PEEL HERE —— TO OPEN Herbicide - CDMS · (If you do not understand the label, ... , SHADOW 3EC...

H e r b i c i d e

Active Ingredient:Clethodim, (E)-2[1-[[(3-chloro-2-propenyl)oxy]limino]propyl]-5-[2-(ethylthio)propyl]- 3-hydroxy-2-cyclohexen-1-one . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 36 .7%Other Ingredients*: . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 63 .3%Total: . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 100 .0%* Contains Petroleum Distillates Contains: 3 .0 lb Clethodim per gallon

See inside booklet for additional precautionary statements.

KEEP OUT OF REACH OF CHILDREN CAUTION/PRECAUCÍON

Si usted no entiende la etiqueta, busque a alguien para que se la explique a usted en detalle . (If you do not understand the label, find someone to explain it to you in detail .)

For Product Use Information, call 1-866-761-9397

Produced for: EPA Reg . No . 66330-414Arysta LifeScience North America, LLC EPA Est . No . 070989-MO-00115401 Weston Parkway, Suite 150 AD041113Cary, NC 27513103439—101713

Net Contents: 2.5 Gallon

PEEL HERE —— TO OPEN'

GROUP 1 HERBICIDE

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FIRST AID

If swallowed: • Immediatelycallapoisoncontrolcenterordoctor.• Donotinducevomitingunlesstoldtodosobythepoisoncontrolcenterordoctor.• Donotgiveanyliquidtotheperson.• Donotgiveanythingbymouthtoanunconsciousperson.

If in eyes: • Holdeyeopenandrinseslowlyandgentlywithwaterfor15–20minutes.• Removecontactlenses,ifpresent,afterthefirst5minutes,thencontinuerinsingeye.• Callapoisoncontrolcenterordoctorfortreatmentadvice.

If on skin or clothing: • Takeoffcontaminatedclothing.• Rinseskinimmediatelywithplentyofwaterfor15–20minutes.• Callapoisoncontrolcenterordoctorforfurthertreatmentadvice.

If inhaled: • Movepersontofreshair.• Ifpersonisnotbreathing,call911oranambulance,thengiveartificialrespiration,preferablymouth-to-mouth,ifpossible.• Callapoisoncontrolcenterordoctorfortreatmentadvice.

NOTE TO PHYSICIAN: Containspetroleumdistillates.Ingestionofthisproductorsubsequentvomitingcanresultinaspirationoflighthydrocarbonliquid,whichcancauseaspiration pneumonitis .

HOT LINE NUMBERHavetheproductcontainerorlabelwithyouwhencallingapoisoncontrolcenterordoctor,orgoingfortreatment.

FOR 24- HOUR MEDICAL EMERGENCY ASSISTANCE CALL: 1-866-303-6952 or 1-651-632-8946FOR 24-HOUR CHEMICAL EMERGENCY: Spill,leak,fire,exposure,oraccidentcallCHEMTRECat1-800-424-9300or1-703-527-3887ifcallingfromoutsideoftheU.S.

PRECAUTIONARY STATEMENTSHAZARDS TO HUMANS & DOMESTIC ANIMALS

CAUTION:Harmfulifswallowed.Causesmoderateeyeirritation.Washthoroughlywithsoapandwaterafterhandlingandbeforeeating,drinking,chewinggum,usingtobaccoorusingthetoilet.Avoidcontactwitheyesorclothing.Wearprotectiveeyewear,Long-sleevedshirtandlongpants,Socks,shoesandchemicalresistantgloves(suchasBarrierLaminate,ButylRubber,NitrileRubber,Viton,SelectionCategoryF,G).

PERSONAL PROTECTIVE EQUIPMENT (PPE)Applicators and other handlers must wear:• Long-sleevedshirtandlongpants• Chemical-resistantgloves,CategoryG(suchasBarrierLaminateorViton≥ 14 mils) .

– Formoreoptions,followtheinstructionsforCategoryGonanEPAchemical-resistancecategoryselectionchart.• Shoesplussocks• ProtectiveeyewearDiscardclothingandotherabsorbentmaterialsthathavebeendrenchedorheavilycontaminatedwiththisproduct’sconcentrate.Donotreusethem.Followmanufacturer’sinstruc-tions for cleaning/maintaining PPE . If no such instructions for washables exist, use detergent and hot water . Keep and wash PPE separately from other laundry .

ENGINEERING CONTROLS STATEMENTSWhen handlers use closed systems, enclosed cabs, or aircraft in a manner that meets the requirements listed in the Worker Protection Standard (WPS) for agricultural pesticides [40 CFR170.240(d)(4–6)],thehandlerPPErequirementsmaybereducedormodifiedasspecifiedintheWPS.

USER SAFETY RECOMMENDATIONSUsersshould:• Washhandsbeforeeating,drinking,chewinggum,usingtobaccoorusingthetoilet.• Removeclothing/PPEimmediatelyifpesticidegetsinside.Thenwashthoroughlyandputoncleanclothing.• RemovePPEimmediatelyafterhandlingthisproduct.Washtheoutsideofglovesbeforeremoving.Assoonaspossible,washthoroughlyandchangeintocleanclothing.

ENVIRONMENTAL HAZARDSDo not apply directly to water, to areas where surface water is present or to intertidal areas below the mean high water mark . Do not apply where runoff is likely to occur . Do not applywhereweatherconditionsfavordriftfromareastreated.Donotcontaminatewaterwhendisposingofequipmentwashwaterorrinsate.TheuseofthisproductmayposeahazardtothefederallydesignatedendangeredspeciesofSolanoGrassandWildRice.Useofthisproductisprohibitedinthefollowingareaswhere the species are known to exist:Solano Grass:SolanoCounty,California:thevernallakesareaboundedbytheUnionPacificRailroadandHastingsRoadtothenorth,Highway113totheeast,Highway12tothesouth,andTravisAirForceBasetothewest.Wild Rice:HaysCounty,Texas

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Important.Read these entire DIRECTIONS FOR USE and WARRANTY AND DISCLAIMER STATEMENTbeforeusingSHADOW3ECHERBICIDE.

PHYSICAL OR CHEMICAL HAZARDSCombustible: Do not use or store near heat or open flame .

DIRECTIONS FOR USEItisaviolationofFederallawtousethisproductinamannerinconsistentwithitslabeling.Donotapplythisproductinawaythatwillcontactworkersorotherpersons,eitherdirectlyorthroughdrift.Onlyprotectedhandlersmaybeintheareaduringapplication.ForanyrequirementsspecifictoyourStateorTribe,consulttheagencyresponsibleforpesticideregulation.

AGRICULTURAL USE REQUIREMENTSUsethisproduceonlyinaccordancewithitslabelingandwiththeWorkerProtectionStandard,40CFRPart170.ThisStandardcontainsrequirementsfortheprotectionofagri-cultural workers on farms, forests, nurseries, and greenhouses, and handlers of agricultural pesticides . It contains requirements for training, decontamination, notification, and emergencyassistance.ItalsocontainsspecificinstructionsandexceptionspertainingtothestatementsonthislabelaboutPersonalProtectiveEquipment(PPE)andrestricted-entryinterval.TherequirementsinthisboxonlyapplytousesofthisproductthatarecoveredbytheWorkerProtectionStandard.Do not enter or allow worker entry into treated areas during the restricted entry interval (REI) of 24 hours. PPErequiredforearlyentrytotreatedareasthatispermittedundertheWorkerProtectionStandardandthatinvolvescontactwithanythingthathasbeentreated,suchasplants,soil, or water, is:• Coveralls• Chemical-resistantgloves,CategoryG(suchasBarrierLaminateorViton≥ 14 mils)• Shoesplussocks• Protectiveeyewear.

NON-AGRICULTURAL USE REQUIREMENTSTherequirementsinthisboxapplytousesofthisproductthatareNOTwithinthescopeoftheWorkerProtectionStandardforagriculturalpesticides(40CFRPart170).TheWPSapplies when this product is used to produce agricultural plants on farms, forest, nurseries, or greenhouses .Keepallunprotectedpersonsoutofoperatingareas,orvicinitywheretheremaybedrift.Donotenterorallowotherpersonstoentertreatedareaswithoutprotectiveclothinguntilsprayshavedried.

PRODUCT INFORMATIONSHADOW3ECHerbicideisaselectivepostemergenceherbicideforcontrolofannualandperennialgrasses.SHADOW3ECHerbicidedoesnotcontrolsedgesorbroadleafweeds.SHADOW3ECHerbicideisasystemicherbicidewhichistranslocatedfromthetreatedfoliagetothegrowingpointsoftheleaves,shootsandroots.Uptakeintotheplantisprimarilythroughitsleaves.Thoroughcoverageofthefoliageisimportantforconsistentgrasscontrol.Thetreatedgrassweedsshowareductioninvigorandgrowth.Earlychlorosis/necrosisofyoungerplanttissueisfollowedbyaprogressivecollapseoftheremainingfoliage.Dependingongrassspeciestreatedandenvironmentalconditions,symptomswillgenerallybeobservedin7to14daysafterapplication.Avoidcontactofthisproductwithdesirablegrasscrops,suchascorn,rice,sorghum,smallgrains,orturfastheseandothergrasscrops will be injured or killed .

RESISTANCE MANAGEMENTForresistancemanagement,SHADOW3ECHerbicideisaWeedScienceSocietyofAmericaGroup1HerbicidelistedundertheHerbicideResistantActionCommittee(HRAC).AnyweedpopulationmaycontainordevelopplantsnaturallyresistanttoSHADOW3ECHerbicideandotherGroup1Herbicides.Theresistantbiotypesmaydominatetheweedpopulationiftheseherbicidesareusedrepeatedlyinthesamefield.Wherepossible,rotatetheuseofSHADOW3ECHerbicidewithherbicidesthathaveadifferentmodeofaction.Otherresistancemechanismsthatarenotlinkedtositeofaction,butspecificforindividualchemicals,suchasenhancedmetabolism,mayalsoexist.Ifpoorperformanceoccursandcannotbeattributedtoadverseweatherorapplicationconditions,aresistantbiotypemaybepresent.TheuseofSHADOW3ECHerbicideshouldconformtoresistancemanagementstrategiesestablishedfortheusearea.Consultyouragriculturaladvisorforresistancemanagementstrategies and recommended pest management practices for your area . Appropriate resistance-management strategies should be followed .

CROPS AND USESSHADOW3ECHerbicideisnotrecommendedforuseonvegetablecropsbeinggrownforseedproductionunlessspecificinstructionsareincludedinthislabeling.

This product is for use on the following crops and uses:Alfalfa,Asparagus,Canola*,Clover**,Corn(Field)***,Cotton,Flax*,Garlic,Hops,Mint,MustardSeed*,Peach,Peanuts,Safflower,Sesame,Soybeans,Strawberry,Sunflower,andRootvegetablesCropGroupSubgroup1B[Beets(Garden),Burdock(edible),Carrot,Celeriac,Chervil(Turnip-rooted),Chicory,Ginseng,Horseradish,Parsley(Turnip-rooted),Parsnip,Radish,Radish(Oriental),Rutabaga,Salsify(BlackandSpanish),Skirret,Turnip],RootvegetablesCropGroupSubgroup1C[Arracacha,Arrowroot,Artichoke*(Globe,ChineseandJerusalem),Canna(Edible),Cassava(BitterandSweet),Chayote(Root),Chufa,Dasheen,Ginger,Leren,Potato,SweetPotato,Tanier,Tumeric,Turnip,Yam(BeanandTrue)],LeavesofRootandTuberVegetablesCropGroup2[Beet(GardenandSugar),Burdock(edible),Carrot,Cassava(BitterandSweet),Celeriac,Chervil(Turnip-rooted),Chicory,Dasheen(Taro),Parsnip,Radish,Radish(Oriental),Rutabaga,Salsify(Black),SweetPotato,Tanier(Cocovam),Turnip,Yam(True)],

