Poster congreso LACAME 2014
1
Results Your text would go here. Your text would go here. Methods & Materials Samples disoriented soils were taken from the productive layer (horizon A) of agricultural soils cultivated with sugar cane in the department of Valle del Cauca and Northern Cauca, taking into account the specifications of the Colombian Agricultural Institute (ICA), The Physical analysis -Chemicals samples were performed in the laboratory of soil (Laserex) of the University of Tolima, following procedure: drying at room temperature, sieved in 0.2 mesh and treated by the technique of bouyoucos, these were analyzed on a diffractometer X ray of internal working group of the national soil Agustin Codazzi laboratory, which allowed us to identify phases present and calculation of lattice parameters of the phases present in soils. The diffractograms were fitted using the Rietveld method which allowed the measurement of the lattice parameters. The analysis of electronic and magnetic properties of these phases containing iron (Fe), they were measured with Mössbauer spectrometer of Materials Science Group, University of Tolima. The spectra were refined and adjusted using the program special. Conclusions Acknowledgements We thank the Office of Research of the University of Tolima for their support., The Department of Physics, the research group in Materials Science, University of Tolima PROPERTIES MINERALOGICAL, STRUCTURAL AND ELECTRONIC OF DISORIENTED SOIL SAMPLES OF THE CULTIVATED WITH SUGAR CANE USING ANALYSIS: PHYSICAL-CHEMICAL, X-RAY DIFFRACTION (XRD) AND MÖSSBAUER SPECTROMETRY (MS) F. M. Vargas Fontalvo 1* , H. Bustos Rodríguez 1 , D. Oyola Lozano 1 , Y.A. Rojas Martínez 1 , E.A. Ávila Pedraza 1 , y G. A. Pérez Alcázar 2 1 Departamento de Física: Ciencia de Materiales, Universidad del Tolima, A.A.,Ibagué 2 Departamento de Física: Metalúrgica Física y Física de transiciones de Fase, Universidad del Valle ,A A Cali Your text would go here. In soil samples disoriented sugarcane grown in the Valle del Cauca-Colombia, were measured by Mössbauer spectroscopy analysis of the mineral phases in the presence of iron ore (Fe), belonging to Fe 2 and 3. We confirm that the MS is a complementary and valid for the analysis of agricultural soils technique. Some of these same phases were determined by X- ray also. The Mössbauer spectrometry serves as an additional technique for the analysis of agricultural soils because soils are rich in iron and Mössbauer spectroscopy determined phases containing iron. Quartz was the mineral that was present in all samples when he applied the technique of X-ray diffraction (XRD) also found this technique other minerals such as andesine, illite Figure. 1 Setting Mössbauer spectra Agricultural soils cultivated with sugar cane in the department of Valle del Cauca and northern Cauca FR57 (a), FR47 (b) FR74 (c) FR90 (d) FR38 (e) Figure 2. Floors of the diffractograms of sugarcane cultivation in the department of Valle del Cauca samples FR57 (a), FR47 (b) FR74 (c) FR90 (d) FR38 (e) 0 20 40 60 1000 2000 3000 4000 5000 Intensity 1/2 [Count 1/2 ] 2 Sample 4-09486-FR-57 Quartz Biotite Muscovite Andesine 0 10 20 30 40 50 60 70 1000 2000 3000 4000 5000 6000 Intensity 1/2 [Count 1/2 ] 2 Sample 