Brimbal Ave. - Environmental Notification Form - 9.2.14 - Volume 2 of 2
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Transcript of Brimbal Ave. - Environmental Notification Form - 9.2.14 - Volume 2 of 2
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August 18, 2014
Secretary Richard K. Sullivan, Jr.
Executive Office of Energy & Environmental Affairs
Attn: MEPA Office100 Cambridge Street, Suite 900
Boston, MA 02114
Re: Corrective Action Design DocumentsSohier Road and Brimbal AvenueBeverly, Massachusetts
Dear Secretary Sullivan:
The attached documents were submitted to Massachusetts Department of Environmental
Protection (DEP) Bureau of Waste Prevention – Solid Waste Division as part of a Corrective
Action Design (CAD) application in 2009. Massachusetts DEP approved the CAD and providedAuthorization to Construct on December 31, 2009. The currently proposed project is a similar
commercial development on the same parcel. The following documents are attached with this
letter:
Engineering Design Report, Tetra Tech, March 5, 2009
Human Health and Environmental Risk Characterization, Tetra Tech, March 5, 2009
Corrective Action Design Plans, Tetra Tech, March 5, 2009, Revised November 24, 2009
Corrective Action Design Specifications, Tetra Tech, November 24, 2009
Approval of the Corrective Action Design and Authorization to Construct, December 31,2009.
Please let me know if you have questions.
Very truly yours,
Matthew T. Madden, P.E., L.S.P.
Senior Project Manager
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Engineering Design Report
Former Brimbal Avenue Landfill
Brimbal Avenue and Sohier Road
Beverly, Massachusetts
Submitted to:
Massachusetts Department of Environmental Protection
Northeast Regional Office
March 5, 2009
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Executive Summary
Human Health and Environmental Risk Characterization
Former Brimbal Avenue Landfill
Brimbal Avenue and Sohier Road, Beverly, Massachusetts
Tetra Tech Rizzo (TTR) has conducted a Method 3 Human Health and Environmental Risk
Characterization for the former landfill property located at Brimbal A venue and Sohier Road in
Beverly, Massachusetts (the Site). This Risk Characterization was conducted in conformance
with the requirements
of
the Massachusetts Solid Waste Regulations 310 CMR 19.000, the
Landfill Technical Guidance Manual,
and the Massachusetts Contingency Plan (MCP), 310
CMR 40.0000. The Massachusetts Department
of
Environmental Protection (DEP) Guidance
document for risk characterization, Guidance
for
Disposal Site Risk Characterization -In
Support of he Massachusetts Contingency Plan (the "Guidance"), and related guidance, such as
Characterizing Risks Posed by Petroleum Contaminated Sites: ImplementationofVPHIEPH
Approach, has been followed in this analysis.
A portion of the human health risk characterization which evaluates potential exposures and risks
to Site receptors due to the inhalation of volatile vapors emitted from the inactive landfill (inside
the proposed new buildings and outside the buildings in the near-field ambient air) was
conducted by our Tetra Tech EC (TTEC) office. The risk characterization report prepared by
TTEC is included as Appendix
F.
The Site consists
of
approximately 6.5-acres
of
vacant land located between Brimbal A venue and
Sohier Road immediately south
of
Route 128 in Beverly, Massachusetts. The Site.is identified
by the Town
of
Beverly (the Town) Tax Assessor's Office as Map 55 Lot 29 and is currently
owned by Brimbal Avenue Development LLC. The Universal Transverse Mercator (UTM)
Coordinators for the Site are Zone 19 East 345470 North 4715300. The Site locus is shown on
Figure
1.
A Site Plan is included as Figure 2. The Site is an inactive landfill that was used by the
Town
of
Beverly from approximately 1946 through 1961. The footprint
of
the landfill extends
beyond the property boundary primarily
to
the south
of
the subject property. When operations
ceased, the landfill was reportedly covered with 2-3 feet of clean sand and gravel and left fallow
for more than 40 years. The Site had been allowed to re-vegetate, but has been largely cleared in
anticipation of future development. Brush and shrubs are still present along portions of the Site's
perimeter. The Site is proposed to be developed into a mixed use property called the North Shore
Commons upon closure
of
the inactive landfill.
Observations during borings at the Site indicated that shallow soil at the Site is primarily sand
and gravel fill. Solid waste including brick fragments, wood, plastic, and glass was observed
mixed with sand and gravel fill at deeper elevations. Tetra Tech Rizzo reviewed available soil
analytical data from previous investigations, and collected soil samples during soil borings
advanced as part
of
the assessment. Soil samples were collected from the Site by Vanasse
Hangen Brustlin, Inc. (VHB) and TTR in 2007. A summary
of
the Site soil data and the
laboratory certificates
of
analyses are presented in Appendix E. The results
of
the soil sampling
and analysis were typical of a heterogeneous matrix of soil and solid waste. Metals, petroleum
hydrocarbons, and other contaminants were detected in some samples. Because of the
heterogeneous nature of the matrix, it was not feasible to obtain a representative set of soil
concentration data. Furthermore, the Corrective Action Design and Post-Closure Use plans
include provisions for maintaining physical separation from the waste, limitations on post-
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Human Health and Environmental Risk Characterization
Former Brimbal Avenue Landfill
Brimbal Avenue and Sohier Road, Beverly, Massachusetts
collected from the Site by Griffin Engineering Group, LLC (Griffin Engineering) in 2007 and
2008. A summary
of
the groundwater data collected from the Site and used to evaluate risks is
presented in Table
1.
The landfill gas data is presented in Table I
of
the TTEC report included in
Appendix F.
Landfill gas (LFG) analytical data from on-site and off-site sampling performed in 2007 and
2008 were compiled and evaluated with regard to spatial trends by TTEC. Based on differences
in the detected sets ofLFG contaminants, the overall site was broken down into a Western
Inhalation Exposure Area (where a Day Care facility is proposed to be built), an Eastern
Inhalation Exposure Area (where Commercial/Retail and Residential facilities are proposed to be
built), and a Site-Wide Inhalation Exposure Area (i.e., the whole site). The landfill gas
characteristics for each Inhalation Exposure Area were used in combination with conservative
indoor air vapor intrusion modeling and outdoor air atmospheric mixing and dispersion modeling
to estimate the concentrations
of
the landfill gas constituents that may be present in the air at
potential future exposure points associated with site development. These concentrations were
then combined with inhalation toxicity values to project the potential cancer and non-cancer risks
for the persons that may access and use this area in the future.
The findings of the risk assessment conducted by TTEC were as follows:
• The analyses indicated that there is "No Significant Risk"
of
harm to human health for
any of the evaluated receptors in any portion of the Site with the exception of a potential
future resident with lifelong exposure to the released LFG constituents in the western
portion of the site. The projected Excess Lifetime Cancer Risk (ELCR) for this scenario
exceeded the DEP threshold of 1.0 E-5, due to potential vapor intrusion into the indoor
air
of
a hypothetical new slab-on-grade residence ·in this area. The LFG constituent
tetrachloroethene was the principal risk driver. No inhalation risk concerns were
identified for the other receptors in the Western Inhalation Exposure Area,
or
for any
of
the evaluated receptors in the Eastern Inhalation Exposure Area. The tetrachloroethene in
the western portion
of
the site also caused the projected cancer risk for a potential future
resident with lifelong Site-Wide exposure to exceed the DEP threshold. The
tetrachloroethene was only detected in the landfill gas at one location in the Western
Inhalation Exposure Area. No inhalation risk issues were identified relative to exposure
to the outdoor air under any of the evaluated scenarios.
• Regarding the potential significance of hydrogen sulfide (H
2
S) relative to development,
no sampling was performed for
HzS
in the Eastern Inhalation Exposure Area, and only 2
of 3 samples collected in the Western Inhalation Exposure Area were analyzed for H
2
S.
The detection
of
H
2
S in the Western Inhalation Exposure Area (at a maximum
concentration of 4.2 parts per million (ppm)) exceeded a number of published odor
thresholds (which ranged between 0.13 ppm and 8.1 ppm). As such, it is likely that
people would be able to smell H
2
S in the Western Inhalation Exposure Area
if
no
mitigative steps are taken.
HzS
levels in the landfill gas in the eastern portion of the Site
have not been quantified. Therefore, it is not known whether H
2
S may pose an odor
problem
or
a potential health concern in this area. There are no known complaints
of
ambient air odors at the Site. In addition, no evidence of strong, pungent or noxious odors
Tetra Tech Rizzo
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Human Health and Environmental Risk Characterization
Former Brimbal Avenue Landfill
Brimbal Avenue and Sohier Road, Beverly, Massachusetts
average groundwater concentrations ofCOCs do not exceed the UCLs.
Based on the above information, we find a condition of"No Significant Risk" of harm to public
welfare exists at the Site for the conditions observed at the Site.
The general definition
of
harm to safety in the MCP (31 0 CMR 40.0992(4) and 310
CMR
40.0960) states that a level
of
no significant risk to safety exists or has been achieved
if
the
conditions at a site which are related to a release of oil and/or hazardous material do not
currently and will not in the foreseeable future pose a threat ofphysical harm or bodily injury to
people. Threats to public safety include physical conditions and chemical agents that may cause
bodily harm or injury (e.g., bums or fractures) as opposed to illness. No uncontained materials
exhibiting characteristics
of
corrosivity, reactivity, or flammability were found on the Site. No
open pits, lagoons, drums, dangerous structures,
or
other apparent threats to public safety and no
danger
of
fire from the conditions evaluated in this report have been observed. Methane was
detected above the Lower Explosive Limit (LEL) in some gas wells located at the Site. No
methane was detected in the building on the abutting residential complex, or in the soil gas in the
vicinity
of
the building. Indoor air methane levels were not measured at the Site since there are
no buildings currently located at the Site. Thus, we find a condition of"No Significant Risk" of
harm to public safety exists for the conditions observed at the Site.
The proposed development includes the construction of several buildings for retail, office,
restaurant, and childcare use. The presence
of
methane gas above the LEL in the subsurface
could pose a potential risk to public safety. However, the Corrective Action Design includes
mitigating measures such as vapor barrier and gas venting systems to be implemented during the
· development of the Site to prevent potential entrainment of methane in future Site buildings.
Once the Site is developed, the condition of "No Significant Risk" will depend on maintenance
of
the mitigating measures mentioned above. The proposed mitigation measures and plans for
maintenance and monitoring during the post-closure period are described in the Engineering
Design Report and Corrective Action Design plans.
In conclusion, a condition
of"No Significant Risk" of harm to public safety, public welfare and
the environment has been found to exist on the Site for the conditions evaluated. However, there
is a condition of "Significant Risk" of potential harm to human health at the Site for the
conditions evaluated. Specifically, the ELCR estimated for potential future residents with
lifelong exposure to the released LFGs was above the DEP risk limit
of
1.0 E-5, due to potential
vapor intrusion into the indoor air
of
a hypothetical new slab-on-grade residence in this area. The
LFG constituent tetrachloroethene was the principal risk driver.
We have prepared these risk assessment estimates using conservative (i.e., health-protective)
assumptions. Thus, the hazard indices and cancer risks presented herein provide an upper-bound
estimate of health risks from quantified Site compounds to the groups of potentially exposed
individuals considered in the assessment. Health risks resulting from differing durations or
frequencies from those described in this report could increase or decrease proportionately in
accordance with particular changes in exposure patterns.
Tetra Tech Rizzo
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Human Health and Environmental Risk Characterization
Former Brimbal Avenue Landfill
Brimbal Avenue and Sohier Road, Beverly, Massachusetts
Compounds of concern were evaluated for both carcinogenic toxicity and chronic or subchronic
systemic toxicity, depending upon the duration of exposure. Carcinogenic toxicity always refers
to a lifetime cumulative effect
of
a given substance, while systemic (noncarcinogenic) toxicity
may refer to several exposure durations. Subchronic, or short-term, exposures generally occur
over a period
of
two weeks to seven years, while chronic exposures generally occur over a
greater period
of
time. In this report, we evaluated chronic systemic exposures for hypothetical
future utility workers that perform utility repair and maintenance who may be exposed for longer
than seven years. Similarly, we evaluated subchronic systemic exposures for construction
workers on the Site who may be exposed for approximately one year.
4.1.1 Noncarcinogenic Effects
The systemic toxicity of noncarcinogenic substances can be estimated using Reference Doses
(RIDs). A chronic RID is an estimate of the daily exposure to an individual human that may
occur without an appreciable risk of harmful effects during a lifetime of exposure. The units of
the reference dose for humans are milligrams
of
compound per kilogram
of
body weight over
one day
of
exposure (mg/(kg•day)). For inhalation exposures, EPA establishes chronic
Reference Concentrations (RfCs), from which benchmark doses may be derived using standard
exposure assumptions: an inhalation rate of 20 cubic meters per hour and a body weight of 70 kg.
RIDs and RfCs are derived from No Observed Adverse Effect Levels (NOAELs) measured in
animal experiments and extrapolated to human dose. RIDs and RfCs are inversely proportional
to toxicity; that is, a lower RID or RfC signifies a greater toxicity.
The EPA also derives subchronic RIDs and RfCs, which estimate the daily exposure to an
individual human that may occur without an appreciable risk
of
harmful effects from an exposure
ranging from two weeks to seven years. Whenever possible, EPA estimates these subchronic
toxicity values using studies comparable to subchronic exposures. However, when appropriate
studies are unavailable, EPA adopts the chronic RID as the subchronic RID or does not publish a
subchronic toxicity value. EPA publishes subchronic RIDs and RfCs in HEAST.
The subchronic and chronic effect(s) of a compound measured by RIDs do not include
carcinogenic effects of the compound. RIDs and RfCs for the Site COCs are presented in Table
4. Carcinogenic effects are considered separately and are discussed below.
4.1.2 Carcinogenic Effects
The toxic effect of carcinogenic substances can be estimated using a Cancer Potency Factor
(CPF). The CPF is the result
of
a low-dose extrapolation procedure and is presented as the risk
per dose of compound (mg/(kg•day)r
1
• From the CPF, risk per concentration in air (J. g/m
3
r
1
or
unit risks for the inhalation pathway have been derived. EPA has not developed cancer potency
factors for dermal exposures, and we apply ingestion CPFs for dermal exposures in this
assessment.
