I1221 semivolatile qrqanic3 ,s_7t!al calibration data ... 1.06*4' 1.052' g. 573 - -1. 052 9.5 « i...

I1221SEMIVOLATILE QRQANIC3 ,S_7T!AL CALIBRATION DATA

-3b Nanii? ; NIJS CORP."Contract:

NUS-PGH Case1 Nc - MC " " " -A-_" ^""' ' "- -AS Wo. : c~- ..... bL'G No, :--ID* 50C

"JJ,b/,ajLlcJ3_5S- l.sv.: ,,12/01/65 12/01/R3

RK--0 " B I C 120 I 380S- .RF.F5O = 3 ! 01 201860HF:~3'"' -- P 1C UO 1 9602-- RHF 1 20 ~ P 1C ! 201 6803 RRFl 6v~ H I C1202 65O

-,!.F2° -V^"F5b- "Was --RRFt20:SRr:rO." r=»~",__ _ ...__ , ^ ^ vg-_. -- cv *t-î.» 729 -11 502 ! 2. v'55

i r i r - r-eh i^rn-*-v r-E'her j___^ 1-. 5.? 2,; , : .Z3 ":.. 1?42: 1. 73 i - 1.6-46-2 -•*- i - - -r"~~-^-: ' -_ _T" •"•"" " " :'"f"""''' .".i • > 7J::,,. 1.,. ^cO ' 1 I 4^~ 1 . "If • I - T^s '

I?1 i '"" J"* T -" "'* *•* ~* * ° ' 1 4 * j"41 ; • • • '"-•—'" "T1:"; r-2-f11?"__:,_ ~; - • ~-~-'* i • -7-^ ~_

r"1 ~ v ' a •' - v- : • • . . ^——"0 - " 95 ;' - Q.--394 0! 936 ' 0.921' 0.96^: n cnr, • = •=_ .-,-,-_-- .. . ,.-cj '-'. •=*_; 1 C. 95 3 I n. S0r! '

: . — - •. ; -?rs "r-^b^""?^*? ____j___; i . 5" 9 ; 1.5-01; 1.539' 1,533: ' . c^^ : 1 . 5"*° '2- • s * h." 3 h 61 n c : - - - • • '' "'- I ' -. ' 9 P ,' i "-'79 ' -" • - -

A-He;P.:v; ;;;rvj'Fyil&c:;!r:..5"-3901 ?-309:-3;aT7- " ~*' •i----" •"> 1 1 - ? ' < - /, o . , - - -, "" " "„ --.•. * » •.. . -.* ,-u.Ag.. . i.. .53 - i_ f 353 •-.356: 3.362i

1 . 536! 1.445.! 1 "3P

vr_x:;,^,_ .-,_ ... . .. . _. , ,——_ ...-?..-_ i 1 -. ...l.-^/iR1- •• - - • --""-'I-r-?-rcpv i ami'ne 4" 1 ôs • 1 qav-HpK3-V.crnetna~r* - " - " "^ A j *':337M-r-sn^^ :"———————————L;.^7^' C-SS5: 0.722' 0.-22' 0.70 n";TTcprcren* "————————————————--^0!;: ^ '' 0_->39 : .0. 443 - 0.579Vo^.i4- —- ___ , n o ^ ^ ' o' as •» < ,-^-1^.™. _ . . — •. —-e-pn^^ - - - - - ---'———r—- .. -• -^-. ,0. 9o3- 0,950' 0.961' i OO^ ' n c-n

:^^,;r,~^r———————^-0.225- 0.22^: 0.230' 0.23*; o i 2?^ n":,:

-• ":1— ZZZ±Z I'-o^-0'^^-^-3651 °-390' ;"R' "';;-?SSS?' ^ -J ?-p*:-.o: ; S:&; S:i?S: ?;=s: '-Hi" r- '--'•.•_______-: . - =•* 0.-5QC' .-) -afne.. ,-, -,-,-, -, _ ----^. , , _ . w-^-û;^_^-_^w ~^——————^—— • - * ~ - -'.. O'.) *5 O.32^: 0 , 3 2 "* ' H -^ "> o - n TI - ,•--•••*••- -T"3Penzen£? ' O -P-T-S. -s -3,,-, ^. ' • - .- . '.. . O.——-. . O.î'-

-,:-,_, i, -, j „ , . ———————' ^ • J ' 3 . 0.349 0. : A -a A /, . r, •=•=--• > — . ~ ' o —; ir, - • - . - - "•. -^ . : - - • • „ . , ' ( it ( l ^ T /•— J 1.105: * - - - - - - - - -.-•..____'": : 0.449;.•i-.-h^-o3^cTT^7———————~——' :' 106: i'017:"o.99S: 6*9"^' o'â^' -:-"c">:- c :;;,,;;,r~-—~; f ; .o,???- 0.4^2= 0.4;.: o.'«r: 0:1^3

:;. • n. , « S95: —— fM=racvcicpentadiene__» o. . . • ,, , p

•-• -----inchlsroph.nol _____ * 0 'g?- o 10- • -" i - C.l-1: 0.151. ————— n', °':i °-=32: 0.259

, -, , ': -; -- .: n;;• . -- 'o- 'J--'a6?: O-«AO- 0.465' o.ix:-:,-*;I":-i--!!i:-i!.hf; ^'^2i ::«;; ;;i2|:

-:ix7T^^-lT:ctr9ne^————-_/0.2|9: n,.323:. 0.299- 0. -0: 0.329 o.,., , t»-Tnp.?=Kv--5-«? V—————~——^-^-'•'* -1: 0-3:i:.-Q..320.1 0.294- 0.259: •:•. ^S^ ' " c * -

______________* "1 . 1*57 : 0. 999. - 1,. Q4^ . 0. 9 " ' 0. 981 : : . 027 'r.. -'j -fii ".: * r-r r-herc i _____' ' " ! '*"C. 026 ' 0. 076-' 0. 092 ! 0.106' 0.117' 0. 0^4--.\:: vrcrherr. ; j*. 0.0*7: 0.0781 0.075. 0.0~i: 0. 0"5 . •"• - ''-•'=•L. .. , '3 '•

flR30!779

SEMIVOLATILE ORGANICS I N I T I A L CALIBRATION DATA

L@b Name: NUS CORF/ Contract: " . _ - . - .

Lnb >"::•:*: NUE-PGH Case No. : ME £AS No. : 5DG Nc. :

;-.7T-Jcn?nt 10: 50C Calibration Date<s3: 12/01/86 12/01/55

'"In F." f^r 5PC7»'#) ~ 0.050 Max %RSD fcr CCCiO = -.

? F:T_H !L-: - RRF20 - BIC12O15605r?v r ='C:20i-e?O2 _ RRF120= BTC12O15SO3

• ,MI- iffr.-. ooz"?n :,

-,, . - r --,., - i_ . 706 '- •: ;-! -:•-'-,.' :"*n« : o. 3*59 :.

*• r:1 • * - * - 7 - 'I - 2 = 0 :

,«....*- i "30R

4 • -T.-? ' i -^ ' " ;

?O !=•

o.1

0.

0.

— 1~>

36"5

S 120-jp

1

-i •1

3 •

»otrc.oRH ~ i 60

r? c c- p r. • -p

1 5 7^» '

0.59 4i ^ •? -. •O. 2r3~ '

= B [C 120 1-3601* B I C1201 3*04

-.— .-^.'-^j-,.--

l.«?e: l.S'.t

i.oe'.i- o.c69.0.5/0. 0.5 = 3;

r\ "'co- f"1. TJ r, T «

0.561.160 "Tp

- -

co .

-.

^

. "'

N -r' ' : " :-x!f?h£ny ;3mine <'!•_* O.R23: 0.55^? 0.551 0.581: 0,«99.' 0.564: 8.O**=- T, "- "v-.v -pn»r.v!«-h<?r__: 0. 25 I ' 0. 23 1 : 0. 2'i6 ' 0, 242 . 0. 225 : 0. 240 : 4,2

_4...- - f -«, n;: -,no ; 0.272" 0. 250 : 0-2.49 0- 245 ' 0. 2591. 0. 255 ' & - Z_ ^ r ,. .,j -* i «r*h vnc : _____.^_____•* ' 0.139: 0.132: 0.125 '• 0.113' 0.1 32 ' -y-.r-^ - --. r,-»,- r&,,f., _________^___ ._ 1.155' 1.011' 1. O09 I 1.01-3! 1, 05 *J ' 1.051^ ,., _,.. ,_ -i-^ __________________ t_ a 17.9 : 0.930 0 . 990 - 0. 39C I 0 . 766 •- 0.9=-" I1

"'••-•?•*--?-? _____•* 1.064; O.537' 0.9 *6' 0.549; ?,855' 0.910 10.f-: ,, - ~r,~, ____.___..._____- ____* 1. 756 I 1 . A IT 9 \ 1. 5" 2 - 1. 6 6^5 ! 1.5^3" 1 . r 9" ~.^s..f .. - ^-., _ n«^x- ;3-.^_______' 0. 781 ! 0. 822; 0. 85 <* . 0. 596 . 0. 8«6 * 0. 3^0 ' 5 . v" . * * "."•: *^:'^r^bcnr:ici r<?_____: O . 311 ' 0.365: O. 376 . ~ 0 . 365- — O. "69 : 0. 35^ T.-'i_

--•rr^r^.___ ' 1.139' 1.034: 1.06*4' 1.052' G. 573 - -1. 052 9.5« i - ; ^ - -' 1 *••* *cv * "• P?itha late ' 1.078: 1.14 5 : 1.154' 1.2 38: 1.229. 1.159- ~.5: : •* :•"• v: »h* h.i: at.e____** i. 7^5 • 2.169: 2.19? - 2. 254 • i. 6?o' 2.033 '- i;. *•r.fc--.., - - = • - .rr-.-tJ-eneZIZZZII1 1--82' 1.227! 1.1*7* 0.507' 0.8O9 i . 03'- 2C - ~"•>•-•' : ?"--?«-.» . * 1.052 l.OTA! 1.055T 1.107' 1.06?' 1.077 2.

';-•-- : . 2, 3-cd>Pvren© _____ I 1.116' C.934; 1.060'. 1.25-4: 1 . 267 :„ _ i . 1 35* 0.721' 0.603' O.756' O.S61 O.S9t 0.511

r ^r-'-.r,i F-^rylene _______ : 0.377! 0.672 O--?^"' 1.011: 1.00""' C.921

' 0. 24 , 0. 416 : 0.42? 0 . t 1/4 ' 0." fi 31 ':--?- *rh«nv i __________ ; 1 . 14= ; I. 2 57 : 1 . 157 ' _^r ,„ - . -i i .j ____ __ ; i . O96 : 1.149' 1 . 097 ' 1.3:5' 1.1 26,_ , 1-. 16' r

- ;•=• _____ ~_ _ ' _____ - ! i . 496 ' 1. 573. I.5u7' 1. 5-05 : i . -622 n 1 - 509 '~ " I 1 , 1 37' 1.217 1 . 27! ; 1 .;?"=" ! . 21 T ' ! . I06 *

'r * brt^hrh^-.ni ____" 0. I2"7' 0. 1'IS ' T». l-'tS . 0. 132 ' O. 1.22'

d from D I pher.v I am 1 n«

SR301780

5BSEMIVOLATILE ORGANIC GC/MS TUNING AND MASS

CALIBRATION - DECAFLUOROTRIPHENYLPHOSPHINE (DFTFP)

Lab Name: NUS CORP. Contract:

Lab Code: NUS-PGH Case No.: ME SAS No.: SDS No.:

Lab File ID: DIC12O1S8O2 DFTPP Injection Date: 12/01/88

Instrument ID: 5OC DFTPP Injection Time: O8O1

m/e :

51 I68 :69 :70 :

127 .'197 ;196 ;199 ;275 !365 I441 :442 !44 : :

1

ION ABUNDANCE CRITERIA

3O. O - 60.0% of mass 198Less than 2. 0"£ of mass 69Mas*; 69 relative abundanceLess than 2. 0'/. of mass 6940.0 - 6O.OX of mass 198Less than 1.07. of mass 198Base peak „ lOO/i relative abundance5.0 to 9. OX of mass 198tO.O - rro,O2, of mass 198Greater than 1 . 0«"'X of mass 198Present, but less than mass 443Greater than 40.0% of mass 19817-0 - 2 .O% of mass 442

% RELATIVEABUNDANCE

51. I0 . 0 < 0 . O >54,40.2 < 0. 4>46.60.0

100,06.419.31.4210.269.513.4 < 19.3)

i

11

*•>

1-Value is 7. mass 69 2-Value is X mass 442

rTHIS TUNE APPLIES TO THE FOLLOWING SAMPLES, MS, USD, BLANKS, AND STANDARDS:

: EPA: SAMPLE NO.

0 1 ! SSTDO5O02JSSTD0800.3ISSTD12004JSSTD16005ISSTD020 - -

LABSAMPLE ID

SSTDO50SSTDO8OSSTD12OSSTD16OSSTD02O

LABFILE ID

BIC12018801BIC12018802BIC120188O3B 1C 1 2O 18804B 1C 120 18805

DATEANALYZED

12/01/8812/01/8812/01/8812/O1/8812/01/88

TIMEANALYZED

O825O914I 00510491139

ftR3~Ol78l

7BSEMIVOLATILE CONTINUING CALIBRATION CHECK

Lab Names NUS CORP. Contract:

Lab Codes NUS-PGH Case No.: ME SAS No.: SDG No.:

Instrument IDt 5OC Calibration date: 12/06/88 Time: 2259

lab File IDs BICI2O68SO3 Init. Calib. Date(s): 12/O1/88 12/O1/B8

Mm FRF50 for SFCCC#> - 0.05O Man 7.D for CCC<*> = 25.'

COMPOUND

tPhenol_________________:bi*s<2-Chloroe?thyl ) Ether,i 2-Chloropheno1 _______

!I,4-Dichlaroben::ene_: Benzyl Alcohol __'1.2-DichI orobenzene,2-fletHy Ipheno 1 _____Ibis <2-Chlaroisaprapyl>Ether4—Methylphenol____________N~Nitraso-D3-n-Propylamine_tt 1.432! 1.516.1 -5.9He;;achIoroe thane __________:Nz tr-obenrene _____________Isophorone ______________ ,__: 2-Ni trophenol _____________2,4-Dimethylphenol ________

I Benroic Acid _____________Ibis (2-Chloroethoj:y)Methane_2, 4-DichIorophenol_________* 0,314! O.33O! -5.1

0. 350 ! -0. 365 ! -4.30,906! 0.972: 1-4O.47B! O.5O2! -5.0

I i , 2, 4—Tnch lorobenzene_INaph thalene__________J 4—Chlaroan i 1 me

RRF !RRF5O "! ZD

2.O31I 1.706! 16.0 *1.739! 1.715! 1.41.414 I 1.305! 7.7_U495! 1.435: 4.O1. 627 ! „! . 64_1 ! -0.9 *0. 9OO ! .0. 999 : -1 1.01.522! 1.535! -0.91.286! l.™9_; -4. 13.382.' 3.539! -4.61.288! 1.3451 -4.4

0.716! O.746! -4.2O.484!.0.473: 2.30.971! 1.032! -6.30.230I O.229i O . 4 *O.363! 0.3801 -4.70, 189: O. 194_: -2.60.579! 0.5851 -1-0

!2,4T5—Trichlorophenol!2-Chloronaphthalene__' 2—N i treran i 1 i ne_______I Dimethyl Phthalate___!Acenaphthylene_______» ~%2. 6-Dmitrotoluene_

Nitraaniline____

O.19O! O,246i-29. 51.122; 1.014! . 9.60.441! 0.493!-ll.S_1.2O3: 1.246: -3.61.699! 1.617! 4,80.312! Q.3OO! 3.80? 287! 0.298! -3- 8

IHexacn-lorobutadiene_______* 0.170! 0.2OOI-17.7 *:4»ChlarQ—3-Methylphenol____* 0.324! O.362!-11.7 *: 2-Me thy I naphthalene________! O. 94O ! O. 964 I -2^ 6 !!He-rachioracyclopentadiene__# O. 145! O. 185!-27. 6:2,4,6-Trichlorophenol______* 0,218! 0.238! -9 2

lAcenaphthene______________* 1.027! 0.948! 7.7 *i244-Din;itrophenol________tt 0.084! .0^1251-48.8I 4-Nitrophenol______________ft O.O69! g. 126_L-S2.6

782

7CSEMIVOLATILE CONTINUING CALIBRATION CHECK

Lab Name: NUS CORP.. Contract:

Lab Code: NUS-PGH Case No.: ME SAS No.: SDG No.:

Instrument IDi 5OC Calibration date: 12/O6/88 Time: 2259

Lab File ID: B1C12068803' Init. Calib. Date is): 12/01/88 12/01/88

Min RRF5O for SPCCCtt) = O.O5O Max 7.D for CCC<*> « 25.0

1t

: COMPOUND

1 Dibenrof uranI 2, 4-Din i trotolueneI DiGthvloh thai ate.' 4-Chlorophenyl-pheny lether_I Fluorene! 4— Ni troan i 1 ine: 4, 6-Dini tro-2-Methylphenol_! N— Ni trosodipheny lamine ( 1) _! 4— Bromopheny 1— pheny lether _; He*;ach lorobenzene.' Pen tach 1 orophenol! Phenanthrene; AnthraceneI Di-n-Butylph thai ate{ FluorantheneI Pyrene: Butvlbenzylphthalate! 3, 3 '-Dich lorobenridine! Beneo<a) Anthracene , ....: ChrvseneIbis (2-Ethylhe:cyl)Phthalate_!Di-n-Octvl Phthalate', Benro (b) FluorantheneI Benzo (k > FluorantheneI Benzo (a) Pyrene! Indeno (1,2, 3-cd) Pyrene ____ ,; Dibenz < a, h) AnthraceneI Benzo <q» hT i )Perylene,I Ni trobenzene— d5: 2-Fluorobiohenyl! Terphenyl— d!4!Phenol-d5: 2-FluorophenylJ 2, 4, 6-Tr ibromophenali

••RRF !

1.548!0.359!1 . 138 !O.581 Ii. IBS:0. 289!0. 105!0.564!O. 24O I0.255!0. 13211.O51 :0.952!1. 46!0.910:1 . 597 ;0.840!0.358!i.29i :1 . 032 !1. 169!2.038!1.331 !1 . 034 !

* 1.077!1.135!o.sii :O.921 !

0.422!i . 2O4 :1. 169!1 . 609 !1. 196!O. 138!

i

\RRF50 !

1.551 :.0.386!1 . 255 !0.635!1. 168!0.268!O. 125!O.541 !0.238!0. 236 !0. 137!O.. 9O3 !O.898!1 «. 283 !0.978!1.473!0.837!O.361 !1 . 267 !0.963!1.242!2. 131 !1 . 437 ,'1. 178!1. 112!O.981 !0.824 .'0.920!

0.456!1.O29!i . oos :1.619!O . 9O2 !o. 141 :•

7.D

-O.2-7.5-10. 3— O T

1.47.3

-19. 14. 1 *O.87.5-3.8 *14. 15.7-3.0-7.57-8O.4-O.81.96.7

_ j_ ••»a . ~-4.6 *-8.0-13.9—3. 313.6-1.60. 1

-8. I14.513.8-0.624.6— *> i

(1) Cannot b© separated from Diphenylanune

ftR301783

SBSEMIVOLATILE ORGANIC GC/MS TUNING AND MASS

CALIBRATION - DECAFLUaROTRIPHENYLPHOSPH_INE (DFTPP)


Lab Cadet NUS-PSH Cam© No.i ME BAB No.i BDQ Na.I

Lab File IDs DIC12O6SSO1 DFTPP Injection Dates 12/06/88

Instrument IDs 5OC DFTPP Injection Times 18O7tt! ffi/e

! 51• 'o8! 69! 70! 127! 197\ 198I 199! 275> u>o5! 441! 442\ 443i


3O.0 - 60.0% of mams 198Less than 2.Q% of mass 69Mass 69 relative abundanceLess than 2.0% of mass 694O.O - 6O.O% of mass 198Less than 1.0% of mass 198Base peak, 1OO7. relative abundance5.0 to 9.0% of mams 19810. O - 3O.0% of mass 198Greater than l.OO% of mass 198Present, but less than mass 443Greater than 40.0% of mass 19817.0 - 23.0% of mass 442

% RELATIVEABUNDANCE

55.20.O ( 0.0)156.30.6 ( 1.1)144.70.0

100.06.721.9 11.789.568.713.7 ( 20. 0)2

i-Value im % mass 69 2-Value is % mass 442

THIS TUNE APPLIES TO THE FOLLOWING SAMPLES, MS, MSD, BLANKS, AND STANDARDS:

! EPA! SAMPLE NO.

01SSSTD05002!SBLKCI

ii

! LAB! SAMPLE ID

! SSTDO50! SBLKCIi•

LABFILE ID

B 1C 12068803KIC120688O2

DATEANALYZED

12/06/8812/O6/88

TIMEANALYZED

22592357

8CSEMIVOLATILE INTERNAL STANDARD AREA SUMMARY

(Lab Name: NUS CORP." ~ Contracts

Lab Code: NUS-PGH Case No.: Q£ SAS No.: SDG No.:

Lab File ID (Standard): BIC12O688O3 Date Analyzed: 12/06/88

Instrument ID: 5OC Time Analyzed: 2259

12 HOUR STD

UPPER LIMIT

LOWER LIMIT

EPA SAMPLENO.

SBLKCI

IS4(PHN)AREA ft

9690O

193800

48450

785O0

RT

15.45

15.44

ISS(CRY)AREA *

65600

131200

32S0O

610OO

RT

22.09

22.05

IS6(PRY)AREA ft

53O00

1060OO

26500

60600

RT

25.39

25.3701

IS4 (PHN> = Phenanthrene-dl0 UPPER LIMIT = + 100%IS5 (CRY) = Chrysene-dl2 of internal standard area.IS6 (PRY) = Perylene-dl2 LOWER LIMIT = - 50%

of internal standard area.

tt Column used to flag internal standard area values with an asterisk

flR30!785

8BSEMIVOLATILE INTERNAL STANDARD AREA SUMMARY

Lab Names NUS CQRf." Contract:

Lab Codes NUS-PGH Case No.s pE SAS No.: SDG No.:

Lab File ID (Standard)s BIC12O6S8O3 Date Analyzed: 12/O6/SSInstrument IDs 50C Time Analyzeds 2259

12 HOUR STD

UPPER LIMIT

LOWER LIMIT

EPA SAMPLENO.

SBLKCI

ISKDCB)AREA ft

211O0

422O0

10550

18700

RT

5.05

5.02

IS2(NPT)AREA ft

83300

166600

41650

67200

RT

7.68

7.65

IS3(ANT>AREA ft

57800

11560O

2890O

44500

RT

11,89

11.8501

IS1 (DCS) - i,4-Dichlorobenzene-d4 UPPER LIMIT = + 100%IS2 (NPT) ^ Naphthalene-d8 of internal standard area.IS3 (ANT) s Acenaphthene-dlO LOWER LIMIT ^ - 5O%




Lab Names NUS CORP. Contracts

Lab Codes NUS-PSK Case No. : ME SAS No. s 5DG No. :

Instrument IDs 4SA Calibration datsi 11/27/88 Timei 15OO

Lab File IDs BA511278SO1 Init. Calib. Date(s)s 10/20/88 10/20/88

Min RRF5O for SPCC(ft) * O.O50 Max %D for CCC(*) = 25.

COMPOUND

I Phenolibis(2-Ch1oroethy1)Ether2-Ch1oropheno1________1,3-Dichlorobenzene,1,4-Dichlorobenzene,Benzyl Alcohol_____1,2-Dichlorobenzene_2-Methy1phenol_____bis(2—Chloroisopropy1)Ether

i 4-Methylphenol____________• N-N i t roso-D i-n-Prapy1am i ne_#i Hexachloroethane________i Ni trobenzene____________! Isophorone______________!2-Nitrophenol_____!2,4-Dimethylphenol.I Benzoic Acid ___ibis(2-Chloroethoxy)Methane^; 2, 4-Dichloraphenol________•1,2,4—Trichlorobenzene_Naphthalene__________!4-Chloroanil me__________I Hexach lorobutad i ene_______*!4-Chloro-3-Metnylphenol_-__*! 2-Methylnaphthalene_______IIHeuachlorocyclopentadiene_ft!2, 4, 6-Trichloropheno 1_____*!2,4,5-Trichloropheno1____I2-Ch1oronaphtha1ene______! 2-Nttroan i 1 ine___________!Di«*thyl Phthalate.!Accnaph thy1ene___!2,6—Dini tratoluene_!3-Nitroani1ine___!Acenaphthene______! 2,4-Dini trophenol! 4-Ni trophenol

Lab Names NUS CORP. ContractsI

Lab Codes NUS-PSH Case No.: ME SAS No.: SDG No,s

Instrument IDs 45A Calibration dates 11/27/88 Timei 1500

Lab File IDs BA51127S8O1 Init. Calib. Date<s)s 10/20/88 10/20/88

Mm RRF5O for SPCC(ft) * 0.05O Max %D for CCC(*) = 25. C

COMPOUND

* Dibenzofuran______!2,4-Dinitrotoluene,iDiethylphthalate_~_14-Chlorophenyl— pheny lethe>r_!F1uorene___________________j4-Nttroani1ine____________j 4,6-Dinitro—2-Methylphenol_!N-Nitrosodiphenylamine (1) _•j 4-Bromopheny1—pheny1ether_IHexmchlorobenzene_________! Pentachlorophenol_________•* Phenanthrene______________!Anthracene________________!Di-n-Butylphthalate_______•Fluoranthene______________•!Pyrene____________________!Butylbenzylphthalate______!3,3'—Dichlorobenzidine^!Benzo(a)Anthracene________!Chrysene_________________!bis(2-£thylhexyl)Phthalat@,,'Di-n-Octyl Phthalate______'Ben zo(b)Fluoranthene_____!Ben zo < k)Fluoran thene______! Benzo (a.) Pyrene____________!Indeno(1,2,3-cd)Pyrene.!Dibenz(a,h>Anthracene,!Benzo<g,h,i)Perylene_

!Nitrobenzene-d5_12—Fluorobiphenyl.

* Phenol-d5__________!2-Fluorophenyl______!2,4,6—Tribromophenol.

RRF JRRF50 ! %D

1.591! 1.414! 11.1O.351! 0.368! -4.81.121! 1,199! -7,OO.626! O.56O! 10.51.324! 1.161! 12.30.279! O.318J-14.00.141 I O. 126! 1O.60.546! 0.546! O.OO.204! 0.192! 5.90.223! 0.197! 11.70.137! 0.132! 3.71.082! 1.016! 6.11,085: 0.955! 12.01.193! 1.294! -8.50.969! O.949! 2. 11.731! 1.388! 19.80.795! 0.727! 8.60.273! 0.396!-45.1.554! 1.214! 2tT91.149! 0.955! 16.91.065! 1.006! 5.5

• 1.927! 2.143J-11.21.770! 1.661! 6.21.104! 1.1O2J 0.21.131! 1.162! -2.70.994! 0.924! 7.0O.810! 0.780! 3.70.871! 0.829! 4.8

0.366! O.4O5!-10.71.387! 1.396! -0.61.279! 1.189! 7.01.603! 1,858!-15.91.28O! 1.121! 12.40.153! 0.140: 8.5

Cannot be separated from Diphenylamin©

flR301788

SEMI VOLATILE ORGANIC GC/MS TUNING AND MASSCALI BRAT!ON - . DECAELUOROTR!PHENYLPHOSPH1NE < DFTPP >

(Lab Name: NUS CORP. - Contract:

liab Code: NUS-PGH Case No.: ME SAS No.: SDG No.:

Lob ~i!i? ID'. DF51127650A r~D"7PP Injection Date: 11/27/88

1 ncr ruinent ID: 45 A ... DFTPP In :ect ion Time: 1419

n/«? : !ON ABUNDANCE CRITERIA _.__ . --

5 1 : 30. 0 - 50. 0% of ma's s 19665 ' Le^s1 than 2.0% of mass 69•5° : MA-=T pq rflativf 'abundance • * - ;-: <•• "70 ' Less than 2.0% cf rcrsss 69 . .C~ * 40.0 - 5.0,0% cf mass.. 195 ..._ .~- - - > - - - - -97 : Lens than 1.0% of mass 196 .. - - -96 " S.3S-? p-sak. 100S relative abundance199 : 5.0 fcc 9,0% cf. mass 19£:7?..: ::X5.C-- 30. 0% cf mass 1S8365 : Greater than 1.00% cf mass 198 . - ..; - -4'iJ. , pT'^'^prjt' fctJ*" I^^'S.^'^'^n TI^SS 4A3 - - • — "«4? : Greater than 40.0% cf mass 196••i43 : i T. o - 23. 0% of mass 442

1 -Vs 1 ue i s % mass 59 2-Va ! ue

M53 TUNE APPLIES TO THE FOLLOWING SAMPLES, MS, MSD.

: EPA I LAB : LAB :' SAMPLE NO. : SAMPLE ID .' FILE ID :

01 ' SSTOOS^ : SSTD050 1 BA51 12"?8aOi !02 'SW-SED-8 ;! P1O3862 I C51 1276.802 :03 ' SW-SED-SMS : P103862M5 . ! C51 1273303•"4 .'-SW-SED-3MSD : P103862MSD : C511278804 :

; t

: % RELATIVEABUNDANCE

: 50.71 0.0.' 0,0 ' 1: 4 -e . o: 0 - 0 • 0 . C • :

- -• - : 49. i' 0.0: 100.0

S . 5: 18. 7: 1 . 56

- '• 5.2; 40. 7: 7.4 ( 18. 3)2;

is % mass 442

BLANKS, AND STANDARDS:

DATE : TIMEANALYZED I ANALYZED :

11/27/38 150011/27/88 175711/27/88 1917 :11/27/88 2028 . :

flR30i789

acSEMiVGLATTLE INTERNAL STANDARD AREA SUMMARY

I Lab Namit: NUS CORP. Contract:

Lab Codg: NUS-PGH Case No.: ME SAS No.: SDG No.:

Lab F i l © ID (Standard): BA511278801 Date Analysed: 11/27/88

Instrument. !D:45A TimeAnalyzed: 1500

Oi0203

; :

12 HOUR STD:1 UPPER LIMIT*

LOVEa LIMIT1

• SPA SAMPLE :NO. :

SU-SED-85U-SED-3MS :SW-SED-3MSD :

IS4CPHN) !AREA t I

___.- — _ _. _ _ t82800 I

1S5600 :

-41400 :

*

48900 I454OO I69200 I

RT

17. 52

17.4917.5017,50

IS5<CRY>AREA #

59200

118400

29600

323003050044400'

; RT: 24.19;

'

11

: 24. 17: 24. 17: 24.17

i sec PRY 'AREA t

45200

. 90400

22600

357003490049200

RT

27. 51

27.5127.5127.52

1IS4 *PHN) * Phenanthrene-dlO UPPER LIMIT = * IOO%!35'CEYv«ChrYsgne-dl2 of internaj^ standard area.15* 'PRY* * P«rv[*ne-dl2 LOWER LI M I T = - 5O96

cf internaI standard area.

* Cc. t:inn used to flag intgrna 1 standard area values with an asterisk

8BSEMIVOLATILE INTERNAL STANDARD AREA SUMMARY,

Lab Name: NUS CORP. Contract:

Lab Code: NUS-PGH Case No,: ME SAS No.: SDG No.:

Lab F i l e ID (Standard): BA511278301 Date Analyzed: 11/27/88

instrument ID: 45A . Time Analyzed: 1500

12 HOUR STD

t -ppcp LIMIT

LOWER LIMIT

EPA SAMPLENO.

SU-SED-8SW-SED-SMSSU-SED-8MSD

151 CDCB)AREA ft

23200

46400 --. — — _ _ _ _ — _ _

1 1 5OO

156001580023300

RT

6. 85

6-826. 726.78

IS2CNPT)AREA t

824OO

164800

41200

564005430078900

RT

9.62

9.609. 599, 60

I S3 (ANT?AREA fc

5O800

101600

25400

337002990045800

RT

13. 39

13.8713,3913.89

!S1 (DCS) = 1, 4-Dichlorobenzene-d4 UPPER LIMIT = + 100%IS2 fNPT) = Naphthalene-dS of internal standard area.•S3 CANT) = Acenaphthene-dlO LOWER LIMIT = - 50% '

o.f internal standard area.

J* Cciumn used to flag internal s tandard area values with an asterisk

AR30I79!


Lab Names NUS CDRP^ Contract:

Lab Codes NUS-FQH Case No.s ME SAS No.: SDG No.:

Instrument IDl 45A Calibration dates U/18/88 Time: 1OO6

Lab File IDs BA5111S88O2 Init. Calib. Date(s)s 1O/2O/B8 1O/2O/88

Mm RRF5O for SPCC<#> » 0,05O Max %D for CCC(*) « 2!

COMPOUND

JPhenol_________________i b is <2-Chloroethy1> Ether,12-Chlorophenol_________I 1,3-Dich1aroben zgne.I 1,4—Dichlorabenzene.!Benzyl Alcohol_____I1,2-Dichlorabenzene,12-Methylphenol_____ibis <2-Chloroisoprapyl)Ether;4-MethyIpnenol____________!N-N i t roso—D i-n-Prop y1am ine_!Hexachloraethane_________!NX trobenzene____________IIsophorone_______________12—Ni tropheno1____________!2,4-Dimethylphenol_______iBenzole Acid __Ibis<2-Chloroethoxy>Methane_I 2,4-Dichlorophenol_______11,2,4-Trichlorobenzene___!Naphthalene______________I4-Ch1oroan i1i ne__________IHexachlorobutad i ene______!4-Chloro—3—Methylphenol__* 2-MethyInaphthalene______IHenachlorocyclopentad iene_I 2,4, 6-Trichlarophenol____12, 4, 5—Tr-ich loropheno 1 ____12—Ch1aronaphtha1ene_____\2—Ni troani1ine__________:Dimethyl Phthalate.!Acenaphthylene____S2,6-Dinitratoiuene.S3—Nitroani1ine___J Acenaphthene______!2,4—Binitrophenol' 4-Ni t ropheno1___

5R301792


Lab Name: NUS CORP^ Contract:

Lab Code: NUS-P6M Case No.: ME SAS No.: SDG No.s

Instrument IP| 4BA Calibration date: 11/18/88 Time: 1O06

Lab File ID: BAS1118S8O2 Init. Calib. Date(s): 1O/2O/88 10/2O/B8

Min RRF5O for SPCC(tt) = O. OSO Max V.D for CCC<*> = 25.

COMPOUND

I Dibenzofuran_____________! 2,4-Dini trotoluene________iDiethyiphtnalate_________I4-Chlorophenyl-phenylethsr,IFluorene________________.' 4-Ni troani 1 ine___________!4,6-Dinitro-2-Methylphenol.IN—Ni trosodiphenylamina {1);4-Bromopheny1-phenylether_IHexachlorobenzene_________IPentachlorophenol________;Phenan threne ___________,'Anthracene_______________!Di-n~Butylphthalate_______I Fluoranthene__________.! Pyrene____________________!Butylbenzylphthalate______I 3,3'-Dichlorobenzidine,.' Benzo <a> Anthracene_______!Chrysene_________________:bis{2-Ethylhe;<yl)Phthalate.IDi-n-Octyl Phthalate_____I Ben zo < b)F1uoranthene______!Benzo(k)Fluoranthene_____!Benzo(a)Pyrene___________!Indeno<1,2,3—cd)Pyrene___IDibenz(a,h)Anthracene_____JBenzo<g,h,i)Perylene______

!Ni trobenzene— _;2-Fluorobiphenyl:Terphenyl~dl4__!Phenol-d5______!2—Fluorophenyl__2, 4t 6-Tr ibramophenol.

RRF IRRF50 ! V.D

1.591J 1.432! 10.O0.3511 0.339! 3.41.121.' 1.152! -2.80.6261 <X618! 1,31.324! 1.244; A.Q,0.279! O. 1581 X43.40.141! O.125! 11.4'O.546J 0.564! -3.3O.204,1 O.201! 1.50.223! 0.2161 3.10.137! 0.131! 4.41.O82! 1.06O.' 2.O1.005! 0.886: 18.31.193.' 1.176! 1.40.969! 0.924S 4.61.731! 1.413! 18.4O.795! 0.7O9J 1O.80,273; On313!-14.71.554! 1.411! 9.21.149! 0-912! 2O.61.O65! 1.145! -7.51.927! 2.014; -4,51.77O! 1.664: 6.O1.1O4; 1.218J-1O.31.131! 1.176! -4.00.9945 1.090! -9.7O.81O! O.S04! 0.70.871! O.S47! 2.8

O.366! O.376! -2.71.387! 1.479! -6.61.279! 1.296! -1.31.603! 1.7931-11.91.280S 1.076! 15.9O.153I O.168! -9.8

(1) Cannot be separated from Diphenyianune

UR301793


Lab Names NUS CORP.- Contract:

Lab Codes NUS-P6H Case No.: ME SAS No.: SDG No.s

Lab File ID (Standard)s BA5111SBBO2 Date Analysed! 11/lB/BB

Instrument IDs 45A Time Analyzed: 10O6

12 HOUR STD

UPPER LIMIT

LOWER LIMIT

EPA SAMPLENO-

SW-SED-7SW-SED-7MSSW-SED-7MSD

IS4(PHN)AREA #

878OO

1756OO

439OO

973OO913O09750O

RT

17.00

17.0O16.9916.99

IS5<CRY)AREA #

5610O

11220O

28050

559OO5O6OO5O6OO

RT

23.64

23.6423.6023.62

IS6CPRY)AREA *

415OO

83000

20750

4610O4O6OO37OOO

RT

26.96

26.9726.9426.94

0102

IS4 CPHN) « Phenanthrene-dlO UPPER LIMIT = -*• 1OO'/CIS5 (CRY) = Chrysene-dl2 of internal standard area.IS6 (PRY) « Perylene-dl2 LOWER LIMIT = - 5OX


# Column used to flag internal standard area values with an asterisk

SBSEMIVOLATILE INTERNAL STANDARD AREA SUMMARY

.Lab Name: NUS CORP- Contract:


Lab File ID (Standard): BA5111888O2 Date Analyzed! 11/19/88

Instrument IDs 45A Time Analyzed: 1OO6

01O2O3

12 HOUR STD

UPPER LIMIT

LOWER LIMIT

EPA SAMPLENO.

SW-SED-7SW-SED-7MSSW-SED-7MSD

IS1 (DCB)AREA #

268OO

53600

1340O

29200280OO29600

RT

6.43

6.436.4O6.4O

IS2<NPT)AREA ft

92100

18420O

46050

9520O97OOO9920O

RT

9.17

9.159.159.15

I S3 (ANT)AREA tt

55 1 OO

1102O0

27550

6160O578OO6O70O

RT

13.40

13. 4O13.3913.39

IS1 (DCB) = !14-Dichlorobenzene-d4 UPPER LIMIT = + 1OOXIS2 (NPT) = Naphthalene-dB of internal standard area.IS3 <ANT) = Acenaphthene-dlO LOWER LIMIT = - 5OX

_of internal standard area.i# Column used to flag internal standard area values with an asterisk

AR30I795


CALIBRATION - DECAFLUOROTRIPHENYLPHOSPHINE fDFTPP?

ib Name: NUS CORP. Contract:

',.3'n. Cod«: NUS-PGH Case No.: ME SAS No.: SDG No.:

La:r:FJie ID: DF511188805 DFTPP Inlection Date: 11/18/38

:-.-truTsnt ID: *5A DFTPP Iniection Time: 0831

: • • : % RELATIVE • :; m/e ; ION ABUNDANCE CRITERIA I ABUNDANCE

51 : 30.0 - 60. O% of mass 198____________________________• 48.0•717 . :_9 s t.han 2.0% of .mass 59 ___________•-- __________'. 0.0 f .0.0; I'69 ' .Mass 69 relative abundance^ ________________________; 4-4,?T0 ' :.f?s- than 2.0% cf mass 69 ________________________: 0.0 < O-0>i:127 ' 40.0 - 50,0% of mass 196 - _____________________' 43.0

' I" «:?ss i-Kan 1 . ~j% of ftass 198_________~_______________.I... 0.0... . 'Boce pea!:. 100% relative abundance__________________\ 100.0 :5-0 to 9.0% of mass 196_________;______- __________' 5.2

: 10.0 - 3C.QX of mass 198______;___________________I 22.5 :: Greater than l. 00* of mass 1S8______________________,' 1.78 IPresent, but- less than mass 443 ______- - . : 7.4.

1 Grater than 40.056_ of .mass 198______________________: 57.1 :.f " 17. 0 -"23-0% of mass 442__________-_________________' 9.8 f 17.1)2-'

1-VsIue is % mass 69 2-VaJ ue is % mass *42

TVN? APPLIES TO THE FOLLOWING SAMPLES. MS..«SD. BLANKS. AND STANDARDS:

EPASAMPLE NO .

