Hazard Communication Alexander Archie Compliance Enforcement Supervisor Chief Engineer's Office...

Hazard CommunicationHazard Communication

Alexander ArchieCompliance Enforcement SupervisorChief Engineer's Office Northern Region5500 Snyder Avenue

Office: (775) 887-3255 Cell: (775) 722-8703

Hazard CommunicationHazard Communication

Keith JaquillardCompliance Enforcement OfficerChief Engineer's Office3955 West Russell Road

Office: (702) 879-1396 Cell: (702) 308-0902

Chemical Safety on the Job

Hazard Communication 29 CFR Hazard Communication 29 CFR 1910.12001910.1200

NDOC Administrative Regulation 443NDOC Administrative Regulation 443

We want you to know how to use them We want you to know how to use them safelysafely

You will learn about…You will learn about… The Hazard Communication StandardThe Hazard Communication Standard NDOC Written ProgramNDOC Written Program LabelingLabeling Material Safety Data SheetsMaterial Safety Data Sheets Spill ResponseSpill Response Who to ask for more informationWho to ask for more information

We use many chemicals…We use many chemicals…

We encounter chemicals almost We encounter chemicals almost every dayevery day Filling your vehicle with gasFilling your vehicle with gas Cleaning the bathroomCleaning the bathroom Applying pesticides or insecticidesApplying pesticides or insecticides Using solvents or acids at workUsing solvents or acids at work

Many chemicals can cause injury or Many chemicals can cause injury or illness if not handled properlyillness if not handled properly

Close Encounters with ChemicalsClose Encounters with Chemicals

OSHA created the Hazard OSHA created the Hazard Communication Standard to help Communication Standard to help ensure safety when working with ensure safety when working with hazardous chemicalshazardous chemicals

You have a RIGHT TO KNOW about You have a RIGHT TO KNOW about the hazardous chemicals you use on the hazardous chemicals you use on the job and how to work safely with the job and how to work safely with those chemicalsthose chemicals

Right to KnowRight to Know

Chemical Manufacturers Must:Chemical Manufacturers Must: Determine a chemical’s hazardsDetermine a chemical’s hazards Provide labels and MSDSsProvide labels and MSDSs

Employers must:Employers must: Provide a hazard communication Provide a hazard communication

programprogram Maintain MSDSsMaintain MSDSs Train on hazardous materialsTrain on hazardous materials

Hazard Communication StandardHazard Communication Standard

Employees must:Employees must: Read labels and MSDSsRead labels and MSDSs Follow employer instructions and Follow employer instructions and

warningswarnings Identify hazards before starting a jobIdentify hazards before starting a job Participate in trainingParticipate in training

Hazard Communication Standard Hazard Communication Standard (cont)(cont)

Hazard Communication Standard Hazard Communication Standard (cont)(cont)

ArticlesArticles FoodFood CosmeticsCosmetics DrugsDrugs

Hazardous Hazardous wastewaste

TobaccoTobacco Wood Wood productsproducts

Consumer Consumer productsproducts

Nuisance Nuisance dustdust

RadiationRadiation Biological Biological hazardshazards

Office & Office & school school

suppliessupplies

What items do (or do not) require What items do (or do not) require MSDS’sMSDS’s

Physical Hazards (external):Physical Hazards (external): FlammableFlammable ExplosiveExplosive ReactiveReactive

Health Hazards (internal):Health Hazards (internal): AcuteAcute ChronicChronic

Chemical HazardsChemical Hazards

DosageDosage Acute effects - immediate health Acute effects - immediate health

effect (irritation, tissue damage, effect (irritation, tissue damage, dizziness, nausea, rashes, or dizziness, nausea, rashes, or respiratory irritation)respiratory irritation)

Chronic effects – exposure over a Chronic effects – exposure over a long period of time (months, years)long period of time (months, years)

Chemical ExposureChemical Exposure

AbsorptionAbsorption

Routes of EntryRoutes of Entry

InhalationInhalation

Ingestion (swallowing)Ingestion (swallowing)

InjectionInjection

Dust mask and respiratorsDust mask and respirators Glasses, goggles, and face shieldsGlasses, goggles, and face shields Hearing protectionHearing protection GlovesGloves Foot protectionFoot protection Head protectionHead protection Aprons or full-body suitsAprons or full-body suits

