CO2 capture, transport and geological storage programmes

CO2 capture, transport and

geological storage programmes

KS CCS Network

8th May, 2014

CIUDEN es.CO2 Centre for technological development

KS CCS Network 8th May, 2014

es.CO2 - Schematic diagram

15-30 MWthCFB

BOILER

FUEL

PREPARATION

SYSTEM

SCR

GAS

CLEANING

SYSTEM

Compression

and Separation

Unit

MIX AND

PREHEATING

SYSTEM

20 MWthPC

BOILER

Air

FGR1

O2 Storage

and

Vaporisation

FGR2

FGDBag Filter

STACK

CO2

ExpanderBiomass

Cyclon

TorchGASIFIER

PC

SILO

MIXERS

Gas Clean up

Preheating

train

CO2 TRANSPORT

TEST RIG

CO2

Final Review Meeting Brussels 13/02/2014


FUEL PREPARATION

BIOMASS

GASIFIER

PC BOILER

20 MWth

CFB BOILER

30 MWth

TECHNICAL BUILDINGS

AND CONTROL ROOM

FLUEGAS

CLEANING

FLUE GAS

RECIRCULATION AND

MIXING

CO2

COMPRESSION &

PURIFICATION

UNIT

CO2 EXPERIMENTAL

TRANSPORT RIG

INDUSTRIAL SITE

65.000 m2

BUILDINGS

• Technical: 3.500 m2

• Industrial: 1.300 m2

es.CO2 – Aerial view

Final Review Meeting Brussels 13/02/2014


July 2011 First gas fire CFB boiler

November 2011 1st phase completed: CO2 capture in oxycombustion

October 2012 Completed CO2 capture in oxycombustion

June 2011 Works completed for: •Balance of the plant •Auxiliary power •Cyclone and bag filter •Ash evacuation system

August 2011 First coal fire CFB boiler

September 2011 First oxycombustion CFB boiler

September 2012 CPU ready for testing

4

Milestones


MORE THAN 2,600 OPERATING HOURS IN

OXYCOMBUSTION!

MORE THAN 3,700 OPERATING

HOURS IN TOTAL!

2011 2012 2013

Lessons learned

Oxycombustion in CFB demonstrated at this scale

Integration of oxycombustion and CO2 capture demonstrated

Complete automation of air to oxy mode and vv. transitions achieved

Adequate operational conditions identified

Dramatic reduction of specific emissions

Important design data for scale-up collected


Technology maturity at low cost

Less risks Public perception

FGD Development: a good case study for CCS technologies at utility scale?

Ref: Rubin, et al. GHGT-8 proceedings, 2006

Lessons learned


• European Energy Programme for Recovery EEPR

• Allocation of

CCS and RES emissions allowances NER-300

• CCS European Industrial Initiative CCS EII

• Horizon 2020 Relevant funding mechanism (EC)

CCS support initiatives

Fundación Ciudad de la Energía

CO2 Geological Storage Programme

J. Carlos de Dios

Director of CO2 Geological Storage Programme

KS Event CCS Network May 8th, 2014

9

WP3 CO2 Storage

Identification, characterization and operation of a Technology Development Plant for CO2 Geological Storage

Activities committed in the project include:

• Site Selection

• Site Characterization

• Design and construction of the TDP

• Modelling of CO2 injection strategies and their behaviour

• CO2 Monitoring Strategies

• Long term Risk Assessment

• Cost reduction actions identification

TDP in operation : December 2013 Final Conclusions Study : October 2014


Transfer of liabilities

Site Selection & Characterization

Injection in the storage rock

Storage Engineering Injection Monitoring

Monitoring

Commercial CO2 Storage

Pre-operational Operational Post-

operational Transfer to the state

CIUDEN´S OBJECTIVES RELATED TO GEOLOGICAL STORAGE OF CO2

To demonstrate its feasibility and security.

To develop methodologies and technologies.

To facilitate technical criteria for the Regulating

Authority.

To promote education.