01 ' SETD05002 ' SW-SED-703 : SW- SED-7MS0'! • SU-3HD-~MSD

-

LABSAMPLE ID

SSTD050P104074P104074MSP104074MSD

LAB. FILE ID

BA511188802C5111888010511188802"C511188803

: DATE :: ANALYZED '

: ii/18/88 :! 11/18/88 !; ii/ie/88 :: 11/13/38 :

TIMEANALYZED

1005110311501235

5R30I796


Lab Names NUS COR£._ Contract:

Lab Codes NUS-PSH Case No.s ME SAS No.: SDG No.:

Instrument IDs 45A Calibration date: 11/17/BB Timei 1221

Lab File IDs BA511178SO2 Init. Calib. Date<s>: 1O/2O/88 10/2O/88

Mm RRF5O for SPCCC#> s O.O5O Max 7.D for CCC(*> « 25

COMPOUND

.' Phgno 1 _________________*bis(2-Chlaroethyl>Ether.;2-Cnlarophenol_________1, ~-Dichlaraben;:ene_1„4—Dichlorabenzene,

l Alcohol!1,2-Dichlarabenzene_\2-MethyIphena1_____!bis(2—Chloroi^apropyl)Ether;4-Methylphenal____________'N-N11 roso—D i-n—Propy1am i ne_#J He:sach loroethane_________JNitrobenzan©_____________JI^opharone_______________12—Nitraph^nol____________12,4-Dimethylphenal_______!Benzo ic Ac id_____

Dichlorophenol* 112,4—Trichlorobenrene_I Naphthalene___________*4-Chloroani1ine_______'Hexachlorobutad i ene___S 4-Chlaro—3-Methylphenol.I2-Methylnaphthalene___!Heuachlorocyclopen tad it2,4,6-Trichlorophenol!2, 4,5-Tr*ichlorophenol!2—ChloronaphthaleneS 2-Nitraan i1ine!Di««thyl Phthalate,!Acenaphthylene____12,6—Dinifcrotaluene_!3-N i t roan illne___IAcenaphthene______; 2, 4-Dxni trophenol.:4—Nitrophenol___

AR3QI797


Lab Name: NUS CORP. -Contract:

Lab Codes NUS-PBH Case No.: ME SAS No.: SDG No.:

Instrument ID: 45A Calibration datei 11/17/88 Timei 1221

Lab File ID: BA51117S8O2 Init. Calib. Date(s): 1O/2O/88 1O/2O/88

Min RRF5O for SPCC(#> = O.O5O , Max %D for CCC<*> =25.*

•! COMPOUND

! Dibenzof uranI 2. 4— Din it ro toluene\ Diethylph tha late: 4-Chlorophenyl-phenylether_! Fluorene! 4-Ni troan i 1 ineJ 4, 6-Dini tro-2-Methy lphenol_!N-Ni trosodi pheny lam ine (1>_*! 4-Bromophenyl-phenylether _! Hexach 1 oroben zene!Pentachlorophenol •»IPhenanthrene! AnthraceneJDi-n-ButylohthalateI Fluoranthene *I Pvrene! But ylbenzylph tha lateI 3, 3 '—Dichlorobenzidine ____! Benzo <a) Anthracene!Chrvsene!bis(2-Ethylhexyl)Phthalate_!Di-n-Octvl PhthalateI Benzo (b) Fluoranthene? Ben zo ( k > F 1 uoran thene! Benzo (a) Pyrene *! Indeno(lt2T3-cd) Pyrene! Dibenz (aT h) AnthraceneI Benzo <qThT i)Perylene1 <— - - ^_r

! Ni trooensene-dS! 2-FIuorobiohenvl! T»roh«nvl-dl4!Phenol-d5I 2-FluoroDhenvl! 2. 4T 6— Tribromophenol;

•*RRF !

1.591 !0.351 !1.121:0.626.*

O.279!0. 141 !0.546!0.2O4!0.223!O. 137!1 . O82 !1 . 085 !1.193!O.969!1.731 !0.795!0.273!1 . 554 !1.149!1 . O65 !1 . 927 !1.77O!1.104!

^ 1. 131 :O. 994 !O.810:o.87i:O.366!1.387!1 . 279 !1-6O3!1.280!O. 153!

!

*

RRF5O !

1 . 534 I0.349!1. 14O!O.610!1.215!O. 183!0. Ill !0.485!0.207!0.219!0. 134!1 . O52 !0.893!1.195!O.916!1 . 564 !0.742!0.217!1 « 354 !O.93911 . O75 !•*k ~yvr •4^ * *imti* f *

1.692!O.955!1.158!O.966!O. 8O4 iO.921!

O. 384 !1.538!1.453!i . 700 :1 . 224 !O. 167!

I

•/.D

c»« 6O.6

-1.72.6

'-.34r421.311.2 *-1.51.8r* i2.8

17.7-0.25.59.66.7

20.512.918.3-0.9

-15.64.4

13.5-2.42.80.7

-5.7

-4.9-1O.9-13.6-6. 14.4

-9.2

(1) Cannot be separated from Diphenylamina

&R301798

acSEMIVOLATILE INTERNAL STANDARD AREA SUMMARY

Lab Names NUS CORP, Contract:

Lab Codes NUS-PGH Came No.s ME SAS No.: SDG No.:

Lab File ID (Standard)2 BA51117SSO2 Date Analysed! 11/17/88

Instrument IDs 45A Time Analyzed: 1221

t1I1

! 12 HOUR STD

J UPPER LIMIT

! LOWER LIMIT

! EPA SAMPLENO.

01 ISW-SED-102ISW-SED-14O3!SW-SEs -1504JSW-SED-2OS ! SW-SED-306 J SW-SED-407:SW-SED-5OS ! SW-SED-609j3BLF,5E

t IS4(PHN>AREA #

842OO

16S4OO

421 GO

soooo628OO685OO722OO742OO6620O692OO77500763OO

RT

17.04

17. CO17.0017.0217. CO17. OO17.0217. O417. O217.04

ISS(CRY)AREA #

481OO

962OO

24O5O

4610O2850O4440043200423OO3920O484OO497004O20O

RT

23.65

23.62T*T -i."—•_• . O*£,

23.6523.6223.6423.6523.6723.6523.65

IS6(PRY>AREA tt

347OO.

694OO

1735O

4300021300435OO422004O10O3S4OO510OO4750O33700

.

RT

26.97

26.9626.9426.9926.9626.9726.9927.0126.9926.97

154 <PHN> - Phenanthrene-dlO UPPER LIMIT - •*- 1OO7.IS5 (CRY) « Chrysene-dl2 of internal standard area.tS6 (PRY) ^ Perylene-dl2 LOWER LIMIT = - 507.


# Column used to flag internal standard area values with an asterisk

301799


Lab Name: NUS CORP,. : Contract:

Lab Code: NUS-PGH Case No.: ME . SAS No.: SDG No.:

Lab File ID (Standard)! BA51 1178302 __ Pate

Instrument ID: 45A Time Analyzed: 1221

1f1

t — _— _..-- — __ — — —

: t2 HOUR STD

I UPPER LIMIT

! LOWER LIMIT

! ERA SAMPLE: NO.

01 ISW-SED-lO2JSW-SED-1403ISW-SED-1504 I SW-SED-205ISW-SED-306ISW-SED-407ISW-SED-508 ! SW-SED-6O9 I SBLK5E

IS! (DCB)AREA #

262OO

524OO

131OO

269O022 1 OO—256OO225OO23OOO23OOO261 OO239OO23OOO

RT

6.47

6.426.456.426.426.456.426.436.426.48

IS2(NPT)AREA #

876OO

1752OO

438OO

902OO7360O888OO736OO.773OO769OO844OO8O4OO7830O

RT

9^1 **\. *_—

9. 179. 199. 179. 179. 199. 199. 199,179.20

IS3(ANT)AREA ft

517OO

1 0340O

2585O

5530O471OO530004690O477OO448OO525OOSO 3 OO499OO

i•RT

13.45

13.4O13.4213.4213.4013.4213.4213-4213-4213.44

IS! (DCB) - l,4-Dichlorobenzene-d4 UPPER LIMIT = + 10O7,152 (NPT) = Naphthalene-dB of internal standard area.TS3 (ANT) = Acenaphthene-dlO ._ LOWER LIMIT = - 507.


tf Column used to flag internal standard area values with an asterisk

flR30J800


CALIBRATION - DECAFLUOROTRIPHENYLPHOSPHINE (DFTPP)

* Lab Names NUS CORP. Contract:

Lab Codes NUS-PGH Case No.: ME SAS No.: SDG No.s

Lab Fila IDf 0F51117S8O3 DFTPP Injection Date: 11/17/88

Instrument IDs 45A . DFTPP Injection Time: 1153

m/e

51686970127197198J99275*~<oZ>441442443


3O.O - 60. OX of masm 198Less than 2. OX of mass 69Masm 69 relative abundanceLess than 2. OX of mass 694O.O - 60. OX of mass 198Less than l.OX of mass 198Base peak, 100X relative abundance5.0 to 9. OX of mass 1981O.O - 3O.OX of mass 198Greater than l.OOX of mass 198Present, but less than mass 443Greater than 4O.OX of mass 19817. O - 23. OX of mass 442

7. RELATIVEABUNDANCE

54.70 . 0 ( O . O ) 1

— lsl> . O

0 . 0 ( 0 . 0 ) 151.20.0

10O.O6.218. 11.456.854.39.4 ( 17.4)2

1-Value is 7. mass 69 2-Value is X mass 442ITHIS TUNE APPLIES TO THE FOLLOWING SAMPLES, MS, MSD, BLANKS, AND STANDARDS:

! EPA! SAMPLE NO.

01!SSTD05Oor : SBLKSEO3ISW-SED-14O4SSW-SED-1OS I SW-SED-2O6ISW-SED-407SSW-SED-15OB 1 SW-SED-3O91SW-SED-51C! SW-SED-6

«i

LABSAMPLE ID

SSTD050SBLKSEPI 03868P1O3935PI 03937P1O3939P1O3941P1O4O67PI O4069P 104071

LABFILE ID

BA5 11 178802CB51 It 78801C5111788O1C5 11 1788O2C5 11 1788O3C5 11 1788O4C51 11 78SO5C51 11 78806C5 111 78807C5 11 I788O8

DATEANALYZED

11/17/8811/17/8811/17/8811/17/8811/17/8811/17/8811/17/8811/17/8811/17/8811/17/88

TIMEANALYZED

1221145115381624171117591846193820252112

&R3Q180!


Lab Name: NUS ytjjtr' ' ' -. -.J/ Contract;

Lab Code: NUS-ff»*p^C«» Wo.: ME SAS No.: SDG No.:' • V. • "

Instrument ID: 4d#* Ca1ibration date; 11/15/88 Time: O757*i

Lab File ID: BA511158801 Init. Calib. Date(s): 10/20/88 10/20/88

Min RRF50 for SPCCC*) * 0.050 Max XD for CCC(*) = 25.0

COMPOUNDP h e n o l _ _ _ _bis(2-Chloroethyl)Ether-ChlorophenoI

1.934! 1.597! 17, 41.554! 1.710!-10.01.432! 1.346! 6.01.538! 1.528! 0.71.583! 1.668! -5.40.682! 0.598! 12.31.573! 1.443! 8.31.208! 1,078! 1Q. 81.809! 2.266.V:v25.3K

'"-Nitro-o-O.-n S uSI :; l 'l *_£*

i «3-Di ch1orobenzene_______1,4-Dich1orobenzene_______Benzyl Alcohol____________i,2-Dich1orobenzene________2-Methylphenol ____________bis(2-Chloroisopropyl)Ether4-MethyIpheno1____________

Hexachloroethane_________Ni trobenzene_____________I sophorone_______________2-Ni trophenol_____________'2,4-Dimethylphenol________Benzo ic Acid______________bis(2-Chloroethoxy)Methane_2, 4-0ich I oropheno 1________•

0.6651 0.564! 15.20.412! 0.428! -3.90,7011 0.722! -3.00.232! 0,202! 12.90.311! 0.288! 7,40.250! 0.173! 30T80.434! 0.434! "o7b0.313! 0.290! 8.80.369! 0.351! 4.91.179! 1.069! 9.3

H.x.oMorobut.dI n=i £?£! 0°! JJJ!

1,2,4-Trichlorobenzene.Naphthaiene__________4-Chloroani1ine______

RRF IRRF'SO ! XD

!4-Chloro-3-Methylphenol___* 0.286! 0.273! 4.5!2-MethyInaphthalene_______! 0.596! 0.585! 1,8IHexachlorocyclopentadiene_# 0.297! 0.254! 14,5!2.4.6-TrLohtoroPheno1 » 0.389! 0,359 ! 7.

;__r.......______, 0.394! 0.353! 10.2-Clg7ronmf»htha 1 en*.2-N iomnf Jiti»

, 1 Phthalate.Acen»phthylen«___2,6-Dinitrotoluene.3-Nitroan11ine___Acenaphthene_____________* 1.050! 1.0282.4-Dinitrophenol^_________t 0.154J 0.0664-Nitrophenol_____________t 0.100! 0<Q62

1.155! 1.1321 2.0.303! 0.306! -1,1.169! 1.155! 1.1.712! 1.596!0.310! 0.292!0.304 j 0.102:

flR30!802


Lab Name: W& S Bf -- ~ Contract:

Lab Code: NUS-P 'C&se No.: ME SAS No.: SDG No.:

Instrum*nt ID: 4MT" Calibration data: 11/15/88 Time: 0757

Lab File ID: BA5111588O1 Init. Calib. DateCs): 10/20/88 1O/20/8S

Min RRF50 for SPCC<*> ^ 0.050 Max XD for CCC(*) = 25.(

• 1

: COMPOUND! Dibenzof uran!2.4-DinitrotolueneiDiathvlphthaiateI &-Chloraph©nyl-phenylether_! F I uorene! 4-Ni troani I ine:A,6-Dinitro-2-Methylph@nol_! N-Ni trosodi pheny I am ine ( 1 ) _: A-Bromcpheny 1 -pheny 1 ether _I Hexach I orobenzene! Pentachl oropheno 11 Phenanthrene! AnthraceneiDi-n-Buty Iphthalate! FI uoranthene! Pyrene: Butyl benzyl phthalate13, 3 '-Dichlorobenzidine ____! Benzo (aJAnthraceneIChrysene!bisC2-Ethylhexyl )Phthalate_SDi-n-Qetyi Phthalate! Benzo(b>Fluoranthene:Benzo(k)F! uoranthene: BanzoCaJPvrene: IndanoCl.2. 3-cd)Pvrene1 Dih*njEtaP h) AnthracenetBenrfTf . h. DPervlene«:NItMb«nz«n»-d5! 2-FlHareb I pheny 1!Terph«nyl-dl4!Phenot-d5!2-Fiuoroph«nyI: 2. 4.6-Tribromopheno 1:

RR

1.0.1.0.1.0.0.0.0.0.0.1.1.1.0.1.0.0.^ t

1.1.1.1.1.1.0.0.0.

0,1.1.1.1.0,

F

591351121626324279141546204223137082085193969731795273554149065927770104131994810871

3663872796O3280153

R, —iIi•iii•

i>t•itti*i•*•iiit•tiit*ii!it«•

i<*«iii»i!

RFs s

1.0.1.0.1.0.0.0.0.0.0.1.0.1.o.1.0.0.1.0.1.2,1.1.1.0.0.0.

0.1.1.1.1.0.

50 :480!334!1O1 !616!247!156!095!477!213!235!122!071!928!265!985!517J742!166!339!929!078!114!617!235!146!913!769!344!S S 3 3

379!501!422!732!290!154 !

!

XDs s = s

7,4.i.1.5.44."32.12.-4.-5.11,1,

14.-6.-1.12.

39.13.19.-1.-9.8.

-11,-1.8.5.3._ _ « _-3.-8.

-11.-8.-0.-0.

08868l'-i-6 •""644005074728 227693111— —622087

C1) Cannot be- separated from Diphenylamine

AR3018Q3

8CSEMIVOLATILE INTERNAL STANDARD AREA SUMMARY<

Lab Name: NUS CORR_ Contracts


Lab File ID (Standard): BA51115S8O1 Date Analysed! U/15/BB

Instrument ID: 45A Time Analyzed: 0757

OlO203O40506070809!Ot t12

12 HOUR STD

UPPER LIMIT

LOWER LIMIT

ERA SAMPLENO.

SW-SE0-10SW-SED-11SW-SED-12SW-SED-13SW-SED-16SW-SED-3SW-SED-5SW-SED-6SW-SED-7SW-SED-9SBLK5CSBLK5D

IS4<PHN)AREA #

875OO

1 75OOO

43750

1 O 1 OOO71400768OO8O70O94OOO1 O4OOO964OO989OO86OOO1O2OOO9370O9980O

RT

17.O9

17. O717. O717.0717.0717.O717. O717.O917.0917.0717.0717.0717.07

ISS(CRY)AREA #

S69OO

1 1 38OO

28450

586OO38OOO435QQ449OO558OO5920O556OO486OO4370O5450049 IOO569OO

RT

•*»"'' T*™*—-j. / —

23. 7O23.7523. 7O23. 7O" 7 ftA. •— • • / *.'

23. 7O23, 7O23, 702306923.. 7023.7023-70

IS6CPRY)AREA *

438OO

87600

21900

417OO327OO356OO3920O446OO485OO4670O3570033 1 OO449OO392OO449OO

•RT

27.04

27.0227. O227.0227 . 0227.022 7. O22 7. 6227.0227. O I27 . 0227.0227.02

IS4 (PHN) = Phenanthrene-dlO UPPER LIMIT = + 10O7.IS5 (CRY) - Chrysene-dl2 of internal standard area.156 (PRY) = Perylene-dl2 LOWER LIMIT = - SO*



8BSEMIVOLATILE INTERNAL STANDARD AREA SUMMARY

Lab Name: NUS CORR~ Contract:


Lab Fila ID (Standard)i BA5111588O1 Date Analyzed: 11/15/88

Instrument IDs 45A Time Analyzed: O757

O4OS06O70809

;!

! 12 HOUR STD

t UPPER LIMIT

: LOWER LIMIT

I EPA SAMPLEI NO.

,'SW-SED-IOiSW-SED-i tJSW-SED-12!SW-SED-1~ISW-SED-16! SW-SED-3J SW-SED-5! SW-SED-6! SW-SED-7! SW-SED-9! SBLK5C! SBLK5D

IS1 (DCB)AREA #

2S7OO

S740O

1 435O

30OOO2B6OO257OO2S3OO298OO3O30O297OO298OO281OO325OO279OO314OO

RT.

6.52

6.486.456.476.526.436.526.47O . J ,

6.436,476,486.43

IS2(NPT)AREA #

972OO

1944OO

4S6OO

1 O3OOO942OO8O1OO8 1 9OO932OO948OO969OO972OO9O7OO1O9OOO9 1 BOO9830O

RT

9,25

9.249^^"V. *L-f~o •">*•?*

9.249. 229.249.249.249 . 2O9T?• *!.*•

9.249. 22

153 (ANT) IAREA ft

S720O

1 1 44OO

28600

642OO5 5 BOO5O2OO521OO6 1 9OO626OO599OO615OO5620O6720O6060066400

•RT !

13.49!

!

:•i:

13.47!13.47!13.47!13.47!13.47113.47-!13.49!13.49:13.47:13.47113.47!13.49!

IS1 (DCB) - l,4-Dichloroben=ene-d4 UPPER LIMIT = +IS2 (NPT> - Naphthalene-d8 of internal standard area.IS~Z <ANT> « Acenaphthene-dlO . LOWER LIMIT = - 5O7.


$ Column used to flag internal standard area values with an asterisk

flR301805

SBSEMIVOLATILE ORGANIC GC/MS TUNING AND MASS


Lab Name: NUS CORP. Contracts

Lab Code: NUS-PGH Case No.: HE SAS No.j SDG No.:

uan Fil* ID: DF51115S8O2 DFTPP Injection Date; 11/15/88

Instrument ID: 45A DFTPP Injection Time: 0729

!,i>/e ! ION ABUNDANCE CRITERIA

5166•SQTO

i ~* "•*197

, 198J9927536544144244.7

70.0 - 6O..O% of mass 198Less than 2. 07. of mass 69M.*ss 69 rotative abundanceLess than 2.O7. of mass 694O . O - 60 . O7. o f mass 1 98Less than 1 . OX of mac??, 198Ba^*^ poaK, lOO'i relat ive abundance5.O to <9.07. of mass 1981O.O - 3O.OX af mass 198Greater than 1 . OO7. of mass 198Present, but less, than mass 443Greater than 4O.OX of mass 19817.O - 2 .02 of mass 442

'/. RELATIVEABUNDANCE

42.40.0 ( O. <>'• 1

40.8O. 0 i O* *"• f 1

41.2<"** '"*

1 <"«0 . (">5.8

22.01.735.7

43.87.7 ( 17.5)2

*1-Value is % mass 69 2— Value is 7. mass 442

LHIS TUNE APPLIES TO THE FOLLOWING SAMPLES, MS, MSD, BLANKS, AND STANDARDS:

EPA J LAB! SAMPLE NO. ! SAMPLE ID

o i ; ssTDOSo ; SSTDOSOi"i ' C CrI t ' f ' CCrt l ' f*'.'». < ot?i_r ,j(— i iDoi—r-.oL,O3!SW-SED-3 I P1O4O6604ISW-SFD-5 I P1O406805 : 3W-SED-6 I P1O4O7OO6 I SW-SED-7 ! P1O4O73•>7 I SW-SED- 16 I P 1 04075O8 ! SBLK5D ! SBLK5Dfi9 I SW-SED-9 ! P 1O38 1 9I O ! SW-SED- 1 O ! PI O3B2O1 L ISW-SED-11 I P103S21I 2 ! SW-SED- 12 ! P 1 0386413!SW-SED-13 ! PI O3B66

• «

LAB ! DATE' FILE ID

BA5 111 58801CBS 13 1538O1C511 1588O1C51 11 58802C5 1 1158803C51115B8O4C51 115S8O5CBS 11 158802CS 111 58806C51 1158807C51 I 158808C5I 11588O9CS1 11588 10

ANALYZED

11/15/S811/15/881 1 /15/8811/15/88I 1/15/8811 / 15/8811/15/9811/15/88i 1/15/8811/15/881 1/15/8811/15/88t 1/15/88

TIMEANALYZED

0757O9261O36112212421^26i 4 1 014551 5401625171017551851

flR30!806




Lab Codes NUS-PGH Case No.: ME SAS No.: SDG No.s

Lab File IDs DF51114S8O1 DFTPP Injection Dates 11/14/88

Instrument IDs 45A DFTPP Injection Time: O7OB

m/e

5168697O127197198199275365441

, 442443


3O.O - 6O.O% of mass 198Less than 2.0% of mass 69Mass 69 relative abundanceLess than 2.O% of mass 6940.0 - 60.0% of mass 198Less than I. OX of mass 198Base peak, 1OO% relative abundance5.O to 9.07. of mams 19810.0 - 30.0% of mass 198Greater than 1,QO% of mass 198Present, but less than mass 443Greater than 40.0% of mass 19817. O - 23.0% of mass 442

•

7. RELATIVEABUNDANCE

49.6O.O < O.O)45.3.O.O ( O.0>48.0O.O

1OO.O6.519.11.4B5.745.18.5 ( 18.8)

1

1

-?

1-Value is 7. mass 69 2-Value is 7. mass 442

THIS TUNE APPLIES TO THE FOLLOWING SAMPLES, MS, MSD, BLANKS, AND STANDARDS:

: EPA! SAMPLE NO.

Ol SSSTDOSO02 ! SBLK5A03 \ SW-SED-304 I SW-SED- 1205! SW-SED- 12MSO6 S SW-SED- 12MSD07 \ SW-SED- 1308ISW-SED-1409 ! SBLK5BIO! SW-SED- 1t 1 \ SW-SED-212SSW-SED-413SSW-SED-15

i

LABSAMPLE ID

SSTD050SBL.K5AP1O3B61P1O3863P1O3863MSP1O3B63MSDP1O3S65P1O3867SBLK5BP1O3934P103936P1O3938P1O3940

i

LABFILE ID

BA5 11-1 488O1CB51 11 48801C51 11 48803C511148BO4C5111488O5C5111488O6C51114B807C51 1148808CB51 11 48802C5111488O9C51 1148810C51 1148811C51 1148812

DATEANALYZED

11/14/8811/14/8811/14/8811/14/8811/14/8811/14/8811/14/8811/14/8811/14/8811/14/8811/14/8811/14/B811/14/BB

TIMEANALYZED

072910451132121913O413491434151916O4165O1737182219O7

flR30!807

1 ., B. 78SEMIVQLATILE CONTINUING CALIBRATION CHECK

Lab Names NUS CORP^ Contracts

Lab Code; NUS-P8H Case No.: ME SAS No.: S06 No.£

Instrument IDs 4SA Calibration dates 11/14/88 Timei O729

Lab File ID: BA5111488O1 Init. Calib, Date(s)s 1O/2O/88 1O/20/88

Mm RRF5O for SPCC<#) = O.O5O Max %D for CCC(*) « 25. C

COMPOUND

! Pheno 1 _____________"Ibis(2-ChloroethyI)Ether.I2-Ch1oropheno1_________!1,3~Dichlorabenrene.!1,4-Dichlorobenzene_.' Ben zy 1 A1 coho I _____!I,2—Dichlorobenzene,!2-Methyiphenol_____Ibis(2—Chloroisopropyl>Etherf4—Methylphenol____________! N-N i t r oso-D i —n—Propy 1 am i ne_JfI He::ach 1 oroethane_________INi trobensene_____________IIsophorone______________2-Ni trophenol_____

i 2, 4-Dimethylphenol,Ben zo i c Ac i d_____•Ibis <2-Chloroethoxy)Methane,!2,4-Dichlorophenol________I 1,2,4—Trichlorobenzene.!Naphthalene________I4-Ch1oroan i1ine___________! He:;ach lorobut ad i ene_______*!4-Ch1aro-3-«ethy1phenol___*I 2—Me thy Inaphthalene_______JI Hex ach1orocyc1open tad i ene_#! 2, 4, 6-Trichlorophenol_____*!2,4,5-Trichlorophenol____•2-Ch1oronaphtha1ene______!2-Ni troan i1ine__________.'Dimethyl Ph tha late,!Acenaphthylene___12,6-Dini trotoluene.!3-N i troan i1i ne___•' Acenaphthene_____________*! 2, 4-Dini trophenol_________#! 4-Ni trophenol_____________#

O.3160,0831.042O.051O.O64iX36.0 If

flR301808

7CSEMIVOLATILE CONTINUING CALIBRATION CHECKt

Lab Names NUS CQRg^ Contracts

Lab Codes NUS-P6H Case No.s ME SAS No.: SDG No.:

Instrument IDs 45A Calibration dates 11/14/88 Timet O729

Lab File ID: BA51114S8O1 Init. Calib. Date(s)s 10/2O/88 10/2O/88

Min RRF50 for SPCC<#) » 0.05O Max %D for CCC(*> ^ 25.

1t! COMPOUND

: Dibenzof uranI 2, 4-Dini tra tolueneIDiethylph tha lateS 4-Chlorophenyl— phenyletber_! Fluorene! 4-Ni troan i 1 ineI 4, 6-Dini tro-2-Methy lphenol_!N-Ni tromodiphenylamine <!)_•*I 4— Bromopheny l-phenylether _! Hexach loroben zene' Pentachlorophenol *I Phenanthrene'AnthraceneiDi-n-Butvlohthalate! Fluoranthene •»! Pvren©IButylbenzylph tha late! 3, 3 '-Dichlorobenzidine* Benzo (a) AnthraceneJChrvsene! bis (2-Ethylhexyl ) Phthalate_;0i-n-Octvl Phthalate ^I B^nzo (b > FluorantheneI Ben za ( k > F 1 uoran thene! Benro (a)Pvrene •»I Indeno < 1 , 2, 3-cd ) PvreneJDibcnz ( a, h) Anthracene!B*nzo<QTh, DPerylene

* Ni trobenzene-d5J2— Fluorofaiohenvl!T«rDh«nvl-dl4SPhenol-dS; 2— Fluoroohenvl! 2« 4«6— Tribromoohenoli

RRF

1.5910.3511. 121O.6261.3240. 279O. 141

* O . 5460.2O40.223

^ 0- 1371.0821.0851. 193

f 0.9691.731O, 7950.2731.5541.1491 . 065

* 1.9271 . 7701. 1O4

f 1.1310.994O.810O.S71

O.3661.3871.2791 . 6O31.28OO. 153

JRRF5O !

! 1.51O!I 0.339!j j. 171 j! O.631!: 1.245;: O.O84!! O.077!: 0.421:J 0.238!! 0.2631: o. 130;: 1.O23!I O.927!: 1.162:! 0.897:I 1 . 545 :! O.744!: 0.113:: i . 336 :J O.987!! 1 . 079 !: 2,192!! 1 . 599 !: i . 250 i: 1.13O!! 1 . 065 !! 0.772!: 0.896;i fi ^QA *

: i . 547 :: i . 435 ;; i . 703 :: i . 253 :! O. 149!• 11 (

%D

5. 13.4-4.5-O. 86.069.9 S'45.4 y

22.9 *-16.7-17.95. 1 *5.514.62.67.4 *1O.86.458.614.O14. 1-1.3-13.8 *9.7

— 13. 2O.I *-7. 14.7-2.9

-5.5-11.5-12.2-6.22. 12.6

t'l) Cannot da separated from Diphenyianune

P-

^

SR301809


Lab Name: NUS CORF*. Contract:


Lab File ID (Standard)s BA5111488O1 Date Analyzed: 11/14/88


t

I 12 HOUR STD

! UPPER LIMIT

I LOWER LIMIT

I EF-A SAMPLE! NO.

Ol f SW-SED- I02ISW-SED-1203-1 SW-SED- 1 2MSO4J SW-SED- 12MSD05 ! SW-SED- 1306! SW-SED- 1407! SW-SED- I 5O8 ! SW-SED-2O9 ! SW-SED-4KHSW-SED-B1 L ! SBLK5A12JSBLK5B!

IS4(PHN)AREA tt

81 BOO

1636OO

4O900

86 1 OO790OO893OO939OO86 2008 1 00084OOO854OO832OO8300O _745OO816OO

RT

17. 10

17.0517, O717.0917. O91 7. O917.0717.0717.0517.0717. O917.0917.O7

ISS(CRY)AREA ft

488OO

976OO

244OO

4370O447OO5O0O0537OO471OO4 1 OOO454OO446OO45OOO459OO417004770O

RT

23.74

23.6723., 7O23. 7O23.6923.7023.7023. 6923.6923.6923.7023. 7O23.69

I 56 (PRY)AREA *

365OO

73OOO

18250

380003S0OO42100465OO441OO346OO4O5OO379OO4 1 3003780037 1 OO448OO

RT

27. O6

27.0127.0227.0227.0227, O42 7. O227.0127. Ol27.0127.0227. 0427.01

TS4 <PHN) = Phenanthrene-dlO UPPER LIMIT = -*- 1OO%tS5 <CRY) =-- Chrysene-dl2 of internal standard area.156 (PRY) ~ Perylene-dl2 LOWER LIMIT = - 5O7.

of internal standard area,

8 Column used to flag internal standard area values with an asterisk



Lab Codes NUS-PGH Case No,: HE SAS No.: SDG No.:

Lab File ID (Standard)s BA51I148801 Date Analyzed: 11/14/88


t1t

I 12 HOUR STD

! UPPER LIMIT

! LOWER LIMIT

! EPA SAMPLE. : wo.01 ; SW-SED- iO2I SW-SED- 12O-> I SW-SED— 12MSO4! SW-SED- 12MSDOS I SW-SED- 1306! SW-SED- 1407! SW-SED- 15081 SW-SED-209 ! SW-SED-410ISW-SED-81 1 ISBLK5A12JSBLK5B

ISI CDCB)AREA *

297OO

594OO

1485O

299OO293OO3OOOO297OO27BOO28OOO293OO293OO2970O277OO277OO2930O

RT

6,45

6.456.476.456.476.476.456.436,456.436,456.5O6.45

IS2(NPT>AREA ft

9910O

1 982OO

4955O

959OO95BOO100OUO

• 1O3OOO884OO953OO944OO931OO938 OO953OO931OO946OO

RT

9.25

T. i*_9.24. A.

9.249.229^^o. .kM.O OO

9.229. 2O9.249.24900. *_*»

1S3<ANT)AREA ft

567OO

113400

28350

595OO594OO596OO5960O556 OO5580O575OO590OO58200571OO564005650O

RT

1 3 . SO

13.4713.4913.4913. 4913.4913.4913.4713.4713.4713.4913.4913.47

151 (DCB) - l,4-Dichlorobenzene-d4 UPPER LIMIT = + 1OO7.IS2 (NPT) = Naphthalene-dS of internal standard area.I S3 (ANT) = Acfjnaphthene-dlO LOWER LIMIT = - 3O7.


& Column umed to flag internal standard area values with an asterisk

f l R 3 Q 1 8 1 I

6BSEMIVOLATILE ORGANICS INITIAL CALIBRATION DATA


Lab Code: NUS-P0H Case No.: ME SAS No.: SD6 No.3

Instrument ID: 45A Calibration Date<»): 1O/2O/88 1O/2O/88

Min RRF for SFCC(*> - O.O5O Max ZRSD for CCC(*) a 3O.C

:LAB FILE ID: RRF20 =* BA5io2088oa RRFSO * BAS 10208804 ';IRRFS0 = BA51O2O88O7 RRF12O» BA51O2O88O6 RRF16O- BA51O2O08O5 !

I I I I I I ./I I I I I I /.RRF20 !RRFSO SRRF8O !RRF12O!RRF16O! RRF ! RSD

2.227! 2.116! 1.669! 1.664! 1.995! 1.934! 13.31.472! 1.523! 1.51O! 1.6O7I 1.656 I 1.554 I 4.91.297! 1.316! 1.473! 1.529! 1.543! 1.432! 8.21.421! 1.49O! 1.533! 1.638! 1.6O7! 1.538! 5.71.469! 1.536! 1.557! 1.635! 1.718! 1.583! 6.1O.598! 0.566! O.811! O.772! O.664! O.682! 15.71.424! 1.549! 1.631! 1.589! 1.672! 1.573: 6.O1.062! 1.158! 1.298! 1.274! 1.248! 1.2OO! 8.11.622! 1.850! 1.9O2S 1.84O! 1.829! 1.8O9! 6.O1.052! 1.228! 1.538! 1.341! 1.379! 1.3O8! 13.8

!N-Nitroso-Di-n-Propylamine_* 0.742! O.926! O.996! 1.O42! 1.03O! O.947! 13.04

COMPOUND

!Pheno1____________________;b is(2-Chloroethyl)Ether___!2-Chlorophenol____________.' 1,3-D i ch 1 oroben zene_______11,4—Dichlorobenzene_______JBenzyl Alcohol____________I 1,2—Dichlorobenzene_______I2-Methylphenol____________I b i s < 2-Chloro i sopropy1)Ether14-Methylphenol____________

!Hexach1oroethane_________!Ni trobenzene_____________!Isophorone_______________!2-Nitrophenol____________H12,4-0imethylphenol________!Benzole Acid______________!bis<2-Chloraethoxy)Methane_12, 4-Dichlorophenol________<!lf 2,4-Trichlorobenzene____!Naph tha1ene_____________!4-Chlaroaniline__________

O.565! O.64O! O.71O! O.684! O.726! O.665! 9.7O.387! O.394! O.42O! O.368! O.493! 0.412! 11.80.679! O.692! O.757! O.681! O.695! O.7O1I 4.6O.208! O.206I O.263! O.243! O.24O! O.232! 1O.6<O.287! O.295! O.338! O.323! 0.311! O.311! 6.6!

! O.219! O.248S O.264! O.269! 0.250 « 9.01O.4O6! O.43OI O.455! O.444! O.434! 0.434! 4.2!O.273! O.297! O.327! O.35O! O.342! O.318! 1O.1*O.349! O.352! O.377! O.389! O.377! O.369! 4.7!1.122! 1.059! 1.256! 1.268! 1.191! 1.179! 7.5!O.295! O.41O! O.47O! 0.487! O.472! O.427! 18.6!

!Hexachlorobutadienv_______* O.174! O.ISO! O.187! O.192! O.185! O.184! 3.7*!4-Chloro-3-Methylphenol___* O.246! O.281! O.3O5! O.3O7! O.292! O.286! 8.7*!2-f1ethylnaphthal«n»_______! O.553! O.57O! O.61O! O.64O! 0.6O8! 0.5961 5.8!!Hexachlorocyclop*ntadi«n«_# 0.262! O.266! O.3O3! O.318! O.336! O.297! 1O.9#12,4,6-Trichlorophwnol_____* O.323! O.323! O.4O5! O.427! O.465! O.389! 16.4*!2f4,5-Trichloroph«nol____-Ch lor onaph tha

O.354! 0.413! O.439! O.369! 0.394 ! 10.01.O86! 1.O9O! 1.166! 1.181! 1.252! 1.155! 6.O!

! 0.283! 0.299! O.316! O.315! 0.303 ! 5.1 !1.O69! 1.147! 1.193! 1.219! 1.219! 1.169! 5.4!1.566! 1.589! 1.764! 1.741! 1.9O1! 1.712! 8.O!O.264! O.3O7! O.334! O.337! O.3O8! O.31O! 9.5!

____________ ! 0.198! 0.320! O.346Z O.354! 0.304 ! 23.8 8.'Acenaphthene______________*O.967! O.971! 1.O86! 1.O95! 1.133! 1.05O! 7.3*!2, 4-Dinitrophenol_________« ! O.122! O.142! O.169! O.181! 0.154 ! 17.3*!4-Nitrophenol_____________* ! O.O91! O.O94! O.1OO! O. 115: 0.100 '• 10.7*

! 2-Ni troan i 1 in«JDimethyl Phthalat»! Acenaphthylene!2,6-Din i troto1uene.-Nitroaniline

flR30!8I2

6CSEMIVOLATILE ORGANICS INITIAL CALIBRATION DATA


Lab Codes NUS-PGH Ca«e No.s HE SAS No.: SDG No.:

Instrument IDs 45A Calibration Date(s>: 10/2O/88 1O/2O/88

Mm RRF for SPCC<#) = O.O5O Max %RSD for CCC(*> ^ 3O. O:

!LAB FILE I D : R R F 2 O ^ BA51O2088O8RRF5O - BA51O2O88O4!JRRF8O « BA51O2O88O7 RRF12O= BA51O2O88O6 RRF16O= BA51O2O88O5 :

i! COMPOUND

SDibenzofuran!2T 4-Dini trotolueneSDiethyloh thai ate! 4-Chlorophenyl-phenyIether_IFluorene! 4-Ni troan x I me'j 4, 6-Din i tro-2-MethyIpnenoI_*N-Ni trosadiphenylamin© ( 1 )_J"! 4— Bromaphenyl— phenylether _I Hexach larabenr eneJPentach laroDhenol •*J Phen an th rene! Anthracene1 Di-n-Butvlohthalate! Fluoranthene •«! Pvrene! Butyl ben zylph tha late! 3, 7 '-Dichlorobenzidine! Benro (a) Anthracene! ChryseneIbis(2-Ethylhe;;yl)Phthalate_JDi-n-OctvI Phthalate <! Ben ro ( b ) F 1 uoran then*I Benzo <fc> Fluarantnene! Benzo (a) Pvrene *} Indeno ( 1.2, 3-cd) Pvrene! Dibenz (a, h) Anthracene! Ben =o ( q T h T i > Perylene

I Ni trobensene-dS1 2~F luorob i ohenv 1!Terohenvl-dl4!Phenal-d5I 2-F I uoraoheny 1! 2, 4, 6-TribromophenolJ

i*RRF2O !l

1 . 486 iO.298!1.O18!0.56O!1.215!

it•

f- O.492!0. 188!O.2OO!

:0.947!1. 10O!1.051 !0.875!1.637!0.707!0. 194!1 . 329 !1 . 058 !O.950!

t 1.655!1 . 3O3 !1.249!

* 1.O4O!0.787!0.709!0.805!

0.345!1 . 425 !1.261!1.422!1.118!0.139!

•*

RRF5O !l

1 . 472 !O.347:1 . 087 !O.592!1 . 226 I0.240!O. 121!0.52S:O.2OO!O.214:O. 124!1 . O27 !1.016!1. 181 !0.986!1 . 5O7 !0,737!O.265!1.437!O.911!1 . 024 !1.999!1.717!1 . O64 !1.141!1 . O86 !0.810!0.884!

0.3S4!1 . 368 !1.214!1 . 572 !1.331!o. i6o:

*

*RF

1.O.

1.

O.1.0.O.O.0.

O.O.1.1.1.0.1.0.O.1.1.1.*>..1.I.1.0.O.

O.

0.1.1.1.1.0.

80

65O358137652371244133561211*>*7"* ' * i *j126070084169933669822243485172O69OO8613335165995830918

389343278643451162

!!• •***t*tii

itiii•*•i**•>r*iitt1ifii•••iiitiii•iit

t53

1tt1t*1

111i

I

RRF 12O !F— — .=_:= , .

1 . 664 !0.371 ;i. 130:O.657!1 . 389 !0.311 !O.151 !O.553!O.213!0,240!O.147!1.153!1 . O90 !1.29O!1.012!2. 1O3!0.965!O.373!1.941!1 . 465 !1 . 257 !1.917!1,941!O.991!1.136!1 . 035 :0.871 !0.908!

0.343!1 . 399 !1 . 507 !1 . 665 !1 . 279 !O. 151 !

!

*RF

1,O.

1.0.1.

O.O.

O.0,

O.O.1.1.1.1.1.0.

0.1.1.I.*•>-

O.

1.

1.

O.0.

O.1.1.1.1.0.

160

68137923166842O32016O5982O923814921513627403974O743288579141024054277879174066832839

371398137711222153

»tfi•t*•iiii*t*t•i•>•*••t«t*iiit**i**i*»it**•»t•tit<*

*•i•*iti*itI

RRF !

i . 59 i ;O.351 :1. 121 !0.626!I . 324 !0. 279 !O.141!0.546!0.204!0.223!0, 137!1 . O82 !1 . 085 !I, 193!0.969!1.731!0,795!0.273!1 . 554 !1. 149!1 . O65 !1 . 927 !1 . 770 !1. 1O4!1. 131 I0.994!O.81O!0,871!

O.366!1 . 387 !1 . 279 !1 . 6O3 !1 . 28O !0.153!

*

7.RSD

6.49. 16.9.7.57.3.15.312.57.2*5.1 :7.519.7-*

•SToi6.8*13. o;13. i ;24.2115. 1 i17.7;10.9:8. 3*20. 6 r16.9!4, 7*12. I !7.515.5!

