OZA GeoEnvironmental, Inc. - United States … GeoEnvironmental, Inc. 380 Harvey Road Manchester New...
Transcript of OZA GeoEnvironmental, Inc. - United States … GeoEnvironmental, Inc. 380 Harvey Road Manchester New...
Englnurs Qld
Scientists IOZA GeoEnvironmental Inc
380 Harvey Road Manchester New Hampshire 03103-3347 603-623-3600 FAX 603-624-9463 wwwgzacom
April 12 2012 File No 04002930700
Ms Amy Daigneault Pretreatment Coordinator Lowell Regional Wastewater Utility 451 First St Blvd (Rte 110) Lowell Massachusetts O1850
Re Supplemental Monthly Self-Monitoring Report March 2012 Merrimack Station Public Service ofNew Hampshire Bow New Hampshire
Dear Ms Daigneault
On behalf of Public Service of New Hampshire (PSNH) OZA OeoEnvironmental Inc (OZA) is pleased to submit a supplement to the Self-Monitoring Report previously submitted for the period March 1 2012 through March 31 2012 The attached Table 1 summarizes the data contained in the attached Analytical Data Report from the Stream B sample collected on March 14 2012 The results indicate that pollutant concentrations were within the Local Sewer Discharge Limits
The analysis on samples collected on March 14 2012 was performed in accordance with the United States Environmental Protection Agency (EPA) draft Standard Operating Procedure (SOP) for trace metals analysis of flue gas desulfurization (FOD) wastewater The SOP is described below
ANALYTICAL DISCUSSION
FOD wastewater requires specialized analytical techniques to overcome matrix interference for certain analysis of trace metals To assist you in evaluating this issue further we offer an excerpt below from the EPA web site and a link to their draft SOP for trace metals analysis ofFOD wastewater that contains further guidance
LABORATORY ANALYSIS OF FOO WASTEWATER
Wastewater from FOD systems can contain constituents known to cause matrix interferences E PA has observed that during inductively coupled plasma - mass spectrometry (ICP-MS) analysis ofFOD wastewater certain elements commonly present in the wastewater may cause polyatomic interferences that bias the detection andor quantification of certain elements of interest These potential interferences may become significant when measuring trace elements at concentrations in the low parts-per-billion range
Copyrightcopy 2012 OZA OeoEnvironmental Inc
An Equal Owortuniiy Employer MFNH
Lowell Regional Wastewater Utility File No 04002930700
April 12 2012 Page2
As part of a recent sampling effort for the steam electric power generating effluent guidelines rulemaking EPA developed an SOP that was used in conjunction with EPA Method 2008 to conduct ICP-MS analyses ofFGD wastewater The SOP describes critical technical and quality assurance procedures that were implemented to mitigate anticipated interferences and generate reliable data for FGD wastewater EPA regulations at 40 CFR 1366 already allow the analytical community flexibility to modify approved methods to lower the costs ofmeasurements overcome matrix interferences or otherwise improve the analysis The draft SOP developed for FGD wastewatermiddot takes a proactive approach toward looking for and taking steps to mitigate matrix interferences including using specialized interference check solutions (ie a synthetic FGD wastewater matrix) EPAs draft SOP is being made available to laboratories contemplating ICP-MS analysis of FGD wastewater either for adoption as currently written or to serve as a framework for developing their own laboratory-specific SOPs For further information please see the following
bull Draft SOP Inductively Coupled PlasmaMass Spectrometry for Trace Element Analysis in Flue Gas Desulfurization Wastewaters (30 pp 174K ) httpwater epagovlscitechwastetechguideuploadlsteam _draft _soppdf EPA May 2011
Considering that specialized analytical techniques are necessary to overcome matrix interference for certain analysis of trace metals in FGD wastewater we recommend any analysis on FGD wastewater be conducted in accordance with the EPA draft SOP for trace metals analysis ofFGD wastewater
Should you have any questions concerning this report please do not hesitate to contact me at (603) 232-8744
Very truly yours
GZA GEOENVIRONMENT AL INC
Ronald A Breton PE Michael P North PE Principal ConsultantReviewer
RABMPN tmd P-l)IJobs0029)00$(W002910lOCJWarlSAMtlNG ANO REPORTINGREPORTSlvelJStJQm13Mir(h B 5Upp)cmcn1final 29307 STREAMB March Splmnt 041212docN
Attachments Table Analytical Data Report
TABLE
TABLEl SUMMARY OF STREAM B CONCENTRATIONS
COMPARED TO LOWELL SEWER DISCHARGE LIMITS Public Service ofNew Hampshire
Merrimack Station Bow New Hampshire
PARAMETER LOWELL SEWER
DISCHARGE LIMITS (mgL)
STREAM B RESULTS 3142012
(mgIL)
Aluminum 2469 0371
Arsenic 0556 00377
Cadmium 0056 000248 Chromium (T) 8108 00532
Copper 3124 00182
Lead 0857 lt 000198
Mercury 0004 00000612
Nickel 1541 0303 pH 50-95 69
Silver 0053 lt 0000990
Zinc 4959 00775
P04obsl0029300sl04002930700WortSAMPLING AND REPORTINGIDATAI 04002930700 RESULTS 032112xll1ltLltgtwcll B GZA GeoEnvironmental Inc
ANALYTICAL DATA REPORT
~--fLAA____________e_a_s_t_e_r_n_a_n_a_ly_t_i_c_a_l__
Paul Pepler
GZA GeoEnvironmental Inc (NH)
380 Harvey Road
Manchester NH 03103
Subject Laboratory Report
Eastern Analytical Inc ID 108420
Client Identification MK
Date Received 3142012
Dear Mr Pepler
Enclosed please find the laboratory report for the above identified project All analyses were performed in accordance with our QAQC Program Unless otherwise stated holding times preservation techniques container types and sample conditions adhered to EPA Protocol Samples which were collected by Eastern Analytical Inc (EAi) were collected in accordance with approved EPA procedures Eastern Analytical Inc certifies that the enclosed test results meet all requirements of NELAP and other applicable state certifications Please refer to our website at wwweailabscom for a copy ofour NELAP certificate and accredited parameters
The following standard abbreviations and conventions apply to all EAi reports Solid samples are reported on a dry weight basis unless otherwise noted lt less than followed by the reporting limit gt greater than followed by the reporting limit R Recovery
Eastern Analytical Inc maintains certification in the following states Connecticut (PH-0492) Maine (NH005) Massachusetts (M-NH005) New HampshireNELAP (1012) Rhode Island (269) and Vermont (VT1012)
The following information is contained within this report Sample Conditions summary Analytical ResultsData Quality Control data (if requested) and copies of the Chain of Custody This report may not be reproduced except in full without the the written approval of the laboratory
If you have any questions regarding the results contained within please feel free to directly contact me or the chemist(s) who performed the testing in question Unless otherwise requested we will dispose of the sample(s) 30 days from the sample receipt date
We appreciate this opportunity to be of service and look forward to your continued patronage
Sincerely
11micro3= Date
JS of pages (excluding cover letter)
11middot1111Llibb ~(( 1111
SAMPLE CONDITIONS PAGE EAi ID 108420
Client middot GZA GeoEnvironmental Inc (NH)
Client Designation MK
Temperature upon receipt (degC) 184 Received on ice or cold packs (YesNo) y Acceptable temperature range (degC) 0-6
Date Date Sample Dry Lab ID Sample ID Received Sampled Matrix Weight ExceptionsComments (other than thermal preservation)
10842001 SWWTF 31412 31412 aqueous Adheres to Sample Acceptance Policy
Samples were properly preserved and the pH measured when applicable unless otherwise noted Analysis ofsolids for pH Flashpoint lgnitibility Paint Filter Corrosivity Conductivity and Specific Gravity are reported on an middotas received basis
All results contained in this report relate only to the above listed samples References include 1) EPA 6004-79-020 1983 2) Standard Methods for Examination ofWater and Wastewater lnorganics 19th Edition 1995 Microbiology 20th Edition 1998 3) Test Methods for Evaluating Solid Waste SW 846 3rd Edition Including updates VA and VB 4) Hach Water Analysis Handbook 2nd edition 1992
eastern analytical inc wwweailabscom Phone (603) 228-0525 1
LABORATORY REPORT EAi I 0 108420
Client GZA GeoEnvironmental Inc (NH)
Client Designation MK
Sample ID SWNTF
Lab Sample ID 10842001
Matrix aqueous
Date Sampled 31412
31412Date Received
Solids Suspended 25000 Solids Dissolved 180000 Chloride 75000 BOD 140 COD 900 pH 69
Analysis
Units Date Time Method Analyst
mgL 31912 1345 2540D DLS mgL 31912 1500 2540C DLS mgL 311912 1030 4500CIE DLS mgL 31512 1412 52108 SKC mgL 32012 900 H8000 KJR SU 31412 1705 4500H+B Jl
TDS Due to sample matrix a constant weight of 000059 could not be achieved
eastern analytical inc wwweailabscom Phone (603) 228-0525 2
QC REPORT EAIID 10842011Jul Client GZA GeoEnvironmental Inc (NH)
Client Designation MK
Date of
Parameter Name Blank LCS LCSO Units Analysis Limits RPO Method
Solids Suspended lt5 96 (96 ooR) 100 (100 ooR) (4 RPO) mgL 31912 90 -110 20 2540D
Solids Dissolved lt5 990 (99 R) NA mgL 31912 85 - 115 20 2540C
Chloride lt 1 27 (106 ooR) 26 (106 ooR) (0 RPD) mgL 31912 90 - 110 20 4500CIE
BOD lt6 400 (100 R) 410 (102 R) (2 RPD) mgL 31512 84-115 20 52108
COD lt 10 100 (97 R) 100 (101 R) (4 RPD) mgL 32012 85 -115 20 H8000
pH 60 (100 ooR) 60 (100 ooR) (0 RPD) SU 31412 595 - 607 10 4500H+B
Duplicate Duplicate Date of Parameter Name Parent ID Parent Duplicate Units Analysls RPO Method
Solids Suspended 10850303 200 190 (4RPD) mgL 31912 20 2540D Solids Dissolved 10843101 270 270 (0 RPO) mgL 31912 20 2540C Chloride NA NA mgL 31912 20 4500CIE BOD NA NA mgL 31512 20 52108 COD NA NA mgl 32012 20 H8000 pH 10838601 82 82 (0 RPO) SU 31412 10 4500H+B
Samples were analyzed within holding times unless noted on the sample results page Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits The associated matrix spikes andor Laboratory Control Samples met the above stated criteria Exceptions to the above statements are flagged or noted above or on the QC Narrative page bull11 Flagged analyte recoveries deviated from the QAQC limits
eastern analytical inc wwweailabscom Phone (603) 228-0525 3
Ill
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
G L OS AL S ( I E N lt ES
04 April 2012
JeffGagne
Eastern Analytical Inc
25 Chenell Drive
Concord NH 03301
RE Merrimack Station 2008
Enclosed are the analytical results for samples received by Frontier Global Sciences All quality control
measurements are within established control limits and there were no analytical difficulties encountered
with the exception ofthose listed in the case narrative section of this report
Ifyou have any questions concerning this report please feel free to contact me
Sincerely 44
Liz Siska
Project Manager
4
~ 11720 North Creek Parkway North Suite 400
Bothell WA 9801 1 Ph 425-686-1996 Fx 425-686-3096
GLOBAl SCIENCES
ANALYTICAL REPORT FOR SAMPLES
Laboratory Frontier Global Sciences Inc SDG
Client Eastern Analytical ]nc Project Merrimack Station 2008
Sample ID Lab ID Matrix Date Sampled Date Received
SWWTF 1203203-01 Water 14-Mar-12 1305 16-Mar-12 0940
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Pagel o20 1203203 Final Report-SWWTF REV2
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Liz Siska Project Manager 5
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
CASE NARRATIVE
Revised Report 4412- Sample name corrected to SWWTF
SAMPLE RECEIPT
Samples were received at Frontier Global Sciences (FGS) on March 16th 2012 The samples were received intact on-ice with temperatures measuredat 22 degrees Celsius
SAMPLE PREPARATION AND ANALYSIS
Samples were prepared and analyzed for total metals in accordance with EPA Method 2008 (modified)
Samples were prepared and analyzed for total mercury in accordance with EPA Method 163 JE
ANALYTICAL ISSUES
The client requested sample SWWTF (1203203-0 l) be analyzed for Mn via email on 31512
Samples were received in a cooler ofmelted ice There was water in the inner most bag of sample Evaporator (1203203-02)
As an additional measure ofthe accuracy ofthe methods utilized for analysis and to check for matrix interference matrix spikes (MS) and matrix spike duplicates (MSD) were digested and analyzed All ofthe matrix spike recoveries were within the control limits with the exception ofany QC flagged and described in the notes and definitions section ofthe following report
A reasonable measure ofthe precision ofthe analytical methods utilized for analysis is the relative percent difference (RPD) between matrix spike and matrix spike duplicate recoveries and between laboratory control sample and laboratory control sample duplicate recoveries All of the relative percent differences were within the control limits with the exception ofany QC flagged and described in the notes and definitions section ofthe following report
Frontier Global Sciences Inc The results in this report 011y apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 2 of20 1203203 Final Report- SWWTF REV2
04042012
Liz Siska Project Manager 6
FRONTIER
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIE NCES
CHAIN OF CUSTODY FORMS
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The results in this report only apply to the samples analy-ed in accordance with the Frontier Global Sciences Inc chain ofcustody docutMnt This aMlytical report must be reprodu~d in its e111irety
Page3of20 1203203 Final Rtport- SWWTFREV2
04042012
Liz Siska Project Manager 7
l l 720 North Creek Parkway Nortn u1Le -tvv Bothell WA 9amp011
Ph 425-686-1996 Fx 425-686-3096
FRONTIER GLOBAL SCIENCES
CHAIN OF CUSTODY FORMS
The results in this report only apply to the samples analyzed in accordance with the cliain ofcustody documenL This analytical report must be reproduced in its entirety
Frontier Global Sciences Inc Page 4 o20 1203203 Final Report- SWWTF REV2
04042012
Liz Siska Project Manager
8
11720 North Creek Parkway North Suite 40U Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
FRONTIER C L 0 B AL SC I~ NC ES
CHAlN OF CUSTODY FORMS
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The results In this report onlyapply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reprodu~din its entirety
Frontier Global Sciences Inc Page 5 o20 T203203 Final Report-SWWTFREV2
ommo12
Liz SiskaProject Manager
9
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11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
Matrix Water Laboratory ID 1203203-01
ANALYTICAL RESULTS
SWWTF
Analyte Result lIDL MRL Units Dilution Batch Sequence Analyzed Method Notes
Aluminum 371 220 198 microgL 5 F203232 2C2000l 031912 EPA 2008 Mod
Arsenic 377 252 743 microgL 5 F203232 2C2000l 031912 EPA 2008 Mod
Cadmium 248 0205 0990 microgL 5 F203232 2C20001 031912 EPA2008 Mod
Chromium 532 045 495 microgL 5 F203232 2C20001 031912 EPA 2008 Mod
Copper 182 050 495 microgL 5 F203232 2C20001 031912 EPA 2008 Mod
Iron 1100 644 495 microgL 5 F203232 2C20001 031912 EPA 2008 Mod
Lead ND 0193 198 microgL 5 F203232 2C2000l 031912 EPA 2008 Mod u Manganese 7180 037 495 microgL 5 F203232 2C2000l 031912 EPA 2008 Mod
Mercury 612 842 505 ngL 100 F203288 2C22016 032212 EPA l631E FB-1631
Molybdenum 2000 297 297 microgL 50 F203260 2C22001 032112 EPA 2008 Mod
Nickel 303 040 495 microgL 5 F203232 2C20001 031912 EPA 2008 Mod
Selenium 587 959 297 microgL 5 F203232 2C20001 031912 EPA 2008 Mod
Silver ND 0297 0990 microgL 5 F203232 2C20001 031912 EPA 2008 Mod u Zinc 775 081 990 microgL 5 F203232 2C20001 031912 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report 011ly apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
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Liz Siska Project Manager 10
gt
C LO BA L S CI E N C ES
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
MATRIX DUPLICATESTRIPLICATES
SOURCE 1203203-01
Batch F203288
Preparation BrCl Oxidation
Sequence 2C22016
Lab Number F203288-DUPI
Sample Duplicate Concentration Concentration RPD
Analyte DgL ngL
5848
MRL 505
RPD 448
Limit
24
Method
EPA 163IE
Notes
Mercury 6116
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced In its entirety
Page 7of20 l 103203 Final Report- SWWTF REV2
04042012 bull 1 1 Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996
FROlJTIER Fx 425-686-3096 GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203203-01
Batch F203232 Sequence 2C20001
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203232-MSMSD 1
Sample Spike MS MS Concentration Added Concentration 0o Recovery
Analyte (microgL) (microgL) (microgL) Recovery Method NotesLimits
Alumimun 3707 15152 1853 978 70 - 130 EPA 2008 Mod
Chromium 5316 70707 1270 104 70- 130 EPA 2008 Mod
Manganese 7181 60606 7231 821 70 - 130 EPA 2008 Mod
Iron 1098 50505 6090 988 70- 130 EPA 2008 Mod
Nickel 3025 40404 3425 988 70 - 130 EPA 2008 Mod
Copper 1816 40404 5182 833 70 - 130 EPA2008 Mod
Arsenic 3770 15152 1904 101 70- 130 EPA 2008 Mod
Seleniwn 587l 30303 9297 113 70 - 130 EPA 2008 Mod
Silver ND 15152 1099 725 70 - 130 EPA 2008 Mod
Cadmillll) 2484 80808 9508 869 70 - 130 EPA 2008 Mod
Lead 0763 15152 1544 968 70-130 EPA2008Mod
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD
Recovery
Oo
RPD Recovery
Limits RPOLimit Method Notes
Aluminum 15152 1826 96l 145 70 shy 130 20 EPA 2008 Mod
Chromium 70707 1288 107 138 70-130 20 EPA 2008 Mod
Manganese 60606 7230 804 00140 70- 130 20 EPA 2008 Mod
Iron 50505 6065 983 0414 70- 130 20 EPA 2008 Mod
Nickel 40404 3378 872 138 70 - 130 20 EPA2008 Mod
Copper 40404 5140 823 0807 70 - 130 20 EPA 2008 Mod
Arsenic 15152 1928 102 123 70 - 130 20 EPA 2008 Mod
Selenium 30303 9063 105 255 70- 130 20 EPA 2008 Mod
Silver 15152 1075 709 219 70- 130 20 EPA 2008 Mod
Cadmium 80808 9347 849 170 70- 130 20 EPA 2008 Mod
Lead 15152 1531 960 0815 70- 130 20 EPA 2008 Mod
Frontier Global Sciences Inc The results In this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
PageBo20 1203203 FinalReport- SWWTFREV2
04042012
Liz Siska Project Manager 12
iii
11720 North Creek Parkway North Suite 400
Bothell WA 98011 Ph 425-686-1996 Fx 425-686-3096 GlOBAL SCIENCES
ij
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203203-01
Batch F203232 Sequence 2Q20001
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203232-MSMSD3
Analyte
Sample Concentration
(microgL)
Spike Added (pgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Limits Method Notes
Aluminum 3707 10000 10270 990 70 - 130 EPA 2008 Mod AS
Chromium 5316 10000 1137 108 70 - 130 EPA 2008 Mod AS Manganese 7181 10000 8207 103 70 - 130 EPA 2008 Mod AS
Iron 1098 50000 6185 102 70 - 130 EPA 2008 Mod AS Nickel 3025 12500 1433 905 70 - 130 EPA 2008 Mod AS Copper 1816 12500 1061 834 70 - 130 EPA 2008 Mod AS Zinc 7752 25000 1995 767 70 - 130 EPA 2008 Mod AS Arsenic 3770 10000 1073 104 70 - 130 EPA 2008 Mod AS Selenium 587l 10000 1530 943 70 - 130 EPA 2008 Mod AS Silver ND 50000 3690 738 70 - 130 EPA 2008 Mod AS Cadmium 2484 10000 8531 828 70 - 130 EPA 2008 Mod AS Lead 0763 25000 2505 999 70 - 130 EPA 2008 Mod AS
middoti
i
Aoalyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD o
Recovery
RPD Recovery
Limits RPDLimit Method Notes
Aluminum 10000 10150 978 121 70 - 130 20 EPA 2008 Mod AS Chromium 10000 1140 109 0293 70 - 130 20 EPA 2008 Mod AS Manganese 10000 8278 llO 0854 70 -130 20 EPA 2008 Mod AS Iron 50000 6243 103 0937 70-130 20 EPA 2008 Mod AS Nickel 12500 1441 91l middotos25 70 - 130 20 EPA 2008 Mod AS Copper 12500 1066 838 0496 70- 130 20 EPA 2008 Mod AS Zinc 25000 1990 765 0245 70- 130 20 EPA 2008 Mod AS Arsenic 10000 1094 106 193 70 - 130 20 EPA 2008 Mod AS Selenium 10000 1554 967 155 70 - 130 20 EPA 2008 Mod AS Silver 50000 3682 736 0222 70 - 130 20 EPA 2008 Mod AS Cadmium 10000 8394 815 l62 70 - 130 20 EPA 2008 Mod AS Lead 25000 250S 999 00263 70- 130 20 EPA 2008 Mod AS
~~ middotmiddot1 bull
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bullmiddot
Frontier Global Sciences Inc The remits in this report only apply lo the samples analyzed in accordance with the chain ofcustody document This analytical report must bt reproductd In Its entirety
Page 9of20 1203203 Final Report-SWWTF REY2
04M2012
Liz Siska Project Manager 13
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 FRONTIER~ Fx 425-686-3096 GLOBAL SCIENCES
MATR1X SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203203-01RE3
Batch F203260 Sequence 2C22001
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203260-MSMSD3
Analyte
Sample Concentration
(microgL)
Spike Added (microgL)
MS Conctntration
(microgL)
MS
Recovery Recovery
Method Limits Notes
Molybdenum 1999 20200 middot 2041 206 70 - 130 EPA 2008 Mod QM-02
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD Oo
Recovery
RPD
Recovery Limits
RPO Limit Method Notes
Molybdenum 20200 2041 207 00141 70 - 130 20 EPA 2008 Mod QM-02
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed In accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page Oo20 1203203 Final Report- SWWTFREV2
04042012
Liz Siska Project Manager 14
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyzed in accordance with the chain ofcustody document This analytical report =tbe reproducedin Its entirety
Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
CLO~AL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1203203-0lREJ
Batch F203260
Preparation Closed Vessel Nitric Oven Digestion
Sequence 2C2200
Lab Number F203260-MSMSD6
Sample Spike MS MS
Analyte Concentration Added
(JtgL) (microgL) Concentration
(microgL)
Recovery Recovery
Method Limits Notes
Molybdenum 1999 50000 7034 101 70 - 130 EPA 2008 Mod AS
Spike MSD Added Concentration
MSD Recovery RPD
Analyte (microgL) (microgL) Recovery RPD Limits Limit Method Notes
Molybdenum 50000 7124 102 128 70 - 130 20 EPA 2008 Mod AS
Page 11 o20 1203203 Final Report- SWWTF REJ2
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11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 ~ Fx 425-686-3096 GLOBAL SCIENCES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203203-01
Batch F203288
Preparation BrCI Oxidation
Sequence 2C22016
Lab Number F203288-MSMSD 1
Sample Spike MS MS Concentration Added Concentration Recovery
Analyte (ngL) (ogL) (ogL) Recovery Method Notes Limits
Mercury 6116 25500 3096 974 71 - 125 EPA 1631E
Spike MSD MSD Oo Recovery RPD Added Concentration Oo
Limits Method Notes (ogL) (ogL) Recovery RPD Limit Analyte
Mercury 25500 2611 784 170 71 - 125 24 EPA 1631E
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed i11 accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 12of20 1203203 Final Report- SWWTF REV2
04042012
Liz Siska Project Manager 16
bull 11720 North Creek Parkway North Suite 400
Bothell WA 98011 Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1203194-17
Batch F203288 Sequence 2C22016
Preparation BrCI Oxidation Lab Number F203288-MSMSD2
Sample Spike MS MS
Analyte Concentration
(ngL) Added (ngL)
Concentration (ngL) Recovery
Recovery Limits Method Notes
Mercury 142800 505000 627200 959 71 - 125 EPA 1631E
Spike Added
MSD Concentration
MSD Recovery RPO
Analyte (ngL) (ngL) Recovery RPD Limits Limit Method Notes
Mercury 505000 632700 970 0879 71 - 125 24 EPA 1631E
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody docu~nt This analytical report must be reproduced In its entirety
Page 13of20 1203203 Final Report- SWWTFREV2
04042012
Liz Siska Project Manager 17
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996
bull ~ Fx 425-686-3096 GLPBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203232 Sequence 2C20001
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203232-BSBSD1
LCS Source mank Siiike
Spike LCS LCS Added Concentration Recovery
Analyte (microgL) (microgL) Recovery Limits Method Notes
Aluminwn 15000 1444 963 85-115 EPA2008Mod Chromium 70000 654 934 85 bull 115 EPA 2008 Mod Manganese 60000 580 967 85 - 115 EPA 2008 Mod Iron 50000 4610 922 85 - 115 EPA 2008 Mod Nickel 40000 394 985 85 ll5 EPA 2008 Mod Copper 40000 418 104 85 - 115 EPA 2008 Mod Zinc 10000 1017 102 85 bull 115 EPA 2008 Mod Arsenic 15000 1445 963 85 bull 115 EPA 2008 Mod Selenium 30000 2975 992 85-115 EPA2008Mod Molybdenum 20000 185 926 85 bull 115 EPA 2008 Mod Silver 15000 1555 104 85 - 115 EPA 2008 Mod
Cadmium 080000 0802 100 85 - 115 EPA 2008 Mod Lead 15000 1565 104 85 - 115 EPA 2008 Mod
shy
Spike LCSD LCSD Added Concentration Oo Recovery RPD
Analyte (microgL)
15000
(microgL)
1424
Recovery
949
RPD
140
Limits
85 bull 115
Limit
20
Method
EPA 2008 Mod
Notes
Aluminum
Chromium 70000 644 920 l58 85 bull 115 20 EPA 2008 Mod
Manganese 60000 575 958 0920 85 - ll5 20 EPA 2008 Mod
Iron 50000 4580 916 0660 85 - 115 20 EPA 2008 Mod
Nickel 40000 394 985 000457 85 bull 115 20 EPA 2008 Mod
Copper 40000 416 104 0367 85 - 115 20 EPA 2008 Mod
Zinc 10000 1032 103 147 85 - ll5 20 EPA 2008 Mod
Arsenic 15000 1440 960 0305 85 bull 115 20 EPA 2008 Mod
Selenium 30000 2867 956 369 85 -115 20 EPA 2008 Mod
Molybdenum 20000 l86 928 0196 85 -115 20 EPA2008 Mod
Silver l5000 1559 104 0233 85 bull 115 20 EPA 2008 Mod
Cadmium 080000 0809 101 0843 85 bull llS 20 EPA 2008 Mod
Lead 15000 l539 103 170 85 - 115 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed In accordance with the chain ofcustody document This analytical report must be reproduced in its enJirety
Page 14of20 1203203 Final Report- SWWTFREV2
04042012 ~~
Liz Siska Project Manager 18
11720 North Creek Parkway North Suite 400 Bothell WA 98011 Ph 425-686-1996
FRONTIER Fx 425-686-3096 GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203260 Sequence 2C22001
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203260-BSBSD1
LCS Source Blank Spike
Spike LCS LC$ Added Concentration Recovery
Analyte (ptgL) (JJgL) Recovery Limits Method Notes
Molybdenum 20000 182 910 85 - 115 EPA 2008 Mod
Spike LCSD LCSD Added Concentration Recovery RPD
Analyte (microgL) (microgL) Recovery RPD Limits Limit Method Notes
Molybdenum 20000 186 930 213 85 -115 20 EPA 2008 Mod
Frontier Global Sciences Inc The results In this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced In its entirety
Page 15 o20 I203203 Ftnal ampport- SWWTFREV2
04041202
Liz Siska Project Manager 19
middot
I
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SC IE NC ES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPO
Batch F203288 Sequence 2C22016
Preparation BrCI Oxidation Lab Number F203288-BSBSD I
LCS Source NIST 1641d
Spike LCS LCS Added Concentration Recovery
Analyte (ngL) (ngL) Recovery Limits Method Notes
Mercury 15679 1525 973 80 - 120 EPA l631E
Spike LCSD LCSD Added Concentration Oo Recovery RPD
Analyte (ngL) (ngL)
1516
Recovery
967
RPD
0622
Limits
80 - 120
Limit
24
Method
EPA 1631E
Notes
Mercury 15679
Frontier Global Sciences Inc The results in this report only apply lo the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 16 o20 1203203 Final Report- SWWIFREV2
041042012
20Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 middot Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096 ~ O GLO B AL SCI E NCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2C20001
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203232-BLK1 Aluminum 01 40 microgL F203232 PA2008 Molt u F203232-BLK1 Chromium -0007 0 10 microgL F203232 PA 2008 Molt u F203232-BLKI Manganese 0002 010 microgL F203232 PA 2008 Moc u F203232-BLK1 Iron -004 100 microgL F203232 PA 2008 Molt u F203232-BLKI Nickel 0005 010 microgL F203232 PA 2008 Moc u F203232-BLKI Copper 001 010 microgL F203232 PA 2008 Molt u F203232-BLK1 Zinc 011 020 microgL F203232 PA 2008 Moc u F203232-BLK I Arsenic -0009 015 microgL F203232 PA 2008 Moc u F203232-BLK1 Selenium 025 060 microgL F203232 PA 2008 Moc u F203232-BLK1 Molybdenum 001 006 microgL F203232 PA 2008 Moc u F203232-BLK1 Silver -00009 0020 microgL F203232 PA 2008 Moc u F203232-BLK1 Cadmium 0002 0020 microgL F203232 PA 2008 Molt u F203232-BLK1 Lead 0024 0040 microgL F203232 PA 2008 Molt u
middoti
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordonce with the chain ofcustody document Tnts analytical rtport must be reproduced In its enlfrtty
Page7of20 J203203 Final ampport-SWWTF REV2
04042012
Liz Siska Project Manager 21
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 FRONTIER~ Fx 425-686-3096 GLOBAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2C22001
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203260-BLK1 Molybdenum 001 006 microgL F203260 ~PA 2008 Moc u
Frontier Global Sciences Inc middot The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 18of20 1203203 Final Report- SWWTFREV2
04042012
Liz Siska Project Manager 22
~ CLOSAL SCIENCES
~
J1720 North Creek Parkway North Suite 400 Bothell WA 980 l l
Ph 425-686-1996 Fx 425-686-3096
PREPARATION BLANKS
Instrument Hg-17 Sequence 2C22016
Preparation BrCI Oxidation
The results in Ihis report only apply to the samples analyzed i12 accordance with the chain ofcustody dccumnt This analytical report must be reproductd in ils enJirety
Page I9oj20 1203203 Final Report- SWWTF REJ2
04042012
Frontier Global Sciences Inc
bull 23bull Liz Siska Project Manager
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203288-BLKl Mercury 007 050 ngL F203288 EPA 1631E u F203288-BLIlt2 Mercury 006 050 ngL F203288 EPA 163lE u F203288-BLK3 Mercury 006 050 ngL F203288 EPA I63lE u F203288-BLK4 Mercury 018 050 ngL F203288 EPA I63IE U QB-04
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
Notes and Definitions
U Analyte included in the analysis but not detected
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than I times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable ASASD
QB-04 The blank was preserved to 2 BrCl rather than I The control limit for blanks presetved to greater than 1 BrCl is the preservation percentage multiplied by the l1RL
FB-1631 Required equipmentfieldfilter blank not submitted by the client The sample has been analyzed according to 163 lE but does not meet 163 lE criteria
AS This MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
l1RL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to lhe samples analyzedin accordance wirh the chain ofcustody document This analytical report must be reproduced in its entirety
Page 20of20 1203203 Final Report- SWWTF REV2
04042012
24
bull bull
irGl Lu Ull 0111C H AIN-OF-CUSTODY RECORD Page of_~~
Bolo FIELDS REQUIRED P LEASE CIRCLE REQUESTED ANALYs1s Lt) CN voe I svoc TClPI M ETALS INORGANICS
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SAMPLING 0 iii 0 ~
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~ - I 2lte E55 NOTESili I j HEOHVIAl 6shy ~a 3
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1
DATE NEEDED b171i1-1~ 1 f METALS 8 RCRA 13 PP FE MN Ps CUPROJECT MANAGER 0v f-e_~ Tmamp- middotc COMPANY pdegZ1)shy 0THE1 METALS __________REPORTING OPTIONSQAQC ICH) NoAonms Jfru lli V =1 Q ) REPORTING LEVEL PUUHS ~OR No
A B C 0lOLYpoundD METALS FIELD flLTtREDI YE NoIF YE F~ oa(ITT STAil~l4t(= ~ ZIP rriu1 NOTES (IE SPEOAl DETECTION LIHIIS BIWNG INFO IF D1mam)PHONE _r~ _z31_ - $ I3 Exr--- OR ELECTRONIC OPTIONSFAX _ __________________ AI l A C J C bull C1
J pbNo FAX E-MAIL PDF EQUIS
E-MAIL tivl el qu ~ pv CvVshyf J --~b Mo ~ tJ k ttJ -z~Sm NAHE W
PROJECT ____________ ___ ___ _ ~111216- aJd M fer P4 jgtZJ)shy
SUTt MA ME VT OTHER _____ ___ ~ 1)--U ( u-middotmiddottut-UJ f bull
REGULATORY PROGRAM NPDES RGP POnY STOilKWATER Ol SITE HISTORY ~i tiT f=
GWP OIL FUND BROWNFJUD OR Orm--------shy RELINQUISHED BY DATE TIME RECEIVED Br Summo (ONTAHINATIOM_______
PO_______QUOTE===-~----shy I RELINQUISHED BY DATE TIME Rmmo BT I FIElllJUDINGStt HI l lS 2
eastern analytical inc 2s CHENELl DR1ve I CoNcoRo NH 03301 I TEL 60322sos2s I 1soo2s7os2s IFAXc 6032284591 I E-MA1l cusToMER_seRv1ceEA1LAascoHj wwweA1lAsscoM
prufmin111ll11bomtory1m1im (WHITE ORIGINAL GREEN PROJECT MANAGER)
shy
shy
Lowell Regional Wastewater Utility File No 04002930700
April 12 2012 Page2
As part of a recent sampling effort for the steam electric power generating effluent guidelines rulemaking EPA developed an SOP that was used in conjunction with EPA Method 2008 to conduct ICP-MS analyses ofFGD wastewater The SOP describes critical technical and quality assurance procedures that were implemented to mitigate anticipated interferences and generate reliable data for FGD wastewater EPA regulations at 40 CFR 1366 already allow the analytical community flexibility to modify approved methods to lower the costs ofmeasurements overcome matrix interferences or otherwise improve the analysis The draft SOP developed for FGD wastewatermiddot takes a proactive approach toward looking for and taking steps to mitigate matrix interferences including using specialized interference check solutions (ie a synthetic FGD wastewater matrix) EPAs draft SOP is being made available to laboratories contemplating ICP-MS analysis of FGD wastewater either for adoption as currently written or to serve as a framework for developing their own laboratory-specific SOPs For further information please see the following
bull Draft SOP Inductively Coupled PlasmaMass Spectrometry for Trace Element Analysis in Flue Gas Desulfurization Wastewaters (30 pp 174K ) httpwater epagovlscitechwastetechguideuploadlsteam _draft _soppdf EPA May 2011
Considering that specialized analytical techniques are necessary to overcome matrix interference for certain analysis of trace metals in FGD wastewater we recommend any analysis on FGD wastewater be conducted in accordance with the EPA draft SOP for trace metals analysis ofFGD wastewater
Should you have any questions concerning this report please do not hesitate to contact me at (603) 232-8744
Very truly yours
GZA GEOENVIRONMENT AL INC
Ronald A Breton PE Michael P North PE Principal ConsultantReviewer
RABMPN tmd P-l)IJobs0029)00$(W002910lOCJWarlSAMtlNG ANO REPORTINGREPORTSlvelJStJQm13Mir(h B 5Upp)cmcn1final 29307 STREAMB March Splmnt 041212docN
Attachments Table Analytical Data Report
TABLE
TABLEl SUMMARY OF STREAM B CONCENTRATIONS
COMPARED TO LOWELL SEWER DISCHARGE LIMITS Public Service ofNew Hampshire
Merrimack Station Bow New Hampshire
PARAMETER LOWELL SEWER
DISCHARGE LIMITS (mgL)
STREAM B RESULTS 3142012
(mgIL)
Aluminum 2469 0371
Arsenic 0556 00377
Cadmium 0056 000248 Chromium (T) 8108 00532
Copper 3124 00182
Lead 0857 lt 000198
Mercury 0004 00000612
Nickel 1541 0303 pH 50-95 69
Silver 0053 lt 0000990
Zinc 4959 00775
P04obsl0029300sl04002930700WortSAMPLING AND REPORTINGIDATAI 04002930700 RESULTS 032112xll1ltLltgtwcll B GZA GeoEnvironmental Inc
ANALYTICAL DATA REPORT
~--fLAA____________e_a_s_t_e_r_n_a_n_a_ly_t_i_c_a_l__
Paul Pepler
GZA GeoEnvironmental Inc (NH)
380 Harvey Road
Manchester NH 03103
Subject Laboratory Report
Eastern Analytical Inc ID 108420
Client Identification MK
Date Received 3142012
Dear Mr Pepler
Enclosed please find the laboratory report for the above identified project All analyses were performed in accordance with our QAQC Program Unless otherwise stated holding times preservation techniques container types and sample conditions adhered to EPA Protocol Samples which were collected by Eastern Analytical Inc (EAi) were collected in accordance with approved EPA procedures Eastern Analytical Inc certifies that the enclosed test results meet all requirements of NELAP and other applicable state certifications Please refer to our website at wwweailabscom for a copy ofour NELAP certificate and accredited parameters
The following standard abbreviations and conventions apply to all EAi reports Solid samples are reported on a dry weight basis unless otherwise noted lt less than followed by the reporting limit gt greater than followed by the reporting limit R Recovery
Eastern Analytical Inc maintains certification in the following states Connecticut (PH-0492) Maine (NH005) Massachusetts (M-NH005) New HampshireNELAP (1012) Rhode Island (269) and Vermont (VT1012)
The following information is contained within this report Sample Conditions summary Analytical ResultsData Quality Control data (if requested) and copies of the Chain of Custody This report may not be reproduced except in full without the the written approval of the laboratory
If you have any questions regarding the results contained within please feel free to directly contact me or the chemist(s) who performed the testing in question Unless otherwise requested we will dispose of the sample(s) 30 days from the sample receipt date
We appreciate this opportunity to be of service and look forward to your continued patronage
Sincerely
11micro3= Date
JS of pages (excluding cover letter)
11middot1111Llibb ~(( 1111
SAMPLE CONDITIONS PAGE EAi ID 108420
Client middot GZA GeoEnvironmental Inc (NH)
Client Designation MK
Temperature upon receipt (degC) 184 Received on ice or cold packs (YesNo) y Acceptable temperature range (degC) 0-6
Date Date Sample Dry Lab ID Sample ID Received Sampled Matrix Weight ExceptionsComments (other than thermal preservation)
10842001 SWWTF 31412 31412 aqueous Adheres to Sample Acceptance Policy
Samples were properly preserved and the pH measured when applicable unless otherwise noted Analysis ofsolids for pH Flashpoint lgnitibility Paint Filter Corrosivity Conductivity and Specific Gravity are reported on an middotas received basis
All results contained in this report relate only to the above listed samples References include 1) EPA 6004-79-020 1983 2) Standard Methods for Examination ofWater and Wastewater lnorganics 19th Edition 1995 Microbiology 20th Edition 1998 3) Test Methods for Evaluating Solid Waste SW 846 3rd Edition Including updates VA and VB 4) Hach Water Analysis Handbook 2nd edition 1992
eastern analytical inc wwweailabscom Phone (603) 228-0525 1
LABORATORY REPORT EAi I 0 108420
Client GZA GeoEnvironmental Inc (NH)
Client Designation MK
Sample ID SWNTF
Lab Sample ID 10842001
Matrix aqueous
Date Sampled 31412
31412Date Received
Solids Suspended 25000 Solids Dissolved 180000 Chloride 75000 BOD 140 COD 900 pH 69
Analysis
Units Date Time Method Analyst
mgL 31912 1345 2540D DLS mgL 31912 1500 2540C DLS mgL 311912 1030 4500CIE DLS mgL 31512 1412 52108 SKC mgL 32012 900 H8000 KJR SU 31412 1705 4500H+B Jl
TDS Due to sample matrix a constant weight of 000059 could not be achieved
eastern analytical inc wwweailabscom Phone (603) 228-0525 2
QC REPORT EAIID 10842011Jul Client GZA GeoEnvironmental Inc (NH)
Client Designation MK
Date of
Parameter Name Blank LCS LCSO Units Analysis Limits RPO Method
Solids Suspended lt5 96 (96 ooR) 100 (100 ooR) (4 RPO) mgL 31912 90 -110 20 2540D
Solids Dissolved lt5 990 (99 R) NA mgL 31912 85 - 115 20 2540C
Chloride lt 1 27 (106 ooR) 26 (106 ooR) (0 RPD) mgL 31912 90 - 110 20 4500CIE
BOD lt6 400 (100 R) 410 (102 R) (2 RPD) mgL 31512 84-115 20 52108
COD lt 10 100 (97 R) 100 (101 R) (4 RPD) mgL 32012 85 -115 20 H8000
pH 60 (100 ooR) 60 (100 ooR) (0 RPD) SU 31412 595 - 607 10 4500H+B
Duplicate Duplicate Date of Parameter Name Parent ID Parent Duplicate Units Analysls RPO Method
Solids Suspended 10850303 200 190 (4RPD) mgL 31912 20 2540D Solids Dissolved 10843101 270 270 (0 RPO) mgL 31912 20 2540C Chloride NA NA mgL 31912 20 4500CIE BOD NA NA mgL 31512 20 52108 COD NA NA mgl 32012 20 H8000 pH 10838601 82 82 (0 RPO) SU 31412 10 4500H+B
Samples were analyzed within holding times unless noted on the sample results page Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits The associated matrix spikes andor Laboratory Control Samples met the above stated criteria Exceptions to the above statements are flagged or noted above or on the QC Narrative page bull11 Flagged analyte recoveries deviated from the QAQC limits
eastern analytical inc wwweailabscom Phone (603) 228-0525 3
Ill
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
G L OS AL S ( I E N lt ES
04 April 2012
JeffGagne
Eastern Analytical Inc
25 Chenell Drive
Concord NH 03301
RE Merrimack Station 2008
Enclosed are the analytical results for samples received by Frontier Global Sciences All quality control
measurements are within established control limits and there were no analytical difficulties encountered
with the exception ofthose listed in the case narrative section of this report
Ifyou have any questions concerning this report please feel free to contact me
Sincerely 44
Liz Siska
Project Manager
4
~ 11720 North Creek Parkway North Suite 400
Bothell WA 9801 1 Ph 425-686-1996 Fx 425-686-3096
GLOBAl SCIENCES
ANALYTICAL REPORT FOR SAMPLES
Laboratory Frontier Global Sciences Inc SDG
Client Eastern Analytical ]nc Project Merrimack Station 2008
Sample ID Lab ID Matrix Date Sampled Date Received
SWWTF 1203203-01 Water 14-Mar-12 1305 16-Mar-12 0940
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Pagel o20 1203203 Final Report-SWWTF REV2
041042012
Liz Siska Project Manager 5
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
CASE NARRATIVE
Revised Report 4412- Sample name corrected to SWWTF
SAMPLE RECEIPT
Samples were received at Frontier Global Sciences (FGS) on March 16th 2012 The samples were received intact on-ice with temperatures measuredat 22 degrees Celsius
SAMPLE PREPARATION AND ANALYSIS
Samples were prepared and analyzed for total metals in accordance with EPA Method 2008 (modified)
Samples were prepared and analyzed for total mercury in accordance with EPA Method 163 JE
ANALYTICAL ISSUES
The client requested sample SWWTF (1203203-0 l) be analyzed for Mn via email on 31512
Samples were received in a cooler ofmelted ice There was water in the inner most bag of sample Evaporator (1203203-02)
As an additional measure ofthe accuracy ofthe methods utilized for analysis and to check for matrix interference matrix spikes (MS) and matrix spike duplicates (MSD) were digested and analyzed All ofthe matrix spike recoveries were within the control limits with the exception ofany QC flagged and described in the notes and definitions section ofthe following report
A reasonable measure ofthe precision ofthe analytical methods utilized for analysis is the relative percent difference (RPD) between matrix spike and matrix spike duplicate recoveries and between laboratory control sample and laboratory control sample duplicate recoveries All of the relative percent differences were within the control limits with the exception ofany QC flagged and described in the notes and definitions section ofthe following report
Frontier Global Sciences Inc The results in this report 011y apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 2 of20 1203203 Final Report- SWWTF REV2
04042012
Liz Siska Project Manager 6
FRONTIER
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIE NCES
CHAIN OF CUSTODY FORMS
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The results in this report only apply to the samples analy-ed in accordance with the Frontier Global Sciences Inc chain ofcustody docutMnt This aMlytical report must be reprodu~d in its e111irety
Page3of20 1203203 Final Rtport- SWWTFREV2
04042012
Liz Siska Project Manager 7
l l 720 North Creek Parkway Nortn u1Le -tvv Bothell WA 9amp011
Ph 425-686-1996 Fx 425-686-3096
FRONTIER GLOBAL SCIENCES
CHAIN OF CUSTODY FORMS
The results in this report only apply to the samples analyzed in accordance with the cliain ofcustody documenL This analytical report must be reproduced in its entirety
Frontier Global Sciences Inc Page 4 o20 1203203 Final Report- SWWTF REV2
04042012
Liz Siska Project Manager
8
11720 North Creek Parkway North Suite 40U Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
FRONTIER C L 0 B AL SC I~ NC ES
CHAlN OF CUSTODY FORMS
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The results In this report onlyapply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reprodu~din its entirety
Frontier Global Sciences Inc Page 5 o20 T203203 Final Report-SWWTFREV2
ommo12
Liz SiskaProject Manager
9
)--J middot ~~
)J fl~~J~c1N~r
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
Matrix Water Laboratory ID 1203203-01
ANALYTICAL RESULTS
SWWTF
Analyte Result lIDL MRL Units Dilution Batch Sequence Analyzed Method Notes
Aluminum 371 220 198 microgL 5 F203232 2C2000l 031912 EPA 2008 Mod
Arsenic 377 252 743 microgL 5 F203232 2C2000l 031912 EPA 2008 Mod
Cadmium 248 0205 0990 microgL 5 F203232 2C20001 031912 EPA2008 Mod
Chromium 532 045 495 microgL 5 F203232 2C20001 031912 EPA 2008 Mod
Copper 182 050 495 microgL 5 F203232 2C20001 031912 EPA 2008 Mod
Iron 1100 644 495 microgL 5 F203232 2C20001 031912 EPA 2008 Mod
Lead ND 0193 198 microgL 5 F203232 2C2000l 031912 EPA 2008 Mod u Manganese 7180 037 495 microgL 5 F203232 2C2000l 031912 EPA 2008 Mod
Mercury 612 842 505 ngL 100 F203288 2C22016 032212 EPA l631E FB-1631
Molybdenum 2000 297 297 microgL 50 F203260 2C22001 032112 EPA 2008 Mod
Nickel 303 040 495 microgL 5 F203232 2C20001 031912 EPA 2008 Mod
Selenium 587 959 297 microgL 5 F203232 2C20001 031912 EPA 2008 Mod
Silver ND 0297 0990 microgL 5 F203232 2C20001 031912 EPA 2008 Mod u Zinc 775 081 990 microgL 5 F203232 2C20001 031912 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report 011ly apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page6 o20 I203203 Final Report- SWWTF REV2
04042012
Liz Siska Project Manager 10
gt
C LO BA L S CI E N C ES
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
MATRIX DUPLICATESTRIPLICATES
SOURCE 1203203-01
Batch F203288
Preparation BrCl Oxidation
Sequence 2C22016
Lab Number F203288-DUPI
Sample Duplicate Concentration Concentration RPD
Analyte DgL ngL
5848
MRL 505
RPD 448
Limit
24
Method
EPA 163IE
Notes
Mercury 6116
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced In its entirety
Page 7of20 l 103203 Final Report- SWWTF REV2
04042012 bull 1 1 Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996
FROlJTIER Fx 425-686-3096 GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203203-01
Batch F203232 Sequence 2C20001
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203232-MSMSD 1
Sample Spike MS MS Concentration Added Concentration 0o Recovery
Analyte (microgL) (microgL) (microgL) Recovery Method NotesLimits
Alumimun 3707 15152 1853 978 70 - 130 EPA 2008 Mod
Chromium 5316 70707 1270 104 70- 130 EPA 2008 Mod
Manganese 7181 60606 7231 821 70 - 130 EPA 2008 Mod
Iron 1098 50505 6090 988 70- 130 EPA 2008 Mod
Nickel 3025 40404 3425 988 70 - 130 EPA 2008 Mod
Copper 1816 40404 5182 833 70 - 130 EPA2008 Mod
Arsenic 3770 15152 1904 101 70- 130 EPA 2008 Mod
Seleniwn 587l 30303 9297 113 70 - 130 EPA 2008 Mod
Silver ND 15152 1099 725 70 - 130 EPA 2008 Mod
Cadmillll) 2484 80808 9508 869 70 - 130 EPA 2008 Mod
Lead 0763 15152 1544 968 70-130 EPA2008Mod
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD
Recovery
Oo
RPD Recovery
Limits RPOLimit Method Notes
Aluminum 15152 1826 96l 145 70 shy 130 20 EPA 2008 Mod
Chromium 70707 1288 107 138 70-130 20 EPA 2008 Mod
Manganese 60606 7230 804 00140 70- 130 20 EPA 2008 Mod
Iron 50505 6065 983 0414 70- 130 20 EPA 2008 Mod
Nickel 40404 3378 872 138 70 - 130 20 EPA2008 Mod
Copper 40404 5140 823 0807 70 - 130 20 EPA 2008 Mod
Arsenic 15152 1928 102 123 70 - 130 20 EPA 2008 Mod
Selenium 30303 9063 105 255 70- 130 20 EPA 2008 Mod
Silver 15152 1075 709 219 70- 130 20 EPA 2008 Mod
Cadmium 80808 9347 849 170 70- 130 20 EPA 2008 Mod
Lead 15152 1531 960 0815 70- 130 20 EPA 2008 Mod
Frontier Global Sciences Inc The results In this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
PageBo20 1203203 FinalReport- SWWTFREV2
04042012
Liz Siska Project Manager 12
iii
11720 North Creek Parkway North Suite 400
Bothell WA 98011 Ph 425-686-1996 Fx 425-686-3096 GlOBAL SCIENCES
ij
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203203-01
Batch F203232 Sequence 2Q20001
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203232-MSMSD3
Analyte
Sample Concentration
(microgL)
Spike Added (pgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Limits Method Notes
Aluminum 3707 10000 10270 990 70 - 130 EPA 2008 Mod AS
Chromium 5316 10000 1137 108 70 - 130 EPA 2008 Mod AS Manganese 7181 10000 8207 103 70 - 130 EPA 2008 Mod AS
Iron 1098 50000 6185 102 70 - 130 EPA 2008 Mod AS Nickel 3025 12500 1433 905 70 - 130 EPA 2008 Mod AS Copper 1816 12500 1061 834 70 - 130 EPA 2008 Mod AS Zinc 7752 25000 1995 767 70 - 130 EPA 2008 Mod AS Arsenic 3770 10000 1073 104 70 - 130 EPA 2008 Mod AS Selenium 587l 10000 1530 943 70 - 130 EPA 2008 Mod AS Silver ND 50000 3690 738 70 - 130 EPA 2008 Mod AS Cadmium 2484 10000 8531 828 70 - 130 EPA 2008 Mod AS Lead 0763 25000 2505 999 70 - 130 EPA 2008 Mod AS
middoti
i
Aoalyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD o
Recovery
RPD Recovery
Limits RPDLimit Method Notes
Aluminum 10000 10150 978 121 70 - 130 20 EPA 2008 Mod AS Chromium 10000 1140 109 0293 70 - 130 20 EPA 2008 Mod AS Manganese 10000 8278 llO 0854 70 -130 20 EPA 2008 Mod AS Iron 50000 6243 103 0937 70-130 20 EPA 2008 Mod AS Nickel 12500 1441 91l middotos25 70 - 130 20 EPA 2008 Mod AS Copper 12500 1066 838 0496 70- 130 20 EPA 2008 Mod AS Zinc 25000 1990 765 0245 70- 130 20 EPA 2008 Mod AS Arsenic 10000 1094 106 193 70 - 130 20 EPA 2008 Mod AS Selenium 10000 1554 967 155 70 - 130 20 EPA 2008 Mod AS Silver 50000 3682 736 0222 70 - 130 20 EPA 2008 Mod AS Cadmium 10000 8394 815 l62 70 - 130 20 EPA 2008 Mod AS Lead 25000 250S 999 00263 70- 130 20 EPA 2008 Mod AS
~~ middotmiddot1 bull
bulli
bullmiddot
Frontier Global Sciences Inc The remits in this report only apply lo the samples analyzed in accordance with the chain ofcustody document This analytical report must bt reproductd In Its entirety
Page 9of20 1203203 Final Report-SWWTF REY2
04M2012
Liz Siska Project Manager 13
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 FRONTIER~ Fx 425-686-3096 GLOBAL SCIENCES
MATR1X SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203203-01RE3
Batch F203260 Sequence 2C22001
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203260-MSMSD3
Analyte
Sample Concentration
(microgL)
Spike Added (microgL)
MS Conctntration
(microgL)
MS
Recovery Recovery
Method Limits Notes
Molybdenum 1999 20200 middot 2041 206 70 - 130 EPA 2008 Mod QM-02
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD Oo
Recovery
RPD
Recovery Limits
RPO Limit Method Notes
Molybdenum 20200 2041 207 00141 70 - 130 20 EPA 2008 Mod QM-02
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed In accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page Oo20 1203203 Final Report- SWWTFREV2
04042012
Liz Siska Project Manager 14
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyzed in accordance with the chain ofcustody document This analytical report =tbe reproducedin Its entirety
Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
CLO~AL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1203203-0lREJ
Batch F203260
Preparation Closed Vessel Nitric Oven Digestion
Sequence 2C2200
Lab Number F203260-MSMSD6
Sample Spike MS MS
Analyte Concentration Added
(JtgL) (microgL) Concentration
(microgL)
Recovery Recovery
Method Limits Notes
Molybdenum 1999 50000 7034 101 70 - 130 EPA 2008 Mod AS
Spike MSD Added Concentration
MSD Recovery RPD
Analyte (microgL) (microgL) Recovery RPD Limits Limit Method Notes
Molybdenum 50000 7124 102 128 70 - 130 20 EPA 2008 Mod AS
Page 11 o20 1203203 Final Report- SWWTF REJ2
040412012
15
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 ~ Fx 425-686-3096 GLOBAL SCIENCES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203203-01
Batch F203288
Preparation BrCI Oxidation
Sequence 2C22016
Lab Number F203288-MSMSD 1
Sample Spike MS MS Concentration Added Concentration Recovery
Analyte (ngL) (ogL) (ogL) Recovery Method Notes Limits
Mercury 6116 25500 3096 974 71 - 125 EPA 1631E
Spike MSD MSD Oo Recovery RPD Added Concentration Oo
Limits Method Notes (ogL) (ogL) Recovery RPD Limit Analyte
Mercury 25500 2611 784 170 71 - 125 24 EPA 1631E
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed i11 accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 12of20 1203203 Final Report- SWWTF REV2
04042012
Liz Siska Project Manager 16
bull 11720 North Creek Parkway North Suite 400
Bothell WA 98011 Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1203194-17
Batch F203288 Sequence 2C22016
Preparation BrCI Oxidation Lab Number F203288-MSMSD2
Sample Spike MS MS
Analyte Concentration
(ngL) Added (ngL)
Concentration (ngL) Recovery
Recovery Limits Method Notes
Mercury 142800 505000 627200 959 71 - 125 EPA 1631E
Spike Added
MSD Concentration
MSD Recovery RPO
Analyte (ngL) (ngL) Recovery RPD Limits Limit Method Notes
Mercury 505000 632700 970 0879 71 - 125 24 EPA 1631E
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody docu~nt This analytical report must be reproduced In its entirety
Page 13of20 1203203 Final Report- SWWTFREV2
04042012
Liz Siska Project Manager 17
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996
bull ~ Fx 425-686-3096 GLPBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203232 Sequence 2C20001
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203232-BSBSD1
LCS Source mank Siiike
Spike LCS LCS Added Concentration Recovery
Analyte (microgL) (microgL) Recovery Limits Method Notes
Aluminwn 15000 1444 963 85-115 EPA2008Mod Chromium 70000 654 934 85 bull 115 EPA 2008 Mod Manganese 60000 580 967 85 - 115 EPA 2008 Mod Iron 50000 4610 922 85 - 115 EPA 2008 Mod Nickel 40000 394 985 85 ll5 EPA 2008 Mod Copper 40000 418 104 85 - 115 EPA 2008 Mod Zinc 10000 1017 102 85 bull 115 EPA 2008 Mod Arsenic 15000 1445 963 85 bull 115 EPA 2008 Mod Selenium 30000 2975 992 85-115 EPA2008Mod Molybdenum 20000 185 926 85 bull 115 EPA 2008 Mod Silver 15000 1555 104 85 - 115 EPA 2008 Mod
Cadmium 080000 0802 100 85 - 115 EPA 2008 Mod Lead 15000 1565 104 85 - 115 EPA 2008 Mod
shy
Spike LCSD LCSD Added Concentration Oo Recovery RPD
Analyte (microgL)
15000
(microgL)
1424
Recovery
949
RPD
140
Limits
85 bull 115
Limit
20
Method
EPA 2008 Mod
Notes
Aluminum
Chromium 70000 644 920 l58 85 bull 115 20 EPA 2008 Mod
Manganese 60000 575 958 0920 85 - ll5 20 EPA 2008 Mod
Iron 50000 4580 916 0660 85 - 115 20 EPA 2008 Mod
Nickel 40000 394 985 000457 85 bull 115 20 EPA 2008 Mod
Copper 40000 416 104 0367 85 - 115 20 EPA 2008 Mod
Zinc 10000 1032 103 147 85 - ll5 20 EPA 2008 Mod
Arsenic 15000 1440 960 0305 85 bull 115 20 EPA 2008 Mod
Selenium 30000 2867 956 369 85 -115 20 EPA 2008 Mod
Molybdenum 20000 l86 928 0196 85 -115 20 EPA2008 Mod
Silver l5000 1559 104 0233 85 bull 115 20 EPA 2008 Mod
Cadmium 080000 0809 101 0843 85 bull llS 20 EPA 2008 Mod
Lead 15000 l539 103 170 85 - 115 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed In accordance with the chain ofcustody document This analytical report must be reproduced in its enJirety
Page 14of20 1203203 Final Report- SWWTFREV2
04042012 ~~
Liz Siska Project Manager 18
11720 North Creek Parkway North Suite 400 Bothell WA 98011 Ph 425-686-1996
FRONTIER Fx 425-686-3096 GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203260 Sequence 2C22001
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203260-BSBSD1
LCS Source Blank Spike
Spike LCS LC$ Added Concentration Recovery
Analyte (ptgL) (JJgL) Recovery Limits Method Notes
Molybdenum 20000 182 910 85 - 115 EPA 2008 Mod
Spike LCSD LCSD Added Concentration Recovery RPD
Analyte (microgL) (microgL) Recovery RPD Limits Limit Method Notes
Molybdenum 20000 186 930 213 85 -115 20 EPA 2008 Mod
Frontier Global Sciences Inc The results In this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced In its entirety
Page 15 o20 I203203 Ftnal ampport- SWWTFREV2
04041202
Liz Siska Project Manager 19
middot
I
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SC IE NC ES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPO
Batch F203288 Sequence 2C22016
Preparation BrCI Oxidation Lab Number F203288-BSBSD I
LCS Source NIST 1641d
Spike LCS LCS Added Concentration Recovery
Analyte (ngL) (ngL) Recovery Limits Method Notes
Mercury 15679 1525 973 80 - 120 EPA l631E
Spike LCSD LCSD Added Concentration Oo Recovery RPD
Analyte (ngL) (ngL)
1516
Recovery
967
RPD
0622
Limits
80 - 120
Limit
24
Method
EPA 1631E
Notes
Mercury 15679
Frontier Global Sciences Inc The results in this report only apply lo the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 16 o20 1203203 Final Report- SWWIFREV2
041042012
20Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 middot Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096 ~ O GLO B AL SCI E NCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2C20001
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203232-BLK1 Aluminum 01 40 microgL F203232 PA2008 Molt u F203232-BLK1 Chromium -0007 0 10 microgL F203232 PA 2008 Molt u F203232-BLKI Manganese 0002 010 microgL F203232 PA 2008 Moc u F203232-BLK1 Iron -004 100 microgL F203232 PA 2008 Molt u F203232-BLKI Nickel 0005 010 microgL F203232 PA 2008 Moc u F203232-BLKI Copper 001 010 microgL F203232 PA 2008 Molt u F203232-BLK1 Zinc 011 020 microgL F203232 PA 2008 Moc u F203232-BLK I Arsenic -0009 015 microgL F203232 PA 2008 Moc u F203232-BLK1 Selenium 025 060 microgL F203232 PA 2008 Moc u F203232-BLK1 Molybdenum 001 006 microgL F203232 PA 2008 Moc u F203232-BLK1 Silver -00009 0020 microgL F203232 PA 2008 Moc u F203232-BLK1 Cadmium 0002 0020 microgL F203232 PA 2008 Molt u F203232-BLK1 Lead 0024 0040 microgL F203232 PA 2008 Molt u
middoti
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordonce with the chain ofcustody document Tnts analytical rtport must be reproduced In its enlfrtty
Page7of20 J203203 Final ampport-SWWTF REV2
04042012
Liz Siska Project Manager 21
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 FRONTIER~ Fx 425-686-3096 GLOBAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2C22001
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203260-BLK1 Molybdenum 001 006 microgL F203260 ~PA 2008 Moc u
Frontier Global Sciences Inc middot The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 18of20 1203203 Final Report- SWWTFREV2
04042012
Liz Siska Project Manager 22
~ CLOSAL SCIENCES
~
J1720 North Creek Parkway North Suite 400 Bothell WA 980 l l
Ph 425-686-1996 Fx 425-686-3096
PREPARATION BLANKS
Instrument Hg-17 Sequence 2C22016
Preparation BrCI Oxidation
The results in Ihis report only apply to the samples analyzed i12 accordance with the chain ofcustody dccumnt This analytical report must be reproductd in ils enJirety
Page I9oj20 1203203 Final Report- SWWTF REJ2
04042012
Frontier Global Sciences Inc
bull 23bull Liz Siska Project Manager
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203288-BLKl Mercury 007 050 ngL F203288 EPA 1631E u F203288-BLIlt2 Mercury 006 050 ngL F203288 EPA 163lE u F203288-BLK3 Mercury 006 050 ngL F203288 EPA I63lE u F203288-BLK4 Mercury 018 050 ngL F203288 EPA I63IE U QB-04
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
Notes and Definitions
U Analyte included in the analysis but not detected
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than I times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable ASASD
QB-04 The blank was preserved to 2 BrCl rather than I The control limit for blanks presetved to greater than 1 BrCl is the preservation percentage multiplied by the l1RL
FB-1631 Required equipmentfieldfilter blank not submitted by the client The sample has been analyzed according to 163 lE but does not meet 163 lE criteria
AS This MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
l1RL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to lhe samples analyzedin accordance wirh the chain ofcustody document This analytical report must be reproduced in its entirety
Page 20of20 1203203 Final Report- SWWTF REV2
04042012
24
bull bull
irGl Lu Ull 0111C H AIN-OF-CUSTODY RECORD Page of_~~
Bolo FIELDS REQUIRED P LEASE CIRCLE REQUESTED ANALYs1s Lt) CN voe I svoc TClPI M ETALS INORGANICS
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SAMPLING 0 iii 0 ~
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PWETAJllt H-HCL N-HNO S-HJO Na-NaOHmiddot H-HEOH
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DATE NEEDED b171i1-1~ 1 f METALS 8 RCRA 13 PP FE MN Ps CUPROJECT MANAGER 0v f-e_~ Tmamp- middotc COMPANY pdegZ1)shy 0THE1 METALS __________REPORTING OPTIONSQAQC ICH) NoAonms Jfru lli V =1 Q ) REPORTING LEVEL PUUHS ~OR No
A B C 0lOLYpoundD METALS FIELD flLTtREDI YE NoIF YE F~ oa(ITT STAil~l4t(= ~ ZIP rriu1 NOTES (IE SPEOAl DETECTION LIHIIS BIWNG INFO IF D1mam)PHONE _r~ _z31_ - $ I3 Exr--- OR ELECTRONIC OPTIONSFAX _ __________________ AI l A C J C bull C1
J pbNo FAX E-MAIL PDF EQUIS
E-MAIL tivl el qu ~ pv CvVshyf J --~b Mo ~ tJ k ttJ -z~Sm NAHE W
PROJECT ____________ ___ ___ _ ~111216- aJd M fer P4 jgtZJ)shy
SUTt MA ME VT OTHER _____ ___ ~ 1)--U ( u-middotmiddottut-UJ f bull
REGULATORY PROGRAM NPDES RGP POnY STOilKWATER Ol SITE HISTORY ~i tiT f=
GWP OIL FUND BROWNFJUD OR Orm--------shy RELINQUISHED BY DATE TIME RECEIVED Br Summo (ONTAHINATIOM_______
PO_______QUOTE===-~----shy I RELINQUISHED BY DATE TIME Rmmo BT I FIElllJUDINGStt HI l lS 2
eastern analytical inc 2s CHENELl DR1ve I CoNcoRo NH 03301 I TEL 60322sos2s I 1soo2s7os2s IFAXc 6032284591 I E-MA1l cusToMER_seRv1ceEA1LAascoHj wwweA1lAsscoM
prufmin111ll11bomtory1m1im (WHITE ORIGINAL GREEN PROJECT MANAGER)
shy
shy
TABLE
TABLEl SUMMARY OF STREAM B CONCENTRATIONS
COMPARED TO LOWELL SEWER DISCHARGE LIMITS Public Service ofNew Hampshire
Merrimack Station Bow New Hampshire
PARAMETER LOWELL SEWER
DISCHARGE LIMITS (mgL)
STREAM B RESULTS 3142012
(mgIL)
Aluminum 2469 0371
Arsenic 0556 00377
Cadmium 0056 000248 Chromium (T) 8108 00532
Copper 3124 00182
Lead 0857 lt 000198
Mercury 0004 00000612
Nickel 1541 0303 pH 50-95 69
Silver 0053 lt 0000990
Zinc 4959 00775
P04obsl0029300sl04002930700WortSAMPLING AND REPORTINGIDATAI 04002930700 RESULTS 032112xll1ltLltgtwcll B GZA GeoEnvironmental Inc
ANALYTICAL DATA REPORT
~--fLAA____________e_a_s_t_e_r_n_a_n_a_ly_t_i_c_a_l__
Paul Pepler
GZA GeoEnvironmental Inc (NH)
380 Harvey Road
Manchester NH 03103
Subject Laboratory Report
Eastern Analytical Inc ID 108420
Client Identification MK
Date Received 3142012
Dear Mr Pepler
Enclosed please find the laboratory report for the above identified project All analyses were performed in accordance with our QAQC Program Unless otherwise stated holding times preservation techniques container types and sample conditions adhered to EPA Protocol Samples which were collected by Eastern Analytical Inc (EAi) were collected in accordance with approved EPA procedures Eastern Analytical Inc certifies that the enclosed test results meet all requirements of NELAP and other applicable state certifications Please refer to our website at wwweailabscom for a copy ofour NELAP certificate and accredited parameters
The following standard abbreviations and conventions apply to all EAi reports Solid samples are reported on a dry weight basis unless otherwise noted lt less than followed by the reporting limit gt greater than followed by the reporting limit R Recovery
Eastern Analytical Inc maintains certification in the following states Connecticut (PH-0492) Maine (NH005) Massachusetts (M-NH005) New HampshireNELAP (1012) Rhode Island (269) and Vermont (VT1012)
The following information is contained within this report Sample Conditions summary Analytical ResultsData Quality Control data (if requested) and copies of the Chain of Custody This report may not be reproduced except in full without the the written approval of the laboratory
If you have any questions regarding the results contained within please feel free to directly contact me or the chemist(s) who performed the testing in question Unless otherwise requested we will dispose of the sample(s) 30 days from the sample receipt date
We appreciate this opportunity to be of service and look forward to your continued patronage
Sincerely
11micro3= Date
JS of pages (excluding cover letter)
11middot1111Llibb ~(( 1111
SAMPLE CONDITIONS PAGE EAi ID 108420
Client middot GZA GeoEnvironmental Inc (NH)
Client Designation MK
Temperature upon receipt (degC) 184 Received on ice or cold packs (YesNo) y Acceptable temperature range (degC) 0-6
Date Date Sample Dry Lab ID Sample ID Received Sampled Matrix Weight ExceptionsComments (other than thermal preservation)
10842001 SWWTF 31412 31412 aqueous Adheres to Sample Acceptance Policy
