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Environmental Services———SAMPLE ANALYSIS REPORT

WESTTNGHOUSE PLANT SUPERFUND SITECUMBERLAND TOWNSHIP, ADAMS COUNTY,

PENNSYLVANIA

Contract No: 68-W9-0005 (IES Vttl)Work Assignment No: C03018

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SAMPLE ANALYSIS REPORTWESTINGHOUSE ELEVATOR PLANT SUPERFUND SITE

CUMBERLAND TOWNSHIP, ADAMS COUNTY, PENNSYLVANIA

Contract No. 68-W94005 (IES VUL)Work Assignment No. C03018

Project No. P021-C01

Prepared ForMr. Frank Vavra

U.S. Environmental Protection Agency, Region841 Chestnut Street

Philadelphia, Pennsylvania 19107April 3, 1992

Prepared By:Dynamac Corporation

53 Darby RoadPaoli, Pennsylvania 19301

Written By: Reviewed By:

h/Cad Rodzewich Kirk McCutcheonProject Manager . Manager Geosciences Department

Sample Analysis ReportWestinghouse Superfund Site

Revision No. 1

TABLE OF CONTENTS

1.0 INTRODUCTION .......................................... 11.1 Facility Description ...................................... 1

2.0 SAMPLING ASSIGNMENT ................................... 32.1 Sampling Activities ....................................... 32.2 Sample Analysis Results ................................... 5

3.0 OBSERVATIONS .......................................... 73.1 South and North Avenues Areas ............................... 73.2 Mundy Residence ........................................ 73.3 Table Rock Road Area, South of Cedar Avenue ..................... 8

U.S. Environmental Protection Agency Dynamic CorporationRegion m April 8, 1992

AR30U969

Sample Analysis ReportWestinghouse Superftind Site

Revision No. 1

LIST OF FIGURES

Figure No. Pagq

1.0 Site Location ....................................... 2

2.0 Residential Wefl Locations ............................... 4

3.0 Detected Compounds in Residential Wells ..................... 6

U.S. Environmental Protection Agency Dynamac CorporationRegion HI April 3,1992

HR30«i97fl


Revision No. 1

LKTOF TABLES

Table No. Page

1.0 Sample Information ................................... 9

2.0 Sample Results of Compounds of Interest..................... 10

U.S. Environmental Protection Agency Dynamac CorporationRegion in April 8,1992

_x

A830l<97!


Revision No. 1

LIST OF ATTACHMENTS

A. LOCKHEED DATA VALIDATION PACKAGE

B. DRINKING WATER STANDARDS AND HEALTH ADVISORIES

U.S. Environmental Protection Agency Dynamac CorporationRegion in April 3,1992

iv


Revision No. 1

1.0 INTRODUCTION

Dynamac Corporation (Dynamac) received Work Assignment (WA) No. C03018 from the U.S.Environmental Protection Agency (EPA) Region ffl, under contract No. 68-W9-0005 (TESVm), to provide compliance oversight of Potentially Responsible Parties (PRPs) during a PRP-lead Remedial Investigation/Feasibility Study (RI/FS) at the Westinghouse Elevator PlantSuperfund Site (the Site) located in Cumberland Township, Adams County, Pennsylvania. PaulC. Rizzo (PCR) has been contracted by the PRP to conduct the RI/FS. As part of the WorkAssignment, Dynamac was tasked by EPA to collect additional residential well water samplesfrom specific off-site locations.

1.1 Facility Description

The Site is located 1.5 miles northeast of Gettysburg in Cumberland Township, Adams County,Pennsylvania (Figure 1.0). The Site occupies approximately 90 acres and is located alongBiglerville Road (Route 34). The facility is drained by two intermittent tributaries of RockCreek that flow from the northern and eastern sides of the Site.

Prior to its current use the property was cultivated farmland. In 1968, the Westinghouse Plantwas constructed for the manufactering of elevator and escalator components. In its operations,primarily parts degreasing, the plant used trichloroethene from 1968 to 1975 after which theplant switched to 1,1,1-trichloroethane.

In response to complaints by local residents, the Pennsylvania Department of EnvironmentalResources (PADER), in 1983, obtained groundwater samples from the on-Site irrigation welland from nearby residential wells for possible laboratory analysis. The chemical analysis ofthese samples indicated the presence of volatile organic compounds (VOC's). Furtherinvestgations by PADER were conducted resulting the removal of some contaminated on-Sitesoils and the installation of an on-Site groundwater air stripping unit. In March 1987,Westinghouse and the U.S. EPA entered into a Consent Agreement to perform a RemedialInvestigation/Feasibility Study of the Site.

U.S. Environmental Protection Agency Dynamac CorporationRegion ffi April 8,1992

WESTINGHOUSE PLANT

U.S.O.3 TOPOGRAPHIC MAP- 7.1 UMJTISERIES

QETTYSBURO, PA. QUAORANQLI

SCALE: 1:24,000DYWAIV1AG FIGURE 1.0

SITE LOCATIONWESTINGHOUSE SUPERFUND SITE

GETTYSBURG, PA.

CGRPOnATOVJEnvironmental530artyRoad Padi.PA 19301


Revision No. 1

2.0 SAMPLING ASSIGNMENT

On October 7,1991, Dynamac, as requested by EPA WAM Mr. Frank Vavra, submitted a draftStatement of Work for the sampling of targeted residential wells hi the vicinity of the Site. Thetargeted off-site residential wells are located to the north along Biglerville Road between SouthAvenue and North Avenue, to the east on Boyd's School Road, and to the southeast along TableRock Road (Figure 2.0). Dynamac was to locate wells within each of these targeted areas thatmet specific criteria and that were accessible for sampling. The criteria for the Table Rock Roadarea was to identify two wells that exhibited the highest concentrations of VOC's during pastsampling events. The criteria for the Boyd's School Road area was to identify a shallow well(less than 75 feet) that exhibited past high concentration of VOCs, and the criteria for the Northand South Avenue, area was to identify two previously unsampled wells as near as possible tothe intersection of Biglersville Rd. and South Ave.

The samples were to be analyzed by a CLP laboratory for volatile organics. Special AnalyticalServices (SAS) were requested for these samples in order to secure an analytical method (EPAmethod 524.2) with the lowest available detection limits.

2.1 Sampling Activities

On October 17,1991, Dynamac personnel, Carl Rodzewich and David Schock, conducted a sitereconnaissance/homewell survey of the targeted off-site residential areas. In each areahomeowners were interviewed concerning well specifications (i.e. depth, casing, treatmentsystems, etc.). The interviews provided minimal information; however, Dynamac obtainedpermission to sample each well at a future date. In the Table Rock Road area two residenceswere chosen, the Wormsley residence and the Botterbusch residence. In the Boyd's School Roadarea a homewell located at the Mundy residence was selected. In the North and South Avenuearea, the Sword and Stauton residences were selected. The locations of these selected residentialwells are indicated on Figure 2.0. All of the selected residential wells met the previouslyidentified screening criteria.

On October 29, 1991 Dynamac personnel, Carl Rodzewich and Tom Greenman began thesampling event southeast of the site on Table Rock Road at the Wormsley residence, thenproceeded north to the Botterbusch residence, where the matrix spike sample was collected.Dynamac personnel proceeded to the Mundy residence where duplicate samples were collected.

U.S. Environmental Protection Agency Dynamac CorporationRegion E April 8, 1992

$8301*975

A83QI*976


Revision No. 1

Samples were then collected at the Stauton and Sword residences, respectively. The sampleswere collected from outside spigots, with the exception of the Stauton residence which wascollected from the kitchen faucet. According to each property owner, no filter or treatmentsystems are connected to the well. Prior to sampling, the water was permitted to flow for aminimum of 10 minutes in order to flush the plumbing systems and to obtain a morerepresentative sample of the groundwater. In addition to residential well samples, Dynamacobtained a trip blank for QA/QC.

Upon completion of the sampling assignment on October 29,1991, a total of seven samples werecollected. The seven samples consisted of four residential well samples and three QA/QCsamples (trip blank, sample duplicate, and matrix spike/matrix spike duplicate). Dynamacobtained the residential well samples from the above locations without deviations from thestatement of work. The samples were labeled and packaged according to CLP protocol andshipped by Federal Express to the Southwest Research Institute (SWRI) laboratory, located inSan Antonio texas, for analysis. Figure 2.0 exhibits sample locations and Table 1.0 presentssample log information.

2.2 Sample Analysis Results

The samples were received by SWRI on October 30,1991. SWRI began sample analysis of allsamples on November 8, 1991, with the exception of the dilution samples for 03-HW-01 and03-HW-02 which were analyzed on November 11, 1991. As per CLP protocol, subsequent toanalysis the laboratory submitted the analytical data package for data validation. The datapackage was submitted to Lockheed Engineering and Sciences Company (Lockheed) ofAnnapolis, Maryland. A preliminary review of the Lockheed data summary forms indicates thatthe following compounds were detected: 1,1-dichloroethene (1,1-DCE) (Sample No. 03-HW-01/02), 1,1-dichloroethane (1,1-DCA) (Sample Nos. 03-HW-01/02 and 02-HW-01), 1,1,1-trichloroethane (TCA) (Sample Nos. Ol-HW-01 and 03-HW-01/02), trichloroethene (TCE)(Sample Nos. Ol-HW-01 and 03-HW-01/02), and tetrachloroethane (PCE) (Sample No. Ol-HW-01). Figure 3.0 indicates the concentrations of detected contaminants and in which wells theywere detected. It should be noted that the target compounds were not detected above currentfederal Maximum Contaminant Levels (MCL), as listed in the Drinking Water Standards andHealth Advisories, dated April 1990. The data validation package submitted by Lockheed isincluded as Attachment 1, and is referenced herein for validation summation.

U.S. Environmental Protection Agency Dynamac CorporationRegion ffl April 8, 1992

AR3014977

aB30i»978


Revision No. 1

3.0 OBSERVATIONS

Based on the laboratory results for the groundwater samples collected by Dynamac and onsimilar samples collected between 1983 and 1986 by the Pennsylvania Department ofEnvironmental Resources (PADER), observations were made for each area sampled. Theseobservations are summarized below.

3.1 South and North Avenues Area

The laboratory results for groundwater samples obtained from the Sword and Stauton residencessuggest that the groundwater in the vicinity of North and South Avenues, north of the Site, todate has not been affected. These results appear to be consistent with previous (PADER; 1983through 1986) groundwater sampling data collected from other wells north of the Site, asindicated on Figures 1-8 through 1-11 of the June 1989 PCR Phase 1 RI/FS report (PCR report),and with the assertion that overall groundwater flow direction is to the southeast.

3.2 Mundy Residence

The laboratory results for the groundwater samples collected from the Mundy residence wellindicate that contamination by ICE and TCA is still present. Prior to Dynamac's samplingevent, the Mundy residence was sampled twice the PADER, in November/December 1983 andhi February/March 1984. The laboratory results from these previous sampling events indicateda decrease in contaminant concentrations during the three month time period. The laboratoryresults for samples obtained by Dynamac indicate the same decreasing levels for TCA; however,a very slight increase in TCE was observed. In addition to TCE and TCA, trace amounts of1,1-DCEand 1,1-DCA were detected in the Dynamac samples. Section 1.4.3 of the PCR reportdoes not discuss the presence, or absence, of these compounds in any of the residential wells;therefore, no comparison can be made between Dynamac and previous sample data. However,the PCR report does state that these compounds were detected in on-Site weU samples indicatingthe Site as a probable source. It should be noted, however, that TCE can breakdown and formone or both of these compounds. The laboratory results for PADER and Dynamac samplingevents are tabulated in Table 2.0.