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BulbVegetablesCropGroup3[Garlic(BulbandGreathead(Elephant)),Leek,Onion(DryBulbandGreen,Welsh),andShallot],LeafyGreensCropGroupSubgroup4A[Amaranth,Arugula,Chervil,Chrysanthemum(EdibleleavedandGarland),CornSalad,Cress(GardenandUpland),Dandelion,Dock,Endive,Lettuce,Orach,Parsley,Purslane(GardenandWinter),Radicchio(RedChicory),Spinach(NewZealandandVine)],LeafyPetiolesCropGroupSubgroup4B[Cardoon,Celery,Celery(Chinese),Celtuce,Fennel(Florence),Rhubarb,SwissChard],HeadandStemBrassicaCropGroupSubgroup5A[Broccoli,Broccoli(Chinese),BrusselsSprouts,Cabbage,Cabbage(Chinese(napa)andChineseMustard),Cauliflower,CavaloBroccolo, Kohlrabi],LeafyBrassicaGreensCropGroupSubgroup5B[BroccoliRaab,Cabbage(BokChoy),Collards,Kale,Mizuna,MustardGreens,MustardSpinach,RapeGreens],LegumeVegetablesCropGroup6 (except soybeans) [Bean (Lupinus spp .) (includes grain lupin, sweet lupin, white lupin, and white sweet lupin), Bean (Phaseolus spp .) (includes field bean,kidneybean,limabean,navybean,pintobean,runnerbean,snapbean,teparybean,waxbean),Bean(Vignaspp.)(includesadzukibean,asparagusbean,blackeyedpea,catjang,Chineselongbean,cowpea,Crowderpea,mothbean,mungbean,ricebean,southernpea,urdbean,yardlongbean),Broadbean(favabean)(Vicia faba),Chickpea(garbanzobean) (Cicer arietinum),Guar(Cyamopsis tetragonoloba),Jackbean(Canavalia ensiformis),Lablabbean(hyacinthbean)(Lablab purpureus),Lentil(Lens esculenta), Pea (Pisum spp .) (includes dwarf pea, edible-pod pea, English pea, field pea, garden pea, green pea, snow pea, sugar snap pea), Pigeon pea (Cajanus cajan), and Sword bean (Canavalia gladiata)],FruitingVegetables(ExceptCucurbits)CropGroup8[Eggplant,Groundcherry,Pepino,Pepperincludingbellpepper,chilipepper,cookingpepper,pimentoandsweetpepper,Tomatillo,andTomato],CucurbitVegetablesCropGroupMelonSubgroup9A [Citron Melon, Muskmelon, and Watermelon],CucurbitVegetableCropGroupSquash/CucumberSubgroup9B[Chayote(fruit),ChineseWaxgourd,Cucumber,Gherkin,Gourd(Edible),Momordica spp ., Pumpkin, Squash (Summer and Winter)], BerryandSmallFruitCropGroupCaneberrySubgroup13-07A*[Blackberry,Loganberry,Raspberry(RedandBlack),WildRaspberry,cultivars,varietiesand/orhybridsofthese],BerryandSmallFruitCropGroupBushberrySubgroup13-07B*[AroniaBerry,Blueberry(HighbushandLowbush),Currant(Black,Buffalo,andRed),Guava(Chilean),Elderberry,EuropeanBarberry,Gooseberry,Cranberry(Highbush),Honeysuckle(Edible),Huckleberry,Jostaberry,Juneberry,Lingonberry,NativeCurrant,Salal,SeaBuckthorn,Cultivars,variet-ies and/or hybrids of these], HerbsandSpiceCropGroup,HerbsSubgroup19A [Angelica,Balm,Basil,Borage,Burnet,Chamomile,Catnip,Chervil(Dried),Chive,Chive(ChineseandClary),Coriander(Leaf),Costmary,Cilantro(Leaf),Curry,Dillweed,Horehound,Hyssop,Lavender,Lemongrass,Lovage(Leaf),Marigold,Marjoram(Origanum spp .), Nasturtium, Parsley (Dried), Pennyroyal, Rosemary,Rue,Sage,Savory(SummerandWinter),SweetBay,Tansy,Tarragon,Thyme,Wintergreen,Woodruff,andWormwood]. * Not registered for use in California . **ForuseonclovergrowninthestatesofIdaho,OregonandWashingtononly.*** SHADOW3ECHerbicideisforusetocontrolexistingstandsoffieldcorn.

PRECAUTIONS• Alwaysreadandfollowlabeldirectionsofallproducts.Alwaysfollowthemostrestrictivelabellanguageforallproductswhetherusedaloneorinatankmix.Themostrestrictive

label language of any product used applies in tank mixtures, including all crop rotational and other crop restrictions .• Thisproductisnotrecommendedforuseonvegetablecropsbeinggrownforseedproductionunlessspecificusedirectionsareprovided.• WhileallthevegetablecropsonthislabelhavebeentestedandaretoleranttoSHADOW3ECHerbicide,notallspecialtyvarietiesofthesecropshavebeentested.Beforeapplying

SHADOW3ECHerbicidetospecialtyvarietiesofvegetablecropsonthislabel,itisadvisedthatcroptolerancebeinvestigatedfirstusingasmallsectionofthefield.Itispossiblethat injury symptoms can occur . Symptoms may appear as leaf speckling or stunting .

• Grasscropssuchascorn,rice,sorghum,smallgrains,orturf,etc.arehighlysensitivetoSHADOW3ECHerbicide.• Optimalperennialgrasscontrolcanbeobtainedifrhizomesorstolonsarecutupbypreplanttillagepractices(disking,plowing,etc.)tostimulatemaximumemergenceofgrass

shoots.Culturalpractices,suchascontinuousno-tillageinwhichtheperennialgrassrhizomesorstolonsarenotcutup,resultinaverystaggered,non-uniformweedemergence.Nofewerthantwo(2)SHADOW3ECHerbicideapplicationsperseasonperyeararerecommendedattheappropriateweed-growthstagerateundercontinuousno-tillconditions,due to this non-uniform weed emergence .

• TankmixesofSHADOW3ECHerbicideandbroadleafherbicidesmayresultinreducedgrasscontrol.Ifgrassregrowthoccurs,anadditionalapplicationofthisproductmaybenecessary .

RESTRICTIONS• Donotplantanycropfor30daysafterapplicationunlessSHADOW3ECHerbicideisregisteredforuseonthatcrop.• Donotapplyifrainisexpectedwithin1hourofapplication,ascontrolmaybeunsatisfactory.• ApplicationinNassauandSuffolkCountiesofNewYorkStateisrestrictedtonomorethan10.67flozofSHADOW3ECHerbicide(0.25lbai)peracreperseason.• Donotapplyunderconditionsofstress.ApplyingSHADOW3ECHerbicideunderconditionsthatdonotpromoteactivegrassgrowthwillreduceherbicideeffectiveness.These

conditions include,drought,excessivewater, lowhumidityandextremes in temperature,andgrasseseitherpartiallycontrolledorstunted frompriorpesticideapplications.GrassesunderthesekindsofstressfulconditionswillnotabsorbandtranslocateSHADOW3ECHerbicideeffectively,andwillbelesssusceptibletoherbicideactivity.

• DonotapplyapostemergencebroadleafherbicidewithinonedayfollowingapplicationofSHADOW3ECHerbicideorreducedgrasscontrolmayresult.

MIXING INSTRUCTIONS1.Fillcleanspraytank1⁄2 to 2⁄3ofdesiredlevelwithcleanwater.Whileagitating,addthecorrectamountofSHADOW3ECHerbicide,makingsurethatagitationmakesaripplingor

rolling action on the water surface .

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2 . When tank mixing this product with other labeled herbicides, add water-soluble bags first, followed by dry formulations, flowables, emulsifiable concentrates and then solutions . Prepare no more spray mixture than is required for the immediate spray operation .

3.Addanyrequiredadjuvants(cropoilconcentrate,nonionicsurfactantand/ornitrogensolution).4.Fillspraytanktodesiredlevelwithwater.Continue agitation until all spray solution has been applied.Failuretoagitatethespraysolutionmayresultinimpropermixingoftheherbicidesandunsatisfactoryweedcontrol.Verifymixingandcompatibilityqualitiesbyconductingajartest.

APPLICATION INFORMATIONMakeapplicationsofSHADOW3ECHerbicidepostemergencetoactivelygrowinggrassesaccordingtotheratetablerecommendations.Applicationstograssplantsexceedingrecommended growth stages could result in unsatisfactory control . Whenirrigationisusedtosupplementlimitedrainfallinaridregions,applySHADOW3ECHerbicideassoonaspossible,afteranirrigation(within7days).Asecondapplicationofthisproductwillgenerallyprovidemoreeffectivecontrolofperennialgrassweedthanasingleapplicationinaridregions.Applyasecondapplicationtoactivelygrowinggrass2to3 weeks after emergence of new growth .Cultivationoftreatedgrasses7dayspriortoorwithin7daysafterapplicationofthisproductcouldreduceweedcontrol.

GROUND APPLICATIONToensurecompletecoverage,itisessentialtousesufficientsprayvolumesandpressure.Useaminimumof5gallonsandamaximumof40gallonsofspraysolutionperacre.Tengallonsperacrecanimprovegrasscontrolundercertainconditionssuchas:ultranarrowrowcotton,narrowrowsoybeans,broadleafherbicidetankmixes,perennialgrasses,volunteercorn,droughtorstressconditions,heavygrasspressureorwhengrassesareatornearmaximumheight.Setspraypressurestoreflectaminimumof30psiandamaximumof60psiatthenozzle.Donotusefloodnozzles.

Spot TreatmentMix 1⁄3% to 2⁄3%(0.44ozto0.85ozpergal)productwhenusinghandsprayersorhighvolumesprayersutilizinghandguns.Whilenotallowingrunoffofspraysolution,applytowetvegetation.NOTE:IfSHADOW3ECHerbicideisappliedasaspottreatment,donotexceedthemaximumrateallowedona“peracre”basisorcropinjurycouldoccur.CaremustbetakenwhenSHADOW3ECHerbicideisappliedasaspottreatmenttoonions,garlic,shallots,ornon-bearingfoodcropsorcropinjurycouldoccur.

AERIAL APPLICATIONUseaminimumof3gallonsofspraysolutionperacreunlessotherwisedirectedinthislabel.Ifgrassorcropfoliagebecomesdense,increasesprayvolumesupto10gallon.Foronions(drybulbs),garlicorshallots(drybulbs):donotexceed5.33floz/Ainasingleapplicationwhenapplyingbyair.Donotexceed2applicationsperseasonongarlicandshallot . In California do not exceed 2 applications per season on onion . Apply a minimum of 20 gallons of spray solution per acre when applying by air to onions, garlic or shallots in the state of California . In states other than California, make air applications to onions, garlic, and shallots in a minimum of 10 gallons per acre . NOTE:Cropinjurycanoccurwhenthisproductisappliedtoonions,garlicorshallotswithaerialequipment.

CHEMIGATION (SPRINKLER IRRIGATION APPLICATION)ONIONS(drybulbs)andGARLICONLYMay be applied to onions and garlic by sprinkler irrigation systems . Only apply to onions and garlic using chemigation .DonotapplybychemigationtoanyothercropotherthanOnionsandGarlic.Do not apply this product by chemigation in the states of Idaho, Montana, Oregon, and Washington . MakeapplicationofSHADOW3ECHerbicidein0.1to0.2acre-inchofwater,eitherattheendofaregularirrigationsetorasaseparateapplicationnotassociatedwitharegularir-rigationusingtheleastamountofwaterthatprovidesproperdistributionandcoverage.Applicationofmorethanlabelrecommendedquantitiesofirrigationwaterperacremayresultindecreasedproductperformancebyremovingthechemicalfromthezoneofeffectiveness.UseameteringdevicetoinjecttheSHADOW3ECHerbicideintotheirrigationwaterataconstantflow.Constantagitationmustbemaintainedinthechemicalsupplytankduringtheentireperiodofherbicideapplication.Injecttheproductwithapositivedisplacementpumpintothemainlineaheadofarightangleturntoensureadequatemixing.Allowtimeforalllinestoflushtheherbicidethroughallnozzlesbeforeturningoffirrigationwater.Toensure the lines are flushed and free of remaining herbicide, a dye indicator may be injected into the lines to mark the end of the application period .Do not apply SHADOW 3EC Herbicide through an irrigation system connected to a public water system.Publicwatersystemmeansasystemfortheprovisiontothepublicofpipedwaterforhumanconsumptionifsuchsystemhasatleast15serviceconnectionsorregularservesanaverageofatleast25individualsdailyatleast60daysoutoftheyear.

