Module 9 - hawaii.edubashburn/bioc141/outlines/module_9_outline.pdfThe active ingredient in many...

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Brad Ashburn, PhD Biochemistry 141 Module 9

Transcript of Module 9 - hawaii.edubashburn/bioc141/outlines/module_9_outline.pdfThe active ingredient in many...

Page 1: Module 9 - hawaii.edubashburn/bioc141/outlines/module_9_outline.pdfThe active ingredient in many commercial antacids is calcium hydroxide, Ca(OH)2, which reacts with stomach acid (HCl)

Brad Ashburn, PhD Biochemistry 141

Module 9

Page 2: Module 9 - hawaii.edubashburn/bioc141/outlines/module_9_outline.pdfThe active ingredient in many commercial antacids is calcium hydroxide, Ca(OH)2, which reacts with stomach acid (HCl)

The Mole

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A mole is a quantity that contains 6.02 x 1023 items

Avogadro’s Number

Page 3: Module 9 - hawaii.edubashburn/bioc141/outlines/module_9_outline.pdfThe active ingredient in many commercial antacids is calcium hydroxide, Ca(OH)2, which reacts with stomach acid (HCl)

Examples

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How many molecules are in 3.00 moles of CO2?

How many moles are 8.7 x 1024 molecules of CO2?

Page 4: Module 9 - hawaii.edubashburn/bioc141/outlines/module_9_outline.pdfThe active ingredient in many commercial antacids is calcium hydroxide, Ca(OH)2, which reacts with stomach acid (HCl)

Molar Mass

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The molar mass is the mass (in grams) of one mole of any substance

Molar mass comes from the Periodic Table

Page 5: Module 9 - hawaii.edubashburn/bioc141/outlines/module_9_outline.pdfThe active ingredient in many commercial antacids is calcium hydroxide, Ca(OH)2, which reacts with stomach acid (HCl)

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Calculate the number of moles present in 152.6 g of the anti-depressant Li2CO3.

Grams to Moles Conversion

Page 6: Module 9 - hawaii.edubashburn/bioc141/outlines/module_9_outline.pdfThe active ingredient in many commercial antacids is calcium hydroxide, Ca(OH)2, which reacts with stomach acid (HCl)

Moles to Moles Conversion

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2C2H6 + 5O2 4CO + 6H2O

What are the coefficients telling us?

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N2 + 2O2 2NO2

How many moles of NO2 are formed from 3.3 moles of N2?

Page 8: Module 9 - hawaii.edubashburn/bioc141/outlines/module_9_outline.pdfThe active ingredient in many commercial antacids is calcium hydroxide, Ca(OH)2, which reacts with stomach acid (HCl)

Grams to Grams Conversion

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Page 9: Module 9 - hawaii.edubashburn/bioc141/outlines/module_9_outline.pdfThe active ingredient in many commercial antacids is calcium hydroxide, Ca(OH)2, which reacts with stomach acid (HCl)

Grams to Grams Conversion

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mole–mole conversion

factor

molar mass conversion

factorGrams of reactant

molar mass conversion

factor

Moles of reactant

[1]

Moles of product

[2]

Grams of product

[3]

Page 10: Module 9 - hawaii.edubashburn/bioc141/outlines/module_9_outline.pdfThe active ingredient in many commercial antacids is calcium hydroxide, Ca(OH)2, which reacts with stomach acid (HCl)

Example

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Ethanol is made by reacting ethylene gas with water. How many grams of ethanol are formed from

14 grams of ethylene?

C2H4 + H2O C2H6O

Page 11: Module 9 - hawaii.edubashburn/bioc141/outlines/module_9_outline.pdfThe active ingredient in many commercial antacids is calcium hydroxide, Ca(OH)2, which reacts with stomach acid (HCl)

Concept Check 1

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The principle component of natural gas is methane, CH4, which undergoes a general combustion reaction below:

CH4 + O2 -----> CO2 + H2O

Write out the balanced chemical reaction.

How many grams of CO2 are produced from 5.50 grams of O2? Show your work.

Page 12: Module 9 - hawaii.edubashburn/bioc141/outlines/module_9_outline.pdfThe active ingredient in many commercial antacids is calcium hydroxide, Ca(OH)2, which reacts with stomach acid (HCl)

Concept Check 2

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The active ingredient in many commercial antacids is calcium hydroxide, Ca(OH)2, which reacts with stomach acid (HCl) to produce calcium chloride (CaCl2) and water:

Ca(OH)2 + HCl ----> CaCl2 + H2O

Write out the balanced reaction.

Classify the reaction.

How many grams of stomach acid (HCl) are needed to produce 12.8 g of CaCl2?

Page 13: Module 9 - hawaii.edubashburn/bioc141/outlines/module_9_outline.pdfThe active ingredient in many commercial antacids is calcium hydroxide, Ca(OH)2, which reacts with stomach acid (HCl)

Energy Change in Chemical Reactions

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ΔHWhen energy is absorbed, the reaction is

endothermic and ΔH is positive.

When energy is released, the reaction is exothermic and ΔH is negative.

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Energy Change in Chemical Reactions

6CO2(g) + 6H2O(l) C6H12O6(aq) + 6O2(g)

ΔH = +678 kcal

CH4(g) + 2O2(g) CO2(g) + 2H2O(l)

ΔH = -213 kcal14

When ΔH is positive:

When ΔH is negative:

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Reaction Rate

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Three Factors determine the rate of a chemical reaction.

ConcentrationTemperature

Catalyst