CONTROL OF CHLORINATED ORGANICS · 6/2/2011 · MONITORING REQUIREMENTS Under the MACT (MON, HON,...
Transcript of CONTROL OF CHLORINATED ORGANICS · 6/2/2011 · MONITORING REQUIREMENTS Under the MACT (MON, HON,...
![Page 1: CONTROL OF CHLORINATED ORGANICS · 6/2/2011 · MONITORING REQUIREMENTS Under the MACT (MON, HON, P&R, etc.) –Group 1 and Group 2 Vents Group 1 – 98% reduction Group 2 – maintain](https://reader031.fdocuments.us/reader031/viewer/2022011918/6005c449e8b4722c080d4c24/html5/thumbnails/1.jpg)
CONTROL OF CHLORINATED ORGANICS
Doris B. Grego
![Page 2: CONTROL OF CHLORINATED ORGANICS · 6/2/2011 · MONITORING REQUIREMENTS Under the MACT (MON, HON, P&R, etc.) –Group 1 and Group 2 Vents Group 1 – 98% reduction Group 2 – maintain](https://reader031.fdocuments.us/reader031/viewer/2022011918/6005c449e8b4722c080d4c24/html5/thumbnails/2.jpg)
OVERVIEW
Chlorinated Organics
Control Devices
MACT Monitoring and Measurement Requirements
Alternatives for MACT Requirements
Recordkeeping
![Page 3: CONTROL OF CHLORINATED ORGANICS · 6/2/2011 · MONITORING REQUIREMENTS Under the MACT (MON, HON, P&R, etc.) –Group 1 and Group 2 Vents Group 1 – 98% reduction Group 2 – maintain](https://reader031.fdocuments.us/reader031/viewer/2022011918/6005c449e8b4722c080d4c24/html5/thumbnails/3.jpg)
Chloroprene Unit
(HON)
Neoprene Unit
(P&R I)
HCl Recovery Unit
(BIF)
Chlorine
Wastes
Wastes
HCl for neutralization
Butadiene
Chloroprene Neoprene
DuPont Performance Elastomers
Pontchartrain Site
Wastes
WWT
Mississippi
River
Wells
Sanitary
![Page 4: CONTROL OF CHLORINATED ORGANICS · 6/2/2011 · MONITORING REQUIREMENTS Under the MACT (MON, HON, P&R, etc.) –Group 1 and Group 2 Vents Group 1 – 98% reduction Group 2 – maintain](https://reader031.fdocuments.us/reader031/viewer/2022011918/6005c449e8b4722c080d4c24/html5/thumbnails/4.jpg)
![Page 5: CONTROL OF CHLORINATED ORGANICS · 6/2/2011 · MONITORING REQUIREMENTS Under the MACT (MON, HON, P&R, etc.) –Group 1 and Group 2 Vents Group 1 – 98% reduction Group 2 – maintain](https://reader031.fdocuments.us/reader031/viewer/2022011918/6005c449e8b4722c080d4c24/html5/thumbnails/5.jpg)
![Page 6: CONTROL OF CHLORINATED ORGANICS · 6/2/2011 · MONITORING REQUIREMENTS Under the MACT (MON, HON, P&R, etc.) –Group 1 and Group 2 Vents Group 1 – 98% reduction Group 2 – maintain](https://reader031.fdocuments.us/reader031/viewer/2022011918/6005c449e8b4722c080d4c24/html5/thumbnails/6.jpg)
![Page 7: CONTROL OF CHLORINATED ORGANICS · 6/2/2011 · MONITORING REQUIREMENTS Under the MACT (MON, HON, P&R, etc.) –Group 1 and Group 2 Vents Group 1 – 98% reduction Group 2 – maintain](https://reader031.fdocuments.us/reader031/viewer/2022011918/6005c449e8b4722c080d4c24/html5/thumbnails/7.jpg)
WHAT IS A CHLORINATED ORGANIC?