Personal Protective EquipmentPersonal Protective Equipment

Eyes: Flush with water for 30 minutesEyes: Flush with water for 30 minutes Skin: Wash with soap and waterSkin: Wash with soap and water Inhalation: Move to fresh airInhalation: Move to fresh air Ingestion: Get emergency medical Ingestion: Get emergency medical

assistanceassistance Injection: Get emergency medical Injection: Get emergency medical

assistance / call coronerassistance / call coroner

Hazardous Materials First AidHazardous Materials First Aid

Evacuate the areaEvacuate the area Notify a supervisor or emergency Notify a supervisor or emergency

response teamresponse team Remove ignition sources (if safe to Remove ignition sources (if safe to

do so)do so) Stay awayStay away

Spills and LeaksSpills and Leaks

The identity of the chemicalThe identity of the chemical Name, address, and emergency phone Name, address, and emergency phone

number of manufacturernumber of manufacturer Physical (Flammable) and health Physical (Flammable) and health

hazardshazards Special handling instructionsSpecial handling instructions Basic PPE recommendationsBasic PPE recommendations First aid, fire response, spill cleanupFirst aid, fire response, spill cleanup

Importance of LabelsImportance of Labels

NFPA Labeling SystemNFPA Labeling SystemHealth Hazard

4 Deadly

3 Extreme Danger

2 Hazardous

1 Slightly Hazardous0 Normal Material

Specific Hazard

ACID = acid

ALK = Alkali

COR = Corrosive

W = use no water

Fire Hazard

Flash Points

4 Below 73 F

3 Below 100F

2 Above 100 F not exceeding 200 F

1 Above 200 F

0 Will not Burn

Reactivity

4 May detonate

3 Shock & heat may

Detonate

2 Violent Chemical

Change

1 Unstable, if heatedNFPA 704 System

230

Hazardous Material Information Hazardous Material Information System (HMIS)System (HMIS)

Ethyl Alcohol

HEALTH 2

FLAMABILITY 3

Reactivity 0

Personal Protection B

Other Label WarningsOther Label Warnings

The identity of the chemicalThe identity of the chemical Name, address, and emergency phone Name, address, and emergency phone

number of manufacturernumber of manufacturer Physical (Flammable) and health Physical (Flammable) and health

hazardshazards Special handling instructionsSpecial handling instructions Basic PPE recommendationsBasic PPE recommendations First aid, fire response, spill cleanupFirst aid, fire response, spill cleanup

Read and become familiar with AR 443Read and become familiar with AR 443 Identify chemical hazards by reading Identify chemical hazards by reading

labels and MSDSslabels and MSDSs Follow warnings and instructions, or Follow warnings and instructions, or

ask your supervisor if in doubtask your supervisor if in doubt Practice sensible, safe work habitsPractice sensible, safe work habits Learn emergency proceduresLearn emergency procedures

Hazard Communication SummaryHazard Communication Summary

Section I Manufacturer InformationSection I Manufacturer Information Section II Hazardous Ingredients/Identity Section II Hazardous Ingredients/Identity

InformationInformation Section III Physical /Chemical CharacteristicsSection III Physical /Chemical Characteristics Section IV Fire and Explosion Hazard DataSection IV Fire and Explosion Hazard Data Section V ReactivitySection V Reactivity Section VI Health Hazard DataSection VI Health Hazard Data Section VII Precautions for safe handling and useSection VII Precautions for safe handling and use Section VIII Control MeasuresSection VIII Control Measures

Hazard Communication MSDSHazard Communication MSDS

OSHA Material Safety Data Sheet (Non- Mandatory OSHA Material Safety Data Sheet (Non- Mandatory Form)Form)

1. Chemical manufacturers must label containers and provide? MSDS

2. Employers should keep material safety data sheets in a locked file cabinet? False

3. Dizziness, nausea, rashes, and respiratory irritation are signs of ________ exposure.Chemical

4. List three routes by which a chemical can enter the body.Inhalation, Ingestion, Absorption

5. Household chemicals are never as hazardous as chemicals used at work. False

Hazard Communication SummaryHazard Communication SummaryTestTest

6. On NFPA labels, a 4 in the red diamond indicates an extreme health hazard. False

7. Typical first aid for chemicals splashed in the eyes includes?At least 30 minutes of flushing the eyes with clear water.

