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    Evaluation of Quality Management Systems and TechnicalStandardization Fundamental to the Solar Photovoltaic Industry

    Agatha Christy Sonma Okoro

    Electrical and Computer Engineering

    Jacobs University Bremen

    College Ring 6

    28759 Bremen, Germany

    Type: Guided Research Thesis

    Submitted to the School of Engineering and Sciences in partial fulfillment of the requirements for the

    degree of Bachelor of Science in Electrical and Computer Engineering

    Date: May 9, 2010Supervisor: Prof. Dr. Werner Bergholz

    Executive Summary

    As an important renewable energy resource, photovoltaic (PV) solar is rapidly gaining worldwide attention

    with increased growth and global expansion. At this stage the industry needs to develop and adopt its own

    quality and technical standards. Major industry players have already obtained the ISO 9001 certification for

    fulfilling requirements of a quality management system developed by the International Organization forStandardization (ISO)

    [1]. However certification alone is not sufficient. Manufacturers need perform a period

    audit of their suppliers processes and quality management system, rather than just inspecting incoming

    material. In addition to this, carrying out inline-process control will help ensure quality of the final product.

    Furthermore, standardization is very critical for the industry as it will facilitate significant improvements

    along the whole value chain including important areas such as material qualifications, test methods, process

    automation and information technology interfaces. The PV industry hardly uses any standards except those

    of the semiconductor industry which is not always suitable. Although the two industries have similar

    processes, in some cases the standards for semiconductor manufacturing are beyond what is required for

    PV, which contributes to unnecessary costs for manufacturers. This research investigates how quality

    management systems (QMS) and standards will help to effectively control quality and manage processes in

    the industry. It goes without saying that a global standard for PV companies will help reduce costs,

    improve product quality and enhance further market expansion. Moreover, it will foster fair and transparent

    competition and increase satisfaction for customers and other stakeholders of the industry.

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    Table of Contents

    1. Introduction ................................................................................................................................. 22. Statement of Motivation and Research ......................................................................................... 33. Process Management and Operation Procedures ........................................................................... 44. Supplier Quality Management ....................................................................................................... 5

    4.1 Material Suppliers and Procurement Specification ......................................................................... 75. Production Processes in Crystalline Silicon Photovoltaic Technology .............................................. 7

    5.1 Production of Crystalline Silicon Solar Cells ..................................................................................... 85.2 Module Production and Assembly ................................................................................................. 10

    6. Optimizing and Controlling Processes through Statistical Process Control ..................................... 116.1 Control of Variation ....................................................................................................................... 116.2 Continual Improvement ................................................................................................................. 126.3 Elimination of Waste ...................................................................................................................... 136.4 Predictability of Processes ............................................................................................................. 136.5 Product Inspection ......................................................................................................................... 14

    7. Process Automation and Information Technology (IT) Interfaces .................................................. 148. Quality Issues / Defects in Solar Photovoltaic Cells and Modules .................................................. 15

    8.1 Tests and Measurements to Characterize Cell and Module Performance .................................... 178.2 Quality Data and Reporting ........................................................................................................... 17

    9. Analysis of Quality Management Systems and Processes of PV Companies ................................... 189.1 Overview of Processes and Certifications ...................................................................................... 189.2 Comparison of Electrical Conversion Efficiencies .......................................................................... 209.3 Reliability of PV Modules in the Market ........................................................................................ 23

    10.Conclusion and Recommendations .............................................................................................. 2311.References .................................................................................................................................. 2512.Appendix .................................................................................................................................... 28

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    1 Introduction A photovoltaic system is typically a system that converts sunlight to electricity using cells made of

    semiconductor material. The materials currently being used in photovoltaic technology include crystalline

    silicon (c-Si), amorphous silicon (a-Si), cadmium telluride (CdTe), copper indium selenide (CIS), and

    copper indium gallium (di)selenide (CIGS)[2]

    . These materials are used to manufacture photovoltaic cells

    and modules but they have different levels of energy conversion efficiency. This research will focus on the

    crystalline silicon technology which is currently the most widely used compared to the thin film and hybrid

    technologies.

    There are three main types of crystalline silicon monocrystalline, polycrystalline (or multicrystalline), and

    ribbon sheets[2]

    . The essential generic manufacturing process steps are:

    Silicon crystal growing or casting, and wafering Solar cell manufacture Module assembly Solar system assembly and installation

    Each of these generic steps constitutes several process sequences. The first step involves growing crystals for

    monocrystalline silicon or ingot casting for multicrystalline silicon. These processes are relatively energy

    intensive and the resulting products are called wafers. In the second step, the wafers are taken through a

    high technology semiconductor processing sequence of etching, diffusion and screen printing, to produce

    solar cells. This part of the manufacturing chain is highly capital intensive due to the complexity and scale

    of solar cell plants. Afterwards, the cells are tested and graded for assembly into modules. This usuallyinvolves soldering the cells together and laminating. Finally in the last step using the modules, the solar

    system is assembled and then installed[3]

    .

    Some PV companies specialize in parts of the manufacturing chain while a few others have an integrated

    supply chain. In any case, the processes require quality assurance which ensures that products are

    manufactured and tested according to a specific standard, and that the manufacturing processes includes

    continuous verification, auditing and improvement. However, quality assurance is not limited to the

    production processes; rather it encompasses all organizational functions. Hence the need for PV companies

    to adopt a Quality Management System (QMS) along with technical standards which should be tailor-made

    for the industry. A QMS provides an organization with important tools to assist in improving its internal

    systems for manufacturing products or providing services.

    The project looks into the current status of QM and standardization in the PV industry with the objective of

    identifying the gaps and recommending possible improvements.

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    2 Statement of Motivation and ResearchTodays companies are faced with higher quality expectations than they were a few decades ago, and this

    expectation is particularly going to increase for the PV industry. This project seeks to address some

    problems in the industry such as:

    Insufficient or non-existing process and quality management Insufficient standardization Lack of uniform guidelines for manufacturers on how to produce reliable systems or

    components and how to install or service them[7]

    Lack of accreditation laboratories, which especially affects small and medium sized companies [7] Sometimes tested and accredited product samples are not a true representation of the rest of the

    products which the manufacturers label as same type[7]

    .