5.9!*•> T «*-•'-*•

10. B!7.0;9.7:5.9!

ii

(1) Cannot be separated from Diphenylamine

SR3QI8i3


CALIBRATION - DECAFLUORQTRIPHENYLPHOSPHINE (DFTPP)

Lab Name: NUS CORP. Contracts

Lab Codei NUS-PBH Case No.i ME SAS No.I SD6 No.i

Lab File IDs DF51O2O88O5 DFTPP Injection Date: 1O/2O/88

Instrument IDr 45A DFTPP Injection Time: 1155

m/e

51686970127197198199275w*O*J

441442443


3O.O - 6O.O% of mass 198Less than 2.0% of mass 69Mass 69 relative abundanceLess than 2. OX of mass 694O.O - 60.07. of mass 198Less than 1.0% of mass 198Base peak, 1O0% relative abundance5.O to 9.0% of mass 1981O.O - 3O.O% of mass 198Greater than 1 . OO% of mass 198Present, but less than mass 443Greater than 4O.O% of mass 19817. O - 23.0% of mass 442

% RELATIVEABUNDANCE

35.60.0 < 0.O)37.1O.O ( 0.O)43.2O.O

IOO.O6.019.31.346.O47.18.2 ( 17.4)

1

1

2

1-Value is % mass 69 2-Value is % mass 442

THIS TUNE APPLIES TO THE FOLLOWING SAMPLES, MS, MSD, BLANKS, AND STANDARDS!

Ol !O2!03!O4!

EPASAMPLE NO.

SSTD050SSTD160SSTD12OSSTDOSOSSTD020

LABSAMPLE ID

SSTDOSOSSTD160SSTD12OSSTDOSOSSTDO2O

LABFILE ID

BA51O2O88O4BA51O2O88O5BA51O2O8806BA51O2O88O7BA51O2OB8O8

DATEANALYZED

1O/2O/8810/2O/8B1O/2O/881O/2O/S810/2O/88

TIMEANALYZED

13451512155916481738

flR30!8IU

« * M r > / - > J ^ i r "anR30 1 8 1 5

-IJln9999-99<S>«03E99909-0990)

E in \ 99<E>99999 99 9« UJ(J ..........

K 3 9 9 9 9 9. 9 9 9 9 9 9

CHART SPEED 0.5 CM/MINATTEN: 16 ZERO: 10* 5 MIN/TICK

-JiEPTEP.04

A-ENDQ.04

D1ELDR.04

I-ENDQ.08

DOT .08

ENDAL .10

OUI

.20

NETHOX.4

RECALCTITLE: RUN * H /'V A-1 3:08 20 NOV seCHANNEL NO: I SAMPLE: f^8-88-9l METHOD: 2A PP-l

PEAK PEAK jUTCuX RESULT TIME TIME AREA SEP Wl/2NO NMME * J FACTOR CMIN D OFFSET CO JNTS CODE CSEC)

02 0.001168U 1.997 -0,003 ^ ?791 BV ? 2.75HEPT .04 0.001603U 2.458 -0.002 62191 VVftlpDfH 04 n Of*T t?4II -T 09-5 c?i g. ^ Q314Q V« A, 9ft

1055 BS 10. 40 -1036953 BB J3.00 '^^

4 HEPTEP.04 O.OC1234U 4.592 0.002 85 A-ENDO.S4 0.001299U 5. 816 -0.0046 DIEL0P.04 O.001191U 7.171 0.001 83997 BB 15.757 B-END0.08 0.001396U 10. 752 0.002 143272 BB 23. 40S DOT .08 C.G02383U 12.756 0.176 83942 BB 27.309 ENDAL .10 0.001952U 14.236 -0.004 129085 BB 38.5510 20.914 62629 BV 47. 301 t DBC . 20 3.001897U 23. 178 -0.002 263523 VV 53.05

METHOx.4 0.005821U 25.146 -0.004 17 805 VB 53.95

TOTALS: 0.165 1288390 ,-RR301817DETECTED PKS: 15 REJECTED PKS: 3

10PESTICIDE/PCB IDENTIFICATION ' EPA

NaM:———————*™__________ contract: ' SW/SED11cod.: —————— Cas. No.:J[E__ SASNo.:_____ SOGMo..

GO Column ID (i>.1.5«SP2250/1.95BP2401 Gc

instrument ID (1): GC#2 Varian 3700 instnmwt ID (2): GC*6 Var^an 3700Lab Saapl* ID: P103821 "—————'—

ID: —————————— (°nly if confirm«d by GC/MS)

PESTICIDE/PCB RETENTION TIME RT WINDOW QUANT? GC/MS?OP STANDARD (Y/N) (Y/N)FROM TO

01 DDE Coluam 1 6-609 6.540 6.782 y N

02 Column 2 _26JL66_ 26.127 26.207 N N

03 DDD_____ Column 1 _10*_255 10.143 10.509 Y N

04 Column 2 29.620 29.571 29,671 N N

05__________ Column I ____ ____" ____

06 Column 2

07__________ Column 108 Column 2

09_________ column l10 Column 2

11_________ Column 112 Column 2

Comments:

pag« _1 of _FORM X PEST flR30l8l8V87R.v.

3DPESTICIDE EVALUATION STANDARDS SUMMARY

Lab Name; v^uS ___________ _ Contract:

_ab Code: ______. Case No.: VMV SAS No.: _____ SDG No,

Instrument lOt^c^s- J A *•»**;£ ?oo GC Column ID:/rDate* of Analyses: [\ /7/gr^ to __///

Evaluation Check for Linearity

PESTICIDE

ALDHINENDRIN4.4--DDTDSC

1 CALIBRATION ]I FACTOR |! EVAL MIX A |

•1"" -1f -2-r ii , m ii f*-*e- *$o I1 fi-V-brt- fM<? 1I 1

1 CALIBRATION |1 FACTOR |I EVAL MIX B |

A M \1 5-0 |S«r I

i IH> 1

! CALIBRATIONI FACTOR! 2VAL MIX C

_*? ci .3?to/ 3Z,

I %RSD I! (</- 1110. 0%) |

I 5.0 'L,I ^-Q i f 1 \1 "T.«.M 1 *- \ i J1 5* 7 T1 -' • f I1 1

(1) If > 10.0% RSD, plot a standard curve and determine the ngfor each sample in that set from the curve.

{ Evaluation ChecX for 4,4f-DDT/Zndrin Breakdown _ A(percent breakdown expressed as total degradatiorA^ f

Oil02|03|04|OS |06|07|OS)^

1111213141

INITIALEVAL MIX BEVAL MIX BEVAL MIX SEVAL MIX BEVAL MIX BEVAL MIX BEVAL MIX BEVAL MIX BEVAL MIX BEVAL MIX BEVAL MIX BEVAL MIX BEVAL MIX BEVAL MIX B

| DATE[ ANALYZED

1I *\/r/&&

u/-?/**1 &H/&/QS tifafat1 ;// /#751 nt8V&8\ /rte/£81 t*%/$1

iiji\\

TIMZANALYZED

f:*iM'-o-z.&Jf • f <j -21:14T 16

"?:/(>4:33£'•&

ENDRIN

^•jfio

on

4,4'-DDTI7~ ~&\%>&-><\C 9>. (^ 10 1\O dt '<!A'"—s

/COMBINED |(2) |

1 „— -|",— 1 — ~[.~ 1— rr — riiiiiiii

(2) See Form instructions.

FORK VIII PEST-1 V37 Rev,

BR3018i9

8EPESTI.CXDE EVALUATION STANDARDS

Evaluation of RetenCion^Time Sfiaft for Dibutylchlorendate

Lab Kama: AjU.S

Lab Code: ______ Cas« Ho.:

Instrument

Dates of Analyses; u/7/g^ to ilhld&GC Colunn ID:/. %

* Values outside of QC limits (2.0% for packed columns,0.3% for capillary columns)

page f of tFORK VIII PEST-2 1/37

flR30!820

8EPESTICIDE EVALUATION STANDARDS SUMMARY

Evaluation o£ Retention Time Shift ror Dibutylchiorendate

Lib Naraa:______ MO*!)______ Contract:_________

Lab Code: ______ Case No.: t^g SAS No.: ___

Instrument IDs 6£ * 2 v.+giflAj >"?oO CC Column ID: /.

Dates of Analyses: uh /SG to nh/S8

03! /MO 304!05!.__06! 5wV3cDS0?I08 |09|inin.«I."I.14 [_____15! Jl^Q A

1«I.171.__18l_^u/AS£D5

20[__211 (s..22*_f£23]24! £<wra A-2S|.2«f.271.281.291.301.31f.32|.331.3<1.351

371.381

IAB SAMPLEID

P/C38&/

P/Q 32-P/0

P/0

p(Q VOfet^P . 0

o . r> vo-^ 3

DATEANALYZED

///<? tea

\ i q / 9 v

TIMEANALYZED

tf'OZ.

It'/?

•a i '

r 3i 35

-7*0-?

7.5

/.7^ 7

(.7;,/,<-

flR30182

•J*-

->-!-X-1-C'

:t

* Values outside of QC limits (2.0% for packed columns,0.3% for capillary coluans)

page Z. of "2,—— —— FORM VIII PEST-2 1/37

PESTICIDE EVALUATION aiANDABnc SUMMARY

*** Man«;_. Mu.s>_________ Contract:________Lab Cod«: ______ Caae No.;<\\£ SAS No.: ^

' otX*Instrument 10:60* 0 .1 37 rt r«i,,m« -r~woman ID:Dates of Analyses; M/to/g^ to


_______ _—_-!__— -• __- - _ _____ I a, B

(1) If > 10.0% RSD, plot a standard curve and d«t«rnin« tha ngfor aacn aaapla in that sat froa tha cur/a.

Evaluation Chack for 4,4'-DDT/Endr:Ln BraaJcdovn(pareant braakdovn aacpraaaad aa total degradation)

4,4'-DOT|COMBINED(2)ANALYZED | ANALYZED [

INITIAL01| EVAL MIX B02| EVAL MIX B03| EVAL MIX B04| EVAL MIX B05) EVAL MIX B061 EVAL MIX B07 | EVAL MIX B08| EVAL MIX •091 EVAL MIX B10| EVAL MIX B11121314

in»truction«.

roj« vxxx PEST-! fl R 3 o i 8 2 2 va?

i£PESTICIDE EVAUJATIOH STANDARDS SUMXABY

• Evaluation of R«t«ntion Tim« Shift for Dibutylchlorendata

Lab N*B«: Kj 1>~S____________ Contract:

Lab Code: ______ Case Ko.: tf\£ SAS Ho.: _____ SOG No.:

Instrument IDgC **2 vA<^^3^» GC Column ID;/,

Dat«s of *«*lv«es: HAfctey to uA

031 &J&-L04!osi r*io A

• I TO y07!0«|o»|101111121131141151 <yJ>

271.2»I.

soi;311.321.33|.34|.3S|.

371.3«r.

£AB SAMPLEID

3 -*' -

0 -VI -Vy1-

Pvo

PlO

DATZANALYZED

1 (y'.c./g'S

2O12D20-64

A 5 "3 >l«t.19 t.

21 £ _ _________ __<^^ | ———^T - - - - - *.(. Q " ^7 i >-. — — '»

O.Iq n24 f25f'

TIMEANALYZED

•. .0

/ 2. :

« Value* outside of QC limits (2.0% for peeked columns,0.3% for capillary columns)

\ of 1 - - -—— FORM VIII PEST-2 1/8?

flR30!823

T 80 f tPESTICIDE EVALUATION STANDARDS SUMMARY

Nam*:"Lab Coda: ______ Caaa No.:Instrument

Datas of Analyaas: ii/-*o/>/ ta—— "— ———— e- uo

EVaIuation «"«=* for Linaarity

FACTOR |(</,C 110.0%)

HTV mMIX A } EVAL MIX B

_____.___________i___________I(1) If > 10.0% RSD, plot a standard curve and determine the ng

for each saaple in that set froa the curve*

Evaluation Check for 4,4'-DDT/Endrin BreaJcdovn(percent breakdown expressed as total degradation)

! =rr ^

I INITIAL01| EVAL MIX B02| EVAL MIX B03| EVAL MIX B04| EVAL MIX B05| EVAL MIX B0«| EVAL MIX B I07| EVAL MIX B I08| EVAL MIX a 109) EVAL MIX a I10| EVAL MIX 8 I11) EVAL MIX B121 EVAL MIX B13| EVAL MIX B14| EVAL MIX B

(2) Sa« Form inatructiona.

ANALYSED j AN!L?!ED | naKM |*'4'-«»|COMBINED

70RM VII! PEST-1 fl R 3 0 1 8 2 k 1/37 Rev.

SEPESTICIDE EVALUATES STANDARDS SUMMARY

Evaluation o£ R«t«ntion Tim* Shirt for Oibutylchlorandate

Lab Name:______MO __________ Contract:

Lab Codes ______ Case Ho.: M£ SAS Mo.: SOG Mo.:

Instruaent ID: £?<- **£ v*i?ifro "V7co CC Column ID:

Dates of Analyses: /r/Zo/S6 to

[ EPA| SAMPLE HO.

Oil £\jAL- ft0203041 iNH-i AOSI ,K.T-> "P.06107|08|______091 ftifiZMS"I.HI."I."I."I."I.l«l.171.l«t.

20 r21 22 »._____23t mD "3241.

2«t;27!.2»i.291.301.311.321.331.3*1.351.

37l!3«l.

LAB SAMPLE10

IHHM BH BBUBHHUn

l-Si-S^-73

-St-38-^f

fi . - Srf -

/T ^ £

--73

H,r7 tJ

i -

-8, -&S-TI

DATZANALYZED

U/Zf >•£&

TIMEANALYZED

1-CC-7'. TO

. 53

e-06tC'-

* I I0 I *{———— >. !

O.C(s.co L 1Q.Q8 1 __0.22 J^- 1Q.5H

< ->-K

0,H7

->-!£25—16.1~ " i *:t0.84

.0,18 :iri.L.I0^_L__/O.M7

0.08 -f"! ,;• -\

(.5 iO.lS 'I 1

* Values outside of QC limits (2.0% for peeked columns,0.3% tor capillary columns)

page ' off ["" TORM VIII PEST-2 1/8?

flR301825

r. -T T - -8D

PESTICIDE EVALUATION STANDARDS SUMMARY

Lab Naae:_____i\j u.s_________ Contract:Lab Code: *>rKj j?&i*-fc- Case No.: fft lr SAS No.: _____ SOG No.:

Instrument ID:g£»C» \JAJ,.W»*» 3700 °C .Cdlumn ID: OfiS"____Dates of Analyses: V2./1 r*rf to l"L/z^/ gy


PESTICIDE

ALDRINENDRIN4,4«-DDTDBC

i

| CALIBRATION| FACTOR| EVAL KB A

r 37?1 *t/1 2**V1 J7J1

CALIBRATIONFACTOREVAL MIX B

3s-oa. W2*«?f S-7

CALIBRATIONFACTOREVAL MIX C

3*b37-*3»f * z-

%RSD I(</- I10.0%) r77~f6. 7 15*. 7 T,3 '!f

(1) If > 10.0% RSD, plot a standard curve and determine the n?for each saaple in that set from the curve.

Evaluation Cfceck for 4,4f-DDT/Endrin Breakdown(percent breakdown expressed as total degradation)

F( INITIAL

01| EVAL MIX B02 | EVAL MIX B03] EVAL MIX B04 \ EVAL MIX BOSf EVAL MIX B06) EVAL MIX B07( EVAL MIX BOS | EVAL MIX B09 1 EVAL MIX B10( EVAL MIX B11) EVAL MIX B12 1 EVAL MIX B13 | EVAL MIX B14 1 EVAL MIX B

1

DATSANALYZED

J^/t f$&*2/t /*ytZ/i /s<l z/i/tt

TIME - |ANALYZED I

S; 2.0A S \&*t2 3 '. S **^ • VO

ENDRIN

OOoe>

4, 4 «-DDT

0O0r)

.._.

COMBINED(2)

———————_

- .-- -

_

_.

^-f

(2) See Fora instructions.

FORM VIII PEST-1 I/*7

flR30i826

asPESTICIDE EVALUATION STANDARDS SUMMARY

Evaluation o Ratantion Ti«e Shift *or Dib lcnlor xiate

*<** Ka»iit J 5_________ contract:.No.; SOGNo.:

Instrument IDs£c*& \j ao.- ,*/ $?ooDates of Analyseas/SA/^ to

(2.0% for pack«l columns,3% for capillary coluans)P*g« _L of _j_

FORM VIII PEST-2 l/i7

flR30i827

.FESTICIOE/FCB STANDARDS SUMMARY

Hame:Code:

Instruaent

COMPOUND

alpha-BBCbeta-BBC

Igamma-BBCtKeptaclorAldrin_

i —.—.•Ten

Contract:SAS No.:fcase Ho.: SOO Ho.:

1 OATE(S) OF FROM!ANALYSIS TO:TIXE(S) OF FROM:ANALYSIS TO: lO'TTO

Of ANALYSISTIM Of ANALYSIS

SAXPU NO.(STAKDARD)

RTWINDOW

FROM I TOCALIBRATION CALIBRATION

V- i g. u •

\2.W l*?.5*3

Kept, eooacidelEndoeulfan IDieldrinEndrin _dosuKan II41.000

;ndo.sulfata_

I Endrin Jcetonela.IToxaphene__Aroclor-lOldAroclor-l«l

IAroclor-1254|Aroclor-12«0- ____ ____' *W ~ -M^^M^H^B.————————————————————— „

un<4er QNT Y/Hi entar T if guantitation was porformod, V if not performed"ID Bust bo less than or equal to 13.0% for quantitation, and loss thanor equal to 20*0% for confirmation.Hotai Determining that no compounds voro found aboro tho OKJt is a form ofquantitation, and therefore at least ono column must moot tho 13.0% criteria.For multieomponont analytes, tho single largest poak that is characteristic•' * tho component should bo usod to establish retention time and %0.

ntification of such analytes is based primarily on pattern recognitionpago j of 2.

FORM IX PISTftR301828

9?SSTIC:DE/?CB STANDARDS

Kama: NJ ^ _____ ____ Contract:Codes ______ Case Ho.: /n£ SAS Ho.:' _____ SDC Ho.:

Instrument Tm fr tMfcj frsQ GC ColumnDATE(S) OF FROHJ.ANALYSIS

OF FUCK*ANALYSIS TO: 121*3

COKPOUNO

Ialpha-SHCIbeta-BHC_Idelta-BHC|<gamaa-lHCIHeptaclorlAldrin

epoxlde)Endosulfan I_____ ___Oioldrin___n-Q* H.QH7 I

4,4'-ODD___,Endo.sul~fato_i Mathoxychlor_ 1.|Endrin ketoneI a. Chlordane,19* Chlordano _| ToxaphoMi^ I jJL|Aroclor-loIi3LIAroclor-1221IAroclor-1232IAroclor-1242"|Aroclor-l24B |tAroclor-12S4_I Aroclor-12<Q'~l f3,?&3 IUnder QNi Y/K: en ax T if quantltation vas portonod. N it not performed%0 must bo less than or oqual to 13.0% for quantitation, and less thanor equal to 20.0% for confirmation.Notoi Determining that no cuapounds voro found abovo tho C*QL is a form ofquantitation, and tharsfero at Isast ono coluan must Mot tho 15.0% criteria,

OATZ OF ANALYSISTIXI OF ANALYSIS1PA SAMPLE NO.(STANBAUD)

aultieevponant analytas, ta« singlo l*r«jMt paak that istha covpenant should ba usad to aatabliah ratantion tia« and %0.

dantification o£ «uch analytas is basad primarily on pattam racognitionpaga ~L- of 7— •*- roiw zx FIST VST s.v.

flR30i829

95i #',*STANDARDS SLTCtARY

» Maae; PO ^J_________ Contract:

lab Code: _ Case No.:

Instrument 1CDATE(S) OF FROM:ANALYSIS TO:*TIMZ(S) OF FROMtANALYSIS TO:

(alpha-BHC(beta-BRCIdelta-BHCj gaaaa-BHCIHeptaclorlAldrinI Kept, epoxideEndosulfan I_Dieldrin4,4'-0Endrinidesulfan4'-ODD__

Endo.sulfate4,4'-DOTMethoxychlor_Endrin ketone)_a. Chlordano | ,9. Chlordano"*ToxaphonoAroclor-ioitfAroclor-1221Aroclor-1232Aroclor-1242

OATI OF ANALYSISTIMX OF ANALYSIS1PA SAMPL1 NO.(STANDARD)

(Aroclor-1254IAreclor-1260under QNT Y/Ni' entar Y if quantitation vas porformod, i if not performed?%o must bo less than or oqual to 1S.O% for quantitation, and loss thanor equal to 20.0% for confirmation.Notes Determining that no compounds voro found above tho OWL is a form ofquantitation, and therefore at least ono ooluaa must most tho 15.0% criteria.For multicomponent analytas. tho singlo largost peak that is characteristic

iho component should bo used to establish retention time and %D.itification of such analytes is based primarily en pattern recognition

page of ?_FORM IX PIST A , rtrtrt 1/87; flR301830

9PESTICIDE/PCS STANDARDS SUMMARY

Names___ rO ^S_________ Contract:,

code: ______ case No.: AI£- SAS No.:' _____ SDO No.:

Instrument TO*gc* (M«.t*«/37go GC Column ID : £2DATE(S) g-fANALYSIS TO:TIMZ{S) OF FROM:'ANALYSIS TOS iq.\ i

COMPOUND

|alpha-BBCibeta-BlfCdelta-BBCgaaaa-BHC

Endosulfan I_

( Jl LaT JJ1ndosulfan II

i4«4'-OD0___I Endq. sulfats I ._. .-JET-- -I4,4*-DDT \i 7r\iT r\I Methoxy chloral i i5.ji2 2SL!IEndrin ketonejla. Chlordano|g. ChlordanoiToxapheno .I Aroclor-lOlO____ ____|Aroclor-l22i_i___I___II Aroclor-1232 |____I____II Aroclor-1242_| « iiJi2 .l|Aroclor-124S.Aroclor-iaio.i.

' ————"————' ———— "•"""—————'"——'—" if not performed

DATS OF ANALYSISTIMX OF ANALYSIS1PA SAMPLE NO.(STANDARD)

to «u»t b. !.«« than or psal to 13.0% for quantitation, and law thanor .qua! to 20.0% for eoafinatioa.Hotat o«tarmining that no compound* voro found abowo tha OQL ia a form ofqaantitation, and tharafero at laaot o»o eoluaa auat moot tho 15.0% crit.ria.»or TOlticemponant analytoa, tho oinglo laryaat poak that ia characteristi] tho c<»penant ihould bo u«ad to aotatolish ratantion tiao and ID.dantification of auch analytao ia baaad primarily on pattarn racognition

l/«7a r> o n l o o !AR30 83

9 -- - i i rljPESTICIDE/PCS "STANDARDS

Contract:Case No.: ..*&. • SAS No.:' SOS No.:

Instruaent Tn:Gc#ZsOt&iA*jU<yQ <X Column

ANALYSIS TO: tvyy/«* TIMm OF ANALYSISTIMZ(S) OF FROM: J f EPJ. SAMPLE NO.ANALYSIS TO: io\ 10 (STANDARD)

COMPOUND RT I WINDOW CALIBRATION JWP CALIBRATION QNT %D' "CM TO FACTOR FACTOR Y/N

I alpha-BBC__ <i5q? j 1 'g<«3 K<«33I beta-BBC[delta-BBC __ ______ __ _______I gamma-BBC^_ a.o-*-fr I i 7i gr°7S 213 <?.oy«r -2,? T/"-IHeptaclor___ avHQa ia. <J *<r™._" i3Q .-*i*J*' 12.7iAldrin .C3s j . Crr 3.10 ^3<b____ 3.Kept, epoxidel. ____ ____ ____Endosulfan 11^. 33g._t . ^ 5".95* 2,00Dieldrin___n 3. !T'°HI 7. -? z-am — 7,1-,, T.M \' Endrin ft-7yj I^.^QQ y.qe 3 ?

dosulfan IIEndo.sulfato;4>4t*DP*.,IMethoxychlor_I Endrin Jcetone[a. Chlordano,g. Chlordano _Toxapheno *" MAroclor-101«_ .ygrz- j 2.M3O . 4 70Aroclor-1221*Aroclor-1232"Aroclor-1242"IAroclor-l24S i r T i .u. STsn|Aroclor-1234IArocior-1250'under QNT Y/N» entor Y if quantitation was porformod,"lf if not perforaedTID must bo less than or oqual to 13.0% for quantitation, and lass thanor equal to 20.0% for confirmation.Notos Determining that no compounds voro found afeova tho OQL is a form ofquantitation, and therefore at least ono column must moot tho 13.0% criteria.For multicomponant analytss, tho singlo largest poak that is characteristic"1 tho component should bo usod to establish retention time and %0.rentificatien of such analytes is based primarily on pattern recognition

pago of _

XPrit (SR30I832


b Kame:____PO °^_____.____ Contract:.Code: ______ Caso No.: me. SAS No.:" ______ SDO No.:

Instruaent TQigc* (Mti**37gQ GC ColumnDATf(S) OF FROM:ANALYSIS TO:,TIMZ(S) OF FROM:.ANALYSIS TOl JOJ^ t O

IZndo.sulfatoJM^'-DDT1MethoxychiorJ1Endrin katonetja. Chlordano |If. chlordane_|IToxapheno_ |IArocior-iols I|Aroclor-1221|Arcclor-1232~~|IAroclor-1242"|Aroclo.r-l24i'| Aroclor-1234"|Aroclor-l2«ol__________under QKT Y/K* eniar T if quantitation was porformed, It it not performed:%0 must bo lass than or oqual to 13.0% for quantitation, and lass thanor equal to 20.0% for confirmation.Notes Determining that no compounds voro found above tho CtQL is a fora ofquantitation, and thareforo at least ono column must moot tho 1S.O% criteria.For multieomponent analytoo, tho • ing Is largest poak that is characteristic. tho component should bo used to establish retention time and %D.

notification of such analytss is based primarily on pattern recognitionP*9« 6 Of "7

1XPMT flR301833

DATS OF ANALYSISTIMI OF ANALYSIS£PA SAMPUI NO.(STANDARD)

STANDARDS SUMMARY

Lab Maae: ^ ______ Contract:

code: _____i Case No.: / e, SA5 No.:' _____ 300 No.:Instruaent tP:C~c*fc ( A'£i**>37 o CC Column

•TIME(S) OF FROM* i;>TANALYSIS

COMPOUND CALIBRATIONI FACTOR

| alpha-BBCI beta-BBCI delta-BBC[gamma-BBCIBeptaclorlAldrin(Bept. eooacidollEndosulfan IIDieldrin|4,4'-DOmjgndrin _

dcsulfan il4 '-DO!) ___ I fQ.170 j

. do.sulfata IJMSthOXVChlOr I 2- 3.3 1 3 79 Ii Endrin Xstonol ____ | ___ Ila. Chlordano "1"(g. Chlordanols.isc. I^.CTMQ II Toxapheno I 1 3T oc? I >a.qe . IAroclor*10l4Aroclor-1221Aroclor-l232

OF ANALYSISTIMS OF ANALYSIS*PA SAMPXat NO. ———"*"(STANDARD) iMft re

|Aroclor-124SIAroclor-1254!Aroclor-126o;Under QNT Y/N: entor Y il quantitation vas porZonod,~* if not porfonedT%D must bo less than or oqual to 13.0% for quantitation, and less thanor equal to 20.0% for confirmation.Note: Determining that no Compounds voro found abcro tho CRQL is a form ofquantitation, and thoroforo at least ono column must moot tho 15.0% criteria.For multicomponent analytes, tho single largost poak that is characteristicof tho component should bo used to sstablish retention time and ID*justification of such analytes is based primarily on pattern recognitionpegs 2> °< -2

FORK IX PXST I/*7

PESTICIDE/PCS STANDARDS SUMHARY

Tab Kama: ft >CvS_____._____ Contract:,________Lab Code: ______ Case No.: r*\e SAS No.:* _____ SDG No.:

Instrument ID*£t*29MU**J&7W> GC ColumnDAf£(S) OFFROM:_______ANALYSIS TO: (»/.«,/>«-TIME(S) OF FROM: \p-.tHANALYSIS ~

alpha-BHC___i //5"7Q_Ibeta-BBC . - - - - •delta-BBC___i A<*r._lgamma-BBC.Heptaclor__I 2*Hc»7._ IAldrin U.U7 !?,«.*

Endosulfan I i 5. •>•?¥.... I ay^oDieldrin___I-7.0 I 6,3074,4'-DDE-Endrinndosulfan ll '.ftj; Tho.3*s-, 4* -ODD 1 I /0.3**Endo.sulfatej4, 4'-DOT|MethoxychlorJI Endrin ketonej,|a. Chlordane_j,____|g. Chlordano i 5 .00,3 lI Toxaphene__Ii J£j22LJ!Aroclor-161i iz^io IiAroclor-1221^1____[Aroclor-1232^1____jAroclor-I242""i 3.m t I

i Aroclor-124S_J2Ja -iIAroclor-1214i Aroclor-1260

r 7^770,50*?

i l l

CALIBRATIONFACTOR

.1X7

2.7

5-7

-76

PATE OF ANALYSIS TTIME OF ANALYSIS -LI -LQEPA SAMPLE NO. —————(STANDARD) ,POO A

RT

2-.O/0?

CALIBRATION QNTFACTOR Y/N

under QNT Y/Nx antor T It quantitation was porformed, N it not performed.ID must bo less than or equal to 15.0% for quantitation, and less thanor equal to 20.0% for confirmation.Notes Determining that no compounds vero found abovo tho CRQL is a fora ofquantitation, and tharoforo at least one column must moot tho 15.0% criteria.For multicomponent analytas, tho single largest poak that is characteristic< tho component should bo usod to establish retention time and ID.-ntification of such analytes is based primarily on pattern recognition

pago I ofFORM IX PEST ^rt-fiR30!835

i a ;<, . ..™, . .

PESTICIDE/PCS STANDARDS SUMMARY

wane: )C*.S. Contract:

i** cod«: ______ Case No.: Mr SAS No.:' _____ SOG No.:

Instrument ID; g J*2 VMUtoJATQo GC Column ID:/.r*| DATE(S) OF FROM:Zi\A,./*,rI ANALYSIS TO! .l/'.L/ r| TIME(S) OF FROM:"ToTT5———I ANALYSIS —————

COMPOUND

Ialpha-BIfCIbeta-BHC '1delta-BHC1gaaaa-BHCIHeptaclorlAldrinKept, epoxide __Endosulfan I I 5-221Dieldrin4,4'-DDEdrinMdosuifan ll|

lEndo.sulfato14,4 001?.IMethoxychlor IIEndrin ketonofI a. Chlordano,jg. ChlordanoI Toxapheno _\|Aroclor-10l«!Aroclor-l22l""j|Aroclor-1232"||Aroclor-1242*||Aroclor-124S*"';____IAroclor-12S4^i 7.xn^ I|Aroclor-12«0_' 'under QNT Y/H* entor Y 1C quantitation was porformod, N if not porforiedT0 must bo less than or equal to 15.0% for quantitation, and loss thanor equal to 20.0% for confirmation.

DATE OF ANALYSIS——u/,«/<-yH?*,?F ANALYSIS .23-02.EPA SAMPLE NO. ———————(STANDARD) Jr^o 6

- tho CXQZ. ia a form of, and tharoforo at laaa« ono column auat Boot tho 15.0% eritarla.

singlo largest peak that is characteristicused to establish retention time and ID.

of such analytes is based primarily on pattern recognition

FORM IX PEST _ 1/17 Rev.flR301836


Lab Name:____KJ^S_____m_____ Contract:

Lab Code: ______ Caso No.: *\c SAS No.:* _____ SDG No.:

Instrument ID - A U£r2 A*j5;oo GC Column

( tndosulfan IIV,4,4I-ODDlEndo.sulJ4,4*~DMi Methoxychlor_1Endrin ketoneI a. chlordane_|g. Chlordane~I Toxaphene__""I Arocior-1016IAroclor-1221|Aroclor-1232[Aroclor-1242IAroclor-124t[Aroclor-1254!Aroclor-1260;

Under QNT 5f/N: antsr Y if quantitation was performed,"!! if not perforaedL%D must bo less than or oqual to 15.0% for quantitation, and less thanor equal to 20.0% for confirmation.Note: Determining that no compounds voro found above tho CRQL is a form ofquantitation, and therefore at least ono column must moot tho 15.0% criteria,For multicomponent analytas, tho single largest poak that is characterist" tho component should bo used to establish retention time and %D.uentifieation of such analytas is based primarily on pattern recognition

page j of j,0»IX»»T aR30|837


Lab Name:____MV*S_______ Contract:

Lab Code: ______. Case No.: MZ. SAS No,:* _____ SOG No.:

Instrument

COMPOUND

Ialpha-BHCIbeta-BHCjdelta-BKCIgamaa-BHCJHeptaclorlAldrinKept, epoxideEndosulfan I_Dieldrin

» Endrin___Endosuifan II4,4'-ODD__lEndo.suifate|4,4'-DDT___IHethoxychlor_IEndrin ketone)fa. chlordane|g. caiordaneIToxapheno IIAroclor-1016IAroclor-1221!Aroclor-l232!Aroclor-1242 ~I_!Aroclor-124i<"li___! Arocior-l2542l2.£25L—iAroclor-1260 • ~Under QNT Y/M« enter Y if quantitation was performed, if if not performed.%D must bo less than or oqual to 15.0% for quantitation, and less thanor equal to 20.0% for confirmation.Note: Determining that no compounds voro found above tho OfcQL is a fora ofquantitation, and therefore at least ono column must moot tho 15.0% criteria,r multicomponent analytas, tho singlo largest peak that is characteristicthe component should bo used to establish retention time and %D.

dentification of such analytes is based primarily on pattern recognitionpaga of _c.

FORK IX PEST RR30I838 V87

9PESTICZDE/PCB STANDARDS SUMMARY

ab Name:f\]^S__________ Contract:_

Lab Code: ______ Case No.: *\? SAS No.:' SDG No.:Instrument iDa fA U*Va*Q5;co OC Column

I ^ <J*TI ;

alpha-SHCbeta-BKC 'delta-lHCgamaa-BHCHeptaclorAldrin __ _Kept, epoxide j t. o.Endosulfan I___Dieldrin___ 17..* 714,4*-DDE.ndrinadosuifan'-ODD___

JEndo.sulfate14,4I-DOTI Methoxychior_ | as-1Endrin ketonelj a. Chlordano.|g. ChlordanoJToxapheno.__'_|Aroclor-101« I .y, ?|Aroclor-1221[Aroclor-1232|Aroclor-1242I Aroclor-124B' ____I Aroclor-1254 12312] Aroclor-l2gQ I i3.».w IUnder QKT Y/KJ enter Y 12 quantitation vas porfonod, V if not perfoiraeo%D must bo less than or oqual to 15.0% for quantitation, and less thanor equal to 20.0% for confirmation.Notei Determining that no compounds voro found abovo tho OQL is a form ofquantitation, and therefore at least one column must moot tho 15.0% criteria.Far multicempenent analytes, tho single largost poak that is characteristic"< tho component should bo used to establish retention time and ID. ^entification of such analytas is based primarily on pattern recognition

pago _5 ofFORK IX PEST „ o n i O O Q 1/a7 Rev'flR301839

PESTICIDE/PCS STANDARDS SUMMARY

Haine:____M^*S__________ Contract:

Lab Code: ______ Case No.: /^ SAS No,:' _____ SOC No.:Instrument ID&<£*£. (lMjj*tj37*x> - GC Column

| DATS(S) OF FROM:ANALYSIS TOt f//zo/gtfTIME(S) OF FROM:H7cT?ANALYSIS

COMPOUND

alpha-BHCIbeta-BHCIdelta-BHCigamaa-BHCf KeptaelorlAldrinKept, epoxide|Endosulfan I_ __Dieldr in___*~ 17.^7.

• -»f;ndrin___ __ndcsulfan II |ja,4'-ODD

Endo. suifato 117,!4<4>-DDTIMethoxychlor_ICndrin ketonola. Chlordanog. ChlordanoToxapheno__~IAroclor-1221IAroclor-1232IAroclor-1242[Aroclor-124S[Aroclor-1254[Aroclor-1250

DATE OF ANALYSISTIME OF ANALYSISEPA SAMPLE NO.(STANDARD)

Under QNT Y/N* sntor T if quantitation vas porformod, if if not performed?ID must bo less than or aqual to 19.0% for quantitation, and less thanor equal to 20.0% for confirmation.Note: Determining that no compounds voro found above* tho CRQL is a fora ofquantitation, and therefore at least ono column must moot tho 15.0% criteria,

multicomponont analytas, tho singlo largest peak that is characteristicr the component should bo used to establish retention time and ID.•ntification of such analytes is based primarily on pattern recognition

page ji of FORK IX PEST flR.30!8UO 1/8?

9PESTICIDE/PCB STANDARDS SUMMARY

Lab Name:____fJv^S___________ Contract:

Lab Code: ______ Case No.: N£ SAS No.:1 _____ SDC No.:

instniaent ID:<££j£ji& &o37eo GC Column mtim*».*„/,.«<* c .| DATE(3) OF FROM: It/go/ggI ANALYSIS TO* \\l?o/&$'TIME(S) OF FROM: «'.o<ANALYSIS

DAlg or ANALYSIS _\\/ZI/APTIME OF ANALYSIS —— ——EPA SAMPLE NO.(STANDARD)

Chlordano j o-s?[Toxapheno """1Aroclor-101*IAroclor-1221JAroclor-1232|Aroclor-1242JAroclor-124SlAroclor-1254JAroclor-1260

Under QWS Y/ifj' antsr T if quantitation vas porformod,*N if not perfoziedT%D must bo less than or equal to 15.0% for quantitation, and less thanor equal to 20.0% for confirmation.Note: Determining that no compounds were found above tho CRQL is a for* ofquantitation, and therefor* at loast ono column must moot tho 15.0% criteria.* r multicompenent analytes, tho single largest peak that is characterlst

1 the component should bo used to establish retention time and ID.identification of such analytes is based primarily on pattern recognitionpegs of _£

FORK IX PEST BR3GI8U1 V87

9PESTICZDE/PCB STANOAKDS SUMMARY

b Name:____v*S__________ Contract:

Lab Code: ______ Case No.: M£ SAS No.:' _____ SOG No.:Instruaent iDXia&L i/frsLi*o3;co GC Column

COMPOUND

!alpha-BHC|beta-3HC_(delta-BHC,Igamaa-BHC^IHeptaclorlAldrin

DATE(S) OF FROMTu/so/ggANALYSIS TO; nfZvleSTIME(S) OF FROM: gtoTANALYSIS

RT

(Kept, epoxideJEndosulfan I_f Dieldrin! 4,4'-DDE.«drin___

desulfan II,4*-DDO__

lEndo.sulfato|4,4'-DDTIMethoxyehlor_IEndrin ketonela. Chlordano |£|g. Chlordane~f£I Toxaphens__~ j ]3.(Aroclor-lOltf ||Aroclor-1221~(Aroclor-1232|Aroclor-1242_ ____I Aroclor-124S_ | **£,__!Aroclor-1254_"____ ___IAroclor-12«0 i >2>3rf I fttm

I \^

DATE OF ANALYSISTIME OF ANALYSISEPA SAMPLE NO.(STANDARD) IMP

AO* i I

Under QNT Y/Nt entor Y if quantitation tras porformod, M if not performed.ID must bo less than or equal to 15.0% for quantitation, and less thanor equal to 20.0% for confirmation.Notai Determining that no compounds voro found abovo tho CRQL is a fora ofquantitation, and therefore at least ono column must moot tho 15.0% criteria.For Multicomponent analytas, tho single largest poak that is characteristic

p5* component should bo used to establish retention time and ID.itification of such analytes is based primarily on pattern recognition

page j ofFORK IX PEST 1/87 Rev.

AR3.Q.I8U2


Lab Name:____ A. !OS_______ Contract:

tab Code: _______ Case Ho.: M g SAS No.: _____ SDG No.:

Instrument ID:£2£i££tj£&2 uo~S70£> GC Column ID:

I DATE(5) OP FROM:I ANALYSIS TO:"| TIME(S) OP FROM:'I ANALYSIS TO:"

FROMWINDOW |CALIBRATION

alpha-BHC___I JO-I^Q j to....tooIbeta-BHC____jjj1 delta-BHC___ | j gamma-BHC___ j n____ _ __| Heptaclor___I iv-*>»5"J jfe.5 6"JAldrin! Hept(Endosulfan J_

*J Dieldrin____ __4,4'-DDE____lafr-'ifcT lafe-ia.7

1 Endrin i *^. 3^7 1 d* . it 7Endosulfan III A .o re \aa,oo*$14,4' -ODD .1 Jtt-toAl IEndo.sulfate4,4'-DOT| Methoxychlor_ i ST»** I 37.7*3| Endrin ketone j 3fa.j a, Chlordane^f__jg. Chlordane^l__[Toxaphene___[__|Aroclor-1016_|__|Aroclor-l22l_|__fAroclor»l232_(__|Aroclor-l242_J__iAroclor-124S_|__iAroclor-l254_j__Aroclor-12SO 1

I I

TO

to.

f A

S.M.5SU

».507

FACTOR

ISO

M/

DATE OP ANALYSISTIME OF ANALYSISEPA SAMPLE NO.(STANDARD)

RT

AS,

CALIBRATIONFACTOR

aV-7-7

QNT1 %0

Under QNT Y/N: enter Y if quantitation was performed, N if not performed.%D must be less than or equal to 15.0% for quantitation, and less thanor equal to 20.0* for confirmation.

