Data validation rpt: #23009, memo #9, 20 soil samples for ... · Regional Sample number on the...

ICF KAISERENVIRONMENT & ENERGY GROUP

ICF Kaiser Engineers, Inc.160 Spear Street, Suite 1380San Francisco, CA 94105-1535415/882-3000 Fax 415/882-3199

SFUND RECORDS CTR4913-00074

MEMORANDUM

TO:

THROUGH:

FROM:

DATE:

SUBJECT:

REVIEWER:

SFUND RECORDS CTR

222407

Brad ShipleyOn- Scene CoordinatorEmergency Response Section, H-8-3

Richard BauerData Validation Task Monitor, USEPA, Region 9Quality Assurance Management Section (QAMS) , P-3-2

Margie D. Weinerior Data Review Oversight Chemist

Environmental Services Assistance Team (ESAT) , Region 9

February 14, 1995

CADRE (Computer-Aided Data Review and Evaluation) of Analytical Data

Mike Mclntosh, ESAT/ICF Kaiser

Attached are final spreadsheets, intermediate spreadsheets, and validationcomments resulting from the CADRE review of the following analytical data:

SITE:EPA SSI NO. :CERCLIS ID No.

CASE/SAS NO.:SDG NO. :

LABORATORY:ANALYSIS:

SAMPLE NO.:

Central Eureka MineZZCA0000726539

23009 Memo #09MYQ229

CompuChem Environmental Corporation (COMPU)Total Metals

20 Soil Samples

COLLECTION DATE: November 30 and December 2 and 3, 1994

As requested, the subject data were reviewed by CADRE 2.1 for validationpurposes. CADRE 2.1 is a software, program designed to check results againstestablished criteria and validate the results based on established protocols .CADRE used the "USEPA Contract Laboratory Program Statement of Work forInorganics Analysis" (ILM03.0), and the EPA draft document, "Laboratory DataValidation Functional Guidelines for Evaluating Inorganic Analyses," January,1993, for qualification guidelines.

ESAT-QA-9A-11044/23009M09.MEM of 3

ICF KAISER

A table listing the CADRE reports included in this memorandum is presentedbelow. Also presented below are comments addressing the items found inCADRE's file importation process and differences noted between CADRE'svalidation report and validation by ESAT Standard Operating Procedures (SOPs)

The comments presented in this report have been reviewed and approved by theEPA Task Monitor for the ESAT Contract, whose signature appears above.

CADRE REPORTS: TABLE OF CONTENTS

I. Final SpreadsheetsII. Intermediate SpreadsheetsIII. Validation Comments

A. Holding Time ReportB. Calibration ReportC. Matrix Spike ReportD. CRDL Standards ReportE. ICS ReportF. LCS ReportG. Duplicate ReportH. Serial Dilution ReportI. Sample Result Verification ReportJ. Laboratory Blanks ReportK. Flag Definitions Report

COMMENTS:

1. During the importation of data, CADRE 2.1 checks for missinginformation. The reviewer enters the missing information intoCADRE 2.1, if possible.

2. The Calibration, Interference Check Sample (ICS), and the LaboratoryControl Sample (LCS) Reports, indicate that the calibration standards,the ICS, and the LCS were not analyzed at the required frequency.However, the analysis run logs, Form 14s, indicate that the frequencyrequirements were met.

3. According to the Functional Guidelines, the acceptance criterion of ICPserial dilution percent difference is 10. ESAT uses a limit of 10.5%,while CADRE uses a limit of 10.0%.

4. ESAT qualifies samples only when blank contamination exceeds the CRDL(Contract Required Detection Limit) values. CADRE qualifies sampleswhen blank contamination exceeds the IDL (Instrument Detection Limit)values.

5. ESAT compares field duplicate sample results and includes a comparisonin the ESAT validation report when the results are inconsistent. CADREdoes not compare field duplicate sample results.

ESAT-QA-9A-11044/23009M09.MEM of 3

ICF KAISER6. Spot checks were performed in the CADRE report, and where discrepancies

or insufficient information were found, the ESAT reviewer madecorrections.

7. Field duplicate pairs are identified by Dl, D2, D3, etc., next to theRegional Sample number on the final spreadsheets. Duplicate pairs inthis report are listed below.

Pup. Pair # Sample Numbers

Dl MYQ236 and MYQ264*D2 MYQ239 and MYQ265*D3 MYQ240 and MYQ266*

^Results for field duplicate samples MYQ264 through MYQ266 are in Case23009 Memo #03, SDG MYQ249.

8. Results for QC samples MYQ236D and MYQ236S are not included in theintermediate and final spreadsheets.

9. ESAT checks potential positive or negative interferences for analytesthat are not present (or are low concentration) in the ICP ICS solutionA (ICSA). Deviations from the..true value must be greater than the CRDL.CADRE only checks potential interferences for analytes that are notpresent in the ICSA solution_that. have results less than the negativeIDL.

When the concentration of an analyte in a sample exceeds ten (10) ppm,CADRE comments that the analyte may be a potential interferent (seedefect code DC-312 in the CADRE ICS Report). ESAT does not normallycheck the potential interference effects of analytes other thanaluminum, calcium, iron, and magnesium.

10. For the CRDL Standards Report, ESAT acceptance criteria of 65-135%recovery are used. The Functional Guidelines do not providequalification guidelines for CRDL standards. The CADRE CRDL StandardsReport indicated that CRDL data for iron was missing. However, theFunctional Guidelines does not require iron to be present in the CRDLstandard. The CRDL Standards Report is included to provide additionalinformation to the user.

If there are any questions, please contact Margie D. Weiner (ESAT/ICF) at(415) 882-3061 or Richard Bauer (QAMS/EPA) at (415) 744-1499.

Attachments

cc: Tom B. Bennett, Jr., TPO USEPA Region 4

ESAT-QA-9A-11044/23009M09.MEM of 3

I. FINAL SPREADSHEETS

TAL QUALIFIED SPREADSHEETCASE NO: 23009 SITE:SDG NO: MYQ229 LABORATORY: COMPUCHEM LABORATORIES, I

EPA SAMPLE NUMBER:REGIONAL SAMPLE NUMBER:SAMPLE LOCATION:SAMPLE TYPE:MATRIX/ANALYSIS:DILUTION FACTOR:PERCENT SOLID:

INORG

AluminumAntimonyArsenicBar innBerylliumCadmiumCalciumChromiumCobaltCopperIronLeadMagnesiumManganeseMercuryNickelPotassiumSeleniumSilverSodiumThalliumVanadiumZincCyanide

MYQ229

Hfi-HW*Routine SampleSOIL/LOW

77.2

158000.31 R68.91620.590.8110800 J34.6 J25.475.0 J4190014.3637011100.3922.825000.87 UJ0.2954.6 UJ1.2 UJ107

65.6

MYQ230

HA-ll-21Routine SampleSOIL/LOW

81.4

190000.29 R83.21700.681.06880 J37.6 J25.975.4 J4790012.3601012400.3516.526800.82 UJ0.2851.3 UJ1.1 UJ13176.6

MYQ231

#/?-YJ-3"Routine SampleSOIL/LOW

80.6

248000.29 R71.6184

0.871.7

17800 J28.1 J28.4127 J

5930012.3632012400.2320.638900.81 UJ0.3350.8 UJ1.1 UJ16276.6

MYQ232

ffA-t$-l'Z"Routine SampleSOIL/LOU

80.2

286000.29 R40.92300.901.66980 J20.5 J31.5129 J

63600 yt9.8668014400.2214.946600.870.3452.1 UJ1.1 UJ169

77.8

MYQ233

#A-is~r&"Routine SampleSOIL/LOU

84.6

76900.28 R20550.30.260.7322600 J16.0 J11.452.9 J2820018.783605760.5519.68620.78 UJ0.3648.9 UJ1.0 UJ

42.261.1

FILENAME: IMYQ229.SDG DATE: 02/13/95 TIME: 13:12 CADRE 2Y10 PAGE: 1

Water units are reported in ug/L.Soil units are reported in ug/Kg.