    This will be accomplished through the application of ISO 9001:2008 requirements for a QMS. For anorganization it implies the provision of products that meet customer and applicable statutory and regulatory

    requirements, enhancement of customer satisfaction, and including processes for continual improvement of

    the system[1]

    . In addition, other important tools of total quality management (TQM) such as the Six-Sigma

    concept, Demings Cycle, Statistical Process Control (SPC) and Benchmarking will also be applied[4]

    .

    Establishing a QM system can be a challenging task, especially for smaller companies, but the investment is

    well worth it in the long run. The Global Approval Program for Photovoltaics (PV GAP) has developed a

    training manual to help PV companies install a QM system easily, and inexpensively[7]

    . International

    organizations such as the European Photovoltaic Industry Association (EPIA), SEMI PV Group, and the

    International Electrotechnical Commission (IEC), have been working to develop existing standards and

    establish new ones for the industry[5][6]

    . Quality Management extends to environment, health and safety

    (EHS) practices for which standards are also available. However this research will mostly look into the

    technical aspects of QM in PV manufacturing.

    Many experts have commented that PV manufacturing is highly synergistic to the semiconductor industry.

    This synergy has the negative effect of high cost in PV production due to the lack of industry-specific

    standards [8]. Hence, the thesis will also analyze the degree of standardization currently in the industry and

    how further progress will be an essential part of the very much needed cost-reduction in manufacturing.

    Existing quality issues in the industry will be investigated and quality management tools applied as a

    solution to these and other potential problems a PV company may encounter. Reference will be made to

    efforts by SEMI PV, EPIA and other organizations to establish global standards for the PV industry. The

    focus as mentioned earlier will be on the technical standards for crystalline silicon technology production

    operations.

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    3 Process Management and Operation ProceduresThe ISO 9001 standard promotes the process approach of a Quality Management System. The processapproach involves planning, controlling and monitoring the performance of input processes, including the

    interactions between these processes, in order to obtain the desired output. The goal is to make

    improvements in manufacturing processes in order to reduce costs, increase throughput and satisfy

    customer requirements. The customers may also be internal customers at the next stage of the production

    process.

    Figure 1: Model of a Process-Based Quality Management System [9]

    A process-based QMS provides input for management review, assesses the system effectiveness and

    efficiency, and provides insight to process owners [9]. Aside from a QMS, there are other tools and

    techniques which can be applied with the unifying aim of attaining a companys strategic goals. The SIPOC

    diagram below is a tool used to identify all relevant elements of process improvement starting from the

    suppliers, through the processes and then to the customers. It helps in defining a complex project that may

    otherwise not be well scoped[10]

    . An organization must first understand its processes before it can sustain

    continuous improvement.

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    Figure 2: SIPOC - A Six-Sigma Model for Assessing Work Processes

    4 Supplier Quality ManagementThe general increase in average efficiency of solar cells over the years can be attributed partly to a better

    understanding of the interaction between the production processes and material quality. For example, it was

    discovered that a well-chosen diffusion process enhances the material quality due to strong gettering effects

    for impurities. Similarly, the introduction of a suitable silicon nitride (SiN) film as antireflection coating is

    an improvement which also enhances material quality[11]

    . Due to this correlation between quality of input

    materials and the final product, any issues with material supply can lead to major problems at the end of the

    value chain. The cell or module manufacturer is responsible for making sure that incoming materialsconform to required quality and specifications. Hence, it should be incorporated into a companys supply

    chain management objectives.

    Equally important is the mode of operation of the industrys supply chain which affects its efficiency. The

    PV industry mainly functions in a static supply chain mode for controlling material cost and securing the

    material supply with mid-to long-term contracts (Krause & Kleemann, 2009). Other industries, such as the

    automotive, electronics and semiconductor industries have moved to a dynamic and responsive on demand

    supply chain. In this dynamic mode, technical as well as quality responsibilities are transferred into the

    supply chain [12]. The PV industry needs to adopt this in order to achieve better improvement potentials in

    terms of technology, quality, yield and cost. Efficient management of the PV industry supply chain can be a

    useful step towards cost reduction, inventory optimization and quality improvement throughout the value

    chain. Following innovative solutions such as IBMs smart supply chain, the complexity of todays

    marketplace can be managed through integrated transactions (integrating ERPS1

    to ERPS of manufacturers

    to suppliers and then to customers). The smart supply chain is intelligent and enables the optimization of

    the Four Flows: product flow, information flow, people/process or work flow and the cash or financial flow[12]

    .

    Effective feedstock management is critical to any facilitys operational plans. Improper feedstockmanagement can negatively affect the quality of the finished product. At the interface between finished

    products (wafer cell module), incoming materials required for production have to be procured, except

    in the case of integrated manufacturers with an internal supply.

    1ERPS Enterprise Resource Planning Systems, an integrated computer-based system used to manage internal and

    external resources including tangible assets, financial resources, materials, and human resources

    [Bidgoli, Hossein, (2004). The Internet Encyclopedia, Volume 1, John Wiley & Sons, Inc. p. 707.]

    Supplier Input Process Output Customer

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    4.1. Material Suppliers and Procurement SpecificationThe PV silicon which wafer manufacturers use in production comes in a variety of geometries and purities

    obtainable from myriad sources - virgin suppliers, recycle houses, brokers, IC crystal manufacturers and

    internally recycled re-melt[13]

    . Whereas the cell manufacturer purchases materials from suppliers of silicon

    wafers, chemicals, gases, silver and aluminium pastes, etc. The quality requirements of these materials are

    usually laid down by the manufacturer in a technical purchase specification. The specifications are contained

    in a controlled document, with version number and revision history, and signed off between the customer

    and supplier[14]

    . Such specifications may include requirements such as wafer properties (diameter,

    thickness, resistivity, etc.), dopant concentration and chemical purity among others. Changes in material

    properties may necessitate an adjustment in the production process; hence this can have a negative effect on

    the stability of the process. To maintain a stable process, manufacturers are recommended to have only one

    or two suppliers, with more or less constant material properties[14]

    .

