Fundamentals and Technology Options for the Anaerobic Treatment of Liquid Wastes

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    FUNDAMENTALS AND TECHNOLOGY

    TREATMENT OF LIQUID WASTES

    E. Ravindranath

    Department of Environmental Technology,

    Central Leather Research Institute

    Chennai 600 020

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    ENERGY

    biogas

    FOOD

    ANAEROBICWASTEWATERTREATMENT

    Industrial, domestic

    SLURRIESsewage slurries

    s pon s

    water forreuse

    ANAEROBICDIGESTION

    qu manure

    SOLID WASTES

    manure (solid)refuse

    TREATMENTMETHODS

    liquideffluents

    water for

    discharge

    STABILIZEDSLUDGETYPES OF BIOMASS

    energy crops

    recovery of

    fertilizers

    NH4+ salts

    PO43- salts

    irrigation,fertilization

    recovery ofelemental

    S

    conditioning

    FOOD RAW MATERIAL

    FOOD

    LIQUID AND SOLID WASTE MANAGEMENT

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    AEROBIC PROCESS

    H2O

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    UNIT OPERATIONS

    a) Physical unit operations

    c) Biological unit operations

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    Typical Flow Diagram of Treatment Plant

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    Biological processes for wastewater treatment

    Aerobic processes

    Sus ended rowth Activated-slud e rocess

    Aerated lagoonsAerobic digestion

    Attached growth Trickling filter

    Rotating biological contractors

    Packed-bed reactors

    Anaerobic processes

    Sus ended rowth Anaerobic contact rocesses

    Attached growth Anaerobic digestion

    bed

    Hybrid Upflow anaerobic sludge blanket

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    Biological treatment systems adopted

    ANAEROBIC

    ep c an Anaerobic lagoon Anaerobic filter UASB

    AEROBIC

    Activated slud e rocess Oxidation ditch Oxidation pond Aerobic lagoon

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    AEROBIC REACTOREnergy

    Escapes

    100 kwh Power

    required

    g

    COD

    10-20 kg

    COD

    20-40 kgSludge

    185 kwhEnergy recovered

    ANAEROBIC REACTOR

    100 kgCOD

    20-30 kgCOD

    5-10 kg

    Sludge

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    ADVANTAGES OF ANAEROBIC

    ow energy cos

    Less bio-mass generation

    Less solid waste to dispose

    Less N&P requirement

    ess space requ re Off-gas air pollution eliminated

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    LAGOON

    LAND AREA REQUIRED IS HIGH

    PERIODICAL CLEANING REQUIRED LESS EFFICIENT

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    Complex organic material

    Acidogenesis

    Fatty acids

    (C>2)

    Acetogenesis

    AcetateH + CO

    Methanogenesis Methanogenesis

    Sulfate

    reductionCH4+CO2 Sulfate

    reduction

    H2S+CO2

    Flow Chart: Anaerobic Digestion of Sulfate Rich Waste

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    HYDROLYSIS

    In the hydrolysis step largeor anic molecules such asproteins, poly-saccharides and

    fats are de raded into smalland soluble componentssu ars amino-acids fatt

    acids) by enzymes excreted byfermentative bacteria.

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    compounds are converted into a-,

    compounds: volatile fatty acids, ,

    butyric acid, etc., alcohols,

    , , , ,NH3. New biomass is also formed.

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    Products of the acidification step can

    be converted into acetate, H2 and CO2by acetogenic bacteria. New biomass ism w . n n

    rates applied in the treatment of

    concentrations of the products ofacidogenesis and acetogenesis are only

    present in very low concentrations.

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    METHANOGENESIS

    decomposition, the products of the, 2

    and CO2, formic acid and methanol

    CO2 as well as new biomass. In

    -takes place.

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    ATTACHED GROWTH ANAEROBICREACTOR

    Upflow contact filter

    Fluidized Bed Reactor

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    Anaerobic Lagoon

    Up flow Anaerobic Sludge Blanket

    UASB

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    DEVELOPMENT OF ANAERPIC REACTORS

    1. Septic Tank

    2. Imhoff Tank

    3. Single stage anaerobic reactors

    .

    5. Anaerobic Fluidized Bed Reactor

    6. Upflow Anaerobic Sludge Blanket

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    O U T L E T C H A M B E R

    O U T L E T P I P E

    I N L E T C H A M B E R

    C O V E R S L A B W I T H M A N H O L E

    I N L E T P I P E

    F I G 1 S E P T I C T A N K

    I N L E T P I P E

    F I G 2 I M H O F F T A N K

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    F I G 3 A N A E R O B I C F I L T E R S

    B I O F I L M / M E D I AS E P A R A T O R

    B I O P A R T I C L E

    F I G 4 A N A E R O B I C F L U I D I Z E D B E D R E A C T O R

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    F IG 5 U P F L O W A N A E R O B I C S L U D G E B L A N K E T

    F IG 6 G L S S E P A R A T O R

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    UASB

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    UASB REACTOR

    LD in UASB Reactor 5 5.5 m -

    Sludge Production COD x 0.75x 0.08

    rgan c oa ng ra e . - g m ay

    Biogas yield 0.20 0.25 m3/kg of

    COD removed Hood width 0.45m

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    REACTOR

    Flow 10MLD .

    COD Conc. 700 mg/L

    oa g ay

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    REACTOR VOLUME BASED

    ON ORGANIC LOADING

    Vol. of Reactor :

    ------------------------------------3

    ------- = 4666 m3

    1.5

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    REACTOR VOLUME BASED

    ON HYDRAULIC RETENTION

    Vol. of Reactor :

    ow x

    x x

    ----------------

    24= 4166 m3

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    REACTOR

    Area of the reactor:

    Volume

    ----------Height

    = 933 m2

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    THE REACTOR

    Area of the reactor:

    Area 933

    ---------- = ------Width 16

    Length = 58 m

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    NUMBER OF REACTORS

    Assuming 1:2 ratio Divide the length of the

    eac or n o wo

    Fix the length of the reactor as 32 m The length of the reactor may be in the

    multiples of four

    Size of each reactor: 3

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    Design of GLS separator

    Assume 4 m centre to centre gas dome

    Assume 18% aperture length

    Width of the Gas collector: 4 x 0.82 = 3.28 m Angle of Gas dome: 450

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    Design of GLS separator

    Overlap 0.15 mm

    Width of Gas Dome: 0.45 m

    Length of projection: 1.41 m

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    FEED INLET ARRANGEMENTS

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    FEED INLET POINT & DEFLECTOR BEAM

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    RC

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    WATERRECOVERY

    NOTCONSIDERED

    1. CONVENTIONAL LAGOON SYSTEM

    IS CONSIDERED

    IFI

    2. FULLY AEROBIC SYSTEM

    DISPOSED

    3. COMBINED TREATMENT WITH UASBPST : PRIMARY SETTLING TANK

    SST : SECONDARY SETTLING TANK(PROPOSED FOR CETP

    AT PERUNDURAI)

    :

    SDWS : SLUDGE DEWATERING SYSTEM

    SEP : SOLAR EVAPORATION PANS

    (FOR WATERRECOVERY)

    TAN NERY EFFLUENT T REATM ENT SYSTEMS

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    CLRI, CHENNAI , INDIA

    FLOW DIAGRAM OF PIL OT SCALE SULFUR RECOVERY UNIT

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    SULPHUR RECOVERY UNIT

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    Post Aerobic Treatment is required(one day polishing pond for sewage).

    T m lif rm l v l in h reffluent maturation pond or chemicalr m n i r ir .

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    THANK YOU