Demonstration of the DMX™ process descripppjtion of the ... pdfs/8_3_PCCC2... · Demonstration of...
Transcript of Demonstration of the DMX™ process descripppjtion of the ... pdfs/8_3_PCCC2... · Demonstration of...
Renewable energies | Eco-friendly production | Innovative transport | Eco-efficient processes | Sustainable resources
Demonstration of the DMX™ processdescription of the Octavius SP3 projectp p j
Ludovic Raynal1, Cristiana La Marca2, Jan Mertens3, Laurent Normand4 and Paul Broutin1Laurent Normand and Paul Broutin
+ other colleagues !1IFPEN, 2ENEL, 3LABORELEC, 4PROSERNAT
rgie
s no
uvel
les
© 2
010
-IFP
Ene
r
IEA-GHG 2nd Post-Combustion Capture Conference
17th -20th September 2013, Bergen, Norway
Outlook
Octavius project
DMX™ process
SP3 : Demonstration of the DMX™ process
Ene
rgie
s no
uvel
les Conclusions & future work
© 2
010
-IFP
PCCC2 – Bergen - 17-20/09/132
OCTAVIUS in Brief Optimisation of CO2 Capture Technology Allowing
Verification and Implementation at Utility ScaleFP7 Project (Call DG Energy 2011)FP7 Project (Call DG Energy 2011)
Start-up: 01/03/2012 Duration : 60 Months Coordinator IFPEN
Ene
rgie
s no
uvel
les (Paul BROUTIN)
Total Budget: 13.56 M€ EU Funding: 7 96 M€
Kick-off Meeting on 13-14 March 2012 in Solaize
© 2
010
-IFP
PCCC2 – Bergen - 17-20/09/1333
EU Funding: 7.96 M€
17 Partners + 1 Sponsor
Ene
rgie
s no
uvel
les
© 2
010
-IFP
PCCC2 – Bergen - 17-20/09/1344
Sub-Project SP3 Sponsor: TOTAL (F)
OCTAVIUS Organisation
2 main technical Sub-Projects SP2 dedicated to demonstration of operability and flexibility
aspects of first generation processes to be used for first full scale demo plant (ROAD and Porto Tolle Projects)
SP3 dedicated to the demonstration of the DMXTM process 2 independent Subprojects
a R&D Sub-Project
Ene
rgie
s no
uvel
les
a R&D Sub Project SP1 will support SP2 & SP3 and will also include cross-
cutting issues such as benchmarking activities
© 2
010
-IFP
PCCC2 – Bergen - 17-20/09/1355
Outlook
Octavius project
DMX™ process
SP3 : Demonstration of the DMX™ process
Ene
rgie
s no
uvel
les Conclusions & future work
© 2
010
-IFP
PCCC2 – Bergen - 17-20/09/136
Post-combustion capture@ IFP Energies nouvelles
Development of new PCC processes G1 : industrial pilot tests => commercialization HiCapt+™ : 40 wt.% MEA + additives
G2 : R&D developments => industrial pilot tests DMX™
G3 : laboratory studies – proof of concept
Ene
rgie
s no
uvel
les
new chemistry solvents, sorbents, hydrates...
Development of new technologies
© 2
010
-IFP
PCCC2 – Bergen - 17-20/09/137
Development of new technologies gas/liquid contacting devices ...
