CS241311 Final Report

Committee E-1 Proficiency Test Program

Chemical Analysis of Plain Carbon and Low-Alloy Steel Sample ID: 4Q13L1 and 4Q13L2

Fourth Quarter 2013

Issued by:

ASTM International

100 Barr Harbor Drive

West Conshohocken, PA 19428-2959

(610)832-9500

Sponsored by ASTM Committee E-1 on Analytical Chemistry for

Metals, Ores, and Related Materials

Copyright 2014 ASTM International, West Conshohocken, PA. All rights reserved. This material may not

be reproduced or copied, in whole or in part, in any printed, mechanical, electronic, film, or other distribution

and storage media, without the written consent of the publisher.

TABLE OF CONTENTS Page Report Introduction .................................................................................................................. 3-4 Alphabetical Listing of Program Participants ......................................................................... 5-7 Z Score Summary Tables Sample 4Q13L1 ................................................................................................................ 8-14 Sample 4Q13L2 ................................................................................................................ 15-21 Aluminum ................................................................................................................................. 22-27 Arsenic...................................................................................................................................... 28-32 Calcium .................................................................................................................................... 33-38 Carbon ...................................................................................................................................... 39-45 Chromium ................................................................................................................................. 46-52 Cobalt ....................................................................................................................................... 53-58 Copper ...................................................................................................................................... 59-65 Manganese ................................................................................................................................ 66-72 Molybdenum ............................................................................................................................ 73-79 Nickel ....................................................................................................................................... 80-86 Nitrogen .................................................................................................................................... 87-92 Oxygen ..................................................................................................................................... 93-96 Phosphorus ............................................................................................................................... 97-102 Silicon ....................................................................................................................................... 103-109 Sulfur ........................................................................................................................................ 110-116 Tin............................................................................................................................................. 117-122 Participant comments .............................................................................................................. 123 Test Instructions and Data Entry Form ................................................................................... 124-131

INTRODUCTION

This report constitutes the final report of results for the Fourth Quarter 2013 Proficiency Test Program for

Chemical Analysis of Plain Carbon and Low Alloy Steel. The report contains tables of results for laboratory

data, statistical summary analyses of test results, and graphs charting laboratory data. Tables and charts are

labeled with the program title and element determined.

The TABLE OF RESULTS provides a listing of laboratories with corresponding test results. Each

laboratory is identified by a randomly selected code with the same laboratory code applying throughout the

entire report. Sample 4Q13L1 and 4Q13L2 results are included on the same page for each element.

The tables are organized by the element determined. Test results for each element are grouped in the table

according to the ASTM method utilized. Individual method summaries are provided at the end of each

grouping enabling you to compare your laboratory data to the Robust Mean obtained by a given method. An

Overall Summary Robust Mean combining all methods is provided at the end of the table for comparison to

the grand mean.

The last grouping of test results in the tables, where applicable, provides the test results received from

laboratories utilizing other methods. Individual summaries are provided for this grouping where there are

sufficient number of data received. This grouping is included in the Overall Summary.

Dev. Column indicates whether or not the laboratory deviated from the ASTM method utilized. A

indicates yes, indicates that the laboratory did not provide a response.

Description of Z-Score Column: The z-score column reports each lab' s deviation in units of standard

deviations. The z-score is the ratio of the deviation to the standard deviation. A z-score greater than 2 -- or

less than negative 2 -- should cause a laboratory to review their test data for any possible systematic error.

Z-scores outside this range should occur only about one time in twenty, if a laboratory has average capability

running the method. Laboratories should strive to obtain z-score values close to zero.

Description of Robust Mean and Robust Standard Deviation

Means and standard deviations are computed using a two-stage robust procedure which is designed to limit

the influence of unusually large or small results, while eliminating only the most egregious among them. The

computations and philosophy of robust statistics are explained more fully in Robust Statistics How Not to Reject Outliers, by the Analytical Methods Committee of the Royal Society of Chemistry, Analyst, 114 pp,

1693-97, Dec. 1989. In this report, data are subjected to these robust computations twice. After the first

stage, results which differ from the (first stage) robust mean by more than three times the (first stage) robust

standard deviation are noted as outliers (shown in the Table of Results marked with a double asterisk) and

excluded from the second-round robust computation. The robust mean and standard deviation resulting from

this second-stage computation are those published in the Table. (There is no second stage exclusion. As the

second-stage robust standard deviation is generally smaller than that of the first stage, some non-excluded

results may differ from the robust mean by more than three robust standard deviations. That is, some non-

excluded data may result in z-scores greater than 3 or less than 3.)

A description of an iterative algorithm for computing robust means and standard deviations is provided in the

next section. The process is tedious, but the estimates do have the following property which can easily be

verified. If n results are included in the computation, and if all the results which differ from the robust mean

by more than n1) - (n5.1 times the robust standard deviation are replaced by the robust mean.

n1) - (n5.1 robust standard deviations, as appropriate. The mean of these trimmed results will equal

the robust mean, and the standard deviation of the trimmed results will be .882 times the robust standard

deviation.

3

Calculation of Robust Mean and Robust Standard Deviation

The Robust Mean and Robust Standard Deviation of a collection of n results are calculated by first finding

the median of all test results and then finding each result' s absolute deviation from this median. An initial

standard deviation for the reported results is determined by dividing the median of the absolute deviations by

0.6745. This value is multiplied by a cutoff value ( n1) - (n5.1 ) and the result is added and subtracted

from the median of the test results to arrive at initial upper and lower limits.

For calculation purposes test results that fall within these limits are retained, and other results are adjusted to

the nearest limit. A robust mean and robust standard deviation are calculated using this new set of values

(Robust Mean = average of trimmed results; Robust Standard Deviation = standard deviation of results

divided by 0.882). The robust standard deviation is compared to the initial standard deviation estimates

determined above. If they are equal then record the values as the robust mean and robust standard deviation.

If the standard deviations are not equal, then a loop process begins by utilizing the robust average and

standard deviation to calculate a new set of upper and lower limits. This looping process continues until the

robust standard deviation stabilizes from one iteration to the next. The resulting values are the Robust Mean

and Robust Standard Deviation. The number of digits carried out in the loop process is one digit more than

the reporting resolution of the test values.

BAR GRAPHS are provided for each element and test sample. The "Y" scale represents the test results and

"X" scale the laboratory codes. Each laboratory' s data is plotted, excluding outliers. Data that falls outside

the scale of the graphs are indicated with an arrow in the bar. Horizontal lines are provided at the Overall

Summary Robust Mean and average plus/minus one and two standard deviations. The bar graphs are

organized by ASTM method.

An XY Graphical presentation for each element determined in the samples is provided utilizing

methodology developed by W. J. Youden and published in "Industrial Quality Control vol XV, No. 1, May

1959" "Journal of Quality Technology". The article is titled "Graphical Diagnosis of Interlaboratory Test

Results. A legend is provided in the graphs that identifies the ASTM method used.

The Youden article points out that reported values can be expected to fall along a diagonal line from the

lower left quadrant to the upper right quadrant. As used in this evaluation the position of a laboratory value

along this line indicates a probable laboratory bias either positive or negative from the consensus value.

Where a laboratory value point falls off this line into another quadrant in a significant way, the laboratory has

an indication of a problem that needs to be corrected. The actual problem depends on the data point' s

position.

GENERAL COMMENTS: Any reported values of "< ", "> ", "0", or "nil" are not included in the

statistics but are included in the tables as reported data.

4

Alphabetical Listing of Laboratories

Participating in CS241311 Chemical Analysis Plain Carbon (2ndQtr, 4thQtr)

ASTM Proficiency Testing Program

(Alphabetical list does not correspond to

randomly selected lab codes published in the report)

A.Q.C. S.R.L.

NAPOLI, ITALY 80147

AGENZIA DELLE DOGANE

VIA DELL'ELETTRICITA N.19

VENEZIA-MARGHERA, ITALY 30175

AL EZZ DEKHEILA STEEL COMPANY

ALEXANDRIA, EGYPT

ALTA STEEL

EDMONTON, AB CANADA T5J 2R3

ANDEC S.A.

PRIMER PASAJE 12C SE MZ 2009

GUAYAQUIL, ECUADOR

ARCELOR MITTAL STEEL, USA RIVERDALE

RIVERDALE, IL 60827

ARCELORMITTAL CLEVELAND

CENTRAL RECEIVING -DOOR 40

CLEVELAND, OH 44105

ARCELORMITTAL LAZARO CARDENAS S.A DE

C.V

ZONA INDUSTRIAL

LAZARO CARDENAS MICHOACAN, MEXICO

60950

ARCELORMITTAL PLATE LLC

COATESVILLE PLANT-C/O CENTRAL STORES

COATESVILLE, PA 19320

ARCELORMITTAL STEEL USA INDIANA

STA026

EAST CHICAGO, IN 46312

ARCELORMITTAL USA LLC

MS 2-101

EAST CHICAGO, IN 46312

ARCELORMITTAL-USA BURNS HARBOR

BURNS HARBOR, IN 46304-9745

ARCELORMITTAL LAS TRUCHAS S.A. DE C.V.

COL CENTRO LAZARO CARDENAS

MICHOACAN, MEXICO 60950

ARCELORMITTAL TUBARAO

SERRA, BRAZIL 29163-970

BELASTINGDIENST / DOUANE LABORATORIUM

AMSTERDAM, NETHERLANDS 1043GN

BRAMMER STANDARD CO

HOUSTON, TX 77069

CASTCO TESTING CENTRE LTD

33 ON KUI ST

FANLING, HONG KONG

CHEMICAL TESTING SECTION, TAIWAN POWER

RESEARCH INSTITUTE, TAIWAN POWER

COMPANY

TAIPEI, TAIWAN 100

CHINA STEEL CORPORATION

1 CHUNG KANG ROAD

KAOHSIUNG, TAIWAN 81233

CLARK LABORATORIES LLC

BUILDING 9

JEFFERSON HILLS, PA 15025

CONSULTORIA Y PRUEBAS DE MATERIALES S A

DE CV

1099 A-1 COL MARGARITA SALAZAR

SAN NICOLAS, MEXICO 66479

DHS CBP

SUITE 400

CHICAGO, IL 60607

DOFASCO

GATE 15 DOOR 700

HAMILTON, ON CANADA L8N 3J5

DOOSAN HEAVY INDUSTRIES

CORPORATE R

CHANGWON GYEONGNAN, KOREA, REPUBLIC

OF 642 792

DRAGON STEEL CORPORATION

TAICHUNG CITY, TAIWAN 434

EMSL ANALYTICAL, INC

CINNAMINSON, NJ 08077

EPI MATERIALS TESTING GROUP

THE WOODLANDS, TX 77380

EMIRATES TECHNO CASTING

SHARJAH, UNITED ARAB EMIRATES 41608

EVRAZ OREGON STEEL

RIVERGATE PORTLAND WORKS

PORTLAND, OR 97203

FIAT AUTO AGENTINA S A

X592XAD

CORDOAB, ARGENTINA

FRANKLIN RESEARCH ASSOCIATES

HOUSTON, TX 77065

FUGRO TECHNICAL SERVICES LTD

FUGRO DEVELOPMENT CENTRE

HONG KONG, CHINA

GALLATIN STEEL CO.

GHENT, KY 41045

GEOSCIENCE TESTING LAB

DUBAI INDUSTRIAL CITY

DUBAI, UNITED ARAB EMIRATES 61670

GEOTECHNICS

HUNG HOM, KOWLOON,

HONG KONG, HONG KONG 852

GERDAU

MONROE, MI 48161

GERDAU ACOMINAS S/A

FAZENDA DO CADETE

OURO BRANCO, MINAS GERAIS BRAZIL

36420-000

GERDAU AMERISTEEL - ARL #1

MIDLOTHIAN, TX 76065

GERDAU AMERISTEEL - ARL #2

MIDLOTHIAN, TX 76065

I L V A S P A

TARANTO, ITALY 74123

INTI REGIONAL CORDOBA

CORDOBA CAPITAL, ARGENTINA 5000

IKA LABORATORIES (2006) LTD.

