CARRS OF SHEFFIELD (MANUFACTURING) LIMITED ASSESSMENT OF ... · CARRS OF SHEFFIELD (MANUFACTURING)...
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CARRS OF SHEFFIELD (MANUFACTURING) LIMITED ASSESSMENT OF WORK ACTIVITY Date of Assessment: September 2009 Assessment by: Martin Carr Responsible Manager: Production Manager Work Activity: Cutlery handle assembly General Description of Activity: Soldering the two halves of cutlery handles together Duration: upto 8 Hours per day Numbers Exposed: Upto 2 Hazards; 1. Skin irritation from flux solution Control From: 1. If this is a problem nitrile gloves should be worn COSHH; a. N/A – but see below Assessment of Control The main hazard is from skin irritation. The datasheets indicate that non-abraded skin has no effect after 4 hours. However, nitrile gloves are available to wear. The process consists of coating one half of the handle with the flux solution, placing the two halves together and holding together with cotton. Powder solder is then put inside the handle, which sticks to the flux, excess is re-used. The handles are then send through the furnace to cure the solder. The main COSHH risk from the chemicals is what may be given off when the materials are heated. However, this process does not heat the handles, so there is no risk from that hazard. Hands should be washed after using the process, before the eating of food. Eye contact with the flux of solder is very unlikely
Transcript of CARRS OF SHEFFIELD (MANUFACTURING) LIMITED ASSESSMENT OF ... · CARRS OF SHEFFIELD (MANUFACTURING)...
CARRS OF SHEFFIELD (MANUFACTURING) LIMITED
ASSESSMENT OF WORK ACTIVITY
Date of Assessment: September 2009 Assessment by: Martin Carr
Responsible Manager: Production Manager
Work Activity: Cutlery handle assembly
General Description of Activity: Soldering the two halves of cutlery handles together Duration: upto 8 Hours per day Numbers Exposed: Upto 2 Hazards;
1. Skin irritation from flux solution
Control From:
1. If this is a problem nitrile gloves should be worn
COSHH;
a. N/A – but see below
Assessment of Control The main hazard is from skin irritation. The datasheets indicate that non-abraded skin has no effect after 4 hours. However, nitrile gloves are available to wear. The process consists of coating one half of the handle with the flux solution, placing the two halves together and holding together with cotton. Powder solder is then put inside the handle, which sticks to the flux, excess is re-used. The handles are then send through the furnace to cure the solder. The main COSHH risk from the chemicals is what may be given off when the materials are heated. However, this process does not heat the handles, so there is no risk from that hazard. Hands should be washed after using the process, before the eating of food. Eye contact with the flux of solder is very unlikely
admin
Sticky Note
05/10/2015 Additional TO258 & TO220 datasheets added to assessment. Overall assessment has not changed.
TURRET BRAZING PRODUCTS LIMITED. UNIT 3, MEADOWBROOK PARK, HALFWAY, SHEFFIELD. S20 3PJ.
TEL; 0114 248 8570: FAX; 0114 251 3077. EMAIL; [email protected]
www.turretbrazing.com
DATA SHEET
Trade Name: Metbraze 67 Standard ISO 8513: L-Ag67 Type of Product: Silver Brazing Alloy ___________________________________________________________________________ Composition: 67% Silver 23% Copper 10% Zinc Melting Range: 700 - 730ºc. ___________________________________________________________________________ 1. APPEARANCE Silver/grey metal 2. OCCUPATIONAL HEALTH DATA TLV Odour threshold:- Silver 0.1mg/m³ as fume Copper 0.2mg/m³ as fume Zinc 5.0mg/m³ as zinc
3. DANGERS TO HEALTH General The only potential health hazards involved with this product arise from its use. There are no storage or handling problems. On heating metal and metal oxide, fumes will be evolved. Inhalation Zinc Oxide fumes, if excessive, can be irritating to the upper respiratory tract and can cause metal fume fever. It is unlikely, however, that the TLV will be exceeded except under exceptional circumstances where overheating is a problem. 4. FIRST AID General Ingestion: None Skin: None Eyes: None 5. INFORMATION TO MEDICAL PERSONNEL Metal fume fever can be caused by exposure to excessive fumes of Copper. Symptoms are similar to those of influenza and often appear after a latent period of up to 10 hours. They will normally disappear after 12 hours with rest. 6. PROTECTIVE MEASURES Preventive measures, protective equipment etc. Tests to determine whether or not TLV's are being exceeded can be carried out by sampling the air using lapel samplers on the operators or static samples suitably situated. Normal analytical techniques are used to determine the metals on the filter. If tests show that TLV's are being exceeded, local exhaust ventilation should be installed. Rules defining care as to use 1) Do not overheat 2) If TLV's exceeded local exhaust ventilation should be installed.