The EPA classifies carcinogenic compounds using a Weight of Evidence classification. In
general, EPA's classification is as follows:
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Human Health and Environmental Risk Characterization
Former Brimbal Avenue Landfill
Brimbal Avenue and Sohier Road, Beverly, Massachusetts
5.6 Estimation of Receptor-Specific Exposure Factors
After estimating EPCs, we estimate exposure doses to humans. We first estimate an average
daily dose
on
a day
of
exposure [ADD (d)] separately for each compound and pathway for each
receptor. Generally, we calculate dose
via
the following equation:
Dose= EPC
*
Receptor-specific Exposure Factor
*
RAF
The RAF is the Relative Absorption Factor, a percentage representing the
how
readily a
compound is absorbed into the body. RAFs are specific to the route
of
exposure and the medium
to which exposure occurs.
In general, the Receptor-specific Exposure Factors incorporate the following similar features:
• Rate
of
exposure
or
intake
• Frequency
of
exposure(#
events/time)
• Duration
of
exposure events (time/event, i.e., hours exposed)
• Duration
of
exposure period (time, years)
• An averaging period (70 years for carcinogenic exposures, shorter periods for
noncarcinogenic exposures [1 to 25 years])
• Conversion factor to reconcile the units
• Body weight
of
the receptor (kg)
The exposure calculations are presented in Tables C-1 and C-2 in Appendix C.
6.0 Risk Characterization
This section combines information
on
chemical toxicity with modeled exposures to estimate
risks and hazards associated with compounds detected in environmental media at the Site.
6.1 Noncancer Health Hazards
The Hazard Index (HI) is a measure
of
systemic (noncancer) toxicity and is defined as the ratio
of
an estimated dose
of
a compound to its RfD. We estimate the chronic
or
subchronic HI as the
ratio
of
the Average Daily Dose to the chronic
or
subchronic RID for each compound and each
pathway.
We estimate His separately for each COC and pathway from the equation below. In the absence
of
specific information
on
possible synergisms or antagonisms, we sum across all compounds
and all exposure pathways to obtain a Total Site HI for each receptor. We calculate His for the
most sensitive receptor. As stated, for the resident receptors, the HI is calculated for the child.
The following general equations are used to calculate hazard indices for each exposure.
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Human Health and Environmental Risk Characterization
Former Brimbal Avenue Landfill
Brimbal Avenue and Sohier Road, Beverly, Massachusetts
Assessment is to eliminate from further evaluation those situations that are unlikely to result in
ecological harm. For sites for which either potential for exposure has not been identified or at
which "apparent significant harm" is not likely to occur, a condition
of
"no significant risk
of
harm to the environment" exists. However, for sites at which the potential for exposure exists
and "apparent significant harm" may occur, a quantitative assessment (Method 1 or 2) for that
site must be performed.
8.1 Stage I Screening Assessment
The Site setting was reviewed to determine
if
potential environmental receptors, exposure
pathways, and exposure points were situated
on
and near the Site. Potential receptors were
defined as those receptors situated within 500 feet
of
the Site and exposed to oil and/or
hazardous materials in groundwater. The Massachusetts Natural Heritage Atlas
(11th Edition
valid from July 1, 2003) and the Massachusetts Surface Water Quality Standards, Basin
Classification and Maps (314
CMR
4.06) were also inspected to determine the presence
of
rare
wetlands wildlife habitat and the DEP-assigned surface water classification
in
the area
of
the
Site.
Potential environmental receptors identified within 500 feet
of
the site include resident and
transient wildlife. Potential exposure pathway at the Site is identified as groundwater flow. The
potential exposure point identified for the Site is contact with groundwater. According to the
Massachusetts Geographic Information System (MassGIS) map
of
the Site area (Figure 3), no
Areas of Critical Environmental Concern
or
Outstanding Resource Waters are located within 500
feet
of
the Site. The MassGIS map shows wetlands and an intermittent brook within 500 feet
of
the Site to the east/southeast. The Massachusetts Natural Heritage Atlas
(11th
Edition) 'shows no
Priority Habitat for Rare Species, Estimated Habitat
of
Rare Wildlife
or
Certified Vernal Pools
within 500 feet
of
the Site.
The potential for adverse effects on environmental receptors within 500 feet
of
the Site that are
potentially exposed to OHM in groundwater was evaluated using an effects-based screening
approach. The EPCs for groundwater were compared to DEP UCLs as shown in Table
8.
In
addition, the groundwater EPCs were diluted by a factor
of
10 corresponding to the percentage
used by DEP to calculate GW-3 groundwater standards from EPA surface water Ambient Water
Quality Criteria (AWQC). These adjusted data were then compared to the A WQC chronic
values for freshwater, where available (Table 9). No exceedences ofUCLs or A WQCs were
identified. Therefore, we find a condition
of"No
Significant Risk"
of
harm to the environment
exists for the Site conditions evaluated.
Therefore, it is determined that a condition
of"No
Significant Risk"
of
harm to the environment
Based on the Stage I Screening Assessment, a Stage
II
Environmental Risk Characterization is
not required for this Site. ·
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LEL
LFG
LOAEL
L
MCP
MMCL
MDL
M
Mg
flg
MW
ND
NOAEL
OHM
PPB
PPM
PRG
RAF
RAO
RIC
RID
RSF
s
UCLs
VOCs
Vp
y
Lower Explosive Limit
Landfill Gas
Human Health and Environmental Risk Characterization
Former Brimbal Avenue Landfill
Brimbal Avenue and Schier Road, Beverly, Massachusetts
Lowest Observed Adverse Effects
Level
Liter
Massachusetts Contingency Plan
Massachusetts Maximum Contaminant Level
Method Detection Limit
Meter
Milligram
Microgram
Molecular weight
Not detected
No Observed Adverse Effect
Level
Oil and Hazardous Material
Parts Per Billion
Parts Per
Million
Preliminary Remediation Goal
Relative Absorption Factor
Response Action Outcome
Reference Concentration
Reference Dose
Receptor-Specific Factor
Solubility (aqueous)
Upper Concentration Limits
Volatile Organic Compounds
Vapor pressure
Year
12.0 References
Agency
for Toxic Substances and Disease
Registry.
Toxicological
Profiles for
Chemicals.
Bodek,
I., W. J.
Lyman,
W. F. Reehl, and D. H. Rosenblatt. Environmental Inorganic
Chemistry,
Properties, Processes,
and Estimation Methods, Pergamon
Press, New York. 1988.
Bowen, H.
J.
M. Environmental Chemistry of
the
Elements, Academic Press, London.
1979.
Dean,
J.
A.
Lange's Handbook
of
Chemistry,
13th
Edition,
McGraw-Hill Book Company,
New
York. Ed. 1985.
GCA Corporation. Development of Statistical Distributions or Ranges of Standard
Factors
Used
in Exposure
Assessments
(EPA 68-02-351 0), Septem\Jer 1984.
Howard,
P. H.
Handbook
of
Environmental Fate
and
Exposure
Data for
Organic Chemicals,
Lewis
Publishers, Chelsea, Missouri. 1990.
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Human Health and Environmental Risk Characterization
Former Brimbal Avenue Landfill
Brimbal Avenue and Sohier Road, Beverly, Massachusetts
Lyman, W. J., W. F. Reehl, and D. H. Rosenblatt. Handbook of Chemical Property Estimation
Methods-
Environmental Behavior of Organic Compounds, McGraw-Hill Book Company,
New York. 1982 .
. Massachusetts Department
of
Environmental Protection. Characterizing Risks Posed by
Petroleum Contaminated Sites: Implementation ofVPH/EPH Approach, Final, October, 2002.
Massachusetts Department
of
Environmental Protection. Guidance for Site Risk Characterization
and Related Phase II Activities In Support
of
the Massachusetts Contingency Plan. May 17,
1989, updated July 1995.
Massachusetts Department
of
Environmental Protection. Documentation for the Risk Assessment
Shortform Residential Scenario. Policy #WSC/ORS-142-92. October 1992.
Massachusetts Division of Fisheries and Wildlife. Natural Heritage
and
Endangered Species
Program. Massachusetts Natural Heritage Atlas. JJ'h Edition. Part 1 -Eastern Massachusetts.
Valid from July
1,
2003.
United States Environmental Protection Agency. Handbook ofRCRA Ground-water Monitoring
Constituents: Chemical
&
Physical Properties (40 CFR Part 264, Appendix 9). Office of Solid
Waste EPA530-R-92-022. September 1992.
United States Environmental Protection Agency. EPA-ECAO Regional Support Provisional
Values published in the EPA Region III Risk Based Concentration document, 1999.
United States Environmental Protection Agency. Health Effects Assessment Summary Tables,
FY 1997. OERR 9200.6-303(97-1), March 1997.
United States Environmental Protection Agency. Exposure Factors Handbook. Office of Health
and Environmental Assessment, EPA/600/C-99/001. May 1999.
United States Environmental Protection Agency. Risk Assessment Guidance for Superfund,
Volume I, Human Health Evaluation Manual (Part A), Interim Final, EP A/540/1-89-002,
December 1989.
United States Environmental Protection Agency. 2000 Database Documented in Integrated Risk
Information System, Volume 1 and Electronic Information System. Office of Health and
Environmental Assessment. November, 2000.
United States Environmental Protection Agency. Method for Estimating Fugitive Particulate
Emissions from Hazardous Waste Sites. Hazardous Waste Engineering Research Laboratory,
Cincinnati, Ohio. EPA/600/2-87/066. 1987.
Verschueren, K. Handbook of Environmental Data on Organic Chemicals, Second Edition. Van
Nostrand Reinhold, New York. 1983.
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Table 3
Compound name
Benzene
Butyl Alcohol
Butylbenzene, n-
Butylbenzene, tert-
Ethyl tert-butyl ether
lsopropyltoluene, p-
Methyl tert-butyl ether
Naphthalene
Tert-amyl methyl ether
(TAME)
Toluene
Trichlorotrifluoroethane 1,1 ,2J
(Freon 113)
Trimethylbenzene,
1
2,4-
Xylene (total)
Acenaphthene
Anthracene
Benzo(a)anthracene
Benzo(b)fluoranthene
Fluoranthene
Fluorene
Methylnaphthalene, 2-
Naphthalene
Phenanthrene
Pyrene
Carbazole
Dibenzofuran
Dimethylphenol, 2,4-
Methylphenol, 2-
Methylphenol, 3-
Phenol
Antimony, Total
Arsenic, Total
Barium, Total
Chromium, Total
Manganese, Total
Mercury, Total
Nickel, Total
Zinc, Total
C11-C22 Aromatics
Page 1 of
1
Natural and Anthropogenic Concentrations for Site Compounds
of
Concern
Maximum Detected
Concentration in
Site Groundwater
( ~ g / L )
1.5
2,890.0
1.3
1.2
18.0
2.7
3,870.0
180.0
33.7
1.9
4.4
1.6
6.0
12.4
6.4
0.10
0.12
8.9
12.0
14.8
92.0
32.9
6.4
16.3
12.0
12.0
11.0
28.0
8.8
6.0
47.3
892.0
6.3
11,500.0
0.3
17.0
99.0
203.0
Low
( ~ g / L )
0.5
NA
NA
NA
NA
NA
NA
0.005
NA
1
NA
NA
0.2
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
0
NA
NA
NA
NA
NA
0.95
<1
3
NA
Common Ranges
Found in
Water
~ g i l
High
( ~ g / L )
80
NA
NA
NA
NA
NA
NA
17
NA
3,500
NA
NA
9.9
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
1
NA
NA
NA
NA
NA
NA
20
2,000
NA
Sources. ATSDR, Toxicological Profiles for Chemicals
Bradley et al., 1993
DEP Documentation for the Risk Assessment Shortform Residential Scenario, 1992
USGS Professional Paper 1270, 1984.
Notes:
Bold print indicates the maximum detected concentration
of
the COG is less than or equal to
the lowest concentration commonly found in groundwater.
NA = Not Available
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&
UW\CHEM_CW
&
UWAnthro
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Page 1 of 1
Table
6
Exposure Assumptions
Construction
Receptor: Worker Utility Worker
Occurrence: Future Future
Existence:
Potential Potential
Location:
Outdoors
Outdoors
Exposure: Subchronic Chronic
Age:
Adult (18+)
Adult (18+)
BodyWeight(kg)
1
:
58 58
Surface Area (m
2
)
1
:
1.82 1.82
Lifetime (y):
70 70
Groundwater Exposures
Dermal Contact
Fraction exposed
1
(frac.)
0.05 0.05
Time Exposed
1
(h/d)
8 8
Days of Exposure (d/wk)
5 5
Weeks of Exposure (wkly)
8
1
Years of Exposure
(y)
25
United States Environmental Protection Agency, Exposure Factors Handbook, 1999.
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RA_CW
& UW\EXP_CW & UWExposure Assumptions
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Table 8
Compound name
Benzene
Butyl Alcohol
Butylbenzene, n
Butylbenzene, tart
Ethyl tert-butyl ether
lsopropyltoluene, p
Methyl tert-butyl et her
Naphthalene
Tert-amyl methyl ether (TAME)
Toluene
Trichlorotriffuoroethane1,1 ,2-
{Freon 113)
Trimethylbenzene, 1,2,4-
Xylene (total)
Acenaphthene
Anthracene
Benzo(a)anthracene
Benzo(b)fluoranthene
Fluoranthene
Fluorene
Methylnaphthalene, 2·
Naphthalene
Phenanthrene
Pyrene
Carbazole
Dibenzofuran
Dimethylphenol, 2,4-
Methylphenol, 2-
Methylphenol, 3-
Phenol
Antimony, Dissolved
Arsenic, Dissolved
Barium, Dissolved
Chromium, Dissolved
Manganese, Dissolved
Mercury, Dissolved
Nickel, Dissolved
Zinc, Dissolved
C11-C22 Aromatics
Upper Concentration Limits for Site Compounds of Concern
MCP Method 3
Upper Concentration Limits
(UCls)
310 CMR 40.0996(5)
Average Groundwater Groundwater UCls
Concentrations (pg/l) (pg/l)
1.3
281.9
1.2
1.5
2.5
1.3
256.0
9.1
3.3
1.4
1.7
1.4
2.3
5.1
4.4
32
3.2
4.6
5.1
5.0
11.3
6.5
4.4
6.2
3.9
4.2
3.6
6.2
3.7
3.7
13.0
270.8
2.8
3,834.3
0.1
12.7
26.1
77.0
NA
- Not Available
100,000
NA
NA
NA
NA
NA
100,000
100,000
NA
80,000
NA
NA
100,000
50,000
30,000
10,000
4,000
2,000
30,000
100,000
100,000
3,000
BOO
NA
NA
100,000
NA
NA
100,000
80,000
9,000
100,000
3,000
NA
200
2,000
50,000
100,000
Page 1
of
1
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Figure 3
·MA DEP - Bureau of Waste Site Cleanup
SITE NAME:
Site Scoring Map: 500 feet & 0.5 Mile Radii
Sohier Road and Brimbal Avenue
Beverly, MA 01915
423424n 705246ew
Roads:
limited
kcess, Divided, Major
Road,
Connector, Street, Track,
rail
is the best available at the date jdtii-= GIS
Grographic and
The information shown on this map
I ~ I Office uf
of printing. Please refer to the
i .v
E ; ~ : : , ' : t ; " ' ; a l
data source descriptions document. MJIIM«kowtu Ertc11tilllt
Dffic• of ~ ' D i t m t m n ~ t o l Afflli,. _2001
EPA Sole Source
Aquifer;
FEMA
100-year floodplain
......
