX32) was included in the case,but was not analyzed, due to insufficient quantity for extraction.One (1) field duplicate pair was also analyzed. The samples wereanalyzed as a Contract Laboratory Program (CLP) Routine AnalyticalService (RAS).

SUMMARY"All samples were successfully analyzed for all target compounds,except 3,3'-dichlorobenzidine in samples CCX30 and CCX31. Allother instrument and method sensitivities were according to theContract Laboratory Program (CLP) Routine Analytical Service (RAS)protocol.

MAJOR PROBLEM

o The relative response factor for 3,3'-dichlorobenzidine was lessthan 0.05 (RRF <0.05) in the semivolatile continuing calibra-tion, dated 03/06/95. Quantitation limits were qualified "R" insamples CCX30 and CCX31.

MINOR PROBLEMS

o Several compounds failed precision criteria in the semivolatileinitial and/or continuing calibrations. No positive resultswere affected, and quantitation limits were qualified "UJ" onlyfor compounds that exceeded fifty percent relative standarddeviation or percent difference (%RSD or %D >50%).

AR3U9I8

of 3

o The "P" qualifier used on the pesticide/PCB Form Is denotes apercent difference greater than 25 percent (%D >25%) between thereported results on the two (2) columns used for the analyses.These results were qualified "J" on the data summary forms.

NOTES

o One (1) field duplicate pair was analyzed. The results andprecision estimates are listed in the following table:

Concentration (u.a/Ka)Compound CCX28 CCX29 RPD

di-n-butylphthalate 220 J 380 J 53bis(2-ethylhexyl)phthalate 110 J ND IN

aldrin 0.48 J 0.45 J 64,4'-DDE 1.0 J ND IN4,4'-ODD 0.79 J 0.71 J 11endosulfan sulfate 0.30 J 1.0 J 1104,4'-DDT 0.41 J ND INendrin aldehyde ND 0.69 J IN

RPD = Relative Percent DifferenceND = Not DetectedIN = Indeterminate

o Non-spiked compounds were detected in sample CCX28 and theMS/MSD analyses of this sample. The results and precisionestimates are as follows:

Concentration fug/Kg)Compound CCX28 CCX28MS CCX28MSD %RSD

di-n-butylphthalate 220 J 300 J 160 J 31bis(2-ethylhexyl)

phthalate 110 J ND ND IN

4,4'-DDE + 1.0 J 0.80 J 0.88 J 114,4'-DDD + 0.79 J 0.96 J 1.3 J 26endosulfan sulfate 0.30 J ND 0.54 J 57*methoxychlor ND ND 12 J INendrin ketone + ND 1.1J 1.2 J IN

%RSD ** Percent Relative Standard DeviationND = Not DetectedIN = Indeterminate* = Relative Percent Difference (RPD) instead of %RSD+ = 4,4'-DDE, 4,4'-ODD, and endrin ketone are considered

degradation compounds.

AR3U9I9

of 3

o The semivolatile extractions of samples CCX30 and CCX31 wereperformed nine (9) days after the date of sample collection.Although no technical holding time for the extraction of semi-yblatiles in soil samples has been established, the technicalholding time of seven (7) days for aqueous samples has beenexceeded by two (2) days. Because semivolatile compounds arepersistent in soil samples, no data were qualified for thisminor infraction of holding time.

o Sample weights other than thirty (30) grams were used in thesemivolatile and pesticide/PCB analyses of several samples. Thedilution factors on the data summary forms have been adjusted toreflect this variance when significant.

o GPC cleanup was performed in the semivolatile and pesticide/PCBanalyses of the soil samples. The dilution factor of two (2)required by this procedure was accounted for in the analyticalprocedures used by the laboratory and is not reflected on theForm Is. .

o The pesticide/PCB Form Is incorrectly denoted a 10000 juL finalvolume. The actual final volume after GPC cleanup was 5000 / L.The reviewer has made the corrections on the Form Is during datavalidation.

o The GPC blank contained methoxychlor at 0.25 J jug/Kg. No datawere qualified.

o The tentatively identified compounds (TICs) in Appendix D werereviewed and corrected during data validation. Compoundsidentified as blank contaminants, aldol condensation products,and laboratory artifacts were crossed off the TIC Form Is.

All data for Case 23274 were reviewed according to the NationalFunctional Guidelines for Evaluating Organic Analyses withmodification for use within Region III. The text of the reportaddresses only those problems affecting usability.

ATTACHMENTS

1) Appendix A - Glossary of Data Qualifiers2) Appendix B - Data Summary. These include:

(a) All positive results for target compounds~with qualifier codes where applicable.

(b) All unusable detection limits (qualified "R").3) Appendix C - Results as Reported by the Laboratory for All

Target Compounds4) Appendix D - Reviewed and Corrected Tentatively Identified

Compounds5) Appendix E - Support Documentation

DCN:DB503A02.KEY

AR3U920

Appendix A

Glossary of Data Qualifiers

A R 3 I U 9 2 I

GLOSSARY OF DATA QUALIFIER CODES (ORGANIC)

CODES RELATED TO IDENTIFICATION(confidence concerning presence or absence of compounds)

U = Not detected. The associated number indicatesapproximate sample concentration necessary to bedetected.

NO CODE = Confirmed identification.

B » Not detected substantially above the level reportedin laboratory or field blanks.

R = Unusable result. Analyte may or may not bepresent in the sample. Supporting data necessary

L_to confirm result.

N = Tentative identification. Consider present.Special methods may be needed to confirm itspresence or absence in future sampling efforts.

CODES RELATED TO OUANTITATION(can be used for both positive results and samplequantitation .limits) :

J = Analyte present. Reported value may not beaccurate or precise.

K = Analyte present. Reported value may be biasedhigh. Actual value is expected to be lower.

L = Analyte present. Reported value may be biased low.Actual value is expected to be higher.

UJ = Not detected, quantitation limit may be inaccurateor imprecise.

= Not detected, quantitation limit is probablyhigher.

OTHER CODES

NJ = Qualitative identification questionable due to poorresolution. Presumptively present at approximatequantity.

Q ss No analytical result.

• AR3IU922

Appendix B

Data Summary Forms

AR3|I*923

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go

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—

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8

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3

sa

8

|

Sanple No.

|

Dilution Factor

1 X Moisture

Location

sN

I

I1

II

N

8

S

1

is|

\N811HS1

<* 1

— 1 O CO 1

CO UL U !

< S ICO S.

a! s asagu> u. u •

31sII1

I I bis(2-Chloroethyl)ether

2-Chlorophenol

iuo1

" 1 .4-Oichlorobenzene

1.2-Dichlorobenzene

15I

M 2.2'-oxybis(1-chloropropane)

4-Hethylphenol

__ N-Nitroso-di-n-propylamine _

Hexachloroethane

Iu

"1" 2.

4-Dimethylphenol

bis(2-Chloroethoxy)methane

2.4-Dichlorophenol

N

L.O

11

IN* Naphthalene

4-Chloroaniline

g al 'al ^ 8! 8!8!8!8!8

|

CRQL = Contract

Required Quantitation

Limi

t SEE

NARRATIVE

FOR CODE

DEFINITIONS

revised 07/90

AR3U92U

S 8

I

§s -

s

ae coium —i

01%V

I Ii I

—

ioso

asCJ

co!M2u

u

—

0

0

o

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a

(M

S

-

1o*

—

1

1

,1

s8

1°8

iR

H

N

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11

11

1

11

j1111

I1

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«C 1

2 % Ia iin j-J Q CO 1a. _i r\j iCO u. U 1i

N

CO Q! H- i :a o o. 8t_i AJ «E u 8

i

Sample No.

Dilution Factor

X Moisture

Location

'CRQL

COMPOUND

i

Hexachlorobutadiene

4-Chloro-3-methylphenol |

2-Methvlnaphthalene

1__ Hexachlorocyclopentadiene _

2.4.6-Trichlorophenol

__ 2.4,5-Trichlorophenol ___

2-Chloronaphthalene

|

XiCM

CTi

i

Dimethyl

S

1

trotoluene

i(V

g

c.

Xm

i

j

1

4-i

ci

c\

114-

ae

I3

'S

trotoluene

c0-i«CM Di

ethvlphthalate

u

iI

IcXu

Fluorene

3'

3'

3

4-Nitro«niline

4,6-Dinitro-2-methylphenol

! o1 o' o1 o1 o1 o1 o1 o1 o1 o1 o1 o1 o1 o' o1 o1 o1 o1 o1 o' o1 o1| R, R, R( R, R, 8, R, §, R, R, R, 8, R, i, 8( R, R, R, R, R, S, i,

SEE

NARRATIVE

FOR

CODE DEFINITIONS

revised 07/90

4-*

'i

g4-*<o4-1

iI4-4

1uH

K

CO N.>• (M

I <

5 |~AR3ii4925

DATA SUMMARY FflBM- R

II A

t n,-«

•*_

-t

L

Site Name:

KEYSTONE

SANITATION

;

SOIL

SAMPLES

' ,

(ug/Kg)

Case *:

23274

Sampling Date(s): 02/22/95

To calculate sample quantitation

limits:

(CRQL *

Dilution factor / ((100 - Xn»isture)/100)

—

i0JOX

1u

s.2S

£41

1CO

—

o

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8:o

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—

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1 40

88

l

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Location |

SD-02,

n5NNM

8HN

88S8

i

8H

1H

18HHH

u. 8

a o « 8a. — i t\j N5 S 2

u.

ill

1 iCOMPOUND

|EZXXMKKXgXXZXXXSXZXSKZXKKZZBSXXUB 1 ••KBXVXXVXI

N-Nitrosodiphenylaroine

14-Bromophenyl-phenylether |

Hexachlorobenzene

Pentachlorophenol

Phenanthrene

Anthracene

Carbazole

_,

^

otM

^

g

Di-n-butylphthalate

Fluoranthene

1-

<>4Ja

4-*I-.

X4rfS

ce

at

3

3'

3

|TJj

x:uoiK>K? Be

nzo(a)anthracene

•Chrysene

.,

0

*~

bis(2-Ethylhexyl)phthalate

JC

|

lC1Q

b)fluoranthene

im

k)f l

uoranthene

.

_j o1 o1 o1 o1 o1 o1 o1 o1 o1 o1 o1 o1 o1 o1 o1 o1 o1 o1

,o

CD

»{1,2,3-ed)pyrene ___

(a.h)anthracene ___

!i0

|c.

x:aO

ca

o1 o1 o1 oR, R, R, R

1RTF ii9

UJ M

Ul II

NARRATIVE

F

UJ

rOCRQL

«= Contract

Required Quantitation

Lim

itcn

J 11§

a-I « 2

- -

COmu

UJ COUJa -"

cauia.

§

——

8

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^

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0 a S t\ (\1 1 1 1 1 1 1C. t. U L. L. U CO O O O O O O

" 8 8 8 8 8 8 8

,**'•j H K B s

SEE

NARRATIVE

FOR CODE

DEFINITIONS

'i

g4-*

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gu1 N

41 tt- 2

AR3U927

Appendix C

Results as Reported by the Laboratoryfor all Target Compounds

AR3U928

"J _ . ' : . . ' - 'IB - EPA SAMPLE NO.S-@IIVOLATILE ORGANICS ANALYSIS DATA SHEET

CCX27Lab Name: COMPUCHEM ENV. CORP. Contract: 68D50004

Lab Code: COMPU Case No.: 23274 SAS No.: SDG No.: CCX27

Matrix: (soil/water) SOIL Lab Sample ID: 686674

Sample wt/vol: 30.3 (g/mL) g Lab File ID: GH086674A21

Level: (low/med) LOW Date-Received: 02/23/95

% Moisture: 40 decanted: (Y/N) N Date Extracted:02/28/95

Concentrated Extract Volume: 500(uL) Date Analyzed: 03/01/95

: Inj ection Volume: 2.0(uL) Dilution Factor: 1.0

GPC Cleanup: (Y/N) Y ' pH: 6.0 .

. CONCENTRATION UNITS:CAS NO, COMPOUND (ug/L or ug/Kg) ug/Kg Q

108-95-2--111-44-4--Q CT C **t Q

541-73-1--106-46-7--95-50-1 ——95-48-7 ——108-60-1--

621-64-7--^ * *"7 O *167-72-1---QO QC -3

*7Q C Q "1

O O *"7C CT88-75-5---105-67-9--111-91-1--1 O A Q O O12Q-83-2--i *^ r\ o o i120-82-1--QT _on-^---106-47-8--O*7 CQ.—~1 __

59-50-7 —— •91-57-6 ——77-47-4 —— •88-06-2 —— •95-95-4 ——QT CQ *7 _

Q Q _ 1A. _/!__-.

131-11-3---OAQ Q£ Q

606-20-2---QQ_OQ-5----J \J y £*

83-32-9 —— •

------Phenol- - - - - -bis ( 2 -Chloroethyl ) ether _____------2- Chlorophenol_ _ _ _ _ _ l f 3 -Dichlorobenzene_ _ _ _ — 1,4 -Dichlorobenzene------1,2 -Dichlorobenzene------ 2 -Methylphenol------2,2' roxybis ( 1 - Chloropropane )- - - - - -4 -Methylphenol_ _ _ _ _ -N-Nitroso-di-n-propylamine_ _ _ _ _ -Hexachloroethane- — - - -Nitrobenzene------ I sophorone_ _ _ _ _ _ 2 -Nit rophenol-____-2,4 - Dimethylphenol_ _ _ _ - -bis ( 2 - Chloroethoxy ) methane______2,4 -Dichlorophenol___ —— i , 2 , 4 -Trichlorobenzene— . — Naphthalene— - - -4 -Chloroaniline- - - — -Hexachlorobutadiene_ ——— 4-Chloro-3-methylphenol ____. —— -2 -Methylnapht halene———— Hexachlorocyclopentadiene— — -2,4,6 -Trichlorophenol-__-__2,4,5 -Trichlorophenol-- —— -2- Chloronaphthalene------ 2 -Nitroaniline- - —— Dimethylphthalate_ _ _ _ _ -Acenaphthylene-- — --2,6 -Dinitrotoluene- ——— 3 -Nitroaniline

540540540540540540540540540540540540

, 540540

' 540540540540540

- 540540540.5405405401400540

1400540540540

1400540

UUuuuuuuuuuuuuu •uuuiiuuuuuuuuuuuuuu

FORM I SV-1 OLM03.0

23274 CCX27 QMPLE DPTP PF)CKBGE&R3 ((4 9 29 40

1C EPA SAMPLE NO.SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET


Lab Code: J3DMPU Case No.: 23274 SAS No.: SDG No.: CCX27


Sample wt/vol: 30.3 (g/mL) g . Lab File.ID: GH086674A21

Level: (low/med) LOW Date Received: 02/23/95


Concentrated Extract Volume: 500(UL) Date Analyzed: 03/01/95

Injection Volume: 2.0(uL) Dilution Factor: 1.0

GPC Cleanup: (Y/N) Y pH: 6.0

- CONCENTRATION UNITS:CAS NO. COMPOUND (ug/L or ug/Kg) ug/Kg Q

C T O Q C51-28-5-----100-02-7 ———132-64-9 ———101 _14_*J____^ J* JU*± £t

84-66-2- ———7005-72-3 ——QC_*7"3 1 _

100-01-6 ———534-52-1-----86-30-6 ————101-55-3 ———-I 1 Q "1 A 1

87-86-5- ———85-01-8 ————120-12-7 ———86-74-8 ————fl4._74_O_____206-44-0----129-00-0-----85-68-7 ————91-94-1 ————56-55-3 ———— •01 a_m Q1 1 T 0 1 *7117-81-7----117-84-0 ——— •o n =»- Q <9 -?_-_-.207-08-9 ——— •C rt "3 O O50-32-8------193-39-5 ——— •c^ in i1 Ol O/1 O

----2,4 -Dinitrophenol- — - 4 -Ni trophenol- - - -Dibenzof uran----2,4 -Dinitrotoluene- - - -Diethylphthalate- - - - 4 - Chlorophenyl -phehylether _----Fluorene— -4 -Nitroaniline----4, 6-Dinitro-2-methylphenol _- - - -N-nitrosodiphenylamine_ ( 1 ) _- - - -4 -Bromophenyl -phenylether __

- - - - Pentachlorophenol- - - - Phenanthrene

—— Carbazole- — -Di -n-butylphthalate- - — Fluoranthene-- — Pyrene- - - -Butylbenzylphthalate- - — 3,3' -Dichlorobenzidine- - - -Benzo (a) anthracene

- —— bis ( 2 -Ethylhexyl ) phthalate _• — Di-n-octylphthalate— -Benzo (b) f luoranthene- —— Benzo (k) f luoranthene- - — Benzo ( a ) pyrene—— Indeno (1,2,3 -cd) pyrene- - — Dibenzo ( a , h) anthracene- — Benzo (g,h, i) perylene

14001400540540540540'54014001400540540540

1400540540540230540540

' 540540540540540540540540540540

V540540

UUuuuuuuuuuuuuuuJuuuuuuuuuuuuuu

(1) - Cannot be separated from Diphenylamine

FORM I SV-2 OIM03

23274 CCX27 SRMPLE OBTR PPCKBGE • ** ' 41

- " - - - -•-"--_- - IB EPA SAMPLE NO.SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET


Lab Code: J20MPU Case No.:• 23274 SAS No.: SDG No.: CCX27



Level: "(low/med) LOW Date Received: 02/23/95

% Moistures.6.0""""" decanted: (Y/N) N Date Extracted:02/28/95

Concentrated "Extract Volume: 500(uL) Date Analyzed: 03/01/95

Inj ection Volume: 2.0(uL) Dilution Factor: 1.0


CONCENTRATION UNITS:CA_TW. COMPOUND (ug/L or ug/Kg) ug/Kg Q

T n Q QC o111-44-4 ———95-57-8.-----541-73-1 — --106-46-7 ———95-50-1-----95-48-7 ————108-60-1 ———106-44-5 ———621-64-7----67-72-1-----QQ QC "2

78-59-1 ———Q Q *7C C

105-67-9----111-91-1----120-83-2 ———120-82-1 ———91-20-3 ————106-47-8 ———Q'7_C:Q_'3__-- —

59-50-7 ————rt*t c **t f91-57-6------77-47-4 ————QQ C\d "5 _ _ _ _ .QC QC A ___.

