Power and CO emissions to methanol Carbon Recycling...

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Carbon Recycling International Power and CO 2 emissions to methanol Benedikt Stefansson Director of Business Development 2015 European Methanol Policy Forum Brussels October 13 2015

Transcript of Power and CO emissions to methanol Carbon Recycling...

Page 1: Power and CO emissions to methanol Carbon Recycling ...eu-ems.com/event_images/presentations/Benedikt Stefansson...Carbon Recycling International Power and CO 2 emissions to methanol

CarbonRecyclingInternational

PowerandCO2emissionstomethanol

BenediktStefanssonDirectorofBusinessDevelopment2015EuropeanMethanolPolicyForumBrusselsOctober132015

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2007 2008 2009 2010 2011 2012 2013 2014 2015

Company launched in Reykjavik

Technologydevelopment

Pilot plantproduction

Plantengineering

Plant construction

Plantopening with1,300t/yrcapacity

Firstsales(exportsanddomestic)Methanexinvests

Plantexpanded to4,000t/yrcapacity

Marketing oftechnology&partnerships

Geely(ownerofVolvoCars)invests

BriefhistoryofCRI

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Methanol(orderivatives)

CO2

Lowcarbonintensitymethanol:energycarrier

Transportandindustry

Renewablepowerorbyproducthydrogen

CRIPower-to-Liquidstechnology

Fluegasemissions

CO2

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CRI’s Power-to-Liquidsplatform

CleanConversion

Lowcarbon-intensity

methanolCH3OH

CO2 Capture

HydrogenGeneration

Industrypartners CRIintegratedCCUandPtLsolutionIndustryemissions

Electricity

IndustryH2 byproduct

Offtake

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ETLmassenergybalanceandefficiency:electrolysis

CarbonCapture

Electrolysis

Compression Reaction Distillation 1tMeOH

0.193tH2;6.45MWhLHV

1.4tCO2

!=99%

0.59tH2O

Fluegas

9

Electricity 5.58MWhLHV

O2

Totalelectricalenergy9.5MWh/tmethanolwithoverallefficiencyof60%

Water

0.8MWhLHV thermal 0.45MWhLHV electric

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CarbonRecyclingInternational- Confidential

CRIfirstofitskindPower-to-LiquidsfacilityinIceland

GeorgeOlahCO2 tomethanolplant,Orkubraut2,Grindavik, IcelandFirstcommissioning:2012Capacityexpansion:2015CCUthroughput:5,600t/yrCO2Electrolyzercapacity:800t/yrH2 (1200Nm3/hr)Productioncapacity:4,000t/yrmethanol

ReykjavikGOPlantCleanConversion

CO2 Capture

HydrogenGenerationFlueGasSource

Product

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CO2 CO2

CO2 CO2 CO2

FrameworktocompareCO2 lifecycleemissionsoffuelsGasoline&diesel

=84gCO2/MJ

1-8gCO2/MJ

=33-54gCO2/MJ

Biofuels

7

CO2

CO2CO2

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FirstPtL plantwithISCC+certificationofsustainability

10/11/15 8

kgCO2e/tRM gCO2e/MJRMLHVEmissions relatedtoraw-material: 0 0Emissions ofelectricityproduction (grid) 134 6.71Emissions ofsteamproduction 4 0.22Emissions ofprocessspecific inputs: 4 0.21Emissions ofwastewatertreatment: 1 0.06Totalprocess-specificemissions: 143 7.2Plant-to-port(50kmbyroad) 7 0.34Port-to-port(2000kmcontainer ship) 20 1.00Totaltransport-specificemissions 27 1.3TotalemissionsCIFRotterdam 170 8.5Comparedtoreferencevalueof83.8gCO2e/MJfossil >90%reduction

ActualGHGemissionvaluesusingISCCEUGHGmodule*

*BasedonEUdirective2009/30/EC(FQD)

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StreamsofinnovationCRIfirsts AchievementUsedCO2 capturefromindustrialsourcestomaketransport fuel