ITIIJ
I<:;:
::
:J
Pubtic Water Supplies: Ground,Surface,Non Comm.mity 0 0 •
Boundaries:
lOwn,
County, DEP Region;
Train;
A:lwertine;
P i p e ~ n e ;
l>queduct Approved Zone
2
; IWPA; Surface Water Supply Zone A
~ r z z . J E3
8 8 -
Basins: Major, Sub; Streams: Perennial, Intermittent, Man Made Shore, Dams
H ~ r o g r a p h y :
Water Features, Public Surface Wate r Supply
••• c::::::::J -
_ _ W tlands : Fresh,Salt,NHESP Wetlands Habitat
••••••• ~ [ I i ]
A:ltentiaUy Productive Aquifers: Medium,High Yield
•••••••
, , , c::::::::Jc::::::::J Protected Open Space; ACEC
•••••••••••••••••••••••••••• [[]]]] I22Z.J
Non-A:ltential Drinking Water Source Area: Medium, High Yield . c::::::::J DEP P e r m ~ e d Sofid Waste
F a c i ~ t i e s ;
Certified Vernal A:lols •
MILP
~
SCALE1:15000
, ~ ~ ~ ~ ~ ~
~
W*E
April
11
, 2
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Appendix A: Limitations
I. The observations described in this report were made under the conditions stated therein. The
conclusions presented in the report were based solely upon the services described therein, and
not on scientific tasks or procedures beyond the scope
of
described services or the time and
budgetary constraints imposed by the CLIENT. The work described
in
this report was
carried out in accordance with the Terms and Conditions in our contract.
2.
In
preparing this report, ENGINEER has relied on certain information provided by state and
local officials and other parties referenced therein, and on information contained in the files
of state and/or local agencies available to ENGINEER at the time of the site assessment.
Although there may have been some degree
of
overlap in the information provided by these
various sources, ENGINEER did not attempt to independently verify the accuracy or
completeness of all information reviewed or received during the course of this site
assessment.
3. Observations were made of the Site and of structures on the Site as indicated within the
report. Where access to portions
of
the Site
or
to structures on the Site was unavailable or
limited, ENGINEER renders no opinion as to the presence of hazardous materials or oil, or to
the presence of indirect evidence relating to hazardous material or oil, in that portion of the
Site or structure.
In
addition, ENGINEER renders no opinion as to the presence of hazardous
material or oil, or the presence of indirect evidence relating to hazardous material or oil,
where direct observation of the interior walls, floor, or ceiling of a structure on a Site was
obstructed by objects or coverings on or over these surfaces.
4. ENGINEER did not perform testing or analyses to determine the presence or concentration of
asbestos at the Site or
in
the environment at the Site.
5.
It
is ENGINEER's understanding that the purpose of this report is to assess the physical
characteristics of the subject Site with respect to the presence on the Site of hazardous
material or oil. This stated purpose has been a significant factor in determining the scope and
level
of
services provided for in the Agreement. Should the purpose for which the Report
is
to be used or the proposed use ofthe site(s) change, this Report is no longer valid and use of
this Report by CLIENT or others without ENGINEER's review and written authorization
shall be at the user's sole risk. Should ENGINEER be required to review the Report after its
date of submission, ENGINEER shall be entitled to additional compensation at then existing
rates or such other terms as agreed between ENGINEER and the CLIENT.
6.
The conclusions and recommendations contained in this report are based in part, where
noted, upon the data obtained from a limited number of soil samples obtained from widely
spaced subsurface explorations. The nature and extent
of
variations between these
explorations may not become evident until further exploration.
If
variations or other latent
conditions then appear evident, it will be necessary to reevaluate the conclusions and
recommendations of this report.
7. Any water level readings made
in
test pits, borings, and/or observation wells were made at
the times and under the conditions stated on the report. However, it must be noted that
fluctuations
in
the level of groundwater may occur due to variations in rainfall and other
factors different from those prevailing at the time measurements were made.
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Appendix 8:
Benzene
Appendix B
Short Toxicological Profiles
Short Toxicological Profiles for Site Compounds
Benzene contains six carbon atoms and six hydrogen atoms and is the parent compound
of
a
class
of
chemicals known as monocyclic aromatic hydrocarbons. As a pure chemical, it is a
colorless to light liquid with an aromatic odor.
It
has a low molecular weight and displays high
water solubility, a medium volatility, and a low affinity to organic carbons in soils. It is a
naturally occurring substance produced by volcanoes and forest fires and is present in plants and
animals, but benzene is also a major industrial chemical obtained from coal and oil. In industry it
is used to make other chemicals, as well as some types
of
plastics, detergents, and pesticides. It is
also a component
of
gasoline. The highest exposure area is in the workplace; however, humans
are commonly exposed to benzene in tobacco smoke and automobile exhaust. Environmental
sources
of
benzene include gasoline filling stations, leaking underground storage tanks,
wastewater and landfills containing benzene, and possibly food products. People living near
industries such as petroleum refineries and chemical manufacturing plants may be affected by
benzene released to the air. Consumer products containing benzene include glues, cleaning
products, and paint strippers. Since benzene evaporates rapidly, the most common exposure
method route is through inhalation
of
air containing benzene. However, absorption, ingestion,
and contact with the skin are also other possible routes
of
exposure. Death may occur
in
humans
after brief ingestion or inhalation exposures to high doses
of
benzene; however, the main effects
of
this type
of
exposure are dizziness, drowsiness, and headaches. Benzene is known to attack
the blood, central nervous system, skin, bone marrow, eyes, and respiratory system. Benzene is
known to be a human carcinogen, and the EPA categorizes benzene as Class A Human
Carcinogen, with sufficient evidence from epidemiological studies.
Butyl Alcohol
Butyl alcohol (CASRN 71-36-3), also commonly referred to as Butanol, is a colorless liquid with
a slightly rancid, sweet odor. Butyl alcohol is primarily used as a solvent and is commonly
found in paint removers and industrial cleaners. It is a corrosive compound, and can break down
some forms
of
plastics, rubber and coatings. Occupational exposure to Burtyl alcohol may occur
through inhalation or dermal contact; however, the general population is commonly exposed
through the ingestion
of
foods that contain Butyl alcohol
or
the inhalation
of
vapors. Short-term
exposure
of
humans to Butanol can cause a variety
of
affects, including headaches, giddiness,
ataxia, confusion, delirium and possible coma. Additionally, vapors from Butyl alcohol can
cause irritation to the eyes and skin. Brief, repeated overexposures with the skin can cause
depression
of
the central nervous system, and in extreme cases may cause death. EPA considers
Butyl alcohol to be not classifiable as a carcinogen (Class D).
Butylbenzene, n-
n-Butylbenzene is a liquid at room temperature and is not soluble in water. No toxicity
information was available from IRIS, HSDB, or ATSDR.
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Butylbenzene, tert-
Appendix 8
Short Toxicological Profiles
tert-Butylbenzene is a liquid a room temperature and is not soluble in water. A toxicity value was
available from the Region III Risk-Based Concentration Table, however this was the only
toxicity information identified after searching IRIS, HSDB and ATSDR.
Carbazole
Pure carbazole (CASRN: 86-74-8) appears at room temperature as white crystals.
It
is an
extremely weak base and exhibits strong fluorescence and long phosphorescence on exposure to
ultraviolet light. Carbazole is an important dye intermediate, in making photographic plates
sensitive to ultraviolet light.
It
is a reagent for lignin, carbohydrates and used in formaldehyde
manufacture
of
insecticides, lubricants, rubber antioxidants and as an odor inhibitor in
detergents. There is mo known commercial production
of
this compound. Carbazole is naturally
contained in coal, petroleum, and peat indicating that it will be released to the environment from
the incomplete combustion
of
these materials. Carbazole may be released to the environment in
emissions from waste incineration, tobacco smoke, aluminum manufacturing, and rubber
combustion. Carbazole may be released to the environment ineffluents from coal processing, and
wood-treatment facilities. Polynuclear aromatic hydrocarbons, such as carbazole, are found in
food as a result
of
char-broiling and smoking. Carbazole is released to the atmosphere in
emissions from waste incineration, tobacco smoke, aluminum manufacturing, and rubber,
petroleum, coal, and wood combustion.
If
released to the atmosphere, vapor-phase carbazole is
rapidly degraded by photochemically-produced hydroxyl radicals (estimated half-life
of3
hr). In
the particulate phase, the rate
of
degradation depends upon the adsorbing substrate. Substrates
containing carbon ( > 5%) stabilize carbazole and permit long-range atmospheric transport.
Physical removal via wet and dry deposition is important. If released to soil, environmental
substrates that commonly adsorb carbazole may limit or prevent photolysis. Biodegradation
in
soil should be the dominant fate process providing the presence
of
specific degrading bacteria in
the microbial community (biodegradation half-life
of
4.3 min-6.2 hr in screening studies).
Carbazole may partition from the water column to sediment and suspended matter. limiting the
rate
of
photolysis. Human exposure to carbazole occurs through inhalation
of
contaminated air
and consumption
of
water and char-broiled food. High exposure occurs through smoking
cigarettes. No carcinogenicity data are available in humans. There is limited evidence
of
carcinogenicity in animals. Carbazole is not classifiable as to its carcinogenicity to humans.
Dibenzofuran
Dibenzofuran is a manmade white crystalline solid with a medium molecular weight.
It
is
released into the air during the combustion
of
coal, biomass, refuse and diesel fuel and
wastewater emissions can occur from coal tar, coal gasification and shale oil operations. Once in
the air, dibenzofuran will exist primarily in the gas phase where it can be degraded by
photochemical processes. Dibenzofuran released into the water will tend to sorb to sediment and
suspended material. In soils, dibenzofuran will be sorbed and is not expected to leach in most
soil types. The general population is primarily exposed to dibenzofurans through inhalation of
air
which has been contaminated with a variety
of
combustion sources; dibenzofurans have been
identified in tobacco smoke. There is no available toxicity information
of
dibenzofuran alone.
The U.S. EPA considers dibenzofuran to be not classifiable as a carcinogen (Class D).
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Appendix B
Short Toxico'logical Profiles
processes. Exposure to 2-Methylphenol may cause respiratory tract irritation, including dryness,
nasal constriction and throat irritation. It is a corrosive material that can cause severe eye and
skin burns -
if
large areas of skin are wetted by 2-Methylphenol, serious or even fatal poisoning
may occur. The EPA categorizes 2-Methylphenol as Class
C -
a possible human carcinogen,
based on an increased incidence of skin papillomas in mice and an initiation-promotion study.
Methylphenol, 3-
3-Methylphenol occurs as a colorless to yellow liquid with a phenolic odor; below 54 degrees
Farenheight it is a solid. 3-Methylphenol is used as a textile scouring agent, industrial solvent,
for synthetic resins, disinfectants and fumigants, in explosives and in insecticides. Because of
the wide use of 3-Methylphenol, it can be released to the environment through various waste
streams, incuding through automobile exhaust and tobacco smoke. Exposure to 3-Methylphenol
can cause irritation of eyes, nose and throat, with symptoms including tearing, conjunctivitis and
corneal edema. The EPA categorizes 2-Methylphenol as Class C - a possible human carcinogen,
based on an increased incidence of skin papillomas in mice and an initiation-promotion study.
Methyl tert-butyl ether
Methyl-tert-butyl ether (MTBE) is a clear liquid with a disagreeable odor. It is a volatile organic
ether with extensive water solubility and lipophilicity.
It
is used clinically in the treatment of
gallstones, as an industrial solvent, and as a gasoline-oxygenated octane enhancer. MTBE is
expected to be very mobile in the soil, subject to volatilization and leach to groundwater. MTBE
is not expected to adsorb to sediment or suspended particles in water bodies or to bioaccumulate
in aquatic organisms. MTBE in air produces local irritation
of
the nose, throat, and eyes. High
acute exposures produce central nervous system depression, including sedation, slowed reflexes,
tremors, incoordination, and altered behavior. Long-term exposure has resulted in minor changes
in the blood, kidneys, liver, and nervous system. The EPA does not classifY MTBE with regard
to human carcinogenicity. ·
Naphthalene
Naphthalene is a white solid at room temperature.
It
has a distinct odor
of
mothballs or tar.
Humidity and sunshine cause evaporation into the air within a few hours. When placed in water
or soil, bacteria will destroy naphthalene or will render it airborne within a few hours. Tobacco
smoke is known to release 3 of naphthalene per cigarette. The compound
is
used in the
production of dyes, solvents, lubricants, and motor fuels and is a major component of many
mothball preparations.
Humans can absorb naphthalene by dermal, inhalation, and oral routes. Adults and children
experience vomiting, abdominal pain, and anemia. Most
of the data is for inhalation of
naphthalene from mothballs. The primary site of toxicity is the erythrocyte resulting in hemolytic
crisis. Jaundice is seen upon dermal, inhalation, and oral exposures, as are kidney effects. Near
blindness resulted in male and female subjects with a 5 gram ingestion.
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Appendix B
Short Toxicological Profiles
molecular weight element; its solubility in water, affinity for organic carbon (e.g., in soil), and
tendency to bioaccumulate in aquatic organisms depends
on
the particular compound present.
Since antimony belongs to the same periodic grouping as arsenic, it is thought to be similar
metabolically. Like arsenic, antimony has beneficial effects and is used to treat people infected
with parasites. However, long-term exposure to antimony may cause heart problems, vomiting,
and diarrhea. The U.S. EPA does not classifY antimony with regard to human carcinogenicity.