Rules defining care as to storage None necessary 7. REACTIVITY & SPECIAL PRECAUTIONS No problems 8. DESTRUCTION & REMOVING OF SPILL No health hazard unless overheated. 9. EMERGENCY PROCEDURE AGAINST LEAKAGE General Not applicable Water contamination Not applicable Contamination of streets, public environments, fields etc. Not applicable 10. PHYSICAL DATA Not applicable 11. INFORMATION REGARDING INFLAMMABILITY Not applicable 12. TRANSPORT AND PACKING General No special precautions Transport and danger class No special arrangements needed
13. LAWS AND OFFICIAL REGULATIONS None 14. USERS OWN INFORMATION As stated above 15. OTHER INFORMATION The information given in this sheet represents the best of our knowledge; it may not be used as a warranty.
DATA SHEET
Product: BN1 Flux Powder Composition: Mixture of complex fluoroborate and borate compounds of potassium. Melting range; 600 - 800 Deg C. ___________________________________________________________________________ PHYSICAL PROPERTIES Odourless powder with off-white appearance. Low solubility in water but forms paste easily; pH of suspension 8. Becomes fluid on heating. Non oxidising. HEALTH HAZARD DATA 1. Harmful by ingestion. Acute oral LD 50> 200mg/kg. 2. Irritating to the eyes. 3. Skin irritation: (a) No reaction to non-abraded skin on 4-hour contact. Immediate irritation will occur on contact with cuts and abrasions. (b) Moderately irritating, primary irritation index 4.13, after 24-hour contact carried out according to Draize skin test.
4. No response by the standard Magnusson andKligman delayed dermal sensitisation test. 5. On heating, the flux will fume slightly. With overheating, the fume will increase. The relevant threshold limit values are hydrogen fluoride 2mg/m³, fluoride (as F) 2.5mg/m³ and boron trifluoride 3mg/m³. In the absence of adequate ventilation, and particularly as the result of bad brazing practice, fume can cause irritation of nasal passages. Chronic over-exposure to fume for many years may result in fluorosis. FIRE & EXPLOSION HAZARD Data Non-flammable - use full protection with breathing apparatus if involved in a fire, as harmful fumes may be evolved. Handling Avoid contact with skin and eyes. Do not inhale dust or fumes evolved during use. In cases of insufficient ventilation, wear suitable respiratory equipment. Smoking is inadvisable. Wash hands and clean fingernails before meals. Keep away from food, drink and animal feeding stuffs and out of the reach of children. Spillage and Disposal: 1. Packing lots: Add slowly to a large container of water. Stir in a slight excess of soda ash, then add slaked lime. Allow to stand for 24 hours. Decant or syphon into another container and neutralise with 1:1 hydrochloric acid before washing down the drain with a large excess of water. The sludge may be added to land fill. 2. (a) Solutions - Cover with soda ash, mix and scoop into container and add slaked lime. Then proceed as in 1. (b) Solids - add to container of hot water proceed as in 1. First Aid 1. Spills: Wash off with soap and water. Seek medical advice. 2. Eyes: Irrigate immediately with water and buffered phosphate for up to 20 minutes. In severe cases patients should be seen at the Hospital Eye Department. 3. Ingestion: Summon medical aid, induce vomiting if conscious, give copious lime water, milk or water drinks. Remove to hospital by ambulance. Intravenous injections of 10% Calcium gluconate repeated hourly remains the routine treatment for systemic poisoning. 4. Inhalation: In acute cases, remove to fresh air, apply artificial respiration and oxygen if necessary summon medical aid. Continue observation for 48 hours because of danger pulmonary oedema. (Note - poisoning by inhalation may also result from brazing metal fume or torch gases.)