8. You will only know the health hazards and PPE requirements if you?Read the MSDS

9. A _________ can be used to protect against breathing hazardous vapors or gases.Face Mask

10. If you see a chemical spill, you should clean it immediately.False

Hazard Communication SummaryHazard Communication SummaryTestTest

Hazard CommunicationHazard CommunicationExample QuestionsExample Questions

RulesRules1. Each question has associated points, 20 questions total.

2. One minute to provide correct answer. Correct answer results in points awarded. Wrong answer, other group will be allowed chance to provide correct answer.

3. First spokesperson to get presenters attention and approval from spokesperson may relay answer.

4. Only spokesperson can relay answer to presenter. Anyone other than spokesperson providing answer will result in loss of points associated with question.


RulesRules5. Group with most points at end wins PRIZE.

6. Tie, presenter will provide final question of choice.


1. One of the ingredients of Ethyl Alcohol is Kerosene. What is Kerosene’s CAS numberSection 2, CAS Number - 8008-20-6

Hazard CommunicationHazard CommunicationQuestionsQuestions

1. What is the flashpoint for Ethyl Alcohol in degrees Fahrenheit? (3 points)Section 5, Flash Point (55 0F)

2. On the MSDS for Ethyl Alcohol, name one other ingredient listed as a component? (2 points)Section 2, Methyl Isobutyl Ketone or Kerosene

3. What is the NFPA health rating for Ethyl Alcohol? (4 points)Section 16, Health 2

4. What is the effective date of the MSDS for Ethyl Alcohol? (1 point)Top of MSDS, Effective Date 07/06/06

5. What first aid measures are to be taken if Ethyl Alcohol is inhaled? (1 point)Section 4, Inhalation


6. What is the NFPA flammability rating for Ethyl Alcohol? (1 point)Section 16, Flammability: 3

7. When shipping Ethyl Alcohol a UN/NA assigned number must be used on the paperwork, what is the UN/NA assigned number? (3 points)Section 14, UN1993

8. Is Ethyl Alcohol stable under ordinary conditions of use and storage? (1 point)Section 10, Stable under ordinary conditions of use and storage.

9 Accidental Release Measures for Ethyl Alcohol is called out in what section of the MSDS? (1 point)Section 6

10. Chronic ethanol exposure may affect the? (5 points)Section 3, central nervous system, liver, blood and reproductive system.


11. Name one of the four routes of entry Ethyl Alcohol could enter the human body? (1 point)Inhalation, Ingestion, injection, absorption (skin contact)

12. What is the name and address of the company that provided the MSDS for Ethyl Alcohol? (2 points)Top of MSDS, Mallinckrodt Baker, Inc. 222 Red School Lane Phillipsburg, NJ 08865

13. Handling and Storage for Ethyl Alcohol is called out in what specific section of the MSDS? (2 points)Section 7

14. Ethyl Alcohol has an autoignition temperature and will self ignite at what temperature in degrees Fahrenheit? (4 points)Section 5, (685 0F)


15. What is the 24 hour emergency number for CHEMTREC as listed on the MSDS for Ethyl Alcohol? (3 points)Top of MSDS, 1-800-424-9300

16. The MSDS lists condition to avoid, what are they? (4 points)Section 10, Heat, flames, ignition sources and incompatibles.

17. The Nevada Department of Corrections Hazard Communication written program is found in Administrative Regulation number? (3 points)443

18. Chemical Manufacturers must label containers and provide a? (1 point)MSDS

19. An employer should keep all MSDS’s in a locked cabinet to keep them secure, true or false? (1 point)

False20. On the MSDS for ethyl alcohol what does PEL and TLV stand

for? (3 points)section 8, Permissible Exposure Limit and Threshold Limit Value

Hazard Communication Alexander Archie Compliance Enforcement Supervisor Chief Engineer's Office...

Documents

Transcript of Hazard Communication Alexander Archie Compliance Enforcement Supervisor Chief Engineer's Office...