Arsenic
Arsenic is a metallic element that is commonly present in its elemental form and in inorganic and
organic compounds. Arsenic and arsenic compounds are commonly used
in
metal alloys, in the
production
of
agricultural pesticides, pharmaceuticals, pigments, glass, and textiles, and in
tanning and taxidermy. Elemental arsenic has low molecular weight, is a solid at room
temperature, and displays low volatility. Its solubility in water, affinity for organic carbon (e.g.,
in soils), and tendency to bioaccumulate in aquatic organisms depend
on
the particular
compound present. Information
on
the crustal abundance
of
arsenic and its potential essentiality
for humans is provided
in
the main report. Organic arsenic complexed with carbon and hydrogen
is generally less toxic than inorganic arsenic. In this report, we conservatively assume that all
reported arsenic is inorganic. Oral ingestion results in such effects as irritation
of
the
gastrointestinal tract, nausea, vomiting, and diarrhea. Arsenic affects several organs, including
the skin, blood, heart, circulatory system, liver, and kidneys. Neurological effects in the
extremities have also been reported. Arsenic is a likely fetotoxic agent in animals. Carcinogenic
effects have been demonstrated
in
humans from inhalation
of
airborne arsenic containing dusts
near smelters. The U.S. EPA has noncarcinogenic and (inhalation) carcinogenic toxicity values
for arsenic and classifies it as a Human Carcinogen (Class A).
Barium
Barium is a somewhat soft, silver white metal that occurs naturally
in
the minerals barite and
witherite. It is a medium molecular weight element that,
in
its pure form, may ignite
spontaneously in air. Barium occurs in many different forms in the environment, and its
solubility in water, affinity for organic carbon (e.g., in soil), and tendency to bioaccumulate
in
aquatic organisms depend
on
the specific compound. Barium has many uses including in metal
alloys, paints, pesticides, soaps, rubber, ceramics, glass, and x-ray diagnostics. Ingested soluble
forms
of
barium may affect the heart, lungs, liver, kidney, spleen, central nervous system, and
respiratory system, although barium poisoning is virtually unknown. The U.S. EPA has not
classified barium with regard to human carcinogenicity.
Chromium
Chromium is a metallic element that may
be
present
in
its elemental form or in inorganic and
organic compounds. Typical uses
of
chromium and chromium compounds include chrome
plating, copper stripping, organic synthesis, photography, and the production
of
metal alloys.
Chromium is a low molecular weight element and is a solid at room temperature. Its solubility in
water, affinity for organic carbon (e.g., in soils and sediments), and tendency to bioaccumulate
in
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Appendix B.
Short Toxicological Profiles
aquatic organisms depend strongly
on
the compound type. Information
on
the crustal abundance
of
chromium is provided in the main report. Most chromium is found in the environment in two
valence forms: trivalent chromium(III) and hexavalent chromium(VI). Chromium(VI) is much
more toxic than chromium(III), which is the form found in foods. The predominant
environmental form is chromium(III). Inhalation exposures to chromium(III) are reported to
adversely affect the immune systems
of
experimental animals, and injected doses (typically into
the area around the intestines) have adverse developmental and reproductive effects. Animal
studies suggest that chromium(III) probably is not a genotoxic agent. Extremely high oral doses
of
chromium(III) can be lethal to laboratory animals. Chromium(III) is not thought to be
carcinogenic. In fact, small amounts
of
chromium are regularly ingested by people as a natural
component
of
many foods, and in these quantities it is considered an essential nutrient. However,
the U.S. EPA classifies chromium(VI) as a Human Carcinogen (Class A).
Lead
Lead is a naturally occurring metal that is widely distributed throughout the environment and is
found
in
small quantities in food and drinking water. Common uses include the manufacture
of
electrical storage batteries and ammunition. Lead was formerly commonly used
in
gasoline,
solders, pipes, and paints. Inhalation exposure to dusts containing lead is common, particularly in
urban areas. Lead is released as a result
of
the combustion
of
coal, petroleum products, and solid
waste. Elemental lead has a medium molecular weight, is a solid at room temperature, and
displays low volatility. Its solubility
in
water, affinity for organic carbon (e.g., in soils), and
ability to bioaccumulate
in
aquatic organisms depend
on
the compound type. Soils
in
urban areas
are usually contaminated with some lead, which may result in exposure due to soil contact.
Children are at particular risk for lead toxemia both because their characteristic mouthing
behavior may increase their potential for lead ingestion and because they are more susceptible to
neurologic damage. Lead, by any exposure route, is highly toxic to the developing fetus a:nd can
result
in
premature birth, lowered birth weight, and reduced intelligence
in
the offspring. Lead
can adversely affect organs such as the brain and kidneys, and it also has adverse reproductive
effects. Studies in animals suggest that lead may be a carcinogen, and U.S. EPA classifies lead as
a Probable Human Carcinogen (Class B2).
Manganese
Manganese is a naturally occurring metal that is found in various types
of
rocks. It is an essential
trace element and is necessary for good health. Manganese can be found
in
several food items,
including grains and cereals, and is found in high amounts in other foods, such as tea. Pure
manganese is silver-colored, but does not occur naturally. It combines with other substances such
as oxygen, sulfur,
or
chlorine. Manganese can also be combined with carbon to make organic
manganese compounds. Common organic manganese compounds include pesticides, such as
maneb
or
mancozeb, and methylcyclopentadienyl manganese tricarbonyl (MMT), a fuel additive
in gasoline. Manganese is used in the iron and steel industry in steel alloys and is in the
manufacture
of
dry cell batteries
(Mn02),
paints, varnishes, inks, dyes, matches and fireworks,
as a fertilizer, disinfectant, bleaching agent, laboratory reagent, drier for oils, an oxidizing agent
in the chemical industry particularly
in
the synthesis
of
potassium permanganate, and as a
decolorizer and coloring agent in the glass and ceramics industry. Manganese can cause a variety
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Appendix C
Exposure Profiles and Calculations
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Appendix C
Exposure Profiles and Calculations
Appendix
C:
Exposure Profiles and Calculations
This attachment provides exposure profiles for the receptors that are evaluated in this risk
characterization. Tables C-1 and C-2 present the calculations
of
the receptor-specific factors.
Construction Worker
Construction workers working at the Site may be exposed to compounds via dermal contact with
groundwater during trenching or excavating. Construction workers are assumed to come into
contact with groundwater 8 hours per day, 5 days per week, for 8 weeks
of
one year at the Site.
We consider workers to be 18 years
of
age and older, with a life span
of
70 years, average body
weight of
58 kg and body surface area
of
1.82 m
2
.
We assume construction workers will work in
long pants and short-sleeved shirts, leaving their head, lower arms, and hands exposed.
Utility Worker
Utility workers repairing utilities at the Site may be exposed to groundwater COCs via dermal
contact during trenching or excavating. Utility workers are assumed to come into contact with
groundwater at the Site 8 hours per day, 5 days
per
week, for 1 week per year for 25 years. We
consider workers to be 18 years
of
age and older, with a life span
of
70 years, average body
weight
of
58 kg and body surface area
of
1.82 m
2
. We assume construction workers will work
in
long pants and short-sleeved shirts, leaving their head, lower arms, and hands exposed.
Exposure Equations
After estimating exposure point concentrations, we estimate exposure doses to humans. We first
estimate an average daily dose
on
a day
of
exposure [ADD(d)] separately for each compound
and pathway for each receptor. We then estimate an average daily dose averaged over a year
in
which exposure occurs and, finally, averaged over the lifetime
of
the receptor.
In general, the formulas to estimate dose incorporate the following similar features:
• Exposure point concentration
• Rate
of
exposure
• Term
of
exposure (if measured in hours rather than days)
• Conversion factor to reconcile the units
• Body weight
of
the receptor
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Table C-2
Utility Worker-
Dermal Contact
with Groundwater
Notes:
Variables
Receptor-
UW
Age
Average body weight (BW)
Frequency of Exposure (EF)
Duration of Exposure Event (ED)
Duration of Exposure Period (EP)
Averaging Period (AP)
for noncancer risk
for cancer risk
Skin surtace area in contact with soil on days exposed (SA)
Skin surface area
Fraction of skin exposed
Skin Permeability Coefficient (Kp)
Dermal Relative Adsorption Factor (RAF)
Exposure Point Concentration (EPCgw)
Exposure Assumptions
Utility
Worker
Adult(18+)
years
58 kilograms
5 events/year
a hours/event
25 years
25 years
70 years
910 cm
2
/day
18,200 cm
2
0.05
Contaminant-specific em/hour
contaminant- specific
arithmetic mean tJg/L
Note:
(1)
(1)
(2)
(3)
(4)
(5)
(6)
(7)
(B)
(9)
(10)
Subchronic Noncarcinogenic Effects
Utility Worker Noncancer
Dermal Groundwater (UWNCDGW) Factor (Ukg-day)
UWNCDGW
Factor
Subchronic Average Daily Dose (mg/kg-day)
SA (cm2)
x
Kp (em/hour)
x
EF (events/year)
xED
( hours/event)
x
EP (years)
x
(1/1,000
Ucm
3
)
x (1
year/365 days)
x
(1/BW (kg))
x
(1/AP (years))
1.7E-03 Ukg-day
EPCgw (tJg/L)
x UWNCDGW
Factor (Ukg-day)
x
dermal RAF X 1/1,000 (mg/f.Jg)
Carcinogenic Effects
Utility
Worker
Cancer
Dermal Groundwater (UWCDGW) Factor (Ukg-day)
UWCDGW Factor
Lifetime Average Daily Dose (mg/kg-day)
SA (cm
2
)
x
Kp (em/hour)
x
EF (events/year)
xED
(hours/event)
x
EP (years)
x
(1/1
,000 Ucm
3
)
x (1
year/365 days)
x
(1/BW (kg))
x
(1/AP (years))
EPCgw {f.Jg/L)
x
UWCDGW Factor (Ukg-day)
x
dermal RAF
x
1/1,000 (mg/f.Jg)
(1) Adults, 18 to 65 years of age, were used to represent Potential Future on-site utility workers. These potential receptors
may
be exposed to
contaminants
in
groundwater during underground utility repair and maintenance work
at
the Site.
(2) Average body weight
of
receptor population obtained from U.S. EPA Exposure Factors Handbook, Volume I of II, Office
of
the Health and Environmental Assessment,
Washington, D.C., EPA 600/C-99/001, February 1999.
(3) Frequency
of
exposure describes how often each even t occurs
over
a given period
of
time. It was assumed that workers would be exposed to contaminants
in groundwater while working on underground utilites at the Site 5 days per week
for
1 week,
for
a total of 5 events per year.
(4) The duration of each exposure describes how long each individual exposure event might
last
For dermal exposure to groundwater, exposure duration is
a hours/event. During this event, the utility worker is assumed to dermally contact contaminants in groundwater.
(5) The exposure period describes the length
of
time
over
which the utility worker may contact contaminants
in
groundwater within a trench.
We a.ssume that utility workers will be exposed to contaminants in groundwater while repairing/maintaining underground utilities at the Site so we evaluate a 25 year exposure.
{6) For noncancer risks, the averaging period is set equal to the exposure period. The averaging period is equal to a lifetime (i.e., 70 years) when estimat ing cancer risks.
(7) Skin surface areas are based on U.S. EPA Exposure Factors Handbook, Office
of
the Health and Environmental Assessment, Washington, D.C., EPA 600/C-99/001, February
Fraction exposed assumes head, forearms, and hands exposed based on assumption in DEP Documentation for Risk Assessment Shortform Residential
Scenario- October, 1992.
(8) Skin permeability values were obtained from Dermal Exposure Assessment : Principles and Applicat ions 1 terim Report EPA 600/8-91/011 B.
(9) Refer to Table 5 for contaminant-specific dermal groundwater contact RAFs.
(1
0) Please refer to Section 5.5 for the derivation of exposure point concentrations.
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Appendix
D:
Risk Calculations
Appendix D
Risk Calculations
Table 7 summarizes the risks calculated for tbe Site. Tables D-1 and D-2 provide the calculations
for tbe risk characterization.
Tetra Tech Rizzo
1
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TABLE
D-1
CALCULATION
OF AVERAGE
DAILY
DOSES
AND
RISK ESTIMATES
FOR DERMAL CONTACT
WITH
GROUNDWATER
RECEPTOR:
Constrution Worker
CARCINOGENIC EFFECTS
Exposure
Lifetime
Oral Exc
Point
Dermal Skin Average
Cancer
Life
Contaminant Concentration X Relative
X Permeability X
CWCDGW
=
Daily
X
Slope
=
Can
EPCgw
Absorption
Constant
Factor
Dose
Factor Ri
~ a t L
Factor (Ucm
2
h)
U k g - d a ~ l
{ m g l k g - d a ~ )
{ m g / k g - d a ~ r
Estim
Benzene
1.5
1.00 2.1E-02 2.0E-04 6.2E-09
5.5E-02
3.4E
Butyl Alcohol
2,890.0 1.00
2.8E-03 2.0E-04 1.6E-06
none
N
Butylbenzene, n-
1.3
1.00 2.8E-01 2.0E-04 7.1E-08
none
N
Ethyl
tert-butyl ether
18.0
1.00 4.5E-04 2.0E-04 1.6E-09
none N
lsopropyltoluene, p-
2.7
1.00 1.4E-01 2.0E-04 7.4E-08
none N
Methyl tert-butyl
ether 3,870.0 1.00 3.1E-03 2.0E-04 2.4E-06
none N
Naphthalene 180.0 1.00 6.8E-02 2.0E-04 2.4E-06 none N
Tert-amyl methyl ether (TAME)
33.7
1.00 6.2E-03 2.0E-04 4.1E-08
none
N
Toluene
1.9 1.00 4.5E-02 2.0E-04
1.7E-08
none
N
Trichlorotrifluoroethane
1,1
,2-
(Freon 113)
4.4
1.00 2.4E-02 2.0E-04 2.1E-08
none N
Trimethylbenzene, 1 2.4-
1.6 1.00 1.3E-01 2.0E-04
4.2E-08
none
N
Xylene (total)
6.0
1.00 8.0E-02 2.0E-04 9.4E-08
none N
Acenaphthene
12.4 1.00 1.5E-01 2.0E-04
3.6E-07
none
N
Anthracene
6.4
1.00 2.3E-01 2.0E-04 2.8E-07
none N
Benzo(a)anthracene
0.1
1.10 8.1
E-01
2.0E-04 1.8E-08 7.3E-01 1.3E
Benzo(b)fluoranthene
0.1
1.10
1.2E+OO
2.0E-04 3.2E-08 7.3E-01 2.3E
Fluoranthene
8.9 1.00
3:6E-01 2.0E-04 6.3E-07
none N
Fluorene
12.0
1.00 1.7E-01 2.0E-04 4.1E-07
none N
Methylnaphthalene,
2-
14.8
1.00 1.4E-01 2.0E-04 4.1E-07
none
N
Naphthalene
92.0 1.00
6.9E-02
2.0E-04
1.2E-06
none
N
Phenanthrene 32.9 1.00 2.7E-01 2.0E-04 1.7E-06 none N
Pyrene
6.4
1.00 3.3E-01 2.0E-04 4.1E-07
none
N
Carbazole
16.3
1.00 8.0E-02 2.0E-04 2.6E-07 2.0E-02
Dibenzofuran
12.0
1.00 1.5E-01 2.0E-04 3.6E-07
none
N
Oimethylphenol, 2,4-
12.0
1.00 1.5E-02 2.0E-04 3.5E-08
none
N
Methylphenol, 2-
11.0
1.00 1.0E-02 2.0E-04 2.2E-08
none
N
Methylphenol,
3-
28.0
1.00 1.0E-02 2.0E-04 5.7E-08
none
N
Phenol
8.8
1.00 5.5E-03 2.0E-04 9.5E-09
none
N
Antimony, Total
6.0
1.00 1.0E-03 2.0E-04 1.2E-09
none
N
Arsenic, Total
47.3
1.00 1.0E-03 2.0E-04 9.3E-09
1.5E+OO
1.4E
Barium, Total
892.0
1.00
1.0E-03
2.0E-04
1.8E-07
none
N
Chromium, Total
6.3
1.00 1.0E-03 2.0E-04 1.2E-09
none
N
Manganese, Total
11,500.0 1.00 1.0E-03 2.0E-04 2.3E-06
none
N
Mercury, Total
0.3
1.00 1.0E-03 2.0E-04
5.1E-11
none
N
Nickel, Total
17.0
1.00 1.0E-04 2.0E-04 3.3E-10
none
N
Zinc, Total
99.0 1.00 6.0E-04 2.0E-04 1.2E-08 none N
C11-C22 Aromatics
203.0
1.00 6.8E-01
2.0E-04
2.7E-05
none
N
SUBTOTAL:
S.OE
NA = Not Analyzed/Not Applicable; NC = Not Calculated; NO= Not Determined.
