PR21 [RISOCAST DA-L] en 180701 - Miyoshi America,...

13
1 Copyright © 2007 KOKYU ALCOHOL KOGYO CO., LTD. All rights reserved. All other company or product names are trademarks or registered trademarks of their respective companies or organizations. KOKYU ALCOHOL KOGYO CO., LTD. Head Office & Plant Taiei Kogyo Danchi, 641-6 Kichioka, Narita, Chiba 287-0225 Japan TEL : +81-476-73-6020 FAX : +81-476-73-6024 Tokyo Office Kasahara Bldg. 4F, 1-7-7 Nihonbashi Ningyocho, Chuo-ku, Tokyo 103-0013 Japan TEL : +81-3-3667-2801 FAX : +81-3-3667-3980 E-mail : [email protected] URL : http://www.hai-global.com/ Raw material approved by ECOCERT GREENLIFE, conform to the ECOCERT Natural and Organic Cosmetics Standard. Nevertheless, for the certification of final cosmetic products containing ECOCERT already approved ingredients, it must be certified individually according to the ECOCERT Cosmetic Standard. PR21 [RISOCAST DA-L] en_180701 Creation date : Oct. 22, 2007 (Revision date : Jul. 01, 2018) 2 Copyright © 2007 KOKYU ALCOHOL KOGYO CO., LTD. All rights reserved. MATERIAL INFORMATION INCI name CAS No. Chinese INCI name : HYDROGENATED CASTOR OIL DIMER DILINOLEATE : 646054-62-8 : 氢化蓖麻油二聚亚油酸酯 RISOCAST DA-L is an ester obtained from dimer acid and hydrogenated castor oil, approved by ECOCERT. FEATURES SPECIFICATIONS ꞏ REFERENCE SPECIFICATIONS Vegetable-based high viscosity pasty oil Rich texture Natural gloss Good water-absorption capacity Prevents syneresis and increases hardness Specification value Description Pale yellow, pasty solid, faint characteristic odor Acid value Not more than 6 Saponification value 160 - 210 Iodine value Not more than 8 Hydroxyl value 60 - 90 Color Not more than 10 Gardner Reference value Viscosity 900 mPas (60 ºC) REFERENCE and bending strength of lipsticks Listed on the Inventory of Existing Cosmetic Ingredients in China

Transcript of PR21 [RISOCAST DA-L] en 180701 - Miyoshi America,...

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1Copyright © 2007 KOKYU ALCOHOL KOGYO CO., LTD. All rights reserved.

All other company or product names are trademarks or registered trademarks of their respective companies or organizations.

KOKYU ALCOHOL KOGYO CO., LTD.Head Office & Plant Taiei Kogyo Danchi, 641-6 Kichioka, Narita, Chiba

287-0225 JapanTEL : +81-476-73-6020 FAX : +81-476-73-6024

Tokyo Office Kasahara Bldg. 4F, 1-7-7 Nihonbashi Ningyocho, Chuo-ku, Tokyo 103-0013 JapanTEL : +81-3-3667-2801 FAX : +81-3-3667-3980E-mail : [email protected] URL : http://www.hai-global.com/

Raw material approved by ECOCERT GREENLIFE, conform to the ECOCERT Natural and Organic Cosmetics Standard.Nevertheless, for the certification of final cosmetic products containing ECOCERT already approved ingredients, it must be certified individually according to the ECOCERT Cosmetic Standard.

PR21 [RISOCAST DA-L] en_180701Creation date : Oct. 22, 2007 (Revision date : Jul. 01, 2018)

2Copyright © 2007 KOKYU ALCOHOL KOGYO CO., LTD. All rights reserved.

MATERIAL INFORMATION

INCI nameCAS No.Chinese INCI name

: HYDROGENATED CASTOR OIL DIMER DILINOLEATE: 646054-62-8: 氢化蓖麻油二聚亚油酸酯

RISOCAST DA-L is an ester obtained from dimer acid and hydrogenated castor oil, approved by ECOCERT.

FEATURES SPECIFICATIONS ꞏ REFERENCE

SPECIFICATIONSVegetable-based high viscosity pasty oil

Rich texture

Natural gloss

Good water-absorption capacity

Prevents syneresis and increases hardness

Specification value

Description Pale yellow, pasty solid, faint characteristic odor

Acid value Not more than 6

Saponification value 160 - 210

Iodine value Not more than 8

Hydroxyl value 60 - 90

Color Not more than 10 Gardner

Reference value

Viscosity 900 mPa・s (60 ºC)

REFERENCEand bending strength of lipsticks

Listed on the Inventory of Existing Cosmetic Ingredients in China

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3Copyright © 2007 KOKYU ALCOHOL KOGYO CO., LTD. All rights reserved.All other company or product names are trademarks or registered trademarks of their respective companies or organizations.