HiCapt+ process Degradation tests
very good performances of the oxidative inhibitor Corrosion tests
MEA 40 wt % after 1000 h mini-pilot test (with and
without inhibitor)
Identification of materials with no corrosion in presence of the oxidative inhibitor (e.g. Duplex steel)
Price difference is very small (higher cost but less material since better mechanical properties) + availability of material is industrialbetter mechanical properties) + availability of material is industrial
20000
25000
30000
on (
ppm
)
250
300
350
400formiate
acetateoxalate20000
25000
30000
on (
ppm
)
250
300
350
400formiate
acetateoxalate
5
6
7
8 NoneU1U2V1V2V3
0.12
0.14
5
6
7
8 NoneU1U2V1V2V3
0.12
0.14
Ene
rgie
s no
uvel
les
0
5000
10000
15000
Ani
on C
ance
ntra
tio
0
50
100
150
200
250
U2 V1 V2 Y1
nitratenitrite
0
5000
10000
15000
Ani
on C
ance
ntra
tio
0
50
100
150
200
250
U2 V1 V2 Y1
nitratenitrite
1
2
3
4
5N
H3
mM
/hV3W1W2W3Y1Y2
0.00
0.02
0.04
0.06
0.08
0.10
0 50 100 1501
2
3
4
5N
H3
mM
/hV3W1W2W3Y1Y2
0.00
0.02
0.04
0.06
0.08
0.10
0 50 100 150
© 2
010
-IFP
PCCC2 – Bergen - 17-20/09/1388
0none U2 V1 V2 Y1
Inhibitors (0,25%-wt)
MEA 40% at 80 C under air + CO2 during 12 days
0none U2 V1 V2 Y1
Inhibitors (0,25%-wt)
MEA 40% at 80 C under air + CO2 during 12 days MEA 30% at 80 C under air + CO2 during 7 days
00 20 40 60 80 100 120 140 160 180
Time (h)
MEA 30% at 80 C under air + CO2 during 7 days
00 20 40 60 80 100 120 140 160 180
Time (h)
Pilot plant presentationMain Characteristics
CCS unit – Main equipments
Absorber1 / 4 Фi = 1.5 m / HLT = 45 m
3 stages solvent inlet Stripper
Фi = 1.3 m / HLT = 31 m Reboiler : Kettle type ~ 1 to 3 MWth
Solvent / Solvent cross heat exchanger
Ene
rgie
s no
uvel
les
Plates type
© 2
010
-IFP
PCCC2 – Bergen - 17-20/09/1399
HiCapt+ main conclusionsLong run industrial pilot test main results (Enel – Brindisi)
Test duration : 380 h CO2 prod. : 2 327 kg/h Efficiency : 89,7 % Loadings : αL = 0,23 αR = 0,48 Energy : ~ 3,02 GJ/tCO2 in good agreement with process simulations ready for in good agreement with process simulations
Lab and mini-pilot test main results (IFPEN)
ready for commercialization
Ene
rgie
s no
uvel
les use of additives
no or little degradation much lower emissions
i ith D l ( i h t i )
© 2
010
-IFP
PCCC2 – Bergen - 17-20/09/131010
no corrosion with Duplex (even in hot regions)
Gas Treated
CO2 lean amine
LP CO2 HP CO2
DMX™ ABSO
STRI
DecanterLean amine
CO2 richi
ORB
ER
IPPER
Flue Gas
amine
CO2
Rich amineReboiler
Leanamine
DMX-1™ : a low stripping low heat ofDMX 1 : a low stripping, low heat of reaction, high capacity demixing solvent
+ lower degradation (and further lower emissions => interest in HP stripper) //
Ene
rgie
s no
uvel
les
CO2 lean phase
emissions > interest in HP stripper) // no corrosion
2.5 – 2.1 GJ/ton CO2
© 2
010
-IFP
PCCC2 – Bergen - 17-20/09/1311
CO2 rich phase -20-30 % in CO2 total cost
Scientific & Technical information VLLE data + adapted thermodynamic model Degradation / Emissions / Corrosion Operational issues Kinetics & Mass transfer performances Laboratory and mini-pilot testsy p Process simulations / cost evaluations
Ene
rgie
s no
uvel
les
© 2
010
-IFP
PCCC2 – Bergen - 17-20/09/1312
DMX-1 Process – Full Scale Unit PFD23
20
11E104
21
22
E105V102
24
K201ACOMP
14
25
E102
11
10T101
Amine makeup
17
18
12
V103E102
