pH Elektrode Brochure en 51724332F V12.12

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  • Lab

    Sens

    ors

    InLab Electrodes

    pH electrodes

    Conductivity probes

    Dissolved oxygen sensors

    ORP electrodes

    Ion-selective electrodes

    Reference electrodes

    Electrode cables and accessories

    Buffers, electrolytes and cleaning solutions

    Simply Reliable The Right Electrode Every Time

    Cont

    ents

  • INGOLD Leading Process Analytics

    Intelligent Sensor Management

    Intelligent Sensor Management

    INGOLD Leading Process Analytics

    Cont

    ents

    The SevenCompact and SevenGo Duo meters incorporate Intelligent Sensor Management (ISM). This ingenious func-tionality offers great advantages such as:

    After connection of ISM sensor immedi-ate transfer of current sensor calibration data and Sensor ID to meter.

    After calibration of ISM sensor immedi-ate transfer of calibration data from meter to sensor chip.

    When an ISM sensor is connected, the initial calibration data in the sensor can be reviewed and transferred to a PC or printer.

    The last 5 calibration data stored in ISM sensor including current calibration can be reviewed and transferred to a PC or printer.

    The maximum temperature that the ISM sensor has been exposed to during measurement is monitored automatically and can be reviewed for valuation of electrode lifetime.

    INGOLD has been producing electrodes since 1948, a name that has been syno-nymous with the success of combined pH electrodes ever since. In 1986 INGOLD joined the METTLER TOLEDO group. The result is the development of the InLab range of laboratory electrodes. InLab is thus the product of over 60 years of expe-rience in the manufacture of electrochemi-cal sensors. And so the tradition continues with every METTLER TOLEDO sensor: INGOLD inside

  • Cont

    ents

    InLab GlossaryDesignation Description

    Type of membrane glass

    A41 glassParticularly resistant to chemicals; suitable for high temperatures up to 130 C; ideal for biological media.

    HA glassHigh alkali glass for use at high pH values and high temperatures; extremely low alkali errors; extremely robust membrane.

    HF glassEspecially suitable for media containing hydrofluoric acid; up to a HF concentration of 1 g/L.

    LoT glassLow resistance glass for use at low temperatures (LoT = low temperature); also suitable for low ion concentrations (ultra-pure water); the glass of choice for thick membranes (puncture or surface electrodes).

    U glassUniversal glass, tried & tested in standard applications; especially suitable for small membranes (microelectrodes).

    Type of junction

    Click & ClearThanks to the press mechanism, the sleeve junction is easy to open with combined perfectION ISE; quick cleaning and stable measurement values are ensured even in difficult samples.

    Movable glass or PTFE sleeve

    Movable sleeve junctions that can be easily and thoroughly cleaned.

    Immovable glass sleeve

    Fixed sleeve junctions for large contact area between reference electrolyte and measurement solution.

    CeramicConventional ceramic junctions for liquid electrolytes or in combination with SteadyForce.

    Ceramic ring Large ring-shaped ceramic junctions for flat membranes.

    Open junctionOpen connections without junctions together with XEROLYT polymer electrolyte.

    Porous PTFE Large contact surface polytetrafluoroethylene (PTFE) junctions.

    Technologies, reference systems and reference electrolytes

    ARGENTHAL

    AgCl granulate-filled cartridge, which supplies the silver ions for the chemical reaction on the conducting wire. The silver ion trap stops the Ag+ ions from discharging into the electrolyte solution,thus preventing contamination of the junction when using sulfides and proteins.

    DPA-Gel Gel electrolyte for electrodes with SteadyForce.driTEK Reference system for ISFET electrodes.

    EquithalSymmetrically structured conducting elements guarantee minimum response times and highly stable potentials when fluctuating temperatures are involved.

    FRISCOLYTSpecial electrolyte for measurements at low temperatures and for media with organic components (e.g. oil, proteins, etc.). Recommended for storage of electrodes with XEROLYT.

    ISM (Intelligent Sensor Management)

    In sensors with ISM, important information, such as calibration data, is stored on a chip directly in the sensor and automatically detected by the meter. Only with SevenCompact and SevenGo Duo meters.

    SteadyForceReference system in which the electrolyte is pressurized (3 bar) to ensure discharge of electrolyte even in viscous samples.

    XEROLYT Solid polymer electrolyte in combination with open connections.

    Shaft materials

    Stainless steel 316L (V4A) grade stainless steel.

    EpoxyVery strong plastic with excellent chemical and mechanical resistance. For very robust sensors.

    PEEKPolyetheretherketone: Highly temperature-resistant plastic with excellent chemical and mechanical resistance. For professional and heavy-duty sensors.