TAL QUALIFIED SPREADSHEETCASE NO: 23009 SITE:SDG NO: HYQ229 LABORATORY: COMPUCHEM LABORATORIES, I


INORG

AluminumAntimonyArsenicBariumBerylliumCadmiumCalciumChromiumCobaltCopperIronLeadMagnesiumManganeseMercuryNickelPotassiumSeleniumSi IverSodiumThalliumVanadiumZincCyanide

MYQ234

rt/)-^-<rRoutine SampleSOIL/LOW

85.2

148000.27 R1331280.481.1

14000 J31.5 J21.467.2 J3800012.679309280.2019.218400.77 UJ0.3648.1 UJ1.0 UJ84.666.0

MYQ235

HA-W-H'Routine SampleSOIL/LOW

86.4

158000.27 R48.3109

0.471.0

23300 J32.1 J22.181.1 J386009.964107250.10 U25.819801.2

0.2748.3 UJ1.0 UJ114

53.4

MYQ236 PI

Hfi-W-i'lo"Field DupSOIL/LOW

84.4

158000.35 UJ68.487.80.461.3

70800 J38.8 J20.282.8 J372007.97580740

0.1321.712600.79 UJ0.3049.5 UJ1.0 UJ96.252.9

MYQ237

HA-50-l'Routine SampleSOIL/LOW

80.8

46700.29 R36729.40.140.6321700 J9.0 J10.165.9 J2490018.289305170.7629.17011.2

0.8575.21.1 UJ

16.556.8

MYQ238

ttA-so-z'Routine SampleSOIL/LOW

85.4

82600.27 R264

50.10.230.6617100 J9.1 J14.675.5 J2800028.079606630.5327.412801.60.6948.0 UJ1.0 UJ43.459.3

FILENAME: IMYQ229.SDG DATE: 02/13/95 TIME: 13:12 CADRE 2.10 PAGE: 2




INORG

AluminumAntimonyArsenicBariumBerylliumCadmiumCalciumChromiumCobaltCopperIronLeadMagnesiumManganeseMercuryNickelPotassiumSeleniumSilverSodiumThalliumVanadiumZincCyanide

MYQ239 D2-"nn - 5l~3

Field DupSOIL/LOW

78.2

166000.30 R88.71340.641.2

10400 J46.8 J23.699.5 J4830045.5669010100.1719.326601.10.3952.4 UJ1.1 UJ12067.0

MYQ240 03J l|

tin -52-1 2Field DupSOIL/LOW

80.9

129000.29 R5751100.421.2

16600 J24.4 J20.390.8 J4160061.098808500.4442.318201.50.6251.6 UJ1.1 UJ67.694.3

MYQ241--- / / Vpn~yy ~2 *

Routine SampleSOIL/LOW

83.9

90100.30 UJ25177.80.300.8415500 J14.7 J14.659.9 J3250020.482707800.5525.912101.30.5049.8 UJ1.0 UJ46.372.3

MYQ2421 / "///)-J>4*' i


73.0

160000.32 R1541850.620.916960 J27.8 J20.650.9 J4140017.0586010400.3618.216200.90 UJ0.4156.7 UJ1.2 UJ102

51.9

MYQ243. _, i1/11

tift~̂ o'f 6Routine SampleSOIL/LOW

75.2

104000.32 R2621190.360.8119100 J26.6 J24.859.8 J3300024.6999011500.2253.618500.960.5156. 1 UJ1.2 UJ48.675.5





INORG


MYQ244• n

tin ~Si> "* •Routine SampleSOIL/LOW

75.0

182000.32 R153131

0.550.6710800 J13.8 J21.486.1 J4370012.469108250.8527.128600.90 UJ0.3856.2 UJ1.2 UJ108

58.3

MYQ245& CO 7"Hn~jS"*J


83.6

252000.28 R59.7107

0.631.4

15000 J11.6 J20.7130 J

60700 yt7.1

101006580.11 U9.612700.78 UJ0.2249.0 UJ1.0 UJ151

61.7

MYQ246/Ll

OU"/T

Routine SampleSOIL/LOU

81.8

194000.28 R93.097.30.601.1

19000 J11.5 J22.3

, 105 J451008.991806870.1911.311300.81 UJ0.4050.6 UJ1.1 UJ11963.2

MYQ247.aSM • n


79.4

245000.29 R48.02230.941.64200 J33.3 J26.3108 J

6020015.0556014100.4112.949500.890.3952.1 UJ1.1 UJ150

80.1

MYQ248

su ~nRoutine SampleSOIL/LOW

82.8

174000.28 R1011740.721.15630 J33.2 J19.663.2 J4330014.661408451.0

34.024701.2

0.2750.0 UJ1.1 UJ82.764.2

FILENAME: IMYQ229.SDG DATE: 02/13/95 TIME: 13:12 CADRE 2,10 PAGE: 4


J.-

II. INTERMEDIATE SPREADSHEETS

INTERMEDIATE FLAGS SPREADSHEETCASE NO: 23009 SITE:SDG NO: HYQ229 LABORATORY: COHPUCHEH LABORATORIES, I


VALIDATION RULE FLAGS

INORG

AluminumAntimonyArsenicBariumBeryl 1 innCadmiumCalciumChromiumCobaltCopperIronLeadMagnesiumManganeseMercuryNickelPotassiumSeleniumSilverSodiumThalliumVanadiumZincCyanide

MYQ229


77.2

Cone Qua 1 PM HT CA MS CR 1C LC DU SD SR LB

15800 S0.31 R R UJ /«68.9162

0.590.8110800 J J J34.6 J J J25.475.0 J J4190014.3637011100.3922.825000.87 UJ UJ0.2954.6 UJ UJ1.2 UJ UJ10765.6


to

Water units are reported in ug/L. Soil units are reported in ug/Kg.Data validated only for rule flags listed.