    Many PV module manufacturers depend on third party solar cell manufacturers for their supply of silicon

    solar cells. Currently there exists no common, detailed, baseline cell procurement (or supply-chain)

    specification for the industry. The standards that exist cover only performance measurement issues but not

    issues faced by module manufacturers in the cell procurement stage (TamizhMani, 2009). Arizona State

    University Photovoltaic Testing Laboratory (ASU-PTL) conducted a failure-rate analysis which indicated

    that a large portion of the accelerated module qualification failures are related to the failure of the cell itself2

    [15]. This emphasizes a need for standards in supply chain procurement, since reliability of the cells is a core

    factor affecting module reliability and performance. A study report prepared by Govindasamy TamizhMani

    of ASU-PTL gives guidelines for PV c-Si supply chain procurement specification, including parking, labeling

    and storage requirements, and recommends their adaptation to other standards as in IEC and SEMI [15].

    Another necessary action toward ensuring the right quality of materials is for manufacturers to perform a

    periodic audit of the suppliers production process and quality management system. A supplier which

    implements an effective quality management system is better positioned to supply high quality materials

    and products according to specifications, cost and timing. This can be accomplished through appropriate

    supplier development and integration program which will increase confidence in quality of suppliers

    products. Moreover, manufacturers need to be aware of any significant modifications in suppliers materials

    or processes in order to make an appropriate procurement decision.

    5 Production Processes in Crystalline Silicon Photovoltaic TechnologyThe value chain of a manufacturing industry consists of value-adding processes from raw material to

    finished product for the end customer. In the case of the PV industry, the value chain ranges from raw

    2Quantitative information on the correlation of module failures to failure of cells could not be found from the reference

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    silicon up to the final installed module at the customers site, including after -sales activities such as

    maintenance, upgrades, grid management, etc.[12]

    . The solar industry had been known to use material

    rejected by the semiconductor industry. This includes seed and end cones of the crystals, and part of the

    crystals that does not meet specification. However, this scrap is now in short supply since the PV industry is

    growing rapidly. The required starting material is a solar grade polysilicon feedstock produced by the

    Siemens process. Afterwards the polysilicon is processed through slightly different methods to obtainmonocrystalline or multicrystalline silicon.

    a. Monocrystalline silicon The main technique for producing monocrystalline silicon for solar cellsis the Czochralski (CZ) method. High-purity polycrystalline is melted in a quartz crucible and

    single-crystal silicon seed is dipped into this molten mass of polycrystalline. As the seed is pulled

    slowly from the melt, a single-crystal ingot is formed. The ingots are then sawed into thin wafers

    with 150 micrometers (mm) diameter and about 200 - 400 mm thick[16]

    .

    b. Multicrystalline silicon The common method of producing multicrystalline silicon is to slice thinwafers from blocks of cast polycrystalline silicon. This material is stronger and can be cut in to onethird of the thickness of monocrystalline wafers. Hence, multicrystalline cells have lower wafer cost

    and less strict growth requirements[16]

    .

    The final wafers are sorted according to thickness and surface quality suitable for manufacturing solar cells,

    and damaged wafers discarded or reworked to meet specifications.

    5.1. Production of Crystalline Silicon Solar CellsThe first stage in the manufacture of crystalline silicon solar cells is wafer processing. Wafers can be

    processed either in batches (vertical) or inline (horizontal). In batch processing, substrates are loaded in

    carriers and transported into a process station. On the other hand for inline processing, wafers are processed

    in a continuous way in all process stations[17]

    . Inline processing is one of the fastest-growing production

    processes for crystalline silicon solar cells. The advantages is has over the traditional batch processing is that

    it achieves higher overall throughput and an improved manufacturing yield through reduced breakage of

    wafers[18]

    . This is due to the fact that it eliminates several handling steps unique to batch processing

    techniques. The following are unit process steps for solar cell manufacturing:

    Wafer Etching and Cleaning: Etching is a process of removing any crystal damage on the wafers. Wet

    etching uses chemical reagents like hydrogen fluoride/water solution while dry etching makes use of gases.

    Wafers are etched and cleaned to remove all particles, organic and metal impurities adsorbed on the surface

    of the silicon. Wet chemical texturing is applied to roughen the surface for higher currents and thus, higher

    efficiencies[17]

    .

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    Diffusion: In this process a P-N junction is created through doping with ions such as phosphorus, boron

    and arsenic although the most commonly used is phosphorus. A layer of oxide material is grown or

    deposited onto the wafer in a furnace with a flow of gas running over the wafers. Phosphorus is then

    diffused into the surface of p-type silicon wafers, forming a P-N junction. Subsequently, the phosphorus

    silicate glass that is formed as a by-product of the diffusion process is removed in an etch bath[19]

    .

    Silicon Nitride Deposition (Passivation): Silicon nitride layer is deposited to protect the wafers from

    contamination during assembly. This is done through Chemical Vapor Deposition (CVD) or Plasma

    Enhanced Chemical Vapor Deposition (PECVD) process. This layer serves as an antireflection coating and

    reduces the losses in the bulk of the silicon and at front surface (bulk and surface passivation)[17]

    .

    The above processes cause some damages (recombination sites) to the wafers, therefore an additional

    heating (annealing) is performed so that the crystal lattice structure of the wafer will repair itself.

    Screen Printing and Back Metallization: Metallization is a process usually integrated into automatic

    manufacturing lines near the end of the cell fabrication process. Typical solar cells require three screen

    printed layers, the grid on the front side and the aluminum plane and silver busbars on the back. The layer

    is dried before the next print process begins[20]

    . After each layer is printed, the wafer is dried to remove

    solvents and fired in a tunnel furnace at high temperatures of about 900 degrees to sinter metal contacts to

    the cell wafer. This is followed by a laser edge isolation procedure which should be done correctly to avoid a

    linear shunt edge.

    Testing and Sorting: In order to increase productivity in the next process step, the solar cells are usually

    tested and sorted according to efficiency, short circuit current (ISC), open circuit voltage (VOC), and fill

    factor (FF). A solar simulator is used to test each cell under standard testing conditions (STC). The

    manufacturer can identify process-induced defects and defect trends, and utilize this data for yield control,

    process management and improvement of the preceding steps[21]

    .