REFRACTIVE INDEX AND WATER-ABSORPTION CAPACITY

Measurement conditions

ApparatusLight sourceTemperature

: Abbe Refractometer NAR-2T (ATAGO CO., LTD.): LED lamp (D-line wavelength): 20 °C

REFRACTIVE INDEX

RISOCAST DA-L is a vegetable derived high viscosity oil with high refractive index and good water-absorption capacity

1.0

1.2

1.4

1.6

1.8

2.0

リソカスタ DA L ⽔添ポリイソブン ラノリン

Ref

ract

ive

inde

x

0

100

200

300

RISOCAST DA-L PB18 LANOLIN

Measurement method

(remove the excess water).

RISOCASTDA-L

HYDROGENATED POLYISOBUTENE

(MW : 1000)

LANOLIN RISOCASTDA-L

HYDROGENATED POLYISOBUTENE

(MW : 1000)

LANOLIN

WATER-ABSORPTION CAPACITY

Wat

er-a

bsor

ptio

n ca

paci

ty (

%)

Water-absorption capacity (%) = x 100Weight of water added (g)

Weight of test sample at start (g)

1. 10 g of sample is weighed in a polyethylene container (500 mL).2. Purified water is added little by little and gently mixed (approx. 0.5 mL/min).3. Mixing is stopped when the sample does not absorb water anymore

4. The water-absorption capacity is calculated.

Similar refractive index toHYDROGENATED POLYISOBUTENE

and LANOLIN.

Good water-absorption capacity compared to HYDROGENATED

POLYISOBUTENE and LANOLIN.

The data shows measurement value.

4Copyright © 2007 KOKYU ALCOHOL KOGYO CO., LTD. All rights reserved.

1

10

100

1000

1 10 100 1000

PB24 PB18 DA-Lラノリン

TEXTURESensory evaluation and viscoelastic measurement

(1) SENSORY EVALUATION (n=4) (2) VISCOELASTIC MEASUREMENT

Texture of RISOCAST DA-L is evaluated by (1) sensory evaluation and (2) viscoelastic measurement (Texture : hardness and spreadability)

HYDROGENATED POLYISOBUTENE (MW : 1350)

HYDROGENATED POLYISOBUTENE (MW : 1000)

RISOCAST DA-LLANOLIN

Shear rate (1/s)

Vis

cosi

ty(P

a・s)

Measurement temperature : 35 ºC

HardSoft

Low spreadability

High spreadability

RISOCAST DA-L

HYDROGENATEDPOLYISOBUTENE

(MW : 1000)

LANOLIN

HYDROGENATEDPOLYISOBUTENE(MW : 1350)

The data shows measurement value.

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5Copyright © 2007 KOKYU ALCOHOL KOGYO CO., LTD. All rights reserved.

COMPATIBILITY

Sample MINERAL OIL(HICALL K-230)

ISOTRIDECYL ISONONANOATE

(KAK 139)

DIPENTAERYTHRITYL HEXAISONONANOATE

(HAILUCENT DPIN6)

CAPRYLIC/CAPRIC TRIGLYCERIDE

(TCG-M)

ISOSTEARYL ISOSTEARATE

(ISIS)

OCTYLDODECYLSTEAROYL STEARATE

(RISOCAST ODSHS)

Concentrationof DA-L 10 % 50 % 10 % 50 % 10 % 50 % 10 % 50 % 10 % 50 % 10 % 50 %

State at 80 ºC T N C C C C C C C C C C

State after1 week at 25 ºC N N N T T T N T N T N T

SampleTRIMETHYLOLPROPANE TRIISOSTEARATE

(KAK TTI)

PENTAERYTHRITYL TETRAISOSTEARATE

(KAK PTI)

OCTYLDODECANOL(RISONOL 20SP)

POLYGLYCERYL-2 TRIISOSTEARATE

(RISOREX PGIS23)

POLYGLYCERYL-2 DIISOSTEARATE(RISOREX PGIS22)

DIISOSTEARYL MALATE

(HAIMALATE DIS)

Concentrationof DA-L 10 % 50 % 10 % 50 % 10 % 50 % 10 % 50 % 10 % 50 % 10 % 50 %

State at 80 ºC C C C C C C C C C C C C

State after1 week at 25 ºC T T T T N T T T T T T T

RISOCAST DA-L is mixed with each oil and heated up to 80 ºC for 1 hour The appearance at 80 ºC is visually observed and then re-checked after 1 week at 25 ºC

Abbr. C : Compatible T : Turbid N : Not compatible Typical data

6Copyright © 2007 KOKYU ALCOHOL KOGYO CO., LTD. All rights reserved.All other company or product names are trademarks or registered trademarks of their respective companies or organizations.