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TABLE D-2
CALCULATION OF AVERAGE DAILY DOSES
AND
RISK ESTIMATES
FOR DERMAL CONTACT
WITH
GROUNDWATER
RECEPTOR: Utlility Worker
SUBCHRONIC NONCARCINOGENIC EFFECTS
Exposure Chronic Oral
Point Dermal Skin Average
Chronic
Haz
Contaminant
Concentration X
Relative
X
Penneability
X
UWNCDGW
=
Daily Reference Ind
EPCgw
Absorption
Constant Factor Dose Dose
~ g i L )
Factor
iUcm
2
( U k g - d a l : ~
{mg/kg-day) (mg/kg-day)
Benzene 1.5 1.00
2.1E-02 1.4E-02 4.3E-07
4.0E-03
1.1E
Butyl Alcohol
2,890.0 1.00
2.8E-03 1.4E-02 1.1 E-04 1.0E-01 1.1E
Butylbenzene, n-
1.3
1.00
2.8E-01
1.4E-02 5.0E-06 1.0E-02 5.0E
Butylbenzene, tert- 1.2 1.00
2.4E-01 1.4E-02 4.0E-06
1.0E-02 4.0E
Ethyl tert-butyl ether
18.0
1.00 4.5E-04 1.4E-02 1.1E-07
none N
lsopropyltoluene, p- 2.7 1.00
1.4E-01
1.4E-02 5.2E-06 none N
Methyl tert-butyl ether 3,870.0 1.00
3.1E-03 1.4E-02 1.7E-04
1.0E-01
1.7E
Naphthalene
180.0
1.00 6.8E-02 1.4E-02 1.7E-04 2.0E-02 8.5E
Tert-amyl methyl ether
(TAME)
33.7 1.00
6.2E-03 1.4E-02 2.9E-06 1.3E-01 2.2E
Toluene 1.9
1.00 4.5E-02 1.4E-02 1.2E-06 2.0E-01 5.9E
Trichlorotrifluoroethane 1,1 ,2-
(Freon 113)
4.4 1.00
2.4E-02 1.4E-02 1.5E-06 3.0E+01 4.8E
Trimethylbenzene, 1 2,4-
1.6
1.00
1.3E-01
1.4E-02 2.9E-06 5.0E-02
5.9E
Xylene (total) 6.0 1.00
8.0E-02 1.4E-02 6.6E-06
2.0E-01
3.3E
AcenaJ)hthene 12.4
1.10 1.5E-01 1.4E-02 2.8E-05 6.0E-02
4.6E
Anthracene 6.4 1.10
2.3E-01 1.4E-02
2.2E-05
3.0E-01 7.3E
Benzo(a)anthracene
0.1
1.00
8.1
E-01
1.4E-02 1.1E-06 3.0E-02 3.7E
Benzo(b)fluoranthene ·
0.1
1.00 1.2E+OO 1.4E-02 2.0E-06 3.0E-02
6.8E
Fluoranthene
8.9
1.10
3.6E-01
1.4E-02
4.8E-05
4.0E-02
1.2E
Fluorene 12.0 1.10
1.7E-01 1.4E-02 3.1E-05 4.0E-02 7.8E
Methylnaphthalene, 2-
14.8 1.00
1.4E-01 1.4E-02 2.9E-05 4.0E-03 7.3E
Naphthalene
92.0
1.00
6.9E-02
1.4E-02 8.7E-05 2.0E-02
4.4E
Phenanthrene
32.9 1.00 2.7E-01 1.4E-02 1.2E-04 3.0E-02 4.1E
Pyrene 6.4 1.10
3.3E-01 1.4E-02 3.2E-05 3.0E-02
1.1E
Carbazole 16.3 1.00
B.OE-02 1.4E-02 1.8E-05
none
N
Dibenzofuran
12.0 1.00
1.5E-01 1.4E-02 2.5E-05 4.0E-03
6.3E
Dimethylphenol, 2,4 -
12.0
1.00
1.5E-02
1.4E-02 2.5E-06 2.0E-02
1.2E
Methylphenol, 2-
11.0 1.00
1.0E-02
1.4E-02
1.5E-06 5.0E-02 3.1E
Methylphenol, 3- 28.0 1.00
1.0E-02 1.4E-02 4.0E-06 5.0E-02
7.9E
Phenol 8.8 1.00
5.5E-03 1.4E-02 6.7E-07 3.0E-01
2.2E
Antimony, Total
6.0 1.00
1.0E-03 1.4E-02 8.3E-08 4.0E-04
2.1E
Arsenic, Total 47.3 1.00
1.0E-03 1.4E-02 6.5E-07 3.0E-04
2.2E
Barium, Total
892.0
1.00
1.0E-03
1.4E-02 1.2E-05
7.0E-02
1.8E
Chromium, Total 6.3 250.00
1.0E-03 1.4E-02 2.2E-05 3.0E-03
7.2E
Manganese, Total
11,500.0 1.00
1.0E-03 1.4E-02 1.6E-04 4.6E-02
3.4E
Mercury, Total
0.3
6.70 1.0E-03 1.4E-02 2.4E-08
3.0E-04
8.0E
Nickel, Total
17.0 10.00
1.0E-04 1.4E-02
2.3E-07
2.0E-02
1.2E
Zinc, Total
99.0 2.20 6.0E-04 1.4E-02 1.8E-06 3.0E-01 6.0E
C11-C22 Aromatics 203.0 1.10
6.8E-01
f4E-02 2.1E-03
3.0E-02
6.9E
SUBTOTAL:
1.2E
Notes:
NA = Not Analyzed/Not Applicable; NC = Not Calculated; NO= Not Determined.
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TABLE D-2
CALCULATION OF AVERAGE
DAILY
DOSES
AND
RISK ESTIMATES
FOR
DERMAL
CONTACT
WITH
GROUNDWATER
RECEPTOR: Utlility Worker
CARCINOGENIC EFFECTS
Exposure
Lifetime Oral Exce
Point
Dermal Skin
Average Cancer
lifeti
Contaminant Concentration
X
Relative
X
Permeability
X
UWCDGW
=
Daily
X
Slope
=
Can
EPCgw
Absorption Constant Factor
Dose
Factor Ris
( ~ g / L }
Factor
{Ucm
2
h)
( U k g - d a ~ )
{ m g / k g - d a ~ }
{ m g / k g - d a ~ r
Estim
Benzene
1.5 1.00
2.1E-02 2.0E-04
6.2E-09 5.5E-02 3.4E
Butyl Alcohol
2,890.0 1.00 2.8E-03 2.0E-04
1.6E-06
none
NC
Butylbenzene, n- 1.3 1.00
2.8E-01 2.0E-04 7.1E-08 none NC
Butylbenzene, tert- 1.2 1.00
2.4E-01 2.0E-04
5.7E-08
none NC
Ethyl
tert-butyl ether
18.0
1.00 4.5E-04
2.0E-04 1.6E-09 none
NC
lsopropyltoluene,
p-
2.7 1.00
1.4E-01 2.0E-04 7.4E-08 none
NC
Methyl tert-butyl ether 3,870.0 1.00
3.1E-03 2.0E-04
2.4E-06
none
NC
Naphthalene
180.0
1.00 6.8E-02
2.0E-04 2.4E-06 none
NC
Tert-amyl methyl ether
(TAME)
33.7 1.00
6.2E-03 2.0E-04
4.1E-08 none
NC
Toluene
1.9
1.00 4.5E-02
2.0E-04 1.7E-08
none
NC
Trichlorotrifluoroethane
1,1 ,2-
(Freon 113) 4.4 1.00
2.4E-02 2.0E-04
2.1E-08 none
NC
Trimethylbenzene, 1 2,4-
1.6 1.00
1.3E-01 2.0E-04 4.2E-08 none
NC
Xylene total) 6.0 1.00
8.0E-02 2.0E-04 9.4E-08
none NC
Acenaphthene
12.4
1.00 1.5E-01
2.0E-04 3.6E-07
none NC
Anthracene 6.4 1.00
2.3E-01 2.0E-04 2.8E-07 none NC
Benzo a)anthracene 0.1 1.10
8.1
E-01
2.0E-04
1.8E-08 7.3E-01 1.3E
Benzo b)fluoranthene
0.1
1.10
1.2E+OO 2.0E-04 3.2E-08 7.3E-01 2.3E
Fluoranthene 8.9 1.00
3.6E-01 2.0E-04 6.3E-07
none NC
Fluorene 12.0 1.00
1.7E-01 2.0E-04
4.1E-07 none
NC
Methylnaphthafene, 2-
14.8
1.00
1.4E-01
2.0E-04
4.1E-07
none NC
Naphthalene 92.0 1.00
6.9E-02 2.0E-04 1.2E-06 none
NC
Phenanthrene 32.9 1.00 2.7E-01 2.0E-04 1.7E-06
none
NC
Pyrene 6.4
1.00 3.3E-01 2.0E-04
4.1E-07
none
NC
Carbazole 16.3 1.00
8.0E-02 2.0E-04 2.6E-07
2.0E-02 5.1E
Dibenzofuran
12.0 1.00
1.5E-01 2.0E-04
3.6E-07
none NC
Dimethylphenol,
2,4-
12.0
1.00 1.5E-02 2.0E-04
3.5E-08 none
NC
Methylphenol, 2- 11.0 1.00
1.0E-02 2.0E-04 2.2E-08
none
NC
Methylphenol, 3- 28.0 1.00
1.0E-02 2.0E-04
5.7E-08
none
NC
Phenol 8.8
1.00 5.5E-03 2.0E-04
9.5E-09
none
NC
Antimony, Total 6.0 1.00
1.0E-03 2.0E-04
1.2E-09
none
NC
Arsenic,
Total
47.3 1.00
1.0E-03 2.0E-04
9.3E-09
1.5E+OO
1.4E
Barium, Total
892.0
1.00
1.0E-03 2.0E-04 1.8E-07
none
NC
Chromium, Total 6.3 1.00
1.0E-03 2.0E-04 1.2E-09
none NC
Manganese,
Total 11,500.0
1.00
1.0E-03 2.0E-04
2.3E-06
none NC
Mercury, Total
0.3
1.00 1.0E-03
2.0E-04 5.1E-11 none
NC
Nickel, Total 17.0 1.00
1.0E-04 2.0E-04 3.3E-10
none
NC
Zinc, Total
99.0 1.00 6.0E-04 2.0E-04 1.2E-08
none
NC
C11-C22
Aromatics 203.0 1.00
6.8E-01 2.0E-04 2.7E-05 none
NC
SUBTOTAL:
5.6E
Notes:
NA =
Not Analyzed/Not Applicable;
NC =
Not
Calculated; ND =
Not
Determined.
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Appendix E
Soil Analytical
Data
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Project Name: Not Specified
Project Number: 12700960
Lab Number:
Report Date:
05180713:48
L0706797
05/18/07
MADEP MCP Response
Action Analytical
Report
Certification
This form provides certifications
for
all samples performed by MCP methods. Please refer
to
the Sample Results
and
Container Information sections of this report for specification of
MCP methods used for each analysis. The
following
questions pertain
only
to MCP
Analytical Methods. ·
An affirmative response to questions A, B, C & 0 is required for "Presumptive Certainty" status
A
YES
'
'
Were all samples received by the laboratory in a condition consistent with those described on
their Chain-of-Custody documentation for hE)data set? ..
--------i
B
c
D
Were all QAIQC procedures required for the specified analytical methods(s) included
in
this
report followed, including the requirement to note and discuss in a narrative QC data that did not
meet appropriate performance standards org.uidelines?
Does the analytical data included in this report meet all the requirements for "Presumptive
Certainty", as described
in
section 2.0 of the MADEP document CAM VII
A,
"Quality Assurance
and Quality Control Guidelines for the Acquisition and Reporting of Analytical Data"?
VPH and EPH methods only: Was the VPH or EPH method run without significant modifications,
as specified in Section 11.3?
YES
YES
YES
A response to questions E and F is required for "Presumptive Certainty" status
~ ~
E Were all QC performance standards and recommendations for the specified method(s)
-----'a"'c..,hieved?
F
Were results for all analyte-list compounds/elements for the specified method(s) reported?
NO
··------j
NO I
_ _ _ _ _ __j
For any questions answered "No", please refer to the case narrative section on the following page(s).
Please note that sample matrix information is located in the Sample Results section
of
this report.
Page 3
of83
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05180713:48
Project Name: Not Specified Lab Number:
Project Number: 12700960 Report Date:
Case Narrative
The samples were received in accordance with the chain
of
custody and no significant deviations were
encountered during preparation or analysis unless otherwise noted below.