U.S. Environmental Protection Agency Dynamac CorporationRegion HI April 8, 1992


Revision No. 1

3.3 Table Rock Road Area, South of Cedar Avenue

The laboratory results for samples collected from the Wormsley well indicated the presence ofTCA, TCE, and tetrachloroethane. The results for samples collected from the Botterbusch wellindicated the presence of 1,1-dichIoroethane. According to PCR's Phase I report, PADERsampled these wells in May/June 1986, and the laboratory results indicated the presence of TCEin the Wormsley well and TCA in the Botterbusch well. The recent sample analysis resultssuggest a decrease in the levels of TCE and TCA in the vicinity of Table Rock Road and CedarAvenue. As there is no previous data on 1,1-DCA or PCE concentrations in this area, nocomparisons can be made.

U.S. Environmental Protection Agency . Dynamac CorporationRegion ffl April 3,1992

8830** 9 80

TABLES

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ATTACHMENT A

UNITED STATES ENVIRONMENTAL PROTECTION AGENCYREGION ill

CENTRAL REGIONAL LABORATORY839 BESTGATE ROAD

ANNAPOLIS. MARYLAND 21401(301) 266-9180

DATE : February 7, 1992

SUBJECT : Region III Data QA Review

FROM : Theresa A.Region III ESAT DPO (3ES23)

TO : Frank VavraRegional Project Manager (3HW23)

Attached is the organic data review for the Westinghouse Electric Site (SAS6701C) completed by the Region III Environmental Services Assistance Team(ESAT) contractor under the direction of Region III ESD.

If you have any questions regarding this review, please call me.

Attachment

cc: Carl Rodzewich, TES VIII DynamacEdward Kantor, EMSL-LVRegional CLP TPO: Raymond Flores Region: VI Lab Code: SWRI

TID File: 03911018 Task 1130

revised 03/91

AR3QI*985

Environmtntal Services Assistance TeamsRegion 31 41 9 Forest Onve. Suite '04Anna polis. Mary land 21403

DATE: February 5, 1992

SUBJECT: Organic Data Validation for SAS 6701HQSite: Westinghouse, PA

i «FROM: Kenneth Curry iO/"' Mahboobeh Mecanic>x-\Organic Data Reviewer Senior Oversight Chemist

TO: Terry SimpsonESAT Regional Project Officer

THRU: JulieESAT- Assistant Team Manager

OVERVIBW

SAS 6701HQ consisted of seven (7) aqueous samples submitted toSWRI for low level volatile analyses. The case included one (1)trip blank. The samples were analyzed as a Contract LaboratoryProgram (CLP) Special Analytical Service (SAS) .

SUMMARY

All samples were successfully analyzed for all target compoundswith the exception of chloroethane. All other instrument andmethod sensitivities were according to the Contract LaboratoryProgram (CLP) Special Analytical Service (SAS) protocol.

MAJOR PROBLEM

o Chloroethane failed minimum Relative Response Factor (RRF)precision criteria in the initial calibration. Thequantitation limits were qualified "R" for all samples. (SeeTable I in Appendix F . )

MINOR PROBLEM

o Br omomethane , chloroethane, acetone, 2-butanone, and trans-1,2-dichloroethene failed precision criteria in the initialand/or continuing calibrations. The quantitation limits werequalified MUJ", except when superseded by the "R" qualifier,and positive results were qualified "J", except whensuperseded by the "B" qualifier, for those compounds in theaffected samples. (See Table I in Appendix F.)

SR3QU986

of 3

NOTES

o The maximum concentration of all compounds found in theanalyses of the trip or laboratory method blanks are listedbelow. Samples with concentrations of common laboratorycontaminants less than ten times (<10X) the blankconcentration, or with concentrations of other contaminantsless than five times (<5X) the blank concentrations, have beenqualified "B" on the data summary forms.

Compound . Concentration fucr/L)

chloromethane 2acetone* 4 Jcarbon disulfide 0.7 Jchloroform 2

* Common Laboratory Contaminant

o The analyses of samples 6701HQ-03 and 6701HQ-04 were performedas dilution in order to achieve accurate results fortrichloroethene, which exceeded the linear calibration range.The results of the diluted analysis for this compound are'reported on the Data Summary Forms.

o Methylene chloride was reported in samples 6701HQ-03DL and6701HQ-04DL at concentrations of 25 J and 6 J ug/L,respectively. No methylene chloride was reported in theundiluted samples. This may be indicative of a laboratoryproblem in the dilution process since methylene chloride is acommon laboratory contaminant.

o No Tentatively Identified Compounds (TIC's) were reported.The form I VOA-TIC's are included in Appendix D.

All data for SAS 6701HQ were reviewed in accordance with theFunctional Guidelines for Evaluating Organic Analyses withModification for use within Region III. The text of the reportaddresses only those problems affecting usability.

AR30i*987

of 3

ATTACHMENTS

1) Appendix A - Glossary of Data Qualifiers2) Appendix 3 - Data Summary. These include:

(a) All positive results for target compoundswith qualifier codes where applicable.

(b) All unusable detection limits (qualified "R").3) Appendix C - Results as Reported by the Laboratory for All

Target Compounds4) Appendix D - Reviewed and Accepted Tentatively Identified

Compounds4) Appendix. E - Organic Regional Data Assessment Summary5) Appendix E - Support Documentation

DCN:KC202A01.WES

Appendix A

Glossary of Data Qualifiers

GLOSSARY 0? DATA QUALIFIER CODES (ORGANIC)

CODES R5T-ATT.NG TO IDENTTTTCATION(confidence concerning presence or absence of compounds)

U = Nor dataczad. The associated number indicatesapproximate sample concentration necessary to bedatactad .

NO CODE =• Confirmed identification.

3 = Not da-actad substantially abova the level raporzadin iaiorazory or field blanks.

R » Unreliable result . Ar.alyta may or may not bepraser.t in -na saapla. Supporting cata necessary

N » Tanativa icer.rif ication. Consider prasant.Special ma^hcds may be neacad to confirm itsprasar.ca or absar.ca in future sampling efforts.

CODES P.ELATE3 TO QL'.--NTTrTATICN(can be usac fcr boch positive rasulrs and samplecuantitaticn Units) :

J = Analyta prasant. Raporcad value may not beaccurate or pracisa.

K = Analyta present. Reported valua may be biasedhigh. Actual valua is axpeczad to be lower.

L » Analyza present. Reported value may be biased low.Actual valua is expected to be higher.

UJ = Not datactad, quantitation limit may be inaccurateor imprecise.

UL =* Not datactad, quantitation liait is probablyhigher.

OTHER COOES

Q =» No analytical result.

Appendix B

Data Summary Forms

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Appendix C

Results as Reported by the Laboratoryfor all Target Compounds

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g U « UVOLATILE ORGASlCb «ulALYSZS DATA SHEET

Lab Name: SWRI Contract: 68-D9-01356701HQ-01

Code: SWRI Case No.: 17359 SAS: 6701HQ SDG No.: 6701HQ-01trix: (soil/water) WATER Lab Sample ID: 6701HQ-01

'""urge Volume: 5.000 (g/mL) ML Lab File ID: G110805

T,evel: (low/med) LOW Date Received: 10/30/91Moisture: not dec. 100. Date Analyzed: ll/ 8/91

Column: (pack/cap) CAP Dilution Factor: 1.00CONCENTRATION UNITS:

CAS NO. COMPOUND (ug/L or ug/Kg) UG/L Q

74-87-3 ——74-83-9 ——75-01-4 ——75-00-3 ——75-09-2 ——67-64-1 ——75-15-0 ——75-35-4 ——75-34-3 ——156-59-4 ——156-60-5 ——67-66-3 ——107-06-2 ——

74-97-5 ——71-55-6 ——56-23-5 ——75-27-4 ——

10061-01-5 ——79-01-6 ——

79-00-5 ——71-43-2 ——

10061-02-6 ——75-25-2 ——108-10-1 ——C Q 1 _TQ_C___

127-18-4 ——79-34-5 ——106-93-4 ——

100-41-4 ——100-42-5 ——1330-20-7 ——541-73-1 ——106-46-7 ——95-50-1 ——

V*-fl Li%Ji^^JPUi X£u%£v£ft3 D O \lf MfT1 W X WT7OAwfTwfUvi JL C«**i&T7THTVT f* 12 T OPTT^P

——— CHLORGETEAKE ,

——— CARBON DISULTIDE

——— 1, 1-DICELOROETHANE/^TC i *} T^ u r op^yr*tgg>Tp

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——— 3ROMODICELOROMETEANE

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FORM I VOA 6/91 Rev.

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LA 001 08A9SAMPLE NO.VOLATILE ORGANICS ANALYSIS DATA SEEET _________

Lab Name: SWRI Contract: S3-D9-01356701HQ-02

T»ab Code: SWRI Case No.: 17359 SAS: 6701EQ SDG No.: 6701EQ-01Matrix: (soil/water) WATER Lab Sample ID: 6701BQ-02

Pnrge Volume: 5.000 (g/mL) ML Lab File ID: G110806

Oevel: (low/med) LOW Data Received: 10/30/91% Moisture: not dec. 100. Data Analyzed: 117 3/91

Zolumn: (pack/cap) CAP Dilution Factor: 1.00CONCENTRATION UNITS:


74-87-3——————CHLOROMETBANE _______74-33-9—————3ROMOMETEANE________75-01-4—————VINYL CELORIDE_______75-00-3——————CHLOROETHANE-________75-09-2—————METHYLENE CHLORIDE___67-64-1—————^ACETONE ____________75-15-0——————CARBON DISULFIDE_____75-35-4 —————— 1,1-DICHLOROETHENE___75-34-3 —————— 1,1-DICHLOROETHANE___156-59-4—————CIS-1,2-DICHLOROETHENE _156-60-5—————TRANS-1,2-DICHLOROETHENES7-65-3—————CHLOROFORM_______107-06-2—————1,2-DICHLOROETHANE78-93-3—————2-3UTANONE_________74-97-5——————3ROMOC3LOROMETHANE __71-55-6——————1,1,1-TRICHLOROETHANE56-23-5——————CARBON TETRACHLORIDEj75-27-4——————3ROMODICHLOROMETHANE_78-37-5—————1,2-DICHLOROPROPANE

10061-01-5——————CIS-1,3-DICHLOROPROPENE79-01-6—————TRICHLOROETHENE ____124-48-1——————DI3ROMOCHLOROMETHANE_79-00-5——————1,1,2-TRICHLOROETHANE71-43-2——————3ENZENE ____________

10061-02-6——————TRANS-1,3-DICHLOROPROPENE _75-25-2——————3ROMOFORM _________108-10-1——————4-METHYL-2-PENTANONE591-78-6—————2-HEXANONE________'_127-18-4 —————TETRACHLOROETHENE79-34-5—————1,1,2,2-TETRACHLOROETBANE _106-93-4—————1,2-DIBROMOETHANE_________108-83-3—————TOLUENE ________________108-90-7——————CHLOROBENZENE ____________100-41-4——————ETHYLBENZENE______________100-42-5——————STYRENE _________________1330-20-7——————XYLENE (TOTAL)____________541-73-1——————1,3-DICHLOROBENZENE________106-46-7 —————— 1,4-DICHLOROBENZENE________95-50-1——————1,2-DICHLOROBENZENE________96-12-8——————l,2-DIBROMO-3-CHLOROPROPANE_