KEY: QL = Quant LimitIP = IPC1C = ICSSD = Serial Oil

PM = Pet MoistureIS = Internal StdCR = CRDL StdSR = Sam Res Ver

HT = Holding TimeSM = SMC/SurrLC = LCSLB = Lab Blanks

CA = CalibrationSP = System PerfDU = DuplicatesFQ = Field QC

MS = Matrix SpikesSC = Sample CleanupFA = Furnace AA QC

INTERMEDIATE FLAGS SPREADSHEETCASE NO: 23009 SITE:SDG NO: MYQ229 LABORATORY: COMPUCHEM LABORATORIES, I



INORG

AtuninunAntimonyArsenicBar innBerylliumCadmiumCalciumChromiumCobaltCopperIronLeadMagnesiumManganeseMercuryNickelPotassiumSeleniumSilverSodiumThalliumVanadiumZincCyanide

MYQ230


81.4


190000.29 R R UJ j£83.2 ^1700.681.06880 J J J37.6 J J J25.975.4 J J4790012.3601012400.3516.526800.82 UJ UJ0.2851.3 UJ UJ1.1 UJ UJ13176.6



KEY: QL = Quant LimitIP = IPC1C = ICSSD = Serial Dil



CA = CalibrationSP = System PerfDU = DuplicatesFO = Field QC


INTERMEDIATE FLAGS SPREADSHEETCASE NO: 23009 SITE:SDG NO: HYQ229 LABORATORY: COMPUCHEM LABORATORIES, I



INORG

AluminumAntimonyArsenicBariumBeryl 1 innCadmiumCalciumChromiumCobaltCopperIronLeadMagnesiumManganeseMercuryNickelPotassiumSeleniumSilverSodiumThalliumVanadiumZincCyanide

MYQ231


80.6


24800 >0.29 R R UJ X71.61840.871.7

17800 J J J28.1 J J J28.4127 J J

5930012.3632012400.2320.638900.81 UJ UJ0.3350.8 UJ UJ1.1 UJ UJ16276.6











INORG


MYQ232


80.2


286000.29 R R UJ40.92300.901.66980 J J J20.5 J J J31.5129 J/ ' J /

63600 / X9.8668014400.2214.946600.870.3452.1 UJ UJ1.1 UJ UJ16977.8











INORG

AluninumAntimonyArsenicBan inBerylli'unCadmiumCalciumChromiumCobaltCopperIronLeadMagnesiumManganeseMercuryNickelPotassiumSeleniumSilverSodiumThalliumVanadiumZincCyanide

MYQ233


84.6


76900.28 R R UJ20550.30.260.7322600 J J J16.0 J J J11.452.9 J J2820018.783605760.5519.68620.78 UJ UJ0.3648.9 UJ UJ1.0 UJ UJ

42.261.1











INORG

AluminunAntimonyArsenicBariumBerylliumCadniunCalciumChromiumCobaltCopperIronLeadMagnesiumManganeseMercuryNickelPotassiumSeleniumSilverSodiumThalliumVanadiumZincCyanide

MYQ234


85.2


148000.27 R R UJ1331280.481.1

14000 J J J31.5 J J J21.467.2 J J3800012.679309280.2019.218400.77 UJ UJ0.3648.1 UJ UJ1.0 UJ UJ84.666.0









EPA SAMPLE NUMBER:REGIONAL SAMPLE NUMBER:SAMPLE LOCATION:SAMPLE TYPE:MATRIX/ ANALYSIS:DILUTION FACTOR:PERCENT SOLID:


INORG


MYQ235


86.4


158000.27 R R UJ48.31090.471.0

23300 J J J32.1 J J J22.181 . 1 J J386009.964107250.10 U25.819801.2

0.2748.3 UJ UJ1.0 UJ UJ114

53.4



KEY: QL = Quant LimitIP = IPC1C = ICSSD = Serial DiI








INORG


MYQ236

Field DupSOIL/LOW

84.4

Cone Qua 1 PM HT CA MS CR 1C LC DU SO SR LB

158000.35WJ J f-68.487.80.461.3

70800 J J J38.8 J J J20.282.8 J J372007.975807400.1321.712600.79 UJ UJ0.3049.5 UJ UJ1.0 UJ UJ

96.252.9


ft*,Z


KEY: QL = Quant LimitIP = IPC1C = ICSSD = Serial DU





INTERMEDIATE FLAGS SPREADSHEETCASE NO: 23009 SITE:SDG NO: MYQ229 LABORATORY: COMPUCHEH LABORATORIES, I



INORG

AluninumAntimonyArsenicBariumBerylliumCadmiumCalciumChromiumCobaltCopperIronLeadMagnesiumManganeseMercuryNickelPotassiumSeleniumSilverSodiumThalliumVanadiumZincCyanide

MYQ237


80.8


46700.29 R R UJ36729.40.140.6321700 J J J9.0 J J J10.165.9 J J2490018.289305170.7629.17011.2

0.8575.21.1 UJ UJ

16.556.8



KEY: QL = Quant LimitIP = IPC1C = ICSSD = Serial DiI








INORG


MYQ238


85.4

Cone Qua 1 PH HT CA MS CR 1C LC DU SD SR LB

82600.27 R R UJ264

50.10.230.6617100 J J J

9.1 J J J14.675.5 J J2800028.079606630.5327.412801.60.6948.0 UJ UJ1.0 UJ UJ43.459.3








INTERMEDIATE FLAGS SPREADSHEETCASE NO: 23009 SITE:SDG NO: MYQ229 LABORATORY: COHPUCHEM LABORATORIES, I



INORG

AluminumAntimonyArsenicBariumBerylliumCadmiumCalciumChromiumCobaltCopperIronLeadMagnesiumManganeseMercuryNickelPotass inn.SeleniumSilverSodiumThalliumVanadiumZincCyanide

MYQ239

Field DupSOIL/LOU

78.2


166000.30 R R UJ88.71340.641.2

10400 J j J46.8 J J J23.699.5 J J4830045.5669010100.1719.326601.1

0.3952.4 UJ UJ1.1 UJ UJ120

67.0








INTERMEDIATE FLAGS SPREADSHEETCASE NO: 23009 SITE:SDG NO: HYQ229 LABORATORY: COMPUCHEH LABORATORIES, I



INORG

A I Lint nunAntimonyArsenicBariunBerylliumCadmiumCalciumChromiumCobaltCopperIronLeadMagnesiumManganeseMercuryNickelPotassiumSeleniumSilverSodiumThalliumVanadiumZincCyanide

MYQ240

Field DupSOIL/LOU

80.9


129000.29 R R UJ575110

0.421.2

16600 J J J24.4 J J J20.390.8 J J4160061.098808500.4442.318201.5

0.6251.6 UJ UJ1.1 UJ UJ

67.694.3








INTERMEDIATE FLAGS SPREADSHEETCASE NO: 23009 SITE:SDG NO: HYQ229 LABORATORY: COMPUCHEH LABORATORIES, I



INORG


MYQ241


83.9


90100.30 UJ J U25177.80.300.8415500 J J J14.7 J J J14.659.9 J J3250020.482707800.5525.912101.30.5049.8 UJ UJ1.0 UJ UJ46.372.3











INORG


MYQ242


73.0


160000.32 R R UJ1541850.620.916960 J J J27.8 J J J20.650.9 J J4140017.0586010400.3618.216200.90 UJ UJ0.4156.7 UJ UJ1.2 UJ UJ102

51.9


Uater units are reported in ug/L. Soil units are reported in ug/Kg.Data validated only for rule flags listed.