Compounds that contain
– Carbon, Hydrogen and Chlorine Atoms
Examples
– Dioxins
– PCBs
– Carbon Tetrachloride
– Vinyl Chloride
– Chloroprene
![Page 8: CONTROL OF CHLORINATED ORGANICS · 6/2/2011 · MONITORING REQUIREMENTS Under the MACT (MON, HON, P&R, etc.) –Group 1 and Group 2 Vents Group 1 – 98% reduction Group 2 – maintain](https://reader031.fdocuments.us/reader031/viewer/2022011918/6005c449e8b4722c080d4c24/html5/thumbnails/8.jpg)
![Page 9: CONTROL OF CHLORINATED ORGANICS · 6/2/2011 · MONITORING REQUIREMENTS Under the MACT (MON, HON, P&R, etc.) –Group 1 and Group 2 Vents Group 1 – 98% reduction Group 2 – maintain](https://reader031.fdocuments.us/reader031/viewer/2022011918/6005c449e8b4722c080d4c24/html5/thumbnails/9.jpg)
![Page 10: CONTROL OF CHLORINATED ORGANICS · 6/2/2011 · MONITORING REQUIREMENTS Under the MACT (MON, HON, P&R, etc.) –Group 1 and Group 2 Vents Group 1 – 98% reduction Group 2 – maintain](https://reader031.fdocuments.us/reader031/viewer/2022011918/6005c449e8b4722c080d4c24/html5/thumbnails/10.jpg)
MACT EMISSIONS CONTROL
Flare
– Halogenated vent streams can’t be flared
– Corrosion, acid formation
Incinerator/Boilers
– Need a scrubber
Condenser
– Cooling Media
– Recovery Device
– Save Money
![Page 11: CONTROL OF CHLORINATED ORGANICS · 6/2/2011 · MONITORING REQUIREMENTS Under the MACT (MON, HON, P&R, etc.) –Group 1 and Group 2 Vents Group 1 – 98% reduction Group 2 – maintain](https://reader031.fdocuments.us/reader031/viewer/2022011918/6005c449e8b4722c080d4c24/html5/thumbnails/11.jpg)
TUBE HEAT EXCHANGER
![Page 12: CONTROL OF CHLORINATED ORGANICS · 6/2/2011 · MONITORING REQUIREMENTS Under the MACT (MON, HON, P&R, etc.) –Group 1 and Group 2 Vents Group 1 – 98% reduction Group 2 – maintain](https://reader031.fdocuments.us/reader031/viewer/2022011918/6005c449e8b4722c080d4c24/html5/thumbnails/12.jpg)
![Page 13: CONTROL OF CHLORINATED ORGANICS · 6/2/2011 · MONITORING REQUIREMENTS Under the MACT (MON, HON, P&R, etc.) –Group 1 and Group 2 Vents Group 1 – 98% reduction Group 2 – maintain](https://reader031.fdocuments.us/reader031/viewer/2022011918/6005c449e8b4722c080d4c24/html5/thumbnails/13.jpg)
![Page 14: CONTROL OF CHLORINATED ORGANICS · 6/2/2011 · MONITORING REQUIREMENTS Under the MACT (MON, HON, P&R, etc.) –Group 1 and Group 2 Vents Group 1 – 98% reduction Group 2 – maintain](https://reader031.fdocuments.us/reader031/viewer/2022011918/6005c449e8b4722c080d4c24/html5/thumbnails/14.jpg)
![Page 15: CONTROL OF CHLORINATED ORGANICS · 6/2/2011 · MONITORING REQUIREMENTS Under the MACT (MON, HON, P&R, etc.) –Group 1 and Group 2 Vents Group 1 – 98% reduction Group 2 – maintain](https://reader031.fdocuments.us/reader031/viewer/2022011918/6005c449e8b4722c080d4c24/html5/thumbnails/15.jpg)
![Page 16: CONTROL OF CHLORINATED ORGANICS · 6/2/2011 · MONITORING REQUIREMENTS Under the MACT (MON, HON, P&R, etc.) –Group 1 and Group 2 Vents Group 1 – 98% reduction Group 2 – maintain](https://reader031.fdocuments.us/reader031/viewer/2022011918/6005c449e8b4722c080d4c24/html5/thumbnails/16.jpg)
MONITORING REQUIREMENTS
Under the MACT (MON, HON, P&R, etc.)