4-09485-FR47 Quartz Andesine Biotite Nontronite 0 20 40 60 1000 2000 3000 4000 5000 6000 7000 8000 9000 10000 11000 12000 13000 14000 Intensity 1/2 [Count 1/2 ] 2 Sample 4-09491-FR-90 Quartz Muscovite Andesine 0 20 40 60 1000 2000 3000 4000 Intensity 1/2 [Count 1/2 ] 2 Sample 4-09489-FR-74 Quartz Illite Andesine 0 10 20 30 40 50 60 70 1000 2000 3000 4000 5000 Intensity1/2 [Count1/2] 2 Sample 4-09484- FR-38 Quartz Muscovite Illite Sample Component DI(mms-1) ± 0.050 SQ (mms1) ± 0.050 GA Area (%) FR-57 Fe +2 1.703 1.549 0.302 32.50 Fe +3 0.332 0.640 0.189 28.09 Fe +3 0.015 0.500 0.244 39.41 FR-47 Fe +2 1.181 2.198 0.209 54.76 Fe +3 0.387 1.126 0.283 21.39 Fe +3 0.240 0.766 0.141 23.85 FR-38 Fe +3 0.361 0.500 0.172 63.94 Fe +3 0.343 0.727 0.301 36.06 FR-90 Fe +2 1.198 2.086 0.442 12.85 Fe +3 0.355 0.747 0.242 44.40 Fe +3 0.359 0.477 0.142 42.75 FR-74 Fe +2 1.079 2.541 0.249 24.51 Fe +3 0.412 0.850 0.498 33.26 Fe +3 0,351 0.452 0.229 42.23 Table.1 Parameters of Mössbauer spectra of the agricultural soils cultivated with sugar cane in the department of Valle del Cauca and northern Cauca FR57 (a), FR47 (b) FR74 (c) FR90 (d) FR38 (e) -9 -6 -3 0 3 6 9 0,96 0,98 1,00 Sample FR57 Exp Total Fe +2 Fe +3 Fe +3 relative transmission V [mm/s] a. SOIL CULTIVATED WITH SUGAR CANE -9 -6 -3 0 3 6 9 0,90 0,95 1,00 Exp The Fe +2 Fe +3 Fe +3 Sample FR47 SOIL CULTIVATED WITH SUGAR CANE relative transmission V [mm/s] -9 -6 -3 0 3 6 9 0,92 0,94 0,96 0,98 1,00 Sample FR90 Today's date is 14/10/2014 The Document name is: ".opj, importp" Exp Total Fe +2 Fe +3 Fe +3 relative transmission V [mm/s] c. SOIL CULTIVATED WITH SUGAR CANE -9 -6 -3 0 3 6 9 0,94 0,96 0,98 1,00 Sample FR74 Today's date is 08/11/2014 The Document name is: "UNTITLED.opj, importp" Exp The Fe +2 Fe +3 Fe +3 relative transmission V [mm/s] d. SOIL CULTIVATED WITH SUGAR CANE -9 -6 -3 0 3 6 9 0,92 0,94 0,96 0,98 1,00 Sample FR38 Exp Total Fe +3 Fe +3 relative transmission V [mm/s] e. SOIL CULTIVATED WITH SUGAR CANE Introduction Samples disoriented soils were taken from the productive layer (horizon A) of agricultural soils cultivated with sugar cane in the department of Valle del Cauca and Northern Cauca, taking into account the specifications of the Colombian Agricultural Institute (ICA), The Physical analysis - Chemicals samples were performed in the laboratory of soil (Laserex) of the University of Tolima, following procedure: drying at room temperature, sieved in 0.2 mesh and treated by the technique of bouyoucos, these were analyzed on a diffractometer X ray of internal working group of the national soil Agustin Codazzi laboratory, which allowed us to identify phases present and calculation of lattice parameters of the phases present in soils. The diffractograms were fitted using the Rietveld method which allowed the measurement of the lattice parameters. The analysis of electronic and magnetic properties of these phases containing iron (Fe), they were measured with Mössbauer spectrometer of Materials Science Group, University of Tolima. The spectra were refined and adjusted using the program special. Abstract
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Transcript of Poster congreso LACAME 2014
Results
Your text would go here. Your text would go here.