� Processes15mt CO2 /dayintotransportfuel

Implementedlarge-scale electrolysisforpower-to-liquidsapplications

� Installedcapacity ofmulti-MWalkalineelectrolyzersforhydrogen production

Deliveredrenewablefuelofnon-biologicalorigintoEUmarket

� Gasolineblending andinbiodiesel inNetherlands,SwedenandIceland

Receivedcertificationfor renewablefuelofnon-biologicalorigin

� Certificationof90%reductionofCO2accordingtoEURenewableEnergyDirective

9

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The MHPSECRIPartnership

10/11/1510

Mitsubishi-HitachiPowerSystemsEurope(MHPSE)andCRIhavecombinedtheirresourcestoofferintegratedindustrialsolutionsforcarboncaptureandpower-to-methanolproduction.Byjoiningforces,thetwocompaniescanofferclientsacompletesuiteofservicesfrom:§ Feasibilitystudies;§ Turn-keycontracts,includingdesign,constructionofmodularizedsystems§ Pre-commissioning,erection,on-sitecommissioning,operatortraining;§ Post-purchaseservicesandoff-takecontracts

CarbonRecyclingInternational– Proprietary– Donotquote

Duisburg Reykjavik

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ThreeapplicationsofCRIPtL platformRenewableFuelEnergyUpgrade CapacityUtilization

Recoverhydrogenreleasedbychemicalandsteelplants

Useexcessthermalcapacitytomakehydrogen

Userenewableenergytomakehydrogen

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Project at Steag Lünen coal-power plant, Germany

Input: 1MWelectric+500t/yrCO2Output: 400t/yrmethanolCapacity:1t/day

CO2capture

HydrogenproductionCleanconversion

MethCO2 Horizon2020(€8.6/m)CollaborationwithSTEAG,MHPSE,Hydrogenics andEUuniversities

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SourcesofCarbonDioxide

13CarbonRecyclingInternational– Proprietary– Donotquote

ConcentratedCO2 inEU:>1.3billiontons

CO2Mt/year

Numberofsources

CO2 percent influe-gas

Powerplants 1033 795 15%

Steel 153 62 15-30%

Cement 125 215 15-30%

Ammonia 17 42 100%

1328 1114

LocationsofconcentratedCO2

Capturingcarbondioxidefromfluegaswithconcentration>15%

Equivalentto>27000siteswith100t/daycapacity

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Sourcesofhydrogen

14CarbonRecyclingInternational– Proprietary– Donotquote

Chemicalproduction siteswithH2 asaby-productandconcentratedCO2

Equivalentto>100siteswith100t/daycapacity

Longtermtotalproduction ofmethanol6million tonsperyear

FocusingonlocationswithconcentratedsourcesofH2 inEurope

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ETLmassenergybalanceandefficiency:capturedH2

CarbonCapture

PSA

Compression Reaction Distillation 1tMeOH

0.193tH2;6.45MWhLHV

1.4tCO2

!=99%

0.59tH2O

Fluegas

9

COG 5.58MWhLHV

Offgas

Totalenergy input:7.7MWh/tmethanolwithoverallefficiency>70%

*Notincluding PSA

0.8MWhLHV thermal 0.45MWhLHV electric

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Ironandsteelwastegasorbyproduct gas

Sodiumchlorideelectrolysis

Waterelectrolysis

Hydrocarbonarcfurnace

Electricity

Hydrogenseparationprocess

H2

Petrochemicalwasteandbyproductgas

Wasteorresidues

GasificationMSW

Syngas

CO2

Lowcarbonintensitymethanol

LowCarbonIntensityMethanolproductionprocesses

2015CarbonRecyclingInternational– Allrightsreserved

Energysource Upstreamtechnology LCIMfeedstocks LCIMoutput

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Opportunitiesforpower-to-methanolinEU-28

Diesel2970TWh/a

Gasoline970TWh

Gas210TWh

RES660TWh

Electricitydemand2140TWh

Unusedcapacitynuclearandthermal2330TWh

Electricitymarket5120TWh* Roadfuelmarket4157TWh*

Energyrecovery

Hydrogen fromcoke-ovengas37TWhHydrogen fromchlor-alkaliprocess9TWh

20%

20%

640TWh

SupplyofPtLmethanolPower-to-liquids

390TWh**

**33millionmetrictonsofoilequivalentCurrentgasolinecons.

Source:Eurostat2012, Eurochlor 2013,Eurocoal 2011

LowCO2 methanol310TWh

“Green”methanol80TWh

*Totalgeneratingcapacity

*Totalconsumption

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MethanolfromCO2andelectricityfortransitiontorenewablepowerandcleanfuel

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Intermittentenergysources Load-balancingpowergeneration

LowCO2 liquid fuel

CO2

1 2

4

6 Balancedgridsupply

Load-balancingPtL production3

M15-M100Fuel blend

5

Power

Distribution

Consumers

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