Q1 CQ *7 _

88-74-4 ———— •131-11-3 ——— -OnQ_Q£_Q-----

606-20-2 ——— •qq_nQ-9------yy\jy &83-32-9 ——— -

----Phenol----bis (2-Chloroethyl) ether- - - - 2 - Chlorophenol----1,3 -Dichlorobenzene

- - - - 1 , 2 -Dichlorobenzene- - - -2 -Methylphenol----2,2' -oxybis (1-Chloropropane)- - - -4 -Methylphenol- - - -N-Nitroso-di-n-propylamine _

TTj j*** *•.!•* 1 c iVV"\ i— \"\ — mA

- - - -Nitrobenzene- - - - 1 sophorone- - - - 2 -Ni trophenol----2,4 -Dime thy Iphenol----bis(2- Chloroethoxy ) methane----2,4 -Dichlorophenol----1,2,4 -Trichlorobenzene- - — Naphthalene- - - -4 -Chloroaniline—— Hexachlorobutadiene. _ _ _4 -chloro-3 -methylphenol ____- - - - 2 -Methylnaphthalene- - — Hexachlorocyclopentadiene— -2,4,6 -Trichlorophenol- — 2 , 4 •, 5 -Trichlorophenol—— 2 - Chloronaphthalene- —— 2 -Nitroaniline- - - -Dimethylphthalate. _ _ -Acenaphthylene- — 2,6 -Dinitrotoluene• — 3 -Nitroan.il ine- — Acenaphthene

820820820820820820820820820820820820820820820820820820820820820820820820820210082021008208208202100820

UUuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuu

FORM I SV-1 OLM03.0

9523274 CCX27 SfiMPLE DBTP PRCKfUy-R^ Mf9-3 -I



Lab Code: £OMPU Case No.: 23274 SAS No.: SDG No.: CCX27







GPC Cleanup: (Y/N) Y pH: 6.1i

CONCENTRATION UNITS:CAS NO. COMPOUND (ug/L or ug/Kg) ug/Kg Q

51-28-5 -----100-02-7----132-64-9 ———1 ? 1 - 1 4. - ? - - - -84-66-2 ————*7A A C TO "3

Q a *n n100-01-6----e,34_c,o_i ----•~J >~J -J i* -_>

86-30-6-----101-55-3- ——118-74-1- ——87-86-5-----85-01-8 -----120-12-7----86-74-8 —— --84-74-2- ———206-44-0- ——129-00-0 ———85-68-7 ————91-94-1 ————56-55-3 ————Ol P_A1 _ Q _ _ _ _11*— Q 1 TT117-81-7----117-84-0 —— -one QQ ion'? no _Q50-32-8 ————193-39-5 ———53-70-3 ————191-24-2 ———

- — -2,4 -Dinitrophenol- - - -4 -Nitrophenol- - - -Dibenzof uran- - — 2,4 -Dinitrotoluene- — -Diethylphthalate. _ _ _4 -chlorophenyl -phenylether _

- - - -4 -Nitroaniline----4,6 -Dinitro-2 -methylphenol _- - - -N-nitrosodiphenylamine_ ( 1 ) _- - - -4 -Bromophenyl -phenylether

- - — Anthracene- — -Carbazole- - - -oi -n-butylpKthaiat e— - Fluoranthene— -Pyrene— "- -Butylbenzylphthalate- —— 3,3' -Dichlorobenzidine—— Benzo (a) anthracene----Chrysene—— bis ( 2 -Ethylhexyl ) phthalate _—— Di -n-octylphthalate—— Benzo (b) f luoranthene— -Benzo (k) f luoranthene_ _ _ -Benzo (a) pyrene- - - - Indeno ( 1 , 2 , 3 -cd) pyrene- - - -Dibenzo ( a , h) anthracene- - - -Benzo (g , h , i ) perylene

21002100820820820820820

21002100820820820

2100820820820220820820820820820820110820820820820820820820

UUuuuuuuuuuuuuuuJuuuuuuJuuuuuuu

(1)- Cannot be separated from Diphenylamine

FORM I SV-2 OLM0376

AR3 11*932COMPJ F noTQ parifQfiF

-------- IB EPA SAMPLE NOSEMIVOLATILE ORGANICS ANALYSIS DATA SHEET


Lab Code: COMPU Case No.: 23274 . SAS No.: SDG No.: CCX27


"Sample wt/vol: """ 30.2 (g/mL) g Lab File ID: GH086682A21




Injection'Volume: 2.0(uL) .Dilution Factor: 1.0


.' .' CONCENTRATION UNITS:CAS NO. . .. COMPOUND (ug/L or ug/Kg) ug/Kg Q

i np-Q^-9----111-44-4- ——QC C*7 Q

541-73-1- ——106-46-7 ———95-50-1 -----95-48-7 -----108-60-1 ———106-44-5----621-64-7- ——^ T T1 167-72-1-----QQ QC 1TQ C Q 1/O-Di7-JL- — — --QQ *~7C C

105-67-9 ———111-91-1 ———i on at o___ _i on_oo_i _ _ _ _91 _on_-3_____3 JL «6 w ^

106-47-8 ———Q*7 /-Q ^ _

CQ en T ___Q1 C"7 C.- _ _ _ _

77-47-4 ————QQ f\C O _ _ _ _ _

jQi/OTEQ1 CD *7

88-74-4 ————131-11-3 ———ona_QC_p____f f\ *"> rt ^606-20-2----QQ_nq_o_____Q"3_-3O_Q_____

----Phenol_ _ _ -bis ( 2 - Chloroethyl ) ether----2-Chlorophenol -———----1,3 -Dichlorobenzene----1,4 -Dichlorobenzene

1^5* T T /™*VlT x y*<* V>fa v «*» » ^ *

---- 2 -Methylphenol----2,2' -oxybis (1-Chloropropane)- - - -4 -Methylphenol- - - -N-Nitroso-di-n-propylamine _- - - -Hexachloroethane— -Nitrobenzene- - - - Isophorone- — 2 -Ni trophenol—— 2,4 -Dimethylphenol- — -bis ( 2 -Chloroethoxy ) methane _----2,4- Dichlorophenol----1,2,4 -Trichlorobenzehe_ _ - -Naphthalene__ — 4-chloroaniline

- — 4 -Chloro- 3 -methylphenol ___- — 2 -Methylnaphthalene

_ TT ^ — i — W 1 f*\v°f*tt ' \ rf* 1 T Ont"i3 T OT*1A

----2,4,6 -Trichlorophenol—— 2,4,5 -Trichlorophenol- - - -2 -Chloronaphthalene— — 2 -Nitroaniline—— Dimethylphthalate— -Acenaphthylene----2,6 -Dinitrotoluene—— 3 -Nitroaniline—— Acenaphthene

110011001100110011001100110011001100110011001100110011001100110011001100110011001100110011001100110028001100280011001100110028001100

uuuuuuuU 'uuuuuu 'uuuuuuuuuuuuuuuuuuu

FORM I SV-1 . .OIM03.0

23274 CCX27 SPMPLE OfiTP PfiCKRG 142












51-28-5 ———— -100-02-7----132-64-9----J.A'— -L i

84-66-2-----7005-72-3 ——OO / -5 /100-01-6- ——CTA-CO-I _ _ _ _^J*X •-) £* -L.

86-30-6- —— -101-55-3 ———118-74-1 ———87-86-5-----85-01-8-- ——-I «— . r\ 1O *7120-12-7----86-74-8-- ——84-74-2-----206-44-0 ———129-00-0 ———85-68-7 ———91-94-1 ————56-55-3 ————218-01-9 ———1 1 *"7 0 1 T117-81-7----117-84-0 ———one QQ o20i>-y:7-<5----207-08-9 ———en •ao Q _ _ _ _ _DU — O^iO — — — — —193-39-5 ———c;>5_7f)_-3__-_-— o — / \j .31 Q1 _O4_O____X./J. *X «»

----2,4 -Dinitrophenol- - - -4 -Nitrophenol- - - -Dibenzof uran—— 2,4 -Dini trotoluene- — Diethylphthalate- - - -4 -Chlorophenyl -phenylether- - - - Fluorene- - - -4 -Nitroaniline----4,6 -Dini tro - 2 -methylphenol _- — -N-nitrosodiphenylamine_ ( 1 ) _- - - -4 -Bromophenyl -phenylether— -Hexachlorobenzene- - - - Pentachlorophenol- - - - Phenanthrene

----Carbazole- - - -Di -n-butylp'hthalate- - - -Fluoranthene- — -Pyrene- - — Butylbenzylphthalate—— 3 , 3 ' -Dichlorobenzidine

T3 T Tf*-% f 3 \ 3in^ V^ T** f*AT^A

- - - -Chrysene- —— bis ( 2 -Ethylhexyl ) phthalate—— Di-n-octylphthalate----Benzo (b) f luoranthene—— Benzo (k) f luoranthene-- — Benzo (a) pyrene- - - - indeno (1,2,3 -cd) pyrene

- — Benzo (g,h, i) perylene

280028001100110011001100110028002800110011001100280011001100110038011001100110011001100110011001100110011001100110011001100

uuuuuuuuuuuuuuu •uJuuuuuuuuuuuuuu

(I)- Cannot be separated from Diphenylamine

FORM I SV-2 OLMO)3 J

23274 CCX27 SBMPLE DflTA PBCKRGE 143

•'-:----- _ _ IB ' EPA SAMPLE NO.SEMIVOLATILE ORGANICS'ANALYSIS DATA SHEET


Lab Code:".COMPU Case No.: 23274 SAS No.: SDG No.: CCX27

Matrix: (soil/water) SOIL Lab Sample ID:: 686683

Sample wt/vol: 30.0 (g/mL) g Lab File ID: GR086683A21

Level: (low/medj LOW Date Received: 02./23/95

% Moisture: 35, decanted: (Y/N) N Date'Extracted:03/03/95


"llnjectioh Volume: 2..0(uL) Dilution Factor: 1.0


'':' - - - - - ••• - CONCENTRATION UNITS:CAS.NQ._ COMPOUND (ug/L or ug/Kg) ug/Kg Q

i n Q QC o111-44-4----QC CT Q _

541-73-1 ———i r\c AC iQC en i _ _ __QC A O "7

108-60-1 ———106-44-5----621-64-7 ———CH I7O_1_____Q Q QC O•70 C Q T _ _/O--3_7~ __.-- — — -O Q TC C

105-67-9 ———. 111-91-1 ———

1 On_Q"5_O_ — — —ion Q O _ I _ _ — —QI _on_ T — — — — —106-47-8 ———O*7 £TQ_-5____ —

59-50-7 ————QT C*7 £ _

77-47-4 ———Q fl n_c o .._.-._.QC QC A

QI C Q *7

QQ-'TA -A-- --.—

131-11-3 ———OrtQ Q/; Q __

606-20-2 ———QQ_ng_o_____y j w AQ-s_-ao_Q_____

----Phenol—— bis (2-Chloroethyl) ether ___- - - - 2 - Chlorophenol----1,3 -Dichlorobenzene

14— T"}i **ViT ov l OTTyono----1,2 -Dichlorobenzene- - - - 2 -Methylphenol----2,2' -oxybis (1-Chlbropropane)--- -4 -Methylphenol- - - -N-Nitroso-di-n-propylamine- - - -Hexachloroethane

_ —"NT'1 t~T fM"iOTi*TO'no

- - - - Isophorone- — - 2 -Ni trophenol----2,4- Dime thy Iphenbl- — -bis ( 2 -Chloroethoxy ) methane----2,4 -Di chlorophenol- - — 1,2,4 -Trichlorobenzene

XTa— Vit^T^-a "I A— t A

_ - _ _ 4 _ chloroanil ifie- - — Hexachlorobutadiene—— -4 -Chloro-3 -methylphenol— -2 -Methylnaphthalene_. _ -. _.7ToYS3i/"tVtT f i'Y r f rr* M*M__TI * ari *t ATI a

- - — 2,4,6 -Trichlorophenol- —— 2,4,5 -Trichlorophenol- - - -2 -Chloronaphthalene- — -2 -Nitroaniline— — Dimethylphthalate- - - -Acenaphthylene—— 2,6 -Dinitrotoluene- - - -3 -Nitroaniline_ _ _ - Acenaphthene

5105105105105105105105105105105105105105105105105105105105105105105105105101300510

13005105105101300510

UUuuuuuuuuuuu-uuuuuuuuuuuuuuuuuuuu

FORM I SV-1 OIM03.0

'23274 CCX27 SRMPLE D8T8 PflCKTflsfeft 3 I 4-93-5"

1C • EPA SAMPLE NO.SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET








Injection Volume: 2.0(uL) .Dilution Factor: 1.0



cci _9Q-.q- _,--.,.100-02-7 ———1TO_C4_Q____XJ^ w^ 3

1 71 -1 4-O____.1.4£ J. J. £ £t

84-66-2 —— --7005-72-3 ——QC (7*3_'7_____.

100-01-6 —— -534-52-1----86-30-6-----101-55-3----118-74-1- ——o — / o c c87-86-5-----85-01-8-----i on_i p _ 7 _ _ _ _86-74-8 ————fl4-74_P_____206-44-0----129-00-0----QC Cfl "7 __ _.

91-94-1 ———56-55-3 ————0 "1 Q m Q^18-01-9----1 1 -/ QI T

117-84-0 ———

207-08-9 ———C A -3O Qbu-J_!-8-----193-39-5 ——— •53-70-3 ———— •

----2,4 -Dinitrophenol- - - - 4 -Ni t rophenol- - - -Dibenzof uran----2,4 -Dini trotoluene- — Diethylphthalate- - - -4 -Chlorophenyl -phenylether

--- -4 -Nitroaniline----4,6- Dini t ro - 2 - methylphenol _- - - -N-nit rosodiphenylamine ( 1 ) _- - - -4 -Bromophenyl -phenyletEer __- - - -Hexachlorobenzene- - - -Pentachlorophenol- - - - Phenanthrene- - - -Anthracene- — -Carbazole- - — Di -n-butylphthalat e-- — Pyrene- - - -Butylbenzylphthalate- - — 3,3' -Dichlorobenzidine- - - -Benzo (a) anthracene—— Chrysene— -bis ( 2 -Ethylhexyl ) phthalate _- - - -Di-n-octylphthalate— -Benzo (b) f luoranthene- • — Benzo (k) f luoranthene- - - - Indeno (1,2,3 -cd) pyrene- - — Dibenzo ( a , h) anthracene- - - -Benzo (g, h, i ) perylene

13001300510510510510510

13001300510510510

1300510510510510510510510510510510510

"510510510510510510510

UUuuuuuuuuuuuuuuuuuuuuuuuuuuuuu


FORM I SV-2 OLMO33 0

23274 CCX27 S8MPLE DRTR PRCKRG^R3jk9 36 190

IB EPA SAMPLE NOSEMIVOLATILE ORGANICS ANALYSIS DATA SHEET

CCX31Lab Name: COMPUCHEM ENV. CORP. . _. Contract: 68D50004





% Moisture^ 42 decanted: (Y/N) N Date Extracted:03/03/95



GPC Cleanup: (Y/N) Y pH: 5.8 •

' CONCENTE?ATION UNITS:CAS NO. COMPOUND (ug/L,or ug/Kg) ug/Kg Q

\

108-95 -2- -------Phenol_________________lll-44-4--------bis(2-Chloroethyl)ether_95-57-8---------2-Chlorophenol_541-73-1--------1,3-Dichlorobenzene_______106-46-7--------1,4-Dichlorobehzene______95-50-1---------1,2-Dichlorobenzene________95-48-7- --------2-Methylphenol ___________108-60-1----—--2,2'-oxybis(1-Chloropropane)106-44-5---———4-Methylphenol________621-64-7--------N-Nitroso-di-n-propylamine67-72-1-------- -Hexachloroethane___________98-95-3---------Nitrobenzene_________78-59-1-------—Isophorone_88-75-5——-----2-NitrophenoT105-67-9--------2,4-DimethylpEenoT"

-bis(2-Chloroethoxy)methane_-2,4-Dichlorophenol_

120-82-l--------l,2,4-Trichlorobenzene91-20-3-----——Naphthalene106-47-8——————4 -Chloroaniline?-68-3---------Hexachlorobutadiene

59-50-7-—-——-4-Chloro-3-methylphenol_91-57-6-----—-2-Methylnaphthalene_77-47-4---- — — -Hexachlorocyclopentadiene_88-06-2-————--2,4,6-Trichlorophenol95-95-4- — ———2,4,5-Trichlorophenol91-58-7—-- ———2-Chloronaphthalene_____88-74-4--——-—2-Nitroaniline ___131-11-3—————Dimethylphthalate_208-96-8--- — ——Acenaphthylene_

>-20-2--------2,6-Dinitrotoluene99-09-2——————3-Nitroani.line83-32-9------——Acenaphthene_____

570570570570570570570570570570570570570570570570570570570570570570570570570140057014005705705701400570


FORM I SV-1 OLM03.0

——:——— 23274 CCX27 SRFIPLE DRTR PRCKR&& 3 I ~k 9 37 2.0




Matrix: (soil/water) SOIL - Lab Sample ID: 686684








51-28-5 ———— •100-02-7 —— -•132-64-9 ——— •m_1 4_O___ _.84-66-2 ————7005-72-3----QC 11 *7 _ _

100-01-6-----c-34_co_i _ _ _ _J J— i .J £t .1.

86-30-6-----101-55-3-----118-74-1- ——Q T Q d C —

Q C fi 1 Q — — .*1 O rt "1 O T120-12-7----86-74-8 ————fl4_74-P_____.OT! / £*

206-44-0 ——— •129-00-0 ———QC CQ T __—

91-94-1 ————56-55-3 ————218-01-9 ——— •1 1 >7_Q1 _•"__ — _.

117-84-0 ———pne,_qq_p____on*? nc Q ___50-32-8- ——— •193-39-5----_L_7w ~J J •_/

53-70-3 ————191-24-2 ——— •

- - — 2,4 -Dinitrophenol- - - -4 -Nitrophenol- - - -Dibenzof uran----2,4 -Dinitrotoluene- - - -Diethylphthalate. _ _ _4 _ chlorophenyl -phenylether _----Fluorene.__ -4 -Nitroaniline- - - -4 , 6 -Dini tro- 2 -methylphenol _- - - -N-nitrosodiphenylamine_ ( 1 ) _- - - - 4 -Bromophenyl -phenylether

- - - - Pentachlorophenol- - - - Phenanthrene

- - - -Di-n-butyl'phthalate- - - - Fluoranthene----Pyrene- -. — Butylbenzylphthalate- —— 3,3' -Dichlorobenzidine- - - -Benzo ( a ) anthracene----Chrysene—— bis ( 2 -Ethylhexyl ) phthalate _- —— Di-n-octylphthalate-- — Benzo (b) f luoranthene- - - -Benzo (k) f luoranthene- — -Benzo (a) pyrene-- — Indeno (1, 2, 3 -cd) pyrene- - - -Dibenzo (a , h) anthracene----Benzo (g, h, i) perylene

14001400570570570570570

14001400570570570

1400570570570570570570570570570570570570570570570570570570


(i.) - Cannot be separated from Diphenylamine

FORM I SV-2 -01M03"

?3274 CCX27 SfMPLE DPTR PRCKRGE? 211JIR3U938'C

' r::=" —-—— ID .. . . EPA SAMPLE NO.PESTICIDE ORGANICS ANALYSIS DATA SHEET __

CCX27Lab Name:COMPUCHEM ENV. CORP. Contract:68050004

Lab Code: COMPU Case No.: 23274 SAS No. : SDG No.: CCX27

Matrix: (soil/water)SOIL Lab Sample ID: 686674

Sample wt/vol: 30.3(g/ml)G Lab File ID:

% Moisture: 40 decanted: (Y/N)N Date Received: 02/23/95

Extraction: (SepF/Cont/Sonc) SONC Date Extracted:02/28/95SQOO

Concentrated Extract Volume: IQOOO'(uL) Date Analyzed: 03/06/95. fe&2ph*" .