1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE
1.1 Product identifiers
Product name : TO258
Product Number : TO258
Brand : TO258
ISO 3677: B-Ag58CuZn-695/740
1.2 Relevant identified uses of the substance or mixture and uses advised against
Identified uses : Brazing, Braze-welding, Laboratory chemicals and Manufacture of substances
1.3 Details of the supplier of the safety data sheet
Company : LINBRAZE S.r.l. (Ltd)Contrada Torre Chimera snc93019 Sommatino (ITALY)
Telephone : +39 0922 871694
Fax: +39 0922 709064
E-mail address : [email protected]
1.4 Emergency telephone number
Emergency Phone : +39 02 6610 1029 (Centro Antiveleni Niguarda Milano)
2. HAZARDS IDENTIFICATION
2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008 [EU-GHS/CLP]None
Classification according to EU Directives 67/548/EEC or 1999/45/ECNone
2.2 Label elements
Labelling according Regulation (EC) No 1272/2008 [CLP]
Pictogram:
Signal word:
Hazard statement(s)
Precautionary statement(s)
P273 Avoid release to the environment.
P501 Dispose of contents/ container to an approved waste disposal plant.
Supplemental Hazard Statements None
According to European Directive 67/548/EEC as amended.
Hazard symbol(s)
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R-phrase(s)
S-phrase(s)
none
2.3 Other hazards
none
3. COMPOSITION/INFORMATION ON INGREDIENTS
3.1 Substances
Formula : Copper 26,0 – 28,0% CAS-No. 7440-50-8 EC-No. 231-159-6
Silver 57,0 – 59,0% CAS-No. 7440-22-4 EC-No. 231-131-3
Zinc 12,0 – 16,0% CAS-No. 7440-66-6 EC-No. 231-150-8
Synonyms :
4. FIRST AID MEASURES
4.1 Description of first aid measures
General advice
Consult a physician. Show this safety data sheet to the doctor in attendance.
If inhaled
If breathed in, move person into fresh air.
In case of skin contact
Wash off with soap and plenty of water.
In case of eye contact
Flush eyes with water as a precaution.
If swallowed
Never give anything by mouth to an unconscious person. Rinse mouth with water.
4.2 Most important symptoms and effects, both acute and delayed
Nausea, Weakness, Symptoms of systemic copper poisoning may include: capillary damage, headache, cold sweat, weak pulse, and kidney and liver damage, centralnervous system excitation followed by depression, jaundice, convulsions, paralysis, and coma. Death may occur from shock or renal failure. Chronic copper poisoningis typified by hepatic cirrhosis, brain damage and demyelination, kidney defects, and copper deposition in the cornea as exemplified by humans with Wilson'sdisease. It has also been reported that copper poisoning has lead to hemolytic anemia and accelerates arteriosclerosis.
4.3 Indication of any immediate medical attention and special treatment needed
no data available
5. FIRE-FIGHTING MEASURES
5.1 Extinguishing media
Suitable extinguishing media
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
5.2 Special hazards arising from the substance or mixture
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Copper/Zinc oxides
5.3 Advice for firefighters
Wear self contained breathing apparatus for fire fighting if necessary.
5.4 Further information
no data available
6. ACCIDENTAL RELEASE MEASURES
6.1 Personal precautions, protective equipment and emergency procedures
Avoid dust formation. Avoid breathing vapors, mist or gas.
6.2 Environmental precautions
Do not let product enter drains.
6.3 Methods and materials for containment and cleaning up
Sweep up and shovel. Keep in suitable, closed containers for disposal.
6.4 Reference to other sections
For disposal see section 13.
7. HANDLING AND STORAGE
7.1 Precautions for safe handling
Provide appropriate exhaust ventilation at places where dust is formed.Normal measures for preventive fire protection.
7.2 Conditions for safe storage, including any incompatibilities
Store in cool place. Keep container tightly closed in a dry and well-ventilated place.
7.3 Specific end uses
no data available
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Components with workplace control parameters
8.2 Exposure controls
Appropriate engineering controls
General industrial hygiene practice
Personal protective equipment
Eye/face protection Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).
Skin protection Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it.
Body Protection Choose body protection in relation to its type, to the concentration and amount of dangerous substances,and to the specific work-place., The type of protective equipment must be selected according to the
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concentration and amount of the dangerous substance at the specific workplace.