NESHER, ISRAEL 36601

INDUSTRIAL SUPPORT SERVICES

OPPOSITE TO DAMMAM TV STATION

DAMMAM, SAUDI ARABIA 31463

INSTITUTO COSTARRICENSE DE ELECTRICIDAD

LAB. CORROSIN

SUITE 506-2465

MIAMI, FL 33126

5

INTERFACE TECHNICAL INSPECTION

RAS AL KHOR INDUSTRIAL AREA-2

DUBAI, UNITED ARAB EMIRATES 78921

ISRAEL INSTITUTE OF METALS

HAIFA, ISRAEL 32000

KEYSTONE STEEL & WIRE

PEORIA, IL 61641

KANSAS DEPT OF TRANSPORTATION

BUREAU OF MATERIALS & RESEARCH

TOPEKA, KS 66611

LAB PROVE MAT S MARCO S R L

SCHIO (VI), ITALY 36015

LABORATORIO NACIONAL DE ENGENHARIA

CIVIL

LISBON, PORTUGAL 1700-066

MAURITIUS STANDARDS BUREAU

MOKA, MAURITIUS 230

MME

DACULA, GA 30019

MTEC MECHANICAL TESTING SERVICES

HOUSTON, TX 77064

NLMK INDIANA

PORTAGE, IN 46368

NOVACERO

LATACUNGA, ECUADOR 050150

NUCOR STEEL

DARLINGTON, SC 29540

OVAKO HOFORS AB

HOFORS, SWEDEN S-81382

PAMA FUNDICAO

RUA ALBINO DE RUSSI 434

SERTOZINHO, BRAZIL 14176-150

PROAQT EMPREENDIMENTOS TECNOLO

OSASCO, BRAZIL 06093010

PROMET METALS TESTING LABORATORY LTD

INDUSTRIAL ESTATE TAI PO

HONG KONG, HONG KONG 852

PUBLIC WORK CENTRAL

LABORATORY/CEDD/HONG KONG SAR

KOWLOON, HONG KONG 999077

QATAR STEEL COMPANY

TECHNICAL DEPARTMENT

DOHA, QATAR 50090

REPUBLIC ENGINEERED STEELS

CANTON STORE ROOM, LAB 2B

CANTON, OH 44704

REPUBLIC ENGINEERED STEELS

LAB A

CANTON, OH 44704

RUUKI METALS OY

RAAHE, FINLAND FI-92101

S K F GMBH

SCHWEINFURT, GERMANY 97419

SAMPLE AND TEST MEXICO, S. A. DE C. V.

COL SANTA MARIA LA RIBERA

DISTRITO FEDERAL, MEXICO 06400

SETSCO SERVICES PTE LTD

SINGAPORE, SINGAPORE 608925

SEVERSTAL INTERNATIONAL DEARBORN

DEARBORN, MI 48121

SGS-CSTC STANDARDS TECHNICAL SERVICES

CO., LTD.

GUANGZHOU, CHINA 510663

SHENG YU STEEL CO LTD

HSIAO KANG DIST

KAOHSIUNG CITY, TAIWAN 81260

SHIU WING STEEL LTD

TUEN MUN

HKSAR, HONG KONG 00000

SIDERCA SAIC

CAMPANA CITY 2804

BUENS AIRES, ARGENTINA

SILCOTUB

ZALAU, ROMANIA 450131

SKF FRANCE

B.P. 239

SAINT CYR SUR LOIRE 37540, FRANCE

SKF INDUSTRIES SPA

AIRASCA, ITALY 10060

SKF PLYMOUTH

PLYMOUTH, MI 48170

STORE STEEL D.O.O.

STORE, SLOVENIA S13220

SUN-JET TECHNOLOGY & CONSULTING CO LTD.

LUNG TAN HSIEN

TAO YUAN HSIEN, TAIWAN

T V A CENTRAL LABS SERVICES

BLDG. A PSC 1B-C

CHATTANOOGA, TN 37415

TAIWAN ACCURATE TESTING LAB. CO., LTD.

TAOYUAN, TAIWAN 338

TENARIS DALMINE

DALMINE (BG), ITALY 24044

TENARIS DALMINE #2

DALMINE (BG), ITALY 24044

TERNIUM COLOMBIA PLANT

SAN NICOLAS DE LOS GARZA

NUEVO LEON, MEXICO 66452

TERNIUM MEXICO S.A. DE C.V.

APODACA LAB



GUERRERO LAB



PUEBLA LAB


TERNIUM SIDERAR LAB. QUMICO

LABORATORIO DE ACERIA

SAN NICOLAS, ARGENTINA B2900

THE TIMKEN COMPANY - FSP

MAIL CODE HSP-27

CANTON, OH 44706

THE TIMKEN COMPANY - HSP

1835 DUEBER AVE. SW

CANTON, OH 44706-0924

THE TIMKEN COMPANY- HSP 2

MAIL CODE: HSP-2

CANTON, OH 44706

THYSSENKRUPP STEEL

CALVERT, AL 36513

THYSSENKRUPP CSA

RIO DE JANEIRO, BRAZIL 23560-352

TITAN METALLURGY

OAK PARK, MI 48237

US STEEL CORP

METALLURGICAL BLDG

GARY, IN 46404

USAPHC

ATTN: BLDG E2100, MCHB-IP-QA

APG, MD 21010

6

UNION ELECTRIC STEEL CORP 31 UNION ELECTRIC ROAD

BURGETTSTOWN, PA 15021

USS - FAIRFIELD WORKS

M/S IS&C

FAIRFIELD, AL 35064

V & M STAR OHIO

YOUNGSTOWN, OH 44510-1033

VALLOUREC SUMITOMO TUBOS DO BRASIL

LABORATORIO QUMICO

JECEABA, MINAS GERAIS BRAZIL

VILLARES METALS S.A.

R ALFREDO DUMONT VILLARES

SAO PUALO, BRAZIL 13178 902

WESTMORELAND MECHANICAL

YOUNGSTOWN, PA 15696

WIRETECH INC

CITY OF COMMERCE, CA 90040

YIEH UNITED STEEL CORP

GANGSHAN DISTRICT

KAOHSIUNG CITY, TAIWAN 82057

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ASTM Proficiency Test Program - Chemical Analysis Plain Carbon Steel

Z Score Summary Sample 4Q13L1

001 E415 -0.4 0.5 -1.0 0.6 -0.4 -0.3 -0.1 -0.1 0.6 -0.3 1.5 -0.4 0.8

002 E1019 -0.5 -0.7

Other 0.7 -0.8 -1.4 1.3 0.8 0.5

003 E1019 -0.4 -0.2 -0.3

E415 -0.5 2.0 -0.7 -0.2 0.1 -0.8 -0.5 0.0 -0.3 -0.5 -0.6

004 E415 -1.2 -1.6 -1.7 1.5 -0.9 -2.5 -2.3

005 E415 0.8 2.5 0.5 0.3 -1.0 -1.3 -1.2 1.7 0.0 -2.1 2.3 0.2 1.8 -0.9 1.3

006 E1019 -0.3 0.7 -1.6

ICP -3.1 -1.2

Other -1.7 0.4 1.3 -0.3 -0.7 1.0 0.4 -0.3 -0.1

007 E1019 -0.6 -1.9

E1085 0.5 -1.2 1.7 -0.5 -2.1 1.7

E415 0.5 1.6 -0.1 3.4 0.6 0.7 2.0 -3.1 -0.5 -2.3 1.8

008 E1019 -0.8 -0.1 1.0

E415 1.4 0.1 0.0 -0.8 -0.1 -0.8 0.4 -0.1 -1.2 0.2 -1.1 0.2 -1.9 1.3 -1.0

009 E415 -0.4 -0.5 0.6 0.5 -1.7 0.8 0.9 1.0 -2.9 0.2 1.1 -0.1 1.3 0.7

010 E1019 -1.8 1.2 -0.9

E415 -0.9 -1.8 0.2 -0.2 -2.8 1.2 0.4 0.2 -0.9 0.8

011 E1019 -0.2 -0.6

E415 2.0 -0.5 0.1 0.0 0.1 -0.6 -1.4 -0.7 1.5 -1.1 -0.6 0.3 -0.2 0.2

012 E1019 -0.1 0.7

E415 0.8 1.0 -1.0 -2.1 -0.4 0.8 0.2 -0.2 -1.2 0.4 1.7 0.6 0.8

013 E415 2.6 -0.4 -1.8 1.5 -0.2 -0.5 2.0 -0.9 -0.9 0.6

014 E415 -0.9 -1.1 -0.1 1.0 0.8 1.8 -0.4 0.8 -0.2

015 E1019 2.5 0.4 2.1

E415 -0.7 -1.1 -0.5 -1.0 -1.2 0.5 -0.8 -1.6 0.9 -0.5 -2.4 -1.1 0.4

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016 ICP 0.4 1.5 0.0 -1.2 -0.6