Precautions• Applythisproductonlythroughsprinklerincludingcenterpivot,lateralmove,endtow,side(wheel)roll,traveler,biggun,solidset,orhandmovesystem(s).Donotapplythis

product through any other type of irrigation system .• Cropinjury,lackofeffectiveness,orillegalpesticideresiduesinthecropcanresultfromnon-uniformdistributionoftreatedwater.• Ifyouhavequestionsaboutcalibration,contactStateExtensionServicespecialists,equipmentmanufacturersorotherexperts.• Apersonknowledgeableofthechemigationsystemandresponsibleforitsoperationorunderthesupervisionoftheresponsibleperson,shallshutthesystemdownandmake

necessary adjustments should the need arise .

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RESTRICTIONS• Donotconnectanirrigationsystem(includinggreenhousesystems)usedforpesticideapplicationtoapublicwatersystemunlessthepesticidelabel-prescribedsafetydevices

for public water systems are in place .• Thesystemmustcontainafunctionalcheckvalve,vacuumreliefvalve,andlowpressuredrainappropriatelylocatedontheirrigationpipelinetopreventwatersourcecontamina-

tion from back flow . • Thepesticideinjectionpipelinemustcontainafunctional,automatic,quick-closingcheckvalvetopreventtheflowoffluidbacktowardtheinjectionpump.• Thepesticideinjectionpipelinemustalsocontainafunctional,normallyclosed,solenoid-operatedvalvelocatedontheintakesideoftheinjectionpumpandconnectedtothe

systeminterlocktopreventfluidfrombeingwithdrawnfromthesupplytankwhentheirrigationsystemiseitherautomaticallyormanuallyshutdown.• Thesystemmustcontainfunctionalinterlockingcontrolstoautomaticallyshutoffthepesticideinjectionpumpwhenthewaterpumpmotorstops.• Theirrigationlineorwaterpumpmustincludeafunctionalpressureswitchwhichwillstopthewaterpumpmotorwhenthewaterpressuredecreasestothepointwherepesticide

distributionisadverselyaffected.• Systemsmustuseameteringpump,suchasapositivedisplacementinjectionpump(e.g.,diaphragmpump)effectivelydesignedandconstructedofmaterialsthatarecompatible

with pesticides and capable of being fitted with a system interlock .• Donotapplywhenwindspeedfavorsdriftbeyondtheareaintendedfortreatment.

SPRAY DRIFT MANAGEMENTAvoidingspraydriftattheapplicationsiteistheresponsibilityoftheapplicator.Theinteractionofmanyequipment-and-weather-relatedfactorsdeterminesthepotentialforspraydrift.Theapplicatorandthegrowerareresponsibleforconsideringallthesefactorswhenmakingdecisions.Thefollowingdriftmanagementrequirementsmustbefollowedtoavoidoff-targetdriftmovementfromaerialapplicationstoagriculturalfieldcrops.Theserequirementsdonotapply to forestry applications, public health uses or to applications using dry formulations .• Thedistanceoftheoutermostnozzlesontheboommustnotexceed3⁄4 the length of the wingspan or rotor .• Nozzlesmustalwayspointbackward,parallelwiththeairstreamandneverbepointeddownwardsmorethan45degrees.WhenapplyingSHADOW3ECHerbicideinatankmixwithotherherbicides(e.g.2,4-D,bromoxynil,MCPA,andsulfonylureaherbicides)ineasternWashington,observeallapplicableWashington State Department of Agriculture herbicide rules .TheapplicatormustbefamiliarwithandtakeintoaccounttheinformationcoveredintheSPRAY DRIFT MANAGEMENT section .AVOIDING SPRAY DRIFT IS THE RESPONSIBILITY OF THE APPLICATOR

Information on Droplet SizeThemosteffectivewaytoreducedriftpotentialistoapplylargedroplets.Thebestdriftmanagementstrategyistoapplythelargestdropletsthatprovidesufficientcoverageandcontrol.Applyinglargerdropletsreducesdriftpotential,butwillnotpreventdriftifapplicationsaremadeimproperly,orunderunfavorableenvironmentalconditions(seeWIND, TEMPERATURE AND HUMIDITY, and TEMPERATURE INVERSIONS) .

Controlling Droplet Size• Volume—Usehighflowratenozzlestoapplythehighestpracticalsprayvolume.Nozzleswithhigherratedflowsproducelargerdroplets.• Pressure—Donotexceed thenozzlemanufacturer’s recommendedpressures.Formanynozzle types, lowerpressureproduces largerdroplets.Whenhigherflowratesare

needed,usehigherflowratenozzlesinsteadofincreasingpressure.• NumberofNozzles—Usetheminimumnumberofnozzlesthatprovideuniformcoverage.• NozzleOrientation—Orientingnozzlessothatthesprayisreleasedparalleltotheairstreamproduceslargerdropletsthanotherorientationsandistherecommendedpractice.

Significantdeflectionfromhorizontalwillreducedropletsizeandincreasedriftpotential.• NozzleType—Useanozzletypethatisdesignedfortheintendedapplication.Withmostnozzletypes,narrowersprayanglesproducelargerdroplets.Considerusinglow-drift

nozzles.Solidstreamnozzlesorientedstraightbackproducethelargestdropletsandthelowestdrift.

Boom LengthForsomeusepatterns,reducingtheeffectiveboomlengthtolessthan¾ofthewingspanorrotorlengthmayfurtherreducedriftwithoutreducingswathwidth.

Application HeightApplicationsmustnotbemadeataheightgreaterthan10feetabovethetopofthelargestplantsunlessagreaterheightisrequiredforaircraftsafety.Makingapplicationsatthelowestheightthatissafereducesexposureofdropletstoevaporationandwind.

Swath AdjustmentWhenapplicationsaremadewithacrosswind,theswathwillbedisplaceddownwind.Therefore,ontheupanddownwindedgesofthefield,theapplicatormustcompensateforthisdisplacement by adjusting the path of the aircraft upwind . Swath adjustment distance should increase, with increasing drift potential (higher wind, smaller drops, etc .)

WindDriftpotentialislowestbetweenwindspeedsof2to10mph.However,manyfactors,includingdropletsizeandequipmenttypedeterminedriftpotentialatanygivenspeed.Ap-plicationmustbeavoidedbelow2mphduetovariablewinddirectionandhighinversionpotential.NOTE:Localterraincaninfluencewindpatterns.Everyapplicatormustbefamiliarwith local wind patterns and how they affect spray drift .

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Temperature and HumidityWhenmakingapplicationsinlowrelativehumidity,setupequipmenttoproducelargerdropletstocompensateforevaporation.Dropletevaporationismostseverewhenconditionsare both hot and dry .

Temperature InversionsApplicationsmustnotoccurduringatemperatureinversionbecausedriftpotentialishigh.Temperatureinversionsrestrictverticalairmixing,whichcausessmallsuspendeddropletstoremaininaconcentratedcloud.Thiscloudcanmoveinunpredictabledirectionsduetothelightvariablewindscommonduringinversions.Temperatureinversionsarecharacter-izedbyincreasingtemperatureswithaltitudeandarecommononnightswithlimitedcloudcoverandlighttonowind.Theybegintoformasthesunsetsandoftencontinueinthemorning.Theirpresencecanbeindicatedbygroundfog;however,iffogisnotpresent,inversionscanalsobeidentifiedbythemovementofsmokefromagroundsourceoranaircraftsmokegenerator.Smokethatlayersandmoveslaterallyinaconcentratedcloud(underlowwindconditions)indicatesaninversion,whilesmokethatmovesupwardandrapidlydissipatesindicatesgoodverticalairmixing.

USE RATES AND APPLICATION PROCEDURES

ADJUVANT OR CROP OIL CONCENTRATE RECOMMENDATIONSSHADOW3ECHerbicidedoesnotcontainanadjuvantsystem.Foritsactivationadjuvantsarerequiredforcontrol.Cropoilconcentrate(COC)providesthemostconsistentactivationofSHADOW3ECHerbicide.Cropoilconcentratescancausecropinjurywithcertaintankmixpartnersoronsensitivecrops.Underthesecircumstancesnon-ionicsurfactants(NIS)canbeusedinreplaceofcropoilconcentrate.Reducedweedcontrolmayresultfromuseofnon-ionicsurfactant.Underdroughtconditionsmethylatedseedoiladjuvantscanbeused in replacement of COC . Methylated seed oils can increase crop injury potential and care should be taken when considering its use . Ammonium sulfate (AMS) or urea-ammonium nitrate(UAN)canimprovecontrolofhardtocontrolgrassesandhelpovercomepotentialantagonismfromtankmixpartners.TheuseofAMSorUANisonlyallowedonspecifiedcrops.FollowtheSHADOW 3EC HERBICIDE USE RATES / RESTRICTIONS / LIMITATIONStableforguidelines.Followthetablebelowforadjuvantuserates:

Specified Adjuvant use with SHADOW 3EC HerbicideAdjuvant Adjuvant Use Rate Comment

COC (Crop Oil Concentrate)OR

1%v/vor1Qt/A UsewithSHADOW3ECHerbicideinmostusepatternsotherthanthelisteddirectlybelow

MSO (Methylated Seed Oil)OR

1%v/vor1.5pt/A Useforimprovedcontrolunderdroughtconditionsorotherweedstressconditions.MSOcanincrease injury with some tank mix partners

NIS (Non-ionic surfactant) 0.25–0.5%v/v Usewhentankmixpartnersorcropsensitivitylimittheuseofoiladjuvants.GrasscontrolfromSHADOW3ECHerbicidewillbereduced

Nitrogen Fertilizer Adjuvant1 Adjuvant Use Rate CommentAmmonium Sulfate (AMS)

OR1–4lb/Aor8.5–17lb/100 gallons of spray solution

Useforimprovedcontrolofdifficultgrassspecies.AMSisnottobeusedonallcrops

28–32%UreaAmmoniumNitrate(UAN) 1–2Qt/A UsewhenasourceofAMSisnotavailable.

1 The addition of liquid fertilizer is not recommended for the following crops:Artichoke,Asparagus,Berryandsmallfruitcrops;Bushberry,Caneberry,Carrot,Cranberry,Cucurbits,FruitingVegetables(exceptTomato),GardenBeet,Garlic,Head&StemBras-sicaVegetables,Herbs,Hops,LeafPetioles,LeafyBrassicaGreens,LeafyGreens,Leek,MustardSeed,Non-BearingFoodCrops,Onion(DryBulb),Peach,Radish,RootVegetables,Sesame,Shallots(DryBulb),Strawberry,Tomato,andRootandTuberLeaves.

Theuseofadjuvantscanincreasecropinjuryoftankmixpartners.Consultthetankmixpartnerlabelforfurtherguidance.Whenanadjuvantistobeusedwiththisproduct,ArystaLifeScienceNorthAmerica,LLCrecommendstheuseofaChemicalProducersandDistributorsAssociationcertifiedadjuvant.

APPLICATION RATES BY CROP

SHADOW 3EC HERBICIDE USE RATES/RESTRICTIONS/LIMITATIONS

CROPSAPPLICATION TIMING AND PRE-HARVEST INTERVAL

(PHI)

USE RATES PER ACRE ALLOWED FOR EACH CROP

CROP OIL CONCENTRATE (COC) and AM-MONIUM SULFATE (AMS)

SPECIAL USE INSTRUCTIONS

Alfalfa Established including:

SainfoinHolyCloverBirdsfoot trefoil

Alfalfa Seedling

15daysbeforegrazing,feed-ingorharvesting(cutting)forforage or hay . Maintaina14dayintervalforrepeat applications .

4–10.67floz COC:1%v/vor1qt/Abyground.1%v/vor1pt/Abyair.AMS:2.5–4.0lb/Aor8.5–17.0lb/100 gallons of spray solution

Donotapplymorethan10.67floz/Aperapplication .Donotapplymorethan21.33floz/Aper season .Thisproductcanbeappliedtoseedlingorestablished alfalfa grown for seed .

N/A—Not ApplicableARefertoCropsandUsessectionofthislabel.* Not registered for use in California .

8



(PHI)




Artichoke* (Globe) 5dayPHIMaintaina14dayintervalforrepeat applications .

4–5.33floz COC:1%v/vor1qt/Abyground.1%v/vor1pt/A by air . AMS: None

Donotapplymorethan5.33floz/Aperapplication .Donotapplymorethan21.33floz/Aper season .

Asparagus 1dayPHIMaintaina14dayintervalforrepeat applications .



Beans(A), Dry Shelled including:Bean (Lupinus spp .)

Grain SweetWhiteWhite Sweet

Bean (Phaseolus spp .)FieldKidneyLima(dry)NavyPintoRunnerSnapTeparyWax

30dayPHIMaintaina14dayintervalforrepeat applications .