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FORM I VGA 6/91 Rev,

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1A 0010 (£S 3SAMPL2 NO.VOLATILE ORGANICS ANALYSIS DATA SHEET ________

Lah Name: SWRI Contract: 6,8-09-01356701HQ-03 j

ab Code: SWRI Case No.: 17359 SAS: 6701HQ SDG No.: 6701EQ-01atrix: (soil/water) WATER Lab Sample ID: 6701EQ-03

Sample wt/vol: 5.000 (g/mL) ML Lab File ID: G110802

Level: (low/med) LOW Date Received: 10/30/91% Moisture: not dec. 100. .Date Analyzed: ll/ 8/91



74-87-3——————CHLOROMETEANE74-83-9——————BROMOMETEANE_'_75-01-4——————VINYL CHLORIDE75-00-3—————CELOROETEANE,. "75-09-2——————METEYLENE CHLORIDE___67-64-1——————ACETONE _____________75-15-0——————CARBON DISULFIDE_____75-35-4 —————— 1,1-DICHLOROETHENE___75-34-3 —————— 1,1-DICHLOROETHANE___156-59-4——————CIS-1,2-DICHLOROETHENE _156-60-5——————THANS-1,2-DICELOROETHENE67-66-3—————CHLOROFORM_______107-06-2——————1,2-DICHLOROETEANE78-93-3—————2-BUTANONE_________74-97-5——————BROMCCHLORCMETHANE __71-55-6——————1,1,1-TRICHLOROETHANE56-23-5——————CARBON TETRACHLORIDE_J75-27-4——————3ROMODICHLOROMETEANE_78-87-5 —————— 1,2-DICHLOROPROPANE

10061-01-5——————CIS-1,3-DICHLOROPROFENE79-01-6——————TRICHLOROETHENE124-48-1——————DIBROMOCHLOROMETEANE_79-00-5——————1,1,2-TRICELOROETHANE71-43-2—————BENZENE ___________

10061-02-6——————TRANS-1,3-DICELOROPROPENE _75-25-2——————BROMOFORM ________________108-10-1——————4-METHYL-2-PENTANONE_______591-78-6——————2-EEXANONE________________127-18-4——————TETRACHLOROETHENE ________79-34-5 —————— 1,1,2,2-TETPACELOROETHANE _106-93-4 —————— 1,2-DIBROMOETEANE_________108-88-3——————TOLUENE _________________108-90-7——————CELOROBENZENE ____________100-41-4-—————ETHYLBENZENE______________100-42-5——————STYRENE _________________1330-20-7——————XYLENE (TOTAL)_____541-73-1 —————— 1,3-DICHLOROBENZENE_______106-46-7——————1,4-DICHLOROBENZENE_______95-50-1——————1,2-DICELOROBENZENE96-12-8 —————— l,2-DIBROMO-3-CELOROPROPANE

1- !1. JU1. JUl. |u2. JU6. j B1. JU4. !l. !1. ju1. JU0.9 j J1. JU5. JU1. JU4. I1. JU1. JU1. JU1. JU

86. j E1. JU1. JU1. JU1. JU1. JU5. JU5. JU1. JU1. JU1. JU1. {U1. JU1. JU1. JU1. JU1. JU1. JU1. JU1. ju •


1A EPA SAMPLE NO.VOLATILE ORGANICS ANALYSIS DATA SHEET _______

Lab Name: SWRI Contract: 63-D9-01356701HQ-03DL

Lab Code: SWRI Case No.: 17359 SAS: 6701HQ SDG No.: 6701HQ-01Matrix: (soil/water) WATER Lab Sample ID: 6701HQ-03DL

Sample wt/vol: 5.000 (g/mL) ML Lab Pile ID: G111102

Level: (low/aied) LOW Date Received: 10/30/91% Moistura: not dec. 100. Data Analyzed: 11/11/91

Column: (pack/cao) CAP Dilution Factor: 50.00CONCENTRATION UNITS:

CAS NO. COMPOUND (ug/L or ug/Xg) UG/L Q

74-37-3—————CHLOROMSTHANS ______74-83-9————-3ROMOM3THANE________75-01-4—————VINYL CHLORIDE______75-00-3—————CHLOROETHANE________75-09-2—————M2THYLENE CHLORIDE___67-64-1—————ACETONE ____________75-15-0—————CARBON DISULJIDE_____75-35-4 ————— 1,1-DICHLCRCETH2NE___75-34-3—————1,1-DICELOROETHANE___136-59-4——————CIS-1, 2-DICHLOROETHENE156-60-5—————TRANS-1,2-DICHLOROSTHENS67-66-3—————CHLOROFORM ___107-06-2—————1,2-DICHLOROETHANS__78-93-3—————2-3UTANONE_________74-97-5——————3ROMOCHLORCMETHANS __71-55-6—————1,1,1-TRICHLOROETEANE56-23-5—————CARBON TETRACHLORIDSj75-27-4——————3ROMODIC3LOROMETHANS_78-87-5—————1,2-DICHLOROPROPANE

10061-01-5—————CIS-1,3-DICHLOROPROPENE79-01-6—————TRICHLOROBTH2NE ____124-43-1———— DI3ROMOCHLOROMETHANE__79-00-5—————1,1,2-TRICHLOROETHANE71-43-2—————3EN22N2 ________

10061-02-6—————TRANS-1,3-DICHLOROPROPENE _75-25-2—————3ROMOFORM _______________108-10-1—————4-METHYL-2-PENTANCNE______591-78-6—————2-H3XANONE127-18-4—————TSTRACHLOROETH2N2 ________79-34-3—————1,1,2,2-TETRACHLOROETHAN2 _106-93-4—————1,2-DI3ROMOETHANS_________103-33-3—————TOLUENE ________________103-90-7—————CHLOR03ENZBNE ___________100-41-4—————3THYLBENZENE_____________100-42-3—————STYREN3 ________________1330-20-7—————XYL2NE (TOTAL)___________541-73-1—————1,3-DICHLOROBSNZENS_______106-46-7——————1,4-DICHLOROBSN2ENS________95-30-1—————1,2-DICHLOROBENZHNE.

50. JU30. JU50. ,'U50. 'U25. j J

350. j 350. JU50. ,'U50. [U50. ,'U50.' JU50. JU50. JU250. JU50. |U50. JU50. JU30. JU50. JU50. JU100. j50. JU50. JU50. }U30. JU50. JU230. JU250. ,'U50. JU50. |U50. JU50. |U50. JU50. JU30. JU50. JU50. JU50. JU

_______ 50. JU96-12-3—————l,2-DI3ROMO-3-CHLOROPROPANE_j 50. JU

FORM I VOA ft p Q H h QQ^91 R«v.

OOCT>cnfOCOcc.

Lab Name: SWRI Contract: 68-D9-0135

VOLATILE ORGANICS ANALYSIS DATA SHEET ___________

6701HQ-04

Lab Code: SWRI Case No.:17359 SAS: 670lS(f1''- SDG No.: 6701EQ-01\trix: (soil/water) WATER Lab Sample ID: 6701EQ-04

Vuxge Volume: 5.000 (g/mL) ML Lab File ID: G11080S

Level: (low/med) LOW* Date Received: 10/30/91% Hoisture: not dec. 100. Date Analyzed: ll/ 8/91



74-87-3-----74-83-9——————3ROMOMETEANE_~75-01-4——————VINYL CHLORIDE75-00-3-——75-09-2——————METHYLENE67-64-1———— _______75-15-0——————CARBON DISULFIDE75-35-4 ——————1,1-75-34-3 —————— 1,1-DICHLOROETHANE______156-59-4——————CIS-1, 2-DICHLOROETHENE _156-60-5——————TRANS-1,2-DICHLOROETHENE67—66—3 —————CHLOROFORM________.____107-06-2 —————— 1,2-DICHLOROETHANE______

J-93-3——————2-3UTANONE74-9 7-5 ——————3ROMOCHLOROMETEANE71-55-6——————1,1,1-TS56-23-5——————CARBON TETRACELORIDE75-27-4——————3ROMODICHLOROMETEANE"

10061-01-5——————CIS-1,3-DICHLOROPROPENE

124-48-1——————DIBROMOCHLOROMETEANE79-00-5 ——————1,1,2-71-43-2——————3ENZENE

10061-02-6——————TRANS-1,3-DICHLOROPROPENE _75-25-2——————3ROMOFORM ________________108-10-1——————4-METEYL-2-PENTANONE_______591-78-6——————2-HEXANONE________________127-18-4-79-34-5 ——————1,1/2,:106-93-4—————1,2-108-88-3—————TOLUENE ____108-90-7——————CHLOROBENZENE100-41-4- ______100-42-5——————STYRENE __________1330-20-7——————XYLENE (TOTAL)____541-73-1 —————— 1,3-DICELOROBENZENE106-46-7 —————— 1,4-DICHLOROBENZENE"95-50-1——————1,2-DICHLOROBENZENE"i-12-8—————— l,2-DIBROMO-3-CHLOROPROPANE_

1

I- !1. JU1. JU1. JU2. JU

26. j B1. JU2. j1,1. JU1. JU0.8 j J1. j U5. }U1. JU3. j1. JU1. JU1. JU1. JU

71. j E1. JU1. JU1. JU1. JU1. JU5. JU5. JU1. JU1. - }U1. JU1. JU1. JU1. JU

1. JU1. JU1. JU1. ju1. JU

FORM I VOA 6/91 Rev,

1A EPA SAMPLS HO.VOLATILE ORGANICS ANALYSIS DATA SHEET _______


Lab Code: SWRI Caaa No.: 17359 SAS: 6701HQ SDG No.: 6701HQ-01Matrix: (aoil/watar) WATER Lab Sample ID: 6701HQ-04DL

Sample wt/vol: 5.000. (g/mL) ML Lab File ID: G111103

Level: (low/med) LOW Data Received: 10/30/91% Moistura: not dec. 100. Data Analyzed: 11/11/91



74-37-3—————CHLOROMSTHANE ___74-33-9——-——3RCMCMETHANE_____75-01-4—————VINYL CHLORIDE___73-00-3——-——CHLOROSTEANS_____75-09-2—————METHYL2NZ CHLORIDE67-64-1—————AC2TONE ___75-15-0—————CARSON DISULFIDE_____75-35-4—————1,1-DICHLCROETHENE___75-34-3—————1,1-DICHLORCETHANE___136-59-4——————CIS-1,2-3ICHLOROET52NB _136-60-5—————TRANS-1,2-DICHLOROETHSNE67-65-3—————CHLOROFORM_________107-06-2—————1,2-DICHLOROETHANE__73-93-3—————2-BUTANCNE_________74-97-5—————3RCMOCHLCROMETHAN2 __71-55-6—————1,1,1-TRICHLOROETHAN256-23-5—————CARBON TETRACHLORIDEj75-27-4—————BRCMODICHLORCMSTHANS_78-87-5—————1,2-DICHLOROPROPAHE

10061-01-5——;———CIS-1,3-DICHLOROPROPENE79-01-6—————TRICHLOROETH2N3 ____12 4-4 3 -1—————DI3ROMOC2LOROMETHANE_79-00-5—————1,1,2-TRICHLOR02THANB71-43-2————-BENZENE ____ _____

10061-02-6—————TRANS-1,3-DICHLOROPROPENE _73-25-2——————3ROMOFORM ______________108-10-1—————4-METHYL-2-P2NTANONS_____5 91-78-6—————2-HEXANONZ_____________127-13-4—————TETRACHLOROETH2NE _______79-34-5—————1,1,2,2-TETRACHLOROETHANE _106-93-4—————1,2-DI3ROMOBTHANH_________103-33-3—————TOLUENE ________________103-90-7—————CHLOROBENZENE ___________100-41-4——————3THYLBENZSNE______________100-42-5——————STYRENE _________________1330-20-7—————XYLENE (TOTAL)___________541-73-1—————1,3-DICHLOR03ENZ2NB_______106-46-7-—————1,4-DICHLOROBENZ2NE_______95-50-1—————1,2-DICHLOROBEN32N296-12-3—————l,2-DI3ROMO-3-CHLOROPROPANE

10. JU10. JU10. JU10. JU6. j J

59. j10. JU10. JU10. JU10. JU10. JU10. JU10. JU30. JU10. JU10. JU10. JU10. JU10. JU10. }U100. i10. }U10. [U10. {U10. JU10. JU50. JU50. {U10. JU10. JU10. |U10. JU10. JU10. |u10. JU10. JU10. JU10. JU10. }U10. JU

IFORM I VOA ' S79i Rev.