INORG

AluninunAntimonyArsenicBariumBerylliumCadmiumCalciumChromiumCobaltCopperIronLeadMagnesiumManganeseMercuryNickelPotassiumSeleniumSilverSod innThalliumVanadiumZincCyanide

MYQ243


75.2


104000.32 R R UJ2621190.360.8119100 J J J26.6 J J J24.859.8 J J3300024.6999011500.2253.618500.960.5156.1 UJ UJ1.2 UJ UJ48.675.5








INTERMEDIATE FLAGS SPREADSHEETCASE NO: 23009 SITE:SDG NO: MYQ2Z9 LABORATORY: COMPUCHEM LABORATORIES, I



INORG

AluninunAntimonyArsenicBariumBeryl 1 innCadmiumCalciumChromiumCobaltCopperIronLeadMagnesiunManganeseMercuryNickelPotass innSeleniumSilverSodiumThalliumVanadiumZincCyanide

MYQ244


75.0


182000.32 R R UJ153131

0.550.6710800 J J J13.8 J J J21.486.1 J J4370012.469108250.8527.128600.90 UJ UJ0.3856.2 UJ UJ1.2 UJ UJ108

58.3











INORG

AluminunAntimonyArsenicBar innBeryl 1 innCactniumCalciunChromiumCobaltCopperIronLeadMagnesiumManganeseMercuryNickelPotassiumSeleniumSilverSodiumThalliumVanadiumZincCyanide

MYQ245


83.6


252000.28 R R UJ59.71070.631.4

15000 J J J11.6 J J J20.7130 J> J s

60700 $ Vf7.1

101006560.11 U9.612700.78 UJ UJ0.2249.0 UJ UJ1.0 UJ UJ15161.7











INORG

AluninumAntimonyArsenicBan inBerylliumCadmiumCalciumChromiumCobaltCopperIronLeadMagnesiumManganeseMercuryNickelPotassiumSeleniumSilverSodiumThalliumVanadiumZincCyanide

MYQ246


81.8


194000.28 R R UJ93.097.30.601.1

19000 J J J11.5 J J J22.3105 J J

451008.991806870.1911.311300.81 UJ UJ0.4050.6 UJ UJ1.1 UJ UJ119

63.2











INORG


MYQ247


79.4

Cone Dual PM HT CA MS CR 1C LC DU SD SR LB

245000.29 R R UJ48.02230.941.64200 J J J33.3 J J J26.3108 J J

6020015.0556014100.4112.949500.890.3952.1 UJ UJ1.1 UJ UJ150

80.1








INTERMEDIATE FLAGS SPREADSHEETCASE NO: 23009 SITE:SDG NO: HYQ229 LABORATORY: COHPUCHEH LABORATORIES, I



INORG

AluminumAntimonyArsenicBariumBeryl LinnCadmiumCalciumChromiumCobaltCopperIronLeadMagnesiumManganeseMercuryNickelPotassiumSeleniumSilverSodiumThai I innVanadiumZincCyanide

HYQ248


82.8


174000.28 R R UJ1011740.721.15630 J J J33.2 J J J19.663.2 J J4330014.661408451.0

34.024701.2

0.2750.0 UJ UJ1.1 UJ UJ82.764.2








I. VALIDATION COMMENTS

Holding Tima Report

SDG NO:

CASE NO:

MYQ229

23009

LABORATORY: coMPOCHEM LAB

AGENCY INPUT FILE: HHQ229.IAS

HOLDING TIME CRITERIA

INORGANICS

-- Holding Time pH

Primary Expanded Primary Expanded

Metals

MercuryCyanide

180

2814

2.02.0

12.0

0.0

0.00.0

DC-271: The following inorganic samples had no sampling date.

Qualification was performed using the Verified Time of

Sample Receipt (VTSR).

Hits and non-detects are not flagged.

MYQ236, MYQ236A. MYQ2360, HYQ236S

DC-280: The following inorganic soil samples were reviewed for holding

time violations using criteria developed for water samples.

HYQ229, MYQ230, MYQ231, MYQ232, HYQ233, MYQ234

HYQ235, MYQ236, MYQ236A, MYQ236D, MYQ236S, MYQ237

MYQ238, MYQ239, HYQ240, MYQ241, MYQ242, MY0243

MYQ244. MYQ245, MYQ246, MYQ247, MYQ248

Filename: nwo.229 Date: 02/13/95 Time: 12.32 CADRE: 2.10 Page

SDG NO:CASE NO:

MYQ229

23009

Calibration Report

LABORATORY: COHPUCHKM LAB

AGENCY INPUT FILE: IHYO.229.IAS

CALIBRATION CRITERIA

INORGANICS

Percent Recovery Limits

— Primary Expanded —

Lou High Low High

Cyanide 85.00 115.00

AA 90.00 110.00

ICP 90.00 110.00Mercury 80.00 120.00

70.00 130.00

75.00 125.00

75.00 125.00

65.00 135.00

DC-301: The following inorganic samples are associated with calibration

standards which were not analyzed in the required frequency.

Please refer to the Memo for more information.

Aluminum

HYQ229, MYQ230, MYQ231, HYQ232, MYQ233, MYQ234MYQ235, MYQ236, MYQ236D, HYQ237, HYQ238, HYQ239MYQ240, MYQ241, MYQ242, MYQ243, MYQ244, MYQ245

HYQ246, MYQ247, HYQ248, PBS02

Barium

HYQ229, HYQ230, HYQ231, MYQ232, MYQ233, MYQ234

HYQ235, MYQ236, MYQ236D, MYQ236S, MYQ237, MYQ238

HYQ239, HYQ240, MYQ241, MYQ242, MYQ243, MYQ244HYQ245, HYQ246, MYQ247, MYQ248, PBS02

BerylliumMYQ229, MYQ230, MYQ231, MYQ232, MYQ233, MYQ234

MYQ235, HYQ236, MYQ2360, HYQ236S, HYQ237, MYQ238MY0239, HY0240, MYQ241, HYQ242, MYQ243, MYQ244

MYQ245, MYQ246, MYQ247, MYQ248, PBS02

CadmiumMYQ229, MYQ230, MYQ231, MYQ232, HYQ233, MYQ234

HYQ235, MYQ236, MYQ236D, HYQ236S, MYQ237, HYQ238MYQ239, MYQ240, MYQ241, MYQ242, MYQ243, MYQ244

HYQ245, HYQ246, MYQ247, MYQ248, PBS02

Calcium

HYQ229, HYQ230, MYQ231, MYQ232, MYQ233, MYQ234

Filename: DKQ229 Date: 02/13/95 Time: 12:33 CADRE: 2.10 Page i

SDG NO:CASE NO:

Calibration Report

MXQ229

23009

LABORATORY: COMPUCHZM LABAGENCY INPUT FILE: IMYQ229.IAS

MY0235, MYQ236, HYQ236D, MYQ237, MYQ238, HYQ239MYQ240, MYQ241, MYQ242, MYQ243, HYQ244, HYQ245MYQ246, MYQ247, MYQ248, PBS02

ChromiumHYQ229, HYQ230, HYQ231, HYQ232, MYQ233, HYQ234MYQ235, MYQ236, MYQ236A, HYQ2360, MYQ236S, HYQ237MYQ238, HYQ239, HYQ240, MYQ241, MYQ242, HYQ243MYQ244, HYQ245, MYQ246, MYQ247, MYQ248, PBS02