Other -2.9 0.8 -2.6 -2.3 -0.2 -1.3 0.4 -0.6 0.9

017 E1019 0.4 0.0 -1.9

E415 0.3 0.8 0.0 0.4 0.2 0.8 0.1 1.1 0.0 -0.4 0.5 -0.2 -0.8 0.0 0.2

018 E1019 -1.0 0.6

E415 0.2 -1.2 1.1 -1.4 -0.1 -1.4 -0.5 0.2 0.8 -0.7 0.6

Other -0.3 0.4 3.2 -1.2 -0.3

019 E1019 -0.8 -0.2

E415 0.5 -1.1 0.7 -0.4 0.0 -2.0 -0.3 0.0 -0.2 -0.4 0.1 2.2 0.7

020 E1019 0.4 -1.1 0.1

E415 0.8 -0.1 -0.5 -0.7 0.6 -0.5 1.0 0.4 -0.9 1.6 1.1 0.6 1.3

021 E1019 0.2 0.4 -0.8

E1085 0.7 0.2 -0.6 0.6 0.2 0.4 -0.5

E415 -0.4 -0.1 0.5 0.6 0.2 2.0 -0.6 0.2 0.4 0.5 0.2 -0.6 0.7

022 E415 -0.4 2.0 0.0 2.7 2.3 0.4 -1.0 -1.9 -0.2 -0.9 0.1 1.3 0.8

ICP 2.1 0.4 -1.2

023 E415 -1.4 0.4 1.1 0.3 -0.3 0.3 -0.6 -0.5 0.2 1.0

024 E1019 -0.4 0.6

E415 -0.4 0.7 -0.1 0.9 -1.4 0.5 -0.6 -0.1

025 E1019 0.7 0.7 -1.9

E1085 0.0 -0.1 -1.8 -0.7 0.5 0.4 -0.3 2.7

E415 0.2 -0.5 0.0 -1.5 -0.1 -0.8 -2.0 -0.4 -0.3 1.6 -1.1 0.4 0.0 -0.4 0.8

026 E1019 -0.8 -0.9

E415 -0.6 -1.2 -1.0 -0.1 0.4 0.0 -0.1 -0.1 0.0 0.5 0.0 0.6 -0.1 0.0

027 E415 0.8 -1.2 0.1 1.6 -0.2 0.8 -0.9 -0.1

028 E1019 -2.3

E415 1.4 -0.9 1.3 1.0 1.1 -0.9 -2.3 -1.9 0.6 -1.0

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029 E1019 -1.5

E1085 -0.3 -0.9 -1.4 -0.3 -0.9

E415 -0.9 1.3 1.5 -0.4 1.5 -0.9 1.1

030 E1085 0.8 1.3 -0.6 0.1 -0.2

E415 -0.3 -0.7 0.8 0.8 -0.4 -0.8 -1.3 -0.2 -0.5 -1.6 -1.0

031 E1019 0.4 0.5

E415 -1.4 0.4 -0.4 -0.2 -0.3 -0.1 -1.2 -1.3 0.0

032 E1019 0.9 0.4 -0.1

E1085 -0.1 -1.0 -1.4 -0.4 -0.6

E415 0.2 0.0 0.0 1.3 0.9 0.5 -2.5 -0.7 -0.3 0.2 0.7 0.2 -0.5 0.7 0.5

033 E415 -0.8 -2.1 0.8 -0.1 2.2 -1.1 0.3 0.2 1.6 -2.3 -1.3 -1.8

034 E1019 -0.1 0.3 0.6

E415 -0.4 1.1 0.7 0.2 0.9 -0.6 -0.3 0.6

035 E415 -3.2 0.2 1.1 -0.5 -0.5 -1.5 -2.0 -0.3 0.5 -1.2 -1.0 -0.2

036 E1019 -0.2 0.6

E415 -0.9 0.2 0.9 0.4 0.9 1.1 0.5 1.0 -0.2 0.6

037 E415 -0.6 0.9 -1.0 1.4 -0.1 0.0 1.3 0.2 1.3 -0.2 0.3 0.0 0.3 1.8 0.3

038 E1019 -0.1 -0.1 0.5

E415 0.2 -0.2 0.0 0.1 -0.4 -0.3 0.2 -0.3 0.2 -0.2 -0.1 0.0 0.4 -0.5

039 E415 0.8 1.8 -1.2 -1.3 1.3 -0.9 -2.0 0.6 0.9 -0.9

040 E1019 -0.1 1.0 -0.1

E415 0.2 0.8 -1.0 0.5 -0.1 0.7 -0.5 -0.2 2.2 -0.5 1.0

041 E415 -0.3 1.4 -0.5 1.1 1.6 2.5 0.7 -0.9 0.9 -0.1 -1.3 0.0 0.1 -0.1 1.7

042 E1019 0.6 -0.8 0.6

E415 1.5 0.1 -0.4 -0.7 -0.1 0.3 0.4 0.0 -0.2 -0.6 -0.1 1.5 -0.3

043 E1019 -1.4 -1.5 -0.1

E415 0.8 0.5 0.8 -0.4 0.5 1.8 0.5 0.4 0.9 0.6 0.8

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044 E1019 0.4 0.0 -1.8

E1085 1.8 -1.2 1.2 -0.7 -0.9 -0.8 -0.8 0.4

E415 0.6 1.1 -0.5 -0.3 -1.1 -0.2 -0.9 0.6 1.1 0.2 1.2 0.6 -0.2 -0.9 -0.2

Other 3.2

045 E1019 0.7

E415 1.2 0.6 0.1 -1.2 0.3 0.0 -1.7 1.9 -0.2 -1.1

046 Other 3.0 -0.2

047 E1019 0.8 -0.1

E322 -0.9 -2.1 -0.5 0.9

048 E1019 -1.0 -0.2 -0.9

E415 0.8 -0.3 -1.2 -0.4 1.1 -0.9 0.6 -0.9

ICP 0.8 -0.2 -1.2 -0.2 -0.9

049 E1019 -0.2 1.1

E415 -0.4 2.0 0.2 0.4 1.0 0.5 1.3 -0.5 -0.7 0.9 0.1 0.8 -0.2

050 E415 2.0 -1.3 1.8 0.6 -0.7 0.5 1.0 2.3 -0.9

051 E415 -1.5 -1.0 -2.0 -1.6 -0.3 1.9 -0.9 -0.2 0.9 -0.8 -1.7 2.6 -1.0

052 E415 2.9 -1.2 1.1 3.1 -2.1 -0.1

053 E415 1.3 -0.4 0.5 -1.4 2.7 -3.3 1.8 0.9 -0.3 -1.1 -1.7 0.0 -0.5 0.4 -2.3

054 Other 1.9

055 E415 1.4 0.4 0.4 1.1 1.5 1.0 -1.3 -1.0 1.4 3.0

056 E1019 -0.3 0.5 0.4

E1085 -0.1 -2.0 -0.2 -0.7 -0.6 0.4 -0.9

E415 -0.9 -0.5 -1.0 -0.2 -1.2 -0.8 -0.9 -1.0 -0.7 -0.6 -0.9 0.7 -0.1 -0.2

057 E1019 0.7 -0.1 -0.9

E1085 -0.7 -0.4 -0.4 -0.9 -0.6 0.2

E415 -0.4 0.5 -0.3 -0.8 -0.4 -0.1 0.6 -2.1 -0.9 -0.9

058 E1019 0.9 -0.3 -1.6

11

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058 E415 -0.9 -0.5 0.0 -0.3 -1.2 0.4 -1.0 -0.3 -0.6 -0.5 -0.1 -0.8 1.3 0.5

059 E415 -0.9 0.0 -0.5 -0.5 -1.1 -0.6 -1.0 -0.5 0.9 0.2 -0.9 0.3 0.2 -0.8

060 E415 0.2 0.1 2.0 0.1 0.5 0.4 -0.5 -0.3 1.0 -0.2 -0.2 -1.3 -2.7

061 E1019 -0.1 0.7 0.7

E415 -1.5 -0.1 0.9 -0.7 -0.1 -0.6 0.4 0.5 -0.6 0.4 1.2 1.2

062 E415 0.9 -1.4 0.0 2.3 1.7 -0.6 1.8 0.6 1.3 0.9 0.0 0.0 -1.4 1.0

063 E415 0.2 3.2 -0.4 -2.1 0.8 -0.9 -1.4 0.4 -0.1 -1.6 -0.8

064 E1019 0.0 0.3 -0.1

E415 -0.1 -0.4 -1.0 -1.0 -0.3 -0.2 0.4 0.1 -0.7 -0.2 -0.2 -0.3 -0.3 -0.5

065 E415 1.4 -0.6 -1.2 0.8 0.4 -0.2 0.6 3.1 0.2 1.8 -0.1

066 E415 -0.9 0.2 0.4 -1.0 0.9 -0.9 1.2 -0.8 -0.9 -0.5

Other -0.1 0.2 0.2 -0.4 0.4 -1.7 -0.8 -1.9 -0.4

067 E1019 -0.6 1.0 -2.3

E415 0.8 -1.0 -0.5 1.0 0.5 0.7 1.2 0.9 1.6 -0.1 0.7 -0.3

068 E1019 1.0

E415 -0.2 0.0 -1.5 1.2 0.5 -1.6 1.9 -0.3 0.2 2.7 -1.6 1.1 1.3 0.1 -1.0

069 E1019 0.9 0.2

E415 1.5 0.6 -2.0 0.8 0.8 -0.2 0.3 -0.7 0.0 1.6 0.2 0.1 -0.4 0.3 0.7

070 E1019 -0.8

E415 0.9 0.8 1.0 2.2 0.8 0.5 1.8 -0.1 1.8 0.7 -0.5 0.6 -0.3 2.1

ICP 2.0 1.4 -2.1

071 E1019 -0.2 -0.2 -0.9

E415 0.2 0.2 -0.5 -0.4 -0.7 0.5 -0.4 -0.2 0.2 0.2 -0.2 0.0 -0.6 -0.9 -0.7

072 E415 -2.1 -2.1 -1.0 -0.7 2.6 -0.9 -1.4 -0.7 -0.2 -1.9 1.9 2.0 -3.3

Other -1.2 -1.7 -0.4 -3.1 -0.4 -0.7 -2.0 -0.5 -0.9 2.2

073 E415 -2.3 2.7 1.2 -1.4 1.0 0.1 0.3 0.6 0.2 1.2 -0.8

074 E1019 -0.3 0.7 -0.7

12

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074 E415 0.2 0.5 0.1 -0.2 0.3 0.5 -0.8 0.2 0.0 0.0

075 E1019 0.1 -0.2 -0.9

E415 1.6 1.5 -0.1 -0.7 -0.3 0.2 -4.0 0.4 -0.7 1.3

076 E415 0.2 0.8 -2.0 -2.3 -1.3 0.8 -0.6 0.2 -1.9 -0.6 -2.5 0.4 -0.9 1.3 -0.8

077 E415 1.0 0.6 -0.8 1.0 -0.2 1.8 2.4 1.3 2.2 0.9 0.8 -1.1 1.0

078 E415 -1.0 -2.5 0.0 0.1 0.2 -1.5 0.3 0.2 -0.6 -2.2 1.0 -0.4

079 Other -0.3 0.3 -0.1 0.3 -0.3 -0.2 -0.2 2.4 -0.2 0.6 0.0

080 Other -0.2 -0.6 0.4 -2.8 -0.6 0.7 0.1

081 E415 2.5 0.6 0.7 1.0 0.2 -1.3 1.0 0.0

082 E1019 0.3 0.7 -0.5

E1085 -0.6 -2.0 -0.5 -0.9 -0.2 1.2

E415 -1.8 -1.0 -1.5 -0.3 -2.0 -1.0 -0.6 -0.5 0.2 -0.6 0.4 -0.4 1.0 -0.2

083 E415 0.8 -0.8 -0.9 2.9 0.5 -0.9 1.3

084 E1019 0.3

E415 -0.4 0.0 1.2 0.1 0.0 -0.9 0.9 1.1 -0.2 0.4 0.2 -0.6 -0.3

085 E415 0.1 -1.0 0.4 -2.2 -0.1 2.6 -1.2 0.5 2.9 0.4 1.2 0.1 0.8

086 E415 0.8 1.1 0.4 0.1 -1.4 0.2 1.6 -0.1

087 E415 -2.1 0.5 -0.9 -1.0 0.7 -0.1 -0.7 -0.6 -2.1 -3.0

088 E1019 0.3 1.9 0.9

E415 0.1 -0.2 -1.5 0.7 0.0 -0.5 0.1 0.7 0.5 -0.1 -0.4 0.7 0.4 0.2

ICP -0.4 -0.2 -0.2 -1.2 1.3 0.4 1.3 -0.7

089 E322 -0.1 1.0 0.7 -3.2

E415 0.0 0.8 -2.0 -1.2 -0.8 0.4 -3.2 -2.1 2.0 -1.5 -1.0 -2.1 -0.1 -0.8

090 E1019 -2.0

E415 -0.9 0.2 -1.3 -0.1 0.0 -2.0 0.2 0.0 0.9 0.2 -1.9 0.3 -0.7

091 E415 -0.5 1.5 0.0 2.1 -0.3 0.1 0.0 0.4 1.3 1.7 -0.2 1.7 -0.4 0.7

092 E415 -0.8 1.5 -0.6 1.3 0.1 -1.3 1.7 0.4 0.4 -0.6 1.5 -0.8

13

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093 E415 0.2 0.8 -0.7 -0.4 1.1 -1.4 1.6

094 E1019 -0.1 0.0 1.3

E415 -0.4 0.9 0.2 -0.4 1.1 0.6 0.5 1.2 0.6

095 E1019 0.2

E415 0.8 0.8 0.5 -0.7 0.3 -1.3 -0.7 2.0 0.3 -0.9 0.2 0.8

096 E415 0.5 0.9 -0.1 1.0 0.6 0.9 0.2 1.8 -0.5

097 E1019 -0.3 0.0 -1.1

E415 0.2 0.8 -0.5 0.1 0.1 0.9 -0.1 1.2 1.1 0.9 -0.3 1.4 0.8 -0.9 0.8

098 E415 0.2 0.1 0.2 -0.6 0.9 2.4 -1.6 -1.6 1.1 0.6

099 E415 -2.1 -0.5 2.0 1.3 1.0 0.8 -1.2 1.5 2.2 1.3 1.7 0.4 -0.1 0.6 -0.8

100 E1019 0.1 -0.2 0.2

E1085 0.8 -0.4 0.0 0.0 0.2 -1.5 -0.2 0.0

E415 0.5 1.2 -1.0 2.0 0.0 0.0 0.2 0.8 0.4 0.2 1.8 -0.1 -0.1 0.4 -0.3

Other 0.2

101 ICP -0.4 0.1 0.4 0.0 -0.5 -0.5

Other 0.0 0.3 -1.4 -0.1

102 E415 -0.5 1.0 0.7 0.8 -0.8 -0.6 0.9 0.0 0.2 0.1 0.0 -0.1 -0.3

103 E415 0.2 -1.0 1.0 -0.1 -1.0 0.0 0.9 1.6 0.2 -0.1

104 E1019 0.2 -2.2

E415 0.6 1.8 -1.1 2.6 0.7 0.1 0.1 -2.1 0.3 -2.0 -1.6 0.4 1.3

14

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001 E415 -0.8 0.5 -0.5 -1.1 -0.3 -0.8 -0.9 0.1 0.4 0.4 1.5 -0.2 -0.8 0.3