Injection Volume: 2.0 (uL) • , Dilution Factor: 1

GPC Cleanup: (Y/N)Y pH;6.0 Sulfur Cleanup: (Y/N) N

^ - CONCENTRATION UNITS:CAS NO. COMPOUND (ug/L or ug/Kg)UG/KG Q

319-84-6-----319-85-7-----319-86-8-----58-89-9------76-44-8------309-00-2-----1024-57-3----959-98-8-----60-57-1------72-55-9------72-20-8------•3 -3 Ol "5 £ C Q_ _ _

72-54-8------1031-07-8----50-29-3------72-43-5------53494-70-5---7421-93-4----5103-71-9----5103-74-2----8001-35-2 — --12674-11-2---11104-28-2---11141-16-5---53469-21-9---12672-29-6---11097-69-1---11096-82-5---

---alpha-BHC---beta-BHC---delta-BHC- - - gamma - BHC ( Lindane )---Heptachlor---Aldrin---Heptachlor epoxide---Endosulfan I---Dieldrin---4. 4 '-DDE---Endrin---Endosulfan II---4. 4 '-ODD---Endosulfan sulfate---4.4' -DDT- - -Methoxvchlor---Endrin ketone__ -Endrin aldehyde- - - alpha - Chlordane- - - qamma - Chlordane---Toxaphene---Aroclor-1016---Aroclor-1221- - -Aroclor-1232---Aroclor-1242---Arbclor-1248---Aroclor-1254---Aroclor-1260

2.82.82.82.82.82.82.82.85.40.205.45.40.140.30

• 0.33285.45.42.82.8280541105454545454

UUuuuuuuJP _uuJP _JPuuuuuuuuuuuuu

ur-.:;^-- ... FORM i PEST OLMOS.O23274 CCX27 SPWFLE DBTR PflCK«l&3 I 939 396

ID EPA SAMPLE NO.PESTICIDE ORGANICS ANALYSIS DATA SHEET ___

CCX28Lab Name:COMPUGHEM ENV. CORP. Contract:68D5Q004



Sample wt/vol: ' 30.4(a/ml)G Lab File ID:

% Moisture: ,60. decanted: (Y/N)N Date Received: 02/23/95

Extraction: (SepF/Cont/Sonc) SONC Date Extracted;02/28/95?ooo

Concentrated Extract Volume: IQOOO'(uL) Date. Analyzed: 03/06/95fc& 3|HIP>

Injection Volume: 2 .0(uL) ' Dilution Factor: 1.

GPC Cleanup: (Y/N)Y pH;6.1 Sulfur Cleanup: (Y/N) N.

CONCENTRATION UNITS:CAS NO. COMPOUND (ug/L or uq/Kq)UG/KQ C

319-84-6-----319-85-7-----319-86-8-----58-89-9------76-44-8------309-00-2-----1024-57-3----959-98-8-----60-57-1------72-55-9------72-20-8------33213-65-9---72-54-8------1031-07-8 ———50-29-3- —— --72-43-5------53494-70-5---7421-93-4----5103-71-9----5103-74-2----8001-35-2-.---12674-11-2---11104-28-2---11141-16-5---53469-21-9 ——12672-29-6---11097-69-1---11096-82-5---

---alpha-BHC---beta-BHC---delta-BHC-- -gamma -BHC (Lindane)---Heptachlor- - -Aldrin---Heptachlor epoxide---Endosulfan I---Dieldrin---4. 4 '-DDE---Endrin---Endosulfan II---4. 4 '-ODD---Endosulfan sulfate---4.4'-DDT- - -Methoxychlor---Endrin ketone---Endrin aldehyde- - -alpha-Chlordane- - -qamma-Chlordane- - -Toxaphene---Aroclor-1016---Aroclor-1221---Aroclor-1232---Aroclor-1242---Aroclor-1248---Aroclor-1254---Aroclor-1260

4.2• 4.24.24.24.2

0.484.24.28.11.08.18.1

0.790.300.41428.18.14.24.2420811708181818181

__uU

U

uuuJPuJJPJPuuuuuuuuuuu

FORM I PEST OLM03.0

F DQTQ PRCKRGI=L' wt-4-si-lw-U- 4Qg

.:.... "-/-"~" ID EPA SAMPLE NO,PESTICIDE ORGANICS ANALYSIS DATA SHEET . _____

CCX29Lab Name;COMPUCHEM ENV. CORP. Contract;68D50004

Lab Code : COMPU Case No . : 23274 SAS No . : SDG No . : CCX27

Matrix: (soil/water )Sp_IL Lab Sample ID: 686682

Sample wt/vol: 30_,3 (q/ml)G Lab File ID:

% Moisture: 7j_ decanted: (Y/N)N Date Received: 02/23/95

Extraction: (SepF/Cont/Sonc) SONC Date Extracted; 02/28/95" " . 5000

Concentrated Extract Volume: 10000 (uL) / Date Analyzed: 03/06/95

Injection Volume: 2 .0 (uL) • Dilution Factor: I

GPC Cleanup: (Y/N)Y pH ; 5 . 8 Sulfur Cleanup: (Y/N)

CONCENTRATION UNITS;CAS NO. COMPOUND (ug/L or ug/Kg) UG/KG

319-84-6-----319-85-7-----319-86-8-----58-89-9------76-44-8------309-00-2-----1024-57-3----959-98-8-----60-57-1------72-55-9------72-20-8------33213-65-9---72-54-8------1031-07-8----50-29-3------72-43-5------53494-70-5---7421-93-4----5103-71-9 ———5103-74-2 ———8001-35-2----12674-11-2---11104-28-2---11141-16-5---53469-21-9---12672-29-6 ——11097-69-1---11096-82-5---

-- -alpha -BHC---beta-BHC---delta-BHC---gamma-BHC (Lindane)---Heptachlor- - -Aldrin---Heptachlor epoxide---Endosulfan I---Dieldrin---4r4'-DDE---Endrin---Endosulfan II---4.4'-DDD---Endosulfan sulfate---4. 4 '-DOT- - -Methoxychlor---Endrin ketone---Endrin aldehyde- - -alpha -Chlordane- - -gamma - Chlordane- - -Toxaphene---Aroclor-1016---Aroclor-1221---Ajroclor-1232---Aroclor-1242---Aroclor-1248---Aroclor-1254---Aroclor-1260

5.85.85.85.85.80.455.85.81111'1111

0.711.0115811

0.695.85.8580110230110110110110110

__UUuuJP ___uuuuJJPuuJuuuuuuuuu

FORM I PEST OLM03.0

23274 CCX27 SffflPLE DflTO PPCKOGf R 3~l k 9 k I 417

ID EPA SAMPLE NO.PESTICIDE ORGANICS ANALYSIS DATA SHEET

CCX30Lab Name:COMPUCHEM ENV. £ORP. Contract;68D50004

Lab Code : COMPU Case No . : 23274 SAS No . : SDG No . : CCX27


Sample wt/vol : 30. 4 (g/ml)G Lab File ID:

% Moisture: 3_5_ decanted: (Y/N)N Date Received: 02/23/95

Extraction: (SepF/Cont/Sonc) SONG Date Extracted : 02/28/955000

Concentrated Extract Volume: IQOOO-(uL) ^ Date Analyzed: 03/06/95— —— ——

Injection Volume: 2.0 (uL) , Dilution Factor: JL.

GPC Cleanup: (Y/N)Y pH:6.6 Sulfur Cleanup: (Y/N) ££

CONCENTRATION UNITS:CAS NO. COMPOUND (ug/L or uq/Kq) UG/KG Q

319-84-6-----319-85-7-----319-86-8-----58-89-9------76-44-8------309-00-2-----1024-57-3----

60-57-1------72-55-9------72-20-8------33213-65-9---

1031-07-8----50-29-3------72-43-5------53494-70-5 ——7421-93-4----5103-71-9 ———5103-74-2----8001-35-2----12674-11-2---11104-28-2---11141-16-5---53469-21-9---12672-29-6---11097-69-1---11096-82-5 ——

-- -alpha -BHC---beta-BHC---delta-BHC- - - qamma - BHC ( Lindane )---Heotachlor- - -Aldrin---Heptachlor epoxide---Endosulfan I---Dieldrin---4. 4 '-DDE---Endrin---Endosulfan II

f ** LfUU

---Endosulfan sulfate---4. 4 '-DOT- - -Methoxychlor---Endrin ketone---Endrin aldehyde---alpha-Chlordane- - -qamma-Chlordane- - -Toxaphehe---Aroclor-1016---Aroclor-1221---Aroclor-1232---Aroclor-1242---Aroclor-1248---Aroclor-1254---Aroclor-1260

-

2.62.62.62.62.62.62.62 C. o5.0

0.155'. 05.0

n 9^\J . £* *J

5.00.23265.05.02.62.6260501005050505050

_.UU

uuu\J

uQ _______———————

U-.Lj

UJPUuuuuuuuuuuuu

FORM I PEST OLM03.0

23274 CCX27 SRMPLE DRTR PRCKRG^ $ ' ' ~ 428

ID EPA SAMPLE NOPESTICIDE ORGANICS ANALYSIS DATA SHEET. _________

, CCX31Lab Name ;COMPUCHEM ENV. -"CORP. Contract: 68D50Q04

Lab Code: COMPU Case No.:' 23274 SAS No.: SDG No.: CCX27

Matrix: (soil/water)SO£L Lab Sample ID: 686684

Sample wt/vol: 30.2(g/ml)Q . Lab File ID:

% Moisture: 42. decanted: (Y/N)N Date Received: 02/23/95

Extraction: (SepF/Cont/Sonc) SONC Date Extracted;02/28/95r • ---• . - - - — 5"0oo

Concentrated Extract Volume: IDOOO-(uL) Date Analyzed: 03/06/95. "•;:-- RfcaM'tf'

Injection Volume: 2.0(uL) Dilution Factor: ±

GPC Cleanup: (Y/N)Y pH;5'. 8 " Sulfur Cleanup: (Y/N) N

^t: - :i_ \" CONCENTRATION UNITS:CAS NO. ; COMPOUND " (ug/L or uq/Kq)UQ/KG C

319-84-6-----319-85-7-----319-86-8-----58-89-9------76-44-8------309-00-2-----1024-57-3----959-98-8-----60-57-1------72-55-9------72-20-8------33213-65-9---72-54-8------1031-07-8----50-29-3------72-43-5 ———— -53494-70-5---7421-93-4----5103-71-9----5103-74-2----8001-35-2----12674-11-2---11104-28-2---11141-16-5---53469-21-9---12672-29-6---11097-69-1 ——11096-82-5---

-- -alpha -BHC---beta-BHC---delta-BHC---gamma-BHC (Lindane)---Heptachlor .,„.„„ , ,---Aldrin---Heptachlor epoxide---Endosulfan I---Dieldrin---4. 4 '-DDE---Endrin---Endosulfan II-__4f4'-DDD---Endosulfan sulfate___4T4'-DDT- - -Methoxychlor---Endrin ketone---Endrin aldehyde- - - alpha - Chlordane- - -gamma-Chlordane- - - Toxaphene---Aroclor-1016---Aroclor-1221---Aroclor-1232- - -Aroclor- 1242___Aroclor-1248---Aroclor-1254---Aroclor-1260

2.92.92.92.92.92.92.92.95.75.75.75.75.7

0.355.7295.75.72.92.9290571105757575757

U

UUuuuuU'uuJPuguuuuuuuuuuu

FORM I PEST OLM03.0

DRTR PPCKPG^ R 3 I k 9 k 3: 43.5

Appendix DReviewed and Corrected

Tentatively Identified Compounds

AR3U9UU

"IF EPA SAMPLE NO..SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET

: TENTATIVELY IDENTIFIED COMPOUNDSCCX27

Lab Name: COMPUCHEM ENV. CORP. Contract: 68D50004




Level: _ (low/med) LOW . Date Received: 02/23/95



Injection Volume: 2.0(uL) -Dilution Factor: 1.0


----'-•--'- CONCENTRATION UNITS:Number TICs found: 33 (ug/L or ug/Kg) ug/Kg

, CAS NUMBER___-==:==:=-=,-:-==-=====:i .

2.3.4.5.*-

7.8.9.10.11.i 2 _____________13.14.15.16.17.18.19.20.21.22.23.24.25.26.27.28.29.30.

COMPOUND NAME=============::=====:=========UNKNOWN (DC) ———————————UNKNOWN CARBOXYLIC 'ACIDUNKNOWN ESTERUNKNOWN ESTERUNKNOWN ESTERLABORATORY ARTIFACT ———————UNKNOWN ESTERUNKNOWNUNKNOWN ESTERUNKNOWN ESTERUNKNOWN ESTERUNKNOWN (BC) ——————————————UNKNOWNUNKNOWNUNKNOWN ALCOHOLUNKNOWNUNKNOWNOCTABENZONEUNKNOWNUNKNOWN ALDEHYDEUNKNOWNUNKNOWNUNKNOWNUNKNOWNUNKNOWNUNKNOWNUNKNOWNUNKNOWNUNKNOWNUNKNOWN

RT========— ' — 4 nn

13.2414.6214.6614.89

—— 11.0315.1915.4515.. 5615.8315.87

——— 15.0416.1616.7217.1417.2917.8117.9018.0418.2220.4021.2721.3121.3822.0424.2825.5326.6726.7027.02

EST. CONC.= = = = = = = = ====:=

inn145277444290

——— '. ————— 758-302143183258155

———————— 3.334-222145

1288218312288114433684188254159190556

1062396211233

Q=5 -5SS-3SS

•BcF ——JJJJ-J ———JJJJJ-&J ——JJJ.JJJJJJJJJJJJJJJ

FORM I SV-TIC ' OIjMOS.O

23274 CCX27 SfMPL E DRTR PRCKRG^^ I **$ k 5

IF EPA SAMPLE NO.SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET

TENTATIVELY IDENTIFIED COMPOUNDSCCX27




Sample wt/vol: 30.3 (g/mL) g Lab File ID: GH086674A21a






CONCENTRATION UNITS:Number TICs found: 33 (ug/L or ug/Kg) ug/Kg

CAS NUMBER

1.2.3.4.5.6.7.8.9.10.11.12.13.14.15.16.17.18.19.20.21.22.23.24.25.26.27.28.29.30.

COMPOUND NAME

UNKNOWNUNKNOWNUNKNOWN

RT

27.8228.6128.65

EST. CONC;

112518482

Q

JJJ

-

FORM I SV-TIC OLM03

23274 CCX27 SPMPLE OPTP PPCKPlM3 I k9k6 45

- -'. 1FA ' EPA SAMPLE' NO.SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET..;•;";•'"'•-- ALKANE SERIES REPORT


Lab Code: _COMPU Case No.: 23274 SAS No.: ' SDG No.: CCX27






-Injection Volume: 2.0(uL) Dilution Factor: 1.0

GPC Cleanup: (Y/NJ Y pH: 6.0

-—•-----— CONCENTRATION UNITS:Number TICs found: 4 (ug/L or ug/Kg) ug/Kg

CAS NUMBER

1.2.3.4.5.6.7.8.9.10.11.12.13.14.15.16.17.18.19.20.21.22.23.24.25.26.27.28.29.30.

COMPOUND NAME

UNKNOWN ALKANEUNKNOWN ALKANEUNKNOWN ALKANEUNKNOWN ALKANE

RT

14.9716.4818.7621.16

EST. CONC.

22016927291165

Q

J 'JJJ

FORM I SV-TIC OIM03.0

23274r CCX27 SPNPLE QPTP PPCKPGE 44

1F EPA SAMPLE NO.SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET











CONCENTRATION UNITS:Number TICs found: 28 ' (ug/L or ug/Kg) ug/Kg

CAS NUMBER

2.3.4.5.

7.8.9.10.11.i-j

13.14.15.16.17.18.19.20.21.22.23.24.25.26.27.28.29.30.

COMPOUND NAME

UNKNOWN (DC) ——————————————UNKNOWNUNKNOWN ESTERUNKNOWN ESTERUNKNOWN ESTER

UNKNOWNUNKNOWN ESTERUNKNOWNUNKNOWNUNKNOWN ESTERUNKNOWN (DC) ———————————UNKNOWNUNKNOWNSUBSTITUTED ALCOHOLUNKNOWN AMIDEUNKNOWNUNKNOWNUNKNOWN ALDEHYDEUNKNOWN ALCOHOLUNKNOWNUNKNOWNUNKNOWNUNKNOWNUNKNOWNUNKNOWNUNKNOWNUNKNOWN

RT

6.0614.6114.6614.89

——— 3.4 — as-14.9615.1915.4415.6115.82i— > Q-J

16.1316.7217.1317.8117.9018.0418.2218.8120.4221.3221.3322.0524.3025.5428.6228.67

EST. CONC.

—————————— 3-gjjL176293406291

365273176240294

~\ T n A217185

1831236253175

1045390210834834906092313772172207

Q-a? —jjJ JT TjJjJ •.n.x,JJJJJJJJJJJJJJJJ

FORM I SV-TIC OLM03?

23274 CCX27 SPMPLE &PTP PPCKPGE .- 9

•f™-"'-~=? -\ . "" 1FA" . " , EPA SAMPLE NO.SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET

ALKANE SERIES REPORTCCX28


Lab Code: ...COMPU Case No. : 23274 SAS No. : . • SDG No. : CCX27

Matrix: (soil/water) SOIL Lab Sample•ID: 686681



% Moisture: 60__ decanted: (Y/N) N Date Extracted:02/28/95



GPC Cleanup! (Y/N) Y pH: 6.1

- - = •: 7 CONCENTRATION UNIT'S:Number TICs found: 2 (ug/L or ug/Kg) ug/Kg

• CAS NUMBER

1. • .2.3.4.5.6.7.8.9.10.11.12.13.14.15.16.17.18. '19.20.21.22.23.24.25.26.27.28.29.30.

COMPOUND NAME

UNKNOWN ALKANEUNKNOWN ALKANE

RT========

21.1721.19

EST. CONC.

810592

Q

JJ .

FORM I SV-TIC . . OLM03,0

23274 CCX27 SPMPLE DPTP PffCKBGE ^ 99













CAS NUMBER

2.3.4.5.6.7.8.g

10.11.12.13.14.15.

-46- ———————————17.18.19.20.21.22.23.24.25.26.27.28.29.30.

COMPOUND NAME

UNKNOWN (DC) ——————————————UNKNOWNUNKNOWNUNKNOWNUNKNOWNUNKNOWN ESTERUNKNOWN ESTERUNKNOWN ESTERLABORATORY ARTIFACT ————————UNKNOWN ESTERUNKNOWNUNKNOWNUNKNOWN ESTERUNKNOWN ESTERUNKNOWNUNKNOWN (EC)UNKNOWNUNKNOWNUNKNOWNUNKNOWN AMIDEUNKNOWNUNKNOWNUNKNOWNUNKNOWN .UNKNOWNUNKNOWNUNKNOWN

RT

———— 4 — 9-6-6.0612.8114.0714.5514.61

' 14.6614.88

——— 11.0215.1915.3715.4215.5515.8215.86

——— 15.0316.1616.4516.7217.8117.9018.2218.8120.3922.0225.5025.52

EST. CONC.