CobaltMYQ229, HYQ230, HYQ231, MYQ232, MYQ233, MYQ234MYQ235, MYQ236, HYQ2360, HYQ236S, MYQ237, MYQ238MYQ239, HY0240, HYQ241, HYQ242, MYQ243, MYQ244MY0245, HYQ246, MYQ247. MYQ248, PBS02

CopperMYQ229, MYQ230, MYQ231, MYQ232, MYQ233, MYQ234HYQ235, MYQ236, MYQ236A, HYQ2360, MY0236S, HYQ237HYQ238, MYQ239, HYQ240, MYQ241, MYQ242, MYQ243MYQ244, MYQ245, MYQ246, HYQ247, MYQ248, PBS02

IronMYQ229, MYQ230, MYQ231, MYQ232, HYQ233, MYQ234HYQ235, HYQ236, MYQ236D, MYQ237, MYQ238, MYQ239MYQ240, MYQ241, HYQ242, MYQ243, MYQ244, HYQ245MYQ246, MYQ247, HYQ248, PBS02

MagnesiumHYQ229, HYQ230, MYQ231, HYQ232, MYQ233, MYQ234MYQ235, HYQ236, HYQ2360, MYQ237, MYQ238, MYQ239MYQ240, MYQ241, MYQ242, MYQ243, MYQ244, MYQ245MYQ246, MYQ247, MYQ248, PBS02

ManganeseMYQ229, HYQ230, MYQ231, HYQ232, MYQ233, HYQ234HYQ235, MYQ236, HYQ2360, HYQ236S, MYQ237, HYQ238HYQ239, HYQ240, MYQ241, HYQ242, MYQ243, MYQ244MYQ245, MYQ246, MYQ247, HYQ248, PBS02

NickelHYQ229, MYQ230, HYQ231, MYQ232, MYQ233, MYQ234HYQ235, HYQ236, HYQ2360, MYQ236S, MYQ237, HYQ238HYQ239, HYQ240, HYQ241, MYQ242, HYQ243, MYQ244HYQ245, HYQ246, MYQ247, HYQ248, PBS02

Potassium

Filename: IMYQ229 Date: 02/13/95 Time: 12:33 CADRE: 2.10 Page 2

SDG NO:CASE NO:

Calibration Report

MYQ229

23009

LABORATORY: COMPUCHBM LAB

AGENCY INPUT FILE: IMYQ229.1AS

MYQ229, MYQ230, MYQ231, MYQ232, MYQ233, MYQ234

MYQ235, MYQ236, MYQ236D, HYQ237, MYQ238, MYQ239

MYQ240, MYQ241, MYQ242, MYQ243, MYQ244, HYQ245

HYQ246, HYQ247, MYQ248, PBS02

SilverMYQ229, HYQ230, HYQ231, MYQ232, HYQ233, HYQ234

MYQ235, HYQ236, HYQ2360, MYQ236S, HYQ237, HYQ238

MYQ239, HYQ240, MYQ241, MYQ242, MYQ243, HYQ244

MYQ245, MYQ246, HYQ247, MYQ248, PBS02

SodiumMYQ229, MYQ230, MYQ231, HYQ232, MYQ233, MYQ234

HYQ235. MY0236, HYQ2360, MYQ237, HYQ238, MY0239MYQ240, MYQ241, MYQ242, HYQ243, MYQ244, MYQ245

HYQ246, HYQ247, HYQ248, PBS02

VanadiunHYQ229, HYQ230, HYQ231, MYQ232, MYQ233, HYQ234

HYQ235, HYQ236, MYQ2360, MYQ236S, HYQ237, HYQ238

MYQ239, MYQ240, MYQ241, MYQ242, MYQ243, MYQ244HYQ245, MYQ246, MYQ247, MYQ248, PBS02

ZincMYQ229, MYQ230, MYQ231, MYQ232, MYQ233, MYQ234MYQ235, MYQ236, MYQ236D, HYQ236S. MYQ237, MYQ238

HYQ239. MYQ240, MYQ241, MYQ242. MYQ243, MYQ244

MYQ245, MYQ246, HYQ247, HYQ248, PBS02

Filename: DKQ229 Date: 02/13/95 Time: 12:33 CADRE: 2.10 Page

SDG NO:

CASE NO:MYQ229

23009

Matrix Spile* Report

LABORATORY: COMFUCHBK LAB

AGENCY INPUT FILE: IMYQ229.IAS

MATRIX SPIKE CRITERIA

INORGANICS

Percent Recovery Limits

Upper

Lower

Extreme lower

125.075.0.30.0

DC-267: The following inorganic samples are associated with a matrixspike recovery which is high, indicating that the sample resultsmay be biased high.Hits are qualified "J".

Copper

MYQ229, HYQ230, HYQ231, MYQ232, MYQ233, MYQ234MYQ235, MYQ236, MYQ236A, MYQ2360, MYQ237, HYQ238HYQ239, MYQ240, HYQ241, MYQ242, HYQ243, MYQ244HYQ245. HYQ246, MYQ247, MYQ248

DC-268: The following inorganic samples are associated with a matrixspike recovery which is low, indicating that sample results may

be biased low.Hits are qualified "J" and non-detects are qualified "UJ".

ChromiumHYQ229, HYQ230, MYQ231, HYQ232, MYQ233, MYQ234MYQ235, HYQ236, MYQ236A, MYQ2360, MYQ237, MYQ238

MYQ239, HYQ240, MYQ241, MYQ242, HYQ243, HYQ244MYQ245, MYQ246, MYQ247, MYQ248

DC-269: The following inorganic samples are associated with a matrixspike recovery which is extremely low, indicating that sampleresults may be biased low.Hits are qualified "J" and non-detects are qualified "R".

AntimonyHYQ229, HYQ230, MYQ231, MYQ232, MYQ233, HYQ234

HYQ235, MYQ236, HYQ236A, HYQ2360, MYQ237, HYQ238MYQ239, MYQ240, MYQ241, MYQ242, MYQ243, MYQ244MYQ245, HYQ246, HYQ247, MYQ248

Filename: IMYQ229 Date: 02/13/95 Time: 12:35 CADRE: 2.10 Page

Matrix Spike Report

SDG NO: MYQ229 LABORATORY: COMPUCHEH LABCASE NO: 23009 AGENCY INPUT FILE: IMYQSSS.IAS

Filename: IMYQ229 Date: oa/13/95 Time: 12:35 CADRE: 2.10 Page

CRDL Standard* Raport

SDG HO: MYQ229 LABORATORY: COHPUCHEM LAB

CASE NO: 23009 AGENCY INPUT FILE: lwro.229.lAS

DC-376: The following inorganic samples have no associated CRDL standard.I l i t n rinrl nnn dim 1 i nro flapgrrl 'MJ

IronHYQ232, HYQ245

Filename: ravo.229 Date: 02/13/95 Time: 12:36 CADRE: 2.10 Page 1

ICS Report

SDG NO: MYQ229 LABORATORY: COMPUCHSM LABCASE NO: 23009 AGENCY INPUT FILE: DR-o.229.IAS

DC-308: The following inorganic samples are associated with interferencecheck samples (ICS) which were not run in the proper analyticalsequence. The data must be qualified using professionaljudgement.