Respiratory protection Respiratory protection is not required. Where protection from nuisance levels of dusts are desired, use type N95 (US) or type P1 (EN 143) dust masks. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical properties
a) Appearance Form: Powder, Colour yellowish
b) Odour: no data available
c) Odour Threshold: no data available
d) pH: no data available
e) Melting point/freezing point: 695 / 740 °C (melting point)
f) Initial boiling point and boiling range: no data available
g) Flash point: no data available
h) Evaporation rate: no data available
i) Flammability (solid, gas): no data available
j) Upper/lower flammability or explosive limits no data available
k) Vapour pressure: no data available
l) Vapour density: no data available
m) Relative density: no data available
n) Water solubility: no data available
o) Partition coefficient: noctanol/water no data available
p) Autoignition temperature: no data available
q) Decomposition temperature: no data available
r) Viscosity: no data available
s) Explosive properties: no data available
t) Oxidizing properties: no data available
9.2 Other safety information
no data available
10. STABILITY AND REACTIVITY
10.1 Reactivity
no data available
10.2 Chemical stability
no data available
10.3 Possibility of hazardous reactions
no data available
10.4 Conditions to avoid
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no data available
10.5 Incompatible materials
Strong bases, Strong oxidizing agents, Strong acids, Acid chlorides, Sulphur compounds, Halogens
10.6 Hazardous decomposition products
Other decomposition products - no data available
11. TOXICOLOGICAL INFORMATION
11.1 Information on toxicological effects
Acute toxicity
no data available
Skin corrosion/irritation
no data available
Serious eye damage/eye irritation
no data available
Respiratory or skin sensitization
no data available
Germ cell mutagenicity
no data available
Carcinogenicity
IARC: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC.
Reproductive toxicity
no data available
Specific target organ toxicity - single exposure
no data available
Specific target organ toxicity - repeated exposure
no data available
Aspiration hazard
no data available
Potential health effects
Inhalation: May be harmful if inhaled. May cause respiratory tract irritation.
Ingestion: May be harmful if swallowed.
Skin: May be harmful if absorbed through skin. May cause skin irritation.
Eyes: May cause eye irritation.
Signs and Symptoms of Exposure
sneezing, Nausea, Weakness, Symptoms of systemic copper poisoning may include: capillary damage, headache, cold sweat, weak pulse, and kidney and liverdamage, central nervous system excitation followed by depression, jaundice, convulsions, paralysis, and coma. Death may occur from shock or renal failure. Chroniccopper poisoning is typified by hepatic cirrhosis, brain damage and demyelination, kidney defects, and copper deposition in the cornea as exemplified by humanswith Wilson's disease. It has also been reported that copper poisoning has lead to hemolytic anemia and accelerates arteriosclerosis.
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Additional Information
RTECS: Not available
12. ECOLOGICAL INFORMATION
12.1 Toxicity
Toxicity to fish no data available
Toxicity to daphnia and other aquatic invertebrates. no data available
no data available
12.2 Persistence and degradability
no data available
12.3 Bioaccumulative potential
Bioaccumulation no data available
12.4 Mobility in soil
no data available
12.5 Results of PBT and vPvB assessment
no data available
12.6 Other adverse effects
no data available
13. DISPOSAL CONSIDERATIONS
13.1 Waste treatment methods
Product
Offer surplus and non-recyclable solutions to a licensed disposal company.
Contaminated packaging
Dispose of as unused product.
14. TRANSPORT INFORMATION
14.1 UN number
ADR/RID: - IMDG: - IATA: -
14.2 UN proper shipping name
ADR/RID: none
IMDG: none
IATA: none
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14.3 Transport hazard class(es)
ADR/RID: - IMDG: - IATA: -
14.4 Packaging group
ADR/RID: - IMDG: - IATA: -
14.5 Environmental hazards
ADR/RID: - IMDG Marine pollutant: - IATA: -
14.6 Special precautions for user
none
15. REGULATORY INFORMATION
This safety datasheet complies with the requirements of Regulation (EC) No. 1272/2008
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
no data available
15.2 Chemical Safety Assessment
no data available
16. OTHER INFORMATION
Further informationCopyright LINBRAZE S.r.l. (Ltd) License granted to make unlimited paper copies for internal use only. The above information is believed to be correct but does notpurport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to theproduct with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. LINBRAZE S.r.l. (Ltd), shall not be heldliable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions ofsale.
