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Halogen free flame retardant:

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International Polyolefins Conference 2010: Finding Value in Today's Business Environment2010

Document Type: Conference PaperSource Type: Conference Proceeding

View references (7)

International Polyolefins Conference 2010: Finding Value in Today's Business Environment; Houston, TX;21 February 2010 through 24 February 2010; Code 81272

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A new halogen-freeflameretardanttechnology for polyolefins

Hatanaka, T.a,Kamimoto, T.a,Yamanoi, H.a,

Yukino, T.a,Ishikawa, S.b,Zingde, G.ba

Polymer Additives R and D Laboratory,ADEKA Corporation, 5-2-13 Shirahata,Minami-ku, Saitama-city, Saitama 336-0022, Japanb

Amfine Chemical Corporation, 10Mountainview Road, Upper Saddle River,NJ 07458, United States

AbstractHalogenated compoundsand metal hydroxides are

the most commonly usedflameretardantsystemsfor polyolefins.Halogenated compoundsprovide good flameretardancy, especially in asynergistic combinationwith antimony trioxide.However, this system cancause serious health andenvironmental problemsdue to the evolution ofcorrosive and toxic smokeduring combustion. Metalhydroxides, such asmagnesium hydroxide andalumina trihydrate, areoften used as flameretardantsfor polyolefinsin textiles and wire andcable applications.However, to achieveadequate flameretardancyin polyolefins, a highloading level of metal

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hydroxide is requiredresulting in a significantloss in mechanicalproperties and higherdensity of the finalcomposite. In order toaddress the deficiencies of

the current systems, ahalogen-freeflameretardantsystem "ADKStabilizer FP-2000 series"has been developed forpolyolefins likepolypropylene (PP),polyethylene (PE), and itscopolymers providingexcellent flameretardancy,while maintaining desiredmechanical properties. Inthis study, the performanceof these intumescent flameretardantswas compared

with the conventional flameretardants. It wasobserved that theintumescent flameretardantsgreatly reduced

heat release ratescompared with theconventional ones.Moreover, intumescentflameretardantsshoweda reduction in smokedensity and CO duringcombustion. Overall, theperformance ofintumescent flame

retardantswas superior toconventional flameretardants.

Annual Technical Conference - ANTEC, Conference ProceedingsVolume 2, 2010, Pages 1206-1209

ISBN: 978-161738660-2CODEN: ACPEDDocument Type: Conference PaperSource Type: Conference Proceeding

View references (8)

68th Annual Technical Conference of the Society of Plastics Engineers 2010, ANTEC 2010; Orlando, FL; 16May 2010 through 20 May 2010; Code 81712

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A new family of flameretardantpolymers andadditives

Lebel, M.,Baumann, M.,Blubaugh, C.

FRX Polymers, Chelmsford, MA, UnitedStates

AbstractPolyphosphonates are anew family of polymeric,flame-resistant oligomersand polymers that can beused in demandingapplications both as FRadditives and stand-aloneplastics. Polyphosphonateplastics have the highestLOI of any of the

thermoplastic-processablepolymers. These materialsare inherently flameretardantand can be usedin a broad variety ofpolymer systems, includingthermoplastic andthermosetting. Being bothhalogen-freeandpolymeric,polyphosphonates areunique in the area of flameretardants.

Scholarsportal

Flame retardant polyethylene with intumescent system containing

macromolecule-encapsulated low molecular weight charring agent

Holdings

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Author(s):Liu M(Liu, Meifang),Huang X(Huang, Xing),Liu Y(Liu, Yuan),Wang Q(Wang, Qi)

Source:POLYMERS & POLYMER COMPOSITES Volume:15 Issue:7 Pages:591-596 Published:2007

Times Cited:1 References:23 Citation Map

Abstract:Intumescent flame retardants are important halogen-free products used in polyethylene. However., their

thermal stability and water-resistance are major shortcomings. In this work, a composite charring agent,

pentaerythritol (PER) encapsulated by thermoplastic polyurethane (TPU) was used in an intumescent system to

improve the flame retardancy of high density polyethylene (HDPE). The encapsulation of macromolecular charring

agent TPU can effectively suppress the esterification reaction of PER and acid source in the intumescent system

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during processing. It can also remarkably decrease the water absorption, thus producing flame retardant HDPE with

high performance. The synergistic effects of other common flame retardants including melamine phosphate,

melamine polyphosphate and ammonium polyphosphate with TPU-encapsulated PER, as well as the ratio of charring

agent to acid source were investigated so as to determine the optimum formula for use in HDPE. The flame retardant

HDPE can reach limiting oxygen index of 33 and achieve UL-94 V-0 rating at 3.2 mm thickness when the ratio of

MP/composite charring agent is 2:1 w/w.