4–10.67floz COC:1%v/vor1qt/Abyground.1%v/vor1pt/Abyair.AMS:2.5–4lb/Aor8.5–17.0lb/100gallons of spray solution


Beans(A), Dry Shelled including:Bean (Vigna spp .)

AdzukiAsparagusBlackeyed PeaCatjangChinese longbeanCowpeaCrowder PeaMoth Mung Rice Southern PeaUrdYardlong

Broad (dry)Chickpea(garbanzo)GuarJackbeanLablabSword

30dayPHIMaintaina14dayintervalforrepeat applications .




9



(PHI)




Bean(A), Succulent including:Bean (Phaseolus spp .)

Broad Bean (succulent)Lima(dry)

Bean (Vigna spp .)Black-eyed PeaCowpeaSouthern Pea

21dayPHI 4–5.33floz COC:1%v/vor1qt/Abyground.1%v/vor1pt/Abyair.AMS:AMS2.5–4lb/Aor8.5–17.0lb/100 gallons of spray solution

Do not apply more than one (1) application per acre per season .

Beet, Garden 30dayPHIMaintain a 14 day interval forrepeat applications .



Beet, Sugar 40dayPHIMaintain a 14 day interval forrepeat applications .



Berry and Small Fruit Crops; Bushberry* including (for Cranberry refer to the Cranberry specific crop informa-tion):Aronia BerryBlueberry(Highbush)Guava,ChileanCurrant, BlackCurrant, BuffaloCurrant,NativeCurrant, RedElderberryEuropean BarberryGooseberryHoneysuckleEdibleHuckleberryJostaberryJuneberryLingonberrySalalSea Buckthorn

14daysPHIMaintain a 14 day interval forrepeat applications .


Donotapplymorethan5.33floz/Aperapplication .Donotapplymorethan21.33floz/Aper season .Do not apply for Bushberry grown for root stock .Direct the application towards the base of theplanttoavoidcontactwithleaftissue.Contact with the upper portions of the plant can result in crop injury .


10



(PHI)




Caneberry * including:BlackberryLoganberryRaspberryBlack RaspberryRed Raspberry

7 daysMaintain a 14 day interval forrepeat applications .


Donotapplymorethan5.33floz/Aperapplication .Donotapplymorethan21.33floz/Aper season .Do not apply for Caneberry grown for root stockDirect the application towards the base of theplanttoavoidcontactwithleaftissue.Contact with the upper portions of the plant can result in crop injury .

Canola* 70dayPHI 2.67–5.33floz COC:1%v/vor1qt/Abyground.1%v/vor1pt/Abyair.AMS:2.5–4lb/Aor8.5–17.0lb/100gallons of spray solution

Do not apply after crop has begun bolting . Donotexceed5.33floz/Ainaseason.Crop injury could occur when this product is applied during the bloom period .

Carrot 30dayPHIMaintain a 14 day interval forrepeat applications .



Clover 15dayPHIbeforegrazing,feeding,orharvesting(cutting)for forage or hay .Maintaina14dayintervalforrepeat applications .


Donotexceed10.67floz/Ainaseason.ForuseonclovergrowninthestatesofIdaho, Oregon and Washington only .

Cotton 60dayPHIMaintain a 14 day interval forrepeat applications .


Donotapplymorethan10.67floz/Aperapplication .Donotapplymorethan21.33floz/Aper season . Donotgrazetreatedfieldsorfeedtreatedforageorhaytolivestock.

Cranberry 30dayPHIMaintain a 14 day interval forrepeat applications .


Donotapplymorethan5.33floz/Aperapplication .Donotapplymorethan21.33floz/Aper season .Donotapplybetweenthe“hook”stageand full fruit set .


11



(PHI)




Cucurbits(A), including: Chayote (fruit)ChineseWaxGourdCitron MelonCucumberGherkinGourd,EdibleMuskmelons (all)

including:CantaloupesHoneydewMelon

PumpkinSquash (all)Watermelon

14dayPHIMaintain a 14 day interval forrepeat applications .



Fallow Land (and other non-producing agricul-tural areas)Non-Crop or Non-Planted areas

N/A Maintain a 14 day interval forrepeat applications .


Donotapplymorethan10.67floz/Aperapplication .Donotapplymorethan21.33floz/Aper season .Do not plant any crop for 30 days fol-lowing application unless clethodim is registered for use on that crop .See NON-CROP OR NON-PLANTED AREAS section for additional information .

Flax* 60dayPHIMaintain a 14 day interval forrepeat applications .


Donotapplymorethan5.33floz/Aperapplication . Donotapplymorethan10.67floz/Aper season .Make application prior to bloom .If applied during bloom, crop injury could occur .

Fruiting Vegetables(A) (except Cucurbits) (for Tomatoes refer to Tomato specific crop informa-tion) including:EggplantGroundcherryPepinoPeppers (all)Tomatillo





12



(PHI)




GarlicBulb Greathead(elephant)

LeekOnions

(Dry Bulbs Only)Shallots

(Dry Bulbs Only)


4–10.67flozForgroundapplica-tion do not exceed 5.33floz/Ainasingle application to garlic or shallots . Foraerialapplica-tion do not exceed 5.33floz/Ainasingle application to onion garlic and shallots .

COC:1%v/vor1qt/Abyground.1%v/vor1pt/A by air . AMS: None

California only: do not apply until the crop hasatleasttwofullleaves.Minimum20gals/AsprayvolumebygroundinentireU.S.Donotapplymorethan10.67floz/Aperapplication .Donotapplymorethan21.33floz/Aper season .See SPOT APPLICATION and AERIAL APPLICATION sections for additional information and restrictions .

Leek Onion

(Greenonly)Shallot

(Greenonly)

14dayPHIMaintain a 14 day interval forrepeat applications


Donotapplymorethan5.33floz/Aperapplication .

Head & Stem Brassica Vegetables(A), including:Broccoli

(Chinese)Brussels SproutsCabbage

(Chinese and Chinese Mustard)

CauliflowerCavaloBroccoloKohlrabi





13



(PHI)




Herbs(A) including: AngelicaBalmBasilBorageBurnetChamomileCatnipChervil,(dried)ChiveChineseChiveChinese ClaryCoriander (leaf)CostmaryCilantro (leaf)Curry (leaf)Dill (dillweed)HorehoundHyssopLavenderLemongrassLovage(leaf)MarigoldMarjoram (Origanum spp .)NasturtiumParsley (dried)PennyroyalRosemaryRueSage Savory:SummerandWinterSweetBayTansyTarragonThymeWintergreenWoodruffWormwood



Donotapplymorethan5.33floz/Aperapplication .Donotapplymorethan21.33floz/Aper season .Thisproducthasnotbeentestedonallherbs,andherbvarieties.Itistherespon-sibility of the user to test this product on a small portion of the crop to be treated before treating the entire field .Verifycroptolerancetothisproductonasmall area of the herb crop, at the desired rate.Ifnocropresponseisevidentseven(7) days after treatment, this product may be used on the entire field at the same rate tested and with the same crop oil used in the tolerance test .

Hops 21dayPHIMaintain a 14 day interval forrepeat applications .



Leaf Petioles(A) including:CardoonCelery Chinese CeleryCeltuceFennel(Florence)RhubarbSwiss chard





14



(PHI)




Leafy Brassica Greens(A), including:Broccoli RaabCabbage, Chinese

(Bok choy)CollardsKaleMizunaMustardGreensMustard SpinachRapeGreens




Leafy Greens(A) including:Amaranth

Chinese SpinachLeafyAmaranthTampala

Arugula (roquette)ChervilChrysanthemum,

Edible-leavedGarlan

Corn SaladCress

GardenUpland

DandelionDock (sorrel)Endive(escarole)Lettuce(headandleaf)OrachParsleyPurslane

GardenWinter

Radicchio (red chicory)Spinach

NewZealandVine





15



(PHI)




Legume Vegetables, Ed-ible Podded(A) including:Bean (Phaseolus spp .) Runner Snap WaxBean (Vigna spp .) AsparagusChineseLongbean MothYardlongJackbeanPea (Pisum spp .) Dwarf Edible-pod Snow Sugar Snap Pigeon Sword Bean

21dayPHI 4–5.33floz COC:1%v/vor1qt/Abyground.1%v/vor1pt/Abyair.AMS:2.5–4.0lb/Aor8.5–17.0lb/100 gallons of spray solution

Donotapplymorethan5.33floz/Ainasingle application .Do not apply more than one (1) application per acre per season .Forpeasapplybeforebloom,butnolaterthan21daysbeforeharvest.

Lentils 30dayPHIMaintain a 14 day interval forrepeat applications .



Mint 21dayPHIMaintain a 14 day interval forrepeat applications .



Mustard Seed* 75dayPHIMaintain a 14 day interval forrepeat applications .

2.67–4.0floz COC:1%v/vor1qt/Abyground.1%v/vor1pt/A by air . AMS: None

Donotapplymorethan10.67flozina season .Do not apply after crop has begun bolting . If applied during the bloom period, crop injury could occur .

Non-Bearing Food Crops N/AMaintain a 14 day interval forrepeat applications .

4–5.33floz COC: not recommended due to injury to flowers andfoliage.Useanon-ionicsurfactant(NIS)at0.25%v/v

Sugar Maples cannot be tapped for syrup within one year of application .Donotapplymorethan5.33floz/Aperapplication . Donotapplymorethan21.33floz/Aper season .See SPOT APPLICATION and AERIAL APPLICATION sections for additional information and restrictions . See NON-BEARING FOOD CROPS section for specific use sites .


16



(PHI)




Pea, Dry Shelled(A) including:Pea (Pisum spp .)Field Pigeon

30dayPHIFor peas apply before bloom,but no later than 30 days be-foreharvest.


Donotapplymorethan5.33floz/Ainasingle application .Do not apply more than one (1) application per acre per season .Applications of this product to peas during thebloomperiodcouldresultinseverecrop injury, including loss of yield and delayed maturity .

Pea, Succulent Shelled(A) including:Pea (Pisum spp .) Dwarf Edible-pod English GardenGreen Pigeon Snow Sugar Snap Sword

21dayPHIFor peas apply before bloom,but no later than 21 days be-foreharvest.

4–5.33floz COC:1%v/vor1qt/Abyground.1%v/vor1pt/Abyair.AMS:2.5–4.0lb/Aor8.5–17.0lb/100 gallons of spray solution .

Donotapplymorethan5.33floz/Ainasingle application .Do not apply more than one (1) application per acre per season .Applications of this product to peas during thebloomperiodcouldresultinseverecrop injury, including loss of yield and delayed maturity .

Peach 14dayPHIMaintain a 14 day interval forrepeat applications .


Donotapplymorethan5.33floz/Aperapplication .Donotapplymorethan21.33floz/Aper season .Do not apply for Peach grown for root stockDirect the application towards the base of theplanttoavoidcontactwithleaftissue.Contact with the upper portions of the plant can result in crop injury .

Peanut (including perennial)



Donotapplymorethan10.67floz/Aperapplication .Donotapplymorethan21.33floz/Aper season .ForFloridaPerennialpeanutsdonotapplymorethan21.33floz/Aperyear.

Potato 30dayPHIMaintain a 14 day interval forrepeat applications .



RadishRadish (Oriental)



Donotapplymorethan5.33floz/Aperapplication . Donotapplymorethan10.67floz/Aper season .


17



(PHI)




Root Vegetables(A) (for Carrot and Radish, refer to Carrot and Radish specific crop informa-tion), including:Burdock (edible)CeleriacChervil(Turnip-rooted)ChicoryGinsengHorseradishParsley(Turnip-rooted)ParsnipRutabagaSalsify

BlackSpanish

SkirretTurnip




Safflower 70dayPHIMaintain a 14 day interval forrepeat applications .


Donotapplymorethan5.33floz/Aperapplication . Donotapplymorethan10.67floz/Aper season .

Sesame 14dayPHIMaintain a 14 day interval forrepeat applications .


Donotapplymorethan5.33floz/Aperapplication .Donotapplymorethan21.33floz/Aperseason . Do not apply during flowering .

Soybean 60dayPHIMaintain a 14 day interval forrepeat applications .


Donotapplymorethan10.67floz/Aperapplication .Donotapplymorethan21.33floz/Aper season .Donotgrazetreatedfieldsorfeedtreatedforageorhaytolivestock.