&R305000

Lab Name: SWRI Contract: ,68. 09-0135

VOLATILE CRGANICS ANALYSIS DATA SHEET ___________

6701EQ-05

Lab Code: SWRI Case No.: 17359 SAS: 6701HQ SDG No.: 6701EQ-01•'atrix: (soil/water) WATER Lab Sample ID: 6701EQ-05

-.-urge Volume: 5.000 (g/mL) ML Lab File ID: G110809

Level: (low/med) LOW Date Received: 10/30/91% Moisture: not dec. 100. Date Analyzed: ll/ 8/91



74-87-3 —— •74-83-9 —— •75-01-4 —— •75-00-3 —— -75-09-2 —— •67-64-1 —— •75-15-0 —— •75-35-4 —— •75-34-3 —— •156-59-4 —— •156-60-5 —— •67-66-3 —— -107-06-2 —— •78-93-3 —— -74-97-5 —— -71-55-6 —— -56-23-5 —— -/ j & * *»78-87-5 —— -

10061-01-5 —— -79-01-6 —— -124-48-1 —— -79-00-5 —— •71-43-2 —— •

10061-02-6 —— -75-25-2 —— -108-10-1 —— -591-78-6 —— -127-18-4 —— -79-34-5 —— -106-93-4 —— -i np—fl R—.T. -.——...108-90-7 —— -100-41-4 —— •100-42-5 —— -1330-20-7 —— •541-73-1 —— •106-46-7 —— -

. 95-50-1 —— •Q£ 1 T Q

TTTVTVT /* BT f\"O TT 'O

_-._—, r*tJT npnpT*T3Tnw5*_ _HiTCl«T>tIVT P\TP f^STOPTT^P

—— HZARBON DISULFIDE11 _nTf*TJT nPOPTTTPHIP

_,___. i i ..nrr'cT OPDPTTiawP__ _/*TC — l *) _ nTf T pripfuirw

_ _ /*t?T ABrtPOOM ~ ~

IT — nTf xr npnpToaiup——— 2-3UTANONE_ ap/ M/ c'WT HB^vrpfcawp

.— — — r*3.T3CnM TPTPaPWT fiPTHP_ 'or\\tf\T\Tf gr oac iupT'tTa.xrp_^ ,1 ¥5_r\Tr'I?TOPOPPOPllWP

nTQPrtxc/ tTT /* p/ mjinu Tvxtp11 '5— iTPT T / BrtPT'tiaMP3 C* \1f V\TV

——— TRANS-1, 3-DIC5LOROPROPENE _2OOM/ P/ PXf

——— 4-METEYL-2-PENTANONE——— 2-HEXANONE._ _TtTrToa«^TTT/^pnPrnnPMP

IT— nT'Qor iu/' pfoaxn? *"~~——— TOLUENE.___r'TIT rttlrtnPMTPTMP

ETTIVT nPMTPTVTP

_ VVT PMP /TrtTAT \IT r%T^nT rtPrtPfMT WTklf1A rtT/^QT rtP/ PffVf Tf >TC*

17— nTr*WTnpnBPM7PnrpIT— .nTPPOMO— "?— r*RmpnppnpaMP

1.1.1.1.2.12.1.1.1.1.1.1.1.5.1.1.1.1.1._ _1 .1.1.1.1.1.5 .5.•\ ^

X •1.1.1.1.1.1.1.1.1.x .

FORM I VOA

irtiu10!Ula! Bjujujuju!u,'u;u!Ufu!Ujujuju!Ujujujujujuju|u,'uiujuju|u|u!u|u|u!u|u!uju

6/9]L Rev

AR30500I

U U I W S-iJ-va-' Ort.--.rVOLATILE ORGAJIICS ANALYSia DATA SHEET '

Name: SWRI Contract: 68-D9-01356701HQ-06

Lab Code: SWRI Case No.: 17359 SAS: 6701HQ SDG No.: 6701HQ-01Matrix: (soil/watar) WATER Lab Sample ID: 6701HQ-06

Purge Volume: 5.000 (g/mL) ML Lab File ID: G110810

Level: (low/mad) LOW Data Received: 10/30/91% Moisture: not dec. 100. Data Analyzed: ll/ 8/91



74-37-3——————CHLOROMETHANE _______7 4 - 3 3 - 9—————3ROMOMETHANE _____75-01-4—————VINYL CHLORIDE_______75-00-3——————CHLOROETHANE,_______75-09-2—————METHYLENE CHLORIDE___67-64-1——————ACETONE ____________75-15-0——————CARBON DISULFIDE_____75-35-4——————1,1-DICHLOROETHENE___75-34-3 —————— 1,1-DICELOROETHANE___156-59-4——————CIS-1, 2-DICHLOROETHENE _156-60-5 ——————TRANS-1,2-DICHLOROETHENE67-65-3—————CHLOROFORM___________107-06-2——————1,2-DICHLOROETHANE____7a-93-3—————2-3UTANONE___________74-97-5——————3ROMOCHLOROMETHANE ___71-55-6——————1,1,1-TRICHLOROETHANE56-23-5——————CARBON TETRACHLORIDE___75-27-4——————3ROMODICHLOROMETHANE___78-87-5 —————— 1,2-DICHLOROPROPANE ___

10061-01-5——————CIS-1,3-DICHLOROPROPENE79-01-6——————TRICHLOROETHENE ______124-48-1——————DI3ROMOCHLOROMETHANE___79-00-5—————1,1,2-TRICHLOROETHANE __71-43-2—————3ENZENE _____________

10061-02-6——————TRANS-1, 3-DICHLOROPROPENE _75-25-2—————3ROMOFORM _______________103-10-1——————4-METHYL-2-PENTANONE591-78-6——————2-HEXANONE________~127-13-4——————TETRACHLOROETHENE79-34-5——————1,1,2,2-TETRACHLOROETHANE _106-93-4—————1,2-DIBROMOETHANE_________108-33-3—————TOLUENE ________________108-90-7——————CHLOROBENZENE ____________100-41-4——————ETHYLBENZENE______________100-42-5—————STYRENE ________________1330-20-7—————XYLENE (TOTAL)___________541-73 -1——————1,3-DICHLOROBENZENE_______106-46-7 —————— 1,4-DICHLOROBENZENE_______95-50-1——————1,2-DICHLOROBENZENE_______96-12-8——————l,2-DIBROMO-3-CHLOROPROPANE_

I

0.8 j J1. JU1. JU1. JU2. JU36. j 31. JU1. JU1. JU1. JU1. JU1. JU1. JU5. JU1. {U1. JU1. JU1. JU1. JU1. JU1. JU1. JU1. {U1. JU1. JU1. JU5. }U5. JU1. JU1. JU1. JU1. |Ul. ju1. ju1. JU1. JU1. JU1. ju1. JU1. JU

IFORM I VGA 6/91 Rev.

&R3G5002


VOLATILE OKurti-4j.v.i. .i-.«*»LjfSIS DATA SHEET

6701HQ-07

Lab Code: SWRI Case No.: 17359 SAS: 6701HQ SDG No.: 6701HQ-01itrix: (soil/water) WATER Lab Sample ID: 6701HQ-07

-Targe Volume: 5.000 (g/mL) ML Lab File ID: G110804

Level: (low/med) LOW Date Received: 10/30/91i Moisture: not dec. 100. Date Analyzed: ll/ 8/91

Column: (pack/can) CAP Dilution Factor: 1.00CONCENTRATION UNITS:


74-87-3——————CHLOROMETHANE '74-83-9——————BROMOMETEANE_\75-01-4——————VINYL CHLORIDE75-00-3 ——————CHLOROETHANE "75-09-2——————METHYLENE CHLORIDE___67-64-1——————ACETONE ____________75-15-0—————'-CARBON DISULFIDE_____75-35-4 —————— 1,1-DICELOROETHENE___75-34-3 —————— 1,1-DICHLOROETHANE___156-59-4——————CIS-1, 2-DICHLOROETHENE _156-60-5——————TRANS-1,2-DICHLOROETHENE67-66-3——————CHLOROFORM__________107-06-2 —————— 1,2-DICHLOROETHANE78-93-3——————2-3UTANONE74-97-5——————BROMOCHLOROMETHANE __71-55-6——————1,1,1-TRICHLOROETHANE56-23-5——————CARBON TETRACHLORIDE__75-27-4——————3ROMODICELOROMETEANE__78-87-5 —————— 1,2-DICHLOHOPROPANE

10061-01-5——————CIS-i,3-DICHLOROPROPENE79-01-6——————TRICHLOROETHENE124-48-1——————DI3ROMOCHLOROMETHANE_79-00-5 —————— 1,1,2-TRICHLOROETEANE71-43-2—————BENZENE ___

10061-02-6——————TRANS-1,3-DICHLOROPROPENE _75-25-2——————3ROMOFORM _________108-10-1——————4-METHYL-2-PENTANONE591-78-6——————2-HEXANONE________"127-18-4 ——————TETRACHLOROETHENE79-34-5 —————— 1,1,2,2-TETRACHLOROETHANE _106-93-4 —————— 1,2-DIBROMOETEANE_________108-88-3——————TOLUENE _________________108-90-7——————CELOROBENZENE ____________100-41-4——————ETHYLBENZENE______________100-42-5——————STYRENE ______________1330-20-7——————XYLENE (TOTAL)____________541-73-1 —————— 1,3-DICHLOROBENZENE_______106-46-7——————1,4-DICHLOROBENZENE______95-50-1——————1,2-DICELOROBENZENE_______96-12-8"—————l,2-DIBROMO-3-CELOROPROPANE_

2. j1. JU1. JU1. JU2. JU4. j BJ1. JU1. JU1. JU1. JU1. JU2. j1. [U5. JU1. JU1. JU1. JU1. JU1. JU1. JU1. JU1. JU1. JU1. JU1. JU1. JU5. JU5. JU1. }U1. JU1. JU1. JU1. JU1. JU1. }U1. JU1. {U1. JU1. JU1. JU


AR305003

Appendix O

Reviewed and AcceptedTentatively Identified Compounds

VOLATILE ORGANICS AMALYSJS. DATA SflfihXTENTATIVELY IDENTIFIED COMPOUNDS

Lab Name: SWRI Contract: 68-D9-01356701EQ-01

-ab Code: SWRI Case No.:17359 SAS: 6701HQ SDG No.: 6701HQ-01

trix: (soil/water) WATER Lab Sample ID: 6701EQ-01

""ample wt/vol: 5.000 (g/mL) ML Lab File ID: G110805

"evel: (low/med) LOW Date Received: 10/30/91

% Moisture: not dec. 100. Date Analyzed: ll/ 8/91

olumn: (pack/cap) CAP Dilution Factor: 1.00

CONCENTRATION UNITS:j Number TICs found: 0 (ug/L or ug/Kg) UG/L

1 1

' ' CAS NUMBER

! 1.! 2.