    Polysulfone Plastic with good chemical and mechanical resistance.

    PPSPolyphenylene sulfide: Partly crystalline, highly temperature-resistant plastic with excellent chemical and mechanical resistance. For robust dissolved oxygen sensors.

  • 2

    Cont

    ents

  • 3Contents

    Competences page 4 Inspirational Solutions The Quick Electrode Guide page 6 Which pH Electrode for Which Application? Routine pH Electrodes page 8 Steady Companions Professional pH Electrodes page 10 Defying the Laws of Physics InLab pH Specialists page 12 Through Thick and Thin Economy pH Electrodes page 18 Robust and Cost Effective pH Half-cells and Reference Electrodes page 19 Useful Helpers RedCap pH Specialists page 20 Artistry in Glass ORP Electrodes page 22 High Potentials Conductivity Probes page 24 Ions in Motion SevenGo Sensors page 26 The Right Electrode Every Time Combined Ion-selective Electrodes page 28 Precise Determinations Ion-selective Half-cells page 30 Tried and Trusted Solutions page 32 Amazing Solutions Accessories page 35 The Right Accessory Every Time Cables and Plugs page 36 Plugnplay... The Seven Instrument Family page 39 Simple and Accurate Measurements

    Irrespective of the industry or application we have the solution for youMETTLER TOLEDO sensors cover innumerable applications in chemical, pharmaceutical, food-processing, cosmetic, biological and many other laboratory and production facilities. Select the electrode that matches your requirements from the application table on page 6 or at www.mt.com/electrode-guide.

  • 4

    Com

    pete

    nces Inspirational Solutions

    Electrochemical sensors are used in a wide variety of applications. METTLER TOLEDO offers a similarly wide variety of select products to help you find the ideal solution for your precise application. Our range focuses on the correct combination of high-quality materials, tried-and-tested technologies, and innovation. You will therefore find reliable and robust sensors for your routine mea-surements, as well as powerful specialist products for specific requirements.

    For the selection and development of our products, it is important for us to know precisely the requirements of our customers. With this knowledge, combined with many years of experience in the manufacturing of electrochemical sensors, we can therefore proudly present a product range that continues to produce success. Customers with an extremely wide range of requirements have tested, and are inspired by, our sensors. See for yourself!

    Solid foundationThe InLab Routine Pro is a reliable work-horse for any lab. With EQUITHAL tech-nology and the ARGENTHAL reference system including silver ion trap, this sensor fulfills two fundamental requirements for optimum pH measurement. I can rely on fast response behavior and clean junctions. The InLab Science with sleeve junction is used for more complex sample matrices, such as emulsions or biological media.

    For more information, see pages 89.

    Well-equipped for challenging tasksFor my more technically challenging measurements, I need an electrode such as the InLab Expert. With its highly resistant PEEK shaft and XEROLYT polymer elec-trolyte with open junction, it is built to with-stand even the toughest conditions. When the very highest performance is expected, I opt for the InLab Power with the success-ful SteadyForce reference system.

    For more information, see pages 1011.

    When form is a factorI expect a pH electrode to be optimally equipped for my specific measurements. Electrodes such as the InLab Solids for penetration measurements, or the InLab Micro for the measurement of small quanti-ties have the correct combination of form, membrane glass, and reference system, and fulfill these expectations perfectly.

    For more information, see pages 1217.

    InLab Science, InLab Routine Pro

    InLab Expert, InLab Power

    InLab Surface, InLab Solids, InLab Micro, InLab Semi-Micro

  • 5Combined power for ORP/Redox measurementWhen taking redox measurements in different samples, the right combination of precious metal and junction type is all-important. For my diverse applications I therefore opt for the InLab Redox platinum electrode. Thanks to the InLab Redox Pro with glass sleeve junction, blocked junc-tions in complex samples are no longer an issue.

    For more information, see pages 2223.

    Equipped for mobile use Mix-ups can happen easily when on the move. Im glad that the pH electrode InLabExpert-Pro-ISM-IP67 with Intelligent Sensor Management technology keeps track at the same time. For use in the fac-tory, I require a robust and watertight sen-sor such as the InLab 605 for dissolved oxygen, or the InLab 742 for conductivity.

    For more information, see pages 2627.

    Sensitive to ionsThanks to the replaceable membrane module on the DX218-NH4

    +, I can replace my ammonium half-cell with another half-cell at any time. The perfectION comb F-, with its integrated reference electrode and matching accessories, offers the complete solution for my fluoride measurement.

    For more information,see pages 2831.

    Conductivity on all levelsSince my measurements in distilled water require absolute precision, I like to rely on the stainless steel InLab 741, in which the actual cell constant has already been deter-mined for me. For samples with higher con-ductivity, the InLab 731 delivers the required results.