Methods & Materials Samples disoriented soils were
taken from the productive layer
(horizon A) of agricultural soils
cultivated with sugar cane in
the department of Valle del
Cauca and Northern Cauca,
taking into account the
specifications of the Colombian
Agricultural Institute (ICA), The
Physical analysis -Chemicals
samples were performed in the
laboratory of soil (Laserex) of
the University of Tolima,
following procedure: drying at
room temperature, sieved in
0.2 mesh and treated by the
technique of bouyoucos, these
were analyzed on a
diffractometer X ray of internal
working group of the national
soil Agustin Codazzi laboratory,
which allowed us to identify
phases present and calculation
of lattice parameters of the
phases present in soils. The
diffractograms were fitted using
the Rietveld method which
allowed the measurement of
the lattice parameters. The
analysis of electronic and
magnetic properties of these
phases containing iron (Fe),
they were measured with
Mössbauer spectrometer of
Materials Science Group,
University of Tolima. The
spectra were refined and
adjusted using the program
special.
Conclusions
Acknowledgements We thank the Office of Research
of the University of Tolima for their
support., The Department of
Physics, the research group in
Materials Science, University of
Tolima
PROPERTIES MINERALOGICAL, STRUCTURAL AND ELECTRONIC OF DISORIENTED SOIL SAMPLES OF THE CULTIVATED WITH SUGAR CANE
USING ANALYSIS: PHYSICAL-CHEMICAL, X-RAY DIFFRACTION (XRD) AND MÖSSBAUER SPECTROMETRY (MS)
F. M. Vargas Fontalvo1*, H. Bustos Rodríguez1, D. Oyola Lozano1, Y.A. Rojas Martínez1, E.A. Ávila Pedraza1, y G. A. Pérez Alcázar2
1Departamento de Física: Ciencia de Materiales, Universidad del Tolima, A.A.,Ibagué 2 Departamento de Física: Metalúrgica Física y Física de transiciones de Fase, Universidad del Valle ,A A Cali
Your text would go here.
In soil samples disoriented
sugarcane grown in the Valle
del Cauca-Colombia, were
measured by Mössbauer
spectroscopy analysis of the
mineral phases in the presence
of iron ore (Fe), belonging to Fe
2 and 3. We confirm that the MS
is a complementary and valid for
the analysis of agricultural soils
technique. Some of these same
phases were determined by X-
ray also.
The Mössbauer spectrometry
serves as an additional
technique for the analysis of
agricultural soils because soils
are rich in iron and Mössbauer
spectroscopy determined
phases containing iron.
Quartz was the mineral that was
present in all samples when he
applied the technique of X-ray
diffraction (XRD) also found this
technique other minerals such
as andesine, illite
Figure. 1 Setting Mössbauer spectra Agricultural soils cultivated with sugar cane in the department of Valle del Cauca and northern Cauca FR57 (a), FR47 (b)
FR74 (c) FR90 (d) FR38 (e)
Figure 2. Floors of the diffractograms of sugarcane cultivation in the department of Valle del Cauca samples FR57 (a), FR47 (b) FR74 (c) FR90 (d) FR38 (e)
0 20 40 60
1000
2000
3000
4000
5000
Inte
ns
ity
1/2 [
Co
un
t1/2]
2
Sample 4-09486-FR-57
Quartz
Biotite
Muscovite
Andesine
0 10 20 30 40 50 60 70
1000
2000
3000
4000
5000
6000
Inte
nsi
ty1