MCP Related Narratives
VPH
L0706797 03 and -04 fell short of the recommended 1 1 methanol:soil ratio.
In reference to question F:
L0706797
05/18/07
At the client's request, all submitted samples were not analyzed for the full MCP list of compounds specified for
the Method.
EPH
L0706797-01: The C9-C18 and C19-C36 Aliphatic range results were obtained from re-analysis on dilution
due to the elevated concentrations of these compounds present in the sample.
L0706797-03: The C11-C22 Aromatic range results were obtained from re-analysis on dilution due
to
the
elevated concentrations
of
these compounds present in the sample.
The WG279975-1 method blank was re-fractionated due to a low surrogate recovery on the original analysis.
The results of the re-fractionation are reported.
In
reference
to
question
E:
The surrogate% recovery for o-Terphenyl is above method acceptance criteria on L0706797-01, possibly due
to co-elution. The chromatogram of the sample
is
provided as an attachment.
The surrogate% recoveries for Chloro-Octadecane and o-Terphenyl are below method acceptance criteria
on
L0706797 02. Re-extraction and re-analysis confirmed possible matrix interference. Both analyses are
reported.
The surrogate% recovery for o-Terphenyl is above method acceptance criteria on L0706797-03, possibly due
to co-elution. The chromatogram
of
the sample is provided as an attachment.
The surrogate % recovery for Chloro-Octadecane is below method acceptance criteria on L0706797 -03. Re
extraction and re-analysis confirmed possible matrix interference. Both analyses are reported.
The surrogate% recovery for Chloro-Octadecane is below method acceptance criteria on L0706797-04. Re
extraction and re-analysis confirmed possible matrix interference. Both analyses are reported.
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Project Name:
Project Number:
Not Specified
12700960
Case Narrative (continued)
Lab Number:
Report Date:
05180713:48
L0706797
05/18/07
L0706797 03 has an elevated detection limit due to the dilution required by the elevated concentrations
of
target compounds in the sample.
The surrogate % recovery is above method acceptance criteria on L0706797 03, possibly due to co-elution
with sample matrix.
I, the undersigned, attest under the pains and penalties of perjury that, to the best of my knowledge and
belief and based upon my personal inquiry of those responsible for providing the information contained
in this analytical report, such information is accurate and complete. This certificate
of
analysis is not
complete unless this page accompanies any and all pages
of
this report.
Authorized Signature:
Title: Technical Director Date: 05/18/07
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05180713:48
ORGANICS
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Page 8 of 83
PETROLEUM
HYDROCARBONS
05180713:48
··&?nA
w f > . ~ h . , • • . «
, . . ,
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Project Name:
Not Specified
Project Number:
12700960
Lab ID: L0706797-01
Client ID: RIZ-1 (5'-7')
Sample Location: BEVERLY,
MA
Matrix:
Soil
Anaytical Method: 1,8015B(M)
Analytical Date: 05/14/07 18:35
Analyst:
RT
Percent Solids:
90%
TPH
Surrogate
o-Terphenyl
Page 9 of
83
SAMPLE RESULTS
NO
Lab Number:
Report Date:
Date Collected:
Date Received:
Field Prep:
05180713:48
L0706797
05/18/07
05/09/07 08:30
05/10/07
Extraction Method:
Not Specified
EPA3545
05/11/07 20:30xtraction Date:
ug/kg
37000
Acceptance
%Recovery Qualifier Criteria
72 40-140
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Project Name:
Not Specified
Project Number:
12700960
LabiD:
L0706797 02
Client
ID:
RIZ-2 (5'-7')
Sample Location:
BEVERLY, MA
Matrix:
Soil
Anaytical Method:
1 8015B(M)
Analytical Date:
05/17/07 02:04
Analyst:
MF
Percent Solids: 80%
TPH
Surrogate
o-Terphenyl
Page 10
of
83
Lab Number:
Report Date:
SAMPLE RESULTS
Date Collected:
Date Received:
Field Prep:
05180713:48
L0706797
05/18/07
05/09/07 10:50
05/10/07
Extraction Method:
Not Specified
EPA 3540C
05/11/07 22:20
xtraction Date:
1260000
ug/kg
208000
5
Acceptance
%Recovery
Qualifier Criteria
100
40-140
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Project Name:
Not Specified
Project Number:
12700960
Lab ID: L0706797-03
Client ID: RIZ-3 ( 10'-12')
Sample Location: BEVERLY, MA
Matrix:
Soil
Anaytical Method: 1,8015B(M)
Analytical Date: 05/17/07 12:53
Analyst:
MF
Percent Solids:
73%
TPH
Surrogate
o-Terphenyl
Page 11 of 83
Lab Number:
Report Date:
SAMPLE
RESULTS
Date Collected:
Date Received:
Field Prep:
05180713:48
L0706797
05/18/07
05/09/07 13:00
05/10/07
Extraction Method:
Not Specified
EPA3540C
05/11/07 22:20
xtraction Date:
8490000
ug/kg
1140000
25
Acceptance
%Recovery
Qualifier Criteria
186
40-140
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Project Name:
Not Specified
Project
Number:
12700960
Lab ID:
L0706797-04
Client
ID:
RIZ-4 (5'-7')
Sample Location: BEVERLY, MA
Matrix:
Soil
Anaytical Method: 1 8015B(M)
Analytical Date: 05/17/07 04:12
Analyst:
MF
Percent Solids:
77%
TPH
Surrogate
o-
Terphenyl
Page 12
of
83
SAMPLE
RESULTS
138000
Lab
Number:
Report Date:
Date Collected:
Date Received:
Field Prep:
05180713:48
L0706797
05/18/07
05/09/07 14:45
05/10/07
Extraction Method:
Not Specified
EPA3540C
05/11/07 22:20xtraction Date:
ug/kg 43300
Acceptance
%Recovery Qualifier Criteria
72
40-140
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Project
Name:
Project Number:
Analytical Method:
Analytical Date:
Analyst:
TPH
Not Specified
12700960
1 8015B(M)
05/16/0714:12
MF
Surrogate
o-Terphenyt
Page 14 of 83
Method Blank.
Analysis
Batch Quality Control
NO
ug/kg
Lab Number:
Report
Date:
05180713:48
L0706797
05/18/07
Extraction Method: EPA 3540C
Extraction Date: 05/11/07 22:20
33300
Acceptance
%Recovery Qualifier Criteria
90
40-140
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Project Name:
Not Specified
Project Number: 12700960
Parameter
TPH
Surrogate
oMTerphenyl
TPH
Surrogate
o-Terphenyl
Page
15
of
83
LCS
Lab
Control
Sample
Analysis
Batch Quality Control
LCSD
%Recovery %Recovery
%Recovery
Limits
40-140
LCS LCSD
%Recovery Qualifier %Recovery Qualifier
61
40-140
LCS LCSD
%Recovery Qualifier %Recovery Qualifier
101
Lab
Repo
RP
Acceptance
Criteria
40-140
Acceptance
Criteria
40-140
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Pro ject Name: Not Specified
Project Number: 12700960
Parameter
Lab Duplicate Analysis
Batch Quality Control
Native Sample Duplicate Sample Units
Acceptance
Surro late %Recoverv Qualifier %Recoverv Qualifier Criteria
o-Terphenyl 79 78
40-140
Acceptance
Surro late %Recoverv Qualifier %Recoverv
_
Qualifier Criteria
o-Terphenyl 96
89
40-140
Page
16
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RP
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Project
Name:
Not Specified
Project Number: 12700960
Lab ID:
Client 10:
Sample Location:
L0706797-01
RIZ-1
(5'-7')
BEVERLY, MA
Soil
59,VPH-04-1.1
05/11/07 16:26
n
Matrix:
Anaylical Method:
Analytical Date:
Analyst:
Percent Solids:
90%
Condition of sample received:
Sample Temperature upon receipt:
Were samples received in methanol?
Methanol ratio:
Parameter
C5-C8 Aliphatics, Unadjusted
C9-C12 Aliphatics, Unadjusted
C9-C10 Aromatics
C5-C8 Aliphatics, Adjusted
C9-C12 Aliphatics, Adjusted
Surrogate
2,5-Dibromotoluene-PID
2,5-Dibromotoluene-FID
Page 17
of
83
SAMPLE RESULTS
Result
Qualifier
ND
ND
ND
ND
ND
%Recovery
Qualifier
----------
100
110
Units
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
Lab Number:
Report Date:
Date Collected:
Date Received:
Field Prep:
05180713:48
L0706797
05/18/07
05/09/07 08:30
05/10/07
Not Specified
Satisfactory
Received on Ice
Yes (Covering the Soil)
1:1 +/- 25%
RDL Dilution Factor
3.50
3.50
3.50
3.50
3.50
Acceptance
Criteria
70-130
70-130
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Project
Name: Not Specified
Project Number: 12700960
Lab ID:
Client ID:
Sample Location:
L0706797-01
RIZ-1 (5'-7')
BEVERLY, MA
Soil
61,EPH-04-1
05/14/07 23:11
BN
Matrix:
Anaytical Method:
Analytical Date:
Analyst:
Percent Solids:
90%
Condition
of
sample received:
Sample Temperature upon receipt:
Sample Extraction method:
Parameter
C11-C22 Aromatics, Unadjusted
C11-C22 Aromatics, Adjusted
Page
18
of83
Surrogate
Chloro-Octadecane
o-Terphenyl
2-Fiuorobiphenyl
2-Bromonaphthalene
SAMPLE RESULTS
Result
2320
2290
mg/kg
mg/kg
Lab Number:
Report
Date:
Date Collected:
Date Received:
Field Prep:
Extraction Method:
Extraction Date:
05180713:48
L0706797
05/18/07
05/09/07 08:30
05/10/07
Not Specified
EPA 3545
05/11/07 09:00
Satisfactory
7.41
7.41
Received on Ice
Extracted Per the Method
Acceptance
%Recovery
Qualifier Criteria
67
141
127
70
40-140
40-140
40-140
40-140
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Project Name: Not Specified
Project
Number: 12700960
Lab ID:
Client ID:
Sample Location:
Matrix:
Anaytical Method:
Analytical Date:
Analyst:
Percent Solids:
L0706797-01 R
RIZ-1 (5'-7')
BEVERLY, MA
Soil
61
,EPH-04-1
05/16/07 00:33
BN
90%
Condition of sample received:
Sample Temperature upon receipt
Sample Extraction method:
C9-C18 Aliphatics
C19-C36 Aliphatics
Page 19 of 83
SAMPLE RESULTS
3160
750
mg/kg
mglkg
Lab Number:
Report
Date:
Date Collected:
Date
Received:
Field Prep:
Extraction Method:
Extraction Date:
05180713:48
L0706797
05/18/07
05/09/07 08:30
05/10/07
Not Specified
EPA 3545
05/11/07 09:00
Satisfactory
37.0
37.0
Received on Ice
Extracted Per the Method
5
5
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Project
Name:
Not
Specified
Project Number: 12700960
Lab 10:
Client ID:
Sample
Location:
L0706797-02
RIZ-2 (5'-7')
BEVERLY,
MA
Soil
59,VPH-04-1.1
05/11/0717:18
TT
Matrix:
Anaytical Method:
Analytical Date:
Analyst:
Percent Solids:
80%
Condition of sample received:
Sample Temperature upon receipt:
Were samples received in methanol?
Methanol ratio:
Parameter
CS-CB Aliphatics, Unadjusted
C9-C12 Aliphatics, Unadjusted
C9-C10 Aromatics
C5-C8 Aliphatics, Adjusted
C9-C12 Aliphatics, Adjusted
Surrogate
2,5-Dibromotoluene-PID
2,5-0ibromotoluene-FID
Page 20 of83
SAMPLE
RESULTS
Result Qualifier
ND
ND
ND
ND
ND
%Recovery
Qualifier
105
115
Lab Number:
Report
Date:
Date Collected:
Date Received:
Field Prep:
05180713:48
L0706797
05/18/07
05/09/07 10:50
05/10/07
Not
Specified
Satisfactory
Received
on
Ice
Yes (Covering the Soil)
1:1 +/- 25%
Units
RDL
Dilution
Factor
mg/kg 4.15
mg/kg 4.15
mg/kg 4.15
mg/kg 4.15
mg/kg
4.15
Acceptance
Criteria
-- -
-----
70-130
70-130
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Project
Name:
Not
Specified
Project Number: 12700960
Lab ID:
L0706797 02
ClientiD:
RIZ-2 (5'-7')
Sample Location:
BEVERLY,
MA
Matrix:
Soil
Anaytical Method: 61,EPH-04-1
Analytical Date: 05/14/07
23:44
Analyst: BN
Percent Solids:
80%
Condition of sample received:
Sample Temperature upon receipt:
Sample Extraction method:
Parameter
C9-C18 Aliphatics
C1 9-C36 Aliphatics
C11-C22 Aromatics, Unadjusted
C11-C22 Aromatics, Adjusted
Page 21
of 83
Surrogate
Chloro-Octadecane
o-Terphenyl
2-Fiuorobiphenyl
2-Bromonaphthalene
SAMPLE
RESULTS
Result Qualifier
8.99
114
85.6
82.1
%Recovery
Qualifier
23
37
92
91
Units
mg/kg
mg/kg
mg/kg
mg/kg
Lab Number:
Report Date:
Date Collected:
Date Received:
Field Prep:
05180713:48
L0706797
05/18/07
05/09/07 10:50
05/10/07
Extraction Method:
Not Specified
EPA 3545
05/11/07 09:00xtraction Date:
Satisfactory
Received on Ice
Extracted Per the Method
RDL Dilution Factor
8.33
8.33
8.33
8.33
Acceptance
Criteria
4 0 ~ 1 4 0
40-140
40-140
40-140
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Project
Name:
Not Specified
Project Number:
12700960
Lab ID:
Client ID:
Sample Location:
L0706797 -02
RE
RIZ-2 (5'-7')
BEVERLY, MA
Soilatrix:
Anaytical Method: 61,EPH-04-1
05/17/07 04:50
BN
Analytical Date:
Analyst:
Percent Solids:
80%
Condition of sample received:
Sample Temperature upon receipt:
Sample Extraction method:
Parameter
C9-C18 Aliphatics
C19-C36 Aliphatics
C11-C22 Aromatics, Unadjusted
C11-C22 Aromatics, Adjusted
Page 22
of83
Surrogate
Chloro-Octadecane
o-Terphenyl
2-Fiuorobiphenyl
2-Bromonaphthalene
SAMPLE
RESULTS
Result Qualifier
9.83
132
125
108
%Recovery
Qualifier
36
62
71
74
Units
mg/kg
mglkg
mg/kg
mglkg
Lab Number:
Report
Date:
Date Collected:
Date Received:
Field Prep:
05180713:48
L0706797
05/18/07
05/09/07 10:50
05/10/07
Extraction Method:
Not Specified
EPA 3545
05/16/07 12:30xtraction Date:
Satisfactory
Received on Ice
Extracted Per the Method
RDL
Dilution Factor
8.33
8.33
8.33
8.33
Acceptance
Criteria
4 0 ~ 1 4 0
40-140
40-140
40-140
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Project Name:
Not
Specified
Project
Number:
12700960
Lab ID:
Client ID:
Sample Location:
L0706797-03
RIZ-3 (10'-12')
BEVERLY,MA
Soil
59,VPH-04-1.1
05/11/07 18:09
TT
Matrix:
Anaytical Method:
Analytical Date:
Analyst:
Percent Solids:
73%
Condition
of
sample received:
Sample Temperature upon
receipt
Were samples received in methanol?