    For more information, see pages 2425.

    InLab Redox, InLab Redox Pro

    InLab 741, InLab 731

    InLab Expert Pro-ISM-IP67, InLab 605-ISM, InLab 742-ISM

    DX218-NH4+, perfectION comb F

  • 6

    The

    Qui

    ck E

    lect

    rode

    Gui

    deWhich pH Electrode for Which Application?

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    ne Pr

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    ode

    See page 8/9 See page 10/11 See page 12/13 See page 14/15 See page 16/17 See page 18 See page 19 See page 20/21

    Electrode properties as selection criteria

    Integrated temperature probe (ATC)

    With cable (attached lead)

    Low maintenance (electrolyte)

    TRIS buffer compatibility

    Aqueous samples Cold samples (< 5 C) Hot samples (> 100 C) Waste water With average conductivity Brine, highly saline solutions

    Cosmetic or viscous samples Gels, soaps & shampoos Hair tinting lotion Skin Cosmetic creams & mascara Natural & synthetic resins

    Pharmaceutical & biological samples

    Vials & NMR samples Serums & gastric juice, test tubes Medicinal formulations Proteinaceous media Enzyme solutions

    Pure and ultrapure water Soft surface water Sterile purified water Distilled water Water for injection Drinking water

    Beverages and dairy products Milk & cream Soft drinks & beer Wine & vinegar Butter, yogurt & ice-cream Cheese

    Food & agricultural products

    Jam & preserves Meat & fish Fruit & vegetables Dough & cocoa Fertilizer & manure

    Surface measurements Skin & leather Textiles & prints Paper & laminates Gelled agar Drop size samples

    Paints, dyes & emulsions Water-based paint Suspended solids (e.g. soil) Oily samples & emulsions Colorants & dyes Varnish & glue

    Chemicals & baths Alcohols, aldehydes & ketones HF bearing media (< 1 g/L) Photographic or galvanic baths Hydrocarbons Corrosive & hot acids/bases

    Large sample vessels Pilot reactors Deep vessels Tanks & barrels Boiler feed water Aquariums

  • 7Powe

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    -Micr

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    Flex-M

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    HA42

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    HA40

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    -611

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    -S7/4

    0

    See page 8/9 See page 10/11 See page 12/13 See page 14/15 See page 16/17 See page 18 See page 19 See page 20/21

    Electrode properties as selection criteria

    Integrated temperature probe (ATC)

    With cable (attached lead)

    Low maintenance (electrolyte)

    TRIS buffer compatibility

    Aqueous samples Cold samples (< 5 C) Hot samples (> 100 C) Waste water With average conductivity Brine, highly saline solutions

    Cosmetic or viscous samples Gels, soaps & shampoos Hair tinting lotion Skin Cosmetic creams & mascara Natural & synthetic resins

    Pharmaceutical & biological samples

    Vials & NMR samples Serums & gastric juice, test tubes Medicinal formulations Proteinaceous media Enzyme solutions

    Pure and ultrapure water Soft surface water Sterile purified water Distilled water Water for injection Drinking water

    Beverages and dairy products Milk & cream Soft drinks & beer Wine & vinegar Butter, yogurt & ice-cream Cheese

    Food & agricultural products

    Jam & preserves Meat & fish Fruit & vegetables Dough & cocoa Fertilizer & manure

    Surface measurements Skin & leather Textiles & prints Paper & laminates Gelled agar Drop size samples

    Paints, dyes & emulsions Water-based paint Suspended solids (e.g. soil) Oily samples & emulsions Colorants & dyes Varnish & glue

    Chemicals & baths Alcohols, aldehydes & ketones HF bearing media (< 1 g/L) Photographic or galvanic baths Hydrocarbons Corrosive & hot acids/bases

    Large sample vessels Pilot reactors Deep vessels Tanks & barrels Boiler feed water Aquariums

    Professional supportYou will find a quick and easy interactive guide to help you select the right sensor for your application at www.mt.com/electrode-guide. Here you will be able to access additional information such as photographs and download detailed specification sheets for each individual electrode.

  • 8

    Steady Companions

    Rout

    ine

    pH E

    lect

    rode

    s

  • 9InLab 1) Routine Routine-L 1) Routine Pro Routine Pt1000 Routine Pro-L Science Science Pro

    Order number 51343050 51343053 51343054 51343056 51343057 51343070 51343071

    Order number ISM version 51344055 51344072

    pH range 0...14 0...14 0...14 0...14 0...14 0...12 0...12

    Temperature probe NTC30k Pt1000 Pt1000 NTC30k

    Type of membrane glass HA HA HA HA HA A41 A41

    Membrane resistance (25 C)