236256286229514711548

i i nn499304474370

• 456268

•5T 17

41544423658426314952850121556010361254

Q

•RrF ————jj

J ij ^jj 1jTjjjjjLJJJJJJJJJJJJ

FORM I SV-TIC OIM03.

23274 CCX27 SPMPLE DPTP PPCKPGE

--'-;; -....-,,..---'; ;r; = ~; 1FA .. . . . . . . - ... . . . EPA SAMPLE NOSEMIVOLATILE ORGANICS ANALYSIS DATA SHEET:-; - - ALKANE SERIES REPORT


Lab Code: COMPU Case No.: 23274 SAS No. : SDG No. : CCX2.7

Matrix: .(soil/water) SOIL . Lab Sample ID: 686682




Concentrated Extract Volume: 500(uL) Date Analyzed: 03/01/95. . . - : _ _ - = - . _ j

Inj ection Volume: 2.0(uL) . Dilution Factor: 1.0

GPC Cleanup:" (Y/N) Y pH: 5.8

.' . ' -'' CONCENTRATION UNITS:Number TICS found: 3 (ug/L or ug/Kg) ug/Kg

CAS NUMBER

1.2.3.4.5.6.7.8.

• 9.10.11.12.13.14.15.16.17.18.19.20'.21.22.23.24.25.26.27.28.29.30.

COMPOUND NAME

UNKNOWN ALKANEUNKNOWN ALKANEUNKNOWN ALKANE

RT

13.9714.9617.11

EST. CONC.

2322811739

Q=:_=-=_= 53

jJJ

. FORM I SV-TIC OIM03.0

23274 CCX27 SRMPLE DPTP PBCKBGE*u ' J° ' 145GE^^




Lab Code: COMPU Case No.: 23274 SAS No. : SDG No. : CCX27








CONCENTRATION UNITS:Number TICs found: 6 " (ug/L or ug/Kg) ug/Kg

CAS NUMBER

—— 3r: —————————————"1

3.4.5.6. '7.8.9.10.11.12.13.14.15.16.17.18.19.20.21.22.23.24.25.26.27.28.29..30.

COMPOUND NAME

ALDOL (DC) ————————————UNKNOWN (DC) ———————————UNKNOWNUNKNOWNUNKNOWNUNKNOWN

RT

———— 4-T-63-—— s-r e-

18.5225.0925.4726.49

EST. CONC.

^e*1————————— i43-

1282301761617

Q

A/m-3B —— \

i

FORM I SV-TIC QLM03

23274 CCX27 SPMPLE DPTP PPCKPG& % 3-I-W 5 2 191

.,—__ -__— 1FA . ' EPA SAMPLE NOSEMIVOLATILE ORGANICS ANALYSIS DATA SHEET

:' -ALKANE SERIES REPORTCCX30


Lab Code: COMPU Case No,: 2,3274 SAS No.: SDG No.: CCX27



Level: _(low/mod). LOW Date Received: 02/23/95* - •

% Mois_ture: 35 : decanted: (Y/N) N Date Extracted: 03/03/95

Concentrated Extract Volume: ,500(uL) Date Analyzed: 03/06/95

Injection Volume: 2.0(uL) ... Dilution Factor: 1.0

GPC Cleanup:, (Y/N) Y pH: 6.6

" " _^;, CONCENTRATION UNITS:Number TICs found: 2 (ug/L or ug/Kg) ug/Kg

CAS NUMBER

1. '2.,3.4..5.6.7.8.9.10.11.12.13.14.15.16.17.18.19.20.21.22.23.24.25.26.27. .28.29.30.

COMPOUND NAME

UNKNOWN ALKANEUNKNOWN ALKANE

RT

16.9820.79

EST. CONC.

101146

Q=====JJ

FORM I SV-TIC OIM03.0

~ 23274 CCX27 SPMPLE DPTP PPCKPG&R.3 I W53 192

IF ' EPA SAMPLE NO.SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET












CAS NUMBER

—— 3r^ ——————————————

3.4.5.6.7.8.9.10.11.12.13.14.15.16.17.18.19.20.21.22.23.24.25.26.27.28.29.30.

COMPOUND NAME

ATJ3OT, £Bgj ——————————————UNKNOWN (EC) ———————————————UNKNOWNUNKNOWN 'UNKNOWN

RT

———— 4.64——— S-r32-

17.7017.8826.51

EST. CONC.

——————— S4e-—————— tee-

90129260

Q

•A3B — 1"ItiSB —— fJ: 4

f

__ .FORM I SV-TIC OIM03

'23274 CCX27 SPMPLE &PTP PPCKPGE &'R~3 I 9 5 k 212

1FA EPA SAMPLE NO.-SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET.-. - ALKANE SERIES REPORT


Lab Code:_COMPU Qase No.: 23274 SAS No.: . SDG No.: CCX27r

Matrix: (soil/water) SOIL ' Lab Sample ID: 686684







- - - CONCENTRATION UNITS:Number TICs found: 4 (ug/L or ug/Kg) ug/Kg

CAS NUMBER====s_= ===_=__:s=:===i=

1.2.3.4.5.6.7.8.9.10.11.12.13.14.15.

• 16.17.18.19.20.21.22.23.24.25.26.27.28.29.30.

COMPOUND NAME=:= = _===: :_» _= == = =i TSSS == == = ===sza= = = s.zs_=

UNKNOWN ALKANEUNKNOWN ALKANEUNKNOWN ALKANEUNKNOWN ALKANE

RT

15.8616.9818.5620.83

.

EST. CONC.

125147301453

^ ' r"

.

Q

JJJJ

FORM,I SV-TIC , OLM03.0

23274 CCX27 SPMPLE ORTP PPCKPG& R 3 M* 95 5 213

*

Appendix B

Support Documentation

AR3U956

TABLE I page 1 of 5

•--; ENVIRONMENTAL PROTECTION AGENCY REGION IIICALIBRATION OUTLIERS

SEMIVOLATILE HSL COMPOUNDS (Part 1 of 2)DAS NO. 23274______________ CONTRACTOR ______________ESAT ____

! Instrument* OWA21 - Unit. Cal.* DATE /TIME:i" Phenolbis f 2-Chloroethvl ) ether

1 2-Chlorophenol1,3-Dichlorobenzene

' 1,4-Dichlorobenzene1,2-Dichlorobenzene2-Methvlohenol2.2' -Oxvbis ( l-Chloronropane »4-MethvlohenolN-Nitroso-di-n-T>roT5vlamineHexachloroethaneNitrobenzeneIsophorone2-Nitrochenol2 . 4-Dimethvlohenolbis f 2-Chlbroethoxvi methane2 . 4-Dichloroohenol1,2, 4-TrichlorobenzeneNaphthalene4-ChloroanilineHexachlorobutadiene4-Chloro~3-Methvlohenol2-MethvlnanhthaleneHexachlorocvclotsentadiene2,4, 6— Trichloroohenol2,4, 5-Trichloroohenol2— Chloronaohthalene2-NitroanilineDimethvlnhthalateAcenanhthvlene2 , 6-Dinitrotoluene

02/27/95- 13:30RP

1

3-Nitroaniline !Acenaohthene !2 . 4-Dinitrophenol. 4— Nit rocheno 1

%RSD ! *!

——— 1 ———

!!i

Cont. Cal. ICont. Cal. !03/01/95 - 10:52RP ! %D ! *

!1 1

! !! !! !1 1

1 lIl

L 1 [

t

[i!It11

!I1

r1

L03/06/95 - 01:01!RP

i{i!

.29.6 C

1

37.1 C

All ! SBLK11AFFECTED J samoles ICCX27SAMPLES :

leviewer jnitials/Date: DSB 03/24/95

- -•• — - -

on ICCX2Sthis ICCX28MScaae ICCX28MSD

ICCX29}!!

• .L -- .- .. - -- - |

•

%D ! * !L _! !i

iii

!

! !i iL L

1

1

!

L ji

ii

!!!i

SBLK47

.

* See last cage of thi« table for DEFINITION OP CODES.

AR3U957

TABLE I page 2 of 5

ENVIRONMENTAL PROTECTION AGENCY REGION IIICALIBRATION OUTLIERS

SEMIVOLATILE HSL COMPOUNDS (Part 2 Of 2)DAS No.______23274_____________ CONTRACTOR _____________ESAT

Instrument* OWA21 Init. Cal. iCont. Cal.DATE/TIME: 02/27/95- 13: 30 ! 03/01/95 - 10:52

RPDibenzofuran2 , 4-DinitrotolueneDiethvlphthalate4-Chlorophenvl-phenvletherFluorene4-Nitroaniline4 , 6-Dinitro-2-methvlPhenolN-Nitrosodiphenvlamine4-Bromophenvl-phenvletherHexachlorobenzene !Pentachlorophenol !PhenanthreneAnthraceneCarbazoleDi-n-butvlphthalateFluoranthenePvreneButvlbenzvlphthalate3,3' -DichlorobenzidineBenzo ( a 1 anthracene .Chrvsenebis f 2-Ethvlhexvl i phthalateDi-n-octvlphthalateJJenzo^b i f luorantheneBenzo Ck) f luorantheneBenzo ( a. > pvreneIndeno (1,2, 3-cd ) pvreneDibenzfa.h) anthracene !Benzo < a , h , i i pervlene

AFFECTED jSAMPLES : .

%RSD * !RP ! %D1 J _J

1. ti1[iI

51.2 I

!j

11ti

! __,i! 53.0

*Cont. Cal. !03/06/95 - 01:01!

RF i %D ! * L! j

j ii

C !

iji

l_l i

L

!i

81.5 C !ij j

i

!i!!j

!!j

j |! 1i ii ji ij j

55.6! C !! !i ij |i i

r_ ! !1

' ]! 1

! ! ! !All ISBLK11samples ICCX27on SCCX28this JCCX28MS

Reviewer | paqe JCCX28MSDCriitials/Date: DSB 03/24/95 ! iCCX29

1 1

! SBLK47 !i i1 !i i| |i • it _i; j

1 . t 1 1

j {i i

* Sea la«t pace of this table for DEFINITION OF CODES.

AR3IU958

TABLE I page 3 of 5


SEMIVOLATILE HSL COMPOUNDS (Part 1 of 2)DAS No. 23274___________" CONTRACTOR ___________ESAT_________

! Instrument* OWA21! DATE /TIME:!! Phenol! bis <2-Chloroethvli ether

Init. Cal. ICont. Cal. ICont. Cal. !02/27/95- 13:30103/06/95 - 14:25!RF !%RSD! * ! RF ! %D «

!! 2-Chlorophenol !! 1.3-Dichlorobenzene! 1,4-Dichlorobenzene

ij

! 1,2-Dichlorobenzene! 2-Methvlphenol

. I 2.2'-Oxvbisf 1-Chloropropanel! 4-Methvlphenol! N-Nitroso-di-n-proovlamine !! Hexachloroethane! NitrobenzeneIsophorone2-Nitrophenol !

! 2.4-Dimethvlphenol !' bis 12— ChloroethoxvAmethane _i! 2,4-Dichlorophenol

1,2. 4-Trichlorobenzene

L j! j

tNaphthalene !

! 4-Chloroaniline ! !! Hexachlorobutadiene !! 4-Chloro-3-MethvlPhenol ! •! 2-Methvlnaphthalene |! Hexachlorocvclopentadiene ! !! 2,4,6-Trichlorophenol !! 2.4,5-Trichlorophenol! 2-Chloronaphthalenei 2-Nitroaniline f! Dimethvlphthalate TL Acenaphthvlene !! 2.6-Dinitrotoluene !! 3-Nitroaniline !! Acenaphthene !! 2,4-Dinitrophenol! 4— Nitrophenol

AFFECTED jSAMPLES: j

i - • • ' •• jReviewer jInitials /Data: DSB 03/24/95

! j j!

——— i ———— '1

* ! RF ! %D ! * .| | i i

{ j | iJ j } [j jii———— i ——— ii

j1j j1 11

J j

Jii!!

jj ___ii

!!]!!!

All CCX30samples CCX31

j

j

jI

1 1t 1

1

1

onthisoaae .

j!i

* Sea last page of this table for DEFINITION OF COPES.

AR3IU959

TABLE I page_£_of_5_


SEMIVOLATILE HSL COMPOUNDS (Part 2 of 2)DAS No. 23274_____________ CONTRACTOR _____________ESAT_____

Instrument* OWA21 ilnit. Cal. iCont. Cal.DATE/TIME: 102/27/95- :

Dibenzofuran2 , 4-Dinitrotoluene

RF %RSD.3:30103/06/95 - 14:25

* !RF ! %D *1 f1 1

Diethvlphthalate ! ! ! (4-Chlorophenvl-phenvlether ! ! ! ! !Fluoreneti-Nitroanilinen 6-Dinitro-2-methvlPhenol iN— Nltrosodiphenvlamine !4-Bromophenvl-phenvlether !Hexachlorobenzene !Pentachlorophenol !

! i11

33.1

_[

I 1 __l

Phenanthrene ! !Anthracene ! !

1 Carbazole ! !Di-n-butvlphthalate i !Fluoranthene ! !

! Pvrene ! !I ButvlbenzvlPhthalate ! !i 3.3'-Dichlorobenzidine !! Benzo (a) anthracene !

51.2

Chrvsene ! !bis(2-EthvlhexvliPhthalate !Di-n-octvlphthalate !

i_ Benzo tb ) f luoranthene L! Benzol ki f luoranthene! Benzo tajjpvren© t

! Indenofl,2.3-cdiPvren@ ! !Dibenzf a, h) anthracene ! j

I

Benzo ( a, h, iipervlene ! ! !

AFFECTEDAllsamples

SAMPLES: \ on! this

0.032! 70.4

c

PC

Cont. Cal.

RF ! %D ! *jj

i

! ;! i >!jj![j|ii[!iiiii!

[,_ j

. j

i!j

ij

_!i

! i ! ! !CCX30CCX31!J

Reviewer ! paaeEnjitials/Date: DSB 03/24/95 !

! i

i ii ! !

* See last pace of this tabla for DEFINITION OF COPES.

AR3ii4960

Page.

DEFINITION OF CODES USED IN TABLE I

I = %RSD exceeded 30% in the initial calibration, positive resultsare qualified "J". When the %RSD exceeded 50%, quantitationlimits are qualified "UJ".

C = %D exceeded 25% in the continuing calibration, positiveresults are qualified "J". When the %D exceeded 50%,quantitation limits are qualified "UJ".

F = RF less than 0.05 in the calibration. All quantitation limitsare qualified "R" and positive results are qualified "L".

+ = The "B" qualifier, denoting blank contamination, supersedesthe qualifier issued in this table.

R = The "R" qualifier, denoting unusable results, supersedes thequalifier issued in this table.

AR3U961

6BSEMIVOLATILE ORGANICS INITIAL CALIBRATION DATA

Lab Name: COMPUCHEM ENV. CORP. ' -Contract: 68D50004


Instrument" ID: OWA21 Calibration Date (s) : 02/27/95 02/27/95

Calibration Time(s): 1330 1559

LAB FILE ID: RRF20 =HI950227A21 RRF50 =HG950227A21RRF80 =HM950227A21 RRF120=HK950227A21 RRF160=HH950227A21

COMPOUND=:s:s-==s3-5_5==s:-S-==-:=s3-= =2 =;_=_= =s ==_£==:_:-£

Phenol . *

RRF20

' 1.310bis(2-Chloroethyl)ether * 1.2202 -Chlorophenol * 1.2121,3 -Dichlorobenzene * 1.4511,4 -Dichlorobenzene * 1.5111,2 -Dichlorobenzene * 1.4142 -Methylphenol * 0.9842,2' -oxybis (1-Chloropropane)4 -Methylphenol y

1.234* 1.053

N-Nitroso-di-n-propylamine * 0.911Hexachloroethane * 0.611Nitrobenzene * 0.352Isophorone * 0.6972-Nitrophenol * 0.1962,4-Dimethylphenol * 0.289bis ( 2 - Chloroethoxy ) methane _ * 0.4392,4-Dichlorophenol * 0.3131 , 2 , 4 -Trichlorobenzene * 0.354Naphthalene * 1.0254 -ChloroanilineHexachlorobutadiene

0.3200.235

4 -Chloro-3 -methylphenol * 0.2812 -Methylnaphthalene * 0.545Hexachlorocyclopentadiene2,4,6 -Trichlorophenol i

0.438* 0.429

2, 4, 5 -Trichlorophenol * 0.4762-Chloronaphthalene * 1.1822 -NitroanilineDimethylphthalate

0.3181.407

Acenaphthylene * 1.8492, 6 -Dini trotoluene * 0.2913 -Nitroaniline 0.264Acenaphthene * 1.1502 , 4 -Dinitrophenol4 -Nitrophenol

0.0930.115

Dibenzofuran * 1.6322,4-Dinitrotoluene * 0.391

RRF50

1.3211.2501.1981.4191.4271.3671.0131.2121.0480.9360.6200.3440.7220.2010.2950.4560.3240.3560.9850.3560.2190.2890.5550.4970.4550.4931.2240.3451.4501.9130.3140.2431.1320.1710.1391.6720.422

RRF80-_;=:s===

1.3121.2631.1731.3561.3621.2701.0011.2961.0240.9420.6090.3660.7520.1990.3000.4680.3130.3440.9490.3320.2110.2940.5280.4660.4400.4761.1850.3701.3851.7780.3220.2121.0160.1690.1461.6040.408

RRF120=SS= = =S-=:S

1.3071.2451.1221.3111.2961.1721.0001.3500.9560.9020.5870.3650.7670.1980.2980.4620.3000.3180.8720.3200.1840.2900.4800.4340.4180.4511.0770.3651.3041.5750.3070.2290.8480.1670.1441.4440.402

RRF160

1.2551.2061.0471.2331.1821.0270.9461.3860.8270.8300.5680.3660.7530.1950.2940.4580.2890.2920.7700.3600.1700.2760.4280.3900.3990.4190.9780.3701.2671.4240.3120.2530.7260.1390.1311.3170.379

RRFrssssjs-ss

1.3011.2371.150,1.3541.3561.2500.9891.2960.9820.9040.5990.3590.7380.1980.2950.4570.3080.3330.9200.3380.2040.2860.5070.4450.4280.4631.1290.3541.3631.7080.3090.2400.9740.1480.1351.5340.400

%RSD

-SS-SSS

2.0*1.9*5.9*6.4*9.3*

12.4*2.6*5.79.7*5.0*3.5*2.9*3.8*

•4.4*8.2*11.0*5.7

13.22.6*

10.5*8.95.0*6.2*8.9*6.35.5

11.9*3.6*8.4

18.8*22.49.19.7*4.1*

* Compounds with required minimum and maximim %RSD values.All other compounds must meet a minimim RRF of 0.010.

FORM VI SV-l OIM03.