6bP102
P101
Water makeup
To Water makeup
V1
7
C102
E101E
2
V101A
C101
V2
3
E101A
6
14
16P104
C1004
5b
V101C
P102
4.6 bar
V3
Ene
rgie
s no
uvel
les
1
E106
13
3
5
P101
K101
C100
E301
P301
P302
P102
P303
7.97.7
© 2
010
-IFP
PCCC2 – Bergen - 17-20/09/1313
P303
P304
Steam Cycle Simulation: IFPEN model Temperature and pressure levels available
T=602°CP=278 bar
T=410°CP=90 bar
T=600°CP=56.8 bar
T=462°CP=24.3 bar
T=377°CP=13.4 bar
T=355°CP=61.4 bar
T=285°CP=6.5 bar
T=189°CP=2.7 bar
T=105°CP=1.09 bar
T=67°CP=0.27 bar
T=27°CP=0.035 bar
Ene
rgie
s no
uvel
les
© 2
010
-IFP
PCCC2 – Bergen - 17-20/09/1314
Thermodynamic model: ASME 1967 steam table correlationsHeat Exchanger pinch: 5 °C, pressure drop neglected
Outlook
Octavius project
DMX™ process
SP3 : Demonstration of the DMX™ process
Ene
rgie
s no
uvel
les Conclusions & future work
© 2
010
-IFP
PCCC2 – Bergen - 17-20/09/1315
Methodology
Full scale -feasibility study
PilotLab
MethodologyFrom lab to Pilot demonstration
- Process testing- Analytical methodologies
development
Flue gases : 10.000 Nm3/hCO2 : 2500 kg/hProcess modeling - Process Design
Ene
rgie
s no
uvel
les - Performance testing
- Validation of design- Emissions measurement and
waste characterization- Development and testing
modeling tools
• Criteria for technology scale-up• Full scale application Capex and
Opex evaluation (cost of CO2 avoided)
• Basic engineering
© 2
010
-IFP
PCCC2 – Bergen - 17-20/09/131616
modeling tools • Basic engineering
SP3 Structure & Objectives
SP3 Objectives
The main objective of SP3 is to demonstrate the DMX TM process on pilot scale and study its application to coal power station and NGCC units with industrial pilot test on the Enel’s coal fired power plant of Brindisi.
SP 3: Demonstration of the DMXTM process
p p
WP 3.1Definition of the Brindisipilot plant revamping
WP 3.2Retrofit of the Brindisi pilot
plant
WP 3.3Demonstration of the DMX process
WP 3.4DMX
Evaluation for PC case
WP 3.5DMX
evaluation for NGCC case
Ene
rgie
s no
uvel
les
Go / No Go decision11th Dec. 2013
Technical Criteria :energy consumptionsolvent degradation and emissionmain component design criteria
S
© 2
010
-IFP
PCCC2 – Bergen - 17-20/09/131717
HSECapex and Opex of full scale application
Financial Criteria : cost of retrofit (budget !)
SP3 Work Packages Description – WP3.1WP 3.1: Definition of the Brindisi pilot plant revamping
Participants: IFPEN, Enel, Laborelec/GDF SUEZ, Prosernat
Objectives
• Define modifications to be carried out on Enel Brindisi CO2 capture pilot plant to test DMX• Design and Estimate the cost of the pilot revamping
TaskTask
• 3.1.1 Experimentation of DMX on Enel minipilot at Brindisi lab facilities and at IFPENresearch centre• 3 1 2 Experimentation at IFPEN on decantation rate on a representative cold mock-up
Ene
rgie
s no
uvel
les
3.1.2 Experimentation at IFPEN on decantation rate on a representative cold mock up• 3.1.3 Preliminary process study– full scale case• 3.1.4 FEED for Enel CO2 capture pilot plant revamping• 3.1.5 Cost estimation of revamping
© 2
010
-IFP
PCCC2 – Bergen - 17-20/09/131818
Minipilot activities - Enel mini-pilot
Brindisi pilot:
Sensitivity test: to optimize the mini-pilot plant
operating conditionsp g
Long run test: focused on the study of solvent’s
degradation / emissions in the optimized g p
conditions.