    Process Step ParametersCrystal growth (Ingot quality) Minority carrier lifetime ()

    Wire sawing Surface roughness / residue

    Incoming wafer quality

    Diffusion length (L) /

    , defect density Wafer etching and cleaning Etch rate, impurity concentration

    Texturing Texture height

    Junction depth Sheet resistance

    Anti-reflective coating Thickness, refractive index

    Metallization Line width

    Table 1: Summary ofMajor Process Steps and Corresponding Quality Parameters [22]

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    5.2. Module Production and AssemblySolar cells are usually categorized into different performance bins in order to reduce mismatch power losses

    in silicon-wafer based photovoltaic modules. This is a common industrial practice and the method is known

    as cell binning. Assembly of the cells into a module involves the following steps: - cell layup, stringing,

    mounting and electrical connection of the cells circuit in the module. Afterwards the module is encapsulated

    usually with encapsulant sheet of transparent polyvinyl butyrol (PVB) or ethylene vinyl acetate (EVA) and

    glass. Back-contact configuration of c-Si PV cells enables assembly using a monolithic module assembly

    (MMA) method where all the PV cells can be electrically connected in a module and encapsulated in a

    single step.

    Figure 3: Illustration of Monolithic Module Assembly[23]Developing cells which have all contacts at the rear and so can be easily interconnected reduces the cost of

    module manufacturing because it makes automation more straightforward. The next step involves framing

    of the modules, usually with aluminium frames. This is followed by standard module qualification tests and

    certification. Finally with the modules and balance of system (BOS)3

    components, the photovoltaic solar

    system is assembled and then installed at the consumer end.

    As mass production in the PV industry grows rapidly, it becomes more and more crucial to implement

    process control and monitoring for better productivity and quality. One means of achieving this is through

    the use of Statistical Process Control.

    3In a photovoltaic system, the term 'balance of system' refers to all of the system components except the PV modules.

    The components consist of structures, enclosures, wiring, switch gear, fuses, ground fault detectors, charge controllers,

    batteries, and inverters. [Source: http://photovoltaics.sandia.gov/docs/BOS.htm]

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    6 Optimizing and Controlling Processes through Statistical Process ControlStatistical Process Control (SPC) is a statistical method of separating variation resulting from special causes

    from variation resulting from natural causes, to eliminate the special causes and to establish and maintain

    consistency in a process, enabling process improvement (Goetsch & Davis, 2006). A broad view of SPC

    includes statistical tools such as Pareto charts, control charts, cause-and-effect diagrams, stratification, check

    sheets, histograms, scatter diagrams, and run charts [4]. Control charts, being at the heart of SPC, are used

    by both companies and their suppliers for processes where they offer real benefit.

    Figure 4: Examples of Processes Without and With SPC (from Infineon training manual) [14]The left graph in the figure above shows a process that, without continuous control, continues to get worse.

    On the other hand, the right hand side shows the graph of a process under control, with constant variations

    only due to the natural causes.

    Five key areas where SPC comes into play are: control of variation, continual improvement, elimination of

    waste, predictability of processes, and product inspection[4]

    .

    6.1. Control of VariationProcess variation is an enemy of quality. SPC uses statistical tools and techniques to control variation in any

    process. Special causes of variation may originate for example from the environment and the five Ms -

    Machines employed, Materials used, Methods (work instructions) provided, Measurements taken, and

    Manpower (people) who operate the process. Natural variation is inherent in any process and is expected to

    account for 2,700 out-of-limits parts per million in a 3-sigma process, 63 out-of-limits parts per million in a

    4-sigma process and 3.4 out-of-limits parts per million in a 6-sigma process[4]

    . Hence, more companies are

    moving to a 6-sigma process (see appendix) to achieve better performance.

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    Figure 5: Sigma Levels and Equivalent Conformance Rates [24]In figure 5 above, the target value is at the center of the bell-shaped frequency distribution curve and any

    variation is to the left or right of the center. A 3-sigma quality level (3 limits) translates to a yield of

    99.73% while a 6-sigma quality level (6) implies a success rate of 99.99999998%[4]

    . The process

    parameters for which variation must be controlled around the target value are the Key Control

    Characteristics (KCCs). They include parameters such as temperature, humidity, particle density, etc. The

    method of Key Characteristics helps companies focus on those features that have a significant impact on

    product conformity[25]

    .

    6.2. Continual ImprovementThis is a major element of total quality through which the improvement of processes can lead to animprovement of products and services. Improving a process requires understanding the process, identifying

    external factors that may generate special causes of variation and eliminating them. However, care must be

    taken to avoid tampering with the process and making changes that could yield worse results.

    Figure 6:PDCA/Demings Cycle: The Wheel of Continual Improvement

    Plan

    Do

    Check

    Act

    USL = Upper Specification Limit

    LSL = Lower Specification Limit

    = Standard Deviation

    = Mean

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    6.3. Elimination of WasteDuring production, defective products or products that do not meet specification are discarded as scrap.

    Therefore, production performance indicators such as rework rate and scrap rate4

    have to be monitored and

    kept at bare minimum. SPC is a key to eliminating such waste so that a company can reduce cost and

    increase the overall quality of process output.

    6.4. Predictability of ProcessesSPC facilitates the predictability of processes since they will be under control. Companies that implement

    SPC will be better able to know whether or not their process is capable of meeting customers requirements.

    The process capability parameters are described below:

    Process Capability, Cp: a straightforward indicator of process capability

    Figure 7: Natural Distribution Fit within Defined Specification Limits [26]In figure 7 above, processes (a) and (b) have Cp greater than 1, (c) is equal to 1 and (d) is less than 1

    [26].

    Process Capability Index, Cpk: an adjustment of Cp for the effect of non-centered distribution.

    A Cpk value less than 1 indicates that the process is incapable, between 1 and 3 indicates a capable process,

    whereas values greater than 3 show that the process is very capable[26]

    .

    4Rework rate is the percentage of defective products re-processed to meet requirements while scrap rate is the

    percentage of defective products that are discarded.