Samples were properly preserved and the pH measured when applicable unless otherwise noted Analysis ofsolids for pH Flashpoint lgnitibility Paint Filter Corrosivity Conductivity and Specific Gravity are reported on an middotas received basis
All results contained in this report relate only to the above listed samples References include 1) EPA 6004-79-020 1983 2) Standard Methods for Examination ofWater and Wastewater lnorganics 19th Edition 1995 Microbiology 20th Edition 1998 3) Test Methods for Evaluating Solid Waste SW 846 3rd Edition Including updates VA and VB 4) Hach Water Analysis Handbook 2nd edition 1992
eastern analytical inc wwweailabscom Phone (603) 228-0525 1
LABORATORY REPORT EAi I 0 108420
Client GZA GeoEnvironmental Inc (NH)
Client Designation MK
Sample ID SWNTF
Lab Sample ID 10842001
Matrix aqueous
Date Sampled 31412
31412Date Received
Solids Suspended 25000 Solids Dissolved 180000 Chloride 75000 BOD 140 COD 900 pH 69
Analysis
Units Date Time Method Analyst
mgL 31912 1345 2540D DLS mgL 31912 1500 2540C DLS mgL 311912 1030 4500CIE DLS mgL 31512 1412 52108 SKC mgL 32012 900 H8000 KJR SU 31412 1705 4500H+B Jl
TDS Due to sample matrix a constant weight of 000059 could not be achieved
eastern analytical inc wwweailabscom Phone (603) 228-0525 2
QC REPORT EAIID 10842011Jul Client GZA GeoEnvironmental Inc (NH)
Client Designation MK
Date of
Parameter Name Blank LCS LCSO Units Analysis Limits RPO Method
Solids Suspended lt5 96 (96 ooR) 100 (100 ooR) (4 RPO) mgL 31912 90 -110 20 2540D
Solids Dissolved lt5 990 (99 R) NA mgL 31912 85 - 115 20 2540C
Chloride lt 1 27 (106 ooR) 26 (106 ooR) (0 RPD) mgL 31912 90 - 110 20 4500CIE
BOD lt6 400 (100 R) 410 (102 R) (2 RPD) mgL 31512 84-115 20 52108
COD lt 10 100 (97 R) 100 (101 R) (4 RPD) mgL 32012 85 -115 20 H8000
pH 60 (100 ooR) 60 (100 ooR) (0 RPD) SU 31412 595 - 607 10 4500H+B
Duplicate Duplicate Date of Parameter Name Parent ID Parent Duplicate Units Analysls RPO Method
Solids Suspended 10850303 200 190 (4RPD) mgL 31912 20 2540D Solids Dissolved 10843101 270 270 (0 RPO) mgL 31912 20 2540C Chloride NA NA mgL 31912 20 4500CIE BOD NA NA mgL 31512 20 52108 COD NA NA mgl 32012 20 H8000 pH 10838601 82 82 (0 RPO) SU 31412 10 4500H+B
Samples were analyzed within holding times unless noted on the sample results page Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits The associated matrix spikes andor Laboratory Control Samples met the above stated criteria Exceptions to the above statements are flagged or noted above or on the QC Narrative page bull11 Flagged analyte recoveries deviated from the QAQC limits
eastern analytical inc wwweailabscom Phone (603) 228-0525 3
Ill
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
G L OS AL S ( I E N lt ES
04 April 2012
JeffGagne
Eastern Analytical Inc
25 Chenell Drive
Concord NH 03301
RE Merrimack Station 2008
Enclosed are the analytical results for samples received by Frontier Global Sciences All quality control
measurements are within established control limits and there were no analytical difficulties encountered
with the exception ofthose listed in the case narrative section of this report
Ifyou have any questions concerning this report please feel free to contact me
Sincerely 44
Liz Siska
Project Manager
4
~ 11720 North Creek Parkway North Suite 400
Bothell WA 9801 1 Ph 425-686-1996 Fx 425-686-3096
GLOBAl SCIENCES
ANALYTICAL REPORT FOR SAMPLES
Laboratory Frontier Global Sciences Inc SDG
Client Eastern Analytical ]nc Project Merrimack Station 2008
Sample ID Lab ID Matrix Date Sampled Date Received
SWWTF 1203203-01 Water 14-Mar-12 1305 16-Mar-12 0940
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Pagel o20 1203203 Final Report-SWWTF REV2
041042012
Liz Siska Project Manager 5
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
CASE NARRATIVE
Revised Report 4412- Sample name corrected to SWWTF
SAMPLE RECEIPT
Samples were received at Frontier Global Sciences (FGS) on March 16th 2012 The samples were received intact on-ice with temperatures measuredat 22 degrees Celsius
SAMPLE PREPARATION AND ANALYSIS
Samples were prepared and analyzed for total metals in accordance with EPA Method 2008 (modified)
Samples were prepared and analyzed for total mercury in accordance with EPA Method 163 JE
ANALYTICAL ISSUES
The client requested sample SWWTF (1203203-0 l) be analyzed for Mn via email on 31512
Samples were received in a cooler ofmelted ice There was water in the inner most bag of sample Evaporator (1203203-02)
As an additional measure ofthe accuracy ofthe methods utilized for analysis and to check for matrix interference matrix spikes (MS) and matrix spike duplicates (MSD) were digested and analyzed All ofthe matrix spike recoveries were within the control limits with the exception ofany QC flagged and described in the notes and definitions section ofthe following report
A reasonable measure ofthe precision ofthe analytical methods utilized for analysis is the relative percent difference (RPD) between matrix spike and matrix spike duplicate recoveries and between laboratory control sample and laboratory control sample duplicate recoveries All of the relative percent differences were within the control limits with the exception ofany QC flagged and described in the notes and definitions section ofthe following report
Frontier Global Sciences Inc The results in this report 011y apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 2 of20 1203203 Final Report- SWWTF REV2
04042012
Liz Siska Project Manager 6
FRONTIER
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIE NCES
CHAIN OF CUSTODY FORMS
bullbull _ ~ -bull uer ( A c 2 - gt Sampre Recefpt CHockJlst
Data Looobulld tn ~tZfrPkttr ~~middot0 middot1)d bull MSi~~gtamp Loss bull d I n Sy
SOG o f Coolns- R~oetvbullG I ( FGSPM
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rT~hbull_ornebullur_10~gt~(~5z2~_--CorrftCtfan rbullclOf (Cfl) ~lt2 - 3 degre-bull O eoolbullr- 1 L ~ middoto CoCttbullr a bullc eoolbullr-2 middot c Cootbullr7 middotc
middot c Cooler a bullc middot c
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NA Comrnbullnta
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middot------------ shy ---ilnt-nat chaln or custOdv irv1d
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lteon-eet aamIbull oontarners U ~ltftd fcrr reauect1Dd 0rnafv8ebull sbullm-reraquo roCHtlvOd In holdrna tlmomiddot bullbullrn- bull vohnlIbull auMolen ~~r raubullbulltbulld anaalvbull a
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CotTbulld orbullbullbulltvotlvbull ucact for aue atect -nahrbull _ -shyM of bull-n~tshy Qhertced a-d mthod l~e-ntbull -
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Mbulltnod ____ _
Olbull~bullronJRbullbullo1utlon
The results in this report only apply to the samples analy-ed in accordance with the Frontier Global Sciences Inc chain ofcustody docutMnt This aMlytical report must be reprodu~d in its e111irety
Page3of20 1203203 Final Rtport- SWWTFREV2
04042012
Liz Siska Project Manager 7
l l 720 North Creek Parkway Nortn u1Le -tvv Bothell WA 9amp011
Ph 425-686-1996 Fx 425-686-3096
FRONTIER GLOBAL SCIENCES
CHAIN OF CUSTODY FORMS
The results in this report only apply to the samples analyzed in accordance with the cliain ofcustody documenL This analytical report must be reproduced in its entirety
Frontier Global Sciences Inc Page 4 o20 1203203 Final Report- SWWTF REV2
04042012
Liz Siska Project Manager
8
11720 North Creek Parkway North Suite 40U Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
FRONTIER C L 0 B AL SC I~ NC ES
CHAlN OF CUSTODY FORMS
i---t--+-l-+-+-+--+--+--+--+_micro~[_amp~lslte---l t---t--+--11-(- -1--+-~-+--l---l---+----------f_ rmiddot 1---+--~--l--f-+---l--l--l-+--I--I---- _____--1 lt 1--1--1--+--l--------4-+-+--l--+-+--____f_ i--t--+--1r-+-+-+-t-+-++-4-________ _j bull-
CN _r(gt --shyshy~
_lj _D ~ -~ Irgt ~ -f
~ ~
The results In this report onlyapply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reprodu~din its entirety
Frontier Global Sciences Inc Page 5 o20 T203203 Final Report-SWWTFREV2
ommo12
Liz SiskaProject Manager
9
)--J middot ~~
)J fl~~J~c1N~r
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
Matrix Water Laboratory ID 1203203-01
ANALYTICAL RESULTS
SWWTF
Analyte Result lIDL MRL Units Dilution Batch Sequence Analyzed Method Notes
Aluminum 371 220 198 microgL 5 F203232 2C2000l 031912 EPA 2008 Mod
Arsenic 377 252 743 microgL 5 F203232 2C2000l 031912 EPA 2008 Mod
Cadmium 248 0205 0990 microgL 5 F203232 2C20001 031912 EPA2008 Mod
Chromium 532 045 495 microgL 5 F203232 2C20001 031912 EPA 2008 Mod
Copper 182 050 495 microgL 5 F203232 2C20001 031912 EPA 2008 Mod
Iron 1100 644 495 microgL 5 F203232 2C20001 031912 EPA 2008 Mod
Lead ND 0193 198 microgL 5 F203232 2C2000l 031912 EPA 2008 Mod u Manganese 7180 037 495 microgL 5 F203232 2C2000l 031912 EPA 2008 Mod
Mercury 612 842 505 ngL 100 F203288 2C22016 032212 EPA l631E FB-1631
Molybdenum 2000 297 297 microgL 50 F203260 2C22001 032112 EPA 2008 Mod
Nickel 303 040 495 microgL 5 F203232 2C20001 031912 EPA 2008 Mod
Selenium 587 959 297 microgL 5 F203232 2C20001 031912 EPA 2008 Mod
Silver ND 0297 0990 microgL 5 F203232 2C20001 031912 EPA 2008 Mod u Zinc 775 081 990 microgL 5 F203232 2C20001 031912 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report 011ly apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page6 o20 I203203 Final Report- SWWTF REV2
04042012
Liz Siska Project Manager 10
gt
C LO BA L S CI E N C ES
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
MATRIX DUPLICATESTRIPLICATES
SOURCE 1203203-01
Batch F203288
Preparation BrCl Oxidation
Sequence 2C22016
Lab Number F203288-DUPI
Sample Duplicate Concentration Concentration RPD
Analyte DgL ngL
5848
MRL 505
RPD 448
Limit
24
Method
EPA 163IE
Notes
Mercury 6116
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced In its entirety
Page 7of20 l 103203 Final Report- SWWTF REV2
04042012 bull 1 1 Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996
FROlJTIER Fx 425-686-3096 GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203203-01
Batch F203232 Sequence 2C20001
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203232-MSMSD 1
Sample Spike MS MS Concentration Added Concentration 0o Recovery
Analyte (microgL) (microgL) (microgL) Recovery Method NotesLimits
Alumimun 3707 15152 1853 978 70 - 130 EPA 2008 Mod
Chromium 5316 70707 1270 104 70- 130 EPA 2008 Mod
Manganese 7181 60606 7231 821 70 - 130 EPA 2008 Mod
Iron 1098 50505 6090 988 70- 130 EPA 2008 Mod
Nickel 3025 40404 3425 988 70 - 130 EPA 2008 Mod
Copper 1816 40404 5182 833 70 - 130 EPA2008 Mod
Arsenic 3770 15152 1904 101 70- 130 EPA 2008 Mod
Seleniwn 587l 30303 9297 113 70 - 130 EPA 2008 Mod
Silver ND 15152 1099 725 70 - 130 EPA 2008 Mod
Cadmillll) 2484 80808 9508 869 70 - 130 EPA 2008 Mod
Lead 0763 15152 1544 968 70-130 EPA2008Mod
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD
Recovery
Oo
RPD Recovery
Limits RPOLimit Method Notes
Aluminum 15152 1826 96l 145 70 shy 130 20 EPA 2008 Mod
Chromium 70707 1288 107 138 70-130 20 EPA 2008 Mod
Manganese 60606 7230 804 00140 70- 130 20 EPA 2008 Mod
Iron 50505 6065 983 0414 70- 130 20 EPA 2008 Mod
Nickel 40404 3378 872 138 70 - 130 20 EPA2008 Mod
Copper 40404 5140 823 0807 70 - 130 20 EPA 2008 Mod
Arsenic 15152 1928 102 123 70 - 130 20 EPA 2008 Mod
Selenium 30303 9063 105 255 70- 130 20 EPA 2008 Mod
Silver 15152 1075 709 219 70- 130 20 EPA 2008 Mod
Cadmium 80808 9347 849 170 70- 130 20 EPA 2008 Mod
Lead 15152 1531 960 0815 70- 130 20 EPA 2008 Mod
Frontier Global Sciences Inc The results In this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
PageBo20 1203203 FinalReport- SWWTFREV2
04042012
Liz Siska Project Manager 12
iii
11720 North Creek Parkway North Suite 400
Bothell WA 98011 Ph 425-686-1996 Fx 425-686-3096 GlOBAL SCIENCES
ij
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203203-01
Batch F203232 Sequence 2Q20001
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203232-MSMSD3
Analyte
Sample Concentration
(microgL)
Spike Added (pgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Limits Method Notes
Aluminum 3707 10000 10270 990 70 - 130 EPA 2008 Mod AS
Chromium 5316 10000 1137 108 70 - 130 EPA 2008 Mod AS Manganese 7181 10000 8207 103 70 - 130 EPA 2008 Mod AS
Iron 1098 50000 6185 102 70 - 130 EPA 2008 Mod AS Nickel 3025 12500 1433 905 70 - 130 EPA 2008 Mod AS Copper 1816 12500 1061 834 70 - 130 EPA 2008 Mod AS Zinc 7752 25000 1995 767 70 - 130 EPA 2008 Mod AS Arsenic 3770 10000 1073 104 70 - 130 EPA 2008 Mod AS Selenium 587l 10000 1530 943 70 - 130 EPA 2008 Mod AS Silver ND 50000 3690 738 70 - 130 EPA 2008 Mod AS Cadmium 2484 10000 8531 828 70 - 130 EPA 2008 Mod AS Lead 0763 25000 2505 999 70 - 130 EPA 2008 Mod AS
middoti
i
Aoalyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD o
Recovery
RPD Recovery
Limits RPDLimit Method Notes
Aluminum 10000 10150 978 121 70 - 130 20 EPA 2008 Mod AS Chromium 10000 1140 109 0293 70 - 130 20 EPA 2008 Mod AS Manganese 10000 8278 llO 0854 70 -130 20 EPA 2008 Mod AS Iron 50000 6243 103 0937 70-130 20 EPA 2008 Mod AS Nickel 12500 1441 91l middotos25 70 - 130 20 EPA 2008 Mod AS Copper 12500 1066 838 0496 70- 130 20 EPA 2008 Mod AS Zinc 25000 1990 765 0245 70- 130 20 EPA 2008 Mod AS Arsenic 10000 1094 106 193 70 - 130 20 EPA 2008 Mod AS Selenium 10000 1554 967 155 70 - 130 20 EPA 2008 Mod AS Silver 50000 3682 736 0222 70 - 130 20 EPA 2008 Mod AS Cadmium 10000 8394 815 l62 70 - 130 20 EPA 2008 Mod AS Lead 25000 250S 999 00263 70- 130 20 EPA 2008 Mod AS
~~ middotmiddot1 bull
bulli
bullmiddot
Frontier Global Sciences Inc The remits in this report only apply lo the samples analyzed in accordance with the chain ofcustody document This analytical report must bt reproductd In Its entirety
Page 9of20 1203203 Final Report-SWWTF REY2
04M2012
Liz Siska Project Manager 13
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 FRONTIER~ Fx 425-686-3096 GLOBAL SCIENCES
MATR1X SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203203-01RE3
Batch F203260 Sequence 2C22001
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203260-MSMSD3
Analyte
Sample Concentration
(microgL)
Spike Added (microgL)
MS Conctntration
(microgL)
MS
Recovery Recovery
Method Limits Notes
Molybdenum 1999 20200 middot 2041 206 70 - 130 EPA 2008 Mod QM-02
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD Oo
Recovery
RPD
Recovery Limits
RPO Limit Method Notes
Molybdenum 20200 2041 207 00141 70 - 130 20 EPA 2008 Mod QM-02
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed In accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page Oo20 1203203 Final Report- SWWTFREV2
04042012
Liz Siska Project Manager 14
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyzed in accordance with the chain ofcustody document This analytical report =tbe reproducedin Its entirety
Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
CLO~AL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1203203-0lREJ
Batch F203260
Preparation Closed Vessel Nitric Oven Digestion
Sequence 2C2200
Lab Number F203260-MSMSD6
Sample Spike MS MS
Analyte Concentration Added
(JtgL) (microgL) Concentration
(microgL)
Recovery Recovery
Method Limits Notes
Molybdenum 1999 50000 7034 101 70 - 130 EPA 2008 Mod AS
Spike MSD Added Concentration
MSD Recovery RPD
Analyte (microgL) (microgL) Recovery RPD Limits Limit Method Notes
Molybdenum 50000 7124 102 128 70 - 130 20 EPA 2008 Mod AS
Page 11 o20 1203203 Final Report- SWWTF REJ2
040412012
15
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 ~ Fx 425-686-3096 GLOBAL SCIENCES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203203-01
Batch F203288
Preparation BrCI Oxidation
Sequence 2C22016
Lab Number F203288-MSMSD 1
Sample Spike MS MS Concentration Added Concentration Recovery
Analyte (ngL) (ogL) (ogL) Recovery Method Notes Limits
Mercury 6116 25500 3096 974 71 - 125 EPA 1631E
Spike MSD MSD Oo Recovery RPD Added Concentration Oo
Limits Method Notes (ogL) (ogL) Recovery RPD Limit Analyte
Mercury 25500 2611 784 170 71 - 125 24 EPA 1631E
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed i11 accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 12of20 1203203 Final Report- SWWTF REV2
04042012
Liz Siska Project Manager 16
bull 11720 North Creek Parkway North Suite 400
Bothell WA 98011 Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1203194-17
Batch F203288 Sequence 2C22016
Preparation BrCI Oxidation Lab Number F203288-MSMSD2
Sample Spike MS MS
Analyte Concentration
(ngL) Added (ngL)
Concentration (ngL) Recovery
Recovery Limits Method Notes
Mercury 142800 505000 627200 959 71 - 125 EPA 1631E
Spike Added
MSD Concentration
MSD Recovery RPO
Analyte (ngL) (ngL) Recovery RPD Limits Limit Method Notes
Mercury 505000 632700 970 0879 71 - 125 24 EPA 1631E
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody docu~nt This analytical report must be reproduced In its entirety
Page 13of20 1203203 Final Report- SWWTFREV2
04042012
Liz Siska Project Manager 17
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996
bull ~ Fx 425-686-3096 GLPBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203232 Sequence 2C20001
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203232-BSBSD1
LCS Source mank Siiike
Spike LCS LCS Added Concentration Recovery
Analyte (microgL) (microgL) Recovery Limits Method Notes
Aluminwn 15000 1444 963 85-115 EPA2008Mod Chromium 70000 654 934 85 bull 115 EPA 2008 Mod Manganese 60000 580 967 85 - 115 EPA 2008 Mod Iron 50000 4610 922 85 - 115 EPA 2008 Mod Nickel 40000 394 985 85 ll5 EPA 2008 Mod Copper 40000 418 104 85 - 115 EPA 2008 Mod Zinc 10000 1017 102 85 bull 115 EPA 2008 Mod Arsenic 15000 1445 963 85 bull 115 EPA 2008 Mod Selenium 30000 2975 992 85-115 EPA2008Mod Molybdenum 20000 185 926 85 bull 115 EPA 2008 Mod Silver 15000 1555 104 85 - 115 EPA 2008 Mod
Cadmium 080000 0802 100 85 - 115 EPA 2008 Mod Lead 15000 1565 104 85 - 115 EPA 2008 Mod
shy
Spike LCSD LCSD Added Concentration Oo Recovery RPD
Analyte (microgL)
15000
(microgL)
1424
Recovery
949
RPD
140
Limits
85 bull 115
Limit
20
Method
EPA 2008 Mod
Notes
Aluminum
Chromium 70000 644 920 l58 85 bull 115 20 EPA 2008 Mod
Manganese 60000 575 958 0920 85 - ll5 20 EPA 2008 Mod
Iron 50000 4580 916 0660 85 - 115 20 EPA 2008 Mod
Nickel 40000 394 985 000457 85 bull 115 20 EPA 2008 Mod
Copper 40000 416 104 0367 85 - 115 20 EPA 2008 Mod
Zinc 10000 1032 103 147 85 - ll5 20 EPA 2008 Mod
Arsenic 15000 1440 960 0305 85 bull 115 20 EPA 2008 Mod
Selenium 30000 2867 956 369 85 -115 20 EPA 2008 Mod
Molybdenum 20000 l86 928 0196 85 -115 20 EPA2008 Mod
Silver l5000 1559 104 0233 85 bull 115 20 EPA 2008 Mod
Cadmium 080000 0809 101 0843 85 bull llS 20 EPA 2008 Mod
Lead 15000 l539 103 170 85 - 115 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed In accordance with the chain ofcustody document This analytical report must be reproduced in its enJirety
Page 14of20 1203203 Final Report- SWWTFREV2
04042012 ~~
Liz Siska Project Manager 18
11720 North Creek Parkway North Suite 400 Bothell WA 98011 Ph 425-686-1996
FRONTIER Fx 425-686-3096 GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203260 Sequence 2C22001
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203260-BSBSD1
LCS Source Blank Spike
Spike LCS LC$ Added Concentration Recovery
Analyte (ptgL) (JJgL) Recovery Limits Method Notes
Molybdenum 20000 182 910 85 - 115 EPA 2008 Mod
Spike LCSD LCSD Added Concentration Recovery RPD
Analyte (microgL) (microgL) Recovery RPD Limits Limit Method Notes
Molybdenum 20000 186 930 213 85 -115 20 EPA 2008 Mod
Frontier Global Sciences Inc The results In this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced In its entirety
Page 15 o20 I203203 Ftnal ampport- SWWTFREV2
04041202
Liz Siska Project Manager 19
middot
I
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SC IE NC ES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPO
Batch F203288 Sequence 2C22016
Preparation BrCI Oxidation Lab Number F203288-BSBSD I
LCS Source NIST 1641d
Spike LCS LCS Added Concentration Recovery
Analyte (ngL) (ngL) Recovery Limits Method Notes
Mercury 15679 1525 973 80 - 120 EPA l631E
Spike LCSD LCSD Added Concentration Oo Recovery RPD
Analyte (ngL) (ngL)
1516
Recovery
967
RPD
0622
Limits
80 - 120
Limit
24
Method
EPA 1631E
Notes
Mercury 15679
Frontier Global Sciences Inc The results in this report only apply lo the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 16 o20 1203203 Final Report- SWWIFREV2
041042012
20Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 middot Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096 ~ O GLO B AL SCI E NCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2C20001
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203232-BLK1 Aluminum 01 40 microgL F203232 PA2008 Molt u F203232-BLK1 Chromium -0007 0 10 microgL F203232 PA 2008 Molt u F203232-BLKI Manganese 0002 010 microgL F203232 PA 2008 Moc u F203232-BLK1 Iron -004 100 microgL F203232 PA 2008 Molt u F203232-BLKI Nickel 0005 010 microgL F203232 PA 2008 Moc u F203232-BLKI Copper 001 010 microgL F203232 PA 2008 Molt u F203232-BLK1 Zinc 011 020 microgL F203232 PA 2008 Moc u F203232-BLK I Arsenic -0009 015 microgL F203232 PA 2008 Moc u F203232-BLK1 Selenium 025 060 microgL F203232 PA 2008 Moc u F203232-BLK1 Molybdenum 001 006 microgL F203232 PA 2008 Moc u F203232-BLK1 Silver -00009 0020 microgL F203232 PA 2008 Moc u F203232-BLK1 Cadmium 0002 0020 microgL F203232 PA 2008 Molt u F203232-BLK1 Lead 0024 0040 microgL F203232 PA 2008 Molt u
middoti
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordonce with the chain ofcustody document Tnts analytical rtport must be reproduced In its enlfrtty
Page7of20 J203203 Final ampport-SWWTF REV2
04042012
Liz Siska Project Manager 21
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 FRONTIER~ Fx 425-686-3096 GLOBAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2C22001
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203260-BLK1 Molybdenum 001 006 microgL F203260 ~PA 2008 Moc u
Frontier Global Sciences Inc middot The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 18of20 1203203 Final Report- SWWTFREV2
04042012
Liz Siska Project Manager 22
~ CLOSAL SCIENCES
~
J1720 North Creek Parkway North Suite 400 Bothell WA 980 l l
Ph 425-686-1996 Fx 425-686-3096
PREPARATION BLANKS
Instrument Hg-17 Sequence 2C22016
Preparation BrCI Oxidation
The results in Ihis report only apply to the samples analyzed i12 accordance with the chain ofcustody dccumnt This analytical report must be reproductd in ils enJirety
Page I9oj20 1203203 Final Report- SWWTF REJ2
04042012
Frontier Global Sciences Inc
bull 23bull Liz Siska Project Manager
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203288-BLKl Mercury 007 050 ngL F203288 EPA 1631E u F203288-BLIlt2 Mercury 006 050 ngL F203288 EPA 163lE u F203288-BLK3 Mercury 006 050 ngL F203288 EPA I63lE u F203288-BLK4 Mercury 018 050 ngL F203288 EPA I63IE U QB-04
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
Notes and Definitions
U Analyte included in the analysis but not detected
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than I times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable ASASD
QB-04 The blank was preserved to 2 BrCl rather than I The control limit for blanks presetved to greater than 1 BrCl is the preservation percentage multiplied by the l1RL
FB-1631 Required equipmentfieldfilter blank not submitted by the client The sample has been analyzed according to 163 lE but does not meet 163 lE criteria
AS This MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
l1RL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to lhe samples analyzedin accordance wirh the chain ofcustody document This analytical report must be reproduced in its entirety
Page 20of20 1203203 Final Report- SWWTF REV2
04042012
24
bull bull
irGl Lu Ull 0111C H AIN-OF-CUSTODY RECORD Page of_~~
Bolo FIELDS REQUIRED P LEASE CIRCLE REQUESTED ANALYs1s Lt) CN voe I svoc TClPI M ETALS INORGANICS
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DATE NEEDED b171i1-1~ 1 f METALS 8 RCRA 13 PP FE MN Ps CUPROJECT MANAGER 0v f-e_~ Tmamp- middotc COMPANY pdegZ1)shy 0THE1 METALS __________REPORTING OPTIONSQAQC ICH) NoAonms Jfru lli V =1 Q ) REPORTING LEVEL PUUHS ~OR No
A B C 0lOLYpoundD METALS FIELD flLTtREDI YE NoIF YE F~ oa(ITT STAil~l4t(= ~ ZIP rriu1 NOTES (IE SPEOAl DETECTION LIHIIS BIWNG INFO IF D1mam)PHONE _r~ _z31_ - $ I3 Exr--- OR ELECTRONIC OPTIONSFAX _ __________________ AI l A C J C bull C1
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PROJECT ____________ ___ ___ _ ~111216- aJd M fer P4 jgtZJ)shy
SUTt MA ME VT OTHER _____ ___ ~ 1)--U ( u-middotmiddottut-UJ f bull
REGULATORY PROGRAM NPDES RGP POnY STOilKWATER Ol SITE HISTORY ~i tiT f=
GWP OIL FUND BROWNFJUD OR Orm--------shy RELINQUISHED BY DATE TIME RECEIVED Br Summo (ONTAHINATIOM_______
PO_______QUOTE===-~----shy I RELINQUISHED BY DATE TIME Rmmo BT I FIElllJUDINGStt HI l lS 2
eastern analytical inc 2s CHENELl DR1ve I CoNcoRo NH 03301 I TEL 60322sos2s I 1soo2s7os2s IFAXc 6032284591 I E-MA1l cusToMER_seRv1ceEA1LAascoHj wwweA1lAsscoM
prufmin111ll11bomtory1m1im (WHITE ORIGINAL GREEN PROJECT MANAGER)
shy
shy
TABLEl SUMMARY OF STREAM B CONCENTRATIONS
COMPARED TO LOWELL SEWER DISCHARGE LIMITS Public Service ofNew Hampshire
Merrimack Station Bow New Hampshire
PARAMETER LOWELL SEWER
DISCHARGE LIMITS (mgL)
STREAM B RESULTS 3142012
(mgIL)
Aluminum 2469 0371
Arsenic 0556 00377
Cadmium 0056 000248 Chromium (T) 8108 00532
Copper 3124 00182
Lead 0857 lt 000198
Mercury 0004 00000612
Nickel 1541 0303 pH 50-95 69
Silver 0053 lt 0000990
Zinc 4959 00775
P04obsl0029300sl04002930700WortSAMPLING AND REPORTINGIDATAI 04002930700 RESULTS 032112xll1ltLltgtwcll B GZA GeoEnvironmental Inc
ANALYTICAL DATA REPORT
~--fLAA____________e_a_s_t_e_r_n_a_n_a_ly_t_i_c_a_l__
Paul Pepler
GZA GeoEnvironmental Inc (NH)
380 Harvey Road
Manchester NH 03103
Subject Laboratory Report
Eastern Analytical Inc ID 108420
Client Identification MK
Date Received 3142012
Dear Mr Pepler
Enclosed please find the laboratory report for the above identified project All analyses were performed in accordance with our QAQC Program Unless otherwise stated holding times preservation techniques container types and sample conditions adhered to EPA Protocol Samples which were collected by Eastern Analytical Inc (EAi) were collected in accordance with approved EPA procedures Eastern Analytical Inc certifies that the enclosed test results meet all requirements of NELAP and other applicable state certifications Please refer to our website at wwweailabscom for a copy ofour NELAP certificate and accredited parameters
The following standard abbreviations and conventions apply to all EAi reports Solid samples are reported on a dry weight basis unless otherwise noted lt less than followed by the reporting limit gt greater than followed by the reporting limit R Recovery
Eastern Analytical Inc maintains certification in the following states Connecticut (PH-0492) Maine (NH005) Massachusetts (M-NH005) New HampshireNELAP (1012) Rhode Island (269) and Vermont (VT1012)
The following information is contained within this report Sample Conditions summary Analytical ResultsData Quality Control data (if requested) and copies of the Chain of Custody This report may not be reproduced except in full without the the written approval of the laboratory
If you have any questions regarding the results contained within please feel free to directly contact me or the chemist(s) who performed the testing in question Unless otherwise requested we will dispose of the sample(s) 30 days from the sample receipt date
We appreciate this opportunity to be of service and look forward to your continued patronage
Sincerely
11micro3= Date
JS of pages (excluding cover letter)
11middot1111Llibb ~(( 1111
SAMPLE CONDITIONS PAGE EAi ID 108420
Client middot GZA GeoEnvironmental Inc (NH)
Client Designation MK
Temperature upon receipt (degC) 184 Received on ice or cold packs (YesNo) y Acceptable temperature range (degC) 0-6
Date Date Sample Dry Lab ID Sample ID Received Sampled Matrix Weight ExceptionsComments (other than thermal preservation)
10842001 SWWTF 31412 31412 aqueous Adheres to Sample Acceptance Policy
Samples were properly preserved and the pH measured when applicable unless otherwise noted Analysis ofsolids for pH Flashpoint lgnitibility Paint Filter Corrosivity Conductivity and Specific Gravity are reported on an middotas received basis
All results contained in this report relate only to the above listed samples References include 1) EPA 6004-79-020 1983 2) Standard Methods for Examination ofWater and Wastewater lnorganics 19th Edition 1995 Microbiology 20th Edition 1998 3) Test Methods for Evaluating Solid Waste SW 846 3rd Edition Including updates VA and VB 4) Hach Water Analysis Handbook 2nd edition 1992
eastern analytical inc wwweailabscom Phone (603) 228-0525 1
LABORATORY REPORT EAi I 0 108420
Client GZA GeoEnvironmental Inc (NH)
Client Designation MK
Sample ID SWNTF
Lab Sample ID 10842001
Matrix aqueous
Date Sampled 31412
31412Date Received
Solids Suspended 25000 Solids Dissolved 180000 Chloride 75000 BOD 140 COD 900 pH 69
Analysis
Units Date Time Method Analyst
mgL 31912 1345 2540D DLS mgL 31912 1500 2540C DLS mgL 311912 1030 4500CIE DLS mgL 31512 1412 52108 SKC mgL 32012 900 H8000 KJR SU 31412 1705 4500H+B Jl
TDS Due to sample matrix a constant weight of 000059 could not be achieved
eastern analytical inc wwweailabscom Phone (603) 228-0525 2
QC REPORT EAIID 10842011Jul Client GZA GeoEnvironmental Inc (NH)
Client Designation MK
Date of
Parameter Name Blank LCS LCSO Units Analysis Limits RPO Method
Solids Suspended lt5 96 (96 ooR) 100 (100 ooR) (4 RPO) mgL 31912 90 -110 20 2540D
Solids Dissolved lt5 990 (99 R) NA mgL 31912 85 - 115 20 2540C
Chloride lt 1 27 (106 ooR) 26 (106 ooR) (0 RPD) mgL 31912 90 - 110 20 4500CIE
BOD lt6 400 (100 R) 410 (102 R) (2 RPD) mgL 31512 84-115 20 52108
COD lt 10 100 (97 R) 100 (101 R) (4 RPD) mgL 32012 85 -115 20 H8000
pH 60 (100 ooR) 60 (100 ooR) (0 RPD) SU 31412 595 - 607 10 4500H+B
Duplicate Duplicate Date of Parameter Name Parent ID Parent Duplicate Units Analysls RPO Method
Solids Suspended 10850303 200 190 (4RPD) mgL 31912 20 2540D Solids Dissolved 10843101 270 270 (0 RPO) mgL 31912 20 2540C Chloride NA NA mgL 31912 20 4500CIE BOD NA NA mgL 31512 20 52108 COD NA NA mgl 32012 20 H8000 pH 10838601 82 82 (0 RPO) SU 31412 10 4500H+B
Samples were analyzed within holding times unless noted on the sample results page Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits The associated matrix spikes andor Laboratory Control Samples met the above stated criteria Exceptions to the above statements are flagged or noted above or on the QC Narrative page bull11 Flagged analyte recoveries deviated from the QAQC limits
eastern analytical inc wwweailabscom Phone (603) 228-0525 3
Ill
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
G L OS AL S ( I E N lt ES
04 April 2012
JeffGagne
Eastern Analytical Inc
25 Chenell Drive
Concord NH 03301
RE Merrimack Station 2008
Enclosed are the analytical results for samples received by Frontier Global Sciences All quality control
measurements are within established control limits and there were no analytical difficulties encountered
with the exception ofthose listed in the case narrative section of this report
Ifyou have any questions concerning this report please feel free to contact me
Sincerely 44
Liz Siska
Project Manager
4
~ 11720 North Creek Parkway North Suite 400
Bothell WA 9801 1 Ph 425-686-1996 Fx 425-686-3096
GLOBAl SCIENCES
ANALYTICAL REPORT FOR SAMPLES
Laboratory Frontier Global Sciences Inc SDG
Client Eastern Analytical ]nc Project Merrimack Station 2008
Sample ID Lab ID Matrix Date Sampled Date Received
SWWTF 1203203-01 Water 14-Mar-12 1305 16-Mar-12 0940
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Pagel o20 1203203 Final Report-SWWTF REV2
041042012
Liz Siska Project Manager 5
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
CASE NARRATIVE
Revised Report 4412- Sample name corrected to SWWTF
SAMPLE RECEIPT
Samples were received at Frontier Global Sciences (FGS) on March 16th 2012 The samples were received intact on-ice with temperatures measuredat 22 degrees Celsius
SAMPLE PREPARATION AND ANALYSIS
Samples were prepared and analyzed for total metals in accordance with EPA Method 2008 (modified)
Samples were prepared and analyzed for total mercury in accordance with EPA Method 163 JE
ANALYTICAL ISSUES
The client requested sample SWWTF (1203203-0 l) be analyzed for Mn via email on 31512
Samples were received in a cooler ofmelted ice There was water in the inner most bag of sample Evaporator (1203203-02)
As an additional measure ofthe accuracy ofthe methods utilized for analysis and to check for matrix interference matrix spikes (MS) and matrix spike duplicates (MSD) were digested and analyzed All ofthe matrix spike recoveries were within the control limits with the exception ofany QC flagged and described in the notes and definitions section ofthe following report
A reasonable measure ofthe precision ofthe analytical methods utilized for analysis is the relative percent difference (RPD) between matrix spike and matrix spike duplicate recoveries and between laboratory control sample and laboratory control sample duplicate recoveries All of the relative percent differences were within the control limits with the exception ofany QC flagged and described in the notes and definitions section ofthe following report
Frontier Global Sciences Inc The results in this report 011y apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 2 of20 1203203 Final Report- SWWTF REV2
04042012
Liz Siska Project Manager 6
FRONTIER
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIE NCES
CHAIN OF CUSTODY FORMS
bullbull _ ~ -bull uer ( A c 2 - gt Sampre Recefpt CHockJlst
Data Looobulld tn ~tZfrPkttr ~~middot0 middot1)d bull MSi~~gtamp Loss bull d I n Sy
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The results in this report only apply to the samples analy-ed in accordance with the Frontier Global Sciences Inc chain ofcustody docutMnt This aMlytical report must be reprodu~d in its e111irety
Page3of20 1203203 Final Rtport- SWWTFREV2
04042012
Liz Siska Project Manager 7
l l 720 North Creek Parkway Nortn u1Le -tvv Bothell WA 9amp011
Ph 425-686-1996 Fx 425-686-3096
FRONTIER GLOBAL SCIENCES
CHAIN OF CUSTODY FORMS
The results in this report only apply to the samples analyzed in accordance with the cliain ofcustody documenL This analytical report must be reproduced in its entirety
Frontier Global Sciences Inc Page 4 o20 1203203 Final Report- SWWTF REV2
04042012
Liz Siska Project Manager
8
11720 North Creek Parkway North Suite 40U Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
FRONTIER C L 0 B AL SC I~ NC ES
CHAlN OF CUSTODY FORMS
i---t--+-l-+-+-+--+--+--+--+_micro~[_amp~lslte---l t---t--+--11-(- -1--+-~-+--l---l---+----------f_ rmiddot 1---+--~--l--f-+---l--l--l-+--I--I---- _____--1 lt 1--1--1--+--l--------4-+-+--l--+-+--____f_ i--t--+--1r-+-+-+-t-+-++-4-________ _j bull-
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The results In this report onlyapply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reprodu~din its entirety
Frontier Global Sciences Inc Page 5 o20 T203203 Final Report-SWWTFREV2
ommo12
Liz SiskaProject Manager
9
)--J middot ~~
)J fl~~J~c1N~r
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
Matrix Water Laboratory ID 1203203-01
ANALYTICAL RESULTS
SWWTF
Analyte Result lIDL MRL Units Dilution Batch Sequence Analyzed Method Notes
Aluminum 371 220 198 microgL 5 F203232 2C2000l 031912 EPA 2008 Mod
Arsenic 377 252 743 microgL 5 F203232 2C2000l 031912 EPA 2008 Mod
Cadmium 248 0205 0990 microgL 5 F203232 2C20001 031912 EPA2008 Mod
Chromium 532 045 495 microgL 5 F203232 2C20001 031912 EPA 2008 Mod
Copper 182 050 495 microgL 5 F203232 2C20001 031912 EPA 2008 Mod
Iron 1100 644 495 microgL 5 F203232 2C20001 031912 EPA 2008 Mod
Lead ND 0193 198 microgL 5 F203232 2C2000l 031912 EPA 2008 Mod u Manganese 7180 037 495 microgL 5 F203232 2C2000l 031912 EPA 2008 Mod
Mercury 612 842 505 ngL 100 F203288 2C22016 032212 EPA l631E FB-1631
Molybdenum 2000 297 297 microgL 50 F203260 2C22001 032112 EPA 2008 Mod
Nickel 303 040 495 microgL 5 F203232 2C20001 031912 EPA 2008 Mod
Selenium 587 959 297 microgL 5 F203232 2C20001 031912 EPA 2008 Mod
Silver ND 0297 0990 microgL 5 F203232 2C20001 031912 EPA 2008 Mod u Zinc 775 081 990 microgL 5 F203232 2C20001 031912 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report 011ly apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page6 o20 I203203 Final Report- SWWTF REV2
04042012
Liz Siska Project Manager 10
gt
C LO BA L S CI E N C ES
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
MATRIX DUPLICATESTRIPLICATES
SOURCE 1203203-01
Batch F203288
Preparation BrCl Oxidation
Sequence 2C22016
Lab Number F203288-DUPI
Sample Duplicate Concentration Concentration RPD
Analyte DgL ngL
5848
MRL 505
RPD 448
Limit
24
Method
EPA 163IE
Notes
Mercury 6116
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced In its entirety
Page 7of20 l 103203 Final Report- SWWTF REV2
04042012 bull 1 1 Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996
FROlJTIER Fx 425-686-3096 GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203203-01
Batch F203232 Sequence 2C20001
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203232-MSMSD 1
Sample Spike MS MS Concentration Added Concentration 0o Recovery
Analyte (microgL) (microgL) (microgL) Recovery Method NotesLimits
Alumimun 3707 15152 1853 978 70 - 130 EPA 2008 Mod
Chromium 5316 70707 1270 104 70- 130 EPA 2008 Mod
Manganese 7181 60606 7231 821 70 - 130 EPA 2008 Mod
Iron 1098 50505 6090 988 70- 130 EPA 2008 Mod
Nickel 3025 40404 3425 988 70 - 130 EPA 2008 Mod
Copper 1816 40404 5182 833 70 - 130 EPA2008 Mod
Arsenic 3770 15152 1904 101 70- 130 EPA 2008 Mod
Seleniwn 587l 30303 9297 113 70 - 130 EPA 2008 Mod
Silver ND 15152 1099 725 70 - 130 EPA 2008 Mod
Cadmillll) 2484 80808 9508 869 70 - 130 EPA 2008 Mod
Lead 0763 15152 1544 968 70-130 EPA2008Mod
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD
Recovery
Oo
RPD Recovery
Limits RPOLimit Method Notes
Aluminum 15152 1826 96l 145 70 shy 130 20 EPA 2008 Mod
Chromium 70707 1288 107 138 70-130 20 EPA 2008 Mod
Manganese 60606 7230 804 00140 70- 130 20 EPA 2008 Mod
Iron 50505 6065 983 0414 70- 130 20 EPA 2008 Mod
Nickel 40404 3378 872 138 70 - 130 20 EPA2008 Mod
Copper 40404 5140 823 0807 70 - 130 20 EPA 2008 Mod
Arsenic 15152 1928 102 123 70 - 130 20 EPA 2008 Mod
Selenium 30303 9063 105 255 70- 130 20 EPA 2008 Mod
Silver 15152 1075 709 219 70- 130 20 EPA 2008 Mod
Cadmium 80808 9347 849 170 70- 130 20 EPA 2008 Mod
Lead 15152 1531 960 0815 70- 130 20 EPA 2008 Mod
Frontier Global Sciences Inc The results In this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
PageBo20 1203203 FinalReport- SWWTFREV2
04042012
Liz Siska Project Manager 12
iii
11720 North Creek Parkway North Suite 400
Bothell WA 98011 Ph 425-686-1996 Fx 425-686-3096 GlOBAL SCIENCES
ij
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203203-01
Batch F203232 Sequence 2Q20001
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203232-MSMSD3
Analyte
Sample Concentration
(microgL)
Spike Added (pgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Limits Method Notes
Aluminum 3707 10000 10270 990 70 - 130 EPA 2008 Mod AS
Chromium 5316 10000 1137 108 70 - 130 EPA 2008 Mod AS Manganese 7181 10000 8207 103 70 - 130 EPA 2008 Mod AS
Iron 1098 50000 6185 102 70 - 130 EPA 2008 Mod AS Nickel 3025 12500 1433 905 70 - 130 EPA 2008 Mod AS Copper 1816 12500 1061 834 70 - 130 EPA 2008 Mod AS Zinc 7752 25000 1995 767 70 - 130 EPA 2008 Mod AS Arsenic 3770 10000 1073 104 70 - 130 EPA 2008 Mod AS Selenium 587l 10000 1530 943 70 - 130 EPA 2008 Mod AS Silver ND 50000 3690 738 70 - 130 EPA 2008 Mod AS Cadmium 2484 10000 8531 828 70 - 130 EPA 2008 Mod AS Lead 0763 25000 2505 999 70 - 130 EPA 2008 Mod AS
middoti
i
Aoalyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD o
Recovery
RPD Recovery
Limits RPDLimit Method Notes
Aluminum 10000 10150 978 121 70 - 130 20 EPA 2008 Mod AS Chromium 10000 1140 109 0293 70 - 130 20 EPA 2008 Mod AS Manganese 10000 8278 llO 0854 70 -130 20 EPA 2008 Mod AS Iron 50000 6243 103 0937 70-130 20 EPA 2008 Mod AS Nickel 12500 1441 91l middotos25 70 - 130 20 EPA 2008 Mod AS Copper 12500 1066 838 0496 70- 130 20 EPA 2008 Mod AS Zinc 25000 1990 765 0245 70- 130 20 EPA 2008 Mod AS Arsenic 10000 1094 106 193 70 - 130 20 EPA 2008 Mod AS Selenium 10000 1554 967 155 70 - 130 20 EPA 2008 Mod AS Silver 50000 3682 736 0222 70 - 130 20 EPA 2008 Mod AS Cadmium 10000 8394 815 l62 70 - 130 20 EPA 2008 Mod AS Lead 25000 250S 999 00263 70- 130 20 EPA 2008 Mod AS
~~ middotmiddot1 bull
bulli
bullmiddot
Frontier Global Sciences Inc The remits in this report only apply lo the samples analyzed in accordance with the chain ofcustody document This analytical report must bt reproductd In Its entirety
Page 9of20 1203203 Final Report-SWWTF REY2
04M2012
Liz Siska Project Manager 13
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 FRONTIER~ Fx 425-686-3096 GLOBAL SCIENCES
MATR1X SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203203-01RE3
Batch F203260 Sequence 2C22001
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203260-MSMSD3
Analyte
Sample Concentration
(microgL)
Spike Added (microgL)
MS Conctntration
(microgL)
MS
Recovery Recovery
Method Limits Notes
Molybdenum 1999 20200 middot 2041 206 70 - 130 EPA 2008 Mod QM-02
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD Oo
Recovery
RPD
Recovery Limits
RPO Limit Method Notes
Molybdenum 20200 2041 207 00141 70 - 130 20 EPA 2008 Mod QM-02
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed In accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page Oo20 1203203 Final Report- SWWTFREV2
04042012
Liz Siska Project Manager 14
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyzed in accordance with the chain ofcustody document This analytical report =tbe reproducedin Its entirety
Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
CLO~AL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1203203-0lREJ
Batch F203260
Preparation Closed Vessel Nitric Oven Digestion
Sequence 2C2200
Lab Number F203260-MSMSD6
Sample Spike MS MS
Analyte Concentration Added
(JtgL) (microgL) Concentration
(microgL)
Recovery Recovery
Method Limits Notes
Molybdenum 1999 50000 7034 101 70 - 130 EPA 2008 Mod AS
Spike MSD Added Concentration
MSD Recovery RPD
Analyte (microgL) (microgL) Recovery RPD Limits Limit Method Notes
Molybdenum 50000 7124 102 128 70 - 130 20 EPA 2008 Mod AS
Page 11 o20 1203203 Final Report- SWWTF REJ2
040412012
15
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 ~ Fx 425-686-3096 GLOBAL SCIENCES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203203-01
Batch F203288
Preparation BrCI Oxidation
Sequence 2C22016
Lab Number F203288-MSMSD 1
Sample Spike MS MS Concentration Added Concentration Recovery
Analyte (ngL) (ogL) (ogL) Recovery Method Notes Limits
Mercury 6116 25500 3096 974 71 - 125 EPA 1631E
Spike MSD MSD Oo Recovery RPD Added Concentration Oo
Limits Method Notes (ogL) (ogL) Recovery RPD Limit Analyte
Mercury 25500 2611 784 170 71 - 125 24 EPA 1631E
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed i11 accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 12of20 1203203 Final Report- SWWTF REV2
04042012
Liz Siska Project Manager 16
bull 11720 North Creek Parkway North Suite 400
Bothell WA 98011 Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1203194-17
Batch F203288 Sequence 2C22016
Preparation BrCI Oxidation Lab Number F203288-MSMSD2
Sample Spike MS MS
Analyte Concentration
(ngL) Added (ngL)
Concentration (ngL) Recovery
Recovery Limits Method Notes
Mercury 142800 505000 627200 959 71 - 125 EPA 1631E
Spike Added
MSD Concentration
MSD Recovery RPO
Analyte (ngL) (ngL) Recovery RPD Limits Limit Method Notes
Mercury 505000 632700 970 0879 71 - 125 24 EPA 1631E
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody docu~nt This analytical report must be reproduced In its entirety
Page 13of20 1203203 Final Report- SWWTFREV2
04042012
Liz Siska Project Manager 17
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996
bull ~ Fx 425-686-3096 GLPBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203232 Sequence 2C20001
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203232-BSBSD1
LCS Source mank Siiike
Spike LCS LCS Added Concentration Recovery
Analyte (microgL) (microgL) Recovery Limits Method Notes
Aluminwn 15000 1444 963 85-115 EPA2008Mod Chromium 70000 654 934 85 bull 115 EPA 2008 Mod Manganese 60000 580 967 85 - 115 EPA 2008 Mod Iron 50000 4610 922 85 - 115 EPA 2008 Mod Nickel 40000 394 985 85 ll5 EPA 2008 Mod Copper 40000 418 104 85 - 115 EPA 2008 Mod Zinc 10000 1017 102 85 bull 115 EPA 2008 Mod Arsenic 15000 1445 963 85 bull 115 EPA 2008 Mod Selenium 30000 2975 992 85-115 EPA2008Mod Molybdenum 20000 185 926 85 bull 115 EPA 2008 Mod Silver 15000 1555 104 85 - 115 EPA 2008 Mod
Cadmium 080000 0802 100 85 - 115 EPA 2008 Mod Lead 15000 1565 104 85 - 115 EPA 2008 Mod
shy
Spike LCSD LCSD Added Concentration Oo Recovery RPD
Analyte (microgL)
15000
(microgL)
1424
Recovery
949
RPD
140
Limits
85 bull 115
Limit
20
Method
EPA 2008 Mod
Notes
Aluminum
Chromium 70000 644 920 l58 85 bull 115 20 EPA 2008 Mod
Manganese 60000 575 958 0920 85 - ll5 20 EPA 2008 Mod
Iron 50000 4580 916 0660 85 - 115 20 EPA 2008 Mod
Nickel 40000 394 985 000457 85 bull 115 20 EPA 2008 Mod
Copper 40000 416 104 0367 85 - 115 20 EPA 2008 Mod
Zinc 10000 1032 103 147 85 - ll5 20 EPA 2008 Mod
Arsenic 15000 1440 960 0305 85 bull 115 20 EPA 2008 Mod
Selenium 30000 2867 956 369 85 -115 20 EPA 2008 Mod
Molybdenum 20000 l86 928 0196 85 -115 20 EPA2008 Mod
Silver l5000 1559 104 0233 85 bull 115 20 EPA 2008 Mod
Cadmium 080000 0809 101 0843 85 bull llS 20 EPA 2008 Mod
Lead 15000 l539 103 170 85 - 115 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed In accordance with the chain ofcustody document This analytical report must be reproduced in its enJirety
Page 14of20 1203203 Final Report- SWWTFREV2
04042012 ~~
Liz Siska Project Manager 18
11720 North Creek Parkway North Suite 400 Bothell WA 98011 Ph 425-686-1996
FRONTIER Fx 425-686-3096 GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203260 Sequence 2C22001
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203260-BSBSD1
LCS Source Blank Spike
Spike LCS LC$ Added Concentration Recovery
Analyte (ptgL) (JJgL) Recovery Limits Method Notes
Molybdenum 20000 182 910 85 - 115 EPA 2008 Mod
Spike LCSD LCSD Added Concentration Recovery RPD
Analyte (microgL) (microgL) Recovery RPD Limits Limit Method Notes
Molybdenum 20000 186 930 213 85 -115 20 EPA 2008 Mod
Frontier Global Sciences Inc The results In this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced In its entirety
Page 15 o20 I203203 Ftnal ampport- SWWTFREV2
04041202
Liz Siska Project Manager 19
middot
I
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SC IE NC ES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPO
Batch F203288 Sequence 2C22016
Preparation BrCI Oxidation Lab Number F203288-BSBSD I
LCS Source NIST 1641d
Spike LCS LCS Added Concentration Recovery
Analyte (ngL) (ngL) Recovery Limits Method Notes
Mercury 15679 1525 973 80 - 120 EPA l631E
Spike LCSD LCSD Added Concentration Oo Recovery RPD
Analyte (ngL) (ngL)
1516
Recovery
967
RPD
0622
Limits
80 - 120
Limit
24
Method
EPA 1631E
Notes
Mercury 15679
Frontier Global Sciences Inc The results in this report only apply lo the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 16 o20 1203203 Final Report- SWWIFREV2
041042012
20Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 middot Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096 ~ O GLO B AL SCI E NCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2C20001
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203232-BLK1 Aluminum 01 40 microgL F203232 PA2008 Molt u F203232-BLK1 Chromium -0007 0 10 microgL F203232 PA 2008 Molt u F203232-BLKI Manganese 0002 010 microgL F203232 PA 2008 Moc u F203232-BLK1 Iron -004 100 microgL F203232 PA 2008 Molt u F203232-BLKI Nickel 0005 010 microgL F203232 PA 2008 Moc u F203232-BLKI Copper 001 010 microgL F203232 PA 2008 Molt u F203232-BLK1 Zinc 011 020 microgL F203232 PA 2008 Moc u F203232-BLK I Arsenic -0009 015 microgL F203232 PA 2008 Moc u F203232-BLK1 Selenium 025 060 microgL F203232 PA 2008 Moc u F203232-BLK1 Molybdenum 001 006 microgL F203232 PA 2008 Moc u F203232-BLK1 Silver -00009 0020 microgL F203232 PA 2008 Moc u F203232-BLK1 Cadmium 0002 0020 microgL F203232 PA 2008 Molt u F203232-BLK1 Lead 0024 0040 microgL F203232 PA 2008 Molt u
middoti
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordonce with the chain ofcustody document Tnts analytical rtport must be reproduced In its enlfrtty
Page7of20 J203203 Final ampport-SWWTF REV2
04042012
Liz Siska Project Manager 21
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 FRONTIER~ Fx 425-686-3096 GLOBAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2C22001
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203260-BLK1 Molybdenum 001 006 microgL F203260 ~PA 2008 Moc u
Frontier Global Sciences Inc middot The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 18of20 1203203 Final Report- SWWTFREV2
04042012
Liz Siska Project Manager 22
~ CLOSAL SCIENCES
~
J1720 North Creek Parkway North Suite 400 Bothell WA 980 l l
Ph 425-686-1996 Fx 425-686-3096
PREPARATION BLANKS
Instrument Hg-17 Sequence 2C22016
Preparation BrCI Oxidation
The results in Ihis report only apply to the samples analyzed i12 accordance with the chain ofcustody dccumnt This analytical report must be reproductd in ils enJirety
Page I9oj20 1203203 Final Report- SWWTF REJ2
04042012
Frontier Global Sciences Inc
bull 23bull Liz Siska Project Manager
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203288-BLKl Mercury 007 050 ngL F203288 EPA 1631E u F203288-BLIlt2 Mercury 006 050 ngL F203288 EPA 163lE u F203288-BLK3 Mercury 006 050 ngL F203288 EPA I63lE u F203288-BLK4 Mercury 018 050 ngL F203288 EPA I63IE U QB-04
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
Notes and Definitions
U Analyte included in the analysis but not detected
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than I times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable ASASD
QB-04 The blank was preserved to 2 BrCl rather than I The control limit for blanks presetved to greater than 1 BrCl is the preservation percentage multiplied by the l1RL
FB-1631 Required equipmentfieldfilter blank not submitted by the client The sample has been analyzed according to 163 lE but does not meet 163 lE criteria
AS This MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
l1RL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to lhe samples analyzedin accordance wirh the chain ofcustody document This analytical report must be reproduced in its entirety
Page 20of20 1203203 Final Report- SWWTF REV2
04042012
24
bull bull
irGl Lu Ull 0111C H AIN-OF-CUSTODY RECORD Page of_~~
Bolo FIELDS REQUIRED P LEASE CIRCLE REQUESTED ANALYs1s Lt) CN voe I svoc TClPI M ETALS INORGANICS
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SAMPLING 0 iii 0 ~
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1
DATE NEEDED b171i1-1~ 1 f METALS 8 RCRA 13 PP FE MN Ps CUPROJECT MANAGER 0v f-e_~ Tmamp- middotc COMPANY pdegZ1)shy 0THE1 METALS __________REPORTING OPTIONSQAQC ICH) NoAonms Jfru lli V =1 Q ) REPORTING LEVEL PUUHS ~OR No
A B C 0lOLYpoundD METALS FIELD flLTtREDI YE NoIF YE F~ oa(ITT STAil~l4t(= ~ ZIP rriu1 NOTES (IE SPEOAl DETECTION LIHIIS BIWNG INFO IF D1mam)PHONE _r~ _z31_ - $ I3 Exr--- OR ELECTRONIC OPTIONSFAX _ __________________ AI l A C J C bull C1
J pbNo FAX E-MAIL PDF EQUIS
E-MAIL tivl el qu ~ pv CvVshyf J --~b Mo ~ tJ k ttJ -z~Sm NAHE W
PROJECT ____________ ___ ___ _ ~111216- aJd M fer P4 jgtZJ)shy
SUTt MA ME VT OTHER _____ ___ ~ 1)--U ( u-middotmiddottut-UJ f bull
REGULATORY PROGRAM NPDES RGP POnY STOilKWATER Ol SITE HISTORY ~i tiT f=
GWP OIL FUND BROWNFJUD OR Orm--------shy RELINQUISHED BY DATE TIME RECEIVED Br Summo (ONTAHINATIOM_______
PO_______QUOTE===-~----shy I RELINQUISHED BY DATE TIME Rmmo BT I FIElllJUDINGStt HI l lS 2
eastern analytical inc 2s CHENELl DR1ve I CoNcoRo NH 03301 I TEL 60322sos2s I 1soo2s7os2s IFAXc 6032284591 I E-MA1l cusToMER_seRv1ceEA1LAascoHj wwweA1lAsscoM
prufmin111ll11bomtory1m1im (WHITE ORIGINAL GREEN PROJECT MANAGER)
shy
shy
ANALYTICAL DATA REPORT
~--fLAA____________e_a_s_t_e_r_n_a_n_a_ly_t_i_c_a_l__
Paul Pepler
GZA GeoEnvironmental Inc (NH)
380 Harvey Road
Manchester NH 03103
Subject Laboratory Report
Eastern Analytical Inc ID 108420
Client Identification MK
Date Received 3142012
Dear Mr Pepler
Enclosed please find the laboratory report for the above identified project All analyses were performed in accordance with our QAQC Program Unless otherwise stated holding times preservation techniques container types and sample conditions adhered to EPA Protocol Samples which were collected by Eastern Analytical Inc (EAi) were collected in accordance with approved EPA procedures Eastern Analytical Inc certifies that the enclosed test results meet all requirements of NELAP and other applicable state certifications Please refer to our website at wwweailabscom for a copy ofour NELAP certificate and accredited parameters
The following standard abbreviations and conventions apply to all EAi reports Solid samples are reported on a dry weight basis unless otherwise noted lt less than followed by the reporting limit gt greater than followed by the reporting limit R Recovery
Eastern Analytical Inc maintains certification in the following states Connecticut (PH-0492) Maine (NH005) Massachusetts (M-NH005) New HampshireNELAP (1012) Rhode Island (269) and Vermont (VT1012)
The following information is contained within this report Sample Conditions summary Analytical ResultsData Quality Control data (if requested) and copies of the Chain of Custody This report may not be reproduced except in full without the the written approval of the laboratory
If you have any questions regarding the results contained within please feel free to directly contact me or the chemist(s) who performed the testing in question Unless otherwise requested we will dispose of the sample(s) 30 days from the sample receipt date
We appreciate this opportunity to be of service and look forward to your continued patronage
Sincerely
11micro3= Date
JS of pages (excluding cover letter)
11middot1111Llibb ~(( 1111
SAMPLE CONDITIONS PAGE EAi ID 108420
Client middot GZA GeoEnvironmental Inc (NH)
Client Designation MK
Temperature upon receipt (degC) 184 Received on ice or cold packs (YesNo) y Acceptable temperature range (degC) 0-6
Date Date Sample Dry Lab ID Sample ID Received Sampled Matrix Weight ExceptionsComments (other than thermal preservation)
10842001 SWWTF 31412 31412 aqueous Adheres to Sample Acceptance Policy
Samples were properly preserved and the pH measured when applicable unless otherwise noted Analysis ofsolids for pH Flashpoint lgnitibility Paint Filter Corrosivity Conductivity and Specific Gravity are reported on an middotas received basis
All results contained in this report relate only to the above listed samples References include 1) EPA 6004-79-020 1983 2) Standard Methods for Examination ofWater and Wastewater lnorganics 19th Edition 1995 Microbiology 20th Edition 1998 3) Test Methods for Evaluating Solid Waste SW 846 3rd Edition Including updates VA and VB 4) Hach Water Analysis Handbook 2nd edition 1992
eastern analytical inc wwweailabscom Phone (603) 228-0525 1
LABORATORY REPORT EAi I 0 108420
Client GZA GeoEnvironmental Inc (NH)
Client Designation MK
Sample ID SWNTF
Lab Sample ID 10842001
Matrix aqueous
Date Sampled 31412
31412Date Received
Solids Suspended 25000 Solids Dissolved 180000 Chloride 75000 BOD 140 COD 900 pH 69
Analysis
Units Date Time Method Analyst
mgL 31912 1345 2540D DLS mgL 31912 1500 2540C DLS mgL 311912 1030 4500CIE DLS mgL 31512 1412 52108 SKC mgL 32012 900 H8000 KJR SU 31412 1705 4500H+B Jl
TDS Due to sample matrix a constant weight of 000059 could not be achieved
eastern analytical inc wwweailabscom Phone (603) 228-0525 2
QC REPORT EAIID 10842011Jul Client GZA GeoEnvironmental Inc (NH)
Client Designation MK
Date of
Parameter Name Blank LCS LCSO Units Analysis Limits RPO Method
Solids Suspended lt5 96 (96 ooR) 100 (100 ooR) (4 RPO) mgL 31912 90 -110 20 2540D
Solids Dissolved lt5 990 (99 R) NA mgL 31912 85 - 115 20 2540C
Chloride lt 1 27 (106 ooR) 26 (106 ooR) (0 RPD) mgL 31912 90 - 110 20 4500CIE
BOD lt6 400 (100 R) 410 (102 R) (2 RPD) mgL 31512 84-115 20 52108
COD lt 10 100 (97 R) 100 (101 R) (4 RPD) mgL 32012 85 -115 20 H8000
pH 60 (100 ooR) 60 (100 ooR) (0 RPD) SU 31412 595 - 607 10 4500H+B
Duplicate Duplicate Date of Parameter Name Parent ID Parent Duplicate Units Analysls RPO Method
Solids Suspended 10850303 200 190 (4RPD) mgL 31912 20 2540D Solids Dissolved 10843101 270 270 (0 RPO) mgL 31912 20 2540C Chloride NA NA mgL 31912 20 4500CIE BOD NA NA mgL 31512 20 52108 COD NA NA mgl 32012 20 H8000 pH 10838601 82 82 (0 RPO) SU 31412 10 4500H+B
Samples were analyzed within holding times unless noted on the sample results page Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits The associated matrix spikes andor Laboratory Control Samples met the above stated criteria Exceptions to the above statements are flagged or noted above or on the QC Narrative page bull11 Flagged analyte recoveries deviated from the QAQC limits
eastern analytical inc wwweailabscom Phone (603) 228-0525 3
Ill
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
G L OS AL S ( I E N lt ES
04 April 2012
JeffGagne
Eastern Analytical Inc
25 Chenell Drive
Concord NH 03301
RE Merrimack Station 2008
Enclosed are the analytical results for samples received by Frontier Global Sciences All quality control
measurements are within established control limits and there were no analytical difficulties encountered
with the exception ofthose listed in the case narrative section of this report
Ifyou have any questions concerning this report please feel free to contact me
Sincerely 44
Liz Siska
Project Manager
4
~ 11720 North Creek Parkway North Suite 400
Bothell WA 9801 1 Ph 425-686-1996 Fx 425-686-3096
GLOBAl SCIENCES
ANALYTICAL REPORT FOR SAMPLES
Laboratory Frontier Global Sciences Inc SDG
Client Eastern Analytical ]nc Project Merrimack Station 2008
Sample ID Lab ID Matrix Date Sampled Date Received
SWWTF 1203203-01 Water 14-Mar-12 1305 16-Mar-12 0940
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Pagel o20 1203203 Final Report-SWWTF REV2
041042012
Liz Siska Project Manager 5
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
CASE NARRATIVE
Revised Report 4412- Sample name corrected to SWWTF
SAMPLE RECEIPT
Samples were received at Frontier Global Sciences (FGS) on March 16th 2012 The samples were received intact on-ice with temperatures measuredat 22 degrees Celsius
SAMPLE PREPARATION AND ANALYSIS
Samples were prepared and analyzed for total metals in accordance with EPA Method 2008 (modified)
Samples were prepared and analyzed for total mercury in accordance with EPA Method 163 JE
ANALYTICAL ISSUES
The client requested sample SWWTF (1203203-0 l) be analyzed for Mn via email on 31512
Samples were received in a cooler ofmelted ice There was water in the inner most bag of sample Evaporator (1203203-02)
As an additional measure ofthe accuracy ofthe methods utilized for analysis and to check for matrix interference matrix spikes (MS) and matrix spike duplicates (MSD) were digested and analyzed All ofthe matrix spike recoveries were within the control limits with the exception ofany QC flagged and described in the notes and definitions section ofthe following report
A reasonable measure ofthe precision ofthe analytical methods utilized for analysis is the relative percent difference (RPD) between matrix spike and matrix spike duplicate recoveries and between laboratory control sample and laboratory control sample duplicate recoveries All of the relative percent differences were within the control limits with the exception ofany QC flagged and described in the notes and definitions section ofthe following report
Frontier Global Sciences Inc The results in this report 011y apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 2 of20 1203203 Final Report- SWWTF REV2
04042012
Liz Siska Project Manager 6
FRONTIER
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIE NCES
CHAIN OF CUSTODY FORMS
bullbull _ ~ -bull uer ( A c 2 - gt Sampre Recefpt CHockJlst
Data Looobulld tn ~tZfrPkttr ~~middot0 middot1)d bull MSi~~gtamp Loss bull d I n Sy
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The results in this report only apply to the samples analy-ed in accordance with the Frontier Global Sciences Inc chain ofcustody docutMnt This aMlytical report must be reprodu~d in its e111irety
Page3of20 1203203 Final Rtport- SWWTFREV2
04042012
Liz Siska Project Manager 7
l l 720 North Creek Parkway Nortn u1Le -tvv Bothell WA 9amp011
Ph 425-686-1996 Fx 425-686-3096
FRONTIER GLOBAL SCIENCES
CHAIN OF CUSTODY FORMS
The results in this report only apply to the samples analyzed in accordance with the cliain ofcustody documenL This analytical report must be reproduced in its entirety
Frontier Global Sciences Inc Page 4 o20 1203203 Final Report- SWWTF REV2
04042012
Liz Siska Project Manager
8
11720 North Creek Parkway North Suite 40U Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
FRONTIER C L 0 B AL SC I~ NC ES
CHAlN OF CUSTODY FORMS
i---t--+-l-+-+-+--+--+--+--+_micro~[_amp~lslte---l t---t--+--11-(- -1--+-~-+--l---l---+----------f_ rmiddot 1---+--~--l--f-+---l--l--l-+--I--I---- _____--1 lt 1--1--1--+--l--------4-+-+--l--+-+--____f_ i--t--+--1r-+-+-+-t-+-++-4-________ _j bull-
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The results In this report onlyapply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reprodu~din its entirety
Frontier Global Sciences Inc Page 5 o20 T203203 Final Report-SWWTFREV2
ommo12
Liz SiskaProject Manager
9
)--J middot ~~
)J fl~~J~c1N~r
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
Matrix Water Laboratory ID 1203203-01
ANALYTICAL RESULTS
SWWTF
Analyte Result lIDL MRL Units Dilution Batch Sequence Analyzed Method Notes
Aluminum 371 220 198 microgL 5 F203232 2C2000l 031912 EPA 2008 Mod
Arsenic 377 252 743 microgL 5 F203232 2C2000l 031912 EPA 2008 Mod
Cadmium 248 0205 0990 microgL 5 F203232 2C20001 031912 EPA2008 Mod
Chromium 532 045 495 microgL 5 F203232 2C20001 031912 EPA 2008 Mod
Copper 182 050 495 microgL 5 F203232 2C20001 031912 EPA 2008 Mod
Iron 1100 644 495 microgL 5 F203232 2C20001 031912 EPA 2008 Mod
Lead ND 0193 198 microgL 5 F203232 2C2000l 031912 EPA 2008 Mod u Manganese 7180 037 495 microgL 5 F203232 2C2000l 031912 EPA 2008 Mod
Mercury 612 842 505 ngL 100 F203288 2C22016 032212 EPA l631E FB-1631
Molybdenum 2000 297 297 microgL 50 F203260 2C22001 032112 EPA 2008 Mod
Nickel 303 040 495 microgL 5 F203232 2C20001 031912 EPA 2008 Mod
Selenium 587 959 297 microgL 5 F203232 2C20001 031912 EPA 2008 Mod
Silver ND 0297 0990 microgL 5 F203232 2C20001 031912 EPA 2008 Mod u Zinc 775 081 990 microgL 5 F203232 2C20001 031912 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report 011ly apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page6 o20 I203203 Final Report- SWWTF REV2
04042012
Liz Siska Project Manager 10
gt
C LO BA L S CI E N C ES
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
MATRIX DUPLICATESTRIPLICATES
SOURCE 1203203-01
Batch F203288
Preparation BrCl Oxidation
Sequence 2C22016
Lab Number F203288-DUPI
Sample Duplicate Concentration Concentration RPD
Analyte DgL ngL
5848
MRL 505
RPD 448
Limit
24
Method
EPA 163IE
Notes
Mercury 6116
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced In its entirety
Page 7of20 l 103203 Final Report- SWWTF REV2
04042012 bull 1 1 Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996
FROlJTIER Fx 425-686-3096 GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203203-01