Note: Determining that no compounds were found above the CRQL is a form ofquantitation, and therefore at least one column must meet the 15.0% criteria,

For raulticomponenc analytes, the single largest peak that is characteristicof the component should be used to establish retention time and %D.Identification of such analytes is based primarily on pattern recognition

page j_ of. FORM IX PEST 1/37 ?,ev'

AR30IBU3

PESTICIDE/PCB STANDARDS

NO. ;„ _ _GC Column ID: T->R. g-

OATaToy

- _Instrument

DATE(S) OP FROM*ANALYSISOP

COMPOUND

, . ———_____i|M@thoxychlor_| Endrin Icetone|a. Chlordan«_|g. Chlordane]]]I Toxaphene__^|Aroclor-1016|Aroclor-122l"IAroclor-1232"JAroclor-12423|Aroclor-1248_|Aroclor-12S4_[Aroclor-12€0~i "" _____.__________,_____I__________I__!_.___________I_____l____I_____I_________f_____l________I__!_Under QNT Y/N: enter Y zf quantitation was performed, N if not performed.%0 must be less than or equal to 15.0% for quantitation, and less thanor equal to 20.0% for confirmation.

Note: Determining that no compounds were found above the CRQL is a form ofquantitation, and therefore at least one column must meet the 15.0% criteria.

»For raulticomponent analytes, the single largest peak that is characteristic:of the component should be used to establish retention time and %D.Identification of such analytas is based primarily on pattern recognitionpage £. of *4Pa<?e £. of __

FORM IX PEST1/3?


Lab Name:_______A. 1iJ^______ Contract:

Lab Code: ______ Case No.: /qg SAS No.: _____ SDG No. :

Instrument XD»f%r.jt \I&v. ti~*>~jon GC Column ID:

DATE(3) OP FROM:ANALYSIS TO:"TIMS(S) OP FROM:ANALYSIS TO:

| COMPOUNDIt 3UMUMME1

Ialpha-BHCIb*ta-BHCIdelta-BHCj gamma-BHCIHeptaclorlAldrin(Kept,JEndosulfan I•JDieldrinI 4,4'-DDEIEndrin ' _JEndosuifan(4,4'-ODD ___j Endo.sulfate14,4'-DOTI Mathoxychlor_ I(Sndrin ketonejLa. ChlordaneIg. Chlordane1 Toxaphan _"j Aroclor-I0l6_|Aroclor-1221-J{Aroclor-1232IAroclor-1242JAroclor-i24S|Aroclor-l2S4_JAroclor-l260_|

DATE OP ANALYSISTIME OP ANALYSISEPA SAMPLE NO.(STANDARD)

Under QNT Y/N: enter r if quantitation was performed, N if not performed"!%D must be less than or equal to 15.0% for quantitation, and less thanor equal to 20.0% for confirmation.

Note: Determining that no compounds were found above the CRQL is a form ofquantitation, and therefore at least one column must meet the 15.0% criteria.

For raulticomponent analytes, the single largest peak that is characteristicof the component: should be used to establish retention time and %D.Identification of such analytes is based primarily on pattern recognition

•rpage 3 of *f_

FORM IX PEST 1/87, ?*v.

flR30i8U5

PESTICIDE/PCS ITANDARDS

Instrument

-~ SAMPLE NO.________ _____ t (STANDARD)

°™ , „ ' i jc Hi ra j«« ! n;V/M,

——

gaaaa-BHCHeptaclorAldrinsept. ipoxidSi iSrim?? £an '-ifestlfegS St-Sk'SSi

_ _ _ _ _ _ , ? 3?8r. 3>i _7_ i a*. «fl7(Bndosulfan II A?.ow Ia&,oosI aft<j gJ4,4r-DDD____ a^-toAf I aft.. g7/ i 3><=f. fa7 1End.i •» / •• ~uuu_____lEndo.sulfate"I 4,4 ' -DOT___~(Methoxychlor".IEndrin ketone |la. Chlordane!g. Chlordane"I Toxaphene__~IAroclor-ioi6~|Aroclor-1221~/Aroclor-1232*fAroclor-I242~||Aroclor-i248~|IAroclor-i254~||Aroclor-l260"|

___ ________,____i________I__i___________i____l____I I________I____I _______i__l_Under QNT Y/N: enter * if quantitation was performed, N if not performed.%D must be less than or equal to 15*0% for quantitation, and less thanor equal to 20.0% for confirmation.

Nota: Determining that no compounds were found above the CRQL is a form ofquantitation, and therefore at least one column must meet the 15.0% criteria.

*For multicomponent analytes, the single largest peak that is characteristicof the component should be used to establish retention time and %D.Identification of such analytes is based primarily on pattern recognition

»page iL of H.FORM IX PEST

1/37

fl'R30!8l*6

10 EPA SAMPLE HO., BI . PESTICIDE ORGANICS ANALYSIS DATA SHEET

.Lab Nane:______NUS___________ Contract:

Lab code: ______ Case No.: ME SAS No.: SDG No.:

Matrix: (soil/water)" UATER Lab Sample ID: ME BLK11/4W

Sample wt/vols 10QQ____(g/»I»)jnL_ Lab File ID: .- _____

Level: (low/med) ___LOW . Data Received: _______

% Moisture: not dec._____ dec._____ Date Extracted: 11/04/88

Extraction: (SepF/Cont/Sonc) SEPF Date Analyzed: 11/08/88

GPC Cleanup: (Y/N) N pH:___ Dilution Factor: ____1

CONCENTRATION UNITS:CAS NO. COMPOUND (ug/L or ug/Kg) ug/L Q

1I 319-84-6 ——————— alpha-BHCi 319-85-7 ——————— beta-BHC1 319-86-8 —————— delta-BHCj 5S-S9-9 ——————— gaama-BHC (Lindane)1 76-4 4 -8 ——————— HeptacnlorI 3 09-00-2 —————— Aldrin! 1024-57-3 ————— Heptachlor epoxide1 959-98-8 —————— Endosulfan I1 60-57-1 —————— DieldrinI 72-55-3 ———————— 4, 4 '-DDEI 72-2 Q-S ——————— EndrinI 3-3213*65*9 ———— Endosultan 11[ 72-5-C-S ———————— 4 , 4 f -DDO1 1031-07-3 ————— Endosulfan sulfate[ 50-29-3 ———————— 4,4f-DDTf * » " » _ * - » _ _ ......_ . . « . W ....^ •% ' __

1 53494-70-5 ———— Endrin ketone\ 5103-71-9 ————— alpha-Chlordajiej 5103-74-2 ————— gaaaa-Chlordane1 8001-35-2 ————— Toaeaphene[ 12674-11-2 ———— Aroclor-1016( 11104-2S-2 ————— Aroclor-1221I 11141-16-5 ————— Aroclor-12321 53469-21-f ————— ATOClor-1242| 12672-29-6 ————— Aroclor-1248I 11097-69-1 ———— Aroclor-1254I 11096-82-5 ———— Aroclor-1260I

0.05n ns1? {?*0.050.050.05n.nfj0.050.10n in0.100.10o.inn in0.10n.5n in0.50.51.00.5R-?0.50,50.5M?1.0

1

If i'] lU 1U I

u 1U 1

__ U !U . . 1U iU .._!!! fI] jU 11 1

ll 'n IU __ 1I) 1U 1(1 iM iU Iu _ iu _ iu _ iU 11

FORM I PEST 1/87 Rev.

AR3018U7

10 EPA SAMPLE NOPESTICIDE ORGANICS ANALYSIS DATA SHEET

Lab Nane: NUS _____ Contract: I P8LK 5

Lab Code: Case No.: ME SAS No.: SDG No.:

Matrix: (soil/water)' UATEft Lab Sample ID: MSE BLK11/8W

Sample wt/vei: 1000 (q/aL) Ml Lab File ID: _ _____

Level: (low/aed) LOW . Date Received: ________

% Moisture: not dec.____ dec.____ Date Extracted; 11/08/88

Extraction: (SepF/Cont/Sonc) SEPF Date Analyzed: 11/08/88

GPC Cleanup: (V/N)_N pH:___ Dilution Factor:

CONCENTRATION UNITS:CAS NO. COMPOUND (ug/L or uq/Kg) uq/L

I.

319-84-6———————alpha-BHC319-85-7——————beta-BHC_J319-86-8———————delta-BHC58-89-9———————gaama-BHC (Lindane)76-44-8—•—-——Heptacnlor______'309-00-2—————Aldrin _____1024-57-3—————Heptachlor epoxide_959-98-8——————Endosulfan I____~60-57-1———————Dieldrin________72-55-9———————4,4 • -DDE_________72-2 Q-8——————Endrin33213-6S-9————Endosullan72-54-5————————4,4f-DDO1031-07-8—————Endosulfan sulfate50-29-3————————4,4'-DOT72-43-5——————Methoxycolor53494-70-5————Endrin ketone5103-71-9——•——alpha-Chlordane_5103-74-2————-gaama-Chlordane"8001-35-2--—-—Toxaphene_12674-11-2—————ATOClor-101611104-28-2————Aroclor-122111141-16-5———— Aroclor-1232"53469-21-9————— Aroclor-1242"12672-29-6—————Aroclor-1248*11097-69-1—————ATOClor-1254*11096-82-5————Aroclor-1260~

0.050.05Q.05n0.05n.nsnQ.1Qn in0.10Q.1QQ.1Q.n in0.10

n m0.5i nQ.5

0.5


ID EPA SAMPLE NOPESTICIDE ORCAKICS ANALYSIS DATA SHEW

f————~ ^ I SW/SED7MSLab Have:______nu:>___________ Contract:________ |

Lab Code: ______ Case Ho.: "* SAS Ho.: SOG Ho.:

Matrix: fsoil/vatar)" Soil Lab saaple ID: P104074MS

Saaple vt/ Hs 30.00 fg/aL) g Lab Pile ID: .

Level: (lotr/aed) Low . Date Received:

% Moisture: not dec. 25_ dee.___ Date Extracted: 11/10/88

Extractions (SepF/Cont/Sonc) Sonc Date Analyzed: .11/20/88

GPC Cleanup: {Y/N)J1_ pH:___ Dilution Factor; 1

COHCENTRATIOH UNITSCAS NO. COMPOOND (ug/L or ug/Kg)

319-84-6 ————319-85-7 ————

58-89-f —————76-44-8 ———— —309-00-2 ————1024-57-3 ———959-9S-8 ———— •60-57-1 —————72-55-9 —————it *i rt f-/"J> *.U (»33213-65** ———72-54-S —————1031*07-8 ———50-29-3 ————— -72-43-5 —————53494-70-5 ———5103-71-f ———S103-74-2 ————8001-35-2 ————12674-11-2 ———11104-28-2 ———11141-16-5 ———5346f-21-f ———12672-2S-6—— -11097-69-1 ———11096-82-5 ——

—— alpha-BHC—— beta-BHC—— delta-BHC—— gana-BHC (LJCndane)— Heptacnlor- — Aldrin- — Heptacnlor epoxide— -Sndosulfan I— Dieldrin—— 4, 4 '-DDE

&fiOfm— Endosullan 21——4,4 f-DOO—Endosulfan sulfate——4, 4 '-DOT- — -Kethoxychlor—-Endrin ketone—alpha -Chlordane•~ a»aa -Chlordane— Toxaphene— Aroclor-1016— Aroclor-1221— Aroclor-1232— Aroclor-1242— Aroclor-12 4 $— Aroclor-12 54•»~Aroclor-1260

111111S551111S71S7171

_ 215nn711JO110210110nn— s —110510210

uuu

uuu

uuuuuuuuuu _. _uuuu_.__u _


10PESTICIDE/PCB IDENTIFICATION

Name:_____NUS - .——'————————— Contract:______^ ,

Cod*s ______ Caee No.: ME————— -*« no.: ______ S06. NoGC Column ID (1>:1-5%SP2250/1.95XSP2401 —— -

——————• GC Column ID (2) • DB-5Instrument ID (1): GC#2 Varian 3700 r „. "T Tw - ,,™

——————— Instrument ID (2)- GC#6 Vanan 3700Lab Sample ID: P103821____ " ———————.

Lab File ID: , ' „ .^(only if confirmed by GC/MS)

Comments:

page _1 of 1_FORM X PEST

——————- —-mrnmmm^mummmmmmm:

PESTICIDE/PCB RETENTION TIME RT WINDOW QUANT? GC/MS?OF STANDARD (Y/N) (Y/N)FROM TO

01 DDE_____ Column 1 6-609 6.540 6.782 y N

02 Column 2 26.166 26.127 26.207 N N

03 DPD_____ Column 1 10.255 10.143 10.509 Y N

04 Column 2 29.620 29.571 29.671 N N• , .^05__________ Column 1

06 Column 2

07_________ Column l08 column 2

09_________ column l10 Column 2

ll_________ Column l12 Column 2

flR30!850 1/37 Rev.

MEISER & EARL - COMMENTS

1. The DEC shift for EVAL B on November 9, 1988 at 4:33 was greater than theacceptable limit for the primary analysis on November 7, 1988. EVAL B wasreanalyzed on November 9, 1988 at 5:59 and the DBC shift was within acceptablelimits, therefore analysis of samples resumed.

2. The percent difference between calibration factors for DOT and Methoxychlor for theprimary analysis on November 16, 1988 at 22:20 for Ind A were greater than theacceptable limit. Analysis was stopped and recalibration occurred on November 20,1988.

3. The percent difference between calibration factors for Endrin for the primary analysison November 21, 1988 at 10:11 for Ind B was greater than the acceptable limit. Nofurther action was taken since no samples were analyzed after this standard.

AR30I85I

e

AR301852

SECTION 4

INORGANIC SUPPORT DOCUMENTATION

853

PROJECT

SUPPORT DOCUMENTATION FOR THE REVIEW OFINORGANIC ANALYTICAL DATA PACKAGE

APPLICABLE SAMPLE N0*«.: —— SWlSEfV- |--TYPE OFCONTRACT LABORATORY :__A£*lS _________ S |5E:Dl9-

REVIEWER s-11____KL.H>. fermQ-H_______t SurJ-a<T(f u,0rfc?rREVIEW nATr f ^l-Vio^ ^___________

THE FOLLOWING TAiLE INDICATESAREAS WHICH WERE EXAMINED INDETAIL, THE IDENTIFIED PROBLEMAREAS, AND SUPPORT DOCUMENTATIONATTACHMENTS:

AREAS EXAMINEDIN DETAIL

CHECK(V) IF YESOR FOOTNOTE LETTERFOR COMMENTS 3ELOW

PROBLEM AREASIDENTIFIED

CHECK (V) IF YESOR FOOTNOTE NUMBERFOR COMMENTS BELOW

SUPPORTDOCUMENTATIONATTACHMENTS

CHECK(V) IF YES~OR IDENTIFY

ATTACHMENT NO.

HOLDING TIMESBLANK ANALYSIS RESULTSMATRIX SPIKES (PRE-OIGESTION )DUPLICATES -QUANTITATION OF RESULTSDETECTION LIMITS/SENSITIVITYINITIAL CALIBRATIONSCONTINUING CALIBRATIONSLABORATORY CONTROL STANDARDSICP LINEAR RANGE ANALYSISICP INTERFERENCE CHECKSICP SERIAL DILUTIONSGFAA POST- DIGESTION SPIKESGFAA DUPLICATE BURNSGFAA STANDARD ADDITIONSOTHERS

^V

yy////,

s,J

s

Y

/

s

/

/\/\s*S

^.yS

s

s-

1

COMMENTS:.

^

1

PRRRMETER

Meta^

M*US|*

M^lCW

MetiisIcK/

Me-tals|cW

l WialslrAj

>

TVPE/MRTRIH

TC / Sed

CCfSed

?B 1 Sed -

TClA,

CC /AqV-fV f \ • \ \

^ — ; .*•TB tSt:d

SRMPLE #

Ca.1 "BikL

Cal Bl C

B^nt

<iT/•* .

CalBlc

ISc

SOURCE

W,s

AJcS'

A/U5

»W5

WJS

taS

CONTRMINRNT (CONCENTRflTION)

'• b.CG n S. .. CNJ

O.OD3 oti>5 CN/

O*3 ™oicq zinc ~f i-^acfl^^

*— . ii tf1 /JT. 1 U^k2 obO-CO^ ctbs C\/

6, / f 2 S bO.CXM <&$ C!\J

None repot fed

LRBORRTORV REPORTED FIELD BLflNK IS COMPRRED WITH THE SflMPLE DRTR IN fl TRBULRTION FORM WITHIN THESftMPLE RNflLyTICRL DRTR SUMMRRY.COMMENTS :

(1) RESULT REPORTED BY THE LRBORRTORY flND CONFIRMED BY REUIEWER(2) RESULT INFERED FROM INSTRUMENT PRINTOUTS flND/OR SUPPORTING DflTfl

OiOfiGANIC CASE OMffiWTS

MEISER & EARL

Cyanide analysis for sample SW-15 (NUS sample number P103940) was not performedon the preserved sample because the sample container was inadvertently notrefrigerated. An aliquot of sample was taken from an unpreserved, refrigeratedglass container instead.

flR301856

U.S. EPA - CLP

2A - 1INITIAL AND CONTINUING CALIBRATION VERIFICATION

Lab Natfe: NUS CORPORATION_________ Contracts

Lab Code: NUS__ Case No.: ME___ SAS No.: _____ SDG No,:

Initial Calibration Source: SPEX STD y

Continuing Calibration Source: SPEX STDvi/

X ""**/ Concentration Units: ua/L~

.' Ar.alyt^

: Aluminum.! An t imony.1 Arssn ic _k&ariumJBeryl 1 iLim! Cadmium _! Calcium _J Chromium_iCocaic1 Capper __J Iron ____!Lead ____I rlacjnesium! Manganese; Mercury _JNickel __r Potassium! Selen ium_f Si Iver __f Sodium __; Thai I ium_I Van ad ium_I Zinc ____! Cyanide _i

InitTrue

ial Cal ibrat ion/ Found XR t 1 )

__99700. -5! 102500.0_10O70. 3 I 10520. 00_i 0020 . 0 ! _9933 . 3310O500. ! 97300. 00_955XiQ. J J 1 00800 . 0_SJ004oTp! 93000. 001 OO 1 OO . 0 ! 94200 . OO100900. 0 ! 99QOO.OO1 00 1 00 .01101 OOO . 01 OOOOO . 0 ! 97300 . 001 OO 1 00 . 0 ! 96000 . 00.10O20.0 .' 10133. 331 00200 . 0 ! 93000. 00_99SOO. 0 .' 100300. 0____ 50 . O ! ___ 50 . 0010070O. 0 ! 102000. 0_1 OO 1 SCO ! _1 022000_10O3O.Q! 10533.33_99SOO. 0 J 9SOOO. 001 OOOOO. 0 ! 9600O. 00__ 997O.O! 10160.00_10O9Q.O! 10560.001 00 1 OO .011 OOOOO .0_ __ 250. 0 J __ 268. 00

ti

i 02 . 3104.51_99. 197.:I£&u5(ff Ty_^^i_93. 1i oo . 9_97.3_95.9Toi, i.97.8101.01 00 . 0101.3102.0105.0_J?8.5_96 . 0101.9104.799.9107.2

Continuing Cal ibrat ionTrue Founa /'.R ( 1 ) Found 7.R ( 1 )

.9970O. 0 i 99000. 00

.1 0070 .011 0 i 90 . 00

.1 0020 . 0 ! 1 0066 . 671 005OO .01991 00 . 00.99900. 0 ! 94300. OO1 00400 ..0 I 97600. 001 00 1 OO . 0 i 99900 . 00100900. 0 ! 9SOOO. 001 00 1 00 . 0 ! 96000 . OOi OOOOO, 0 i 96800 . 001 00 100.019 2000 . 00_10020. 0 I . 9900. OO100200. 0 ! 96000. OO.99800. 0 ! 97700. 00

50 . 0 ! _ _ 48 . 001 00700 . 0 ! 1 OOOOO . 0. 1 00 1 500 J .1 OOSOOO.1 0030 .0111 000 . 00.99500 . 0 ! 97000 . 001 OOOOO . 0 ! 95000 . 00__9970. 0 i 10560. 00.10090. 0 ! 10500. 001 00 1 00 .011 0 1 OOO . 0___ 250 . 0 J __ 26S . 00

i

_99. 3193900.00101. 2 J 10240. 00100. 5 ! I 020O.OO98.6199900. 00.94, 4! 91 100, 00_ 97. 2 I 970OO. OO_ 99.8! 104000.0_97. 1 198000.0095. 9 ! 96O(">0. <">U_96. 8 199400. 00_ 9 1 . 9 J 92000 . OOT S « a » t _ 7000. -j".'

J?5. 8 J 96000. 00_97. 9 198200. 00_96»0i 48, 00_99. 3 ! 92000. OU100.61.1021000109. 7!_9933.33_97.5 195000. Ou_95.0I 96UOO. OO105.9! 10 ISO. 00104. 1 { 10070.00100. 9 i 1 OOOOO. 0107.2! __ 280. 00

i

J94.2To i . 7101.8_99. 4191.296 . 6103.9J?7. 195. ?_99.4.91. 9_96. 1_95.£J?8. 4-6. 0.91.-101.9.99.0_95.5_96 . 0102. i.99.8199.9112.0

(1) Control Limits: Mercury 80-120; Other Metals 90-110; Cyanide 85-115See Attachment 2A - 7

M _

F

r

FORM II (PART 1> - 2

U.S. EPA - CLP

2A- 2INITIAL AND CONTINUING CALIBRATION VERIFICATION

Lao NAmai NUS CORPORATION_________ Contract:

Lab Code: NUS__ Came No.: ME___ SAS No.: _____ SDG No.:

Initial Calibration Source: SPEX STCsS)

Continuing Cal ib rat ion Source: SPEX STCkj)

Concentration Units: ug/L

1 1: .' Initial CalibrationI Analyts ! True Found MR < 1)• iJ Aluminum : I[Antimony !!Ar««nic '! Barium !tBervl 1 ium !i Cadmium IS C A 1 c i urn J! Chromium \! Cobalt1 Copper ;! Iron!L^ad I• Magnesium ilM*nGan«@Ji rercury ;.Nickel1 ,co t-asmium !! Selenium !1 Silver i! Sodium I: Tn&l 1 ium I! Vanadium !IZinc IICyaniaa I; : i

———

Cant in u ing CalibrationTrue Found XR ( 1 ) Found XR ( 1 )

.99700. 010070,01OO2O.O100500.0.99900. "100400. <>lOOlOO.o100900. u100100.0i OOOOO. 010O100.010020.010O2OO.O998OO. 0

50.01OO700.010O150010030.0.99500.01 OOOOO. 0_ 9970.0.1OO90. 0i oo loo.o

250.0

94800. 009960.0010200.00101100.090100. OO96500. OO1035OO.O102000. 099000.0098300.0091 OOO. 0010133.339700O.OO9S50O. 00

48.0094000.0010660009966.6797000. OO96000.001063O.OO.9610.OO101000. 0__ 280. 00

_95. 1J98.9101.8100.6_9O. 296. 1

103.4101. 1_98.9_98.3.90. 9101. 196.3.98.796 . 093.3

106.499,4_97.5.96.0107. 1

TOO. 9112.0

9780.0010566.67

93000. UO10033. 3393UUO. UO97900. 00

10333. 33

10530.009420. 00

_97. 1105. 5j

"

^~ . ?100. 1v7.398, 1

103.0

104). 193.4

; A

; A_* *»' 1i F_

:^_i C

•' A.! A_I F ^i A]! A_i r* _,F"

•A.i c

<1) Control Limits: Mercury 30-120; Other Metals 90-110; Cyanide 35-115^See Attachment 2A-7

flR301858FORM II (PART U - IN

U.S. EPA - CLP


Lao Name: NUS CORPORATION_________ Contract:

Lab Code: NUS__ • Case .Nc. : ME___ SAS No.: _____ SDG No.:(2)

Initial Calibration Source: SPEX STDj ;

Continuing Calibration Source: SPEX STD

, Cc-n cent rat ion Un i ts: ug/L

: ! Initial Cal ior at ion ._ Con t muting Calicration ; ii Analyte ; True round ".R (1) True Found XR C1) Found XR < 1) : l

•' Aluminum ; ! :.' An t imonv r i !.'Arsenic ; i ' i(Barium ! i I\ rervi 1 ium ; ; i; Cadmium ; i ;. Calci-m ; ! ; -I Chromium I ! •:! Cos A It ; ; •; Copper i ; i: :rcn i ,' ;!s_ead : ! !i Maqnesium i ! ;! "^anoanese I . i IMercurv i i !: Nickel ! ! !! Potassium! i I; Selen ium i < !iSi Iver ! i '>! Sodium J *; Thallium ; ! !! Vanadium I ! !; Z i n c f ! !! Cyanide ! ! !! ' 1 *

10020". 0

10C20. 0

-

1009O. 0

1056o. 67

10000.00

"

10030.00

i i • »' ' * T

105. 5 i 10733. 33 i 107. 1 . .1 P I T

1 1

1 1 ' '

! • - ,- .i > •i ' ' ii • >r i ( i

1 ; ; ,"

99 . 3 I 9500 . 00 i 94.3;;1 1 < r

f i I '

i r l i1 ' l •l i l •

f i * 'l 1 'I 1 1 i

i i ' 'i ' "i * '

i • ' '

99. 4! i ..; ;' •' i !r « ' '' ' , , , ' ',

'' * > Control Limits: Mercury 30-120; Other Metals 90-110: Cyanide 35-1*5See Attachment 2A-7

FORM :I

U.S. EPA - CLP


Lab Name: NUS CORPORATION_________ Contract:

Laa Codes NUS__ Case No.: ME___ SAS No.: _____ SD6 No.:

InitIA! Calinration Sourca: SPEX STD (2)

__..__..,._- „ _ _ . _ . _. . .. _ _ _

\Concentrat ion Un i ts: ua/L

J J Init'lAnAl-yt* « Tru»

_al CalibrationFound XP:<i>

: Aluminum. :. 97OO. it 1 *?9OOO. OO ; .99. !:! Antimony.! _10070.Q! 1036O.OO! 102. * ': Ar»»n ic _ i _10O20. di _J?5OO. OO i .94. £Barium __ \ 10O50O. 0« 95OOO. 00 1 94. S

• Beryllium: 95S0iX JL9 9OOO. OO IgSjJ{Cadmium _ :Q 040._gj>77OO.OO (973-J! Calcium _ : l'X*"iOO.Oi 1O1OOO. O I rDO79, Cnramium.l 10O900.OI 99OOO.OO ! .98. 1ICooait "": 100100. O I 9S8OO.OO! 98.7Capper __ J 1 OOOOO. O! 1 OOOOO. O 5 1OO. 0

; Iron ____ J 100100.OI 1 OOOOO. O ! .99. 9iLeaa _____ !. 10020.0! 1O166.67! 101.5:M»$n«»ium; 100200,0! 1 OOOOO. O ! _99. 8; r*nQ*n»m» I .99800. O ! 1O10OO. 0 1101.2.! v!«rcurv I 50.0! 48.50? 97.0'.Nickel __ ! 100700.O:996OO.OOt_98.9

J 5s l»n ium { lOOoQ. 0 I _93£6. 67 1 _J?3. 4I 31 1 v«r __ ! .99500. 0 ! 96OOO. 00 ! .96. S! Sad ium __ 1 100000.0! 1 OOOOO, 0! 100.0. Thallium.! __ 9970. OS 1O16O.OOJ 1O1.9J Vanadium.!. 1 0090.0 11O6OO.OO1 105. 1i Zinc ____ i lOOlOO.Cf! IQ20QO.O! 101.9I Cyan ids _ ! __ 25O. 0 I __ 2SO. OO! 112.0> t » i! I l l

i >Continuing Calibration 1 ;

True round XR ( 1 ) Found XR (. 1 ) ! ! r

.99700. 0

.10070. 0

.10O20.0100500. 099900. 0100400.010O 100.0100900.0100100". 01 L>OOOO . O100100.0.10020.010O200.0.99800. 0

50 . 0100700. 0.1001500.10030. 0.99500. 0100000.0_ 9*70.0.10090.0100100.0_ __ 250.0

100000, O10110.00

105000. 098800.0097200. 00100000.099000. OO9660O. 001 OOOOO. O9740O.OO10300. 00101 OOO . 0103000.0

52 . OO97800.00.100OOOO10366.679600O.OO101000. 010540.OO10150.0010400O.O__ 280. OO

1 00 . 31 00 . 4.95. 1104.598.9.96.8.99.9.98. 196.5

1 00 . 0.97.3102.81 OO . S103.2104.0.97.1.99 . 91 03 . 4.96.5101.0105.7100.6103.9112.0

105000. 0! 105.3! ! A.10110.00! 100.4! IF. 533.331.95. 1 '9 1 000 . 00 1 .90 . 5 1^19760O. 00 1 97 . ~ 1 : A98300 . 00 ! _9£ . &- \ ! A.101000. 0 I 1OO. ? . 1 A.P500O. 00 ' __94. 2 i i A,95800*00 ! 95. 7 ; A1 OOOOO .O.I 00 .<-•'• ; A.96200. 001.96. I ! J A.10266. 67:102. 5! ! F.1 0 1 OOO - 0 I 1 00 .SI ! A102000.0! 102.2! , A

48. 5O! 9™.0! 1C196200. 00 I. =55. 5 I !t-\992000.0! "99. 1 ! I A10533.331105.0; IF94000 . 00 I _G4 . 5 ! ; A99000 P 00 I .9? . 0 I *. A1 0720 . 00 i 1 07 . 5 ! ; F10410. 00 1 103.2! IF1 08000 . 0 ; 1 07 . 9 i I A_ 240 . 00 ! .96 . 0 J ! C.

i ;

Control Limits: Hercury 80-120; Other Metals 90-110; Cyanic© 35-115See Attachment 2A-7

flR30i8FORM II (FART 1) - IN

-U.S. EPA - CLP


uah Name: NUS CORPORATION__________ Contract:

i_ab Code: NUS__ Case No.: ME___ SAS No.: _____ 3DS No.:. - _ - - - . ~ f^\

Initial Calibration Source: SPEX

. . . _ . . _ _

Concentrat ion Units: ug/L

; . Initial Cali&rat ion,'Analvte , True round XR (1)

Continuing Calibration I!True Found '.& <.1) Found XR <! 1) I ! r

. HlumirtL'.iTi i; Ant imonv i1 Ar-san ic !

\ &arium !1 2e*-vi 1 iu.Ti .'. Cadmium !- Calcium ;> Chromium I; Cobal t '; Copper: Ir^on ;I Lead i( aones turn ;i Manoanese !. Mercury :iNickel: Potassium !i Selen turn J.Silver irSoaium !fTnalliu.Ti J; Van ad ium I! Zinc If Cyan ice 'i >i i

1

i

997 W, '-.'10070. 010020.01005OO. 099900. 0100400. O100 ICO. 01009OO. 01001OO. 01 OOOOO. -0100100. 010020.01002OO.O99800. 0

100700. 010015001 0030 . 0J99500.01 OOOOO. 09?70. 0

.10090.0100100. U

250. 0

1 '.:-luuo. 010240. 0010366, 67103000. 099200. 009750O. 00103000.0100000, 094200. 00102000.0101400.09800.0010 1000. 0101000.0

96300. 001013000.9633.33960UO. UU990UO. 0010260.00101 10. 00104OOO.O240, 00

101.3101.71 03 . 5102.599.397. 1102.999. 194. i102.0101.397.8

1 Ot3 . 8101.2

96. 1101. 196.096.599.0102.91 00 . 2103.996.0

I ! A9900 . 00 ! .93 . 3 I ! F10166.67! 101.51 IF

; ; :A' • A

! ! Ift1 0200O .0:1 0 1.91 ! A

1 ' • ±,i i i H

i • ! Ai t . Ai i i hf

i j i A10000. 00! 99. 8 I ! F1 0 1 000 .01 1 00 . 5 i ; A

1 i ' fL\ r » H! •p ; •

1 t 1 K«

1 ' ' -it , 1 t-i

9766.67! 97.4! :Ft « « .>t i i rt

i ' i«i i i i-i

9940. 00 i '99 . 7 ; ; F9770.00! 96. 3! !F

! ! ! Ai t i pi i i L/

i i i

-,J.) Control Limits: Mercury 30-120; Other Metals 90-110; Cyanide 85-115See Attachment 2A-7

AR30I86I

U.S. EPA - CLP


Lao Name": NUS CORPORATION_________ Contracts

Lab Cod@s NUS__ Case No.: ME___ SAS No.: _____ 5DG No.:

.. ....... _ _.... ... _ _ _

Continuinc Calibration Source: SrE> 5TD (2)

Cor.c»n trsit ion Jni t3 : uo/L

:£nAlyt* I True

; Aluminum !lAntimanv IJAraenic 1

f Barium ;^ i 5»fiv 1 1 :um !

! Cadmium I; Calcium !I Chromium !tCoo'mltJCopoer «! I rcn i, L.saa I;MAan««iuJi!;r.*noAn«»«:i^ercurv: Nicj'»l I1 F ocas si urn •> i»l»nium I» 5 1 1 v » r I:5oaium !\ 7-i4u 1 ium !t Van Ad ium !iZinc I! Cyanide I• ii t

Founa

.-

~

~~

/»t"\ '. j. .- "rue Found

10070. O ! 10290. 00>ri*

i

;Jt;r ~ ~i

iii

i

fj

t

tti

9970. .'.: ! 10130. 00r

',

i

XR ', 1 ) Found XR C 1 )

! 1J 1

1 ("j"1 T1 ' '

! !i >

- I - - - fi

i i

"" i fi i" " i ii i,

i 'i •i i, i

iit tii itf i

i '

;102. 1 i

. _._. _ ; ;; ;', i! I1 '

(1) Control Limits: M«rcury 80-120: Other Metals 90-110; Cyanide 55-115'T) See Attachment 2A-7

RR301862FORM II (PAST i; - IN

U.S. EPA - CLP

2B - 1CRDL STANDARD FCR AA. AND ICP


Lab Cede: NUS___ Case No.: ME____ SAS No.: ______ 5DG No,:

AA CRDL Standard Source: - LEEMAN STD

ICP CRDu Stanoard Source: _________

Concentrat ion Units: uo/L

i CRDL Standard far AA

Analyte J True Four, a XR

A 1 urn i n um_ ! __20< J . 0_Antimony I 6< >, 0Arsenic ; 10. 0Barium : 200.05eryi 1 ium ! 5. 0-admium _ : __ 5. U_Calcium ! 5000. 0Chromium ! 10. 0Cods' i t ; 50. 0Copper ! 25.0Iron i 100. 0Lead ! 5.0f^agnasium i 20OO, 0_Manganese ! _ 15. 0_Mercury !Nickel i 40.0Potassium i 500O. 0_Se 1 en i um_ ! __ 5 . 0—Silver I 10.0Sodium 15OOO.OThallium I 10.0Vanadium J 50.0Zinc J 20.0

I

__ 190. 00_6 1 . 009. 80

__ 200. 00____ 5. C0_____ 5 . 00_5070. 01 0 . OO50. 0026.00

1 00 . 00a. 20

__ 2090. 0____ 15. 00_

40.004790. 0

___ 5.30_10.00

50OO . 09. 10

51.0020.00

101.79S. 0

_100. 0_100. 0100. 0101. 4100.0100. 0

. 104.0

" 16 4/0)1_ 1O4. D_1 00. 0

1 00 . 0__ 95.8.106.0.100.0100. 051.0102.0100. 0

C RDL 3 tan a a r d for I CPInitial Final

True Found Xft Found Tir.

; > ii <i

_____

;;;;I;

|;i!;1ir

l

•

t

ilitl

FORM II CP^RT 2) - IN

U.S. EPA - CLP

2B - 2CRDL STANDARD FOR AA AND ICF

NAmtti NUS CORPORATION________ Contract:

LAO Cod©: NUS__ Case No. : ME___ SAS No. : _____ 5DG No. :

AA CRDL Standard Source: LEEMAN 3TD

ICP -RXt_ Standard Source: __________

Concentration Un i ts: ug/'_

i _ _ - •• ' .. .. ( t ^CrHL 3C-^ncJtrd tor AA I \ CRDL Standard for ICF

J I ; ! Initial Final•-^riAlvta • Tru* Found "/.R r ; ~rua Found "/.R: "ouna

i A i '-',7) l nuiin • 2vO . O, *__..,_—_—. » r f i*~*• f-in v i in on y i Q'J . yiAr*33*îc ' 1 *~j • 0» An urn ! ZOO. O

. Seryl 1 i«m i 5, O1 Cadmium ; 5.0i CA Ic ium ; 3OOC . 0'.Chromium ! 10.0'Coc^lt ; 50.0, Caooar I 25. 0. Iron ; 1OO.Oi L@€ic! i w . 0;,MAgneîum!"OOO.O-Manoangse! 15.0irnercurv i; r\i i c t e 1 : ^0 . 0, rot JIM mi am 1 5OOO.O; Selsn ium ! 5.O.3;lêr ! 10.0! socium S5000.O! 7**.*1 1 ium i 1O. 0iVmnaoium I 5O.OJZinc . 20.O

"OC- . OO64. SOa, 90

200 . oo4. 004.OO

5100.01 0 . 005O.OO30. OO130.OO7.80

1940.020 . 00

30. OO483O.O5.00

1O.OO5OOO.O10.3053.303O.OO

•

10O. 0 i !loa.o: iSnrr; ;

iQuTvl :^so . u} ;s T j s1 02 rol '100.0! ;idQ-,0 ! !

\1 *i U . ty > •T r*i 7*i • 'li •— ' . ***,! t

f 1 A t't ' '.IjQ.Jji/t i

^97~O i !( 33." ! [

^._ ( [V. / w . On '5To! .

loo.os :100.0! !10O. O! ;1O3.0! !l<i& 6! :

TlSOÔS 1i '

J

;:1itiiiii•i,Iti! - -iir41

1

1

I

t

t

f

1 . K.

; ^^B

;

;

•:,t.:;:•,;;

*

FORM II CrART 2.' - IN fiR30 I

U.S. EPA - CLP

3- ABLANKS


Lab Coae: NUS__ , Case No. : ME____ SAS No* : ______ SDG No,

Preparation Blank Matrix (soil/water): 3QIL_

Preparation Blank Caneentration Un i cs Cug/L or mg/kg): MG/K3

; ; i n i 11 a l ; - ; ;I Calib. I Continuing Calibrat ion J J * Prepa-I ! Blank ,' Blank (ug/L; !i rationJnnalyce i *ug/L) C! 1 C 2 C 3 C! ; Blank

f A 1 urn i n urn ! 200 , 0! Antimony f 4,0; Ar<3sn ic 2.0; Bar ium ,' 200. OI Bervl i ium : 4.0I Caamium i - 4. 01 Calcium ; 200.0. Chromium • 10. 0; Cooal t ; 40. 0'. Copper -' 10. 0 _flran i 30. OiL-ead - J 2.0. aqnesium ; 10. 0! Ma.ncanese I 10.0Iîe^curv" ! 0.2! Nickel ! 30.0; Pcrassium ! 20. 0i Selenium ! 2.OHilêr ; 10.0! Sod ium ! 1OOO.O: Thai! ium ! 2.0.'VanaaiutT, : 2.0! Zinc ; 10.0 -îCy&niae 10.003 abs Cl)i i

U! 20 O.O iUu; 4.0 fuUi 2.0 ,'UU! 200.0 !UU!, 4.0 JUU ! 4 . 0 ! UU! 200.0 JUu: 10.0 iuU! .40.0 !UU! 10.0 iUU! 30.0 iUU 1 . 2.0 i Uuj 10.0 ;uU! 10.0 !Uui 0.2 ;uU! 30.0 iUUJ 20.0 JUu: 2.0 iuUi 10.0 iUU i 1 OOO . 0 J UU! 2.0 JUU! 2.0 JUu; 10.0 IL!0.003 absCwr '1 1

.200. o . i u4.0 . J U2.0 ; u

200.0 !U4.0 :u4.0 JU

200.0 !U10.0 !U40 . 0 ! U10.0 J.U30.0 !U2.0 JU

1 0.0 i Ui o . o ; u0.2 ?U30.0 JU2O. 0 iU2.0 !U10.0 JU

1000.0 JU2.0 ; u2.0 IU10.0 4.U

0.003 abs lj•

20O. 0 J U ! ! 2<>. 04.0 !UJ I f . 42.0 ! U J ! - ) . 2

20O. 0 !U! ! 2(>. O4.0 JU! : : . 44.0 fin ; * . *

200. 0 JU; ! 2' -.010.0 JUJ i 1.040.0 JU! ! 4. 010. O JU! ! 1.030. 0 I U ! ! 3. 02,0 !U! ! 0,2io.o ;u; ! i.o10. o JU! : i.o0.2 JU! ; 0.02 ...

30. 0 lU.' J 3.0 _20. 0 :Ui ! 2.02.0 JU! ! 0.2. ....io.o ; u i J i . o

1 000 .0 J U J ! 1 00 . 0"? ,-'. M l ' 1 t*i *•i . t J i U i ' ',.'.*_

2.0 iU.' ! 0.210.0 >-UJ! ! . ...l.O s

0.003 absvj) ; ; 10.0_Vj.i i i

u:u;u;u:u;UIU!1 1 >w i

Uiu;u;u:u;U!' J i

U!U i

u:u;Uiu:• i '• j ti ' *

\)'j'•

AFt—A•\rfAAA•\rtAAFH

ri

cvAA .F-i

A

rFA•_ ,

Footnotes immediately follow Form^3-F.* Solid preparation blank of 11/03/88.

FORM III - IN flR30i865

U.S. EPA - CLP

3 BBLANKS

_&O NAm»t NUS CORPORATION__________ Contract:

Ccdg: NUS__ Case No.: ME____ SAS No.: ______ SDG «-ia.