23274 CCX27 SPMPLE DPTP PPCKPGE' 234

________ 6C------. ••SEMi'VOiiATILE" ORGA flCS INITIAL CALIBRATION DATA

Lab Name:. COMPUCHEMENV. CORP. /^Contract: 68050004-


Instrument-ID:.OWA21 Calibration Date(s): 02/27/95 02/27/95

"-•-" """• Calibration Time (s) : 1330 1559

LAB FILE ID: RRF20 =HI950227A21 RRF50 =HG950227A21RRF80 =HM950227A21 RRF120=HK950227A21 RRF160=HH950227A21

COMPOUND

Diethylphthalate

RRF20

1.5384 -Chlorophenyl -phenylether _ * 0.670Fluorene * 1.2624 -Nitroaniline4, 6 -Dinitro- 2 -methylphenol _N-ni trosodiphenylamine ( 1 ) _4 -Bromophenyl -phenylether __ iHexachlorobenzene •>

0.2190.1180.537

" 0.282" 0.402

Pentachlorophenol * 0.159Phenanthrene * 1.165Anthracene * 1.151CarbazoleDi-n-butylphthalate

0.8501.650

Fluoranthene * 1.020Pyrene * 1.565Butylbenzylphthalate3,3' -Dichlorobenzidine

0.7130.176

Benzo (a) anthracene • * 1.220Chrysene * 1.089bis (2 -Ethylhexyl) phthalate _Di-n-octylphthalate

1.1351.635

Benzo (b) f luoranthene * 1 . 058Benzo (k) f luoranthene * 1.175Benzo (a) pyrene * 0.957Indeno (1,2, 3 -cd) pyrene * 1.051Dibenzo( a, h) anthracene * 0.883Benzo(q>h,i)perylene * 0.887

Nitrobenzene-d5 0,3612-Fluorobiphenyl * 1.417Terphenyl-dl4 * 1.224Phenol-d5 * 1.2882-Fluorophenol * 0.9672,4,6 -Tribrpmophenol 0.1582- Chlorophenol -d4 ' * 1.234l,'2-Dichlorobenzene-d4 * 0.938

RRF50

1.5160.6981.2450.1960.1690.5440.2820.3700.2011.2031.225

' 0.9191.7801.0771.5530.7990.1491.2371.1121.2181.8641.1131.1541.0061.2161.0161.038

0.3751.4091.1561.3030.9940.1561.2460.902

RRF80

1.4750.6601.1150.1790.1650.4940.2720.3290.1981.1411.1650.8721.6941.0391.4620.8220.1051.2011.1091.2751.9761.1391.1430.9921.1880.9801.012

0.3851.2751.0561.3031.0140'.1521.2110.863

RRF120

1.3210.585

' 0.9540.1400.1780.5020.2500.3020.2021.0811.0550.815.1.5810.9511.3810.8550.0601.1741.0761.2951.9351.0911.0700.9731.2581.0081.068

0.3911.0910.9521.2721.0310.1401.1930.797

RRF160

1.1730.5050.8320.0930.1690.4630.2310.2590.1860.9940.8860.7641.4170.8241.3270.8670.0481.1521.0281.3001.8841.0930.970

• 0.9671.2921.0221.118

0.3930.9640.8581.2381.0310.1311.1240.703

RRF

1.4050.6241.0820.1650.1600.5080.2630.3320.1891.1171.0960.8441.6240.9821.4580.8110.1081.1971.0831.2451.8591.0991.1020.9791.2010.9821.025

0.3811.2311.0491.2811.0070.1471.2020.841

RSD

11.012.5*17.2*29.914.96.58.4*16.8*9.5*7.3*12.1*6.98.410.2*7.1*

S* \(51.212.9*3.2*5.67.12.7*7.6*2.0*

. 7.7*5.8*8.4*

3.5<16.2*14.1*2.1*2.7*7.84.0*11.1*

(1) Cannot be seperated from Dipheny! .amine* Compounds with required minimum and maximim %RSD values.All other compounds must meet a minimim RRF of 0.010.

FORM VI SV-2 OIM03.0

23274 CCX27~ SfMPLE DPTP PPCKPGE $ R 3 j |j g £ 3 235

7BSEMIVOLATILE CONTINUING CALIBRATION CHECK

Lab Name: COMPUCHEM ENV. CORP. Contract: 68D50004-

Lab Code: COMPU Case No.: 23274 SAS No.: SDG No.: CCX27«*

Instrument ID: OWA21 Calibration Date: 03/01/95 Time: 1052

Lab File ID: HG950301A21 Init. Calib. Date(s): 02/27/95 02/27/95

Init. Calib. Times: 1330 1559

COMPOUND

Phenolbis (2-Chloroethyl) ether ______2 -Chlorophenol1 , 3 -Dichlorobenzene1 , 4 -Dichlorobenzene1 , 2 -Dichlorobenzene2 -Methylphenol2,2' -oxybis (1-Chloropropane)4 -MethylphenolN-Nitroso-di-n-propylamineHexachloroethaneNitrobenzeneIsophorone2 -Nitrophenol2 , 4 -Dimethylphenolbis (2-Chloroethoxy) methane2 , 4 -Dichlorophenol1,2,4 -TrichlorobenzerieNaphthalene4 -ChloroanilineHexachlorobutadiene4 -Chloro - 3 -methylphenol ____2 -MethylnaphthaleneHexachlorocyclopentadiene __2,4, 6 -Trichlorophenol2,4,5 -Trichlorophenol2 -Chloronaphthalene2 -NitroanilineDimethylphthalateAcenaphthylene2 , 6 -Dini trotoluene3 -NitroanilineAcenaphthene2 , 4 -Dinitrophenol4 -NitrophenolDibenzofuran2 , 4 -Dinitrotoiuene

RRF

1.3011.2371.1511.3541.3561.2500.9891.2960.9820.9040.5990.3580.7380.1980.2950.4570.3080.3330.9200.3380.2040.2860.5070.4450.4280.4631.1290.3541.3631.7080.3090.2400.9740.1480.1351.5340.400

RRF50

1.4841.4001.2601.4731.4671.3321.1341.6791.1521.0160.6510.4150.8340.2050.3200.5130.3310.3700.9980.4220.2250.3390.5660.4800.4440.5221.2100.4131.4371.8580.3350.3291.0810.1350.1481.6790.455

MINRRF

0.8000.7000.8000.6000.5000.4000.700

0.6000.5000.3000.2000.4000.1000.2000.3000.2000.2000.700

0.2000.400

0.2000.2000.800

0.9000.200

0.900

0.8000.200

%D_===_;===

14.113.29.58.88.26.6

14-7dUE17.312.48.7

15.913.03.58.5

12.27.511.18.524.810.318.511.67.93.7

12.77.216.75.4

. 8.8• ia.OS11.08.89.69.4

13.8

MAX%D

25.025.025.025.025.025.025. 01

25.025.025.025.025.025.025.025.025.025.025.0

25.025.0

25.025.025.0

25.025.0

25.0

25.025.0

All other compounds must meet a minimum RRF of 0.010.

CCXilccxzSCOO.BMS

FORM VII SV-1 OLM031

- 23274 CCX27 SPMPLE DPTP PPCKPGE R 344-9 6 k 263

^__

-- :. _ SEMIVOLATILE CONTINUING CALIBRATION CHECK

"Lab Name: COMPUCHEM ENV. CORP. .'"'' Contract: 68D50004.


Instrument" ID: OWA21 Calibration Date: 03/01/95 Time: 1052


• Init. Calib. Times: 1330 1559

COMPOUND=:====:== ===s========_s=======:zs

Diethylphthalate4 -Chlorophenyl -phenylether ___Fluorene4 -Nitroaniline4, 6 -Dini tro- 2 -methylphenol _N-nitrosodiphenylamine (1) __4 -Bromophenyl -phenyletherHexachlorobenzenePentachlorophenolPhenanthreneAnthraceneCarbazoleDi -n-butylphthalateFluoranthenePyreneButylbenzylphthalate3,3' -DichlorobenzidineBenzo (a) anthraceneChrysenebis (2-Ethylhexyl) phthalate _Di -n-octylphthalateBenzo (b) f luorantheneBenzo (k) f luorantheneBenzo (a) pyreneIndeno (1,2,3 -cd) pyreneDibenzo (a, h) anthraceneBenzo (q, h, i) perylene

Nitrobenzene-d5 .2 - FluorobiphenylTerphenyl - d!4Phenol -d52 - Fluorophenol2,4,6 -Tribromophenol2 -Chlorophenol -d41, 2-Dichlorobenzene-d4

RRF

1.4040.6241.0820.1660.1600.5080 . 2640.3320.1891.1171.0960.8441.6240.9821.4580.8110.1081.1971.0831.2441.8591.0991.1020.9791.2010.9821.025

0.3811.2311 . 04-91.2811.0070.1481.2020.841

RRF50======1.5280.7021.1990.2540.1440.5510.2790.3360.1541.1551.2031.0131.7371.2201.5550.8530.1961.3311.1671.2781.7921.1561.0861.0071.1940.9621.008

0.4361.3231.1101.4291.0040.1451.3000.913

MINRRF

-=rs==:s

0.4000.900

0.1000.1000.0500.7000.700

0 . 6000.600

0.8000.700

0.7000.7000.7000.5000.4000.500

0.2000.7000.5000.8000.600

0.8000.400

%D

8.812.510 ..8

10 !o8.55.71.218.53.49.820.07.024.26.65.2

11 ! 27.82.73.65.21.42.90.62.01.6

14.47.55.811.60.32.08.28.6

MAX%D

25.025.0

25.025.025.025.025.0

25.025.0

25.025.0

25.025.025.025.025.025.0

25.025.025.025.025.0

25.025.0

(1) Cannot be separated from Diphenyi .amineAll other compounds must meet a minimum RRF of 0.010.

FORM VII SV-2 OIM03.0

23274 ;CC; SPMPLE DPTP PPCKPG ^ 1 49 .&-§264





Lab File ID: HG950306C21 Init. Calib. Date(s): 02/27/95 02/27/95


COMPOUND==_===^=ss=s====:-:=s=;===_-::====r===ss

Phenolbis (2-Chloroethyl) ether _____2 -Chlorophenol1 , 3 -Dichlorobenzene1 , 4 -Dichlorobenzene1 , 2 -Dichlorobenzene2 -Methylphenol2,2' -oxybis ( 1 -Chloropropane )4 -MethylphenolN- Ni t roso - di - n - propy 1 amineHexachloroe thaneNitrobenzeneIsophorone2 -Nitrophenol2 , 4 -Dimethylphenolbis (2-Chloroethoxy) methane _2 , 4 -Dichlorophenol1,2,4 -TrichlorobenzeneNaphthalene4 -ChloroanilineHexachlorobutadiene4 -Chloro-3 -methylphenol2 -MethylnaphthaleneHexachlorocyclopentadiene2,4, 6 -Trichlorophenol2,4, 5 -Trichlorophenol2 -Chloronaphthalene2 -NitroanilineDimethylphthalateAcenaphthylene2 , 6 -Dini trotoluene3 -NitroanilineAcenaphthene2 , 4 -Dinitrophenbl4 -NitrophenolDibenzofuran2 , 4 -Dinitrotoluene

RRF======1.3011.2371.1511.3541.3561.2500.9891.2960.9820.9040.5990.3580.7380.1980.2950.4570.3080.3330.9200.3380.2040.2860.5070.4450.4280.4631.1290.3541.3631.7080.3090.2400.9740.1480.1351.5340.400

RRF50==_==:s=

1.5261.4591.3291.5021.4981.3951.1271.4601.2121.0790.6930.3980.8160.2050.3280.4850.2970.3291.0450.3540.1920.3100.5560.4190.3880.4551.1940.3691.4651.8780.3250.2401.0800.1450.1631.6390.405

MINRRF

0.8000.7000.8000.6000.5000.4000.700

0.6000.5000.3000.2000.4000.1000.2000.3000.2000.2000.700

0.2000.400

0.2000.2000.800

0.9000.200

0.900

0.8000.200

%D==;====

17.317.915.510.910.511.614.012.623.419.415.711.210.63.511.26.13.61.213.64.75.98.49.75.89.31.75.84.27.510.05.20.010.92.020.76.81.2

MAX%D

issrsss

25.025.025.025.025.025.025.0

25.025.025.025.025.025.025.025.025.025.025.0

25.025.0

25.025.025.0

25.025.0

25.0

25.025.0


FORM VII SV-1 OLM03

AR3U96623274 CCX27 SfWPLF DPTP POCKPGE ~ - 27l

""-:" - - • : - - 7C

-.-_, . SEMIVOLATILE. CONTINUING CALIBRATION CHECK

Lab Name: COMPUCHEM ENV. CORP. .... Contract: 68D50004

Lab Code: COMPU Case No. : 23274 SAS No. : SDG No. : CCX27


Lab File ID: 'HG950306C21 Init. Calib. Date(s) : 02/27/95 02/27/95

,-.-'..-.--- -•----• •••• .Init. Calib. Times: 1330 1559

COMPOUND

Diethylphthalate4 -Chlorophenyl -phenyletherFluorene4 -Nitroaniline4, 6-Dinitro-2-methylphenol _N-nitrosodiphenylamine ( 1 ) __4 -Bromophenyl -phenyletherHexachlorobenzenePentachlorophenolPhenanthreneAnthraceneCarbazoleDi-n-butylphthalateFluoranthenePyreneButylbenzylphthalate3,3' -DichlorobenzidineBenzo (a) anthraceneChrysenebis ( 2 -Ethylhexyl ) phthalate _Di-n-octylphthalateBenzo (b) f luorantheneBenzo (k) f luorantheneBenzo (a) pyreneIndeno ( 1 , 2 , 3 -cd) pyreneDibenzo (a, h) anthraceneBenzo ( g , h , i ) perylene

Nitrobenzene -d52 -FluorobiphenylTerphenyl - d!4Phenol -d52 -Fluorophenol2,4,6 -Tribromophenol2 - Chlorophenol - d41, 2-Dichlorobenzene-d4

RRF

1.4040.6241.0820.1660.1600.5080.2640.3320.1891.1171.0960.8441.6240.9821.4580.8110.1081.1971.0831.2441.8591.0991.1020.9791.2010.9821.025

0.3811.2311.0491.2811.0070.1481.2020.841

(1) Cannot be separated from Diphenyl

RRF50======1.5450.6621.2470.1890.1500.5420.244

' 0.3100.1551.1501.1780.7931.6671.0481.7700.8740.1681.3531.2071.2851.7441.1361.1721.0381.1160.9210.863

0.4191.3321.1911.4661.1750.1361.3680 . 887

MINRRF=====

0.4000.900

0.1000.1000.0500.7000.700

0.6000.600

0.8000.700

0.7000.7000.7000.5000.4000.500=====0.2000.7000.5000.8000.600

0.8000.400

%D======10.06.115.213.8,6.26.77.66.618.03.07.56.02.66.721.4

gs.'e.11.43.36. .23.46.46.07.16.215.8

10.08.213.514.416.78.113.85.5

MAX%D

25.025.0

25.025.025.025.025.0

25.025.0

)25.025.0

25.025.025.025.025.025.0

25.025.025.025.025.0

25.025.0

amineAll other compounds must meet a minimum RRF of 0.010.

FORM VII SV-2 OIM03.0

23274 CCX27 SPMPLE DPTPAR3U967




Instrument ID: OWA21 Calibration Date: 03/06/95' Time: 1425



COMPOUND

Phenolbis (2-Chloroethyl) ether2 -Chlorophenol1 , 3 -Dichlorobenzene1 , 4 -Dichlorobenzene1 , 2 -Dichlorobenzene2 -Methylphenol2,2' -oxybis (1-Chloropropane)4 -MethylphenolN-Nitroso-di-n-propylamineHexachloroethaneNitrobenzeneIsophorone2 -Nitrophenol2 , 4 -Dimethylphenolbis (2-Chloroethoxy) methane2 , 4 -Dichlorophenol1,2,4 -TrichlorobenzeneNaphthalene4 -ChloroanilineHexachlorobutadiene4 -Chloro-3 -methylphenol ____2 -MethylnaphthaleneHexachlorocyclopentadiene2,4, 6 -Trichlorophenol2,4, 5 -Trichlorophenol2 -Chloronaphthalene2 -NitroanilineDimethylphthalateAcenaphthylene2 , 6 -Dini trotoluene3 -NitroanilineAcenaphthene2 , 4 -Dinitrophenol4 -NitrophenolDibenzofuran2 , 4 -Dinitrotoluene

RRF

1.3011.2371.1511.3541.3561.2500.9891.2960.9820.9040.5990.3580.7380.1980.2950.4570.3080.3330.9200.3380.2040.2860.5070.4450.4280.4631.1290.3541.3631.7080.3090.2400.9740.1480.1351.5340.400

RRF50= -5 = = = -=

1.4881.2901.2491.4521.4751.3481.0141.2321.0860.9540.6360.3600.7660.1950.3300.4470.3160.3561.0110.3330.2090.2970.5510.4250.4180.4651.1400.3141.3551.7390.2920.2271.0470.1640.1651.569,0.389

MINRRF===35=

0.8000.7000.8000.6000.5000.4000.700

0.6000.5000.3000.2000.4000.1000.2000.3000.2000.2000.700

0.2000.400

0.2000.2000.800

0.9000.200

0.900

0.8000.200

%D======

14.44.38.57.28.87'. 82.54.910.65.56.20.63.81.511.92.22.66.99.91.52.43.88.74.52.30.41.011.30.61.85.55.47.510.822.22.32.8

MAX%D

25.025.025.025.025.025.025.0

25.025.025.025.025.025.025.025.025.025.025.0

25.025.0

25.025.025.0

25.025.0

25.0

25.025.0

CCX3oCCX3I


FORM VII SV-1 OLM03

23274 CCX27 SPMPLE DPTP PPCKPGE 279

.-,-,__ ...,,...,. .7C-: • . • ,:T-V. ., -•- SEMIVOLATILE CONTINUING CALIBRATION CHECK ™*



Instrument" "ID: OWA21 . Calibration Date: 03/06/95 Time: 1425

Lab File ID: HG950306A21 Init. Calib. Date (s)-: 02/27/95 . 02/27/95

• ...... .__._- Init. Calib. Times: 1330 1559

COMPOUND

Diethylphthalate4 -Chlorophenyl -phenylether _Fluorene4 -Nitroaniline4, 6-Dinitro-2 -methylphenol _N-nitrosodiphenylamine (1) __4 -Bromophenyl -phenylether ____Hexachlorobenz enePentachlorophenolPhenanthreneAnthraceneCarbazoleDi-n-butylphthalateFluoranthenePyreneButylbenzylphthalate3,3' -DichlorobenzidineBenzo (a) anthraceneChrysenebis (2-Ethyihexyl) phthalate _Di -n-octylphthalateBenzo (b) f luorantheneBenzo (k) f luorantheneBenzo (a) pyreneIndeno (1,2,3 -cd) pyreneDibenzo (a, h) anthraceneBenzo (q, h, i) perylene============================Nitrobenzene-d5 •2 - FluorobiphenylTerphenyl -d!4Phenol -d52 -Fluorophenol2,4, 6-Tribromophenol2 - Chlorophenol - d41 , 2 -Dichlorobenzene -d4

RRF

1.4040.6241.0820.1660.1600.5080.2640.3320.1891.1171.0960.8441.6240.9821.4580.8110.1081.1971.0831.2441.8591.0991.1020.9791.2010.9821.025

0.3811.2311.0491.2811.0070.1481.2020.841

(1) Cannot be separated from Dipheny]All other compounds must meet a mir

RRF50

1.4420.6501.2100.2210.1580.4430.2560.3100.1771.1361.1720.7521.5501.1311.609Q.731£9.032,1.2281.1801.0861.7681.1541.1741.0121.1870.9860.986======

0.3861.3591.1131.3431.1240.1441.2870.915

MINRRF

0.4000.900

0.1000.1000.0500.7000.700

0.6000.600

0.8000.700

0.7000.7000.7000.5000.4000.500

0.2000.7000.5000.8000.600

0.8000.400

%D

2.74.2

11.8

1.212.83.06.66.31.76.9

10.94.6

15.210.4/-170.4)2.69.0

12.74.95.06.53.41.20.43.8

1.310.46.14.8

11.62.77.18.8

MAX%D

25.025.0

25.025.025.025.025.0

25.025.0

25.025.0

25.025.025.025.025.025.0

25.025.025.025.025.0

25.025.0

.aminelimum RRF of 0.010.

