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    CHAPTER 6: ELECTROLYSIS :STRUCTURE A

    1 Diagram 5 shows the apparatus setup use! "# a pupi$ to e$etrop$ate a% iro%

    spoo% with &opper'

    (a) *hat is mea%t "# a% e$e&tro$#te+

    ,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,'

    ,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,'

    -. marks/

    (") *h# a% e$e&tro$#te is a"$e to &o%!u&t e$e&tri&it#+'

    ,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,

    -0 mark/

    (&) 1ame e$e&tro$#te 2'

    ,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,

    -0 mark/

    (d)*hat is the o"ser3atio% at the a%o!e a%! the &atho!e !uri%g thee4perime%t'

    (i) A%o!e : ',,,,,,,,,,,,,,,'',,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,''

    (ii) Catho!e : ',,,,,,,,,,,,,,'',,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,

    -. marks/

    (iii) *rite the ha$ euatio% or the rea&tio% ta7i%g p$a&e at the a%o!e'

    ,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,''

    E$e&tro$#te 2Iron spoon

    Zinc electrode

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    Copper(II) su$phate so$utio%

    &opper8eta$ P

    -0 mark/

    (e) A pupi$ wa%te! to &o%stru&t the e$e&tro&hemi&a$ series'' He measure! the pote%tia$!i9ere%&e o a ew pairs o meta$s' The setup o the apparatus o his e4perime%t isshow% "e$ow

    Ta"$e 5 shows the 3o$tmeter rea!i%gs he o"tai%e! rom the pairs o meta$s'

    ase! o% the ta"$e a"o3e;

    (i) !etermi%e the pote%tia$ !i9ere%&e i the pupi$ uses P a%! R as thee$e&tro!es'

    ,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,

    -0 mark/(ii) arrange the metals in an ascending order according to their relative position in the

    electrochemical series.

    ..

    [1 mark]

    E4perime%tPair o meta$s Pote%tia$

    !i9ere%&e

    < =

    1egati3e

    e$e&tro!e

    Positi3e

    e$e&tro!eIIIIIII=

    P>RS

    CopperCopperCopperCopper

    0'0?.'@.?'@?'B5

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    A

    P QE$e&tro$#te R

    E$e7tro$it R

    TRIAL TERE1A1U .??

    Diagram '. shows the set up o the apparatus use! to e$e&trop$ate a% iro% 7e# withsi$3er meta$'

    Rajah '.menunjukkan susunan radas yang digunakan untuk menyadur satu kunci besi

    dengan logam perak.

    ase! o% Diagram '. :Berdasarkan Rajah'. :

    (i) State the &orre&t positio% o the iro% 7e# either e$e&tro!es P or >'Nyatakan kedudukan yang betul bagi kunci besi samada elektrod Patau>.

    ,,,,,,,,,,,,,,,,,,,,,,,,,''''''''''''''''''''''''''

    -0 mark/

    (ii) 1ame a suita"$e so$utio% that &a% "e use! as e$e&tro$#te R'Namakan satu larutan yang sesuai digunakan sebagai elektrolit R.

    ,,,,,,,,,,,,,,,,,,,,,,,,,''''''''''''''''''''''''''-0 mark/

    (iii) Suggest o%e step that must "e ta7e% to get a "etter e$e&trop$ate! 7e#'Cadangkan satu langkah yang perlu diambil untuk mendapatkansaduran yang baik pada kunci tersebut.

    ,,,,,,,,,,,,,,,,,,,,,,,,,''''''''''''''''''''''''''''''''''''

    '''''''''''''''''''''''''''''''''''''-0 mark

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    Impure &opper p$ate

    epi%ga% 7uprum ta7 tu$e%

    Pure &opper p$ate

    epi%ga% 7uprum tu$e%

    Copper(II) su$phate so$utio%

    Laruta% 7uprum(II) su$at

    A

    E$e&tri&a$ sour&e

    Sum"er te%aga e$e7tri7

    X Y

    (&) Diagram ' shows the setup o apparatus o a puriF&atio% pro&ess'Rajah 'menunjukkan susunan radas bagi suatu proses penulenan.

    (i) I!e%ti# the a%o!e a%! the &atho!e'Kenal pasti anod dan katod'

    2 : ,,,,,,,,,,,,,,,,,,,,,,,,,,,''''''''''''

    Y : ,,,,,,,,,,,,,,,,,,,,,,,,,,,''''''''''''-0 mark/

    (ii) Duri%g this pro&ess; the i%te%sit# o the "$ue &o$our o &opper(II)

    su$phate remai%s u%&ha%ge!' E4p$ai% wh#'Semasa proses ini, didapati keamatan warna biru larutan kuprum(II)sulfat tidak berubah.erangkan mengapa.

    ,,,,,,,,,,,,,,,,,,,,,,,,,''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''

    ,,,,,,,,,,,,,,,,,,,,,,,,,''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''

    ,,,,,,,,,,,,,,,,,,,,,,,,,''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''

    -. marks/

    ' A simp$e &hemi&a$ &e$$ is show% i% Diagram 0

    Diagram 1

    Copper (II) sulphate solution

    Zinc metal Copper metal

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    =

    a) I!e%ti# the %egati3e termi%a$ a%! positi3e termi%a$'

    i) 1egati3e termi%a$ : ''.........................................................................................

    ii) Positi3etermi%a$ : ''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''............

    -. mar7s/

    ") State the o"ser3atio% at the positi3e termi%a$'

    ''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''

    -0 mar7/&) *rite the ha$ euatio%s or the rea&tio% at

    i) 1egati3etermi%a$!...............................................................................................

    ii) Positi3etermi%a$! ..............................................................................................

    "# marks$

    !) *rite the o3era$$ euatio% or the &e$$ a"o3e'

    ' ''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''

    -0 mar7/

    B' Diagram . shows a 3o$tai& &e$$ "etwee% $ea! a%! &opper meta$S i% their respe&ti3ee$e&tro$#tes'

    Diagram 2a) I!e%ti# the positi3e a%! %egati3e termi%a$s o the 3o$tai& &e$$'

    i) Positi3etermi%a$ : ''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''

    ii) 1egati3etermi%a$ : ''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''

    ") *rite the io%i& euatio%s or the rea&tio%s at the positi3e a%! %egati3e termi%a$s'

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    i) Positi3etermi%a$ : ''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''

    ii) 1egati3etermi%a$ : ''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''

    &) *rite the o3era$$ euatio% o the &e$$'

    '''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''

    !) State the u%&tio% o the sa$t "ri!ge'

    '''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''

    e)*hat is the e%erg# &o%3ersio% i% the 3o$tai& &e$$+ '''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''