BRN: What do you see?. Bonding New section in table of contents.
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Transcript of BRN: What do you see?. Bonding New section in table of contents.
What is an ionic compound?
KC 1: An ionic compound consists of a metal and a non-metal bound together in a lattice structure by ionic bonds
KC 2: An ionic compound = metal + nonmetal
Or cation + anion
Ionic Compounds
KC 3: Cation – positively charged ion
KC 4: Anion – negatively charged ion
Polyatomic Ions “Poly” = many
“atomic” = atoms
Ion = charged
KC 5: Polyatomic ion = many atoms bonded together having an overall charge
See periodic table
Ionic Bonding
KC 6: Ionic Bond – bond formed through electrostatic attraction between 2 oppositely charged ions
Review: What is an ion? Different number of electrons from protons
Not a neutral atom
Contains a charge
Ionic bond is formed through electrostatic attraction between 2 oppositely charged ions
These ions are attracted to one another and form what is called a lattice or crystalline structure
Ionic Bonding
8 is the magic number!
KC 7: All atoms are trying to reach a valence shell of 8 – like a noble gas
KC 8: If this cannot be achieved easily, an atom will lose electrons to have a valence shell of zero
Ionic Bonding
Each atom forms a charge that is related to its number of valence electrons
Example: calcium – 1s22s22p63s23p64s2
2 valence electrons
8 is the magic number!
Is it easier to gain 6 or lose 2?
Covalent Compounds & Bonding
KC 9: Covalent compounds consist of 2 or more nonmetals bonded together
KC 10: A covalent bond is formed from the sharing of electrons
Naming Rules: If you need these for your reference, you can print them from my website
We need to spend the class time practicing, not copying down the rules
Naming Ionic Compounds – formula to name
Type A:Metal + Nonmetal
Name the metal
Name the nonmetal
Change the nonmetal ending
to “ide”
Type B: Metal +
Polyatomic Ion
Name the metal
Name the polyatomic ion
Type C: Transition Metal + Nonmetal
Name the transition metal
Find the charge of the metal and place in roman
numerals
Name the nonmetal
Naming Ionic Compounds – formula to name
Type A:Metal +
Nonmetal
Example: KCl
Type B: Metal +
Polyatomic Ion
Example: Ca(NO3)2
Type C: Transition Metal +
Nonmetal
Example: FeF2
Creating Ionic Compounds – the switcheroo!
When bonding a metal and nonmetal in an ionic compound, the charges have to balance
To do this, you just switch the charges and cross them down: the switcheroo
Can also be done the opposite way to determine charges
EXCEPTION ALERT!!
What if you do the switcheroo and the charge for a nonmetal does not come out correctly?
EXCEPTION ALERT!!
If the charge of the nonmetal comes out wrong, that means the charges have reduced
• To correct the charge, just multiply both charges by the necessary number to make it the charge that you know it is
Naming Ionic compounds
- Name to formula
Write the formula for the compound using
subscripts
Write the element symbol
Determine the charge of each
element from looking at the periodic table
Do the switcheroo!Cross charges down
Covalent Compounds
-formula to name
Write the Greek prefix for the first
element and name it
1 = mono 6 = hexa2 = di 7 = hepta3 = tri 8 = octa4 = tetra 9 = nano5 = penta 10 = deca
Write the prefix for the second element
and name it
Bonding
KC 11: Some molecules are more stable when they are found as diatomic – two of the same element covalently bonded
BrINClHOF
BromineIodineNitrogenChlorineHydrogenOxygenFluorine
KC 12: Lewis Structure Rules
1. Draw skeleton of molecule or compound and count total valence electrons able to use
2. Give all elements full octet and a single bond between elements.
3. Count number of electrons in drawing from step #2 and compare to number of electrons allowed
4. If too many, do the “move a pair lose a pair” rule until you have the correct number of electrons Move electrons from outside in to form double or triple bond then erase a pair of
electrons from the outside
How many electrons does hydrogen have?
Will it be happy with 8?
NO!
KC 13: Hydrogen follows the duet rule – only needs 2 electrons to be happy
EXCEPTION ALERT!!
Lewis Structure Rules
1. Draw skeleton of molecule or compound and count total number of valence electrons to use Follows logic; place the element that is only contained
once in the middle
Example: CO2
C = 4e-
O = 6 x 2 = 12e-
Total = 16e-
Lewis Structure Rules
2. Give all elements full octet (8 around each element) and a single bond between elements.
Example: CO2 16e-
Lewis Structure Rules
3. Count number of electrons in drawing from step #2 and compare to number of electrons allowed
Example: CO2
Lewis Structure Rules
4. If too many, do the move a pair lose a pair rule until you have the correct number of electrons
Move electrons from outside in to form double or triple bond then erase a pair of electrons from the outside
Example: CO2
**Cannot break octet rule!!**
Lewis Structure Rules
Most Lewis structures for compounds follow the common bonding patterns:
4 bonds 3 bonds 2 bonds 1 bond
0 L.P. 1 L.P. 2 L.P. 3L.P.
Shapes of Molecules
The Lewis structure can be transferred into a 3D model that tells us the exact shape, bond angles, and polarity of molecules
# of things # bonds # lone
pairsMolecular geometry
Bond angle Example
2 2 0 linear 180 CO2
3 3 0 Trigonal planar 120 BF3
3 2 1 Bent <120 SO2
4 4 0 tetrahedral <109.5 CH4
4 3 1 Trigonal pyramidal <109.5 NH3
4 2 2 Bent <109.5 H2O
Polarity
KC 14: The shape of the molecule and the electronegativity of the elements determines the molecule’s polarity
We use vectors to represent polarity
Demonstration:
H2O
Your turn!
You are going to be given a molecule to build and show to the class
You must include: Name
Formula
Lewis structure
Molecular geometry
polarity