EFFECT ON SOLID MIXTURESEvaluation of DA-L-wax interaction : application to lipstick

0

0.1

0.2

0.3

0.4

0.5

0.6

10 15 20 25

DA-L

PB-18

PB-24

ラノリン

0

0.5

1.0

1.5

2.0

5 10 15 20

PB24

PB18

DA-L

LANOLIN

SOLID MIXTURES OF SOLID MIXTURES OFMICROCRYSTALLINE WAX AND OIL POLYETHYLENE AND OIL

Concentration ofMICROCRYSTALLINE WAX (%)

Concentration ofPOLYETHYLENE (%)

Har

dnes

s (N

)

Har

dnes

s (N

)

Measurement method of hardness

Compact Table-Top Universal Tester EZ Test 20N (SHIMADZU CORPORATION) : A 1.0 mm diameter needle penetrates into a solid mixture at 10 mm/min. The hardness is the highest result obtained after a penetration of 10 mm (at 25 ºC).

Measurement temperature : 25 ºCMeasurement temperature : 25 ºC

• HYDROGENATED POLYISOBUTENE (MW : 1350) : PB24• HYDROGENATED POLYISOBUTENE (MW : 1000) : PB18

RISOCAST DA-L is mixed with various concentrations of wax in order to measure the hardness of the mixture HYDROGENATED POLYISOBUTENE (commonly used high viscosity oil) and LANOLIN are selected as comparative oils

The data shows measurement value.

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7Copyright © 2007 KOKYU ALCOHOL KOGYO CO., LTD. All rights reserved.All other company or product names are trademarks or registered trademarks of their respective companies or organizations.

EFFECT ON LIPSTICK (1) Comparison with HYDROGENATED POLYISOBUTENE and LANOLIN

The effect of RISOCAST DA-L on lipstick formulations is evaluated RISOCAST DA-L is compared to HYDROGENATED POLYISOBUTENE (commonly used high viscosity oil) and LANOLIN

Product name/Supplier INCI name wt%

Bas

e fo

rmul

atio

n

1.TCG-M(KOKYU ALCOHOL KOGYO CO., LTD.)

CAPRYLIC/CAPRIC TRIGLYCERIDE 48.0

2. High viscosity oil*1 - 25.0

3. HAIMALATE DIS(KOKYU ALCOHOL KOGYO CO., LTD.)

DIISOSTEARYL MALATE 13.0

4. Refined Microcrystalline Wax(NIKKO RICA CORPORATION)

MICROCRYSTALLINE WAX 7.0

5.POLYWAX-500(Baker Hughes Incorporated)

POLYETHYLENE 7.0

Lips

tick

form

ulat

ion

Base formulation 90 %

Pink pigment paste 10 %

Product name/INCI name Abbr. Viscosity*2

(mPaꞏs, 25 ºC)

HYDROGENATED POLYISOBUTENE(MW : 1350)

PB24 75200

RISOCAST DA-L DA-L 26100

LANOLIN LANOLIN 21700

LIPSTICK FORMULATIONS FOR COMPARISON

*2 The viscosity is the one at 10 (1/s) of shear rateby viscoelasticity measurement.

*1 High viscosity oils are used one by one from the list on the right.

The data shows measurement value.

8Copyright © 2007 KOKYU ALCOHOL KOGYO CO., LTD. All rights reserved.

EFFECT ON LIPSTICK (1) Comparison with HYDROGENATED POLYISOBUTENE and LANOLIN

0

0.1

0.2

0.3

0.4

00.51.01.52.02.53.0

DA-LPB241.0

1.5

2.0

2.5

8

10

12

14

16

Har

dnes

s (N

)

HARDNESS BENDING STRENGTH

Dep

osite

d qu

antit

y of

lips

tick

(mg)

DEPOSITED QUANTITY SMOOTHNESS

LANOLIN

Ben

ding

stre

ngth

(N

)

PB24

DA-L

LANOLIN

Sufficient

Insufficient

MIU

(sm

ooth

ness

)

1 2 3Frequency of application

(reciprocating time)

Measurement temperature : 25 ºC Measurement temperature : 25 ºC

Measurement temperature : 35 ºC Measurement temperature : 35 ºC

: H (high) : M (medium) : L (low)

The data shows measurement value.

DA-LPB24 LANOLIN

DA-LPB24 LANOLIN

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9Copyright © 2007 KOKYU ALCOHOL KOGYO CO., LTD. All rights reserved.All other company or product names are trademarks or registered trademarks of their respective companies or organizations.

SEM IMAGES OF LIPSTICK

Apparatus : SEM JSM-6460LA(JEOL Ltd.)