Real-scale Technological

Development Plant is required

11

CIUDEN´S TECHNOLOGICAL DEVELOPMENT PLANT FOR CO2 GEOLOGICAL STORAGE

Site selection, since 2008

The process involved

the study of data at

national level. The

screening works led to the

election of Hontomin,

based on its structure,

properties, availability of

previous data, being also

compared with other

options in the same basin

on a risk assessment basis.

12

Baseline, characterization & monitoring at Hontomín TDP


Micro-seismic network of 30 stations

446400 446500 446600 446700 446800 446900 447000 447100

47

14

50

04

71

46

00

47

14

70

04

71

48

00

47

14

90

0

Este

No

rte

2

4

4

4

4

4

6

6

6

6

6

8 8

8

8

8

8 8

8

10

10

10

10

10

10

10

10

12 12

12

12

12

12

12

12

12

14

14 14

14

14

14

14

16

16

Gas Flow

Displacement measurement from satellite

High resolution 3D Seismics

13

Baseline, characterization & monitoring at Hontomín TDP

This installation is

highly instrumented with

a wide range of

monitoring technologies,

which will allow to track

the changes once in

operation.

These data is also

essential to validate risk

assessment activities,

increasing knowledge in

safe CO2 storage.


14

Knowledge of the groundwater state before the CO2 injection. Hydrogeological characterization of the aquifer and seal formations.

Identification of geological structures which allow the CO2 to migrate upwards.

Hydrogeological and hydrochemical monitoring of the CO2 migration.

HYDROGEOLOGICAL CHARACTERIZATION


TECHNOLOGICAL DEVELOPMENT PLANT OF HONTOMÍN

H-A Well

H-I Well

Gas Plant

Water Plant

Pools

16

PROCESS DIAGRAM OF THE TDP OF HONTOMÍN

17

WELL DRILLING

0

50

100

150

200

250

300

350

400

450

500

550

600

650

700

750

800

850

900

950

1000

1050

1100

1150

1200

1250

1300

1350

1400

1450

1500

1550

1600

1650

0 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 105 110 115 120 125 130 135 140

H-A: Curva Profundidad vs. Tiempo

Días

Pro

fun

did

ad

(m

)

PrognosisActual

216,60 m Casing 13 3/8"

20 m Casing 20"

593,92 m Casing 9 5/8"

Perforación 12 1/4" a Rotación C.I.

Perforación 8 1/2" a Rotación C.D.

Registro CBL/VDL Casing 9 5/8"

1281 - 489,6 m 7" LinerTestigo-1: 1313 - 1320 m

Testigo-2: 1320 - 1323,8 m

Testigo-3: 1343 - 1350 m

Testigo-10: 1515 - 1522 m

Testigo-11: 1522 - 1528,8 mTestigo-12: 1528,8 - 1531 m

16/08/2013

Perforación 6" a Rotación C.D.

Perforación 17 1/2" a Percusión

Perforación 17 1/2" a Rotación C. I.

Testigo-4: 1401 - 1405 mTestigo-5: 1405 - 1412 m

Testigo-6: 1442 - 1449 m

Testigo-7: 1449 - 1450,26 mTestigo-8: 1457 - 1463 m (Rec.0%)

Testigo-9: 1464 - 1464,12 m

TD: 1580 m MD

WO logging: 4 díasLogging: 3 díasDesplazar lodo: 1 díaProducción agua: 5 díasTests inyección: 6 díasTP&A and rig down: 3 días

23/03/2013

18

PETROLOGICAL AND PETROPHYSICAL CHARACTERIZATION OF RESERVOIR AND SEAL FORMATIONS

Composition

Mechanical properties

Porosity and pore size distribution

0,000

0,500

1,000

1,500

2,000

2,500

3,000

3,500

4,000

4,500

K

1/Pm

Permeability

19

COMPLETION AND INSTRUMENTATION OF HI & HA WELLS

20

INJECTIVITY AND CONNECTIVITY TESTS

Determination of hydraulic parameters (permeability, injectivity, etc.).

Determination of connectivity between HI and HA wells.