Preparation Blank Matrix (§01 I/water): SOIL_

Preparation Blank Concent rat icn Uni ts (ug/L or mg/ kg 't : MG/KG

1 1

; i In i t 1^1J . Citl 13.I J Blank'An&iyre J t^g/D

•i Aluminum .I An c imonv {iAr'^»tniC *i Ban urn J; Barv I i ium •iC*amium t' Calcium •J Chromium !Cocalt i!Copo«r ;I I ron !;L§ad =1 MAor.«»ium .:Manc,angme!:M»rcur*y :JNickgl !. c'a»;a«ium!; Selenium !;S;l\«r !I Sod ium JSThailium Ji Van ad ium JZinc IiCyanid^ !i i

f"

.••

Conti

j.

4.02.0

30 . 02.0

IO.O10.0

2.0

2.02.0

/ ~>0.003 abs

."U

BJC

Uu

uuuu

u

uu'

'.ing CaiibrLank (ug/LI

T1

2. 0

-

'

T fi

'

r-\ >-•.£. * {J

0.003 absCi

^ai

C

U

u

uV

; ion

-

2.0

_._

2.0

—0.003 absvA,

C

U

_.

I 1

"

)

t

* !Prep a- iration 1Blank C! .1

*

0.4 <*' P0.2 " :u; :F

20. 0 JU : JA0 .4 ! U ; I A0.4 ; u ; ; A

20 . C» 1 U i . A1.0 J U ! 5 H4 . .:< : u ; , Ai . -. j ; u ; i A3.0 . U I ! A0.2 J U J : F1.0 : U . J A -1 • O t U i i H

• 1 t' • 1

3.0 ; u ; ; A— Ti ' ! 1 ' ' ij* * V i U t i ri0.2 :u: IF1.0 lUi JA

i oo . o 1 u ; ; AO.I ; Li i . FCO. 3 IB") IF1 .U" iG i • rt

• 1 1 W

i t

Footnotes immediately follow Form 3-F.1 * Solid preparation blanfc of 11/05/88.

FORM HI - IN BR3Q1866

U.S. Er'A - CLP

3- CBLANKS

Lab Name: NUB CORPORATION_________ Contract:

Lao Code: NUS__ _ :. Casa No.: ME____ SAS No.: _____ 3DG No,

Preparation Blank Matr i x (soi 1 /water) : 5OIL__

Prepara-c ion Blank. Concentration Units <ug/L or mg/kgt : MS/KG

I I In i tlal 1 , J ; :Calib. ; Continuing Calibration ! '. Prepa- i

! ,' Blank ; Blank (ug/L) . i J ration !f Ana lyes 1 - -,U,Q / L/ - C, 1 C 2 C 3 C J - Blank C!

I Alum inuin .I An t; imonv !! Arseni-- :! Bar ium 1• Bervl 1 ium i! Cadmium !. C-3 j. ClUrTl

f Chromium I! Cabal t! Copper JI Iron !JLead ;, Magnesium .1 hanoanese !; Mercurv J[Nickel ... J, Potassium :• 5e 1 en i urn !I 5i I vsr ;! Sodium I' T)-.al 1 i'jin ,I vanad i urn i; Z ine ii C yah ida !i ;

1 . i

1 t 1; t i

' ' r i• i i' i i1 1 !t ( 1

! ! i1 1 1i ; it 1 11 1 '• I1 - 11 ' 11 1 1> l ;1 1 11 , I I1 1 11 1 11 1 {' , 1 •1 t 11 1 1

1 ' 1 .1 t 11 : JI 1 11 1 11 1 !

i I il i 't i ii , ' ii i 't i ii i ti i •

_ !0.003.absQ _ !t I i •

;c

Footnote immediately follows Form 3-F.

in --IN/JR30J867

U.S. EPA - CLP

3 - DBLANKS


LAb Code: NUS__ Came Na.: ME____ 5AS No.: ______ SD5 No.

Preparation BIAHK Marrix (soiI/water)i WATER

r-at icn 51 Ank Concentration units %ug/L or mg/kg> : UG/i-_

* . • Calib. , Continuing Calibration! Blank J BlanK (ug/L;;Analyte i iug/D C! l C 2 C 3 C

! Al urn i -urn . 2OO . O I u ; ZOO . <j _ _i UJ Ansimonv '- s*5. i j &*] #7l IB!Ar*»nic J ^rd — "TLJJ 2.O JU! Barium ; 2OO. O I U I 200. 0 i U!B»rylliJun! 4.O : LM 4.0 IUJ Caa m ium : 4.0 I U . 4.0 ! Ui u A 1 c t urn I 200 . 0 JUS 200 .0 I U.'Chromium ; 10-0 !U' IO.O !U! Cobalt : J-0.0 .UJ 40.0 iU' Cooper ; 10.0 ! U J 10. 0 ! U.Iran i 30.0 *«U: 30. 0 !U.'Lead J 2.0 !U! 2.O JUt Magnesium : 10.0 ! U J 10. 0 i U1 rianctan«g i IO.O ! U ! IO.O ! UI Mercury : 0.2 !U! 0.2 !UJiMicKel I 30. 0 !U! 3O.O JU!cQtaisium; 20.0 JU1. 20.0 IU;S»l»nium J 2.0 JU! 2.O IUiSi i ,»r : 10.0 JU! 10.0 JUj Bod ium I 1000.0 IUJ 10OO. 0 ! LJ: "ha 11 ium i 1.0 JU! 1* 0 ! U! Vanad ium ' 2. 0 ! U t 2. O ! U.Zinc J 10.0 rxU! 10.0/rsiUJCsanids : 0.003 abs W ;0.003 aOss

• i > i

20O.O ;Us- 4 . 0 ! U

2 . 0 ; U200. 0 ! U

4.0 !U4.0 !U

200. 0 \ U10.0 !U40.0 :U10.0 SU30 .0 ! U2*0 !U

•io.o ;u10.0 J'U0.2 i'J30.0 ;U20.0 ,U2.0 ;u10.0 . U

1000. 0 ! Ui.o ; u2.0 !U10.0 xr>U

0.003 absvi?;

2O O.O !U4.O JU2.O JU

20 O.O !U4.0 iU4/0 IU

200.0 !U10.0 JU40.0 ;u10.0 ^ JU30 . 0 ! U2.0 I U

1 0 . 0 i U1 0 . O ! U

t30.0 !U20.0 'U2.0 !U

1 0 . 0 ! U1000.0 !U

i . o ; u2.0 !U10.0/-NJU

0.003 abai;

* Prep a- :ration «'B 1 an k C !

zoo . o4.0- ;')

200. 04 . 04.0

200. 01 0 . 040 . 01 0 . 030 . 02 . 0

1 0 . 01 0 . 0*j f 30 . 020 . "jZ. 0

1 0 . < J1OOO. 0

2. 02.0

io.o /- >10.0

l|

u;uuUuuUUUUuuu. J

uuu'Ju

*'

i H

H_

F

; A_! F_

•A";F_

A"»c

Footnotes immediately follow Form 3-F.* Liquid preparation blank of 11/04/88.

FORM III - IN fiR301868

U.S. EPA - CLP

3 - EBLANKS

Name: NUS CORPORATION_________ Contract:

Lac Code: NUS__ .. .Case No.: ME____ SAS No, s _____ 3DG No.

Preparation Blank Matrix isoi1/water;: WATER

Preparation Blank Ccnceneration units tug/L or mg/kg;: L3/ L_

' 1 i

l ! Initial ! .' Cal ic. ; Continuing Cal ib rat ion

: ! Blank i Blank Cug/L); Ar a I y t a i i ug / L ) C i i C 2 . . .C 3 C

f f= Aluminum ! ! I i.Antimonv I ; ; 4.0 I Ui Arsan ic ; • 2. 0 i U! Bar ium I i i !; Berv 1 1 ium : i! ~admium • ! ; !Calcium ! ! 1 200 . 0 i U

; Cnromi-.im ! I ! !! Coc A it • I i ;.Capper ! ! ! ;•Ircn , i '. !' i_ead i i i " 2.0 IU• J*. a. Q n s s i u m ! : ! 1 0 . 0 ! U;viancanese! J J ;Ij^ercurv I i ! !M i — L. a 1 ' I' 'i . M i '_K3 1 i i t i= OSA5SiUi71 J i i , !

' Selenium '. 1 1 2 . 0 I U; SilvS^ ! I J J

! Sodium I ! J I• Thai I ium J I I i . 0 ! Uf Van ad ium 1 J J 2.0 IUi Z i n c 1 I ! ,~\

t i •

4.0 ! U ;1 11 •I

- - . ; :tT

i)!

I

|

1

- t

1

t

11

1

11

;!

._ i.o ;Uts-r*.

JCvanide ! I ! 0.004 absU/ ;0.004 abs Wi • : r 1 1 i

0.004 abs1 *)-

t 1> !

*Prep a- ; ,ration •' !Blank C; J M

• ii •200.0 ;u; i A

a . o i u ; i c2 . o : u ; ; F

2C-J'_' . V ! U/ r i H

4.0 i :j 1 ; -A4 . i. j i • j , i A

200, C I U ! ; A10.0 ! U . - A40 .0 U ! i Ai o . o ; u ; ; A30 . 0 , L •' 'A2.0 iUi !r

i C . 0 ; u ; : Ai (j . c« i u i ;

j . i30.-. 0 ! U ! i A20.0 ;u: i A2 . 0 i U ! I r

io.o i j; ; A1000. 0 1 U J >'A

2.0 -j; ;F2.0 !U ! i"10.0 U : ; A

; ; • ci i i

Footnotes immediately follow Form 3-F.* Liquid preparation blank of 11/05/88.

III - IN AKOUI003 7, £

U.S. EPA - CLP

3 - FBLANKS

Lab Name: NUS CORPORATION_________ Contract!

LAb Code: NUS__ Case No.: ME___ SAS No,: _____ SDG No.:

Preparation Blank Matrix (soil/water)! WATER

Preparation Blank Concentration Units (ug/L or mg/kg>j UG/L

1

it11i

J Analyfce4

i Aluminum^! Antimony{Arsenic ._.„.! Bar turnJ Beryll ium.' Cadmium5 CalciumJ Chromium! Cabal t! CooDer._ ..__._* I ronJLead\ Magnesium! Manganese! Mercury _JNickel! Pot ass iumJSelenium—!Si Iver .........._J Sodium .....[Thallium^I Van ad ium_J Zinc1 Cyanidej

InitialCalib.Blanktug/L) C

—

—

_

II!~"ri

I.t"*iii•

i

Continuing CalibrationBlank (ug/L)

1 C 2 C 3 C

.

0.004 ab i)_

..

_!

-

-

—

«.

Prepa-rationBlank- C M

Footnote inroadiately follows Form 3-F.

FORM I I I - IN n nOniQ-m 7/SflR30

U.S. EPA - CLP

5A " l EPA SAMPLE NO,SPIKE SAMPLE RECOVERY ,—_________

I SED-2Lab Name: NUS CORPORATION________ Contract; ILab Code: NUS case No.: ME__ SAS No.: ____ SDG No.:

Matrix (soil/water): SOIL Level (low/med):

Concentration Units (ug/L or mg/kg dry weight): MS/KG

I1/JAnalyte1| Aluminum| AatimonyI Arsenic/ Barium ._._ _(BerylliumI Cadmiumf Calcium| Chromiumj baltJpper[Iron(Lead[Magnesium[Manganese!/ MercuryI Nickel || Potassium)[Selenium[Silver[Sodium[Thallium1 Vanadium|2inc1 Cyanide1

ControlLimit%R

75- 25

Spiked SampleResult (SSR)

13.000

CSample

Result (SR)

•

0.69

CSpike

Added fSA)

14.6

*R_ ____ —

90.4

Q

_

M

_.

C

romments:

AR30I871FORM V (PART 1) - IN V/87

U\S. EPA - CLP

5A - 2 SPA SAMPLE

1 SEI>-7Lab Names NUS CORPORATION Contract: j

Lab Cod©: NUS Gas* No.: ME SAS No.: SDG Nn. s

Matrix (soil/water) : s011*

Concentration Units (u

1 1 1j I Control [| ' J Limit I Spiked Sample[Analyte | *R f Result (SSR)I 1 i(Aluminum i I1 Antimony 1 [[Arsenic 1 1[ Barium I 1f Beryl Hum 1 ff Cadmium I 1f calcium [ ![Chromium [ j{ bait I IXopper 1 _...!I Iron I r[ Lead [ ff Magnesium 1 |[Manganese j I[Mercury 1 I! Nickel I I[Potassium! [[Selenium | I[silver I 1[Sodium | I[Thallium [ It Vanadium I iI Zinc | I[Cyanide I 75-125 1 12.0000I 1 I

Comments:

Level (lo*

ig/L or mg/kg dry weight) : M3/f

«-

——

~

"

SampleResult (SR)

•

0.67

C

-~

"

I

~si

r/aed) :

CG

SpikeAdded (SA)

14.0

%R

.

85.7

Q

__

~*

"

—

1I1

M |11I1111

*1111I11Ii111|

c 11

1

t

flR30!872FORM V (PART 1) - IN V/B7

U.S. EPA - CLP

5A - 3 EPA SAMPLE NO.SPIKE SAMPLE RECOVERY __

SED-9Lab Name: NUS CORPORATION_________ . Contract:

Lao Code: NUS___ Case No.: fl£___ SAS No.: _____ £DG No.:

Matrix (soiI/water)J SOIL_ - Level Clow/med):

Cancan t rat ion Un i ts fug/L or mg/kg dry weight) : r[G/K3

I ! Control I : _ _ _ . . ;, Limit I Soiled Same la ! Sample ! Spike

iAnalyte ' "IR • Resu.lt _(33R) C! Result (SR) C! Added <SA)

, A luminurr,• Ant imon /! Arsen ic• Bar" 1 '_iiTl' Ee^y 1 1 1 Lifn: Cadmium' Calc ium[ wl~* c*'3m i i_ii7i' —! L.oba* t! Cc^oeri Iron'-sadI MagnesiumriAfioane-sa

i nerrurv, rJicKel — .; Potassium• Selenium! 5i Iver; Soa iuml Thai 1 ium: Vanadium• Zinc• Cyan ise1

r

; 75- 125 ;175-125 I: •TlSr_ « -if

175-125 ;- "— er _ i "T=" '

i

; 75-125 :; 75-125. !' 75-125 !! :

- i!:; Ji75 125 ' .1 ' :~J —— J. *L. ._) 1

i <

.'75-125 i; 75-125 ;! ;' Tf _ i -?c" '

175-125 !175-125 1i ri 1l Ii l

12. 40C14. 100596. JO7:. 100O6. 3000

- 35. 9OO_--- 307. 00

^ 1 . Pfi(";

37. 100

5260. O1 . 900C131 . 00

1 . 20OO1 . 3 OOO

6. 00006 1 . OOO203. OO

. •; . 1 „ 700Oi i 9.3000, ! 174.0C1- ' 2.OOOO^ O.5400

j 1i i *""16. 200; i 28.400; ; 37. OOOi ji - i 35.200i ri •

! i 660.00J I 0. 1300i ! 95.900-I ;.' I 0 . 27OOJ : l . 3000i i! ! 0. 4300! ! ' 51.200i ! S3. 7001 ii

jB: 13.

; 5.i 266.

6.L: o.

1

; 26.1 6a.i 3~ .;I 2.I! 66.

u; 2.• 66.

1U! 1-u; 6.

I1

B: 6.13,66.

11

1

-f-0T

7

65T;

6

305

-r

6

D25

i <i iso. s ; iQ _ Q A ; |

CpsT?'7 1 N ;<74 6 ,; N '94,0 i !

i t(r^r ; in \^ 5 : N ;i 34. 5 .' Pi l~ ~7 , ;

'>--j ; V-s——^ 1 __ J I1 — < — -p's iVy^

^ SUC ! ^ 2 5 : N ;

,' ,

-5 3 ; :CT TZ N;

M^ /- * '

i 74-"r" : N ;179. 4 N i^ —— \ \

t i

NRFFAAANRAy*1-1

ANR?s.**\ANR£T

A

NRFFA

:;R . Q , r-;

flR30!873rART 1> - IN

U.S. EPA - CLP

5A - 4 EPA SAMPLE ™SPIKE SAMPLE RECOVERY ____________

| SW-7Lab Name: NUS CORPORATION ___ Contract: I

Lab Code: Mas case No.: ME__ SAS No.: _____ SDG No.:

Matrix (soil/water): WATER Level (low/med):

Concentration Units (ug/£» or mg/kg dry weight) :

f I I| | Control [j | Limit 1 Spiked Sample[Analyte | %R ( Result (SSR)I I II Aluminum | II Antimony i [I Arsenic | 11 Barium J 1f Beryllium | I1 cadmium I I[Calcium I j1 chromium 1 1! >alt 1 I

1 copper _ I ..f_1 Iron I I[ Lead | 1IMagnesiumj jf Manganese! jI Mercury j I1 Nickel 1 ](Potassium! 1(Selenium j [[Silver 1 Ij Sodium I 1(Thallium [ II Vanadium I 1|2inc | |I cyanide [ 75-125 I 240. oooI i I

cSample

Result (SR).

10.0000

c

lu_

SpikeAdded (SA)

250.0

111*R |Q

1!111111I111111111111I11

96.0 _ _ ! _ .!

M

Ic 11

Comments:

flR30!87UFORM V (PART 1) - IN V/87

U.S. EPA - CLP

5A- 5 ERA SAMPLE NO.5FIKE SAMPLE RECOVER'/

i_aD Name:

LaD Cods:

Matrix \'so

: Analy te

; Aluminumi An t i mcny1 Arsen ic; Bar ium• Beryl 1 ium! Cadmiuml Calcium _1 Chromium"Cobalt! Cocoeri I ronJuead• Magnesium

•' fy' 1 C :-. e i! Potass ium'< Selan i -.m

"I 5 l i -v e r

NUS CORPORATION

(NiL'S

1 1/' water/ :

Cancan tr

i iJ Control !i Limit !

!75 1^5 •i 75- 125 ;; 75- 1 25 ;; 75-125 ,• Ter_ 1 ^er i' / — ' 1 A. -~J •; 75-125 !t •i i175-125 :i /*_•— l*i >j I175-125 I: 75. 125 ;i / >— — X +- _l J

'

• - i

i

' 75-125 i!

• /-/"• i -i >j -T g __ -t -i =: i

Case No. : riE

WATER

a t i on units ( UQ / L

Spiked Sample JResult (3SR) Ci

2010.0 ; ;" " 103. 50 ,' !

34 . 600' ! !2330. 0 . i I37.000 , '4o. 000 i !

i j' 160. 00 1500.00 ! !243.00 ; !2o6O . 0 I I1 i . 3OC" ; i

; ;39 GO. 0 . :3. BO 00 i :490.00 1 !

i ;3.5000 1 !

10. OOOO I i

Contract:

3A5 No. :

Level

or mg/kg dry weight;:

Samp 1 eReaul t v 5R) C

200. 004. OOOO2. OOOO450. 004 . OOOO4. OOOO

i v. OOOO40. OOO "23. 0001^1 O . 0. (")(";("; n

."O, .'>0. 2000200 . 00

2. OOO'O10. OOOO

! Sod ium ! 1 ; :! Tnal I ium: Van ad i i_;m.'lineJ Cyan i 3=

175-125 i175-125 J175-125 !i i• <

44. 100 J .'ill. oo ; i510. 00 1 !

I I

2. OOOO• o. 100050. 000

i i i i i• ' i 1 1

UUuuu

uB

s

U

U

uB

Sp IKAaaed

20 OO1 OO40

20005050

200500er,'i«i.-jU

1 1~> '"><'i

20

J SW-Srt

5DG No. ;

C low/med / :

UG,- L_

(5A> i :;R

.0 ; 100.5

. o ; 103. 5

.0 ! 86.5

. '-'. ; 9a s, — . — XT>-. u ! \L**Jf}'J 92, O*

.0 : 75. 0

.0 11 0 0 . 0

. 0 ! ~0. j

.0 , 75.0. o ! < rrs*

1

! u i t"» •

: ; AI I Fi IFi . f-i

h i N I A ,! ' A: i NR,' r~

t i rrt •*

' t f-*

• r-j . ;~1 v —— """ : I Mr

500n

50 C

. G i 1 1 -1 . 0

. o ; 95 . o

.O ; V55.0

A ,1 •— V t

1 ; N : A; ^ "" ; . NP .

1050

. 0 i 55^£>. o .* <TO.O f '. '-"** ~ « "/i N ! H r

'"rr .

50100500

.0 ; 38.2

. 0 I 104. 9

. 0 1 92.0

; ' F :I F

i i i~i *> i r

t 1 1 .

Commen ts:

S3QI875

U.5. EPA - CLF

5A EPA SAMPLE NO.SPIKE SAMPLE RECOVERY __________

isw-a

L&D N«m«i NUS CORPORATION_________ Contract:

Coaet NUS—— C*«e No.: ME___ SAS No.: ______ SDG No.: Sw-12

Matrix i»oil/water)i WATER Lsvel Clow/med;:

Concentration Units *ug/L or mg/kg dry weight): UG/L

Comments:

! 1 ControlJ : LimitJAnalytg I XRi •).'Aluminum _ _ _ _ _ ...' Ant imonv : 75-125i Arsenic .' 75- 125I Barium i . 5-12sJBary 11 ium 175-125> Cadmium _ . 75-125I Calcium !' Chramium— i 75-125ICooalt 175-125! Cooper '75-125I Iron _. I' ( H» s v4 ""•&• — ' ~*eri L. Si-la t , _j— i ij

iM*&ne*ium!! Miin5ftn«» .: Pteccurv I . .. NxcKel ,. ,.. 75-125,J Fot*»«ium J; Be i©niuffl_ 175-125iC- T e»k- ~*s:_ 1 ~>^i5=li*ef i , 3— i ,j! Sad ium I[Thallium J 75- 125: V/*n*dium • 75-125; Zinc 175-125: Cvanid^ !• ii t

Spiked SampleResult tSSR) C

2400.0 i95. 600 I39. 100 !26oo.o ;42.000 !55.000 ;

ii150. 00 !490.00 !239,00 !2410.0 !

__16.5OG !ii

3900 . 0 !4. 1OOO51O.OO !

riS . 7OOO J10. OOOO !

ii40.6OO I112.10 :4SO . oo :•t

!

Samp leResult (SR)

200. 004. OOOO2. OOOO600. 004. OOOO4. OOOO

10. OOOO40. 00010. OOOOi ~\ i o nllm> A •— ' A •.' . V

2. OOOO

3400.O0. 200070, OOO

"*2. OOOO40 ."OOO

2. OOOO2, 9000•30.OOO

•

C

uuuuuuBU

i •w

1 IL/

U

uB

So i keAdded (5A)

"2000. 0100, 040. 0

2000. 050 . 050. 0

2OO . 0500 . 0250.01000.020.0

~5C-0. 04. 0

"500.0

10.050 . 0

50.01 00 . 0500 . 0

• i"/.R ; c : M .

120,0 , ;A •'95.6 ; IF ;97 71 ' F100. 0 I i A34.0 ; !A .110.0 ! IA

: j NR :75. O I !A .90.0 ! ! A?S.O , jj

110. 0 ^&,84. 5 • :-

: INF10O. 0 . .A102.5 t :CV5S . 0 • ; A .

! , NF, ;87. O ; IF '0 i M ! A .

; ,%F .81.2 I . F ,

109.2 ; ;F90.o ; , A ;

1 , NR :i

:ORM '. .FART i; - IN :

flR301876

U.S. EPA - CLP

5A - 6 EPA SAHPLE NO,

J SW-16Lab Name: NUS CORPORATION Contract: fLab Code: MS - Case No. : ME SAS No. : SDG NO. :Matrix (soil/water) : WATER

Concentration Units (ug/L or mg/kg dry w

1

1JAnalyte

| Aluminumj Antimony^(Arsenic ~"f Barium'BerylliumCadmiumCalciumChromium^&*balt ""BpperTronLeadMagnesium!Manganese |MercuryNickel |Potassium fSelenium j

ControlLimit*R

SilverSodium |ThalllumJVanadium""]Zinc ICyanide | 75-125

1

Spiked SampleResult (SSR)

250.000

omments :

C

~_~

~~

~

SampleResult (SR)

10.0000

c~

~~

~

"

~s.

Level (lo*

eight) : O3/t

f/ned) :

SpikeAdded (SA)

..

250.0

%R

100.0

Q

——

——

——

——

"

M

i n

C

'

3R3Q/877FORM V (PART 1) - IM V/87

U.S. EPA - CLP

SB ErA SAMPLE NO.POST DIGEST SPIKE SAMPLE RECOVERY ______

3ED-10Lao Names NUS CORPORATION_________ Contract:

*_*0 Code: NUS___ Came No. : ME___ SAS No. s " 3DG Mo. 2

Matrix \soi l/w*t«r > s SOIL_ Level C low/med)

Concsntrat ion LJn i ta: UQ/L

1 '• Control i! L.imi t ; So it= ed 3 amp I«s

Anaiy ts • "in 1 R»»ul t <5SR)> i i -! Aluminum • Jt Ant i nor. / - T 115,10; Arsenic i I 24. 100f car1* i urn ' ti E»rv 1 I ium ! 'I ladmiuin< C s 1 c i urn {* CnrctTi ium i I:CoDalt : ::Ccoo«r i !; Iron ! ;_smo : ! 63. 400!nacn»«iumJ i^arQ^.ng^^ ! !

. Mgrcurv i J1 N i c \ g 1 J !i Potasi ium ' ;:5*l*nium * " 9.8000. sliver .: Ji BoGium t tiTr.allium : I 21.600.'VanadiUtTi J ! 136.80i - i r,— i "i — i n— i >'Cvanice ' I

i i

CSamp le

R*sul t C5R>•r

4 . OOOO4 . 9000

42.400

2. OOOO

1 . 200042 . 000

C

uB

U

BB

• 1 1

Spike . ; - : :Added (3A> I T1R : Q r

i • •> i i___. .. i t ii -120.0 ! =?a. 4 i IF20.0 ; 96.0 I ;F

i • >i i rt t i1 *,'.—.

: M; ;

' i ii

; ; *" "0.0 « 105.0 : ! F

i r i( 1

- I '1 11 * •1 1 1

' I

10. o ; 9s.o i . r• 1 I1 I 1! : .

20. o i 102. C1 ; ; t-100. 0 ! 94. 3 ! : F

i i i( 1 11 1 111 '

;;fl-R30!878

U.S. EPA - CLP

5B ERA SAMPLE NO.POST DIGEST SPIKE SAMPLE RECOVERY

SED-liLab Name: NUS CORPORATION_________ Contract:

Lao Code: NUS__ Case No.: ME___ SAS No.: _____ SuG No.:

Matrix isoiI/water) : SOIL_ Level (low/med):

Concentration Units: ua/L

.' Control ; !! ! Limir ! Spiked S-arnpIe .!.... . _.3amp 1 a; Analy te : /;R i "Rssul t- <35F\; _ C I Resul t v

Comments;

: Aluminum ! ;\ An t imcny ! ! 119, 50I *-if*'Ssn 1C: i 70. 200.'Ear iumJ 5erv 1 1 ium I . !; Cacmium ; iiLCalcium i !fc-w . " iv_ n .*"* o m i LI m i iJCooalt ! i . _ . . _ . . - .:Ccoper i j! I ron ! (i Lsad ! : 536. 00IMaonesium! Ii Manoanese 1 •! Mercurv ; !INiCr-el :!Pota=sium! ;! i e i en i urn i i 1 0 . 700! Silver !! 3cd ium : !; Tha 11 ium ! • 21.500(Vanadium 1 J 363.30IZinc f !1C van ids ! !i r i

•i

; 4. oooo; 33.8001 - - -

1

1

;iii

.'

!370. 00

Iiii

rii

! 2. OOOOjr

! 2 . 7000i 134. 00;;i

U

u

B

j120-O i 99,640. 0 ! 91.0

j«t•r

i

i

l

20,0 ! iJ9.0t<,ii

10.0 : 107.0!,

20.0 I 94.0200.0 ! 114.9

;iii

SpikeAdded (SA)I

,!F_;F~

;F .

rCRM V 7 Q/ 3

U.S. EPA - CLP

SB EPA SAMPLE NO.POST DIGEST SPIKE SAMPLE RECOVERY

E 3ED-12Lao Names NUS CORPORATION_________ Contract: J

Lao Cod-ts NUS___ Came No.: ME____ SAS No. s ______ 5DG No.:

Matrix tsoi1/water): SOIi__ Level C low/med) :

Concentration units: uo/L

I Control I

Commontss

i i uimifc : =>oik»d Sample ! Sample1 An & 1 y r a I *%P t n,¥su It ( SSR ) C i Resu 1 1 < SR t C

* Aluminum : I!Ar. timanv I : 114.70i Ar'Mn l c ! : 40 . 400

i 1

f ; 4.0000J I 22.300

:B*r*ium : : ii 5»rvl 1 iunr. I• Cadmium . !ICalcium ' i! Chromium ! - i.Cobalt ' !tCcoovr ! !. I ran : .'. L.SHG I • 162.40IMaanMium! J^ancaneMl !

iMercurv ! :. N i c * • I \ :i^otammium! J^ Selenium • ; 10,200

> tI 1t 1r ;1 11 i

1 •I

' 11 1

i I 124.40i it •i i

< i

t ii ii i

1 ! 2. OOOOJ Silver ! ! ! ;, Sod ium : I ; i.' Th a 1 1 i urn i i 22 . 2OO! Vanadium ! I 194.60IZinc S J

: J i. 1000___ I _ i ____ 98 . 400 ___

•Cv«nia» ! E * Jt i r r

U

—

u

B

_

So i keAdded (3A)

120.0"20 . 0

-

40.0

1 0 . 0

20 . 0___ 100.0 __

• ii i71R I Q i 1

r i

75.6 : ;F90.5 ; IF

1

1 11 11 1

.1 1

; ,!

75-O !!1 •;• ti i

102. U| !

i i•i i-, c- i i "1 (.- -J . -_» I 1

9 o . 2 : ; Fi ;I ;;

flR301880(PAR T 2; " — IN

U.S. EPA - CLP

38 EPA SAMPLE NO.POST DIGEST SPIKE SAMPLE RECOVERY ________

3ED-13LaD Name: NUS CORPORATION_________ Contract:

Code: NUS__ Case No.: ME___; SAS No.: _____ SDG No.:

Matrix (soil/water): 3011__ • • - Level <low/med):

Concentration Units; ug/L

I !Control!i v _ L < n i t ; S^ikeid Sample : . Sample

:An aIvt e ; \R ! Re Su11 (SSR) C i Re su11 (5R >

Comments:

I Aluminum I !An 1 1 mo r. y . 1 1 S . 40! Arsen i c f 33 . 600' Barium « .! Beryl 1 ium i :i Cadmium ! :! Calcium ! ij Chromium . ;.Cobalt S iI Cooper i J.'Iron ' !' Lea.d ; ! 97. 750. Maanesium i !. Manaanese ;i Mercury : !^Nickel • !I Potassium ! ;i Se 1 en i u m ; ! i 0 . 20OI =• i 1 v e r !; So a ium i ;! Tha 11 ium ! I 20.900{Vanadium i i 128.3O: Zinc J !; C^-ar, ide I • I> ; i« t i

.

« 4 , 0000! 14.5OOj;ti'

JiiJ

!I 73.250:I -|;!i 2.0000i1

I 1 . OOOOi • 40.8001!;

U

u

uB

( ri >

120.0 ! 9S.7 i .F20.0 ! 94.0 i IF

i > tt i •t i •i i ii > *• i i

i •i i

t ii i i• i

25.0 i =5 -0 i .*-! ; .. * *i : t

i i

! • :i i •

10. 0 ! 1C 2. 0 - • F: i i1 • '

20.0 ! 104.5 I Ir100.0 ! S7.5 . :F

t 11 1

i ; i

i i

Spike ! i :Added (3A) ! '/.R IQ , :<

i r t f i ; —

U.S. EPA - CLP

SB EFA SAMPLE NC.POST DIGEST SPIKE SAMPLE RECOVERY

L.ab Name:

Lab Code;

SED-I4NUS CORPORATION Contract:

NUS Case No.: ME SAS J^4o. : ' 3DG No. s

Matri x <&oi I/ water) t 3QIL__

Concen rrnt ion Un i ts: ug/L

ii

. Aluminum

Level C low/med ': :

• » . -.1 i -1 1 1 1 1 i !

I L.imi t ' 5a iked Samp 1st '> Sarnp la i So iKe . i! XR J r;e BU 1 1 < SSR ) C i Resu It < 5R . C i Ad ded v 5 A / ! */.R 1 Z \ ^ -

l • ~ "^ • . ~ 1 ! i' i l . :

; ; i ;I An * i »Tion y ' ' ~116. 41.'; Arftn ir ! . ___- 45- TOOi Barium . . ._i S«ry 1 1 iumi «_ »GiTJ 1 UfTl

. ' Calciumt —

t 11 1

t «1t) ,

:Cooalt ; . :;Ccco£r- - *1 I ranL M &*a

i Mercury _1 . ___ M !

t

J .' 146.00: • = -:

i•, ;

:Fot**»ium" 1s 3^1 en ium'SilverScaium. Thai 1 ium•Vanadiumi 2inc

1 I 10. 20Oi > . . .i _ _ » ........• t• *

t 21.600i ! 16S.SOi »

:C^*nia» ! !i t

! 4. OOOO! 26.600,1!iiiiitt[ * ;"}— Tt'i;J;j•! 2. OOOO;1! 1 . OOOO! 70. 100;•;

• i i i iUi 120.0 i 97.0 ! IF •

:• 20.0 I 110.5 1 Iri 1 1 ,. " i it i i

I i t '

.• ii i •

i •i i t -! t - .I I - I

i " 40. 0 ! 102 .O " ri i . •\ i i i} i i! ; - - ii 'i i •i ' * . '

UI 10.0 1 K.-2.O ! Iri 1 i Jt i t i •• ' ' , '

Us 20.0 : 103,0 ; !*=" ii ioo.o i 9S.7 :__: F . /• * ' 't t 1 !

t 1 '1 1 i |

i 1 1 i1 1 I I I

Hommen t B ;

flR30i882ART 2; - IN

U.S. EPA - CLP

5B EPA SAMPLE NO.POST DIGEST SPIKE SAMPLE RECOVERY

! SED-15Lab Name: NUS CORPORATION_________ Contract: ____

Lao Code: NUS__ Case No.: ME___ SAS No.: _____ SDG No.: SED-iO

Matrix \ soii/water): SOIL_ Level <low/med.:

Concentration Units; ug/L

: ; Control ;1 ; L. i m 1 1 i Sp i K ed 3amp I a: nnal v te i !*R ! Resul t C 33R'J

.' AI um in urn '. ~ ~ ' \I An 1 1 mon v : , 119. 50: Arsenic ,' ! 45. 1001 E-ar^ ium ,; ~ , " "I Bervl 1 ium • ;' Cacmium I !1 Calcium ! !> Chromium . !Cobalt ; :ICcooer : ,! I ron 1 !! L_ead I ! 554. 00! MaGnesium ; '; rianoansse ; !i Mercury ;N i c K a i ' - I

; r-Dt assiurr. I•Selenium , : 10. 10O; 5i 1 <*&r ! J1 3 co i urn ; ji Tha 1 1 i um { 19. 600: Van ad l um ! ; 1 48. SOI T , — — I 1i 1. 1 n L- t iI C *an ids I !« i ii i

rl

; Samp leC ! Resul t iSR)

:

i 4. OOOO! 24.500iit',<•i;ii<! -3-73.001iitii•1 2. OOOOiiii! i . OOOOI • 54.300i• . . . .r

:

fUi

U

U

u

5p i keAdaec <3A)

120,020 . 0

200.0

1 0 . 0

20 . 01 00 . 0

.

y.p

99.6103.0

1 05 • 0

101. 0

96.0"4. 5

Comments:

! F

•F

;F

3R30I883FORM V (FART I;-- IN

U.S. EPA - CLP


SED-1Lab Nam©: NUS CORPORATION_________ Contract:

Lab Codes NUS__ Case No.: ME___ SAS No.: _____ 3DG No.:

Matrix tsoi1/watar) i SDIL_ , Level (low/med):

Concentration Units: UQ/L.

J

t

Aluminum• Ant imar.y) Arsenic' & Atrium: Ee^v 1 1 ium' Caa.r iamCalcium ...... Chromium; Cooal t!Copoers Iron.LeaciM«gn»»ium: Manganese1 Mercury!Nick»l! Potasnum! S@ 1 sn i um1 Si 1 v»r! Scd ium, Thai 1 turn; v«n*.d ium; Zincj w /anid*,

itControl i ' -Limit ! Hoiked Samp leXR J Fcesult (SSR) C

; ji 120. 2G i! -- 84.20O 1; ,I j; ;j ;i r; [: . j, ;1 2 24. 0 '.1 11 11 . 11 I; - ij ;\ \1 — . 8.SOOO; j;J 21.200 ;J 308 . 00 !1it :

Samp leR'e»ul t (SR)

S. 7vOO4 . 5000

1792.0

2. OOOO

, 1 . OOOO112.60

C

BB

U

U

iSpike

Added C3A.

120. 040 . 0

-300. 0

10.0_

20 . c2O 0.0

:_R . c ; M .I * i

92.9 , ,F93.0 : :F .

i •i : ;i i

.: :i ii •i • i

10*. 0 ; i r :t; i, ! ;

i i

i i i

a 5. 0 ! :•- :• !: :

106.0 : IF ;97.7 . :F

1 I

; i :1

'CRf! V v = ABT 2) - IN

U.S. EPA - CLP


Lab Name: NUS CORPORATION Contract:

i_ab Code: NCS Case No. : ME SAS No. :

Matrix '.soil/water): SOIL


: Control 1 ;i .' Liiiii t ; So iked 3amo Is i Sample! Analy te ! TiR I Resul t ( 33R) C ! -Resul t C5R)

• Aluminum * i !'Anti.-nonv ; J 122.10 . i 4.500O.Arsenic f i 77. 4OO J «' 39.300; Barium ; • ! '! Beryl 1 ium J .' ! I; Cadmium : I i 1- Calcium ! ! '. i ' ' ' '', Chromium f ! • I !J Cobalt ' ! ! !. Copper 1 ; ! !-Iron I ! ! !! Lead ; i 1000.0 • .: i 1475.0; Mac ns s ium i I ! J! ttanaanesei - - - - - ; - I ;! Mercurv ! i ! !.Nickel ! . i ! J

! r-ctassium ' I i !J Selenium J 1 10.200 ! ! - -3.0000{Silver ! ! ! '1 Sod i -tm ! ! 1I Tha 1 1 1 um I ! 21. 3OO J ! 1 . OOOO; Vanadium I J 286.20 i ! • 101.301 Z i n c ! ! ! i; Ivan :de i i 1 ;1 I I ! l

I t I t

Co rumen ts :

SED-2

5DG No. :

Level ( low/med ) :

! So ike - : :Ci Added (5A) ! "1R ; Q '< M.

! ! I I

r i i i

B! 120.0 ! 93. O ! IF .i 40.0 1 94. C i IFI ! ' • !

! ' !I ; ; ;; ; i ii i • „ ' , , „ ,• ' ' , •t i • •i i < •I oOO."0 • 1C 5. 0 ! r1 ( I I -1 i 1 , '

1 1 * 1

1 I '

: •'I ! ^— ~^\ '

BJ 10.0 ! ( 2.0 >' . F! ! ^ ——— \ •: . ; ;

B! 20.0 ! 101.5 J ' F •J 200. 0 .' 92. 2 i i r !i ' ' : '

! '• ' '

! : ; ; ;

_.„ ... :VflR30!885<. - Hr, i -i ; - -— i M

U.S. EPA - CLP

5B EPA 3AMFi_E Ntj?POST DIGEST SPIKE SAMPLE RECOVERY

! SED-3L&b Namtss NUS CORPORATION_________ Contract: _______

Lab Coda: NUS__ Case No.: ME___ SAS No.: _____ SDG No.:

Matrix (soi1/MAtor)s SOIL_ Level Clow/med):

Concentration Units: uo/L

11(: Analyte<i Aluminum! Ant imonywJ Arsenic. Bar* ium! Beryl 1 iumJ Cadmium: Calc ium! Chromium1 Canal t: Coooer; 1 ran'Lead1 MagnesiumJ ManganeseJ Mercurv: MicKttl! Potassium!S*Z«n lufli!Silv«^, Sod ium! Thai 1 ium! Vanaa iumJZxnci Cyan icmI

i iControl !Lifni s J Sp iked Samp im•;R f Result i33R. C

»1[ _ . . _ . ,

! —— 12v.SOI 70.600 i1 t1 1

1 1

» • 1

I 1• 1f 1t It 1f •1 11 1

! 34OO.O1 1t 1

1 1t I1 tI It 1I " fI >

. _ _ _ _ I 9.8000 it i* i* ii i! 19.900 \i 185.10 Ii *i iI :J l

Samp laResult (SR)

1 0. 000030. 300

2450.0

-

2. OOOO

1 . OOOO92,300

C

B

U

U

5p ikeAdoed <5A.

120. 040 . 0

--

1000. 0

1 0 . 0

20 . O100. 0

1

1 1

:;R , Q . tj j

92.1 : IF99-5 ' :r

i ii •i i• ir' '.iH, ,

T 5 . o ; >ii ii i

;i

95. 0 ! :ri i; ;

99,5 I ;r9Zi S . ' F

i i

i

nflR30I886

U.S. EPA - CLP


3ED-4Lab Name: NUS CORPORATION_________ Contract: ____ J

Lab Code: NUS___ Ca.se No.: ME___ SAS No.: ______ SDG No.:

Matrix (soil/water): SOIL_ = , Level (low/med):

Concentration Units: uo/L

i-ommen ts i

• .' Control i t.: ; Ln.it • Soiled Samoie 1 ._ 5-amp 1 ainnaiyte i "iR .! Result (SSR) C! Result C3R)i - i' i ' 1

; Aluminum J ! : ;; Ant imcnv : : 124. £0 , ; 4. OOOOArsenic i ! 72. 600 \ \ 37. 400Barium ; : i •

i Bsrv 1 1 ium • '. ; ,: Cadmium I 1 ,iCaiciuiT. ; i ! ;•Chromium ; [ iJcoDal t ! . ! ;Coocer ; ! I I: Iran ! I J !-sad i ! - oO6 . 00 ; i 392 . 00

. acnesium i : ; jXanqanesa '• : • : i:Mercurv ! j \ \Nickel J 1 - = , ••Potassium! ! J J3e 1 en i '_;,-n ; ! 10. 200 i ! 2 . 3000.3: Iver ; ! | ;Bod ium ; ! ; !