Batch F203232 Sequence 2C20001
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203232-MSMSD 1
Sample Spike MS MS Concentration Added Concentration 0o Recovery
Analyte (microgL) (microgL) (microgL) Recovery Method NotesLimits
Alumimun 3707 15152 1853 978 70 - 130 EPA 2008 Mod
Chromium 5316 70707 1270 104 70- 130 EPA 2008 Mod
Manganese 7181 60606 7231 821 70 - 130 EPA 2008 Mod
Iron 1098 50505 6090 988 70- 130 EPA 2008 Mod
Nickel 3025 40404 3425 988 70 - 130 EPA 2008 Mod
Copper 1816 40404 5182 833 70 - 130 EPA2008 Mod
Arsenic 3770 15152 1904 101 70- 130 EPA 2008 Mod
Seleniwn 587l 30303 9297 113 70 - 130 EPA 2008 Mod
Silver ND 15152 1099 725 70 - 130 EPA 2008 Mod
Cadmillll) 2484 80808 9508 869 70 - 130 EPA 2008 Mod
Lead 0763 15152 1544 968 70-130 EPA2008Mod
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD
Recovery
Oo
RPD Recovery
Limits RPOLimit Method Notes
Aluminum 15152 1826 96l 145 70 shy 130 20 EPA 2008 Mod
Chromium 70707 1288 107 138 70-130 20 EPA 2008 Mod
Manganese 60606 7230 804 00140 70- 130 20 EPA 2008 Mod
Iron 50505 6065 983 0414 70- 130 20 EPA 2008 Mod
Nickel 40404 3378 872 138 70 - 130 20 EPA2008 Mod
Copper 40404 5140 823 0807 70 - 130 20 EPA 2008 Mod
Arsenic 15152 1928 102 123 70 - 130 20 EPA 2008 Mod
Selenium 30303 9063 105 255 70- 130 20 EPA 2008 Mod
Silver 15152 1075 709 219 70- 130 20 EPA 2008 Mod
Cadmium 80808 9347 849 170 70- 130 20 EPA 2008 Mod
Lead 15152 1531 960 0815 70- 130 20 EPA 2008 Mod
Frontier Global Sciences Inc The results In this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
PageBo20 1203203 FinalReport- SWWTFREV2
04042012
Liz Siska Project Manager 12
iii
11720 North Creek Parkway North Suite 400
Bothell WA 98011 Ph 425-686-1996 Fx 425-686-3096 GlOBAL SCIENCES
ij
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203203-01
Batch F203232 Sequence 2Q20001
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203232-MSMSD3
Analyte
Sample Concentration
(microgL)
Spike Added (pgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Limits Method Notes
Aluminum 3707 10000 10270 990 70 - 130 EPA 2008 Mod AS
Chromium 5316 10000 1137 108 70 - 130 EPA 2008 Mod AS Manganese 7181 10000 8207 103 70 - 130 EPA 2008 Mod AS
Iron 1098 50000 6185 102 70 - 130 EPA 2008 Mod AS Nickel 3025 12500 1433 905 70 - 130 EPA 2008 Mod AS Copper 1816 12500 1061 834 70 - 130 EPA 2008 Mod AS Zinc 7752 25000 1995 767 70 - 130 EPA 2008 Mod AS Arsenic 3770 10000 1073 104 70 - 130 EPA 2008 Mod AS Selenium 587l 10000 1530 943 70 - 130 EPA 2008 Mod AS Silver ND 50000 3690 738 70 - 130 EPA 2008 Mod AS Cadmium 2484 10000 8531 828 70 - 130 EPA 2008 Mod AS Lead 0763 25000 2505 999 70 - 130 EPA 2008 Mod AS
middoti
i
Aoalyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD o
Recovery
RPD Recovery
Limits RPDLimit Method Notes
Aluminum 10000 10150 978 121 70 - 130 20 EPA 2008 Mod AS Chromium 10000 1140 109 0293 70 - 130 20 EPA 2008 Mod AS Manganese 10000 8278 llO 0854 70 -130 20 EPA 2008 Mod AS Iron 50000 6243 103 0937 70-130 20 EPA 2008 Mod AS Nickel 12500 1441 91l middotos25 70 - 130 20 EPA 2008 Mod AS Copper 12500 1066 838 0496 70- 130 20 EPA 2008 Mod AS Zinc 25000 1990 765 0245 70- 130 20 EPA 2008 Mod AS Arsenic 10000 1094 106 193 70 - 130 20 EPA 2008 Mod AS Selenium 10000 1554 967 155 70 - 130 20 EPA 2008 Mod AS Silver 50000 3682 736 0222 70 - 130 20 EPA 2008 Mod AS Cadmium 10000 8394 815 l62 70 - 130 20 EPA 2008 Mod AS Lead 25000 250S 999 00263 70- 130 20 EPA 2008 Mod AS
~~ middotmiddot1 bull
bulli
bullmiddot
Frontier Global Sciences Inc The remits in this report only apply lo the samples analyzed in accordance with the chain ofcustody document This analytical report must bt reproductd In Its entirety
Page 9of20 1203203 Final Report-SWWTF REY2
04M2012
Liz Siska Project Manager 13
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 FRONTIER~ Fx 425-686-3096 GLOBAL SCIENCES
MATR1X SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203203-01RE3
Batch F203260 Sequence 2C22001
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203260-MSMSD3
Analyte
Sample Concentration
(microgL)
Spike Added (microgL)
MS Conctntration
(microgL)
MS
Recovery Recovery
Method Limits Notes
Molybdenum 1999 20200 middot 2041 206 70 - 130 EPA 2008 Mod QM-02
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD Oo
Recovery
RPD
Recovery Limits
RPO Limit Method Notes
Molybdenum 20200 2041 207 00141 70 - 130 20 EPA 2008 Mod QM-02
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed In accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page Oo20 1203203 Final Report- SWWTFREV2
04042012
Liz Siska Project Manager 14
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyzed in accordance with the chain ofcustody document This analytical report =tbe reproducedin Its entirety
Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
CLO~AL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1203203-0lREJ
Batch F203260
Preparation Closed Vessel Nitric Oven Digestion
Sequence 2C2200
Lab Number F203260-MSMSD6
Sample Spike MS MS
Analyte Concentration Added
(JtgL) (microgL) Concentration
(microgL)
Recovery Recovery
Method Limits Notes
Molybdenum 1999 50000 7034 101 70 - 130 EPA 2008 Mod AS
Spike MSD Added Concentration
MSD Recovery RPD
Analyte (microgL) (microgL) Recovery RPD Limits Limit Method Notes
Molybdenum 50000 7124 102 128 70 - 130 20 EPA 2008 Mod AS
Page 11 o20 1203203 Final Report- SWWTF REJ2
040412012
15
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 ~ Fx 425-686-3096 GLOBAL SCIENCES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203203-01
Batch F203288
Preparation BrCI Oxidation
Sequence 2C22016
Lab Number F203288-MSMSD 1
Sample Spike MS MS Concentration Added Concentration Recovery
Analyte (ngL) (ogL) (ogL) Recovery Method Notes Limits
Mercury 6116 25500 3096 974 71 - 125 EPA 1631E
Spike MSD MSD Oo Recovery RPD Added Concentration Oo
Limits Method Notes (ogL) (ogL) Recovery RPD Limit Analyte
Mercury 25500 2611 784 170 71 - 125 24 EPA 1631E
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed i11 accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 12of20 1203203 Final Report- SWWTF REV2
04042012
Liz Siska Project Manager 16
bull 11720 North Creek Parkway North Suite 400
Bothell WA 98011 Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1203194-17
Batch F203288 Sequence 2C22016
Preparation BrCI Oxidation Lab Number F203288-MSMSD2
Sample Spike MS MS
Analyte Concentration
(ngL) Added (ngL)
Concentration (ngL) Recovery
Recovery Limits Method Notes
Mercury 142800 505000 627200 959 71 - 125 EPA 1631E
Spike Added
MSD Concentration
MSD Recovery RPO
Analyte (ngL) (ngL) Recovery RPD Limits Limit Method Notes
Mercury 505000 632700 970 0879 71 - 125 24 EPA 1631E
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody docu~nt This analytical report must be reproduced In its entirety
Page 13of20 1203203 Final Report- SWWTFREV2
04042012
Liz Siska Project Manager 17
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996
bull ~ Fx 425-686-3096 GLPBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203232 Sequence 2C20001
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203232-BSBSD1
LCS Source mank Siiike
Spike LCS LCS Added Concentration Recovery
Analyte (microgL) (microgL) Recovery Limits Method Notes
Aluminwn 15000 1444 963 85-115 EPA2008Mod Chromium 70000 654 934 85 bull 115 EPA 2008 Mod Manganese 60000 580 967 85 - 115 EPA 2008 Mod Iron 50000 4610 922 85 - 115 EPA 2008 Mod Nickel 40000 394 985 85 ll5 EPA 2008 Mod Copper 40000 418 104 85 - 115 EPA 2008 Mod Zinc 10000 1017 102 85 bull 115 EPA 2008 Mod Arsenic 15000 1445 963 85 bull 115 EPA 2008 Mod Selenium 30000 2975 992 85-115 EPA2008Mod Molybdenum 20000 185 926 85 bull 115 EPA 2008 Mod Silver 15000 1555 104 85 - 115 EPA 2008 Mod
Cadmium 080000 0802 100 85 - 115 EPA 2008 Mod Lead 15000 1565 104 85 - 115 EPA 2008 Mod
shy
Spike LCSD LCSD Added Concentration Oo Recovery RPD
Analyte (microgL)
15000
(microgL)
1424
Recovery
949
RPD
140
Limits
85 bull 115
Limit
20
Method
EPA 2008 Mod
Notes
Aluminum
Chromium 70000 644 920 l58 85 bull 115 20 EPA 2008 Mod
Manganese 60000 575 958 0920 85 - ll5 20 EPA 2008 Mod
Iron 50000 4580 916 0660 85 - 115 20 EPA 2008 Mod
Nickel 40000 394 985 000457 85 bull 115 20 EPA 2008 Mod
Copper 40000 416 104 0367 85 - 115 20 EPA 2008 Mod
Zinc 10000 1032 103 147 85 - ll5 20 EPA 2008 Mod
Arsenic 15000 1440 960 0305 85 bull 115 20 EPA 2008 Mod
Selenium 30000 2867 956 369 85 -115 20 EPA 2008 Mod
Molybdenum 20000 l86 928 0196 85 -115 20 EPA2008 Mod
Silver l5000 1559 104 0233 85 bull 115 20 EPA 2008 Mod
Cadmium 080000 0809 101 0843 85 bull llS 20 EPA 2008 Mod
Lead 15000 l539 103 170 85 - 115 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed In accordance with the chain ofcustody document This analytical report must be reproduced in its enJirety
Page 14of20 1203203 Final Report- SWWTFREV2
04042012 ~~
Liz Siska Project Manager 18
11720 North Creek Parkway North Suite 400 Bothell WA 98011 Ph 425-686-1996
FRONTIER Fx 425-686-3096 GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203260 Sequence 2C22001
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203260-BSBSD1
LCS Source Blank Spike
Spike LCS LC$ Added Concentration Recovery
Analyte (ptgL) (JJgL) Recovery Limits Method Notes
Molybdenum 20000 182 910 85 - 115 EPA 2008 Mod
Spike LCSD LCSD Added Concentration Recovery RPD
Analyte (microgL) (microgL) Recovery RPD Limits Limit Method Notes
Molybdenum 20000 186 930 213 85 -115 20 EPA 2008 Mod
Frontier Global Sciences Inc The results In this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced In its entirety
Page 15 o20 I203203 Ftnal ampport- SWWTFREV2
04041202
Liz Siska Project Manager 19
middot
I
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SC IE NC ES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPO
Batch F203288 Sequence 2C22016
Preparation BrCI Oxidation Lab Number F203288-BSBSD I
LCS Source NIST 1641d
Spike LCS LCS Added Concentration Recovery
Analyte (ngL) (ngL) Recovery Limits Method Notes
Mercury 15679 1525 973 80 - 120 EPA l631E
Spike LCSD LCSD Added Concentration Oo Recovery RPD
Analyte (ngL) (ngL)
1516
Recovery
967
RPD
0622
Limits
80 - 120
Limit
24
Method
EPA 1631E
Notes
Mercury 15679
Frontier Global Sciences Inc The results in this report only apply lo the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 16 o20 1203203 Final Report- SWWIFREV2
041042012
20Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 middot Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096 ~ O GLO B AL SCI E NCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2C20001
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203232-BLK1 Aluminum 01 40 microgL F203232 PA2008 Molt u F203232-BLK1 Chromium -0007 0 10 microgL F203232 PA 2008 Molt u F203232-BLKI Manganese 0002 010 microgL F203232 PA 2008 Moc u F203232-BLK1 Iron -004 100 microgL F203232 PA 2008 Molt u F203232-BLKI Nickel 0005 010 microgL F203232 PA 2008 Moc u F203232-BLKI Copper 001 010 microgL F203232 PA 2008 Molt u F203232-BLK1 Zinc 011 020 microgL F203232 PA 2008 Moc u F203232-BLK I Arsenic -0009 015 microgL F203232 PA 2008 Moc u F203232-BLK1 Selenium 025 060 microgL F203232 PA 2008 Moc u F203232-BLK1 Molybdenum 001 006 microgL F203232 PA 2008 Moc u F203232-BLK1 Silver -00009 0020 microgL F203232 PA 2008 Moc u F203232-BLK1 Cadmium 0002 0020 microgL F203232 PA 2008 Molt u F203232-BLK1 Lead 0024 0040 microgL F203232 PA 2008 Molt u
middoti
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordonce with the chain ofcustody document Tnts analytical rtport must be reproduced In its enlfrtty
Page7of20 J203203 Final ampport-SWWTF REV2
04042012
Liz Siska Project Manager 21
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 FRONTIER~ Fx 425-686-3096 GLOBAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2C22001
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203260-BLK1 Molybdenum 001 006 microgL F203260 ~PA 2008 Moc u
Frontier Global Sciences Inc middot The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 18of20 1203203 Final Report- SWWTFREV2
04042012
Liz Siska Project Manager 22
~ CLOSAL SCIENCES
~
J1720 North Creek Parkway North Suite 400 Bothell WA 980 l l
Ph 425-686-1996 Fx 425-686-3096
PREPARATION BLANKS
Instrument Hg-17 Sequence 2C22016
Preparation BrCI Oxidation
The results in Ihis report only apply to the samples analyzed i12 accordance with the chain ofcustody dccumnt This analytical report must be reproductd in ils enJirety
Page I9oj20 1203203 Final Report- SWWTF REJ2
04042012
Frontier Global Sciences Inc
bull 23bull Liz Siska Project Manager
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203288-BLKl Mercury 007 050 ngL F203288 EPA 1631E u F203288-BLIlt2 Mercury 006 050 ngL F203288 EPA 163lE u F203288-BLK3 Mercury 006 050 ngL F203288 EPA I63lE u F203288-BLK4 Mercury 018 050 ngL F203288 EPA I63IE U QB-04
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
Notes and Definitions
U Analyte included in the analysis but not detected
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than I times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable ASASD
QB-04 The blank was preserved to 2 BrCl rather than I The control limit for blanks presetved to greater than 1 BrCl is the preservation percentage multiplied by the l1RL
FB-1631 Required equipmentfieldfilter blank not submitted by the client The sample has been analyzed according to 163 lE but does not meet 163 lE criteria
AS This MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
l1RL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to lhe samples analyzedin accordance wirh the chain ofcustody document This analytical report must be reproduced in its entirety
Page 20of20 1203203 Final Report- SWWTF REV2
04042012
24
bull bull
irGl Lu Ull 0111C H AIN-OF-CUSTODY RECORD Page of_~~
Bolo FIELDS REQUIRED P LEASE CIRCLE REQUESTED ANALYs1s Lt) CN voe I svoc TClPI M ETALS INORGANICS
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1
DATE NEEDED b171i1-1~ 1 f METALS 8 RCRA 13 PP FE MN Ps CUPROJECT MANAGER 0v f-e_~ Tmamp- middotc COMPANY pdegZ1)shy 0THE1 METALS __________REPORTING OPTIONSQAQC ICH) NoAonms Jfru lli V =1 Q ) REPORTING LEVEL PUUHS ~OR No
A B C 0lOLYpoundD METALS FIELD flLTtREDI YE NoIF YE F~ oa(ITT STAil~l4t(= ~ ZIP rriu1 NOTES (IE SPEOAl DETECTION LIHIIS BIWNG INFO IF D1mam)PHONE _r~ _z31_ - $ I3 Exr--- OR ELECTRONIC OPTIONSFAX _ __________________ AI l A C J C bull C1
J pbNo FAX E-MAIL PDF EQUIS
E-MAIL tivl el qu ~ pv CvVshyf J --~b Mo ~ tJ k ttJ -z~Sm NAHE W
PROJECT ____________ ___ ___ _ ~111216- aJd M fer P4 jgtZJ)shy
SUTt MA ME VT OTHER _____ ___ ~ 1)--U ( u-middotmiddottut-UJ f bull
REGULATORY PROGRAM NPDES RGP POnY STOilKWATER Ol SITE HISTORY ~i tiT f=
GWP OIL FUND BROWNFJUD OR Orm--------shy RELINQUISHED BY DATE TIME RECEIVED Br Summo (ONTAHINATIOM_______
PO_______QUOTE===-~----shy I RELINQUISHED BY DATE TIME Rmmo BT I FIElllJUDINGStt HI l lS 2
eastern analytical inc 2s CHENELl DR1ve I CoNcoRo NH 03301 I TEL 60322sos2s I 1soo2s7os2s IFAXc 6032284591 I E-MA1l cusToMER_seRv1ceEA1LAascoHj wwweA1lAsscoM
prufmin111ll11bomtory1m1im (WHITE ORIGINAL GREEN PROJECT MANAGER)
shy
shy
~--fLAA____________e_a_s_t_e_r_n_a_n_a_ly_t_i_c_a_l__
Paul Pepler
GZA GeoEnvironmental Inc (NH)
380 Harvey Road
Manchester NH 03103
Subject Laboratory Report
Eastern Analytical Inc ID 108420
Client Identification MK
Date Received 3142012
Dear Mr Pepler
Enclosed please find the laboratory report for the above identified project All analyses were performed in accordance with our QAQC Program Unless otherwise stated holding times preservation techniques container types and sample conditions adhered to EPA Protocol Samples which were collected by Eastern Analytical Inc (EAi) were collected in accordance with approved EPA procedures Eastern Analytical Inc certifies that the enclosed test results meet all requirements of NELAP and other applicable state certifications Please refer to our website at wwweailabscom for a copy ofour NELAP certificate and accredited parameters
The following standard abbreviations and conventions apply to all EAi reports Solid samples are reported on a dry weight basis unless otherwise noted lt less than followed by the reporting limit gt greater than followed by the reporting limit R Recovery
Eastern Analytical Inc maintains certification in the following states Connecticut (PH-0492) Maine (NH005) Massachusetts (M-NH005) New HampshireNELAP (1012) Rhode Island (269) and Vermont (VT1012)
The following information is contained within this report Sample Conditions summary Analytical ResultsData Quality Control data (if requested) and copies of the Chain of Custody This report may not be reproduced except in full without the the written approval of the laboratory
If you have any questions regarding the results contained within please feel free to directly contact me or the chemist(s) who performed the testing in question Unless otherwise requested we will dispose of the sample(s) 30 days from the sample receipt date
We appreciate this opportunity to be of service and look forward to your continued patronage
Sincerely
11micro3= Date
JS of pages (excluding cover letter)
11middot1111Llibb ~(( 1111
SAMPLE CONDITIONS PAGE EAi ID 108420
Client middot GZA GeoEnvironmental Inc (NH)
Client Designation MK
Temperature upon receipt (degC) 184 Received on ice or cold packs (YesNo) y Acceptable temperature range (degC) 0-6
Date Date Sample Dry Lab ID Sample ID Received Sampled Matrix Weight ExceptionsComments (other than thermal preservation)
10842001 SWWTF 31412 31412 aqueous Adheres to Sample Acceptance Policy
Samples were properly preserved and the pH measured when applicable unless otherwise noted Analysis ofsolids for pH Flashpoint lgnitibility Paint Filter Corrosivity Conductivity and Specific Gravity are reported on an middotas received basis
All results contained in this report relate only to the above listed samples References include 1) EPA 6004-79-020 1983 2) Standard Methods for Examination ofWater and Wastewater lnorganics 19th Edition 1995 Microbiology 20th Edition 1998 3) Test Methods for Evaluating Solid Waste SW 846 3rd Edition Including updates VA and VB 4) Hach Water Analysis Handbook 2nd edition 1992
eastern analytical inc wwweailabscom Phone (603) 228-0525 1
LABORATORY REPORT EAi I 0 108420
Client GZA GeoEnvironmental Inc (NH)
Client Designation MK
Sample ID SWNTF
Lab Sample ID 10842001
Matrix aqueous
Date Sampled 31412
31412Date Received
Solids Suspended 25000 Solids Dissolved 180000 Chloride 75000 BOD 140 COD 900 pH 69
Analysis
Units Date Time Method Analyst
mgL 31912 1345 2540D DLS mgL 31912 1500 2540C DLS mgL 311912 1030 4500CIE DLS mgL 31512 1412 52108 SKC mgL 32012 900 H8000 KJR SU 31412 1705 4500H+B Jl
TDS Due to sample matrix a constant weight of 000059 could not be achieved
eastern analytical inc wwweailabscom Phone (603) 228-0525 2
QC REPORT EAIID 10842011Jul Client GZA GeoEnvironmental Inc (NH)
Client Designation MK
Date of
Parameter Name Blank LCS LCSO Units Analysis Limits RPO Method
Solids Suspended lt5 96 (96 ooR) 100 (100 ooR) (4 RPO) mgL 31912 90 -110 20 2540D
Solids Dissolved lt5 990 (99 R) NA mgL 31912 85 - 115 20 2540C
Chloride lt 1 27 (106 ooR) 26 (106 ooR) (0 RPD) mgL 31912 90 - 110 20 4500CIE
BOD lt6 400 (100 R) 410 (102 R) (2 RPD) mgL 31512 84-115 20 52108
COD lt 10 100 (97 R) 100 (101 R) (4 RPD) mgL 32012 85 -115 20 H8000
pH 60 (100 ooR) 60 (100 ooR) (0 RPD) SU 31412 595 - 607 10 4500H+B
Duplicate Duplicate Date of Parameter Name Parent ID Parent Duplicate Units Analysls RPO Method
Solids Suspended 10850303 200 190 (4RPD) mgL 31912 20 2540D Solids Dissolved 10843101 270 270 (0 RPO) mgL 31912 20 2540C Chloride NA NA mgL 31912 20 4500CIE BOD NA NA mgL 31512 20 52108 COD NA NA mgl 32012 20 H8000 pH 10838601 82 82 (0 RPO) SU 31412 10 4500H+B
Samples were analyzed within holding times unless noted on the sample results page Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits The associated matrix spikes andor Laboratory Control Samples met the above stated criteria Exceptions to the above statements are flagged or noted above or on the QC Narrative page bull11 Flagged analyte recoveries deviated from the QAQC limits
eastern analytical inc wwweailabscom Phone (603) 228-0525 3
Ill
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
G L OS AL S ( I E N lt ES
04 April 2012
JeffGagne
Eastern Analytical Inc
25 Chenell Drive
Concord NH 03301
RE Merrimack Station 2008
Enclosed are the analytical results for samples received by Frontier Global Sciences All quality control
measurements are within established control limits and there were no analytical difficulties encountered
with the exception ofthose listed in the case narrative section of this report
Ifyou have any questions concerning this report please feel free to contact me
Sincerely 44
Liz Siska
Project Manager
4
~ 11720 North Creek Parkway North Suite 400
Bothell WA 9801 1 Ph 425-686-1996 Fx 425-686-3096
GLOBAl SCIENCES
ANALYTICAL REPORT FOR SAMPLES
Laboratory Frontier Global Sciences Inc SDG
Client Eastern Analytical ]nc Project Merrimack Station 2008
Sample ID Lab ID Matrix Date Sampled Date Received
SWWTF 1203203-01 Water 14-Mar-12 1305 16-Mar-12 0940
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Pagel o20 1203203 Final Report-SWWTF REV2
041042012
Liz Siska Project Manager 5
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
CASE NARRATIVE
Revised Report 4412- Sample name corrected to SWWTF
SAMPLE RECEIPT
Samples were received at Frontier Global Sciences (FGS) on March 16th 2012 The samples were received intact on-ice with temperatures measuredat 22 degrees Celsius
SAMPLE PREPARATION AND ANALYSIS
Samples were prepared and analyzed for total metals in accordance with EPA Method 2008 (modified)
Samples were prepared and analyzed for total mercury in accordance with EPA Method 163 JE
ANALYTICAL ISSUES
The client requested sample SWWTF (1203203-0 l) be analyzed for Mn via email on 31512
Samples were received in a cooler ofmelted ice There was water in the inner most bag of sample Evaporator (1203203-02)
As an additional measure ofthe accuracy ofthe methods utilized for analysis and to check for matrix interference matrix spikes (MS) and matrix spike duplicates (MSD) were digested and analyzed All ofthe matrix spike recoveries were within the control limits with the exception ofany QC flagged and described in the notes and definitions section ofthe following report
A reasonable measure ofthe precision ofthe analytical methods utilized for analysis is the relative percent difference (RPD) between matrix spike and matrix spike duplicate recoveries and between laboratory control sample and laboratory control sample duplicate recoveries All of the relative percent differences were within the control limits with the exception ofany QC flagged and described in the notes and definitions section ofthe following report
Frontier Global Sciences Inc The results in this report 011y apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 2 of20 1203203 Final Report- SWWTF REV2
04042012
Liz Siska Project Manager 6
FRONTIER
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIE NCES
CHAIN OF CUSTODY FORMS
bullbull _ ~ -bull uer ( A c 2 - gt Sampre Recefpt CHockJlst
Data Looobulld tn ~tZfrPkttr ~~middot0 middot1)d bull MSi~~gtamp Loss bull d I n Sy
SOG o f Coolns- R~oetvbullG I ( FGSPM
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rT~hbull_ornebullur_10~gt~(~5z2~_--CorrftCtfan rbullclOf (Cfl) ~lt2 - 3 degre-bull O eoolbullr- 1 L ~ middoto CoCttbullr a bullc eoolbullr-2 middot c Cootbullr7 middotc
middot c Cooler a bullc middot c
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Chbullln orCutody COO $ pria1-ct-n bullnd lneludee thbull folto~ng Information for obulloh ~~mple
NA Comrnbullnta
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middot------------ shy ---ilnt-nat chaln or custOdv irv1d
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---l shy ---+--~-shy ----+-----------1
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lteon-eet aamIbull oontarners U ~ltftd fcrr reauect1Dd 0rnafv8ebull sbullm-reraquo roCHtlvOd In holdrna tlmomiddot bullbullrn- bull vohnlIbull auMolen ~~r raubullbulltbulld anaalvbull a
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Mbulltnod ____ _
Olbull~bullronJRbullbullo1utlon
The results in this report only apply to the samples analy-ed in accordance with the Frontier Global Sciences Inc chain ofcustody docutMnt This aMlytical report must be reprodu~d in its e111irety
Page3of20 1203203 Final Rtport- SWWTFREV2
04042012
Liz Siska Project Manager 7
l l 720 North Creek Parkway Nortn u1Le -tvv Bothell WA 9amp011
Ph 425-686-1996 Fx 425-686-3096
FRONTIER GLOBAL SCIENCES
CHAIN OF CUSTODY FORMS
The results in this report only apply to the samples analyzed in accordance with the cliain ofcustody documenL This analytical report must be reproduced in its entirety
Frontier Global Sciences Inc Page 4 o20 1203203 Final Report- SWWTF REV2
04042012
Liz Siska Project Manager
8
11720 North Creek Parkway North Suite 40U Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
FRONTIER C L 0 B AL SC I~ NC ES
CHAlN OF CUSTODY FORMS
i---t--+-l-+-+-+--+--+--+--+_micro~[_amp~lslte---l t---t--+--11-(- -1--+-~-+--l---l---+----------f_ rmiddot 1---+--~--l--f-+---l--l--l-+--I--I---- _____--1 lt 1--1--1--+--l--------4-+-+--l--+-+--____f_ i--t--+--1r-+-+-+-t-+-++-4-________ _j bull-
CN _r(gt --shyshy~
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The results In this report onlyapply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reprodu~din its entirety
Frontier Global Sciences Inc Page 5 o20 T203203 Final Report-SWWTFREV2
ommo12
Liz SiskaProject Manager
9
)--J middot ~~
)J fl~~J~c1N~r
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
Matrix Water Laboratory ID 1203203-01
ANALYTICAL RESULTS
SWWTF
Analyte Result lIDL MRL Units Dilution Batch Sequence Analyzed Method Notes
Aluminum 371 220 198 microgL 5 F203232 2C2000l 031912 EPA 2008 Mod
Arsenic 377 252 743 microgL 5 F203232 2C2000l 031912 EPA 2008 Mod
Cadmium 248 0205 0990 microgL 5 F203232 2C20001 031912 EPA2008 Mod
Chromium 532 045 495 microgL 5 F203232 2C20001 031912 EPA 2008 Mod
Copper 182 050 495 microgL 5 F203232 2C20001 031912 EPA 2008 Mod
Iron 1100 644 495 microgL 5 F203232 2C20001 031912 EPA 2008 Mod
Lead ND 0193 198 microgL 5 F203232 2C2000l 031912 EPA 2008 Mod u Manganese 7180 037 495 microgL 5 F203232 2C2000l 031912 EPA 2008 Mod
Mercury 612 842 505 ngL 100 F203288 2C22016 032212 EPA l631E FB-1631
Molybdenum 2000 297 297 microgL 50 F203260 2C22001 032112 EPA 2008 Mod
Nickel 303 040 495 microgL 5 F203232 2C20001 031912 EPA 2008 Mod
Selenium 587 959 297 microgL 5 F203232 2C20001 031912 EPA 2008 Mod
Silver ND 0297 0990 microgL 5 F203232 2C20001 031912 EPA 2008 Mod u Zinc 775 081 990 microgL 5 F203232 2C20001 031912 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report 011ly apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page6 o20 I203203 Final Report- SWWTF REV2
04042012
Liz Siska Project Manager 10
gt
C LO BA L S CI E N C ES
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
MATRIX DUPLICATESTRIPLICATES
SOURCE 1203203-01
Batch F203288
Preparation BrCl Oxidation
Sequence 2C22016
Lab Number F203288-DUPI
Sample Duplicate Concentration Concentration RPD
Analyte DgL ngL
5848
MRL 505
RPD 448
Limit
24
Method
EPA 163IE
Notes
Mercury 6116
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced In its entirety
Page 7of20 l 103203 Final Report- SWWTF REV2
04042012 bull 1 1 Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996
FROlJTIER Fx 425-686-3096 GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203203-01
Batch F203232 Sequence 2C20001
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203232-MSMSD 1
Sample Spike MS MS Concentration Added Concentration 0o Recovery
Analyte (microgL) (microgL) (microgL) Recovery Method NotesLimits
Alumimun 3707 15152 1853 978 70 - 130 EPA 2008 Mod
Chromium 5316 70707 1270 104 70- 130 EPA 2008 Mod
Manganese 7181 60606 7231 821 70 - 130 EPA 2008 Mod
Iron 1098 50505 6090 988 70- 130 EPA 2008 Mod
Nickel 3025 40404 3425 988 70 - 130 EPA 2008 Mod
Copper 1816 40404 5182 833 70 - 130 EPA2008 Mod
Arsenic 3770 15152 1904 101 70- 130 EPA 2008 Mod
Seleniwn 587l 30303 9297 113 70 - 130 EPA 2008 Mod
Silver ND 15152 1099 725 70 - 130 EPA 2008 Mod
Cadmillll) 2484 80808 9508 869 70 - 130 EPA 2008 Mod
Lead 0763 15152 1544 968 70-130 EPA2008Mod
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD
Recovery
Oo
RPD Recovery
Limits RPOLimit Method Notes
Aluminum 15152 1826 96l 145 70 shy 130 20 EPA 2008 Mod
Chromium 70707 1288 107 138 70-130 20 EPA 2008 Mod
Manganese 60606 7230 804 00140 70- 130 20 EPA 2008 Mod
Iron 50505 6065 983 0414 70- 130 20 EPA 2008 Mod
Nickel 40404 3378 872 138 70 - 130 20 EPA2008 Mod
Copper 40404 5140 823 0807 70 - 130 20 EPA 2008 Mod
Arsenic 15152 1928 102 123 70 - 130 20 EPA 2008 Mod
Selenium 30303 9063 105 255 70- 130 20 EPA 2008 Mod
Silver 15152 1075 709 219 70- 130 20 EPA 2008 Mod
Cadmium 80808 9347 849 170 70- 130 20 EPA 2008 Mod
Lead 15152 1531 960 0815 70- 130 20 EPA 2008 Mod
Frontier Global Sciences Inc The results In this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
PageBo20 1203203 FinalReport- SWWTFREV2
04042012
Liz Siska Project Manager 12
iii
11720 North Creek Parkway North Suite 400
Bothell WA 98011 Ph 425-686-1996 Fx 425-686-3096 GlOBAL SCIENCES
ij
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203203-01
Batch F203232 Sequence 2Q20001
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203232-MSMSD3
Analyte
Sample Concentration
(microgL)
Spike Added (pgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Limits Method Notes
Aluminum 3707 10000 10270 990 70 - 130 EPA 2008 Mod AS
Chromium 5316 10000 1137 108 70 - 130 EPA 2008 Mod AS Manganese 7181 10000 8207 103 70 - 130 EPA 2008 Mod AS
Iron 1098 50000 6185 102 70 - 130 EPA 2008 Mod AS Nickel 3025 12500 1433 905 70 - 130 EPA 2008 Mod AS Copper 1816 12500 1061 834 70 - 130 EPA 2008 Mod AS Zinc 7752 25000 1995 767 70 - 130 EPA 2008 Mod AS Arsenic 3770 10000 1073 104 70 - 130 EPA 2008 Mod AS Selenium 587l 10000 1530 943 70 - 130 EPA 2008 Mod AS Silver ND 50000 3690 738 70 - 130 EPA 2008 Mod AS Cadmium 2484 10000 8531 828 70 - 130 EPA 2008 Mod AS Lead 0763 25000 2505 999 70 - 130 EPA 2008 Mod AS
middoti
i
Aoalyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD o
Recovery
RPD Recovery
Limits RPDLimit Method Notes
Aluminum 10000 10150 978 121 70 - 130 20 EPA 2008 Mod AS Chromium 10000 1140 109 0293 70 - 130 20 EPA 2008 Mod AS Manganese 10000 8278 llO 0854 70 -130 20 EPA 2008 Mod AS Iron 50000 6243 103 0937 70-130 20 EPA 2008 Mod AS Nickel 12500 1441 91l middotos25 70 - 130 20 EPA 2008 Mod AS Copper 12500 1066 838 0496 70- 130 20 EPA 2008 Mod AS Zinc 25000 1990 765 0245 70- 130 20 EPA 2008 Mod AS Arsenic 10000 1094 106 193 70 - 130 20 EPA 2008 Mod AS Selenium 10000 1554 967 155 70 - 130 20 EPA 2008 Mod AS Silver 50000 3682 736 0222 70 - 130 20 EPA 2008 Mod AS Cadmium 10000 8394 815 l62 70 - 130 20 EPA 2008 Mod AS Lead 25000 250S 999 00263 70- 130 20 EPA 2008 Mod AS
~~ middotmiddot1 bull
bulli
bullmiddot
Frontier Global Sciences Inc The remits in this report only apply lo the samples analyzed in accordance with the chain ofcustody document This analytical report must bt reproductd In Its entirety
Page 9of20 1203203 Final Report-SWWTF REY2
04M2012
Liz Siska Project Manager 13
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 FRONTIER~ Fx 425-686-3096 GLOBAL SCIENCES
MATR1X SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203203-01RE3
Batch F203260 Sequence 2C22001
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203260-MSMSD3
Analyte
Sample Concentration
(microgL)
Spike Added (microgL)
MS Conctntration
(microgL)
MS
Recovery Recovery
Method Limits Notes
Molybdenum 1999 20200 middot 2041 206 70 - 130 EPA 2008 Mod QM-02
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD Oo
Recovery
RPD
Recovery Limits
RPO Limit Method Notes
Molybdenum 20200 2041 207 00141 70 - 130 20 EPA 2008 Mod QM-02
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed In accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page Oo20 1203203 Final Report- SWWTFREV2
04042012
Liz Siska Project Manager 14
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyzed in accordance with the chain ofcustody document This analytical report =tbe reproducedin Its entirety
Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
CLO~AL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1203203-0lREJ
Batch F203260
Preparation Closed Vessel Nitric Oven Digestion
Sequence 2C2200
Lab Number F203260-MSMSD6
Sample Spike MS MS
Analyte Concentration Added
(JtgL) (microgL) Concentration
(microgL)
Recovery Recovery
Method Limits Notes
Molybdenum 1999 50000 7034 101 70 - 130 EPA 2008 Mod AS
Spike MSD Added Concentration
MSD Recovery RPD
Analyte (microgL) (microgL) Recovery RPD Limits Limit Method Notes
Molybdenum 50000 7124 102 128 70 - 130 20 EPA 2008 Mod AS
Page 11 o20 1203203 Final Report- SWWTF REJ2
040412012
15
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 ~ Fx 425-686-3096 GLOBAL SCIENCES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203203-01
Batch F203288
Preparation BrCI Oxidation
Sequence 2C22016
Lab Number F203288-MSMSD 1
Sample Spike MS MS Concentration Added Concentration Recovery
Analyte (ngL) (ogL) (ogL) Recovery Method Notes Limits
Mercury 6116 25500 3096 974 71 - 125 EPA 1631E
Spike MSD MSD Oo Recovery RPD Added Concentration Oo
Limits Method Notes (ogL) (ogL) Recovery RPD Limit Analyte
Mercury 25500 2611 784 170 71 - 125 24 EPA 1631E
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed i11 accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 12of20 1203203 Final Report- SWWTF REV2
04042012
Liz Siska Project Manager 16
bull 11720 North Creek Parkway North Suite 400
Bothell WA 98011 Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1203194-17
Batch F203288 Sequence 2C22016
Preparation BrCI Oxidation Lab Number F203288-MSMSD2
Sample Spike MS MS
Analyte Concentration
(ngL) Added (ngL)
Concentration (ngL) Recovery
Recovery Limits Method Notes
Mercury 142800 505000 627200 959 71 - 125 EPA 1631E
Spike Added
MSD Concentration
MSD Recovery RPO
Analyte (ngL) (ngL) Recovery RPD Limits Limit Method Notes
Mercury 505000 632700 970 0879 71 - 125 24 EPA 1631E
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody docu~nt This analytical report must be reproduced In its entirety
Page 13of20 1203203 Final Report- SWWTFREV2
04042012
Liz Siska Project Manager 17
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996
bull ~ Fx 425-686-3096 GLPBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203232 Sequence 2C20001
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203232-BSBSD1
LCS Source mank Siiike
Spike LCS LCS Added Concentration Recovery
Analyte (microgL) (microgL) Recovery Limits Method Notes
Aluminwn 15000 1444 963 85-115 EPA2008Mod Chromium 70000 654 934 85 bull 115 EPA 2008 Mod Manganese 60000 580 967 85 - 115 EPA 2008 Mod Iron 50000 4610 922 85 - 115 EPA 2008 Mod Nickel 40000 394 985 85 ll5 EPA 2008 Mod Copper 40000 418 104 85 - 115 EPA 2008 Mod Zinc 10000 1017 102 85 bull 115 EPA 2008 Mod Arsenic 15000 1445 963 85 bull 115 EPA 2008 Mod Selenium 30000 2975 992 85-115 EPA2008Mod Molybdenum 20000 185 926 85 bull 115 EPA 2008 Mod Silver 15000 1555 104 85 - 115 EPA 2008 Mod
Cadmium 080000 0802 100 85 - 115 EPA 2008 Mod Lead 15000 1565 104 85 - 115 EPA 2008 Mod
shy
Spike LCSD LCSD Added Concentration Oo Recovery RPD
Analyte (microgL)
15000
(microgL)
1424
Recovery
949
RPD
140
Limits
85 bull 115
Limit
20
Method
EPA 2008 Mod
Notes
Aluminum
Chromium 70000 644 920 l58 85 bull 115 20 EPA 2008 Mod
Manganese 60000 575 958 0920 85 - ll5 20 EPA 2008 Mod
Iron 50000 4580 916 0660 85 - 115 20 EPA 2008 Mod
Nickel 40000 394 985 000457 85 bull 115 20 EPA 2008 Mod
Copper 40000 416 104 0367 85 - 115 20 EPA 2008 Mod
Zinc 10000 1032 103 147 85 - ll5 20 EPA 2008 Mod
Arsenic 15000 1440 960 0305 85 bull 115 20 EPA 2008 Mod
Selenium 30000 2867 956 369 85 -115 20 EPA 2008 Mod
Molybdenum 20000 l86 928 0196 85 -115 20 EPA2008 Mod
Silver l5000 1559 104 0233 85 bull 115 20 EPA 2008 Mod
Cadmium 080000 0809 101 0843 85 bull llS 20 EPA 2008 Mod
Lead 15000 l539 103 170 85 - 115 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed In accordance with the chain ofcustody document This analytical report must be reproduced in its enJirety
Page 14of20 1203203 Final Report- SWWTFREV2
04042012 ~~
Liz Siska Project Manager 18
11720 North Creek Parkway North Suite 400 Bothell WA 98011 Ph 425-686-1996
FRONTIER Fx 425-686-3096 GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203260 Sequence 2C22001
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203260-BSBSD1
LCS Source Blank Spike
Spike LCS LC$ Added Concentration Recovery
Analyte (ptgL) (JJgL) Recovery Limits Method Notes
Molybdenum 20000 182 910 85 - 115 EPA 2008 Mod
Spike LCSD LCSD Added Concentration Recovery RPD
Analyte (microgL) (microgL) Recovery RPD Limits Limit Method Notes
Molybdenum 20000 186 930 213 85 -115 20 EPA 2008 Mod
Frontier Global Sciences Inc The results In this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced In its entirety
Page 15 o20 I203203 Ftnal ampport- SWWTFREV2
04041202
Liz Siska Project Manager 19
middot
I
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SC IE NC ES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPO
Batch F203288 Sequence 2C22016
Preparation BrCI Oxidation Lab Number F203288-BSBSD I
LCS Source NIST 1641d
Spike LCS LCS Added Concentration Recovery
Analyte (ngL) (ngL) Recovery Limits Method Notes
Mercury 15679 1525 973 80 - 120 EPA l631E
Spike LCSD LCSD Added Concentration Oo Recovery RPD
Analyte (ngL) (ngL)
1516
Recovery
967
RPD
0622
Limits
80 - 120
Limit
24
Method
EPA 1631E
Notes
Mercury 15679
Frontier Global Sciences Inc The results in this report only apply lo the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 16 o20 1203203 Final Report- SWWIFREV2
041042012
20Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 middot Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096 ~ O GLO B AL SCI E NCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2C20001
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203232-BLK1 Aluminum 01 40 microgL F203232 PA2008 Molt u F203232-BLK1 Chromium -0007 0 10 microgL F203232 PA 2008 Molt u F203232-BLKI Manganese 0002 010 microgL F203232 PA 2008 Moc u F203232-BLK1 Iron -004 100 microgL F203232 PA 2008 Molt u F203232-BLKI Nickel 0005 010 microgL F203232 PA 2008 Moc u F203232-BLKI Copper 001 010 microgL F203232 PA 2008 Molt u F203232-BLK1 Zinc 011 020 microgL F203232 PA 2008 Moc u F203232-BLK I Arsenic -0009 015 microgL F203232 PA 2008 Moc u F203232-BLK1 Selenium 025 060 microgL F203232 PA 2008 Moc u F203232-BLK1 Molybdenum 001 006 microgL F203232 PA 2008 Moc u F203232-BLK1 Silver -00009 0020 microgL F203232 PA 2008 Moc u F203232-BLK1 Cadmium 0002 0020 microgL F203232 PA 2008 Molt u F203232-BLK1 Lead 0024 0040 microgL F203232 PA 2008 Molt u
middoti
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordonce with the chain ofcustody document Tnts analytical rtport must be reproduced In its enlfrtty
Page7of20 J203203 Final ampport-SWWTF REV2
04042012
Liz Siska Project Manager 21
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 FRONTIER~ Fx 425-686-3096 GLOBAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2C22001
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203260-BLK1 Molybdenum 001 006 microgL F203260 ~PA 2008 Moc u
Frontier Global Sciences Inc middot The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 18of20 1203203 Final Report- SWWTFREV2
04042012
Liz Siska Project Manager 22
~ CLOSAL SCIENCES
~
J1720 North Creek Parkway North Suite 400 Bothell WA 980 l l
Ph 425-686-1996 Fx 425-686-3096
PREPARATION BLANKS
Instrument Hg-17 Sequence 2C22016
Preparation BrCI Oxidation
The results in Ihis report only apply to the samples analyzed i12 accordance with the chain ofcustody dccumnt This analytical report must be reproductd in ils enJirety
Page I9oj20 1203203 Final Report- SWWTF REJ2
04042012
Frontier Global Sciences Inc
bull 23bull Liz Siska Project Manager
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203288-BLKl Mercury 007 050 ngL F203288 EPA 1631E u F203288-BLIlt2 Mercury 006 050 ngL F203288 EPA 163lE u F203288-BLK3 Mercury 006 050 ngL F203288 EPA I63lE u F203288-BLK4 Mercury 018 050 ngL F203288 EPA I63IE U QB-04
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
Notes and Definitions
U Analyte included in the analysis but not detected
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than I times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable ASASD
QB-04 The blank was preserved to 2 BrCl rather than I The control limit for blanks presetved to greater than 1 BrCl is the preservation percentage multiplied by the l1RL
FB-1631 Required equipmentfieldfilter blank not submitted by the client The sample has been analyzed according to 163 lE but does not meet 163 lE criteria
AS This MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
l1RL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to lhe samples analyzedin accordance wirh the chain ofcustody document This analytical report must be reproduced in its entirety
Page 20of20 1203203 Final Report- SWWTF REV2
04042012
24
bull bull
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~ - I 2lte E55 NOTESili I j HEOHVIAl 6shy ~a 3
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1
DATE NEEDED b171i1-1~ 1 f METALS 8 RCRA 13 PP FE MN Ps CUPROJECT MANAGER 0v f-e_~ Tmamp- middotc COMPANY pdegZ1)shy 0THE1 METALS __________REPORTING OPTIONSQAQC ICH) NoAonms Jfru lli V =1 Q ) REPORTING LEVEL PUUHS ~OR No
A B C 0lOLYpoundD METALS FIELD flLTtREDI YE NoIF YE F~ oa(ITT STAil~l4t(= ~ ZIP rriu1 NOTES (IE SPEOAl DETECTION LIHIIS BIWNG INFO IF D1mam)PHONE _r~ _z31_ - $ I3 Exr--- OR ELECTRONIC OPTIONSFAX _ __________________ AI l A C J C bull C1
J pbNo FAX E-MAIL PDF EQUIS
E-MAIL tivl el qu ~ pv CvVshyf J --~b Mo ~ tJ k ttJ -z~Sm NAHE W
PROJECT ____________ ___ ___ _ ~111216- aJd M fer P4 jgtZJ)shy
SUTt MA ME VT OTHER _____ ___ ~ 1)--U ( u-middotmiddottut-UJ f bull
REGULATORY PROGRAM NPDES RGP POnY STOilKWATER Ol SITE HISTORY ~i tiT f=
GWP OIL FUND BROWNFJUD OR Orm--------shy RELINQUISHED BY DATE TIME RECEIVED Br Summo (ONTAHINATIOM_______
PO_______QUOTE===-~----shy I RELINQUISHED BY DATE TIME Rmmo BT I FIElllJUDINGStt HI l lS 2
eastern analytical inc 2s CHENELl DR1ve I CoNcoRo NH 03301 I TEL 60322sos2s I 1soo2s7os2s IFAXc 6032284591 I E-MA1l cusToMER_seRv1ceEA1LAascoHj wwweA1lAsscoM
prufmin111ll11bomtory1m1im (WHITE ORIGINAL GREEN PROJECT MANAGER)
shy
shy
SAMPLE CONDITIONS PAGE EAi ID 108420
Client middot GZA GeoEnvironmental Inc (NH)
Client Designation MK
Temperature upon receipt (degC) 184 Received on ice or cold packs (YesNo) y Acceptable temperature range (degC) 0-6
Date Date Sample Dry Lab ID Sample ID Received Sampled Matrix Weight ExceptionsComments (other than thermal preservation)
10842001 SWWTF 31412 31412 aqueous Adheres to Sample Acceptance Policy
Samples were properly preserved and the pH measured when applicable unless otherwise noted Analysis ofsolids for pH Flashpoint lgnitibility Paint Filter Corrosivity Conductivity and Specific Gravity are reported on an middotas received basis
All results contained in this report relate only to the above listed samples References include 1) EPA 6004-79-020 1983 2) Standard Methods for Examination ofWater and Wastewater lnorganics 19th Edition 1995 Microbiology 20th Edition 1998 3) Test Methods for Evaluating Solid Waste SW 846 3rd Edition Including updates VA and VB 4) Hach Water Analysis Handbook 2nd edition 1992
eastern analytical inc wwweailabscom Phone (603) 228-0525 1
LABORATORY REPORT EAi I 0 108420
Client GZA GeoEnvironmental Inc (NH)
Client Designation MK
Sample ID SWNTF
Lab Sample ID 10842001
Matrix aqueous
Date Sampled 31412
31412Date Received
Solids Suspended 25000 Solids Dissolved 180000 Chloride 75000 BOD 140 COD 900 pH 69
Analysis
Units Date Time Method Analyst
mgL 31912 1345 2540D DLS mgL 31912 1500 2540C DLS mgL 311912 1030 4500CIE DLS mgL 31512 1412 52108 SKC mgL 32012 900 H8000 KJR SU 31412 1705 4500H+B Jl
TDS Due to sample matrix a constant weight of 000059 could not be achieved
eastern analytical inc wwweailabscom Phone (603) 228-0525 2
QC REPORT EAIID 10842011Jul Client GZA GeoEnvironmental Inc (NH)
Client Designation MK
Date of
Parameter Name Blank LCS LCSO Units Analysis Limits RPO Method
Solids Suspended lt5 96 (96 ooR) 100 (100 ooR) (4 RPO) mgL 31912 90 -110 20 2540D
Solids Dissolved lt5 990 (99 R) NA mgL 31912 85 - 115 20 2540C
Chloride lt 1 27 (106 ooR) 26 (106 ooR) (0 RPD) mgL 31912 90 - 110 20 4500CIE
BOD lt6 400 (100 R) 410 (102 R) (2 RPD) mgL 31512 84-115 20 52108
COD lt 10 100 (97 R) 100 (101 R) (4 RPD) mgL 32012 85 -115 20 H8000
pH 60 (100 ooR) 60 (100 ooR) (0 RPD) SU 31412 595 - 607 10 4500H+B
Duplicate Duplicate Date of Parameter Name Parent ID Parent Duplicate Units Analysls RPO Method
Solids Suspended 10850303 200 190 (4RPD) mgL 31912 20 2540D Solids Dissolved 10843101 270 270 (0 RPO) mgL 31912 20 2540C Chloride NA NA mgL 31912 20 4500CIE BOD NA NA mgL 31512 20 52108 COD NA NA mgl 32012 20 H8000 pH 10838601 82 82 (0 RPO) SU 31412 10 4500H+B
Samples were analyzed within holding times unless noted on the sample results page Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits The associated matrix spikes andor Laboratory Control Samples met the above stated criteria Exceptions to the above statements are flagged or noted above or on the QC Narrative page bull11 Flagged analyte recoveries deviated from the QAQC limits
eastern analytical inc wwweailabscom Phone (603) 228-0525 3
Ill
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
G L OS AL S ( I E N lt ES
04 April 2012
JeffGagne
Eastern Analytical Inc
25 Chenell Drive
Concord NH 03301
RE Merrimack Station 2008
Enclosed are the analytical results for samples received by Frontier Global Sciences All quality control
measurements are within established control limits and there were no analytical difficulties encountered
with the exception ofthose listed in the case narrative section of this report
Ifyou have any questions concerning this report please feel free to contact me
Sincerely 44
Liz Siska
Project Manager
4
~ 11720 North Creek Parkway North Suite 400
Bothell WA 9801 1 Ph 425-686-1996 Fx 425-686-3096
GLOBAl SCIENCES
ANALYTICAL REPORT FOR SAMPLES
Laboratory Frontier Global Sciences Inc SDG
Client Eastern Analytical ]nc Project Merrimack Station 2008
Sample ID Lab ID Matrix Date Sampled Date Received
SWWTF 1203203-01 Water 14-Mar-12 1305 16-Mar-12 0940
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Pagel o20 1203203 Final Report-SWWTF REV2
041042012
Liz Siska Project Manager 5
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
CASE NARRATIVE
Revised Report 4412- Sample name corrected to SWWTF
SAMPLE RECEIPT
Samples were received at Frontier Global Sciences (FGS) on March 16th 2012 The samples were received intact on-ice with temperatures measuredat 22 degrees Celsius
SAMPLE PREPARATION AND ANALYSIS
Samples were prepared and analyzed for total metals in accordance with EPA Method 2008 (modified)
Samples were prepared and analyzed for total mercury in accordance with EPA Method 163 JE
ANALYTICAL ISSUES
The client requested sample SWWTF (1203203-0 l) be analyzed for Mn via email on 31512
Samples were received in a cooler ofmelted ice There was water in the inner most bag of sample Evaporator (1203203-02)
As an additional measure ofthe accuracy ofthe methods utilized for analysis and to check for matrix interference matrix spikes (MS) and matrix spike duplicates (MSD) were digested and analyzed All ofthe matrix spike recoveries were within the control limits with the exception ofany QC flagged and described in the notes and definitions section ofthe following report
A reasonable measure ofthe precision ofthe analytical methods utilized for analysis is the relative percent difference (RPD) between matrix spike and matrix spike duplicate recoveries and between laboratory control sample and laboratory control sample duplicate recoveries All of the relative percent differences were within the control limits with the exception ofany QC flagged and described in the notes and definitions section ofthe following report
Frontier Global Sciences Inc The results in this report 011y apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 2 of20 1203203 Final Report- SWWTF REV2
04042012
Liz Siska Project Manager 6
FRONTIER
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIE NCES
CHAIN OF CUSTODY FORMS
bullbull _ ~ -bull uer ( A c 2 - gt Sampre Recefpt CHockJlst
Data Looobulld tn ~tZfrPkttr ~~middot0 middot1)d bull MSi~~gtamp Loss bull d I n Sy
SOG o f Coolns- R~oetvbullG I ( FGSPM
Sarn01 AnIVed bull)I ----Shipp ing --=--___~~-=-------=_lta=~-=--===---------
___Nona (ArnblbullnQ
SbullNfo Cour1bullr TrecklngJAtrtgtIII Nubbulltbull) e Xlt---Z-~q gt
-rhermal PreuorvatJon Loo~ l~ ___GeleJubull lea
rT~hbull_ornebullur_10~gt~(~5z2~_--CorrftCtfan rbullclOf (Cfl) ~lt2 - 3 degre-bull O eoolbullr- 1 L ~ middoto CoCttbullr a bullc eoolbullr-2 middot c Cootbullr7 middotc
middot c Cooler a bullc middot c
middotc middot c
Coolar 18
Chbullln orCutody COO $ pria1-ct-n bullnd lneludee thbull folto~ng Information for obulloh ~~mple
NA Comrnbullnta
Sbullrnolampd BvshyPrbullbullation bullmiddot ~uoa1bulld Ana1vbullbullbullmiddot Roaulbulld SlcnHt vrbullr
middot------------ shy ---ilnt-nat chaln or custOdv irv1d
l-~=V
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Samplbull CondltJonltnte-oi $bullmole containerbull wbullra -oehbulld Jr1tlact bull--bull labolbull bullshy _nt bulln lenfbln
lteon-eet aamIbull oontarners U ~ltftd fcrr reauect1Dd 0rnafv8ebull sbullm-reraquo roCHtlvOd In holdrna tlmomiddot bullbullrn- bull vohnlIbull auMolen ~~r raubullbulltbulld anaalvbull a
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CotTbulld orbullbullbulltvotlvbull ucact for aue atect -nahrbull _ -shyM of bull-n~tshy Qhertced a-d mthod l~e-ntbull -
Cllent Communloatfott Po~ Contaicta Oat611mbull _____ _
Commentbull
Mbulltnod ____ _
Olbull~bullronJRbullbullo1utlon
The results in this report only apply to the samples analy-ed in accordance with the Frontier Global Sciences Inc chain ofcustody docutMnt This aMlytical report must be reprodu~d in its e111irety
Page3of20 1203203 Final Rtport- SWWTFREV2
04042012
Liz Siska Project Manager 7
l l 720 North Creek Parkway Nortn u1Le -tvv Bothell WA 9amp011
Ph 425-686-1996 Fx 425-686-3096
FRONTIER GLOBAL SCIENCES
CHAIN OF CUSTODY FORMS
The results in this report only apply to the samples analyzed in accordance with the cliain ofcustody documenL This analytical report must be reproduced in its entirety
Frontier Global Sciences Inc Page 4 o20 1203203 Final Report- SWWTF REV2
04042012
Liz Siska Project Manager
8
11720 North Creek Parkway North Suite 40U Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
FRONTIER C L 0 B AL SC I~ NC ES
CHAlN OF CUSTODY FORMS
i---t--+-l-+-+-+--+--+--+--+_micro~[_amp~lslte---l t---t--+--11-(- -1--+-~-+--l---l---+----------f_ rmiddot 1---+--~--l--f-+---l--l--l-+--I--I---- _____--1 lt 1--1--1--+--l--------4-+-+--l--+-+--____f_ i--t--+--1r-+-+-+-t-+-++-4-________ _j bull-
CN _r(gt --shyshy~
_lj _D ~ -~ Irgt ~ -f
~ ~
The results In this report onlyapply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reprodu~din its entirety
Frontier Global Sciences Inc Page 5 o20 T203203 Final Report-SWWTFREV2
ommo12
Liz SiskaProject Manager
9
)--J middot ~~
)J fl~~J~c1N~r
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
Matrix Water Laboratory ID 1203203-01
ANALYTICAL RESULTS
SWWTF
Analyte Result lIDL MRL Units Dilution Batch Sequence Analyzed Method Notes
Aluminum 371 220 198 microgL 5 F203232 2C2000l 031912 EPA 2008 Mod
Arsenic 377 252 743 microgL 5 F203232 2C2000l 031912 EPA 2008 Mod
Cadmium 248 0205 0990 microgL 5 F203232 2C20001 031912 EPA2008 Mod
Chromium 532 045 495 microgL 5 F203232 2C20001 031912 EPA 2008 Mod
Copper 182 050 495 microgL 5 F203232 2C20001 031912 EPA 2008 Mod
Iron 1100 644 495 microgL 5 F203232 2C20001 031912 EPA 2008 Mod
Lead ND 0193 198 microgL 5 F203232 2C2000l 031912 EPA 2008 Mod u Manganese 7180 037 495 microgL 5 F203232 2C2000l 031912 EPA 2008 Mod
Mercury 612 842 505 ngL 100 F203288 2C22016 032212 EPA l631E FB-1631
Molybdenum 2000 297 297 microgL 50 F203260 2C22001 032112 EPA 2008 Mod
Nickel 303 040 495 microgL 5 F203232 2C20001 031912 EPA 2008 Mod
Selenium 587 959 297 microgL 5 F203232 2C20001 031912 EPA 2008 Mod
Silver ND 0297 0990 microgL 5 F203232 2C20001 031912 EPA 2008 Mod u Zinc 775 081 990 microgL 5 F203232 2C20001 031912 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report 011ly apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page6 o20 I203203 Final Report- SWWTF REV2
04042012
Liz Siska Project Manager 10
gt
C LO BA L S CI E N C ES
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
MATRIX DUPLICATESTRIPLICATES
SOURCE 1203203-01
Batch F203288
Preparation BrCl Oxidation
Sequence 2C22016
Lab Number F203288-DUPI
Sample Duplicate Concentration Concentration RPD
Analyte DgL ngL
5848
MRL 505
RPD 448
Limit
24
Method
EPA 163IE
Notes
Mercury 6116
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced In its entirety
Page 7of20 l 103203 Final Report- SWWTF REV2
04042012 bull 1 1 Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996
FROlJTIER Fx 425-686-3096 GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203203-01
Batch F203232 Sequence 2C20001
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203232-MSMSD 1
Sample Spike MS MS Concentration Added Concentration 0o Recovery
Analyte (microgL) (microgL) (microgL) Recovery Method NotesLimits
Alumimun 3707 15152 1853 978 70 - 130 EPA 2008 Mod
Chromium 5316 70707 1270 104 70- 130 EPA 2008 Mod
Manganese 7181 60606 7231 821 70 - 130 EPA 2008 Mod
Iron 1098 50505 6090 988 70- 130 EPA 2008 Mod
Nickel 3025 40404 3425 988 70 - 130 EPA 2008 Mod
Copper 1816 40404 5182 833 70 - 130 EPA2008 Mod
Arsenic 3770 15152 1904 101 70- 130 EPA 2008 Mod
Seleniwn 587l 30303 9297 113 70 - 130 EPA 2008 Mod
Silver ND 15152 1099 725 70 - 130 EPA 2008 Mod
Cadmillll) 2484 80808 9508 869 70 - 130 EPA 2008 Mod
Lead 0763 15152 1544 968 70-130 EPA2008Mod
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD
Recovery
Oo
RPD Recovery
Limits RPOLimit Method Notes
Aluminum 15152 1826 96l 145 70 shy 130 20 EPA 2008 Mod
Chromium 70707 1288 107 138 70-130 20 EPA 2008 Mod
Manganese 60606 7230 804 00140 70- 130 20 EPA 2008 Mod
Iron 50505 6065 983 0414 70- 130 20 EPA 2008 Mod
Nickel 40404 3378 872 138 70 - 130 20 EPA2008 Mod
Copper 40404 5140 823 0807 70 - 130 20 EPA 2008 Mod
Arsenic 15152 1928 102 123 70 - 130 20 EPA 2008 Mod
Selenium 30303 9063 105 255 70- 130 20 EPA 2008 Mod
Silver 15152 1075 709 219 70- 130 20 EPA 2008 Mod
Cadmium 80808 9347 849 170 70- 130 20 EPA 2008 Mod
Lead 15152 1531 960 0815 70- 130 20 EPA 2008 Mod
Frontier Global Sciences Inc The results In this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
PageBo20 1203203 FinalReport- SWWTFREV2
04042012
Liz Siska Project Manager 12
iii
11720 North Creek Parkway North Suite 400
Bothell WA 98011 Ph 425-686-1996 Fx 425-686-3096 GlOBAL SCIENCES
ij
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203203-01
Batch F203232 Sequence 2Q20001
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203232-MSMSD3
Analyte
Sample Concentration
(microgL)
Spike Added (pgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Limits Method Notes
Aluminum 3707 10000 10270 990 70 - 130 EPA 2008 Mod AS
Chromium 5316 10000 1137 108 70 - 130 EPA 2008 Mod AS Manganese 7181 10000 8207 103 70 - 130 EPA 2008 Mod AS
Iron 1098 50000 6185 102 70 - 130 EPA 2008 Mod AS Nickel 3025 12500 1433 905 70 - 130 EPA 2008 Mod AS Copper 1816 12500 1061 834 70 - 130 EPA 2008 Mod AS Zinc 7752 25000 1995 767 70 - 130 EPA 2008 Mod AS Arsenic 3770 10000 1073 104 70 - 130 EPA 2008 Mod AS Selenium 587l 10000 1530 943 70 - 130 EPA 2008 Mod AS Silver ND 50000 3690 738 70 - 130 EPA 2008 Mod AS Cadmium 2484 10000 8531 828 70 - 130 EPA 2008 Mod AS Lead 0763 25000 2505 999 70 - 130 EPA 2008 Mod AS
middoti
i
Aoalyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD o
Recovery
RPD Recovery
Limits RPDLimit Method Notes
Aluminum 10000 10150 978 121 70 - 130 20 EPA 2008 Mod AS Chromium 10000 1140 109 0293 70 - 130 20 EPA 2008 Mod AS Manganese 10000 8278 llO 0854 70 -130 20 EPA 2008 Mod AS Iron 50000 6243 103 0937 70-130 20 EPA 2008 Mod AS Nickel 12500 1441 91l middotos25 70 - 130 20 EPA 2008 Mod AS Copper 12500 1066 838 0496 70- 130 20 EPA 2008 Mod AS Zinc 25000 1990 765 0245 70- 130 20 EPA 2008 Mod AS Arsenic 10000 1094 106 193 70 - 130 20 EPA 2008 Mod AS Selenium 10000 1554 967 155 70 - 130 20 EPA 2008 Mod AS Silver 50000 3682 736 0222 70 - 130 20 EPA 2008 Mod AS Cadmium 10000 8394 815 l62 70 - 130 20 EPA 2008 Mod AS Lead 25000 250S 999 00263 70- 130 20 EPA 2008 Mod AS
~~ middotmiddot1 bull
bulli
bullmiddot
Frontier Global Sciences Inc The remits in this report only apply lo the samples analyzed in accordance with the chain ofcustody document This analytical report must bt reproductd In Its entirety
Page 9of20 1203203 Final Report-SWWTF REY2
04M2012
Liz Siska Project Manager 13
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 FRONTIER~ Fx 425-686-3096 GLOBAL SCIENCES
MATR1X SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203203-01RE3
Batch F203260 Sequence 2C22001
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203260-MSMSD3
Analyte
Sample Concentration
(microgL)
Spike Added (microgL)
MS Conctntration
(microgL)
MS
Recovery Recovery
Method Limits Notes
Molybdenum 1999 20200 middot 2041 206 70 - 130 EPA 2008 Mod QM-02
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD Oo
Recovery
RPD
Recovery Limits
RPO Limit Method Notes
Molybdenum 20200 2041 207 00141 70 - 130 20 EPA 2008 Mod QM-02
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed In accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page Oo20 1203203 Final Report- SWWTFREV2
04042012
Liz Siska Project Manager 14
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyzed in accordance with the chain ofcustody document This analytical report =tbe reproducedin Its entirety
Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
CLO~AL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1203203-0lREJ
Batch F203260
Preparation Closed Vessel Nitric Oven Digestion
Sequence 2C2200
Lab Number F203260-MSMSD6
Sample Spike MS MS
Analyte Concentration Added
(JtgL) (microgL) Concentration
(microgL)
Recovery Recovery
Method Limits Notes
Molybdenum 1999 50000 7034 101 70 - 130 EPA 2008 Mod AS
Spike MSD Added Concentration
MSD Recovery RPD
Analyte (microgL) (microgL) Recovery RPD Limits Limit Method Notes
Molybdenum 50000 7124 102 128 70 - 130 20 EPA 2008 Mod AS
Page 11 o20 1203203 Final Report- SWWTF REJ2
040412012
15
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 ~ Fx 425-686-3096 GLOBAL SCIENCES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203203-01
Batch F203288
Preparation BrCI Oxidation
Sequence 2C22016
Lab Number F203288-MSMSD 1
Sample Spike MS MS Concentration Added Concentration Recovery
Analyte (ngL) (ogL) (ogL) Recovery Method Notes Limits
Mercury 6116 25500 3096 974 71 - 125 EPA 1631E
Spike MSD MSD Oo Recovery RPD Added Concentration Oo
Limits Method Notes (ogL) (ogL) Recovery RPD Limit Analyte
Mercury 25500 2611 784 170 71 - 125 24 EPA 1631E
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed i11 accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 12of20 1203203 Final Report- SWWTF REV2
04042012
Liz Siska Project Manager 16
bull 11720 North Creek Parkway North Suite 400
Bothell WA 98011 Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1203194-17
Batch F203288 Sequence 2C22016
Preparation BrCI Oxidation Lab Number F203288-MSMSD2
Sample Spike MS MS
Analyte Concentration
(ngL) Added (ngL)
Concentration (ngL) Recovery
Recovery Limits Method Notes
Mercury 142800 505000 627200 959 71 - 125 EPA 1631E
Spike Added
MSD Concentration
MSD Recovery RPO
Analyte (ngL) (ngL) Recovery RPD Limits Limit Method Notes
Mercury 505000 632700 970 0879 71 - 125 24 EPA 1631E
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody docu~nt This analytical report must be reproduced In its entirety
Page 13of20 1203203 Final Report- SWWTFREV2
04042012
Liz Siska Project Manager 17
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996
bull ~ Fx 425-686-3096 GLPBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203232 Sequence 2C20001
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203232-BSBSD1
LCS Source mank Siiike
Spike LCS LCS Added Concentration Recovery
Analyte (microgL) (microgL) Recovery Limits Method Notes
Aluminwn 15000 1444 963 85-115 EPA2008Mod Chromium 70000 654 934 85 bull 115 EPA 2008 Mod Manganese 60000 580 967 85 - 115 EPA 2008 Mod Iron 50000 4610 922 85 - 115 EPA 2008 Mod Nickel 40000 394 985 85 ll5 EPA 2008 Mod Copper 40000 418 104 85 - 115 EPA 2008 Mod Zinc 10000 1017 102 85 bull 115 EPA 2008 Mod Arsenic 15000 1445 963 85 bull 115 EPA 2008 Mod Selenium 30000 2975 992 85-115 EPA2008Mod Molybdenum 20000 185 926 85 bull 115 EPA 2008 Mod Silver 15000 1555 104 85 - 115 EPA 2008 Mod
Cadmium 080000 0802 100 85 - 115 EPA 2008 Mod Lead 15000 1565 104 85 - 115 EPA 2008 Mod
shy
Spike LCSD LCSD Added Concentration Oo Recovery RPD
Analyte (microgL)
15000
(microgL)
1424
Recovery
949
RPD
140
Limits
85 bull 115
Limit
20
Method
EPA 2008 Mod
Notes
Aluminum
Chromium 70000 644 920 l58 85 bull 115 20 EPA 2008 Mod
Manganese 60000 575 958 0920 85 - ll5 20 EPA 2008 Mod
Iron 50000 4580 916 0660 85 - 115 20 EPA 2008 Mod
Nickel 40000 394 985 000457 85 bull 115 20 EPA 2008 Mod
Copper 40000 416 104 0367 85 - 115 20 EPA 2008 Mod
Zinc 10000 1032 103 147 85 - ll5 20 EPA 2008 Mod
Arsenic 15000 1440 960 0305 85 bull 115 20 EPA 2008 Mod
Selenium 30000 2867 956 369 85 -115 20 EPA 2008 Mod
Molybdenum 20000 l86 928 0196 85 -115 20 EPA2008 Mod
Silver l5000 1559 104 0233 85 bull 115 20 EPA 2008 Mod
Cadmium 080000 0809 101 0843 85 bull llS 20 EPA 2008 Mod
Lead 15000 l539 103 170 85 - 115 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed In accordance with the chain ofcustody document This analytical report must be reproduced in its enJirety
Page 14of20 1203203 Final Report- SWWTFREV2
04042012 ~~
Liz Siska Project Manager 18
11720 North Creek Parkway North Suite 400 Bothell WA 98011 Ph 425-686-1996
FRONTIER Fx 425-686-3096 GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203260 Sequence 2C22001
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203260-BSBSD1
LCS Source Blank Spike
Spike LCS LC$ Added Concentration Recovery
Analyte (ptgL) (JJgL) Recovery Limits Method Notes
Molybdenum 20000 182 910 85 - 115 EPA 2008 Mod
Spike LCSD LCSD Added Concentration Recovery RPD
Analyte (microgL) (microgL) Recovery RPD Limits Limit Method Notes
Molybdenum 20000 186 930 213 85 -115 20 EPA 2008 Mod
Frontier Global Sciences Inc The results In this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced In its entirety
Page 15 o20 I203203 Ftnal ampport- SWWTFREV2
04041202
Liz Siska Project Manager 19
middot
I
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SC IE NC ES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPO
Batch F203288 Sequence 2C22016
Preparation BrCI Oxidation Lab Number F203288-BSBSD I
LCS Source NIST 1641d
Spike LCS LCS Added Concentration Recovery
Analyte (ngL) (ngL) Recovery Limits Method Notes
Mercury 15679 1525 973 80 - 120 EPA l631E
Spike LCSD LCSD Added Concentration Oo Recovery RPD
Analyte (ngL) (ngL)
1516
Recovery
967
RPD
0622
Limits
80 - 120
Limit
24
Method
EPA 1631E
Notes
Mercury 15679
Frontier Global Sciences Inc The results in this report only apply lo the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 16 o20 1203203 Final Report- SWWIFREV2
041042012
20Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 middot Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096 ~ O GLO B AL SCI E NCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2C20001
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203232-BLK1 Aluminum 01 40 microgL F203232 PA2008 Molt u F203232-BLK1 Chromium -0007 0 10 microgL F203232 PA 2008 Molt u F203232-BLKI Manganese 0002 010 microgL F203232 PA 2008 Moc u F203232-BLK1 Iron -004 100 microgL F203232 PA 2008 Molt u F203232-BLKI Nickel 0005 010 microgL F203232 PA 2008 Moc u F203232-BLKI Copper 001 010 microgL F203232 PA 2008 Molt u F203232-BLK1 Zinc 011 020 microgL F203232 PA 2008 Moc u F203232-BLK I Arsenic -0009 015 microgL F203232 PA 2008 Moc u F203232-BLK1 Selenium 025 060 microgL F203232 PA 2008 Moc u F203232-BLK1 Molybdenum 001 006 microgL F203232 PA 2008 Moc u F203232-BLK1 Silver -00009 0020 microgL F203232 PA 2008 Moc u F203232-BLK1 Cadmium 0002 0020 microgL F203232 PA 2008 Molt u F203232-BLK1 Lead 0024 0040 microgL F203232 PA 2008 Molt u
middoti
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordonce with the chain ofcustody document Tnts analytical rtport must be reproduced In its enlfrtty
Page7of20 J203203 Final ampport-SWWTF REV2
04042012
Liz Siska Project Manager 21
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 FRONTIER~ Fx 425-686-3096 GLOBAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2C22001
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203260-BLK1 Molybdenum 001 006 microgL F203260 ~PA 2008 Moc u
Frontier Global Sciences Inc middot The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 18of20 1203203 Final Report- SWWTFREV2
04042012
Liz Siska Project Manager 22
~ CLOSAL SCIENCES
~
J1720 North Creek Parkway North Suite 400 Bothell WA 980 l l
Ph 425-686-1996 Fx 425-686-3096
PREPARATION BLANKS
Instrument Hg-17 Sequence 2C22016
Preparation BrCI Oxidation
The results in Ihis report only apply to the samples analyzed i12 accordance with the chain ofcustody dccumnt This analytical report must be reproductd in ils enJirety
Page I9oj20 1203203 Final Report- SWWTF REJ2
04042012
Frontier Global Sciences Inc
bull 23bull Liz Siska Project Manager
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203288-BLKl Mercury 007 050 ngL F203288 EPA 1631E u F203288-BLIlt2 Mercury 006 050 ngL F203288 EPA 163lE u F203288-BLK3 Mercury 006 050 ngL F203288 EPA I63lE u F203288-BLK4 Mercury 018 050 ngL F203288 EPA I63IE U QB-04
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
Notes and Definitions
U Analyte included in the analysis but not detected
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than I times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable ASASD
QB-04 The blank was preserved to 2 BrCl rather than I The control limit for blanks presetved to greater than 1 BrCl is the preservation percentage multiplied by the l1RL
FB-1631 Required equipmentfieldfilter blank not submitted by the client The sample has been analyzed according to 163 lE but does not meet 163 lE criteria
AS This MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
l1RL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to lhe samples analyzedin accordance wirh the chain ofcustody document This analytical report must be reproduced in its entirety
Page 20of20 1203203 Final Report- SWWTF REV2
04042012
24
bull bull
irGl Lu Ull 0111C H AIN-OF-CUSTODY RECORD Page of_~~
Bolo FIELDS REQUIRED P LEASE CIRCLE REQUESTED ANALYs1s Lt) CN voe I svoc TClPI M ETALS INORGANICS
i w I shy i
SAMPLING 0 iii 0 ~
w = ~ DATET1ME QIll c X
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INDICATE 80TH ~ bulllo- t5a5 START amp FINISH
er Ill liSAMPLE 1 0 i ct -a ~shyDATEITIME l r ~~
bull 7gtItJJJI JWj T ~ tlt
IHAnlX A-Ala S-SOIL GW-GROUHD WATEl SW-SURfACE WATEA DW-DllNIING WAm WW-WAITE WATEl
PWETAJllt H-HCL N-HNO S-HJO Na-NaOHmiddot H-HEOH
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1
DATE NEEDED b171i1-1~ 1 f METALS 8 RCRA 13 PP FE MN Ps CUPROJECT MANAGER 0v f-e_~ Tmamp- middotc COMPANY pdegZ1)shy 0THE1 METALS __________REPORTING OPTIONSQAQC ICH) NoAonms Jfru lli V =1 Q ) REPORTING LEVEL PUUHS ~OR No
A B C 0lOLYpoundD METALS FIELD flLTtREDI YE NoIF YE F~ oa(ITT STAil~l4t(= ~ ZIP rriu1 NOTES (IE SPEOAl DETECTION LIHIIS BIWNG INFO IF D1mam)PHONE _r~ _z31_ - $ I3 Exr--- OR ELECTRONIC OPTIONSFAX _ __________________ AI l A C J C bull C1
J pbNo FAX E-MAIL PDF EQUIS
E-MAIL tivl el qu ~ pv CvVshyf J --~b Mo ~ tJ k ttJ -z~Sm NAHE W
PROJECT ____________ ___ ___ _ ~111216- aJd M fer P4 jgtZJ)shy
SUTt MA ME VT OTHER _____ ___ ~ 1)--U ( u-middotmiddottut-UJ f bull
REGULATORY PROGRAM NPDES RGP POnY STOilKWATER Ol SITE HISTORY ~i tiT f=
GWP OIL FUND BROWNFJUD OR Orm--------shy RELINQUISHED BY DATE TIME RECEIVED Br Summo (ONTAHINATIOM_______
PO_______QUOTE===-~----shy I RELINQUISHED BY DATE TIME Rmmo BT I FIElllJUDINGStt HI l lS 2
eastern analytical inc 2s CHENELl DR1ve I CoNcoRo NH 03301 I TEL 60322sos2s I 1soo2s7os2s IFAXc 6032284591 I E-MA1l cusToMER_seRv1ceEA1LAascoHj wwweA1lAsscoM
prufmin111ll11bomtory1m1im (WHITE ORIGINAL GREEN PROJECT MANAGER)
shy
shy
LABORATORY REPORT EAi I 0 108420
Client GZA GeoEnvironmental Inc (NH)
Client Designation MK
Sample ID SWNTF
Lab Sample ID 10842001
Matrix aqueous
Date Sampled 31412
31412Date Received
Solids Suspended 25000 Solids Dissolved 180000 Chloride 75000 BOD 140 COD 900 pH 69
Analysis
Units Date Time Method Analyst
mgL 31912 1345 2540D DLS mgL 31912 1500 2540C DLS mgL 311912 1030 4500CIE DLS mgL 31512 1412 52108 SKC mgL 32012 900 H8000 KJR SU 31412 1705 4500H+B Jl
TDS Due to sample matrix a constant weight of 000059 could not be achieved
eastern analytical inc wwweailabscom Phone (603) 228-0525 2
QC REPORT EAIID 10842011Jul Client GZA GeoEnvironmental Inc (NH)
Client Designation MK
Date of
Parameter Name Blank LCS LCSO Units Analysis Limits RPO Method
Solids Suspended lt5 96 (96 ooR) 100 (100 ooR) (4 RPO) mgL 31912 90 -110 20 2540D
Solids Dissolved lt5 990 (99 R) NA mgL 31912 85 - 115 20 2540C
Chloride lt 1 27 (106 ooR) 26 (106 ooR) (0 RPD) mgL 31912 90 - 110 20 4500CIE
BOD lt6 400 (100 R) 410 (102 R) (2 RPD) mgL 31512 84-115 20 52108
COD lt 10 100 (97 R) 100 (101 R) (4 RPD) mgL 32012 85 -115 20 H8000
pH 60 (100 ooR) 60 (100 ooR) (0 RPD) SU 31412 595 - 607 10 4500H+B
Duplicate Duplicate Date of Parameter Name Parent ID Parent Duplicate Units Analysls RPO Method
Solids Suspended 10850303 200 190 (4RPD) mgL 31912 20 2540D Solids Dissolved 10843101 270 270 (0 RPO) mgL 31912 20 2540C Chloride NA NA mgL 31912 20 4500CIE BOD NA NA mgL 31512 20 52108 COD NA NA mgl 32012 20 H8000 pH 10838601 82 82 (0 RPO) SU 31412 10 4500H+B
Samples were analyzed within holding times unless noted on the sample results page Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits The associated matrix spikes andor Laboratory Control Samples met the above stated criteria Exceptions to the above statements are flagged or noted above or on the QC Narrative page bull11 Flagged analyte recoveries deviated from the QAQC limits
eastern analytical inc wwweailabscom Phone (603) 228-0525 3
Ill
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
G L OS AL S ( I E N lt ES
04 April 2012
JeffGagne
Eastern Analytical Inc
25 Chenell Drive
Concord NH 03301
RE Merrimack Station 2008
Enclosed are the analytical results for samples received by Frontier Global Sciences All quality control
measurements are within established control limits and there were no analytical difficulties encountered
with the exception ofthose listed in the case narrative section of this report
Ifyou have any questions concerning this report please feel free to contact me
Sincerely 44
Liz Siska
Project Manager
4
~ 11720 North Creek Parkway North Suite 400
Bothell WA 9801 1 Ph 425-686-1996 Fx 425-686-3096
GLOBAl SCIENCES
ANALYTICAL REPORT FOR SAMPLES
Laboratory Frontier Global Sciences Inc SDG
Client Eastern Analytical ]nc Project Merrimack Station 2008
Sample ID Lab ID Matrix Date Sampled Date Received
SWWTF 1203203-01 Water 14-Mar-12 1305 16-Mar-12 0940
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Pagel o20 1203203 Final Report-SWWTF REV2
041042012
Liz Siska Project Manager 5
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
CASE NARRATIVE
Revised Report 4412- Sample name corrected to SWWTF
SAMPLE RECEIPT
Samples were received at Frontier Global Sciences (FGS) on March 16th 2012 The samples were received intact on-ice with temperatures measuredat 22 degrees Celsius
SAMPLE PREPARATION AND ANALYSIS
Samples were prepared and analyzed for total metals in accordance with EPA Method 2008 (modified)
Samples were prepared and analyzed for total mercury in accordance with EPA Method 163 JE
ANALYTICAL ISSUES
The client requested sample SWWTF (1203203-0 l) be analyzed for Mn via email on 31512
Samples were received in a cooler ofmelted ice There was water in the inner most bag of sample Evaporator (1203203-02)
As an additional measure ofthe accuracy ofthe methods utilized for analysis and to check for matrix interference matrix spikes (MS) and matrix spike duplicates (MSD) were digested and analyzed All ofthe matrix spike recoveries were within the control limits with the exception ofany QC flagged and described in the notes and definitions section ofthe following report
A reasonable measure ofthe precision ofthe analytical methods utilized for analysis is the relative percent difference (RPD) between matrix spike and matrix spike duplicate recoveries and between laboratory control sample and laboratory control sample duplicate recoveries All of the relative percent differences were within the control limits with the exception ofany QC flagged and described in the notes and definitions section ofthe following report
Frontier Global Sciences Inc The results in this report 011y apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 2 of20 1203203 Final Report- SWWTF REV2
04042012
Liz Siska Project Manager 6
FRONTIER
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIE NCES
CHAIN OF CUSTODY FORMS
bullbull _ ~ -bull uer ( A c 2 - gt Sampre Recefpt CHockJlst
Data Looobulld tn ~tZfrPkttr ~~middot0 middot1)d bull MSi~~gtamp Loss bull d I n Sy
SOG o f Coolns- R~oetvbullG I ( FGSPM
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rT~hbull_ornebullur_10~gt~(~5z2~_--CorrftCtfan rbullclOf (Cfl) ~lt2 - 3 degre-bull O eoolbullr- 1 L ~ middoto CoCttbullr a bullc eoolbullr-2 middot c Cootbullr7 middotc
middot c Cooler a bullc middot c
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Cllent Communloatfott Po~ Contaicta Oat611mbull _____ _
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Olbull~bullronJRbullbullo1utlon
The results in this report only apply to the samples analy-ed in accordance with the Frontier Global Sciences Inc chain ofcustody docutMnt This aMlytical report must be reprodu~d in its e111irety
Page3of20 1203203 Final Rtport- SWWTFREV2
04042012
Liz Siska Project Manager 7
l l 720 North Creek Parkway Nortn u1Le -tvv Bothell WA 9amp011
Ph 425-686-1996 Fx 425-686-3096
FRONTIER GLOBAL SCIENCES
CHAIN OF CUSTODY FORMS
The results in this report only apply to the samples analyzed in accordance with the cliain ofcustody documenL This analytical report must be reproduced in its entirety
Frontier Global Sciences Inc Page 4 o20 1203203 Final Report- SWWTF REV2
04042012
Liz Siska Project Manager
8
11720 North Creek Parkway North Suite 40U Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
FRONTIER C L 0 B AL SC I~ NC ES
CHAlN OF CUSTODY FORMS
i---t--+-l-+-+-+--+--+--+--+_micro~[_amp~lslte---l t---t--+--11-(- -1--+-~-+--l---l---+----------f_ rmiddot 1---+--~--l--f-+---l--l--l-+--I--I---- _____--1 lt 1--1--1--+--l--------4-+-+--l--+-+--____f_ i--t--+--1r-+-+-+-t-+-++-4-________ _j bull-
CN _r(gt --shyshy~
_lj _D ~ -~ Irgt ~ -f
~ ~
The results In this report onlyapply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reprodu~din its entirety
Frontier Global Sciences Inc Page 5 o20 T203203 Final Report-SWWTFREV2
ommo12
Liz SiskaProject Manager
9
)--J middot ~~
)J fl~~J~c1N~r
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
Matrix Water Laboratory ID 1203203-01
ANALYTICAL RESULTS
SWWTF
Analyte Result lIDL MRL Units Dilution Batch Sequence Analyzed Method Notes
Aluminum 371 220 198 microgL 5 F203232 2C2000l 031912 EPA 2008 Mod
Arsenic 377 252 743 microgL 5 F203232 2C2000l 031912 EPA 2008 Mod
Cadmium 248 0205 0990 microgL 5 F203232 2C20001 031912 EPA2008 Mod
Chromium 532 045 495 microgL 5 F203232 2C20001 031912 EPA 2008 Mod
Copper 182 050 495 microgL 5 F203232 2C20001 031912 EPA 2008 Mod
Iron 1100 644 495 microgL 5 F203232 2C20001 031912 EPA 2008 Mod
Lead ND 0193 198 microgL 5 F203232 2C2000l 031912 EPA 2008 Mod u Manganese 7180 037 495 microgL 5 F203232 2C2000l 031912 EPA 2008 Mod
Mercury 612 842 505 ngL 100 F203288 2C22016 032212 EPA l631E FB-1631
Molybdenum 2000 297 297 microgL 50 F203260 2C22001 032112 EPA 2008 Mod
Nickel 303 040 495 microgL 5 F203232 2C20001 031912 EPA 2008 Mod
Selenium 587 959 297 microgL 5 F203232 2C20001 031912 EPA 2008 Mod
Silver ND 0297 0990 microgL 5 F203232 2C20001 031912 EPA 2008 Mod u Zinc 775 081 990 microgL 5 F203232 2C20001 031912 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report 011ly apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page6 o20 I203203 Final Report- SWWTF REV2
04042012
Liz Siska Project Manager 10
gt
C LO BA L S CI E N C ES
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
MATRIX DUPLICATESTRIPLICATES
SOURCE 1203203-01
Batch F203288
Preparation BrCl Oxidation
Sequence 2C22016
Lab Number F203288-DUPI
Sample Duplicate Concentration Concentration RPD
Analyte DgL ngL
5848
MRL 505
RPD 448
Limit
24
Method
EPA 163IE
Notes
Mercury 6116
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced In its entirety
Page 7of20 l 103203 Final Report- SWWTF REV2
04042012 bull 1 1 Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996
FROlJTIER Fx 425-686-3096 GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203203-01
Batch F203232 Sequence 2C20001
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203232-MSMSD 1
Sample Spike MS MS Concentration Added Concentration 0o Recovery
Analyte (microgL) (microgL) (microgL) Recovery Method NotesLimits
Alumimun 3707 15152 1853 978 70 - 130 EPA 2008 Mod
Chromium 5316 70707 1270 104 70- 130 EPA 2008 Mod
Manganese 7181 60606 7231 821 70 - 130 EPA 2008 Mod
Iron 1098 50505 6090 988 70- 130 EPA 2008 Mod
Nickel 3025 40404 3425 988 70 - 130 EPA 2008 Mod
Copper 1816 40404 5182 833 70 - 130 EPA2008 Mod
Arsenic 3770 15152 1904 101 70- 130 EPA 2008 Mod
Seleniwn 587l 30303 9297 113 70 - 130 EPA 2008 Mod
Silver ND 15152 1099 725 70 - 130 EPA 2008 Mod
Cadmillll) 2484 80808 9508 869 70 - 130 EPA 2008 Mod
Lead 0763 15152 1544 968 70-130 EPA2008Mod
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD
Recovery
Oo
RPD Recovery
Limits RPOLimit Method Notes
Aluminum 15152 1826 96l 145 70 shy 130 20 EPA 2008 Mod
Chromium 70707 1288 107 138 70-130 20 EPA 2008 Mod
Manganese 60606 7230 804 00140 70- 130 20 EPA 2008 Mod
Iron 50505 6065 983 0414 70- 130 20 EPA 2008 Mod
Nickel 40404 3378 872 138 70 - 130 20 EPA2008 Mod
Copper 40404 5140 823 0807 70 - 130 20 EPA 2008 Mod
Arsenic 15152 1928 102 123 70 - 130 20 EPA 2008 Mod
Selenium 30303 9063 105 255 70- 130 20 EPA 2008 Mod
Silver 15152 1075 709 219 70- 130 20 EPA 2008 Mod
Cadmium 80808 9347 849 170 70- 130 20 EPA 2008 Mod
Lead 15152 1531 960 0815 70- 130 20 EPA 2008 Mod
Frontier Global Sciences Inc The results In this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
PageBo20 1203203 FinalReport- SWWTFREV2
04042012
Liz Siska Project Manager 12
iii
11720 North Creek Parkway North Suite 400
Bothell WA 98011 Ph 425-686-1996 Fx 425-686-3096 GlOBAL SCIENCES
ij
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203203-01
Batch F203232 Sequence 2Q20001
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203232-MSMSD3
Analyte
Sample Concentration
(microgL)
Spike Added (pgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Limits Method Notes
Aluminum 3707 10000 10270 990 70 - 130 EPA 2008 Mod AS
Chromium 5316 10000 1137 108 70 - 130 EPA 2008 Mod AS Manganese 7181 10000 8207 103 70 - 130 EPA 2008 Mod AS
Iron 1098 50000 6185 102 70 - 130 EPA 2008 Mod AS Nickel 3025 12500 1433 905 70 - 130 EPA 2008 Mod AS Copper 1816 12500 1061 834 70 - 130 EPA 2008 Mod AS Zinc 7752 25000 1995 767 70 - 130 EPA 2008 Mod AS Arsenic 3770 10000 1073 104 70 - 130 EPA 2008 Mod AS Selenium 587l 10000 1530 943 70 - 130 EPA 2008 Mod AS Silver ND 50000 3690 738 70 - 130 EPA 2008 Mod AS Cadmium 2484 10000 8531 828 70 - 130 EPA 2008 Mod AS Lead 0763 25000 2505 999 70 - 130 EPA 2008 Mod AS
middoti
i
Aoalyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD o
Recovery
RPD Recovery
Limits RPDLimit Method Notes
Aluminum 10000 10150 978 121 70 - 130 20 EPA 2008 Mod AS Chromium 10000 1140 109 0293 70 - 130 20 EPA 2008 Mod AS Manganese 10000 8278 llO 0854 70 -130 20 EPA 2008 Mod AS Iron 50000 6243 103 0937 70-130 20 EPA 2008 Mod AS Nickel 12500 1441 91l middotos25 70 - 130 20 EPA 2008 Mod AS Copper 12500 1066 838 0496 70- 130 20 EPA 2008 Mod AS Zinc 25000 1990 765 0245 70- 130 20 EPA 2008 Mod AS Arsenic 10000 1094 106 193 70 - 130 20 EPA 2008 Mod AS Selenium 10000 1554 967 155 70 - 130 20 EPA 2008 Mod AS Silver 50000 3682 736 0222 70 - 130 20 EPA 2008 Mod AS Cadmium 10000 8394 815 l62 70 - 130 20 EPA 2008 Mod AS Lead 25000 250S 999 00263 70- 130 20 EPA 2008 Mod AS
~~ middotmiddot1 bull
bulli
bullmiddot
Frontier Global Sciences Inc The remits in this report only apply lo the samples analyzed in accordance with the chain ofcustody document This analytical report must bt reproductd In Its entirety
Page 9of20 1203203 Final Report-SWWTF REY2
04M2012
Liz Siska Project Manager 13
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 FRONTIER~ Fx 425-686-3096 GLOBAL SCIENCES
MATR1X SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203203-01RE3
Batch F203260 Sequence 2C22001
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203260-MSMSD3
Analyte
Sample Concentration
(microgL)
Spike Added (microgL)
MS Conctntration
(microgL)
MS
Recovery Recovery
Method Limits Notes
Molybdenum 1999 20200 middot 2041 206 70 - 130 EPA 2008 Mod QM-02
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD Oo
Recovery
RPD
Recovery Limits
RPO Limit Method Notes
Molybdenum 20200 2041 207 00141 70 - 130 20 EPA 2008 Mod QM-02
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed In accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page Oo20 1203203 Final Report- SWWTFREV2
04042012
Liz Siska Project Manager 14
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyzed in accordance with the chain ofcustody document This analytical report =tbe reproducedin Its entirety
Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
CLO~AL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1203203-0lREJ
Batch F203260
Preparation Closed Vessel Nitric Oven Digestion
Sequence 2C2200
Lab Number F203260-MSMSD6
Sample Spike MS MS
Analyte Concentration Added
(JtgL) (microgL) Concentration
(microgL)
Recovery Recovery
Method Limits Notes
Molybdenum 1999 50000 7034 101 70 - 130 EPA 2008 Mod AS
Spike MSD Added Concentration
MSD Recovery RPD
Analyte (microgL) (microgL) Recovery RPD Limits Limit Method Notes
Molybdenum 50000 7124 102 128 70 - 130 20 EPA 2008 Mod AS
Page 11 o20 1203203 Final Report- SWWTF REJ2
040412012
15
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 ~ Fx 425-686-3096 GLOBAL SCIENCES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203203-01
Batch F203288
Preparation BrCI Oxidation
Sequence 2C22016
Lab Number F203288-MSMSD 1
Sample Spike MS MS Concentration Added Concentration Recovery
Analyte (ngL) (ogL) (ogL) Recovery Method Notes Limits
Mercury 6116 25500 3096 974 71 - 125 EPA 1631E
Spike MSD MSD Oo Recovery RPD Added Concentration Oo
Limits Method Notes (ogL) (ogL) Recovery RPD Limit Analyte
Mercury 25500 2611 784 170 71 - 125 24 EPA 1631E
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed i11 accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 12of20 1203203 Final Report- SWWTF REV2
04042012
Liz Siska Project Manager 16
bull 11720 North Creek Parkway North Suite 400
Bothell WA 98011 Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1203194-17
Batch F203288 Sequence 2C22016
Preparation BrCI Oxidation Lab Number F203288-MSMSD2
Sample Spike MS MS
Analyte Concentration
(ngL) Added (ngL)
Concentration (ngL) Recovery
Recovery Limits Method Notes
Mercury 142800 505000 627200 959 71 - 125 EPA 1631E
Spike Added
MSD Concentration
MSD Recovery RPO
Analyte (ngL) (ngL) Recovery RPD Limits Limit Method Notes
Mercury 505000 632700 970 0879 71 - 125 24 EPA 1631E
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody docu~nt This analytical report must be reproduced In its entirety
Page 13of20 1203203 Final Report- SWWTFREV2
04042012
Liz Siska Project Manager 17
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996
bull ~ Fx 425-686-3096 GLPBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203232 Sequence 2C20001
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203232-BSBSD1
LCS Source mank Siiike
Spike LCS LCS Added Concentration Recovery
Analyte (microgL) (microgL) Recovery Limits Method Notes
Aluminwn 15000 1444 963 85-115 EPA2008Mod Chromium 70000 654 934 85 bull 115 EPA 2008 Mod Manganese 60000 580 967 85 - 115 EPA 2008 Mod Iron 50000 4610 922 85 - 115 EPA 2008 Mod Nickel 40000 394 985 85 ll5 EPA 2008 Mod Copper 40000 418 104 85 - 115 EPA 2008 Mod Zinc 10000 1017 102 85 bull 115 EPA 2008 Mod Arsenic 15000 1445 963 85 bull 115 EPA 2008 Mod Selenium 30000 2975 992 85-115 EPA2008Mod Molybdenum 20000 185 926 85 bull 115 EPA 2008 Mod Silver 15000 1555 104 85 - 115 EPA 2008 Mod
Cadmium 080000 0802 100 85 - 115 EPA 2008 Mod Lead 15000 1565 104 85 - 115 EPA 2008 Mod
shy
Spike LCSD LCSD Added Concentration Oo Recovery RPD
Analyte (microgL)
15000
(microgL)
1424
Recovery
949
RPD
140
Limits
85 bull 115
Limit
20
Method
EPA 2008 Mod
Notes
Aluminum
Chromium 70000 644 920 l58 85 bull 115 20 EPA 2008 Mod
Manganese 60000 575 958 0920 85 - ll5 20 EPA 2008 Mod
Iron 50000 4580 916 0660 85 - 115 20 EPA 2008 Mod
Nickel 40000 394 985 000457 85 bull 115 20 EPA 2008 Mod
Copper 40000 416 104 0367 85 - 115 20 EPA 2008 Mod
Zinc 10000 1032 103 147 85 - ll5 20 EPA 2008 Mod
Arsenic 15000 1440 960 0305 85 bull 115 20 EPA 2008 Mod
Selenium 30000 2867 956 369 85 -115 20 EPA 2008 Mod
Molybdenum 20000 l86 928 0196 85 -115 20 EPA2008 Mod
Silver l5000 1559 104 0233 85 bull 115 20 EPA 2008 Mod
Cadmium 080000 0809 101 0843 85 bull llS 20 EPA 2008 Mod
Lead 15000 l539 103 170 85 - 115 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed In accordance with the chain ofcustody document This analytical report must be reproduced in its enJirety
Page 14of20 1203203 Final Report- SWWTFREV2
04042012 ~~
Liz Siska Project Manager 18
11720 North Creek Parkway North Suite 400 Bothell WA 98011 Ph 425-686-1996
FRONTIER Fx 425-686-3096 GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203260 Sequence 2C22001
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203260-BSBSD1
LCS Source Blank Spike
Spike LCS LC$ Added Concentration Recovery
Analyte (ptgL) (JJgL) Recovery Limits Method Notes
Molybdenum 20000 182 910 85 - 115 EPA 2008 Mod
Spike LCSD LCSD Added Concentration Recovery RPD
Analyte (microgL) (microgL) Recovery RPD Limits Limit Method Notes
Molybdenum 20000 186 930 213 85 -115 20 EPA 2008 Mod
Frontier Global Sciences Inc The results In this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced In its entirety
Page 15 o20 I203203 Ftnal ampport- SWWTFREV2
04041202
Liz Siska Project Manager 19
middot
I
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SC IE NC ES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPO
Batch F203288 Sequence 2C22016
Preparation BrCI Oxidation Lab Number F203288-BSBSD I
LCS Source NIST 1641d
Spike LCS LCS Added Concentration Recovery
Analyte (ngL) (ngL) Recovery Limits Method Notes
Mercury 15679 1525 973 80 - 120 EPA l631E
Spike LCSD LCSD Added Concentration Oo Recovery RPD
Analyte (ngL) (ngL)
1516
Recovery
967
RPD
0622
Limits
80 - 120
Limit
24
Method
EPA 1631E
Notes
Mercury 15679
Frontier Global Sciences Inc The results in this report only apply lo the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 16 o20 1203203 Final Report- SWWIFREV2
041042012
20Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 middot Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096 ~ O GLO B AL SCI E NCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2C20001
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203232-BLK1 Aluminum 01 40 microgL F203232 PA2008 Molt u F203232-BLK1 Chromium -0007 0 10 microgL F203232 PA 2008 Molt u F203232-BLKI Manganese 0002 010 microgL F203232 PA 2008 Moc u F203232-BLK1 Iron -004 100 microgL F203232 PA 2008 Molt u F203232-BLKI Nickel 0005 010 microgL F203232 PA 2008 Moc u F203232-BLKI Copper 001 010 microgL F203232 PA 2008 Molt u F203232-BLK1 Zinc 011 020 microgL F203232 PA 2008 Moc u F203232-BLK I Arsenic -0009 015 microgL F203232 PA 2008 Moc u F203232-BLK1 Selenium 025 060 microgL F203232 PA 2008 Moc u F203232-BLK1 Molybdenum 001 006 microgL F203232 PA 2008 Moc u F203232-BLK1 Silver -00009 0020 microgL F203232 PA 2008 Moc u F203232-BLK1 Cadmium 0002 0020 microgL F203232 PA 2008 Molt u F203232-BLK1 Lead 0024 0040 microgL F203232 PA 2008 Molt u
middoti
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordonce with the chain ofcustody document Tnts analytical rtport must be reproduced In its enlfrtty
Page7of20 J203203 Final ampport-SWWTF REV2
04042012
Liz Siska Project Manager 21
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 FRONTIER~ Fx 425-686-3096 GLOBAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2C22001
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203260-BLK1 Molybdenum 001 006 microgL F203260 ~PA 2008 Moc u
Frontier Global Sciences Inc middot The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 18of20 1203203 Final Report- SWWTFREV2
04042012
Liz Siska Project Manager 22
~ CLOSAL SCIENCES
~
J1720 North Creek Parkway North Suite 400 Bothell WA 980 l l
Ph 425-686-1996 Fx 425-686-3096
PREPARATION BLANKS
Instrument Hg-17 Sequence 2C22016
Preparation BrCI Oxidation
The results in Ihis report only apply to the samples analyzed i12 accordance with the chain ofcustody dccumnt This analytical report must be reproductd in ils enJirety
Page I9oj20 1203203 Final Report- SWWTF REJ2
04042012
Frontier Global Sciences Inc
bull 23bull Liz Siska Project Manager
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203288-BLKl Mercury 007 050 ngL F203288 EPA 1631E u F203288-BLIlt2 Mercury 006 050 ngL F203288 EPA 163lE u F203288-BLK3 Mercury 006 050 ngL F203288 EPA I63lE u F203288-BLK4 Mercury 018 050 ngL F203288 EPA I63IE U QB-04
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
Notes and Definitions
U Analyte included in the analysis but not detected
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than I times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable ASASD
QB-04 The blank was preserved to 2 BrCl rather than I The control limit for blanks presetved to greater than 1 BrCl is the preservation percentage multiplied by the l1RL
FB-1631 Required equipmentfieldfilter blank not submitted by the client The sample has been analyzed according to 163 lE but does not meet 163 lE criteria
AS This MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
l1RL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to lhe samples analyzedin accordance wirh the chain ofcustody document This analytical report must be reproduced in its entirety
Page 20of20 1203203 Final Report- SWWTF REV2
04042012
24
bull bull
irGl Lu Ull 0111C H AIN-OF-CUSTODY RECORD Page of_~~
Bolo FIELDS REQUIRED P LEASE CIRCLE REQUESTED ANALYs1s Lt) CN voe I svoc TClPI M ETALS INORGANICS
i w I shy i
SAMPLING 0 iii 0 ~
w = ~ DATET1ME QIll c X
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INDICATE 80TH ~ bulllo- t5a5 START amp FINISH
er Ill liSAMPLE 1 0 i ct -a ~shyDATEITIME l r ~~
bull 7gtItJJJI JWj T ~ tlt
IHAnlX A-Ala S-SOIL GW-GROUHD WATEl SW-SURfACE WATEA DW-DllNIING WAm WW-WAITE WATEl
PWETAJllt H-HCL N-HNO S-HJO Na-NaOHmiddot H-HEOH
i ~~ ~ I ~ X
j i I i= -shy 2 s~ ~ == a~ -shy I t
~~ =~ 2 ~~
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~ - I 2lte E55 NOTESili I j HEOHVIAl 6shy ~a 3
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1
DATE NEEDED b171i1-1~ 1 f METALS 8 RCRA 13 PP FE MN Ps CUPROJECT MANAGER 0v f-e_~ Tmamp- middotc COMPANY pdegZ1)shy 0THE1 METALS __________REPORTING OPTIONSQAQC ICH) NoAonms Jfru lli V =1 Q ) REPORTING LEVEL PUUHS ~OR No
A B C 0lOLYpoundD METALS FIELD flLTtREDI YE NoIF YE F~ oa(ITT STAil~l4t(= ~ ZIP rriu1 NOTES (IE SPEOAl DETECTION LIHIIS BIWNG INFO IF D1mam)PHONE _r~ _z31_ - $ I3 Exr--- OR ELECTRONIC OPTIONSFAX _ __________________ AI l A C J C bull C1
J pbNo FAX E-MAIL PDF EQUIS
E-MAIL tivl el qu ~ pv CvVshyf J --~b Mo ~ tJ k ttJ -z~Sm NAHE W
PROJECT ____________ ___ ___ _ ~111216- aJd M fer P4 jgtZJ)shy
SUTt MA ME VT OTHER _____ ___ ~ 1)--U ( u-middotmiddottut-UJ f bull
REGULATORY PROGRAM NPDES RGP POnY STOilKWATER Ol SITE HISTORY ~i tiT f=
GWP OIL FUND BROWNFJUD OR Orm--------shy RELINQUISHED BY DATE TIME RECEIVED Br Summo (ONTAHINATIOM_______
PO_______QUOTE===-~----shy I RELINQUISHED BY DATE TIME Rmmo BT I FIElllJUDINGStt HI l lS 2
eastern analytical inc 2s CHENELl DR1ve I CoNcoRo NH 03301 I TEL 60322sos2s I 1soo2s7os2s IFAXc 6032284591 I E-MA1l cusToMER_seRv1ceEA1LAascoHj wwweA1lAsscoM
prufmin111ll11bomtory1m1im (WHITE ORIGINAL GREEN PROJECT MANAGER)
shy
shy
QC REPORT EAIID 10842011Jul Client GZA GeoEnvironmental Inc (NH)
Client Designation MK
Date of
Parameter Name Blank LCS LCSO Units Analysis Limits RPO Method
Solids Suspended lt5 96 (96 ooR) 100 (100 ooR) (4 RPO) mgL 31912 90 -110 20 2540D
Solids Dissolved lt5 990 (99 R) NA mgL 31912 85 - 115 20 2540C
Chloride lt 1 27 (106 ooR) 26 (106 ooR) (0 RPD) mgL 31912 90 - 110 20 4500CIE
BOD lt6 400 (100 R) 410 (102 R) (2 RPD) mgL 31512 84-115 20 52108
COD lt 10 100 (97 R) 100 (101 R) (4 RPD) mgL 32012 85 -115 20 H8000
pH 60 (100 ooR) 60 (100 ooR) (0 RPD) SU 31412 595 - 607 10 4500H+B
Duplicate Duplicate Date of Parameter Name Parent ID Parent Duplicate Units Analysls RPO Method
Solids Suspended 10850303 200 190 (4RPD) mgL 31912 20 2540D Solids Dissolved 10843101 270 270 (0 RPO) mgL 31912 20 2540C Chloride NA NA mgL 31912 20 4500CIE BOD NA NA mgL 31512 20 52108 COD NA NA mgl 32012 20 H8000 pH 10838601 82 82 (0 RPO) SU 31412 10 4500H+B
Samples were analyzed within holding times unless noted on the sample results page Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits The associated matrix spikes andor Laboratory Control Samples met the above stated criteria Exceptions to the above statements are flagged or noted above or on the QC Narrative page bull11 Flagged analyte recoveries deviated from the QAQC limits
eastern analytical inc wwweailabscom Phone (603) 228-0525 3
Ill
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
G L OS AL S ( I E N lt ES
04 April 2012
JeffGagne
Eastern Analytical Inc
25 Chenell Drive
Concord NH 03301
RE Merrimack Station 2008
Enclosed are the analytical results for samples received by Frontier Global Sciences All quality control
measurements are within established control limits and there were no analytical difficulties encountered
with the exception ofthose listed in the case narrative section of this report
Ifyou have any questions concerning this report please feel free to contact me
Sincerely 44
Liz Siska
Project Manager
4
~ 11720 North Creek Parkway North Suite 400
Bothell WA 9801 1 Ph 425-686-1996 Fx 425-686-3096
GLOBAl SCIENCES
ANALYTICAL REPORT FOR SAMPLES
Laboratory Frontier Global Sciences Inc SDG
Client Eastern Analytical ]nc Project Merrimack Station 2008
Sample ID Lab ID Matrix Date Sampled Date Received
SWWTF 1203203-01 Water 14-Mar-12 1305 16-Mar-12 0940
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Pagel o20 1203203 Final Report-SWWTF REV2
041042012
Liz Siska Project Manager 5
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
CASE NARRATIVE
Revised Report 4412- Sample name corrected to SWWTF
SAMPLE RECEIPT
Samples were received at Frontier Global Sciences (FGS) on March 16th 2012 The samples were received intact on-ice with temperatures measuredat 22 degrees Celsius
SAMPLE PREPARATION AND ANALYSIS
Samples were prepared and analyzed for total metals in accordance with EPA Method 2008 (modified)
Samples were prepared and analyzed for total mercury in accordance with EPA Method 163 JE
ANALYTICAL ISSUES
The client requested sample SWWTF (1203203-0 l) be analyzed for Mn via email on 31512
Samples were received in a cooler ofmelted ice There was water in the inner most bag of sample Evaporator (1203203-02)
As an additional measure ofthe accuracy ofthe methods utilized for analysis and to check for matrix interference matrix spikes (MS) and matrix spike duplicates (MSD) were digested and analyzed All ofthe matrix spike recoveries were within the control limits with the exception ofany QC flagged and described in the notes and definitions section ofthe following report
A reasonable measure ofthe precision ofthe analytical methods utilized for analysis is the relative percent difference (RPD) between matrix spike and matrix spike duplicate recoveries and between laboratory control sample and laboratory control sample duplicate recoveries All of the relative percent differences were within the control limits with the exception ofany QC flagged and described in the notes and definitions section ofthe following report
Frontier Global Sciences Inc The results in this report 011y apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 2 of20 1203203 Final Report- SWWTF REV2
04042012
Liz Siska Project Manager 6
FRONTIER
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIE NCES
CHAIN OF CUSTODY FORMS
bullbull _ ~ -bull uer ( A c 2 - gt Sampre Recefpt CHockJlst
Data Looobulld tn ~tZfrPkttr ~~middot0 middot1)d bull MSi~~gtamp Loss bull d I n Sy
SOG o f Coolns- R~oetvbullG I ( FGSPM
Sarn01 AnIVed bull)I ----Shipp ing --=--___~~-=-------=_lta=~-=--===---------
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middot c Cooler a bullc middot c
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Olbull~bullronJRbullbullo1utlon
The results in this report only apply to the samples analy-ed in accordance with the Frontier Global Sciences Inc chain ofcustody docutMnt This aMlytical report must be reprodu~d in its e111irety
Page3of20 1203203 Final Rtport- SWWTFREV2
04042012
Liz Siska Project Manager 7
l l 720 North Creek Parkway Nortn u1Le -tvv Bothell WA 9amp011
Ph 425-686-1996 Fx 425-686-3096
FRONTIER GLOBAL SCIENCES
CHAIN OF CUSTODY FORMS
The results in this report only apply to the samples analyzed in accordance with the cliain ofcustody documenL This analytical report must be reproduced in its entirety
Frontier Global Sciences Inc Page 4 o20 1203203 Final Report- SWWTF REV2
04042012
Liz Siska Project Manager
8
11720 North Creek Parkway North Suite 40U Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
FRONTIER C L 0 B AL SC I~ NC ES
CHAlN OF CUSTODY FORMS
i---t--+-l-+-+-+--+--+--+--+_micro~[_amp~lslte---l t---t--+--11-(- -1--+-~-+--l---l---+----------f_ rmiddot 1---+--~--l--f-+---l--l--l-+--I--I---- _____--1 lt 1--1--1--+--l--------4-+-+--l--+-+--____f_ i--t--+--1r-+-+-+-t-+-++-4-________ _j bull-
CN _r(gt --shyshy~
_lj _D ~ -~ Irgt ~ -f
~ ~
The results In this report onlyapply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reprodu~din its entirety
Frontier Global Sciences Inc Page 5 o20 T203203 Final Report-SWWTFREV2
ommo12
Liz SiskaProject Manager
9
)--J middot ~~
)J fl~~J~c1N~r
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
Matrix Water Laboratory ID 1203203-01
ANALYTICAL RESULTS
SWWTF
Analyte Result lIDL MRL Units Dilution Batch Sequence Analyzed Method Notes
Aluminum 371 220 198 microgL 5 F203232 2C2000l 031912 EPA 2008 Mod
Arsenic 377 252 743 microgL 5 F203232 2C2000l 031912 EPA 2008 Mod
Cadmium 248 0205 0990 microgL 5 F203232 2C20001 031912 EPA2008 Mod
Chromium 532 045 495 microgL 5 F203232 2C20001 031912 EPA 2008 Mod
Copper 182 050 495 microgL 5 F203232 2C20001 031912 EPA 2008 Mod
Iron 1100 644 495 microgL 5 F203232 2C20001 031912 EPA 2008 Mod
Lead ND 0193 198 microgL 5 F203232 2C2000l 031912 EPA 2008 Mod u Manganese 7180 037 495 microgL 5 F203232 2C2000l 031912 EPA 2008 Mod
Mercury 612 842 505 ngL 100 F203288 2C22016 032212 EPA l631E FB-1631
Molybdenum 2000 297 297 microgL 50 F203260 2C22001 032112 EPA 2008 Mod
Nickel 303 040 495 microgL 5 F203232 2C20001 031912 EPA 2008 Mod
Selenium 587 959 297 microgL 5 F203232 2C20001 031912 EPA 2008 Mod
Silver ND 0297 0990 microgL 5 F203232 2C20001 031912 EPA 2008 Mod u Zinc 775 081 990 microgL 5 F203232 2C20001 031912 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report 011ly apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page6 o20 I203203 Final Report- SWWTF REV2
04042012
Liz Siska Project Manager 10
gt
C LO BA L S CI E N C ES
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
MATRIX DUPLICATESTRIPLICATES
SOURCE 1203203-01
Batch F203288
Preparation BrCl Oxidation
Sequence 2C22016
Lab Number F203288-DUPI
Sample Duplicate Concentration Concentration RPD
Analyte DgL ngL
5848
MRL 505
RPD 448
Limit
24
Method
EPA 163IE
Notes
Mercury 6116
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced In its entirety
Page 7of20 l 103203 Final Report- SWWTF REV2
04042012 bull 1 1 Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996
FROlJTIER Fx 425-686-3096 GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203203-01
Batch F203232 Sequence 2C20001
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203232-MSMSD 1
Sample Spike MS MS Concentration Added Concentration 0o Recovery
Analyte (microgL) (microgL) (microgL) Recovery Method NotesLimits
Alumimun 3707 15152 1853 978 70 - 130 EPA 2008 Mod
Chromium 5316 70707 1270 104 70- 130 EPA 2008 Mod
Manganese 7181 60606 7231 821 70 - 130 EPA 2008 Mod
Iron 1098 50505 6090 988 70- 130 EPA 2008 Mod
Nickel 3025 40404 3425 988 70 - 130 EPA 2008 Mod
Copper 1816 40404 5182 833 70 - 130 EPA2008 Mod
Arsenic 3770 15152 1904 101 70- 130 EPA 2008 Mod
Seleniwn 587l 30303 9297 113 70 - 130 EPA 2008 Mod
Silver ND 15152 1099 725 70 - 130 EPA 2008 Mod
Cadmillll) 2484 80808 9508 869 70 - 130 EPA 2008 Mod
Lead 0763 15152 1544 968 70-130 EPA2008Mod
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD
Recovery
Oo
RPD Recovery
Limits RPOLimit Method Notes
Aluminum 15152 1826 96l 145 70 shy 130 20 EPA 2008 Mod
Chromium 70707 1288 107 138 70-130 20 EPA 2008 Mod
Manganese 60606 7230 804 00140 70- 130 20 EPA 2008 Mod
Iron 50505 6065 983 0414 70- 130 20 EPA 2008 Mod
Nickel 40404 3378 872 138 70 - 130 20 EPA2008 Mod
Copper 40404 5140 823 0807 70 - 130 20 EPA 2008 Mod
Arsenic 15152 1928 102 123 70 - 130 20 EPA 2008 Mod
Selenium 30303 9063 105 255 70- 130 20 EPA 2008 Mod
Silver 15152 1075 709 219 70- 130 20 EPA 2008 Mod
Cadmium 80808 9347 849 170 70- 130 20 EPA 2008 Mod
Lead 15152 1531 960 0815 70- 130 20 EPA 2008 Mod
Frontier Global Sciences Inc The results In this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
PageBo20 1203203 FinalReport- SWWTFREV2
04042012
Liz Siska Project Manager 12
iii
11720 North Creek Parkway North Suite 400
Bothell WA 98011 Ph 425-686-1996 Fx 425-686-3096 GlOBAL SCIENCES
ij
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203203-01
Batch F203232 Sequence 2Q20001
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203232-MSMSD3
Analyte
Sample Concentration
(microgL)
Spike Added (pgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Limits Method Notes
Aluminum 3707 10000 10270 990 70 - 130 EPA 2008 Mod AS
Chromium 5316 10000 1137 108 70 - 130 EPA 2008 Mod AS Manganese 7181 10000 8207 103 70 - 130 EPA 2008 Mod AS
Iron 1098 50000 6185 102 70 - 130 EPA 2008 Mod AS Nickel 3025 12500 1433 905 70 - 130 EPA 2008 Mod AS Copper 1816 12500 1061 834 70 - 130 EPA 2008 Mod AS Zinc 7752 25000 1995 767 70 - 130 EPA 2008 Mod AS Arsenic 3770 10000 1073 104 70 - 130 EPA 2008 Mod AS Selenium 587l 10000 1530 943 70 - 130 EPA 2008 Mod AS Silver ND 50000 3690 738 70 - 130 EPA 2008 Mod AS Cadmium 2484 10000 8531 828 70 - 130 EPA 2008 Mod AS Lead 0763 25000 2505 999 70 - 130 EPA 2008 Mod AS
middoti
i
Aoalyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD o
Recovery
RPD Recovery
Limits RPDLimit Method Notes
Aluminum 10000 10150 978 121 70 - 130 20 EPA 2008 Mod AS Chromium 10000 1140 109 0293 70 - 130 20 EPA 2008 Mod AS Manganese 10000 8278 llO 0854 70 -130 20 EPA 2008 Mod AS Iron 50000 6243 103 0937 70-130 20 EPA 2008 Mod AS Nickel 12500 1441 91l middotos25 70 - 130 20 EPA 2008 Mod AS Copper 12500 1066 838 0496 70- 130 20 EPA 2008 Mod AS Zinc 25000 1990 765 0245 70- 130 20 EPA 2008 Mod AS Arsenic 10000 1094 106 193 70 - 130 20 EPA 2008 Mod AS Selenium 10000 1554 967 155 70 - 130 20 EPA 2008 Mod AS Silver 50000 3682 736 0222 70 - 130 20 EPA 2008 Mod AS Cadmium 10000 8394 815 l62 70 - 130 20 EPA 2008 Mod AS Lead 25000 250S 999 00263 70- 130 20 EPA 2008 Mod AS
~~ middotmiddot1 bull
bulli
bullmiddot
Frontier Global Sciences Inc The remits in this report only apply lo the samples analyzed in accordance with the chain ofcustody document This analytical report must bt reproductd In Its entirety
Page 9of20 1203203 Final Report-SWWTF REY2
04M2012
Liz Siska Project Manager 13
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 FRONTIER~ Fx 425-686-3096 GLOBAL SCIENCES
MATR1X SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203203-01RE3
Batch F203260 Sequence 2C22001
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203260-MSMSD3
Analyte
Sample Concentration
(microgL)
Spike Added (microgL)
MS Conctntration
(microgL)
MS
Recovery Recovery
Method Limits Notes
Molybdenum 1999 20200 middot 2041 206 70 - 130 EPA 2008 Mod QM-02
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD Oo
Recovery
RPD
Recovery Limits
RPO Limit Method Notes
Molybdenum 20200 2041 207 00141 70 - 130 20 EPA 2008 Mod QM-02
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed In accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page Oo20 1203203 Final Report- SWWTFREV2
04042012
Liz Siska Project Manager 14
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyzed in accordance with the chain ofcustody document This analytical report =tbe reproducedin Its entirety
Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
CLO~AL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1203203-0lREJ
Batch F203260
Preparation Closed Vessel Nitric Oven Digestion
Sequence 2C2200
Lab Number F203260-MSMSD6
Sample Spike MS MS
Analyte Concentration Added
(JtgL) (microgL) Concentration
(microgL)
Recovery Recovery
Method Limits Notes
Molybdenum 1999 50000 7034 101 70 - 130 EPA 2008 Mod AS
Spike MSD Added Concentration
MSD Recovery RPD
Analyte (microgL) (microgL) Recovery RPD Limits Limit Method Notes
Molybdenum 50000 7124 102 128 70 - 130 20 EPA 2008 Mod AS
Page 11 o20 1203203 Final Report- SWWTF REJ2
040412012
15
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 ~ Fx 425-686-3096 GLOBAL SCIENCES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203203-01
Batch F203288
Preparation BrCI Oxidation
Sequence 2C22016
Lab Number F203288-MSMSD 1
Sample Spike MS MS Concentration Added Concentration Recovery
Analyte (ngL) (ogL) (ogL) Recovery Method Notes Limits
Mercury 6116 25500 3096 974 71 - 125 EPA 1631E
Spike MSD MSD Oo Recovery RPD Added Concentration Oo
Limits Method Notes (ogL) (ogL) Recovery RPD Limit Analyte
Mercury 25500 2611 784 170 71 - 125 24 EPA 1631E
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed i11 accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 12of20 1203203 Final Report- SWWTF REV2
04042012
Liz Siska Project Manager 16
bull 11720 North Creek Parkway North Suite 400
Bothell WA 98011 Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1203194-17
Batch F203288 Sequence 2C22016
Preparation BrCI Oxidation Lab Number F203288-MSMSD2
Sample Spike MS MS
Analyte Concentration
(ngL) Added (ngL)
Concentration (ngL) Recovery
Recovery Limits Method Notes
Mercury 142800 505000 627200 959 71 - 125 EPA 1631E
Spike Added
MSD Concentration
MSD Recovery RPO
Analyte (ngL) (ngL) Recovery RPD Limits Limit Method Notes
Mercury 505000 632700 970 0879 71 - 125 24 EPA 1631E
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody docu~nt This analytical report must be reproduced In its entirety
Page 13of20 1203203 Final Report- SWWTFREV2
04042012
Liz Siska Project Manager 17
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996
bull ~ Fx 425-686-3096 GLPBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203232 Sequence 2C20001
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203232-BSBSD1
LCS Source mank Siiike
Spike LCS LCS Added Concentration Recovery
Analyte (microgL) (microgL) Recovery Limits Method Notes
Aluminwn 15000 1444 963 85-115 EPA2008Mod Chromium 70000 654 934 85 bull 115 EPA 2008 Mod Manganese 60000 580 967 85 - 115 EPA 2008 Mod Iron 50000 4610 922 85 - 115 EPA 2008 Mod Nickel 40000 394 985 85 ll5 EPA 2008 Mod Copper 40000 418 104 85 - 115 EPA 2008 Mod Zinc 10000 1017 102 85 bull 115 EPA 2008 Mod Arsenic 15000 1445 963 85 bull 115 EPA 2008 Mod Selenium 30000 2975 992 85-115 EPA2008Mod Molybdenum 20000 185 926 85 bull 115 EPA 2008 Mod Silver 15000 1555 104 85 - 115 EPA 2008 Mod
Cadmium 080000 0802 100 85 - 115 EPA 2008 Mod Lead 15000 1565 104 85 - 115 EPA 2008 Mod
shy
Spike LCSD LCSD Added Concentration Oo Recovery RPD
Analyte (microgL)
15000
(microgL)
1424
Recovery
949
RPD
140
Limits
85 bull 115
Limit
20
Method
EPA 2008 Mod
Notes
Aluminum
Chromium 70000 644 920 l58 85 bull 115 20 EPA 2008 Mod
Manganese 60000 575 958 0920 85 - ll5 20 EPA 2008 Mod
Iron 50000 4580 916 0660 85 - 115 20 EPA 2008 Mod
Nickel 40000 394 985 000457 85 bull 115 20 EPA 2008 Mod
Copper 40000 416 104 0367 85 - 115 20 EPA 2008 Mod
Zinc 10000 1032 103 147 85 - ll5 20 EPA 2008 Mod
Arsenic 15000 1440 960 0305 85 bull 115 20 EPA 2008 Mod
Selenium 30000 2867 956 369 85 -115 20 EPA 2008 Mod
Molybdenum 20000 l86 928 0196 85 -115 20 EPA2008 Mod
Silver l5000 1559 104 0233 85 bull 115 20 EPA 2008 Mod
Cadmium 080000 0809 101 0843 85 bull llS 20 EPA 2008 Mod
Lead 15000 l539 103 170 85 - 115 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed In accordance with the chain ofcustody document This analytical report must be reproduced in its enJirety
Page 14of20 1203203 Final Report- SWWTFREV2
04042012 ~~
Liz Siska Project Manager 18
11720 North Creek Parkway North Suite 400 Bothell WA 98011 Ph 425-686-1996
FRONTIER Fx 425-686-3096 GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203260 Sequence 2C22001
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203260-BSBSD1
LCS Source Blank Spike
Spike LCS LC$ Added Concentration Recovery
Analyte (ptgL) (JJgL) Recovery Limits Method Notes
Molybdenum 20000 182 910 85 - 115 EPA 2008 Mod
Spike LCSD LCSD Added Concentration Recovery RPD
Analyte (microgL) (microgL) Recovery RPD Limits Limit Method Notes
Molybdenum 20000 186 930 213 85 -115 20 EPA 2008 Mod
Frontier Global Sciences Inc The results In this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced In its entirety
Page 15 o20 I203203 Ftnal ampport- SWWTFREV2
04041202
Liz Siska Project Manager 19
middot
I
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SC IE NC ES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPO
Batch F203288 Sequence 2C22016
Preparation BrCI Oxidation Lab Number F203288-BSBSD I
LCS Source NIST 1641d
Spike LCS LCS Added Concentration Recovery
Analyte (ngL) (ngL) Recovery Limits Method Notes
Mercury 15679 1525 973 80 - 120 EPA l631E
Spike LCSD LCSD Added Concentration Oo Recovery RPD
Analyte (ngL) (ngL)
1516
Recovery
967
RPD
0622
Limits
80 - 120
Limit
24
Method
EPA 1631E
Notes
Mercury 15679
Frontier Global Sciences Inc The results in this report only apply lo the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 16 o20 1203203 Final Report- SWWIFREV2
041042012
20Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 middot Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096 ~ O GLO B AL SCI E NCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2C20001
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203232-BLK1 Aluminum 01 40 microgL F203232 PA2008 Molt u F203232-BLK1 Chromium -0007 0 10 microgL F203232 PA 2008 Molt u F203232-BLKI Manganese 0002 010 microgL F203232 PA 2008 Moc u F203232-BLK1 Iron -004 100 microgL F203232 PA 2008 Molt u F203232-BLKI Nickel 0005 010 microgL F203232 PA 2008 Moc u F203232-BLKI Copper 001 010 microgL F203232 PA 2008 Molt u F203232-BLK1 Zinc 011 020 microgL F203232 PA 2008 Moc u F203232-BLK I Arsenic -0009 015 microgL F203232 PA 2008 Moc u F203232-BLK1 Selenium 025 060 microgL F203232 PA 2008 Moc u F203232-BLK1 Molybdenum 001 006 microgL F203232 PA 2008 Moc u F203232-BLK1 Silver -00009 0020 microgL F203232 PA 2008 Moc u F203232-BLK1 Cadmium 0002 0020 microgL F203232 PA 2008 Molt u F203232-BLK1 Lead 0024 0040 microgL F203232 PA 2008 Molt u
middoti
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordonce with the chain ofcustody document Tnts analytical rtport must be reproduced In its enlfrtty
Page7of20 J203203 Final ampport-SWWTF REV2
04042012
Liz Siska Project Manager 21
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 FRONTIER~ Fx 425-686-3096 GLOBAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2C22001
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203260-BLK1 Molybdenum 001 006 microgL F203260 ~PA 2008 Moc u
Frontier Global Sciences Inc middot The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 18of20 1203203 Final Report- SWWTFREV2
04042012
Liz Siska Project Manager 22
~ CLOSAL SCIENCES
~
J1720 North Creek Parkway North Suite 400 Bothell WA 980 l l
Ph 425-686-1996 Fx 425-686-3096
PREPARATION BLANKS
Instrument Hg-17 Sequence 2C22016
Preparation BrCI Oxidation
The results in Ihis report only apply to the samples analyzed i12 accordance with the chain ofcustody dccumnt This analytical report must be reproductd in ils enJirety
Page I9oj20 1203203 Final Report- SWWTF REJ2
04042012
Frontier Global Sciences Inc
bull 23bull Liz Siska Project Manager
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203288-BLKl Mercury 007 050 ngL F203288 EPA 1631E u F203288-BLIlt2 Mercury 006 050 ngL F203288 EPA 163lE u F203288-BLK3 Mercury 006 050 ngL F203288 EPA I63lE u F203288-BLK4 Mercury 018 050 ngL F203288 EPA I63IE U QB-04
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
Notes and Definitions
U Analyte included in the analysis but not detected
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than I times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable ASASD
QB-04 The blank was preserved to 2 BrCl rather than I The control limit for blanks presetved to greater than 1 BrCl is the preservation percentage multiplied by the l1RL
FB-1631 Required equipmentfieldfilter blank not submitted by the client The sample has been analyzed according to 163 lE but does not meet 163 lE criteria
AS This MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
l1RL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to lhe samples analyzedin accordance wirh the chain ofcustody document This analytical report must be reproduced in its entirety
Page 20of20 1203203 Final Report- SWWTF REV2
04042012
24
bull bull
irGl Lu Ull 0111C H AIN-OF-CUSTODY RECORD Page of_~~
Bolo FIELDS REQUIRED P LEASE CIRCLE REQUESTED ANALYs1s Lt) CN voe I svoc TClPI M ETALS INORGANICS
i w I shy i
SAMPLING 0 iii 0 ~
w = ~ DATET1ME QIll c X
w ~sacw 0IF COMPOSITE -gtc ~ u - ~
INDICATE 80TH ~ bulllo- t5a5 START amp FINISH
er Ill liSAMPLE 1 0 i ct -a ~shyDATEITIME l r ~~
bull 7gtItJJJI JWj T ~ tlt
IHAnlX A-Ala S-SOIL GW-GROUHD WATEl SW-SURfACE WATEA DW-DllNIING WAm WW-WAITE WATEl
PWETAJllt H-HCL N-HNO S-HJO Na-NaOHmiddot H-HEOH
i ~~ ~ I ~ X
j i I i= -shy 2 s~ ~ == a~ -shy I t
~~ =~ 2 ~~
~ X a c 2 ~ ~ = -- 2 ~
l j t z i () ~
C 0 5~ s~ = IC 0
C -s ~ = ~ ~e f
0 ~= ~ _sC a ~ C) -shyt( I rt
1 g0
3 i ~-
]-
f~ js~ i
~bull m = olt 1 o(
1 e
j
M ICRO middot-- -shy108420
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sect= s
~ - I 2lte E55 NOTESili I j HEOHVIAl 6shy ~a 3
I 3 ~ It _ c
1
DATE NEEDED b171i1-1~ 1 f METALS 8 RCRA 13 PP FE MN Ps CUPROJECT MANAGER 0v f-e_~ Tmamp- middotc COMPANY pdegZ1)shy 0THE1 METALS __________REPORTING OPTIONSQAQC ICH) NoAonms Jfru lli V =1 Q ) REPORTING LEVEL PUUHS ~OR No
A B C 0lOLYpoundD METALS FIELD flLTtREDI YE NoIF YE F~ oa(ITT STAil~l4t(= ~ ZIP rriu1 NOTES (IE SPEOAl DETECTION LIHIIS BIWNG INFO IF D1mam)PHONE _r~ _z31_ - $ I3 Exr--- OR ELECTRONIC OPTIONSFAX _ __________________ AI l A C J C bull C1
J pbNo FAX E-MAIL PDF EQUIS
E-MAIL tivl el qu ~ pv CvVshyf J --~b Mo ~ tJ k ttJ -z~Sm NAHE W
PROJECT ____________ ___ ___ _ ~111216- aJd M fer P4 jgtZJ)shy
SUTt MA ME VT OTHER _____ ___ ~ 1)--U ( u-middotmiddottut-UJ f bull
REGULATORY PROGRAM NPDES RGP POnY STOilKWATER Ol SITE HISTORY ~i tiT f=
GWP OIL FUND BROWNFJUD OR Orm--------shy RELINQUISHED BY DATE TIME RECEIVED Br Summo (ONTAHINATIOM_______
PO_______QUOTE===-~----shy I RELINQUISHED BY DATE TIME Rmmo BT I FIElllJUDINGStt HI l lS 2
eastern analytical inc 2s CHENELl DR1ve I CoNcoRo NH 03301 I TEL 60322sos2s I 1soo2s7os2s IFAXc 6032284591 I E-MA1l cusToMER_seRv1ceEA1LAascoHj wwweA1lAsscoM
prufmin111ll11bomtory1m1im (WHITE ORIGINAL GREEN PROJECT MANAGER)
shy
shy
Ill
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
G L OS AL S ( I E N lt ES
04 April 2012
JeffGagne
Eastern Analytical Inc
25 Chenell Drive
Concord NH 03301
RE Merrimack Station 2008
Enclosed are the analytical results for samples received by Frontier Global Sciences All quality control
measurements are within established control limits and there were no analytical difficulties encountered
with the exception ofthose listed in the case narrative section of this report
Ifyou have any questions concerning this report please feel free to contact me
Sincerely 44
Liz Siska
Project Manager
4
~ 11720 North Creek Parkway North Suite 400
Bothell WA 9801 1 Ph 425-686-1996 Fx 425-686-3096
GLOBAl SCIENCES
ANALYTICAL REPORT FOR SAMPLES
Laboratory Frontier Global Sciences Inc SDG
Client Eastern Analytical ]nc Project Merrimack Station 2008
Sample ID Lab ID Matrix Date Sampled Date Received
SWWTF 1203203-01 Water 14-Mar-12 1305 16-Mar-12 0940
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Pagel o20 1203203 Final Report-SWWTF REV2
041042012
Liz Siska Project Manager 5
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
CASE NARRATIVE
Revised Report 4412- Sample name corrected to SWWTF
SAMPLE RECEIPT
Samples were received at Frontier Global Sciences (FGS) on March 16th 2012 The samples were received intact on-ice with temperatures measuredat 22 degrees Celsius
SAMPLE PREPARATION AND ANALYSIS
Samples were prepared and analyzed for total metals in accordance with EPA Method 2008 (modified)
Samples were prepared and analyzed for total mercury in accordance with EPA Method 163 JE
ANALYTICAL ISSUES
The client requested sample SWWTF (1203203-0 l) be analyzed for Mn via email on 31512
Samples were received in a cooler ofmelted ice There was water in the inner most bag of sample Evaporator (1203203-02)
As an additional measure ofthe accuracy ofthe methods utilized for analysis and to check for matrix interference matrix spikes (MS) and matrix spike duplicates (MSD) were digested and analyzed All ofthe matrix spike recoveries were within the control limits with the exception ofany QC flagged and described in the notes and definitions section ofthe following report
A reasonable measure ofthe precision ofthe analytical methods utilized for analysis is the relative percent difference (RPD) between matrix spike and matrix spike duplicate recoveries and between laboratory control sample and laboratory control sample duplicate recoveries All of the relative percent differences were within the control limits with the exception ofany QC flagged and described in the notes and definitions section ofthe following report
Frontier Global Sciences Inc The results in this report 011y apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 2 of20 1203203 Final Report- SWWTF REV2
04042012
Liz Siska Project Manager 6
FRONTIER
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIE NCES
CHAIN OF CUSTODY FORMS
bullbull _ ~ -bull uer ( A c 2 - gt Sampre Recefpt CHockJlst
Data Looobulld tn ~tZfrPkttr ~~middot0 middot1)d bull MSi~~gtamp Loss bull d I n Sy
SOG o f Coolns- R~oetvbullG I ( FGSPM
Sarn01 AnIVed bull)I ----Shipp ing --=--___~~-=-------=_lta=~-=--===---------
___Nona (ArnblbullnQ
SbullNfo Cour1bullr TrecklngJAtrtgtIII Nubbulltbull) e Xlt---Z-~q gt
-rhermal PreuorvatJon Loo~ l~ ___GeleJubull lea
rT~hbull_ornebullur_10~gt~(~5z2~_--CorrftCtfan rbullclOf (Cfl) ~lt2 - 3 degre-bull O eoolbullr- 1 L ~ middoto CoCttbullr a bullc eoolbullr-2 middot c Cootbullr7 middotc
middot c Cooler a bullc middot c
middotc middot c
Coolar 18
Chbullln orCutody COO $ pria1-ct-n bullnd lneludee thbull folto~ng Information for obulloh ~~mple
NA Comrnbullnta
Sbullrnolampd BvshyPrbullbullation bullmiddot ~uoa1bulld Ana1vbullbullbullmiddot Roaulbulld SlcnHt vrbullr
middot------------ shy ---ilnt-nat chaln or custOdv irv1d
l-~=V
---l shy ---+--~-shy ----+-----------1
Samplbull CondltJonltnte-oi $bullmole containerbull wbullra -oehbulld Jr1tlact bull--bull labolbull bullshy _nt bulln lenfbln
lteon-eet aamIbull oontarners U ~ltftd fcrr reauect1Dd 0rnafv8ebull sbullm-reraquo roCHtlvOd In holdrna tlmomiddot bullbullrn- bull vohnlIbull auMolen ~~r raubullbulltbulld anaalvbull a
Voa No
CotTbulld orbullbullbulltvotlvbull ucact for aue atect -nahrbull _ -shyM of bull-n~tshy Qhertced a-d mthod l~e-ntbull -
Cllent Communloatfott Po~ Contaicta Oat611mbull _____ _
Commentbull
Mbulltnod ____ _
Olbull~bullronJRbullbullo1utlon
The results in this report only apply to the samples analy-ed in accordance with the Frontier Global Sciences Inc chain ofcustody docutMnt This aMlytical report must be reprodu~d in its e111irety
Page3of20 1203203 Final Rtport- SWWTFREV2
04042012
Liz Siska Project Manager 7
l l 720 North Creek Parkway Nortn u1Le -tvv Bothell WA 9amp011
Ph 425-686-1996 Fx 425-686-3096
FRONTIER GLOBAL SCIENCES
CHAIN OF CUSTODY FORMS
The results in this report only apply to the samples analyzed in accordance with the cliain ofcustody documenL This analytical report must be reproduced in its entirety
Frontier Global Sciences Inc Page 4 o20 1203203 Final Report- SWWTF REV2
04042012
Liz Siska Project Manager
8
11720 North Creek Parkway North Suite 40U Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
FRONTIER C L 0 B AL SC I~ NC ES
CHAlN OF CUSTODY FORMS
i---t--+-l-+-+-+--+--+--+--+_micro~[_amp~lslte---l t---t--+--11-(- -1--+-~-+--l---l---+----------f_ rmiddot 1---+--~--l--f-+---l--l--l-+--I--I---- _____--1 lt 1--1--1--+--l--------4-+-+--l--+-+--____f_ i--t--+--1r-+-+-+-t-+-++-4-________ _j bull-
CN _r(gt --shyshy~
_lj _D ~ -~ Irgt ~ -f
~ ~
The results In this report onlyapply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reprodu~din its entirety
Frontier Global Sciences Inc Page 5 o20 T203203 Final Report-SWWTFREV2
ommo12
Liz SiskaProject Manager
9
)--J middot ~~
)J fl~~J~c1N~r
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
Matrix Water Laboratory ID 1203203-01
ANALYTICAL RESULTS
SWWTF
Analyte Result lIDL MRL Units Dilution Batch Sequence Analyzed Method Notes
Aluminum 371 220 198 microgL 5 F203232 2C2000l 031912 EPA 2008 Mod
Arsenic 377 252 743 microgL 5 F203232 2C2000l 031912 EPA 2008 Mod
Cadmium 248 0205 0990 microgL 5 F203232 2C20001 031912 EPA2008 Mod
Chromium 532 045 495 microgL 5 F203232 2C20001 031912 EPA 2008 Mod
Copper 182 050 495 microgL 5 F203232 2C20001 031912 EPA 2008 Mod
Iron 1100 644 495 microgL 5 F203232 2C20001 031912 EPA 2008 Mod
Lead ND 0193 198 microgL 5 F203232 2C2000l 031912 EPA 2008 Mod u Manganese 7180 037 495 microgL 5 F203232 2C2000l 031912 EPA 2008 Mod
Mercury 612 842 505 ngL 100 F203288 2C22016 032212 EPA l631E FB-1631
Molybdenum 2000 297 297 microgL 50 F203260 2C22001 032112 EPA 2008 Mod
Nickel 303 040 495 microgL 5 F203232 2C20001 031912 EPA 2008 Mod
Selenium 587 959 297 microgL 5 F203232 2C20001 031912 EPA 2008 Mod
Silver ND 0297 0990 microgL 5 F203232 2C20001 031912 EPA 2008 Mod u Zinc 775 081 990 microgL 5 F203232 2C20001 031912 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report 011ly apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page6 o20 I203203 Final Report- SWWTF REV2
04042012
Liz Siska Project Manager 10
gt
C LO BA L S CI E N C ES
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
MATRIX DUPLICATESTRIPLICATES
SOURCE 1203203-01
Batch F203288
Preparation BrCl Oxidation
Sequence 2C22016
Lab Number F203288-DUPI
Sample Duplicate Concentration Concentration RPD
Analyte DgL ngL
5848
MRL 505
RPD 448
Limit
24
Method
EPA 163IE
Notes
Mercury 6116
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced In its entirety
Page 7of20 l 103203 Final Report- SWWTF REV2
04042012 bull 1 1 Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996
FROlJTIER Fx 425-686-3096 GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203203-01
Batch F203232 Sequence 2C20001
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203232-MSMSD 1
Sample Spike MS MS Concentration Added Concentration 0o Recovery
Analyte (microgL) (microgL) (microgL) Recovery Method NotesLimits
Alumimun 3707 15152 1853 978 70 - 130 EPA 2008 Mod
Chromium 5316 70707 1270 104 70- 130 EPA 2008 Mod
Manganese 7181 60606 7231 821 70 - 130 EPA 2008 Mod
Iron 1098 50505 6090 988 70- 130 EPA 2008 Mod
Nickel 3025 40404 3425 988 70 - 130 EPA 2008 Mod
Copper 1816 40404 5182 833 70 - 130 EPA2008 Mod
Arsenic 3770 15152 1904 101 70- 130 EPA 2008 Mod
Seleniwn 587l 30303 9297 113 70 - 130 EPA 2008 Mod
Silver ND 15152 1099 725 70 - 130 EPA 2008 Mod
Cadmillll) 2484 80808 9508 869 70 - 130 EPA 2008 Mod
Lead 0763 15152 1544 968 70-130 EPA2008Mod
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD
Recovery
Oo
RPD Recovery
Limits RPOLimit Method Notes
Aluminum 15152 1826 96l 145 70 shy 130 20 EPA 2008 Mod
Chromium 70707 1288 107 138 70-130 20 EPA 2008 Mod
Manganese 60606 7230 804 00140 70- 130 20 EPA 2008 Mod
Iron 50505 6065 983 0414 70- 130 20 EPA 2008 Mod
Nickel 40404 3378 872 138 70 - 130 20 EPA2008 Mod
Copper 40404 5140 823 0807 70 - 130 20 EPA 2008 Mod
Arsenic 15152 1928 102 123 70 - 130 20 EPA 2008 Mod
Selenium 30303 9063 105 255 70- 130 20 EPA 2008 Mod
Silver 15152 1075 709 219 70- 130 20 EPA 2008 Mod
Cadmium 80808 9347 849 170 70- 130 20 EPA 2008 Mod
Lead 15152 1531 960 0815 70- 130 20 EPA 2008 Mod
Frontier Global Sciences Inc The results In this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
PageBo20 1203203 FinalReport- SWWTFREV2
04042012
Liz Siska Project Manager 12
iii
11720 North Creek Parkway North Suite 400
Bothell WA 98011 Ph 425-686-1996 Fx 425-686-3096 GlOBAL SCIENCES
ij
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203203-01
Batch F203232 Sequence 2Q20001
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203232-MSMSD3
Analyte
Sample Concentration
(microgL)
Spike Added (pgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Limits Method Notes
Aluminum 3707 10000 10270 990 70 - 130 EPA 2008 Mod AS
Chromium 5316 10000 1137 108 70 - 130 EPA 2008 Mod AS Manganese 7181 10000 8207 103 70 - 130 EPA 2008 Mod AS
Iron 1098 50000 6185 102 70 - 130 EPA 2008 Mod AS Nickel 3025 12500 1433 905 70 - 130 EPA 2008 Mod AS Copper 1816 12500 1061 834 70 - 130 EPA 2008 Mod AS Zinc 7752 25000 1995 767 70 - 130 EPA 2008 Mod AS Arsenic 3770 10000 1073 104 70 - 130 EPA 2008 Mod AS Selenium 587l 10000 1530 943 70 - 130 EPA 2008 Mod AS Silver ND 50000 3690 738 70 - 130 EPA 2008 Mod AS Cadmium 2484 10000 8531 828 70 - 130 EPA 2008 Mod AS Lead 0763 25000 2505 999 70 - 130 EPA 2008 Mod AS
middoti
i
Aoalyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD o
Recovery
RPD Recovery
Limits RPDLimit Method Notes