FORM VII SV-2 OLM03.0

23274 CCX27 SPMPLE DPTP PPCKPGE & R 3 \ k B 6 9 2SQ

COMPUCHEMENVIRONMENTALCORPORATION

SDG NARRATIVECASE NUMBER: 23274SDG NUMBER: CCX27

SDG NUMBER: 68D50004

SAMPLE IDENTIFICATIONS: CCX27, CCX28, CCX29, CCX30, CCX31

The five (5) soil samples listed above were received intact,properly refrigerated, with proper documentation, in a sealedshipping container, on February 23, 1995. The samples werescheduled for the requested analyses of the semivolatile and thepesticide/PCB fractions. These samples were analyzed followingdocument OLM03.1 protocol. The pH values of these soil samplesranged from 5.8 to 6.6, and the percent moisture values variedfrom 35 to'71 . Each of the samples in this SDG was received ata temperature of 4 degrees Celsius. No U.S. EPA CoolerTemperature Indicator was received with these samples. Thisportion of the SDG narrative deals with the semi-volatilefraction only.

All pertinent Quality Assurance notices are included innarrative section, and all pertinent Laboratory notices forNumber 23274, SDG Number CCX27 are included in the sample datasections.

8EMI-VQIATILE8

Extraction and analysis holding time requirements were met forall of these samples. There were no semivolatile target compoundlist (TCL) analytes identified above the contract requiredquantitation limit (CRQL) in any of these samples. Tentativelyidentified compounds (TICs) were found in all of these samples.Some of the TICs could be characterized as hydrocarbons,polyaromatic hydrocarbons (PAH), aldol condensation products, andunknowns. Some of the other TICs were assessed as laboratoryartifacts and blank contaminants, and therefore may not be sampleconstituents.

When the operator performs manual integrations and/or manualedits for the TCL analytes, these manual integrations or editsare indicated by the "M", "HM, or the "MH" flag present on thequantitation report. An extracted ion current profile (EICP)will be provided for each analyte requiring a manual integrationor a manual edit. Additionally, the quantitation reports willindicate the reason for the integrations or edits based on thefollowing: 1) TCL analytes were initially not found byautomatic integration routine, 2) TCL analytes were incorrectintegrated by the automatic integration routine, 3).the

fl p o j L Q 7 Q23274 CCX27 SPMPLE DPTP PPCKPGE 3


selected an alternate peak within the retention time window for aparticular TCL analyte than that chosen by the computer software.The explanations for the manual integrations and/or manual editsare summarized in a quality assurance notice which is located inthe narrative section of the data package.

All of the surrogates met recovery criteria in the analyses ofthese samples. All of the internal standards met response andretention time criteria in the analyses of these samples. Theassociated method blanks met all quality control criteria . Themethod blanks did not contain any TCL analytes. TICs were foundin both of the associated semi-volatile method blanks. CCX28 wasused as the original sample to prepare the duplicate matrixspikes as requested. The associated duplicate matrix spikes metall advisory accuracy and precision criteria.

I certify that this data package is in compliance with the termsand conditions of the contract „ both technically and forcompleteness, for other than conditions detailed above. Releaseof the data contained in the hardcopy data package and in thecomputer-readable data submitted on diskette has been authorizedby the Laboratory Manager or his designee, as verified by thefollowing signature.

(Ln 31 ICjfnthia E. EdwardsTechnical ReviewerMarch 10, 1995

2 23274 CCX27 SEMI-VOLATILE FRACTION23274 CCX27 SPMPLE OPTP PPCKPGE A R 3 [ U 9 7 | 4


Sample Identifications: CCX27, CCX28, CCX20, CCX3G, CCX31

Tnis portion cf the COG narrative addresses the pesticide/PCBtraction only. "or ti^e receiving information associated with these~=~i~..—~, P_L£SS£ ireier to tue semivolatixe L>CG nsrrutive.

All pertinent Quality Assurance notices are included -in thenarrcitive section, 2nd all pertinent LiSuoratory notices tor Case•?->T7o "^n r-^v-?-? i--~ :~-" 'i sd. in the sample clata sections.£. ~J £, l i -iLJ\J .S L . / dJL ti .L J 1 .1. i—.*»

samples. There were no pesticide TCL analytcs confirmed by dualabOVG tuS CRQL in tn£3£ 3Smp-LG3.

All advisory surrogate recovery criteria were met. The associatedmethod blank mat all quality control criteria. "o TCL analytes werefound in. the method blank.

CCX28 was used as the original to prepare the duplicate matrixspikes. The associated duplicate matrix spikes met all advisoryaccuracy and precision criusria.

.-*._• **^»— 1«^.M i^^lwj_ rij. OC J.U/J- "~ J. &. z* J-AR12213Q, tuS opsrator psrtormsd manuaj. inuagrQtions and/'c™ medits. Thesa manual integrations or edits are indicated by an "M"flag. Extracted Ion Currant Profiles (EICPs) have bean provided forthe analyte requiring manual integration. These manual edits and/ormanual integrations were required because one or more peaks for aHtulticcmponent analyte were not found by the automatic integrationroutine .

I certify that this data package is in compliance with the terms andconditions of the contract, both technically and for completeness,for other than conditions detailed above. Release of the datacontained in the hardcopy data package and in the computer-readabledata submitted on diskette has been authorized by the Laboratory{Manager or his dasignee, as verified by the following signature.

5ean M. immermanFinal Technical ReviewerFebruary 10, 1995

23274 CCX27 SPMPLE DPTP PPCKPGEAR3U972

(conJU—__DATA REPORTING OUALI

Goncencraaon flaggea with an E on Form I for the original analysis. If thedilution of the extract causes any compounds identified in the first analysis tobe below the calibration range in the second analysis, then the results of bothanalyses shall be reported on separate copies of Form i. The Form I for thediluted sample shall have the DL suffix appended to the sample number.

D - This flag is used for all compounds identified in an analysis at a secondarydilution factor, If a sample or extract is reanalyzed at a higher dilution factor.as in the E flag, the DL suffix is appended to the sample number on Form I forthe diluted sample, .and ail concentration values reported on that Form I areflagged with the D flag. This flag alerts data users that any discrepanciesbetween the reported concentrations may be due to dilution of the sample or.extract.; " " - • • " ' . . ' " " • " • • • •

A; - This flag indicates that a tentatively identified compound is a suspectedaidol-condensaaon product,

X - Other specific flags may be required to properly define the results. If used, theflags shall be fully described, with the description attached to the sample datasummary package and the SDG Narrative. Begin by using X. If more than oneflag is required, use Y and Z as needed. If more than five qualifiers arerequired for a sample result, use the X flag to represent a combination ofseveral flags. For instance, the X flag might combine the A. B. and D flags forsome samples. The laboratory-defined flags are limited to X. V. and Z.

23274 CCX27 SPMPLE OPTP PPCKPGE $R3 1 973

Carat!C!*.ga* g Paerirarigr; C3-ver.-i.~

Conpucaam. has purchased a high, speed machine which provides forpagination in ascending. order.In the event that the paginating; machine inadvertently skips page**,numbers pages twice, or otherwise- contributes to a breach in thsconsecutive numbering- ol data, it is CempnChem's policy to addLan.alphabetic suffix to a page number vh*tt nseatssary (e.g., 100 &„100 S, etc. > . T&is poiisy has. b«*n approved by nn ESA.

As srarad in rns organic and inorganic, starsmsnr cf Worjc (SOW)table vnicb praseirss tns- contract. Reports/ Deliverable*Distriiutisn. Sample Data Pacxages and tie compiate SOS File (CST)are required to ae delivered vitbin tbe contract, requiredturnaround time. Ttxe original. Sample Data Pacxago* asma final tacbmcal. review is performed f and tb» paexagespaginnted and copied: on* copy is gene te

and anoi-i-ar is sent to. e^meWB-t*- TheSaaple Data Pacxage then beeoneus parr of the CSF, wbicJi is saafr-totbs. EPA Region-Ciiant. (Tacnnical Prcrjecr Officer) .FOTB DC-2 presents an inventory of tba». contents of tne csr, ..including tna- pagei nuabes; locations, for tb» indexed items. Tfisreeare cencurrantr delivery requirements for t_ast Sasple. Data Paexmgescand the CSF. Because- of tbis and the tim«r required for tHe. finaltse&nical review process-* v* have- instituted a policy to expediteaesemnly of tiie CST. I tarns 2-€ on tne. organic Fezs DC-2 and. item*.2-26 on tn» Inortranic Fors CC-2 contain. t&osiE itsms; wnicii arm partof the SU-pie Oats: Pacxages, T&os* iteas will b« paginated in.ascending order. However, v&ile sazsple Data Pacjeages receive- afinal technical, review , iteauc. 7-10 on the organic Form DC-2 and.itssw 27-32 on: t&» Inorganic. Fora DC-2 will be, asseabled andpeginatedv, * T&st first, peg* number for* th» f irsr entry for itsm 7 onth» organic Forrr DC-2 and for item. 27 on the Inorganic Form DC-2will always, begin with, page number 10,0.00..

AR3U97Uparts-one- ••••-•————

9*7-*b

In Reference to case No(s):23274

—03941004—————JContract Laboratory Progr_REGIONAL/LABORATORY COMMUNICATION SYSTEM

Telephone Record LogDate of Call: ________February 23.

Laboratory Name: ____ COMPU. Richard Bloom

Contact:Region: _____________ III

Regional Contact: —— J. Snvdar. ESAT/S. wilding. EPA _________

Call Initiated by: ___ Laboratory ___ _ Region x SMOla reference to data for the following sample number (s):CCX32, aqueous sample

Summery of Queetioaa/Iseuee Discussed*Sample CCX32 was listed on the TR/COC ae a sediment but it is anaqueous sample. Also, only two eight ounce containers- of samplevolume were received. How shall the lab proceed?summary of ResolutionsThe sampler states that the TR/COC is in error. CCX32 is a fieldblank and should have been listed as "#4, Field QC**. The samplerwill write a memo to file to correct the error, since CCX32 is afield QC sample, the Region requests that analysis not be performedon this sample due to lack of volume. The lab should nota theproblem and its resolution in the case narrative and include a copyof this phone log in its data package.

(Affiliation) Date

gnature (Afflition) DateDistribution: (1) Lab Copy, (2) Region Copy,(4) site (5) trouble (6) pending (7)RPM-Chris Corbatt, 3HW24(8) requestor-Trish Armstrong, Brown & Root (Haliburton Nus)(9)RPO-Joe Trailie, 3HW43

AR3U975

Contact ajhone DFaxName: ^ HHBIHHMl- Recv>dVla: QVMail Q Memo Q Other__

-,Date/Time of Contact; 7- -HS / /<f<py—— Initiated By: Q Region Q Other

Contact Name/OrgJPhone #: KXC kj-U i. SlOowi I CflMPvH />t«.\ t/ofr'.

Lab 0-OiM<M Contract f brboo Case # IVL SOQ Region

SOW: _____ Affected Samples: _ ____ __ . . > . ____ Invoice #

Resolution:

0^0.

- az.-gAAA —

RAS OPS /Q Yes . /i\ ARouted a No Referred To __________Date/Tlrne——————WA i jJlrJ&L

Distribution: (1) Lab, (2) Region, (3) CLASS (4) AOB

l1~Kl_ _ D

CLASS is op«rattd by HUundw Contract 164-044104 to the US. Environmental Protection Agency

AR3U978

lOA EPA SAMPLE NO.PESTICIDE IDENTIFICATION SUMMARY ___________FOR SINGLE COMPONENT ANALYTES

CCX27Lab Name;COMPUCHEM ENV. CORP. Contract;68D500Q4


Lab Sample ID : 686674 Date(s) Analyzed: 03/06/95 03/06/95

Instrument ID (1): VARIAN08 Instrument ID (2): VARIAN09

GC Column(1): DB-608 ID; 0.53(mm) GC Column(2): RTX-1701 ID: 0.53(mm)

ANALYTE

4.4' -DDE

4. 4 '-ODD

4.4' -DOT

Endosulfan sulfate

'-._---

.

COL

1

2

1

2

1

2

1

2

1

2

1

2

1

2

1

2

RT

19.47

15.39

21.72

18.36.

22.94

18.90

23.69

21.16

RT W]FROM

19.36

15.25

21.65

18.25

22.85

18.78

23.64

21.03

ENDOW. TO

19.50

15.39

21.79

18.39

22.99

18.92

23.78

21.17

•

CONCENTRATION

0.20

0.27

0.37

0.14

0.33

0.42

0.69

0.30/

%D

( 3£JL

A 64. 3s .— -

(•21 .3

'"130.0*x~.s _

page I of 1__ FORM X PEST-1 OLM03.0

- ™. 23274 CCX27 SPMPLE DPTP PPCKPG&3 \k 91 9 485

10A EPA SAMPLE NO.PESTICIDE IDENTIFICATION SUMMARYFOR SINGLE COMPONENT ANALYTES

Lab Name:COMPUCHEM ENV. CORP. Contract;68D50004CCX28



Instrument ID (1): VARIAN09 Instrument'ID (2): VARIAN08

GC Column(l): RTX-1701 ID: 0.53(mm) GC Column(2): DB-608 ID: 0.53(mm)

ANALYTE

Aldrin

4r4' -DDE

4 f 4 ' -DDD

4r4' -DOT

Endosulfan sulfate

COL

1

2

1

2

1

2

1

2

1

2

1

2

1

2

1

2

RT

10.82

14.65

15.38

19.48

18.36

21.75

18.90

22.95

21.07

23.69

RT W3FROM

10.78

14.55

15.25

19.36

18.25

21.65

18.78

22.85

21.03

23.64

:NDOWTO

10.88

14.65

15.39

19.50

18.39

21.79

18.92

22.99

21.17

23.78

CONCENTRATION

0.48

0.66

1.0

1.8

0.89

0.79

0.41

0.82^

0.30

0.52

%D

( 37.5

'a o.o'

12.7

f"ioo.o

( 73 3

page i ofFORM X PEST-1 OLM03.0

23274 CCX27 SPMPLE DPTP PPCKPGE^"^ <f 4S6

rt- 10A EPA SAMPLE NO.PESTICIDE IDENTIFICATION SUMMARY ________________FOR SINGLE COMPONENT ANALYTES

CCX29Lab Name;COMPUCHEM ENV. CORP. Contract;68D50004


Lab Sample ID : 686682 Date(s) Analyzed: 03/06/95 03706/95


GC Column(1); DB-608 ID: 0.53(mm) GC Column(2): RTX-1701 ID: 0.53(mm)

ANALYTE

Aldrin

4.4' -ODD

Endrin aldehyde

Endosulfan sulfate

" • ' -

. " "". - -

t

• .

COL

1

2

1

2

1

2

1

2

1

2

1

2

1

2

1

2.

RT

14.64

10.81

21.74

18.36

23.16

19.84

23.68

21.16

RT W]FROM

14.55

10.78

21.65

18.25

23.13

19.80

23.64

21.03

-

ENDOWTO

14.65

10.88

21.79

18.39

23.27

19.94

23.78

21.17

CONCENTRATION

0.45

1.1

0.84

0.71

0.81

0.69

1.0

1.4

%D

(144.4

18.3

17.4

pa.ge I of IFORM X PEST-1 OLM03.0

23274 CCX27 SPMPLE DPTP PPCKPGE-* I 4Q7


CCX30Lab Name ; COMPUGHEM ENV. -"CORP. Contract; 68D50Q04



Instrument ID (1) : VARIAN08 Instrument ID (2): yARIAN09

GC Column (1) : DB-608 ID: 0.53 (mm) GC Column (2) : RTX-1701 ID: Q . 5_3 (mm)

ANALYTE

4. 4 '-DDE

4,4' -ODD

4. 4 '-DOT •

•

COL

1

2

1

2

1

2

1

2

1

2

1

2

1

2

1

2

RT

19.47

15.38

21.75

18.36

22.94

18.90

RT W]FROM

19.36

15.25

21.65

18.25

22.85

18.78

:NDOWTO

======

19.50

15.39

21.79

18.39

22.99

18.92

CONCENTRATIONSSSSISSSSSSSSS

0.15

0.25

0.25

0.30

0.23

0.42

%D3S33S3

(66.7•-•>• . •:

20.0

(82.6

<page 1 of

FORM X PEST-1 OLM03.0

I

23274 CCX27 SPMPLE OPTP PPCKPGE ^ 98 2

10A EPA SAMPLE NO.PESTICIDE IDENTIFICATION SUMMARY _____________FOR SINGLE COMPONENT ANALYTES

CCX31Lab Name;COMPUCHEM ENV. CORP. "' Contract;68D50004




GC Column(1): RTX-1701 ID: 0.53(mm) GC Column(2): DB-608 ID: 0.53(mm)

ANALYTE

Endosulfan sulfate

• ' -

- ' :--•--

. _ . .

...:. ....-.-. . . . '-.:

. .

COL

1

2

1

2

1

2

1

2

1

2

1

2

1

2

1

2

RT

21.16

23.68

RT W]FROM

21.03

23.64

ENDOW •TO

======

21.17

23.78

CONCENTRATION

0.35

0.51

%D

(J15.7

page 1, of 1.- ;.,,,,; FORM X PEST-1 OLM03.0

~-——-23274 CCX27 SPMPLE DPTP PPCKPGE 'A R '3 i W 8 3 489


CCX28MSLab Name:COMPUCHEM ENV. CORP. Contract:68D50004



Instrument ID (1) : VARIANO8 Instrument ID (2): VARIANO9

GC Column(1): DB-608 ID: 0.53(mm) GC Column(2): RTX-1701 ID: Q.53(mm)

ANALYTE

cramma-BHC (Lindane)

Heptachlor

Aldrin

4.4' -DDE

Dieldrin

Endrin

4. 4 '-ODD '

4,4' -DOT•

COL

1

2

1

2

1

2

1

2

1

2

1

2

1

2

1

2

RT

•12.01

9.38

13.31

9.99

14.64

10.87

19.47

15.37

19.66

15.70

21.14

16.44

21.72

18.35

22.94

18.89

RT W]FROM .