3., 4.: s.

6.7.: e.

' 9..0.

V-41.1 12.13.

, 14.! 15.16.17.

[ 18.1 19.20.

! 21.! 22.23.

i . 24.j 25.26.27.

j 28.1 29.30.

ii

COMPOUND NAME

.

RT

V

EST. CONC. Q

FORM I VOA-TIC 1/87 Rev.

SR305Q05

12 .; ' J U 1 U U MA SAMPLE NOVOLATIL2 ORGANICS ANALYSIS DATA SH22T _____________TENTATIVELY ID2NTIFI2D COMPOUNDS


Lab Code: SWRI Case No.: 17359 SAS: 6701HQ SDG No.: 6701HQ-01

Matrix: (soil/water) WATER Lab Sample ID: 6701HQ-02

Sample wt/vol: S.'OOO (g/mL) ML Lab File ID: G110806

Level: (low/mad) LOW Data Received: 10/30/91

% Moisture: not dec. 100. Data Analyzed: ll/ 8/91

i Column: (pack/cap) CAP Dilution Factor: 1.00

j . CONC2NTRATION UNITS:Humber TICs found: 0 (ug/L or ug/Kg) UG/L

CAS NUMBER

1.2.3.4.5.6.7 .3.910.11.12.13.14.15.16.17.13.19.20.21.22.23.24.25.26.27.23.29.30. ii

COMPOUND NAME

•

RT

«•

EST. CONC.

•

Q

——— S

FORM I VOA-TIC 1/87 I

AR305006

IE - ; . . • . . ' - ' " • S iPLE NOVOLATILE ORGANICS ANALYSIS DATA SHEET ____________TENTATIVELY IDENTIFIED COMPOUNDS


Code: SWRI Case No. :17359 SAS: 6701HQ SDG No.: 6701EQ-01

_ a.trix: (soil/water) WATER Lab Sample ID: 6701HQ-03


•evel: (low/med) LOW Date Received: 10/30/91


• Column: (pack/cap) CAP Dilution Factor: 1.00

jj CONCENTRATION UNITS:> Humfaer TICs found: 0 (ug/L or ug/Kg) UG/L

CAS NUMBER_ — ___, — ___,.- ——————

1.2 .3.4.5.6.7.8.9.

-"10.11.12.13.14.15.16.17.18.19.20.21.22.23.24.25.26.27.28.29.30.

COMPOUND NAME RT

•w

EST. CONC.

-

.

Q

FORM I VOA-TIC 1/87 Rev,

4R305Q07

TENTATIVELY IDENTIFI2D COMPOUNDS6701HQ-03DL

j-ab Name: SWRI Contract: 63-09-0135

,ab Code: SWRI Case No.: 17359 SAS: 6701HQ SDG No.: 6701HQ-01

Matrix: (soil/water) WATER Lab Sample ID: 6701HQ-03DL

ample wt/vol: 5.000 (g/mL) ML Lab File ID: G111102

T,eval: (low/mad) LOW Date Received: 10/30/91

s Moisture: not dec. 100. Date Analyzed: 11/11/91

lolumn: (pack/cap) CAP Dilution Factor: 50.00

CONCENTRATION UNITS:Humber TICs found: 0 • (ug/L or ug/Kg) UG/L

1

' CAS NUMBERi.i.3— JJ — J -•• -ra-5»

, 1.! 2.

3.. 4.! 5.' 6.

7.> 91 W •

1 9.10.

i 11.! 12.13.

. 14.j 15.' 16.17.

! 13.1 19.20.

i 21.! 22.23.

. 24.! 25.' 26.27.

! 23.1 29.30.

i

COMPOUND NAME> -^r __. j, _.,_ .„— j , ^* jjjj jjj.RT EST. CONC. Q

\


flR305008

VOi-AliJ-i. ORGANICS ANALYSIS DATA SHEETTENTATIVELY IDENTIFIED COMPOUNDS


Code: SWRI Case No.: 17359 SAS: 6701HQ SDG No.: 6701HQ-01

.trix: (soil/water) WATER Lab Sample ID: 6701HQ-04_

'ample wt/vol: 5.000 (g/mL) ML Lab File ID: G110808

~,evel: (low/med) LOW Date Received: 10/30/91


rolumn: (pack/cap) CAP Dilution Factor: 1.00

CONCENTRATION UNITS:Number TICs found: 0 ' (ug/L or ug/Kg) UG/L

CAS NUMBER

1 .2.3.4.5.6.7.8.g

10 .' 11.12.13.14.15.16.17.18.19.20.21.22.23.24.25.26.27.28.29.30.

COMPOUND NAME

.

-

RT—— ,

*

•

EST. CONC. Q


6R305009

- - > ' f'• •-. VOE-4T1&3. ORGANICS ANALYSIS DATA SHEETTENTATIVELY IDENTIFIED COMPOUNDS


_ab Code: SWRI Case No.:17359 SAS: 6701HQ SDG No.: 6701HQ-01

Matrix: (soil/water) WATER Lab Sample ID: 6701HQ-04DL

;ample wt/vol: 5.000 (g/rnL) ML Lab File ID: G111103

".evel: (low/med) LOW Date Received: 10/30/91

% Moisture: not dec. 100. Date Analyzed: 11/11/91

tolumn: (pack/cap) CAP Dilution Factor: 10.00

CONCENTRATION UNITS:Number TICs found: 0 • (ug/L or ug/Xg) UG/L

CAS NUMBER

X •2.3.4.5.6.7.3.Q

10.11.12.13.14.15.16.17.18.19.20.21.22.23.24.25.26.27.23.29.30.

COMPOUND NAME% •

.

RT

'

EST. CONC.

•

Q

——————— x

FORM I VOA-TIC 1/37 R<?"

ftR3050iO

TENTATIVELY IDENTIFIED COMPOUNDS6701EQ-05


Lab Code: SWRI Case No.: 17359 SAS: 6701HQ SDG No.: 6701HQ-01

trix: (soil/water) WATER Lab Sample ID: 6701HQ-05


Level: (low/med) LOW Date Received: 10/30/91

i Moisture: not dec. 100. Date Analyzed: ll/ 8/91

j Zolumn: (pack/cap) CAP Dilution Factor: 1.00

j . CONCENTRATION UNITS:t Number TICs found: 0 (ug/L or ug/Kg) UG/L

CAS NUMBER

1.2 .3.4.5.6.7

8.9.10.

- 11 .12.13.14.15.16.17.18.19.20.21.22.23.24.25.26.27.28.29.30.

COMPOUND NAME

-

RT

V

EST. CONC.*i_ ,-,-.-,„ -v-n,———————— ———— _JJmJ -4-,-

.

Q


AR3050I!

VOLATILE ORGANICS ANAuuiSIS DATA SHEETTENTATIVELY IDENTIFIED COMPOUNDS


f!.ah Code: SWRI Case No.: 17359 SAS: 6701HQ SDG No.: 6701HQ-01

Matrix: (soil/water) WATER Lab Sample ID: 6701HQ-06

Jainple wt/vol: 5.000 (g/mL) ML Lab File ID: G110310

".ervel: (low/med) LOW Date Received: 10/30/91

% Moisture: not dec. 100. Data Analyzed: ll/ 3/91

lolumn: (pack/cap) CAP Dilution Factor: 1.00

CONCENTRATION UNITS:Hunfaer TICs found: 0 • (ug/L or ug/Kg) UG/L

CAS NUMBER

1.2.3.4.5.6.7.3.9.10.11.12.13.14.15.16.17.13.19.20.21.22.23.24.25.26.27.28.29.30.

COMPOUND NAME RT EST. CONC. Q

VT

FORM I VOA-TIC 1/87 R-

AR3050I2

VOLATILE ORGANICS ANALYSIS DATA SHEETTENTATIVELY IDENTIFIED COMPOUNDS

L>ih Name: SWRI Contract: 68-D9-01356701EQ-07

Code: SWRI Case No.: 17359 SAS: 6701EQ SDG No.: 6701EQ-01

itrix: (soil/water) WATER Lab Sample ID: 6701HQ-07

example wt/vol: 5.000 (g/mL) ML Lab File ID: G110804

j _evel: (low/med) LOW Date Received: 10/30/91»

j % Moisture: not dec. 100. Date Analyzed: ll/ 8/91J

! Jolumn: (pack/cap) CAP Dilution Factor: 1.00

i CONCENTRATION UNITS:' Humber TICs found: 0 ' (ug/L or ug/Kg) UG/L

CAS NUMBER

1.2.3.4.5.6.7.8.9.

,10.11.12.13.14.15.16.17.18.19.20.21.22.23.24.25.26.27.28.29.30.

COMPOUND NAME

•

•

RT EST. CONC.

-

Q


fiR305013

Appendix 2

Organic Regional Data Assessment Summary

flR3Q50U

of 2

TPO: [ ] ACTION [X] FYI Region III

ORGANIC REGIONAL DATA ASSESSMENT SUMMARY

SAS NO; 6701HO______________ LABORATORY; SWRI_____________SDG NO: 67Q1HO-Q1__________ DATA USER: Raymond Flores_____SOW: 6/91_______________ REVIEW COMPLETION DATE: 2/3/92NO. OF SAMPLES; Seven m____ MATRIX: Aqueous_____

REVIEWER: ESAT

VOA BNA PEST OTHER

1. HOLDING TIMES O ____ ____ ____

2. GC-MS TUNE/GC PERFORMANCE 0 ____ ____ ____

3. INITIAL CALIBRATIONS ____.

4. CONTINUING CALIBRATION __X_

5. FIELD BLANKS (F=NOT APPLICABLE) __£_

6. LABORATORY BLANKS

7. SURROGATES

8. MATRIX SPIKE/DUPLICATES

9. REGIONAL QC (F=NOT APPLICABLE)

10. INTERNAL STANDARDS

11. COMPOUND IDENTIFICATION

12. COMPOUND QUANTITATION

13. SYSTEM PERFORMANCE

14. OVERALL ASSESSMENT

O =»No problems or minor problems that do not affect data usabilityX —No more than about 5% of the data points are qualified as either estimated or unusable.M -More than about 5% of the data points are qualified as estimated.Z -More than about 5% of the data points are qualified as unusable.A »TPO action requested; use in conjunction with one of the above codes.

TPO ACTION ITEMS:

AREAS OF CONCERN: f Documentation Attached, See Followina Paaes)

AR3050I5

of 2

ORGANIC REGIONAL DATA ASSESSMENT SUMMARY NOTESSAS 6701HQ SDG 5701HQ-01 Aqueous Samples

Item 3A Chloroethane had a RRF less than 0.05 and acetone, and2-butanone had %RSD's greater than 30% in the initialcalibration. (See Table I in Appendix F.)