Aluminum 10000 10150 978 121 70 - 130 20 EPA 2008 Mod AS Chromium 10000 1140 109 0293 70 - 130 20 EPA 2008 Mod AS Manganese 10000 8278 llO 0854 70 -130 20 EPA 2008 Mod AS Iron 50000 6243 103 0937 70-130 20 EPA 2008 Mod AS Nickel 12500 1441 91l middotos25 70 - 130 20 EPA 2008 Mod AS Copper 12500 1066 838 0496 70- 130 20 EPA 2008 Mod AS Zinc 25000 1990 765 0245 70- 130 20 EPA 2008 Mod AS Arsenic 10000 1094 106 193 70 - 130 20 EPA 2008 Mod AS Selenium 10000 1554 967 155 70 - 130 20 EPA 2008 Mod AS Silver 50000 3682 736 0222 70 - 130 20 EPA 2008 Mod AS Cadmium 10000 8394 815 l62 70 - 130 20 EPA 2008 Mod AS Lead 25000 250S 999 00263 70- 130 20 EPA 2008 Mod AS
~~ middotmiddot1 bull
bulli
bullmiddot
Frontier Global Sciences Inc The remits in this report only apply lo the samples analyzed in accordance with the chain ofcustody document This analytical report must bt reproductd In Its entirety
Page 9of20 1203203 Final Report-SWWTF REY2
04M2012
Liz Siska Project Manager 13
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 FRONTIER~ Fx 425-686-3096 GLOBAL SCIENCES
MATR1X SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203203-01RE3
Batch F203260 Sequence 2C22001
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203260-MSMSD3
Analyte
Sample Concentration
(microgL)
Spike Added (microgL)
MS Conctntration
(microgL)
MS
Recovery Recovery
Method Limits Notes
Molybdenum 1999 20200 middot 2041 206 70 - 130 EPA 2008 Mod QM-02
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD Oo
Recovery
RPD
Recovery Limits
RPO Limit Method Notes
Molybdenum 20200 2041 207 00141 70 - 130 20 EPA 2008 Mod QM-02
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed In accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page Oo20 1203203 Final Report- SWWTFREV2
04042012
Liz Siska Project Manager 14
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyzed in accordance with the chain ofcustody document This analytical report =tbe reproducedin Its entirety
Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
CLO~AL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1203203-0lREJ
Batch F203260
Preparation Closed Vessel Nitric Oven Digestion
Sequence 2C2200
Lab Number F203260-MSMSD6
Sample Spike MS MS
Analyte Concentration Added
(JtgL) (microgL) Concentration
(microgL)
Recovery Recovery
Method Limits Notes
Molybdenum 1999 50000 7034 101 70 - 130 EPA 2008 Mod AS
Spike MSD Added Concentration
MSD Recovery RPD
Analyte (microgL) (microgL) Recovery RPD Limits Limit Method Notes
Molybdenum 50000 7124 102 128 70 - 130 20 EPA 2008 Mod AS
Page 11 o20 1203203 Final Report- SWWTF REJ2
040412012
15
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 ~ Fx 425-686-3096 GLOBAL SCIENCES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203203-01
Batch F203288
Preparation BrCI Oxidation
Sequence 2C22016
Lab Number F203288-MSMSD 1
Sample Spike MS MS Concentration Added Concentration Recovery
Analyte (ngL) (ogL) (ogL) Recovery Method Notes Limits
Mercury 6116 25500 3096 974 71 - 125 EPA 1631E
Spike MSD MSD Oo Recovery RPD Added Concentration Oo
Limits Method Notes (ogL) (ogL) Recovery RPD Limit Analyte
Mercury 25500 2611 784 170 71 - 125 24 EPA 1631E
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed i11 accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 12of20 1203203 Final Report- SWWTF REV2
04042012
Liz Siska Project Manager 16
bull 11720 North Creek Parkway North Suite 400
Bothell WA 98011 Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1203194-17
Batch F203288 Sequence 2C22016
Preparation BrCI Oxidation Lab Number F203288-MSMSD2
Sample Spike MS MS
Analyte Concentration
(ngL) Added (ngL)
Concentration (ngL) Recovery
Recovery Limits Method Notes
Mercury 142800 505000 627200 959 71 - 125 EPA 1631E
Spike Added
MSD Concentration
MSD Recovery RPO
Analyte (ngL) (ngL) Recovery RPD Limits Limit Method Notes
Mercury 505000 632700 970 0879 71 - 125 24 EPA 1631E
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody docu~nt This analytical report must be reproduced In its entirety
Page 13of20 1203203 Final Report- SWWTFREV2
04042012
Liz Siska Project Manager 17
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996
bull ~ Fx 425-686-3096 GLPBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203232 Sequence 2C20001
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203232-BSBSD1
LCS Source mank Siiike
Spike LCS LCS Added Concentration Recovery
Analyte (microgL) (microgL) Recovery Limits Method Notes
Aluminwn 15000 1444 963 85-115 EPA2008Mod Chromium 70000 654 934 85 bull 115 EPA 2008 Mod Manganese 60000 580 967 85 - 115 EPA 2008 Mod Iron 50000 4610 922 85 - 115 EPA 2008 Mod Nickel 40000 394 985 85 ll5 EPA 2008 Mod Copper 40000 418 104 85 - 115 EPA 2008 Mod Zinc 10000 1017 102 85 bull 115 EPA 2008 Mod Arsenic 15000 1445 963 85 bull 115 EPA 2008 Mod Selenium 30000 2975 992 85-115 EPA2008Mod Molybdenum 20000 185 926 85 bull 115 EPA 2008 Mod Silver 15000 1555 104 85 - 115 EPA 2008 Mod
Cadmium 080000 0802 100 85 - 115 EPA 2008 Mod Lead 15000 1565 104 85 - 115 EPA 2008 Mod
shy
Spike LCSD LCSD Added Concentration Oo Recovery RPD
Analyte (microgL)
15000
(microgL)
1424
Recovery
949
RPD
140
Limits
85 bull 115
Limit
20
Method
EPA 2008 Mod
Notes
Aluminum
Chromium 70000 644 920 l58 85 bull 115 20 EPA 2008 Mod
Manganese 60000 575 958 0920 85 - ll5 20 EPA 2008 Mod
Iron 50000 4580 916 0660 85 - 115 20 EPA 2008 Mod
Nickel 40000 394 985 000457 85 bull 115 20 EPA 2008 Mod
Copper 40000 416 104 0367 85 - 115 20 EPA 2008 Mod
Zinc 10000 1032 103 147 85 - ll5 20 EPA 2008 Mod
Arsenic 15000 1440 960 0305 85 bull 115 20 EPA 2008 Mod
Selenium 30000 2867 956 369 85 -115 20 EPA 2008 Mod
Molybdenum 20000 l86 928 0196 85 -115 20 EPA2008 Mod
Silver l5000 1559 104 0233 85 bull 115 20 EPA 2008 Mod
Cadmium 080000 0809 101 0843 85 bull llS 20 EPA 2008 Mod
Lead 15000 l539 103 170 85 - 115 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed In accordance with the chain ofcustody document This analytical report must be reproduced in its enJirety
Page 14of20 1203203 Final Report- SWWTFREV2
04042012 ~~
Liz Siska Project Manager 18
11720 North Creek Parkway North Suite 400 Bothell WA 98011 Ph 425-686-1996
FRONTIER Fx 425-686-3096 GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203260 Sequence 2C22001
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203260-BSBSD1
LCS Source Blank Spike
Spike LCS LC$ Added Concentration Recovery
Analyte (ptgL) (JJgL) Recovery Limits Method Notes
Molybdenum 20000 182 910 85 - 115 EPA 2008 Mod
Spike LCSD LCSD Added Concentration Recovery RPD
Analyte (microgL) (microgL) Recovery RPD Limits Limit Method Notes
Molybdenum 20000 186 930 213 85 -115 20 EPA 2008 Mod
Frontier Global Sciences Inc The results In this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced In its entirety
Page 15 o20 I203203 Ftnal ampport- SWWTFREV2
04041202
Liz Siska Project Manager 19
middot
I
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SC IE NC ES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPO
Batch F203288 Sequence 2C22016
Preparation BrCI Oxidation Lab Number F203288-BSBSD I
LCS Source NIST 1641d
Spike LCS LCS Added Concentration Recovery
Analyte (ngL) (ngL) Recovery Limits Method Notes
Mercury 15679 1525 973 80 - 120 EPA l631E
Spike LCSD LCSD Added Concentration Oo Recovery RPD
Analyte (ngL) (ngL)
1516
Recovery
967
RPD
0622
Limits
80 - 120
Limit
24
Method
EPA 1631E
Notes
Mercury 15679
Frontier Global Sciences Inc The results in this report only apply lo the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 16 o20 1203203 Final Report- SWWIFREV2
041042012
20Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 middot Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096 ~ O GLO B AL SCI E NCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2C20001
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203232-BLK1 Aluminum 01 40 microgL F203232 PA2008 Molt u F203232-BLK1 Chromium -0007 0 10 microgL F203232 PA 2008 Molt u F203232-BLKI Manganese 0002 010 microgL F203232 PA 2008 Moc u F203232-BLK1 Iron -004 100 microgL F203232 PA 2008 Molt u F203232-BLKI Nickel 0005 010 microgL F203232 PA 2008 Moc u F203232-BLKI Copper 001 010 microgL F203232 PA 2008 Molt u F203232-BLK1 Zinc 011 020 microgL F203232 PA 2008 Moc u F203232-BLK I Arsenic -0009 015 microgL F203232 PA 2008 Moc u F203232-BLK1 Selenium 025 060 microgL F203232 PA 2008 Moc u F203232-BLK1 Molybdenum 001 006 microgL F203232 PA 2008 Moc u F203232-BLK1 Silver -00009 0020 microgL F203232 PA 2008 Moc u F203232-BLK1 Cadmium 0002 0020 microgL F203232 PA 2008 Molt u F203232-BLK1 Lead 0024 0040 microgL F203232 PA 2008 Molt u
middoti
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordonce with the chain ofcustody document Tnts analytical rtport must be reproduced In its enlfrtty
Page7of20 J203203 Final ampport-SWWTF REV2
04042012
Liz Siska Project Manager 21
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 FRONTIER~ Fx 425-686-3096 GLOBAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2C22001
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203260-BLK1 Molybdenum 001 006 microgL F203260 ~PA 2008 Moc u
Frontier Global Sciences Inc middot The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 18of20 1203203 Final Report- SWWTFREV2
04042012
Liz Siska Project Manager 22
~ CLOSAL SCIENCES
~
J1720 North Creek Parkway North Suite 400 Bothell WA 980 l l
Ph 425-686-1996 Fx 425-686-3096
PREPARATION BLANKS
Instrument Hg-17 Sequence 2C22016
Preparation BrCI Oxidation
The results in Ihis report only apply to the samples analyzed i12 accordance with the chain ofcustody dccumnt This analytical report must be reproductd in ils enJirety
Page I9oj20 1203203 Final Report- SWWTF REJ2
04042012
Frontier Global Sciences Inc
bull 23bull Liz Siska Project Manager
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203288-BLKl Mercury 007 050 ngL F203288 EPA 1631E u F203288-BLIlt2 Mercury 006 050 ngL F203288 EPA 163lE u F203288-BLK3 Mercury 006 050 ngL F203288 EPA I63lE u F203288-BLK4 Mercury 018 050 ngL F203288 EPA I63IE U QB-04
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
Notes and Definitions
U Analyte included in the analysis but not detected
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than I times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable ASASD
QB-04 The blank was preserved to 2 BrCl rather than I The control limit for blanks presetved to greater than 1 BrCl is the preservation percentage multiplied by the l1RL
FB-1631 Required equipmentfieldfilter blank not submitted by the client The sample has been analyzed according to 163 lE but does not meet 163 lE criteria
AS This MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
l1RL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to lhe samples analyzedin accordance wirh the chain ofcustody document This analytical report must be reproduced in its entirety
Page 20of20 1203203 Final Report- SWWTF REV2
04042012
24
bull bull
irGl Lu Ull 0111C H AIN-OF-CUSTODY RECORD Page of_~~
Bolo FIELDS REQUIRED P LEASE CIRCLE REQUESTED ANALYs1s Lt) CN voe I svoc TClPI M ETALS INORGANICS
i w I shy i
SAMPLING 0 iii 0 ~
w = ~ DATET1ME QIll c X
w ~sacw 0IF COMPOSITE -gtc ~ u - ~
INDICATE 80TH ~ bulllo- t5a5 START amp FINISH
er Ill liSAMPLE 1 0 i ct -a ~shyDATEITIME l r ~~
bull 7gtItJJJI JWj T ~ tlt
IHAnlX A-Ala S-SOIL GW-GROUHD WATEl SW-SURfACE WATEA DW-DllNIING WAm WW-WAITE WATEl
PWETAJllt H-HCL N-HNO S-HJO Na-NaOHmiddot H-HEOH
i ~~ ~ I ~ X
j i I i= -shy 2 s~ ~ == a~ -shy I t
~~ =~ 2 ~~
~ X a c 2 ~ ~ = -- 2 ~
l j t z i () ~
C 0 5~ s~ = IC 0
C -s ~ = ~ ~e f
0 ~= ~ _sC a ~ C) -shyt( I rt
1 g0
3 i ~-
]-
f~ js~ i
~bull m = olt 1 o(
1 e
j
M ICRO middot-- -shy108420
sshyj
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~ - I 2lte E55 NOTESili I j HEOHVIAl 6shy ~a 3
I 3 ~ It _ c
1
DATE NEEDED b171i1-1~ 1 f METALS 8 RCRA 13 PP FE MN Ps CUPROJECT MANAGER 0v f-e_~ Tmamp- middotc COMPANY pdegZ1)shy 0THE1 METALS __________REPORTING OPTIONSQAQC ICH) NoAonms Jfru lli V =1 Q ) REPORTING LEVEL PUUHS ~OR No
A B C 0lOLYpoundD METALS FIELD flLTtREDI YE NoIF YE F~ oa(ITT STAil~l4t(= ~ ZIP rriu1 NOTES (IE SPEOAl DETECTION LIHIIS BIWNG INFO IF D1mam)PHONE _r~ _z31_ - $ I3 Exr--- OR ELECTRONIC OPTIONSFAX _ __________________ AI l A C J C bull C1
J pbNo FAX E-MAIL PDF EQUIS
E-MAIL tivl el qu ~ pv CvVshyf J --~b Mo ~ tJ k ttJ -z~Sm NAHE W
PROJECT ____________ ___ ___ _ ~111216- aJd M fer P4 jgtZJ)shy
SUTt MA ME VT OTHER _____ ___ ~ 1)--U ( u-middotmiddottut-UJ f bull
REGULATORY PROGRAM NPDES RGP POnY STOilKWATER Ol SITE HISTORY ~i tiT f=
GWP OIL FUND BROWNFJUD OR Orm--------shy RELINQUISHED BY DATE TIME RECEIVED Br Summo (ONTAHINATIOM_______
PO_______QUOTE===-~----shy I RELINQUISHED BY DATE TIME Rmmo BT I FIElllJUDINGStt HI l lS 2
eastern analytical inc 2s CHENELl DR1ve I CoNcoRo NH 03301 I TEL 60322sos2s I 1soo2s7os2s IFAXc 6032284591 I E-MA1l cusToMER_seRv1ceEA1LAascoHj wwweA1lAsscoM
prufmin111ll11bomtory1m1im (WHITE ORIGINAL GREEN PROJECT MANAGER)
shy
shy
~ 11720 North Creek Parkway North Suite 400
Bothell WA 9801 1 Ph 425-686-1996 Fx 425-686-3096
GLOBAl SCIENCES
ANALYTICAL REPORT FOR SAMPLES
Laboratory Frontier Global Sciences Inc SDG
Client Eastern Analytical ]nc Project Merrimack Station 2008
Sample ID Lab ID Matrix Date Sampled Date Received
SWWTF 1203203-01 Water 14-Mar-12 1305 16-Mar-12 0940
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Pagel o20 1203203 Final Report-SWWTF REV2
041042012
Liz Siska Project Manager 5
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
CASE NARRATIVE
Revised Report 4412- Sample name corrected to SWWTF
SAMPLE RECEIPT
Samples were received at Frontier Global Sciences (FGS) on March 16th 2012 The samples were received intact on-ice with temperatures measuredat 22 degrees Celsius
SAMPLE PREPARATION AND ANALYSIS
Samples were prepared and analyzed for total metals in accordance with EPA Method 2008 (modified)
Samples were prepared and analyzed for total mercury in accordance with EPA Method 163 JE
ANALYTICAL ISSUES
The client requested sample SWWTF (1203203-0 l) be analyzed for Mn via email on 31512
Samples were received in a cooler ofmelted ice There was water in the inner most bag of sample Evaporator (1203203-02)
As an additional measure ofthe accuracy ofthe methods utilized for analysis and to check for matrix interference matrix spikes (MS) and matrix spike duplicates (MSD) were digested and analyzed All ofthe matrix spike recoveries were within the control limits with the exception ofany QC flagged and described in the notes and definitions section ofthe following report
A reasonable measure ofthe precision ofthe analytical methods utilized for analysis is the relative percent difference (RPD) between matrix spike and matrix spike duplicate recoveries and between laboratory control sample and laboratory control sample duplicate recoveries All of the relative percent differences were within the control limits with the exception ofany QC flagged and described in the notes and definitions section ofthe following report
Frontier Global Sciences Inc The results in this report 011y apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 2 of20 1203203 Final Report- SWWTF REV2
04042012
Liz Siska Project Manager 6
FRONTIER
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIE NCES
CHAIN OF CUSTODY FORMS
bullbull _ ~ -bull uer ( A c 2 - gt Sampre Recefpt CHockJlst
Data Looobulld tn ~tZfrPkttr ~~middot0 middot1)d bull MSi~~gtamp Loss bull d I n Sy
SOG o f Coolns- R~oetvbullG I ( FGSPM
Sarn01 AnIVed bull)I ----Shipp ing --=--___~~-=-------=_lta=~-=--===---------
___Nona (ArnblbullnQ
SbullNfo Cour1bullr TrecklngJAtrtgtIII Nubbulltbull) e Xlt---Z-~q gt
-rhermal PreuorvatJon Loo~ l~ ___GeleJubull lea
rT~hbull_ornebullur_10~gt~(~5z2~_--CorrftCtfan rbullclOf (Cfl) ~lt2 - 3 degre-bull O eoolbullr- 1 L ~ middoto CoCttbullr a bullc eoolbullr-2 middot c Cootbullr7 middotc
middot c Cooler a bullc middot c
middotc middot c
Coolar 18
Chbullln orCutody COO $ pria1-ct-n bullnd lneludee thbull folto~ng Information for obulloh ~~mple
NA Comrnbullnta
Sbullrnolampd BvshyPrbullbullation bullmiddot ~uoa1bulld Ana1vbullbullbullmiddot Roaulbulld SlcnHt vrbullr
middot------------ shy ---ilnt-nat chaln or custOdv irv1d
l-~=V
---l shy ---+--~-shy ----+-----------1
Samplbull CondltJonltnte-oi $bullmole containerbull wbullra -oehbulld Jr1tlact bull--bull labolbull bullshy _nt bulln lenfbln
lteon-eet aamIbull oontarners U ~ltftd fcrr reauect1Dd 0rnafv8ebull sbullm-reraquo roCHtlvOd In holdrna tlmomiddot bullbullrn- bull vohnlIbull auMolen ~~r raubullbulltbulld anaalvbull a
Voa No
CotTbulld orbullbullbulltvotlvbull ucact for aue atect -nahrbull _ -shyM of bull-n~tshy Qhertced a-d mthod l~e-ntbull -
Cllent Communloatfott Po~ Contaicta Oat611mbull _____ _
Commentbull
Mbulltnod ____ _
Olbull~bullronJRbullbullo1utlon
The results in this report only apply to the samples analy-ed in accordance with the Frontier Global Sciences Inc chain ofcustody docutMnt This aMlytical report must be reprodu~d in its e111irety
Page3of20 1203203 Final Rtport- SWWTFREV2
04042012
Liz Siska Project Manager 7
l l 720 North Creek Parkway Nortn u1Le -tvv Bothell WA 9amp011
Ph 425-686-1996 Fx 425-686-3096
FRONTIER GLOBAL SCIENCES
CHAIN OF CUSTODY FORMS
The results in this report only apply to the samples analyzed in accordance with the cliain ofcustody documenL This analytical report must be reproduced in its entirety
Frontier Global Sciences Inc Page 4 o20 1203203 Final Report- SWWTF REV2
04042012
Liz Siska Project Manager
8
11720 North Creek Parkway North Suite 40U Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
FRONTIER C L 0 B AL SC I~ NC ES
CHAlN OF CUSTODY FORMS
i---t--+-l-+-+-+--+--+--+--+_micro~[_amp~lslte---l t---t--+--11-(- -1--+-~-+--l---l---+----------f_ rmiddot 1---+--~--l--f-+---l--l--l-+--I--I---- _____--1 lt 1--1--1--+--l--------4-+-+--l--+-+--____f_ i--t--+--1r-+-+-+-t-+-++-4-________ _j bull-
CN _r(gt --shyshy~
_lj _D ~ -~ Irgt ~ -f
~ ~
The results In this report onlyapply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reprodu~din its entirety
Frontier Global Sciences Inc Page 5 o20 T203203 Final Report-SWWTFREV2
ommo12
Liz SiskaProject Manager
9
)--J middot ~~
)J fl~~J~c1N~r
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
Matrix Water Laboratory ID 1203203-01
ANALYTICAL RESULTS
SWWTF
Analyte Result lIDL MRL Units Dilution Batch Sequence Analyzed Method Notes
Aluminum 371 220 198 microgL 5 F203232 2C2000l 031912 EPA 2008 Mod
Arsenic 377 252 743 microgL 5 F203232 2C2000l 031912 EPA 2008 Mod
Cadmium 248 0205 0990 microgL 5 F203232 2C20001 031912 EPA2008 Mod
Chromium 532 045 495 microgL 5 F203232 2C20001 031912 EPA 2008 Mod
Copper 182 050 495 microgL 5 F203232 2C20001 031912 EPA 2008 Mod
Iron 1100 644 495 microgL 5 F203232 2C20001 031912 EPA 2008 Mod
Lead ND 0193 198 microgL 5 F203232 2C2000l 031912 EPA 2008 Mod u Manganese 7180 037 495 microgL 5 F203232 2C2000l 031912 EPA 2008 Mod
Mercury 612 842 505 ngL 100 F203288 2C22016 032212 EPA l631E FB-1631
Molybdenum 2000 297 297 microgL 50 F203260 2C22001 032112 EPA 2008 Mod
Nickel 303 040 495 microgL 5 F203232 2C20001 031912 EPA 2008 Mod
Selenium 587 959 297 microgL 5 F203232 2C20001 031912 EPA 2008 Mod
Silver ND 0297 0990 microgL 5 F203232 2C20001 031912 EPA 2008 Mod u Zinc 775 081 990 microgL 5 F203232 2C20001 031912 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report 011ly apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page6 o20 I203203 Final Report- SWWTF REV2
04042012
Liz Siska Project Manager 10
gt
C LO BA L S CI E N C ES
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
MATRIX DUPLICATESTRIPLICATES
SOURCE 1203203-01
Batch F203288
Preparation BrCl Oxidation
Sequence 2C22016
Lab Number F203288-DUPI
Sample Duplicate Concentration Concentration RPD
Analyte DgL ngL
5848
MRL 505
RPD 448
Limit
24
Method
EPA 163IE
Notes
Mercury 6116
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced In its entirety
Page 7of20 l 103203 Final Report- SWWTF REV2
04042012 bull 1 1 Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996
FROlJTIER Fx 425-686-3096 GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203203-01
Batch F203232 Sequence 2C20001
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203232-MSMSD 1
Sample Spike MS MS Concentration Added Concentration 0o Recovery
Analyte (microgL) (microgL) (microgL) Recovery Method NotesLimits
Alumimun 3707 15152 1853 978 70 - 130 EPA 2008 Mod
Chromium 5316 70707 1270 104 70- 130 EPA 2008 Mod
Manganese 7181 60606 7231 821 70 - 130 EPA 2008 Mod
Iron 1098 50505 6090 988 70- 130 EPA 2008 Mod
Nickel 3025 40404 3425 988 70 - 130 EPA 2008 Mod
Copper 1816 40404 5182 833 70 - 130 EPA2008 Mod
Arsenic 3770 15152 1904 101 70- 130 EPA 2008 Mod
Seleniwn 587l 30303 9297 113 70 - 130 EPA 2008 Mod
Silver ND 15152 1099 725 70 - 130 EPA 2008 Mod
Cadmillll) 2484 80808 9508 869 70 - 130 EPA 2008 Mod
Lead 0763 15152 1544 968 70-130 EPA2008Mod
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD
Recovery
Oo
RPD Recovery
Limits RPOLimit Method Notes
Aluminum 15152 1826 96l 145 70 shy 130 20 EPA 2008 Mod
Chromium 70707 1288 107 138 70-130 20 EPA 2008 Mod
Manganese 60606 7230 804 00140 70- 130 20 EPA 2008 Mod
Iron 50505 6065 983 0414 70- 130 20 EPA 2008 Mod
Nickel 40404 3378 872 138 70 - 130 20 EPA2008 Mod
Copper 40404 5140 823 0807 70 - 130 20 EPA 2008 Mod
Arsenic 15152 1928 102 123 70 - 130 20 EPA 2008 Mod
Selenium 30303 9063 105 255 70- 130 20 EPA 2008 Mod
Silver 15152 1075 709 219 70- 130 20 EPA 2008 Mod
Cadmium 80808 9347 849 170 70- 130 20 EPA 2008 Mod
Lead 15152 1531 960 0815 70- 130 20 EPA 2008 Mod
Frontier Global Sciences Inc The results In this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
PageBo20 1203203 FinalReport- SWWTFREV2
04042012
Liz Siska Project Manager 12
iii
11720 North Creek Parkway North Suite 400
Bothell WA 98011 Ph 425-686-1996 Fx 425-686-3096 GlOBAL SCIENCES
ij
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203203-01
Batch F203232 Sequence 2Q20001
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203232-MSMSD3
Analyte
Sample Concentration
(microgL)
Spike Added (pgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Limits Method Notes
Aluminum 3707 10000 10270 990 70 - 130 EPA 2008 Mod AS
Chromium 5316 10000 1137 108 70 - 130 EPA 2008 Mod AS Manganese 7181 10000 8207 103 70 - 130 EPA 2008 Mod AS
Iron 1098 50000 6185 102 70 - 130 EPA 2008 Mod AS Nickel 3025 12500 1433 905 70 - 130 EPA 2008 Mod AS Copper 1816 12500 1061 834 70 - 130 EPA 2008 Mod AS Zinc 7752 25000 1995 767 70 - 130 EPA 2008 Mod AS Arsenic 3770 10000 1073 104 70 - 130 EPA 2008 Mod AS Selenium 587l 10000 1530 943 70 - 130 EPA 2008 Mod AS Silver ND 50000 3690 738 70 - 130 EPA 2008 Mod AS Cadmium 2484 10000 8531 828 70 - 130 EPA 2008 Mod AS Lead 0763 25000 2505 999 70 - 130 EPA 2008 Mod AS
middoti
i
Aoalyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD o
Recovery
RPD Recovery
Limits RPDLimit Method Notes
Aluminum 10000 10150 978 121 70 - 130 20 EPA 2008 Mod AS Chromium 10000 1140 109 0293 70 - 130 20 EPA 2008 Mod AS Manganese 10000 8278 llO 0854 70 -130 20 EPA 2008 Mod AS Iron 50000 6243 103 0937 70-130 20 EPA 2008 Mod AS Nickel 12500 1441 91l middotos25 70 - 130 20 EPA 2008 Mod AS Copper 12500 1066 838 0496 70- 130 20 EPA 2008 Mod AS Zinc 25000 1990 765 0245 70- 130 20 EPA 2008 Mod AS Arsenic 10000 1094 106 193 70 - 130 20 EPA 2008 Mod AS Selenium 10000 1554 967 155 70 - 130 20 EPA 2008 Mod AS Silver 50000 3682 736 0222 70 - 130 20 EPA 2008 Mod AS Cadmium 10000 8394 815 l62 70 - 130 20 EPA 2008 Mod AS Lead 25000 250S 999 00263 70- 130 20 EPA 2008 Mod AS
~~ middotmiddot1 bull
bulli
bullmiddot
Frontier Global Sciences Inc The remits in this report only apply lo the samples analyzed in accordance with the chain ofcustody document This analytical report must bt reproductd In Its entirety
Page 9of20 1203203 Final Report-SWWTF REY2
04M2012
Liz Siska Project Manager 13
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 FRONTIER~ Fx 425-686-3096 GLOBAL SCIENCES
MATR1X SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203203-01RE3
Batch F203260 Sequence 2C22001
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203260-MSMSD3
Analyte
Sample Concentration
(microgL)
Spike Added (microgL)
MS Conctntration
(microgL)
MS
Recovery Recovery
Method Limits Notes
Molybdenum 1999 20200 middot 2041 206 70 - 130 EPA 2008 Mod QM-02
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD Oo
Recovery
RPD
Recovery Limits
RPO Limit Method Notes
Molybdenum 20200 2041 207 00141 70 - 130 20 EPA 2008 Mod QM-02
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed In accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page Oo20 1203203 Final Report- SWWTFREV2
04042012
Liz Siska Project Manager 14
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyzed in accordance with the chain ofcustody document This analytical report =tbe reproducedin Its entirety
Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
CLO~AL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1203203-0lREJ
Batch F203260
Preparation Closed Vessel Nitric Oven Digestion
Sequence 2C2200
Lab Number F203260-MSMSD6
Sample Spike MS MS
Analyte Concentration Added
(JtgL) (microgL) Concentration
(microgL)
Recovery Recovery
Method Limits Notes
Molybdenum 1999 50000 7034 101 70 - 130 EPA 2008 Mod AS
Spike MSD Added Concentration
MSD Recovery RPD
Analyte (microgL) (microgL) Recovery RPD Limits Limit Method Notes
Molybdenum 50000 7124 102 128 70 - 130 20 EPA 2008 Mod AS
Page 11 o20 1203203 Final Report- SWWTF REJ2
040412012
15
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 ~ Fx 425-686-3096 GLOBAL SCIENCES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203203-01
Batch F203288
Preparation BrCI Oxidation
Sequence 2C22016
Lab Number F203288-MSMSD 1
Sample Spike MS MS Concentration Added Concentration Recovery
Analyte (ngL) (ogL) (ogL) Recovery Method Notes Limits
Mercury 6116 25500 3096 974 71 - 125 EPA 1631E
Spike MSD MSD Oo Recovery RPD Added Concentration Oo
Limits Method Notes (ogL) (ogL) Recovery RPD Limit Analyte
Mercury 25500 2611 784 170 71 - 125 24 EPA 1631E
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed i11 accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 12of20 1203203 Final Report- SWWTF REV2
04042012
Liz Siska Project Manager 16
bull 11720 North Creek Parkway North Suite 400
Bothell WA 98011 Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1203194-17
Batch F203288 Sequence 2C22016
Preparation BrCI Oxidation Lab Number F203288-MSMSD2
Sample Spike MS MS
Analyte Concentration
(ngL) Added (ngL)
Concentration (ngL) Recovery
Recovery Limits Method Notes
Mercury 142800 505000 627200 959 71 - 125 EPA 1631E
Spike Added
MSD Concentration
MSD Recovery RPO
Analyte (ngL) (ngL) Recovery RPD Limits Limit Method Notes
Mercury 505000 632700 970 0879 71 - 125 24 EPA 1631E
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody docu~nt This analytical report must be reproduced In its entirety
Page 13of20 1203203 Final Report- SWWTFREV2
04042012
Liz Siska Project Manager 17
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996
bull ~ Fx 425-686-3096 GLPBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203232 Sequence 2C20001
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203232-BSBSD1
LCS Source mank Siiike
Spike LCS LCS Added Concentration Recovery
Analyte (microgL) (microgL) Recovery Limits Method Notes
Aluminwn 15000 1444 963 85-115 EPA2008Mod Chromium 70000 654 934 85 bull 115 EPA 2008 Mod Manganese 60000 580 967 85 - 115 EPA 2008 Mod Iron 50000 4610 922 85 - 115 EPA 2008 Mod Nickel 40000 394 985 85 ll5 EPA 2008 Mod Copper 40000 418 104 85 - 115 EPA 2008 Mod Zinc 10000 1017 102 85 bull 115 EPA 2008 Mod Arsenic 15000 1445 963 85 bull 115 EPA 2008 Mod Selenium 30000 2975 992 85-115 EPA2008Mod Molybdenum 20000 185 926 85 bull 115 EPA 2008 Mod Silver 15000 1555 104 85 - 115 EPA 2008 Mod
Cadmium 080000 0802 100 85 - 115 EPA 2008 Mod Lead 15000 1565 104 85 - 115 EPA 2008 Mod
shy
Spike LCSD LCSD Added Concentration Oo Recovery RPD
Analyte (microgL)
15000
(microgL)
1424
Recovery
949
RPD
140
Limits
85 bull 115
Limit
20
Method
EPA 2008 Mod
Notes
Aluminum
Chromium 70000 644 920 l58 85 bull 115 20 EPA 2008 Mod
Manganese 60000 575 958 0920 85 - ll5 20 EPA 2008 Mod
Iron 50000 4580 916 0660 85 - 115 20 EPA 2008 Mod
Nickel 40000 394 985 000457 85 bull 115 20 EPA 2008 Mod
Copper 40000 416 104 0367 85 - 115 20 EPA 2008 Mod
Zinc 10000 1032 103 147 85 - ll5 20 EPA 2008 Mod
Arsenic 15000 1440 960 0305 85 bull 115 20 EPA 2008 Mod
Selenium 30000 2867 956 369 85 -115 20 EPA 2008 Mod
Molybdenum 20000 l86 928 0196 85 -115 20 EPA2008 Mod
Silver l5000 1559 104 0233 85 bull 115 20 EPA 2008 Mod
Cadmium 080000 0809 101 0843 85 bull llS 20 EPA 2008 Mod
Lead 15000 l539 103 170 85 - 115 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed In accordance with the chain ofcustody document This analytical report must be reproduced in its enJirety
Page 14of20 1203203 Final Report- SWWTFREV2
04042012 ~~
Liz Siska Project Manager 18
11720 North Creek Parkway North Suite 400 Bothell WA 98011 Ph 425-686-1996
FRONTIER Fx 425-686-3096 GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203260 Sequence 2C22001
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203260-BSBSD1
LCS Source Blank Spike
Spike LCS LC$ Added Concentration Recovery
Analyte (ptgL) (JJgL) Recovery Limits Method Notes
Molybdenum 20000 182 910 85 - 115 EPA 2008 Mod
Spike LCSD LCSD Added Concentration Recovery RPD
Analyte (microgL) (microgL) Recovery RPD Limits Limit Method Notes
Molybdenum 20000 186 930 213 85 -115 20 EPA 2008 Mod
Frontier Global Sciences Inc The results In this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced In its entirety
Page 15 o20 I203203 Ftnal ampport- SWWTFREV2
04041202
Liz Siska Project Manager 19
middot
I
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SC IE NC ES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPO
Batch F203288 Sequence 2C22016
Preparation BrCI Oxidation Lab Number F203288-BSBSD I
LCS Source NIST 1641d
Spike LCS LCS Added Concentration Recovery
Analyte (ngL) (ngL) Recovery Limits Method Notes
Mercury 15679 1525 973 80 - 120 EPA l631E
Spike LCSD LCSD Added Concentration Oo Recovery RPD
Analyte (ngL) (ngL)
1516
Recovery
967
RPD
0622
Limits
80 - 120
Limit
24
Method
EPA 1631E
Notes
Mercury 15679
Frontier Global Sciences Inc The results in this report only apply lo the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 16 o20 1203203 Final Report- SWWIFREV2
041042012
20Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 middot Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096 ~ O GLO B AL SCI E NCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2C20001
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203232-BLK1 Aluminum 01 40 microgL F203232 PA2008 Molt u F203232-BLK1 Chromium -0007 0 10 microgL F203232 PA 2008 Molt u F203232-BLKI Manganese 0002 010 microgL F203232 PA 2008 Moc u F203232-BLK1 Iron -004 100 microgL F203232 PA 2008 Molt u F203232-BLKI Nickel 0005 010 microgL F203232 PA 2008 Moc u F203232-BLKI Copper 001 010 microgL F203232 PA 2008 Molt u F203232-BLK1 Zinc 011 020 microgL F203232 PA 2008 Moc u F203232-BLK I Arsenic -0009 015 microgL F203232 PA 2008 Moc u F203232-BLK1 Selenium 025 060 microgL F203232 PA 2008 Moc u F203232-BLK1 Molybdenum 001 006 microgL F203232 PA 2008 Moc u F203232-BLK1 Silver -00009 0020 microgL F203232 PA 2008 Moc u F203232-BLK1 Cadmium 0002 0020 microgL F203232 PA 2008 Molt u F203232-BLK1 Lead 0024 0040 microgL F203232 PA 2008 Molt u
middoti
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordonce with the chain ofcustody document Tnts analytical rtport must be reproduced In its enlfrtty
Page7of20 J203203 Final ampport-SWWTF REV2
04042012
Liz Siska Project Manager 21
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 FRONTIER~ Fx 425-686-3096 GLOBAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2C22001
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203260-BLK1 Molybdenum 001 006 microgL F203260 ~PA 2008 Moc u
Frontier Global Sciences Inc middot The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 18of20 1203203 Final Report- SWWTFREV2
04042012
Liz Siska Project Manager 22
~ CLOSAL SCIENCES
~
J1720 North Creek Parkway North Suite 400 Bothell WA 980 l l
Ph 425-686-1996 Fx 425-686-3096
PREPARATION BLANKS
Instrument Hg-17 Sequence 2C22016
Preparation BrCI Oxidation
The results in Ihis report only apply to the samples analyzed i12 accordance with the chain ofcustody dccumnt This analytical report must be reproductd in ils enJirety
Page I9oj20 1203203 Final Report- SWWTF REJ2
04042012
Frontier Global Sciences Inc
bull 23bull Liz Siska Project Manager
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203288-BLKl Mercury 007 050 ngL F203288 EPA 1631E u F203288-BLIlt2 Mercury 006 050 ngL F203288 EPA 163lE u F203288-BLK3 Mercury 006 050 ngL F203288 EPA I63lE u F203288-BLK4 Mercury 018 050 ngL F203288 EPA I63IE U QB-04
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
Notes and Definitions
U Analyte included in the analysis but not detected
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than I times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable ASASD
QB-04 The blank was preserved to 2 BrCl rather than I The control limit for blanks presetved to greater than 1 BrCl is the preservation percentage multiplied by the l1RL
FB-1631 Required equipmentfieldfilter blank not submitted by the client The sample has been analyzed according to 163 lE but does not meet 163 lE criteria
AS This MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
l1RL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to lhe samples analyzedin accordance wirh the chain ofcustody document This analytical report must be reproduced in its entirety
Page 20of20 1203203 Final Report- SWWTF REV2
04042012
24
bull bull
irGl Lu Ull 0111C H AIN-OF-CUSTODY RECORD Page of_~~
Bolo FIELDS REQUIRED P LEASE CIRCLE REQUESTED ANALYs1s Lt) CN voe I svoc TClPI M ETALS INORGANICS
i w I shy i
SAMPLING 0 iii 0 ~
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INDICATE 80TH ~ bulllo- t5a5 START amp FINISH
er Ill liSAMPLE 1 0 i ct -a ~shyDATEITIME l r ~~
bull 7gtItJJJI JWj T ~ tlt
IHAnlX A-Ala S-SOIL GW-GROUHD WATEl SW-SURfACE WATEA DW-DllNIING WAm WW-WAITE WATEl
PWETAJllt H-HCL N-HNO S-HJO Na-NaOHmiddot H-HEOH
i ~~ ~ I ~ X
j i I i= -shy 2 s~ ~ == a~ -shy I t
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DATE NEEDED b171i1-1~ 1 f METALS 8 RCRA 13 PP FE MN Ps CUPROJECT MANAGER 0v f-e_~ Tmamp- middotc COMPANY pdegZ1)shy 0THE1 METALS __________REPORTING OPTIONSQAQC ICH) NoAonms Jfru lli V =1 Q ) REPORTING LEVEL PUUHS ~OR No
A B C 0lOLYpoundD METALS FIELD flLTtREDI YE NoIF YE F~ oa(ITT STAil~l4t(= ~ ZIP rriu1 NOTES (IE SPEOAl DETECTION LIHIIS BIWNG INFO IF D1mam)PHONE _r~ _z31_ - $ I3 Exr--- OR ELECTRONIC OPTIONSFAX _ __________________ AI l A C J C bull C1
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E-MAIL tivl el qu ~ pv CvVshyf J --~b Mo ~ tJ k ttJ -z~Sm NAHE W
PROJECT ____________ ___ ___ _ ~111216- aJd M fer P4 jgtZJ)shy
SUTt MA ME VT OTHER _____ ___ ~ 1)--U ( u-middotmiddottut-UJ f bull
REGULATORY PROGRAM NPDES RGP POnY STOilKWATER Ol SITE HISTORY ~i tiT f=
GWP OIL FUND BROWNFJUD OR Orm--------shy RELINQUISHED BY DATE TIME RECEIVED Br Summo (ONTAHINATIOM_______
PO_______QUOTE===-~----shy I RELINQUISHED BY DATE TIME Rmmo BT I FIElllJUDINGStt HI l lS 2
eastern analytical inc 2s CHENELl DR1ve I CoNcoRo NH 03301 I TEL 60322sos2s I 1soo2s7os2s IFAXc 6032284591 I E-MA1l cusToMER_seRv1ceEA1LAascoHj wwweA1lAsscoM
prufmin111ll11bomtory1m1im (WHITE ORIGINAL GREEN PROJECT MANAGER)
shy
shy
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
CASE NARRATIVE
Revised Report 4412- Sample name corrected to SWWTF
SAMPLE RECEIPT
Samples were received at Frontier Global Sciences (FGS) on March 16th 2012 The samples were received intact on-ice with temperatures measuredat 22 degrees Celsius
SAMPLE PREPARATION AND ANALYSIS
Samples were prepared and analyzed for total metals in accordance with EPA Method 2008 (modified)
Samples were prepared and analyzed for total mercury in accordance with EPA Method 163 JE
ANALYTICAL ISSUES
The client requested sample SWWTF (1203203-0 l) be analyzed for Mn via email on 31512
Samples were received in a cooler ofmelted ice There was water in the inner most bag of sample Evaporator (1203203-02)
As an additional measure ofthe accuracy ofthe methods utilized for analysis and to check for matrix interference matrix spikes (MS) and matrix spike duplicates (MSD) were digested and analyzed All ofthe matrix spike recoveries were within the control limits with the exception ofany QC flagged and described in the notes and definitions section ofthe following report
A reasonable measure ofthe precision ofthe analytical methods utilized for analysis is the relative percent difference (RPD) between matrix spike and matrix spike duplicate recoveries and between laboratory control sample and laboratory control sample duplicate recoveries All of the relative percent differences were within the control limits with the exception ofany QC flagged and described in the notes and definitions section ofthe following report
Frontier Global Sciences Inc The results in this report 011y apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 2 of20 1203203 Final Report- SWWTF REV2
04042012
Liz Siska Project Manager 6
FRONTIER
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIE NCES
CHAIN OF CUSTODY FORMS
bullbull _ ~ -bull uer ( A c 2 - gt Sampre Recefpt CHockJlst
Data Looobulld tn ~tZfrPkttr ~~middot0 middot1)d bull MSi~~gtamp Loss bull d I n Sy
SOG o f Coolns- R~oetvbullG I ( FGSPM
Sarn01 AnIVed bull)I ----Shipp ing --=--___~~-=-------=_lta=~-=--===---------
___Nona (ArnblbullnQ
SbullNfo Cour1bullr TrecklngJAtrtgtIII Nubbulltbull) e Xlt---Z-~q gt
-rhermal PreuorvatJon Loo~ l~ ___GeleJubull lea
rT~hbull_ornebullur_10~gt~(~5z2~_--CorrftCtfan rbullclOf (Cfl) ~lt2 - 3 degre-bull O eoolbullr- 1 L ~ middoto CoCttbullr a bullc eoolbullr-2 middot c Cootbullr7 middotc
middot c Cooler a bullc middot c
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Sbullrnolampd BvshyPrbullbullation bullmiddot ~uoa1bulld Ana1vbullbullbullmiddot Roaulbulld SlcnHt vrbullr
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lteon-eet aamIbull oontarners U ~ltftd fcrr reauect1Dd 0rnafv8ebull sbullm-reraquo roCHtlvOd In holdrna tlmomiddot bullbullrn- bull vohnlIbull auMolen ~~r raubullbulltbulld anaalvbull a
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Mbulltnod ____ _
Olbull~bullronJRbullbullo1utlon
The results in this report only apply to the samples analy-ed in accordance with the Frontier Global Sciences Inc chain ofcustody docutMnt This aMlytical report must be reprodu~d in its e111irety
Page3of20 1203203 Final Rtport- SWWTFREV2
04042012
Liz Siska Project Manager 7
l l 720 North Creek Parkway Nortn u1Le -tvv Bothell WA 9amp011
Ph 425-686-1996 Fx 425-686-3096
FRONTIER GLOBAL SCIENCES
CHAIN OF CUSTODY FORMS
The results in this report only apply to the samples analyzed in accordance with the cliain ofcustody documenL This analytical report must be reproduced in its entirety
Frontier Global Sciences Inc Page 4 o20 1203203 Final Report- SWWTF REV2
04042012
Liz Siska Project Manager
8
11720 North Creek Parkway North Suite 40U Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
FRONTIER C L 0 B AL SC I~ NC ES
CHAlN OF CUSTODY FORMS
i---t--+-l-+-+-+--+--+--+--+_micro~[_amp~lslte---l t---t--+--11-(- -1--+-~-+--l---l---+----------f_ rmiddot 1---+--~--l--f-+---l--l--l-+--I--I---- _____--1 lt 1--1--1--+--l--------4-+-+--l--+-+--____f_ i--t--+--1r-+-+-+-t-+-++-4-________ _j bull-
CN _r(gt --shyshy~
_lj _D ~ -~ Irgt ~ -f
~ ~
The results In this report onlyapply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reprodu~din its entirety
Frontier Global Sciences Inc Page 5 o20 T203203 Final Report-SWWTFREV2
ommo12
Liz SiskaProject Manager
9
)--J middot ~~
)J fl~~J~c1N~r
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
Matrix Water Laboratory ID 1203203-01
ANALYTICAL RESULTS
SWWTF
Analyte Result lIDL MRL Units Dilution Batch Sequence Analyzed Method Notes
Aluminum 371 220 198 microgL 5 F203232 2C2000l 031912 EPA 2008 Mod
Arsenic 377 252 743 microgL 5 F203232 2C2000l 031912 EPA 2008 Mod
Cadmium 248 0205 0990 microgL 5 F203232 2C20001 031912 EPA2008 Mod
Chromium 532 045 495 microgL 5 F203232 2C20001 031912 EPA 2008 Mod
Copper 182 050 495 microgL 5 F203232 2C20001 031912 EPA 2008 Mod
Iron 1100 644 495 microgL 5 F203232 2C20001 031912 EPA 2008 Mod
Lead ND 0193 198 microgL 5 F203232 2C2000l 031912 EPA 2008 Mod u Manganese 7180 037 495 microgL 5 F203232 2C2000l 031912 EPA 2008 Mod
Mercury 612 842 505 ngL 100 F203288 2C22016 032212 EPA l631E FB-1631
Molybdenum 2000 297 297 microgL 50 F203260 2C22001 032112 EPA 2008 Mod
Nickel 303 040 495 microgL 5 F203232 2C20001 031912 EPA 2008 Mod
Selenium 587 959 297 microgL 5 F203232 2C20001 031912 EPA 2008 Mod
Silver ND 0297 0990 microgL 5 F203232 2C20001 031912 EPA 2008 Mod u Zinc 775 081 990 microgL 5 F203232 2C20001 031912 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report 011ly apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page6 o20 I203203 Final Report- SWWTF REV2
04042012
Liz Siska Project Manager 10
gt
C LO BA L S CI E N C ES
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
MATRIX DUPLICATESTRIPLICATES
SOURCE 1203203-01
Batch F203288
Preparation BrCl Oxidation
Sequence 2C22016
Lab Number F203288-DUPI
Sample Duplicate Concentration Concentration RPD
Analyte DgL ngL
5848
MRL 505
RPD 448
Limit
24
Method
EPA 163IE
Notes
Mercury 6116
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced In its entirety
Page 7of20 l 103203 Final Report- SWWTF REV2
04042012 bull 1 1 Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996
FROlJTIER Fx 425-686-3096 GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203203-01
Batch F203232 Sequence 2C20001
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203232-MSMSD 1
Sample Spike MS MS Concentration Added Concentration 0o Recovery
Analyte (microgL) (microgL) (microgL) Recovery Method NotesLimits
Alumimun 3707 15152 1853 978 70 - 130 EPA 2008 Mod
Chromium 5316 70707 1270 104 70- 130 EPA 2008 Mod
Manganese 7181 60606 7231 821 70 - 130 EPA 2008 Mod
Iron 1098 50505 6090 988 70- 130 EPA 2008 Mod
Nickel 3025 40404 3425 988 70 - 130 EPA 2008 Mod
Copper 1816 40404 5182 833 70 - 130 EPA2008 Mod
Arsenic 3770 15152 1904 101 70- 130 EPA 2008 Mod
Seleniwn 587l 30303 9297 113 70 - 130 EPA 2008 Mod
Silver ND 15152 1099 725 70 - 130 EPA 2008 Mod
Cadmillll) 2484 80808 9508 869 70 - 130 EPA 2008 Mod
Lead 0763 15152 1544 968 70-130 EPA2008Mod
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD
Recovery
Oo
RPD Recovery
Limits RPOLimit Method Notes
Aluminum 15152 1826 96l 145 70 shy 130 20 EPA 2008 Mod
Chromium 70707 1288 107 138 70-130 20 EPA 2008 Mod
Manganese 60606 7230 804 00140 70- 130 20 EPA 2008 Mod
Iron 50505 6065 983 0414 70- 130 20 EPA 2008 Mod
Nickel 40404 3378 872 138 70 - 130 20 EPA2008 Mod
Copper 40404 5140 823 0807 70 - 130 20 EPA 2008 Mod
Arsenic 15152 1928 102 123 70 - 130 20 EPA 2008 Mod
Selenium 30303 9063 105 255 70- 130 20 EPA 2008 Mod
Silver 15152 1075 709 219 70- 130 20 EPA 2008 Mod
Cadmium 80808 9347 849 170 70- 130 20 EPA 2008 Mod
Lead 15152 1531 960 0815 70- 130 20 EPA 2008 Mod
Frontier Global Sciences Inc The results In this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
PageBo20 1203203 FinalReport- SWWTFREV2
04042012
Liz Siska Project Manager 12
iii
11720 North Creek Parkway North Suite 400
Bothell WA 98011 Ph 425-686-1996 Fx 425-686-3096 GlOBAL SCIENCES
ij
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203203-01
Batch F203232 Sequence 2Q20001
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203232-MSMSD3
Analyte
Sample Concentration
(microgL)
Spike Added (pgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Limits Method Notes
Aluminum 3707 10000 10270 990 70 - 130 EPA 2008 Mod AS
Chromium 5316 10000 1137 108 70 - 130 EPA 2008 Mod AS Manganese 7181 10000 8207 103 70 - 130 EPA 2008 Mod AS
Iron 1098 50000 6185 102 70 - 130 EPA 2008 Mod AS Nickel 3025 12500 1433 905 70 - 130 EPA 2008 Mod AS Copper 1816 12500 1061 834 70 - 130 EPA 2008 Mod AS Zinc 7752 25000 1995 767 70 - 130 EPA 2008 Mod AS Arsenic 3770 10000 1073 104 70 - 130 EPA 2008 Mod AS Selenium 587l 10000 1530 943 70 - 130 EPA 2008 Mod AS Silver ND 50000 3690 738 70 - 130 EPA 2008 Mod AS Cadmium 2484 10000 8531 828 70 - 130 EPA 2008 Mod AS Lead 0763 25000 2505 999 70 - 130 EPA 2008 Mod AS
middoti
i
Aoalyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD o
Recovery
RPD Recovery
Limits RPDLimit Method Notes
Aluminum 10000 10150 978 121 70 - 130 20 EPA 2008 Mod AS Chromium 10000 1140 109 0293 70 - 130 20 EPA 2008 Mod AS Manganese 10000 8278 llO 0854 70 -130 20 EPA 2008 Mod AS Iron 50000 6243 103 0937 70-130 20 EPA 2008 Mod AS Nickel 12500 1441 91l middotos25 70 - 130 20 EPA 2008 Mod AS Copper 12500 1066 838 0496 70- 130 20 EPA 2008 Mod AS Zinc 25000 1990 765 0245 70- 130 20 EPA 2008 Mod AS Arsenic 10000 1094 106 193 70 - 130 20 EPA 2008 Mod AS Selenium 10000 1554 967 155 70 - 130 20 EPA 2008 Mod AS Silver 50000 3682 736 0222 70 - 130 20 EPA 2008 Mod AS Cadmium 10000 8394 815 l62 70 - 130 20 EPA 2008 Mod AS Lead 25000 250S 999 00263 70- 130 20 EPA 2008 Mod AS
~~ middotmiddot1 bull
bulli
bullmiddot
Frontier Global Sciences Inc The remits in this report only apply lo the samples analyzed in accordance with the chain ofcustody document This analytical report must bt reproductd In Its entirety
Page 9of20 1203203 Final Report-SWWTF REY2
04M2012
Liz Siska Project Manager 13
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 FRONTIER~ Fx 425-686-3096 GLOBAL SCIENCES
MATR1X SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203203-01RE3
Batch F203260 Sequence 2C22001
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203260-MSMSD3
Analyte
Sample Concentration
(microgL)
Spike Added (microgL)
MS Conctntration
(microgL)
MS
Recovery Recovery
Method Limits Notes
Molybdenum 1999 20200 middot 2041 206 70 - 130 EPA 2008 Mod QM-02
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD Oo
Recovery
RPD
Recovery Limits
RPO Limit Method Notes
Molybdenum 20200 2041 207 00141 70 - 130 20 EPA 2008 Mod QM-02
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed In accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page Oo20 1203203 Final Report- SWWTFREV2
04042012
Liz Siska Project Manager 14
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyzed in accordance with the chain ofcustody document This analytical report =tbe reproducedin Its entirety
Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
CLO~AL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1203203-0lREJ
Batch F203260
Preparation Closed Vessel Nitric Oven Digestion
Sequence 2C2200
Lab Number F203260-MSMSD6
Sample Spike MS MS
Analyte Concentration Added
(JtgL) (microgL) Concentration
(microgL)
Recovery Recovery
Method Limits Notes
Molybdenum 1999 50000 7034 101 70 - 130 EPA 2008 Mod AS
Spike MSD Added Concentration
MSD Recovery RPD
Analyte (microgL) (microgL) Recovery RPD Limits Limit Method Notes
Molybdenum 50000 7124 102 128 70 - 130 20 EPA 2008 Mod AS
Page 11 o20 1203203 Final Report- SWWTF REJ2
040412012
15
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 ~ Fx 425-686-3096 GLOBAL SCIENCES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203203-01
Batch F203288
Preparation BrCI Oxidation
Sequence 2C22016
Lab Number F203288-MSMSD 1
Sample Spike MS MS Concentration Added Concentration Recovery
Analyte (ngL) (ogL) (ogL) Recovery Method Notes Limits
Mercury 6116 25500 3096 974 71 - 125 EPA 1631E
Spike MSD MSD Oo Recovery RPD Added Concentration Oo
Limits Method Notes (ogL) (ogL) Recovery RPD Limit Analyte
Mercury 25500 2611 784 170 71 - 125 24 EPA 1631E
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed i11 accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 12of20 1203203 Final Report- SWWTF REV2
04042012
Liz Siska Project Manager 16
bull 11720 North Creek Parkway North Suite 400
Bothell WA 98011 Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1203194-17
Batch F203288 Sequence 2C22016
Preparation BrCI Oxidation Lab Number F203288-MSMSD2
Sample Spike MS MS
Analyte Concentration
(ngL) Added (ngL)
Concentration (ngL) Recovery
Recovery Limits Method Notes
Mercury 142800 505000 627200 959 71 - 125 EPA 1631E
Spike Added
MSD Concentration
MSD Recovery RPO
Analyte (ngL) (ngL) Recovery RPD Limits Limit Method Notes
Mercury 505000 632700 970 0879 71 - 125 24 EPA 1631E
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody docu~nt This analytical report must be reproduced In its entirety
Page 13of20 1203203 Final Report- SWWTFREV2
04042012
Liz Siska Project Manager 17
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996
bull ~ Fx 425-686-3096 GLPBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203232 Sequence 2C20001
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203232-BSBSD1
LCS Source mank Siiike
Spike LCS LCS Added Concentration Recovery
Analyte (microgL) (microgL) Recovery Limits Method Notes
Aluminwn 15000 1444 963 85-115 EPA2008Mod Chromium 70000 654 934 85 bull 115 EPA 2008 Mod Manganese 60000 580 967 85 - 115 EPA 2008 Mod Iron 50000 4610 922 85 - 115 EPA 2008 Mod Nickel 40000 394 985 85 ll5 EPA 2008 Mod Copper 40000 418 104 85 - 115 EPA 2008 Mod Zinc 10000 1017 102 85 bull 115 EPA 2008 Mod Arsenic 15000 1445 963 85 bull 115 EPA 2008 Mod Selenium 30000 2975 992 85-115 EPA2008Mod Molybdenum 20000 185 926 85 bull 115 EPA 2008 Mod Silver 15000 1555 104 85 - 115 EPA 2008 Mod
Cadmium 080000 0802 100 85 - 115 EPA 2008 Mod Lead 15000 1565 104 85 - 115 EPA 2008 Mod
shy
Spike LCSD LCSD Added Concentration Oo Recovery RPD
Analyte (microgL)
15000
(microgL)
1424
Recovery
949
RPD
140
Limits
85 bull 115
Limit
20
Method
EPA 2008 Mod
Notes
Aluminum
Chromium 70000 644 920 l58 85 bull 115 20 EPA 2008 Mod
Manganese 60000 575 958 0920 85 - ll5 20 EPA 2008 Mod
Iron 50000 4580 916 0660 85 - 115 20 EPA 2008 Mod
Nickel 40000 394 985 000457 85 bull 115 20 EPA 2008 Mod
Copper 40000 416 104 0367 85 - 115 20 EPA 2008 Mod
Zinc 10000 1032 103 147 85 - ll5 20 EPA 2008 Mod
Arsenic 15000 1440 960 0305 85 bull 115 20 EPA 2008 Mod
Selenium 30000 2867 956 369 85 -115 20 EPA 2008 Mod
Molybdenum 20000 l86 928 0196 85 -115 20 EPA2008 Mod
Silver l5000 1559 104 0233 85 bull 115 20 EPA 2008 Mod
Cadmium 080000 0809 101 0843 85 bull llS 20 EPA 2008 Mod
Lead 15000 l539 103 170 85 - 115 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed In accordance with the chain ofcustody document This analytical report must be reproduced in its enJirety
Page 14of20 1203203 Final Report- SWWTFREV2
04042012 ~~
Liz Siska Project Manager 18
11720 North Creek Parkway North Suite 400 Bothell WA 98011 Ph 425-686-1996
FRONTIER Fx 425-686-3096 GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203260 Sequence 2C22001
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203260-BSBSD1
LCS Source Blank Spike
Spike LCS LC$ Added Concentration Recovery
Analyte (ptgL) (JJgL) Recovery Limits Method Notes
Molybdenum 20000 182 910 85 - 115 EPA 2008 Mod
Spike LCSD LCSD Added Concentration Recovery RPD
Analyte (microgL) (microgL) Recovery RPD Limits Limit Method Notes
Molybdenum 20000 186 930 213 85 -115 20 EPA 2008 Mod
Frontier Global Sciences Inc The results In this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced In its entirety
Page 15 o20 I203203 Ftnal ampport- SWWTFREV2
04041202
Liz Siska Project Manager 19
middot
I
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SC IE NC ES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPO
Batch F203288 Sequence 2C22016
Preparation BrCI Oxidation Lab Number F203288-BSBSD I
LCS Source NIST 1641d
Spike LCS LCS Added Concentration Recovery
Analyte (ngL) (ngL) Recovery Limits Method Notes
Mercury 15679 1525 973 80 - 120 EPA l631E
Spike LCSD LCSD Added Concentration Oo Recovery RPD
Analyte (ngL) (ngL)
1516
Recovery
967
RPD
0622
Limits
80 - 120
Limit
24
Method
EPA 1631E
Notes
Mercury 15679
Frontier Global Sciences Inc The results in this report only apply lo the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 16 o20 1203203 Final Report- SWWIFREV2
041042012
20Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 middot Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096 ~ O GLO B AL SCI E NCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2C20001
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203232-BLK1 Aluminum 01 40 microgL F203232 PA2008 Molt u F203232-BLK1 Chromium -0007 0 10 microgL F203232 PA 2008 Molt u F203232-BLKI Manganese 0002 010 microgL F203232 PA 2008 Moc u F203232-BLK1 Iron -004 100 microgL F203232 PA 2008 Molt u F203232-BLKI Nickel 0005 010 microgL F203232 PA 2008 Moc u F203232-BLKI Copper 001 010 microgL F203232 PA 2008 Molt u F203232-BLK1 Zinc 011 020 microgL F203232 PA 2008 Moc u F203232-BLK I Arsenic -0009 015 microgL F203232 PA 2008 Moc u F203232-BLK1 Selenium 025 060 microgL F203232 PA 2008 Moc u F203232-BLK1 Molybdenum 001 006 microgL F203232 PA 2008 Moc u F203232-BLK1 Silver -00009 0020 microgL F203232 PA 2008 Moc u F203232-BLK1 Cadmium 0002 0020 microgL F203232 PA 2008 Molt u F203232-BLK1 Lead 0024 0040 microgL F203232 PA 2008 Molt u
middoti
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordonce with the chain ofcustody document Tnts analytical rtport must be reproduced In its enlfrtty
Page7of20 J203203 Final ampport-SWWTF REV2
04042012
Liz Siska Project Manager 21
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 FRONTIER~ Fx 425-686-3096 GLOBAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2C22001
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203260-BLK1 Molybdenum 001 006 microgL F203260 ~PA 2008 Moc u
Frontier Global Sciences Inc middot The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 18of20 1203203 Final Report- SWWTFREV2
04042012
Liz Siska Project Manager 22
~ CLOSAL SCIENCES
~
J1720 North Creek Parkway North Suite 400 Bothell WA 980 l l
Ph 425-686-1996 Fx 425-686-3096
PREPARATION BLANKS
Instrument Hg-17 Sequence 2C22016
Preparation BrCI Oxidation
The results in Ihis report only apply to the samples analyzed i12 accordance with the chain ofcustody dccumnt This analytical report must be reproductd in ils enJirety
Page I9oj20 1203203 Final Report- SWWTF REJ2
04042012
Frontier Global Sciences Inc
bull 23bull Liz Siska Project Manager
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203288-BLKl Mercury 007 050 ngL F203288 EPA 1631E u F203288-BLIlt2 Mercury 006 050 ngL F203288 EPA 163lE u F203288-BLK3 Mercury 006 050 ngL F203288 EPA I63lE u F203288-BLK4 Mercury 018 050 ngL F203288 EPA I63IE U QB-04
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
Notes and Definitions
U Analyte included in the analysis but not detected
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than I times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable ASASD
QB-04 The blank was preserved to 2 BrCl rather than I The control limit for blanks presetved to greater than 1 BrCl is the preservation percentage multiplied by the l1RL
FB-1631 Required equipmentfieldfilter blank not submitted by the client The sample has been analyzed according to 163 lE but does not meet 163 lE criteria
AS This MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
l1RL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to lhe samples analyzedin accordance wirh the chain ofcustody document This analytical report must be reproduced in its entirety
Page 20of20 1203203 Final Report- SWWTF REV2
04042012
24
bull bull
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PO_______QUOTE===-~----shy I RELINQUISHED BY DATE TIME Rmmo BT I FIElllJUDINGStt HI l lS 2
eastern analytical inc 2s CHENELl DR1ve I CoNcoRo NH 03301 I TEL 60322sos2s I 1soo2s7os2s IFAXc 6032284591 I E-MA1l cusToMER_seRv1ceEA1LAascoHj wwweA1lAsscoM
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FRONTIER
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIE NCES
CHAIN OF CUSTODY FORMS
bullbull _ ~ -bull uer ( A c 2 - gt Sampre Recefpt CHockJlst
Data Looobulld tn ~tZfrPkttr ~~middot0 middot1)d bull MSi~~gtamp Loss bull d I n Sy
SOG o f Coolns- R~oetvbullG I ( FGSPM
Sarn01 AnIVed bull)I ----Shipp ing --=--___~~-=-------=_lta=~-=--===---------
___Nona (ArnblbullnQ
SbullNfo Cour1bullr TrecklngJAtrtgtIII Nubbulltbull) e Xlt---Z-~q gt
-rhermal PreuorvatJon Loo~ l~ ___GeleJubull lea
rT~hbull_ornebullur_10~gt~(~5z2~_--CorrftCtfan rbullclOf (Cfl) ~lt2 - 3 degre-bull O eoolbullr- 1 L ~ middoto CoCttbullr a bullc eoolbullr-2 middot c Cootbullr7 middotc
middot c Cooler a bullc middot c
middotc middot c
Coolar 18
Chbullln orCutody COO $ pria1-ct-n bullnd lneludee thbull folto~ng Information for obulloh ~~mple
NA Comrnbullnta
Sbullrnolampd BvshyPrbullbullation bullmiddot ~uoa1bulld Ana1vbullbullbullmiddot Roaulbulld SlcnHt vrbullr
middot------------ shy ---ilnt-nat chaln or custOdv irv1d
l-~=V
---l shy ---+--~-shy ----+-----------1
Samplbull CondltJonltnte-oi $bullmole containerbull wbullra -oehbulld Jr1tlact bull--bull labolbull bullshy _nt bulln lenfbln
lteon-eet aamIbull oontarners U ~ltftd fcrr reauect1Dd 0rnafv8ebull sbullm-reraquo roCHtlvOd In holdrna tlmomiddot bullbullrn- bull vohnlIbull auMolen ~~r raubullbulltbulld anaalvbull a
Voa No
CotTbulld orbullbullbulltvotlvbull ucact for aue atect -nahrbull _ -shyM of bull-n~tshy Qhertced a-d mthod l~e-ntbull -
Cllent Communloatfott Po~ Contaicta Oat611mbull _____ _
Commentbull
Mbulltnod ____ _
Olbull~bullronJRbullbullo1utlon
The results in this report only apply to the samples analy-ed in accordance with the Frontier Global Sciences Inc chain ofcustody docutMnt This aMlytical report must be reprodu~d in its e111irety
Page3of20 1203203 Final Rtport- SWWTFREV2
04042012
Liz Siska Project Manager 7
l l 720 North Creek Parkway Nortn u1Le -tvv Bothell WA 9amp011
Ph 425-686-1996 Fx 425-686-3096
FRONTIER GLOBAL SCIENCES
CHAIN OF CUSTODY FORMS
The results in this report only apply to the samples analyzed in accordance with the cliain ofcustody documenL This analytical report must be reproduced in its entirety
Frontier Global Sciences Inc Page 4 o20 1203203 Final Report- SWWTF REV2
04042012
Liz Siska Project Manager
8
11720 North Creek Parkway North Suite 40U Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
FRONTIER C L 0 B AL SC I~ NC ES
CHAlN OF CUSTODY FORMS
i---t--+-l-+-+-+--+--+--+--+_micro~[_amp~lslte---l t---t--+--11-(- -1--+-~-+--l---l---+----------f_ rmiddot 1---+--~--l--f-+---l--l--l-+--I--I---- _____--1 lt 1--1--1--+--l--------4-+-+--l--+-+--____f_ i--t--+--1r-+-+-+-t-+-++-4-________ _j bull-
CN _r(gt --shyshy~
_lj _D ~ -~ Irgt ~ -f
~ ~
The results In this report onlyapply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reprodu~din its entirety
Frontier Global Sciences Inc Page 5 o20 T203203 Final Report-SWWTFREV2
ommo12
Liz SiskaProject Manager
9
)--J middot ~~
)J fl~~J~c1N~r
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
Matrix Water Laboratory ID 1203203-01
ANALYTICAL RESULTS
SWWTF
Analyte Result lIDL MRL Units Dilution Batch Sequence Analyzed Method Notes
Aluminum 371 220 198 microgL 5 F203232 2C2000l 031912 EPA 2008 Mod
Arsenic 377 252 743 microgL 5 F203232 2C2000l 031912 EPA 2008 Mod
Cadmium 248 0205 0990 microgL 5 F203232 2C20001 031912 EPA2008 Mod
Chromium 532 045 495 microgL 5 F203232 2C20001 031912 EPA 2008 Mod
Copper 182 050 495 microgL 5 F203232 2C20001 031912 EPA 2008 Mod
Iron 1100 644 495 microgL 5 F203232 2C20001 031912 EPA 2008 Mod
Lead ND 0193 198 microgL 5 F203232 2C2000l 031912 EPA 2008 Mod u Manganese 7180 037 495 microgL 5 F203232 2C2000l 031912 EPA 2008 Mod
Mercury 612 842 505 ngL 100 F203288 2C22016 032212 EPA l631E FB-1631
Molybdenum 2000 297 297 microgL 50 F203260 2C22001 032112 EPA 2008 Mod
Nickel 303 040 495 microgL 5 F203232 2C20001 031912 EPA 2008 Mod
Selenium 587 959 297 microgL 5 F203232 2C20001 031912 EPA 2008 Mod
Silver ND 0297 0990 microgL 5 F203232 2C20001 031912 EPA 2008 Mod u Zinc 775 081 990 microgL 5 F203232 2C20001 031912 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report 011ly apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page6 o20 I203203 Final Report- SWWTF REV2
04042012
Liz Siska Project Manager 10
gt
C LO BA L S CI E N C ES
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
MATRIX DUPLICATESTRIPLICATES
SOURCE 1203203-01
Batch F203288
Preparation BrCl Oxidation
Sequence 2C22016
Lab Number F203288-DUPI
Sample Duplicate Concentration Concentration RPD
Analyte DgL ngL
5848
MRL 505
RPD 448
Limit
24
Method
EPA 163IE
Notes
Mercury 6116
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced In its entirety
Page 7of20 l 103203 Final Report- SWWTF REV2
04042012 bull 1 1 Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996
FROlJTIER Fx 425-686-3096 GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203203-01
Batch F203232 Sequence 2C20001
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203232-MSMSD 1
Sample Spike MS MS Concentration Added Concentration 0o Recovery
Analyte (microgL) (microgL) (microgL) Recovery Method NotesLimits
Alumimun 3707 15152 1853 978 70 - 130 EPA 2008 Mod
Chromium 5316 70707 1270 104 70- 130 EPA 2008 Mod
Manganese 7181 60606 7231 821 70 - 130 EPA 2008 Mod
Iron 1098 50505 6090 988 70- 130 EPA 2008 Mod
Nickel 3025 40404 3425 988 70 - 130 EPA 2008 Mod
Copper 1816 40404 5182 833 70 - 130 EPA2008 Mod
Arsenic 3770 15152 1904 101 70- 130 EPA 2008 Mod
Seleniwn 587l 30303 9297 113 70 - 130 EPA 2008 Mod
Silver ND 15152 1099 725 70 - 130 EPA 2008 Mod
Cadmillll) 2484 80808 9508 869 70 - 130 EPA 2008 Mod
Lead 0763 15152 1544 968 70-130 EPA2008Mod
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD
Recovery
Oo
RPD Recovery
Limits RPOLimit Method Notes
Aluminum 15152 1826 96l 145 70 shy 130 20 EPA 2008 Mod
Chromium 70707 1288 107 138 70-130 20 EPA 2008 Mod
Manganese 60606 7230 804 00140 70- 130 20 EPA 2008 Mod
Iron 50505 6065 983 0414 70- 130 20 EPA 2008 Mod
Nickel 40404 3378 872 138 70 - 130 20 EPA2008 Mod
Copper 40404 5140 823 0807 70 - 130 20 EPA 2008 Mod
Arsenic 15152 1928 102 123 70 - 130 20 EPA 2008 Mod
Selenium 30303 9063 105 255 70- 130 20 EPA 2008 Mod
Silver 15152 1075 709 219 70- 130 20 EPA 2008 Mod
Cadmium 80808 9347 849 170 70- 130 20 EPA 2008 Mod
Lead 15152 1531 960 0815 70- 130 20 EPA 2008 Mod
Frontier Global Sciences Inc The results In this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
PageBo20 1203203 FinalReport- SWWTFREV2
04042012
Liz Siska Project Manager 12
iii
11720 North Creek Parkway North Suite 400
Bothell WA 98011 Ph 425-686-1996 Fx 425-686-3096 GlOBAL SCIENCES
ij
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203203-01
Batch F203232 Sequence 2Q20001
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203232-MSMSD3
Analyte
Sample Concentration
(microgL)
Spike Added (pgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Limits Method Notes
Aluminum 3707 10000 10270 990 70 - 130 EPA 2008 Mod AS
Chromium 5316 10000 1137 108 70 - 130 EPA 2008 Mod AS Manganese 7181 10000 8207 103 70 - 130 EPA 2008 Mod AS
Iron 1098 50000 6185 102 70 - 130 EPA 2008 Mod AS Nickel 3025 12500 1433 905 70 - 130 EPA 2008 Mod AS Copper 1816 12500 1061 834 70 - 130 EPA 2008 Mod AS Zinc 7752 25000 1995 767 70 - 130 EPA 2008 Mod AS Arsenic 3770 10000 1073 104 70 - 130 EPA 2008 Mod AS Selenium 587l 10000 1530 943 70 - 130 EPA 2008 Mod AS Silver ND 50000 3690 738 70 - 130 EPA 2008 Mod AS Cadmium 2484 10000 8531 828 70 - 130 EPA 2008 Mod AS Lead 0763 25000 2505 999 70 - 130 EPA 2008 Mod AS
middoti
i
Aoalyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD o
Recovery
RPD Recovery
Limits RPDLimit Method Notes
Aluminum 10000 10150 978 121 70 - 130 20 EPA 2008 Mod AS Chromium 10000 1140 109 0293 70 - 130 20 EPA 2008 Mod AS Manganese 10000 8278 llO 0854 70 -130 20 EPA 2008 Mod AS Iron 50000 6243 103 0937 70-130 20 EPA 2008 Mod AS Nickel 12500 1441 91l middotos25 70 - 130 20 EPA 2008 Mod AS Copper 12500 1066 838 0496 70- 130 20 EPA 2008 Mod AS Zinc 25000 1990 765 0245 70- 130 20 EPA 2008 Mod AS Arsenic 10000 1094 106 193 70 - 130 20 EPA 2008 Mod AS Selenium 10000 1554 967 155 70 - 130 20 EPA 2008 Mod AS Silver 50000 3682 736 0222 70 - 130 20 EPA 2008 Mod AS Cadmium 10000 8394 815 l62 70 - 130 20 EPA 2008 Mod AS Lead 25000 250S 999 00263 70- 130 20 EPA 2008 Mod AS