11.94

9.31

13.23

9.91

14.55

10.78

19.36

15.25

19.57

15.60

21.04

16.33

21.65

18.25

22.85

18.78

:NDOWTO

12.04

9.41

13.33

10.01

14.65

10.88

19.50

15.39

19.71

15.74

21.18

16.47

21.79

18.39

22.99

18.92

CONCENTRATION

26

26

27

28

22

24

0.80

1.4

58

59

55

58

1.7

0.96

59

57

%D

0.0

J1.7

5.5

J— *•*page 1 of 2_

FORM X PEST-1 OLM03.0

_ —_ 23274 CCX27-SPMPLE DPTP PPCKPGE


Lab Name:COMPUCHEM ENV. CORP. Contract:68D5QQQ4CCX28MS


Lab Sample ID : 686678 "" Date(s) Analyzed: 03/06/95 03/06/95

Instrument ID (1) : VARIAN08 Instrument ID (2) : VARIANQ9

GC Column(1): DB-608 ID: 0.53(mm) .GC Column(2): RTX-1701 ID: 0.53(mm)

ANALYTE:: = = = = = = = =: = = = = = = = = = = = = = = = = = =

Endrin ketone

... . _,----- -- ..--.- .

.

COL===

1

2

1

2

1

2

1

2

1

2

1

2

1

2

1

2

RT

26.78

22.43

RT w:FROM .

======

26.67

22:30

:NDOWTO

26.81

22.44

CONCENTRATION

1.6

1.1

i

%D

<^45. 5^— ==

-

page 2. of 2.FORM X PEST-1 OLM03.0

23274 CCX27~SPMPLEOPTP PPCKPGE&&3 I' 1*48 5 491


Lab Name:COMPUCHEM ENV. CORP. Contract:68D50004CCX28MSD




GC Column(1): DB-608 ID: 0.53(mm) GC Column(2): RTX-1701 ID: 0.53(mm)

ANALYTE

gamma -BHC (Lindane)

Heptachlor

Aldrin

4f4' -DDE

Dieldrin

Endrin

4. 4 '-ODD

4. 4 '-DOT

,

COL

1

2

1

2

1

2

1

2

1

2

1

2

1

2

1

2

RT

12.02

9.38

13.32

9.99

14.64

10.87

19.46

15.36

19.66

15.70

21.14

16.43

21.74

18.34

22.93

18.88

RT WIFROM

11.94

9.31

13.23

9.91

14.55

10.78

19.36

15.25

19.57

15.60

21.04

•16.33

21.65

18.25

22.85

18.78

:NDOWTO

12.04

9.41

13.33

10.01

14.65

10.88

19.50

15.39

19.71

15.74

21.18

16.47

21.79

18.39

22.99

18.92

CONCENTRATION

27

28

29

29

22

24

0.88

1.7

59

61

56

59

1.3

1.3

60

58

%D

3.7

i9.1

C93.2

3.4

5.4

0.0

J__i^

»

page I of 1FORM X PEST-1 OLM03.0

— ——— 23274 CCX27 SPMPLE DPTP PPCKPGE &&$ i MJ86 49;

:r\2 10A EPA SAMPLE NO.PESTICIDE IDENTIFICATION.SUMMARY _______FOR SINGLE COMPONENT ANALYTES

Lab Name : COMPUCHEM ENV ."'"CORP. Contract; 68D5QOQ4CCX28MSD

Lab Code: COMPU Case No. : 23274 SAS No. : SDG No. :_ CCX27


Instrument: ID (1) : VARIAN08 . Instrument ID (2) : VARIAN09

GC Column(1): DB-608 ID: 0.53(mm) GC Column(2): RTX-1701 ID: 0.53(mm)

ANALYTE

Endosulfan sulfate

Methoxychlor

Sndrin ketone

-----

• .-----,- . •' "-•-

'•

COL

1

2

1

2

1

2

1

2

1

2

1

2

1

2

1

2

RT

23.68

21.15

26.51

21.34

26.78

22.42

RT W3FROM

23.64

21.03

26.43

21.24

26.67

22.30

ENDOWTO

= s: = := si =:

23.78

21.17

26.57

21.38

26.81

22.44

CONCENTRATION=============

0.54

0.79

16

12

1.2

1.2

%D

/ 46.3i

(33.3

0.0

pa.ge 2. of 2.FORM X PEST-1 OLM03.0

23274 CCX27 SPMPLE DPTP PPCKPGE AR3 i 98/493

IB EPA SAMPLE NO.SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET

Lab Name: COMPUCHEM ENV. CORP. Contract: 68D50004CCX28MS

Lab Code:-COMPU Case No.: 23274 SAS No.: SDG No.: CCX27


Sample wt/vol: 30.4 (g/mL) g Lab File ID: GJOS6675B21






CONCENTRATION UNITS:CAS NO. COMPOUND (ug/L or .ug/Kg) ug/Kg Q

i n Q oc o111-44-4----QC C"7 Q

CAI -7*3 -i ----106-46-7 ———95-50-1 ————QC /tQ 1

108-60-1----1 nfi_44.-q____621-64-7----G.1 -T5 -~\ _ _ _ _ _QQ QC n _

78-59-1-----DO •— C C

105-67-9- ——111-91-1----i on QI oi on QO i91-20-3 ————T nC-A"? Q _ _ _ _iUO "t / -o — — — —0*7 £TQ '"3

C Q C A •—

QI CT £

77-47-4.-----Qo nc oQC QC A

QI CO T

QQ "/A A

131-11-3 ———OHQ-QC Q

606-20-2 ———Qo_na oOO TO Q

- — -Phenol----bis (2-Chloroethyl) ether _______- - — 2 - Chlorophenol----1,3 -Dichlorobenzene----1,4 -Dichlorobenzene

- - - - 2 -Methylphenol----2,2' -oxybis (1-cHloropropane)- - - -4 -Methylphenol- - - -N-Nitroso-di-n-propylamine _

- - - - Isophorone—— - 2 -Nitrophenol----2,4 -Dimethylphenol-__-bis(2- Chloroe thoxy ) methane—— 2,4 -Dichlorophenol •— -1,2,4 -Trichlorobenzene

— --4-Chloroaniline- - - -Hexachlorobutadiene-_--4-Chloro-3 -methylphenol ____

_ _ _ -Hexachlorocyclopentactiene—— 2 , 4 , 6 -Trichlorophenol—— 2,4,5 -Trichlorophenol- - - - 2 - Chloronapht halene- - - - 2 -Nitroaniline— - -Dimethylphthalate—— Acenaphthylene—— 2 , 6 -Dinitrotoluene—— 3 -Nitroaniline- - - -Acenaphthene

50008104600810

310081081081081036008108108108108108108103200810810810

51008108108102000810200081081081020003000

U

U

uuuuuuuuuuuuuuuuuuuuuuuu

FORM I SV-1 OIM>3.0

KQTQ PPrtfORF " .T.T.T

1C EPA SAMPLE NO.SEMIVOLATILE ORGANICS"ANALYSIS DATA SHEET

Lab Name: COMPUCHEM ENV. CORP. ~"~ Contract: 68D50004CCX28MS



Sample wt/vol: 30.4 (g/mL) g Lab File ID: GJ086675B21



Concentrated "Extract Volume: 500(uL) Date Analyzed: 03/01/95



CONCENTRATION UNITS:CAS NO. COMPOUND (ug/L or ug/Kg) ug/Kg Q'

C 1 *"> O C5 1 - 2 8 - D - - - - -100-02-7- ——132-64-9----

84-66-2-----7005-72-3---O C T3 —/

100-01-6----

86-30-6 ————101-55-3----118-74-1----o~. i Q /r c _O CT r\ 1 Q85-01-8-----120-12-7----QC_7A_Q_____

84-74-2------206-44-0----129-00-0-----QC <rn_'7_____.91-94-1 ———— -56-55-3 ———— -218-01-9 ——— •117-81-7 ——— •IT'7 QA- H — — — — -

205-99-2 ——— -ft \J 1 \J O 3c r\ o o o50-32-8------193-39-5- —— -c — f TA o53-70-.3------1 QI _OA_O___-.

----2,4 -Dini trophenol- - - -4 -Nitrophenol- - - -Dibenzofuran----2,4 -Dini trotoluene- - — Diethylphthalate- — 4 -Chlorophenyl -phenylether _

T?T ii^Y*ono

- - - -4 -Nitroaniline----4, 6-Dinitro-2-methylphenol _- - - -N-nitrosodiphenylamine_ ( 1 ) _- - - -4 -Bromophenyl -phenylether __- - - -Hexachlorobenzene- - - - Pentachlorophenol

- - - -Di-n-butylphthalate- - - -Fluoranthene

- *• - -Butylbenzylphthalate—— 3,3' -Dichlorobenzidine• — -Benzo (a) anthracene- - - -Chrysene- — bis ( 2 -Ethylhexyl ) phthalate _• - — Di-n-octylphthalate- —— Benzo (b) f luoranthene- - - -Benzo (k) f luoranthene- - - -Benzo (a) pyrene- — -Indeno (1, 2, 3-cd) pyrene- - - -Dibenzo (a , h) anthracene•---Benzo (g,h, i)perylene

2000' 540081034008108108102000200081081081057008108108103008103200810810810810810810810810810810.810810

U

U

uuuuuuuuuuuJuuuuuuuuuuuuu


' ' . FORM I SV-2 .OIM03.0

23274 CCX27 SPMPLE DPTP PPCKPGE $R3ik9 8 9 334


CCX28MSDLab Name: COMPUCHEM ENV. CORP. Contract: 68D50004

Lab Code: COMPU Case No.: 23274 SAS No.: SDG No.: tCCX27


Sample wt/vol: 30.3 (g/mL) g Lab File ID: ' GH086676A21


% Moisture: 60 decanted: (Y/N) N .Date Extracted:02/28/95





1 AQ QC O

111-44-4----QC C*7 Q

541-73-1-----106-46-7 ——— -95-50-1------95-48-7- ——— -108-60-1-----106-44-5 ——— •621-64-7 ——— •^ T "70 167-72-1------98-95-3 —— --•78-59-1------O O *-7C C

1 AC £7 Q _

111-91-1 ——— •1 "5 (\ Q "_! "3

120-82-1-----Ql _OA--5_____.J _. £t W J

106-47-8 —— --Q-/ CQ •a59-50-7-- —— •QI _C'7_C_____.

77-47-4 ———— •88-06-2 ———— •95-95-4 ———— •QT CO r/

po_74._4_____.131-11-3 —— -•OAQ Q£? Q

606-20-2 ——— -QQ_0<3_?_-----Q-a_-3O_Q_____.

----Phenol- - - -bis ( 2 -Chloroethyl ) ether ______- - - - 2 - Chlorophenol

1O —F^i /-*Vil f"\y*oVvaT *?* f^n o

- — -1,4 -Dichlorobenzene- - — 1,2 -Dichlorobenzene- - - - 2 -Methylphenol----2,2' -oxybis ( 1 -Chloropropane )- - - -4 -Methylphenol- - - -N-Nitroso-di-n-propylamine _- - — Hexachloroethane- - - -Nitrobenzene- - - - I sophorone- - - - 2 -Nitrophenol----2,4 -Dime thy Iphenol- - - -bis ( 2 -Chloroethoxy ) methane _----2,4 -Dichlorophenol

. _ _ -Naphthalene

. _ _ _4 -chloroanilliie- — -Hexachlorobutadiene• - — 4 -Chloro- 3 -methylphenol• — 2 -Me thylnapht halene- - - -HexachlorocyclopentadZene----2,4,6 -Trichlorophenol- —— 2,4,5- Trichlorophenol- - - -2 -Chloronaphthalene- — -2 -Nitroaniline• - - -Dimethylphtnalate• — Acenaphthylene----2, 6-Dinitrotoluene' - - -3 -Nitroaniline- - - -Acenaphthene

4800820450082030008208208208203500820820820820820820820290082082082044008208208202000820200082082082020002600

U

U

uuuuuuuuuuuuuuuuuuuuuuuu

FORM I SV-1 OLMO

\3274 CCX27 SPMPLE OPTP PPCKPGE A R3 I 1*9 90 343

1C "' ' EPA SAMPLE NOSEMIVOLATILE ORGANICS ANALYSIS DATA SHEET

Lab Name: COMPUCHEM ENV. CORP;. ." Contract: 68D50004CCX28MSD



Sample wt/vol: ___ 30.3 (g/mL) g Lab File ID: GH086676A21





GPC Cleanup: JY/N) Y pH: 6.1

--'..- CONCENTRATION UNITS:CAS NO. COMPOUND ' (ug/L or ug/Kg) ug/Kg Q

C1 O Q Cbl-28-b-----100-02-7 ———132-64-9 ———

84-66-2- ———7005-72-3 ——f\ f* ntf* m86-73-7-----100-01-6 ———534-52-1----*J J L -J £* -!•

86-30-6 ————101-55-3 ———118-74-1- ——Q7 Q C C

o c r\ i o85-01-8-----120-12-7 ——— •Q£ 7 A. Q _ _ _ — — .

84-74-2-- —— •206-44-0 ——— •129-00-0- —— •p.c,_<ro_-7_____.91-94-1 ———— •56-55-3 ———— ••51 o_ni _Q____.117-81-7 ——— •117-84-0 ——— •205-99-2 ——— ••5A"7_AQ_Q — _ — -.en -ao Q193-39-5 ——— -53-70-3 ———— •1 QI -OA-O----.

----2,4 -Dinitrophenol- - - -4 -Nitrophenol- - - -Dibenzofuran- - - -2 , 4 -Dinitrotoluene—— Diethylphthalate- - - -4 -Chlorophenyl -phenylether _-- — Fluorene- — -4 -Nitroaniline----4 , 6 -Dinitro- 2 -methylphenol _

----4-Bromophenyl-phenylether- - - -Hexachlorobenzene- - - - Pentachlorophenol- - - - Phenanthrene

- - - -Di-n-butylphthalate- - - -Fluoranthene----Pyrene- - — Butylbenzylphthalate

-- — Chrysene. _ _ -bis ( 2 -Ethylhexyl ) phthalate- - - -Di-n-octylphthalate----Benzo (b) f luoranthene----Benzo (k) f luoranthene- —— Benzo (a) pyrene----Indeno (1, 2, 3-cd) pyrene- — Dibenzo (a , h) anthracene- — Benzo (g,.h, ijperylene

2000490082028008208208202000200082082082046008208208201608202800

. 820820820820820820820820820820820820

U

U

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FORM I SV-2 OLM03.0

23274 CCX27 SPMPLE OPTP PPCKPGE #R3 1^99! 344

ID EPA SAMPLE NO.PESTICIDE ORGANICS ANALYSIS DATA SHEET

CCX28MSLab Name:CQMPUCHEM ENV. CORP. Contract;68D50004

Lab Code: COMPU Case No.: 23274 SAS No. : SDG No.: CCX27



% Moisture: 6__ decanted: (Y/N)H Date Received: 02/23/95

Extraction: (SepF/Cont/Sonc) SONC Date Extracted:02/28/95


Injection Volume: 2 .0 (uL) ' Dilution Factor: i.

GPC Cleanup: (Y/N)Y PH; 6.1 Sulfur Cleanup: (Y/N) N.

CONCENTRATION UNITS:CAS NO. COMPOUND (ug/L or ucr/Kcr)UG/KG C

319-84-6--------alpha-BHC_319-85-7--------beta-BHC_319-86-8--------delta-BHC58-89-9---------gamma-BHC (Lindane).76-44-8-------- -Heptachlor__________309-00-2- -------Aldrin___________1024-57-3-------Heptachlor epoxide_959-98-8--------Endosulfan I_____60-57-1---------Dieldrin___________72-55-9---------4,4'-DDE__________72-20-8---------Endrin_________33213-65-9------Endosulfan II____72-54-8---------4,4'-ODD__________1031-07-8-------Endosulfan sulfate,50-29-3---------4, 4'-DOT____________72-43-5---------Methoxychlor___53494-70-5------Endrin ketone__7421-93-4-------Endrin aldehyde.5103-71-9-------alpha-Chlordane.5103-74-2-------gamraa-Chlordane.8001-35-2-------Toxaphene.12674-11-2------Aroclor-101611104-28-2------Aroclor-1221.11141-16-5------Aroclor-123253469-21-9------Aroclor-124212672-29-6---——Aroclor-124811097-69-l------Aroclor-125411096-82-5------Aroclor-1260

4.24.24.2

0.80

0.96

170

818181

FORM I PEST OLM03.0

CCX?7 SPMPLE OPTP PBCKBGF $ R 3 I k 9 9 2

-ID . . . EPA SAMPLE NO.PESTICIDE ORGANICS ANALYSIS DATA SHEET

Lab Name:COMPUCHEM ENV. CORP. Contract:68D50004CCX28MSD


Matrix: (soil/water)SQIL Lab Sample ID: 686679

Sample wt/vol: 30.3(q/ml)G Lab File ID:

% Moisture: 60 decanted: (Y/N)N ' Date Received: 02/23/95

Extraction:' (SepF/Cont/Sonc) SONC Date Extracted;02/28/95

Concentrated Extract Volume: 10000 (uL) Date Analyzed.: 03/06/95

Injection Volume: 2 .0 (uL) • Dilution Factor: 1.