Accelerating voltage : 5 kVResolution : HV modeMagnification :X 200, X 1000Detector : secondary electron detectorPre-treatment : freeze-fracture,

Osmium evaporation

Product name wt%

TCG-M 48.0

High viscosity oil 25.0

HAIMALATE DIS 13.0

Refined Microcrystalline Wax 7.0

POLYWAX-500 7.0

Measurement conditions

The formulations with different high viscosity oils are observed by SEM to check their crystal size HYDROGENATED POLYISOBUTENE (commonly used high viscosity oil) and LANOLIN are selected as comparative oils Crystal size of RISOCAST DA-L is found finer than the others

PB24 DA-L LANOLIN

X 200

PB24 DA-L LANOLIN

X 1000

10Copyright © 2007 KOKYU ALCOHOL KOGYO CO., LTD. All rights reserved.

EFFECT ON LIPSTICK (1) Comparison with HYDROGENATED POLYISOBUTENE and LANOLIN

0

500

1000

0 100 2000

500

1000

1500

2000

0 120 240 360

DA-L

Shear rate (1/s)

She

ar s

tres

s (P

a)

Time (s)

She

ar s

tres

s (P

a)

She

ar s

tres

s (P

a)

Time (s)

0

100

200

300

400

500

600

0 60 120 180 240 300 360

PB24

DA-L

LANOLIN

Light

Heavy

Smooth

LANOLIN

PB24

Good adhesion

Presence of “shoulder”

Height of stress value

Texture by viscoelasticity

Viscosity(mPaꞏs, 25 ºC)

PB24 YES MediumEven coverage and medium adhesion 75200

DA-L YES MediumEven coverage and medium adhesion 26100

LANOLIN NO Low Smooth and light texture 21700

: H (heavy) : M (medium) : L (light)

Hysteresis loop is observedduring the 1st cycle

Stress changes during the 3 cycles

Stress changes during the 3 cycles (enlarged view)

TEXTURE EVALUATION BY VISCOELASTIC MEASUREMENTSENSORY EVALUATION (n=6)

The data shows measurement value.

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EFFECT ON LIPSTICK (1) Conclusion

Texture by viscoelasticity Hardness

Bending strength

Deposited quantity

HYDROGENATED POLYISOBUTENE(MW : 1350)

M

M M M

RISOCAST DA-L M H M

LANOLIN L M M M

Characteristics of lipstick with RISOCAST DA-L :

Increases bending strength with good adhesion Similar lipstick texture to the one with HYDROGENATED POLYISOBUTENE (PB24)

: H (heavy/high) : M (medium) : L (light/low)

12Copyright © 2007 KOKYU ALCOHOL KOGYO CO., LTD. All rights reserved.All other company or product names are trademarks or registered trademarks of their respective companies or organizations.

EFFECT ON LIPSTICK (2) In combination with various oils

Product name/INCI name Abbr. Viscosity

(mPaꞏs, 25 ºC)

KAK PTI(PENTAERYTHRITYL TETRAISOSTEARATE)

PTI 309

KAK TTI(TRIMETHYLOLPROPANE TRIISOSTEARATE)

TTI 205

KAK DADIP-R(DIISOPROPYL DIMER DILINOLEATE)

DADIP 111

RISOCAST ODSHS(OCTYLDODECYL STEAROYL STEARATE)

ODSHS 96

RISOCAST IOHS(ETHYLHEXYL HYDROXYSTEARATE)

IOHS 55

RISONOL 20SP(OCTYLDODECANOL)

20SP 49

TCG-M(CAPRYLIC/CAPRIC TRIGLYCERIDE)

TCG 26

KAK 139(ISOTRIDECYL ISONONANOATE)

139 11

Product name/Supplier INCI name wt%

Bas

e fo

rmul

atio

n

1. Liquid oil* - 48.0

2. RISOCAST DA-L(KOKYU ALCOHOL KOGYO CO., LTD.)

HYDROGENATED CASTOR OIL DIMER DILINOLEATE 25.0

3.HAIMALATE DIS(KOKYU ALCOHOL KOGYO CO., LTD.)

DIISOSTEARYL MALATE 13.0

4.Refined Microcrystalline Wax(NIKKO RICA CORPORATION)

MICROCRYSTALLINE WAX 7.0

5.POLYWAX-500(Baker Hughes Incorporated)

POLYETHYLENE 7.0

Lips

tick

form

ulat

ion

Base formulation 90 %

Pink pigment paste 10 %

*Liquid oils are used one by one from the list on the right.

The effect of liquid oils used in combination with RISOCAST DA-L is checked by evaluation of the following formulations

LIPSTICK FORMULATIONS FOR COMPARISON The data shows measurement value.

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13Copyright © 2007 KOKYU ALCOHOL KOGYO CO., LTD. All rights reserved.