002 E1019 -0.4 -0.9

Other 0.7 -1.0 -0.3 0.6 -0.3

003 E1019 0.7 0.2 0.3

E415 -0.5 0.3 -0.9 0.4 -1.1 -1.0 -0.3 -0.7 -0.2 0.5 1.2 -0.4

004 E415 0.4 -1.5 -1.7 0.6 -1.3 -2.7

005 E415 0.9 2.6 -1.8 -1.1 -1.8 -1.1 1.9 -0.1 -1.3 -1.8 0.2 1.9 0.8 1.0

006 E1019 -0.4 0.4

ICP -1.3 -0.5

Other -1.3 0.5 1.6 0.0 -1.2 -1.1 -0.5 0.1 -0.2

007 E1019 0.3

E1085 1.0 1.0 1.6 1.2 -1.3 0.9

E415 0.2 -0.3 0.7 2.8 -0.4 0.2 1.1 0.2 -0.8 0.1

008 E1019 -0.5 -0.9 0.3

E415 1.5 -0.1 -0.5 0.2 -0.9 0.4 -0.2 -1.7 0.4 -2.6 0.4 -2.1 1.0 -0.9

009 E415 -0.1 0.6 0.6 -1.4 1.0 0.8 1.4 -2.5 -0.2 1.1 -0.1 0.5 0.3

010 E1019 -1.4 -0.7 1.4

E415 -0.8 -1.4 -1.7 -0.2 -0.9 2.3 -0.7 -0.5 -0.8 1.0 0.3

011 E1019 -0.4 -0.5

E415 2.5 2.9 0.0 0.1 0.4 -0.9 -1.3 0.1 0.3 -2.0 -2.0 0.3 -0.6 0.3

012 E1019 0.3 1.5

E415 1.5 -0.7 -2.2 -0.5 1.0 0.3 0.4 -1.7 0.8 1.7 0.5 0.3

013 E415 2.1 0.0 -2.5 1.0 -1.8 -1.2 0.9 -1.8 -0.8 -0.8

014 E415 -0.6 -0.1 0.6 1.0 0.9 1.9 -0.6 -0.1 -0.3

015 E1019 1.5 0.8 0.9

E415 -0.6 -1.0 -1.0 -1.1 0.6 -0.2 -1.9 1.3 1.0 -2.0 -0.9 0.9

15

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016 ICP 0.1 2.2 -0.4 -0.1 -0.4

Other 1.3 -0.8 0.3 -0.4 -1.5 0.5 0.1 0.5

017 E1019 1.8 0.2 -1.3

E415 0.5 0.5 -1.1 -0.4 0.9 -0.7 0.0 -0.8 -1.0 0.8 -0.8 -1.5 -1.1 -0.6

018 E1019 -1.6 -0.6

E415 -0.2 -1.2 0.9 -0.7 -0.5 -1.3 -0.8 0.4 0.6 0.8 1.0

Other 0.2 0.4 -1.7 -2.1 -0.7

019 E1019 -0.1 -0.5 2.0

E415 0.3 -0.9 1.6 0.0 0.2 -2.3 0.3 0.6 0.0 0.5 0.4 1.3 1.2

020 E1019 -0.2 -0.2 -0.4

E415 0.6 -0.2 -0.5 0.4 -0.6 0.7 0.3 -1.0 1.0 1.3 0.3 1.2

021 E1019 -0.5 0.6 -1.2

E1085 -0.4 0.1 -0.7 0.6 -0.2 0.8 -0.7

E415 -0.2 -0.1 0.2 0.3 1.8 -0.2 0.9 0.3 0.2 0.6 0.0 0.9

022 E415 -0.2 3.1 2.3 0.4 -1.2 -1.9 -0.8 -0.5 0.0 2.0 0.3

ICP 3.4 0.3

023 E415 -1.5 0.9 1.2 0.3 -0.4 0.4 -0.6 -0.2 0.1

024 E1019 0.4 0.3

E415 -0.2 1.1 -0.5 2.2 -1.7 0.4 -0.7

025 E1019 -0.1 0.2 -1.8

E1085 -3.0 -0.2 -2.3 -0.3 -0.2 -0.5 -1.3

E415 0.4 -0.5 -0.4 0.0 -0.9 -2.0 -0.4 -0.8 1.5 -1.7 -0.5 0.3 -0.6 0.3

026 E1019 -1.3 -0.8

E415 -0.5 -1.0 0.2 0.4 -0.7 -0.2 -0.3 0.1 -0.8 0.4 -1.3 0.8 -0.2

027 E415 0.1 -1.1 -0.1 1.7 -1.9 3.8 -1.0 -0.4

028 E1019 -0.8 -1.3 -2.2

E415 0.9 -0.8 -0.9 0.5 0.3 -0.2 -1.3 -1.8 0.1 -2.2 -1.1

16

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029 E1019 -1.7

E1085 -0.3 -0.8 -1.5 -0.3 -0.6

E415 -0.8 1.2 -0.6 -0.5 2.1 -0.6 0.8 -1.4

030 E1085 0.6 1.1 -0.6 -0.2 -0.3

E415 -0.1 0.2 2.1 1.8 1.1 1.7 -0.6 1.2 0.4 0.7 0.2

031 E1019 1.5 -0.7

E415 -1.5 1.3 -0.1 0.4 -0.1 0.1 -0.2 -1.0 -1.2 -0.8

032 E1019 0.7 0.4 0.3

E1085 0.6 0.3 -1.7 -0.9 -1.1

E415 0.6 -0.1 0.9 0.8 0.1 -0.2 0.4 -0.3 0.0 0.2 -0.2 0.0 -0.2 0.3

033 E415 -0.8 -2.2 0.5 0.2 2.5 -1.0 0.2 -0.5 -4.3 1.5 -1.8 -1.1 -1.8

034 E1019 0.5 0.2 -0.2

E415 -0.2 0.5 0.4 0.3 1.0 0.0 -0.7

035 E415 0.5 1.7 -0.4 -0.1 -2.0 -2.1 -1.0 0.6 -1.3 0.3 0.4

036 E1019 -0.6 -0.5

E415 0.4 -0.4 1.1 0.4 0.9 0.6 -0.4 0.4 0.3

037 E415 -0.5 0.8 1.5 -0.2 0.1 0.1 -0.4 1.7 -0.4 0.0 -0.2 0.3 0.6 0.3

038 E1019 -0.2 -0.2 0.1

E415 0.4 -0.1 0.7 0.1 -0.3 0.4 0.2 0.3 -0.2 -0.1 0.0 0.5 0.0

039 E415 0.9 1.0 -0.8 -1.6 1.2 -3.2 0.6 0.5 0.3

040 E1019 -0.2 0.0 -0.8

E415 0.4 0.4 0.0 -0.8 -0.2 -1.0 -0.2 0.8 -0.7 0.6

041 E415 -0.3 1.5 1.8 2.5 2.6 1.0 -0.9 1.7 -0.2 -0.5 -0.1 0.1 -0.5 1.6

042 E1019 0.5 -0.5 -0.1

E415 2.0 0.2 -0.3 -0.4 -0.2 0.5 0.6 0.2 0.4 -0.4 0.2 0.6 0.1

043 E1019 -2.2 -0.5 -0.8

E415 0.9 -0.1 -2.6 0.7 -0.8 -0.5 0.3 0.4 -0.5 0.1 -0.8 0.3

17

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044 E1019 -1.9 0.0 -1.2

E1085 2.1 -1.7 1.3 -1.0 -1.3 -1.2 -1.3

E415 0.9 1.4 1.2 -0.5 0.2 -1.1 1.5 1.4 0.4 2.3 1.2 0.1 0.6 0.6

Other 1.6

045 E1019 0.2

E415 0.5 0.6 0.1 -0.7 0.3 -0.2 -0.6 1.5 -0.1 -0.5

046 Other 1.1 0.2

047 E1019 0.0 2.0

E322 -0.4 -2.0 -1.0 0.9

048 E1019 -0.5 -0.2 -0.8

E415 0.4 0.1 -1.4 0.3 1.4 -0.8 0.4

ICP 0.9 0.2 -1.1 0.6 -0.8

049 E1019 -0.1 0.2

E415 -0.4 0.1 0.3 1.6 0.5 0.1 -0.6 0.4 0.4 0.5 0.9 0.1

050 E415 2.7 0.9 0.3 1.3 0.7 -0.5 0.2 0.8 2.7 -1.2

051 E415 -1.4 -0.4 -2.0 0.2 0.0 -1.7 0.0 0.6 -0.6 -0.3 0.2 -0.9

052 E415 -0.1 -1.1 -0.5 0.3 0.4 -0.5 1.6

053 E415 1.1 -0.5 0.1 -3.4 2.2 1.4 0.3 0.2 -1.8 0.0 -0.2 2.3 -1.5

054 Other 2.2

055 E415 1.2 0.5 0.3 1.1 0.7 1.0 -0.6 -0.8 2.0 -2.4

056 E1019 -0.8 0.2 1.2

E1085 1.3 -2.3 -0.3 -1.4 -1.1 0.8

E415 -1.4 -0.5 0.4 -0.8 -0.9 -0.8 -1.1 -0.5 -0.4 -0.5 -0.2 0.1 0.1

057 E1019 0.7 0.2 0.9

E1085 -0.5 -0.8 -0.2 -1.4 -0.2 -0.3

E415 -0.2 0.5 -0.3 -0.2 0.7 1.2 -1.5 -0.3 0.6

058 E1019 -0.1 -0.3 -1.2

18

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058 E415 -0.8 -0.5 -0.2 -0.8 1.0 -0.8 -0.3 -1.1 0.0 0.0 -0.8 1.0 0.9

059 E415 -0.8 0.0 0.8 -1.4 -0.2 0.0 -0.8 1.1 0.6 -0.5 0.6 -0.5 -1.2

060 E415 0.1 0.1 1.7 -0.1 0.7 0.1 -0.9 -0.9 0.2 -0.4 -0.6 -0.2 -2.3

061 E1019 1.1 1.0 1.4

E415 -0.8 -0.1 1.2 0.6 -0.5 1.0 -0.1 -0.6 1.7 0.9 -1.3 -0.4 -0.9

062 E415 1.3 -1.2 1.5 1.8 -0.4 1.6 0.6 0.6 1.1 -0.1 -0.2 -1.5 1.0

063 E415 -0.2 3.2 -1.3 -2.6 0.7 -1.7 -2.3 -0.5 -1.3 -1.2

064 E1019 -1.4 0.6 -0.8

E415 -0.4 -0.2 -1.0 -0.4 0.1 0.4 -0.3 -0.3 -0.2 -0.2 -1.1 -2.0 -0.3

065 E415 0.9 0.1 -0.5 -1.2 0.1 0.3 0.6 3.0 0.4 1.6 -0.5

066 E415 -1.0 0.8 0.7 -0.6 0.3 -1.3 1.9 -0.5 -1.1 0.2

Other -0.1 -0.3 0.4 -0.4 0.3 -1.3 -0.6 -0.8 0.1

067 E1019 -1.5 0.4 -1.3

E415 0.9 -0.9 0.1 0.4 0.1 -0.4 -0.1 0.2 -0.1 0.3 -0.8

068 E1019 0.0

E415 -0.1 0.4 0.6 0.7 -1.5 1.8 -0.2 0.8 2.1 3.1 1.2 1.3 0.5 0.0

069 E1019 1.5 0.2

E415 1.4 0.8 1.3 0.9 -0.1 0.5 -0.5 -0.1 1.9 0.0 0.0 -0.5 -1.1 0.9

070 E1019 -0.9

E415 0.9 0.5 1.3 0.9 0.5 1.3 -0.4 1.2 0.9 -2.0 0.2 -0.8 0.6

ICP 2.1

071 E1019 -0.4 -0.5 0.2

E415 0.4 0.4 0.0 -0.3 0.7 -0.2 0.4 0.6 0.2 0.2 -0.1 -0.7 0.1 -0.2

072 E415 -1.4 -2.2 -0.8 -0.2 2.3 -0.2 -1.1 -0.3 0.9 -1.5 3.1 -2.7

Other -2.3 -0.2 -1.2 0.1 -2.6 0.3 -0.9 -1.5 0.2 -2.6 2.4

073 E415 -2.4 0.3 1.2 -0.9 1.4 0.3 0.0 1.0 0.6 3.0 -0.5

074 E1019 0.2 0.6 -0.5

19

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074 E415 0.5 0.5 0.5 -0.4 0.0 0.4 0.0 0.1 0.0 0.1