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    6.5. Product InspectionInspection is performed on products during manufacturing (in-process inspection) and as finished goods

    (final inspection). Inspection costs money, time, equipment and labor. It will be unrealistic to have a 100%

    inspection of all products in a large scale manufacturing firm such as in the PV where millions of wafers

    and solar cells are produced per year. Therefore products are usually sampled for inspection. The ISO 2859

    standard gives detailed sampling procedures for tests and inspections [1].But for sampling to be accepted,

    the process must be under control. If a suppliers process is under control and capable of meeting customer

    requirements, then the manufacturer can confidently reduce inspection, and focus more on periodic audit of

    the process[4]

    . This also applies to the companys internal operations where the internal quality assurance

    organization can reduce its inspection and process surveillance, relying more on a planned process audit

    program[4]

    .

    SPC is applicable to all process stages in the PV industry, ranging from purity of materials and processes, to

    product data analysis and quality reporting. An example is in Siemens Solar Industries where SPC is

    implemented in their diffusion and cell printing lines to improve capability and electrical yields [27]. Software

    interface solutions enable implementation of SPC in manufacturing equipment and automation, to provide

    real-time data.

    7 Process Automation and Information Technology (IT) InterfacesProcess automation involves using computer technology and software engineering to help factories operate

    more efficiently and safely. Without process automation, plant operators will have to physically monitor

    performance values and the quality of outputs to determine the best settings on which to run theproduction equipment

    [28]. In PV manufacturing, existing and developing areas of automation include:

    Process stages in solar cell manufacturing Automated material handling and transport Automated tests, inspection Cell interconnection Integrated module-edge processing system combining automated edge trimming, edge sealing

    and framing processes

    Automated junction-box installation system Automated buffer storage system

    The SEMI PV Transport Carrier Task Force, led by Q-Cells, is looking at standards needed for PV wafer

    and cell carriers, equipment load ports and transport systems within PV production lines. A new SEMI PV

    Automation Standards Committee will be formed as well in Europe and Japan to focus on both mechanical

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    In Total Quality Management (TQM), quality is to be expected not inspected, which means that quality

    should be built into the product right from the beginning of the manufacturing process. A company which

    implements a proper quality management system is better equipped to produce very reliable solar cells and

    modules with minimum efficiency losses. Examples of quality and reliability problems that have been

    known to occur in PV products include:

    Physical defects such as bubbles, metallic inclusions, chips or cracks on a cell Misaligned cell connection string, hotspots in cells or interconnections Non-uniform sealant in module frame, delamination, glass fracture Incorrect electrical isolation between module current conductor parts and the frame Slow degradation of the short circuit current Light-Induced degradation (LID) associated with p-type CZ-Si solar cells Failure of BOS components Modules performing below labeled power output

    These defects contribute to failures in PV systems and can be avoided from the beginning of the

    manufacturing chain through process management and sophisticated quality assurance programs.

    Understanding how these problems arise during production is essential to controlling and improving the

    process in order to get the desired results. The following are some important quality detractors which need

    to be monitored during production.

    Detractor OutcomeCrystal defects

    Impurities in chemicals, materials

    These determine the material quality, and thus the

    solar cell conversion efficiency

    Particle density

    Particles in equipment

    Impurities introduced by processes

    Contaminants are one of the major causes of

    defects; therefore standard level of cleanliness has

    to be maintained in all process steps

    Improper handling

    Poorly carried-out processes

    Rough processing

    These can affect electrical properties, e.g. low

    shunt resistance leading to decrease in conversion

    efficiencyFlaws in wafer dimensions

    Failed mechanical and electrical properties

    These have to be checked to minimize risk of

    breakage and deficiencies in cell parameters

    Wrong setup in production line

    Defective laminating processes

    Faulty frame assemblies

    Such problems lead to production of modules

    with poor quality and reliability

    Table 2: Causes of Poor Quality in PV Cells and Modules

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    Conversion efficiencies of commercial modules are typically 2% lower than bare cell efficiencies. This has

    been attributed to factors such as area-related losses from cell packing density and the module frame,

    absorption of the glass, cell mismatch losses and losses in the cell interconnect ribbon. Nevertheless,

    developments in module technology are closing this gap[30]

    .

    8.1. Tests and Measurements to Characterize Cell and Module PerformanceEfficient tests and measurements have to be carried out on all solar cells during production to avoid

    assembling defective solar cells in a module. In order to identify the magnitude and sources of defects, the

    following parameters are most commonly measured[31]

    :

    Several varying test and measurement methods exist, but the three broad areas of test technology are [31]:

    Spectroscopy Electrical (contact) measurements Infrared (IR) imaging

    SEMI, ISO and IEC have developed standards including guidelines for tests and measurements. ISO/IEC

    17025:2005 specifies the general requirements for the competence to carry out tests and/or calibrations;

    including sampling using standard, non-standard or laboratory-developed methods[1]

    . The certification IEC

    61215:2005 of PV modules includes 17 tests which determine the thermal and electrical characteristics of themodule. These qualification tests are not expected to identify all possible module reliability issues in the

    actual field. However, they cover the major design quality issues and are thus regarded as minimum

    requirements for reliability testing[32]

    .

    8.2. Quality Data and ReportingData records provide a source of information for management to assess the performance of a system and for

    quality control. Data can be stored and properly documented either digitally or in written form. For

    business operations, typical records contain such things as contracts, purchase orders received, specialrequirements for products, deliveries, and meeting notes. On the other hand manufacturing records contain

    data of the quality process, including tests performed to check product operating parameters, records of the

    results of these tests, preventive and corrective actions, stock records, shipping, and the disposition of non-

    compliant products[7]

    . However, it is important to avoid unnecessary data that are not significant to the

    quality of the product. The PV GAP Quality Control Training Manual provides a detailed description of

    how companies can manage and utilize reports and documentations for quality control[7]

    .