EFFECT ON LIPSTICK (2) In combination with various oils

0

0.1

0.2

0.3

0.4

00.51.01.52.02.53.0

ODSHS

PTI

PTITTIDADIPODSHSIOHS20SPTCG139

0

0.5

1.0

1.5

2.0

2.5

0

4

8

12

16

DADIP

20SP 139TCGTTI IOHS ODSHS

PTI DADIP

20SP 139TCGTTI IOHS

ODSHS

PTI DADIP

20SP 139TCGTTI IOHS

HARDNESS BENDING STRENGTH

DEPOSITED QUANTITY SMOOTHNESS

Measurement temperature : 25 ºC Measurement temperature : 25 ºC

Measurement temperature : 35 ºC Measurement temperature : 35 ºC

Har

dnes

s (N

)D

epos

ited

quan

tity

of li

pstic

k (m

g)

Ben

ding

stre

ngth

(N

)

Sufficient

Insufficient

MIU

(sm

ooth

ness

)

1 2 3Frequency of application

(reciprocating time)

: H (high) : M (medium) : L (low)

The data shows measurement value.

14Copyright © 2007 KOKYU ALCOHOL KOGYO CO., LTD. All rights reserved.

EFFECT ON LIPSTICK (2) In combination with various oils

Presence of “shoulder”

Height of stress value Texture by viscoelasticity Viscosity

(mPaꞏs, 25 ºC)

PTI YES High Heavy texture and good adhesion 309

TTI YES High Heavy texture and good adhesion 205

DADIP YES High Heavy texture and good adhesion 111

ODSHS YES Medium Even coverage and medium adhesion 96

IOHS YES Medium Even coverage and medium adhesion 55

20SP YES Medium Even coverage and medium adhesion 49

TCG YES Medium Even coverage and medium adhesion 26

139 NO Low Smooth and light texture 11

0

500

1000

0 100 2000

500

1000

1500

2000

0 120 240 3600

100

200

300

400

500

600

0 60 120 180 240 300 360

PTI TTI DADIP ODSHS IOHS 20SP TCG 139

ODSHS

TCG

139

DADIP

PTI

20SP

TTI

IOHS

Light

Heavy

Smooth Good adhesion

Measurement temperature : 35 ºC

Shear rate (1/s)

She

ar s

tres

s (P

a)

Time (s)

She

ar s

tres

s (P

a)

She

ar s

tres

s (P

a)

Time (s)

: H (heavy) : M (medium) : L (light)

Hysteresis loop is observedduring the 1st cycle

Stress changes during the 3 cycles

Stress changes during the 3 cycles (enlarged view)

TEXTURE EVALUATION BY VISCOELASTIC MEASUREMENTSENSORY EVALUATION (n=6)

The data shows measurement value.

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15Copyright © 2007 KOKYU ALCOHOL KOGYO CO., LTD. All rights reserved.

RISOCAST DA-L could be combined with various oils for lipsticks to obtain the following effects :

EFFECT ON LIPSTICK (2) In combination with various oils : conclusion

Texture by viscoelasticity Hardness

Bending strength

Deposited quantity

KAK PTI

H

M H MKAK TTI M M M

KAK DADIP-R M H L

RISOCAST ODSHS

M

L M MRISOCAST IOHS L L MRISONOL 20SP M L MTCG-M M H LKAK 139 L M M L

KAK DADIP-R and KAK PTI KAK PTI, KAK DADIP-R and TCG-M RISOCAST ODSHS, KAK TTI and RISOCAST IOHS KAK PTI, KAK TTI and KAK DADIP-R KAK 139

To increase hardness To increase bending strength To increase deposited quantity To add good adhesion To add smooth spreadability

: H (heavy/high) : M (medium) : L (light/low)

16Copyright © 2007 KOKYU ALCOHOL KOGYO CO., LTD. All rights reserved.All other company or product names are trademarks or registered trademarks of their respective companies or organizations.

EFFECT ON LIP GLOSSComparison with HYDROGENATED POLYISOBUTENE (PB)

Product name/Supplier INCI name wt%

1. High viscosity oil* - 40.0

2. RISOREX PGIS22(KOKYU ALCOHOL KOGYO CO., LTD.)

POLYGLYCERYL-2 DIISOSTEARATE 30.0

3. HAIMALATE DIS(KOKYU ALCOHOL KOGYO CO., LTD.) DIISOSTEARYL MALATE 14.0

4. KAK PTI(KOKYU ALCOHOL KOGYO CO., LTD.)

PENTAERYTHRITYL TETRAISOSTEARATE 8.7

5. Rheopearl KL2(Chiba Flour Milling Co., Ltd.) DEXTRIN PALMITATE 5.0

6. Hi-Mic-1090(NIPPON SEIRO CO., LTD) MICROCRYSTALLINE WAX 2.0

7. Pink pigment paste - 0.2

8. d-δ-TOCOPHEROL(Tama Biochemical Co., Ltd.) TOCOPHEROL 0.1

Product name/INCI name Abbr.