GPC Cleanup: (Y/N)Y pH;6.1 Sulfur Cleanup: (Y/N) N

_ . CONCENTRATION UNITS:CAS NO.. COMPOUND (ug/L or ug/Kg)UG/KG Q

319-84-6--------alpha-BHC_319-85-7--------beta-BHC_319-86-8--------delta-BHC58-89-9---------gamma-BHC (Lindane).76-44-8-------- -Heptachlor________309-00-2--------Aldrin___________1024-57-3-------Heptachlor epoxide.959-98-8--------Endosulfan I_________60-57-1- --------Dieldrin__________72-55-9---------4,4'-DDE__________72-20-8---------Endrin____________33213-65-9------Endosulfan II____72 - 54 - 8 - - - ----- -4, 4 ' -DDD__________1031-07-8-------Endosulfan sulfate50-29-3---——-T-4,4'-DDT_72-43-5---------Methoxychlor___53494-70-5------Endrin ketone7421-93-4-------Endrin aldehyde.5103-71-9-------alpha-Chlordane.5103-74-2-------gamma-Chlordane,8001-35-2-------Toxaphene_____12674-11-2------Aroclor-1016___11104-28-2------Aroclor-1221____11141-16-5------Aroclor-1232___53469-21-9------Aroclor-1242___12672-29-6------ArOclor-1248___11097-69-1------Aroclor-1254___11096-82-5------Aroclor-1260___

4.24.24.2272922,

'u4.24.259

0.88'568.21.3

•0.5458121.28.24.24.2420821708282828282

U

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23274-CCX27 SPMPLE OPTP PPCKPGP- AR3 i 993 628

ID EPA SAMPLE NOPESTICIDE ORGANICS ANALYSIS DATA SHEET ______

Lab Name;COMPUCHEM ENV. CORP. Contract:

Lab Code: COMPU Case No.: GPCCK SAS No.: SDG No.: FEB

Matrix: (soil/water)SOIL Lab Sample ID: A40227B


% Moisture: decanted: (Y/N) Date Received: j

Extraction: (SepF/Cont/Sonc) SONC Date Extracted:-OS &9- »5


Injection Volume: 2.0(uL) Dilution Factor: 1

GPC Cleanup: (Y/N)2 pH: Sulfur Cleanup: (Y/N) M

CONCENTRATION UNITS:CAS NO. COMPOUND (ug/L or ucr/Kcr) UG/KG Q

319-84-6-----319-85-7-----319-86-8-----58-89-9------76-44-8------309-00-2-----1024-57-3----959-98-8-----60-57-1------72-55-9------72-20-8------33213-65-9---72-54-8------1031-07-8----50-29-3 ———— -72-43-5------

7421-93-4----5103-71-9----5103-74-2----8001-35-2----12674-11-2---11104-28-2---11141-16-5---53469-21-9---12672-29-6---

11096-82-5---

----alpha-BHC----bet a- BHC.___delta-BHC-rr- gamma -BHC (Lindane)- - - -Heptachlor• - - -Aldrin----Heptachlor epoxide•---Endosulfan I----Dieldrin----4. 4 '-DDE----Endrin----Endosulfan II.___4.4'-DDD•---Endosulfan sulfate• —— 4. 4 '-DOT- - - -Methoxychlor•---Endrin ketone----Endrin aldehyde• - - -alpha-Chlordane. _ - _ qanuna - Chlordane•---Toxaphene•---Aroclor-1016•-- -Aroclor- 1221• - - -Aroclor-1232• - - -Aroclor- 1242• - - -Aroclor-1248•-- -Aroclor- 1254•-- -Aroclor- 12 60

1.71.71.71.71.71.71.71.73.33.33.33.33.33.33.3

0.253.33.31.71.717033673333333333

uU_i_ . . ——————

Uuuuuuuuyu_.\jUJP\JunyggU--V,Juguu -

FORM I PEST OLM03.0

23274 CCX27 SPMPLF'OPTP PPCKPGE ^ R 3 I 9 9 644 I

10A EPA SAMPLE NO.PESTICIDE IDENTIFICATION SUMMARY ______FOR SINGLE COMPONENT ANALYTES

Lab Name;COMPUCHEM ENV. CORP. Contract:

Lab Code: COMPU Case No.: QPCCK SAS No.: SDG No.: FEB

Lab Sample ID : A40227B Date(s) Analyzed: 02/28/95 02/28/95


GC Column(1): RTX-1701 ID: 0.53(mm) GC Column(2): DB-608 ID: 0.53(mm)

ANALYTE

Methoxychlor

. - , .-_: . /.... '-

• " - - - -

- -.-",-:

-

COL

1

2

1

2

1

2

1

2

1

2

1

2

1

2

1

2

RT:=35S = = =

15.42

14.97

RT WlFROM

15.35

14.89

ENDOWTO

15.49

15.03

CONCENTRATION

0.25

0.34

%D

\36.0_

page i ofFORM X PEST-1 OLM03.0

—— - -23274 CCX27 SPMPLE OPTP PPCKPGE & R 3 i k 9'9 5 64*5


SBLK11Lab Name: COMPUCHEM ENV. CORP. Contract: 68D50004

Lab Code: J3DMPU Case No. : 23274 SAS No. : SDG No. : CCX27



Level: (low/med) LOW ' Date Received: ______

% Moisture: ____ decanted: (Y/N)__ Date Extracted:02/28/95


Injection'Volume: 2.0(uL) .Dilution Factor: 1.0

GPC Cleanup: (Y/N) Y pH: ___


1 AQ QC O _

111-44-4----QC C*7 Q

541-73-1 ———106-46-7----QC C A T

95-48-7- ———108-60-1- ——,1. \J O T:*± J

621-64-7 ———

QQ QC "3 _ _ _ __

78-59-1 —— --Q Q *7C C

111-91-1----1 *3A QT -O __ —

91-20-3-----106-47-8 ———

CQ CA '7

QI C'7_£_____

77-47-4 ————QQ AC *5QC QC A

Q"! C Q *—

88-74-4-- ——131-11-3 ———

606-20-2 ———QQ_no o ___0-3 -30 Q _

----Phenol----bis (2-Chloroethyl) ether _______- - - - 2 - Chlorophenol----1,3 -Dichlorobenzene

----1,2 -Dichlorobenzene- - - - 2 -Methylphenol----2,2' -oxybis ( 1 -Chlbropropane )

- - - -N-Nitroso-di-n-propylamine•t t-SJCciC.Li-LQJ-vJSt— Jlii_ii-.Q

- - - -Nitrobenzene- - - - Isophorone- - - -2 -Nitrophenol----2,4 -Dimethylphenol- - - -bis ( 2 -Chloroethoxy ) methane _- - - T 2 , 4 -Dichlorophenol

- — -Naphthalene_ _ _ _4 -chloroaniiine- - - -Hexachlorobutadiene_ _ _ _4 -chloro- 3 -methylphenol ____- - - - 2 -Methylnaphthalene- - - -Hexachlorocyclopentadiene—— 2,4,6 -Trichlorophenol----2,4,5 -Trichlorophenol— - - 2 -Chloronaphthalene- - - -2-Nitroaniline- —— Dime thylphthalate- - - -Acenaphthylene—— 2,6 -Dini trotoluene- - - -3 -Nitroaniline- - - - Acenaphthene

330330330330330330'330330330330330330330330330330330330330330330330330330330820330820330330330820330


FORM I SV-1 OLM03.0

23274 CCX27 SPMPLE OPTP PPCKPGE & R 3 I k 9 9 6303

1C EPA SAMPLE NO.:-SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET

SBLK11Lab Name: COMPUCHEM ENV. CORP. Contract": 68D50004

Lab Code:-COMPU Case No.: 23274 SAS No.: SDG No.: CCX27



Level: (low/med) LOW Date Received: ______

% Moisture: ____ decanted: (Y/N)___ • Date Extracted:02/28/95


Injection Volume: 2.0(uL) Dilution Factor: 1.0GPC Cleanup: (Y/N) Y pH: ___ . '

V CONCENTRATION UNITS:CAS NO. COMPOUND (ug/L or ug/Kg) ug/Kg Q

C 1 *^ O C51-28-5-----100-02-7- ——1 — :O CA Q

i ?i_-i 4_?____84-66-2 ————TAAC 77 "3

Q c 71 7

100-01-6 —— -534-52-1----QC "3 A d

101-55-3- ——118-74-1 —— -0-7 Q /r cO C A 1 O85-01-8-----TOA 1 *"} "7

O C 'fA Qoo- /4-y------P4.-74-9------206-44-0 ——— •129-00-0 —— --QC CQ 7 _

91-94-1 ——— -•56-55-3 ———— •OT Q AT Q•4 * 1— Q — /117-81-7-----117-84-0- —— -OAC.-QQ-'?----.OA7_AQ_Q____.C A T Q50-32-8------i Q-J -a Q c53-70-3 ———— -1 QI _?A-?----.X_IX^'±A

----2,4 -Dinitrophenol- - - -4 -Nitrophenol- - - -Dibenzofuran >----2,4 -Dinitrotoluene- - - -Diethylphthalate- - - -4 -Chlorophenyl -phenylether _----Fluorene- - - -4 -Nitroaniline----4, 6-Dinitro-2-methylphenol _. _ _ -N-nitrosodiphenylamine (1)----4-Bromophenyl-phenyletHer "

- - - - Pentachlorophenol- - — Phenanthrene- - - -Anthracene- — Carbazole----Di-n-butylphthalate .- - - -Fluoranthene----Pyrene- - - -Butylbenzylphthalate----3,3' -Dichlorobenzidine• - - -Benzo ( a ) anthracene----Chrysene- —— bis ( 2 -Ethylhexyl ) phthalate _- - - -Di-n-octylphthalate- —— Benzo (b) f luoranthene- - - -Benzo (k) f luoranthene- - — Benzo (a) pyrene• — Indeno (1, 2, 3 -cd) pyrene• — Dibenzo ( a , h) anthracene- — Benzo (g, h, i) perylene

820820330330330330330820820330330330820330330330330330330330330330330330330330330330330330330



.-"....-^._.:. : FORM I SV-2 -OLM03.0

Jr -f CCX27 SPMPLE OPTP PPCKPGE& R 3 1U 9 9 7 304

lp ' EPA SAMPLE NO.SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET

TENTATIVELY IDENTIFIED COMPOUNDSSBLK11


Lab Code:_ COMPU Case No.: 23274 SAS No.: SDG No.: CCX27



Level: (low/med) LOW Date Received: ________

% Moisture: ____ decanted: (Y/N)__ Date Extracted.-02/28/95





CAS NUMBER

—— __ ———————————2.3.4.5.6.7.8.9.10.11.12.13.14. .15.16.17.18.19.20.21.22.23.24.25.26.27.28.29.30.

COMPOUND NAME

ALDOL (DC) —————————————— -—UNKNOWN (BC)UNKNOWN (BC)

RT

——— 4-r£4-4.8715.92

EST. CONC.

—————— n3-14989

Q

-fcj —— *y'

___ M

»

FORM I SV-TIC OLM03.0

SPMPLE OPTP PPCKPGE R3 j *f 9 9 8 3

..' ' 1FA .. . EPA SAMPLE NO.SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET":.:". : ALKANE SERIES REPORT



Matrix: (soil/water) SOIL . - Lab Sample ID: 687322

Sample wt/vol: . 30'.2 (g/mL) g Lab File ID: GH087322A21


% Moisture: ...... decanted: (Y/N)__ Date Extracted:02/28/95



GPC Cleanup: (Y/N) Y pH: ___ . •

' CONCENTRATION UNITS:Number TICs found: 0 . (ug/L or ug/Kg) ug/Kg

CAS NUMBER

1.2.3.4.5.6.7.8.9.10.11.12.13.14.15.16.17.18.19.20.21'.22.23.24.25.26.'27.28.29.30.

COMPOUND NAME RT EST. CONC. Q=====

FORM I SV-TIC OLM03.0

ILQQQ23274 CCX27 SPMPLE OPTP PPCKPGE ' *J^* 3Q6





Sample wt/vol: 30.0 (g/mL) g Lab File ID: GH088037C21


% Moisture: ______ decanted: (Y/N)__ Date Extracted:03/03/95





1 AQ QC O

111-44-4 —— -QC C1"? Q

541-73-1----106-46-7 ———QC_Cfl-1 _ _ _ _ _

QC__lfi_7-____

108-60-1----106-44-5----621-64-7 ———/" T T^ 167-72-1-----QQ QC "3<~JQ c Q -1

QQ_r7C_C — — _ — —

105-67-9 ———111-91-1 ———1 TA QT 7 _1 TA QT 1 _ _ __

91-20-3 ———i nc A7 oQ'7_(;a_'3_____o /— oo — o — — — — —CO C A 7QI C"7 £_

77-47-4 ————QQ_A£ — *5 — — - _ _QC QC AQI _CQ_7_____RQ-'7A -A- _ _ — —

131-11-3 ———OAQ QC Q

Cf\C ">(\ 1 _QQ_nQ_O __at _-JO_Q _ _

----Phenol- - - -bis (2 -Chloroethyl ) ether _______- - - - 2 - Chlorophenol----1,3 -Dichlorobenzene

10 T -J ( "Vi 1 i*"M / V _tm Tcsn«3

- - - - 2 -Methylphenol----2,2' -oxybis(l-Chloropropane)- - - -4 -Methylphenol- - - -N-Nitroso-di-n-propylamine _

_Tjd — . /— 'j n I'- T-I' ^ t- v TI - - - -Nitrobenzene- - - - Isophorone- - - - 2 -Nitrophenol----2,4 -Dime thy Iphenol— -bis ( 2 - Chloroethoxy ) methane _----2,4 -Dichlorophenol----1,2,4 -Trichlorobenzehe- — Naphthalene- - - -4 -Chloroaniline- - - -Hexachlorobutadiene- - - -4 -Chloro-3 rmethy Iphenol ______- - - - 2 -Methylnaphthalene

----2,4,6-Trichlorophenol—— 2,4,5 -Trichlorophenol- - - - 2 - Chloronaphthalene- - - - 2 -Nitroaniline— - -Dime thy Iphthalate

----2,6 -Dini trotoluene- - - -3 -Nitroaniline

-T_>V CXlCL|«<'llU.Xlw4>lC

, 330330330330330330330330330330330330330330330330330330330330330330330330330830330830330330330830330


FORM I SV-1 OLM03.0

7 SPMPLE OPTP PPCKPGE* * ' *® "" 31S

;^1"' -"-. V'.IC. ... EPA SAMPLE NO..SEMIVOLATILE ORGANICS'ANALYSIS DATA SHEET


Lab Code: _COMPU Case No.: 23274 SAS No.: SDG No.: CCX27




% Moisture: _____ decanted: (Y/N)__ Date Extracted:03/03/95


Inj ection Volume: 2.0 (uL) Dilution Factor: •' 1.0

GPC Cleanup: (Y/N) Y " pH: _____

. CONCENTRATION UNITS:CAS NO. COMPOUND (ug/L or ug/Kg) ug/Kg Q

51-28-5-----100-02-7 ———132-64-9----1 0 1 _ 1 4 -*?----J._*J. .L £t

84-66-2 ————7005-72-3 ——Q£_'7"3_*7—_ — _ —

100-01-6----534-5P-1----^j J ^i _J £* J_

86-30-6 -----101-55-3- ---118-74-1-----87-86-5- ——— •85-01-8 —— --•-inn TO ^120-12-7-----86-74-8- ——— -fid. - 74 - 9 - - - - - •206-44-0 ——— •129-00-0 ——— •QC ca 7 __— .91-94-1 ——— •56-55-3- ——— -

1 1 *7_QA_n_ — _ _ .•?AC,_QQ_7____.7f\7 AQ_Q___ — .C A O O Q"1 Q— i "3 Q C

53-70-3 ———— •1 QI — OA — *5 — — — — -

- - - -2 , 4-Dinitrophenol- - - -4 -Nitrophenol- - - -Dibenzofuran----2,4 -Dinitrotoluene- - - -Diethylphthalate- - — 4 -Chlorophenyl -phenylether _----Fluorene- - - -4 -Nitroaniline-___4, 6-Dinitro-2-methylphenol- - - -N-nitrosodiphenylamine_ ( 1 ) _- - - -4-Bromophenyl-phenylether ____- - - -Hexachlorobenzene- - - - Pentachlorophenol- - - - Phenanthrene- - — Anthracene----Carbazole- - - -Di-n-butylphthalate- — - Fluoranthene----Pyrene• — -Butylbenzylphthalate• — 3,3' -Dichlorobenzidine- - - -Benzo (a) anthracene

• —— bis ( 2 -Ethylhexyl ) phthalate _• —— Di -n-octylphthalate• - - -Benzo (b ) f luoranthene•'---Benzo (k) f luoranthene• - - -Benzo (a) pyrene• —— Indeno (1,2, 3 -cd) pyrene•---Dibenzo (a, h) anthracene•---Benzo (cr,h, i) perylene

830830330330330330330830830330330330

. 830330330330330330330

• 330330330330330330330330330330330330



FORM I SV-2 OLM03.0

23274 CCX27 SPMPLE OPTP PPCKPG^ 3 i 50 0 I 3I9


TENTATIVELY IDENTIFIED COMPOUNDSSBLK47


Lab Code: GOMPU Case No.: 23274 SAS No.: SDG No.: CCX27




% Moisture: ____ decanted: (Y/N)__ Date Extracted:03/03/95




- CONCENTRATION UNITS:Number TICs found: 2 . (ug/L or ug/Kg) ug/Kg

CAS NUMBER

—— 3_ ———————————2.3.4.5.6.7.8.9.10.11.12.13.14.15.16.17.18.19.20.21.22.23.24.25.26.27.28.29.30.

COMPOUND NAME

7VTTV~'L (B1"1)UNKNOWN (BC)

.

RT

————— 4-r64-6.32

EST. CONC.

————————— 258-82

*

QAJ —— S

JH

_FORM I SV-TIC OLM03.

23274 CCX27 SPNPLE OPTP PPCKPGE 320

——— .-- 1FA . EPA SAMPLE NO.SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET": - - - - - - ALKANE SERIES REPORT


Lab Code: COMPU Case No.: 23274= SAS No.: SDG No.: CCX27

..Matrix:, (soil/water) SOIL ., L. Lab Sample ID: 688037

Sample wt/vol: 30.0 (g/mL) g Lab'File ID: GH088037C21


% Moisture: _____ decanted: (Y/N)__ Date Extracted:03/03/95



GPC .Cleanup: (Y/N) Y pH: ___

;-:-ri=_ ' .--".-,... CONCENTRATION UNITS:Number TICs found: 0 (ug/L or ug/Kg) ug/Kg

CAS NUMBER

' 1.2.3.4.5.6.7.8.9.10.11.12.13.14.15.16.17.18.19.20.21.22.23.24.25.26.27.28.29. .30.

COMPOUND NAME RT EST. CONC. , Q

FORM I SV-TIC OIMJ3.0

23274 CCX27 SPMPLE OPTP PPCKPGE AR3 I 5003321

ID EPA SAMPLE NO.PESTICIDE ORGANICS ANALYSIS DATA SHEET ____

PBLK95Lab Name:COMPUCHEM ENV. CORP. Contract:68D50004




% Moisture: decanted: (Y/N) Date Received:

Extraction: (SepF/Cont/Sonc) SONC Date Extracted;02/28/95'


Injection Volume: 2.0(uL) ' Dilution Factor: 1

GPC Cleanup: (Y/N)Y • pH: Sulfur Cleanup: (Y/N) N.

CONCENTRATION UNITS:CAS NO. , COMPOUND (ug/L or ua/Kq)UG/KG C

319-84-6-----319-85-7-----319-86-8-----58-89-9------76-44-8------309-00-2-----1024-57-3----959-98-8-----60-57-1------72-55-9------72-20-3------33213-65-9---72-54-8------1031-07-8----50-29-3--- ——72-43-5------53494-70-5---7421-93-4 —— -5103-71-9----5103-74-2----8001-35-2----12674-11-2---11104-28-2---11141-16-5---53469-21-9---12672-29-6---11097-69-1---11096-82-5---

-- -alpha -BHC---beta-BHC---delta-BHC---gamma- BHC (Lindane)---Heptachlor---Aldrin---Heptachlor epoxide---Endosulfan I---Dieldrin---4. 4 '-DDE---Endrin---Endosulfan II---4.4/-DDD---Endosulfan sulfate ,—— 4.4'-DDT- - -Methoxychlor---Endrin ketone---Endrin aldehyde- - -alpha-Chlordane- - -gamma-Ghlordane- - -Toxaphene---Aroclor- 1016---Aroclor-1221---Aroclor-1232---Aroclor- 1242---Aroclor- 124 8---Aroclor- 1254---Aroclor- 12 60

1.71.71.71.71.71.71.71.73.33.33.33.33.33.33.317

3.33.31.71.717033673333333333

UuuuuuugUUUUUUUUUUUUUUuuuuu

FORM I PEST OLM03.0

IT noro partratztr A R 3 I o U U U

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