• Thai 1 ium ; I 18. 900 ! I 2. 100O.Vanadium : ! 187.60 ; ! 84.1001 Z me ! ! j !.C^aniae I ! . 1t < . . .

: i i t

c

u

g

B

So i keAdaeci (3A)

120. 040' . 0

200. 0

10.0

20 . 01 00 . 0

•'In : CC 7

i ti r

103.7 : ;FS3.0 I IF

r t

l

> ii ••• ti t; ;j; •i .

107. 0 1 : Fi i; 'i •* ;

y — —. .' ;79. -.:O W.F^——— </ \ ;s —— -^ : '^84 . O) 1 yJ ! ="103. 5 i . F

E t> Ii ,

flR30I887ruRM V -'PART 2-) - IN

U.S. EPA - CLP

SB EPA SAMPLE NO."POST DIGEST SPIKE SAMPLE RECOVERY _________

5ED-5Lab Namas NUS CORPORATION_________ Contract:

Lao Coci?: NUS___ Cas^ No.: ME____ SAS No.: ______ 3DG r4o. :

Matrix (sot l/waser) s 3QIL— Level

Concentrat ion Un its: ug/L

, Control• L- i m 1 1

AnalytSample ' Sample ; Spike I'iSSR) C ! Result CSR) C ; Added <SA) ! /.R ! Q; M

; Aluminum, An t imcr.yI Arsenic• Bar TurnI Beryl 1 iumi Cacmium1 talcxumChromiumSCobalt: Coooer! IronLeadJMaonemium, Manoans^g; f^rcurv>J 1 C '< © 1

I Po~ass ium" z& l«n iu mI 5i Is »r: ice i um."nail ium; Vanftdium; 2 ineI Cvan i cm.

- 119.7040.500

_..

o74. OO

_ 9.9OOO

19.200141. 4O

i i ii ~ " i1 4.0000 ;U! 120.0 i 99.7! 21.900 ! ! 20.0 ! 93.0i • » i1 ! 1

1 | 1' --.- -.-._ ...... t ' - - I ...

i i ' '1 t 1 i• I t !1 I I 11 ! 1 t1 1 1 :t 1 1 ii i l ll 1 JI i i ii 1 1 )i i i '

i 462 . 00 I I 200. 0 ! 10*. 01 ! ! i1 I I :i i t '> i i *i i t i• 1 *' l l

i i ii i i ' i

i 2. oooo ;u; io.o ; 99.0• i t i• ! • i! ! ! :! 1 . 6000 IB! 20 . 0 i 83 . 0! 37 . 9OO ! B ! 1 UO .0 , 1 03 . i i i 'l ~ 1 « ii t <l . i ...

i i i •i t ( •

Comm^ntm:

. r

;F

flR301888V (PART 2> - IN4

U.S. EPA - CLP


SED-6Lab Name: NUS CORPORATION Contract:

wao Code: NUS Case No,: ME SAS No.: SDG No.: 3ED-

Matrix (soi 1 /water) : SOIL Level (low/med; :

10

Concent rar ion Un i ts: UQ/L

• i i

; I Control fi ! Limit t Spiked SampleiAnalyte ! 7.R ! Resul t'" <53R) C

i Alum in urn ! i :.Antimony J 1 119.30 ;iArsanic J \ 3c. 100; Barium ! ; ;i Berv 1 1 ium i ! !'• Cadmi um ; ; - - - :tCalc ium • I I1-^ •_. n /" o m i u m i i ;i Cobalt ! ! !Cob" o'er - • - ; • ' . '

. Iron ! ! I• Le^ci '• i 16 6.' JO ! -- Maonesium 1 . !• Marqanese-i ! ;! nercurv ! ; . I• Nickel : 1 '.l Potassium I ! i: Selenium ; J 9,3000 !i 5i Iver ! I !. Sod ium I !! Thallium ! ! 19.600; Vanad i u/n i ! 1 76 . 50 !1 Zinc !: Cv -. n ide i !> ' i ii i i

i i r i_ .._ _ _T :.._ _ ; ; ! :Sample i Spike ; ; ,

Result (SR) C! Added C3A)! T.R ! 0 J: : i •i i i

i ; i • >' i i > i

4 . 4 OOO ! B i 1 20 . 0 ! 96.2;:IB. OOO ! ! 20. 0 «' 9O.5 ! i

r;

FF

_-.: — : . : ; ; J ; Jt i r i ii i l i iI I 1 1 iI I 1 > 1

- 1 1 1 tI I 1 ' 1

1 ! • 't 1 : I t

—— .

i : i )1 1 ' ' , 'i i J ' : rr i i ' iI i t ; i '

121.60 : i 40.0 ; 111. 0 . :r- l : ( i i i

1 1 I !

i i ' t—— ',

- - - - - 4 f I I

I I 1 . 1 •I I 1 1 1 •

2.0000 JUI 10.0 ! 93.0 : •i t i " i !

;Cr— '

I I i 1 '

. 1 . 5000 J B i 20 . 0 ! 90 . 5 i J73. 10O ! i 100,0 I 9S.4 , :

F .F *

i t < ' ii i i t i

i i ' ' t

•

i

Comments:

AR30I889QFM V '.PART "2) - IN

U.S. EPA - CLP

SB EPA SAMPLE NO.POST DIGEST 3PIKE SAMPLE RECOVERY

SED-7Uab Name: NUS CORPORATION_________ Contract:

Lao Codes NUS__ C^-mm No.: ME___ SA3 No.: _____ 5DG No.:

Matrix (moil/water)s 5DXL_ Level (low/med;!

Cc-ncen trat ion Un i fcs: UQ /L

' Control - - ;J L. i nit - 33 x* ad Samola • Sample

yt* I ^ t P.*»ult ,SSR) C! Result C5R) C

.Alt.min^.-n * t '• An timer, • ~- « ~ 12S. lO . ; -.'I-OOOIArg©ni- : 112.50 ; 1 67,000: Barium J I . ;. Barylliumt I ! 1; Cadmium . : : !iCalcium . • _ . _ . . . . • ,Chi-* G mi urn ; . ' . jiCooalt ; ; !"*anr* . u p - 1 ' '

i T *.,-,,-, ; < J ii z r o n i i i tI -..sad i i ^2 / . •.?'.• . : Z-4.b, 00I Maonesium ! I 1 !M*ncan«««. : j ;.lercurx ! . _.-. .. ! !Nic>-:«l ! ; i.Potaimium. . ! . j i -H«l*-niuin . . .- 9.3OOO ' ! 2."0000

1 5iiv»»* ; i ; iBoa ium I i • 1

« Tn*i 1 ium ! I . 20. 200 . ! 1 . 2000'.Vanadium ! I 302*60 ! ! 109.40: Z i n r ! ! ; 'i <L* v :? l~ 1 0 ^ i i - ri » i i t

U

u

B

1 11 ( '

120. o i 106. 7 ; : F50.0 ! 91 .O i IF

f • 11 • 11 1 '1 1 1

i i jdi i mL - t

1 1 'ti i :

100. o ; 111.0 '•• . F\ J

i ;r i ti • !

J '1 I i

liJ.O . 93.-,) : .r1 ' '1 • 1

I 11 I 120.0 i 95 . o : ; -200.0 . 96.6 ; F

1 1 '( I •

i ' :t 1 •

.aded (3A» I

ess

SR3018V spART 2-' - IN

U.S. EPA - CLP


5ED-3Lao Name: NUS CORPORATION_________ Contract: ____ !

Lao Cede: NUS__ Case No. : ME____ £AS No, i _____ SDG N'o. :

Matrix (sai 1/wafer) z 3GIL__ Level (low/med):

Cor. can tr at ion Un its: ug/L

i • . • -i . i ,i ;Control! : J' ! LI.TII t J So iked . Sa-Tio le • - Samp le ; So ike - !;An_?.lyte ! %R ! Result <35R> C !._ Result (SR/ ClAdced (5A. J ";R

I Aluminum ii An 1 1 mon v I! Arsenic !. Barium i! Be^y I i ium !! Cadmium ii Calcium ;i Cfiromium If Cobalt IICcDDer E! I ran I: Lsaa! Maanesium !

1 ' - i r i t i

; 1 1 4 , 60 . , : a . oooo J U i i 20 , 0 ! 95.5; : FJ 46 . 600 ! . ; 27 . 300 I : 20 . 0 J 96.5! J Fi i t • ; i • > •' i i i • i i if 1 1 i i i i ti ; i ; i i ii i 1 I I 1 I I

i ( i i ' i 1 1I I I r | | t

t 1 1 1 i - I

' I I 1 1 • •i i i i i - ' ;

i i i i i i

t i i i t 1

! 225. 00 :.. ! 1 73. 00 I i 50. 0 ! -G-^- 0 . ' F; j i ' I I '• i J

iManoanese i - . « • - • • • • - ; . . _ . , ,I Mercury iMCKel ;

! Potassium ii Sal en ium .'; Si I ver I• '"CC. t LltTl •

JTnalliuiTi I•' /ansaium !-Zinc !- C v an i ae !: l

1 1 1 I r i •' - ' ' ' • - ' ., M . . ,

' 1 1 1 '

1 t 1 I I ' 1 I

t - 1 1 | I I

1 I I 1 1 1 1

- 10. 200 i ! 2. OOOO : U i 10. 0 ! 102. 0 I J Fi . i i i ii t < .i i i >

; | ; ; ;! 21 . 700 ! ! 1 .5000 I B ! 20. 0 ! 1 Ol . 0 I J -! 163.30 ' 1 * 1.300 I I 100.0 I 1 Ol . 5 , Fi i i i t *

t 1 I I T ' '

i 1 1 i i i •i i i i > i ,

Commen t: s:

flR30189iT 2:: - IN

U.S. EPA - CLP

5B - EPA SAMPLEPOST DIGEST SPIKE SAMPLE RECOVERY

^ j.

! SED-9uab Name: NUS CORPORATION________ Contract: !

Lab Cods: NcS__ Case No.: ME___ SAS No.: _____ SDG No.:

latrix isciI/water}i SOIL_ — . Level Clow/mea. s

Concentrat ion Uni ta: ug/L

t

: Control' Limir

iAr.nIyte * "R

A lavs mum :Antimony :

I Arsenic •; &a r i um ;. Serv 1 1 ium I' Cadmium ;.Calcium !l Chromium •':Cobalt ;: Cooper I, I ran :.Lead :JMaonggium!•^nQAnee* i

. Mercurv tr.Nickel ;• Pct«««lUffi I' 5© 1 -in i um ..Silver t. SodiLsn ;: Tnal 1 iu.-n !, Van ad ium !«• __ i'C/anide !

;

SpiKsd SampleResul t vSSR)

, — -. . ,-t

I ID. 25

__. .

374. 00.

1O. 70O

23 . OOO1275.0

i

I Samp leC! Result (SR)

•! 12. oOO! 69.230j;;1:irT'

I 263. 00I!

i';i 2. OOOO1iI 3.600O; • 200. oo!111

ft

1 SpikeC , Added C3A)

!

i 50 . 0j;Ii. ..,~— -\\f; " 10 o.o,i;1;

u: io.oj;

B; 20.0; 1000.0ji-; - -

"*"-• '• 'jj i

; )9 "7 C ~/ • T

94.0 : Fj;;

. !j— ,H

^..*

; 1

in.-: ; ;.F• ;,, -r~~-

,i s

107-0 ;Fi ;

;97 . 0 : . i-39.- ! ,F

; ;

i

\M V (?Ah;T 2;

U.S. EPA - CLP

5B EPA SAMPLE NOPOST DIGEST SPIKE SAMPLE RECOVERY

; SW-12Lab Name: NU5 CORPORATION_________ Contract: ;

:_ab Cedes NUS__ .L Case No. s ME___ SAS No.: _____ SDG No.,

ratrz;-. laaii/wat@"J: WATER Level (low/med.i

Cancan7ration Units: UQ> L

. -on tr^i . ' .= ... :

Arai/te . . ".r-, ; Result <35F. > C! Result. *.=R'-. C!'"-^-~

V _• ______i ____;.: 4. oo___; __; ____4. .J»0_00__•' L . __12 j. o_; ~m_95. 0_: __; F_: __. _________ ! _____1 . 2C'0_____; _! ____2. OOOO___! U I ____2C . 0__ • __96. 0_! _! F_

— a ** i L;»n ___!_ _________; ____________B___ i _ i ____________ i i _______ J ! I _5erviiium: ; ; ; ; ' ; , ;

Calciu.n_:C^rcmiuiTi ;

•_wOper.Iron

"L 6. 000 ! t -. 1000 '• > ___10. 0 ' 109. 0

e l.=n 1,.,-n r , 11.300

?.I IIU.T, ; ______,____21.000___; ; ___X. OOOO__JU!. an *c i am _: _______ J _____100* 40____ • _! ___3. SC'OO__ i B i __100. 0.Zinc ____ i ______ i _____________; _: ___________; _: _______C/aniiV : f : ; \

.,„ . . .J3R301893V ..-'ART _.,<, --irV

U.S. EPA - CLP

^B EPA SAMPLEPOST DI3EST SPIKE SAMPLE RECOVERY

: sw-13Name: NUS CORPORATION_________ Contract:

Laa Coa^s NUS__ Caie No.: rt£___ 5A5 No.: _____ SDG No.:

Matrix doi I/water; s WATER , Level (low/msd; :

Con cent rat ion un i t's: ug/L

i i a i; Contfol * ;

i I L.imi t * Soiked Samp le i Samp ieAnalyte J XR 1 Result <S3P) Ci Result tSr;:-

< • •Al'-tminu/r* ; . :

} An 1 1 mon y ' 1 2 . -O ; 1 4 . OOOO:A**««nic : f 17.300 I • 2.0000•Barium • i . ;. B»rv 1 1. ium ; i ! i• C a - m i u m • * ! ;! Is Izium ! «. Chroinium i ;JCobalt : ! i• Caooer ! . t! Iron I ;. l_@aa . i lOt sOO i i 2. OOOO ~^~~J i^Gn^S 1 v'iTI • I t 1 • — -, rtanaanasa i i f ! - •: rierzurv i I 1 1. « , , — , _ i i j. i >, r « .*—-•> s 1 i r i i

IPo^ASBiumi I J !. SaleniuiH ! . 11.10O I ! 2,0000;sii^«»- s _ i . t :; oc lu.iti * » ! = -I Th « 1 1 1 um I \ 21, 900 - \ 2 . OOOO: Vanadium J 1 102.20 . ; 2.0000izir.c : : : :!Cr*nid» I 1 ; ;

i i ; •

C

uu

u

•J

uu

"

1 1 •t I1 1 1

So ike i ; ;Added CSA) ; "/;P , Q ; r

i - ii i >

~^ 120.0 i ICO. 3 J tr20.0 ; 89.0 I IF

i i ii >t ii i i

• ^: •t r

f i

l i '

10.0 i lOcs. 0 I F' . . . *• : \i ii i •i ii i t

io.o . 1 1 1 . o ; ; .-i ' ir

20.0 ; 109.5 :F100.0 .; 1O2.*. i . r

1 ' 1

1 I1 1 11 ' '

AR30I89UV iFAr.T 2; - i?t

U.S. EPA - CLP

SB EPA SAMPLE NOPOST DI3EST SPIKE SAMPLE RECOVERY

: sw-14.Lab Name: NUS CORPORATION_________ Contract: !

Lab Code: NUS__ Case MO.: ""E____ _.__SA5 No. s _____ 5DG No.:

Matrix '.soi I/water; : WATER Level C low/med; :

Concentration Units: UQ/L

1 i ( i i' C"i tral . • " ~"_ ' I

•: Li.tu fc i Sc i f-- .ec . .5amo Is i , sample ! . SpiKe :; Arva 1> vS (' '\R ' F:esul t C35F. . C ! Resul t i 3R.

. Alum l -UM, i . !• Ar. ~ i .ncr. .-" r , -120. T*J - - - 1 S.oCOOi nrsen ic ; -. IS * 70C i , 2. 0000; Bar; 'win i . ;Berv 1 1 ia.fi •' I ;

. Cac.nium ; '. ,- C a ICIU/M • i . ; ! - - • • "1 Chromi uin i ; ; ;; Cobalt . ; 1 i .:1 Ccpcer ! . , ! ;; Iron i ; ; ;-Lead ' .._i 10.900 " ' ! 2, OOOO; haon^sium J J i !: anoanesa J ! -. ; • : : '; Mercurv ! .' ; ,':. Mick el ; : ; ;; rctassi um i ! ! J; 5s 1 en i um ! ! 9 . 9000 I 2 . OOOO! =1 I ver : ; - -- ' • ! !Be a ium i i ; i

; nal 1 ium ! ! 20. 200 ! ' 2. OOOO.'Vanadium i ! 107. SO 1 • • 2.0000• A. i n c . i t . i. Z .'.an i^e . . i ' , ;

'• ' •

C : ndaed *. 3A)i,

S! 120.0U! 20. 0

ii,

iiiii

U! 10.01i•i•ti;c

Ui 10.0J

1

UI 20.0u: loo.o

I111

;

::F. . -3 :

1 r

9o. 1 ! i F93.5 ! IF

• ti ii ii ii ii ,: ii ii i

,< •

109. 0 . , f-i '

•iii .;

, i99.0 : f;-

1 1,

1 0 i.O ; ; F107.3 ' F

;.• i

-jmment=i

flR30!895v V tPAFT Z; ' - IN

U.S. EFA - CLP

5B EPA SAMPLE NC.. POST DISE5T 5FIKE SAMPLE RECOVERY _______

Lab Nam©: NUS CORPORATION__________ Contract:

i_ab Codg: NUS__ __. Case No. : ME___ SAS No. : _____ SDG No. s

Matrix '.moil, water) : WATER Level (low/med >:

Concentration un i ts: UQ/L

* ' i I !i — — _ _. , _ i - - i• : _Ot i j f tj - i i j •

. i_ 1011 e : 5o i K.sd Same I e ! 5&mo i e ; £p i *e ;;Anai\T§ - tin" * Feiult ' 5SR-' Z ; Result «. 5R, CI

. -i 1 '.-m int..Tiftntimcn^ .Arsenic

* - ' 1 I1 ' 4. ~V) " cr'",f'n " l - ' 1 "t't <';--**• *-1.' . i — . wJ>.'1- .• t JT i 1 — '.' . '-.'

= 2C.1OO i i 2.000C '• u ! 20.0

1 ' 1

; 91.4 ; i: 100.5 ; i

IBanv.i: - ~ -- - • - . , , • - - - : -- ;! B»r 11 ium r i 1 1 L

iCacini..^ . ; ; !- , : . -j.' Calc IUTI . . J - . ; i . : Mf-> — m m • . , . . , '•H

iCocalt J 1 , ! I J - - i i "

. 'Zooowr : . i i i :' irsn4 ©aa

J ' ( '

1 : j . 500 , 2 i OOOO I U 1 10.0ii «

"' * i" Pi j. V. C • V

: naon^gium I ' I ; ; i . : :; -^a.-iQiingie , _, - ; - \ -. -• hgrcur ! I ' ! ' ! I r

! NICK*! . : ; i '; : ~ :'Potassium; i , . I ; ;« D S - ©fl 1 LiiB !I5iiv»r'coaium iJTnailium ;• Vanadium !•Zinc !.Cvan i d m ,.„„„.. .

!

j 9.1 ooo : ; 2 . oooo ~ i u i i o . ot i i t :> . 1 ' , 1« I t I I} 20 . 5OO : I 2 . OOOO ! U I 20 . 0i to*? .20 .1 ~ . oooo ; u ; i oo . o* ; i • 1I 1 • . t -

< I ': ! i

! 91.0.i i

;; 102.5 ' ;; 10^, 2 ••i\

i i

fiR30!896'.rART 2) - IN

U.S. EPA - CLP


uab Name:

Lad Cede:

Matrix tso

. Analy te

i MiL-.m in '/n; Ar. t imonvi Arseni c

NUS CORPORATIONi SW-16

Contract: :

NUS Case No.: ME SAS iMo. : SDG No.:

i I /water) : WATER

! Control ,*

: .'.ft " : Result; i

,'

1141 i ti .•**-.

Level (low/med>: •

cncen tr a t i on Un its: ug/L

i : i l i ',' i i

l i i t

Same la i Samp le ; So i k& i IC 55R t C I nesu It ; =R ) C I Aa a ea < SA > I .;ft , -X . r-

; ;. 30 •' I 4 . OOOO700 I " I 2. OOOO

•Barium i ;; Beryl I ium ! ; t iiLaamium • I . ;; ualcium ; ; I Ii •— J~ roiTi i u*mI Cabal tICaDoari I ron: LeadI Magnesium

I Mercury

i ii ii i . .1! 1

1 f

f ! 17.i . ii J: t

1 i> ti i

i ii it i

40O ! i 6. 9000i ii '• li i

j i

:MCKei : i ; I: PotassiumI eel en ium; 5i 1 ver; S-3G1U.71i Tna.l 1 ium'. van a: ium''Zinc: L> anus

i i

i ! . ... 10.: ti i

• i( \T"' i J.'-< .

I I 1031 ii ii i

i i

3 0 0 I I 2 . OOOO! 1

! 11 1

30O f ; 2 . OOOO.70 f j 2. OOOO

,i '_

' I 1 i

i t •' i 1 1u : 120. o ; ^5.7, ; FUI 20.0 I 113.5 i 'F

I I i f' 1 I Ii 1 I I> 1 I I1 1 1 1r i i •1 1 I I1 1 11 1 '1 ( 11 1 11

t 1 I '1 1 1 1

10.0 .' lO^.O : ri • i t: • \ ' i

i • ' •< ti . i .

i • i I

; i i

u: 10. o ; 103. o ; i F; ; ; :I ; ^- — -^ •

UI 20. 0 1 (lie. 5 ^' -v!,-(J * i 00 . 0 ; fOGx " -' • F: ; \ . :

i i •i i ' '

:—.«.. ^

fiR30!897.PART r> - IN

U.S. EPA - CLP


I SW— iLaD Na.Tie: NUS CORPORATION Contract: !

wao Codes tV

matrut <soi

i ;

; An B 1 y t s '

' Al-*.minum_».Antimony i* Arsenic

US Cave wo.: HE SAS No.: 5DG No.:

I /water; s WATER


-Control ; !uimi t I So ikea Samp le ; Samp leT.R ! Result '.BBR't C; Result (SR) C

i i; ; ; ;I ~ 123. 30 I I 4 . <I OOO I LJ

. ... . . : 17. 1OO '. ! 2.0000 !UI Parium . . ; . . . . i i :; Beryl i IUM. •.Cadmium ;t C a 1 c i ufn i, Chrcmium_!JCooalt :

i ' "' i> i i* ' ' *-* i > t• i ii i • i

t Ccco©^ i • ! -.i Iron ____ .-s -ad

t tn*-tii@a^»Aii*

inercurv1 t*J I C S? I •

* c *- - «-5"§ 1 en iUiTl^

Silver . I, Sea i um. "nal 1 ium :; /anaoium ;

T ' 1t .. - - 1 i I

L3. 5OO : • 3. 4000 • &i . 1 1 t

; ; ;t i ii i ' ii i* * ' »• 1 1 i; <3. 10OO I i 2. OOOO ~ . Ui * i - *i . i i i• i t t _i i t " i

19.5OO i I 2. OOOO iUI 107. 40 : ! 2.0000 iU

IZxr.c i I ! ! I. C *an:d* : I I • 1

; ; 1 ; ;

Level ( low/med; :

i * i• • i

5p ike ; ; ;Added <SA> ! ';R ; 3 \ r

i ~ S i120.0 ; 102.7 ; ;F20.0 i 35.5 I IF

1 >

1 1• • 1

1 ^ ^ ki ^ ^ H

: : ^1

1 ' '

1 * . 1

io.o ; 101.0 i :Fi ; ' '•i < >

: : , ' - - .; i'i ! " '

io.o ; 7 1 . '.- i ; Ft ' 1f - I J .

1 I I I

20.0 , 97.5 I 1- •100.0 ! 107.J- ; IF ;

i •,i . '

-CF?" V -FART 2) - IN

U.S. EFA - CLP


Lab Name: NUS CORPORATION Contracts

Lab Code: NUS , Case No. j rie 3AS No.:

Matrix isci 1 /water. : ujATER

Cancan t rat i an Un i ts: ug/L

i.* Con trc 1 . '. i_ i .T. 1 1 ; 5o i * ed 3 amp 1 e i Samp 1 3

. Ar- a 1 y ta I '.R : ftesu 1 1 "" ("San. !• C . F.esu It .. 3R -•

: Aluminum • - : 'lAntimonv . " • ' 114.30 i . 4.0000lArssnir I -' 20.300 ... , ; 2. OOOOeariu-.m i «' ' .

: 5ar vl 1 i _;m I ;. Cadmium ; : I. Calc ium ! l ; i. Chrcmium ! I - - . ; ~-Cobalt ; ; I ;; Coocer ; ; ; ; ., Iron I ; I ;- uead I i 1 4 . 300 J . 3 . 6000.'naanesium .' . ; ! !- :ianaanesa i ! ; ;iriercurv i i ; i; N i c k e i ; ! ; ;' Potassium ; - ; I i. Se I sn i um . J 9 . 3000 i 1 2 . OOOO: 3i I ver" i ; i ;.Sad ium i ! !' Th a 1 1 1 um i ! 20 . 1 00 11 2 . OOOO.Vanadium : I 109.70 I . ' 2*0000~ i - , — i i - i. - 1 n •_ i i i , ,

; Cv an ice ; - ! ; ;i i i

Cci^men ts:

i: SW-2•

SDG No. :

Level (low/fried) : ____

' . > i( i ii 3 p i tt . s :

C I Added ' 5Aj ! ::? ; -I ; ri i

' I ; •U. 120.0 ! 95.7 : IFu: 20. o ! 101. s : IF

t 1 I t1 1 I• • t I I

1I ' t i1 1 1 '1 1 > tI 1 11 1 tI 1 I II 1 '1 11 :1 1 '

B } 1 0 . 0 i 112.0 ; -! f ! J> 1 '•. '. ' I1 1 • 11 1 ' '1 • '1 • 11 ! i 'I 1 ' '

Ul 10.0 ' 3.0. - . J Fi : ; '

i i •UE 20.0 100.5 ; ;"U I 100. 0 ! 109.7 I . F

' , 1' 1 I I

i ' ' '

11 1 . ' . „

flR30J899

U.S. EPA - CLP

SB EPA SAMPLEPOST DI3E5T SFIKE SAMPLE RECOVERY

I T

j sw-.:Lab Name: NUS CORPORATION_________ Contract: {

Lab Codas NUS__ Camm No.: E___ SAS No.: _____ SDG No.:

Matriu \BOI I/ water > s WATEft Level f low/med.':


i Control ;i . Limi t : id i ked Samp 1^! Analyse ! *1R : Result 'SSR)• .; Aluminum : '• -tr. 1 1 men v i ! i \j~~ . v ..-lArmenic , I 20.3001 Barium :; ErervX 1 ium .1 Cadmium . Ji Calcium I !iCnrcmium . :iCobalt I itCcooe^ J J! I ron ; ;I «sa£ " I ^ . 6OOOiâQnâiufn' s|JVtB>-1-^K|P^M|«B< •

.riercurv ! !>* i - -. e 1 ; :iFocassium :. Selani'jm : 9. 1000, 5i 1 ver : I• 5co ium i II ""n * 1 1 i um . : 20 . 200Iânaaiu.Ti I I 1O4.SOi ~* , — — 1 1, i. 1 M „ i I

iCvftniae •' !! I

. SctiTlQ 1 S

2 ; r.esu * t •' 3R>

: ,4.0 COO

! 2. t")000, ii •i ii >i ii iii 'i iii i; ; 2. oooo: ;( 1

i i!

1 1

1 . 2.00001 c

1 1

t I 2. OOOO1 • 2. OOOOi :• •i

i • i tI Spike : , :

C I Aaaea (..3 A) I ".R '• C ! »*fi i i

• i * i '! U ! 1 20. 0 : 91 . 6 • i F!L! 20.0 I 1O4.0 : !r• . > 1 1i i i i ii . • ii t t 1 1

i i > Mk.:;:; ; ;•:1 1 ii i i -i t i 'i t " i '

I U ! 10.0 1 =?6, 0 ' ; -i f I '

! 1 \ • '•i f i1 r i . 1

i i it • '. - •i U ! 10.0 1 ? 1 . 0 . , "1 i • *i t i . . - . . 'i i!U: 20.0 r 1C 1.0 _: r: u; 100.0 , 104. •=. F__. 1 . •I I ' ' , 'i 1 ' '•: ;

Ca.nmen eg:

--Jr

U.S. EPA - CLP

5B EPA SAMPLE (\iCPOST DIGEST SPIKE SAMPLE RECOVERY

! SW-4Lao Name: NUS CORPORATION_________ Contract: ___ \

uao Coae: NUS__ Case No.: ME___ SAS No.: _____ SDG No.:

Matrix I.S01 I/water) : WATER Level (low/med/:

Concentration Units; UQ/L

• i \ iI \ Control I « . . : - . = , ! :! i Limit . SP iKea Samp le i Same le . 3p ike ;I Anal v te I ".r; I F;esul t ( 33R> C i Resul t (SR) C ! Aaaed <. 5A. I ''.R

: Aluminum- •i An t i-ncn v* Ti Arsenic !i Barium: Ber v'l I ium I' C a d .TI i u m'Calcium ;; Cn rQiTl 1 Ufil .'

i Cobalt i. Cocoer •I I ron i. Lead IJ Mao res ium I.var.Q-*nes-=I

; :<ercurv I. N i c e ii P 3* as sium ;' 3 si an ium ;I 5 i 1 v e ••• r; =od ium •; Thai 1 ium I' V3n ad ium II Zinc !ICv&nids I> i

i i . i ( .• . i i < i: 115.70. ; ; 4 . oooo ; u ; 1 20 .0 : 96.4. :I 20 . 200 ; ' 2 . OOOO ; U ! 20 . 0 I 101.0 . I: 1 1 i ' . . i

1 1 i i• i • : i i ' ii - • • i i ii i i i i i , • , :

• i * < * ' :' i i t i i i ii • ii i i ( i t .

' ' ' • ! ' ' ..I I , . tI I I I 1

! i i i t i • . . i• c. 9 OOO . 1 2. OOOO iU J 10.0 r cr. 0 - -• i i i f' i i i . i •

. i " " i i . • . ii i i ' i• • i i i * • —

. i •- i i •: i i i ti - i ii i . i t i , , , , '

- - 1 r . 4OOO I ! 2 . 0<XO i U ! 1 0 . 0 • ^^ . Ci i t i •i i t i ' ,,i ' i

• 1 1 i ;i 1 1 : i i , , '

i 20 . 600 I i 2 . -1*000 1 U i 20 . 0 - 1 OT . 0 ' iI 1 08 . 00 ' i ' 2 . OOOO . U ! 1 00 . 0 ! 1 C-c . 0 ;' • I I ' ' .i i - - i . „ 'i - i i i <i i < i f i

Comments:

JRJ30I90- AF. T 2 ; — IN

u.3. EPA - CLP

SB EPA SAMPLE NCKPOST DIGEST SPIKE SAMPLE RECOVERY

I SW-!Lao N*mei NUS CORPORATION_________ Contract: "LJ___1 i _

Lao Cods: NUS___ Case No,: ME____ SAS No.: _____ SDG No.:

Matrix *§oiI/water): WATER • Level (lon/med):

Concentrat ion Uni ts: ug/L

i : ;! .* Control Ii • h. i m i & t So i fc ad Samp i ©* Analyse ' t'.R I Fee mult (55R.1

.Aluminum ' _ :i &n C inory : i 1 13. 50i A r«en i c .' J 20 . 1 00J ear ium ; :1 Beryllium! I• C sdm ium . Ii Ca Ic ium ' ii Cnrcmium . »i Coo al t ." ;. Cooper , I. Iron !• l_M3 . . 17. oOOi !naonggiam t ;1 Manoangg© i !: Mercurv ; ;; -JicKsI i -J Fotag^iL'.m I I; B* 1 en i um i i S . OOOO! Silver ; \: Sad ium : !! Tha 11 ium ! ! 20.800.Vanadium ; • 107.90, Zinc i S. Ci. an Ida S !' i i

r'— i

SampleResult (SR)

4. OOOO2. OOOO

~

3. 7 OOO'

.

2. OOOO

2.00002. OOOO

Sp ikeC Added (SA)

u 120.-:U 20.0

-

-

-- io.o.

U 10.0

U 20.0U 100.0

-

< 1

I •

• p . — . f Jl.•m~, 1 Ur >

I

J

96.2 1 IF100. 5 • IF

, if i> t; |f1 ^P- ;

:

•59. 0 i . Fi i

t< ;

• ;njr • 1

( SO. 0 jl .^ - FV_ - "; :

•io^.o ; F107. 7 ; ' "

i >i

, ;

U.S. EPA - CLP


I SW-6Lab Name: NUS CORPORATION_________ Contract; ________ I

Lab Code: NUS __ ; Casa No.: ME ___ SAS No.: _____ SOG No.:

Matrix (soil/water): i*'ATER Level (low/med):

Concentration Uni ts j ug/L

l u o n t r o A i I 'i '•. . _ i .TI 1 1 I So iXec. "~3amp I e , 3amo 1 e . . . - I Sp i k e !'Analyse '•'.* ; Result <53F.; C .' Result (SR? C ! Acded CSA) !

. Alu.Ti in urn : !; Ant i i7.cn v ! . '- ---i*3.40i H r s e n z c ! •' 20, 0 C* 0I Bar i-_t;Ti r .J Bervl 1 ium :. CadiTiium l I: Calcium f !, Ch rcm i *im ; IJCobalt I !J Coocer • I, I ron !: Lead : ; '9. OOOO; Maonssium ,. !; r^ncansse { i "ir-e^cu^v . ;:-%:ckei ; i; Potassium .' I: Se 1 en i uin ; , 11. 0001 5 1 1 v =* r ! i: s-id ium : ;i Th a i 1 i um i I 20 . 400- vanadium I I 105. 10• - , ~ - i i• ». * • i — • *:Cvanica ; !

: 11 . l

,

• 4^ OOOO: 2.0000i!ij

1I!1

'.

;

I 2. OOOOi1•tiii! 2, OOOOii

I 2.0000I 2. OOOO

iit

:UI 120.0 I 9&.2U; 20.0 ! 100.0

ii •• ii ii ii ij 'i iJ

!il :

U! 10.0 ' 90.0i i• *i '• i• 'i •i i

U i 1 0 . 0 ! 1 1 0 . 0i •i

U ! 20.0 f 102. 0_Ui 100. 0 I 105. i

; ;t111 '

13 j

V (FAnT 2) - I.. 301903

U.S. EPA - CLP

53 EPA SAMPLE 1POST DIGEST SPIKE SAMFLE RECOVERY ______

SW-7L.&D N«mei NUS CORPORATION________ Contract: ___ 1

Lao Codes NUS__ Case No. : ME____ BAS No. : ______ 5DG No. :

Matrix (moil/Mater): WATER Level (law/med.1:

Concentration units: ug/L

t1 • I

; ; Control \* i L i m 1 1 . So i ked Bamo *. ©

» * ~ -i; Aluminum :. An t : mar. , • 114. SO, Ar»en ic * 2O. TOO; oar turn ; !. Barvl liunTtl i"ndiniwm . ; -- -C$ Ic ium • '

i . L * t GIT! - JiTl __ . —————————— . ——————— , —————————————»• T .- — — - i *.

1 M-^JU @, 1 W * 1

-oczer , *. Iron ; rv.gaa . ; r. 1OOO!^*cine«icini :.rt*na*ne«*tiMercurv I iiNiCft*! I iJrotamsiurr.: :iS^i^niaiTi • * 10.7OO1 Silver I i•Sodium ! It Tna Hi um ', I 2O . SOO! Vanadium ! ! 104. *0. Z me I S. L van i — s I 1• i ii * i

t t . i i

i i " t ' .

! Samp le ! Sp i H e I . iC : F;esu 1 1 •: 5R > C ! Added ( 3A ) ! *:R -Ii : r

• ... i i _ i i i: ; 4. OOOO i U ! 120. J 1 95.7 1 IF'-i 2 . oooo ... : u ; 20 . o : 107.5 ; ; F

1 1 : 1I I 1 > 1

1 . 1 ' 1 • 11 . 1 ' 1 " 1

i i • i i i i

: • : ; ; ; -^• ; ; i , ^Bi .: _ ! ) " . " . i • ^^i -. i i i

• - i i •

1 1 i • *1 1 i i i •! I 2 . OOOO . U ! 10.0 I 7 1 . 0 : i F

1 • 1! 1 1 1 t '

1 * I1 . 1 . 11 1 I I •1 1 1 1 . 1I I 1 1 tI I I I • ' _I I 1 1 1 '

i ; 2 , OOOO 1 U ! 1 'J - 0 '< 1 0 / . 0 ! ri i i i i >1 1 * - i i i • M• i • i • (i i i t i *I J 2. OOOO i U i 20. 0 S 104. 0 ._: ___ F_; i 2 . OOOO i U I 1 00 .0 '1 04 . a i FI 1 I •. ' < •, : . ._. i ! : : .i : ' ! ; i i

134

-.P4KT 2) - IN

U.S. EPA - CLF _ „_. ... . . . .


I SW-3Lao Name: NUS CORPORATION_________ Contract: _________ I

Lao Cooes NUS__ Case No.: ME___ SAS No.: _____ SDG No.:

Matrix isoi 1/t.atsr) : WATER Level (low/med) :


1 f - •: i i

I Control I- i L 1 'U l t i; Ana! y ts" "• *'.R <

.' Al LUT. mum I' t-f-n 1 1 men v• nrsen ic i !Barium ; i

< Bervi i ium • I

Soiree Sample-- - ! SampleResult <55F:_ C; .Result <3R)

:

121* '.MJ . - •, '~ . O'OOO20. 2-00 . ! • 2. OC'OO

-I - - . - -', i

1 • - ' 1 .t 1 . 11 ' • 11 1 I 1

I Sp 1 r,e i i .'C I Ad d ed . 5 A ) ,' *:R ! Q . :

i i i i

IU! 120.0 ! 100.3 I ! F_ ; u i __ 20 . o _ ,« _i o i . 5_ i _ ; F.

I I 1 I I

i i : i :

i •- a d ji i u m • , , ; ; ; ; ;; Calc lurr, • Ji Ch rcmi UITI • !• Ccoal t • ;i -oossr >\ I ror - : ;•w-asa ;• Hacnesium ' ;; riar.oanese i "="!; riercurv • :. NICKS! I — i^ Potassium > !. Selen ium . i! 5i i ver ; _ ;. Hoaiu.'n I II Thallium ! !•Vanadium 1 {

i <i i• i, i•

13. 200 i • 3. 0000Y '

1

I r

" " ! '| j

9. 4000 I 2. OOOOi '

i f

ia. 400 i ; 2.. oo'oo1 14. 90 ; i -b, 1000

• 1 , . 11 1 1 )

: " i ' . 1

1 I i I T1 'I I • 1

I I 1 1I I 1 I I

!BI 10.0 102.0 :F

t ! ' •i . i < ii i i i i; j ; ; ii i i ii t . iu: io.o i ?4.o..' ;F: l . l .I i t i >

i *,i i t t

IU ! 20. 0 i 92. 0 i • FiBi loo. o i ioe.3 ; F

. Zinc ! I : ; I : : : ;J Cyan ice i !

r l

j•

• , i ' '1 ' ' • „ ' ,i i i ' •i t i * , '

^amments:

. .._..__.._.,., .Jiff301 905r _nf*l V (r nP T 2': — IN

U.S. EPA - CLP

6 - A EPA SAMPLE

Lab Name: NUS CORPORATION <

Lab Code: NUS Case No.: ME

Matrix (soil/water) : SOIL

% Solids for Sample: 72.4

Concentration Units (ug/L o

1 1 11| 1 Control I IlAnalyte { Limit || Sample (S)1 1 II1 Aluminum 1 II(Antimony i 1 1I Arsenic 1 1 f1 Barium I 1 I1 Beryllium 1 [ 1I cadmium I 1 11 Calcium 1 I 1

i 1 Chromium 1 1 j* 1 Cobalt \ II

1 Copper 1 i Ii iron i I 1(Lead 1 ||IMacmesiuml 1 11 Manganese j j I(Mercury I II(Nickel 1 II1 Potassium! I 11 Selenium 1 I I1 Silver I III Sodium | 1 1(Thallium 1 N(Vanadium I M1 Zinc I 1 1(Cyanide I H 0.69I f II

:oi

r

c

u_

71

ID

.

iract:

SAS No.:

Lave

% Solids fc

g/Jcg dry weight

'Duplicate (D)

*

1.5

ll

>r

):

c

"

tf

(t

\

SED

SDG No.:

low/med)Juplicate

M3/KG

RPD

— t

.

t:

2

Q

12-*

M

*

c

}

>

flR30!906FORM VI - IN

EPA SAMPLE NO

U.S. EPA - CLP

6 - BDUPLICATES


^b 9odai US__ Case No.: M__ SAS No.: ____ SDG No.:Matrix (soil/water): SOIL vel (lotf/Md) .