    - Resistivity

    - Current/Voltage (I-V) curves

    - Capacitance/Current (C-V) curves

    - Optical properties

    - Charge carrier characteristics

    - Free charge recombination lifetime

    - Bulk material lifetime

    - Effective lifetime

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    9 Analysis of Quality Management Systems and Processes of PV CompaniesThere are three important aspects which can be regarded as the key performance indicators of quality in

    organizations:

    1. Structure quality how well a companys organizational structure influences its mode of operationfor high performance.

    2. Process quality - howthe companys business and manufacturing processes are optimized for highperformance and productivity.

    3. Product qualityhow well a companys product satisfies the customers and gains market share.These aspects can be perceived and measured differently, depending on the type of company. In this

    section, some PV companies will be analyzed based on information obtained from their websites,

    publications and PV news magazines. The aim is to have an idea of what goes on in the PV industry in

    terms of quality assurance measures, process stability, automation, efficiency and reliability of cells/modules.

    9.1. Overview of Processes and CertificationsTable 1 below shows information gathered from company websites and technical data sheets classified into

    different categories (columns A - G):

    A. Process steps stated as automated according to description of companys production processes. Somecompanies have fully automated processes while others mentioned specific processes which are

    automated.

    B. Information on how companies manage their incoming material supply and quality. Companies whichoperate along the whole value chain are vertically integrated and therefore do not rely on external

    suppliers for silicon materials. This implies that the quality of those materials depend on their internal

    operations and is not affected by damages due to transportation. Other companies indicate type of

    relationship or activities with their suppliers.

    C. Indicates which companies have a quality management system certified according to ISO 9001standards.

    D. Indicates which companies have certification for an environmental management system according toISO 14001 standards.

    E. Indicates which companies have the IEC 61215 certification for crystalline silicon terrestrialphotovoltaic (PV) modules: Design qualification and type approval.

    F. Judges from the goals, mission statements, etc. found on the company website which companies seem toemphasize commitment to quality.

    G. Based on description of the companys processes with regard to quality control, inspection, tests andmeasurements. (Refer to appendix for abbreviations).

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    A

    B C D E F GCompany/

    Products

    Process

    automation

    Supplier Quality

    ManagementISO 9001 ISO 14001 IEC 61215

    Company

    goals show

    commitment

    to quality

    Other quality measures

    SUNTECH/

    cells, modules?

    Developing s upplier

    relationship, virtual

    integration with upstream and

    downstream partners

    Yes Yes YES Yes

    Team of 700 quali ty control

    professionals who work

    closely with UL, IEC, CE, TV

    Q-CELLS/

    cells

    Fully automated

    (warehousing to

    final quality

    control)

    Handling all product flow

    logis tics through to working

    on technology with s uppliers

    Yes Yes Yes

    Detailed documentation of test

    criteria , objective and benefit,

    quali ty pre-checks on

    incoming wafers

    YINGLI/

    polysili con to

    modules

    Automated soldering Vertically integrated Yes Yes Yes Yes

    Implements at l east 39

    separate quality inspection

    steps from start to finish,

    stric ter ac celerated aging tests

    than IEC and UL

    JA SOLAR/

    cells, modulesAutomated soldering ? Yes ? Yes Yes

    Daily SPC, visual and

    performance ins pections,

    cross l inking and stripping

    tests

    KYOCERA/

    modulesFully automated ? Yes Yes Yes Yes ?

    TRINASOLAR/

    ignots to

    modules

    ?Long-term partnerships with

    leading equipment suppliersYes Yes Yes Yes

    Incoming inspections, in-

    process qual ity control, output

    inspection and test, offers

    after-sales technical service

    support

    SUNPOWER/

    modules? ? Yes ? Yes Yes

    Use preventive processes and

    testing

    BOSCH/

    wafer, cell ,

    module

    Automation in al lproduction lines

    Suppliers subjected to thesame high quality standards

    Yes Yes Yes Yes

    Preventive quali ty assura nce,

    packaging: suitable for digitalrecording of i ncoming goods

    usi ng barcode system

    GINTECH/

    cells, modules

    Automated

    Inspection

    Forming strategic alliances

    with upstream polysilicon and

    wafer makers

    Yes Yes ? Somewhat

    100% inspection for shunt

    resis tance and reverse current,

    in-line optical inspection on

    all products

    BP SOLAR/

    cells, modules? ? Yes Yes Yes Somewhat

    Routine use of special ized

    accelerated tests to predict

    product li fetime

    MOTECH/

    cells, modules? ? Yes Yes Yes Yes

    Frequent internal monitoring

    of LID, color uniformity within

    cells are closely monitored

    and controlled

    MITSUBISHI

    ELECTRIC/

    cells, modules

    Integrated facilities,

    automated

    processes

    ? Yes Yes Yes SomewhatAll modules are 100%

    inspected

    DELSOLAR/cells

    Automated wafer

    transport s ystem,

    automation

    equipment

    developed in-house

    Vertical integration with DeltaElectroincs

    Yes Yes Yes Yes ?

    SUNWAYS/

    modules? ? Yes Underway Yes Somewhat

    Meticul ous tolerance and

    quality checks

    SOLARWORLD/

    raw sili con to

    complete sola r

    electric

    systems

    Automated wafer

    testing a nd sorting,

    highly automated

    cell and module

    production

    Fully integrated Yes Yes Yes Yes

    Cell position measured and

    al igned before screen printing,

    quality check on arrival of

    pure silicon, continuous batch

    tracking, digital data

    collection of incoming goods,

    internal recycling

    PHOTOWATT/

    ignot to

    modules

    ? Vertical ly integrated Yes ? Yes YesQuality and relia bili ty

    validated at each stage

    SOLLAND/

    cells

    Automated

    production

    Work cl osely with producers

    of solar modules and

    suppliers (producers of

    wafers, ancil lary materialsand equipment)

    Underway ? Yes ?