AluminumMYQ229, MYQ230, MYQ231, HYQ232, HYQ233, HYQ234MYQ235, MYQ236, MYQ237, MYQ238, HYQ239, HYQ240MYQ241, MYQ242, MYQ243, HYQ244, MYQ245, HYQ246MYQ247, MYQ248

AntimonyMYQ229, MYQ230, MYQ231, HYQ232, MYQ233, MYQ234HYQ235, MYQ236, MYQ237, HYQ238, MYQ239, MYQ240HYQ241, MYQ242, HYQ243, HYQ244, HYQ245, MYQ246MYQ247, MYQ248

ArsenicMYQ229, HYQ230, MYQ231, MYQ232. MYQ233, MYQ234MYQ235, HYQ236, HYQ237, MYQ23B, MYQ239, MYQ240MYQ241, HYQ242, MYQ243, MYQ244, MYQ245, MYQ246MYQ247, HYQ248

BariumMYQ229, MYQ230, MYQ231, MYQ232, MY0233, HYQ234MYQ235, MYQ236, MYQ237, HYQ238, MYQ239, HYQ240MYQ241, MYQ242, MYQ243, HYQ244, MYQ245, MYQ246MYQ247, MYQ248

BerylliumMYQ229. MYQ230, MYQ231, MYQ232, MYQ233, MYQ234MYQ235, HYQ236, MYQ237, HYQ238, MYQ239, HYQ240MYQ241, MYQ242, HYQ243, HYQ244, HYQ245, HYQ246HYQ247, HYQ248

Cadmi urnHYQ229, HYQ230, MYQ231, MYQ232, MYQ233, HYQ234HYQ235, MYQ236, MYQ237, MYQ238, MYQ239, MYQ240MYQ241, MYQ242, MYQ243, MYQ244, MYQ245, MYQ246MYQ247, HYQ248

CalciumMYQ229, MYQ230, MYQ231, MYQ232, HY0233, MYQ234MYQ235, MY0236, HYQ237, MYQ238, MY0239, MYQ240MYQ241, MYQ242, MYQ243, HYQ244, MYQ245, HYQ246HYQ247, MYQ248

Filename: niyo.229 Date: 02/13/95 Time; 12:37 CADRE; 2.10 Page

ICS R.port

SDG NO:

CASE NO:

MYQ229

23009

LABORATORY: COMPUCHEM LAB

AGENCY INPUT FILE: Dnro.229.IAS

ChromiumMYQ229, HYQ230, MYQ231, MYQ232, MYQ233, MYQ234

MYQ235, MYQ236, HYQ237, HYQ238, MYQ239, MYQ240

HYQ241, HYQ242, HYQ243, MYQ244, MYQ245, MYQ246HYQ247, MYQ248

Cobalt

HYQ229, HYQ230, MY0231, HYQ232, MYQ233, HYQ234


MYQ241, MYQ242, MYQ243, MYQ244, MYQ245, MYQ246HYQ247, HYQ248

Copper

MYQ229, MYQ230, MYQ231, MYQ232, MY0233, MYQ234

MYQ235, MYQ236, MYQ237, HYQ238, MYQ239, HYQ240

MYQ241, MYQ242, HYQ243, MYQ244, MYQ245, HYQ246HYQ247, MY0248

IronMYQ229. HYQ230, MY0231, MY0233, HYQ234, HYQ235

MYQ236, HYQ237, HYQ238, MYQ239, HYQ240, HYQ241HYQ242, MYQ243, MYQ244, HYQ246, MYQ247, HYQ248

LeadMYQ229, HYQ230, MYQ231, MYQ232, HYQ233, MYQ234

MYQ235, HYQ236, HYQ237, MYQ238, MYQ239, HYQ240

MYQ241, MYQ242. MYQ243, MYQ244, MYQ245, MYQ246

MYQ247, MYQ248

MagnesiumMYQ229, HYQ230, MYQ231, MYQ232, MYQ233, MYQ234MYQ235, MYQ236, HYQ237, MYQ238, MYQ239, HYQ240MYQ241, MYQ242, HYQ243. MYQ244, MYQ245, HYQ246

MYQ247, MYQ248

ManganeseMYQ229, MYQ230, MYQ231, MYQ232, MYQ233, MYQ234


MYQ241, MYQ242, MYQ243, MYQ244, MYQ245, MYQ246MYQ247, MYQ248

NickelMYQ229, MYQ230, MYQ231, MYQ232, MYQ233, MYQ234



HYQ247, MYQ248

Filename: IMYQ229 Date: 02/13/95 Time: I2s37 CADRE: 2.10 Page

SDG NO:

CASE NO:

ICS Rvport

MXQ229

23009

LABORATORY: COMPDCHEH LAB


PotassiumMYQ229, MYQ230, MYQ231, MYQ232, MYQ233, MYQ234

HYQ235, MYQ236, MYQ237, MYQ238, HY0239, MYQ240

HYQ241, HYQ242, MYQ243, HYQ244, MYQ245, HYQ246

MYQ247, HYQ248

SeleniumMYQ229, MYQ230, MYQ231, MYQ232, HYQ233, HYQ234

MY0235, HYQ236, MYQ237, MYQ238, HYQ239, HYQ240MYQ241, HYQ242, MYQ243, MYQ244, MYQ245, HYQ246

MYQ247, HYQ248

SilverMYQ229, HYQ230, MYQ231, MYQ232, MYQ233, MYQ234

MYQ235, HYQ236, MYQ237, HYQ238, MYQ239, MYQ240


MYQ247, MYQ248

SodiumHYQ229, MYQ230, MYQ231, HYQ232, MYQ233, HYQ234

HYQ235, HYQ236, MYQ237, MYQ238, HYQ239, MYQ240

MYQ241, MYQ242, MYQ243, MYQ244, HYQ245, MYQ246HYQ247, MYQ248

ThalliumMYQ229, MYQ230, MYQ231, MYQ232, HYQ233, MYQ234


MYQ241, MYQ242, HYQ243, MYQ244, HYQ245, MYQ246

MYQ247, HYQ248

VanadiumMYQ229, MYQ230, MYQ231, MYQ232, MYQ233, HYQ234

MYQ235, MYQ236, MYQ237, HY0238, MYQ239, HYQ240MYQ241, MYQ242, MYQ243, HYQ244. MYQ245, MYQ246MYQ247, HYQ248

ZincHYQ229, HYQ230, HYQ231, MYQ232, MYQ233, MYQ234

HYQ235, MYQ236, MYQ237, MYQ238, MYQ239, MYQ240

HYQ241, HYQ242, MYQ243, MYQ244, MYQ245, MYQ246

HYQ247, HYQ248

DC-312: The following inorganic samples have elements other than Al, Ca,Fe, and Mg at concentrations higher than 10 ppm that may causepotential interference.

Filename: HKQ229 Date; 02/13/95 Time; 12:37 CADRE: 2.10 Page

ICS Report

SDG NO:CASE NO:

HYQ229

23009

LABORATORY: COMPUCHEH LABAGENCY INPUT FILE: IMYQ229.IAS

PotassiumMYQ230, MYQ231, MYQ232, HYQ239, MYQ244, MYQ247MYQ248

DC-314: The following inorganic samples have analytes, not spiked in theinterference check sample (ICS) but reported as negative valuesin the ICS, present at or below the IDL. Interferents were foundin the sample at or above concentrations in the ICS, indicatingpotential false negatives. Non-detects are qualified "UJ".