RISOCAST DA-L DA-L

HYDROGENATED POLYISOBUTENE(MW : 1000)

PB18

LIP GLOSS FORMULATIONS FOR COMPARISON

(1) Mix 1 - 8 into a suitable container and heat up. (2) Stir until completely melted and well dispersed, and de-aerate.(3) Cool down.

Process

The effect of RISOCAST DA-L on lip gloss formulations is evaluated RISOCAST DA-L is compared to HYDROGENATED POLYISOBUTENE (commonly used high viscosity oil)

*High viscosity oils are used one by one from the list on the right.

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EFFECT ON LIP GLOSSComparison with PB : sensory evaluation and viscoelastic measurement

0

200

400

600

800

1000

1200

0 60 120 180 240 300 360 420

DA-L

PB18500 2.5

PB18

DA-L

0.1

1

10

100

1000

0.1 1 10 100 1000

DA-L

PB18

DA-L

Measurement temperature : 35 ºC Measurement temperature : 35 ºC

Time (s)

She

ar s

tres

s(P

a)

Shear rate (1/s)

Vis

cosi

ty(P

a・s)

: Good adhesion/Rich type : Smooth/Light type

Rich

Light

SmoothGoodadhesion

Results of sensory evaluation and viscoelastic measurement for lip gloss are shown in this slide

Lip gloss with RISOCAST DA-L is richer and smoother than PB18

The data shows measurement value.

18Copyright © 2007 KOKYU ALCOHOL KOGYO CO., LTD. All rights reserved.

CHARACTERISTICSConclusion

BASIC CHARACTERISTICS

EFFECT ON LIPSTICK FORMULATIONS

EFFECT ON LIP GLOSS FORMULATIONS

• Vegetable-based (approved by ECOCERT) high viscosity pasty oil with rich texture• Natural gloss and good water-absorption capacity • Good compatibility with various oils at high temperature

Recommended applications : lipstick, lip gloss and skin cream

• Improves bending strength compared to HYDROGENATED POLYISOBUTENE (PB24) and LANOLINE• Even coverage and medium adhesion

• Light texture and smooth spreadability compared to HYDROGENATED POLYISOBUTENE (PB18)

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19

The formulations given in this leaflet can be freely changed, applied and commercialized. However, KOKYU ALCOHOL KOGYO CO., LTD.assumes no responsibility for any liability or damage which may arise directly or indirectly in connection with the use of such formulations. Accordingly, please exercise all due caution in respect of intellectual property rights, safety and other matters when using the formulations.

KOKYU ALCOHOL KOGYO CO., LTD. R&D Division

All other company or product names are trademarks or registered trademarks of their respective companies or organizations.

20All other company or product names are trademarks or registered trademarks of their respective companies or organizations.

LIPSTICK Lab code : LS-AJ1NA

Product name INCI name wt% Supplier

1. RISOCAST DA-LHYDROGENATED CASTOR OIL DIMER DILINOLEATE 29.9 KOKYU ALCOHOL KOGYO CO., LTD.

2. NPDC NEOPENTYL GLYCOL DICAPRATE 20.0 KOKYU ALCOHOL KOGYO CO., LTD.

3. KAK DADIP-R DIISOPROPYL DIMER DILINOLEATE 20.0 KOKYU ALCOHOL KOGYO CO., LTD.

4. AJK-IS3613*ISOSTEARIC ACID, DIBUTYL LAUROYL GLUTAMIDE,DIBUTYL ETHYLHEXANOYL GLUTAMIDE 10.0 KOKYU ALCOHOL KOGYO CO., LTD.

5. Refined Microcrystalline Wax MICROCRYSTALLINE WAX 10.0 NIKKO RICA CORPORATION

6. Pink pigment paste - 10.0 -

7. d-δ-TOCOPHEROL TOCOPHEROL 0.1 Tama Biochemical Co., Ltd.

Stability : Ongoing

*

Process (1) Mix 1 - 7 into a suitable container and heat up.

(2) Stir until completely melted and well dispersed, and de-aerate.

(3) Pour into lipstick molds and cool down.

*AJK-IS3613 is a mixture of ISOSTEARIC ACID EX : ISOSTEARIC ACID (KOKYU ALCOHOL KOGYO CO., LTD.) 64 %, GP-1 : DIBUTYL LAUROYL GLUTAMIDE (AJINOMOTO CO., INC.) 27 %,EB-21 : DIBUTYL ETHYLHEXANOYL GLUTAMIDE (AJINOMOTO CO., INC.) 9 %.

This lipstick with MICROCRYSTALLINE WAX and AJK-IS3613 which are used as a solidification agents gives light and smooth texture effect. AJK-IS3613 features lightening oily texture.

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21All other company or product names are trademarks or registered trademarks of their respective companies or organizations.

LIPSTICK : LONG-LASTING TYPE

Combining pigments and coloring agents makes long-lasting lipsticks.