Strawberry 4dayPHIMaintain a 14 day interval forrepeat applications .



Sunflower 70dayPHIMaintain a 14 day interval forrepeat applications .




18



(PHI)




Sweet Potato, Yam and other tuberous and corm vegetables(A) (for Potato, refer to Potato specific crop information), including:ArracachaArrowrootArtichoke*

Chinese Jerusalem

CannaCassava

BitterSweet

ChayoteChufaDasheenGingerLerenSweet PotatoTanierTumericTurnipYam




Tomato 20dayPHIMaintain a 14 day interval forrepeat applications .




19



(PHI)




Root and Tuber Leaves (for Beets, Carrots, and Radish, refer to Beets, Carrot and Radish spe-cific crop information)Burdock (edible)Cassava;bitterandsweetCeleriacChervilChicoryDasheenParsnipRutabagaSalsify (Black)Sweet potatoTanierTurnipYam(True)





ATTENTIONPlanttolerancetoSHADOW3ECHerbicideatlabeledrateshasbeenfoundtobeacceptablefortheindicatedgeneraandspecieslistedbelow.Duetovariabilitywithinspecies,cropgrowthstage,environmentalconditions,andapplicationtechniques,it isrecommendedthattheuserdetermineiftheherbicidecanbeusedsafelyonafewplantspriortowidespreadapplication.NeitherthesellernorthemanufacturerofSHADOW3ECHerbicidehasinvestigatedthesafetyfactortoplantsnotlistedonthislabel.

NON-BEARING FOOD CROPSDO NOT APPLY SHADOW 3EC HERBICIDE TO NON-BEARING FRUIT OR NUT CROPS GROWN FOR ROOT STOCK.IfSHADOW3ECHerbicideisimproperlyapplied,cropinjurytonon-bearingfruitandnutcropscanoccur.DonotapplySHADOW3ECHerbicidedirectlyoverthetopoftheseplanttypes . Rather, direct the spray at the base of the plant where grassy weeds are growing near the ground .Non-bearingfruitandnutcropsareplants,whichwillnotbearfruitornutsforatleastoneyearfollowinganapplicationofSHADOW3ECHerbicide.

NON-BEARING FOOD CROPS

COMMON NAME SCIENTIFIC NAMEApples Malus spp .

Berries Vaccinium spp .

Rubus spp .

Cherry, sweet Prunus avium

Citrus fruit Citrus spp .

Grapes Vitis spp .

Olives Olea spp .

Peach Prunus persica

Pears Pyrus communis

Prunes Prunus spp .

Stone fruit Prunus spp .

Strawberries Fragaria spp .

20

COMMON NAME SCIENTIFIC NAMETree nuts Almond Prunus tribola

Filbert Corylus maxima

Pecan Carya illinoinensis

Pistachio Pistacia vera

Walnut Juglans spp .

NON-CROP OR NON-PLANTED AREASThefollowingareasareconsiderednon-cropornon-plantedareas:Rights-of-way,includingrailroads,highways,roads,dividers,medians,pipelines,publicutilitylines,pumpingstations,transformerstationsandsubstations;aroundairports;electricutilities;commercialbuildings;manufacturingplants;storageyards;railyards;fencelines;parkways;post-harvestcroplands;andbeneathgreenhousebenchesandaroundgolfcourses.

DIRECTIONS FOR ANNUAL GRASSES(EXCEPT FOR IN ESTABLISHED ALFALFA AND MINT)Makeapplicationtoactivelygrowinggrassesatrecommendedweedheights.Make application when the first grass weed species in a mixed grass weed population reaches the recommended growth stage for treatment .Usethehigherrateunderheavygrasspressureand/orwhengrassesareatmaximumheights.

Grass Species Scientific Name Weed Height (inches) Rate(3) FL OZ/ABarnyardgrass Echinochloa crus-galli 2 to 8 4 5 .33

Broadleaf Signalgrass Brachiaria platyphylla 2 to 6 4 5 .33

BromeCalifornia Bromus carinatus 2 to 6 4 5 .33

Cheat Bromus secalinus 2 to 6 4 5 .33

Downy Bromus tectorum 2 to 6 4 5 .33

Ripgut Bromus diandrus 2 to 6 4 5 .33

Canarygrass Phalaris canariensis 1 to 4 4 5 .33

CrabgrassHairy Digitaria adscendens 2 to 6** 4 5 .33

Large Digitaria sanguinalis 2 to 6** 4 5 .33

Smooth Digitaria ischaemum 2 to 6** 4 5 .33

Southern Digitaria ciliaris 2 to 6** 4 5 .33

Crowfootgrass Dactyloctenium aegyptium 2 to 6** 4 5 .33

Fall Panicum Panicum dichotomiflorum 2 to 8 4 5 .33

Field Sandbur Cenchrus incertus 2 to 6 4 5 .33

FoxtailGiant Setaria faberi 2 to 12 4 5 .33

Green Setaria viridis 2 to 8 4 5 .33

Yellow Setaria glauc 2 to 8 4 5 .33

Goosegrass Eleusine indica 2 to 6** 4 5 .33

Itchgrass Rottboellia cochinchinensis 2 to 6 4 5 .33

Junglerice Echinochloa colona 2 to 6 4 5 .33

Lovegrass (Stinkgrass) Eragrostis cilianensis 2 to 6 4 5 .33

Rabbitsfootgrass Polypogon monspeliensis 1 to 4 4 5 .33

Red Rice Oryza sativa 1 to 3 4 5 .33

RyegrassHardy Lolium remotum 2 to 6 4 5 .33

Italian Lolium multiflorum 2 to 6 4 5 .33

Seedling Johnsongrass Sorghum halepense 4 to 10 4 5 .33

Shattercane Sorghum bicolor 6 to 18 4 5 .33

21

Grass Species Scientific Name Weed Height (inches) Rate(3) FL OZ/ASouthwestern Cupgrass Eriochloa gracilis 2 to 6 4 5 .33

Sprangle topAmazon Leptochloa panicoides 2 to 6 4 5 .33

Bearded Leptochloa fascicularis 2 to 6 4 5 .33

Mexican Leptochloa uninervia 2 to 6 4 5 .33

Red Leptochloa filiformis 2 to 6 4 5 .33

Texas Panicum Panicum texanum 2 to 6 4 5 .33

Volunteer Cereals(2)

Barley Hordeum vulgare 2 to 6 4 5 .33

Oats Avena sativa 2 to 6 4 5 .33

Rye Secale cereale 2 to 6 4 5 .33

Wheat Triticum aestivum 2 to 6 4 5 .33

Volunteer Corn(1) Zea mays up to 12 2 .67 4

Volunteer Corn(1) Zea mays up to 24 4 5 .33

Volunteer Corn(1) Zea mays up to 36 5 .33 6 .67

Volunteer Grain Sorghum Sorghum bicolor 8 to 12 4 5 .33

Wild Oats Avena fatua 2 to 6 4 5 .33

Wild Proso Millet Panicum miliaceum 2 to 10 4 5 .33

Witchgrass Panicum capillare 2 to 8 4 5 .33

Woolly Cupgrass Eriochloa villosa 2 to 8 4 5 .33

* Generallyoccursbetween3-leafstageandtillering.**Lengthoflateralgrowth.1 Includes Roundup Ready®,LibertyLink®, and IMI-CORN®volunteercorn.2 TheminimumSHADOW3ECHerbicideuserateforcontrolwhenacerealgraincrop(suchaswheat)isinterseededforcropestablishmentorisplantedaswindbreakstoaid

cropestablishmentis5.33floz/A.3 Whereexperiencehasshownthathigherratesareneededforsatisfactorycontrolofannualgrasses,rateshigherthan5.33floz/Amaybeappliedincertaingeographicareas,

croppingsituations,orenvironmentalconditions.Inthesesituations,ratesfrom5.33to10.67floz/Acanbeapplied.FollowtheuseraterestrictionsinthatSHADOW 3EC HERBICIDE USE RATES/RESTRICTIONS/LIMITATIONS table before applying higher rates .

22

DIRECTIONS FOR ANNUAL & PERENNIAL GRASS CONTROL IN ESTABLISHED ALFALFA AND MINT WITH SHADOW 3EC HERBICIDEGRASS SPECIES WEED STAGE RATE FL OZ/A

Annual&perennialGrassesListedinGrassTable SeeTable 6 .67 10 .6

Mowing:AchievingthebestcontrolofannualgrassescanbemadebyapplyingSHADOW3ECHerbicidebeforegrassweedsaremowed.Oncegrassismoweditbecomestoughertocontrol,asmuchoftheavailableleafsurfacehasbeenremoved.Inareaswithoutakillingfrost,someannualscanover-winterafterhavingbeenmowedmultipletimes.Thesegrassesformlargecrownsandmaycontainmanyviablebuds.Eventhoughthesegrassesmaybeanannualgrass, theymayrequirerepeatedapplicationofSHADOW3ECHerbicideforpartialorcompletecontrol.Irrigated Alfalfa and Mint:IrrigationpracticescanbeverycriticaltothesuccessfuluseofSHADOW3ECHerbicideinestablishedalfalfaandmintandmaybenecessarytoinitiateactivegrowthoftheweedspriortoapplication.Generallyapplications2to4daysafteranirrigationaremosteffective.Irrigationmadeshortlyafterapplication(2days)canbeeffective,butmoreconsistentgrasscontroloccurswhentheirrigationismadebeforetheapplication.Aerial Application:Whenapplyingbyairinestablishedalfalfaandmint,applySHADOW3ECHerbicideinaminimumof10GPA.Annual Grass Control:MakeapplicationatthegrasssizesindicatedintheRecommendationforAnnualGrassTableandratesindicate.Ifagrasshasbeencut,makeapplicationafteractivegrowthhasresumedandregrowthhasreachedtheminimumheightandbeforeitreachesthemaximumheightindicated.Makeapplicationbeforethealfalfa/mintcanopycoversthegrassesandinterfereswiththespraycoverage.Someannualgrassesarespring-andsummer-germinatingplants,whileothersarefall-germinatingplants,andthetimetheyareactivelygrowingandmostsusceptibletoSHADOW3ECHerbicidemayvaryfromregiontoregion.Inaddition,someannualsgerminateoveranextendedperiodof time and because control of small grasses is desired, application after each weed flush may be required . As a general rule spray spring and summer-germinating grasses as earlyintheseasonaspossible,afterinitialgreen-up.Sprayfall-germinatingweedsinthefallsoonaftertheybegingrowingbutbeforeanydamageisdoneduetofrost.Latefallapplicationsmaybelesseffectiveduetoenvironmentalconditions,suchasfrost,slowerplantgrowth,ortheonsetofflowering.Perennial Grass Control: SHADOW3ECHerbicideeffectivelycontrolsperennialgrasses,suchasBermudagrass,Johnsongrass,quackgrass,wirestemmuhly,tallfescue,foxtailbarley and orchardgrass . Due in part to lack of tillage, perennial grasses are more difficult to control in a perennial crop, such as established alfalfa or mint . A program of repeated applicationsisusuallynecessaryforbestresults.Thebestwaytocontrolperennialgrassesistodosointheyearofstandestablishmentbeforerhizomesandstolonsbecomelarge and difficult to kill .Usethehighrateunderheavygrasspressureand/orwhengrassesareatornearmaximumheight.

DIRECTIONS FOR ANNUAL BLUEGRASS CONTROL WITH SHADOW 3EC HERBICIDEGRASS SPECIES WEED STAGE RATE FL OZ/A

Annual Bluegrass (Poa annua) 1 to 4-leaf 4* 10 .67**

Applyunderfavorablesoilmoistureandhumidity,whichexistswithinafewdaysafterrainfallorwithin7daysafterirrigation.Grassneedstobeactivelygrowingattimeofapplication(s) .Apply at weed stage indicated on the label, as reduced control can be expected with more mature annual bluegrass .Usethehighrateunderheavygrasspressureand/orwhenannualbluegrassismoremature.

*Useaminimumof6.67floz/Atocontrolannualbluegrassinseedlingandestablishedalfalfaandmint.**See CROP SPECIFIC USE DIRECTIONS, for maximum application rates and restrictions .