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1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE
1.1 Product identifiers
Product name : TO220
Product Number : TO220
Brand : TO220
ISO 17672 Ag 220
1.2 Relevant identified uses of the substance or mixture and uses advised against
Identified uses : Brazing, Braze-welding, Laboratory chemicals and Manufacture of substances
1.3 Details of the supplier of the safety data sheet
Company : LINBRAZE S.r.l. (Ltd)Contrada Torre Chimera snc93019 Sommatino (ITALY)
Telephone : +39 0922 871694
Fax: +39 0922 709064
E-mail address : [email protected]
1.4 Emergency telephone number
Emergency Phone : +39 02 6610 1029 (Centro Antiveleni Niguarda Milano)
2. HAZARDS IDENTIFICATION
2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008 [EU-GHS/CLP]None
Classification according to EU Directives 67/548/EEC or 1999/45/ECNone
2.2 Label elements
Labelling according Regulation (EC) No 1272/2008 [CLP]
Pictogram:
Signal word:
Hazard statement(s)
Precautionary statement(s)
P273 Avoid release to the environment.
P501 Dispose of contents/ container to an approved waste disposal plant.
Supplemental Hazard Statements None
According to European Directive 67/548/EEC as amended.
Hazard symbol(s)
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R-phrase(s)
S-phrase(s)
none
2.3 Other hazards
none
3. COMPOSITION/INFORMATION ON INGREDIENTS
3.1 Substances
Formula : Copper 43,0 – 45,0% CAS-No. 7440-50-8 EC-No. 231-159-6
Silver 19,0 – 21,0% CAS-No. 7440-22-4 EC-No. 231-131-3
Zinc 34,0 – 38,0% CAS-No. 7440-66-6 EC-No. 231-150-8
Synonyms :
4. FIRST AID MEASURES
4.1 Description of first aid measures
General advice
Consult a physician. Show this safety data sheet to the doctor in attendance.
If inhaled
If breathed in, move person into fresh air.
In case of skin contact
Wash off with soap and plenty of water.
In case of eye contact
Flush eyes with water as a precaution.
If swallowed
Never give anything by mouth to an unconscious person. Rinse mouth with water.
4.2 Most important symptoms and effects, both acute and delayed
Nausea, Weakness, Symptoms of systemic copper poisoning may include: capillary damage, headache, cold sweat, weak pulse, and kidney and liver damage, centralnervous system excitation followed by depression, jaundice, convulsions, paralysis, and coma. Death may occur from shock or renal failure. Chronic copper poisoningis typified by hepatic cirrhosis, brain damage and demyelination, kidney defects, and copper deposition in the cornea as exemplified by humans with Wilson'sdisease. It has also been reported that copper poisoning has lead to hemolytic anemia and accelerates arteriosclerosis.
4.3 Indication of any immediate medical attention and special treatment needed
no data available
5. FIRE-FIGHTING MEASURES
5.1 Extinguishing media
Suitable extinguishing media
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
5.2 Special hazards arising from the substance or mixture
Page 2/7
Copper/Zinc oxides
5.3 Advice for firefighters
Wear self contained breathing apparatus for fire fighting if necessary.
5.4 Further information
no data available
6. ACCIDENTAL RELEASE MEASURES
6.1 Personal precautions, protective equipment and emergency procedures
Avoid dust formation. Avoid breathing vapors, mist or gas.
6.2 Environmental precautions
Do not let product enter drains.
6.3 Methods and materials for containment and cleaning up
Sweep up and shovel. Keep in suitable, closed containers for disposal.
6.4 Reference to other sections
For disposal see section 13.
7. HANDLING AND STORAGE
7.1 Precautions for safe handling
Provide appropriate exhaust ventilation at places where dust is formed.Normal measures for preventive fire protection.
7.2 Conditions for safe storage, including any incompatibilities
Store in cool place. Keep container tightly closed in a dry and well-ventilated place.
7.3 Specific end uses
no data available
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Components with workplace control parameters
8.2 Exposure controls
Appropriate engineering controls
General industrial hygiene practice
Personal protective equipment
Eye/face protection Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).
Skin protection Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it.
Body Protection Choose body protection in relation to its type, to the concentration and amount of dangerous substances,and to the specific work-place., The type of protective equipment must be selected according to the
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concentration and amount of the dangerous substance at the specific workplace.