Adding RISOCAST DA-L, it smoothly applies and gives good adhesion.

Lab code : LS-D3NA-PL

Product name INCI name wt% Supplier

1. HAILUCENT DPIN6 DIPENTAERYTHRITYL HEXAISONONANOATE 25.0 KOKYU ALCOHOL KOGYO CO., LTD.

2. TCG-M CAPRYLIC/CAPRIC TRIGLYCERIDE 22.5 KOKYU ALCOHOL KOGYO CO., LTD.

3. RISOCAST DA-LHYDROGENATED CASTOR OIL DIMER DILINOLEATE 17.1 KOKYU ALCOHOL KOGYO CO., LTD.

4. Pink pigment paste - 10.0 -

5. HAIMALATE DIS DIISOSTEARYL MALATE 9.0 KOKYU ALCOHOL KOGYO CO., LTD.

6. RISOREX PGIS23 POLYGLYCERYL-2 TRIISOSTEARATE 4.5 KOKYU ALCOHOL KOGYO CO., LTD.

7. Refined Microcrystalline Wax MICROCRYSTALLINE WAX 4.5 NIKKO RICA CORPORATION

8. CERESIN#810 CERESIN 3.6 NIKKO RICA CORPORATION

9. POLYWAX-500 POLYETHYLENE 2.7 Baker Hughes Incorporated

10. CANDELILLA WAX Super refine EUPHORBIA CERIFERA (CANDELILLA) WAX 0.9 Watahan Trading Co., Ltd.

11. D & C Red No.27 RED 27 (CI 45410) 0.1 KISHI KASEI CO., LTD.

12. d-δ-TOCOPHEROL TOCOPHEROL 0.1 Tama Biochemical Co., Ltd.

(1) Mix 1 - 12 into a suitable container and heat up.

(2) Stir until completely melted and well dispersed, and de-aerate.

(3) Pour into lipstick molds and cool down.

Process

Stability : The stability has been confirmed at 25 ºC and 45 ºC for 3 months and by cycle test (5 ºC ↔ 25 ºC ↔ 45 ºC, 5 cycles).

Just after application Tissue off after 30 minutes

Long lastinglipstick

Normal typelipstick

22All other company or product names are trademarks or registered trademarks of their respective companies or organizations.

This lipstick containing RISOCAST DA-L, RISOCAST ODSHS and TCG-M provides even coverage and medium adhesion.

LIPSTICK : MEDIUM TYPE Lab code : LST-12NA

Product name INCI name wt% Supplier

1. RISOCAST DA-LHYDROGENATED CASTOR OILDIMER DILINOLEATE 22.0 KOKYU ALCOHOL KOGYO CO., LTD.

2. RISOCAST ODSHS OCTYLDODECYL STEAROYL STEARATE 21.1 KOKYU ALCOHOL KOGYO CO., LTD.

3. TCG-M CAPRYLIC/CAPRIC TRIGLYCERIDE 21.1 KOKYU ALCOHOL KOGYO CO., LTD.

4. HAIMALATE DIS DIISOSTEARYL MALATE 13.1 KOKYU ALCOHOL KOGYO CO., LTD.

5. Pink pigment paste - 10.0 -

6. POLYWAX-500 POLYETHYLENE 4.8 Baker Hughes Incorporated

7. Refined Microcrystalline Wax MICROCRYSTALLINE WAX 4.2 NIKKO RICA CORPORATION

8. CANDELILLA WAX Super refine EUPHORBIA CERIFERA (CANDELILLA) WAX 3.6 Watahan Trading Co., Ltd.

9. d-δ-TOCOPHEROL TOCOPHEROL 0.1 Tama Biochemical Co., Ltd.

(1) Mix 1 - 9 into a suitable container and heat up.

(2) Stir until completely melted and well dispersed, and de-aerate.

(3) Pour into lipstick molds and cool down.

Process Stability : The stability has been confirmed at 25 ºC and 45 ºC for 3 months and by cycle test (5 ºC ↔ 25 ºC ↔ 45 ºC, 5 cycles).

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23All other company or product names are trademarks or registered trademarks of their respective companies or organizations.

This is a light and smooth texture lip gloss with RISOCAST DA-L.

RISOCAST DA-L gives natural glossy effect and prevents from looseness.