Methanol ratio:
Parameter
C5-CB Aliphatics, Unadjusted
C9-C12 Aliphatics, Unadjusted
C9-C10 Aromatics
C5-C8 Aliphatics, Adjusted
C9-C12 Aliphatics, Adjusted
Surrogate
2,5-Dibromotoluene-PID
2,5-Dibromotoluene-FID
Page 23 of83
SAMPLE
RESULTS
Result
Qualifier
ND
ND
ND
ND
ND
%Recovery Qualifier
90
100
Units
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
Lab Number:
Report
Date:
Date Collected:
Date Received:
Field Prep:
05180713:48
L0706797
05/18/07
05/09/07 13:00
05/10/07
Not Specified
Satisfactory
Received on Ice
Yes (Covering the Soil)
1.5:1
RDL Dilution Factor
6.52
6.52
6.52
6.52
6.52
Acceptance
Criteria
70-130
70-130
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Project Name:
Not Specified
Project Number: 12700960
Lab ID:
Client ID:
Sample
Location:
L0706797
03
RIZ-3 (10'-12')
BEVERLY,
MA
Soil
61,EPH-04-1
05/14/07 22:37
Matrix:
Anaytical Method:
Analytical Date:
Analyst: BN
Percent Solids:
73%
Condition
of
sample received:
Sample Temperature upon receipt:
Sample Extraction method:
Parameter
C9-C18 Aliphatics
C19-C36 Aliphatics
Page 24 of83
Surrogate
Chloro-Octadecane
o-Terphenyl
2-Fluorobiphenyl
2-Bromonaphthalene
SAMPLE RESULTS
Result
Qualifier
ND
26.6
Recovery
Qualifier
23
340
85
89
Units
mg/kg
mg/kg
Lab Number:
Report Date:
Date
Collected:
Date
Received:
Field Prep:
05180713:48
L0706797
05/18/07
05/09/07 13:00
05/10/07
Extraction Method:
Not Specified
EPA 3545
05/11/07
09:00
xtraction Date:
Satisfactory
Received on lee
Extracted Per the Method
RDL
Dilution Factor
9.13
9.13
Acceptance
Criteria
40M140
40-140
40-140
40-140
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Project
Name:
Not Specified
Project
Number:
12700960
Lab ID:
Client ID:
Sample Location:
Matrix:
Anaylical Method:
Analytical Date:
Analyst:
Percent Solids:
L0706797 -03 RE
RIZ-3 (10'-12')
BEVERLY, MA
Soil
61
,EPH-04-1
05/17/07 05:23
BN
73%
Condition of sample received:
Sample Temperature upon receipt:
Sample Extraction method:
Parameter
C9-C18 Aliphatics
C19-C36 Aliphatics
Surrogate
SAMPLE RESULTS
Result
Qualifier
ND
14.5
%Recovery
Qualifier
Page
25 of 83
Chloro-Octadecane
o-Terphenyl
2-Fiuorobiphenyl
2-Bromonaphthalene
7
110
66
73
Units
mglkg
mg/kg
Lab Number:
Report
Date:
Date Collected:
Date Received:
Field Prep:
05180713:48
L0706797
05/18/07
05/09/07 13:00
05/10/07
Extraction Method:
Not Specified
EPA 3545
05/16/07 12:30
xtraction Date:
Satisfactory
Received on Ice
Extracted Per the
Method
RDL
Dilution Factor
9.13
9.13
Acceptance
Criteria
40-140
40-140
40-140
40-140
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Project Name:
Not Specified
Project Number: 12700960
Lab ID:
Client ID:
Sample Location:
Matrix:
Anaytical Method:
Analytical Date:
Analyst:
Percent Solids:
L0706797
03
R
RIZ-3 (10'-12')
BEVERLY,
MA
Soil
61
,EPH-04-1
05/15/07
22:54
BN
73%
Condition of sample received:
Sample Temperature upon receipt:
Sample Extraction method:
C11wC22 Aromatics, Unadjusted
C11-C22 Aromatics, Adjusted
Page
27
of
83
SAMPLE RESULTS
1420
775
mgfkg
mgfkg
Lab Number:
Report Date:
Date
Collected:
Date
Received:
Field Prep:
Extraction Method:
Extraction Date:
05180713:48
L0706797
05/18/07
05/09/07 13:00
05/10/07
Not Specified
EPA
3545
05/11/07
09:00
Satisfactory
91.3
91.3
Received on Ice
Extracted Per the Method
10
10
8/11/2019 Brimbal Ave. - Environmental Notification Form - 9.2.14 - Volume 2 of 2
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Project Name: Not Specified
Project
Number:
12700960
Lab 10:
Client ID:
Sample Location:
L0706797 04
RIZ-4 (5'-7')
BEVERLY, MA
Soil
59,VPH-04-1.1
05/11/07 19:01
n
Matrix:
Anaytical Method:
Analytical Date:
Analyst:
Percent Solids:
77%
Condition
of
sample received:
Sample Temperature upon receipt:
Were samples received in methanol?
Methanol ratio:
Parameter
C5-C8 Aliphatics, Unadjusted
C9-C12 Aliphatics, Unadjusted
C9-C10 Aromatics
C5-C8 Aliphatics, Adjusted
C9-C12 Aliphatics, Adjusted
Page
28 of 83
Surrogate
2,5-Dibromotoluene-PID
2,5-Dibromotoluene-FID
SAMPLE
RESULTS
Result
NO
36.6
18.2
NO
17.5
Units
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
Lab Number:
Report Date:
Date Collected:
Date Received:
Field Prep:
05180713:48
L0706797
05/18/07
05/09/07 14:45
05/10/07
Not Specified
Satisfactory
Received on Ice
Yes (Covering the Soil)
1.6:1
RDL Dilution Factor
6.33
6.33
6.33
6.33
6.33
Acceptance
%Recovery
Qualifier Criteria
102
109
70-130
70-130
8/11/2019 Brimbal Ave. - Environmental Notification Form - 9.2.14 - Volume 2 of 2
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Project
Name:
Not Specified
Project
Number: 12700960
Lab ID: L0706797-04
Client ID:
RIZ-4 (5'-7')
Sample Location: BEVERLY,
MA
Matrix: Soil
Anaytical Method: 61,EPH-04-1
Analytical Date: 05/14/07 21:31
Analyst: BN
Percent Solids:
77%
Condition
of
sample received:
Sample Temperature upon receipt:
Sample Extraction method:
C9-C18 Aliphatics
C19-C36 Aliphatics
C11-C22 Aromatics, Unadjusted
C11-C22 Aromatics, Adjusted
Page 29
of83
Surrogate
Chloro-Octadecane
o-Terphenyl
2-Fiuorobiphenyl
2-Bromonaphthalene
SAMPLE RESULTS
Result
Qualifier
10.4
28.5
35.2
29.7
Recovery Qualifier
29
50
78
77
Units
mg/kg
mg/kg
mg/kg
mg/kg
Lab
Number:
Report
Date:
Date Collected:
Date Received:
Field Prep:
05180713:48
L0706797
05/18/07
05/09/07 14:45
05/10/07
Extraction Method:
Not Specified
EPA3545
05/11/07 09:00xtraction Date:
Satisfactory
Received on Ice
Extracted Per the Method
RDL Dilution Factor
8.66
8.66
8.66
8.66
Acceptance
Criteria
40-140
40-140
40-140
40-140
8/11/2019 Brimbal Ave. - Environmental Notification Form - 9.2.14 - Volume 2 of 2
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Project Name:
Not Specified
Project Number:
12700960
Lab ID: L0706797 -04 RE
Client ID:
RIZ-4 (5'-7')
Sample Location: BEVERLY, MA
Matrix: Soil
Anaytical Method:
61,EPH-04-1
Analytical Date: 05/17/07 04:16
Analyst: BN
Percent Solids: 77%
Condition
of
sample received:
Sample Temperature upon receipt:
Sample Extraction method:
Parameter
C9-C18 Aliphatics
C19-C36 Aliphatics
C11-C22 Aromatics, Unadjusted
C11-C22 Aromatics, Adjusted
Page 30
of
83
Surrogate
Chloro-Octadecane
o-Terphenyl
2-Fiuorobiphenyl
2-Bromonaphthalene
SAMPLE
RESULTS
Result
Qualifier
NO
29.1
31.1
25.5
%Recovery
Qualifier
25
36
75
73
Units
mglkg
mg/kg
mg/kg
mglkg
05180713:48
Lab Number: L0706797
Report
Date: 05/18/07
Date Collected: 05/09/07 14:45
Date Received: 05/10/07
Field Prep: Not Specified
Extraction Method: EPA 3545
Extraction Date: 05/16/07 12:30
Satisfactory
Received on Ice
Extracted Per the
Method
RDL
Dilution
Factor
8.66
8.66
8.66
8.66
Acceptance
Criteria
40-140
40-140
40-140
40-140
8/11/2019 Brimbal Ave. - Environmental Notification Form - 9.2.14 - Volume 2 of 2
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Project Name: Not Specified
Project Number: 12700960
Analytical Method: 59,VPH-04-1.1
05/11/07 07:29
TT
Analytical Date:
Analyst:
Page
31
of 83
C 5 ~ C 8
Aliphatics, Unadjusted
C9·C12 Aliphatics, Unadjusted
C9-C10 Aromatics
C5-C8 Aliphatics, Adjusted
C9-C12 Aliphatics, Adjusted
Surrogate
2,5-0ibromotoluene-PID
2,5-Dibromotoluene-FID
Method Blank Analysis
Batch Quality Control
NO
mg/kg
NO
mg/kg
NO
mg/kg
NO
mg/kg
NO
mg/kg
Lab Number:
Report Date:
2.67
2.67
2.67
2.67
2.67
Acceptance
%Recovery
Qualifier
Criteria
79
85
70-130
70-130
05180713:48
L0706797
05/18/07
8/11/2019 Brimbal Ave. - Environmental Notification Form - 9.2.14 - Volume 2 of 2
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Project Name: Not Specified
Project Number: 12700960
Analytical Method:
61
,EPH-04-1
05/14/07 08:54
BN
Analytical Date:
Analyst:
Page 32 of 83
C 9 ~ C 1 8 Aliphatics
C19·C36 Aliphatics
C11-C22 Aromatics, Unadjusted
C11-C22 Aromatics, Adjusted
Surrogate
Chloro-Octadecane
o-Terphenyl
2-Fiuorobiphenyl
2-Bromonaphthalene
Method
Blank
Analysis
Batch Quality Control
NO
NO
NO
NO
mg/kg
mg/kg
mg/kg
mg/kg
Lab Number:
Report Date:
05180713:48
L0706797
05/18/07
Extraction Method: EPA 3545
Extraction Date: 05/11/07 03:00
6.67
6.67
6.67
6.67
Acceptance
%Recovery
Qualifier
Criteria
43
40-140
41 40-140
63
40-140
61
40-140
8/11/2019 Brimbal Ave. - Environmental Notification Form - 9.2.14 - Volume 2 of 2
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Project Name:
Not Specified
Project Number: 12700960
Parameter
C5·C8 Aliphatics
C9-C12 Aliphatics
C9-C10 Aromatics
Benzene
Toluerie
Ethylbenzene
p/m-Xylene
a-Xylene
Methyl tert butyl ether
Naphthalene
1 2,4-Trimethylbenzene
Pentane
2-Methylpentane
2,2,4-Trimethylpentane
n-Nonane
n-Decane
n-Butylcyclohexane
Page
33
of
83
LCS
Lab Control Sample
Analysis
Batch Quality Control
LCSD
%Recovery %Recovery
%Recovery
Limits
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
30-130
70-130
)[;; : m ~ m n 1 t s : a ; m m i ~ i i w :
:;rmm
H m : ~ o ; : t ; m m t m : ; : w ' 70-130
Lab
Repo
RP
8/11/2019 Brimbal Ave. - Environmental Notification Form - 9.2.14 - Volume 2 of 2
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Project Name: Not Specified
Project Number: 12700960
Parameter
Surrogate
2,5-Dibromotoluene-P D
2,5-Dibromotoluene-FID
C9-C18 Aliphatics
C19-C36 A iphatics
C11-C22 Aromatics
Naphthalene
2-Methylnaphthalene
Acenaphthylene
Acenaphthene
Fluorene
Phenanthrene
Page 34 of 83
LCS
Lab Control Sample
Analysis
Batch Quality Control
LCSD
%Recovery %Recovery
%Recovery
Limits
LCS LCSD
%Recovery Qualif ier %Recovery Qualifier
98 99
106 107
40-140
40-140
40-140
40-140
40-140
40-140
40-140
40-140
40-140
Lab
Repo
RP
Acceptance
Criteria
70-130
70-130
8/11/2019 Brimbal Ave. - Environmental Notification Form - 9.2.14 - Volume 2 of 2
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Project Name:
Not Specified
Project Number: 12700960
Parameter
Anthracene
Fluoranthene
Pyrene
Benzo(a)anthracene
Chrysene
Benzo(b )fluoranthene
Benzo(k)fluoranthene
Benzo(a)pyrene
lndeno(1 ,2,3-cd)Pyrene
Dibenzo(a,h)anthracene
Benzo(ghi)perylene
Nonane (C9)
Decane (C10)
Dodecane (C12)
Tetradecane (C14)
Hexadecane (C16)
Octadecane (C18)
Nonadecane (C19)
Eicosane (C20)
Docosane (C22)
Tetracosane (C24)
Page 35 of 83
LCS
Lab Control Sample
Analysis
Batch Quality Control
LCSD
%Recovery %Recovery
%Recovery
Limits
40-140
40-140
40-140
40-140
40-140
40-140
40-140
40-140
40-140
40-140
40-140
30-140
40-140
40-140
40-140
40-140
40-140
40-140
40-140
