Inorganic Nano Particles Were Synthesized by Matrix Mediated Growth Technique,
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Transcript of Inorganic Nano Particles Were Synthesized by Matrix Mediated Growth Technique,
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8/14/2019 Inorganic Nano Particles Were Synthesized by Matrix Mediated Growth Technique,
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Conclusion
CHAPETER 5
CONCLUSION
Inorganic nano particles were synthesized by matrix mediated growth technique,
which is also known as in-situ deposition technique. It is observed that with
increasing molar ratio of PEG, nano size reduces. XRD peaks become broader
which is major indication of reduction in nano size. The broadening of peak may
be due to vigorous mixing at molecular level.
PA nanocomposites of filled with different nano sizes of CaCO3, CaSO4,
Ca3(PO4)2 and Mg(OH)2 were prepared on Twin Screw Extruder and specimen
preparation was done on Injection Molding Machine. Sizes of nano CaCO3,
CaSO4, Ca3(PO4)2 and Mg(OH)2 were calculated by XRD and confirmed by TEM,
the particle size was calculated using Scherers formula. Amount of filler added is
very less in PA i. e. (1 to 4 wt %) shows drastic improvement in mechanical and
Thermal properties, than commercial inorganic filled PA. Reduction in nanosize
gives more enhancements in properties due to uniform dispersion of nano
particles into PA matrix that inter relates among the polymer chains and
increases degree of chain linking capacity of matrix during compounding, which
transfer the heat uniformly throughout the matrix.
The nanoparticles mixed in PA composites give higher intercalation with increase
in filler content. Intercalation was confirmed by X-ray diffractometer. Absence of
peak is major indication of exfoliation, while presence of peak shows intercalation
phenomenon. The DSC results showed that nano size addition leads to
increment in glass transition temperature of PA. This increment in Tg was due to
Ph.D Thesis, Mr. Shriram S. Sonawane, UDCT, North Maharashtra University, Jalgaon Page 140
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Conclusion
the confinement of the polymer chains within the nano particles with restriction in
the mobility of polymer chains. Also thermal stability of PA nanocomposites
increases with increase in filler content.
Substantial improvements in mechanical, thermal and physical properties are
observed by addition of smaller amount of nano nanofillers, which is having
variety of structures. This improvement is due to the uniform dispersion of nano
particles in PA, which gets intercalated and exfoliated within the polymer chains.
Intercalation and agglomeration phenomenon have been confirmed using XRD
grams, which the evidence for improvement in properties.
Addition of Mg(OH)2 in PA shows enhancement in mechanical, thermal and
physical properties. Moreover improvement in flame retarding properties of PA
nanocomposite was significant.The improvement in flame retarding property was
more compared to other two sizes with commercial Mg(OH)2. This improvement
in flame retarding properties was due to uniform transfer of heat with uniform
dispersion of nano particles into the matrix. Moreover, Mg(OH)2 is an inorganic
flame retardant. When Mg(OH)2 is heated it decomposes to MgO with release of
water, and at the same time process was absorb a great deal of heat to lessen
the temperature on the surface of material.
The extent of reinforcement has been correlated with concentration of filler in
polymer. The addition of a small amount of organo-montmorillonite (14mass%)
showed enhanced properties like mechanical parameters,flammability, hardness
and rheological behavior due to uniform dispersion of OMMT in the polyamide
matrix. However, OMMT also acted as lubricating agent, which reduced the
Ph.D Thesis, Mr. Shriram S. Sonawane, UDCT, North Maharashtra University, Jalgaon Page 141
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8/14/2019 Inorganic Nano Particles Were Synthesized by Matrix Mediated Growth Technique,
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Conclusion
torque and decreased viscosity along with increased elongation at break. Due to
OMMT, the processing of polyamide is very easy and OMMT provides a good
processing aid along with the role of the filler.
Ph.D Thesis, Mr. Shriram S. Sonawane, UDCT, North Maharashtra University, Jalgaon Page 142