075 E1019 0.1 -2.4

E415 2.1 1.8 1.0 -0.2 0.0 0.2 -0.5 0.8 -0.2 0.3

076 E415 0.4 0.8 -1.3 -1.1 0.7 -0.2 0.6 -2.1 -1.3 -1.8 0.8 -1.0 3.4 -1.2

077 E415 1.3 1.0 -1.0 0.6 0.4 1.6 1.6 1.2 1.7 0.8 0.8 -0.1 2.2

078 E415 -1.3 -2.6 0.4 -0.3 -3.3 1.1 -0.3 1.3 -2.7 -1.7 -2.4 1.5 -0.5

079 Other 0.4 0.2 0.4 0.1 0.7 0.8 0.0 -0.5 2.2 0.4 -0.1 0.0

080 Other -3.2 0.1 -0.8 -0.2 1.9 0.0 0.6 -0.4

081 E415 1.5 0.6 0.7 0.7 0.1 1.3 1.0 0.3

082 E1019 -0.5 -0.2 -1.2

E1085 -1.8 -2.3 -0.9 -1.4 -1.3 1.1

E415 -1.7 -0.9 -1.1 -1.9 -0.9 -0.8 -0.5 0.6 -0.2 -0.2 -0.8 0.8 -0.8

083 E415 -0.9 -1.7 3.0 1.1 2.0 1.1

084 E1019 0.8

E415 -0.2 1.3 -0.3 0.2 -0.8 1.0 1.0 -0.4 0.4 0.1 0.1 0.0

085 E415 0.2 -0.3 -2.3 0.1 2.8 -1.9 0.0 0.0 1.9 -0.1 1.8

086 E415 0.4 1.5 1.0 0.5 -1.7 0.2 0.6

087 E415 -2.0 -1.8 -1.3 0.1 -0.4 -0.5 1.3 -2.7 -3.4

088 E1019 -0.4 1.4 0.9

E415 0.0 -0.4 -0.2 -0.5 -0.3 -0.4 -0.1 -0.2 0.0 -0.6 0.0 0.3 -0.2

ICP -0.2 -0.2 -0.6 -1.1 0.3 0.1 2.0 -0.3

089 E322 0.1 0.1 -2.5 -2.8 1.3

E415 0.2 0.8 -1.6 -1.3 -0.7 0.7 -3.1 -2.1 0.9 -2.4 -0.9 -1.9 0.6 0.3

090 E1019 -1.5

E415 -1.4 0.4 -0.5 0.4 -0.3 -2.0 1.0 0.3 1.5 0.0 -1.6 1.1 -0.6

091 E415 -1.5 0.4 2.3 -0.3 0.7 0.0 0.3 1.0 3.8 0.6 0.7 0.3 1.0

092 E415 -0.8 -0.4 1.4 0.4 -1.4 1.7 0.6 2.4 0.8 -0.2 3.4 -0.2

20

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093 E415 -0.2 -0.3 -0.7 0.4 2.9 0.6 1.2

094 E1019 0.4 -0.5 0.2

E415 -0.2 0.7 -0.2 -0.5 0.8 -0.3 1.1 0.6

095 E1019 0.2

E415 0.9 0.8 0.0 0.7 -0.9 -0.8 0.9 1.0 -0.5 0.8 0.5 0.3

096 E415 0.6 1.4 0.1 1.0 0.9 0.6 0.0 1.6

097 E1019 -2.0 0.4 -2.0

E415 0.4 0.4 -1.1 -0.6 0.7 -0.5 0.0 0.1 1.1 0.2 1.1 0.0 -1.5 -1.2

098 E415 0.4 -0.7 -0.1 0.3 1.0 2.0 -1.8 1.1 1.0

099 E415 -2.6 -0.5 0.0 0.6 0.7 -1.4 0.6 2.1 1.1 2.7 -0.5 -0.5 0.6 -2.7

100 E1019 -1.0 -0.5 0.8

E1085 0.7 -0.5 -0.1 -1.0 -0.8 -1.8 -0.5

E415 0.6 1.4 1.0 -0.3 0.2 0.4 0.3 0.1 -0.2 1.7 -0.2 -0.2 -0.6 -0.3

Other 0.1

101 ICP -0.4 0.1 0.5 0.4 -0.6 -0.3

Other -0.4 -0.2 -1.2 -0.4

102 E415 -0.5 0.2 0.7 -0.6 -0.8 0.8 -0.3 0.2 0.0 0.1 -0.9 -0.3

103 E415 0.4 -1.1 1.0 0.1 -0.9 -0.3 0.4 0.8 1.7 0.6

104 E1019 0.5 -1.2

E415 0.8 2.5 0.0 2.9 0.7 0.3 0.6 0.9 1.4 -1.9 -1.5 1.5

21

ASTM Proficiency Test Program

Chemical Analysis Plain Carbon Steel - Aluminum

Result Dev

Method

Z

Factor

Lab

Code

E415

Z

Factor Result Dev

4Q13L1 4Q13L2

-0.8 -0.4 001 0.025 0.028 -0.5 -0.5 003 0.0248 0.0285 0.9 0.8 005 0.027 0.031 0.2 0.5 007 0.0264 0.0297 1.5 1.4 008 0.028 0.032 -0.1 -0.4 009 0.0250 0.0292 -0.8 -0.9 010 0.024 0.028 2.5 2.0 011 0.0291 0.0336 1.5 0.8 012 0.027 0.032 2.1 2.6 013 0.030 0.033 -0.6 -0.9 014 0.0241 0.0283 -0.6 -0.7 015 0.0244 0.0283 0.5 0.3 017 0.0261 0.0303 -0.2 0.2 018 0.0259 0.0291 0.3 0.5 019 0.0265 0.0299 0.6 0.8 020 0.0269 0.0305 -0.2 -0.4 021 0.025 0.029 -0.2 -0.4 022 0.025 0.029 -1.5 -1.4 023 0.0233 0.0269 -0.2 -0.4 024 0.025 0.029 0.4 0.2 025 0.026 0.030 -0.5 -0.6 026 0.0246 0.0286 0.9 1.4 028 0.028 0.031 -0.8 -0.9 029 0.024 0.028 -0.1 -0.3 030 0.0251 0.0293 -1.5 -1.4 031 0.0232 0.0269 0.6 0.2 032 0.026 0.0304 -0.8 -0.8 033 0.0243 0.0281 -0.2 -0.4 034 0.025 0.029 -3.2 035 0.0202 ** 0.0237 0.4 -0.9 036 0.024 0.030 -0.5 -0.6 037 0.0245 0.0285 0.4 0.2 038 0.026 0.030 0.9 0.8 039 0.027 0.0310 0.4 0.2 040 0.026 0.0301 -0.3 -0.3 041 0.0251 0.0289 2.0 1.5 042 0.0282 0.0328 0.9 0.8 043 0.027 0.031 0.9 0.6 044 0.0267 0.0309 0.5 1.2 045 0.0276 0.0302 0.4 0.8 048 0.027 0.030 -0.4 -0.4 049 0.0250 0.0287 2.7 2.0 050 0.029 0.034 -1.4 -1.5 051 0.0230 0.0271 1.1 1.3 053 0.0278 0.0313 1.2 1.4 055 0.0280 0.0314 -1.4 -0.9 056 0.024 0.027 -0.2 -0.4 057 0.025 0.029

22



Result Dev

Method

Z

Factor

Lab

Code

E415

Z

Factor Result Dev

4Q13L1 4Q13L2

-0.8 -0.9 058 0.024 0.028 -0.8 -0.9 059 0.0240 0.028 0.1 0.2 060 0.0259 0.0296 -0.8 -1.5 061 0.023 0.028 1.3 0.9 062 0.0272 0.0316 -0.2 0.2 063 0.026 0.029 -0.4 -0.1 064 0.0254 0.0288 0.9 1.4 065 0.028 0.031 0.9 0.8 067 0.027 0.031 -0.1 -0.2 068 0.0253 0.0293 1.4 1.5 069 0.0281 0.0317 0.9 0.9 070 0.0271 0.0309 0.4 0.2 071 0.026 0.030 -1.4 -2.1 072 0.022 0.027 -2.4 -2.3 073 0.0217 0.0254 0.5 0.2 074 0.0259 0.0302 0.4 0.2 076 0.026 0.030 1.3 1.0 077 0.0273 0.0316 -1.3 -1.0 078 0.0239 0.0272 -1.7 -1.8 082 0.0225 0.0265 083 ** 0.015 ** 0.016 -0.2 -0.4 084 0.0249 0.0291 0.2 0.1 085 0.0258 0.0298 0.4 0.8 086 0.027 0.030 -2.0 -2.1 087 0.022 0.026 0.0 0.1 088 0.0258 0.0294 0.2 0.0 089 0.0256 0.0298 -1.4 -0.9 090 0.024 0.027 -1.5 -0.5 091 0.0247 0.0268 -0.8 -0.8 092 0.0243 0.0281 -0.2 0.2 093 0.026 0.029 -0.2 -0.4 094 0.025 0.029 0.9 0.8 095 0.027 0.031 0.6 0.5 096 0.0265 0.0305 0.4 0.2 097 0.026 0.030 0.4 0.2 098 0.026 0.030 -2.6 -2.1 099 0.022 0.025 0.6 0.5 100 0.0264 0.0304 -0.5 -0.5 102 0.0248 0.0286 0.4 0.2 103 0.026 0.030 0.8 0.6 104 0.0266 0.0308

Robust Mean

Robust Std. Dev

0.0256

0.0017

0.0295

0.0017

23



Result Dev

Method

Z

Factor

Lab

Code

ICP

Z

Factor Result Dev

4Q13L1 4Q13L2

022 ** 0.003 ** 0.003 0.9 0.8 048 0.027 0.031 2.1 2.0 070 0.029 0.033 -0.2 -0.4 088 0.025 0.029 -0.4 -0.4 101 0.0250 0.0288

Robust Mean

Robust Std. Dev

0.0265

0.0022

0.0305

0.0022

Result Dev

Method

Z

Factor

Lab

Code

Other

Result Dev

4Q13L1 4Q13L2

046 EDXRF ** 0.058 ** 0.083 -2.3 072 ASTM E415 (OES) on ARL 3460 0.0203 0.0255 0.4 079 OES 0.026 0.030 -3.2 080 ISO 13898, 15350, 15351 ** 0.020 0.024

Robust Mean

Robust Std. Dev

0.0292

0.0164

0.0265

0.0035

Overall Summary

Robust Std.Dev

Robust Mean

Comment:

** Data which is asterisked is not included in statistical analysis.

See report introduction for information.

0.0256

0.0017

0.0294

0.0017

Committee E01 has determined that when the Robust Standard Deviation is greater than 20% of the Robust Mean then

the Z-Factor calculations are meaningless and should not be calculated.