Respiratory protection Respiratory protection is not required. Where protection from nuisance levels of dusts are desired, use type N95 (US) or type P1 (EN 143) dust masks. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical properties
a) Appearance Form: Powder, Colour yellowish
b) Odour: no data available
c) Odour Threshold: no data available
d) pH: no data available
e) Melting point/freezing point: 690 / 810 °C (melting point)
f) Initial boiling point and boiling range: no data available
g) Flash point: no data available
h) Evaporation rate: no data available
i) Flammability (solid, gas): no data available
j) Upper/lower flammability or explosive limits no data available
k) Vapour pressure: no data available
l) Vapour density: no data available
m) Relative density: no data available
n) Water solubility: no data available
o) Partition coefficient: noctanol/water no data available
p) Autoignition temperature: no data available
q) Decomposition temperature: no data available
r) Viscosity: no data available
s) Explosive properties: no data available
t) Oxidizing properties: no data available
9.2 Other safety information
no data available
10. STABILITY AND REACTIVITY
10.1 Reactivity
no data available
10.2 Chemical stability
no data available
10.3 Possibility of hazardous reactions
no data available
10.4 Conditions to avoid
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no data available
10.5 Incompatible materials
Strong bases, Strong oxidizing agents, Strong acids, Acid chlorides, Sulphur compounds, Halogens
10.6 Hazardous decomposition products
Other decomposition products - no data available
11. TOXICOLOGICAL INFORMATION
11.1 Information on toxicological effects
Acute toxicity
no data available
Skin corrosion/irritation
no data available
Serious eye damage/eye irritation
no data available
Respiratory or skin sensitization
no data available
Germ cell mutagenicity
no data available
Carcinogenicity
IARC: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC.
Reproductive toxicity
no data available
Specific target organ toxicity - single exposure
no data available
Specific target organ toxicity - repeated exposure
no data available
Aspiration hazard
no data available
Potential health effects
Inhalation: May be harmful if inhaled. May cause respiratory tract irritation.
Ingestion: May be harmful if swallowed.
Skin: May be harmful if absorbed through skin. May cause skin irritation.
Eyes: May cause eye irritation.
Signs and Symptoms of Exposure
sneezing, Nausea, Weakness, Symptoms of systemic copper poisoning may include: capillary damage, headache, cold sweat, weak pulse, and kidney and liverdamage, central nervous system excitation followed by depression, jaundice, convulsions, paralysis, and coma. Death may occur from shock or renal failure. Chroniccopper poisoning is typified by hepatic cirrhosis, brain damage and demyelination, kidney defects, and copper deposition in the cornea as exemplified by humanswith Wilson's disease. It has also been reported that copper poisoning has lead to hemolytic anemia and accelerates arteriosclerosis.
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Additional Information
RTECS: Not available
12. ECOLOGICAL INFORMATION
12.1 Toxicity
Toxicity to fish no data available
Toxicity to daphnia and other aquatic invertebrates. no data available
no data available
12.2 Persistence and degradability
no data available
12.3 Bioaccumulative potential
Bioaccumulation no data available
12.4 Mobility in soil
no data available
12.5 Results of PBT and vPvB assessment
no data available
12.6 Other adverse effects
no data available
13. DISPOSAL CONSIDERATIONS
13.1 Waste treatment methods
Product
Offer surplus and non-recyclable solutions to a licensed disposal company.
Contaminated packaging
Dispose of as unused product.
14. TRANSPORT INFORMATION
14.1 UN number
ADR/RID: - IMDG: - IATA: -
14.2 UN proper shipping name
ADR/RID: none
IMDG: none
IATA: none
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14.3 Transport hazard class(es)
ADR/RID: - IMDG: - IATA: -
14.4 Packaging group
ADR/RID: - IMDG: - IATA: -
14.5 Environmental hazards
ADR/RID: - IMDG Marine pollutant: - IATA: -
14.6 Special precautions for user
none
15. REGULATORY INFORMATION
This safety datasheet complies with the requirements of Regulation (EC) No. 1272/2008
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
no data available
15.2 Chemical Safety Assessment
no data available
16. OTHER INFORMATION
Further informationCopyright LINBRAZE S.r.l. (Ltd) License granted to make unlimited paper copies for internal use only. The above information is believed to be correct but does notpurport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to theproduct with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. LINBRAZE S.r.l. (Ltd), shall not be heldliable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions ofsale.
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