* Solids for Sampie: 75.1 % solids for Duplicate:

Concentration Units (ug/L or mg/kg dry weight):—j ~f | Control(Analyte | LimitI

_(Antimony™(Arsenic ""I Barium(Beryllium|Cadmium|Calcium|Chromium^|Cobalt[Copper|Iron____(Lead{Magnesium!|Manganese|(Mercury(Nickel|Potassium(Selenium(Silver|Sodium|Thallium_j Vanadium(Zinc__~I CyanideI_______

flR3019FORM VI -

7/87

U.S. EPA - CLP

o - C EPA SAMPLEDUPLICATES

i H

! 3ED-9Mwn«: NUS CORPORATION________ Contract: i

Coos: NUS__ C**e No.: ME__ 3A5 No. : _____ 5DG No.;

"lAtri?: («oi l/wjtt«r> s SOIi__ L^v^l (low/fried):

*'. Hciids *or S&mpl^: _",7 "1 Solids for' Duolicate:

uni ts (ug/L or mo/kg dry weight): MG/KS

* 1

i Aluminum *I An c i-Ttcn /jArianic ;' Sari umi Eg^v i 1 ium !CAGJiu^m !IC&ic ium :-hrsmium .ZDQ^I t

i Caop***»» i ror, :*_!§&'-

^^Qng 3 i umN*n-5*n»*«:' M*rcurv I, M c - * 1» F'o t &Ea lurr. •Salami .Silver

i Boc i um i• Thai 1 ium It v>n AC ium ;i 1 me I,C van id« !• i

:_- o n r c iuimifc

a. ii.4

27. IC.7

•Tps _r

1 & *r

o. 33. 4

67a» •*

_5.4

673 » 4— - -----

o7a,41.46.32.7

i

1 Sa.mpla v3)

! 1 26OO1 , 7000

i 9. 3000-i 1 74.OO'• 2. OOOO'• 0. 3400i £54. 00; ia. 200i 28.400

37. OOC: 43=00! -3-0.200; iiso.oi 60 0 . 00: 0.1300: C5.9OO! 969.00! 0. 2700! 1 . 30OOi i •~'sr i\,'\i l-j;«j.OUI 0. 4300! 51.200S 33.700Jri

C

&

u

u

uuBB

! Dupl icate f.D) C ' i

i 12100 • ! -; : . 4000 ; 5 : i; 3. 4000 . ! :; 1 75 . '."'0 ; ;! 1 . 5000 - I i :! v.5300 ; j\ -- 579. 00 !' * 5 1*11^ • '' * J » TV-' • f- i

! 27. 300 _ T ! ' ! :i 36. 500 ! '• i1 41000 ! ! ;! 31.300 ' ! .! 963. UO ! ! J1 o43. 00 } i 1; 0.1300 iu ; i! 90. OOO ! - S! 961.00 i i !

0.2700 su: ;1 1 . 3000 . U i !

132.00 !E1 ',i 0. 4300 ! B ; i

42.600 ! i 1i a •? i ,")!', ' ' •• a_ • l '.'U t t i

i it < ! 1

; ~ « "i i

RFC-

4 . 019.410.20. 623 . b

0 . 61 - 'T- -

i.411...1 1. r»J U * „•

o. 30. 5

) . 00 . 0

i •— > » _•i. 9

ti r' r ~t • v1

• r

i i Ai i ' ~; I r, 1 , A1 ! i Aj ; m:: 1! ; A

! : ,-A• i pii • .1-1! ! . ri l * ; A, -A! I ; CV* 't ; A. j ;A

! 1 ~

i ! i A{ ; ! A\ I i >-' . J r! . ; A. ;; ; :

- i.NftR3QI9Q8

U.S. EPA - CLP

mr

Lab Name: NUS CORPORATE

Lab Code: NUS

Matrix (soil/water) :

* Solids for Sample;

Concentrat1( Controlj Analy te Limit1I Aluminum1 Antimony(Arsenicf Barium( Berylliumf Cadmium

^1 CalciumBl Chromium[Cobalt1 Copper(Iron(Lead[Magnesium!(Manganese!1 Mercury 1(Nickel 1j Potassium!(Selenium I[Silver Ij Sodium j(Thallium 1(Vanadium 1IZinc |/ cyanide |1 I

DUPLI

5N C

Case No. : MEWATER

ion Units (ug/L or

Sample (S) c

10.000 Ul1

EPA SAMPLE NO.r>ATFS

J SW-7ontract: /SA5 No.:

Leve]% Solids fox

mg/kg dry weight)

Duplicate (D) C

20.000 |U1

SDG No.:

. (low/med) :* Duplicate:

; UG/L

RPD1t

Q M f_ _l- _i- _i_ _l_ _l- _l- _IiI ~t_ _!_ _ I-_ _l

[_ _f_ _l_ _l- _JI Hi_ _i_ _l_ _l_ _J_ _[c 1

I

flR301909FORM VI - IN 7/87

I

U.S. EFA - CLF

<b - E EPA SAMPLE NO.DUPLICATES

J SW-3Lao Name: NUS CORPORATION_________ Contracts ___ ;

L*o Coc«x NUS___ CMS No.! MS___ 5A3 No.: ______ SDG No,:

Matrix \»ai I* wfttar) : UA~ER ~"Level Clow/mad, s

" Solids far E#mp£«: __>.v Ji, Ealids for Duo 1 ic<n7;@:

Un i t m <ua/L. or m<y/ka dry weight): UG/L_

t

• An 51 i > ts iiHiuffiinum

I An 71 men > •f*Ar<«nicEjinuffl.,. , ' ,

i &«rvl 1 ium =(Cadmium• Calcium. Chromiui7j_(",; Cobs 1 ~ it€cop*r* i! Iron'L^md :» nmQn^sium .{ -^^n^an^M© i, Mgrcurv I, r* i r x m 1 i, PorsgmLum ;. 3«l*n i JIITI .silver

, Sod la.n ITn & 1 1 1 um •

• *'«n*a:iuiTi . ! Zinc !4 C / &n ic^ . i

*, - - i

» i

Zzn trol f *uimit -; 5a.mpi^ -.5;

; ; 200. oo» * — . '/OOO

- i * 2 . OOOO20C .0 * J 45O. OO

« r 4. OOOO

IS -i. OOO'C'' r t 184600

io.o ; r 10. ooooi- ( 5-0 . OO'~*

25- O . ! 23. 000- I = 1910.0

5. 0 i E 7. OOOOE ? J-&6OO1 r 333O. 0* i 0. 20OO

4O. 0 • t ZOOVOO£ T 63300: i 2. oooo

10. o s ; i o.o ooo; t 105000Si 2. OOOC

so. o : J o. 100020. o : r so.ooo

t Vt> *I »F »

c.uIU;ui!U!Uiij:uIB;i 5;

!Ui

i

.Uf

;-• ; -j

; 5i•i

rt

{ _ Duo i icats (D)

J 200.004 . OOOO

I 2. OOOOJ S90.0Oi 4. OOOOi 4. OOOO

18900010. OOOO

; 40. ooo! 21.000! 1360.0i 2. OOOO! 46300! 35oO.O! 0. 4000: 170.00! 62500T" 2. CCOO; 10.0000; 111000

'~l 2. OOOO1 3. ?000: 40. 000.j

i ii >• i

C 1 i RPD1 I• t

' I f ' 'i Lf i *

. U ! .'i L1 i ii ; ; 26. •?! U i ;; u ! l* 11 <j . •*! ! ; •:>.>;;u; ;;Bi ; 9.1; i ; 2.7i u J ' 200. 'ji * j.i t i ..' . C*

i ; i o . r;LJ; iI i ! i t . 2t i 1 'Ti i » 4.4• • • i t' '— i "

1 1 1 C . 0• i i 1 * O

iu; ,3— * l yl /» ,*iit •+ *• . l^1

j ; ; 22. 2i i <i i ii i i

i t ti .i t -^ i 1*1i t1 '. I A; ; ;F: : ;Fj i : Hi J ;A

i . * *! . , Ai i , Ai , IA, i F: ! INi • • •i i i i -it ' ~~ v'

.! .A11 i H

! F; . ;,;• i '. A: : -Fi i ~• • ! S\I I . - ~

1 ' 1« i

- :NAR301910

U.S. EPA - CLP

* ~ FDUPLICATES EPA SAMPLE NO.

Lab Name: NUS CORPORATION * I <ar————— ———— • ———— ——— — Contract: ___ { Sftr"Lab Code: _____ Case No.: *®__ SAS No.: _____ SDG No.:

Matrix (soil/water) : WATER Level (low/med) :

% Solids for Sample: _____ % Solids for Duplicate:

Concentration Units (ug/L or mg/kg dry weight): CX3/L

If1 Analy te1( Aluminum(Antimony(Arsenic _I Bariumj BerylliumI cadmium(Calciumij Chromiumr| Cobalt __1 Copper(Iron(Lead(Magnesium]| Manganese |I MercuryI Nickel(Potassiumf Selenium[Silver1 SodiumI Thallium| Vanadium(2 ineI Cyanide1

ControlLimit Sample (S)

10.000

c

uJ

1

'

Duplicate (D)

25.000

C

n_

RPD Q M

C

____

7/87

U.S. EPA - CLF

7 - ALABORATORY CONTROL SAMPLE *


Lao Code: NUS__ Case No.: ME___ SAS No. i _____ SDG No.

Sol id LC3 Source: SPEX 5TD ^/

Aqueous LCS Source: __________

: Aqueous (ug/L) • Sol ia '.{fig/kg)i Anal vte I True Found '/.R J True Found C Limi ts 7*R

! A 1 um i n um ! 997O . 0,'Antimcnv - 10070i Arsenic J 10020! Barium i 10O50! Eervl 1 ium ! 999O. 0! Cacm x um ; 1 0040! Calcium J 1O010; Ch r om i um i 1 0090;uooalt ! 10U10; Ccccer ! 1 OOOO: Iron 1 10010lueao ; 10020! Placjnesium ; 10020; anaanese ;99SO. 0! Nsrcurv I 50. 0•' ' j 1 c k -s I ! 1 '. '• 0 70: PC t a s s i um J 1 00 1 50: Si* 1 en i um I 1 OOZOJ 3i 1 ver ! 995/eC 0i Sod ium ! loOOOI Thai i ium J 9970.0I Van ad ium i 10090IZinc ! 10010f Cvan ide !

(

10930. OO10460/0010400. 009230. 009930. 009760. 009630. 0010000. 0010300. 0097&0 . 009600.009933 . 339800.009920. 0048.00

9700. 00101400. 092o3?Y3-VT _ y fj .Vl»O(.yeC* yO1 TO 4/DO1 04 0 . 009960.009SOO.OO

K 9. a iIi 3.9 Jit 3.s ;91. s ;79. 4 !97.2 i96.7 !99. 1 !

102.9 I97.6 ,'95.9 !99.1 .'97. S i99.4 I96,0 !.96.3 J 1101.2 ; ,/93 . 1 ! n9\ - >

'~~ ~ rtM SL T l \-f /~CTfl^T«V™' I \ f '

100.0 I /104.5 ! '96.7 !97.9 !

;!

•

tiiii•tiii1ii,ti,I

i;i

i'

ii

* Solid Laboratory Control Sample of 11/03/88.T) Sol id LCS was not available. An aqueous standajM was prepared and analyzed as thesolid Laboratory Control Sample. \ / *\, v .

**\flR3Q19!2

*M VII - IN

U.3. EPA - CLP

7 - BLABORATORY CONTROL 5AMPL.E *

Lao N«m*i NUS CORPORATION__________ Contract:

_AD Coa^s NUS___ Case No.: ME____ 3AS No.: _____ SDG No.

Sol ic! L.2S Sourc«t SP"£X 3TD *

Aoueous *-CB Sources ___

Aq Uttcu i ug / L', * So lid i^ /no / f-, g ;Tru» ^"ound ";R I True Found C Limits '/.R.

, Aluminum I; Ant i.Ticr.v i.^rsgnic !-Sarxu.Ti. &§ry 1 i ium -! Cadmium I! Calcium !. Chromium ;; Cabal^'"ocoar it Iron S'^saa *tMsgngmium:Mangar.jgi^ ;*n§rcur\• '•> 1 C ': © i

'P'OT^igium;=el^n-u,T> ,

:5ilv«r ;I'-lCCl^.n !i T~^ 1 1 ium !; % & -\ & r i -im :Z ine I

. C</»nia« ;.

9970. Clv'17010O7O1OO3O

=? ?90 . 0LOO 401O01Ot OG9O100 101OOOO1O01O1 OO201OO2O

95SG . G

1 -JO / 01OC15O1O03O9950. O1OOOO?97O.O_100901001O

_?90G.OG_9760. OO9450.00w -r-O*.' . OO_?760.OO987O. 001OOOO. 0096OO.OO10000.00990O.OO9330. OO9300.00101OO.OG1 GOOD . OO

1OO40.0OiooaoG.010200.009600. OO1OOOO.OO1O8SO.OO10100.00104OO.OO

99.**: :Z6. 9 , :94,3 I !92.5 , i97.7 I !9S.3 ; !9.9 ! !

95. i ; i9.9 : i

99 . 0 ; J98.7 1 i92-3 ! !

1OO.S :i oo .2 :

1 11 1

99 , 7 ; ;10O.6 ! i101.7! ;9A.5 j - ;loo. o i •109. i ; ;100. 1 . !103.9 ! ;

,1 1I :1

I* . 1

« . I' • 1f I t1 ' t _ ^ k1 • I ^ K

1 ' ; ^^1 11 1I • '

1 1t •1 i; ; I1 ~" . 1'. • , ,

t (1

t t 1i f ;1 '

r . T

• 1: i •1 1. . _ _ _ . _ . _

1 •1 1 11 ' •1 I 't >1 • 1

i i

* Solid Laboratory Control Saitcple of 11/05/88.(T) Sol id LCS was not available. An aqueous standard was prepared and analyzed as the

solid Laboratory Control Sample.

flR30i9!3

U.S. SPA - CLP

7 - CLABORATORY CONTROL SAMPLE *

i_ad earner NUS CORPORATION_________ Contract:

L<3— Cods;

5ciid LC5

' An a i y t s

; Aluminum" An t: imcn ,Arsen i -r __

. Berv 11 lain: Cadmium' Calcium _

1 '"" -~3 *~ — 1 ITCc-ccs."*

; I ron• LSA.3

."lasnesium

; r.srcu'-v:--iic*.«i:c :l;;iTt* s» 1 1 '. s ri Sociu.ni Thai 1 ium. Van ad ium_JZinc

i

NUS ___

Sources

-: T-ue

: i x>7v~!~1'"<':<50~! 999O.O; 1004O; 1 00 1 C1; 10<".9G: 10010• 1 0000

1 00 1010020

• j[ H ' ."L * Ll

! 50 . 0' iV;7"-"'

! 1 C'O 1 50, 1C03019950.0; i OOOG19970.0; 1 0090;_iooio_t

Ca

: b<-t.<

se

STD

Found

9560.

i 96 "'; _?C50.*_92iO.J ..9670.i 10080;. 9500.! -5 JO.i 9520.; 950O.

i 50.; 970O.i 102900. 10366.J 9600.1 10000.i 1G58G.!_9540.I 10100.iii

•J'j •"00 I00 I00 1

00 :OG .00 :

r.'O lGO iGO ."

00!00 I. 0 i

67!OO !OO!00 !00 100 i

iii

I'MO. : ME £AS No. : =DG No. :

- - - - - - - -

' . - 5o i i d '^ Tig / !• g >'.R .' True r Dund C L-imits '/.R.

95.9, t : . ; , • :i 1 1 . 4 ; ; i : : :95.5 , ! : i !^ C' . O 1 • : i t.— — i — i ' iT ji. • *^ i • i i

'"f £> m «• 1 • f 1 1

l '"<<."' ~ ; ' ;j, -• **• . . * i i i *97.1! •' j I •T 4 . 9 ! ; . . „ . : - - , J , ,

95.2 ; ! I ; •. i94. 9 , i 1 J i !9=5. S = i ! i . !96.3 : : ,' : ;93,4 j i ; ;100. C- ! - j - : " i ! 1 !96-3 1 i ! .' I '-

102. 71 J " • > '• I103. 4 i : i J i :'f Q . J 1 ' f 1 ( 1 ' , r .

100. 0 i J J i ' - '106. l : i ; i ; ;94,5 ; ; ; j i J

100. 9 ! i i 1 i •i - ' ' ' ' „ , „ , . , , .

i j ; ; : ;_.....__ ..* Aqueous Laboratory Control Sampie of 11/04/88.

AR30I9U. ,_

U.S. EPA - CL?

LABORATORY CONTROL SAMPLE *

u*o Names NUS CORPORATION,.;________ Contract:

Lmo Coo©: NUS

Solid LC5 Source:

Aaueous LCS Source:

nr.&l y te ; Tru^

; i-t . am i r um IT*?/ '-• . *-> >An ^ i.-ncr r Z.OO7 J1 -

i Arssnir ' 10C2? '.£*n jim ; 1 X»5O i

; s@*-\ :iai.ffl:?790, :• :U&CJ.TI ium ivO4O I.Calcium 1-jOlO 1; I.-rc.siu.-n . lOOÔ i; Cos*l t 10010 i. Cc3i3*r __ ; _ZGOOO_*. I^cr ICOlv :LSiiG 1 02 j II^SQngsium 10020 !ÂnÂnwB* 9980.0 ;iMgrcurv S' Nict ei .lOOTv !: P = t a s g i am 1 GO X 5O \'£«l*n iu.n IC030 i.silver 995O.O !* Sodium 10000 !,rh»:iium 9970.0 1;V«r.*ai»j.n 10G90 Jlînc 10010 !C * 1 1 "^ *

( i

C*B9 No.: ME SAS No.:

SPEX 5TD

O'-lS -Uw/-— .' • ScIlCFauna '.'.R ', 7ru» Pound C

lOioo.o:?. iv'i.T t * ]1OCC3<. . oo . i-.<w . f j i ; i3H5^.OO- 95.3 : 1 Ilv4OO.OO i 10T. z ' !7640.00: 9E.5 ! ; iT990.OO; 99. s ; i ;

1C-LOO. OO I 100. 9 ! . J?iaCG. CO . 9 "7". 1 .?aaO.OO; 9o.5 ' ; ;icioo. oo ; 101 . o i • t ;940,00: 9 ?.3 : ; irVG6.6/ I 97.5 i !

lOtOO.GOi 1O0.3 ! ! !10 00.00: 102.2 i .. ;

. : i i

vTSa.OG; 97. i ; 1 !102TOO.O! 102.5 J ; i1O966:. 67 i 1O9.3 I i93OO.OOJ 95.5 ! ; ilOGOO.OOilOO.O ! i i1O380.0OJ 104. 1 I ! !954O.OOJ 94.5 !1O60O.OO! I OS. 9 i i !

-- 1 11 1 1

i r t i

5DS No. :

1 •' .719 / • g tLimi-m '.'.R

i i•

: II

^ ^ H> • ^ ^ ^"~ " .

i •ii •i ii

i

i .•

ii ;!: Ii i;!Ir il1

•

* Aqueous Laboratory Control Sample of 11/05/88.

VI 6R3019I5

U.S. EPA - CLP

10 - AHOLDING TIMES

ame: NUS CORPORATION

ode: NUS Case No.: r

i >

EPA ! : DateSampie MC. , r^atri;; Jftecsived

3ED-10... _! SCIt- : 11/01/635ED-11 J SOIL " I 11/01/33

_ ScP-12 __ .'_30IL __ ! 11/02/SS3EC--13 : SOIL ' ! 11/02/33SED-14_ ; SOIL -'11/02/Sa

_ 3ED-15 _ !_SOIL ___ 1 11/03/83_ SED-1 1 SOIL ..i 11/03/33SED-2 ! SOIL - 111/03/83SED-3 ! SOIL ._, Ii il/04/ 635ED-4 i SOIL "111/03/83SED-5 ; SOIL ! 11/04/885ED-6 : : ! SOIL i 11/04/883ED-7 ! SOIL , . U1/04/ESSED-8 ! SOIL ! 11/02/835ED-9 . ; SOIL I 11/01/38

r ir il ii (j t, i

r ii fr tl ti ri ii ii it *l il .i i

IE

. . .Contract:

: SAS NO. 2

Nercur^y" ; MercuryPrep .. i Kola ingCats ; Time

11/14/33; 13. 11/14/88; 13_11/14/S5: __ 1211/14/33! 121 l/i4/53 ! 12

_11/14/S8I ___ 11 __11/14/38! 1111/14/38! 1111/14/86! 1011/14/33! 1111/14/83! 1011/14/881 1011/14/58; 1011/14/38! 12li/14/Sai 13

11I

.ji:i

iii

i

SDG No. s

iCyan ioe • Cyanic a :Prep ! riold ina •Da4:© 1 Tims

11/10/3S; 9 ;11/10/33! 9 i

_i 1/09/88 ! ___ 7 ___ i11/09/88! 7 i11/00/38 i .7. ;

_1 1/10/88 ! ___ 7 ___ I1 1/09/88! 6 ;11/09/88; _ 6__ .. ,1 1/1 0/83 I 61 1/1 0/88 i 7 ;11/10/83! 6 :11/10/33; 6 ;11/10/33,' 6ii/ 09/88 ; 7 ;ii/io/se; 9 ;

;;

: ii i' r> 1i t

:ie

t i

i

U.S. EPA - CLP

10 - BHOLDING TIMES

^ JID i\*m* i NUS CORPORATI ON_________ Con t r ac t:

Lab Ccidg; NUS ___ Cam^ No.: ME

• i

• _ _s+*-l2 • MATES. . i l/O'/SS ;SU-I3 ' U-A~ER ! 11/02/33!5&-14 wA^ES ! 11/02/58!= W-13 . ulATEF ill/03/33;=W-lo ; -uA"~.£F : 11/04/53;H-A-1 WATER ! 1 1/0-3/33 .=w-2 : WATER .11/03/83-!3v^-3 : WATER' ! 1 1/04/38 != _g-A • WATER ! 1 1/03/33 1SW-5 WATER ; 11/04/33:SW-o i WATER I 1 i/04/83 !Brfj-T ; WATE? I i 1/04/88 '.

. JHW-S t *ATER ! 1 1/02/38 1» I

• i iJ I! I ii t •

I

: s 'I i ;

i SA3

!Mercury ;

F-' r M iD m t s i

I 1/15/83:11/15/33,11/15/SS!11/15/35!11/15/83,11/15/38!11/15/E3I11/15/88!11/15/33!11/15/33;11/15/38!11/13/38!11/15/33!

1,jt

. ______ _ {;iti

No. s

Ho la inc. 1Tima ,

13 ;!•"!;

1211121211 !i "^11 ;ii ;11 !13 ;

j;1i!

.;j

3DG No. :

i C* an ids ' C/AT. ic-= i; prap J Hole r.Ci ,i .'Ate ; ItT.5 i1 . i; :i/ 09/33; ~: 11/09/83: 7!- 1 1/ 09/58 i 7 i: ii/i 0/33 , 7 ;

1 1/ 10/58 ! 6 i! 11/1O/88. 7! 11/10/381 7 '^^! 11/09/83 : 5 !^^i ll/ 10/38 J ~ :! 11/09/38! 5 ;! ; I/ 09/331 5! 11/09/88! 5! 11/09/551 7

ii )! I1 1 '

J J

! : ;i i! i ii

11 - A"INSTRUMENT DETECTION LIMITS (QUARTERLY)

-so Name: NUS CORPORATION_________ Contract:

;_as C-ae: wuS __ Case No.: ME ___ 3A5 No.: _____ SDG .N

ICF ID Null-no er: ___________ _ , . Dare:

AH ID Nuindar : FEoO3 _______ Date: 10/05/88

F:jrr. srs AA ID Numce-^ : FE3C3C ______ Date: 09/24/88

i^snctn ! 5acr.—. " CRDL . IDu.aly ~s r ;nm/ .^rounci '.ua/L/ • ;.UG/

! An t; irnon /_.. 217. oO; Arsenic _ 193. 70_; _ 3Z _ ! __ ___ lv— ." __ 2. 0_J F_ .! Earium ___ _i 553. 60_J ______ i ____ 200_ J — 200. O_ ! Aî: Beryl 1 ium i 234. ?0_I ______ i ______ 5^; ___ 4. 0_i A_i, Cadmium _ !223.SO_; _ __ i _____ 5_J __ 4. 0_;A_;: Cc. 1 c i L!i7i __ i 422 . 40_ ! ______ i . __ 30pO_ . __2C' ~!Cr.romium_,' 357. 90_!I Cob a i t __ : 240 . 70_ -f Copper ___ ! 324. 70_;I I rcn _____ ; 243 . 30_ i

_ . __ . _ •1O_J __ 1O. 0_I A_, fl50 i -0 . 0I A_ ; L

— — —1- •-•x. .770.19o,•-• -c. a i" r i"'276.-*. 4 -*

OO ioo i i00 i EZi * '1 .-r i i

3O J i50 •' r=Z !i •-. i — —

4-500*" "~~:,i 300<

!•

.' 30 . 0 I A ;20.0 lA j

1 T* ("• • P '. - <\

. 1OOO. 0 i A .; 1 . 0 . F ,

- Magnesium T285, 20 _t ____ _ _ __ 4 — __ j *! Manganese! 279. 50 ; ____ i ' " '~ . 15 i _ "lO.OîAî \\V^• Mercury __ i '. N i c K e 1 ___ 1.• r o t a s s i um ;iSelenium_!i Silver __ 1! Sodium __ i-IThall ium_J! Vanadium^! 313. 40_ ! _ 51. _ i ____ 5<-! Zinc ____ i 213. 90

- IN flR30J9!8

U.5. EPA - CLF

11 - BINSTRUMENT DETECTION LIMITS (QUARTERLY)

NUS CORPORATION_________ Contract:

Lab Cooe: NUS___ Case No.: ME____ SAS No.: _____ 5DG No,

ICP :0 Mumcars ___________ ..__C'ate: • ______

Fl*.r.» AA ID Nunraer : PE5CE_______ Date: 09/29/88

ru,rn*c« AA ID Nu.no er : FE2330_____ Date: 09/23/88

. Wave- , ;l Lansch ! HACK-; CF.DL i IDL :; Cnm. ! around; (ua/L) ! (uo/L) !

i Aluminum ; I 1 1 1

• Ar. ^ imon v i i • i i — * - rJArgenic . ! i .1 3.nrsium . ! ;

I < I

1 '

J Bervl 1 ium ' ! ! ; !.CAd.nium I , •: i '•:Calcium . i ! :.CnrcmT-un ; i i > I 1

'.Cobalt I • ; ; i i• Cccc.!r . I •. Iron * I iJL-tiia ,253.30 ; 3D !

" t ' '""

• - i .5 , 2jO IF i

iMaanMium. , 1 i i;r.ar,oaneseJ . ; -i •. rnercarv 1253.70 ! ;. N 1C KM 1 i i !

J F'ot . 3 ium » : IISelsnium ! i •.Silver I ;.Sodium ; ; iI Thallium !27a.SO J BD .! Vanadium i 318. 40 ! !!*Zinc 1 i !

0.2 ! 0.2 'CV:i '. '

t i ii - - ii i t

i i

; i10 1 2.0_Ir_50 ; 2 . o ; F ;

t i i

PROJECT NAME;

SUPPORT DOCUMENTATION FOR THE REVIEW OFINORGANIC ANALYTICAL DATA PACKAGE

j APPLICABLE SAMPLE Mn'« • ' ere 5u.r^fTYPE or *»*iv«i«. e - V V j Cyan.d^ ggnsKSu:-! thrcofk sic-S ? "£vM)-f.3CONTRACT LABORATORY:

REVIEW DATE :il-C

THE FOLLOWING TABLE INDICATESAREAS WHICH WERE EXAMINED INDETAIL, THE IDENTIFIED PROBLEMAREAS, AND SUPPORT DOCUMENTATIONATTACHMENTS:

AREAS EXAMINEDIN DETAIL

CHECK(V) IF YESOR FOOTNOTE LETTERFOR COMMENTS BELOW

PROBLEM AREASIDENTIFIED

CHECX(V) IF YESOR FOOTNOTE NUMBERFOR COMMENTS BELOW

SUPPORTDOCUMENTATIONATTACHMENTS

CHECK (V] IF YES"OR IDENTIFY

ATTACHMENT NO.

HOLDING TIMESBLANK ANALYSIS RESULTSMATRIX SPIKES (PRE-OIGESTION )DUPLICATESQUANTITATION OF RESULTSDETECTION LIMITS/SENSITIVITYINITIAL CALIBRATIONSCONTINUING CALIBRATIONSLABORATORY CONTROL STANDARDSICP LINEAR RANGE ANALYSISICP INTERFERENCE CHECKSICP SERIAL DfLUTIONSGFAA POST- DIGESTION SPIKESGFAA DUPLICATE BURNSGFAA STANDARD ADDITIONSOTHERS

s-s-s-s'S'

ssf

fs~s-

^

fS,

^

/

/^

>f '

^

^

j'

COMMENTS:.

/IR3CM930

BLRNK flNRLVSlS RESULTS FOR INORGflNICS

!

PflRflMETER

T da\S

Mtf -fa.15

/Mda»5

TVPE/MRTFUK

TC/4,

aW*?B | A<j

SflMPLE #

I CAL

CCAL

T?-<rp B)*\

SOURCE

AJ ^(A)

A/cS

CONTflMINflNT (CONCENTRflTION) ^

cn _-p06rH* d ^i rr- •> , ,_, ,,y

^-S w^/5 vanadium

Ajbn rzpc* 'fed

t——————————————————————————————————————————————————

LflBORRTORV REPORTED FIELD BLRNK IS COMPRRED WITH THE SflMPLE DflTft IN R TRBULRTION FORM WITHIN THESflMPLE flNRLVTICRL DRTR SUMMflRV.COMMENTS :

(1) RESULT REPORTED BV THE LflBORRTORV RND CONFIRMED BV REUIEWER(2) RESULT INFEREB FROM INSTRUMENT PRINTOUTS flND/OR SUPPORTING DflTfl

•

3R30J92J

INORGANIC CASE

MEISER & EARL

DISSOLVED METAtS

samples were„__ „. «,„„,_ WM- «*4«xjr«=v* uii 4. / /00, causing poor recoverv Th<s oiivo.-results have been flagged with an »N» on Form V and Forml's.

U.S. EFA - CLP

2A-1INITIAL AND CONTINUING CALIBRATION VERIFICATION

Lab Namg; NUS CORPORATION__________ Contract:

Lab Codes NUS_;_ -- Case No.: ME 5AS No.: ' 5DG No

Initial Calibration Source: SPEX STD \&

Continuing Calibration Source: SF'EX STD \&

Concantration Un i tm: ug/L

1

; Anal/te

I Aluminum^I Ant,imony_! Arsen ic _{ Barium __\ Bery 1 1 iumt CadmiumCalc ium _! Chromium_SCooalt __I Capper __i Iron ____

:Nic**l

; c 1 1 vm r! Sodium __: Thai 1 ium_. Vanad ium_JZincJCyanide,, ,„„;

Ini t i«Trun

_99700.010070.0

_1 0020. Of100500.0)_<?£90Q d

iOOlOO.O100900, OIOOIOC.01 OOOOO. OIGOIOO.O10O20.010O20O.O9930O, 0

50. O100700.0_1 00 1500

1 OOOOO. O

U0090.0100100.0

|tl Cal ib rat ion! Found 7.R < 1 >

99OOO. OO ! __ 99 . 31O52O.OO! 104.5_9500.00!_94.8950OO.OO!_94.51990OO.OO! 99 _V9T70O. OO K5737£>1010OO.O! 100.990QOO.OO! =?S. 1

9630O.OO! 196.3. 1 OOOOO. 0!_99. 9! 1O166.67! 101.5iOOOCO.O!_99.81O100O.O! 101.2

48 . OO ! 96.0S99&OO.OO! 98.9;_IO1400O! 101.210533.33; 105.09800O«.OO!__98.51 OOOOO. O! 100.0! 1016O.OO! 1C 1.9, 1060O.OO! 105. 1199OOO.OOI 98.9I }! »

1! True

_99 700,0,_1 0070.0_10020. 0100500.0__ 99900. 0100400. 0100100. 0100900. O100 100. 01 OOOOO . 0100100. 010020.01002OO.O_99SOO. 0

50 . O1OO70O.O_1CO150O_1 0030.0_99500. 01 OOOOO. 0__ 9970.0_1 0090.0100100.0

i>

Continuing Cal i brat ionFound '/.R C 1 ) Founa

1 OOOOO . 0 i 1 OO . 3 i i O5OOO . 0 I1 0 1 90 .00;i01.2:i 024O . 00_J7533.33iJ?5. 1 !_9533.331 05000 . O ! 1 04 . 5 f 9 1 000 . 0098800. 00 ! _98. 9 ! 97600. 0097200. OO ! 96. 8 ! 988OO. 001 OOOOO . 0 ! _99 . 9 ! 1 O 1 OOO . 099000. OO ! 98. 1 I 95000. 0096600. 00 ! _96. 5 ! 95800. 0096300. 00 ! _96. 3 ! 96300. t'O97400. 00 ! _97. 3 ! 96200. 0010300. 00 ! 102. 8 i 10266, 671 0 1 OOO . 0 ! 1 00 . S J 1 0 1 OOO , 0103000. 0 ! 103. 2 ! 102000. 0

52 . OO ! 1 04 . 0 ! 43 . 0097BOO.OO! 97. 1 I962OO.OO_10OOOOO ! _99. 9 ! 992000. 01 1000. OO ! 109. 7 i _9933. 339500O. 00 ! J?5. 5 ! 98000. 00101 OOO . 0 .' 1 0 1 . 0 I 99000 . 0010560. 00 ! 105. 9 I 10 ISO, 0010150.00! 100.6! 10410.0096000. OO i 95. 9 J 95000. 00

[ ;! !

t rl t

%R c 1 ) ! : r

105, 3i IA__101.7! fF_95. i ; ;F_90.5! IA__97,7I i A•8.4; Jtfft

1 OO . 9 i ff94 "^ ; ; A

_=5. 71 : A_

__7O . I i I A_

102.5; ;F100. a; : A_102. 2\ ; A_96.0; :cv95.5. ! A

__c;9. i . ! A___99 .01 S F__98.5! A__99.0i I A_102. 1 . !F_103.21 !r__?4. ? S I A

• ii ii *

Control Limits: Mercury BO-120: Other Metals 90-110; Cyanide 85-115See Attactoent 2A-5

I I vFART i) - IN

AR30I923

U.S. EFA - CLP.

2A -2INITIAL AND CONTINUING CALIBRATION VERIFICATION


Lab Code: NUS__ Case No.! ME____ SAS No.-* _____ SDS No.: SW-12.

2)Initial Calibration Source: SPEX STD_

Continuing Calibration Source: SPEX STD_y

Concentration Units? ug/L.

', l Ini 11 al Cal ID rat ion! An a 1 v t e .' T rue Fcun a Y.R \ 1

Continuing Calibration J!True Found XR CI) ~aund /,R (1) ! i r

1 Aluminum ;! Ant imonv i I! Ar-senic ': Barium ! <i Berv 1 1 ium • ;! Cadmium J . :) Calc ium; Ch ram ium ! iiCabait • •.' Copoer ; .:i:.-3n - : . _ . . _ .!• ead ; . '; --laonss ium ; if Manaanese .' . .. '<^e^cury •

; N i c K e 1 ! '•. r'a t ass ium ! I• Selenium ! ,. !; Silver ! Ii Sodium i I! Thallium II Vanadium ! •: Zinc I II Cyanide ! .'! I 11 i 1

997OO. 010070.G10020. O100500. 0•59 900. 010O40O. 0100100. 01OO900. 0100100. O

i 00 100. 010020. O100200. O993OO. O

100700. 0iooisoo10030. 0

1 OOOOO. O9970.01 OC90 . O

iOlOOO. 09960. 0010366, 671O3000.099200. 0097500. 00103000. 01 OOOOO. O94200.00

101400. 09300. 00101000.0iOlCOO.O

96800. 00i 01 30009966.67

99000.0010630.001011 0 , 00

101.398. 9103. 5102.599.397, 11 02 . 999. 194, 1

101.397.3iOO.8101.2

96. 1101. 199.4

99.0107. 1100.2

97000.00.' 97.3! ! A9730.00! 97. 1 ! IF10166.67! 101.5! IF91000.00! 90.51 1 A97300.00! 97.91 ! A99900.00!_99.5! 'A102000. o; :oi . - i ;A96000 .CO! ?5. 1 : ,f A94600. 00 ! S4. £; . A

• • <100400. 0 ! ivO. " '. . Hl oooo . oo ; _99 » £ ; : » -101000.0! 100. Si ; A1 OOOOO . 0 ! 1 OC . 2 '. ! A

• i95600. 00 i _95. I I I A_iC2iooa: 10: .9; ; A10333.33! 103.0! IF

i i ii i99000.00! ?9. 0! ! HlOSSO.-vO! 106. 1 ; ; -9770.00: 96.3! IF

i r ti . •i i . _i i ii > i

<1) Control Limits: Mercury 80-120; Otner Metals 90-110; Cyanide 35-11!f2) See Attachment 2A-5

\PAF7 1) - IN

AR30192U

U.S. EPA - CLP

2A -3INITIAL AND CONTINUING CALIBRATION VERIFICATION

Lab Names NUS CORPORATION_________ Contract:

Lab Codes NUS__ Case No.: ME___ SAS No.: _____ SDG No.: SW-1Z

Initial CalioratLort Source: SPEX 3TD \s

Continuing Calibration Source: SPEX STD


,' •' Initial Calibration! Ana lyre i True Found /;R ( 1 )! *I Aluminum '! Antimony I! Arsen ic *I Barium !SB^.rvlliumi! Cadmium ! .'Calcium Jl Chromium II Cobalt !! Capper "! I rcn ;!LMd -j Ma^ngsium !! Manoan@s@!'Mercury !!NicK.©l II Potassium I! Selenium J-. S i lv«gr 'iSocium !: Tnal 1 ium !! Vanadium I ,,,, ,:Zinc[Cvanide I{ ! I

ContinuinQ CaliDration 'True Found %R < 1 ) Found 7.R < 1 ) IT

99700.010070.010020.0

1001QO.O

100100. 0_1 0020.0100200.0_99800. 0

10030.0

9970.010090. O

i

10100O.O 101.3looao. 001 100. i1O700. 00

1O4OOO. O

102200.0_9900. 0099000. OO1 OOOOO. O

10333.33

10680.00_9740. 00

106.3

103.9

102. 1J?3.8_98.8100.2

103.0

107. iJ?6.5

!

10320.00

1O3OOO. 0

_

9733.33looOOo. 0

10266.67

_9900. 0010 no. oo

! A102.5 IF97.5 IF

I

T r~cB«"

i j, (1 > rt

97.1 r-99. = . ; A

t A, ,1

(102. •*; ^_

;

=9. 3 , .rl«^..,;r.

, ,1 ,

tl) Control Limits: Mercury 8O-120; Other Metals 90-110; Cyanide s5-il'

(2) See Attachment 2A-5

FCr.M II <-£RT i. - IN

flR301925

U.S. EPA - CLP



Lab Code: NUS__ Case No.: ME___ SAS No.: :_____ SD3 No.:

Initial Caiitration Source: SPEX STD

Continuing Calibration Source: SPEX STD W

Concentrat ion Uni ts: ug/L

Initial CaliorationAnalyte ' True Found /.R ( 1)

iHluminu.Ti JAnt i man v IArsenicBarium IEerv 1 1 ium iCadmium !Calcium IChromium !Ccaai*: ICopper !Ircn !Leac .--Magnesium If^an^anese !Mercury iNi-kel fPotassium iSelenium ISL 1 ver •Soaium !Thallium !Vanadium 'Zinc -ICvaniae i

i<[l4t

11

i

t1 t

iiii

I

iiiiiiifi1,

I

ii

Iiii

iIii

Continuing Calioration ; iTrue Found T.R < 1 ) Found 7.R ( 1 ) ! ! M

i *i i

_10070. O_i0020. 0

_ 10020.01002QO. 0

_1 0030.0

_ 9970.0_i 009O.O

10210.0O_9933 , 33

_9366.6710 1000. 0

_9700, 00

9720.00J?440. 00

101.4J?9. 1

_93.5IOO.S

_96.7_

J?7.5_93.6

10170.0010466. 67

_9866. 67101000. 0

10300. 00

_9 36 0.0010530. 00

• ii i101.0! !F__104.5: !F_

1 ri ii ii il ri :i 1

i ti i

< iS tt I

'. I

_J?6. 5! !F_100. 5 . ; H_

1 1

1

1 1t •1 1

102.7! !r• ii ii •i i

*S. =i ir104.41 IF

1 •1 1i ! .