Item 4A Bromomethane, chloroethane, acetone, 2-butanone andtrans-l,2-dichloroethene had %D's greater than 25% inthe continuing calibrations. (See Table I in AppendixF.)

Item 5A The maximum concentration of all compounds found in theanalysis of the trip blank are listed below:

Compound Concentration fuq/L)

chloromethane 2acetone* 4 Jchloroform 2

* Common Laboratory Contaminant

Item 6A The maximum concentration of all compounds found in theanalyses of the laboratory method blanks are listedbelow:

Compound Concentration fug/LV

acetone* 4 Jcarbon disulfide 0.7 J

* common Laboratory Contaminant

AR3Q50I6

Appendix F

Support Documentation

SR3050I7

I • . : • gaga I of

CXSZ f 3A3 JXa. 19 IV \ H V_______CSSTSACTCa

! rrtsrr-rrse--:* T& TO >< 'T.rit. Cai . 'Crrr. Cal.lCcr:-. Cal.^Csr-. Cai.fCs--. Cal.l' ///t»K/ •- stftifi /can //////fa»?.? .'

! CSi-rcrsa-. arte 1 f 1 1\33.0

•' Mai.r' la-9 CMsrids 1 170. " 1 U.

C"— ?c*

C-5 - 1 , 2-ais*lercer.-.er!

J 2— 3u~ arena 30.*

.2 - Orc/'<.«««£-rw5«'f

GTUAJfI |

I I, 1. -

i i

Ot

Initials/Date:Lf'lOl )HO-O<,

* See last oace of this table for DEFINITION OF CODES.

AR305018

page <=>£ of

DE7I27ITION OF CODES USED IN TABLE I

I »= %RSD exceeded 30% in the initial calibration, positiveresults are qualified "J", and cuantitation limits arequalified "UJ".

C = %D exceeded 25% in the continuing calibration. Positiveresults are qualified "J", and quantitation limits arequalified "UJ".

? = RJ less than 0.05 in the calibration. All quantitationlimits are qualified "R".

•f = The "3" qualifier, denoting blarJc contamination, supersedesthe qualifier issued in this table.

R * The "R" qualifier, denoting unusable results, supersedes thecualifier issued in this table.

HR3050I9

Wl G 0 3 16A

VOLATILE ORGANICS INITIAL CALIBRATION DATA

_} Name: SWRI Contract: 63

» Code: SWRI Caaa No.: /735"7" SAS No.: C,70/ HQ. SDG No.:

i3«rurnent ID: TRIOTa./S Calibration Date(s): ll/ 6/91 ll/ 6/91•'/"'*' ^ -s

jrix: (soil/J atary Laval: f lou/med): Column: (pack/qaoy CAP

La RR? for S?CC(#) » .100 (0.250 for Bronofora) Max %RSO for CCC(*) * 30.0%

-.3 FILE ID: RRF001- G1105S5 RRT002" G1106S4WPOOS- G1106S3 RRF010- G1105S2 RRT025- G1106S1

COMPOUND

t-3ROMOFLUOR03ENZENSlaLOROMETHANE2CfL CHLORIDE

__:CMOMSTHANErHLOROETHANE1-D I CHLOROETKENESTONE

ZAB3ON DISOLFIDEXBTTH1fL2NE CHLORIDESNS-1, 2-DICHLOROETHENE __

Lt 1-DICHLOROETHAN22-3UTANONEIS-l , 2-DICHLOROETHENE ___. .IOMOCHLOROME'THANEIHiaROFORM1,1-T?.ICHLOROETEANE ___ __JQON TETRACHLORZDE

1,2-01 CHLOROETHANE3r312SNEUCHLOROETHENE

j. , 2-DICHLOROPROPANE3RCMOD I CHLOROMETHANE•_S-1,3-DICHLORO?RO?ENS __•METHYL-2-PENTANONE

rOLSTSNEiaNS-l,3-DICHLORO?RO?ENE _• 1,2-TRI CHLOROETHANE ___ ~

I' TKACHLOROETHENE'-SEXANONErBROMOCHLOHOMETHANS

A. , 2-D I3ROMOETHANErHTOROBENZENE•HTL3ENZSNS

..JZSNE (TOTAL)SrgRENEtOMOFORM1,2,2-TETRACHLOROETHANE _

1.3-DICHLOR03ENZENE ~1 4-DICHLORO3ENZENE

RRF001

.633

.492

.323

.145

.055

.132

.244

.594

.203

.129

.516

.497

.459

.236

.765

.679

.531

.5392.039.563.520.659.691.6122.234.653.503.727.396.505.514

1.4242.443.392

1.536.472.6912.0432.194

RRF002

.630

.453

.332

.149

.056

.150

.131

.643

.227

.161

.435

.334

.472

.293

.781

.509

.514

.5531.399.511.476.607.655.549

2.051.635.430.534.334.434.475

1.3622.175.333

1.469.502.603

2.1342.233

RR7005

, . .630.442.342.107.035.121.093.596.171.119.429.270.433.279.759.629.552.530

1.920.513.523.649.726.627

2.122.659.462.651.422.542.514

1.4142.343.393

1.563.527.631

2.0102.103

RRF010

.629

.399

.304

.125

.043

.033

.040

.564

.162

.121

.420

.442

.453

.257

.747

.604

.564

.5311.357.540.437.639.733.6632.039.633.477.636.453.592.533

1.3652.329.919

1.557.512.640

1.9131.936

RR7025

.617

.342

.256

.070

.031

.095

.060

.390

.139

.113

.355

.230

.333'

.233

.674

.474

.462

.5041.527.397.442.534.655.554

1.336.607.339.522.336.546.455

1.2112.007.753

1.352.516.617

1.6541.743

RRP

•sraatsaai

.639

.427

.321

.119

.117

.115

.553

.131

.129

.441

.365

.443

.270

.745

.599

.535

.5311.353.507.490.633.693.6012.076.643.463.634.409.534.499

1.3552.259.360

1.495.506.636

1.9522.054

RSD

3.313.614.527.126.122.0

17.619.214.314.1

7.49.05.6

12.73.93.3

11.012.37.16.65.63.27.34.49.6

11.57.67.36.76.37.57.35.94.15.39.49.5

HR3Q5020 >r»C-

0010082. 2-OICHLOROBENZENE

1 , 2-DIBROKO-3-CHLOROPROPANE2.014.174

2.094.164

2.156.156

1.958.160

1.676.172

1.960.165

9.44.6

FORM VI VOA 1/87 Rev.

ftR30502i

U U 1 U U 3

7AVOLATILE CONTINUING CALIBRATION CHECK

ib Nane: SWRI Contract: 63-D9-005-"r- o* ,••/«/I73S-? (,-}oi»G . .

Code: SWRI Case No.: SAS No.: SOG No.: £ '* b7ofHa - €!>!••f-*t

istrunent ID: TRIO7S 'S Calibration Date: ll/ 3/91 Tiaa: 10:21e»— W./| ,

Fila 10: G1103S1 lait. Calib. Date(a): ll/ 6/91 ll/ 6/91

rix: (soil /water) Laval: (low/mad) : Column: (pack/cap) CAP

jx RRF50 for S?CC{#) » .100 (0.250 for Bromofora) Max %D for CCC(») - 30.0%

COMPOUND

4-3ROMOFLUOROBENZENECHLOROMETHAN2VINYL CHLORIDE3ROMOMETHANECHLOROETHANE1, 1-DICHLOROETHENEACETONECARBON DISULFIDEMETHYLENE CHLORIDETRANS-1 , 2-DICHLOROETHENE __1 , 1-DICHLOROETHANE2-3UTANONECIS-1 , 2-DICHLOROETHENE ____3ROMOCHLOROMETHANECHLOROFORM1,1,1-TRICHLOROETHANE ____CAR3ON TETRACHLORIDE1 . 2-DICHLOROETHANEBENZENETRI CHLOROETHENE1 , 2-OICHLOROPROPANE3ROMOD I CHLOROMETHANECIS-1, 3-DICHLOROPROPENE __4-METHYL-2-PENTANONETOLUENETRANS-1, 3-DICHLOROPROPENE _1,1,2-TRICHLOROETHANE ___ TETRACHLOROETHENE2-HEXANONED I3ROMOCHLOROMETHANE1 , 2-DI3ROMOETHANECHLORO3ENZENEETHYL3ENZENEXYLENE (TOTAL)STYRENE3ROMOFORM1,1,2,2-TETRACHLOROETHANE _1, 3-DICHLOROBENZENE1. 4-DICHLOROBENZENS1 , 2-DICHLORO3ENZEKE

RRF

.639,--«7.321.119.044.117.115.553.131.129.441.365.443.270.745.599.535.531

1.353.507.490.633.693.6012.076.643.463.634.409.534.4991.3552.259.3601.495.506.6361.9522.0541.930

RRF50

.601

.346

.243

.031

.054

.109

.073

.464

.155

.095

.340

.135

.363

.237

.693

.567

.522

.4591.635.469.419.605.642.5361.933.539.450.505.374.511.4731.3422.159.3591.439.455.6091.3902.0201.927

%D

6.013.924.3dz-o i22.67.0

£~32.3316.713.9

22.9Cag. -Q16.912.16.45.42.313.69.37.414.55.17.310.34.59.12.920.43.54.34.31.04.0.1.49.94.33.11.72.7

'°

SR305022

U U 1 U U9.5

FORK VII VOA 1/87 Rev.

1, 2-DIBROMO-3-CHLOROPROPANE .165 .149

flR305023

7AVOLATILE CONTINUING CALIBRATION CHECK

U U 1 U U 3 /

Name: SWRI Contract: 63-D9-Q057- <*f- -"• . -, """*'< ' 5 i" 7 i.-7Cl frQ

i1- Coela: SWRI Caae No.: SAS No.: SDG No.: i rcf &Gf - o (.

istrument ID: TRIOTStS Calibration Data: 11/11/91 Tina: 11:20£4*f.././4 1

. File ID: G1111S1 Init. Calib. Dato(a): ll/ 6/91 ll/ 6/91

itrix: (soil /water) Level: (low/mad) : Column: (pack/cap) CAP

. RRF50 for SPCC(#) * .100 (0.250 for Brcoofora) Max %D for CCC(*} * 30.0%

COMPOUND

4-3ROMOFLUOR03ENZENECHLOROMETHANEVINYL CHLORIDE3ROMOMETHANECHLOROETHANE1 , 1-D ICHLOROETHENEACETONECARBON DISULFIDEMETHYLENE CHLORIDETRANS-1, 2-DICHLOROETHENE __1 , 1-DICHLOROETHANE2-3UTANONECIS-1. 2-DICHLOROETHENE ____3ROMOCHLOROMETHANECHLOROFORM1,1,1-TRICKLOROSTKANE ____CARSON TSTRACHLORI3E1 , 2 -D I CHLOROETHANEBENZENETRI CKLOROETKENE1,2-DICHLOROPROPANE3ROMOD I CHLOROMETHANECIS-1, 3-DICHLOROPROPENE __4-METHYL-2-PENTANONETOLUENETRANS-1, 3-DICHLOROPROPENE _1,1, 2 -TRI CHLOROETHANE ___ ~TETRACHLOROETHENE2-HEXANONED I3ROMOCHLOROMETHANE1,2-0 I3ROMOETHANECHLOROBENZENEETHYL3ENZENEXYLESE (TOTAL)STYRSNS3ROMOFORM1,1,2,2-TSTRACHLOROETHANE _1,3-DICHLOROBENZENE "1, 4-OICHLOROBENZENE1 , 2-OICHLOROBENZENZ

R2?