~~ middotmiddot1 bull
bulli
bullmiddot
Frontier Global Sciences Inc The remits in this report only apply lo the samples analyzed in accordance with the chain ofcustody document This analytical report must bt reproductd In Its entirety
Page 9of20 1203203 Final Report-SWWTF REY2
04M2012
Liz Siska Project Manager 13
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 FRONTIER~ Fx 425-686-3096 GLOBAL SCIENCES
MATR1X SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203203-01RE3
Batch F203260 Sequence 2C22001
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203260-MSMSD3
Analyte
Sample Concentration
(microgL)
Spike Added (microgL)
MS Conctntration
(microgL)
MS
Recovery Recovery
Method Limits Notes
Molybdenum 1999 20200 middot 2041 206 70 - 130 EPA 2008 Mod QM-02
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD Oo
Recovery
RPD
Recovery Limits
RPO Limit Method Notes
Molybdenum 20200 2041 207 00141 70 - 130 20 EPA 2008 Mod QM-02
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed In accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page Oo20 1203203 Final Report- SWWTFREV2
04042012
Liz Siska Project Manager 14
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyzed in accordance with the chain ofcustody document This analytical report =tbe reproducedin Its entirety
Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
CLO~AL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1203203-0lREJ
Batch F203260
Preparation Closed Vessel Nitric Oven Digestion
Sequence 2C2200
Lab Number F203260-MSMSD6
Sample Spike MS MS
Analyte Concentration Added
(JtgL) (microgL) Concentration
(microgL)
Recovery Recovery
Method Limits Notes
Molybdenum 1999 50000 7034 101 70 - 130 EPA 2008 Mod AS
Spike MSD Added Concentration
MSD Recovery RPD
Analyte (microgL) (microgL) Recovery RPD Limits Limit Method Notes
Molybdenum 50000 7124 102 128 70 - 130 20 EPA 2008 Mod AS
Page 11 o20 1203203 Final Report- SWWTF REJ2
040412012
15
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 ~ Fx 425-686-3096 GLOBAL SCIENCES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203203-01
Batch F203288
Preparation BrCI Oxidation
Sequence 2C22016
Lab Number F203288-MSMSD 1
Sample Spike MS MS Concentration Added Concentration Recovery
Analyte (ngL) (ogL) (ogL) Recovery Method Notes Limits
Mercury 6116 25500 3096 974 71 - 125 EPA 1631E
Spike MSD MSD Oo Recovery RPD Added Concentration Oo
Limits Method Notes (ogL) (ogL) Recovery RPD Limit Analyte
Mercury 25500 2611 784 170 71 - 125 24 EPA 1631E
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed i11 accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 12of20 1203203 Final Report- SWWTF REV2
04042012
Liz Siska Project Manager 16
bull 11720 North Creek Parkway North Suite 400
Bothell WA 98011 Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1203194-17
Batch F203288 Sequence 2C22016
Preparation BrCI Oxidation Lab Number F203288-MSMSD2
Sample Spike MS MS
Analyte Concentration
(ngL) Added (ngL)
Concentration (ngL) Recovery
Recovery Limits Method Notes
Mercury 142800 505000 627200 959 71 - 125 EPA 1631E
Spike Added
MSD Concentration
MSD Recovery RPO
Analyte (ngL) (ngL) Recovery RPD Limits Limit Method Notes
Mercury 505000 632700 970 0879 71 - 125 24 EPA 1631E
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody docu~nt This analytical report must be reproduced In its entirety
Page 13of20 1203203 Final Report- SWWTFREV2
04042012
Liz Siska Project Manager 17
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996
bull ~ Fx 425-686-3096 GLPBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203232 Sequence 2C20001
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203232-BSBSD1
LCS Source mank Siiike
Spike LCS LCS Added Concentration Recovery
Analyte (microgL) (microgL) Recovery Limits Method Notes
Aluminwn 15000 1444 963 85-115 EPA2008Mod Chromium 70000 654 934 85 bull 115 EPA 2008 Mod Manganese 60000 580 967 85 - 115 EPA 2008 Mod Iron 50000 4610 922 85 - 115 EPA 2008 Mod Nickel 40000 394 985 85 ll5 EPA 2008 Mod Copper 40000 418 104 85 - 115 EPA 2008 Mod Zinc 10000 1017 102 85 bull 115 EPA 2008 Mod Arsenic 15000 1445 963 85 bull 115 EPA 2008 Mod Selenium 30000 2975 992 85-115 EPA2008Mod Molybdenum 20000 185 926 85 bull 115 EPA 2008 Mod Silver 15000 1555 104 85 - 115 EPA 2008 Mod
Cadmium 080000 0802 100 85 - 115 EPA 2008 Mod Lead 15000 1565 104 85 - 115 EPA 2008 Mod
shy
Spike LCSD LCSD Added Concentration Oo Recovery RPD
Analyte (microgL)
15000
(microgL)
1424
Recovery
949
RPD
140
Limits
85 bull 115
Limit
20
Method
EPA 2008 Mod
Notes
Aluminum
Chromium 70000 644 920 l58 85 bull 115 20 EPA 2008 Mod
Manganese 60000 575 958 0920 85 - ll5 20 EPA 2008 Mod
Iron 50000 4580 916 0660 85 - 115 20 EPA 2008 Mod
Nickel 40000 394 985 000457 85 bull 115 20 EPA 2008 Mod
Copper 40000 416 104 0367 85 - 115 20 EPA 2008 Mod
Zinc 10000 1032 103 147 85 - ll5 20 EPA 2008 Mod
Arsenic 15000 1440 960 0305 85 bull 115 20 EPA 2008 Mod
Selenium 30000 2867 956 369 85 -115 20 EPA 2008 Mod
Molybdenum 20000 l86 928 0196 85 -115 20 EPA2008 Mod
Silver l5000 1559 104 0233 85 bull 115 20 EPA 2008 Mod
Cadmium 080000 0809 101 0843 85 bull llS 20 EPA 2008 Mod
Lead 15000 l539 103 170 85 - 115 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed In accordance with the chain ofcustody document This analytical report must be reproduced in its enJirety
Page 14of20 1203203 Final Report- SWWTFREV2
04042012 ~~
Liz Siska Project Manager 18
11720 North Creek Parkway North Suite 400 Bothell WA 98011 Ph 425-686-1996
FRONTIER Fx 425-686-3096 GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203260 Sequence 2C22001
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203260-BSBSD1
LCS Source Blank Spike
Spike LCS LC$ Added Concentration Recovery
Analyte (ptgL) (JJgL) Recovery Limits Method Notes
Molybdenum 20000 182 910 85 - 115 EPA 2008 Mod
Spike LCSD LCSD Added Concentration Recovery RPD
Analyte (microgL) (microgL) Recovery RPD Limits Limit Method Notes
Molybdenum 20000 186 930 213 85 -115 20 EPA 2008 Mod
Frontier Global Sciences Inc The results In this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced In its entirety
Page 15 o20 I203203 Ftnal ampport- SWWTFREV2
04041202
Liz Siska Project Manager 19
middot
I
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SC IE NC ES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPO
Batch F203288 Sequence 2C22016
Preparation BrCI Oxidation Lab Number F203288-BSBSD I
LCS Source NIST 1641d
Spike LCS LCS Added Concentration Recovery
Analyte (ngL) (ngL) Recovery Limits Method Notes
Mercury 15679 1525 973 80 - 120 EPA l631E
Spike LCSD LCSD Added Concentration Oo Recovery RPD
Analyte (ngL) (ngL)
1516
Recovery
967
RPD
0622
Limits
80 - 120
Limit
24
Method
EPA 1631E
Notes
Mercury 15679
Frontier Global Sciences Inc The results in this report only apply lo the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 16 o20 1203203 Final Report- SWWIFREV2
041042012
20Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 middot Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096 ~ O GLO B AL SCI E NCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2C20001
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203232-BLK1 Aluminum 01 40 microgL F203232 PA2008 Molt u F203232-BLK1 Chromium -0007 0 10 microgL F203232 PA 2008 Molt u F203232-BLKI Manganese 0002 010 microgL F203232 PA 2008 Moc u F203232-BLK1 Iron -004 100 microgL F203232 PA 2008 Molt u F203232-BLKI Nickel 0005 010 microgL F203232 PA 2008 Moc u F203232-BLKI Copper 001 010 microgL F203232 PA 2008 Molt u F203232-BLK1 Zinc 011 020 microgL F203232 PA 2008 Moc u F203232-BLK I Arsenic -0009 015 microgL F203232 PA 2008 Moc u F203232-BLK1 Selenium 025 060 microgL F203232 PA 2008 Moc u F203232-BLK1 Molybdenum 001 006 microgL F203232 PA 2008 Moc u F203232-BLK1 Silver -00009 0020 microgL F203232 PA 2008 Moc u F203232-BLK1 Cadmium 0002 0020 microgL F203232 PA 2008 Molt u F203232-BLK1 Lead 0024 0040 microgL F203232 PA 2008 Molt u
middoti
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordonce with the chain ofcustody document Tnts analytical rtport must be reproduced In its enlfrtty
Page7of20 J203203 Final ampport-SWWTF REV2
04042012
Liz Siska Project Manager 21
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 FRONTIER~ Fx 425-686-3096 GLOBAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2C22001
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203260-BLK1 Molybdenum 001 006 microgL F203260 ~PA 2008 Moc u
Frontier Global Sciences Inc middot The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 18of20 1203203 Final Report- SWWTFREV2
04042012
Liz Siska Project Manager 22
~ CLOSAL SCIENCES
~
J1720 North Creek Parkway North Suite 400 Bothell WA 980 l l
Ph 425-686-1996 Fx 425-686-3096
PREPARATION BLANKS
Instrument Hg-17 Sequence 2C22016
Preparation BrCI Oxidation
The results in Ihis report only apply to the samples analyzed i12 accordance with the chain ofcustody dccumnt This analytical report must be reproductd in ils enJirety
Page I9oj20 1203203 Final Report- SWWTF REJ2
04042012
Frontier Global Sciences Inc
bull 23bull Liz Siska Project Manager
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203288-BLKl Mercury 007 050 ngL F203288 EPA 1631E u F203288-BLIlt2 Mercury 006 050 ngL F203288 EPA 163lE u F203288-BLK3 Mercury 006 050 ngL F203288 EPA I63lE u F203288-BLK4 Mercury 018 050 ngL F203288 EPA I63IE U QB-04
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
Notes and Definitions
U Analyte included in the analysis but not detected
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than I times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable ASASD
QB-04 The blank was preserved to 2 BrCl rather than I The control limit for blanks presetved to greater than 1 BrCl is the preservation percentage multiplied by the l1RL
FB-1631 Required equipmentfieldfilter blank not submitted by the client The sample has been analyzed according to 163 lE but does not meet 163 lE criteria
AS This MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
l1RL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to lhe samples analyzedin accordance wirh the chain ofcustody document This analytical report must be reproduced in its entirety
Page 20of20 1203203 Final Report- SWWTF REV2
04042012
24
bull bull
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GWP OIL FUND BROWNFJUD OR Orm--------shy RELINQUISHED BY DATE TIME RECEIVED Br Summo (ONTAHINATIOM_______
PO_______QUOTE===-~----shy I RELINQUISHED BY DATE TIME Rmmo BT I FIElllJUDINGStt HI l lS 2
eastern analytical inc 2s CHENELl DR1ve I CoNcoRo NH 03301 I TEL 60322sos2s I 1soo2s7os2s IFAXc 6032284591 I E-MA1l cusToMER_seRv1ceEA1LAascoHj wwweA1lAsscoM
prufmin111ll11bomtory1m1im (WHITE ORIGINAL GREEN PROJECT MANAGER)
shy
shy
l l 720 North Creek Parkway Nortn u1Le -tvv Bothell WA 9amp011
Ph 425-686-1996 Fx 425-686-3096
FRONTIER GLOBAL SCIENCES
CHAIN OF CUSTODY FORMS
The results in this report only apply to the samples analyzed in accordance with the cliain ofcustody documenL This analytical report must be reproduced in its entirety
Frontier Global Sciences Inc Page 4 o20 1203203 Final Report- SWWTF REV2
04042012
Liz Siska Project Manager
8
11720 North Creek Parkway North Suite 40U Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
FRONTIER C L 0 B AL SC I~ NC ES
CHAlN OF CUSTODY FORMS
i---t--+-l-+-+-+--+--+--+--+_micro~[_amp~lslte---l t---t--+--11-(- -1--+-~-+--l---l---+----------f_ rmiddot 1---+--~--l--f-+---l--l--l-+--I--I---- _____--1 lt 1--1--1--+--l--------4-+-+--l--+-+--____f_ i--t--+--1r-+-+-+-t-+-++-4-________ _j bull-
CN _r(gt --shyshy~
_lj _D ~ -~ Irgt ~ -f
~ ~
The results In this report onlyapply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reprodu~din its entirety
Frontier Global Sciences Inc Page 5 o20 T203203 Final Report-SWWTFREV2
ommo12
Liz SiskaProject Manager
9
)--J middot ~~
)J fl~~J~c1N~r
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
Matrix Water Laboratory ID 1203203-01
ANALYTICAL RESULTS
SWWTF
Analyte Result lIDL MRL Units Dilution Batch Sequence Analyzed Method Notes
Aluminum 371 220 198 microgL 5 F203232 2C2000l 031912 EPA 2008 Mod
Arsenic 377 252 743 microgL 5 F203232 2C2000l 031912 EPA 2008 Mod
Cadmium 248 0205 0990 microgL 5 F203232 2C20001 031912 EPA2008 Mod
Chromium 532 045 495 microgL 5 F203232 2C20001 031912 EPA 2008 Mod
Copper 182 050 495 microgL 5 F203232 2C20001 031912 EPA 2008 Mod
Iron 1100 644 495 microgL 5 F203232 2C20001 031912 EPA 2008 Mod
Lead ND 0193 198 microgL 5 F203232 2C2000l 031912 EPA 2008 Mod u Manganese 7180 037 495 microgL 5 F203232 2C2000l 031912 EPA 2008 Mod
Mercury 612 842 505 ngL 100 F203288 2C22016 032212 EPA l631E FB-1631
Molybdenum 2000 297 297 microgL 50 F203260 2C22001 032112 EPA 2008 Mod
Nickel 303 040 495 microgL 5 F203232 2C20001 031912 EPA 2008 Mod
Selenium 587 959 297 microgL 5 F203232 2C20001 031912 EPA 2008 Mod
Silver ND 0297 0990 microgL 5 F203232 2C20001 031912 EPA 2008 Mod u Zinc 775 081 990 microgL 5 F203232 2C20001 031912 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report 011ly apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page6 o20 I203203 Final Report- SWWTF REV2
04042012
Liz Siska Project Manager 10
gt
C LO BA L S CI E N C ES
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
MATRIX DUPLICATESTRIPLICATES
SOURCE 1203203-01
Batch F203288
Preparation BrCl Oxidation
Sequence 2C22016
Lab Number F203288-DUPI
Sample Duplicate Concentration Concentration RPD
Analyte DgL ngL
5848
MRL 505
RPD 448
Limit
24
Method
EPA 163IE
Notes
Mercury 6116
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced In its entirety
Page 7of20 l 103203 Final Report- SWWTF REV2
04042012 bull 1 1 Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996
FROlJTIER Fx 425-686-3096 GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203203-01
Batch F203232 Sequence 2C20001
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203232-MSMSD 1
Sample Spike MS MS Concentration Added Concentration 0o Recovery
Analyte (microgL) (microgL) (microgL) Recovery Method NotesLimits
Alumimun 3707 15152 1853 978 70 - 130 EPA 2008 Mod
Chromium 5316 70707 1270 104 70- 130 EPA 2008 Mod
Manganese 7181 60606 7231 821 70 - 130 EPA 2008 Mod
Iron 1098 50505 6090 988 70- 130 EPA 2008 Mod
Nickel 3025 40404 3425 988 70 - 130 EPA 2008 Mod
Copper 1816 40404 5182 833 70 - 130 EPA2008 Mod
Arsenic 3770 15152 1904 101 70- 130 EPA 2008 Mod
Seleniwn 587l 30303 9297 113 70 - 130 EPA 2008 Mod
Silver ND 15152 1099 725 70 - 130 EPA 2008 Mod
Cadmillll) 2484 80808 9508 869 70 - 130 EPA 2008 Mod
Lead 0763 15152 1544 968 70-130 EPA2008Mod
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD
Recovery
Oo
RPD Recovery
Limits RPOLimit Method Notes
Aluminum 15152 1826 96l 145 70 shy 130 20 EPA 2008 Mod
Chromium 70707 1288 107 138 70-130 20 EPA 2008 Mod
Manganese 60606 7230 804 00140 70- 130 20 EPA 2008 Mod
Iron 50505 6065 983 0414 70- 130 20 EPA 2008 Mod
Nickel 40404 3378 872 138 70 - 130 20 EPA2008 Mod
Copper 40404 5140 823 0807 70 - 130 20 EPA 2008 Mod
Arsenic 15152 1928 102 123 70 - 130 20 EPA 2008 Mod
Selenium 30303 9063 105 255 70- 130 20 EPA 2008 Mod
Silver 15152 1075 709 219 70- 130 20 EPA 2008 Mod
Cadmium 80808 9347 849 170 70- 130 20 EPA 2008 Mod
Lead 15152 1531 960 0815 70- 130 20 EPA 2008 Mod
Frontier Global Sciences Inc The results In this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
PageBo20 1203203 FinalReport- SWWTFREV2
04042012
Liz Siska Project Manager 12
iii
11720 North Creek Parkway North Suite 400
Bothell WA 98011 Ph 425-686-1996 Fx 425-686-3096 GlOBAL SCIENCES
ij
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203203-01
Batch F203232 Sequence 2Q20001
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203232-MSMSD3
Analyte
Sample Concentration
(microgL)
Spike Added (pgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Limits Method Notes
Aluminum 3707 10000 10270 990 70 - 130 EPA 2008 Mod AS
Chromium 5316 10000 1137 108 70 - 130 EPA 2008 Mod AS Manganese 7181 10000 8207 103 70 - 130 EPA 2008 Mod AS
Iron 1098 50000 6185 102 70 - 130 EPA 2008 Mod AS Nickel 3025 12500 1433 905 70 - 130 EPA 2008 Mod AS Copper 1816 12500 1061 834 70 - 130 EPA 2008 Mod AS Zinc 7752 25000 1995 767 70 - 130 EPA 2008 Mod AS Arsenic 3770 10000 1073 104 70 - 130 EPA 2008 Mod AS Selenium 587l 10000 1530 943 70 - 130 EPA 2008 Mod AS Silver ND 50000 3690 738 70 - 130 EPA 2008 Mod AS Cadmium 2484 10000 8531 828 70 - 130 EPA 2008 Mod AS Lead 0763 25000 2505 999 70 - 130 EPA 2008 Mod AS
middoti
i
Aoalyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD o
Recovery
RPD Recovery
Limits RPDLimit Method Notes
Aluminum 10000 10150 978 121 70 - 130 20 EPA 2008 Mod AS Chromium 10000 1140 109 0293 70 - 130 20 EPA 2008 Mod AS Manganese 10000 8278 llO 0854 70 -130 20 EPA 2008 Mod AS Iron 50000 6243 103 0937 70-130 20 EPA 2008 Mod AS Nickel 12500 1441 91l middotos25 70 - 130 20 EPA 2008 Mod AS Copper 12500 1066 838 0496 70- 130 20 EPA 2008 Mod AS Zinc 25000 1990 765 0245 70- 130 20 EPA 2008 Mod AS Arsenic 10000 1094 106 193 70 - 130 20 EPA 2008 Mod AS Selenium 10000 1554 967 155 70 - 130 20 EPA 2008 Mod AS Silver 50000 3682 736 0222 70 - 130 20 EPA 2008 Mod AS Cadmium 10000 8394 815 l62 70 - 130 20 EPA 2008 Mod AS Lead 25000 250S 999 00263 70- 130 20 EPA 2008 Mod AS
~~ middotmiddot1 bull
bulli
bullmiddot
Frontier Global Sciences Inc The remits in this report only apply lo the samples analyzed in accordance with the chain ofcustody document This analytical report must bt reproductd In Its entirety
Page 9of20 1203203 Final Report-SWWTF REY2
04M2012
Liz Siska Project Manager 13
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 FRONTIER~ Fx 425-686-3096 GLOBAL SCIENCES
MATR1X SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203203-01RE3
Batch F203260 Sequence 2C22001
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203260-MSMSD3
Analyte
Sample Concentration
(microgL)
Spike Added (microgL)
MS Conctntration
(microgL)
MS
Recovery Recovery
Method Limits Notes
Molybdenum 1999 20200 middot 2041 206 70 - 130 EPA 2008 Mod QM-02
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD Oo
Recovery
RPD
Recovery Limits
RPO Limit Method Notes
Molybdenum 20200 2041 207 00141 70 - 130 20 EPA 2008 Mod QM-02
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed In accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page Oo20 1203203 Final Report- SWWTFREV2
04042012
Liz Siska Project Manager 14
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyzed in accordance with the chain ofcustody document This analytical report =tbe reproducedin Its entirety
Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
CLO~AL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1203203-0lREJ
Batch F203260
Preparation Closed Vessel Nitric Oven Digestion
Sequence 2C2200
Lab Number F203260-MSMSD6
Sample Spike MS MS
Analyte Concentration Added
(JtgL) (microgL) Concentration
(microgL)
Recovery Recovery
Method Limits Notes
Molybdenum 1999 50000 7034 101 70 - 130 EPA 2008 Mod AS
Spike MSD Added Concentration
MSD Recovery RPD
Analyte (microgL) (microgL) Recovery RPD Limits Limit Method Notes
Molybdenum 50000 7124 102 128 70 - 130 20 EPA 2008 Mod AS
Page 11 o20 1203203 Final Report- SWWTF REJ2
040412012
15
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 ~ Fx 425-686-3096 GLOBAL SCIENCES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203203-01
Batch F203288
Preparation BrCI Oxidation
Sequence 2C22016
Lab Number F203288-MSMSD 1
Sample Spike MS MS Concentration Added Concentration Recovery
Analyte (ngL) (ogL) (ogL) Recovery Method Notes Limits
Mercury 6116 25500 3096 974 71 - 125 EPA 1631E
Spike MSD MSD Oo Recovery RPD Added Concentration Oo
Limits Method Notes (ogL) (ogL) Recovery RPD Limit Analyte
Mercury 25500 2611 784 170 71 - 125 24 EPA 1631E
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed i11 accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 12of20 1203203 Final Report- SWWTF REV2
04042012
Liz Siska Project Manager 16
bull 11720 North Creek Parkway North Suite 400
Bothell WA 98011 Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1203194-17
Batch F203288 Sequence 2C22016
Preparation BrCI Oxidation Lab Number F203288-MSMSD2
Sample Spike MS MS
Analyte Concentration
(ngL) Added (ngL)
Concentration (ngL) Recovery
Recovery Limits Method Notes
Mercury 142800 505000 627200 959 71 - 125 EPA 1631E
Spike Added
MSD Concentration
MSD Recovery RPO
Analyte (ngL) (ngL) Recovery RPD Limits Limit Method Notes
Mercury 505000 632700 970 0879 71 - 125 24 EPA 1631E
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody docu~nt This analytical report must be reproduced In its entirety
Page 13of20 1203203 Final Report- SWWTFREV2
04042012
Liz Siska Project Manager 17
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996
bull ~ Fx 425-686-3096 GLPBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203232 Sequence 2C20001
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203232-BSBSD1
LCS Source mank Siiike
Spike LCS LCS Added Concentration Recovery
Analyte (microgL) (microgL) Recovery Limits Method Notes
Aluminwn 15000 1444 963 85-115 EPA2008Mod Chromium 70000 654 934 85 bull 115 EPA 2008 Mod Manganese 60000 580 967 85 - 115 EPA 2008 Mod Iron 50000 4610 922 85 - 115 EPA 2008 Mod Nickel 40000 394 985 85 ll5 EPA 2008 Mod Copper 40000 418 104 85 - 115 EPA 2008 Mod Zinc 10000 1017 102 85 bull 115 EPA 2008 Mod Arsenic 15000 1445 963 85 bull 115 EPA 2008 Mod Selenium 30000 2975 992 85-115 EPA2008Mod Molybdenum 20000 185 926 85 bull 115 EPA 2008 Mod Silver 15000 1555 104 85 - 115 EPA 2008 Mod
Cadmium 080000 0802 100 85 - 115 EPA 2008 Mod Lead 15000 1565 104 85 - 115 EPA 2008 Mod
shy
Spike LCSD LCSD Added Concentration Oo Recovery RPD
Analyte (microgL)
15000
(microgL)
1424
Recovery
949
RPD
140
Limits
85 bull 115
Limit
20
Method
EPA 2008 Mod
Notes
Aluminum
Chromium 70000 644 920 l58 85 bull 115 20 EPA 2008 Mod
Manganese 60000 575 958 0920 85 - ll5 20 EPA 2008 Mod
Iron 50000 4580 916 0660 85 - 115 20 EPA 2008 Mod
Nickel 40000 394 985 000457 85 bull 115 20 EPA 2008 Mod
Copper 40000 416 104 0367 85 - 115 20 EPA 2008 Mod
Zinc 10000 1032 103 147 85 - ll5 20 EPA 2008 Mod
Arsenic 15000 1440 960 0305 85 bull 115 20 EPA 2008 Mod
Selenium 30000 2867 956 369 85 -115 20 EPA 2008 Mod
Molybdenum 20000 l86 928 0196 85 -115 20 EPA2008 Mod
Silver l5000 1559 104 0233 85 bull 115 20 EPA 2008 Mod
Cadmium 080000 0809 101 0843 85 bull llS 20 EPA 2008 Mod
Lead 15000 l539 103 170 85 - 115 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed In accordance with the chain ofcustody document This analytical report must be reproduced in its enJirety
Page 14of20 1203203 Final Report- SWWTFREV2
04042012 ~~
Liz Siska Project Manager 18
11720 North Creek Parkway North Suite 400 Bothell WA 98011 Ph 425-686-1996
FRONTIER Fx 425-686-3096 GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203260 Sequence 2C22001
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203260-BSBSD1
LCS Source Blank Spike
Spike LCS LC$ Added Concentration Recovery
Analyte (ptgL) (JJgL) Recovery Limits Method Notes
Molybdenum 20000 182 910 85 - 115 EPA 2008 Mod
Spike LCSD LCSD Added Concentration Recovery RPD
Analyte (microgL) (microgL) Recovery RPD Limits Limit Method Notes
Molybdenum 20000 186 930 213 85 -115 20 EPA 2008 Mod
Frontier Global Sciences Inc The results In this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced In its entirety
Page 15 o20 I203203 Ftnal ampport- SWWTFREV2
04041202
Liz Siska Project Manager 19
middot
I
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SC IE NC ES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPO
Batch F203288 Sequence 2C22016
Preparation BrCI Oxidation Lab Number F203288-BSBSD I
LCS Source NIST 1641d
Spike LCS LCS Added Concentration Recovery
Analyte (ngL) (ngL) Recovery Limits Method Notes
Mercury 15679 1525 973 80 - 120 EPA l631E
Spike LCSD LCSD Added Concentration Oo Recovery RPD
Analyte (ngL) (ngL)
1516
Recovery
967
RPD
0622
Limits
80 - 120
Limit
24
Method
EPA 1631E
Notes
Mercury 15679
Frontier Global Sciences Inc The results in this report only apply lo the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 16 o20 1203203 Final Report- SWWIFREV2
041042012
20Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 middot Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096 ~ O GLO B AL SCI E NCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2C20001
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203232-BLK1 Aluminum 01 40 microgL F203232 PA2008 Molt u F203232-BLK1 Chromium -0007 0 10 microgL F203232 PA 2008 Molt u F203232-BLKI Manganese 0002 010 microgL F203232 PA 2008 Moc u F203232-BLK1 Iron -004 100 microgL F203232 PA 2008 Molt u F203232-BLKI Nickel 0005 010 microgL F203232 PA 2008 Moc u F203232-BLKI Copper 001 010 microgL F203232 PA 2008 Molt u F203232-BLK1 Zinc 011 020 microgL F203232 PA 2008 Moc u F203232-BLK I Arsenic -0009 015 microgL F203232 PA 2008 Moc u F203232-BLK1 Selenium 025 060 microgL F203232 PA 2008 Moc u F203232-BLK1 Molybdenum 001 006 microgL F203232 PA 2008 Moc u F203232-BLK1 Silver -00009 0020 microgL F203232 PA 2008 Moc u F203232-BLK1 Cadmium 0002 0020 microgL F203232 PA 2008 Molt u F203232-BLK1 Lead 0024 0040 microgL F203232 PA 2008 Molt u
middoti
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordonce with the chain ofcustody document Tnts analytical rtport must be reproduced In its enlfrtty
Page7of20 J203203 Final ampport-SWWTF REV2
04042012
Liz Siska Project Manager 21
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 FRONTIER~ Fx 425-686-3096 GLOBAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2C22001
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203260-BLK1 Molybdenum 001 006 microgL F203260 ~PA 2008 Moc u
Frontier Global Sciences Inc middot The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 18of20 1203203 Final Report- SWWTFREV2
04042012
Liz Siska Project Manager 22
~ CLOSAL SCIENCES
~
J1720 North Creek Parkway North Suite 400 Bothell WA 980 l l
Ph 425-686-1996 Fx 425-686-3096
PREPARATION BLANKS
Instrument Hg-17 Sequence 2C22016
Preparation BrCI Oxidation
The results in Ihis report only apply to the samples analyzed i12 accordance with the chain ofcustody dccumnt This analytical report must be reproductd in ils enJirety
Page I9oj20 1203203 Final Report- SWWTF REJ2
04042012
Frontier Global Sciences Inc
bull 23bull Liz Siska Project Manager
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203288-BLKl Mercury 007 050 ngL F203288 EPA 1631E u F203288-BLIlt2 Mercury 006 050 ngL F203288 EPA 163lE u F203288-BLK3 Mercury 006 050 ngL F203288 EPA I63lE u F203288-BLK4 Mercury 018 050 ngL F203288 EPA I63IE U QB-04
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
Notes and Definitions
U Analyte included in the analysis but not detected
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than I times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable ASASD
QB-04 The blank was preserved to 2 BrCl rather than I The control limit for blanks presetved to greater than 1 BrCl is the preservation percentage multiplied by the l1RL
FB-1631 Required equipmentfieldfilter blank not submitted by the client The sample has been analyzed according to 163 lE but does not meet 163 lE criteria
AS This MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
l1RL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to lhe samples analyzedin accordance wirh the chain ofcustody document This analytical report must be reproduced in its entirety
Page 20of20 1203203 Final Report- SWWTF REV2
04042012
24
bull bull
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GWP OIL FUND BROWNFJUD OR Orm--------shy RELINQUISHED BY DATE TIME RECEIVED Br Summo (ONTAHINATIOM_______
PO_______QUOTE===-~----shy I RELINQUISHED BY DATE TIME Rmmo BT I FIElllJUDINGStt HI l lS 2
eastern analytical inc 2s CHENELl DR1ve I CoNcoRo NH 03301 I TEL 60322sos2s I 1soo2s7os2s IFAXc 6032284591 I E-MA1l cusToMER_seRv1ceEA1LAascoHj wwweA1lAsscoM
prufmin111ll11bomtory1m1im (WHITE ORIGINAL GREEN PROJECT MANAGER)
shy
shy
11720 North Creek Parkway North Suite 40U Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
FRONTIER C L 0 B AL SC I~ NC ES
CHAlN OF CUSTODY FORMS
i---t--+-l-+-+-+--+--+--+--+_micro~[_amp~lslte---l t---t--+--11-(- -1--+-~-+--l---l---+----------f_ rmiddot 1---+--~--l--f-+---l--l--l-+--I--I---- _____--1 lt 1--1--1--+--l--------4-+-+--l--+-+--____f_ i--t--+--1r-+-+-+-t-+-++-4-________ _j bull-
CN _r(gt --shyshy~
_lj _D ~ -~ Irgt ~ -f
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The results In this report onlyapply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reprodu~din its entirety
Frontier Global Sciences Inc Page 5 o20 T203203 Final Report-SWWTFREV2
ommo12
Liz SiskaProject Manager
9
)--J middot ~~
)J fl~~J~c1N~r
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
Matrix Water Laboratory ID 1203203-01
ANALYTICAL RESULTS
SWWTF
Analyte Result lIDL MRL Units Dilution Batch Sequence Analyzed Method Notes
Aluminum 371 220 198 microgL 5 F203232 2C2000l 031912 EPA 2008 Mod
Arsenic 377 252 743 microgL 5 F203232 2C2000l 031912 EPA 2008 Mod
Cadmium 248 0205 0990 microgL 5 F203232 2C20001 031912 EPA2008 Mod
Chromium 532 045 495 microgL 5 F203232 2C20001 031912 EPA 2008 Mod
Copper 182 050 495 microgL 5 F203232 2C20001 031912 EPA 2008 Mod
Iron 1100 644 495 microgL 5 F203232 2C20001 031912 EPA 2008 Mod
Lead ND 0193 198 microgL 5 F203232 2C2000l 031912 EPA 2008 Mod u Manganese 7180 037 495 microgL 5 F203232 2C2000l 031912 EPA 2008 Mod
Mercury 612 842 505 ngL 100 F203288 2C22016 032212 EPA l631E FB-1631
Molybdenum 2000 297 297 microgL 50 F203260 2C22001 032112 EPA 2008 Mod
Nickel 303 040 495 microgL 5 F203232 2C20001 031912 EPA 2008 Mod
Selenium 587 959 297 microgL 5 F203232 2C20001 031912 EPA 2008 Mod
Silver ND 0297 0990 microgL 5 F203232 2C20001 031912 EPA 2008 Mod u Zinc 775 081 990 microgL 5 F203232 2C20001 031912 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report 011ly apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page6 o20 I203203 Final Report- SWWTF REV2
04042012
Liz Siska Project Manager 10
gt
C LO BA L S CI E N C ES
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
MATRIX DUPLICATESTRIPLICATES
SOURCE 1203203-01
Batch F203288
Preparation BrCl Oxidation
Sequence 2C22016
Lab Number F203288-DUPI
Sample Duplicate Concentration Concentration RPD
Analyte DgL ngL
5848
MRL 505
RPD 448
Limit
24
Method
EPA 163IE
Notes
Mercury 6116
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced In its entirety
Page 7of20 l 103203 Final Report- SWWTF REV2
04042012 bull 1 1 Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996
FROlJTIER Fx 425-686-3096 GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203203-01
Batch F203232 Sequence 2C20001
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203232-MSMSD 1
Sample Spike MS MS Concentration Added Concentration 0o Recovery
Analyte (microgL) (microgL) (microgL) Recovery Method NotesLimits
Alumimun 3707 15152 1853 978 70 - 130 EPA 2008 Mod
Chromium 5316 70707 1270 104 70- 130 EPA 2008 Mod
Manganese 7181 60606 7231 821 70 - 130 EPA 2008 Mod
Iron 1098 50505 6090 988 70- 130 EPA 2008 Mod
Nickel 3025 40404 3425 988 70 - 130 EPA 2008 Mod
Copper 1816 40404 5182 833 70 - 130 EPA2008 Mod
Arsenic 3770 15152 1904 101 70- 130 EPA 2008 Mod
Seleniwn 587l 30303 9297 113 70 - 130 EPA 2008 Mod
Silver ND 15152 1099 725 70 - 130 EPA 2008 Mod
Cadmillll) 2484 80808 9508 869 70 - 130 EPA 2008 Mod
Lead 0763 15152 1544 968 70-130 EPA2008Mod
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD
Recovery
Oo
RPD Recovery
Limits RPOLimit Method Notes
Aluminum 15152 1826 96l 145 70 shy 130 20 EPA 2008 Mod
Chromium 70707 1288 107 138 70-130 20 EPA 2008 Mod
Manganese 60606 7230 804 00140 70- 130 20 EPA 2008 Mod
Iron 50505 6065 983 0414 70- 130 20 EPA 2008 Mod
Nickel 40404 3378 872 138 70 - 130 20 EPA2008 Mod
Copper 40404 5140 823 0807 70 - 130 20 EPA 2008 Mod
Arsenic 15152 1928 102 123 70 - 130 20 EPA 2008 Mod
Selenium 30303 9063 105 255 70- 130 20 EPA 2008 Mod
Silver 15152 1075 709 219 70- 130 20 EPA 2008 Mod
Cadmium 80808 9347 849 170 70- 130 20 EPA 2008 Mod
Lead 15152 1531 960 0815 70- 130 20 EPA 2008 Mod
Frontier Global Sciences Inc The results In this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
PageBo20 1203203 FinalReport- SWWTFREV2
04042012
Liz Siska Project Manager 12
iii
11720 North Creek Parkway North Suite 400
Bothell WA 98011 Ph 425-686-1996 Fx 425-686-3096 GlOBAL SCIENCES
ij
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203203-01
Batch F203232 Sequence 2Q20001
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203232-MSMSD3
Analyte
Sample Concentration
(microgL)
Spike Added (pgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Limits Method Notes
Aluminum 3707 10000 10270 990 70 - 130 EPA 2008 Mod AS
Chromium 5316 10000 1137 108 70 - 130 EPA 2008 Mod AS Manganese 7181 10000 8207 103 70 - 130 EPA 2008 Mod AS
Iron 1098 50000 6185 102 70 - 130 EPA 2008 Mod AS Nickel 3025 12500 1433 905 70 - 130 EPA 2008 Mod AS Copper 1816 12500 1061 834 70 - 130 EPA 2008 Mod AS Zinc 7752 25000 1995 767 70 - 130 EPA 2008 Mod AS Arsenic 3770 10000 1073 104 70 - 130 EPA 2008 Mod AS Selenium 587l 10000 1530 943 70 - 130 EPA 2008 Mod AS Silver ND 50000 3690 738 70 - 130 EPA 2008 Mod AS Cadmium 2484 10000 8531 828 70 - 130 EPA 2008 Mod AS Lead 0763 25000 2505 999 70 - 130 EPA 2008 Mod AS
middoti
i
Aoalyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD o
Recovery
RPD Recovery
Limits RPDLimit Method Notes
Aluminum 10000 10150 978 121 70 - 130 20 EPA 2008 Mod AS Chromium 10000 1140 109 0293 70 - 130 20 EPA 2008 Mod AS Manganese 10000 8278 llO 0854 70 -130 20 EPA 2008 Mod AS Iron 50000 6243 103 0937 70-130 20 EPA 2008 Mod AS Nickel 12500 1441 91l middotos25 70 - 130 20 EPA 2008 Mod AS Copper 12500 1066 838 0496 70- 130 20 EPA 2008 Mod AS Zinc 25000 1990 765 0245 70- 130 20 EPA 2008 Mod AS Arsenic 10000 1094 106 193 70 - 130 20 EPA 2008 Mod AS Selenium 10000 1554 967 155 70 - 130 20 EPA 2008 Mod AS Silver 50000 3682 736 0222 70 - 130 20 EPA 2008 Mod AS Cadmium 10000 8394 815 l62 70 - 130 20 EPA 2008 Mod AS Lead 25000 250S 999 00263 70- 130 20 EPA 2008 Mod AS
~~ middotmiddot1 bull
bulli
bullmiddot
Frontier Global Sciences Inc The remits in this report only apply lo the samples analyzed in accordance with the chain ofcustody document This analytical report must bt reproductd In Its entirety
Page 9of20 1203203 Final Report-SWWTF REY2
04M2012
Liz Siska Project Manager 13
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 FRONTIER~ Fx 425-686-3096 GLOBAL SCIENCES
MATR1X SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203203-01RE3
Batch F203260 Sequence 2C22001
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203260-MSMSD3
Analyte
Sample Concentration
(microgL)
Spike Added (microgL)
MS Conctntration
(microgL)
MS
Recovery Recovery
Method Limits Notes
Molybdenum 1999 20200 middot 2041 206 70 - 130 EPA 2008 Mod QM-02
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD Oo
Recovery
RPD
Recovery Limits
RPO Limit Method Notes
Molybdenum 20200 2041 207 00141 70 - 130 20 EPA 2008 Mod QM-02
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed In accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page Oo20 1203203 Final Report- SWWTFREV2
04042012
Liz Siska Project Manager 14
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyzed in accordance with the chain ofcustody document This analytical report =tbe reproducedin Its entirety
Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
CLO~AL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1203203-0lREJ
Batch F203260
Preparation Closed Vessel Nitric Oven Digestion
Sequence 2C2200
Lab Number F203260-MSMSD6
Sample Spike MS MS
Analyte Concentration Added
(JtgL) (microgL) Concentration
(microgL)
Recovery Recovery
Method Limits Notes
Molybdenum 1999 50000 7034 101 70 - 130 EPA 2008 Mod AS
Spike MSD Added Concentration
MSD Recovery RPD
Analyte (microgL) (microgL) Recovery RPD Limits Limit Method Notes
Molybdenum 50000 7124 102 128 70 - 130 20 EPA 2008 Mod AS
Page 11 o20 1203203 Final Report- SWWTF REJ2
040412012
15
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 ~ Fx 425-686-3096 GLOBAL SCIENCES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203203-01
Batch F203288
Preparation BrCI Oxidation
Sequence 2C22016
Lab Number F203288-MSMSD 1
Sample Spike MS MS Concentration Added Concentration Recovery
Analyte (ngL) (ogL) (ogL) Recovery Method Notes Limits
Mercury 6116 25500 3096 974 71 - 125 EPA 1631E
Spike MSD MSD Oo Recovery RPD Added Concentration Oo
Limits Method Notes (ogL) (ogL) Recovery RPD Limit Analyte
Mercury 25500 2611 784 170 71 - 125 24 EPA 1631E
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed i11 accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 12of20 1203203 Final Report- SWWTF REV2
04042012
Liz Siska Project Manager 16
bull 11720 North Creek Parkway North Suite 400
Bothell WA 98011 Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1203194-17
Batch F203288 Sequence 2C22016
Preparation BrCI Oxidation Lab Number F203288-MSMSD2
Sample Spike MS MS
Analyte Concentration
(ngL) Added (ngL)
Concentration (ngL) Recovery
Recovery Limits Method Notes
Mercury 142800 505000 627200 959 71 - 125 EPA 1631E
Spike Added
MSD Concentration
MSD Recovery RPO
Analyte (ngL) (ngL) Recovery RPD Limits Limit Method Notes
Mercury 505000 632700 970 0879 71 - 125 24 EPA 1631E
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody docu~nt This analytical report must be reproduced In its entirety
Page 13of20 1203203 Final Report- SWWTFREV2
04042012
Liz Siska Project Manager 17
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996
bull ~ Fx 425-686-3096 GLPBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203232 Sequence 2C20001
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203232-BSBSD1
LCS Source mank Siiike
Spike LCS LCS Added Concentration Recovery
Analyte (microgL) (microgL) Recovery Limits Method Notes
Aluminwn 15000 1444 963 85-115 EPA2008Mod Chromium 70000 654 934 85 bull 115 EPA 2008 Mod Manganese 60000 580 967 85 - 115 EPA 2008 Mod Iron 50000 4610 922 85 - 115 EPA 2008 Mod Nickel 40000 394 985 85 ll5 EPA 2008 Mod Copper 40000 418 104 85 - 115 EPA 2008 Mod Zinc 10000 1017 102 85 bull 115 EPA 2008 Mod Arsenic 15000 1445 963 85 bull 115 EPA 2008 Mod Selenium 30000 2975 992 85-115 EPA2008Mod Molybdenum 20000 185 926 85 bull 115 EPA 2008 Mod Silver 15000 1555 104 85 - 115 EPA 2008 Mod
Cadmium 080000 0802 100 85 - 115 EPA 2008 Mod Lead 15000 1565 104 85 - 115 EPA 2008 Mod
shy
Spike LCSD LCSD Added Concentration Oo Recovery RPD
Analyte (microgL)
15000
(microgL)
1424
Recovery
949
RPD
140
Limits
85 bull 115
Limit
20
Method
EPA 2008 Mod
Notes
Aluminum
Chromium 70000 644 920 l58 85 bull 115 20 EPA 2008 Mod
Manganese 60000 575 958 0920 85 - ll5 20 EPA 2008 Mod
Iron 50000 4580 916 0660 85 - 115 20 EPA 2008 Mod
Nickel 40000 394 985 000457 85 bull 115 20 EPA 2008 Mod
Copper 40000 416 104 0367 85 - 115 20 EPA 2008 Mod
Zinc 10000 1032 103 147 85 - ll5 20 EPA 2008 Mod
Arsenic 15000 1440 960 0305 85 bull 115 20 EPA 2008 Mod
Selenium 30000 2867 956 369 85 -115 20 EPA 2008 Mod
Molybdenum 20000 l86 928 0196 85 -115 20 EPA2008 Mod
Silver l5000 1559 104 0233 85 bull 115 20 EPA 2008 Mod
Cadmium 080000 0809 101 0843 85 bull llS 20 EPA 2008 Mod
Lead 15000 l539 103 170 85 - 115 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed In accordance with the chain ofcustody document This analytical report must be reproduced in its enJirety
Page 14of20 1203203 Final Report- SWWTFREV2
04042012 ~~
Liz Siska Project Manager 18
11720 North Creek Parkway North Suite 400 Bothell WA 98011 Ph 425-686-1996
FRONTIER Fx 425-686-3096 GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203260 Sequence 2C22001
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203260-BSBSD1
LCS Source Blank Spike
Spike LCS LC$ Added Concentration Recovery
Analyte (ptgL) (JJgL) Recovery Limits Method Notes
Molybdenum 20000 182 910 85 - 115 EPA 2008 Mod
Spike LCSD LCSD Added Concentration Recovery RPD
Analyte (microgL) (microgL) Recovery RPD Limits Limit Method Notes
Molybdenum 20000 186 930 213 85 -115 20 EPA 2008 Mod
Frontier Global Sciences Inc The results In this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced In its entirety
Page 15 o20 I203203 Ftnal ampport- SWWTFREV2
04041202
Liz Siska Project Manager 19
middot
I
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SC IE NC ES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPO
Batch F203288 Sequence 2C22016
Preparation BrCI Oxidation Lab Number F203288-BSBSD I
LCS Source NIST 1641d
Spike LCS LCS Added Concentration Recovery
Analyte (ngL) (ngL) Recovery Limits Method Notes
Mercury 15679 1525 973 80 - 120 EPA l631E
Spike LCSD LCSD Added Concentration Oo Recovery RPD
Analyte (ngL) (ngL)
1516
Recovery
967
RPD
0622
Limits
80 - 120
Limit
24
Method
EPA 1631E
Notes
Mercury 15679
Frontier Global Sciences Inc The results in this report only apply lo the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 16 o20 1203203 Final Report- SWWIFREV2
041042012
20Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 middot Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096 ~ O GLO B AL SCI E NCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2C20001
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203232-BLK1 Aluminum 01 40 microgL F203232 PA2008 Molt u F203232-BLK1 Chromium -0007 0 10 microgL F203232 PA 2008 Molt u F203232-BLKI Manganese 0002 010 microgL F203232 PA 2008 Moc u F203232-BLK1 Iron -004 100 microgL F203232 PA 2008 Molt u F203232-BLKI Nickel 0005 010 microgL F203232 PA 2008 Moc u F203232-BLKI Copper 001 010 microgL F203232 PA 2008 Molt u F203232-BLK1 Zinc 011 020 microgL F203232 PA 2008 Moc u F203232-BLK I Arsenic -0009 015 microgL F203232 PA 2008 Moc u F203232-BLK1 Selenium 025 060 microgL F203232 PA 2008 Moc u F203232-BLK1 Molybdenum 001 006 microgL F203232 PA 2008 Moc u F203232-BLK1 Silver -00009 0020 microgL F203232 PA 2008 Moc u F203232-BLK1 Cadmium 0002 0020 microgL F203232 PA 2008 Molt u F203232-BLK1 Lead 0024 0040 microgL F203232 PA 2008 Molt u
middoti
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordonce with the chain ofcustody document Tnts analytical rtport must be reproduced In its enlfrtty
Page7of20 J203203 Final ampport-SWWTF REV2
04042012
Liz Siska Project Manager 21
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 FRONTIER~ Fx 425-686-3096 GLOBAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2C22001
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203260-BLK1 Molybdenum 001 006 microgL F203260 ~PA 2008 Moc u
Frontier Global Sciences Inc middot The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 18of20 1203203 Final Report- SWWTFREV2
04042012
Liz Siska Project Manager 22
~ CLOSAL SCIENCES
~
J1720 North Creek Parkway North Suite 400 Bothell WA 980 l l
Ph 425-686-1996 Fx 425-686-3096
PREPARATION BLANKS
Instrument Hg-17 Sequence 2C22016
Preparation BrCI Oxidation
The results in Ihis report only apply to the samples analyzed i12 accordance with the chain ofcustody dccumnt This analytical report must be reproductd in ils enJirety
Page I9oj20 1203203 Final Report- SWWTF REJ2
04042012
Frontier Global Sciences Inc
bull 23bull Liz Siska Project Manager
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203288-BLKl Mercury 007 050 ngL F203288 EPA 1631E u F203288-BLIlt2 Mercury 006 050 ngL F203288 EPA 163lE u F203288-BLK3 Mercury 006 050 ngL F203288 EPA I63lE u F203288-BLK4 Mercury 018 050 ngL F203288 EPA I63IE U QB-04
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
Notes and Definitions
U Analyte included in the analysis but not detected
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than I times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable ASASD
QB-04 The blank was preserved to 2 BrCl rather than I The control limit for blanks presetved to greater than 1 BrCl is the preservation percentage multiplied by the l1RL
FB-1631 Required equipmentfieldfilter blank not submitted by the client The sample has been analyzed according to 163 lE but does not meet 163 lE criteria
AS This MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
l1RL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to lhe samples analyzedin accordance wirh the chain ofcustody document This analytical report must be reproduced in its entirety
Page 20of20 1203203 Final Report- SWWTF REV2
04042012
24
bull bull
irGl Lu Ull 0111C H AIN-OF-CUSTODY RECORD Page of_~~
Bolo FIELDS REQUIRED P LEASE CIRCLE REQUESTED ANALYs1s Lt) CN voe I svoc TClPI M ETALS INORGANICS
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DATE NEEDED b171i1-1~ 1 f METALS 8 RCRA 13 PP FE MN Ps CUPROJECT MANAGER 0v f-e_~ Tmamp- middotc COMPANY pdegZ1)shy 0THE1 METALS __________REPORTING OPTIONSQAQC ICH) NoAonms Jfru lli V =1 Q ) REPORTING LEVEL PUUHS ~OR No
A B C 0lOLYpoundD METALS FIELD flLTtREDI YE NoIF YE F~ oa(ITT STAil~l4t(= ~ ZIP rriu1 NOTES (IE SPEOAl DETECTION LIHIIS BIWNG INFO IF D1mam)PHONE _r~ _z31_ - $ I3 Exr--- OR ELECTRONIC OPTIONSFAX _ __________________ AI l A C J C bull C1
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REGULATORY PROGRAM NPDES RGP POnY STOilKWATER Ol SITE HISTORY ~i tiT f=
GWP OIL FUND BROWNFJUD OR Orm--------shy RELINQUISHED BY DATE TIME RECEIVED Br Summo (ONTAHINATIOM_______
PO_______QUOTE===-~----shy I RELINQUISHED BY DATE TIME Rmmo BT I FIElllJUDINGStt HI l lS 2
eastern analytical inc 2s CHENELl DR1ve I CoNcoRo NH 03301 I TEL 60322sos2s I 1soo2s7os2s IFAXc 6032284591 I E-MA1l cusToMER_seRv1ceEA1LAascoHj wwweA1lAsscoM
prufmin111ll11bomtory1m1im (WHITE ORIGINAL GREEN PROJECT MANAGER)
shy
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)--J middot ~~
)J fl~~J~c1N~r
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
Matrix Water Laboratory ID 1203203-01
ANALYTICAL RESULTS
SWWTF
Analyte Result lIDL MRL Units Dilution Batch Sequence Analyzed Method Notes
Aluminum 371 220 198 microgL 5 F203232 2C2000l 031912 EPA 2008 Mod
Arsenic 377 252 743 microgL 5 F203232 2C2000l 031912 EPA 2008 Mod
Cadmium 248 0205 0990 microgL 5 F203232 2C20001 031912 EPA2008 Mod
Chromium 532 045 495 microgL 5 F203232 2C20001 031912 EPA 2008 Mod
Copper 182 050 495 microgL 5 F203232 2C20001 031912 EPA 2008 Mod
Iron 1100 644 495 microgL 5 F203232 2C20001 031912 EPA 2008 Mod
Lead ND 0193 198 microgL 5 F203232 2C2000l 031912 EPA 2008 Mod u Manganese 7180 037 495 microgL 5 F203232 2C2000l 031912 EPA 2008 Mod
Mercury 612 842 505 ngL 100 F203288 2C22016 032212 EPA l631E FB-1631
Molybdenum 2000 297 297 microgL 50 F203260 2C22001 032112 EPA 2008 Mod
Nickel 303 040 495 microgL 5 F203232 2C20001 031912 EPA 2008 Mod
Selenium 587 959 297 microgL 5 F203232 2C20001 031912 EPA 2008 Mod
Silver ND 0297 0990 microgL 5 F203232 2C20001 031912 EPA 2008 Mod u Zinc 775 081 990 microgL 5 F203232 2C20001 031912 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report 011ly apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page6 o20 I203203 Final Report- SWWTF REV2
04042012
Liz Siska Project Manager 10
gt
C LO BA L S CI E N C ES
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
MATRIX DUPLICATESTRIPLICATES
SOURCE 1203203-01
Batch F203288
Preparation BrCl Oxidation
Sequence 2C22016
Lab Number F203288-DUPI
Sample Duplicate Concentration Concentration RPD
Analyte DgL ngL
5848
MRL 505
RPD 448
Limit
24
Method
EPA 163IE
Notes
Mercury 6116
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced In its entirety
Page 7of20 l 103203 Final Report- SWWTF REV2
04042012 bull 1 1 Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996
FROlJTIER Fx 425-686-3096 GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203203-01
Batch F203232 Sequence 2C20001
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203232-MSMSD 1
Sample Spike MS MS Concentration Added Concentration 0o Recovery
Analyte (microgL) (microgL) (microgL) Recovery Method NotesLimits
Alumimun 3707 15152 1853 978 70 - 130 EPA 2008 Mod
Chromium 5316 70707 1270 104 70- 130 EPA 2008 Mod
Manganese 7181 60606 7231 821 70 - 130 EPA 2008 Mod
Iron 1098 50505 6090 988 70- 130 EPA 2008 Mod
Nickel 3025 40404 3425 988 70 - 130 EPA 2008 Mod
Copper 1816 40404 5182 833 70 - 130 EPA2008 Mod
Arsenic 3770 15152 1904 101 70- 130 EPA 2008 Mod
Seleniwn 587l 30303 9297 113 70 - 130 EPA 2008 Mod
Silver ND 15152 1099 725 70 - 130 EPA 2008 Mod
Cadmillll) 2484 80808 9508 869 70 - 130 EPA 2008 Mod
Lead 0763 15152 1544 968 70-130 EPA2008Mod
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD
Recovery
Oo
RPD Recovery
Limits RPOLimit Method Notes
Aluminum 15152 1826 96l 145 70 shy 130 20 EPA 2008 Mod
Chromium 70707 1288 107 138 70-130 20 EPA 2008 Mod
Manganese 60606 7230 804 00140 70- 130 20 EPA 2008 Mod
Iron 50505 6065 983 0414 70- 130 20 EPA 2008 Mod
Nickel 40404 3378 872 138 70 - 130 20 EPA2008 Mod
Copper 40404 5140 823 0807 70 - 130 20 EPA 2008 Mod
Arsenic 15152 1928 102 123 70 - 130 20 EPA 2008 Mod
Selenium 30303 9063 105 255 70- 130 20 EPA 2008 Mod
Silver 15152 1075 709 219 70- 130 20 EPA 2008 Mod
Cadmium 80808 9347 849 170 70- 130 20 EPA 2008 Mod
Lead 15152 1531 960 0815 70- 130 20 EPA 2008 Mod
Frontier Global Sciences Inc The results In this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
PageBo20 1203203 FinalReport- SWWTFREV2
04042012
Liz Siska Project Manager 12
iii
11720 North Creek Parkway North Suite 400
Bothell WA 98011 Ph 425-686-1996 Fx 425-686-3096 GlOBAL SCIENCES
ij
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203203-01
Batch F203232 Sequence 2Q20001
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203232-MSMSD3
Analyte
Sample Concentration
(microgL)
Spike Added (pgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Limits Method Notes
Aluminum 3707 10000 10270 990 70 - 130 EPA 2008 Mod AS
Chromium 5316 10000 1137 108 70 - 130 EPA 2008 Mod AS Manganese 7181 10000 8207 103 70 - 130 EPA 2008 Mod AS
Iron 1098 50000 6185 102 70 - 130 EPA 2008 Mod AS Nickel 3025 12500 1433 905 70 - 130 EPA 2008 Mod AS Copper 1816 12500 1061 834 70 - 130 EPA 2008 Mod AS Zinc 7752 25000 1995 767 70 - 130 EPA 2008 Mod AS Arsenic 3770 10000 1073 104 70 - 130 EPA 2008 Mod AS Selenium 587l 10000 1530 943 70 - 130 EPA 2008 Mod AS Silver ND 50000 3690 738 70 - 130 EPA 2008 Mod AS Cadmium 2484 10000 8531 828 70 - 130 EPA 2008 Mod AS Lead 0763 25000 2505 999 70 - 130 EPA 2008 Mod AS
middoti
i
Aoalyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD o
Recovery
RPD Recovery
Limits RPDLimit Method Notes
Aluminum 10000 10150 978 121 70 - 130 20 EPA 2008 Mod AS Chromium 10000 1140 109 0293 70 - 130 20 EPA 2008 Mod AS Manganese 10000 8278 llO 0854 70 -130 20 EPA 2008 Mod AS Iron 50000 6243 103 0937 70-130 20 EPA 2008 Mod AS Nickel 12500 1441 91l middotos25 70 - 130 20 EPA 2008 Mod AS Copper 12500 1066 838 0496 70- 130 20 EPA 2008 Mod AS Zinc 25000 1990 765 0245 70- 130 20 EPA 2008 Mod AS Arsenic 10000 1094 106 193 70 - 130 20 EPA 2008 Mod AS Selenium 10000 1554 967 155 70 - 130 20 EPA 2008 Mod AS Silver 50000 3682 736 0222 70 - 130 20 EPA 2008 Mod AS Cadmium 10000 8394 815 l62 70 - 130 20 EPA 2008 Mod AS Lead 25000 250S 999 00263 70- 130 20 EPA 2008 Mod AS
~~ middotmiddot1 bull
bulli
bullmiddot
Frontier Global Sciences Inc The remits in this report only apply lo the samples analyzed in accordance with the chain ofcustody document This analytical report must bt reproductd In Its entirety
Page 9of20 1203203 Final Report-SWWTF REY2
04M2012
Liz Siska Project Manager 13
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 FRONTIER~ Fx 425-686-3096 GLOBAL SCIENCES
MATR1X SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203203-01RE3
Batch F203260 Sequence 2C22001
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203260-MSMSD3
Analyte
Sample Concentration
(microgL)
Spike Added (microgL)
MS Conctntration
(microgL)
MS
Recovery Recovery
Method Limits Notes
Molybdenum 1999 20200 middot 2041 206 70 - 130 EPA 2008 Mod QM-02
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD Oo
Recovery
RPD
Recovery Limits
RPO Limit Method Notes
Molybdenum 20200 2041 207 00141 70 - 130 20 EPA 2008 Mod QM-02
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed In accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page Oo20 1203203 Final Report- SWWTFREV2
04042012
Liz Siska Project Manager 14
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyzed in accordance with the chain ofcustody document This analytical report =tbe reproducedin Its entirety
Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
CLO~AL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1203203-0lREJ
Batch F203260
Preparation Closed Vessel Nitric Oven Digestion
Sequence 2C2200
Lab Number F203260-MSMSD6
Sample Spike MS MS
Analyte Concentration Added
(JtgL) (microgL) Concentration
(microgL)
Recovery Recovery
Method Limits Notes
Molybdenum 1999 50000 7034 101 70 - 130 EPA 2008 Mod AS
Spike MSD Added Concentration
MSD Recovery RPD
Analyte (microgL) (microgL) Recovery RPD Limits Limit Method Notes
Molybdenum 50000 7124 102 128 70 - 130 20 EPA 2008 Mod AS
Page 11 o20 1203203 Final Report- SWWTF REJ2
040412012
15
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 ~ Fx 425-686-3096 GLOBAL SCIENCES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203203-01
Batch F203288
Preparation BrCI Oxidation
Sequence 2C22016
Lab Number F203288-MSMSD 1
Sample Spike MS MS Concentration Added Concentration Recovery
Analyte (ngL) (ogL) (ogL) Recovery Method Notes Limits
Mercury 6116 25500 3096 974 71 - 125 EPA 1631E
Spike MSD MSD Oo Recovery RPD Added Concentration Oo
Limits Method Notes (ogL) (ogL) Recovery RPD Limit Analyte
Mercury 25500 2611 784 170 71 - 125 24 EPA 1631E
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed i11 accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 12of20 1203203 Final Report- SWWTF REV2
04042012
Liz Siska Project Manager 16
bull 11720 North Creek Parkway North Suite 400
Bothell WA 98011 Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1203194-17
Batch F203288 Sequence 2C22016
Preparation BrCI Oxidation Lab Number F203288-MSMSD2
Sample Spike MS MS
Analyte Concentration
(ngL) Added (ngL)
Concentration (ngL) Recovery
Recovery Limits Method Notes
Mercury 142800 505000 627200 959 71 - 125 EPA 1631E
Spike Added
MSD Concentration
MSD Recovery RPO
Analyte (ngL) (ngL) Recovery RPD Limits Limit Method Notes
Mercury 505000 632700 970 0879 71 - 125 24 EPA 1631E
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody docu~nt This analytical report must be reproduced In its entirety
Page 13of20 1203203 Final Report- SWWTFREV2
04042012
Liz Siska Project Manager 17
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996
bull ~ Fx 425-686-3096 GLPBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203232 Sequence 2C20001
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203232-BSBSD1
LCS Source mank Siiike
Spike LCS LCS Added Concentration Recovery
Analyte (microgL) (microgL) Recovery Limits Method Notes
Aluminwn 15000 1444 963 85-115 EPA2008Mod Chromium 70000 654 934 85 bull 115 EPA 2008 Mod Manganese 60000 580 967 85 - 115 EPA 2008 Mod Iron 50000 4610 922 85 - 115 EPA 2008 Mod Nickel 40000 394 985 85 ll5 EPA 2008 Mod Copper 40000 418 104 85 - 115 EPA 2008 Mod Zinc 10000 1017 102 85 bull 115 EPA 2008 Mod Arsenic 15000 1445 963 85 bull 115 EPA 2008 Mod Selenium 30000 2975 992 85-115 EPA2008Mod Molybdenum 20000 185 926 85 bull 115 EPA 2008 Mod Silver 15000 1555 104 85 - 115 EPA 2008 Mod
Cadmium 080000 0802 100 85 - 115 EPA 2008 Mod Lead 15000 1565 104 85 - 115 EPA 2008 Mod
shy
Spike LCSD LCSD Added Concentration Oo Recovery RPD
Analyte (microgL)
15000
(microgL)
1424
Recovery
949
RPD
140
Limits
85 bull 115
Limit
20
Method
EPA 2008 Mod
Notes
Aluminum
Chromium 70000 644 920 l58 85 bull 115 20 EPA 2008 Mod
Manganese 60000 575 958 0920 85 - ll5 20 EPA 2008 Mod
Iron 50000 4580 916 0660 85 - 115 20 EPA 2008 Mod
Nickel 40000 394 985 000457 85 bull 115 20 EPA 2008 Mod
Copper 40000 416 104 0367 85 - 115 20 EPA 2008 Mod
Zinc 10000 1032 103 147 85 - ll5 20 EPA 2008 Mod
Arsenic 15000 1440 960 0305 85 bull 115 20 EPA 2008 Mod
Selenium 30000 2867 956 369 85 -115 20 EPA 2008 Mod
Molybdenum 20000 l86 928 0196 85 -115 20 EPA2008 Mod
Silver l5000 1559 104 0233 85 bull 115 20 EPA 2008 Mod
Cadmium 080000 0809 101 0843 85 bull llS 20 EPA 2008 Mod
Lead 15000 l539 103 170 85 - 115 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed In accordance with the chain ofcustody document This analytical report must be reproduced in its enJirety
Page 14of20 1203203 Final Report- SWWTFREV2
04042012 ~~
Liz Siska Project Manager 18
11720 North Creek Parkway North Suite 400 Bothell WA 98011 Ph 425-686-1996
FRONTIER Fx 425-686-3096 GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203260 Sequence 2C22001
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203260-BSBSD1
LCS Source Blank Spike
Spike LCS LC$ Added Concentration Recovery
Analyte (ptgL) (JJgL) Recovery Limits Method Notes
Molybdenum 20000 182 910 85 - 115 EPA 2008 Mod
Spike LCSD LCSD Added Concentration Recovery RPD
Analyte (microgL) (microgL) Recovery RPD Limits Limit Method Notes
Molybdenum 20000 186 930 213 85 -115 20 EPA 2008 Mod
Frontier Global Sciences Inc The results In this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced In its entirety
Page 15 o20 I203203 Ftnal ampport- SWWTFREV2
04041202
Liz Siska Project Manager 19
middot
I
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SC IE NC ES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPO
Batch F203288 Sequence 2C22016
Preparation BrCI Oxidation Lab Number F203288-BSBSD I
LCS Source NIST 1641d
Spike LCS LCS Added Concentration Recovery
Analyte (ngL) (ngL) Recovery Limits Method Notes
Mercury 15679 1525 973 80 - 120 EPA l631E
Spike LCSD LCSD Added Concentration Oo Recovery RPD
Analyte (ngL) (ngL)
1516
Recovery
967
RPD
0622
Limits
80 - 120
Limit
24
Method
EPA 1631E
Notes
Mercury 15679
Frontier Global Sciences Inc The results in this report only apply lo the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 16 o20 1203203 Final Report- SWWIFREV2
041042012
20Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 middot Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096 ~ O GLO B AL SCI E NCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2C20001
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203232-BLK1 Aluminum 01 40 microgL F203232 PA2008 Molt u F203232-BLK1 Chromium -0007 0 10 microgL F203232 PA 2008 Molt u F203232-BLKI Manganese 0002 010 microgL F203232 PA 2008 Moc u F203232-BLK1 Iron -004 100 microgL F203232 PA 2008 Molt u F203232-BLKI Nickel 0005 010 microgL F203232 PA 2008 Moc u F203232-BLKI Copper 001 010 microgL F203232 PA 2008 Molt u F203232-BLK1 Zinc 011 020 microgL F203232 PA 2008 Moc u F203232-BLK I Arsenic -0009 015 microgL F203232 PA 2008 Moc u F203232-BLK1 Selenium 025 060 microgL F203232 PA 2008 Moc u F203232-BLK1 Molybdenum 001 006 microgL F203232 PA 2008 Moc u F203232-BLK1 Silver -00009 0020 microgL F203232 PA 2008 Moc u F203232-BLK1 Cadmium 0002 0020 microgL F203232 PA 2008 Molt u F203232-BLK1 Lead 0024 0040 microgL F203232 PA 2008 Molt u
middoti
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordonce with the chain ofcustody document Tnts analytical rtport must be reproduced In its enlfrtty
Page7of20 J203203 Final ampport-SWWTF REV2
04042012
Liz Siska Project Manager 21
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 FRONTIER~ Fx 425-686-3096 GLOBAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2C22001
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203260-BLK1 Molybdenum 001 006 microgL F203260 ~PA 2008 Moc u
Frontier Global Sciences Inc middot The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 18of20 1203203 Final Report- SWWTFREV2
04042012
Liz Siska Project Manager 22
~ CLOSAL SCIENCES
~
J1720 North Creek Parkway North Suite 400 Bothell WA 980 l l
Ph 425-686-1996 Fx 425-686-3096
PREPARATION BLANKS
Instrument Hg-17 Sequence 2C22016
Preparation BrCI Oxidation
The results in Ihis report only apply to the samples analyzed i12 accordance with the chain ofcustody dccumnt This analytical report must be reproductd in ils enJirety
Page I9oj20 1203203 Final Report- SWWTF REJ2
04042012
Frontier Global Sciences Inc
bull 23bull Liz Siska Project Manager
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203288-BLKl Mercury 007 050 ngL F203288 EPA 1631E u F203288-BLIlt2 Mercury 006 050 ngL F203288 EPA 163lE u F203288-BLK3 Mercury 006 050 ngL F203288 EPA I63lE u F203288-BLK4 Mercury 018 050 ngL F203288 EPA I63IE U QB-04
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
Notes and Definitions
U Analyte included in the analysis but not detected
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than I times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable ASASD
QB-04 The blank was preserved to 2 BrCl rather than I The control limit for blanks presetved to greater than 1 BrCl is the preservation percentage multiplied by the l1RL
FB-1631 Required equipmentfieldfilter blank not submitted by the client The sample has been analyzed according to 163 lE but does not meet 163 lE criteria
AS This MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
l1RL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to lhe samples analyzedin accordance wirh the chain ofcustody document This analytical report must be reproduced in its entirety
Page 20of20 1203203 Final Report- SWWTF REV2
04042012
24
bull bull
irGl Lu Ull 0111C H AIN-OF-CUSTODY RECORD Page of_~~
Bolo FIELDS REQUIRED P LEASE CIRCLE REQUESTED ANALYs1s Lt) CN voe I svoc TClPI M ETALS INORGANICS
i w I shy i
SAMPLING 0 iii 0 ~
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w ~sacw 0IF COMPOSITE -gtc ~ u - ~
INDICATE 80TH ~ bulllo- t5a5 START amp FINISH
er Ill liSAMPLE 1 0 i ct -a ~shyDATEITIME l r ~~
bull 7gtItJJJI JWj T ~ tlt
IHAnlX A-Ala S-SOIL GW-GROUHD WATEl SW-SURfACE WATEA DW-DllNIING WAm WW-WAITE WATEl
PWETAJllt H-HCL N-HNO S-HJO Na-NaOHmiddot H-HEOH
i ~~ ~ I ~ X
j i I i= -shy 2 s~ ~ == a~ -shy I t
~~ =~ 2 ~~
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C 0 5~ s~ = IC 0
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0 ~= ~ _sC a ~ C) -shyt( I rt
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DATE NEEDED b171i1-1~ 1 f METALS 8 RCRA 13 PP FE MN Ps CUPROJECT MANAGER 0v f-e_~ Tmamp- middotc COMPANY pdegZ1)shy 0THE1 METALS __________REPORTING OPTIONSQAQC ICH) NoAonms Jfru lli V =1 Q ) REPORTING LEVEL PUUHS ~OR No
A B C 0lOLYpoundD METALS FIELD flLTtREDI YE NoIF YE F~ oa(ITT STAil~l4t(= ~ ZIP rriu1 NOTES (IE SPEOAl DETECTION LIHIIS BIWNG INFO IF D1mam)PHONE _r~ _z31_ - $ I3 Exr--- OR ELECTRONIC OPTIONSFAX _ __________________ AI l A C J C bull C1
J pbNo FAX E-MAIL PDF EQUIS
E-MAIL tivl el qu ~ pv CvVshyf J --~b Mo ~ tJ k ttJ -z~Sm NAHE W
PROJECT ____________ ___ ___ _ ~111216- aJd M fer P4 jgtZJ)shy
SUTt MA ME VT OTHER _____ ___ ~ 1)--U ( u-middotmiddottut-UJ f bull
REGULATORY PROGRAM NPDES RGP POnY STOilKWATER Ol SITE HISTORY ~i tiT f=
GWP OIL FUND BROWNFJUD OR Orm--------shy RELINQUISHED BY DATE TIME RECEIVED Br Summo (ONTAHINATIOM_______
PO_______QUOTE===-~----shy I RELINQUISHED BY DATE TIME Rmmo BT I FIElllJUDINGStt HI l lS 2
eastern analytical inc 2s CHENELl DR1ve I CoNcoRo NH 03301 I TEL 60322sos2s I 1soo2s7os2s IFAXc 6032284591 I E-MA1l cusToMER_seRv1ceEA1LAascoHj wwweA1lAsscoM
prufmin111ll11bomtory1m1im (WHITE ORIGINAL GREEN PROJECT MANAGER)
shy
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gt
C LO BA L S CI E N C ES
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
MATRIX DUPLICATESTRIPLICATES
SOURCE 1203203-01
Batch F203288
Preparation BrCl Oxidation
Sequence 2C22016
Lab Number F203288-DUPI
Sample Duplicate Concentration Concentration RPD
Analyte DgL ngL
5848
MRL 505
RPD 448
Limit
24
Method
EPA 163IE
Notes
Mercury 6116