• i i

(1) Control Limits: Mercury 30-120: Other Metals 90-110; Cyanide 85-115

See Attachment 2A-5

F3RM II .PART 1? - IN " '

926

ATTAOMNT 2A.-5

MENTAL SOORCE PREP REP TOPE VaUDBI

ALUMINUM SPEX QC-7 LOT 3-74-NK 222-88-16 99700ANTIMONY SPEX QC-19 LOT 1-9-TH 222-88-16 10070ARSENIC SPEX QC-19 LOT 1-9-TH 222-88-16 10020BARIUM SPEX QC-7 LOT 3-74-NK 222-88-16 100500BERYLLIUM SPEX QC-19 LOT 1-9-TO 222-88-16 99900CADMIUM SPEX QC-19 LOT 1-9-TH 222-88-16 10040CALCIUM SPEX QC-19 LOT 1-9-TH 222-88-16 100100CHROMIUM SPEX QC-19 LOT 1-9-TH 222-88-16 100900COBALT SPEX QC-19 LOT 1-9-TH 222-88-16 100100

COPPER SPEX QC-19 LOT 1-9-TH 222-88-16 100000IRON SPEX QC-19 LOT 1-9-TH 222-88-16 100100LEAD SPEX QC-19 LOT 1-9-TH 222-88-16 10020MAGNESIUM SPEX QC-19 LOT 1-9-TH 222-88-16 100200MAW3ANESE SPEX QC-19 LOT 1-9-TH 222-88-16 99800MEROORY MORTON THIOKOL HG STD. SOLN. 173-88-10 50.0NICKEL SPEX QC-19 LOT 1-9-TH 222-88-16 100700

f POTASSIUM SPEX QC-7 LOT 3-74-NK 222-88-16 1001500I SELENIUM SPEX QC-19 LOT 1-9-TH 222-88-16 10030

SILVER SPEX QC-7 LOT 3-74-NK 222-88-16 99500SODIUM SPEX QC-7 LOT 3-74-NK 222-88-16 100000

THALLIUM SPEX QC-19 LOT 1-9-TH 222-88-16 9970VANADIUM SPEX QC-19 LOT 1-9-TH 222-88-16 10090

ZINC SPEX QC-19 LOT 1-9-TH 222-88-16 100100

927

U.5, EPA - CLP•i «

2BCRDL STANDARD FOR AA AND ICF


Lao Code: NUS___. Case No.: HE___ SAS No.: ______ SDG No.: SW-12.

AA CRDL Standard Source: LEEMAN_____

ICP CROL Standard Source: __________

Concentration Un i ts: ug/L

ri

i

! Analy ta

; Aluminum^..' Ant imony_! Ar-sen ic! Barium• Eery 1 1 ium; Cadmium|Calcium „! Chromium.! Cocal t ,i Coooer! Ircn! Lead. Magnesium! Manaanese! MercuryINickelPotass ium! Selen ium{Silver, ri_! Sodium; Thai I ium! VanadiumI Zinc ____

CRDL Standard for AA

True Four a . . '/.R

2OO. 0 .__ 60.0__ 10. 0_200. 0_5.05.0

5000. 0_.10.0__

_ 50. 0_25.0100.05. 0

50OO. 0_ 15.0_

40 . 05000, 0

5.0_ 10.0.5000. 0__ 10.0.

50.0___ 20. 0_

__ 2OO.OO____ 61. 00_

8 . 90200. 004 , 004 . 00

5100. 010. 0050 . 0024 . 00130. 007. SO

5000.0___ 20. 00.

30. OO__ 4830. "0_

5.30___ JO.OO.__ SOOO.O_____ 9. 10_

53.30__ 2O.OO_

1OO. O__10JuJ^s¥7oj(1 0 u . 0— Sjij'BUTojKTSTT100.01 OO . 0_i6 . 0

< 30.j7/A-i rru"x"DOro33._ i

(^5 • 096.61O6.0100.0100. 091.0

1 06 . 6_100. 0

CRDL Standard for ICPI.nitiai Final

True Found XR Found

FOR,"i II CPART 2'f - IN 7'-57

flR30!928

U.S. EPA - CLP

3-ABLANKS

Lab Name: NUS CORPORATION_________ Contracts

Lab Code: NUS___ Case No. : ME____ SAS No.: ______" SDB No.: SW-12_

Preparation Blank Matrix (soii/water): WATER

Preparat ion Blank Concentration Units (uci/L or mg/kgj~: UG/L_

Ii Analysei

! Aluminum^{Antimony! Arsenic' Barium• Beryl 1 ium1 Cadmium! Calcium, ,! ChromiumiCobaltiCaooer! Iranii_ead! Magnus ium! ManganeseI.larcuryiNickelI Potassium! Selen ium! Si lv»r1 Sodium ___] hal 1 ium

Cal ib.Blank(ug/L)

200.04.O2.0

200.04.04.0

200,010.04O.O10.030. O2.O10,0IO.O0.230.020.02.O10.0

10OO.O2.0

! Vanadium ! 2.0JZinc 10. O! Cvanide, , .:

**c:

\u\JU!J U iju;ju:ju:SU!JU!J U JJ U ttu:JU!JU!:u:tutsurSU5!Ur

ruf~sut*inr T L *i Lr »r *e r1! t> r

Continuing Cal ibratBlank (ug/L)

1 C 2 C

2O O. O4.02 . 0

20O . O4.O4.0

200 . 01 0 . O4O. Oio.o3O.O2.O

i 0 . 0IO.O0.230 . O20 . 02.OIO.O

_iOoo.e_2.O2.0IO.O

; u ! 200 . o: u ! 4.0' U ! 2 . OSU! 200. OtU! 4.0f U ! 4 . OiU! 2O O.O; u ! 10. o: U ! 40. 0! U ! 10. 0.' U ! 30.0! U ! 2 . 0! U ! 10.0!UJ IO.O: u i 0.2! U ! 30 . 0; u j 20 . o! U i 2.0! U J 10. 0

_! u :_iooo. o! b ! 2.0:u: 2.0, U ! 10, 0i ii i

:u;!U!!U!:ui,'UIIU!!U!iu:iu:ju:JU!iu;:ui:ui!U1;ui!U!!U!!U!

__ !U!!U!;ui.U!! i1 1

ion

•*?

200. 04.02.0

200 . 04.04,0

200.01 0 . 04O.O

30.02.010.0IO.O

30 . 020.02.0

_10OO. 0_2.02.0

iI

C!

!U1j ui1U!!Ui!U!JU!!U!!U!JU.1• ii i:u!!U!JU!f U !i1 M 't U I

i u;! U!: t

~!U!!U !! ;; ;; j

Prepa- !!ration !!Blank CJ ! M

FORM III - IN

flR30!929

•U.

3- BBLANKS

Lab Name: NUS CORPORATION—————-———- Contract:

Lab Coda: NUS__ - ,2ase Na. / _^ •' o.: _

Preparation Blank Matrix (soi1/water)s WATER

Preoaration Blank Concentration Units (U'9/L or mg/k9,

Analy ta

AluminumAnt imonvArsenicBariumBeryl 1 iumCadmiumCalc iumChromiumCobaltCopperI ranLeacMagnesiumManganeseMercuryNickelc'otassiumSelen iumSi 1 v'erSodiumThai 1 ium_VanadiumZincCvanide

InitialCalib.B 1 an k

. . (ug/L) C

—

—

Continuing CalibrationBlank Cug/L)

1 C 2 C 3 C

200. 0 L1 "-•"• -"4.0 U2,0 U

iiri.200. 0 U4.0 U4.0 U

200.0 UIO.O U40.0 U

——————— l — — .30.0 U2.0 U

1 0 . 0 U10.0 U

30.0 U20.0 U2.0 U

_ 10OO. 0 _ . U2.0 " U2.0 U

.

200. 04.Oo ("j

200. 0

30 . 02. O

1 0 . 01 0 . 0

""> r>«i . U

*~* i't______ -i * V __ -•TI /*»-i. U

UUU

u

uuuu

u

uu

____ 4.0 __2. 0

2. 01 0 . 0

T> /"]______ ,,-i . V

2. 04.8

UU

-

uu

U

UB

t

Prepa- ;ration ;

M

.'• I A

.! ! fi

,•• n

, A

.? ; F

.'i ! A"

.; , A

1 • A

FOr:M III -

flR301930

U.S. SPA - CLP

3- CBUNKS

Lab Name: NOS CORPORATION _________ Contract: ___

Lab Code: NUS case No.: m __ SAS No.* ____ SDG Ho.: sw-12Preparation Blank Matrix («oil/vater) :

Preparation Blank Concentration Unit* (ug/L or mg/kg) : UG/L

l i t| I Initial || 1 Calib. [ Cont| [ Blank I(Analyte | (ug/L) C| 11 f 1! Aluminum | I |I Antimony 1 J 1 4.0(Arsenic I 11 2.0IBariua I II ,V^rvlliuml i 1\ daiUM ! ! (iCalciua f f i1 Chromium I j j/Cobalt I f I(Copper 1 I fIlron I I I(Lead I 1 1 2.0IMasneeiua! 1 1 10,0(M&nganejiel 1 fI Mercury ! 1 I(Nickel | I I|Pota**imi| I tISeleniua i . . . I . I 2.0(Silver 1 I IISodiua t II(Thallium | f 1 2.0 i(Vanadium f 1 1 2.0 iIZInc l || 1[Cyanide I If iI • 1 I f 1

inuing CalibmBlank (ug/L)C 2 c

1171 4.0 lylul 2.0 ly

'UI 2.0 1 -yOl 10.0 1 J>

"1

til 2.n n

"Ul 2.0 IfJai 2.0 ITJ1 J

tion

3

1!

c™

* *

™ ™—""—

I

I___""

2

Prepa-rationBlank

.

c™*

™-»

**

™*

I

11

111

1111

Ml1

EL.'•"

1I111|1

E 1t«(

A 1tiu.11111

E-l11

P tr i

E_l11i

PORK III - IN 7/87

AR3Q193!

U.S. EPA - CLP

5ASPIKE SAMPLE RECOVERY • EPA SANPLE NO.

Name: NUS CORPORATION r fc 3W-3-——————.—— Con t rac t:

Lab Coae: NUS r».NUS —— Case NOB; ___———— • ana No. : cnn KIM . ————— - bDl^ No.:

natrix isai I/water) : WATER Level C low/med) :

Concantration Units lug/L or mg/kg flry

Comments:

' i

j ! Control.'Limit

JAnaiyte ,' ;-;Ri :

J Aluminum i• n t i mon v i 75- 1 "5! Arsenic { 75-125'Barium ; 75-17=;.' Beryl 1 ium ; 75-125• Cadmium , 75- i "5> ;-alc ium ,'Lh r om i um i 75- 1 75ICooalt j 75-1-^5• uopoer : 75- J 75I ron !

• Lead j 75-; 7=5i Maonesium 1• ang anese .! Mercurv ;. Mickel ; 75- 1^5! Potassium i• -selenium ! 75-' ~5!.Srl ver ; 75- i ?^' wOd ium ;! Tha 11 ium ! 75-125' Vanadium ; 75- i -51 Zinc I75-17SiUvanide !

,Spiked SampleResult (SSR)

2400. O?5_ 60O39. 1002AOO.O4^^ OOO55. 000

15O.OO49("). On2-T9. OU2410. M1A.900

3900. 04. 10OO51O.OO

-..- 9. 700010. oooo40. 6OO115. 104SO.OO '•

CSamp le

Result <SR>

2OO. oo4. OOOO2. OOOO6OO. OO4. OOOO4. OOOO

10. OOOO4O. OOO

,„ „, io.o ooo1310.02- OOOO

.34OO. 0O. 200O

.....,,„ „. 7O. OOO

2 . OOCu'i4O.OOO

2. OOOO_ ,. 2. ooo

3O. 000

•<1 Sp i ke

C! Added (SA)i'J.1 2000.0U! 100.0 ——u: 4o.o —

2000.0"Ui _ 50.0u: so.o

ju: 200.0B J 5OO. 0U.' 250.0

i 1000.0UJ 2O. o

I "'

500. 0U,'_ 4.0' -- , 500. 0i -«

U! io.o' 50.0i

U 50.0B 100.0

5OO.O

t

t

7,R ;

120.095.697- 7100.0S4.0 J

110.0 :•75.0 ;90.o ;95.Q ;

110.0 •64.5 :i100.0 .102.5 1_ ,S S . 0i§ *.0 I~^rT^\-t U > ;- . J81.2 ;109.2 ;90.0 :

!:

H_;F__;F_;A_

NR;A_;A_

NR

r*_ ,

NR;F__'A .

A_;NR I

FORM '. ,;-ART i> - IN .

flR301932

U.=. EFA - CLP

5B EPA SAMPLE NO.POST DISEST SFIKE SAMPLE RECOVERY ________

i ' !: sw-aLab Name: NUS CORPORATION_________ Contract: _________ !

Lab Cod«i NUS__ Case No.: ME___ SAS No.: _____ SDG No.: 5W-12_

i;< tsoi I/water) s WATER Level (low/med) : ____.


1

1 Anal v t®

1 Aluminumt An t imcpy1 Arsenic! Bar ium1 Beryl 1 ium: Cadmium! Calcium! ChromiumiCobalt: CoocerJ IronILgadiMaQnMium, *iangane»*I Mercury: N i : v © lt Potais iumJ Selgn iumISiivef-I Scdium' Thai 1 ium'Vanadium! Zinci Cvan id«.

ControlLimit

- ---

Sp itcvd Samp le • SampieResult <35R_ Ci Result (SR.

' !117. 10 - ! 4.000022.400 , : 2.0000

> ij ;

I; ;• i• ii >

ii

- 9. 6000 : i "?. OOOO• i •"

i•ii ii i

10. 200 ! ! 2. OOOO_ , ,

^ ri i

_ 19.400 \ i 2.0000115.00 i ! 2.9000

; •i ii •'

r+

Uu

u

u

uB

Sp ikeAdded (SA)

120,020.0

~

1 0 . 0

-

1 0 . 0

20 . 0100. 0

-

i i

::?: ; c ; r;

112.0 i JF

; ;j i1 ;; ;

—— 19 & . o ; 1 1-

; !. ;

j

; ,102.0 ! .F

j

97. 'j \ \r112.1 i F

; ;i ,, ,

-OR."" V .PART 2) - IN

flR30!933

U. 5. EPA - CLF

SB EPA SAMPLE NO.POST DIGEST 3FIKE SAMPLE RECOVERY1

Lab Names NIJS CORPORATION Contract:

Lao Code: NUS Case No.: r*£ SAS No.:

Matrix '. soi 1 / water) : WATER


! 1 Con -'•"Di I : i ' - ,'• ' Limit • SpiK-ed Sample i .SamplelAnalyte ! '.R ; =_Resulr <S3R> CJ Result "(SR. C

! Aluminum ! •,• .i - \ • \' An 1 1 mor, y . ; * 22 . 30 ', i - - . OOi". 0 • U• Arseni- i :- 19. 7OC i I 2. OOOO . UJ Ear ium : i i• Berv 1 1 ium ! . ' i . . i! Cadmium : ! ' ! ;! Calcium i J ! ',i Chromium ( 11 ._ - ^ ; -; Cobalt J i .' ; !^L c o c e T" • '. i i IPI ran : ; ! ; iILead : . 11. .200 •;- ! 2.0000 IBJMaonesiuml : i - IJManaanesei 1 ' ' ' i \ ;1 Mercurv - - - - - - - - - - - . : .iNicKel • : : ; \\ Patass-ium • i i'Selenium-; i 11- 000 ; ; . 2 . OOOO ! U; Silver ! '- • ; I: Sod i'.-m '• • : ;: Th a 1 1 1 um : : 19. 700 II 2.0 000 ; UI Vanadium ; ; 99, t.'vU : ; «. i.»u<.'U 1 'JiZin-- 1 ! . : . . . ! . ! . ! .:Cv^n*.^e i --! '. •i t - > i

SW-12

5DG No. : 5UJ-12

Level C low/med,' : ____

Spike i :Added (SA) ; ":F. i 0 . n

120- 0 ; 101.9 ! IF .20.0 ! 93. s ; ;F :

1 I I I

1 1 11 1j 1 . ,

1 1 •

1 • 11 11 11 ' 1

; ., r

i o . o : = 2 . :• .-;

:JI .t

io.o i :io. ; ; . ~: ii i i

20.0 ! 95.5 I . - .iOO.O . ?9.0 ' '. r

i!i • i

u-ommen t = J

i^ V • ;= ART ^.' - IN

U.S. EPA - CLP

S3 EPA SAMPLE NO.POST DIGEST SPIKE SAMPLE RECOVERY

SW-1Lab Name; NUS CORPORATION__________ Contract: ___

Lab Codes NUS__ CM© Nc. i ME___ SAS No.: _____ 5DG No. s SW-12

Matrix teoil/water) s WATER Level (low/med) : ____


Comments:

> 1 1

{ t Control !; J Limit 1 Spiked SampleiAnaiyte \ XR J Result CS5R)

{Aluminum J J .' Ant i men v : ' L2O. »0J Arsenic ! ' - 2O.40O) Barium ' '.1 Beryl 1 ium i JJCadmium ; !! Calcium ! I! Chromium I JSCobalt i ; • --iCcooer ! :Iron ! I

JLead : • 1O.50OJMaonemium! J'"iana*r.e«e ;J Mercury •JMlC^»i i !I Patafisium; !! Selenium ; i 9.3OOOi Silver ! ! ^i Sod iumt Thallium J ! 20. 80O1 Van ad ium ! ! 95.80OtZinc i J'Cyaniae ; I1 ! !

CSamp le

Resul t tSR.1

4 . OOOO2. OOOO

2. OOOO

2. OOOO

2 . OOOO3. OOOO

C

uu

u

u

uB

SpikeAdded (SA)

120.02O. 0

1 0 . O

10.0

" 20 . 0100.0

/.f\ ! Q •'

.10O. 5 , '102.0 i :

; ;

;

103.-.'. - i1 jr; :

Ii •

?3.0 : :i >

;104.0 ; ,92. 3 : :

1

1

,

M

FORM V .PART 2) - IN

flR30i935

U.S. EPA -"CLP

5B EPA SAMPLE NO.POST DIGEST SPIKE SAMPLE RECOVERY ___

I SW-14Lab Name: NUS CORPORATION_________ Contract: ___ i

Lab Code: NUS__ Case No.: HE___ SAS No.: _____ SDG No.: 3W-12

Matrix (soi I/water) : WATER "" ""*""" Level (low/med) : ____*•

Concentrat ion Uni ts: ug/U

Commen ts:

I 1

,' ,' Control! L i m 1 1

: Analy ts ! "iR

! A.I uminum :i Ant i men / I1 Arisen ic !; Barium i' Beryl 1 ium Ii Cadmium i! Calcium !! Chromium 1JCobalt ;! Cooper ;llron fi Lead !! Maones ium I; Manoanese i•' Mercury \i Nickel! Potassium !{Selenium i! Silve^ i; Sodium 1! Thai 1 ium i•' Van ad iam !! Zinc !JC/anide !;

So i f:-ed Samp IsResult tSSR)

1=13. 602O, 7OO

-

12. &OO

- - - ' • ' :

S. 6000

21.900as . 500

cSame 1 e

Result (SR)

.4. OOOO2. OOOO

- --

2. .5000

: .-2. OOOO

2. OOOO3. 1000

•

C

LJu

3

U

U5

Sp i keAdded (SA)

120.020.0

10.0

10.0

20 . 01 OO . 0

•«94.7103.5

1 0 1 . v

3*.-:

109.53w . -r

FORM V PART 2) - IN

/IR30I936

U.S. EPA - CL*

5B _ EPA SAMPLE NO.POST DIGEST SPIKE SAMPLE RECOVERY

Lao Names NUS CORPORATION_________ Contract:SW-1

uao Code: NUS__ Case Nc. : ME___ SAS No.: _____ SDG No.: SW-12

Matrix \rnoi I/ water.1 : WATER Level (low/med) : ____

Concentration Uni ts: ug/L

J .Contra* i! ; u i.Ti it He iked Samolei Anal y te 1 "-R J Resul t <S3R)iI Alum inuffl •lAntimcnv . * 109.701 Armenic ! 1 18. 900i Bar ium f I! Beryl I ium' *'2admium " ;iCalcium I iJ Chromium ;iCobalt - !' Coooer ; ,- .,-_-:: Iron ' I!L§aa : . 12.600! MaGnesiurn •J Manpane»e • !I Mercury : :; Sic-^1 J.'Potassium: :Selenium ; : . 1O.200JSilver - -; Sodium . i: Thallium : ; 13.5001 Vanaoium • - i 16. 00: Zinc ! *•Cyanide ! *i i »i i i

i.' Sample

C! Result <SR) Cii i

! 4. OOOO ;U! 2. OOOO ! Ut 11 11 1t 11 11 t1 1t 111 11 11 11 tI 11 1

! 3. 4000 ! Bi . :i >. i. - ii ii ii '< ii ii1 *~? t*\t'-tt'it':i i ' 1i -i . Uf U*.' i U: i» i

i t

; 2 . oooo ~ i u2. oooo ; u

t1 1

i it 't 1

Sp i keAdaed (SA>

"120.020.0

1 0 . 0

1 0 . 0

_ 20. 010 0.0 t

/

1 11 11

•/.R 0

;

91.4 i F94.5 ! F

i:II

ili: ;i> «•; ^

<=~2.0 i .'i i• iit <

i102.0 ' r

i it i*

_ ,9-2 -5- : r•' lie. 0 .ify-I " - - - , ;

/t

M

cCooi/nen t §s

FCRM V (PART 2) - IN

flR30i937

U.S. EPA - CLP


1I

SW-2.ab Name: NUS CORPORATION Contract. !

_ab Code: NUS Case No.: ME SAS No.: SDG No.; SU-1*?

atrix (soil/water); WATER Level . low/fried): ____ .

Concentration iJni ts: ug/L

Analyte

A luminumAn t ijior.vArsen icBariumBeryl 1 iumCadmiumCalciumChromiumCobal tCooperIronLeadMagnesiumManganeseMercuryNicKelPotassiumSe len iumSi 1 verSodiumThai 1 iumVanao i umZincCyanide _

ControlLimit

--

Sp iked Samp leResult (SSR) C

i121 ."2020. 300

14.200

9. 7000

19. 1001 06 . 50

— .

—

—

—

Samp 1 2Result (SR) C

4. OOOO2. OOOO

...—-- -

____ 3. 7000 __

2.0000

2 noor*2. OOOO*

;

ommen tss

UU

B

U

UU

Sp i keAdaed (5A>

120.020 . 0

____ 10. O __

1 0 . 0

20 . 0100. o

I 1 It 1I 1 1

'/.R i Q\ f i

ioi.o : IF f104.0 i IF I

1 1 '•

t 11 1 1

( 1 1! 1

f ! I1 < 1

.105. 0_;_:F_:

1

1 I1I 11 1

97, 0 ; • F •i t i

J ;

95, 5 ; ; F ;106.5 ; ;F

i i >• i i1 ;i i <i i <

-ORfl V -.PART 2) --IN - 7''3.

flR30!938

U.S. EPn - CLF

^B EPA SAMPLE NOPOST DIGEST SPIKE SAMPLE RECOVERY __________

! SU-4Lao Name: NU3 CORPORATION_________ Contract: _______ !

Laa Codes NUS__ Came No.: ME___ " SAS Nc.: ' SDG No.: SW-12

Matrix fsoiI•water;s WATER Level (low/med):' ____

Concantrat ion Ln i ts:

!Control I ! ; .> Lini t • So i keC Samp i § i Samo le _ >. 5p i !•; e: ;-.» : P**ult <55R) II Result (SR) C! Ad dad (SA) !

;Mercjry

Comments:

Alum _ ___ ___ _ _____... __ _ ____________ _ _________ ______ _ _An t imon/_; _______ _____12 I . 70____• _J ____4. 0000___: U ! __120. 0_! _101. 4 I IFArsenic_' ______ ____21. 300____ _: ___2. OOOO__; U : 20, C I 106. 5~: "; F~

Beryl 1 ium* ______I ____________;_! ___________: _: ._____; ______:_C a d m i um _. ______; _____________! __ l ____________ I j ________ j _____ •Calc ium_I ______• _____________! „! ___________ J —J ________I ___ ! Chromium_ ______!,______________ __i ____________;_ _________; ______ ICao*lt__!______ ____________;_»____________!.«__________!______-„Ccpoer __: ______; ___;_________; _".' ___________; _i ________, ______£ron____;______' -- -__________5_!___________i i '______;______ 1 _Lgad_____I _______. _____10. IvC___: _! ___2. OOOO__I U I ___10. .5 i 101 . v . , - -

'5*1 £niu;n__' ______; ____?. 50*: 0 ..... i _! ___2. 0000__; U ! ___10. 0; 511 v r __: ______: ' ___;_____ J —; ___________ I „ - -____; led ium__ ; , ,' , i -; Thai 1 ium_* ______: _____I4?. 30O___.'_; ___2. OOOO__, U : 2O. 0_A V*n*dium_! ______; _____105. TV___: ; ___3.20OO__ B\ __10O.O

flR30l939

•J. 5". H~FA ~

SB EPA SAMPLE Nu.POST DIGEST SPIKE SAMPLE RECOVERV

Lab Name: NUS CORPORATION Contract:

Lao CCGSI NUS Case No. : ME SAS No. :

Matrix Osai 1 /water) : WATER

Concantrat ion Un i ts: ug/L

: ! Control 1 ! ,: ' L i -ni t : Sp : *_ed Samo 1 s : Samp i s!AraJ_. ts I \R ! Result OS3R. C, Result (SR) C

1 A ium inu:Ti • • i i: Antimony . : 111.70 I 4.0000 !U: Arsen 1 c I I 19. 5OO J ; 2 . OOOO 1 U• B a r i u m ; 1 - I !I Bervi 1 ium ! J i ! J' Cad.Ti ium ; I ! : ;f Calcium i J 1 i i* 2hromiL'm ; ', ; i ;I Cod a l t i * • ' >; Copper ) ! ; iL I ran : ! J !r. Lead i ; 17. 20O : ! 7.1 OOO 1

i Maanesium ; '• - 1 .; anqaness ; ! i J: nercurv ' I ' !.Nickel i ; 1 1 ;; Potassium ! ; I : I.'Selenium! ! 9 . EOOO . «' 2 . OOOO 1 Ui Silver i ! . . ... _.:..! _ ' Jr SCO 1 '.iiT) ! i i ,

! Th a 1 1 1 um : ! 19.1 00 II 2 . OOOO • U'. vanadium i ! 95. 500 ; 2. OOOO 1 U'; Zinc J ! irCvanida J ! • '. \

I t I T

11

! SW-15

SDG No- : EW-1-'

Level C low/med) :

i ' I

i , '

So ike ; ;Adaed ^SA) ! ';R i C ' f^

; ; ;

120.0 I ?2,7 - ,'F____ 20.0 I ?9.0 ! :F '

1 I I .1 I I It «1 I I I4 1 1

1 11 I I .

I

1 0 , 0 ' 1 0 1 . v , ; F;:

:

t •10.0 ! ? 8 . .".' : r

• i ' .i

20. 0 1 95.5 I ! - :100. 0 ! <=5. S - ."

,

i •

Comments:

FO;*F! ^ .FART 2.' - I

U.S. EFA - CLP

SB £PA SAMPLE NG.POST DIGEST SPIKE SAMPLE RECOVERY

(

.ab Name i NUS CORPORATION

.ao Coa^s NUS __ Cam© No. : ."

latn:: i§oi I/water ; : WATER

Cor.cen tr*

I Control »', Limit J Sp ifcea S-amp le

Anal> te ! 7.R 1 Re»ult tSBR.'

Aluminum ! \An cimcny ; : 113. -iOArvenic I 0.700Barium ; .' ~~Beryllium! ICadmium • :Calcium ! >Chromium ! ICobalt . !Cooper :Iron ! ;Lead I ! 9.9OOOMaqnenum' ;r.arLQAneBe? !nercurv ;.^JiCKel ; :Fora ••ium!5e i en IJUTI . I 9. 90OOSilver : !sodium i iThallium • t 19.6OOvanadium • I 1O8. 70Zinc ! !C ^ an i d m • _.. i

i ' i

dmmentBi

IE

.t:

Contract:

_. _ SAS No. :

on Units: ug/L

SampleResult <3R>

4. OOOO2. OOOO

2. OOOO

- -2. O.OOO*•

2. OOOO2. OOOO

c

UU

u

u

uu

: Sk-3 ^^

SDG No. i 5Ui-I2

Level (low/med):' ____

•- iSpike i . :

Added (.SA) ; *.R ;c i M

i . i120.0 ! 8.5 ! IF20.0 ! 103.5 : IF •

i i *i i ii i i< < i' i ! •i ii ii ii i

——— i —— •10.0 ; 7^ . i"3 , . r

.... i .• • i -;

; . •

i

10. 0 • 99 , 0 . Fiti

20.0 I 75.0 . r _ _ .100.0 ; 10£. 7 JF .

;l ' i r

tFART 2) - IN

flR30!9U

U.S. EFA - CLF

5B EPA SAMPLE N-j.POST DIGEST SPIKE SAMPLE RECOVERY _____________

Lab Name: NUS CORPORATION_________ Contract:SW-5

Code: NUS__ Case No.: ME___ SAS No.: _____ SDG No.: SW-12.

Matr i x isoi 1 /'water) : WATER Level (low/med) : ____

Concentrat ion Un i ts: ug/L

i ! Control 1t ; Limit i Spiked SamplelAnalyte J XR 1 Result <SSR) Ci • i; Aluminum . I - . !! An 1 1 mon v : ! i 1 S . 50; Arsenic ! . : 22. 100 .. : .! Barium i .' 1I B a r v i I i u m ; • . 1! CactiTi i u.n ! ; :J Calcium 1 .. J.' Lh rcjm i uiti t <JCobalt . " .: !JCoooer : ! i•Iran I _ .! " ITLsaa ; ! 11. 700 ;j Maone" ium ! ! -. Manganese i >. --> ,1 Mercurv ' ' " .. _i .j r-ickei - ) !i Potassium ! . '; S e I en i um i '. 10. 600 iI 5i I vsr J ! .f .... Hod ium J ' !I Thallium i ! 19. 40O . !; Vanadium ' l 94.700 •!; Zinc 1 1 J . . .•C van ids i ! •

• i• - ' ' . , . . , ' • •

Samp 1 eResul t <SR)

i. OCOO2. OOOO

2. 4 OOO

2. OOOO

2 . OOOO2. OOOO

C

UU

B

U

UU

3p ikeAaded (. 5A)

120. O20. 0

1 0 . 0

1 0 . 0

20. 0100. 0

V_R

98.7110.5

93.0

lOo. 0

97. 0?4.7 .

;

"ORM V (PART 2) - IN

U.S. EPA - CLP

5B EPA SAMPLE NO.POST DIGEST SPIKE SAMPLE RECOVERY __________

SW-6.ab Name: NUS CORPORATION_________ Contract:

Lab Cod^s NUS__ Cama No.: ME___ SAS No.s " 3DG No.: SW-12

Matrix (soiI/water): WATER Level (low/med): ____

Concentration Units: UQ/L

1

J An e lyte

3 Aluminuml Antimonyi Arsenic: Barium! Beryl 1 ium! Cadmium! Calcium! ChromiumiCobalt• COD oarI ron

ILaad! Magnesium.Manganese! MercurviNlcKel! Potassium! Sel^n ium* Si Is er! 3oaium! Thai 1 iumJ Vanadium: line: Cyanide,

1 Control !' t_i.nit ' Spiked Sample

7.R ; Resent CSSRJ•

; 112.90J -•- 20. 200i•1Ii;ij: 10.600:j

1 1i: 10.60Oi

i 18.60C3 97.3OOtt:i

cSsinp 1 e

Result CSR)

4. OOOO2. OOOO

"

2 . OOOO

2. OOOO

2. OOOO3. 400O

LJ

Uu

u

u

uB

Sp ikeAdded (5A)

120.020 . 0

1 0 . 0

IO.O

20 . o1OO. 0

1

1

XR :i

94. i ;101.0 i

111t

11J

1

I

1C1 6. 0 ';;j•j

106.0 :;i

93.0 S93.9 1

j*!

' -1 ' M1 J/ i f I !

,F";F~

FORM V ^rART 2) - I,M

U.S. EPA - CLP

5B EPA SAMPLE NO,POST DIGEST SPIKE SAMPLE RECOVERY _____________

! SW-7Lab Name: NUS CORPORATION_________ Contract: _____ I

Lab Code: NUS__ Case No. : ME___ SAS No.: _____ SDG No.: SW-1I

Matrix (soil/water): WATER Level (low/med) : ___

Concentration Uni ts: ug/L

Comments:

111

1

! Analy teiI Aluminum! Ant imonvI Arsenic' BariumI Bervl 1 iumI CadmiumI Ca 1 c i um! Chromiumi Cobalt' CooperIi ron"LeadJ Magnesiumi ManganeseI Mercurv! NickelJ Potassium,' Selenium! Silver! SodiumI Thai 1 ium! VanadiumJ Zinci CvanideiE

ControlLimit7.R

Spiked SampleResult <SSR)

112. 1021.500

9. 1000

10. 100

19.300.96.600

i

CSamp le

Result (SR)

4. OOOO2. OOOO

2. OOOO

2.0000

2. OOOO3. OOOO

t

C

uu

u

u

uB

Spike i :Added (5A) J '/.R id

.120.0_I__93.4.20.0 J 107.5

10.0

10.0 ! 101.0

__20. 0__ I _96. 5.10O.O !_=?3_6

FORM V '.PART 2) - IN

U.S. EPA - CLP


SW—16Lab Name: NUS CORPORATION_________ Contract: __

Lab Codes NUS__ Case No. s ME____ SAS No.: ______ SDG No.: SW-12.

Matrix (soil/water)s WATER Level (low/med)s ____


Comments!

1 1

1 ' Con t r o 1! i LimitlAnalyte ! "/.Ri >1 Aluminum ;.Antimony >SArsenic !! Bar ium .!(Bervl lium Jt Cadmium !! Calcium '! Chromium 1i Cobalt __.._,'ICoDDer !I ran i!Lead I\ Magnesium I! Manganese II Mercury IINickel J! Potassium I! Selenium ;ISllver !1 Sod ium I! Thallium !! Vanadium JIZinc !i Cyanide *t i

Sp iked SampleResult <SSR)

108.9022.300

10.600

i i . 40O

19.30093.40O

CSamp le

Result (SR)

4. OOOO2. OOOO

2.0000

2 . OOOO

2. OOOO2 . OOOO

;

C

uu

u

u

uu

SpikeAdded (SA)

1 20 . 020.0

10.0

10.0

20.01 OO . 0

7.R

90.7111.5

1 06 . O

114.0

9o.593.4

a; M;

!F

IF

;F

FOF.M V <PART 2; - IN

flR3019ii5

U.S. EPA - CLP

6 SPA SAMPLE NO.DUPLICATES ___

I SW-8Name: NUS CORPORATION_________ Contract: _________ I________

Lab Code: NUS__ Case No,: ME__ SAS No.: _._____ SDG No.: SW-12_

Matrix (soil/water): WATER Level (low/med): ____

7. Solids for Samples _0.0 7. Solids for Duplicate: _O.O

Concentration Units <ug/L or mg/ftg dry weight): UG/L_

1t1

! Analyte•iI Aluminum! Antimony! ArsenicJ BariumI Beryllium: Cadmium! Ca 1 c i umI ChromiumiCobaltJ CooperI I ronILead.'Magnesium! ManganeseJ MercuryINickel .! Potassiumi Se 1 en i um! Si 1 ver• SodiumI Thai 1 iumi VanadiumJZincI Cyanide*•

ControlLimit

200 . 0

50.0

40.0

IO.O

SO.O20.0

Sample <3> C

20O. OO ! U4. OOOO !U2. OOOO IU600. OO !4.0000 !U4. OOOO !U2670OO !10. OOOO iU4O.OOO IB1O.OOOO .'U1310.0 :2. OOOO !U467OO !3400. O !0.2000 : u70.000 :61600 !

2. OOOO JU40. OOO .'1 1 OOOO !2. OOOO !U2.90OO ! B30 . ooo :

111.

Duplicate <D)

20O.OO4 .OOOO2. OOOO600.004. OOOO4. OOOO26200010. OOOO40. OOO10.00001240.02. OOOO4660O33OO . 0

_ _ 0,400040. OOO603002.00004O.OOO113OOO2 . OOOO2. OOOO30.000

C

uuuuuuuuu

[J

u

uu

RPD

0 . 0

1.9

200. 0

5.5

0.23.0

54.52. 1

0.0*"• T*i. /

200.00.0

.

• •ii

QJ MiiIAIF!F**-

-•'A:A!A:AI AJA:A:F;A:A;cv;A; AIF: A: A!F;FIA:NR*t

FORM VI - IN 7/S7

flR3QI9i»6

I

U.S. EPA - CLF

7LABORATORY CONTROL SAMPLE

Lab Name: NUS CORPORATION _________ Contract:

Lab Code: NUS__ Case No. s ME___ SAS No. s _____ SDG No.: SW-12_

Solid LCS Sources ___________

Aqueous LCS Source: SPEX STD___

! ; Aqueous ug/L)! Analyte i Tru© Found %R

Solid (mg/kg;True Found C Limits ".R

! Aluminum..! 9970. 0_iAnt imony_J _10070_i Arsenic \ 10OCO _5 Barium __ > _1OO50_J Beryl 1 ium i 999O.O_! Cadmium. IOO4Orcalcium 1O0103h ram i um_ 1 OO90.Cabalt 10O10JCoooer 10OOOI Iran 10O10(Lead 10O20! Magnesium 1O020! Manganese 998O.O! Mercurv 5O.Oi Nickel 1007O1 Pot ass ium 100150J Selenium 1003O{Silver 9950. OJSocium 100OOiThallium 9970. O{Vanadium 10O9OIZinc 10O10! Cyan icei

1O3OO.OO! 103.311000.00! 109.210850.00! 108.39600.001 95.59680. OO! 96.998<i.O.OO«l 98.2I01OO.OO! 100.996OO.OO! J?5. 1__9400.0O!_93.9_9630. OO J 96. 310020. OO! 100. 1_9900. OO! 98. 899OO.OO:_9S.B10000.00! 1OO.2—

52. OOJ 104.09700, OO I 9fi>.3100800.0! 100.610233.33! 102. O_9700. OO! 97.510000.00! 10O.O10220. OO! 102. 5_934O.OO! 92.6970O.OO! 96.9

.>t

I1<t11Itt

111

!titit

iiIii\ii•iiiii\

*iiii*irii; ——< fl

: ^•ii[i:riJ

i;iitiitjI

FuRM VII - IN

U.S. EPA - CLP

10HOLDING TIMES

Lao Name: NUS CORPORATION_________ Contracts

LaD Code: NUS__ Case No. t ME___. SAS No.: _____ SDG No.: SW-12_

EPASample No.

SwJ-1SW-2•3W-33W-4SW-5SW-6SW-7SW-8SW-12SW-135W-14SW-15sW-16

i

,

Matrix

WATERWATER-WATERWATERWATERWATERWATER-WATERWATER-WATERWATERWATERWATER

i4

Date lReceived !

i11/03/88!11/03/33!11/03/83!11/03/88!1 1/04/88 !11/04/88!11/04/68!11/02/88!11/02/88!11/02/88!11/02/88!11/03/83!11/04/83!

iit>i;<iiiiii»i•iii

Mercury ! MercuryPrep !HoldingDate I Time

.i11/16/88! 1311/16/88! 1311/16/881 1311/16/88! 1311/16/88! 1211/16/881 1211/16/88! 1211/16/83! 1411/16/38! 1411/16/88! 1411/16/88! 1411/16/88! 13li/lo/88! 12

iiitiii<ii.tii•.t

iCyan idsPrepData

Cyan ide iHold ingTime

FORM X - IN . 7'S:

AR30!9t_8

U.S. EPA - CLP

11 - AINSTRUMENT DETECTION LIMITS (QUARTERLY)

Lab Name: NUS CORPORATION _________ Contract:

Lab Coaei NUS—— Case No.: ME___ SAS No.: _____ SDG No.: SW-12

ICP ID Number i ___________ Dates ______

Flame AA ID Number i PE603______ Date: 10/05/88

Furnace AA ID Number : PE3030_____ Dates • 09/24/88

Comments:

1ttt

. AnalytetiI Aluminum! AntimonyArsenic

I Bariumi Beryl 1 ium; Cadmium\ Calcium! Chromium! Canal t! Cooo©r* Iron!Leaa. Magnesium! ManganeseI MercuryiNickel! Potassium! Se-leniumISilveri SodiumI Thai HumJ VanadiumSZinci

Wave-length*.nm)

309 , 30217.60193,70553.60234,90228.80422.40357.90240,70324.70248.30

285.20279.50

232 . OO77O, 00196.00328. 10330. 3O

213.90

iiBack-! CRDL

ground ! (ug/L)i! 2OO

BZ _ ! _ 6OBZ ! 10

! 2OO; 5

55000

! 101 50! 25! 1OOti! SO 00! 1 i l *J»i! 4OJ 5000

BZ I 5: 10! 5OOOii1 "?(*»i jiU«

*iti

IDL ;(ug/L) ! M

ii200.0 !A4.0 !F2.0 IF

200.0 !A4.O !A4.0 !A

20O.O !AIO.O ! A

,,„ 40.0 !AIO.O !A30.0_!A

iIO.O JAIO.O iA

i3O.O !A20,0 !A2.0 !F

.^lO.O^SA1OOO.O I A

ii

10.0 !Ai

FORM xl - IN

SR30I9U9

U.S. EPA - CLP

11- BINSTRUMENT DETECTION LIMITS (QUARTERLY)


Lab Code: NUS__ Case No.: ME___ SAS No. s _____ SDG No.: SW-12_

ICP ID Numoer: ___________ Date: ______

Flame AA ID Number : PE50B______ Dates 09/29/88

Furnace AA ID Number : FE23BO_____ Date; 09/23/88

Comments:

!t

1

! AnalyteiJ Aluminum,' Ant imonvi Arsenic1 Bar ium1 Beryl 1 ium! Cadmiumi Calcium! Chromium! Cob alti Copper! I ron; Lead! Magnesium! Manganese! MercuryINickel! Potassiumi Selenium{Silver! Sod i um!Thallium_.' Vanadium..IZincti

wave-lengthtnm)

253.30

253.70

276.80318.40

Back-ground

BD

BD

CRDL(ug/L)

1

5

('i t*1 j . -i

1050

IDL(ug/L)

^ t'\-w • V

0.2

•"" : i'\. . fj

2.O

M

F

CV

FF

FORM XI - IN

I1221 semivolatile qrqanic3 ,s_7t!al calibration data ... 1.06*4' 1.052' g. 573 - -1. 052 9.5 « i...

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Transcript of I1221 semivolatile qrqanic3 ,s_7t!al calibration data ... 1.06*4' 1.052' g. 573 - -1. 052 9.5 « i...