Well Tests Summary - Hontomin H-A

Test Bottom Packer Bottom Packer Total H Total net H P @ depth P/hydr T Formation

mMD mMD m m bar mMD °C

Production #1 296 111,7 1281 0,872163 37,8 All

Injection #1 1530 unset - TD = 1580 50 ? - 1530 - 46,5

Dolomias de sopeña +

anhidritas

Injection #2 1501 1529,8 28,8 8 141,2 1501 0,941 45,8 Dolomias de sopeña

Injection #3 1472 1500,8 28,8 5 138,6 1472 0,942 44,8 calizas inf sopeña

Injection #4 1439,1 1467,9 28,8 15 135,4 1439,1 0,941 43,9 calizas sup sopeña

Injection #5 1414,2 unset - TD = 1580 165,8 28 132,7 1414,2 0,938 43,3 All

Injection #5B 1414,2 unset - TD = 1580 165,8 28 132,5 1414,2 0,937 43,3 All

In red: doubtful values

Test Model Remarks DP WH Rate Dt K.h K S K outside zone

l/hr hr mD.m mD for radial comp model

Production #1

Rate drops down to 1/4

within 24hr 50 ? 200 > 24

Injection #1 unconclusive tests 23 - - - - -

Injection #2 Possible Double F (weak) Inj with N2 at WH 53 17,34 0,52 0,18 0,0225 -1

Injection #3 Possible Double F (weak) Inj with N2 at WH 48 47,8 1,03 1,43 0,286 -0,4

Injection #4 Possible Double F (weak) Inj with N2 at WH 41,6 9,42 1,09 0,95 0,063192 9,8

Injection #5 Radial comp

Inj with Solexpert small

pump 12,5 90 4,00 8,83 0,316 2,11 # 3 mD @ 12m ?

Injection #5B Radial comp Inj with Rig pump 42 600 2,00 24,23042 0,866 1 # 3-5mD @ 20m ?

no packer / whole OH section = 1284 - 1580

1E-4 1E-3 0.01 0.1 1 10

Time [hr]

1

10

100

Pre

ssure

[psi]

119

119.5

Pre

ssure

[bara

]

0 20 40

Time [hr]

-250

-125

Liq

uid

rate

[m

3/D

]

RISK ASSESSMENT

To develop a risk probabilistic assessment model related to deep geological CO2 Storage in saline carbonate aquifers, proved with results from experimental activities at real scale in Hontomin TDP

Resultado Riesgo de fuga en el primario

Resultado Riesgo de fuga en el secundario

Resultado Riesgo de fuga

Resultado Capacidad de dispersión edáfica

Análisis de Sensibilidad

Falla del primario

Tectónica

Alcance de la pluma de CO2 en el primario

Formación sello del primario

Escape estructural en el primario

Pozo del primario

Función matemática

Falla del secundario

Formación sello del secundario

Alcance de la pluma de CO2 en el secundario

Escape estructural en el secundario

Pozo del secundario


Capacidad de dispersión edáfica


( ) ( )

( )( )

i i

i

P B A P AP A B

P B

( ) ( )

( )( )

i i

i

P B A P AP A B

P B ( ) ( )

( )( )

i i

i

P B A P AP A B

P B

22

The works developed in this project have allowed to create a trustworthy relationship with key stakeholders as with the local community.

PUBLIC ENGAGEMENT

23

Drilling phase finished, operative last quarter 2013

This installation will be devoted to real scale experiments in deep porous rock formations to test and develop new technologies in storage engineering, CO2 injection strategies and safe operation.

• Current site capacity threshold by Law: 100,000 t. • On-shore deep saline aquifer storage. (administrative requirement Spanish Law 40/2010 CO2 Geological Storage) • Cost reduction Action with the use of Light Drilling Equipment (up to 60%). • Safe operation including well integrity and leakage prediction techniques. • CO2 injection strategies: liquid, supercritical and gas.

CURRENT STATUS OF THE TDP OF HONTOMÍN


HONTOMÍN TDP


Thanks for the attention

J. Carlos de Dios CO2 Geological Storage Programme

Tel.+34 987 456 323 Mobile +34-639 110 760

[email protected] Technological Development Plant for CO2 Storage

www.ciuden.es

mailto:[email protected]

www.ciuden.es

CO2 capture, transport and geological storage programmes

Environment

Transcript of CO2 capture, transport and geological storage programmes