DIRECTIONS FOR REDUCED RATE USE IN CANOLA, DRY SHELLED BEAN & PEA (INCLUDING SOYBEAN), EDIBLE PODDED LEGUME VEGETABLES, FLAX, MUSTARD SEED, SUC-CULENT BEAN & PEA AND SUGAR BEET

DIRECTIONS FOR SMALL ANNUAL GRASSES(REDUCED RATE DIRECTIONS NOT FOR USE IN CALIFORNIA)• Makeapplicationonlytoactivelygrowinggrassesandtherecommendedweedheights.• Makeapplicationwhenthefirstgrassweedspeciesinamixedgrassweedpopulationreachestherecommendedgrowthstagefortreatment.• Regrowthbytilleringmayoccurifapplicationismadewhenplantsarestressedbylackofmoisture,excessivemoisture,loworhightemperaturesand/orunderverylowhumidity.

ANNUAL GRASS SPECIES SCIENTIFIC NAME WEED HEIGHT (inches) RATE FL OZ/ABarnyardgrass Echinochloa crus-galli 1 to 4 2 .66

Broadleaf Signalgrass Brachiaria platyphylla 1 to 4 3 .33

CrabgrassLarge Digitaria sanguinalis 1 to 3* 2 .66

Large Digitaria sanguinalis 1 to 4* 3 .33

Smooth Digitaria ischaemum 1 to 3* 2 .66

Smooth Digitaria ischaemum 1 to 4* 3 .33

Southern Digitaria ciliaris 1 to 4* 3 .33

Fall Panicum Panicum dichotomiflorum 1 to 4 2 .66

23

ANNUAL GRASS SPECIES SCIENTIFIC NAME WEED HEIGHT (inches) RATE FL OZ/AFoxtail

Giant Setaria faberi 1 to 4 2 .66

Green Setaria viridis 1 to 4 2 .66

Millet Setaria italica 1 to 4 3 .33

Yellow Setaria glauca 1 to 4 2 .66

Seedling Johnsongrass Sorghum halepense 1 to 6 3 .33

Shattercane Sorghum bicolor 4 to 10 2 .66

Texas Panicum Panicum texanum 1 to 4 3 .33

Volunteer Cereals Barley Hordeum vulgare 1 to 4 3 .33

Oats Avena sativa 1 to 4 3 .33

Wheat Triticum aestivum 1 to 4 3 .33

Volunteer Corn Zea Mays 4 to 12 2 .66

Wild Proso Millet Panicum miliaceum 1 to 6 2 .66

Wild Oats Avena fatua 1 to 4 3 .33

*Lengthoflateralgrowth

DIRECTIONS FOR PERENNIAL GRASSES• Makeapplicationonlytoactivelygrowinggrassesatthelistedweedheights.Makeapplicationwhenthefirstgrassweedspeciesinamixedgrassweedpopulationreachesthe

listed growth stage for treatment .

PERENNIAL GRASS SPECIES(1) WEED HEIGHT (inches) RATE(2) FL OZ/A Bermudagrass (Cynodon dactylon)

FirstApplication 3 (or up to 6 runners) 5 .33 10 .67

Repeat Application(s) (if regrowth occurs) 3 (or up to 6 runners) 5 .33 10 .67

Fescue, Tall (Festuca arundinacea)FirstApplication 4 to 8 5 .33 10 .67

Repeat Application(s) if regrowth occurs) 4 to 8 5 .33 10 .67

Foxtail Barley (Hordeum jubatum)FirstApplication 2 to 6 5 .33 10 .67

Repeat Application(s) (if regrowth occurs) 2 to 6 5 .33 10 .67

Orchardgrass (Dactylis glomerata)FirstApplication 4 to 8 5 .33 10 .67


Quackgrass (Elytrigia repens)FirstApplication 4 to 12 5 .33 10 .67


Rhizome Johnsongrass (Sorghum halepense)FirstApplication 12 to 24 5 .33 10 .67

Repeat Application(s) (if regrowth occurs) 6 to 18 4 5 .33

Wirestem Muhly (Muhlenbergia frondosa)FirstApplication 4 to 8 5 .33 10 .67


Perennial BluegrassRoughstalk (Poa trivialis)Kentucky (Poa prantensis)

FirstApplication 2 to 4 5 .33 10 .67


24

PERENNIAL GRASS SPECIES(1) WEED HEIGHT (inches) RATE(2) FL OZ/A Bentgrass (Agrostis spp.)

FirstApplication 2 to 4 — 10 .67

Repeat Application(s) (if regrowth occurs) 2 to 4 — 10 .671 Control of perennial grasses such as quackgrass, perennial bluegrass and bentgrass with this product may be enhanced by adding AMS .2 Usethehigherrateunderheavygrasspressureand/orwhengrassesareatmaximumheight.FollowtheuseraterestrictionsinthatSHADOW 3EC HERBICIDE USE RATES/

RESTRICTIONS/LIMITATIONS table before applying higher rates .

TANK MIXESINFORMATION ThelabelsforeachoftheherbicidesrecommendedfortankmixingwithSHADOW3ECHerbicideareuniquetothecharacteristicsofthoseproductsandcontainrestrictionsandlimitationsthatmaybemorerestrictivethanSHADOW3ECHerbicideincertainconsiderations.Thoseconcernsmayinclude,butarenotlimitedto:• Geographicrestrictions—allproductsarenotregisteredforuseinallareasandratesmayvaryfromoneregionoflabeledusetoanother• Croprotationrestrictionsmaydiffer• Applicatorcertificationrequirements• Workersafetyrules,i.e.,personalprotectiveequipment(PPE),reentrytime,posting• Soilcharacteristicsorsoiltype,e.g.pH,OM• Numberofapplicationsandormaximumdosageperseason• Rainfreeperiodrequired—or• Applicationtiming,e.g.pre-harvestinterval• Totalseasonratesnottobeexceeded.

ALWAYS FOLLOW THE MOST RESTRICTIVE LABELING OF ANY PRODUCT USED IN A TANK MIX.

DIRECTIONS FOR TANK MIX APPLICATION OF SHADOW 3EC HERBICIDE AND BROADLEAF HERBICIDES FOR CONTROL OF GRASSES AND BROADLEAF WEEDS• Makeapplicationonlytoactivelygrowinggrassandbroadleafweedsatlistedheightorgrowthstagelistedoneachlabel.• Makeapplicationwhenthefirstgrassorbroadleafweedspeciesinamixedpopulationreachesthelistedheightorgrowthstagefortreatment.• Makeapplicationunderfavorablesoilmoistureandhumiditythatexistafewdaysafterrainfallorwithinseven(7)daysafterirrigation.• Alwaysaddtheappropriateadjuvanttothespraymixattheratedirectionsforeachspecifictankmixcombination.• Tankmixapplicationcansometimesresultinreducedgrasscontrolandpossibleincreasesincropinjuryascomparedtoeitherproductusedalone.Ifregrowthoccursoran

additionalflushofnewgrassemerges,applyasecondapplicationofSHADOW3ECHerbicideasspecifiedintherespectivesizeandratetables.• DonottankmixSHADOW3ECHerbicidewhenbroadleafweedsaretalland/ordenseenoughtopreventpropergrasscoverage.

ANTAGONISM INFORMATIONTankmixesofSHADOW3ECHerbicidewithpostemergencebroadleafherbicideshaveshownsomereductionorfailuretocontrolcertaingrassspecies,whichwouldhaveotherwisebeencontrolledbySHADOW3ECHerbicidealone.Activityofthepostemergencebroadleafherbicideinthetankmixisnotaffected.

ALFALFASHADOW 3EC HERBICIDE TANK MIXES WITH BROADLEAF HERBICIDES FOR ALFALFA (See crop specific tables for application directions)

TANK MIX PRODUCT1, 2SHADOW 3EC HERBICIDE APPLICATION RATES/A

ANNUAL GRASSES PERENNIAL GRASSESGLYPHOSATE(foruseonRoundupReadyAlfalfaonly)

6.67–10.67floz 6.67–10.67floz

2,4-DB3

PURSUIT®DG4orPURSUIT4

RAPTOR®

BUCTRIL®2L5,6

25

ALFALFASHADOW 3EC HERBICIDE TANK MIXES WITH BROADLEAF HERBICIDES FOR ALFALFA (See crop specific tables for application directions)

TANK MIX PRODUCT1, 2SHADOW 3EC HERBICIDE APPLICATION RATES/A

ANNUAL GRASSES PERENNIAL GRASSES1 Ifgrassregrowthoccursoranadditionalflushofnewgrassemerges,applyasecondapplicationofSHADOW3ECHerbicidealone—withoutatankmixherbicide,accordingto

theappropriatesizeandratedirections.2 Followthelabelofthebroadleaftankmixpartnerforspecifiedratesandadjuvantuse.3 SHADOW3ECHerbicideplus2,4-DBmayincreasetheseverityofcropinjurywhentankmixed.Alfalfawillgenerallyoutgrowthistemporarycropinjurywithinafewweeks.Do

notapplySHADOW3ECHerbicideand2,4-DBasatankmixtoalfalfaunlessthe60dayfeeding,grazing,andharvestingrestrictiononthe2,4-DBlabelcanbeobserved.4 Beforeusingthistankmix,readandunderstandthePURSUITorPURSUITDGlabelsforgeographicalrestrictionsandrestrictionsregardingalfalfagrowthstageandtype.Failure

todosocanresultincropinjurytoalfalfa.DONOTfeed,grazeorharvestalfalfafor30daysfollowinganapplicationofPURSUITtoalfalfa.5 StatesofColorado,Idaho,Montana,Nevada,Oregon,Utah,Washington,WyomingandthewesternhalvesofKansas,Nebraska,NorthDakota,SouthDakota:Thetankmixof

SHADOW3ECHerbicideplusBUCTRILmustbeappliedinthefallorspringtoseedlingalfalfawhenthemajorityofthefieldhasaminimumof2trifoliate.Unacceptablecropinjurycanoccurtoalfalfaseedlingslessthanthe2trifoliateleafstage.BUCTRILplusSHADOW3ECHerbicideapplicationsmadewhentemperaturesareexpectedtoexceed80°Fanddaysfollowingapplicationcanresultinunacceptablecropinjury.Inthestatesnotlistedabove,applyinthefallorspringtoseedlingalfalfawhenthemajorityofthefieldhasaminimumof4trifoliateleaves.Unacceptablecropinjurymayoccurtoalfalfainthe2trifoliateorsmallerstagegrowth,whenalfalfastandisunevenandconditionsfavorleafburn.WhenapplicationsofSHADOW3ECHerbicideplusBUCTRILaremadewhentemperaturesareexpectedtoexceed70°Fandthreedaysfollowingsuchapplicationcanresultinunacceptablecropinjury.CropleafburncanoccurfollowingSHADOW3ECHerbicideplusBUCTRILapplications.Warm,humidconditionsmayenhanceleafburn.However,newcropgrowthwillnotbeaffected.

6 Donotmakeapplicationwhenalfalfaisundermoisture,temperature,insectordiseasestressorhasbeenstressedbyotherpesticidecarryoverorapplication.

CANOLAREDUCED RATE SHADOW 3EC HERBICIDE TANK MIXES WITH BROADLEAF HERBICIDES (See crop specific tables for application directions)

TANK MIX PRODUCT1SHADOW 3EC2 HERBICIDE APPLICATION RATES/A

ANNUAL GRASSES4 PERENNIAL GRASSESIgnite®280SLHerbicide3 2.66–4floz NA1 Followthelabelofthebroadleaftankmixpartnerforspecifiedratesandadjuvantuse.2 DonotapplySHADOW3ECHerbicidetankmixduringorafterboltingorfloweringorcropinjurycouldoccur.3 ForuseonlyonLibertyLink® canola .4 AnnualgrassesandsizescontrolledwiththesetankmixturesarethosethatareidentifiedintheDIRECTIONSFORREDUCEDRATEUSEINDRYBEAN,CANOLA,FLAX,MUSTARD

SEED,SOYBEANANDSUGARBEETFORSMALLANNUALGRASSEStable.

COTTONSHADOW 3EC HERBICIDE TANK MIXED WITH COBRA® AND MSMA APPLIED POST DIRECTED

TANK MIX PRODUCT1SHADOW 3EC HERBICIDE APPLICATION RATES/A2

COMMENTSANNUAL GRASSES3 PERENNIAL GRASSES3

COBRA + MSMA (4 .0 lbs/gal)or

MSMA (6 .6 lbs/gal)4–5.33floz 5.33–10.67floz

Reduce broadcast rate in proportion to the band area actually treated .