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced In its entirety
Page 7of20 l 103203 Final Report- SWWTF REV2
04042012 bull 1 1 Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996
FROlJTIER Fx 425-686-3096 GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203203-01
Batch F203232 Sequence 2C20001
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203232-MSMSD 1
Sample Spike MS MS Concentration Added Concentration 0o Recovery
Analyte (microgL) (microgL) (microgL) Recovery Method NotesLimits
Alumimun 3707 15152 1853 978 70 - 130 EPA 2008 Mod
Chromium 5316 70707 1270 104 70- 130 EPA 2008 Mod
Manganese 7181 60606 7231 821 70 - 130 EPA 2008 Mod
Iron 1098 50505 6090 988 70- 130 EPA 2008 Mod
Nickel 3025 40404 3425 988 70 - 130 EPA 2008 Mod
Copper 1816 40404 5182 833 70 - 130 EPA2008 Mod
Arsenic 3770 15152 1904 101 70- 130 EPA 2008 Mod
Seleniwn 587l 30303 9297 113 70 - 130 EPA 2008 Mod
Silver ND 15152 1099 725 70 - 130 EPA 2008 Mod
Cadmillll) 2484 80808 9508 869 70 - 130 EPA 2008 Mod
Lead 0763 15152 1544 968 70-130 EPA2008Mod
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD
Recovery
Oo
RPD Recovery
Limits RPOLimit Method Notes
Aluminum 15152 1826 96l 145 70 shy 130 20 EPA 2008 Mod
Chromium 70707 1288 107 138 70-130 20 EPA 2008 Mod
Manganese 60606 7230 804 00140 70- 130 20 EPA 2008 Mod
Iron 50505 6065 983 0414 70- 130 20 EPA 2008 Mod
Nickel 40404 3378 872 138 70 - 130 20 EPA2008 Mod
Copper 40404 5140 823 0807 70 - 130 20 EPA 2008 Mod
Arsenic 15152 1928 102 123 70 - 130 20 EPA 2008 Mod
Selenium 30303 9063 105 255 70- 130 20 EPA 2008 Mod
Silver 15152 1075 709 219 70- 130 20 EPA 2008 Mod
Cadmium 80808 9347 849 170 70- 130 20 EPA 2008 Mod
Lead 15152 1531 960 0815 70- 130 20 EPA 2008 Mod
Frontier Global Sciences Inc The results In this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
PageBo20 1203203 FinalReport- SWWTFREV2
04042012
Liz Siska Project Manager 12
iii
11720 North Creek Parkway North Suite 400
Bothell WA 98011 Ph 425-686-1996 Fx 425-686-3096 GlOBAL SCIENCES
ij
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203203-01
Batch F203232 Sequence 2Q20001
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203232-MSMSD3
Analyte
Sample Concentration
(microgL)
Spike Added (pgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Limits Method Notes
Aluminum 3707 10000 10270 990 70 - 130 EPA 2008 Mod AS
Chromium 5316 10000 1137 108 70 - 130 EPA 2008 Mod AS Manganese 7181 10000 8207 103 70 - 130 EPA 2008 Mod AS
Iron 1098 50000 6185 102 70 - 130 EPA 2008 Mod AS Nickel 3025 12500 1433 905 70 - 130 EPA 2008 Mod AS Copper 1816 12500 1061 834 70 - 130 EPA 2008 Mod AS Zinc 7752 25000 1995 767 70 - 130 EPA 2008 Mod AS Arsenic 3770 10000 1073 104 70 - 130 EPA 2008 Mod AS Selenium 587l 10000 1530 943 70 - 130 EPA 2008 Mod AS Silver ND 50000 3690 738 70 - 130 EPA 2008 Mod AS Cadmium 2484 10000 8531 828 70 - 130 EPA 2008 Mod AS Lead 0763 25000 2505 999 70 - 130 EPA 2008 Mod AS
middoti
i
Aoalyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD o
Recovery
RPD Recovery
Limits RPDLimit Method Notes
Aluminum 10000 10150 978 121 70 - 130 20 EPA 2008 Mod AS Chromium 10000 1140 109 0293 70 - 130 20 EPA 2008 Mod AS Manganese 10000 8278 llO 0854 70 -130 20 EPA 2008 Mod AS Iron 50000 6243 103 0937 70-130 20 EPA 2008 Mod AS Nickel 12500 1441 91l middotos25 70 - 130 20 EPA 2008 Mod AS Copper 12500 1066 838 0496 70- 130 20 EPA 2008 Mod AS Zinc 25000 1990 765 0245 70- 130 20 EPA 2008 Mod AS Arsenic 10000 1094 106 193 70 - 130 20 EPA 2008 Mod AS Selenium 10000 1554 967 155 70 - 130 20 EPA 2008 Mod AS Silver 50000 3682 736 0222 70 - 130 20 EPA 2008 Mod AS Cadmium 10000 8394 815 l62 70 - 130 20 EPA 2008 Mod AS Lead 25000 250S 999 00263 70- 130 20 EPA 2008 Mod AS
~~ middotmiddot1 bull
bulli
bullmiddot
Frontier Global Sciences Inc The remits in this report only apply lo the samples analyzed in accordance with the chain ofcustody document This analytical report must bt reproductd In Its entirety
Page 9of20 1203203 Final Report-SWWTF REY2
04M2012
Liz Siska Project Manager 13
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 FRONTIER~ Fx 425-686-3096 GLOBAL SCIENCES
MATR1X SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203203-01RE3
Batch F203260 Sequence 2C22001
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203260-MSMSD3
Analyte
Sample Concentration
(microgL)
Spike Added (microgL)
MS Conctntration
(microgL)
MS
Recovery Recovery
Method Limits Notes
Molybdenum 1999 20200 middot 2041 206 70 - 130 EPA 2008 Mod QM-02
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD Oo
Recovery
RPD
Recovery Limits
RPO Limit Method Notes
Molybdenum 20200 2041 207 00141 70 - 130 20 EPA 2008 Mod QM-02
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed In accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page Oo20 1203203 Final Report- SWWTFREV2
04042012
Liz Siska Project Manager 14
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyzed in accordance with the chain ofcustody document This analytical report =tbe reproducedin Its entirety
Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
CLO~AL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1203203-0lREJ
Batch F203260
Preparation Closed Vessel Nitric Oven Digestion
Sequence 2C2200
Lab Number F203260-MSMSD6
Sample Spike MS MS
Analyte Concentration Added
(JtgL) (microgL) Concentration
(microgL)
Recovery Recovery
Method Limits Notes
Molybdenum 1999 50000 7034 101 70 - 130 EPA 2008 Mod AS
Spike MSD Added Concentration
MSD Recovery RPD
Analyte (microgL) (microgL) Recovery RPD Limits Limit Method Notes
Molybdenum 50000 7124 102 128 70 - 130 20 EPA 2008 Mod AS
Page 11 o20 1203203 Final Report- SWWTF REJ2
040412012
15
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 ~ Fx 425-686-3096 GLOBAL SCIENCES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203203-01
Batch F203288
Preparation BrCI Oxidation
Sequence 2C22016
Lab Number F203288-MSMSD 1
Sample Spike MS MS Concentration Added Concentration Recovery
Analyte (ngL) (ogL) (ogL) Recovery Method Notes Limits
Mercury 6116 25500 3096 974 71 - 125 EPA 1631E
Spike MSD MSD Oo Recovery RPD Added Concentration Oo
Limits Method Notes (ogL) (ogL) Recovery RPD Limit Analyte
Mercury 25500 2611 784 170 71 - 125 24 EPA 1631E
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed i11 accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 12of20 1203203 Final Report- SWWTF REV2
04042012
Liz Siska Project Manager 16
bull 11720 North Creek Parkway North Suite 400
Bothell WA 98011 Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1203194-17
Batch F203288 Sequence 2C22016
Preparation BrCI Oxidation Lab Number F203288-MSMSD2
Sample Spike MS MS
Analyte Concentration
(ngL) Added (ngL)
Concentration (ngL) Recovery
Recovery Limits Method Notes
Mercury 142800 505000 627200 959 71 - 125 EPA 1631E
Spike Added
MSD Concentration
MSD Recovery RPO
Analyte (ngL) (ngL) Recovery RPD Limits Limit Method Notes
Mercury 505000 632700 970 0879 71 - 125 24 EPA 1631E
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody docu~nt This analytical report must be reproduced In its entirety
Page 13of20 1203203 Final Report- SWWTFREV2
04042012
Liz Siska Project Manager 17
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996
bull ~ Fx 425-686-3096 GLPBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203232 Sequence 2C20001
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203232-BSBSD1
LCS Source mank Siiike
Spike LCS LCS Added Concentration Recovery
Analyte (microgL) (microgL) Recovery Limits Method Notes
Aluminwn 15000 1444 963 85-115 EPA2008Mod Chromium 70000 654 934 85 bull 115 EPA 2008 Mod Manganese 60000 580 967 85 - 115 EPA 2008 Mod Iron 50000 4610 922 85 - 115 EPA 2008 Mod Nickel 40000 394 985 85 ll5 EPA 2008 Mod Copper 40000 418 104 85 - 115 EPA 2008 Mod Zinc 10000 1017 102 85 bull 115 EPA 2008 Mod Arsenic 15000 1445 963 85 bull 115 EPA 2008 Mod Selenium 30000 2975 992 85-115 EPA2008Mod Molybdenum 20000 185 926 85 bull 115 EPA 2008 Mod Silver 15000 1555 104 85 - 115 EPA 2008 Mod
Cadmium 080000 0802 100 85 - 115 EPA 2008 Mod Lead 15000 1565 104 85 - 115 EPA 2008 Mod
shy
Spike LCSD LCSD Added Concentration Oo Recovery RPD
Analyte (microgL)
15000
(microgL)
1424
Recovery
949
RPD
140
Limits
85 bull 115
Limit
20
Method
EPA 2008 Mod
Notes
Aluminum
Chromium 70000 644 920 l58 85 bull 115 20 EPA 2008 Mod
Manganese 60000 575 958 0920 85 - ll5 20 EPA 2008 Mod
Iron 50000 4580 916 0660 85 - 115 20 EPA 2008 Mod
Nickel 40000 394 985 000457 85 bull 115 20 EPA 2008 Mod
Copper 40000 416 104 0367 85 - 115 20 EPA 2008 Mod
Zinc 10000 1032 103 147 85 - ll5 20 EPA 2008 Mod
Arsenic 15000 1440 960 0305 85 bull 115 20 EPA 2008 Mod
Selenium 30000 2867 956 369 85 -115 20 EPA 2008 Mod
Molybdenum 20000 l86 928 0196 85 -115 20 EPA2008 Mod
Silver l5000 1559 104 0233 85 bull 115 20 EPA 2008 Mod
Cadmium 080000 0809 101 0843 85 bull llS 20 EPA 2008 Mod
Lead 15000 l539 103 170 85 - 115 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed In accordance with the chain ofcustody document This analytical report must be reproduced in its enJirety
Page 14of20 1203203 Final Report- SWWTFREV2
04042012 ~~
Liz Siska Project Manager 18
11720 North Creek Parkway North Suite 400 Bothell WA 98011 Ph 425-686-1996
FRONTIER Fx 425-686-3096 GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203260 Sequence 2C22001
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203260-BSBSD1
LCS Source Blank Spike
Spike LCS LC$ Added Concentration Recovery
Analyte (ptgL) (JJgL) Recovery Limits Method Notes
Molybdenum 20000 182 910 85 - 115 EPA 2008 Mod
Spike LCSD LCSD Added Concentration Recovery RPD
Analyte (microgL) (microgL) Recovery RPD Limits Limit Method Notes
Molybdenum 20000 186 930 213 85 -115 20 EPA 2008 Mod
Frontier Global Sciences Inc The results In this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced In its entirety
Page 15 o20 I203203 Ftnal ampport- SWWTFREV2
04041202
Liz Siska Project Manager 19
middot
I
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SC IE NC ES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPO
Batch F203288 Sequence 2C22016
Preparation BrCI Oxidation Lab Number F203288-BSBSD I
LCS Source NIST 1641d
Spike LCS LCS Added Concentration Recovery
Analyte (ngL) (ngL) Recovery Limits Method Notes
Mercury 15679 1525 973 80 - 120 EPA l631E
Spike LCSD LCSD Added Concentration Oo Recovery RPD
Analyte (ngL) (ngL)
1516
Recovery
967
RPD
0622
Limits
80 - 120
Limit
24
Method
EPA 1631E
Notes
Mercury 15679
Frontier Global Sciences Inc The results in this report only apply lo the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 16 o20 1203203 Final Report- SWWIFREV2
041042012
20Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 middot Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096 ~ O GLO B AL SCI E NCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2C20001
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203232-BLK1 Aluminum 01 40 microgL F203232 PA2008 Molt u F203232-BLK1 Chromium -0007 0 10 microgL F203232 PA 2008 Molt u F203232-BLKI Manganese 0002 010 microgL F203232 PA 2008 Moc u F203232-BLK1 Iron -004 100 microgL F203232 PA 2008 Molt u F203232-BLKI Nickel 0005 010 microgL F203232 PA 2008 Moc u F203232-BLKI Copper 001 010 microgL F203232 PA 2008 Molt u F203232-BLK1 Zinc 011 020 microgL F203232 PA 2008 Moc u F203232-BLK I Arsenic -0009 015 microgL F203232 PA 2008 Moc u F203232-BLK1 Selenium 025 060 microgL F203232 PA 2008 Moc u F203232-BLK1 Molybdenum 001 006 microgL F203232 PA 2008 Moc u F203232-BLK1 Silver -00009 0020 microgL F203232 PA 2008 Moc u F203232-BLK1 Cadmium 0002 0020 microgL F203232 PA 2008 Molt u F203232-BLK1 Lead 0024 0040 microgL F203232 PA 2008 Molt u
middoti
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordonce with the chain ofcustody document Tnts analytical rtport must be reproduced In its enlfrtty
Page7of20 J203203 Final ampport-SWWTF REV2
04042012
Liz Siska Project Manager 21
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 FRONTIER~ Fx 425-686-3096 GLOBAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2C22001
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203260-BLK1 Molybdenum 001 006 microgL F203260 ~PA 2008 Moc u
Frontier Global Sciences Inc middot The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 18of20 1203203 Final Report- SWWTFREV2
04042012
Liz Siska Project Manager 22
~ CLOSAL SCIENCES
~
J1720 North Creek Parkway North Suite 400 Bothell WA 980 l l
Ph 425-686-1996 Fx 425-686-3096
PREPARATION BLANKS
Instrument Hg-17 Sequence 2C22016
Preparation BrCI Oxidation
The results in Ihis report only apply to the samples analyzed i12 accordance with the chain ofcustody dccumnt This analytical report must be reproductd in ils enJirety
Page I9oj20 1203203 Final Report- SWWTF REJ2
04042012
Frontier Global Sciences Inc
bull 23bull Liz Siska Project Manager
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203288-BLKl Mercury 007 050 ngL F203288 EPA 1631E u F203288-BLIlt2 Mercury 006 050 ngL F203288 EPA 163lE u F203288-BLK3 Mercury 006 050 ngL F203288 EPA I63lE u F203288-BLK4 Mercury 018 050 ngL F203288 EPA I63IE U QB-04
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
Notes and Definitions
U Analyte included in the analysis but not detected
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than I times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable ASASD
QB-04 The blank was preserved to 2 BrCl rather than I The control limit for blanks presetved to greater than 1 BrCl is the preservation percentage multiplied by the l1RL
FB-1631 Required equipmentfieldfilter blank not submitted by the client The sample has been analyzed according to 163 lE but does not meet 163 lE criteria
AS This MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
l1RL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to lhe samples analyzedin accordance wirh the chain ofcustody document This analytical report must be reproduced in its entirety
Page 20of20 1203203 Final Report- SWWTF REV2
04042012
24
bull bull
irGl Lu Ull 0111C H AIN-OF-CUSTODY RECORD Page of_~~
Bolo FIELDS REQUIRED P LEASE CIRCLE REQUESTED ANALYs1s Lt) CN voe I svoc TClPI M ETALS INORGANICS
i w I shy i
SAMPLING 0 iii 0 ~
w = ~ DATET1ME QIll c X
w ~sacw 0IF COMPOSITE -gtc ~ u - ~
INDICATE 80TH ~ bulllo- t5a5 START amp FINISH
er Ill liSAMPLE 1 0 i ct -a ~shyDATEITIME l r ~~
bull 7gtItJJJI JWj T ~ tlt
IHAnlX A-Ala S-SOIL GW-GROUHD WATEl SW-SURfACE WATEA DW-DllNIING WAm WW-WAITE WATEl
PWETAJllt H-HCL N-HNO S-HJO Na-NaOHmiddot H-HEOH
i ~~ ~ I ~ X
j i I i= -shy 2 s~ ~ == a~ -shy I t
~~ =~ 2 ~~
~ X a c 2 ~ ~ = -- 2 ~
l j t z i () ~
C 0 5~ s~ = IC 0
C -s ~ = ~ ~e f
0 ~= ~ _sC a ~ C) -shyt( I rt
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]-
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1
DATE NEEDED b171i1-1~ 1 f METALS 8 RCRA 13 PP FE MN Ps CUPROJECT MANAGER 0v f-e_~ Tmamp- middotc COMPANY pdegZ1)shy 0THE1 METALS __________REPORTING OPTIONSQAQC ICH) NoAonms Jfru lli V =1 Q ) REPORTING LEVEL PUUHS ~OR No
A B C 0lOLYpoundD METALS FIELD flLTtREDI YE NoIF YE F~ oa(ITT STAil~l4t(= ~ ZIP rriu1 NOTES (IE SPEOAl DETECTION LIHIIS BIWNG INFO IF D1mam)PHONE _r~ _z31_ - $ I3 Exr--- OR ELECTRONIC OPTIONSFAX _ __________________ AI l A C J C bull C1
J pbNo FAX E-MAIL PDF EQUIS
E-MAIL tivl el qu ~ pv CvVshyf J --~b Mo ~ tJ k ttJ -z~Sm NAHE W
PROJECT ____________ ___ ___ _ ~111216- aJd M fer P4 jgtZJ)shy
SUTt MA ME VT OTHER _____ ___ ~ 1)--U ( u-middotmiddottut-UJ f bull
REGULATORY PROGRAM NPDES RGP POnY STOilKWATER Ol SITE HISTORY ~i tiT f=
GWP OIL FUND BROWNFJUD OR Orm--------shy RELINQUISHED BY DATE TIME RECEIVED Br Summo (ONTAHINATIOM_______
PO_______QUOTE===-~----shy I RELINQUISHED BY DATE TIME Rmmo BT I FIElllJUDINGStt HI l lS 2
eastern analytical inc 2s CHENELl DR1ve I CoNcoRo NH 03301 I TEL 60322sos2s I 1soo2s7os2s IFAXc 6032284591 I E-MA1l cusToMER_seRv1ceEA1LAascoHj wwweA1lAsscoM
prufmin111ll11bomtory1m1im (WHITE ORIGINAL GREEN PROJECT MANAGER)
shy
shy
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996
FROlJTIER Fx 425-686-3096 GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203203-01
Batch F203232 Sequence 2C20001
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203232-MSMSD 1
Sample Spike MS MS Concentration Added Concentration 0o Recovery
Analyte (microgL) (microgL) (microgL) Recovery Method NotesLimits
Alumimun 3707 15152 1853 978 70 - 130 EPA 2008 Mod
Chromium 5316 70707 1270 104 70- 130 EPA 2008 Mod
Manganese 7181 60606 7231 821 70 - 130 EPA 2008 Mod
Iron 1098 50505 6090 988 70- 130 EPA 2008 Mod
Nickel 3025 40404 3425 988 70 - 130 EPA 2008 Mod
Copper 1816 40404 5182 833 70 - 130 EPA2008 Mod
Arsenic 3770 15152 1904 101 70- 130 EPA 2008 Mod
Seleniwn 587l 30303 9297 113 70 - 130 EPA 2008 Mod
Silver ND 15152 1099 725 70 - 130 EPA 2008 Mod
Cadmillll) 2484 80808 9508 869 70 - 130 EPA 2008 Mod
Lead 0763 15152 1544 968 70-130 EPA2008Mod
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD
Recovery
Oo
RPD Recovery
Limits RPOLimit Method Notes
Aluminum 15152 1826 96l 145 70 shy 130 20 EPA 2008 Mod
Chromium 70707 1288 107 138 70-130 20 EPA 2008 Mod
Manganese 60606 7230 804 00140 70- 130 20 EPA 2008 Mod
Iron 50505 6065 983 0414 70- 130 20 EPA 2008 Mod
Nickel 40404 3378 872 138 70 - 130 20 EPA2008 Mod
Copper 40404 5140 823 0807 70 - 130 20 EPA 2008 Mod
Arsenic 15152 1928 102 123 70 - 130 20 EPA 2008 Mod
Selenium 30303 9063 105 255 70- 130 20 EPA 2008 Mod
Silver 15152 1075 709 219 70- 130 20 EPA 2008 Mod
Cadmium 80808 9347 849 170 70- 130 20 EPA 2008 Mod
Lead 15152 1531 960 0815 70- 130 20 EPA 2008 Mod
Frontier Global Sciences Inc The results In this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
PageBo20 1203203 FinalReport- SWWTFREV2
04042012
Liz Siska Project Manager 12
iii
11720 North Creek Parkway North Suite 400
Bothell WA 98011 Ph 425-686-1996 Fx 425-686-3096 GlOBAL SCIENCES
ij
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203203-01
Batch F203232 Sequence 2Q20001
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203232-MSMSD3
Analyte
Sample Concentration
(microgL)
Spike Added (pgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Limits Method Notes
Aluminum 3707 10000 10270 990 70 - 130 EPA 2008 Mod AS
Chromium 5316 10000 1137 108 70 - 130 EPA 2008 Mod AS Manganese 7181 10000 8207 103 70 - 130 EPA 2008 Mod AS
Iron 1098 50000 6185 102 70 - 130 EPA 2008 Mod AS Nickel 3025 12500 1433 905 70 - 130 EPA 2008 Mod AS Copper 1816 12500 1061 834 70 - 130 EPA 2008 Mod AS Zinc 7752 25000 1995 767 70 - 130 EPA 2008 Mod AS Arsenic 3770 10000 1073 104 70 - 130 EPA 2008 Mod AS Selenium 587l 10000 1530 943 70 - 130 EPA 2008 Mod AS Silver ND 50000 3690 738 70 - 130 EPA 2008 Mod AS Cadmium 2484 10000 8531 828 70 - 130 EPA 2008 Mod AS Lead 0763 25000 2505 999 70 - 130 EPA 2008 Mod AS
middoti
i
Aoalyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD o
Recovery
RPD Recovery
Limits RPDLimit Method Notes
Aluminum 10000 10150 978 121 70 - 130 20 EPA 2008 Mod AS Chromium 10000 1140 109 0293 70 - 130 20 EPA 2008 Mod AS Manganese 10000 8278 llO 0854 70 -130 20 EPA 2008 Mod AS Iron 50000 6243 103 0937 70-130 20 EPA 2008 Mod AS Nickel 12500 1441 91l middotos25 70 - 130 20 EPA 2008 Mod AS Copper 12500 1066 838 0496 70- 130 20 EPA 2008 Mod AS Zinc 25000 1990 765 0245 70- 130 20 EPA 2008 Mod AS Arsenic 10000 1094 106 193 70 - 130 20 EPA 2008 Mod AS Selenium 10000 1554 967 155 70 - 130 20 EPA 2008 Mod AS Silver 50000 3682 736 0222 70 - 130 20 EPA 2008 Mod AS Cadmium 10000 8394 815 l62 70 - 130 20 EPA 2008 Mod AS Lead 25000 250S 999 00263 70- 130 20 EPA 2008 Mod AS
~~ middotmiddot1 bull
bulli
bullmiddot
Frontier Global Sciences Inc The remits in this report only apply lo the samples analyzed in accordance with the chain ofcustody document This analytical report must bt reproductd In Its entirety
Page 9of20 1203203 Final Report-SWWTF REY2
04M2012
Liz Siska Project Manager 13
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 FRONTIER~ Fx 425-686-3096 GLOBAL SCIENCES
MATR1X SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203203-01RE3
Batch F203260 Sequence 2C22001
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203260-MSMSD3
Analyte
Sample Concentration
(microgL)
Spike Added (microgL)
MS Conctntration
(microgL)
MS
Recovery Recovery
Method Limits Notes
Molybdenum 1999 20200 middot 2041 206 70 - 130 EPA 2008 Mod QM-02
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD Oo
Recovery
RPD
Recovery Limits
RPO Limit Method Notes
Molybdenum 20200 2041 207 00141 70 - 130 20 EPA 2008 Mod QM-02
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed In accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page Oo20 1203203 Final Report- SWWTFREV2
04042012
Liz Siska Project Manager 14
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyzed in accordance with the chain ofcustody document This analytical report =tbe reproducedin Its entirety
Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
CLO~AL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1203203-0lREJ
Batch F203260
Preparation Closed Vessel Nitric Oven Digestion
Sequence 2C2200
Lab Number F203260-MSMSD6
Sample Spike MS MS
Analyte Concentration Added
(JtgL) (microgL) Concentration
(microgL)
Recovery Recovery
Method Limits Notes
Molybdenum 1999 50000 7034 101 70 - 130 EPA 2008 Mod AS
Spike MSD Added Concentration
MSD Recovery RPD
Analyte (microgL) (microgL) Recovery RPD Limits Limit Method Notes
Molybdenum 50000 7124 102 128 70 - 130 20 EPA 2008 Mod AS
Page 11 o20 1203203 Final Report- SWWTF REJ2
040412012
15
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 ~ Fx 425-686-3096 GLOBAL SCIENCES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203203-01
Batch F203288
Preparation BrCI Oxidation
Sequence 2C22016
Lab Number F203288-MSMSD 1
Sample Spike MS MS Concentration Added Concentration Recovery
Analyte (ngL) (ogL) (ogL) Recovery Method Notes Limits
Mercury 6116 25500 3096 974 71 - 125 EPA 1631E
Spike MSD MSD Oo Recovery RPD Added Concentration Oo
Limits Method Notes (ogL) (ogL) Recovery RPD Limit Analyte
Mercury 25500 2611 784 170 71 - 125 24 EPA 1631E
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed i11 accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 12of20 1203203 Final Report- SWWTF REV2
04042012
Liz Siska Project Manager 16
bull 11720 North Creek Parkway North Suite 400
Bothell WA 98011 Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1203194-17
Batch F203288 Sequence 2C22016
Preparation BrCI Oxidation Lab Number F203288-MSMSD2
Sample Spike MS MS
Analyte Concentration
(ngL) Added (ngL)
Concentration (ngL) Recovery
Recovery Limits Method Notes
Mercury 142800 505000 627200 959 71 - 125 EPA 1631E
Spike Added
MSD Concentration
MSD Recovery RPO
Analyte (ngL) (ngL) Recovery RPD Limits Limit Method Notes
Mercury 505000 632700 970 0879 71 - 125 24 EPA 1631E
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody docu~nt This analytical report must be reproduced In its entirety
Page 13of20 1203203 Final Report- SWWTFREV2
04042012
Liz Siska Project Manager 17
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996
bull ~ Fx 425-686-3096 GLPBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203232 Sequence 2C20001
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203232-BSBSD1
LCS Source mank Siiike
Spike LCS LCS Added Concentration Recovery
Analyte (microgL) (microgL) Recovery Limits Method Notes
Aluminwn 15000 1444 963 85-115 EPA2008Mod Chromium 70000 654 934 85 bull 115 EPA 2008 Mod Manganese 60000 580 967 85 - 115 EPA 2008 Mod Iron 50000 4610 922 85 - 115 EPA 2008 Mod Nickel 40000 394 985 85 ll5 EPA 2008 Mod Copper 40000 418 104 85 - 115 EPA 2008 Mod Zinc 10000 1017 102 85 bull 115 EPA 2008 Mod Arsenic 15000 1445 963 85 bull 115 EPA 2008 Mod Selenium 30000 2975 992 85-115 EPA2008Mod Molybdenum 20000 185 926 85 bull 115 EPA 2008 Mod Silver 15000 1555 104 85 - 115 EPA 2008 Mod
Cadmium 080000 0802 100 85 - 115 EPA 2008 Mod Lead 15000 1565 104 85 - 115 EPA 2008 Mod
shy
Spike LCSD LCSD Added Concentration Oo Recovery RPD
Analyte (microgL)
15000
(microgL)
1424
Recovery
949
RPD
140
Limits
85 bull 115
Limit
20
Method
EPA 2008 Mod
Notes
Aluminum
Chromium 70000 644 920 l58 85 bull 115 20 EPA 2008 Mod
Manganese 60000 575 958 0920 85 - ll5 20 EPA 2008 Mod
Iron 50000 4580 916 0660 85 - 115 20 EPA 2008 Mod
Nickel 40000 394 985 000457 85 bull 115 20 EPA 2008 Mod
Copper 40000 416 104 0367 85 - 115 20 EPA 2008 Mod
Zinc 10000 1032 103 147 85 - ll5 20 EPA 2008 Mod
Arsenic 15000 1440 960 0305 85 bull 115 20 EPA 2008 Mod
Selenium 30000 2867 956 369 85 -115 20 EPA 2008 Mod
Molybdenum 20000 l86 928 0196 85 -115 20 EPA2008 Mod
Silver l5000 1559 104 0233 85 bull 115 20 EPA 2008 Mod
Cadmium 080000 0809 101 0843 85 bull llS 20 EPA 2008 Mod
Lead 15000 l539 103 170 85 - 115 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed In accordance with the chain ofcustody document This analytical report must be reproduced in its enJirety
Page 14of20 1203203 Final Report- SWWTFREV2
04042012 ~~
Liz Siska Project Manager 18
11720 North Creek Parkway North Suite 400 Bothell WA 98011 Ph 425-686-1996
FRONTIER Fx 425-686-3096 GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203260 Sequence 2C22001
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203260-BSBSD1
LCS Source Blank Spike
Spike LCS LC$ Added Concentration Recovery
Analyte (ptgL) (JJgL) Recovery Limits Method Notes
Molybdenum 20000 182 910 85 - 115 EPA 2008 Mod
Spike LCSD LCSD Added Concentration Recovery RPD
Analyte (microgL) (microgL) Recovery RPD Limits Limit Method Notes
Molybdenum 20000 186 930 213 85 -115 20 EPA 2008 Mod
Frontier Global Sciences Inc The results In this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced In its entirety
Page 15 o20 I203203 Ftnal ampport- SWWTFREV2
04041202
Liz Siska Project Manager 19
middot
I
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SC IE NC ES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPO
Batch F203288 Sequence 2C22016
Preparation BrCI Oxidation Lab Number F203288-BSBSD I
LCS Source NIST 1641d
Spike LCS LCS Added Concentration Recovery
Analyte (ngL) (ngL) Recovery Limits Method Notes
Mercury 15679 1525 973 80 - 120 EPA l631E
Spike LCSD LCSD Added Concentration Oo Recovery RPD
Analyte (ngL) (ngL)
1516
Recovery
967
RPD
0622
Limits
80 - 120
Limit
24
Method
EPA 1631E
Notes
Mercury 15679
Frontier Global Sciences Inc The results in this report only apply lo the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 16 o20 1203203 Final Report- SWWIFREV2
041042012
20Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 middot Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096 ~ O GLO B AL SCI E NCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2C20001
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203232-BLK1 Aluminum 01 40 microgL F203232 PA2008 Molt u F203232-BLK1 Chromium -0007 0 10 microgL F203232 PA 2008 Molt u F203232-BLKI Manganese 0002 010 microgL F203232 PA 2008 Moc u F203232-BLK1 Iron -004 100 microgL F203232 PA 2008 Molt u F203232-BLKI Nickel 0005 010 microgL F203232 PA 2008 Moc u F203232-BLKI Copper 001 010 microgL F203232 PA 2008 Molt u F203232-BLK1 Zinc 011 020 microgL F203232 PA 2008 Moc u F203232-BLK I Arsenic -0009 015 microgL F203232 PA 2008 Moc u F203232-BLK1 Selenium 025 060 microgL F203232 PA 2008 Moc u F203232-BLK1 Molybdenum 001 006 microgL F203232 PA 2008 Moc u F203232-BLK1 Silver -00009 0020 microgL F203232 PA 2008 Moc u F203232-BLK1 Cadmium 0002 0020 microgL F203232 PA 2008 Molt u F203232-BLK1 Lead 0024 0040 microgL F203232 PA 2008 Molt u
middoti
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordonce with the chain ofcustody document Tnts analytical rtport must be reproduced In its enlfrtty
Page7of20 J203203 Final ampport-SWWTF REV2
04042012
Liz Siska Project Manager 21
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 FRONTIER~ Fx 425-686-3096 GLOBAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2C22001
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203260-BLK1 Molybdenum 001 006 microgL F203260 ~PA 2008 Moc u
Frontier Global Sciences Inc middot The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 18of20 1203203 Final Report- SWWTFREV2
04042012
Liz Siska Project Manager 22
~ CLOSAL SCIENCES
~
J1720 North Creek Parkway North Suite 400 Bothell WA 980 l l
Ph 425-686-1996 Fx 425-686-3096
PREPARATION BLANKS
Instrument Hg-17 Sequence 2C22016
Preparation BrCI Oxidation
The results in Ihis report only apply to the samples analyzed i12 accordance with the chain ofcustody dccumnt This analytical report must be reproductd in ils enJirety
Page I9oj20 1203203 Final Report- SWWTF REJ2
04042012
Frontier Global Sciences Inc
bull 23bull Liz Siska Project Manager
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203288-BLKl Mercury 007 050 ngL F203288 EPA 1631E u F203288-BLIlt2 Mercury 006 050 ngL F203288 EPA 163lE u F203288-BLK3 Mercury 006 050 ngL F203288 EPA I63lE u F203288-BLK4 Mercury 018 050 ngL F203288 EPA I63IE U QB-04
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
Notes and Definitions
U Analyte included in the analysis but not detected
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than I times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable ASASD
QB-04 The blank was preserved to 2 BrCl rather than I The control limit for blanks presetved to greater than 1 BrCl is the preservation percentage multiplied by the l1RL
FB-1631 Required equipmentfieldfilter blank not submitted by the client The sample has been analyzed according to 163 lE but does not meet 163 lE criteria
AS This MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
l1RL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to lhe samples analyzedin accordance wirh the chain ofcustody document This analytical report must be reproduced in its entirety
Page 20of20 1203203 Final Report- SWWTF REV2
04042012
24
bull bull
irGl Lu Ull 0111C H AIN-OF-CUSTODY RECORD Page of_~~
Bolo FIELDS REQUIRED P LEASE CIRCLE REQUESTED ANALYs1s Lt) CN voe I svoc TClPI M ETALS INORGANICS
i w I shy i
SAMPLING 0 iii 0 ~
w = ~ DATET1ME QIll c X
w ~sacw 0IF COMPOSITE -gtc ~ u - ~
INDICATE 80TH ~ bulllo- t5a5 START amp FINISH
er Ill liSAMPLE 1 0 i ct -a ~shyDATEITIME l r ~~
bull 7gtItJJJI JWj T ~ tlt
IHAnlX A-Ala S-SOIL GW-GROUHD WATEl SW-SURfACE WATEA DW-DllNIING WAm WW-WAITE WATEl
PWETAJllt H-HCL N-HNO S-HJO Na-NaOHmiddot H-HEOH
i ~~ ~ I ~ X
j i I i= -shy 2 s~ ~ == a~ -shy I t
~~ =~ 2 ~~
~ X a c 2 ~ ~ = -- 2 ~
l j t z i () ~
C 0 5~ s~ = IC 0
C -s ~ = ~ ~e f
0 ~= ~ _sC a ~ C) -shyt( I rt
1 g0
3 i ~-
]-
f~ js~ i
~bull m = olt 1 o(
1 e
j
M ICRO middot-- -shy108420
sshyj
sect= s
~ - I 2lte E55 NOTESili I j HEOHVIAl 6shy ~a 3
I 3 ~ It _ c
1
DATE NEEDED b171i1-1~ 1 f METALS 8 RCRA 13 PP FE MN Ps CUPROJECT MANAGER 0v f-e_~ Tmamp- middotc COMPANY pdegZ1)shy 0THE1 METALS __________REPORTING OPTIONSQAQC ICH) NoAonms Jfru lli V =1 Q ) REPORTING LEVEL PUUHS ~OR No
A B C 0lOLYpoundD METALS FIELD flLTtREDI YE NoIF YE F~ oa(ITT STAil~l4t(= ~ ZIP rriu1 NOTES (IE SPEOAl DETECTION LIHIIS BIWNG INFO IF D1mam)PHONE _r~ _z31_ - $ I3 Exr--- OR ELECTRONIC OPTIONSFAX _ __________________ AI l A C J C bull C1
J pbNo FAX E-MAIL PDF EQUIS
E-MAIL tivl el qu ~ pv CvVshyf J --~b Mo ~ tJ k ttJ -z~Sm NAHE W
PROJECT ____________ ___ ___ _ ~111216- aJd M fer P4 jgtZJ)shy
SUTt MA ME VT OTHER _____ ___ ~ 1)--U ( u-middotmiddottut-UJ f bull
REGULATORY PROGRAM NPDES RGP POnY STOilKWATER Ol SITE HISTORY ~i tiT f=
GWP OIL FUND BROWNFJUD OR Orm--------shy RELINQUISHED BY DATE TIME RECEIVED Br Summo (ONTAHINATIOM_______
PO_______QUOTE===-~----shy I RELINQUISHED BY DATE TIME Rmmo BT I FIElllJUDINGStt HI l lS 2
eastern analytical inc 2s CHENELl DR1ve I CoNcoRo NH 03301 I TEL 60322sos2s I 1soo2s7os2s IFAXc 6032284591 I E-MA1l cusToMER_seRv1ceEA1LAascoHj wwweA1lAsscoM
prufmin111ll11bomtory1m1im (WHITE ORIGINAL GREEN PROJECT MANAGER)
shy
shy
iii
11720 North Creek Parkway North Suite 400
Bothell WA 98011 Ph 425-686-1996 Fx 425-686-3096 GlOBAL SCIENCES
ij
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203203-01
Batch F203232 Sequence 2Q20001
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203232-MSMSD3
Analyte
Sample Concentration
(microgL)
Spike Added (pgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Limits Method Notes
Aluminum 3707 10000 10270 990 70 - 130 EPA 2008 Mod AS
Chromium 5316 10000 1137 108 70 - 130 EPA 2008 Mod AS Manganese 7181 10000 8207 103 70 - 130 EPA 2008 Mod AS
Iron 1098 50000 6185 102 70 - 130 EPA 2008 Mod AS Nickel 3025 12500 1433 905 70 - 130 EPA 2008 Mod AS Copper 1816 12500 1061 834 70 - 130 EPA 2008 Mod AS Zinc 7752 25000 1995 767 70 - 130 EPA 2008 Mod AS Arsenic 3770 10000 1073 104 70 - 130 EPA 2008 Mod AS Selenium 587l 10000 1530 943 70 - 130 EPA 2008 Mod AS Silver ND 50000 3690 738 70 - 130 EPA 2008 Mod AS Cadmium 2484 10000 8531 828 70 - 130 EPA 2008 Mod AS Lead 0763 25000 2505 999 70 - 130 EPA 2008 Mod AS
middoti
i
Aoalyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD o
Recovery
RPD Recovery
Limits RPDLimit Method Notes
Aluminum 10000 10150 978 121 70 - 130 20 EPA 2008 Mod AS Chromium 10000 1140 109 0293 70 - 130 20 EPA 2008 Mod AS Manganese 10000 8278 llO 0854 70 -130 20 EPA 2008 Mod AS Iron 50000 6243 103 0937 70-130 20 EPA 2008 Mod AS Nickel 12500 1441 91l middotos25 70 - 130 20 EPA 2008 Mod AS Copper 12500 1066 838 0496 70- 130 20 EPA 2008 Mod AS Zinc 25000 1990 765 0245 70- 130 20 EPA 2008 Mod AS Arsenic 10000 1094 106 193 70 - 130 20 EPA 2008 Mod AS Selenium 10000 1554 967 155 70 - 130 20 EPA 2008 Mod AS Silver 50000 3682 736 0222 70 - 130 20 EPA 2008 Mod AS Cadmium 10000 8394 815 l62 70 - 130 20 EPA 2008 Mod AS Lead 25000 250S 999 00263 70- 130 20 EPA 2008 Mod AS
~~ middotmiddot1 bull
bulli
bullmiddot
Frontier Global Sciences Inc The remits in this report only apply lo the samples analyzed in accordance with the chain ofcustody document This analytical report must bt reproductd In Its entirety
Page 9of20 1203203 Final Report-SWWTF REY2
04M2012
Liz Siska Project Manager 13
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 FRONTIER~ Fx 425-686-3096 GLOBAL SCIENCES
MATR1X SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203203-01RE3
Batch F203260 Sequence 2C22001
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203260-MSMSD3
Analyte
Sample Concentration
(microgL)
Spike Added (microgL)
MS Conctntration
(microgL)
MS
Recovery Recovery
Method Limits Notes
Molybdenum 1999 20200 middot 2041 206 70 - 130 EPA 2008 Mod QM-02
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD Oo
Recovery
RPD
Recovery Limits
RPO Limit Method Notes
Molybdenum 20200 2041 207 00141 70 - 130 20 EPA 2008 Mod QM-02
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed In accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page Oo20 1203203 Final Report- SWWTFREV2
04042012
Liz Siska Project Manager 14
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyzed in accordance with the chain ofcustody document This analytical report =tbe reproducedin Its entirety
Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
CLO~AL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1203203-0lREJ
Batch F203260
Preparation Closed Vessel Nitric Oven Digestion
Sequence 2C2200
Lab Number F203260-MSMSD6
Sample Spike MS MS
Analyte Concentration Added
(JtgL) (microgL) Concentration
(microgL)
Recovery Recovery
Method Limits Notes
Molybdenum 1999 50000 7034 101 70 - 130 EPA 2008 Mod AS
Spike MSD Added Concentration
MSD Recovery RPD
Analyte (microgL) (microgL) Recovery RPD Limits Limit Method Notes
Molybdenum 50000 7124 102 128 70 - 130 20 EPA 2008 Mod AS
Page 11 o20 1203203 Final Report- SWWTF REJ2
040412012
15
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 ~ Fx 425-686-3096 GLOBAL SCIENCES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203203-01
Batch F203288
Preparation BrCI Oxidation
Sequence 2C22016
Lab Number F203288-MSMSD 1
Sample Spike MS MS Concentration Added Concentration Recovery
Analyte (ngL) (ogL) (ogL) Recovery Method Notes Limits
Mercury 6116 25500 3096 974 71 - 125 EPA 1631E
Spike MSD MSD Oo Recovery RPD Added Concentration Oo
Limits Method Notes (ogL) (ogL) Recovery RPD Limit Analyte
Mercury 25500 2611 784 170 71 - 125 24 EPA 1631E
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed i11 accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 12of20 1203203 Final Report- SWWTF REV2
04042012
Liz Siska Project Manager 16
bull 11720 North Creek Parkway North Suite 400
Bothell WA 98011 Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1203194-17
Batch F203288 Sequence 2C22016
Preparation BrCI Oxidation Lab Number F203288-MSMSD2
Sample Spike MS MS
Analyte Concentration
(ngL) Added (ngL)
Concentration (ngL) Recovery
Recovery Limits Method Notes
Mercury 142800 505000 627200 959 71 - 125 EPA 1631E
Spike Added
MSD Concentration
MSD Recovery RPO
Analyte (ngL) (ngL) Recovery RPD Limits Limit Method Notes
Mercury 505000 632700 970 0879 71 - 125 24 EPA 1631E
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody docu~nt This analytical report must be reproduced In its entirety
Page 13of20 1203203 Final Report- SWWTFREV2
04042012
Liz Siska Project Manager 17
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996
bull ~ Fx 425-686-3096 GLPBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203232 Sequence 2C20001
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203232-BSBSD1
LCS Source mank Siiike
Spike LCS LCS Added Concentration Recovery
Analyte (microgL) (microgL) Recovery Limits Method Notes
Aluminwn 15000 1444 963 85-115 EPA2008Mod Chromium 70000 654 934 85 bull 115 EPA 2008 Mod Manganese 60000 580 967 85 - 115 EPA 2008 Mod Iron 50000 4610 922 85 - 115 EPA 2008 Mod Nickel 40000 394 985 85 ll5 EPA 2008 Mod Copper 40000 418 104 85 - 115 EPA 2008 Mod Zinc 10000 1017 102 85 bull 115 EPA 2008 Mod Arsenic 15000 1445 963 85 bull 115 EPA 2008 Mod Selenium 30000 2975 992 85-115 EPA2008Mod Molybdenum 20000 185 926 85 bull 115 EPA 2008 Mod Silver 15000 1555 104 85 - 115 EPA 2008 Mod
Cadmium 080000 0802 100 85 - 115 EPA 2008 Mod Lead 15000 1565 104 85 - 115 EPA 2008 Mod
shy
Spike LCSD LCSD Added Concentration Oo Recovery RPD
Analyte (microgL)
15000
(microgL)
1424
Recovery
949
RPD
140
Limits
85 bull 115
Limit
20
Method
EPA 2008 Mod
Notes
Aluminum
Chromium 70000 644 920 l58 85 bull 115 20 EPA 2008 Mod
Manganese 60000 575 958 0920 85 - ll5 20 EPA 2008 Mod
Iron 50000 4580 916 0660 85 - 115 20 EPA 2008 Mod
Nickel 40000 394 985 000457 85 bull 115 20 EPA 2008 Mod
Copper 40000 416 104 0367 85 - 115 20 EPA 2008 Mod
Zinc 10000 1032 103 147 85 - ll5 20 EPA 2008 Mod
Arsenic 15000 1440 960 0305 85 bull 115 20 EPA 2008 Mod
Selenium 30000 2867 956 369 85 -115 20 EPA 2008 Mod
Molybdenum 20000 l86 928 0196 85 -115 20 EPA2008 Mod
Silver l5000 1559 104 0233 85 bull 115 20 EPA 2008 Mod
Cadmium 080000 0809 101 0843 85 bull llS 20 EPA 2008 Mod
Lead 15000 l539 103 170 85 - 115 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed In accordance with the chain ofcustody document This analytical report must be reproduced in its enJirety
Page 14of20 1203203 Final Report- SWWTFREV2
04042012 ~~
Liz Siska Project Manager 18
11720 North Creek Parkway North Suite 400 Bothell WA 98011 Ph 425-686-1996
FRONTIER Fx 425-686-3096 GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203260 Sequence 2C22001
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203260-BSBSD1
LCS Source Blank Spike
Spike LCS LC$ Added Concentration Recovery
Analyte (ptgL) (JJgL) Recovery Limits Method Notes
Molybdenum 20000 182 910 85 - 115 EPA 2008 Mod
Spike LCSD LCSD Added Concentration Recovery RPD
Analyte (microgL) (microgL) Recovery RPD Limits Limit Method Notes
Molybdenum 20000 186 930 213 85 -115 20 EPA 2008 Mod
Frontier Global Sciences Inc The results In this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced In its entirety
Page 15 o20 I203203 Ftnal ampport- SWWTFREV2
04041202
Liz Siska Project Manager 19
middot
I
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SC IE NC ES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPO
Batch F203288 Sequence 2C22016
Preparation BrCI Oxidation Lab Number F203288-BSBSD I
LCS Source NIST 1641d
Spike LCS LCS Added Concentration Recovery
Analyte (ngL) (ngL) Recovery Limits Method Notes
Mercury 15679 1525 973 80 - 120 EPA l631E
Spike LCSD LCSD Added Concentration Oo Recovery RPD
Analyte (ngL) (ngL)
1516
Recovery
967
RPD
0622
Limits
80 - 120
Limit
24
Method
EPA 1631E
Notes
Mercury 15679
Frontier Global Sciences Inc The results in this report only apply lo the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 16 o20 1203203 Final Report- SWWIFREV2
041042012
20Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 middot Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096 ~ O GLO B AL SCI E NCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2C20001
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203232-BLK1 Aluminum 01 40 microgL F203232 PA2008 Molt u F203232-BLK1 Chromium -0007 0 10 microgL F203232 PA 2008 Molt u F203232-BLKI Manganese 0002 010 microgL F203232 PA 2008 Moc u F203232-BLK1 Iron -004 100 microgL F203232 PA 2008 Molt u F203232-BLKI Nickel 0005 010 microgL F203232 PA 2008 Moc u F203232-BLKI Copper 001 010 microgL F203232 PA 2008 Molt u F203232-BLK1 Zinc 011 020 microgL F203232 PA 2008 Moc u F203232-BLK I Arsenic -0009 015 microgL F203232 PA 2008 Moc u F203232-BLK1 Selenium 025 060 microgL F203232 PA 2008 Moc u F203232-BLK1 Molybdenum 001 006 microgL F203232 PA 2008 Moc u F203232-BLK1 Silver -00009 0020 microgL F203232 PA 2008 Moc u F203232-BLK1 Cadmium 0002 0020 microgL F203232 PA 2008 Molt u F203232-BLK1 Lead 0024 0040 microgL F203232 PA 2008 Molt u
middoti
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordonce with the chain ofcustody document Tnts analytical rtport must be reproduced In its enlfrtty
Page7of20 J203203 Final ampport-SWWTF REV2
04042012
Liz Siska Project Manager 21
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 FRONTIER~ Fx 425-686-3096 GLOBAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2C22001
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203260-BLK1 Molybdenum 001 006 microgL F203260 ~PA 2008 Moc u
Frontier Global Sciences Inc middot The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 18of20 1203203 Final Report- SWWTFREV2
04042012
Liz Siska Project Manager 22
~ CLOSAL SCIENCES
~
J1720 North Creek Parkway North Suite 400 Bothell WA 980 l l
Ph 425-686-1996 Fx 425-686-3096
PREPARATION BLANKS
Instrument Hg-17 Sequence 2C22016
Preparation BrCI Oxidation
The results in Ihis report only apply to the samples analyzed i12 accordance with the chain ofcustody dccumnt This analytical report must be reproductd in ils enJirety
Page I9oj20 1203203 Final Report- SWWTF REJ2
04042012
Frontier Global Sciences Inc
bull 23bull Liz Siska Project Manager
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203288-BLKl Mercury 007 050 ngL F203288 EPA 1631E u F203288-BLIlt2 Mercury 006 050 ngL F203288 EPA 163lE u F203288-BLK3 Mercury 006 050 ngL F203288 EPA I63lE u F203288-BLK4 Mercury 018 050 ngL F203288 EPA I63IE U QB-04
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
Notes and Definitions
U Analyte included in the analysis but not detected
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than I times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable ASASD
QB-04 The blank was preserved to 2 BrCl rather than I The control limit for blanks presetved to greater than 1 BrCl is the preservation percentage multiplied by the l1RL
FB-1631 Required equipmentfieldfilter blank not submitted by the client The sample has been analyzed according to 163 lE but does not meet 163 lE criteria
AS This MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
l1RL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to lhe samples analyzedin accordance wirh the chain ofcustody document This analytical report must be reproduced in its entirety
Page 20of20 1203203 Final Report- SWWTF REV2
04042012
24
bull bull
irGl Lu Ull 0111C H AIN-OF-CUSTODY RECORD Page of_~~
Bolo FIELDS REQUIRED P LEASE CIRCLE REQUESTED ANALYs1s Lt) CN voe I svoc TClPI M ETALS INORGANICS
i w I shy i
SAMPLING 0 iii 0 ~
w = ~ DATET1ME QIll c X
w ~sacw 0IF COMPOSITE -gtc ~ u - ~
INDICATE 80TH ~ bulllo- t5a5 START amp FINISH
er Ill liSAMPLE 1 0 i ct -a ~shyDATEITIME l r ~~
bull 7gtItJJJI JWj T ~ tlt
IHAnlX A-Ala S-SOIL GW-GROUHD WATEl SW-SURfACE WATEA DW-DllNIING WAm WW-WAITE WATEl
PWETAJllt H-HCL N-HNO S-HJO Na-NaOHmiddot H-HEOH
i ~~ ~ I ~ X
j i I i= -shy 2 s~ ~ == a~ -shy I t
~~ =~ 2 ~~
~ X a c 2 ~ ~ = -- 2 ~
l j t z i () ~
C 0 5~ s~ = IC 0
C -s ~ = ~ ~e f
0 ~= ~ _sC a ~ C) -shyt( I rt
1 g0
3 i ~-
]-
f~ js~ i
~bull m = olt 1 o(
1 e
j
M ICRO middot-- -shy108420
sshyj
sect= s
~ - I 2lte E55 NOTESili I j HEOHVIAl 6shy ~a 3
I 3 ~ It _ c
1
DATE NEEDED b171i1-1~ 1 f METALS 8 RCRA 13 PP FE MN Ps CUPROJECT MANAGER 0v f-e_~ Tmamp- middotc COMPANY pdegZ1)shy 0THE1 METALS __________REPORTING OPTIONSQAQC ICH) NoAonms Jfru lli V =1 Q ) REPORTING LEVEL PUUHS ~OR No
A B C 0lOLYpoundD METALS FIELD flLTtREDI YE NoIF YE F~ oa(ITT STAil~l4t(= ~ ZIP rriu1 NOTES (IE SPEOAl DETECTION LIHIIS BIWNG INFO IF D1mam)PHONE _r~ _z31_ - $ I3 Exr--- OR ELECTRONIC OPTIONSFAX _ __________________ AI l A C J C bull C1
J pbNo FAX E-MAIL PDF EQUIS
E-MAIL tivl el qu ~ pv CvVshyf J --~b Mo ~ tJ k ttJ -z~Sm NAHE W
PROJECT ____________ ___ ___ _ ~111216- aJd M fer P4 jgtZJ)shy
SUTt MA ME VT OTHER _____ ___ ~ 1)--U ( u-middotmiddottut-UJ f bull
REGULATORY PROGRAM NPDES RGP POnY STOilKWATER Ol SITE HISTORY ~i tiT f=
GWP OIL FUND BROWNFJUD OR Orm--------shy RELINQUISHED BY DATE TIME RECEIVED Br Summo (ONTAHINATIOM_______
PO_______QUOTE===-~----shy I RELINQUISHED BY DATE TIME Rmmo BT I FIElllJUDINGStt HI l lS 2
eastern analytical inc 2s CHENELl DR1ve I CoNcoRo NH 03301 I TEL 60322sos2s I 1soo2s7os2s IFAXc 6032284591 I E-MA1l cusToMER_seRv1ceEA1LAascoHj wwweA1lAsscoM
prufmin111ll11bomtory1m1im (WHITE ORIGINAL GREEN PROJECT MANAGER)
shy
shy
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 FRONTIER~ Fx 425-686-3096 GLOBAL SCIENCES
MATR1X SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203203-01RE3
Batch F203260 Sequence 2C22001
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203260-MSMSD3
Analyte
Sample Concentration
(microgL)
Spike Added (microgL)
MS Conctntration
(microgL)
MS
Recovery Recovery
Method Limits Notes
Molybdenum 1999 20200 middot 2041 206 70 - 130 EPA 2008 Mod QM-02
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD Oo
Recovery
RPD
Recovery Limits
RPO Limit Method Notes
Molybdenum 20200 2041 207 00141 70 - 130 20 EPA 2008 Mod QM-02
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed In accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page Oo20 1203203 Final Report- SWWTFREV2
04042012
Liz Siska Project Manager 14
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyzed in accordance with the chain ofcustody document This analytical report =tbe reproducedin Its entirety
Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
CLO~AL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1203203-0lREJ
Batch F203260
Preparation Closed Vessel Nitric Oven Digestion
Sequence 2C2200
Lab Number F203260-MSMSD6
Sample Spike MS MS
Analyte Concentration Added
(JtgL) (microgL) Concentration
(microgL)
Recovery Recovery
Method Limits Notes
Molybdenum 1999 50000 7034 101 70 - 130 EPA 2008 Mod AS
Spike MSD Added Concentration
MSD Recovery RPD
Analyte (microgL) (microgL) Recovery RPD Limits Limit Method Notes
Molybdenum 50000 7124 102 128 70 - 130 20 EPA 2008 Mod AS
Page 11 o20 1203203 Final Report- SWWTF REJ2
040412012
15
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 ~ Fx 425-686-3096 GLOBAL SCIENCES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203203-01
Batch F203288
Preparation BrCI Oxidation
Sequence 2C22016
Lab Number F203288-MSMSD 1
Sample Spike MS MS Concentration Added Concentration Recovery
Analyte (ngL) (ogL) (ogL) Recovery Method Notes Limits
Mercury 6116 25500 3096 974 71 - 125 EPA 1631E
Spike MSD MSD Oo Recovery RPD Added Concentration Oo
Limits Method Notes (ogL) (ogL) Recovery RPD Limit Analyte
Mercury 25500 2611 784 170 71 - 125 24 EPA 1631E
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed i11 accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 12of20 1203203 Final Report- SWWTF REV2
04042012
Liz Siska Project Manager 16
bull 11720 North Creek Parkway North Suite 400
Bothell WA 98011 Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1203194-17
Batch F203288 Sequence 2C22016
Preparation BrCI Oxidation Lab Number F203288-MSMSD2
Sample Spike MS MS
Analyte Concentration
(ngL) Added (ngL)
Concentration (ngL) Recovery
Recovery Limits Method Notes
Mercury 142800 505000 627200 959 71 - 125 EPA 1631E
Spike Added
MSD Concentration
MSD Recovery RPO
Analyte (ngL) (ngL) Recovery RPD Limits Limit Method Notes
Mercury 505000 632700 970 0879 71 - 125 24 EPA 1631E
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody docu~nt This analytical report must be reproduced In its entirety
Page 13of20 1203203 Final Report- SWWTFREV2
04042012
Liz Siska Project Manager 17
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996
bull ~ Fx 425-686-3096 GLPBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203232 Sequence 2C20001
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203232-BSBSD1
LCS Source mank Siiike
Spike LCS LCS Added Concentration Recovery
Analyte (microgL) (microgL) Recovery Limits Method Notes
Aluminwn 15000 1444 963 85-115 EPA2008Mod Chromium 70000 654 934 85 bull 115 EPA 2008 Mod Manganese 60000 580 967 85 - 115 EPA 2008 Mod Iron 50000 4610 922 85 - 115 EPA 2008 Mod Nickel 40000 394 985 85 ll5 EPA 2008 Mod Copper 40000 418 104 85 - 115 EPA 2008 Mod Zinc 10000 1017 102 85 bull 115 EPA 2008 Mod Arsenic 15000 1445 963 85 bull 115 EPA 2008 Mod Selenium 30000 2975 992 85-115 EPA2008Mod Molybdenum 20000 185 926 85 bull 115 EPA 2008 Mod Silver 15000 1555 104 85 - 115 EPA 2008 Mod
Cadmium 080000 0802 100 85 - 115 EPA 2008 Mod Lead 15000 1565 104 85 - 115 EPA 2008 Mod
shy
Spike LCSD LCSD Added Concentration Oo Recovery RPD
Analyte (microgL)
15000
(microgL)
1424
Recovery
949
RPD
140
Limits
85 bull 115
Limit
20
Method
EPA 2008 Mod
Notes
Aluminum
Chromium 70000 644 920 l58 85 bull 115 20 EPA 2008 Mod
Manganese 60000 575 958 0920 85 - ll5 20 EPA 2008 Mod
Iron 50000 4580 916 0660 85 - 115 20 EPA 2008 Mod
Nickel 40000 394 985 000457 85 bull 115 20 EPA 2008 Mod
Copper 40000 416 104 0367 85 - 115 20 EPA 2008 Mod
Zinc 10000 1032 103 147 85 - ll5 20 EPA 2008 Mod
Arsenic 15000 1440 960 0305 85 bull 115 20 EPA 2008 Mod
Selenium 30000 2867 956 369 85 -115 20 EPA 2008 Mod
Molybdenum 20000 l86 928 0196 85 -115 20 EPA2008 Mod
Silver l5000 1559 104 0233 85 bull 115 20 EPA 2008 Mod
Cadmium 080000 0809 101 0843 85 bull llS 20 EPA 2008 Mod
Lead 15000 l539 103 170 85 - 115 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed In accordance with the chain ofcustody document This analytical report must be reproduced in its enJirety
Page 14of20 1203203 Final Report- SWWTFREV2
04042012 ~~
Liz Siska Project Manager 18
11720 North Creek Parkway North Suite 400 Bothell WA 98011 Ph 425-686-1996
FRONTIER Fx 425-686-3096 GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203260 Sequence 2C22001
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203260-BSBSD1
LCS Source Blank Spike
Spike LCS LC$ Added Concentration Recovery
Analyte (ptgL) (JJgL) Recovery Limits Method Notes
Molybdenum 20000 182 910 85 - 115 EPA 2008 Mod
Spike LCSD LCSD Added Concentration Recovery RPD
Analyte (microgL) (microgL) Recovery RPD Limits Limit Method Notes
Molybdenum 20000 186 930 213 85 -115 20 EPA 2008 Mod
Frontier Global Sciences Inc The results In this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced In its entirety
Page 15 o20 I203203 Ftnal ampport- SWWTFREV2
04041202
Liz Siska Project Manager 19
middot
I
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SC IE NC ES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPO
Batch F203288 Sequence 2C22016
Preparation BrCI Oxidation Lab Number F203288-BSBSD I
LCS Source NIST 1641d
Spike LCS LCS Added Concentration Recovery
Analyte (ngL) (ngL) Recovery Limits Method Notes
Mercury 15679 1525 973 80 - 120 EPA l631E
Spike LCSD LCSD Added Concentration Oo Recovery RPD
Analyte (ngL) (ngL)
1516
Recovery
967
RPD
0622
Limits
80 - 120
Limit
24
Method
EPA 1631E
Notes
Mercury 15679
Frontier Global Sciences Inc The results in this report only apply lo the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 16 o20 1203203 Final Report- SWWIFREV2
041042012
20Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 middot Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096 ~ O GLO B AL SCI E NCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2C20001
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203232-BLK1 Aluminum 01 40 microgL F203232 PA2008 Molt u F203232-BLK1 Chromium -0007 0 10 microgL F203232 PA 2008 Molt u F203232-BLKI Manganese 0002 010 microgL F203232 PA 2008 Moc u F203232-BLK1 Iron -004 100 microgL F203232 PA 2008 Molt u F203232-BLKI Nickel 0005 010 microgL F203232 PA 2008 Moc u F203232-BLKI Copper 001 010 microgL F203232 PA 2008 Molt u F203232-BLK1 Zinc 011 020 microgL F203232 PA 2008 Moc u F203232-BLK I Arsenic -0009 015 microgL F203232 PA 2008 Moc u F203232-BLK1 Selenium 025 060 microgL F203232 PA 2008 Moc u F203232-BLK1 Molybdenum 001 006 microgL F203232 PA 2008 Moc u F203232-BLK1 Silver -00009 0020 microgL F203232 PA 2008 Moc u F203232-BLK1 Cadmium 0002 0020 microgL F203232 PA 2008 Molt u F203232-BLK1 Lead 0024 0040 microgL F203232 PA 2008 Molt u
middoti
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordonce with the chain ofcustody document Tnts analytical rtport must be reproduced In its enlfrtty
Page7of20 J203203 Final ampport-SWWTF REV2
04042012
Liz Siska Project Manager 21
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 FRONTIER~ Fx 425-686-3096 GLOBAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2C22001
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203260-BLK1 Molybdenum 001 006 microgL F203260 ~PA 2008 Moc u
Frontier Global Sciences Inc middot The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 18of20 1203203 Final Report- SWWTFREV2
04042012
Liz Siska Project Manager 22
~ CLOSAL SCIENCES
~
J1720 North Creek Parkway North Suite 400 Bothell WA 980 l l
Ph 425-686-1996 Fx 425-686-3096
PREPARATION BLANKS
Instrument Hg-17 Sequence 2C22016
Preparation BrCI Oxidation
The results in Ihis report only apply to the samples analyzed i12 accordance with the chain ofcustody dccumnt This analytical report must be reproductd in ils enJirety
Page I9oj20 1203203 Final Report- SWWTF REJ2
04042012
Frontier Global Sciences Inc
bull 23bull Liz Siska Project Manager
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203288-BLKl Mercury 007 050 ngL F203288 EPA 1631E u F203288-BLIlt2 Mercury 006 050 ngL F203288 EPA 163lE u F203288-BLK3 Mercury 006 050 ngL F203288 EPA I63lE u F203288-BLK4 Mercury 018 050 ngL F203288 EPA I63IE U QB-04
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
Notes and Definitions
U Analyte included in the analysis but not detected
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than I times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable ASASD
QB-04 The blank was preserved to 2 BrCl rather than I The control limit for blanks presetved to greater than 1 BrCl is the preservation percentage multiplied by the l1RL
FB-1631 Required equipmentfieldfilter blank not submitted by the client The sample has been analyzed according to 163 lE but does not meet 163 lE criteria
AS This MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
l1RL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to lhe samples analyzedin accordance wirh the chain ofcustody document This analytical report must be reproduced in its entirety
Page 20of20 1203203 Final Report- SWWTF REV2
04042012
24
bull bull
irGl Lu Ull 0111C H AIN-OF-CUSTODY RECORD Page of_~~
Bolo FIELDS REQUIRED P LEASE CIRCLE REQUESTED ANALYs1s Lt) CN voe I svoc TClPI M ETALS INORGANICS
i w I shy i
SAMPLING 0 iii 0 ~
w = ~ DATET1ME QIll c X
w ~sacw 0IF COMPOSITE -gtc ~ u - ~
INDICATE 80TH ~ bulllo- t5a5 START amp FINISH
er Ill liSAMPLE 1 0 i ct -a ~shyDATEITIME l r ~~
bull 7gtItJJJI JWj T ~ tlt
IHAnlX A-Ala S-SOIL GW-GROUHD WATEl SW-SURfACE WATEA DW-DllNIING WAm WW-WAITE WATEl
PWETAJllt H-HCL N-HNO S-HJO Na-NaOHmiddot H-HEOH
i ~~ ~ I ~ X
j i I i= -shy 2 s~ ~ == a~ -shy I t
~~ =~ 2 ~~
~ X a c 2 ~ ~ = -- 2 ~
l j t z i () ~
C 0 5~ s~ = IC 0
C -s ~ = ~ ~e f
0 ~= ~ _sC a ~ C) -shyt( I rt
1 g0
3 i ~-
]-
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~bull m = olt 1 o(
1 e
j
M ICRO middot-- -shy108420
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~ - I 2lte E55 NOTESili I j HEOHVIAl 6shy ~a 3
I 3 ~ It _ c
1
DATE NEEDED b171i1-1~ 1 f METALS 8 RCRA 13 PP FE MN Ps CUPROJECT MANAGER 0v f-e_~ Tmamp- middotc COMPANY pdegZ1)shy 0THE1 METALS __________REPORTING OPTIONSQAQC ICH) NoAonms Jfru lli V =1 Q ) REPORTING LEVEL PUUHS ~OR No
A B C 0lOLYpoundD METALS FIELD flLTtREDI YE NoIF YE F~ oa(ITT STAil~l4t(= ~ ZIP rriu1 NOTES (IE SPEOAl DETECTION LIHIIS BIWNG INFO IF D1mam)PHONE _r~ _z31_ - $ I3 Exr--- OR ELECTRONIC OPTIONSFAX _ __________________ AI l A C J C bull C1
J pbNo FAX E-MAIL PDF EQUIS
E-MAIL tivl el qu ~ pv CvVshyf J --~b Mo ~ tJ k ttJ -z~Sm NAHE W
PROJECT ____________ ___ ___ _ ~111216- aJd M fer P4 jgtZJ)shy
SUTt MA ME VT OTHER _____ ___ ~ 1)--U ( u-middotmiddottut-UJ f bull
REGULATORY PROGRAM NPDES RGP POnY STOilKWATER Ol SITE HISTORY ~i tiT f=
GWP OIL FUND BROWNFJUD OR Orm--------shy RELINQUISHED BY DATE TIME RECEIVED Br Summo (ONTAHINATIOM_______
PO_______QUOTE===-~----shy I RELINQUISHED BY DATE TIME Rmmo BT I FIElllJUDINGStt HI l lS 2
eastern analytical inc 2s CHENELl DR1ve I CoNcoRo NH 03301 I TEL 60322sos2s I 1soo2s7os2s IFAXc 6032284591 I E-MA1l cusToMER_seRv1ceEA1LAascoHj wwweA1lAsscoM
prufmin111ll11bomtory1m1im (WHITE ORIGINAL GREEN PROJECT MANAGER)
shy
shy
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyzed in accordance with the chain ofcustody document This analytical report =tbe reproducedin Its entirety
Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
CLO~AL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1203203-0lREJ
Batch F203260
Preparation Closed Vessel Nitric Oven Digestion
Sequence 2C2200
Lab Number F203260-MSMSD6
Sample Spike MS MS
Analyte Concentration Added
(JtgL) (microgL) Concentration
(microgL)
Recovery Recovery
Method Limits Notes
Molybdenum 1999 50000 7034 101 70 - 130 EPA 2008 Mod AS
Spike MSD Added Concentration
MSD Recovery RPD
Analyte (microgL) (microgL) Recovery RPD Limits Limit Method Notes
Molybdenum 50000 7124 102 128 70 - 130 20 EPA 2008 Mod AS
Page 11 o20 1203203 Final Report- SWWTF REJ2
040412012
15
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 ~ Fx 425-686-3096 GLOBAL SCIENCES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203203-01
Batch F203288
Preparation BrCI Oxidation
Sequence 2C22016
Lab Number F203288-MSMSD 1
Sample Spike MS MS Concentration Added Concentration Recovery
Analyte (ngL) (ogL) (ogL) Recovery Method Notes Limits
Mercury 6116 25500 3096 974 71 - 125 EPA 1631E
Spike MSD MSD Oo Recovery RPD Added Concentration Oo
Limits Method Notes (ogL) (ogL) Recovery RPD Limit Analyte
Mercury 25500 2611 784 170 71 - 125 24 EPA 1631E
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed i11 accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 12of20 1203203 Final Report- SWWTF REV2
04042012
Liz Siska Project Manager 16
bull 11720 North Creek Parkway North Suite 400
Bothell WA 98011 Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1203194-17
Batch F203288 Sequence 2C22016
Preparation BrCI Oxidation Lab Number F203288-MSMSD2
Sample Spike MS MS
Analyte Concentration
(ngL) Added (ngL)
Concentration (ngL) Recovery
Recovery Limits Method Notes
Mercury 142800 505000 627200 959 71 - 125 EPA 1631E
Spike Added
MSD Concentration
MSD Recovery RPO
Analyte (ngL) (ngL) Recovery RPD Limits Limit Method Notes
Mercury 505000 632700 970 0879 71 - 125 24 EPA 1631E
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody docu~nt This analytical report must be reproduced In its entirety
Page 13of20 1203203 Final Report- SWWTFREV2
04042012
Liz Siska Project Manager 17
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996
bull ~ Fx 425-686-3096 GLPBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203232 Sequence 2C20001
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203232-BSBSD1
LCS Source mank Siiike
Spike LCS LCS Added Concentration Recovery
Analyte (microgL) (microgL) Recovery Limits Method Notes
Aluminwn 15000 1444 963 85-115 EPA2008Mod Chromium 70000 654 934 85 bull 115 EPA 2008 Mod Manganese 60000 580 967 85 - 115 EPA 2008 Mod Iron 50000 4610 922 85 - 115 EPA 2008 Mod Nickel 40000 394 985 85 ll5 EPA 2008 Mod Copper 40000 418 104 85 - 115 EPA 2008 Mod Zinc 10000 1017 102 85 bull 115 EPA 2008 Mod Arsenic 15000 1445 963 85 bull 115 EPA 2008 Mod Selenium 30000 2975 992 85-115 EPA2008Mod Molybdenum 20000 185 926 85 bull 115 EPA 2008 Mod Silver 15000 1555 104 85 - 115 EPA 2008 Mod
Cadmium 080000 0802 100 85 - 115 EPA 2008 Mod Lead 15000 1565 104 85 - 115 EPA 2008 Mod
shy
Spike LCSD LCSD Added Concentration Oo Recovery RPD
Analyte (microgL)
15000
(microgL)
1424
Recovery
949
RPD
140
Limits
85 bull 115
Limit
20
Method
EPA 2008 Mod
Notes
Aluminum
Chromium 70000 644 920 l58 85 bull 115 20 EPA 2008 Mod
Manganese 60000 575 958 0920 85 - ll5 20 EPA 2008 Mod
Iron 50000 4580 916 0660 85 - 115 20 EPA 2008 Mod
Nickel 40000 394 985 000457 85 bull 115 20 EPA 2008 Mod
Copper 40000 416 104 0367 85 - 115 20 EPA 2008 Mod
Zinc 10000 1032 103 147 85 - ll5 20 EPA 2008 Mod
Arsenic 15000 1440 960 0305 85 bull 115 20 EPA 2008 Mod
Selenium 30000 2867 956 369 85 -115 20 EPA 2008 Mod
Molybdenum 20000 l86 928 0196 85 -115 20 EPA2008 Mod
Silver l5000 1559 104 0233 85 bull 115 20 EPA 2008 Mod
Cadmium 080000 0809 101 0843 85 bull llS 20 EPA 2008 Mod
Lead 15000 l539 103 170 85 - 115 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed In accordance with the chain ofcustody document This analytical report must be reproduced in its enJirety
Page 14of20 1203203 Final Report- SWWTFREV2
04042012 ~~
Liz Siska Project Manager 18
11720 North Creek Parkway North Suite 400 Bothell WA 98011 Ph 425-686-1996
FRONTIER Fx 425-686-3096 GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203260 Sequence 2C22001
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203260-BSBSD1
LCS Source Blank Spike
Spike LCS LC$ Added Concentration Recovery
Analyte (ptgL) (JJgL) Recovery Limits Method Notes
Molybdenum 20000 182 910 85 - 115 EPA 2008 Mod
Spike LCSD LCSD Added Concentration Recovery RPD
Analyte (microgL) (microgL) Recovery RPD Limits Limit Method Notes
Molybdenum 20000 186 930 213 85 -115 20 EPA 2008 Mod
Frontier Global Sciences Inc The results In this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced In its entirety
Page 15 o20 I203203 Ftnal ampport- SWWTFREV2
04041202
Liz Siska Project Manager 19
middot
I
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SC IE NC ES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPO
Batch F203288 Sequence 2C22016
Preparation BrCI Oxidation Lab Number F203288-BSBSD I
LCS Source NIST 1641d
Spike LCS LCS Added Concentration Recovery
Analyte (ngL) (ngL) Recovery Limits Method Notes
Mercury 15679 1525 973 80 - 120 EPA l631E
Spike LCSD LCSD Added Concentration Oo Recovery RPD
Analyte (ngL) (ngL)
1516
Recovery
967
RPD
0622
Limits
80 - 120
Limit
24
Method
EPA 1631E
Notes
Mercury 15679
Frontier Global Sciences Inc The results in this report only apply lo the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 16 o20 1203203 Final Report- SWWIFREV2
041042012
20Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 middot Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096 ~ O GLO B AL SCI E NCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2C20001