AntimonyMYQ229, MYQ230, HY0231, MYQ232, MYQ233, MYQ234

MYQ235, MYQ237, MYQ238, MYQ239, HYQ240, MYQ242

HYQ243, HY0244, MYQ245, HYQ246, HYQ247, MYQ248

SeleniumHYQ229, MYQ230, MYQ231, MYQ233, MYQ234, MYQ236HYQ242, MYQ244, MYQ245, MYQ246

SodiumHYQ229, HYQ230, MYQ231, HYQ232, HYQ233, HYQ234

HYQ235, MYQ236, MYQ238, MY0239, MYQ240, MYQ241

MYQ242, HYQ243, MYQ244, MYQ245, MYQ246, MYQ247

HYQ248

ThalliumHYQ229, MYQ230, MYQ231, HYQ232, MYQ233, HYQ234MYQ235, MYQ236, MYQ237, HYQ238, MYQ239, MYQ240MYQ241, MYQ242, MYQ243, HYQ244, MYQ245, MYQ246HYQ247, MYQ248

Filename: imo.229 Date: 02/13/95 Time: 12:37 CADRE: 2.10 Page

LCS Report

SDG NO: MYQ229 LABORATORY: COMPUCHEM LABCASE NO: 23009 AGENCY INPUT FILE: XM5fO.229.lAS

DC-259: The following inorganic samples are associated with laboratorycontrol samples (LCS) which were not run in the requiredanalytical frequency.

AluminumHYQ229, MYQ230, MYQ231, HYQ232, HYQ233, HYQ234MYQ235, HYQ236, MYQ236D, MYQ237, HYQ238, MYQ239HYQ240, HYQ241, MYQ242, MYQ243, HYQ244, MYQ245MYQ246, MYQ247, MYQ248

AntimonyHYQ229, MYQ230, MYQ231, MYQ232, MYQ233, HYQ234HYQ235, MYQ236, HYQ236A, MYQ236D, HYQ236S, MYQ237HYQ238, HYQ239, MYQ240, MYQ241, MYQ242, HYQ243MYQ244, HYQ245, MYQ246, MYQ247, MYQ248

ArsenicMYQ229, HYQ230, MYQ231, MYQ232, MYQ233, HYQ234MYQ235, MY0236, MYQ236D, MYQ236S, HYQ237, MYQ238MYQ239, HYQ240, MYQ241, HYQ242, MYQ243, HYQ244HYQ245, MYQ246, MYQ247, MYQ248

BariumHYQ229, MYQ230, MYQ231, HYQ232, HYQ233, MYQ234HYQ235, MYQ236, MYQ236D, MYQ236S, HYQ237, MYQ238MYQ239, MYQ240, MYQ241, MYQ242, MYQ243, MYQ244HYQ245, MYQ246, MYQ247, HYQ248

BerylliumMYQ229, MYQ230, MYQ231, MYQ232, MYQ233, HYQ234HYQ235, MYQ236, MYQ236D, MYQ236S, HYQ237, MYQ238MYQ239, MYQ240, HYQ241, HYQ242, HYQ243, HYQ244HYQ245, HYQ246, MYQ247, MYQ248

CadmiumHYQ229, HYQ230, HYQ231, MYQ232, MYQ233, HYQ234MYQ235, MYQ236, HYQ236D, MYQ236S, MY0237, HYQ238HYQ239, MYQ240, MYQ241, HYQ242, MY0243, HYQ244HYQ245, HYQ246, MYQ247, MYQ248

CalciumMYQ229, MYQ230, MYQ231, MYQ232, MYQ233, MYQ234MYQ235, MYQ236, MYQ236D, MYQ237, MYQ238, MYQ239HYQ240, MYQ241, MYQ242, MYQ243, HYQ244, HYQ245MYQ246, MYQ247, MYQ248

Chromium

Filename: ZHYQ229 Date: 02/13/95 Time: 12>39 CADRE: 2.10 Page

SDG NO:

CASE NO:

LCS Report

HYQ229

23009

LABORATORY: COMPUCHEM LAB


HYQ229, HYQ230, MYQ231, MYQ232, HYQ233, MYQ234

HYQ235, MYQ236, MYQ236A, MYQ236D, MYQ236S, MYQ237


HYQ244, HYQ245, MYQ246, MYQ247, MYQ248

CobaltMYQ229, MYQ230. HYQ231, MYQ232, MYQ233, MYQ234

MYQ235, MYQ236, MYQ236D, HYQ236S, MYQ237, HYQ238

MYQ239, HYQ240, MYQ241, MYQ242, MYQ243, MYQ244

MYQ245, MYQ246, MYQ247, MYQ248

CopperHYQ229, MYQ230, MYQ231, HYQ232, MYQ233, HYQ234

HYQ235, MYQ236, HYQ236A, MYQ2360, HYQ236S, HYQ237HYQ238, HYQ239, HYQ240, MYQ241, HYQ242, HYQ243

HYQ244, HYQ245, HYQ246, HYQ247, MYQ248

IronMYQ229, HYQ230, MYQ231, HYQ233, MYQ234, HYQ235

MYQ236, MYQ2360. HYQ237, HYQ238, MYQ239, MYQ240

MYQ241, HYQ242, HYQ243, MYQ244, MYQ246, MYQ247

MYQ248

LeadHYQ229, HYQ230, MYQ231, MYQ232, MYQ233, HYQ234

MYQ235, MYQ236, MYQ2360, MYQ236S, HYQ237, MYQ238

MYQ239, MYQ240, MYQ241, HYQ242, HYQ243, HYQ244

HYQ245, HYQ246, MYQ247, MYQ248

MagnesiumHYQ229, MYQ230, MYQ231, MYQ232, MYQ233, HYQ234MYQ235, HYQ236, MYQ2360, HYQ237, MYQ238, HY0239HYQ240, HYQ241, MYQ242, MYQ243, HYQ244, HYQ245