    Every cell individually tested

    and sorted, visual inspection

    on every si ngle cell for

    mechanical and aestheticfaults

    SCHOTT SOLAR/

    wafers to

    modules

    Fully automated

    wafer i nspection,

    highly automated

    production

    Qualify and test suppliers

    regularlyYes Yes Yes Yes

    Strict 100% i ncoming goods

    ins pection, optimum c ontrol

    and monitoring of each step

    ALEO SOLAR/

    modules? ? Yes Yes Yes Somewhat Very strict quality control

    ISOFOTON/

    cells, modules? ? Yes Yes Yes Somewhat

    Assures proper measurement

    through verificati ons and

    maintenance of its l aboratory

    equipmentsTable 3: Information from Websites of 20 PV Companies around the World? No information found in that category

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    As can be observed from the above table, no information was found on some company websites for certain

    categories. It may mean that such information either exists in other portions of the website but were not

    found, or was not stated at all on the website. Therefore the limitation of this research is that one cannot

    come to any conclusions on what the company does or does not do in those areas since no field

    survey/audit was involved. Nevertheless the impression is that companies which have highly automated

    processes, or carry out stringent quality assurance measures and hold these of significant importance to thecompanies operations, most likely have this stated on their website. In general, all the companies

    researched have ISO 9001 certification except for Solland Solar which states that its quality policy will be

    certified according to that standard. Not all companies have the ISO 14001 certification but all the module

    producers have IEC 61215 certification. Not much information was found from the websites on the use of

    SPC in processes. But it seems that for many companies, improvement is needed in the utilization of

    equipment automation and in supplier quality management.

    9.2. Comparison of Electrical Conversion EfficienciesResearch and development efforts in the PV industry have been largely geared towards increasing the

    conversion efficiency of solar cells and modules. Higher efficiency attained through increased productivity

    and reduced costs will subsequently result in lower cost per watt peak. However there is still a large gap

    between efficiency of cells produced on a large scale at the plants and those obtainable in the laboratory

    (about 25% for c-Si). The conversion efficiency of a companys product to a large extent is an indication of

    the companys process technology and product quality which also translates to its market performance. The

    charts below show the average efficiency of solar cells and modules produced by a few companies between

    the years 2004 and 2010.

    Figure 9: Average Conversion Efficiency of Monocrystalline Solar Cells [33]In general, companies achieved higher efficiencies over the years for monocrystalline cells. Monocrystalline

    silicon produces better efficiency cells than multicrystalline silicon material. However multicrystalline cells

    are cheaper to produce, therefore more companies manufacture with this material than with monocrystalline

    silicon.

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    Figure 10: Average Conversion Efficiency of Multicrystalline Solar Cells [33]From the chart above, it appears that most companies achieved in average, higher efficiencies over the yearswith the exception of Sunways which has a lower average efficiency in 2010 than in 2005. The reason for

    this is not clear, but looking at table 1, one may deduce that the companys processes do not reflect as much

    quality assurance or quality information as some other companies in that table. However, one may also cite

    economic reasons as a possible explanation for the lower average efficiency in 2010.

    Figure 11: Average Conversion Efficiency of Monocrystalline Solar Modules [33]From the chart above, it can be seen that ErSol (Bosch) achieved significantly higher average efficiency in its

    monocrystalline modules than the other companies. This is a reflection of better production processes and

    quality management.

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    Figure 12: Average Conversion Efficiency of Multicrystalline Solar Modules [33]In addition to average conversion efficiency, another important factor is the efficiency variation in the same

    batch of a companys products.

    Figure 13: Probability Density vs. Conversion Efficiencies in PV Cells and Modules of Companies

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    The above plots show variations in efficiency of cells and modules from different companies technical

    datasheets. Some product series have a narrower efficiency range than others, which is a good sign. In

    contrast Photowatts multicrystalline module (bottom right) shows a very wide range of efficiencies

    which explains the low average efficiency obtained in 2009 [figure 12]. Such variations may be traced to

    variations in materials, processes or environmental parameters. Hence a stable and consistent process

    which can be accomplished through process and quality management is essential for reducing this gap.

    9.3. Reliability of PV Modules in the Market

    Figure 14: Failure Rate Comparison of c-Si Modules for the 1997-2005 and 2005-2007 Periods [32]The above figure shows the results of the failure rate analysis of crystalline silicon PV modules conducted by

    ASU-PTL. It shows that the failure rate dramatically increased in the period 2005-2007 as compared to1997-2005. According to the analysis, this higher percentage of failure was partly due to the market entry of

    a large number of new manufacturers[32]

    . This implies that the new PV manufacturers did not have as

    much stringent quality management as the older companies in the industry. Such a situation poses a risk of

    jeopardizing customer and investor confidence in PV products. If not properly addressed, it will curtail

    progress at this stage when the industry is in constant need of improvements throughout the whole value

    chain. Therefore, it is important that new PV manufacturers establish a quality management system right

    from the start of their operations. Better yet, quality assurance should be enforced globally by appropriate

    regulatory bodies for all companies entering the PV market. Supplemented by standardization in the

    industry, companies can be equipped with uniform guidelines for operation along the manufacturing chain.

    10 Conclusion and RecommendationsQuality in the PV industry is a reflection of the structure, process and product quality of PV companies.

    Ultimately, such quality has to be bankable in the sense that it is stable enough to ensure profitability and

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    hence attract more investors to the industry. Implementing adequate quality and process management is

    instrumental to achieving this. Major companies in the industry have the ISO 9001 certification for a QM

    system. However some areas still need to be improved such as in:

    Supply chain efficiency shifting from a static to a dynamic and efficient supply chain Supplier QM performing periodic audits of suppliers quality system and processes Upgrade of IT structure for the supply network and equipment communication interfaces Implementing proper SPC Control for improved stability in all process stages Increasing in-line product tests to reduce rate of failed products at the end of the line Technical inspections preferably unannounced inspection of production sites to check that

    manufacturers processes are continually improved and conform to quality standards

    Module Certification - In addition to testing products, performing quality audit of PV processes,before issuing certifications

    With new manufacturers entering the supply chain, the continued growth of the PV industry makes the

    need for standards more important than ever. Standardization efforts are already underway through SEMI

    PV Group in co-operation with EPIA and other technical experts in the industry. Several PV standards

    committees have been formed across the globe to handle specific tasks in such areas as tests and

    measurements, processes, materials and equipment.

    Some PV companies have formed partnerships and strategic alliances with other companies in order to

    benefit through resources such as manufacturing capability, distribution channels, equipment, expertise, etc.