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203232-BLK1 Aluminum 01 40 microgL F203232 PA2008 Molt u F203232-BLK1 Chromium -0007 0 10 microgL F203232 PA 2008 Molt u F203232-BLKI Manganese 0002 010 microgL F203232 PA 2008 Moc u F203232-BLK1 Iron -004 100 microgL F203232 PA 2008 Molt u F203232-BLKI Nickel 0005 010 microgL F203232 PA 2008 Moc u F203232-BLKI Copper 001 010 microgL F203232 PA 2008 Molt u F203232-BLK1 Zinc 011 020 microgL F203232 PA 2008 Moc u F203232-BLK I Arsenic -0009 015 microgL F203232 PA 2008 Moc u F203232-BLK1 Selenium 025 060 microgL F203232 PA 2008 Moc u F203232-BLK1 Molybdenum 001 006 microgL F203232 PA 2008 Moc u F203232-BLK1 Silver -00009 0020 microgL F203232 PA 2008 Moc u F203232-BLK1 Cadmium 0002 0020 microgL F203232 PA 2008 Molt u F203232-BLK1 Lead 0024 0040 microgL F203232 PA 2008 Molt u
middoti
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordonce with the chain ofcustody document Tnts analytical rtport must be reproduced In its enlfrtty
Page7of20 J203203 Final ampport-SWWTF REV2
04042012
Liz Siska Project Manager 21
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 FRONTIER~ Fx 425-686-3096 GLOBAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2C22001
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203260-BLK1 Molybdenum 001 006 microgL F203260 ~PA 2008 Moc u
Frontier Global Sciences Inc middot The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 18of20 1203203 Final Report- SWWTFREV2
04042012
Liz Siska Project Manager 22
~ CLOSAL SCIENCES
~
J1720 North Creek Parkway North Suite 400 Bothell WA 980 l l
Ph 425-686-1996 Fx 425-686-3096
PREPARATION BLANKS
Instrument Hg-17 Sequence 2C22016
Preparation BrCI Oxidation
The results in Ihis report only apply to the samples analyzed i12 accordance with the chain ofcustody dccumnt This analytical report must be reproductd in ils enJirety
Page I9oj20 1203203 Final Report- SWWTF REJ2
04042012
Frontier Global Sciences Inc
bull 23bull Liz Siska Project Manager
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203288-BLKl Mercury 007 050 ngL F203288 EPA 1631E u F203288-BLIlt2 Mercury 006 050 ngL F203288 EPA 163lE u F203288-BLK3 Mercury 006 050 ngL F203288 EPA I63lE u F203288-BLK4 Mercury 018 050 ngL F203288 EPA I63IE U QB-04
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
Notes and Definitions
U Analyte included in the analysis but not detected
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than I times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable ASASD
QB-04 The blank was preserved to 2 BrCl rather than I The control limit for blanks presetved to greater than 1 BrCl is the preservation percentage multiplied by the l1RL
FB-1631 Required equipmentfieldfilter blank not submitted by the client The sample has been analyzed according to 163 lE but does not meet 163 lE criteria
AS This MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
l1RL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to lhe samples analyzedin accordance wirh the chain ofcustody document This analytical report must be reproduced in its entirety
Page 20of20 1203203 Final Report- SWWTF REV2
04042012
24
bull bull
irGl Lu Ull 0111C H AIN-OF-CUSTODY RECORD Page of_~~
Bolo FIELDS REQUIRED P LEASE CIRCLE REQUESTED ANALYs1s Lt) CN voe I svoc TClPI M ETALS INORGANICS
i w I shy i
SAMPLING 0 iii 0 ~
w = ~ DATET1ME QIll c X
w ~sacw 0IF COMPOSITE -gtc ~ u - ~
INDICATE 80TH ~ bulllo- t5a5 START amp FINISH
er Ill liSAMPLE 1 0 i ct -a ~shyDATEITIME l r ~~
bull 7gtItJJJI JWj T ~ tlt
IHAnlX A-Ala S-SOIL GW-GROUHD WATEl SW-SURfACE WATEA DW-DllNIING WAm WW-WAITE WATEl
PWETAJllt H-HCL N-HNO S-HJO Na-NaOHmiddot H-HEOH
i ~~ ~ I ~ X
j i I i= -shy 2 s~ ~ == a~ -shy I t
~~ =~ 2 ~~
~ X a c 2 ~ ~ = -- 2 ~
l j t z i () ~
C 0 5~ s~ = IC 0
C -s ~ = ~ ~e f
0 ~= ~ _sC a ~ C) -shyt( I rt
1 g0
3 i ~-
]-
f~ js~ i
~bull m = olt 1 o(
1 e
j
M ICRO middot-- -shy108420
sshyj
sect= s
~ - I 2lte E55 NOTESili I j HEOHVIAl 6shy ~a 3
I 3 ~ It _ c
1
DATE NEEDED b171i1-1~ 1 f METALS 8 RCRA 13 PP FE MN Ps CUPROJECT MANAGER 0v f-e_~ Tmamp- middotc COMPANY pdegZ1)shy 0THE1 METALS __________REPORTING OPTIONSQAQC ICH) NoAonms Jfru lli V =1 Q ) REPORTING LEVEL PUUHS ~OR No
A B C 0lOLYpoundD METALS FIELD flLTtREDI YE NoIF YE F~ oa(ITT STAil~l4t(= ~ ZIP rriu1 NOTES (IE SPEOAl DETECTION LIHIIS BIWNG INFO IF D1mam)PHONE _r~ _z31_ - $ I3 Exr--- OR ELECTRONIC OPTIONSFAX _ __________________ AI l A C J C bull C1
J pbNo FAX E-MAIL PDF EQUIS
E-MAIL tivl el qu ~ pv CvVshyf J --~b Mo ~ tJ k ttJ -z~Sm NAHE W
PROJECT ____________ ___ ___ _ ~111216- aJd M fer P4 jgtZJ)shy
SUTt MA ME VT OTHER _____ ___ ~ 1)--U ( u-middotmiddottut-UJ f bull
REGULATORY PROGRAM NPDES RGP POnY STOilKWATER Ol SITE HISTORY ~i tiT f=
GWP OIL FUND BROWNFJUD OR Orm--------shy RELINQUISHED BY DATE TIME RECEIVED Br Summo (ONTAHINATIOM_______
PO_______QUOTE===-~----shy I RELINQUISHED BY DATE TIME Rmmo BT I FIElllJUDINGStt HI l lS 2
eastern analytical inc 2s CHENELl DR1ve I CoNcoRo NH 03301 I TEL 60322sos2s I 1soo2s7os2s IFAXc 6032284591 I E-MA1l cusToMER_seRv1ceEA1LAascoHj wwweA1lAsscoM
prufmin111ll11bomtory1m1im (WHITE ORIGINAL GREEN PROJECT MANAGER)
shy
shy
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 ~ Fx 425-686-3096 GLOBAL SCIENCES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1203203-01
Batch F203288
Preparation BrCI Oxidation
Sequence 2C22016
Lab Number F203288-MSMSD 1
Sample Spike MS MS Concentration Added Concentration Recovery
Analyte (ngL) (ogL) (ogL) Recovery Method Notes Limits
Mercury 6116 25500 3096 974 71 - 125 EPA 1631E
Spike MSD MSD Oo Recovery RPD Added Concentration Oo
Limits Method Notes (ogL) (ogL) Recovery RPD Limit Analyte
Mercury 25500 2611 784 170 71 - 125 24 EPA 1631E
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed i11 accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 12of20 1203203 Final Report- SWWTF REV2
04042012
Liz Siska Project Manager 16
bull 11720 North Creek Parkway North Suite 400
Bothell WA 98011 Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1203194-17
Batch F203288 Sequence 2C22016
Preparation BrCI Oxidation Lab Number F203288-MSMSD2
Sample Spike MS MS
Analyte Concentration
(ngL) Added (ngL)
Concentration (ngL) Recovery
Recovery Limits Method Notes
Mercury 142800 505000 627200 959 71 - 125 EPA 1631E
Spike Added
MSD Concentration
MSD Recovery RPO
Analyte (ngL) (ngL) Recovery RPD Limits Limit Method Notes
Mercury 505000 632700 970 0879 71 - 125 24 EPA 1631E
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody docu~nt This analytical report must be reproduced In its entirety
Page 13of20 1203203 Final Report- SWWTFREV2
04042012
Liz Siska Project Manager 17
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996
bull ~ Fx 425-686-3096 GLPBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203232 Sequence 2C20001
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203232-BSBSD1
LCS Source mank Siiike
Spike LCS LCS Added Concentration Recovery
Analyte (microgL) (microgL) Recovery Limits Method Notes
Aluminwn 15000 1444 963 85-115 EPA2008Mod Chromium 70000 654 934 85 bull 115 EPA 2008 Mod Manganese 60000 580 967 85 - 115 EPA 2008 Mod Iron 50000 4610 922 85 - 115 EPA 2008 Mod Nickel 40000 394 985 85 ll5 EPA 2008 Mod Copper 40000 418 104 85 - 115 EPA 2008 Mod Zinc 10000 1017 102 85 bull 115 EPA 2008 Mod Arsenic 15000 1445 963 85 bull 115 EPA 2008 Mod Selenium 30000 2975 992 85-115 EPA2008Mod Molybdenum 20000 185 926 85 bull 115 EPA 2008 Mod Silver 15000 1555 104 85 - 115 EPA 2008 Mod
Cadmium 080000 0802 100 85 - 115 EPA 2008 Mod Lead 15000 1565 104 85 - 115 EPA 2008 Mod
shy
Spike LCSD LCSD Added Concentration Oo Recovery RPD
Analyte (microgL)
15000
(microgL)
1424
Recovery
949
RPD
140
Limits
85 bull 115
Limit
20
Method
EPA 2008 Mod
Notes
Aluminum
Chromium 70000 644 920 l58 85 bull 115 20 EPA 2008 Mod
Manganese 60000 575 958 0920 85 - ll5 20 EPA 2008 Mod
Iron 50000 4580 916 0660 85 - 115 20 EPA 2008 Mod
Nickel 40000 394 985 000457 85 bull 115 20 EPA 2008 Mod
Copper 40000 416 104 0367 85 - 115 20 EPA 2008 Mod
Zinc 10000 1032 103 147 85 - ll5 20 EPA 2008 Mod
Arsenic 15000 1440 960 0305 85 bull 115 20 EPA 2008 Mod
Selenium 30000 2867 956 369 85 -115 20 EPA 2008 Mod
Molybdenum 20000 l86 928 0196 85 -115 20 EPA2008 Mod
Silver l5000 1559 104 0233 85 bull 115 20 EPA 2008 Mod
Cadmium 080000 0809 101 0843 85 bull llS 20 EPA 2008 Mod
Lead 15000 l539 103 170 85 - 115 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed In accordance with the chain ofcustody document This analytical report must be reproduced in its enJirety
Page 14of20 1203203 Final Report- SWWTFREV2
04042012 ~~
Liz Siska Project Manager 18
11720 North Creek Parkway North Suite 400 Bothell WA 98011 Ph 425-686-1996
FRONTIER Fx 425-686-3096 GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203260 Sequence 2C22001
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203260-BSBSD1
LCS Source Blank Spike
Spike LCS LC$ Added Concentration Recovery
Analyte (ptgL) (JJgL) Recovery Limits Method Notes
Molybdenum 20000 182 910 85 - 115 EPA 2008 Mod
Spike LCSD LCSD Added Concentration Recovery RPD
Analyte (microgL) (microgL) Recovery RPD Limits Limit Method Notes
Molybdenum 20000 186 930 213 85 -115 20 EPA 2008 Mod
Frontier Global Sciences Inc The results In this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced In its entirety
Page 15 o20 I203203 Ftnal ampport- SWWTFREV2
04041202
Liz Siska Project Manager 19
middot
I
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SC IE NC ES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPO
Batch F203288 Sequence 2C22016
Preparation BrCI Oxidation Lab Number F203288-BSBSD I
LCS Source NIST 1641d
Spike LCS LCS Added Concentration Recovery
Analyte (ngL) (ngL) Recovery Limits Method Notes
Mercury 15679 1525 973 80 - 120 EPA l631E
Spike LCSD LCSD Added Concentration Oo Recovery RPD
Analyte (ngL) (ngL)
1516
Recovery
967
RPD
0622
Limits
80 - 120
Limit
24
Method
EPA 1631E
Notes
Mercury 15679
Frontier Global Sciences Inc The results in this report only apply lo the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 16 o20 1203203 Final Report- SWWIFREV2
041042012
20Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 middot Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096 ~ O GLO B AL SCI E NCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2C20001
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203232-BLK1 Aluminum 01 40 microgL F203232 PA2008 Molt u F203232-BLK1 Chromium -0007 0 10 microgL F203232 PA 2008 Molt u F203232-BLKI Manganese 0002 010 microgL F203232 PA 2008 Moc u F203232-BLK1 Iron -004 100 microgL F203232 PA 2008 Molt u F203232-BLKI Nickel 0005 010 microgL F203232 PA 2008 Moc u F203232-BLKI Copper 001 010 microgL F203232 PA 2008 Molt u F203232-BLK1 Zinc 011 020 microgL F203232 PA 2008 Moc u F203232-BLK I Arsenic -0009 015 microgL F203232 PA 2008 Moc u F203232-BLK1 Selenium 025 060 microgL F203232 PA 2008 Moc u F203232-BLK1 Molybdenum 001 006 microgL F203232 PA 2008 Moc u F203232-BLK1 Silver -00009 0020 microgL F203232 PA 2008 Moc u F203232-BLK1 Cadmium 0002 0020 microgL F203232 PA 2008 Molt u F203232-BLK1 Lead 0024 0040 microgL F203232 PA 2008 Molt u
middoti
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordonce with the chain ofcustody document Tnts analytical rtport must be reproduced In its enlfrtty
Page7of20 J203203 Final ampport-SWWTF REV2
04042012
Liz Siska Project Manager 21
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 FRONTIER~ Fx 425-686-3096 GLOBAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2C22001
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203260-BLK1 Molybdenum 001 006 microgL F203260 ~PA 2008 Moc u
Frontier Global Sciences Inc middot The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 18of20 1203203 Final Report- SWWTFREV2
04042012
Liz Siska Project Manager 22
~ CLOSAL SCIENCES
~
J1720 North Creek Parkway North Suite 400 Bothell WA 980 l l
Ph 425-686-1996 Fx 425-686-3096
PREPARATION BLANKS
Instrument Hg-17 Sequence 2C22016
Preparation BrCI Oxidation
The results in Ihis report only apply to the samples analyzed i12 accordance with the chain ofcustody dccumnt This analytical report must be reproductd in ils enJirety
Page I9oj20 1203203 Final Report- SWWTF REJ2
04042012
Frontier Global Sciences Inc
bull 23bull Liz Siska Project Manager
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203288-BLKl Mercury 007 050 ngL F203288 EPA 1631E u F203288-BLIlt2 Mercury 006 050 ngL F203288 EPA 163lE u F203288-BLK3 Mercury 006 050 ngL F203288 EPA I63lE u F203288-BLK4 Mercury 018 050 ngL F203288 EPA I63IE U QB-04
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
Notes and Definitions
U Analyte included in the analysis but not detected
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than I times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable ASASD
QB-04 The blank was preserved to 2 BrCl rather than I The control limit for blanks presetved to greater than 1 BrCl is the preservation percentage multiplied by the l1RL
FB-1631 Required equipmentfieldfilter blank not submitted by the client The sample has been analyzed according to 163 lE but does not meet 163 lE criteria
AS This MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
l1RL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to lhe samples analyzedin accordance wirh the chain ofcustody document This analytical report must be reproduced in its entirety
Page 20of20 1203203 Final Report- SWWTF REV2
04042012
24
bull bull
irGl Lu Ull 0111C H AIN-OF-CUSTODY RECORD Page of_~~
Bolo FIELDS REQUIRED P LEASE CIRCLE REQUESTED ANALYs1s Lt) CN voe I svoc TClPI M ETALS INORGANICS
i w I shy i
SAMPLING 0 iii 0 ~
w = ~ DATET1ME QIll c X
w ~sacw 0IF COMPOSITE -gtc ~ u - ~
INDICATE 80TH ~ bulllo- t5a5 START amp FINISH
er Ill liSAMPLE 1 0 i ct -a ~shyDATEITIME l r ~~
bull 7gtItJJJI JWj T ~ tlt
IHAnlX A-Ala S-SOIL GW-GROUHD WATEl SW-SURfACE WATEA DW-DllNIING WAm WW-WAITE WATEl
PWETAJllt H-HCL N-HNO S-HJO Na-NaOHmiddot H-HEOH
i ~~ ~ I ~ X
j i I i= -shy 2 s~ ~ == a~ -shy I t
~~ =~ 2 ~~
~ X a c 2 ~ ~ = -- 2 ~
l j t z i () ~
C 0 5~ s~ = IC 0
C -s ~ = ~ ~e f
0 ~= ~ _sC a ~ C) -shyt( I rt
1 g0
3 i ~-
]-
f~ js~ i
~bull m = olt 1 o(
1 e
j
M ICRO middot-- -shy108420
sshyj
sect= s
~ - I 2lte E55 NOTESili I j HEOHVIAl 6shy ~a 3
I 3 ~ It _ c
1
DATE NEEDED b171i1-1~ 1 f METALS 8 RCRA 13 PP FE MN Ps CUPROJECT MANAGER 0v f-e_~ Tmamp- middotc COMPANY pdegZ1)shy 0THE1 METALS __________REPORTING OPTIONSQAQC ICH) NoAonms Jfru lli V =1 Q ) REPORTING LEVEL PUUHS ~OR No
A B C 0lOLYpoundD METALS FIELD flLTtREDI YE NoIF YE F~ oa(ITT STAil~l4t(= ~ ZIP rriu1 NOTES (IE SPEOAl DETECTION LIHIIS BIWNG INFO IF D1mam)PHONE _r~ _z31_ - $ I3 Exr--- OR ELECTRONIC OPTIONSFAX _ __________________ AI l A C J C bull C1
J pbNo FAX E-MAIL PDF EQUIS
E-MAIL tivl el qu ~ pv CvVshyf J --~b Mo ~ tJ k ttJ -z~Sm NAHE W
PROJECT ____________ ___ ___ _ ~111216- aJd M fer P4 jgtZJ)shy
SUTt MA ME VT OTHER _____ ___ ~ 1)--U ( u-middotmiddottut-UJ f bull
REGULATORY PROGRAM NPDES RGP POnY STOilKWATER Ol SITE HISTORY ~i tiT f=
GWP OIL FUND BROWNFJUD OR Orm--------shy RELINQUISHED BY DATE TIME RECEIVED Br Summo (ONTAHINATIOM_______
PO_______QUOTE===-~----shy I RELINQUISHED BY DATE TIME Rmmo BT I FIElllJUDINGStt HI l lS 2
eastern analytical inc 2s CHENELl DR1ve I CoNcoRo NH 03301 I TEL 60322sos2s I 1soo2s7os2s IFAXc 6032284591 I E-MA1l cusToMER_seRv1ceEA1LAascoHj wwweA1lAsscoM
prufmin111ll11bomtory1m1im (WHITE ORIGINAL GREEN PROJECT MANAGER)
shy
shy
bull 11720 North Creek Parkway North Suite 400
Bothell WA 98011 Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1203194-17
Batch F203288 Sequence 2C22016
Preparation BrCI Oxidation Lab Number F203288-MSMSD2
Sample Spike MS MS
Analyte Concentration
(ngL) Added (ngL)
Concentration (ngL) Recovery
Recovery Limits Method Notes
Mercury 142800 505000 627200 959 71 - 125 EPA 1631E
Spike Added
MSD Concentration
MSD Recovery RPO
Analyte (ngL) (ngL) Recovery RPD Limits Limit Method Notes
Mercury 505000 632700 970 0879 71 - 125 24 EPA 1631E
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody docu~nt This analytical report must be reproduced In its entirety
Page 13of20 1203203 Final Report- SWWTFREV2
04042012
Liz Siska Project Manager 17
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996
bull ~ Fx 425-686-3096 GLPBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203232 Sequence 2C20001
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203232-BSBSD1
LCS Source mank Siiike
Spike LCS LCS Added Concentration Recovery
Analyte (microgL) (microgL) Recovery Limits Method Notes
Aluminwn 15000 1444 963 85-115 EPA2008Mod Chromium 70000 654 934 85 bull 115 EPA 2008 Mod Manganese 60000 580 967 85 - 115 EPA 2008 Mod Iron 50000 4610 922 85 - 115 EPA 2008 Mod Nickel 40000 394 985 85 ll5 EPA 2008 Mod Copper 40000 418 104 85 - 115 EPA 2008 Mod Zinc 10000 1017 102 85 bull 115 EPA 2008 Mod Arsenic 15000 1445 963 85 bull 115 EPA 2008 Mod Selenium 30000 2975 992 85-115 EPA2008Mod Molybdenum 20000 185 926 85 bull 115 EPA 2008 Mod Silver 15000 1555 104 85 - 115 EPA 2008 Mod
Cadmium 080000 0802 100 85 - 115 EPA 2008 Mod Lead 15000 1565 104 85 - 115 EPA 2008 Mod
shy
Spike LCSD LCSD Added Concentration Oo Recovery RPD
Analyte (microgL)
15000
(microgL)
1424
Recovery
949
RPD
140
Limits
85 bull 115
Limit
20
Method
EPA 2008 Mod
Notes
Aluminum
Chromium 70000 644 920 l58 85 bull 115 20 EPA 2008 Mod
Manganese 60000 575 958 0920 85 - ll5 20 EPA 2008 Mod
Iron 50000 4580 916 0660 85 - 115 20 EPA 2008 Mod
Nickel 40000 394 985 000457 85 bull 115 20 EPA 2008 Mod
Copper 40000 416 104 0367 85 - 115 20 EPA 2008 Mod
Zinc 10000 1032 103 147 85 - ll5 20 EPA 2008 Mod
Arsenic 15000 1440 960 0305 85 bull 115 20 EPA 2008 Mod
Selenium 30000 2867 956 369 85 -115 20 EPA 2008 Mod
Molybdenum 20000 l86 928 0196 85 -115 20 EPA2008 Mod
Silver l5000 1559 104 0233 85 bull 115 20 EPA 2008 Mod
Cadmium 080000 0809 101 0843 85 bull llS 20 EPA 2008 Mod
Lead 15000 l539 103 170 85 - 115 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed In accordance with the chain ofcustody document This analytical report must be reproduced in its enJirety
Page 14of20 1203203 Final Report- SWWTFREV2
04042012 ~~
Liz Siska Project Manager 18
11720 North Creek Parkway North Suite 400 Bothell WA 98011 Ph 425-686-1996
FRONTIER Fx 425-686-3096 GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203260 Sequence 2C22001
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203260-BSBSD1
LCS Source Blank Spike
Spike LCS LC$ Added Concentration Recovery
Analyte (ptgL) (JJgL) Recovery Limits Method Notes
Molybdenum 20000 182 910 85 - 115 EPA 2008 Mod
Spike LCSD LCSD Added Concentration Recovery RPD
Analyte (microgL) (microgL) Recovery RPD Limits Limit Method Notes
Molybdenum 20000 186 930 213 85 -115 20 EPA 2008 Mod
Frontier Global Sciences Inc The results In this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced In its entirety
Page 15 o20 I203203 Ftnal ampport- SWWTFREV2
04041202
Liz Siska Project Manager 19
middot
I
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SC IE NC ES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPO
Batch F203288 Sequence 2C22016
Preparation BrCI Oxidation Lab Number F203288-BSBSD I
LCS Source NIST 1641d
Spike LCS LCS Added Concentration Recovery
Analyte (ngL) (ngL) Recovery Limits Method Notes
Mercury 15679 1525 973 80 - 120 EPA l631E
Spike LCSD LCSD Added Concentration Oo Recovery RPD
Analyte (ngL) (ngL)
1516
Recovery
967
RPD
0622
Limits
80 - 120
Limit
24
Method
EPA 1631E
Notes
Mercury 15679
Frontier Global Sciences Inc The results in this report only apply lo the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 16 o20 1203203 Final Report- SWWIFREV2
041042012
20Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 middot Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096 ~ O GLO B AL SCI E NCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2C20001
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203232-BLK1 Aluminum 01 40 microgL F203232 PA2008 Molt u F203232-BLK1 Chromium -0007 0 10 microgL F203232 PA 2008 Molt u F203232-BLKI Manganese 0002 010 microgL F203232 PA 2008 Moc u F203232-BLK1 Iron -004 100 microgL F203232 PA 2008 Molt u F203232-BLKI Nickel 0005 010 microgL F203232 PA 2008 Moc u F203232-BLKI Copper 001 010 microgL F203232 PA 2008 Molt u F203232-BLK1 Zinc 011 020 microgL F203232 PA 2008 Moc u F203232-BLK I Arsenic -0009 015 microgL F203232 PA 2008 Moc u F203232-BLK1 Selenium 025 060 microgL F203232 PA 2008 Moc u F203232-BLK1 Molybdenum 001 006 microgL F203232 PA 2008 Moc u F203232-BLK1 Silver -00009 0020 microgL F203232 PA 2008 Moc u F203232-BLK1 Cadmium 0002 0020 microgL F203232 PA 2008 Molt u F203232-BLK1 Lead 0024 0040 microgL F203232 PA 2008 Molt u
middoti
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordonce with the chain ofcustody document Tnts analytical rtport must be reproduced In its enlfrtty
Page7of20 J203203 Final ampport-SWWTF REV2
04042012
Liz Siska Project Manager 21
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 FRONTIER~ Fx 425-686-3096 GLOBAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2C22001
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203260-BLK1 Molybdenum 001 006 microgL F203260 ~PA 2008 Moc u
Frontier Global Sciences Inc middot The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 18of20 1203203 Final Report- SWWTFREV2
04042012
Liz Siska Project Manager 22
~ CLOSAL SCIENCES
~
J1720 North Creek Parkway North Suite 400 Bothell WA 980 l l
Ph 425-686-1996 Fx 425-686-3096
PREPARATION BLANKS
Instrument Hg-17 Sequence 2C22016
Preparation BrCI Oxidation
The results in Ihis report only apply to the samples analyzed i12 accordance with the chain ofcustody dccumnt This analytical report must be reproductd in ils enJirety
Page I9oj20 1203203 Final Report- SWWTF REJ2
04042012
Frontier Global Sciences Inc
bull 23bull Liz Siska Project Manager
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203288-BLKl Mercury 007 050 ngL F203288 EPA 1631E u F203288-BLIlt2 Mercury 006 050 ngL F203288 EPA 163lE u F203288-BLK3 Mercury 006 050 ngL F203288 EPA I63lE u F203288-BLK4 Mercury 018 050 ngL F203288 EPA I63IE U QB-04
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
Notes and Definitions
U Analyte included in the analysis but not detected
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than I times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable ASASD
QB-04 The blank was preserved to 2 BrCl rather than I The control limit for blanks presetved to greater than 1 BrCl is the preservation percentage multiplied by the l1RL
FB-1631 Required equipmentfieldfilter blank not submitted by the client The sample has been analyzed according to 163 lE but does not meet 163 lE criteria
AS This MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
l1RL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to lhe samples analyzedin accordance wirh the chain ofcustody document This analytical report must be reproduced in its entirety
Page 20of20 1203203 Final Report- SWWTF REV2
04042012
24
bull bull
irGl Lu Ull 0111C H AIN-OF-CUSTODY RECORD Page of_~~
Bolo FIELDS REQUIRED P LEASE CIRCLE REQUESTED ANALYs1s Lt) CN voe I svoc TClPI M ETALS INORGANICS
i w I shy i
SAMPLING 0 iii 0 ~
w = ~ DATET1ME QIll c X
w ~sacw 0IF COMPOSITE -gtc ~ u - ~
INDICATE 80TH ~ bulllo- t5a5 START amp FINISH
er Ill liSAMPLE 1 0 i ct -a ~shyDATEITIME l r ~~
bull 7gtItJJJI JWj T ~ tlt
IHAnlX A-Ala S-SOIL GW-GROUHD WATEl SW-SURfACE WATEA DW-DllNIING WAm WW-WAITE WATEl
PWETAJllt H-HCL N-HNO S-HJO Na-NaOHmiddot H-HEOH
i ~~ ~ I ~ X
j i I i= -shy 2 s~ ~ == a~ -shy I t
~~ =~ 2 ~~
~ X a c 2 ~ ~ = -- 2 ~
l j t z i () ~
C 0 5~ s~ = IC 0
C -s ~ = ~ ~e f
0 ~= ~ _sC a ~ C) -shyt( I rt
1 g0
3 i ~-
]-
f~ js~ i
~bull m = olt 1 o(
1 e
j
M ICRO middot-- -shy108420
sshyj
sect= s
~ - I 2lte E55 NOTESili I j HEOHVIAl 6shy ~a 3
I 3 ~ It _ c
1
DATE NEEDED b171i1-1~ 1 f METALS 8 RCRA 13 PP FE MN Ps CUPROJECT MANAGER 0v f-e_~ Tmamp- middotc COMPANY pdegZ1)shy 0THE1 METALS __________REPORTING OPTIONSQAQC ICH) NoAonms Jfru lli V =1 Q ) REPORTING LEVEL PUUHS ~OR No
A B C 0lOLYpoundD METALS FIELD flLTtREDI YE NoIF YE F~ oa(ITT STAil~l4t(= ~ ZIP rriu1 NOTES (IE SPEOAl DETECTION LIHIIS BIWNG INFO IF D1mam)PHONE _r~ _z31_ - $ I3 Exr--- OR ELECTRONIC OPTIONSFAX _ __________________ AI l A C J C bull C1
J pbNo FAX E-MAIL PDF EQUIS
E-MAIL tivl el qu ~ pv CvVshyf J --~b Mo ~ tJ k ttJ -z~Sm NAHE W
PROJECT ____________ ___ ___ _ ~111216- aJd M fer P4 jgtZJ)shy
SUTt MA ME VT OTHER _____ ___ ~ 1)--U ( u-middotmiddottut-UJ f bull
REGULATORY PROGRAM NPDES RGP POnY STOilKWATER Ol SITE HISTORY ~i tiT f=
GWP OIL FUND BROWNFJUD OR Orm--------shy RELINQUISHED BY DATE TIME RECEIVED Br Summo (ONTAHINATIOM_______
PO_______QUOTE===-~----shy I RELINQUISHED BY DATE TIME Rmmo BT I FIElllJUDINGStt HI l lS 2
eastern analytical inc 2s CHENELl DR1ve I CoNcoRo NH 03301 I TEL 60322sos2s I 1soo2s7os2s IFAXc 6032284591 I E-MA1l cusToMER_seRv1ceEA1LAascoHj wwweA1lAsscoM
prufmin111ll11bomtory1m1im (WHITE ORIGINAL GREEN PROJECT MANAGER)
shy
shy
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996
bull ~ Fx 425-686-3096 GLPBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203232 Sequence 2C20001
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203232-BSBSD1
LCS Source mank Siiike
Spike LCS LCS Added Concentration Recovery
Analyte (microgL) (microgL) Recovery Limits Method Notes
Aluminwn 15000 1444 963 85-115 EPA2008Mod Chromium 70000 654 934 85 bull 115 EPA 2008 Mod Manganese 60000 580 967 85 - 115 EPA 2008 Mod Iron 50000 4610 922 85 - 115 EPA 2008 Mod Nickel 40000 394 985 85 ll5 EPA 2008 Mod Copper 40000 418 104 85 - 115 EPA 2008 Mod Zinc 10000 1017 102 85 bull 115 EPA 2008 Mod Arsenic 15000 1445 963 85 bull 115 EPA 2008 Mod Selenium 30000 2975 992 85-115 EPA2008Mod Molybdenum 20000 185 926 85 bull 115 EPA 2008 Mod Silver 15000 1555 104 85 - 115 EPA 2008 Mod
Cadmium 080000 0802 100 85 - 115 EPA 2008 Mod Lead 15000 1565 104 85 - 115 EPA 2008 Mod
shy
Spike LCSD LCSD Added Concentration Oo Recovery RPD
Analyte (microgL)
15000
(microgL)
1424
Recovery
949
RPD
140
Limits
85 bull 115
Limit
20
Method
EPA 2008 Mod
Notes
Aluminum
Chromium 70000 644 920 l58 85 bull 115 20 EPA 2008 Mod
Manganese 60000 575 958 0920 85 - ll5 20 EPA 2008 Mod
Iron 50000 4580 916 0660 85 - 115 20 EPA 2008 Mod
Nickel 40000 394 985 000457 85 bull 115 20 EPA 2008 Mod
Copper 40000 416 104 0367 85 - 115 20 EPA 2008 Mod
Zinc 10000 1032 103 147 85 - ll5 20 EPA 2008 Mod
Arsenic 15000 1440 960 0305 85 bull 115 20 EPA 2008 Mod
Selenium 30000 2867 956 369 85 -115 20 EPA 2008 Mod
Molybdenum 20000 l86 928 0196 85 -115 20 EPA2008 Mod
Silver l5000 1559 104 0233 85 bull 115 20 EPA 2008 Mod
Cadmium 080000 0809 101 0843 85 bull llS 20 EPA 2008 Mod
Lead 15000 l539 103 170 85 - 115 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed In accordance with the chain ofcustody document This analytical report must be reproduced in its enJirety
Page 14of20 1203203 Final Report- SWWTFREV2
04042012 ~~
Liz Siska Project Manager 18
11720 North Creek Parkway North Suite 400 Bothell WA 98011 Ph 425-686-1996
FRONTIER Fx 425-686-3096 GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203260 Sequence 2C22001
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203260-BSBSD1
LCS Source Blank Spike
Spike LCS LC$ Added Concentration Recovery
Analyte (ptgL) (JJgL) Recovery Limits Method Notes
Molybdenum 20000 182 910 85 - 115 EPA 2008 Mod
Spike LCSD LCSD Added Concentration Recovery RPD
Analyte (microgL) (microgL) Recovery RPD Limits Limit Method Notes
Molybdenum 20000 186 930 213 85 -115 20 EPA 2008 Mod
Frontier Global Sciences Inc The results In this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced In its entirety
Page 15 o20 I203203 Ftnal ampport- SWWTFREV2
04041202
Liz Siska Project Manager 19
middot
I
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SC IE NC ES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPO
Batch F203288 Sequence 2C22016
Preparation BrCI Oxidation Lab Number F203288-BSBSD I
LCS Source NIST 1641d
Spike LCS LCS Added Concentration Recovery
Analyte (ngL) (ngL) Recovery Limits Method Notes
Mercury 15679 1525 973 80 - 120 EPA l631E
Spike LCSD LCSD Added Concentration Oo Recovery RPD
Analyte (ngL) (ngL)
1516
Recovery
967
RPD
0622
Limits
80 - 120
Limit
24
Method
EPA 1631E
Notes
Mercury 15679
Frontier Global Sciences Inc The results in this report only apply lo the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 16 o20 1203203 Final Report- SWWIFREV2
041042012
20Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 middot Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096 ~ O GLO B AL SCI E NCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2C20001
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203232-BLK1 Aluminum 01 40 microgL F203232 PA2008 Molt u F203232-BLK1 Chromium -0007 0 10 microgL F203232 PA 2008 Molt u F203232-BLKI Manganese 0002 010 microgL F203232 PA 2008 Moc u F203232-BLK1 Iron -004 100 microgL F203232 PA 2008 Molt u F203232-BLKI Nickel 0005 010 microgL F203232 PA 2008 Moc u F203232-BLKI Copper 001 010 microgL F203232 PA 2008 Molt u F203232-BLK1 Zinc 011 020 microgL F203232 PA 2008 Moc u F203232-BLK I Arsenic -0009 015 microgL F203232 PA 2008 Moc u F203232-BLK1 Selenium 025 060 microgL F203232 PA 2008 Moc u F203232-BLK1 Molybdenum 001 006 microgL F203232 PA 2008 Moc u F203232-BLK1 Silver -00009 0020 microgL F203232 PA 2008 Moc u F203232-BLK1 Cadmium 0002 0020 microgL F203232 PA 2008 Molt u F203232-BLK1 Lead 0024 0040 microgL F203232 PA 2008 Molt u
middoti
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordonce with the chain ofcustody document Tnts analytical rtport must be reproduced In its enlfrtty
Page7of20 J203203 Final ampport-SWWTF REV2
04042012
Liz Siska Project Manager 21
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 FRONTIER~ Fx 425-686-3096 GLOBAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2C22001
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203260-BLK1 Molybdenum 001 006 microgL F203260 ~PA 2008 Moc u
Frontier Global Sciences Inc middot The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 18of20 1203203 Final Report- SWWTFREV2
04042012
Liz Siska Project Manager 22
~ CLOSAL SCIENCES
~
J1720 North Creek Parkway North Suite 400 Bothell WA 980 l l
Ph 425-686-1996 Fx 425-686-3096
PREPARATION BLANKS
Instrument Hg-17 Sequence 2C22016
Preparation BrCI Oxidation
The results in Ihis report only apply to the samples analyzed i12 accordance with the chain ofcustody dccumnt This analytical report must be reproductd in ils enJirety
Page I9oj20 1203203 Final Report- SWWTF REJ2
04042012
Frontier Global Sciences Inc
bull 23bull Liz Siska Project Manager
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203288-BLKl Mercury 007 050 ngL F203288 EPA 1631E u F203288-BLIlt2 Mercury 006 050 ngL F203288 EPA 163lE u F203288-BLK3 Mercury 006 050 ngL F203288 EPA I63lE u F203288-BLK4 Mercury 018 050 ngL F203288 EPA I63IE U QB-04
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
Notes and Definitions
U Analyte included in the analysis but not detected
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than I times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable ASASD
QB-04 The blank was preserved to 2 BrCl rather than I The control limit for blanks presetved to greater than 1 BrCl is the preservation percentage multiplied by the l1RL
FB-1631 Required equipmentfieldfilter blank not submitted by the client The sample has been analyzed according to 163 lE but does not meet 163 lE criteria
AS This MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
l1RL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to lhe samples analyzedin accordance wirh the chain ofcustody document This analytical report must be reproduced in its entirety
Page 20of20 1203203 Final Report- SWWTF REV2
04042012
24
bull bull
irGl Lu Ull 0111C H AIN-OF-CUSTODY RECORD Page of_~~
Bolo FIELDS REQUIRED P LEASE CIRCLE REQUESTED ANALYs1s Lt) CN voe I svoc TClPI M ETALS INORGANICS
i w I shy i
SAMPLING 0 iii 0 ~
w = ~ DATET1ME QIll c X
w ~sacw 0IF COMPOSITE -gtc ~ u - ~
INDICATE 80TH ~ bulllo- t5a5 START amp FINISH
er Ill liSAMPLE 1 0 i ct -a ~shyDATEITIME l r ~~
bull 7gtItJJJI JWj T ~ tlt
IHAnlX A-Ala S-SOIL GW-GROUHD WATEl SW-SURfACE WATEA DW-DllNIING WAm WW-WAITE WATEl
PWETAJllt H-HCL N-HNO S-HJO Na-NaOHmiddot H-HEOH
i ~~ ~ I ~ X
j i I i= -shy 2 s~ ~ == a~ -shy I t
~~ =~ 2 ~~
~ X a c 2 ~ ~ = -- 2 ~
l j t z i () ~
C 0 5~ s~ = IC 0
C -s ~ = ~ ~e f
0 ~= ~ _sC a ~ C) -shyt( I rt
1 g0
3 i ~-
]-
f~ js~ i
~bull m = olt 1 o(
1 e
j
M ICRO middot-- -shy108420
sshyj
sect= s
~ - I 2lte E55 NOTESili I j HEOHVIAl 6shy ~a 3
I 3 ~ It _ c
1
DATE NEEDED b171i1-1~ 1 f METALS 8 RCRA 13 PP FE MN Ps CUPROJECT MANAGER 0v f-e_~ Tmamp- middotc COMPANY pdegZ1)shy 0THE1 METALS __________REPORTING OPTIONSQAQC ICH) NoAonms Jfru lli V =1 Q ) REPORTING LEVEL PUUHS ~OR No
A B C 0lOLYpoundD METALS FIELD flLTtREDI YE NoIF YE F~ oa(ITT STAil~l4t(= ~ ZIP rriu1 NOTES (IE SPEOAl DETECTION LIHIIS BIWNG INFO IF D1mam)PHONE _r~ _z31_ - $ I3 Exr--- OR ELECTRONIC OPTIONSFAX _ __________________ AI l A C J C bull C1
J pbNo FAX E-MAIL PDF EQUIS
E-MAIL tivl el qu ~ pv CvVshyf J --~b Mo ~ tJ k ttJ -z~Sm NAHE W
PROJECT ____________ ___ ___ _ ~111216- aJd M fer P4 jgtZJ)shy
SUTt MA ME VT OTHER _____ ___ ~ 1)--U ( u-middotmiddottut-UJ f bull
REGULATORY PROGRAM NPDES RGP POnY STOilKWATER Ol SITE HISTORY ~i tiT f=
GWP OIL FUND BROWNFJUD OR Orm--------shy RELINQUISHED BY DATE TIME RECEIVED Br Summo (ONTAHINATIOM_______
PO_______QUOTE===-~----shy I RELINQUISHED BY DATE TIME Rmmo BT I FIElllJUDINGStt HI l lS 2
eastern analytical inc 2s CHENELl DR1ve I CoNcoRo NH 03301 I TEL 60322sos2s I 1soo2s7os2s IFAXc 6032284591 I E-MA1l cusToMER_seRv1ceEA1LAascoHj wwweA1lAsscoM
prufmin111ll11bomtory1m1im (WHITE ORIGINAL GREEN PROJECT MANAGER)
shy
shy
11720 North Creek Parkway North Suite 400 Bothell WA 98011 Ph 425-686-1996
FRONTIER Fx 425-686-3096 GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203260 Sequence 2C22001
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203260-BSBSD1
LCS Source Blank Spike
Spike LCS LC$ Added Concentration Recovery
Analyte (ptgL) (JJgL) Recovery Limits Method Notes
Molybdenum 20000 182 910 85 - 115 EPA 2008 Mod
Spike LCSD LCSD Added Concentration Recovery RPD
Analyte (microgL) (microgL) Recovery RPD Limits Limit Method Notes
Molybdenum 20000 186 930 213 85 -115 20 EPA 2008 Mod
Frontier Global Sciences Inc The results In this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced In its entirety
Page 15 o20 I203203 Ftnal ampport- SWWTFREV2
04041202
Liz Siska Project Manager 19
middot
I
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SC IE NC ES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPO
Batch F203288 Sequence 2C22016
Preparation BrCI Oxidation Lab Number F203288-BSBSD I
LCS Source NIST 1641d
Spike LCS LCS Added Concentration Recovery
Analyte (ngL) (ngL) Recovery Limits Method Notes
Mercury 15679 1525 973 80 - 120 EPA l631E
Spike LCSD LCSD Added Concentration Oo Recovery RPD
Analyte (ngL) (ngL)
1516
Recovery
967
RPD
0622
Limits
80 - 120
Limit
24
Method
EPA 1631E
Notes
Mercury 15679
Frontier Global Sciences Inc The results in this report only apply lo the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 16 o20 1203203 Final Report- SWWIFREV2
041042012
20Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 middot Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096 ~ O GLO B AL SCI E NCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2C20001
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203232-BLK1 Aluminum 01 40 microgL F203232 PA2008 Molt u F203232-BLK1 Chromium -0007 0 10 microgL F203232 PA 2008 Molt u F203232-BLKI Manganese 0002 010 microgL F203232 PA 2008 Moc u F203232-BLK1 Iron -004 100 microgL F203232 PA 2008 Molt u F203232-BLKI Nickel 0005 010 microgL F203232 PA 2008 Moc u F203232-BLKI Copper 001 010 microgL F203232 PA 2008 Molt u F203232-BLK1 Zinc 011 020 microgL F203232 PA 2008 Moc u F203232-BLK I Arsenic -0009 015 microgL F203232 PA 2008 Moc u F203232-BLK1 Selenium 025 060 microgL F203232 PA 2008 Moc u F203232-BLK1 Molybdenum 001 006 microgL F203232 PA 2008 Moc u F203232-BLK1 Silver -00009 0020 microgL F203232 PA 2008 Moc u F203232-BLK1 Cadmium 0002 0020 microgL F203232 PA 2008 Molt u F203232-BLK1 Lead 0024 0040 microgL F203232 PA 2008 Molt u
middoti
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordonce with the chain ofcustody document Tnts analytical rtport must be reproduced In its enlfrtty
Page7of20 J203203 Final ampport-SWWTF REV2
04042012
Liz Siska Project Manager 21
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 FRONTIER~ Fx 425-686-3096 GLOBAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2C22001
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203260-BLK1 Molybdenum 001 006 microgL F203260 ~PA 2008 Moc u
Frontier Global Sciences Inc middot The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 18of20 1203203 Final Report- SWWTFREV2
04042012
Liz Siska Project Manager 22
~ CLOSAL SCIENCES
~
J1720 North Creek Parkway North Suite 400 Bothell WA 980 l l
Ph 425-686-1996 Fx 425-686-3096
PREPARATION BLANKS
Instrument Hg-17 Sequence 2C22016
Preparation BrCI Oxidation
The results in Ihis report only apply to the samples analyzed i12 accordance with the chain ofcustody dccumnt This analytical report must be reproductd in ils enJirety
Page I9oj20 1203203 Final Report- SWWTF REJ2
04042012
Frontier Global Sciences Inc
bull 23bull Liz Siska Project Manager
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203288-BLKl Mercury 007 050 ngL F203288 EPA 1631E u F203288-BLIlt2 Mercury 006 050 ngL F203288 EPA 163lE u F203288-BLK3 Mercury 006 050 ngL F203288 EPA I63lE u F203288-BLK4 Mercury 018 050 ngL F203288 EPA I63IE U QB-04
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
Notes and Definitions
U Analyte included in the analysis but not detected
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than I times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable ASASD
QB-04 The blank was preserved to 2 BrCl rather than I The control limit for blanks presetved to greater than 1 BrCl is the preservation percentage multiplied by the l1RL
FB-1631 Required equipmentfieldfilter blank not submitted by the client The sample has been analyzed according to 163 lE but does not meet 163 lE criteria
AS This MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
l1RL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to lhe samples analyzedin accordance wirh the chain ofcustody document This analytical report must be reproduced in its entirety
Page 20of20 1203203 Final Report- SWWTF REV2
04042012
24
bull bull
irGl Lu Ull 0111C H AIN-OF-CUSTODY RECORD Page of_~~
Bolo FIELDS REQUIRED P LEASE CIRCLE REQUESTED ANALYs1s Lt) CN voe I svoc TClPI M ETALS INORGANICS
i w I shy i
SAMPLING 0 iii 0 ~
w = ~ DATET1ME QIll c X
w ~sacw 0IF COMPOSITE -gtc ~ u - ~
INDICATE 80TH ~ bulllo- t5a5 START amp FINISH
er Ill liSAMPLE 1 0 i ct -a ~shyDATEITIME l r ~~
bull 7gtItJJJI JWj T ~ tlt
IHAnlX A-Ala S-SOIL GW-GROUHD WATEl SW-SURfACE WATEA DW-DllNIING WAm WW-WAITE WATEl
PWETAJllt H-HCL N-HNO S-HJO Na-NaOHmiddot H-HEOH
i ~~ ~ I ~ X
j i I i= -shy 2 s~ ~ == a~ -shy I t
~~ =~ 2 ~~
~ X a c 2 ~ ~ = -- 2 ~
l j t z i () ~
C 0 5~ s~ = IC 0
C -s ~ = ~ ~e f
0 ~= ~ _sC a ~ C) -shyt( I rt
1 g0
3 i ~-
]-
f~ js~ i
~bull m = olt 1 o(
1 e
j
M ICRO middot-- -shy108420
sshyj
sect= s
~ - I 2lte E55 NOTESili I j HEOHVIAl 6shy ~a 3
I 3 ~ It _ c
1
DATE NEEDED b171i1-1~ 1 f METALS 8 RCRA 13 PP FE MN Ps CUPROJECT MANAGER 0v f-e_~ Tmamp- middotc COMPANY pdegZ1)shy 0THE1 METALS __________REPORTING OPTIONSQAQC ICH) NoAonms Jfru lli V =1 Q ) REPORTING LEVEL PUUHS ~OR No
A B C 0lOLYpoundD METALS FIELD flLTtREDI YE NoIF YE F~ oa(ITT STAil~l4t(= ~ ZIP rriu1 NOTES (IE SPEOAl DETECTION LIHIIS BIWNG INFO IF D1mam)PHONE _r~ _z31_ - $ I3 Exr--- OR ELECTRONIC OPTIONSFAX _ __________________ AI l A C J C bull C1
J pbNo FAX E-MAIL PDF EQUIS
E-MAIL tivl el qu ~ pv CvVshyf J --~b Mo ~ tJ k ttJ -z~Sm NAHE W
PROJECT ____________ ___ ___ _ ~111216- aJd M fer P4 jgtZJ)shy
SUTt MA ME VT OTHER _____ ___ ~ 1)--U ( u-middotmiddottut-UJ f bull
REGULATORY PROGRAM NPDES RGP POnY STOilKWATER Ol SITE HISTORY ~i tiT f=
GWP OIL FUND BROWNFJUD OR Orm--------shy RELINQUISHED BY DATE TIME RECEIVED Br Summo (ONTAHINATIOM_______
PO_______QUOTE===-~----shy I RELINQUISHED BY DATE TIME Rmmo BT I FIElllJUDINGStt HI l lS 2
eastern analytical inc 2s CHENELl DR1ve I CoNcoRo NH 03301 I TEL 60322sos2s I 1soo2s7os2s IFAXc 6032284591 I E-MA1l cusToMER_seRv1ceEA1LAascoHj wwweA1lAsscoM
prufmin111ll11bomtory1m1im (WHITE ORIGINAL GREEN PROJECT MANAGER)
shy
shy
middot
I
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SC IE NC ES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPO
Batch F203288 Sequence 2C22016
Preparation BrCI Oxidation Lab Number F203288-BSBSD I
LCS Source NIST 1641d
Spike LCS LCS Added Concentration Recovery
Analyte (ngL) (ngL) Recovery Limits Method Notes
Mercury 15679 1525 973 80 - 120 EPA l631E
Spike LCSD LCSD Added Concentration Oo Recovery RPD
Analyte (ngL) (ngL)
1516
Recovery
967
RPD
0622
Limits
80 - 120
Limit
24
Method
EPA 1631E
Notes
Mercury 15679
Frontier Global Sciences Inc The results in this report only apply lo the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 16 o20 1203203 Final Report- SWWIFREV2
041042012
20Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 middot Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096 ~ O GLO B AL SCI E NCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2C20001
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203232-BLK1 Aluminum 01 40 microgL F203232 PA2008 Molt u F203232-BLK1 Chromium -0007 0 10 microgL F203232 PA 2008 Molt u F203232-BLKI Manganese 0002 010 microgL F203232 PA 2008 Moc u F203232-BLK1 Iron -004 100 microgL F203232 PA 2008 Molt u F203232-BLKI Nickel 0005 010 microgL F203232 PA 2008 Moc u F203232-BLKI Copper 001 010 microgL F203232 PA 2008 Molt u F203232-BLK1 Zinc 011 020 microgL F203232 PA 2008 Moc u F203232-BLK I Arsenic -0009 015 microgL F203232 PA 2008 Moc u F203232-BLK1 Selenium 025 060 microgL F203232 PA 2008 Moc u F203232-BLK1 Molybdenum 001 006 microgL F203232 PA 2008 Moc u F203232-BLK1 Silver -00009 0020 microgL F203232 PA 2008 Moc u F203232-BLK1 Cadmium 0002 0020 microgL F203232 PA 2008 Molt u F203232-BLK1 Lead 0024 0040 microgL F203232 PA 2008 Molt u
middoti
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordonce with the chain ofcustody document Tnts analytical rtport must be reproduced In its enlfrtty
Page7of20 J203203 Final ampport-SWWTF REV2
04042012
Liz Siska Project Manager 21
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 FRONTIER~ Fx 425-686-3096 GLOBAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2C22001
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203260-BLK1 Molybdenum 001 006 microgL F203260 ~PA 2008 Moc u
Frontier Global Sciences Inc middot The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 18of20 1203203 Final Report- SWWTFREV2
04042012
Liz Siska Project Manager 22
~ CLOSAL SCIENCES
~
J1720 North Creek Parkway North Suite 400 Bothell WA 980 l l
Ph 425-686-1996 Fx 425-686-3096
PREPARATION BLANKS
Instrument Hg-17 Sequence 2C22016
Preparation BrCI Oxidation
The results in Ihis report only apply to the samples analyzed i12 accordance with the chain ofcustody dccumnt This analytical report must be reproductd in ils enJirety
Page I9oj20 1203203 Final Report- SWWTF REJ2
04042012
Frontier Global Sciences Inc
bull 23bull Liz Siska Project Manager
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203288-BLKl Mercury 007 050 ngL F203288 EPA 1631E u F203288-BLIlt2 Mercury 006 050 ngL F203288 EPA 163lE u F203288-BLK3 Mercury 006 050 ngL F203288 EPA I63lE u F203288-BLK4 Mercury 018 050 ngL F203288 EPA I63IE U QB-04
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
Notes and Definitions
U Analyte included in the analysis but not detected
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than I times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable ASASD
QB-04 The blank was preserved to 2 BrCl rather than I The control limit for blanks presetved to greater than 1 BrCl is the preservation percentage multiplied by the l1RL
FB-1631 Required equipmentfieldfilter blank not submitted by the client The sample has been analyzed according to 163 lE but does not meet 163 lE criteria
AS This MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
l1RL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to lhe samples analyzedin accordance wirh the chain ofcustody document This analytical report must be reproduced in its entirety
Page 20of20 1203203 Final Report- SWWTF REV2
04042012
24
bull bull
irGl Lu Ull 0111C H AIN-OF-CUSTODY RECORD Page of_~~
Bolo FIELDS REQUIRED P LEASE CIRCLE REQUESTED ANALYs1s Lt) CN voe I svoc TClPI M ETALS INORGANICS
i w I shy i
SAMPLING 0 iii 0 ~
w = ~ DATET1ME QIll c X
w ~sacw 0IF COMPOSITE -gtc ~ u - ~
INDICATE 80TH ~ bulllo- t5a5 START amp FINISH
er Ill liSAMPLE 1 0 i ct -a ~shyDATEITIME l r ~~
bull 7gtItJJJI JWj T ~ tlt
IHAnlX A-Ala S-SOIL GW-GROUHD WATEl SW-SURfACE WATEA DW-DllNIING WAm WW-WAITE WATEl
PWETAJllt H-HCL N-HNO S-HJO Na-NaOHmiddot H-HEOH
i ~~ ~ I ~ X
j i I i= -shy 2 s~ ~ == a~ -shy I t
~~ =~ 2 ~~
~ X a c 2 ~ ~ = -- 2 ~
l j t z i () ~
C 0 5~ s~ = IC 0
C -s ~ = ~ ~e f
0 ~= ~ _sC a ~ C) -shyt( I rt
1 g0
3 i ~-
]-
f~ js~ i
~bull m = olt 1 o(
1 e
j
M ICRO middot-- -shy108420
sshyj
sect= s
~ - I 2lte E55 NOTESili I j HEOHVIAl 6shy ~a 3
I 3 ~ It _ c
1
DATE NEEDED b171i1-1~ 1 f METALS 8 RCRA 13 PP FE MN Ps CUPROJECT MANAGER 0v f-e_~ Tmamp- middotc COMPANY pdegZ1)shy 0THE1 METALS __________REPORTING OPTIONSQAQC ICH) NoAonms Jfru lli V =1 Q ) REPORTING LEVEL PUUHS ~OR No
A B C 0lOLYpoundD METALS FIELD flLTtREDI YE NoIF YE F~ oa(ITT STAil~l4t(= ~ ZIP rriu1 NOTES (IE SPEOAl DETECTION LIHIIS BIWNG INFO IF D1mam)PHONE _r~ _z31_ - $ I3 Exr--- OR ELECTRONIC OPTIONSFAX _ __________________ AI l A C J C bull C1
J pbNo FAX E-MAIL PDF EQUIS
E-MAIL tivl el qu ~ pv CvVshyf J --~b Mo ~ tJ k ttJ -z~Sm NAHE W
PROJECT ____________ ___ ___ _ ~111216- aJd M fer P4 jgtZJ)shy
SUTt MA ME VT OTHER _____ ___ ~ 1)--U ( u-middotmiddottut-UJ f bull
REGULATORY PROGRAM NPDES RGP POnY STOilKWATER Ol SITE HISTORY ~i tiT f=
GWP OIL FUND BROWNFJUD OR Orm--------shy RELINQUISHED BY DATE TIME RECEIVED Br Summo (ONTAHINATIOM_______
PO_______QUOTE===-~----shy I RELINQUISHED BY DATE TIME Rmmo BT I FIElllJUDINGStt HI l lS 2
eastern analytical inc 2s CHENELl DR1ve I CoNcoRo NH 03301 I TEL 60322sos2s I 1soo2s7os2s IFAXc 6032284591 I E-MA1l cusToMER_seRv1ceEA1LAascoHj wwweA1lAsscoM
prufmin111ll11bomtory1m1im (WHITE ORIGINAL GREEN PROJECT MANAGER)
shy
shy
11720 North Creek Parkway North Suite 400 middot Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096 ~ O GLO B AL SCI E NCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2C20001
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203232-BLK1 Aluminum 01 40 microgL F203232 PA2008 Molt u F203232-BLK1 Chromium -0007 0 10 microgL F203232 PA 2008 Molt u F203232-BLKI Manganese 0002 010 microgL F203232 PA 2008 Moc u F203232-BLK1 Iron -004 100 microgL F203232 PA 2008 Molt u F203232-BLKI Nickel 0005 010 microgL F203232 PA 2008 Moc u F203232-BLKI Copper 001 010 microgL F203232 PA 2008 Molt u F203232-BLK1 Zinc 011 020 microgL F203232 PA 2008 Moc u F203232-BLK I Arsenic -0009 015 microgL F203232 PA 2008 Moc u F203232-BLK1 Selenium 025 060 microgL F203232 PA 2008 Moc u F203232-BLK1 Molybdenum 001 006 microgL F203232 PA 2008 Moc u F203232-BLK1 Silver -00009 0020 microgL F203232 PA 2008 Moc u F203232-BLK1 Cadmium 0002 0020 microgL F203232 PA 2008 Molt u F203232-BLK1 Lead 0024 0040 microgL F203232 PA 2008 Molt u
middoti
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordonce with the chain ofcustody document Tnts analytical rtport must be reproduced In its enlfrtty
Page7of20 J203203 Final ampport-SWWTF REV2
04042012
Liz Siska Project Manager 21
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 FRONTIER~ Fx 425-686-3096 GLOBAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2C22001
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203260-BLK1 Molybdenum 001 006 microgL F203260 ~PA 2008 Moc u
Frontier Global Sciences Inc middot The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 18of20 1203203 Final Report- SWWTFREV2
04042012
Liz Siska Project Manager 22
~ CLOSAL SCIENCES
~
J1720 North Creek Parkway North Suite 400 Bothell WA 980 l l
Ph 425-686-1996 Fx 425-686-3096
PREPARATION BLANKS
Instrument Hg-17 Sequence 2C22016
Preparation BrCI Oxidation
The results in Ihis report only apply to the samples analyzed i12 accordance with the chain ofcustody dccumnt This analytical report must be reproductd in ils enJirety
Page I9oj20 1203203 Final Report- SWWTF REJ2
04042012
Frontier Global Sciences Inc
bull 23bull Liz Siska Project Manager
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203288-BLKl Mercury 007 050 ngL F203288 EPA 1631E u F203288-BLIlt2 Mercury 006 050 ngL F203288 EPA 163lE u F203288-BLK3 Mercury 006 050 ngL F203288 EPA I63lE u F203288-BLK4 Mercury 018 050 ngL F203288 EPA I63IE U QB-04
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
Notes and Definitions
U Analyte included in the analysis but not detected
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than I times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable ASASD
QB-04 The blank was preserved to 2 BrCl rather than I The control limit for blanks presetved to greater than 1 BrCl is the preservation percentage multiplied by the l1RL
FB-1631 Required equipmentfieldfilter blank not submitted by the client The sample has been analyzed according to 163 lE but does not meet 163 lE criteria
AS This MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
l1RL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to lhe samples analyzedin accordance wirh the chain ofcustody document This analytical report must be reproduced in its entirety
Page 20of20 1203203 Final Report- SWWTF REV2
04042012
24
bull bull
irGl Lu Ull 0111C H AIN-OF-CUSTODY RECORD Page of_~~
Bolo FIELDS REQUIRED P LEASE CIRCLE REQUESTED ANALYs1s Lt) CN voe I svoc TClPI M ETALS INORGANICS
i w I shy i
SAMPLING 0 iii 0 ~
w = ~ DATET1ME QIll c X
w ~sacw 0IF COMPOSITE -gtc ~ u - ~
INDICATE 80TH ~ bulllo- t5a5 START amp FINISH
er Ill liSAMPLE 1 0 i ct -a ~shyDATEITIME l r ~~
bull 7gtItJJJI JWj T ~ tlt
IHAnlX A-Ala S-SOIL GW-GROUHD WATEl SW-SURfACE WATEA DW-DllNIING WAm WW-WAITE WATEl
PWETAJllt H-HCL N-HNO S-HJO Na-NaOHmiddot H-HEOH
i ~~ ~ I ~ X
j i I i= -shy 2 s~ ~ == a~ -shy I t
~~ =~ 2 ~~
~ X a c 2 ~ ~ = -- 2 ~
l j t z i () ~
C 0 5~ s~ = IC 0
C -s ~ = ~ ~e f
0 ~= ~ _sC a ~ C) -shyt( I rt
1 g0
3 i ~-
]-
f~ js~ i
~bull m = olt 1 o(
1 e
j
M ICRO middot-- -shy108420
sshyj
sect= s
~ - I 2lte E55 NOTESili I j HEOHVIAl 6shy ~a 3
I 3 ~ It _ c
1
DATE NEEDED b171i1-1~ 1 f METALS 8 RCRA 13 PP FE MN Ps CUPROJECT MANAGER 0v f-e_~ Tmamp- middotc COMPANY pdegZ1)shy 0THE1 METALS __________REPORTING OPTIONSQAQC ICH) NoAonms Jfru lli V =1 Q ) REPORTING LEVEL PUUHS ~OR No
A B C 0lOLYpoundD METALS FIELD flLTtREDI YE NoIF YE F~ oa(ITT STAil~l4t(= ~ ZIP rriu1 NOTES (IE SPEOAl DETECTION LIHIIS BIWNG INFO IF D1mam)PHONE _r~ _z31_ - $ I3 Exr--- OR ELECTRONIC OPTIONSFAX _ __________________ AI l A C J C bull C1
J pbNo FAX E-MAIL PDF EQUIS
E-MAIL tivl el qu ~ pv CvVshyf J --~b Mo ~ tJ k ttJ -z~Sm NAHE W
PROJECT ____________ ___ ___ _ ~111216- aJd M fer P4 jgtZJ)shy
SUTt MA ME VT OTHER _____ ___ ~ 1)--U ( u-middotmiddottut-UJ f bull
REGULATORY PROGRAM NPDES RGP POnY STOilKWATER Ol SITE HISTORY ~i tiT f=
GWP OIL FUND BROWNFJUD OR Orm--------shy RELINQUISHED BY DATE TIME RECEIVED Br Summo (ONTAHINATIOM_______
PO_______QUOTE===-~----shy I RELINQUISHED BY DATE TIME Rmmo BT I FIElllJUDINGStt HI l lS 2
eastern analytical inc 2s CHENELl DR1ve I CoNcoRo NH 03301 I TEL 60322sos2s I 1soo2s7os2s IFAXc 6032284591 I E-MA1l cusToMER_seRv1ceEA1LAascoHj wwweA1lAsscoM
prufmin111ll11bomtory1m1im (WHITE ORIGINAL GREEN PROJECT MANAGER)
shy
shy
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 FRONTIER~ Fx 425-686-3096 GLOBAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2C22001
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203260-BLK1 Molybdenum 001 006 microgL F203260 ~PA 2008 Moc u
Frontier Global Sciences Inc middot The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 18of20 1203203 Final Report- SWWTFREV2
04042012
Liz Siska Project Manager 22
~ CLOSAL SCIENCES
~
J1720 North Creek Parkway North Suite 400 Bothell WA 980 l l
Ph 425-686-1996 Fx 425-686-3096
PREPARATION BLANKS
Instrument Hg-17 Sequence 2C22016
Preparation BrCI Oxidation
The results in Ihis report only apply to the samples analyzed i12 accordance with the chain ofcustody dccumnt This analytical report must be reproductd in ils enJirety
Page I9oj20 1203203 Final Report- SWWTF REJ2
04042012
Frontier Global Sciences Inc
bull 23bull Liz Siska Project Manager
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203288-BLKl Mercury 007 050 ngL F203288 EPA 1631E u F203288-BLIlt2 Mercury 006 050 ngL F203288 EPA 163lE u F203288-BLK3 Mercury 006 050 ngL F203288 EPA I63lE u F203288-BLK4 Mercury 018 050 ngL F203288 EPA I63IE U QB-04
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
Notes and Definitions
U Analyte included in the analysis but not detected
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than I times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable ASASD
QB-04 The blank was preserved to 2 BrCl rather than I The control limit for blanks presetved to greater than 1 BrCl is the preservation percentage multiplied by the l1RL
FB-1631 Required equipmentfieldfilter blank not submitted by the client The sample has been analyzed according to 163 lE but does not meet 163 lE criteria
AS This MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
l1RL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to lhe samples analyzedin accordance wirh the chain ofcustody document This analytical report must be reproduced in its entirety
Page 20of20 1203203 Final Report- SWWTF REV2
04042012
24
bull bull
irGl Lu Ull 0111C H AIN-OF-CUSTODY RECORD Page of_~~
Bolo FIELDS REQUIRED P LEASE CIRCLE REQUESTED ANALYs1s Lt) CN voe I svoc TClPI M ETALS INORGANICS
i w I shy i
SAMPLING 0 iii 0 ~
w = ~ DATET1ME QIll c X
w ~sacw 0IF COMPOSITE -gtc ~ u - ~
INDICATE 80TH ~ bulllo- t5a5 START amp FINISH
er Ill liSAMPLE 1 0 i ct -a ~shyDATEITIME l r ~~
bull 7gtItJJJI JWj T ~ tlt
IHAnlX A-Ala S-SOIL GW-GROUHD WATEl SW-SURfACE WATEA DW-DllNIING WAm WW-WAITE WATEl
PWETAJllt H-HCL N-HNO S-HJO Na-NaOHmiddot H-HEOH
i ~~ ~ I ~ X
j i I i= -shy 2 s~ ~ == a~ -shy I t
~~ =~ 2 ~~
~ X a c 2 ~ ~ = -- 2 ~
l j t z i () ~
C 0 5~ s~ = IC 0
C -s ~ = ~ ~e f
0 ~= ~ _sC a ~ C) -shyt( I rt
1 g0
3 i ~-
]-
f~ js~ i
~bull m = olt 1 o(
1 e
j
M ICRO middot-- -shy108420
sshyj
sect= s
~ - I 2lte E55 NOTESili I j HEOHVIAl 6shy ~a 3
I 3 ~ It _ c
1
DATE NEEDED b171i1-1~ 1 f METALS 8 RCRA 13 PP FE MN Ps CUPROJECT MANAGER 0v f-e_~ Tmamp- middotc COMPANY pdegZ1)shy 0THE1 METALS __________REPORTING OPTIONSQAQC ICH) NoAonms Jfru lli V =1 Q ) REPORTING LEVEL PUUHS ~OR No
A B C 0lOLYpoundD METALS FIELD flLTtREDI YE NoIF YE F~ oa(ITT STAil~l4t(= ~ ZIP rriu1 NOTES (IE SPEOAl DETECTION LIHIIS BIWNG INFO IF D1mam)PHONE _r~ _z31_ - $ I3 Exr--- OR ELECTRONIC OPTIONSFAX _ __________________ AI l A C J C bull C1
J pbNo FAX E-MAIL PDF EQUIS
E-MAIL tivl el qu ~ pv CvVshyf J --~b Mo ~ tJ k ttJ -z~Sm NAHE W
PROJECT ____________ ___ ___ _ ~111216- aJd M fer P4 jgtZJ)shy
SUTt MA ME VT OTHER _____ ___ ~ 1)--U ( u-middotmiddottut-UJ f bull
REGULATORY PROGRAM NPDES RGP POnY STOilKWATER Ol SITE HISTORY ~i tiT f=
GWP OIL FUND BROWNFJUD OR Orm--------shy RELINQUISHED BY DATE TIME RECEIVED Br Summo (ONTAHINATIOM_______
PO_______QUOTE===-~----shy I RELINQUISHED BY DATE TIME Rmmo BT I FIElllJUDINGStt HI l lS 2
eastern analytical inc 2s CHENELl DR1ve I CoNcoRo NH 03301 I TEL 60322sos2s I 1soo2s7os2s IFAXc 6032284591 I E-MA1l cusToMER_seRv1ceEA1LAascoHj wwweA1lAsscoM
prufmin111ll11bomtory1m1im (WHITE ORIGINAL GREEN PROJECT MANAGER)
shy
shy
~ CLOSAL SCIENCES
~
J1720 North Creek Parkway North Suite 400 Bothell WA 980 l l
Ph 425-686-1996 Fx 425-686-3096
PREPARATION BLANKS
Instrument Hg-17 Sequence 2C22016
Preparation BrCI Oxidation
The results in Ihis report only apply to the samples analyzed i12 accordance with the chain ofcustody dccumnt This analytical report must be reproductd in ils enJirety
Page I9oj20 1203203 Final Report- SWWTF REJ2
04042012
Frontier Global Sciences Inc
bull 23bull Liz Siska Project Manager
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203288-BLKl Mercury 007 050 ngL F203288 EPA 1631E u F203288-BLIlt2 Mercury 006 050 ngL F203288 EPA 163lE u F203288-BLK3 Mercury 006 050 ngL F203288 EPA I63lE u F203288-BLK4 Mercury 018 050 ngL F203288 EPA I63IE U QB-04
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
Notes and Definitions
U Analyte included in the analysis but not detected
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than I times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable ASASD
QB-04 The blank was preserved to 2 BrCl rather than I The control limit for blanks presetved to greater than 1 BrCl is the preservation percentage multiplied by the l1RL
FB-1631 Required equipmentfieldfilter blank not submitted by the client The sample has been analyzed according to 163 lE but does not meet 163 lE criteria
AS This MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
l1RL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to lhe samples analyzedin accordance wirh the chain ofcustody document This analytical report must be reproduced in its entirety
Page 20of20 1203203 Final Report- SWWTF REV2
04042012
24
bull bull
irGl Lu Ull 0111C H AIN-OF-CUSTODY RECORD Page of_~~
Bolo FIELDS REQUIRED P LEASE CIRCLE REQUESTED ANALYs1s Lt) CN voe I svoc TClPI M ETALS INORGANICS
i w I shy i
SAMPLING 0 iii 0 ~
w = ~ DATET1ME QIll c X
w ~sacw 0IF COMPOSITE -gtc ~ u - ~
INDICATE 80TH ~ bulllo- t5a5 START amp FINISH
er Ill liSAMPLE 1 0 i ct -a ~shyDATEITIME l r ~~
bull 7gtItJJJI JWj T ~ tlt
IHAnlX A-Ala S-SOIL GW-GROUHD WATEl SW-SURfACE WATEA DW-DllNIING WAm WW-WAITE WATEl
PWETAJllt H-HCL N-HNO S-HJO Na-NaOHmiddot H-HEOH
i ~~ ~ I ~ X
j i I i= -shy 2 s~ ~ == a~ -shy I t
~~ =~ 2 ~~
~ X a c 2 ~ ~ = -- 2 ~
l j t z i () ~
C 0 5~ s~ = IC 0
C -s ~ = ~ ~e f
0 ~= ~ _sC a ~ C) -shyt( I rt
1 g0
3 i ~-
]-
f~ js~ i
~bull m = olt 1 o(
1 e
j
M ICRO middot-- -shy108420
sshyj
sect= s
~ - I 2lte E55 NOTESili I j HEOHVIAl 6shy ~a 3
I 3 ~ It _ c
1
DATE NEEDED b171i1-1~ 1 f METALS 8 RCRA 13 PP FE MN Ps CUPROJECT MANAGER 0v f-e_~ Tmamp- middotc COMPANY pdegZ1)shy 0THE1 METALS __________REPORTING OPTIONSQAQC ICH) NoAonms Jfru lli V =1 Q ) REPORTING LEVEL PUUHS ~OR No
A B C 0lOLYpoundD METALS FIELD flLTtREDI YE NoIF YE F~ oa(ITT STAil~l4t(= ~ ZIP rriu1 NOTES (IE SPEOAl DETECTION LIHIIS BIWNG INFO IF D1mam)PHONE _r~ _z31_ - $ I3 Exr--- OR ELECTRONIC OPTIONSFAX _ __________________ AI l A C J C bull C1
J pbNo FAX E-MAIL PDF EQUIS
E-MAIL tivl el qu ~ pv CvVshyf J --~b Mo ~ tJ k ttJ -z~Sm NAHE W
PROJECT ____________ ___ ___ _ ~111216- aJd M fer P4 jgtZJ)shy
SUTt MA ME VT OTHER _____ ___ ~ 1)--U ( u-middotmiddottut-UJ f bull
REGULATORY PROGRAM NPDES RGP POnY STOilKWATER Ol SITE HISTORY ~i tiT f=
GWP OIL FUND BROWNFJUD OR Orm--------shy RELINQUISHED BY DATE TIME RECEIVED Br Summo (ONTAHINATIOM_______
PO_______QUOTE===-~----shy I RELINQUISHED BY DATE TIME Rmmo BT I FIElllJUDINGStt HI l lS 2
eastern analytical inc 2s CHENELl DR1ve I CoNcoRo NH 03301 I TEL 60322sos2s I 1soo2s7os2s IFAXc 6032284591 I E-MA1l cusToMER_seRv1ceEA1LAascoHj wwweA1lAsscoM
prufmin111ll11bomtory1m1im (WHITE ORIGINAL GREEN PROJECT MANAGER)
shy
shy
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
Notes and Definitions
U Analyte included in the analysis but not detected
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than I times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable ASASD
QB-04 The blank was preserved to 2 BrCl rather than I The control limit for blanks presetved to greater than 1 BrCl is the preservation percentage multiplied by the l1RL
FB-1631 Required equipmentfieldfilter blank not submitted by the client The sample has been analyzed according to 163 lE but does not meet 163 lE criteria
AS This MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
l1RL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to lhe samples analyzedin accordance wirh the chain ofcustody document This analytical report must be reproduced in its entirety
Page 20of20 1203203 Final Report- SWWTF REV2
04042012
24
bull bull
irGl Lu Ull 0111C H AIN-OF-CUSTODY RECORD Page of_~~
Bolo FIELDS REQUIRED P LEASE CIRCLE REQUESTED ANALYs1s Lt) CN voe I svoc TClPI M ETALS INORGANICS
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DATE NEEDED b171i1-1~ 1 f METALS 8 RCRA 13 PP FE MN Ps CUPROJECT MANAGER 0v f-e_~ Tmamp- middotc COMPANY pdegZ1)shy 0THE1 METALS __________REPORTING OPTIONSQAQC ICH) NoAonms Jfru lli V =1 Q ) REPORTING LEVEL PUUHS ~OR No
A B C 0lOLYpoundD METALS FIELD flLTtREDI YE NoIF YE F~ oa(ITT STAil~l4t(= ~ ZIP rriu1 NOTES (IE SPEOAl DETECTION LIHIIS BIWNG INFO IF D1mam)PHONE _r~ _z31_ - $ I3 Exr--- OR ELECTRONIC OPTIONSFAX _ __________________ AI l A C J C bull C1
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E-MAIL tivl el qu ~ pv CvVshyf J --~b Mo ~ tJ k ttJ -z~Sm NAHE W
PROJECT ____________ ___ ___ _ ~111216- aJd M fer P4 jgtZJ)shy
SUTt MA ME VT OTHER _____ ___ ~ 1)--U ( u-middotmiddottut-UJ f bull
REGULATORY PROGRAM NPDES RGP POnY STOilKWATER Ol SITE HISTORY ~i tiT f=
GWP OIL FUND BROWNFJUD OR Orm--------shy RELINQUISHED BY DATE TIME RECEIVED Br Summo (ONTAHINATIOM_______
PO_______QUOTE===-~----shy I RELINQUISHED BY DATE TIME Rmmo BT I FIElllJUDINGStt HI l lS 2
eastern analytical inc 2s CHENELl DR1ve I CoNcoRo NH 03301 I TEL 60322sos2s I 1soo2s7os2s IFAXc 6032284591 I E-MA1l cusToMER_seRv1ceEA1LAascoHj wwweA1lAsscoM
prufmin111ll11bomtory1m1im (WHITE ORIGINAL GREEN PROJECT MANAGER)
shy
shy
bull bull
irGl Lu Ull 0111C H AIN-OF-CUSTODY RECORD Page of_~~
Bolo FIELDS REQUIRED P LEASE CIRCLE REQUESTED ANALYs1s Lt) CN voe I svoc TClPI M ETALS INORGANICS
i w I shy i
SAMPLING 0 iii 0 ~
w = ~ DATET1ME QIll c X
w ~sacw 0IF COMPOSITE -gtc ~ u - ~
INDICATE 80TH ~ bulllo- t5a5 START amp FINISH
er Ill liSAMPLE 1 0 i ct -a ~shyDATEITIME l r ~~
bull 7gtItJJJI JWj T ~ tlt
IHAnlX A-Ala S-SOIL GW-GROUHD WATEl SW-SURfACE WATEA DW-DllNIING WAm WW-WAITE WATEl
PWETAJllt H-HCL N-HNO S-HJO Na-NaOHmiddot H-HEOH
i ~~ ~ I ~ X
j i I i= -shy 2 s~ ~ == a~ -shy I t
~~ =~ 2 ~~
~ X a c 2 ~ ~ = -- 2 ~
l j t z i () ~
C 0 5~ s~ = IC 0
C -s ~ = ~ ~e f
0 ~= ~ _sC a ~ C) -shyt( I rt
1 g0
3 i ~-
]-
f~ js~ i
~bull m = olt 1 o(
1 e
j
M ICRO middot-- -shy108420
sshyj
sect= s
~ - I 2lte E55 NOTESili I j HEOHVIAl 6shy ~a 3
I 3 ~ It _ c
1
DATE NEEDED b171i1-1~ 1 f METALS 8 RCRA 13 PP FE MN Ps CUPROJECT MANAGER 0v f-e_~ Tmamp- middotc COMPANY pdegZ1)shy 0THE1 METALS __________REPORTING OPTIONSQAQC ICH) NoAonms Jfru lli V =1 Q ) REPORTING LEVEL PUUHS ~OR No
A B C 0lOLYpoundD METALS FIELD flLTtREDI YE NoIF YE F~ oa(ITT STAil~l4t(= ~ ZIP rriu1 NOTES (IE SPEOAl DETECTION LIHIIS BIWNG INFO IF D1mam)PHONE _r~ _z31_ - $ I3 Exr--- OR ELECTRONIC OPTIONSFAX _ __________________ AI l A C J C bull C1
J pbNo FAX E-MAIL PDF EQUIS
E-MAIL tivl el qu ~ pv CvVshyf J --~b Mo ~ tJ k ttJ -z~Sm NAHE W
PROJECT ____________ ___ ___ _ ~111216- aJd M fer P4 jgtZJ)shy
SUTt MA ME VT OTHER _____ ___ ~ 1)--U ( u-middotmiddottut-UJ f bull
REGULATORY PROGRAM NPDES RGP POnY STOilKWATER Ol SITE HISTORY ~i tiT f=
GWP OIL FUND BROWNFJUD OR Orm--------shy RELINQUISHED BY DATE TIME RECEIVED Br Summo (ONTAHINATIOM_______
PO_______QUOTE===-~----shy I RELINQUISHED BY DATE TIME Rmmo BT I FIElllJUDINGStt HI l lS 2
eastern analytical inc 2s CHENELl DR1ve I CoNcoRo NH 03301 I TEL 60322sos2s I 1soo2s7os2s IFAXc 6032284591 I E-MA1l cusToMER_seRv1ceEA1LAascoHj wwweA1lAsscoM
prufmin111ll11bomtory1m1im (WHITE ORIGINAL GREEN PROJECT MANAGER)
shy
shy