.639

.427,.321.119.044.117.115.553.131.129.441.365.443.270.745.599.535.531

1.353.507.490.633.693.5012.076.643.463.634.409.534.499

1.3552.259.3601.495.506.636

1.9522.0541.930

RRFSO

.653

.447

.313• .104

.095

.102

.061

.641

.203

.120

.433

.217

.331

.251

.703

.566

.496

.4951.679.457.444'.605.601.595

1.923.559.451.571.411.517.4631.327'2.155.3641.479.465.6161.9372.0492.000

%D

2.24.9.9

12.3jjlT12.6/*rrs215.112.47.0.7

(%$•£>14.16.95.05.6

. 7.26.9.9.69.39.45.2

. 13.2.97.4

13.62.79.3.43.17.32.14.6.51.13.03.2.7.31.0

AR30502U

1,2-DI3ROKO-3-CHLOROPROPANE .165 .145 12.1 0010098

FORM VII VOA . 1/87 Rev.

6R305025

U.S. Environmental Protection Agency £/" SAS numberCLP Sasrple Management Office ^ --..P. 0. 30X 313ALEXANDRIA. VA 22313PHONE: (703) 557-2490 or FTS .557-2490

SPECIAL ANALYTICAL SERVICES — "Regional Request

X Regional Transmi teal . . _ _ _ _ . _ _ __ Telephone Request

A. EPA Region and Client: EPA Region III

B. Regional Representative: COLLEEN K. WALLING

C. Telephone Number: (301) 266-9130 '

D. Dace of Request: September 23, 1991

E. Sice Name: Westinghouse Plant Site/Gettysburg^ \ff\

Please provide below a description of your request for Special AnalyticalServices under the Contract Laboratory Program. In order to most efficientlyobtain laboratory capability for your request, please address the followingconsiderations, if applicable. Incomplete or erroneous information may resultin delay in the processing of your request. Please continue response onaddicional sheets, or attach supplementary information as needed.

1. General description of analytical service requested:

Seven (7)Avolatile organic water sample.. «*t«0*sss ^/ The SuperfundAnalytical Methods for Low Concentration water for Organic Analysis(Statement of Work 6/91) .

2. Definition and number of work units involved (specify whether whole samplesor fractions; whether organics or inorganics; whether aqueous or soil andsediments; and whether low, medium, or high concentration):

Seven (7) whole samples, organics (volatiles), aqueous at lowconcentration. The Superfund Analytical Methods for Low ConcentrationWater for Organic Analysis (Statement of Work 6/91). Including one tripblank and a duplicate.

3. Program (specify whether Superfund (Remedial or Enforcement), RCRA, NPDES,etc.), Justification for analysis and Site Account Number.

Residential Well Sampling for a Superfund RemedialInvestigation/Feasibility Study, Work Assignment Number C03013,ID Number PAD043332231. and Site Spill ID Number 3PA7.

SAS APPROVED BY:

AR305026

4. Estimated date(s) of collection:

October 28 through November 1. 1991.

5. • Estimated date(s) and method of shipment: - :-. . ..•

• October 28 through November 1. 1991 via Federal Express. .•

6.* Approximate number of days results required after lab receipt of samples:

Same as CLP requirements. . • • '

7. Analytical protocol required (attach copy if other than a protocolcurrently used in this program) :

Vola.iles by ' the Superfund Analytical Methods for LowConcentration Water for 'Organic Analysis (Statement of Work 6/91) .

8. Special technical instructions (if outside protocol requirements, specifycompound .names, CAS numbers, detection limits, etc.):

Requesting analysis for all the volatiles in the Statement of Work (6/91).

9. Analytical results required (if known, specify format for data sheets,QA/QC reports, Chain-of-Custody documentation, etc.). If not completed,format of results will be left to program discretion.

All CLP Deliverables

10. Other (use additional sheets or attachsupplemental information, as needed):

See attached pages for CLP deliverables .

11. Name of sampling/shipping contact:DYKAKAC CORPORATION

Phone: (215) 440-7340

Fax: (215) 440-7346

12. Data Requirements:

Volatile organics per t'Ae. t*frt S0«-J re^fffnccj / ** 7

13. QC Requirements:

Volatile organics per i**e 6/*jf iOcJ n-fcresiccd //%. **

14. Action required if limits are exceeded:

Fer specific method* -if problems pcrstst contact Region III and SKOimmediately for further instructions.

JIR305027

. -•- «. *.

15. Request prepared by: Anthony VelliosDYNAKAC CORPORATION

. Date: .September 23, 1991 ....

16 . Request, reviewed by:

Date: '' f . /0-,2.- **

Please return this request to the Sample Management Office as soon as possibleto expedite processing of your request for Special Analytical Services. Shouldyou have any questions .or need any assistance, please contact your Regionalrepresentative at the Sample Management Office.

SR3Q5028

aoi. at.awn.

0 00/CZContract: 63-09-0135Novoafcar 12, 1991First aampla in SOS: S7013Q-01Last saapla ia 3QQI 67012Q-07

SVftlCA33 173S9 SAS S701SQ, SDO: 6701BQ-Q1

SEVEN LOW WATER SAMPLES FOR VOLATILS ANALYSIS: 01, 02, 03, 04,05, 06, AND 07.

QC SAMPLES: MATRIX SPIKE: LABORATORY CONTROL SAMPLE 01DILUTIONS: 03 AND 04

Saapla received on October 30, 1991 for a fourteen dayturnaround froa VTSR.The QC performed is that as specified in tha SAS Solicitation.

Tha chronicles consisting of the solicitation and custodysheets as indicated in the solicitation are enclosad.

VOLATI-23

1. Volatile analyses were dona according to the requirements inSOW 3/91.

2. Due to the low intensity of a/Z 72 for 2-Butanona, thiscompound is quantitated on a/Z 43. All primary quantitationions were used for remaining compounds.

3. Manual peak integration is occasionally necessary for one oraore of the following reasons:

Not found - The peak in question was not correctlyidentified by the Autoquan software,therefore, it was necessary to manuallyadd tha peak to the quantitation report.

Tailing - Due to a concentration, matrix, orsolvent affect: aanual integration isnecessary to integrate the whole paak.

Splitting - Dua to a concentration, matrix, orsolvent effect: aanual integration isnecessary to integrate the whole peak.

4. All raw data areas for trio instruments (VG*s) are divided by100.

5. No P.S. sample was received as confirmed by SMO.S. Eight samples were analyzed for OLC01 and two of them required

dilutions, 5701HQ-03 and S701HQ-04. Dilutions ware requireddue to concentrations being out of calibration range.

AR3Q5Q29

0 003contract: 68-D9-013S .-.;..November 12, 1991 • : =.,,.....First sample in SDGt 670IEQ-01Last sample in 80S: 6701HQ-07

7. on all samples acetone is labeled vith a "B". This flag isused when the analyte is found in the associated blank as wellas in the sample. Zt indicates possible/probable blankcontamination and warns the data user to take appropriateaction.

8. internal standard used for analyses contained three additionalcompounds. These compounds (Fluorobenzene, Pentafluoro-benzene, and i,2-Dichlorobenzene-D4) are labelled on RIC ofall method blanks.

"I certify that this data package is in compliance vith thoterms and conditions of the contract, both technically and forcompleteness, for other than the conditions detailed above.Release of the data contained in this hardcopy data package and inthe computer-readable data submitted on floppy diskette has beenauthorized by the Laboratory Manager or bis/fear deeignee, asverified by the following signature."

Ann Boyd, supervisor(J&nvironmental Chemistry

"R30S03Q

1A 0 0 1 t< -^U^AMPLE NO..VOLATILE ORGANICS ANALYSIS DATA SHEET _________

Lab Name: SWRI Contract: 63-D9-0135VBLK01

Lab Code: SWRI Casa No.:17359 SAS: 5701HQ SDG No.: 6701HQ-01Matrix: (soil/water) WATER Lab Sample ID: VBLX01 <>

Sample wt/vol: 5.000 (g/mL) ML Lab Fila ID: G110331

Level: (low/nad) LOW Date Received: O/ O/ 0% Moisture: not dec. 100. Date Analyzed: ll/ 3/91



74-37-3———74-33-9—————BROMOMETHANE_~75-01-4—————VINYL CHLORIDE75-00-3———75-09-2-———67-54-1——— _______75-15-0—————CARBON DISULFIDE75-35-4 —————1,1-75-34-3——————1,1-DXCHLOROETHAHS~156-59-4—————CIS-1,2- _156-50-5—————TRANS-1, 2-DICHLOROETHENE57-65-3-----107-06-2—————1,2-73-93-3—————2-3UTANONE•74-97-5———— " __71-55-5———1,1, 1-TRICHLOROETHANE.75-27-4————BROMODICHLOROMETHANE"73-37-5 ———— 1,2-DICHLOROPROPANE

10061-01-5—————CIS-1,3-179-01-5—————TRICHLOROETHBNB124-43-1------79-00-5—————1,1,2-'71-43-2————

10061-02-6——————TRANS-1, 3-DICHLOROPROPENE _75-25-2- __103-10-1—————4-METHYL-2-PE: _____591-73-5—————2-HEXANONB______________127-13-4—————TETRACHLOROETHENE ________79-34-5——————1,1,2,2-TETRACHLOROETHANE _

1 rt £ » Q 1 -^ A. m f ^ M m m m 1 ^ ^ T S S M'- yfTHTtfiyJLUO -7 J —4—^—~— — A f Z Ui-OItVjr_VJJl AflACiIi103-33-3—————TOLUENE ________________108-90-7—————CHLOROBENZENE ____________100-41-4——————ETHYLBENZENE______________100-42-5—————STYRENE ________________1330-20-7——————XYLENE (TOTAL)____________541-73-1—————1,3-:106-46-7 ————— 1,4-DICHLOROBENZENE95-50-1—————1,2- _______96-12-3—————l,2-DIBROMO-3-CHLOROPROPANE

1. |U1. |U1. JU1. iU2. |U4. J J.0.7 i J1. }U1. [U1. |U1. [U1. }Ui; |us. |u1. ,'U1. iu1. [U1. !U1. [U1. (U1. [U1. JU1. {U1. {U1. ,'U1. JU5. !U5. |ul. iu1. {U1. |U1. JU1. [U1. {U1. }U1. [U1. JU1. JU1. JU1. JU


AR305Q3J

tlJ ,[._.+•

IE 00101 fe$A SAMPLE NOVOLATILE ORGANICS ANALYSIS DATA SHEET _____________TENTATIVELY IDENTIFIED COMPOUNDS

Lab Name: SWRI < Contract: 68-D9-0135•VBLK01 J

Lab Code: SWRI Case No.:17359 SAS: 6701EQ SDG No.: 6701EQ-01

Matrix: (soil /water) WATER Lab Sample ID: VBLK01

Sample wt/vol: 5.000 (g/mL) ML Lab File ID: G1108B1

Level: (low/med) LOW Date Received: O/ O/ 0


Column: (pack/cap) CAP Dilution Factor: 1.00

CONCENTRATION UNITS:Number TICs found: 0 . (ug/L or ug/Kg) UG/L

.CAS NUMBER

1.2.3.4.5.6.7.8.9.10.11.12.13.14.15.16.'17.18.19.20.21.22.23.24.25.26.27.28.29.30.