    This highlights the importance of benchmarking, a tool of total quality used among companies striving to

    be more competitive. Benchmarking will help PV companies improve their process or product quality by

    learning best practices of other companies in the industry.

    Figure 15: Quality Management and Standardization PV Industry Cooperation for Good Results

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    11 References[1] International Organization for Standardization (ISO). International Standards for Business,

    Government and Society (2010).http://www.iso.org/iso/home.html

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    [14]Prof. Dr. Werner Bergholz. Jacobs University Bremen, Germany. Microelectronics. (Spring 2010).[15]Govindasamy TamizhMani. Crystalline Silicon Terrestrial Photovoltaic Cells Supply Chain

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    technology/

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    (Summer 2000).

    [22]B. Sopori, Y. Zhang, and W. Chen. Process Monitoring in Solar Cell Manufacturing. NationalRenewable Energy Laboratory (NREL). (October 1999).

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    [24]Thomas Pyzdek, Paul Keller. The Six Sigma Handbook.(Chapter 3). Quality Publishing. (1999).[25]Don J. Lee, Anna C. Thornton. The Identification and Use of Key Characteristics in the Product

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    Technology, USA. (1996).

    [26]Process Capability: How to Understand it. Quality Tools: Tools and Techniques for QualityImprovement and Problem Solving.http://syque.com/quality_tools/toolbook/Procap/how.htm

    [27]C.E. Witt, R.L. Mitchell, H.P. Thomas, M.L. Symko, R. King, and D.S. Ruby. ManufacturingImprovements in the Photovoltaic Manufacturing Technology (PVMaT) Project. NationalRenewable Energy Laboratory (NREL). (July, 1998).

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    http://www.ecn.nl/units/zon/rd-programme/silicon-photovoltaics/crystalline-silicon-solar-cell-technology/http://www.ecn.nl/units/zon/rd-programme/silicon-photovoltaics/crystalline-silicon-solar-cell-technology/http://www.ecn.nl/units/zon/rd-programme/silicon-photovoltaics/crystalline-silicon-solar-cell-technology/http://www.q-cells.com/http://www.q-cells.com/http://www.sefar.com/htm/609/en/Solar-Industry.htm?Folder=31423http://www.sefar.com/htm/609/en/Solar-Industry.htm?Folder=31423http://www.sefar.com/htm/609/en/Solar-Industry.htm?Folder=31423http://photovoltaics.sandia.gov/docs/cells5.htmhttp://photovoltaics.sandia.gov/docs/cells5.htmhttp://photovoltaics.sandia.gov/docs/cells5.htmhttp://syque.com/quality_tools/toolbook/Procap/how.htmhttp://syque.com/quality_tools/toolbook/Procap/how.htmhttp://www.abb.com/cawp/db0003db002698/b3913fe3a1296b7bc12571f10040f47f.aspxhttp://www.abb.com/cawp/db0003db002698/b3913fe3a1296b7bc12571f10040f47f.aspxhttp://www.abb.com/cawp/db0003db002698/b3913fe3a1296b7bc12571f10040f47f.aspxhttp://syque.com/quality_tools/toolbook/Procap/how.htmhttp://photovoltaics.sandia.gov/docs/cells5.htmhttp://www.sefar.com/htm/609/en/Solar-Industry.htm?Folder=31423http://www.q-cells.com/http://www.ecn.nl/units/zon/rd-programme/silicon-photovoltaics/crystalline-silicon-solar-cell-technology/http://www.ecn.nl/units/zon/rd-programme/silicon-photovoltaics/crystalline-silicon-solar-cell-technology/
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    [29] Win Baylies, Marty Burkhart, Don Cook, Dick Hockett, Matthias Meier and Bettina Weiss.Structuring Standards for the Photovoltaic Manufacturing Industry. SEMI/PV Group Photovoltaic

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    12 Appendix

    1. SIX-SIGMAThe Six-Sigma concept is an innovative tool which is used to improve the performance of processes to the

    point of 3.4 per million or less defects. It was designed for use in high-volume production settings; therefore

    it is well suited to manufacturing systems. It follows a six-step protocol for process movement which is asfollows

    [4]:

    1. Identify the product characteristics wanted by customers2. Classify the characteristics in terms of their criticality3. Determine if the classified characteristics are controlled by part and/or process4. Determine the maximum allowable tolerance for each classified characteristic5. Determine the process variation for each classified characteristic6. Change the design of the product, process, or both to achieve a Six Sigma process performance

    2. DEMINGS CYCLEThe Deming (PDCA) Cycle links production of a product with consumer needs and focuses the resources

    of all departments (research, design, production, marketing).

    1. Plan plan to improve operations by identifying problems and finding solutions2. Do make changes accordingly on a small or experimental scale, to minimize disruptions3. Check check whether the changes are achieving the desired results or not, including continuous

    check of key parameters (e.g. the KCCs) to ensure that any new problems are identified.

    4. Act implement changes on a larger scale if successful. Otherwise, plan to make adjustments fordesired results.

    3. BENCHMARKINGBenchmarking is part of the total quality process where companies compare processes and performance

    metrics to best practices within the industry or from other industries. There are two types:

    Competitive benchmarking a competitors operation is studied using publicly available data without

    cooperation with the target firm[4]

    .

    Cooperative or process benchmarking a partner companys key processes are studied through cooperation

    efforts by both firms so as to improve the benchmarking firm from a substandard to a world-class level[4]

    .

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    4. EXAMPLES QUALITY ISSUES IN PV CELLS AND MODULES

    Jorge Coello, 23rd European Photovoltaic Solar Energy Conference, 1-5 September 2008, Valencia, Spain

    5. ABBREVIATIONS IN TABLE 3UL Underwriters laboratories Inc.; provides product safety certification and compliance solutions.

    IEC International Electrotechnical Commission; prepares and publishes standards for electrical, electronic

    and related technologies.

    CE - Conformit Europenne; conformance to EC (European Commission) directives. The CE mark on a

    product indicates that the manufacturer or the importer for the EEA (European Economic Area) has

    respected the requirements for safety, health and the environment.

    TV - Technischer berwachungs-Verein (Technical Surveillance Association); carries out tests, inspections

    and certification of products, services and systems in industries worldwide.