– Group 1 and Group 2 Vents
Group 1 – 98% reduction
Group 2 – maintain TRE 1 to 4
– Use recovery device
– Continuous monitoring of specific parameters
![Page 17: CONTROL OF CHLORINATED ORGANICS · 6/2/2011 · MONITORING REQUIREMENTS Under the MACT (MON, HON, P&R, etc.) –Group 1 and Group 2 Vents Group 1 – 98% reduction Group 2 – maintain](https://reader031.fdocuments.us/reader031/viewer/2022011918/6005c449e8b4722c080d4c24/html5/thumbnails/17.jpg)
![Page 18: CONTROL OF CHLORINATED ORGANICS · 6/2/2011 · MONITORING REQUIREMENTS Under the MACT (MON, HON, P&R, etc.) –Group 1 and Group 2 Vents Group 1 – 98% reduction Group 2 – maintain](https://reader031.fdocuments.us/reader031/viewer/2022011918/6005c449e8b4722c080d4c24/html5/thumbnails/18.jpg)
![Page 19: CONTROL OF CHLORINATED ORGANICS · 6/2/2011 · MONITORING REQUIREMENTS Under the MACT (MON, HON, P&R, etc.) –Group 1 and Group 2 Vents Group 1 – 98% reduction Group 2 – maintain](https://reader031.fdocuments.us/reader031/viewer/2022011918/6005c449e8b4722c080d4c24/html5/thumbnails/19.jpg)
TRACKED PARAMETERS
Inlet temperature of brine
Valve position on the brine lines (open/closed)
Discharge pressure of brine pump
Check on visible emissions
![Page 20: CONTROL OF CHLORINATED ORGANICS · 6/2/2011 · MONITORING REQUIREMENTS Under the MACT (MON, HON, P&R, etc.) –Group 1 and Group 2 Vents Group 1 – 98% reduction Group 2 – maintain](https://reader031.fdocuments.us/reader031/viewer/2022011918/6005c449e8b4722c080d4c24/html5/thumbnails/20.jpg)
![Page 21: CONTROL OF CHLORINATED ORGANICS · 6/2/2011 · MONITORING REQUIREMENTS Under the MACT (MON, HON, P&R, etc.) –Group 1 and Group 2 Vents Group 1 – 98% reduction Group 2 – maintain](https://reader031.fdocuments.us/reader031/viewer/2022011918/6005c449e8b4722c080d4c24/html5/thumbnails/21.jpg)
![Page 22: CONTROL OF CHLORINATED ORGANICS · 6/2/2011 · MONITORING REQUIREMENTS Under the MACT (MON, HON, P&R, etc.) –Group 1 and Group 2 Vents Group 1 – 98% reduction Group 2 – maintain](https://reader031.fdocuments.us/reader031/viewer/2022011918/6005c449e8b4722c080d4c24/html5/thumbnails/22.jpg)
![Page 23: CONTROL OF CHLORINATED ORGANICS · 6/2/2011 · MONITORING REQUIREMENTS Under the MACT (MON, HON, P&R, etc.) –Group 1 and Group 2 Vents Group 1 – 98% reduction Group 2 – maintain](https://reader031.fdocuments.us/reader031/viewer/2022011918/6005c449e8b4722c080d4c24/html5/thumbnails/23.jpg)
![Page 24: CONTROL OF CHLORINATED ORGANICS · 6/2/2011 · MONITORING REQUIREMENTS Under the MACT (MON, HON, P&R, etc.) –Group 1 and Group 2 Vents Group 1 – 98% reduction Group 2 – maintain](https://reader031.fdocuments.us/reader031/viewer/2022011918/6005c449e8b4722c080d4c24/html5/thumbnails/24.jpg)
SUMMARY
Condensers
Monitoring Alternatives
Electronic Records
![Page 25: CONTROL OF CHLORINATED ORGANICS · 6/2/2011 · MONITORING REQUIREMENTS Under the MACT (MON, HON, P&R, etc.) –Group 1 and Group 2 Vents Group 1 – 98% reduction Group 2 – maintain](https://reader031.fdocuments.us/reader031/viewer/2022011918/6005c449e8b4722c080d4c24/html5/thumbnails/25.jpg)
QUESTIONS?