COMPOUND NAME

.

'•

-

•

RT

^

•

EST. CONC.

•

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Q


SR305032

1A 0010 £4*6SAMPLE NO.VOLATILE ORGANICS ANALYSIS DATA SHEET _ _ _ _ _ _ _ _ _

Lab Name: SWRI Contract: 63-D9-0135VBLK02

Lab Code: SWRI Case No.: 17359 SAS: 57013Q SDG No.: 6701HQ-01Matrix: (soil/water) WATER Lab Sample ID: V3LX02

Sample wt/vol: 5.000 (g/mL) ML Lab Fila ID: G111131

Level: (low/mad) LOW Data Received: O/ O/ 0% Moisture: not dec. 100. Data Analyzed: 11/11/91



74-37-3—————CHLOROMETHANE _____74-33-9—————3ROMOMETHANE_____75-01-4—————VINYL CHLORIDE75-00-3—————CHLOROETHANE_____7 5-09-2-—————METHYLENE - CHLORIDE67-64-1—————ACETONE ______•75-15-0—————CARBON DISULFIDE__75-35-4—————1, 1-DICHLOROETHENE75-34-3—————1,1-DICHLOROETHANE"156-59-4—————CIS-1,2-DICHLOROETHENE _156-60-5—————TRANS-1,2-DICHLOROETHENE57-66-3—————CHLOROFORM___________107-06-2—————1,2-DICHLOROETHANB•78-93-3——————2-3UTANONE_________74-97-5—————3ROMOCHLOROMSTHANE __71-55-6—————1, 1,1-TRICHLOROETHANE56-23-5—————CARBON TETRACHLORIDE75-27-4—————3ROMODICHLOROMETHANE__73-37-5—————1,2-DICHLOROPROPANE _

10061-01-5—————CIS-1,3-DICHLOROPROPENE79-01-5—————TRICHLOROETHENE ________124-43-1—————DI3ROMOCHLOROHETHANB \79-00-5—————1,1,2-TRICHLOROETHANE ___71-43-2——————3EN2ENB ______________

10061-02-6—————TRANS-1, 3 -DIC3LOROPROPENB75-25-2—————3ROMOFORM _____________~108-10-1—————4-METHYL-2-PENTANONE_______591-73-5—————2-HEXANONE _ _____127-13-4—————TETRACHLOROETHENE ________79-34-5—————1,1,2,2-TETRACHLOROETHANE _106-93-4—————1,2-DIBROMOETHANE_________103-38-3—————TOLUENE ________________103-90-7—————CHLOROBENZENE ___________100-41-4—————ETHYLBENZENE_____________100-42-5—————STYRENE ________________1330-20-7—————XYLENE (TOTAL)___________541-73.-1—————1,3-DICHLOROBENZENE_______106-46-7—————1,4-DICHLOROBENZENE_______95-50-1—————1,2-DICHLOROBENZENE______;96-12-3--———-1,2-DI3ROMO-3-CHLOROPROPANE_

1. JU1. JU1. JU1. JU2. JU5. JU1. JU1. JU1. JU1. JU1. JU1. }U1. JU5. JU1. JU1. JU1. JU1. JU1. JU1. JU1. {U1. [U1. !U1. }u1. JU1. iu5. JU5. JU1. JU1. JU1. JU1. JU1. JU1. JU1. {U1. }U1. JU1. }U1. JU1. {U


AR305033

IE 00101 IE!A SAMPLE NOVOLATILE ORGANICS ANALYSIS DATA SHEET _________ _TENTATIVELY IDENTIFIED COMPOUNDS

Lab Name: SWRI ? Contract: j6'8-*D9-0135VBLK02

Lab Code: SWRI Case No.:17359 SAS: 6701EQ SDG No.: 6701HQ-01

Matrix: (soil/water) WATER Lab Sample ID: VBLK02*

Sample vt/vol: 5.000 (g/mL) ML Lab File ID: G1111B1

Level: (low/med) LOW Date Received: O/ O/ 0

% Moisture: not dec. 100. Date Analyzed: 11/11/91

Column: (pack/cap) CAP Dilution Factor: 1.00

CONCENTRATION UNITS:Number TICs found: 0 . (ug/L or ug/Kg) UG/L

CAS NUMBER

1.2.3.4.5.6.7.8.9.10.11.12.13.14.15.16.17.18.19.20.21.22.23.24.25.26.27.28.29.30.

COMPOUND NAME

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EST. CONC.

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. 1A U U 1 0 %2ftOSAMPLE NO.VOLATILE ORGANICS ANALYSIS DATA SHEET

Lab Name: SWRI Contract: 63-09-0135VLCS01

Lab Coda: SWRI Case No.:17359 SAS: 6701HQ SDG No.: 6701HQ-01Matrix: (soil/water) WATER Lab Sample ID:VLCS01

Purge Volume: 5.000 {g/mL) ML Lab Fila ID: G110301

Level: (low/mad) LOW Data Received: 10/30/91% Moisture: not dec. 100. Date Analyzed: ll/ 3/91



74-37-3—————CHLOROMETHANE _______74-33-9——————BROMOMETHANB^________75-01-4——————VINYL CHLORIDE_______75-00-3—————CHLOROETHANE________75-09-2—————METHYLENE CHLORIDE___67-54-1——————ACETONE ____________75-15-0—————CARBON DISULFIDE_____75-35-4 ————— 1,1-DICHLOROETHENE___75-34-3—————-1,1-DICHLOROSTHAN2___156-59-4——————CIS-1, 2-DICHLOROETHENE _156-60-5—————TRANS-1,2-DICHLOROETHENE67-56-3——————CHLOROFORM107-06-2——————1, 2-DICHLOROETHANE73-93-3—————2-3UTANONE__________.74-97-5——————3ROMOCHLOROMETHANE __71-55-6——————1,1,1-TRICHLOROETHANE56-23-5——————CARBON TETRACHLORIDEj75-27-4—————3ROMODIC3LOROMETHANE_78-37-5——————1,2-DICHLOROPROPANE

10061-01-5—————CIS-1,3-DICHLOROPROPENE79-01-6——————TRICHLOROETHENE ____124-43-1 ——————DI3ROMOCHLOROMETHANE__79-00-5———:——1, 1,2-TRICHLOROETHANE71-43-2—————BENZENE __________

10061-02-5——————TRANS-1,3-DICHLOROPROPENE75-25-2——————3ROMOFORM _________108-10-1—————4-METHYL-2-PENTANONE591-73-5—————2-3EXANONE_________127-13-4—————TETRACHLOROETHENE79-34-5—————1,1,2,2-TETRACHLOROETHANE _106-93-4—————1,2-DIBROMOETHANB_________103-33-3—————TOLUENE ____________________103-90-7—————CHLOROBENZENB ___________100-41-4—————ETHYLBENZENE_____________100-42-5—————STYRENB ________________1330-20-7—————XYLENE (TOTAL)___________541-73-1——————1,3-DICHLOROBENZENB_______106-46-7——————1,4-DICHLOROBENZENE_______95-50-1—————1,2-DICHLOROBENZENE_________96-12-3—————l,2-DI3ROMO-3-CHLOROPROPANE

1. JU1. JU6. \1. JU2. {U5. JU1. JU1. {U1. JU1. JU1. JU1. }U5. J5. {U1. JU1. JU5. !1. JU5. J1. JU5. !1. JU5.5.4.5.5. JU5. {U5. !1. |U4.1. JU1. JU1. JU1. JU1. JU1. {U4. J1. JU1. JU

________________________ ____FORM I VOA 6/91 Rev.

aR305Q35

3A ' . U U 1 UH£H SAMPLE NO.WATER VOLATILE LAB CONTROL SAMPLE' RECOVERY ______.________

ib Name: SWRI Contract: 68-09-0135VLCS01

Code: SWRI Case No.: 17359 SAS No.: 6701SQ SDG No.: 6701HQ-01

Sample ID: VLCS01 ' LCS Lot NdtjIV'f

,ab File ID: G110801 Date Analyzed: ll/ 8/91

xge Volume: 5 (ml) Dilution Factor: 1.00

-.S Aliquot: (ul)

. COMPOUND

Vinvl Cloride1 , 2-Dichloroe thaneCarbon Tetrachloride •1 , 2-DichloropropaneTrichloroethene1,1, 2-Trichloroethane ___

• Benzenetrans-1 , 3-DichloropropeneBromoformrtrachloroethene

V >2-Dibromoethane~1 , 4-Dichlorobenzene

AMOUNTADDED(NG)

25,25.25.25.25.25.25.25.25.25.25.25.

AMOUNTRECOVERED

(NG)

28.27.27.25.24.25.23.23.24.24.22.21.

%REC

112108108100961009292969688

„ 84

i ii QC i

f J LIMITS!_ 1 _ _____ ___ |

J 60-140JJ 60-140!J 60-140![60-140![60-140JJ 60-140J| 60-140 JJ 60-140JJ 60-140!J 60-140JJ60-140JJ 60-140}i ii i

Column to be used to flag LCS recovery with an asterisk

Values outside of QC limits

Ipike Recovery: 0 out of 12 outside limits

3MMENTS:

FORM III LCV 6/91 Rev,

AR305036

ATTACHMENTS

Aft305037

a

DRINKING WATER REGULATIONSAND HEALTH ADVISORIES

ByOffice of Drinking Water

U.S. Environmental Protection AgencyWashington, D.C,

SAFE DRINKING WATER HOTLINE1-800-426-4791 (Toll-Free)

'202-382-5533(Washington, D.C.)Monday thru Friday, 8:30 AM to 4:30 PM EST

April 1990

HR305038

LEGEND

Abbreviations column descriptions are:

NIPDWR - National Interim Primary Drinking Water Regulation. Interim enforceable drinkingwater regulations first established under the Safe Drinking Water Act that areprotective of public health to the extent feasible.

MCLG - Maximum Contaminant Level Goal. A non-enforceable concentration of a drinkingwater contaminant that is protective of adverse human health effects and allows anadequate margin of safety.

MCL - Maximum Contaminant Level. Maximum permissible level of a contaminant in waterwhich is delivered to any user of a public water system.

RfD • Reference Dose. An estimate of a daily exposure to the human population that islikely to be without appreciable risk of deleterious effects over a lifetime.

DWEL - Drinking Water Equivalent Level. A lifetime exposure concentration protective ofadverse, non-cancer health effects, that assumes all of the exposure to acontaminant is from a drinking water source.

(*) The codes for the Status Reg and Status HA columns are as follows:

£ - finalD • draft__, - listed for regulationP - proposed (Phase II draft proposal)I - tentative (Phase V)

V

Other codes found in the table include the following:

NA - not applicablePS • performance standard 0.5 NTU • 1.0 NTUTT • treatment technique

** - No more than 5% of the samples may be positive. For systems collecting fewerthan 40 samples/month, no more than 1 sample may be positive.

*•** guidance

Large discrepances between Lifetime and Longer-term HA values may occurbecause of the Agency's conservative policies, especially with regard tocarcinogenicJty, relative source contribution, and less than lifetime exposures inchronic toxicity testing. These factors can result in a cumulative UP (uncertaintyfactor) of 10 to 1000. when calculating a Lifetime HA.

AR305039

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