1 Followthelabelofthebroadleaftankmixpartnerforspecifiedratesandadjuvantuse.2 Ifgrassregrowthoccursoranadditionalflushofnewgrassemerges,applyasecondapplicationofSHADOW3ECHerbicidealone—withoutatankmixherbicide—according

totheappropriatesizeandratedirections.3 Ifatthetimeofapplication,grassheightissotallthatpost-directedapplicationscannotgetgoodcoverageoverthetopofthegrassyweeds,thenpoorcontrolcanresultand

asecondnon-postdirectedapplicationofSHADOW3ECHerbicidemaybenecessary.

COTTONSHADOW 3EC HERBICIDE TANK MIXED WITH GLYPHOSATE TO CONTROL EMERGED GRASSES IN ROUNDUP READY® COTTON AS A BROADCAST APPLICATION

TANK MIX PRODUCT1SHADOW 3EC HERBICIDE APPLICATION RATES/A

ANNUAL GRASSES PERENNIAL GRASSESGLYPHOSATE 4–5.33floz 5.33–10.67floz1 Followthelabelofthetankmixpartnerforspecifiedratesandadjuvantuse.

26

COTTONSHADOW 3EC HERBICIDE TANK MIX- WITH IGNITE 280 SL HERBICIDE FOR THE CONTROL OF GRASSES AND VOLUNTEER CORN IN LIBERTYLINK COTTON

TANK MIX PRODUCT1 SHADOW 3EC HERBICIDE APPLICATION RATES/A

CORN HEIGHT(inches)

IGNITE280SL(foruseonLIBERTYLINKCottononly)

2.67floz Upto12inches

4floz Upto24inches

5.33floz Upto36inches1 Followthelabelofthetankmixpartnerforspecifiedratesandadjuvantuse.

DRY SHELLED BEANSSHADOW 3EC HERBICIDE TANK MIXES WITH BROADLEAF HERBICIDES (See crop specific tables for application directions)


ANNUAL GRASSES PERENNIAL GRASSESBASAGRAN®

5.33–6.67floz 6.67–10.67flozRAPTOR1 Ifgrassregrowthoccursoranadditionalflushofnewgrassemerges,makeasecondapplicationofSHADOW3ECHerbicidealone—withoutatankmixherbicide—according

totheappropriatesizeandratedirections.2 Followthelabelofthetankmixpartnerforspecifiedratesandadjuvantuse.

DRY SHELLED PEASSHADOW 3EC HERBICIDE TANK MIXES WITH BROADLEAF HERBICIDES (See crop specific tables for application directions)


ANNUAL GRASSES3 PERENNIAL GRASSESBASAGRAN

4–5.33floz NARAPTOR1 Apply prior to bloom .2 Followthelabelofthetankmixpartnerforspecifiedratesandadjuvantuse.3 Grassregrowthorincompletecontrolmayoccurwiththesetankmixes.Makeapplicationstosmallgrassesandifregrowthoccursretreatwithanothergraminicide.

FLAXREDUCED RATE SHADOW 3EC HERBICIDE TANK MIXES WITH BROADLEAF HERBICIDES (See crop specific tables for application directions)

TANK MIX PRODUCT1,2,3SHADOW 3EC HERBICIDE APPLICATION RATES/A1

ANNUAL GRASSES4 PERENNIAL GRASSESBRONATEADVANCED™

2.67–3.33floz NA

Bromoxynil + MCPA

BUCTRIL

Curtail® M

MCPA1 Followthelabelofthetankmixpartnerforspecifiedratesandadjuvantuse.2 Do Not apply during or after the bud stage or to ornamental flax as crop injury can occur3 DoNotapplytankmixeswhentemperaturesareexpectedtoexceed85°Fatorfor3daysfollowingapplicationascropinjurycanoccur.4 AnnualgrassesandsizescontrolledwiththesetankmixturesarethosethatareidentifiedintheDIRECTIONSFORREDUCEDRATEUSEINDRYBEAN,CANOLA,FLAX,MUSTARD

SEED,SOYBEANANDSUGARBEETFORSMALLANNUALGRASSEStable.

27

SOYBEAN BURNDOWNSHADOW 3EC HERBICIDE TANK MIX WITH 2,4-D ESTER IN A BURNDOWN APPLICATION IN NO-TILL SOYBEAN FOR CONTROL OF ANNUAL GRASSES.

TANK MIX PRODUCT1 SHADOW 3EC HERBICIDE APPLICATION RATE/A

ANNUAL GRASS HEIGHT2,3 (inches)

2,4-D ester

2.67floz 1–3Inchfoxtail

4floz 1–4Inchfoxtail

5.33floz Followgrasschartforheights1 Followthe2,4-Desterlabelforspecifiedratesanddriftcontrolmeasuresrequired.2 AlwaysuseCropOilConcentrateat1qt/Aandnitrogenfertilizerforbestcontrolofburndowngrasses.3 AdditionalproductscanbetankmixedwithSHADOW3ECHerbicide+2,4-DEsterforresidualcontrol.Theseinclude:Valor®, Canopy®XL,metolachlor,Prowl®andmetribuzen.

SOYBEANSHADOW 3EC HERBICIDE TANK MIX- WITH GLYPHOSATE FOR THE CONTROL OF VOLUNTEER CORN (INCLUDING ROUNDUP READY) IN SOYBEAN

TANK MIX PRODUCT1,2 SHADOW 3EC HERBICIDE APPLICATION RATE/A

CORN HEIGHT(inches)

GLYPHOSATE(foruseonRoundupReadySoybeanonly)


4floz Upto24inches

5.33floz Upto36inches1 Foradjuvantloadedglyphosateformulationsadd0.25%v/vofadditionalnon-ionicsurfactant.Forunloadedglyphosateformulationsadd1%v/vCropOilConcentrate.2 ThistankmixmaybeappliedpostemergencetoRoundupReadysoybeansupthroughfullfloweringstage.Donotapplylessthan60daysbeforeharvest.

SOYBEANSHADOW 3EC HERBICIDE TANK MIX- WITH IGNITE 280 SL HERBICIDE FOR THE CONTROL OF GRASSES AND VOLUNTEER CORN IN SOYBEAN

TANK MIX PRODUCT1 SHADOW 3EC HERBICIDE APPLICATION RATE/A

CORN HEIGHT(inches)

IGNITE280SL(foruseonLIBERTYLINKSoybeanonly)


4floz Upto24inches

5.33floz Upto36inches1 Followthelabelofthetankmixpartnerforspecifiedratesandadjuvantuse.

SOYBEANSHADOW 3EC HERBICIDE TANK MIXES WITH BROADLEAF HERBICIDES (See crop specific tables for application directions)

TANK MIX PRODUCT2,3,4 SHADOW 3EC HERBICIDE APPLICATION RATE FOR ANNUAL GRASS CONTROL1,5

COBRA

4–5.33floz/A

FIRSTRATE®

FLEXSTAR®HL

FRONTROW™

HARMONY®GT

PHOENIX™

RESOURCE®

BASAGRAN

5.33–6.67floz/APURSUIT

RAPTOR

SYNCHRONY®STS®orSYNCHRONYXP(mp)(STSsoybeansonly)

28

SOYBEANSHADOW 3EC HERBICIDE TANK MIXES WITH BROADLEAF HERBICIDES (See crop specific tables for application directions)

TANK MIX PRODUCT2,3,4 SHADOW 3EC HERBICIDE APPLICATION RATE FOR ANNUAL GRASS CONTROL1,5

1 Ifgrassregrowthoccursoranadditionalflushofnewgrassemerges,makeasecondapplicationofSHADOW3ECHerbicidealone—withoutatankmixherbicide—accordingtotheappropriatesizeandratedirections.

2 Followthelabelofthetankmixpartnerforspecifiedratesandadjuvantuse.3 AMScanbeaddedtoalltankmixpartnersforimprovedgrasscontrol.4 Refer to the label of the tank mix partner for geographic and rotational restrictions .5 AnnualgrassesandsizescontrolledwiththesetankmixturesarethosethatareidentifiedintheDIRECTIONS FOR REDUCED RATE USE IN DRY BEAN, CANOLA, FLAX, MUS-

TARD SEED, SOYBEAN AND SUGAR BEET FOR SMALL ANNUAL GRASSES table .

PEANUTSHADOW 3EC HERBICIDE TANK MIXES WITH BROADLEAF HERBICIDES (See crop specific tables for application directions)


ANNUAL GRASSES PERENNIAL GRASSESBASAGRAN

5.33–6.67floz NASTORM®

ULTRABLAZER®

1 MakeasecondapplicationofSHADOW3ECHerbicidealone—withoutatankmixherbicide—accordingtotheappropriatesizeandratedirections,ifgrassregrowthoccursoran additional flush of new grass emerges .

2 Followthelabelofthetankmixpartnerforspecifiedratesandadjuvantuse.

PEANUTDIRECTIONS FOR GRASS SUPPRESSION FOR HARVEST EFFICIENCY WITH SHADOW 3EC HERBICIDE

GRASS SPECIES WEED STAGE RATE FL OZ/AAnnual and perennial grasses that exceed height claimed for control on height charts,DIRECTIONS FOR ANNUAL GRASSES & DIRECTIONS FOR PERENNIAL GRASSES

Uptoandincludinggrassesintheseedheadstage 10 .67 21 .33

DonotapplyaspartofatankmixwhenapplyingSHADOW3ECHerbicideforgrasssuppression.

SUGAR BEET SHADOW 3EC HERBICIDE TANK MIXED WITH STINGER® HERBICIDE OR FUNGICIDES (See crop specific tables for application directions)


ANNUAL GRASSES3 PERENNIAL GRASSESSTINGER

4–5.33floz 5.33–10.67floz

GLYPHOSATE(foruseonRoundupReadySugarbeetonly)

EMINENT®

HEADLINE®

GEM™1 MakeasecondapplicationofSHADOW3ECHerbicidealone—withoutatankmixherbicide—accordingtotheappropriatesizeandratedirections,ifgrassregrowthoccursor

an additional flush of new grass emerges .2 Followthelabelofthetankmixpartnerforspecifiedratesandadjuvantuse.3 AnnualgrassesandsizescontrolledwiththesetankmixturesarethosethatareidentifiedintheDIRECTIONS FOR REDUCED RATE USE IN DRY BEAN, CANOLA, FLAX, MUS-

TARD SEED, SOYBEAN AND SUGAR BEET FOR SMALL ANNUAL GRASSES table .

TANK MIX APPLICATION OF SHADOW 3EC HERBICIDE AND INSECTICIDES FOR CONTROL OF GRASS WEEDS AND INSECTS.SHADOW3ECHerbicidecanbetankmixedwithinsecticidesthatareregisteredforuseineachspecificcrop.Certaininsecticidescancausetemporaryphytotoxicsymptomsonal-falfaandmintfoliage.Forfurtherinformationontankmixingwithaninsecticide,refertotheinsecticideproductlabel.Priortousinganyoftheseinsecticide/herbicidetankmixtures,itisrecommendedtotreatasmallareaofthefieldandobservedforcropinjurybeforetreatingtheentirefieldwiththetankmixture.Followthelabelofthetankmixpartnerforspecifiedratesandadjuvantuse.

29

FALLOW LANDDIRECTIONS FOR USESHADOW3ECHerbicidecanbeusedtocontrolannualandperennialgrassesinlandthathasbeenleftfallowthepreviousyearandonothernon-producingagriculturalareas.Makeapplicationat4–5.33floz/Aforannualgrassesand10.67–21.33floz/Aforperennialgrasses.SHADOW3ECHerbicidecanbetankedmixedwith2,4-DesterorBANVEL® forbroadspectrumcontrolwhenbothgrassandbroadleafweedsarethetargetpest.Applyaminimumof10.67floz/ASHADOW3ECHerbicidewhenbothannualandperennialgrasses occur in the same field .

INFORMATIONUseaminimumsprayvolumeof5gal/Aforaerialapplicationsand15gal/Aforgroundapplications.Makeapplicationsonlytoactivelygrowinggrasseswhenthefirstgrassreachesthe recommended weed height as specified by the DIRECTIONS FOR ANNUAL AND PERENNIAL GRASSES section of this label .Do not apply to drought stressed grasses .Donotapplytograssesthathavetillered,formedseed-headsorexceededrecommendedgrowthstage.Donotplantanycropfor30daysafterapplicationunlessSHADOW3ECHerbicideisregisteredforuseonthatcrop.AnnualgrassesthatemergeaftertheSHADOW3ECHerbicideapplicationwillnotbecontrolledandasecondapplicationcouldbenecessary.Donotmowareafortwo(2)weekspriortooraftertheSHADOW3ECHerbicideapplication.Control of perennial grasses may require more than one (1) application in non-tilled areas .