24

Average

Std. Dev

2 Std. Dev

Std. Dev

2 Std. Dev

E415 ICP Other

Method

0.0205

0.0222

0.0239

0.0256

0.0273

0.029

0.0307

8

3

3

5

7

3

9

9

7

2

8

7

8

2

6

1

5

1

3

1

2

3

7

8

5

9

5

6

3

6

2

9

5

8

1

0

9

0

1

4

9

2

3

3

1

5

3

7

2

6

9

1

3

1

0

2

8

4

9

9

4

2

1

2

2

2

4

3

4

4

9

5

7

1

4

1

3

0

6

8

6

4

8

9

8

8

8

5

7

4

1

8

6

0

1

0

3

9

8

9

7

4

0

9

3

7

6

7

1

6

3

3

8

3

2

2

5

1

7

1

0

0

7

1

9

9

6

1

0

4

4

4

2

0

3

9

8

6

9

5

1

2

5

4

3

6

7

4

8

7

0

6

2

7

7

4

5

5

3

2

8

5

5

8

6

5

6

9

4

2

5

0

1

1

1

3

2

2

8

8

1

0

1

4

8

7

0

8

0

7

2

7

9

4

6

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Lab code

ASTM Proficiency Test Program - Aluminum Sample ID :4Q13L1

25

Average

Std. Dev

2 Std. Dev

Std. Dev

2 Std. Dev

E415 ICP Other

Method

0.0243

0.026

0.0277

0.0294

0.0311

0.0328

0.0345

8

3

3

5

9

9

7

3

8

7

8

2

9

1

3

1

2

3

9

0

7

2

5

6

5

1

7

8

6

1

5

9

1

0

2

9

5

8

1

9

2

3

3

1

4

1

5

3

7

3

2

6

1

0

2

4

9

6

4

4

1

3

4

6

3

2

2

2

1

9

4

9

3

2

4

5

7

8

4

1

8

9

6

8

3

0

8

8

6

0

7

8

9

8

5

1

9

2

5

7

6

7

1

4

8

3

8

3

6

8

6

1

0

3

9

8

9

7

4

0

7

4

4

5

1

7

3

2

1

0

0

9

6

2

0

1

0

4

4

4

7

0

2

8

6

7

6

5

9

5

5

4

3

3

9

5

3

5

5

6

2

7

7

6

9

8

1

2

4

2

1

3

1

1

5

0

2

2

1

0

1

8

8

4

8

7

0

8

0

7

2

7

9

4

6

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Lab code

ASTM Proficiency Test Program - Aluminum Sample ID :4Q13L2

26

Average

Average

Std. Dev

2 Std. Dev

0.0243

0.026

0.0277

0.0294

0.0311

0.0328

0.0345

0.0205 0.0222 0.0239 0.0256 0.0273 0.029 0.0307

Sam

ple

ID

: 4Q

13L

2

Sample ID: 4Q13L1

ASTM Proficiency Test Program - Aluminum

E415

ICP

Other Method

27


Chemical Analysis Plain Carbon Steel - Arsenic

Result Dev

Method

Z

Factor

Lab

Code

E415

Z

Factor Result Dev

4Q13L1 4Q13L2

0.5 0.5 001 0.0048 0.0048 2.6 2.5 005 0.0064 0.0065 -0.1 0.1 008 0.0045 0.0043 009 ** 0.0075 ** 0.0075 2.9 011 ** 0.0075 0.0067 -1.0 -1.1 015 0.0035 0.0036 0.5 0.8 017 0.0050 0.0048 -0.9 -1.1 019 0.0035 0.0037 -0.2 -0.1 020 0.0043 0.0042 -0.1 -0.1 021 0.0043 0.0043 2.0 022 0.006 ** 0.009 -0.5 -0.5 025 0.004 0.004 -1.0 -1.2 026 0.0034 0.0036 031 ** 0.0016 ** 0.0013 -0.1 0.0 032 0.0044 0.0043 -2.2 -2.1 033 0.0027 0.0026 0.8 0.9 037 0.0051 0.0050 -0.1 -0.2 038 0.0042 0.0043 0.4 0.8 040 0.005 0.0047 1.5 1.4 041 0.0055 0.0056 0.2 0.1 042 0.0045 0.0046 1.4 1.1 044 0.0053 0.0055 -0.5 -0.4 053 0.0041 0.0040 -0.5 -0.5 056 0.0040 0.0040 -0.5 -0.5 058 0.0040 0.0040 0.0 0.0 059 0.0044 0.0044 0.1 0.1 060 0.0045 0.0045 -0.1 -0.1 061 0.0043 0.0043 -1.2 -1.4 062 0.0033 0.0034 3.2 3.2 063 0.007 0.007 -0.2 -0.4 064 0.0041 0.0042 -0.9 -1.0 067 0.0036 0.0037 0.4 0.0 068 0.0044 0.0047 0.8 0.6 069 0.0049 0.0050 0.5 0.8 070 0.005 0.0048 0.4 0.2 071 0.0046 0.0047 -2.2 -2.1 072 0.0027 0.0026 0.8 0.8 076 0.005 0.005 1.0 0.6 077 0.0049 0.0052 -2.6 -2.5 078 0.0024 0.0023 -0.9 -1.0 082 0.0036 0.0037 -0.4 -0.2 088 0.0042 0.0041 0.8 0.8 089 0.0050 0.0050 0.4 0.2 090 0.0046 0.0047 0.8 0.8 095 0.005 0.005 0.4 0.8 097 0.0050 0.0047 -0.5 -0.5 099 0.004 0.004 1.4 1.2 100 0.0054 0.0055

28


Chemical Analysis Plain Carbon Steel - Arsenic

Result Dev

Method

Z

Factor

Lab

Code

E415

Z

Factor Result Dev

4Q13L1 4Q13L2

2.5 1.8 104 0.0058 0.0064

Robust Mean

Robust Std. Dev

0.0045

0.0008

0.0045

0.0008

Result Dev

Method

Z

Factor

Lab

Code

ICP

Z

Factor Result Dev

4Q13L1 4Q13L2

-0.2 -0.2 088 0.0042 0.0042

Robust Mean

Robust Std. Dev

Result Dev

Method

Lab

Code

Other

Result Dev

4Q13L1 4Q13L2

044 E1085 0.0041 0.0039 072 ASTM E415 (OES) on ARL 3460 0.0025 0.0025

Robust Mean

Robust Std. Dev

Overall Summary

Robust Std.Dev

Robust Mean

Comment:



E1085 is specified by this element, but is not in the scope.

0.0044

0.0008

0.0044

0.0008



29

Average

Std. Dev

2 Std. Dev

Std. Dev

2 Std. Dev

E415 ICP

Other Method

0.002

0.0028

0.0036

0.0044

0.0052

0.006

0.0068

3

1

7

8

3

3

7

2

6

2

2

6

1

5

1

9

8

2

6

7

5

8

2

5

9

9

5

6

6

4

5

3

8

8

3

8

2

0

6

1

2

1

3

2

6

8

5

9

6

0

8

4

2

9

0

7

1

1

6

9

7

7

9

7

4

0

8

9

7

6

1

7

9

5

7

0

3

7

4

4

1

0

0

4

1

1

0

4

2

2

5

6

3

1

1

9

8

8

7

2

4

4

Av

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ge R

esu

lts

Lab code

ASTM Proficiency Test Program - Arsenic Sample ID :4Q13L1

30

Average

Std. Dev

2 Std. Dev

Std. Dev

2 Std. Dev

E415 ICP

Other Method

0.002

0.0028

0.0036

0.0044

0.0052

0.006

0.0068

3

1

7

8

7

2

3

3

6

2

1

5

2

6

1

9

8

2

6

7

5

3

5

6

9

9

5

8

2

5

8

8

2

0

6

4

3

8

8

3

2

2

1

6

1

5

9

6

0

4

2

9

0

9

7

4

0

7

1

6

8

7

0

1

7

1

7

6

6

9

9

5

3

7

8

9

7

7

1

0

0

4

4

4

1

1

0

4

5

1

1

6

3

9

2

2

8

8

7

2

4

4

Av

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Lab code

ASTM Proficiency Test Program - Arsenic Sample ID :4Q13L2

31

Average

Average

Std. Dev

2 Std. Dev

0.002

0.0028

0.0036

0.0044

0.0052

0.006

0.0068

0.002 0.0028 0.0036 0.0044 0.0052 0.006 0.0068

Sam

ple

ID

: 4Q

13L

2

Sample ID: 4Q13L1

ASTM Proficiency Test Program - Arsenic

E415

ICP

Other Method

32


Chemical Analysis Plain Carbon Steel - Calcium

Result Dev

Method

Z

Factor

Lab

Code

E1085

Z

Factor Result Dev

4Q13L1 4Q13L2

-3.0 0.0 025 0.0010 0.0000

Robust Mean

Robust Std. Dev

Result Dev

Method

Lab

Code

E415

Z

Factor Result Dev

4Q13L1 4Q13L2

-1.0 001 0.0008 0.0003 2.0 003 0.0014 0.0002 0.5 005 0.0011 0.0005 0.0 008 0.0010 0.0003 -0.5 009 0.0009 0.0003 -0.5 011 0.0009 0.0004 1.0 012 0.0012 0.0004 -0.5 015 0.0009 0.0003 0.0 017 0.0010 0.0004 -0.5 020 0.0009 0.0002 0.5 021 0.0011 0.0004 0.0 022 0.001 ** 0.001 0.0 025 0.001 0.0003 -1.0 026 0.0008 0.0003 0.0 032 0.0010 0.0004 -1.0 037 0.0008 0.0003 0.0 038 0.0010 -1.0 040 0.0008 0.0003 -0.5 041 0.0009 0.0004 043 ** 0.000 0.000 -0.5 044 0.0009 0.0005 2.0 049 0.0014 0.0002 -1.0 051 0.0008 0.0003 0.5 053 0.0011 0.0004 -1.0 056 0.0008 0.0003 0.5 057 0.0011 0.0004 0.0 058 0.0010 0.0003 -0.5 059 0.0009 0.0003 061 ** 0.0025 ** 0.0037 0.0 062 0.0010 0.0004 063 0.000 -1.0 064 0.0008 0.0002 -0.5 067 0.0009 0.0003 -1.5 068 0.0007 0.0002 -2.0 069 0.0006 0.0001 1.0 070 0.0012 0.0006 -0.5 071 0.0009 0.0003 072 ** 0.0018 0.0009 -2.0 076 0.0006 0.0000



33



Result Dev

Method

Lab

Code

E415

Z

Factor Result Dev

4Q13L1 4Q13L2

0.0 078 0.0010 0.0007 -1.5 082 0.0007 0.0008 0.0 084 0.0010 0.0003 -1.0 085 0.0008 0.0003 0.5 087 0.0011 -1.5 088 0.0007 0.0001 090 ** 0.0018 ** 0.0010 1.5 091 0.0013 0.0004 1.5 092 0.0013 0.0004 0.5 095 0.0011 0.0003 -0.5 097 0.0009 0.0003 2.0 099 0.0014 0.0002 -1.0 100 0.0008 0.0003 1.0 102 0.0012 0.0005

Robust Mean

Robust Std. Dev

0.0010

0.0002

0.0003

0.0001

Result Dev

Method

Lab

Code

ICP

Result Dev

4Q13L1 4Q13L2

022 ** 0.011 ** 0.009 088 0.0016 ** 0.0010

Robust Mean

Robust Std. Dev

Result Dev

Method

Lab

Code

Other

Z

Factor Result Dev

4Q13L1 4Q13L2

046 EDXRF ** 0.0102 072 ASTM E415 (OES) on ARL 3460 0.0016 0.0009 079 OES 0.0011 0.0003

Robust Mean

Robust Std. Dev

0.0038

0.0063



34



Overall Summary

Robust Std.Dev

Robust Mean

Comment:



0.0010

0.0002

0.0003

0.0001



35

Average

Std. Dev

2 Std. Dev

Std. Dev

2 Std. Dev

E1

08

5

E415 ICP

Oth

er

M

eth

od

0.0004

0.0006

0.0008

0.001

0.0012

0.0014

0.0016

2

5

4

3

6

9

7

6

8

2

6

8

8

8

4

0

6

4

8

5

5

6

1

5

1

3

7

2

6

1

0

0

4

1

2

0

5

9

6

7

1

5

9

1

1

4

4

9

7

7

1

1

7

2

2

2

5

3

2

6

2

5

8

8

8

4

3

8

7

8

5

3

2

1

5

5

7

9

5

8

7

7

0

1

0

2

1

2

9

1

9

2

3

4

9

9

9

9

0

7

2

6

1

8

8

2

2

7

9

7

2

Av

era

ge R

esu

lts

Lab code

ASTM Proficiency Test Program - Calcium Sample ID :4Q13L1

36

Average

Std. Dev

2 Std. Dev

Std. Dev

2 Std. Dev

E1

08

5

E415 ICP Other

Method

0

0.0001

0.0002

0.0003

0.0004

0.0005

0.0006

2

5

7

6

6

3

4

3

6

9

8

8

6

8

4

9

9

9

2

0

6

4

3

4

0

9

5

5

1

5

6

1

5

5

8

5

9

9

7

7

1

8

5

3

7

9

2

6

2

5

1

0

0

8

8

4

6

7

1

5

7

5

3

4

1

3

2

2

1

1

7

1

2

1

1

6

2

9

2

9

1

5

1

0

2

4

4

7

0

7

8

8

2

7

2

2

2

9

0

6

1

8

8

2

2

7

9

7

2

4

6

Av

era

ge R

esu

lts

Lab code

ASTM Proficiency Test Program - Calcium Sample ID :4Q13L2

37

Average

Average

Std. Dev

2 Std. Dev

0

0.0001

0.0002

0.0003

0.0004

0.0005

0.0006

0.0004 0.0006 0.0008 0.001 0.0012 0.0014 0.0016

Sam

ple

ID

: 4Q

13L

2

Sample ID: 4Q13L1

ASTM Proficiency Test Program - Calcium

E1085

E415

Other Method

38


Chemical Analysis Plain Carbon Steel - Carbon

Result Dev

Method

Z

Factor

Lab

Code

E1019

Z

Factor Result Dev

4Q13L1 4Q13L2

-0.4 -0.5 002 0.4290 0.4160 0.7 -0.4 003 0.4300 0.4260 -0.4 -0.3 006 0.431 0.416 0.3 -0.6 007 0.428 0.423 -0.5 -0.8 008 0.4262 0.4148 -1.4 -1.8 010 0.416 0.407 -0.4 -0.2 011 0.4323 0.4158 0.3 -0.1 012 0.4332 0.4227 1.5 2.5 015 0.4598 0.4343 1.8 0.4 017 0.4383 0.4370 -1.6 -1.0 018 0.424 0.405 -0.1 -0.8 019 0.426 0.419 -0.2 0.4 020 0.4388 0.4183 -0.5 0.2 021 0.436 0.415 0.4 -0.4 024 0.430 0.424 -0.1 0.7 025 0.442 0.419 -1.3 -0.8 026 0.426 0.408 -0.8 028 ** 0.401 0.412 -1.7 -1.5 029 0.419 0.404 1.5 0.4 031 0.4380 0.4340 0.7 0.9 032 0.444 0.426 0.5 -0.1 034 0.433 0.425 -0.6 -0.2 036 0.432 0.414 -0.2 -0.1 038 0.433 0.418 -0.2 -0.1 040 0.433 0.418 0.5 0.6 042 0.4405 0.4245 -2.2 -1.4 043 0.420 0.399 -1.9 0.4 044 0.438 0.402 0.0 0.8 047 0.443 0.420 -0.5 -1.0 048 0.424 0.415 -0.1 -0.2 049 0.4319 0.4193 -0.8 -0.3 056 0.431 0.412 0.7 0.7 057 0.441 0.426 -0.1 0.9 058 0.444 0.419 1.1 -0.1 061 0.433 0.430 -1.4 0.0 064 0.434 0.407 -1.5 -0.6 067 0.428 0.406 1.5 0.9 069 0.4437 0.4336 -0.9 -0.8 070 0.4261 0.4114 -0.4 -0.2 071 0.432 0.416 0.2 -0.3 074 0.4312 0.4220 0.1 0.1 075 0.435 0.421 -0.5 0.3 082 0.437 0.415 -0.4 0.3 088 0.4370 0.4160 -1.5 -2.0 090 0.414 0.406 0.4 -0.1 094 0.433 0.424 -2.0 -0.3 097 0.431 0.401 -1.0 0.1 100 0.435 0.411

39



Result Dev

Method

Z

Factor

Lab

Code

E1019

Z

Factor Result Dev

4Q13L1 4Q13L2

0.5 0.2 104 0.4367 0.4243

Robust Mean

Robust Std. Dev

0.4327

0.0068

0.4173

0.0091

Result Dev

Method

Z

Factor

Lab

Code

E415

Z

Factor Result Dev

4Q13L1 4Q13L2

-0.5 0.6 001 0.440 0.415 0.3 -0.7 003 0.4270 0.4224 0.4 -1.2 004 0.422 0.424 -1.8 0.3 005 0.437 0.403 -0.3 1.6 007 0.4502 0.4169 -0.5 -0.8 008 0.426 0.415 0.6 0.6 009 0.4408 0.4258 -1.4 -1.8 010 0.416 0.407 0.0 0.1 011 0.4349 0.4196 -0.7 -1.0 012 0.4238 0.4134 0.0 -0.4 013 0.430 0.420 -0.1 -1.1 014 0.4230 0.4190 -1.0 -1.0 015 0.424 0.4103 -1.1 0.4 017 0.4381 0.4093 -1.2 -1.2 018 0.422 0.409 1.6 0.7 019 0.442 0.435 -0.5 -0.7 020 0.4274 0.4149 0.2 0.6 021 0.440 0.422 022 ** 0.399 ** 0.387 0.9 0.4 023 0.4387 0.4286 1.1 0.7 024 0.441 0.430 -0.4 -1.5 025 0.419 0.416 0.2 -0.1 026 0.433 0.422 0.1 0.8 027 0.4426 0.4206 -0.8 028 ** 0.401 0.412 1.2 1.3 029 0.448 0.431 0.2 -0.7 030 0.4268 0.4213 1.3 0.4 031 0.4381 0.4324 0.9 1.3 032 0.448 0.428 0.5 0.8 033 0.4428 0.4244 0.5 1.1 034 0.446 0.425 0.5 0.2 035 0.4359 0.4243 -0.4 0.2 036 0.436 0.416 1.5 1.4 037 0.449 0.434 0.7 0.1 038 0.435 0.426 1.0 1.8 039 0.453 0.4290 1.8 1.1 041 0.4454 0.4371 -0.3 -0.4 042 0.4302 0.4173 -0.1 0.5 043 0.439 0.419

40



Result Dev

Method

Z

Factor

Lab

Code

E415

Z

Factor Result Dev

4Q13L1 4Q13L2

1.2 -0.3 044 0.431 0.431 0.6 0.6 045 0.4400 0.4253 0.1 0.2 049 0.4367 0.4207 0.9 050 ** 0.475 0.428 -0.4 -2.0 051 0.4137 0.4164 -0.1 2.9 052 0.464 0.419 0.1 -1.4 053 0.420 0.421 0.5 0.4 055 0.4381 0.4247 0.4 -0.2 056 0.432 0.424 0.5 -0.3 057 0.431 0.425 -0.2 -0.3 058 0.431 0.418 0.8 -0.5 059 0.4290 0.427 1.7 2.0 060 0.4543 0.4361 1.2 0.9 061 0.444 0.431 1.5 2.3 062 0.458 0.434 -1.3 -0.4 063 0.430 0.408 -1.0 -1.0 064 0.424 0.411 0.1 -0.6 065 0.428 0.421 -1.0 -0.9 066 0.425 0.411 0.6 1.2 068 0.4466 0.4254 1.3 0.8 069 0.4423 0.4322 1.3 2.2 070 0.457 0.432 0.0 -0.4 071 0.430 0.420 -0.8 -1.0 072 0.424 0.412 0.3 2.7 073 0.4616 0.4231 2.1 1.6 075 0.4507 0.4395 -1.3 -2.3 076 0.411 0.408 -1.0 -0.8 077 0.426 0.411 0.4 0.1 078 0.4351 0.4233 1.5 2.5 081 0.460 0.434 -1.1 -0.3 082 0.431 0.410 083 ** 0.377 ** 0.379 1.3 1.2 084 0.447 0.432 -0.3 0.4 085 0.438 0.417 1.5 1.1 086 0.446 0.434 -1.8 -0.9 087 0.425 0.403 -0.2 0.7 088 0.4417 0.4183 -1.6 -2.0 089 0.414 0.405 -0.5 -1.3 090 0.421 0.415 0.4 0.0 091 0.4348 0.4239 -0.4 -0.6 092 0.4285 0.4166 -0.3 0.8 093 0.443 0.417 0.7 0.9 094 0.444 0.426 1.4 0.9 096 0.444 0.433 -1.1 0.1 097 0.435 0.410 -0.7 0.1 098 0.435 0.413 0.0 1.3 099 0.448 0.420 1.0 2.0 100 0.455 0.429

41



Result Dev

Method

Z

Factor

Lab

Code

E415

Z

Factor Result Dev

4Q13L1 4Q13L2

0.2 0.7 102 0.441 0.422 -1.1 -1.0 103 0.424 0.410 0.0 -1.1 104 0.4226 0.420

Robust Mean

Robust Std. Dev

0.4354

0.0122

0.4212

0.0092

Result Dev

Method

Z

Factor

Lab

Code

Other

Z

Factor Result Dev

4Q13L1 4Q13L2

-1.3 -1.7 006 Spark OES 0.417 0.408 -2.9 016 ISO/ASTM E353/BS6200/BS EN 0.405 ** 0.389 2.2 1.9 054 Combustion-infrared absorption 0.454 0.440 -0.1 -0.1 066 Combustion and gasometric method 0.433 0.419 -0.2 -1.2 072 ASTM E415 (OES) on ARL 3460 0.4224 0.4182 0.2 -0.3 079 OES 0.431 0.422 0.1 -0.2 080 ISO 13898, 15350, 15351 0.4319 0.4211 -0.4 0.0 101 ISO15350 0.4342 0.4165

Robust Mean

Robust Std. Dev

0.4283

0.0126

0.4194

0.0049

Overall Summary

Robust Std.Dev

Robust Mean

Comment:


E353 is specified in Other Methods section.E353applies to Stainless, Heat Resisting, Maraging and other Similar Cr-Ni-Fe Alloys. E350 applies to low alloy steel


0.4343

0.0102

0.4199

0.0093

42

Average

Std. Dev

2 Std. Dev

Std. Dev

2 Std. Dev

E1019 E415 Other

Method

0.4037

0.4139

0.4241

0.4343

0.4445

0.4547

0.4649

2

8

1

0

4

3

4

8

1

9

8

7

2

4

5

6

6

4

9

7

1

6

1

9

4

3

8

6

4

1

0

0

1

0

4

8

8

3

1

2

0

5

7

4

7

5

8

1

5

2

2

7

6

8

9

2

5

9

0

1

8

1

4

7

2

1

0

3

6

6

8

3

0

2

0

9

2

1

3

6

3

5

8

8

2

5

6

9

1

9

7

3

8

3

5

4

9

8

5

1

7

2

3

1

2

1

1

0

2

8

8

6

9

3

3

9

6

9

4

3

4

6

8

2

9

3

2

7

3

9

1

0

0

6

2

7

3

5

0

6

7

9

6

6

5

4

Av

era

ge R

esu

lts

Lab code

ASTM Proficiency Test Program - Carbon Sample ID :4Q13L1

43

Average

Std. Dev

2 Std. Dev

Std. Dev

2 Std. Dev

E1019 E415 Other

Method

0.392

0.4013

0.4106

0.4199

0.4292

0.4385

0.4478

4

3

4

4

1

8

9

0

1

0

1

0

0

2

8

3

6

2

1

8

2

8

8

7

1

4

0

2

0

5

8

4

9

7

5

1

2

2

4

1

0

4

3

4

3

6

1

3

1

1

7

2

2

8

7

1

0

6

3

1

7

1

0

3

1

5

6

4

7

2

9

8

2

0

9

0

2

5

5

1

7

9

3

5

8

4

3

5

2

1

3

9

9

2

7

5

3

3

0

2

6

3

7

8

5

6

3

5

5

5

5

7

6

8

9

4

5

9

5

0

1

0

0

2

4

4

4

8

4

6

9

9

6

3

7

6

2

6

0

7

5

6

7

2

8

0

5

4

Av

era

ge R

esu

lts

Lab code

ASTM Proficiency Test Program - Carbon Sample ID :4Q13L2

44

Average

Average

Std. Dev

2 Std. Dev

0.392

0.4013

0.4106

0.4199

0.4292

0.4385

0.4478

0.4037 0.4139 0.4241 0.4343 0.4445 0.4547 0.4649

Sam

ple

ID

: 4Q

13L

2

Sample ID: 4Q13L1

ASTM Proficiency Test Program - Carbon

E1019

E415

Other Method

45


Chemical Analysis Plain Carbon Steel - Chromium

Result Dev

Method

Z

Factor

Lab

Code

E1085

Z

Factor Result Dev

4Q13L1 4Q13L2

1.0 0.5 007 1.061 1.026 -0.4 0.7 021 1.065 1.003 025 ** 1.113 ** 1.071 -0.3 -0.3 029 1.046 1.006 0.6 0.8 030 1.066 1.020 0.6 -0.1 032 1.050 1.020 2.1 1.8 044 1.085 1.043 1.3 -0.1 056 1.050 1.030 -0.5 -0.7 057 1.040 1.002 -1.8 -0.6 082 1.041 0.982 0.7 0.8 100 1.066 1.021

Robust Mean

Robust Std. Dev

1.0596

0.0180

1.0190

0.0199

Result Dev

Method

Z

Factor

Lab

Code

E322

Z

Factor Result Dev

4Q13L1 4Q13L2

-0.4 -0.9 047 1.036 1.004 0.1 -0.1 089 1.050 1.011

Robust Mean

Robust Std. Dev

Result Dev

Method

Z

Factor

Lab

Code

E415

Z

Factor Result Dev

4Q13L1 4Q13L2

-1.1 -0.4 001 1.044 0.993 -0.9 -0.2 003 1.048 0.9950 -1.5 -1.6 004 1.024 0.986 -1.1 -1.0 005 1.035 0.993 0.7 -0.1 007 1.051 1.022 0.2 -0.1 008 1.051 1.014 0.6 0.5 009 1.0602 1.0203 -1.7 010 ** 0.103 0.983 0.1 0.0 011 1.0518 1.0121 -2.2 -2.1 012 1.014 0.975 -2.5 -1.8 013 1.020 0.970 0.6 -0.1 014 1.050 1.0200 -1.1 -1.2 015 1.0303 0.9919 -0.4 0.2 017 1.0558 1.0043 0.9 1.1 018 1.071 1.025 0.0 -0.4 019 1.044 1.010 0.4 0.6 020 1.0622 1.0164 0.3 0.2 021 1.056 1.015