HYQ246, MYQ247, HYQ248

ManganeseMYQ229, MYQ230, HYQ231, MYQ232, HYQ233, MYQ234

MY0235, MYQ236, MYQ236D, MYQ236S, MYQ237, MYQ238MYQ239, HYQ240, MYQ241, MYQ242, MYQ243, MYQ244


Nickel

MYQ229, MYQ230, HYQ231, MYQ232, MYQ233, MYQ234

MYQ235, MYQ236, MYQ2360, MYQ236S, MYQ237, MYQ238HYQ239, MYQ240, MYQ241, MYQ242, MYQ243, MYQ244


Filename: IMYQ229 Date; 02/13/95 Time: 12:39 CADRE: 2.10 Page

SDG NO: MYQ229

CASE NO: 23009

PotassiumMYQ229,MYQ235,MYQ240,MYQ246,

SeleniumHYQ229,MYQ235,MYQ239,MYQ245,

SilverHYQ229,MYQ235,MYQ239,MYQ245,

SodiumHYQ229,MYQ235,HYQ240,HYQ246,

ThalliumHYQ229,HYQ235 ,HYQ239,HYQ245,

VanadiumMYQ229,MYQ235,MYQ239,HYQ245,

ZincHYQ229,MYQ235,MYQ239.HYQ245,

Filename: IMYQ229

HYQ230,HYQ236,HYQ241,HYQ247,

MYQ230,MYQ236,MYQ240,MY0246,

MYQ230,HYQ236,HYQ240,HYQ246,

MYQ230,HYQ236,HYQ241 ,HYQ247,

MYQ230,HYQ236,MYQ240,MYQ246,

MYQ230,HYQ236,MYQ240,MYQ246,

MYQ230,HYQ236,MYQ240,HYQ246,

MYQ231 ,MYQ2360HYQ242,HYQ248

MYQ231,MYQ236DMYQ241,MYQ247,

HYQ231 ,MYQ236DMYQ241 ,MYQ247,

HYQ231,MYQ236DMYQ242,MYQ248

HYQ231 ,MYQ236DHYQ241 ,HYQ247,

MY0231,MYQ2360HYQ241,HYQ247,

MYQ231 ,MYQ2360MYQ241 ,MYQ247,

LCS ReportLABORATORY: COMPUCHEM LABAGENCY INPUT FILE: IM5TQ229.IAS

MYQ232, MYQ233, HYQ234, MYQ237, MYQ238, MYQ239MYQ243. MYQ244, HYQ245

HYQ232, MYQ233, MYQ234, MYQ236S, MYQ237, MYQ238MY0242, MYQ243, HYQ244MYQ248

MYQ232, MYQ233, MYQ234, MYQ236S, MYQ237, HYQ238MY0242, MYQ243, HYQ244MYQ248

MYQ232, HYQ233, MYQ234, HYQ237, MYQ238, MYQ239MYQ243. MYQ244, HYQ245

MYQ232, MYQ233, HYQ234, MYQ236S, HYQ237, HYQ238MYQ242, HYQ243, MYQ244MYQ248

MYQ232, MY0233, HYQ234, HYQ236S, HYQ237, MYQ238HYQ242, MYQ243, HYQ244MYQ248

HYQ232, MYQ233, MYQ234, MYQ236S, MYQ237, HYQ238MYQ242, MYQ243, MYQ244MYQ248

Date: 02/13/95 Time: 12:39 CADRE: 2.10 Page 3

Duplicates Report

SDG NO: HYQ229 LABORATORY: COMPUCHEM LAB

CASE NO: 23009 AGENCY INPUT FILE: DfifQ229.lAS

DC-256: The following inorganic samples are associated with duplicateresults which did not meet relative percent difference (RPD)criteria.Hits are qualified "J" and non-detects are qualified "UJ".

CalciumMYQ229, HYQ230, HYQ231, MYQ232, MYQ233, MYQ234HYQ235, MYQ236, MYQ237, MYQ238, MYQ239, MYQ240MYQ241, HYQ242, MYQ243. MYQ244, MYQ245, HYQ246MYQ247, HYQ248

ChromiumMYQ229, MY0230, MYQ231, MYQ232, MY0233, MYQ234HYQ235, MYQ236, HYQ236A, MYQ236S, MYQ237, MYQ238MYQ239, MYQ240, MYQ241, HYQ242, MYQ243, HYQ244HYQ245, MYQ246, HYQ247, HYQ248

Filename; pnfp.229 Date; 02/13/95 Time: 12;40 CADRE; 2.10 Page

Serial Dilution Report

SDG NO: MYQ229 LABORATORY: COMPUCHKM LABCASE NO: 23009 AGENCY INPUT FILE: IM1TO.229.IAS

DC-295: The following inorganic samples are associated with an ICP serialdilution percent difference which is not in criteria. The serialdilution result is greater than the sample result, indicating apotential negative interference. The data, must be qualified usingprofessional judgement. Hits and non-detects are flagged.

CalciumMYQ229, MYQ230, MYQ231, HYQ232, MY0233, MYQ234

MYQ235, HYQ236, HYQ236D, MY0237, HYQ238, HYQ239


MYQ246, MYQ247, MYQ248

Filename: MYQ229 Date: 02/13/95 Time: 12:41 CADRE: 2.10 Page

Sample Result Verification Report

SDG NO: MYQ229 LABORATORY: COHPUCHEM LABCASE NO: 23009 AGENCY INPUT FILE: IMYQ229.IAS

No problems found for this qualification.


Laboratory Blanks Report

SDG NO: MYQ229 LABORATORY: COMPUCHKH LAB

CASE NO: 23009 AGENCY INPUT FILE: IMYQ229.IAS

LABORATORY BLANKS CRITERIA

DC-282: The following inorganic samples/are associated with initial orcontinuing calibration blank* which were not run in the requiredanalytical frequency.Hits and non-detects are flagged "VS".

MYQ236A

Ant i mony, jEfi romi urn, Copper

DC -284: The following inorganic samples are associated with a blankconcentration which is greater than the instrument detectionlimit (IDL). The sample concentration is also greater thanthe IDL and less than five times the blank concentration.Thi i i i 11 1 l [H i- 'inn ii il I > riftT P-mlt" nrT rtrr, flajgTl ,

MYQ229Antimony

HYQ230

Antimony

HYQ231

Antimony

HYQ233Antimony

MYQ236Antimony

HYQ237

Antimony

HYQ239

Antimony

HYQ241Antimony

HYQ242Antimony

MYQ243Antimony

Filename: n«Q229 Date: 02/13/95 Time; 12:44 CADRE; 2.10 Page 1

Laboratory Blanks Report

SDG NO: MYQ229 LABORATORY: COMPUCHKM LABCASE NO: 23009 AGENCY INPUT FILE: nnro.229.XAS

MYQ2WAntimony

MYQ245Antimony


Flag Definition* Report

SDG NO: MYQ461 LABORATORY: COMPOCHBH LAB

CASE NO: 23009 AGENCY INPUT FILE: IMTQ4S1.IAS

DATA QUALIFIER DEFINITIONS

The following definitions provide a brief explanation of thenational qualifiers assigned to results in the data review process.Special CADRE flags are also defined here.

U - The analyte was analyzed for, but was not detected abovethe reported sample quantitation limit.

J - The analyte was positively identified; the associatednumerical value is the approximate concentration of theanalyte in the sample.

UJ - The analyte was not detected above the reported samplequantitation limit. However, the reported quantitationlimit is approximate and may not represent the actuallimit of quantitation necessary to accurately andprecisely measure the analyte in the sample.

R - The sample results are rejected due to seriousdeficiencies in the ability to analyze the sample andmeet quality control criteria. The presence or absenceof the analyte cannot be verified.

H - The data review for this result could not be completed byCADRE due to missing information.

VS - Some quality control criteria were not met but CADRE wasunable to assess the full impact of the problem. Such anassessment requires the professional judgement of a datareviewer and additional information not available toCADRE.

Filename: FIAGSSI Date: 01/19/95 Time: oiiio CADRE: 2.10 Page

Data validation rpt: #23009, memo #9, 20 soil samples for ... · Regional Sample number on the...

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Transcript of Data validation rpt: #23009, memo #9, 20 soil samples for ... · Regional Sample number on the...