SHADOW 3EC HERBICIDE IN TANK MIXES TO CONTROL ANNUAL AND PERENNIAL GRASSES IN FALLOW LAND

TANK MIX PRODUCTSHADOW 3EC HERBICIDE APPLICATION RATES/A1,2

ANNUAL GRASSES PERENNIAL GRASSES2,4-D ester

orBANVEL

4–5.33floz 10.67–21.33floz.

1 SeetheBANVELand2,4-Desterlabelsforuserates,weedscontrolledandcroprotationrestrictions.2 Alwaysuseacropoilconcentrateat1%v/v.

SHADOW 3EC HERBICIDE TO CONTROL EXISTING STANDS OF FIELD CORN AND VOLUNTEER FIELD CORN (BURNDOWN)Time From Application

to Re-seeding cornUse Rate per

AcreAdjuvant Recommendation Special Use Instructions and Restrictions

6 days 2flozCOCat1%v/vplusAMSat

2 .5 to 4 .0 lb/A

WeedSize—upto12inches.Do not make more than 1 application per season .Donotapplymorethan2floz/Aperseason.Caremustbetakentoavoidin-fieldboom(spray)overlapsorexcessivecropinjurymayoccur .90dayPre-HarvestInterval

DIRECTIONS FOR GRASS SUPPRESSION IN NON-CROP AREAS WITH SHADOW 3EC HERBICIDEGRASS SPECIES WEED STAGE RATE FL OZ/A

Annual and perennial grasses that exceed height claimed for control on height chart

Uptoandincludinggrassesintheseedheadstage8 21 .33

DonotapplyaspartofatankmixwhenapplyingSHADOW3ECHerbicideforgrasssuppression.

SHADOW 3EC HERBICIDE FOR THE CONTROL AND/OR SUPPRESSION OF TALL FESCUE IN NATIVE PRAIRIE WARM-SEASON GRASS RESTORATION PROJECTS

PRODUCT PRODUCT RATESGRASS WEEDS CONTROLLED/SUPPRESSED

WEED STAGESCommon Name Scientific Name

SHADOW3ECHerbicide 6.67–8floz/A TallFescue Festuca arundinacea 4to6inchestall(40–60%green-up)

ADJUVANT:SHADOW3ECHerbicidemustbeappliedwithcropoilconcentrateat1qt/Aandaspraygradeammoniumsulfate(AMS)at2.5–4lb/Aor8.5–17.0lb/100gallonsofspray solution . SpecifiedMixingOrder:Thoroughlymixspraygradeammoniumsulfateinwater,thenaddSHADOW3ECHerbicide.

SPECIAL APPLICATION INSTRUCTIONS• Burnormowfieldsaminimumof3weekspriortoapplicationtoremoveexcesscropresidue.• Makeapplicationinthespringat40–60%tallfescuegreen-up,priortoemergenceofwarm-seasongrasses.• Makeapplicationinaminimumof15–20gallonswaterperacre.

30

• Makeapplicationonlytofieldsthathavewarmseasongrassesestablishedfortwo(2)years.

PRECAUTIONS• ApplicationofSHADOW3ECHerbicidetoemergedwarm-seasongrassesmaycauseinjury.

RESTRICTIONS• Donotmowareafortwo(2)weeksaftertheSHADOW3ECHerbicideapplication.• Donotmakeapplicationstowarm-seasongrassesgrownforseed.• Donotgrazetreatedfieldsorfeedtreatedforageand/orhaytolivestock.• Donotplantanycropfor30daysafterapplication,unlessclethodimisregisteredforuseonthatcrop.

SHADOW 3EC HERBICIDE FOR THE SUPPRESSION OF TALL FESCUE SEED-HEADS IN NON-PRODUCING AGRICULTURAL AREAS

PRODUCT PRODUCT RATEGRASS WEEDS CONTROLLED/SUPPRESSED

APPLICATION TIMINGCommon Name Scientific Name

SHADOW3ECHerbicide 1–1.33floz/A TallFescueSeed-Heads Festuca arundinacea (50to90%TallFescuegreen-up)

ADJUVANT:SHADOW3ECHerbicidemustbeappliedwithcropoilconcentrateat1qt/Aandaspraygradeammoniumsulfate(AMS)at2.5–4lb/Aor8.5–17.0lb/100gallonsofspray solution . SpecifiedMixingOrder:Thoroughlymixspraygradeammoniumsulfateinwater,thenaddSHADOW3ECHerbicide.

SPECIAL APPLICATION INSTRUCTIONS• Makeapplicationat50–90%tallfescuegreen-up.• Iflesstallfescuegreenmatterispresent,usethehigherSHADOW3ECHerbiciderate.• Makeapplicationinaminimumof15–20gallonswaterperacreataspraypressureof40–60PSIatthenozzle.Makeapplicationusingflatfanorhollowconenozzles.Donot

usefloodnozzles.

PRECAUTIONS• 2,4-Dester,Tordon®22K,Grazon®, P+D or Crossbow® may be added to this tank mix for broadleaf control (see the tank mix label for use rates, and for weeds controlled .)

RESTRICTIONS• Donotmowareafortwo(2)weeksaftertheSHADOW3ECHerbicideapplication.• Donotgrazetreatedfieldsorfeedtreatedforageand/orhaytolivestock.• Donotplantanycropfor30daysafterapplicationunlessclethodimisregisteredforuseonthatcrop.

STORAGE AND DISPOSALDo not contaminate water, food or feed by storage or disposal . Pesticide Storage: Storeinacool,dryplaceandinsuchamannerastopreventcrosscontaminationwithotherpesticides,fertilizers,food,andfeed.Storeinoriginalcontainerandoutofreachof children, preferably in a locked storage area .Handleandopencontainerinamannerastopreventspillage.Ifthecontainerisleakingormaterialspilledforanyreasonorcause,carefullysweepmaterialintoapile.RefertoPrecautionaryStatementsonlabelforhazardsassociatedwiththehandlingofthismaterial.Donotwalkthroughspilledmaterial.Disposeofpesticideasdirectedbelow.Inspillorleakincidents,keepunauthorizedpeopleaway.Forhelpwithanyspill,leak,fireorexposureinvolvingthismaterial,calldayornightCHEMTREC(800)424-9300or(703)527-3887ifcallingfromoutsideoftheU.S.Pesticide Disposal: Wastesresultingfromtheuseofthisproductmaybedisposedofonsiteoratanapprovedwastedisposalfacility.Improperdisposalofexcesspesticide,spraymixtureorrinsateisaviolationofFederalLaw.Ifthesewastescannotbedisposedofbyuseaccordingtolabelinstructions,contactyourStatePesticideorEnvironmentalControlAgency,ortheHazardousWasterepresentativeatthenearestEPARegionalOfficeforguidance.Container Handling: Rigid,Non-refillablecontainerssmallenoughtoshake(i.e.,withcapacitiesequaltoorlessthan5gallons).Non-refillablecontainer.Donotreuseorrefillthiscontainer.Triplerinseorpressurerinsecontainer(orequivalent)promptlyafteremptying.Triplerinseasfollows:Emptytheremainingcontentsintoapplicationequipmentoramixtank.Fillthecontainer ¼ full with water and recap . Shake for 10 seconds . Pour rinsate into application equipment or a mix tank or store rinsate for later use or disposal . Drain for 10 seconds aftertheflowbeginstodrip.Repeatthisproceduretwomoretimes.Offerforrecycling,ifavailableorpunctureanddisposeofinasanitarylandfillorbyotherproceduresap-provedbystateandlocalauthorities.Pressurerinseasfollows:Emptytheremainingcontentsintoapplicationequipmentoramixtankandcontinuetodrainfor10secondsaftertheflowbeginstodrip.Holdcontainerupsidedownoverapplicationequipmentormixtankorcollectrinsateforlateruseordisposal.Insertpressurerinsingnozzleinthesideofthecontainer,andrinseatabout40PSI for at least 30 seconds . Drain for 10 seconds after the flow begins to drip .Oncecontainerisrinsed,offerforrecyclingifavailable,orpunctureanddisposeofinasanitarylandfill.

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Warranty and Disclaimer StatementThedirectionsforuseofthisproductarebelievedtobeadequateandmustbefollowedcarefully.However,itisimpossibletoeliminateallrisksassociatedwiththeuseofthisproduct.Suchrisksmayarisefromweatherconditions,soilfactors,off-targetmovement,unconventionalfarmingtechniques,thepresenceofothermaterials,themannerofuseorapplication,orotherunknownfactors,allofwhicharebeyondthecontrolofArystaLifeScienceNorthAmerica,LLC(“Arysta”),andcancausecropinjury,injurytonon-targetcropsorplants,ineffectivenessoftheproduct,orotherunintendedconsequences.Allsuchrisksshallbeassumedbytheuserorbuyer.ArystawarrantsthatthisproductconformstothechemicaldescriptiononthelabelandisreasonablyfitforthepurposesstatedintheDirectionsforUse,subjecttotheinherentrisksdescribedabove,whenusedinaccordancewiththeDirectionsforUseundernormalconditions.ThiswarrantydoesnotextendtotheuseofthisproductcontrarytolabelinstructionsorunderconditionsnotreasonablyforeseeabletoArysta,andissubjecttotheinherentrisksdescribedabove.TO THE EXTENT CONSISTENT WITH APPLICABLE LAW, ARYSTA DISCLAIMS ALL OTHER WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING ANY WARRANTY OF MER-CHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE. TO THE EXTENT CONSISTENT WITH APPLICABLE LAW, ARYSTA, MANUFACTURER, AND SELLER DISCLAIM AND SHALL NOT BE LIABLE FOR ANY SPECIAL, INCIDENTAL, INDIRECT, OR CONSEQUENTIAL DAMAGES RESULTING FROM THE USE, HANDLING, APPLICATION, STORAGE, OR DISPOSAL OF THIS PRODUCT OR FOR DAMAGES IN THE NATURE OF PENALTIES, AND THE USER AND BUYER WAIVE ANY RIGHT THAT THEY MAY HAVE TO SUCH DAMAGES. NO AGENT, REPRESENTATIVE OR EMPLOYEE OF ARYSTA IS AUTHORIZED TO MAKE ANY WARRANTY, GUARANTEE OR REPRESENTATION BEYOND THOSE CONTAINED HEREIN OR TO MODIFY THE WARRANTIES CONTAINED HEREIN.TO THE EXTENT CONSISTENT WITH APPLICABLE LAW, THE EXCLUSIVE REMEDY OF THE USER OR BUYER, AND THE TOTAL LIABILITY OF ARYSTA, MANUFACTURER, AND SELLER, SHALL BE LIMITED TO THE PURCHASE PRICE PAID, OR AT ARYSTA’S ELECTION, THE REPLACEMENT OF THE PRODUCT.

ArystaLifeScienceandtheArystaLifeSciencelogoareregisteredtrademarksofArystaLifeScienceCorporation.SHADOW®andtheSHADOWlogoareregisteredtrademarksofArystaLifeScienceNorthAmerica,LLC.HARMONY®,STS®,andSYNCHRONY®areregisteredtrademarksofE.I.duPontdeNemours&Co.,Inc.BASAGRAN®,HEADLINE®, IMI-CORN®,PURSUIT®,andRAPTOR®areregisteredtrademarksofBASFCorp.BUCTRIL®,IGNITE®,andLIBERTYLINK®areregisteredtrademarksandBRONATEADVANCED™andGEM™aretrademarksofBayerCropScience.COBRA®andRESOURCE®areregisteredtrademarksandPHOENIX™isatrademarkofValentU.S.A.Corp.CROSSBOW®,CURTAIL®,FIRSTRATE®,GRAZON®,STINGER®,andTORDON®areregisteredtrademarksandFRONTROW™isatrademarkofDowAgroSciencesLLC.EMINENT®isaregisteredtrademarkofISAGROS.P.A.FLEXSTAR®isaregisteredtrademarkofSyngentaGroupCompany.ROUNDUPREADY®isaregisteredtrademarkofMonsantoTechnologyCompany,LLC.STORM®andULTRABLAZER®areregisteredtrademarksofUnitedPhosphorus,Inc.

PEEL HERE —— TO OPEN Herbicide - CDMS · (If you do not understand the label, ... , SHADOW 3EC...

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