46



Result Dev

Method

Z

Factor

Lab

Code

E415

Z

Factor Result Dev

4Q13L1 4Q13L2

3.1 2.7 022 1.100 1.060 1.2 1.1 023 1.0714 1.0291 0.0 -0.1 025 1.050 1.010 0.4 0.4 026 1.060 1.017 -1.1 -1.2 027 1.0314 0.9933 -0.9 -0.9 028 1.036 0.996 2.1 0.8 030 1.0658 1.0434 -0.1 -0.4 031 1.0446 1.0085 0.8 0.9 032 1.068 1.023 0.2 -0.1 033 1.0503 1.0133 1.7 1.1 035 1.072 1.037 1.1 0.9 036 1.068 1.028 -0.2 -0.1 037 1.050 1.007 0.1 -0.4 038 1.045 1.012 039 ** 1.134 ** 1.093 0.0 0.5 040 1.061 1.010 2.5 1.6 041 1.0800 1.0500 -0.4 -0.7 042 1.0391 1.0041 -2.6 043 ** 0.910 0.969 -0.5 -1.1 044 1.033 1.002 0.1 0.1 045 1.0540 1.0118 0.1 -0.3 048 1.047 1.012 0.3 0.4 049 1.0594 1.0146 0.3 -1.3 050 1.029 1.015 -2.0 -1.6 051 1.0229 0.9774 -1.1 -1.2 052 1.031 0.992 2.7 053 1.100 ** 1.070 0.3 0.4 055 1.0590 1.0147 -0.8 -1.2 056 1.030 0.998 -0.3 -0.8 057 1.037 1.006 -0.8 -1.2 058 1.030 0.997 -1.4 -1.1 059 1.0320 0.987 -0.1 0.1 060 1.053 1.008 0.6 -0.7 061 1.040 1.020 1.8 1.7 062 1.083 1.039 -2.6 -2.1 063 1.014 0.969 -0.4 -0.3 064 1.047 1.004 -0.5 -1.2 065 1.031 1.002 0.8 0.2 066 1.056 1.023 0.1 1.0 067 1.069 1.012 0.7 0.5 068 1.0607 1.0210 0.9 0.8 069 1.0655 1.0247 0.9 0.8 070 1.066 1.024 -0.3 -0.7 071 1.040 1.005 -0.2 -0.7 072 1.039 1.007 1.2 1.2 073 1.073 1.029 0.5 0.5 074 1.0606 1.0177 1.8 1.5 075 1.079 1.039

47



Result Dev

Method

Z

Factor

Lab

Code

E415

Z

Factor Result Dev

4Q13L1 4Q13L2

-1.1 -1.3 076 1.029 0.992 0.6 1.0 077 1.070 1.020 -0.3 0.2 078 1.0560 1.0057 0.6 0.6 081 1.062 1.020 -1.9 -2.0 082 1.016 0.979 0.8 083 1.067 ** 0.017 -0.3 0.1 084 1.054 1.006 -2.3 -2.2 085 1.012 0.973 -1.3 -1.0 087 1.035 0.990 -0.5 0.0 088 1.0516 1.0021 -1.3 -1.2 089 1.030 0.990 0.4 -0.1 090 1.051 1.016 2.3 2.1 091 1.0886 1.0460 1.4 1.3 092 1.0758 1.0326 -0.7 -0.7 093 1.040 0.999 -0.2 0.2 094 1.055 1.007 0.0 -0.7 095 1.040 1.010 0.1 -0.1 096 1.050 1.012 -0.6 0.1 097 1.053 1.000 -0.1 0.2 098 1.055 1.009 0.6 1.0 099 1.069 1.019 -0.3 0.0 100 1.052 1.005 0.7 0.8 102 1.066 1.022 1.0 1.0 103 1.070 1.026 104 ** 0.967 ** 0.937

Robust Mean

Robust Std. Dev

1.0509

0.0184

1.0094

0.0166

Result Dev

Method

Z

Factor

Lab

Code

ICP

Z

Factor Result Dev

4Q13L1 4Q13L2

-1.3 -3.1 006 0.996 0.989 0.1 0.4 016 1.059 1.012 2.1 022 1.090 ** 1.099 0.2 -0.2 048 1.048 1.014 1.4 070 1.077 ** 1.107 -0.6 -0.2 088 1.049 1.000 0.1 0.1 101 1.0532 1.0112

Robust Mean

Robust Std. Dev

1.0570

0.0245

1.0332

0.0550

48



Result Dev

Method

Z

Factor

Lab

Code

Other

Z

Factor Result Dev

4Q13L1 4Q13L2

0.7 0.7 002 E352-93(2006) 1.0637 1.0220 0.5 0.4 006 Spark OES 1.060 1.018 1.3 0.8 016 ISO/ASTM E353/BS6200/BS EN 1.066 1.031 0.2 -0.3 018 Atomic Absorption 1.047 1.013 1.1 3.0 046 EDXRF 1.106 1.028 -0.3 0.2 066 AAS Method 1.055 1.005 -1.2 -1.7 072 ASTM E415 (OES) on ARL 3460 1.0224 0.9905 0.4 0.3 079 OES 1.058 1.016 -0.8 -0.6 080 ISO 13898, 15350, 15351 1.041 0.997

Robust Mean

Robust Std. Dev

1.0533

0.0123

1.0136

0.0150

Overall Summary

Robust Std.Dev

Robust Mean

Comment:


E352 is specified in the Other Methods section. E353applies to Tool Steels and Medium to High Alloy Steels. E350 applies to low alloy steel.


1.0520

0.0178

1.0101

0.0159

49

Average

Std. Dev

2 Std. Dev

Std. Dev

2 Std. Dev

E1085 E3

22

E415 ICP Other

Method

0.9986

1.0164

1.0342

1.052

1.0698

1.0876

1.1054

5

7

2

9

5

6

2

1

1

0

0

2

5

8

9

4

3

8

5

1

2

1

3

4

7

6

5

6

1

5

5

2

5

9

8

7

2

8

7

2

9

5

7

1

1

9

3

1

4

8

3

1

4

9

6

9

0

8

1

1

9

7

4

5

9

8

1

7

7

8

5

5

2

6

7

4

4

0

2

0

3

0

1

0

2

3

2

9

9

1

0

3

1

8

3

5

9

2

4

1

9

1

5

3

6

8

8

1

6

2

2

8

0

6

6

6

1

6

Av

era

ge R

esu

lts

Lab code

ASTM Proficiency Test Program - Chromium Sample ID :4Q13L1

50

Average

Std. Dev

2 Std. Dev

Std. Dev

2 Std. Dev

E1085 E3

22

E415 ICP Other

Method

0.9624

0.9783

0.9942

1.0101

1.026

1.0419

1.0578

8

2

2

1

3

0

1

0

0

5

6

2

5

8

9

1

0

4

6

3

8

5

5

1

1

0

5

9

8

7

7

6

5

2

7

2

8

5

6

9

7

4

4

6

4

1

7

7

1

8

4

3

7

9

4

3

1

2

5

9

5

4

5

9

6

3

8

3

3

4

9

2

1

9

0

2

6

9

9

6

1

7

7

6

8

7

3

2

6

9

1

0

3

7

3

9

2

7

5

3

0

4

1

5

3

6

1

0

1

4

8

7

0

8

0

1

8

6

4

6

Av

era

ge R

esu

lts

Lab code

ASTM Proficiency Test Program - Chromium Sample ID :4Q13L2

51

Average

Average

Std. Dev

2 Std. Dev

0.9624

0.9783

0.9942

1.0101

1.026

1.0419

1.0578

0.9986 1.0164 1.0342 1.052 1.0698 1.0876 1.1054

Sam

ple

ID

: 4Q

13L

2

Sample ID: 4Q13L1

ASTM Proficiency Test Program - Chromium

E1085

E322

E415

ICP

Other Method

52


Chemical Analysis Plain Carbon Steel - Cobalt

Result Dev

Method

Lab

Code

E1085

Result Dev

4Q13L1 4Q13L2

025 ** 0.004 ** 0.004 030 0.0070 0.0080

Robust Mean

Robust Std. Dev

Result Dev

Method

Z

Factor

Lab

Code

E415

Z

Factor Result Dev

4Q13L1 4Q13L2

-0.3 -0.3 001 0.0063 0.0074 0.4 0.1 003 0.0066 0.0078 -1.8 -1.3 005 0.0057 0.0064 007 ** 0.0097 ** 0.0107 -0.9 -0.8 008 0.0060 0.0070 -1.4 -1.7 009 0.0054 0.0067 0.4 0.1 011 0.0066 0.0078 0.9 0.8 017 0.0070 0.0081 -0.7 -1.4 018 0.0056 0.0071 0.2 0.0 019 0.0065 0.0077 1.8 2.0 021 0.0078 0.0087 2.3 2.3 022 0.008 0.009 -0.9 -0.8 025 0.006 0.007 -0.7 0.0 026 0.0065 0.0071 -0.6 1.5 029 0.0075 0.0072 1.8 0.8 030 0.0070 0.0087 031 ** 0.0024 0.1 0.5 032 0.0068 0.0076 -0.4 -0.5 035 0.0062 0.0073 0.1 0.0 037 0.0065 0.0076 -0.3 -0.3 038 0.0063 0.0074 2.6 2.5 041 0.0081 0.0092 0.7 0.8 043 0.007 0.008 0.2 -0.2 044 0.0064 0.0077 0.2 -0.3 051 0.0063 0.0077 -3.4 -3.3 053 0.0044 0.0054 -0.9 -0.8 056 0.006 0.007 0.7 0.5 060 0.0068 0.0080 -0.4 -0.6 062 0.0061 0.0073 0.7 0.8 063 0.007 0.008 0.1 -0.2 064 0.0064 0.0076 -1.2 0.8 065 0.0070 0.0068 0.4 0.5 067 0.0068 0.0078 -1.5 -1.6 068 0.0055 0.0066 -0.1 -0.2 069 0.0064 0.0075 0.5 0.5 070 0.0068 0.0079 0.7 0.5 071 0.0068 0.0080 2.3 2.6 072 0.0082 0.0090



53



Result Dev

Method

Z

Factor

Lab

Code

E415

Z

Factor Result Dev

4Q13L1 4Q13L2

-0.9 -1.4 073 0.0056 0.0070 0.5 0.1 074 0.0066 0.0079 0.7 0.8 076 0.007 0.008 0.4 -0.2 077 0.0064 0.0078 -3.3 078 ** 0.0040 0.0055 -0.9 -1.0 082 0.0059 0.0070 -0.9 -0.8 083 0.006 0.007 0.2 0.0 084 0.0065 0.0077 -0.3 -0.5 088 0.0062 0.0074 -0.7 -0.8 089 0.0060 0.0071 -0.3 0.0 090 0.0065 0.0074 -0.3 -0.3 091 0.0063 0.0074 0.4 0.1 092 0.0066 0.0078 0.7 0.3 095 0.0067 0.008 0.7 0.9 097 0.0071 0.0080 0.7 0.8 099 0.007 0.008 0.2 0.0 100 0.0065 0.0077 -0.6 -0.8 102 0.0060 0.0072 2.9 2.6 104 0.0082 0.0094

Robust Mean

Robust Std. Dev

0.0065

0.0006

0.0076

0.0006

Result Dev

Method

Lab

Code

ICP

Result Dev

4Q13L1 4Q13L2

022 0.0056 0.0067 070 0.008 0.009 088 0.005 0.006

Robust Mean

Robust Std. Dev

0.0062

0.0018

0.0072

0.0018

Result Dev

Method

Lab

Code

Other

Result Dev

4Q13L1 4Q13L2

072 ASTM E415 (OES) on ARL 3460 ** 0.0140 ** 0.0150 079 OES 0.0067 0.0077

Robust Mean

Robust Std. Dev



54



Overall Summary

CS241311 Final Report

Documents

Transcript of CS241311 Final Report