/2 [C
ou
nt1
/2]
2
Sample 4-09485-FR47
Quartz
Andesine
Biotite
Nontronite
0 20 40 60
1000
2000
3000
4000
5000
6000
7000
8000
9000
10000
11000
12000
13000
14000
Inte
nsi
ty1
/2 [C
ou
nt1
/2]
2
Sample 4-09491-FR-90
Quartz
Muscovite
Andesine
0 20 40 60
1000
2000
3000
4000
Inte
nsi
ty1
/2 [C
ou
nt1
/2]
2
Sample 4-09489-FR-74
Quartz
Illite
Andesine
0 10 20 30 40 50 60 70
1000
2000
3000
4000
5000
Inte
ns
ity
1/2
[C
ou
nt1
/2]
2
Sample 4-09484- FR-38
Quartz
Muscovite
Illite
Sample Component DI(mms-1) ± 0.050 SQ (mms1) ± 0.050 GA Area (%)
FR-57 Fe+2 1.703 1.549 0.302 32.50
Fe+3 0.332 0.640 0.189 28.09
Fe+3 0.015 0.500 0.244 39.41
FR-47 Fe+2 1.181 2.198 0.209 54.76
Fe+3 0.387 1.126 0.283 21.39
Fe+3 0.240 0.766 0.141 23.85
FR-38 Fe+3 0.361 0.500 0.172 63.94
Fe+3 0.343 0.727 0.301 36.06
FR-90 Fe+2 1.198 2.086 0.442 12.85
Fe+3 0.355 0.747 0.242 44.40
Fe+3 0.359 0.477 0.142 42.75
FR-74 Fe+2
1.079 2.541 0.249 24.51
Fe+3 0.412 0.850 0.498 33.26
Fe+3 0,351 0.452 0.229 42.23
Table.1 Parameters of Mössbauer spectra of the agricultural soils cultivated with sugar cane in the department of Valle del Cauca
and northern Cauca FR57 (a), FR47 (b) FR74 (c) FR90 (d) FR38 (e)
-9 -6 -3 0 3 6 90,96
0,98
1,00
Sample FR57
Exp
Total
Fe+2
Fe+3
Fe+3
re
lati
ve
tra
ns
mis
sio
n
V [mm/s]
a. SOIL CULTIVATED WITH SUGAR CANE
-9 -6 -3 0 3 6 90,90
0,95
1,00
Exp
The
Fe+2
Fe+3
Fe+3
Sample FR47
SOIL CULTIVATED WITH SUGAR CANE
re
lati
ve
tra
ns
mis
sio
n
V [mm/s]
-9 -6 -3 0 3 6 90,92
0,94
0,96
0,98
1,00
Sample FR90
Today's date is 14/10/2014
The Document name is:
".opj, importp"
Exp
Total
Fe+2
Fe+3
Fe+3
rela
tiv
e t
ran
sm
iss
ion
V [mm/s]
c. SOIL CULTIVATED WITH SUGAR CANE
-9 -6 -3 0 3 6 9
0,94
0,96
0,98
1,00
Sample FR74
Today's date is 08/11/2014
The Document name is:
"UNTITLED.opj, importp"
Exp
The
Fe+2
Fe+3
Fe+3
rela
tiv
e t
ran
sm
iss
ion
V [mm/s]
d.SOIL CULTIVATED WITH SUGAR CANE
-9 -6 -3 0 3 6 9
0,92
0,94
0,96
0,98
1,00
Sample FR38
Exp
Total
Fe+3
Fe+3
rela
tiv
e t
ran
sm
iss
ion
V [mm/s]
e. SOIL CULTIVATED WITH SUGAR CANE
Introduction Samples disoriented soils were
taken from the productive layer
(horizon A) of agricultural soils
cultivated with sugar cane in the
department of Valle del Cauca
and Northern Cauca, taking into
account the specifications of the
Colombian Agricultural Institute
(ICA), The Physical analysis -
Chemicals samples were
performed in the laboratory of
soil (Laserex) of the University
of Tolima, following procedure:
drying at room temperature,
sieved in 0.2 mesh and treated
by the technique of bouyoucos,
these were analyzed on a
diffractometer X ray of internal
working group of the national
soil Agustin Codazzi laboratory,
which allowed us to identify
phases present and calculation
of lattice parameters of the
phases present in soils. The
diffractograms were fitted using
the Rietveld method which
allowed the measurement of the
lattice parameters. The analysis
of electronic and magnetic
properties of these phases
containing iron (Fe), they were
measured with Mössbauer
spectrometer of Materials
Science Group, University of
Tolima. The spectra were
refined and adjusted using the
program special.
Abstract