LIP GLOSS : LIGHT TYPE Lab code : LG-DA50NA

Product name INCI name wt% Supplier

1. RISOREX PGIS22 POLYGLYCERYL-2 DIISOSTEARATE 55.0 KOKYU ALCOHOL KOGYO CO., LTD.

2. KAK PTI PENTAERYTHRITYL TETRAISOSTEARATE 19.0 KOKYU ALCOHOL KOGYO CO., LTD.

3. HAILUCENT DPIN6 DIPENTAERYTHRITYL HEXAISONONANOATE 10.7 KOKYU ALCOHOL KOGYO CO., LTD.

4. RISOCAST DA-LHYDROGENATED CASTOR OIL DIMER DILINOLEATE 10.0 KOKYU ALCOHOL KOGYO CO., LTD.

5. Rheopearl KL2 DEXTRIN PALMITATE 4.0 Chiba Flour Milling Co., Ltd.

6. Hi-Mic-1090 MICROCRYSTALLINE WAX 1.0 NIPPON SEIRO CO., LTD.

7. Pink pigment paste - 0.2 -

8. d-δ-TOCOPHEROL TOCOPHEROL 0.1 Tama Biochemical Co., Ltd.

(1) Mix 1 - 8 into a suitable container and heat up.

(2) Stir until completely melted and well dispersed, and de-aerate.

(3) Cool down.

Process Stability : The stability has been confirmed at 25 ºC and 45 ºC for 3 months and by cycle test (5 ºC ↔ 25 ºC ↔ 45 ºC, 5 cycles).

24All other company or product names are trademarks or registered trademarks of their respective companies or organizations.

This night cream takes advantage of rich texture of RISOCAST DA-L.

It gives rich texture on the skin after applying on.

NIGHT CREAM : DA-L Lab code : SDJ-032/1

Process

Product name INCI name wt% Supplier

Oil

phas

e

1. RISOCAST DA-LHYDROGENATED CASTOR OIL DIMER DILINOLEATE 7.00 KOKYU ALCOHOL KOGYO CO., LTD.

2. TCG-M CAPRYLIC/CAPRIC TRIGLYCERIDE 5.00 KOKYU ALCOHOL KOGYO CO., LTD.

3. NPDIN NEOPENTYL GLYCOL DIISONONANOATE 5.00 KOKYU ALCOHOL KOGYO CO., LTD.

4. CETOSTEARYL ALCOHOL CETEARYL ALCOHOL 3.90 KOKYU ALCOHOL KOGYO CO., LTD.

Wat

er p

hase

5. HAISUGARCANE BG BUTYLENE GLYCOL 3.00 KOKYU ALCOHOL KOGYO CO., LTD.

6. DIOL PD PENTYLENE GLYCOL 3.00 KOKYU ALCOHOL KOGYO CO., LTD.

7. TEGO CARE CG 90 CETEARYL GLUCOSIDE 1.00 Evonik Industries AG

8. ARISTOFLEX AVCAMMONIUM ACRYLOYLDIMETHYLTAURATE/VP COPOLYMER 0.05 Clariant International Ltd.

9. SATIAXANE CX911 XANTHAN GUM 0.05 LASERSON SA

10. Purified water WATER 72.00 -

Stability : The stability has been confirmed at 25 ºC and 45 ºC for 3 months and by cycle test (5 ºC ↔ 25 ºC ↔ 45 ºC, 5 cycles).

pH : 6.5

(1) Mix 5, 6, 8 and 9 in a suitable container at RT.

(2) Add 7 - 10 and heat up to 75 ºC to obtain semi-transparent liquid without stirring.

(3) Mix 1 - 4 and heat up to 75 ºC.

(4) Heat up (2) to 75 ºC and pour (1) into (2) (1000 rpm, 8 min).

(5) Heat up (3) to 75 ºC and pour into (4) (1500 rpm, 5 min).

(6) Homogenize at 1500 rpm and cool down to RT.

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25All other company or product names are trademarks or registered trademarks of their respective companies or organizations.

This oil balm takes advantage of rich texture of RISOCAST DA-L.

It gives no unpleasant stickiness and smoothly melts on the skin.

FACE OIL BALM Lab code : FOB-3YK

(1) Mix 1 - 5 into a suitable container.

(2) Heat up to 90 ºC and stir until completely melted.

(3) Cool down to RT.

Process

Product name INCI name wt% Supplier

1. TCG-M CAPRYLIC/CAPRIC TRIGLYCERIDE 40.0 KOKYU ALCOHOL KOGYO CO., LTD.

2. NEOLIGHT 180P ISOSTEARYL NEOPENTANOATE 25.0 KOKYU ALCOHOL KOGYO CO., LTD.

3. KAK TTO TRIMETHYLOLPROPANE TRIETHYLHEXANOATE 25.0 KOKYU ALCOHOL KOGYO CO., LTD.

4. RISOCAST DA-L HYDROGENATED CASTOR OIL DIMER DILINOLEATE 5.0 KOKYU ALCOHOL KOGYO CO., LTD.

5. POLYWAX-500 POLYETHYLENE 5.0 Baker Hughes Incorporated

Stability : The stability has been confirmed at 25 ºC and 45 ºC for 3 months and by cycle test (5 ºC ↔ 25 ºC ↔ 45 ºC, 5 cycles).