Flue gas condition Brindisi pilot:
E i i t ti i ti f
Ene
rgie
s no
uvel
les Emissions measurements: participation of
Laborelec via FTIR measurements (with
calibration at IFPEN)
© 2
010
-IFP
PCCC2 – Bergen - 17-20/09/131919
Lab & Minipilot activities – IFPEN
Target :Bottle-tests decantationUltaturrax – 11,000 rpm
dmax (mm)
fresh case 3.9
degraded 2.5
Demixing test to decanter design
Capture efficiency (lean and reach loadings)
Solvent degradation g
Semi-open batch reactor degradation testsT = 80°C, Patm
Emission
Corrosion
IFPEN Lab test
VLE data + adapted thermodynamic model
Degradation / Corrosion and other % amine lossa [formiate]
T 80 C, PatmPO2 = 200mbar PCO2 = 4.6mbarVsolvent = 130 ml1 week
Ene
rgie
s no
uvel
les
Degradation / Corrosion and other
operational issues
Kinetics & Mass transfer performances
L/L decantation – effect of degradation
[ ]ppmb
DMX-1 6% 100
MEA 58% 19000
Ratio 0.10 0.005
© 2
010
-IFP
PCCC2 – Bergen - 17-20/09/1320
L/L decantation effect of degradation
a : GC analysisb : IC analysis
Lab & Minipilot activities – IFPEN
Target :
Demixing test to decanter design
Capture efficiency (lean and reach loadings)
Solvent degradation
Emission
Corrosion
IFPEN mini-pilot
Mechanical/validation tests : T1 2013
Operation on a 24/7 basis
Ene
rgie
s no
uvel
les
Operation on a 24/7 basis
Long run tests on MEA (reference case) : 1000 hrs
Long run tests on DMX : in progress
Operation on representative synthetic gas (SOx/NOx)
© 2
010
-IFP
PCCC2 – Bergen - 17-20/09/1321
Operation on representative synthetic gas (SOx/NOx)
Full scale application and costing
Preliminary process study for application on a 660 MWe power plant, comparison between two cases:
Assessment of the energy consumption :
comparison between two cases: MEA 30% (benchmarking) DMX
Assessment of the energy consumption : Process scheme definition (steam turbine and capture process):
Definition of the steam turbine scheme and optimization for the two cases Simulation and evaluation of the impact on the thermal cycle for each capture Simulation and evaluation of the impact on the thermal cycle for each capture
process CAPEX and OPEX estimation:
Definition of the method
Ene
rgie
s no
uvel
les Cost estimation with accuracy ± 30%
Final comparison based on : LCOE
C t f CO2 id d
© 2
010
-IFP
PCCC2 – Bergen - 17-20/09/1322
Cost of CO2 avoided
FEED study for Enel’s pilot revamping
Pre-FEED in 2012 with strong interaction betweenENEL / IFPEN / PROSERNAT teams
FEED : ENEL engineering + PROSERNAT withf IFPENsupport of IFPEN
Kick-Off Meeting in Milan (28th May 2013) basis of design Heat and Mass Bances
PFD PID PFD – PID piping classes list of chemicals Process Data Sheets of main/retrofitted equipments Instrument list + controls
Ene
rgie
s no
uvel
les Plot plan
Operating manual Cost estimation
HAZOP meeting (30th Sept. 2nd Oct. 2013)
© 2
010
-IFP
PCCC2 – Bergen - 17-20/09/1323
Final documents for November
23
Outlook
Octavius project
DMX™ process
SP3 : Demonstration of the DMX™ process
Ene
rgie
s no
uvel
les Conclusions & future work
© 2
010
-IFP
PCCC2 – Bergen - 17-20/09/1324
Conclusions & perspectives Conclusions
HiCapt+ : a G1 process (MEA 40wt.% + proprietary oxidation inhibitor + material recommendation) => PROSERNATinhibitor + material recommendation) => PROSERNAT
DMX-1™ : a promising G2 process under development for reducing energy penaltyl d ti i i il t t t FEED t d f E l’ il t long duration mini-pilot tests + FEED study for Enel’s pilot retrofit under progress
Future steps
Ene
rgie
s no
uvel
les
Octavius EU project - Go/NoGo milestone Dec. 2013 (technical – financial criteria – budget !)
tests of DMX-1 on Enel's Brindisi industrial pilot for further
© 2
010
-IFP
PCCC2 – Bergen - 17-20/09/1325
pevaluation on full scale cases – tests in 2015-2016
process ready for commercialization T1 2017
Thank you !Thank you !@
Ene
rgie
s no
uvel
© 2
010
-IFP
PCCC2 – Bergen - 17-20/09/1326