40-140
40-140
Lab
Repo
RP
8/11/2019 Brimbal Ave. - Environmental Notification Form - 9.2.14 - Volume 2 of 2
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Pro ject Name: Not Specified
Project Number: 12700960
LCS
Lab Control Sample Analysis
Batch Quality Control
LCSD
Parameter
%Recovery %Recovery
%Recovery
Limits
Hexacosane (C26)
Octacosane (C28)
Triacontane (C30)
Hexatriaconlane (C36)
Page
36
of
83
Surrogate
Chloro-Octadecane
o-Terphenyl
2-Fiuorobiphenyl
2-Bromonaphthalene
% Naphthalene Breakthrough
% 2-Methylnaphthalene Breakthrough
LCS
%Recovery Qualifier
58
73
81
82
0
0
LCSD
40-140
40-140
40-140
40-140
%Recovery Qualifier
57
73
70
71
0
0
Lab N
Repo
RP
Acceptance
Criteria
40-140
40-140
40-140
40-140
8/11/2019 Brimbal Ave. - Environmental Notification Form - 9.2.14 - Volume 2 of 2
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Project Name: Not Specified
12700960roject Number:
Parameter
C9-C18 Aliphatics
C19-C36 Aliphatics
C11-C22 Aromatics
N"aphthalene
2-Methylnaphthalene
Acenaphthylene
Acenaphthene
Fluorene
Phenanthrene
Anthracene
Fluoranthene
Pyrene
Benzo(a)anthracene
Chrysene
Benzo(b)fluoranthene
Benzo(k)fluoranthene
Benzo(a)pyrene
1 deno( 1,2,3-cd)Pyrene
Dibenzo(a,h)anthracene
Benzo(g,h,i)perylene
Nonane
Decane
Dodecane
Tetradecane
Hexadecane
Octadecane
Nonadecane
Eicosane
Docosane
Tetracosane
Hexacosane
Octacosane
Triacontane
Hexatriacontane
Page 37 of 83
Fractionation Check Standard
Quality Control
Recovery
78
82
101
91
90
96
94
95
99
104
102
103
102
102
93
103
96
88
95
95
65
70
73
74
75
76
78
79
84
86
86
84
83
86
Lab Number:
Report Date:
QC Criteria
40-140
40-140
40-140
40-140
40-140
40-140
40-140
40-140
40-140
40-140
40-140
40-140
40-140
40-140
40-140
40-140
40-140
40-140
40-140
40-140
30-140
40-140
40-140
40-140
40-140
40-140
40-140
40-140
40-140
40-140
40-140
40-140
40-140
40-140
05180713:48
L0706797
05/18/07
8/11/2019 Brimbal Ave. - Environmental Notification Form - 9.2.14 - Volume 2 of 2
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Project Name: Not Specified
Project Number: 12700960
Surrogate
Chloro-Octadecane
o-Terphenyl
2-Fiuorobiphenyl
2-Bromonaphthalene
Page 38 of 83
Fractionation Check
Standard
Quality Control
%Recovery QC Criteria
74 40-140
95
40-140
90
40-140
97 40-140
Lab Number:
Report Date:
05180713:48
L0706797
05/18/07
8/11/2019 Brimbal Ave. - Environmental Notification Form - 9.2.14 - Volume 2 of 2
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05180713:48
PCBS
Page 39
of83
8/11/2019 Brimbal Ave. - Environmental Notification Form - 9.2.14 - Volume 2 of 2
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05180713:48
Project Name:
Not Specified
Lab Number: L0706797
Project
Number: 12700960
Report Date:
05/18/07
SAMPLE
RESULTS
Lab ID: L0706797 01 Date Collected:
05/09/07 08:30
Client ID: RIZ-1 (5'-7')
Date Received:
05/10/07
Sample Location: BEVERLY, MA Field Prep:
Not Specified
Matrix: Soil Extraction Method:
EPA3540C
Anaytical Method:
64,8082 Extraction Date:
05/14/07 20:50
Analytical Date: 05/16/07 11 :33 Cleanup
Method :
EPA3665A
Analyst:
ss
Cleanup Date1:
05/16/07
Percent Solids:
90%
Aroclor 1016
NO
ug/kg
37.0
Aroclor 1221
NO
ug/kg
37.0
Aroclor 1232
NO
ug/kg
37.0
Aroclor 1242
NO
ug/kg 37.0
Aroclor 1248
NO
ug/kg
37.0
Aroclor 1254 NO ug/kg 37.0
Aroclor 1260
NO ug/kg 37.0
Aroclor 1262 NO ug/kg 37.0
Aroclor 1268
NO ug/kg 37.0
Acceptance
Surrogate
%Recovery
Qualifier
Criteria
Column
2,4 5,6-Tetrachloro-m-xylene 101 30-150
A
Oecachlorobiphenyl
97 30-150
A
2,4,5,6-Tetrachloro-m-xylene
87
30-150
B
Decachlorobiphenyl
99 30-150
B
Page 40 of83
8/11/2019 Brimbal Ave. - Environmental Notification Form - 9.2.14 - Volume 2 of 2
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Project Name:
Project
Number:
Lab
ID:
Client ID:
Sample Location:
Matrix:
Anaytical Method:
Analytical Date:
Analyst:
Percent Solids:
Aroclor 1254
Aroclor 1260
Not Specified
12700960
L0706797-02
RIZ-2 (5'-7')
BEVERLY,MA
Soil
64,8082
05/16/07
12:01
ss
80%
Surrogate
Page
41 of 83
2,4,5,6-Tetrachloro-m-xylene
Decachlorobiphenyl
2,4,5,6-Tetrachloro-m-xylene
Decachlorobiphenyl
SAMPLE
RESULTS
165
119
%Recovery
Qualifier
81
126
63
138
05180713:48
Lab Number:
L0706797
Report
Date: 05/18/07
Date Collected:
05/09/07 10:50
Date Received:
05/10/07
Field Prep:
Not Specified
Extraction Method:
EPA
3540C
Extraction Date:
05/14/07 20:50
Cleanup Method1:
EPA3665A
Cleanup Date1:
05/16/07
ug/kg
41.7
ug/kg
41.7
Acceptance
Criteria
Column
30-150
A
30-150
A
30-150
B
30-150
B
8/11/2019 Brimbal Ave. - Environmental Notification Form - 9.2.14 - Volume 2 of 2
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Project
Name:
Not Specified
Project Number:
12700960
SAMPLE
RESULTS
Lab ID:
L0706797 -02
Client ID:
RIZ-2 (5'-7')
Sample Location:
BEVERLY, MA
Matrix:
Soil
Anaytical Method:
64,8082
Analytical Date: 05/16/07
12:01
Analyst: ss
Percent Solids: 80%
Aroclor 1016
ND
Aroclor 1221
ND
Aroclor 1232
ND
Aroclor 1242
ND
Aroclor 1248
ND
Aroclor 1262
ND
Aroclor 12-68
ND
Surrogate
%Recovery
Qualifier
· ·
2,4,5,6-Tetrachloro-m-xylene 81
Decachlorobiphenyl 126
2,4,5,6-Tetrachloro-m-xylene 63
Decachlorobiphenyl
138
Page 42 of83
Lab
Number:
Report
Date:
Date Collected:
Date Received:
Field Prep:
05180713:48
L0706797
05/18/07
05/09/07 10:50
05/10/07
Not Specified
Extraction Method:
EPA3540C
Extraction Date: 05/14/07 20:50
Cleanup Method1: EPA3665A
Cleanup Date1:
05/16/07
ug/kg
41.7
ug/kg 41.7
ug/kg
41.7
ug/kg
41.7
ug/kg
41.7
ug/kg
41.7
ug/kg
41.7
Acceptance
Criteria
Column
30-150 A
30-150 A
30-150
8
30-150
8
8/11/2019 Brimbal Ave. - Environmental Notification Form - 9.2.14 - Volume 2 of 2
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Project Name:
Not Specified
Project
Number:
12700960
SAMPLE RESULTS
Lab ID:
L0706797 03
Client ID:
RIZ-3 (10'-12')
Sample Location:
BEVERLY,MA
Matrix: Soil
Anaytical Method: 64,8082
Analytical Date: 05/16/07 12:30
Analyst: ss
Percent Solids: 73%
Aroclor 1016
ND
Aroclor
1221 ND
Aroclor 1232
ND
Aroctor 1242
ND
Aroclor 1248
ND
Aroclor 1254
ND
Aroclor 1260
ND
Aroclor 1262
ND
Aroclbr 1268
ND
Surrogate
%Recovery
Qualifier
2,4,5,6-Tetrachloro-m-xylene
118
Decachlorobiphenyl 90
2,4,5,6-Tetrachloro-m-xylene 77
Decachlorobiphenyl
104
Page
43 of83
Lab Number:
Report Date:
Date Collected:
Date Received:
Field Prep:
05180713:48
L0706797
05/18/07
05/09/07 13:00
05/10/07
Not Specified
Extraction Method:
EPA3540C
Extraction Date: 05/14/07 20:50
Cleanup Method1:
EPA3665A
Cleanup Date1:
05/16/07
ug/kg
183 4
ug/kg
183
4
ug/kg
183
4
ug/kg
183
4
ug/kg
183
4
ug/kg
183
4
ug/kg
183
4
ug/kg
183
4
ug/kg
183
4
Acceptance
Criteria
Column
30-150 A
30-150 A
30-150
8
30-150
8
8/11/2019 Brimbal Ave. - Environmental Notification Form - 9.2.14 - Volume 2 of 2
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Project
Name:
Project
Number:
Lab ID:
Client ID:
Sample Location:
Matrix:
Anaytical Method:
Analytical Date:
Analyst:
Percent Solids:
Aroclor 1016
Aroclor 1221
Aroclor 1232
Aroclor 1242
Aroclor 1248
Aroclor 1254
Aroclor 1260
Aroclor 1262
Aroclor 1268
Not Specified
12700960
L0706797 04
RIZ-4 (5'-7')
BEVERLY, MA
Soil
64,8082
05/16/07 12:58
ss
77%
Surrogate
Page
44 of83
2,4,5,6-Tetrachloro-m-xylene
Decachlorobiphenyl
2,4 5,6-Tetrachloro-m-xylene
Decachlorobiphenyl
SAMPLE RESULTS
ND
ND
ND
NO
ND
NO
NO
NO
ND
Recovery
Qualifier
64
59
51
53
Lab
Number:
Report Date:
Date Collected:
Date Received:
Field Prep:
05180713:48
L0706797
05/18/07
05/09/07 14:45
05/10/07
Not Specified
Extraction Method: EPA 3540C
Extraction Date:
05/14/07 20:50
Cleanup Method1:
EPA 3665A
Cleanup Date1:
05/16/07
ug/kg
43.3
ug/kg
43.3
ug/kg 43.3
ug/kg
43.3
ug/kg
43.3
ug/kg 43.3
ug/kg
43.3
ug/kg 43.3
ug/kg
43.3
Acceptance
Criteria
Column
30-150
A
30-150
A
30-150
B
30-150
B
8/11/2019 Brimbal Ave. - Environmental Notification Form - 9.2.14 - Volume 2 of 2
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Project Name: Not Specified
Project Number: 12700960
Analytical Method:
64,8082
05/16/07 14:24
ss
Analytical Date:
Analyst:
Aroclor 1016
Aroclor 1221
Aroclor 1232
Aroclor 1242
Aroclor 1248
Aroclor 1254
Aroclor 1260
Aroclor 1262
Aroclor 1268
Surrogate
2,4 5,6-Tetrachloro-m-xylene
Decachlorobiphenyl
2,4 5,6-Tetrachloro-m-xylene
Decachlorobiphenyl
Page 45 of83
Method Blank Analysis
Batch Quality Control
ND ug/kg
ND
ug/kg
ND
ug/kg
ND ug/kg
ND
ug/kg
ND
ug/kg
ND ug/kg
ND
ug/kg
ND
ug/kg
Lab Number:
Report Date:
05180713:48
L0706797
05/18/07
Extraction Method: EPA 3540C
Extraction Date: 05/14/07 20:50
Cleanup Method1: EPA 3665A
Cleanup Date1: 05/16/07
33.3
33.3
33.3
33.3
33.3
33.3
33.3
33.3
33.3
Acceptance
%Recovery
Qualifier
Criteria
Column
112 30-150
A
64 30-150
A
83
30-150
B
91
30-150
B
8/11/2019 Brimbal Ave. - Environmental Notification Form - 9.2.14 - Volume 2 of 2
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Project Name:
Not Specified
Project Number: 12700960
Parameter
Aroclor 1016
Aroclor 1260
Surrogate
2,4,5,6-Tetrachloro-m-xylene
Oecachlorobiphenyl
2 4 5,6-Tetrachloro-m-xylene
Decachlorobiphenyl
Page 46 of
83
LCS
Lab Control Sample Analysis
Batch Quality Control
LCSD
%Recovery %Recovery
%Recovery
Limits
LCS
%Recovery Qualifier
107
68
81
83
LCSD
40-140
40-140
%Recovery Qualifier
105
70
83
82
Lab
Repo
R
Acceptance
Criteria
30-150
30-150
30-150
30-150
8/11/2019 Brimbal Ave. - Environmental Notification Form - 9.2.14 - Volume 2 of 2
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05180713:48
PESTICIDES
Page 47 of 83
8/11/2019 Brimbal Ave. - Environmental Notification Form - 9.2.14 - Volume 2 of 2
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Project
Name:
Project Number:
Lab ID:
Client ID:
Sample Location:
Matrix:
Anaytical Method:
Analytical Date:
Analyst:
Percent Solids:
4,4'-000
Endosulfan
II
Not Specified
12700960
L0706797-01
RIZ-1 (5'-7')
BEVERLY, MA
Soil
64,8081A
05115107 19:47
JB
90%
Surrogate
Page
48
of83
2,4,5,6-Tetrachloro-m-xylene
Decachlorobi phenyl
2,4,5,6-Tetrachloro-m-xyJene
Decachlorobiphenyl
SAMPLE
RESULTS
NO
NO
%Recovery
Qualifier
60
81
56
84
Lab Number:
Report Date:
Date Collected:
Date Received:
Field Prep:
05180713:48
L0706797
05118107
05/09107 08:30
05110/07
Not Specified
Extraction Method: EPA 3545
Extraction Date: 05111107 14:45
Cleanup Method : EPA3620B
Cleanup Date :
05115107
ug/kg
3.70
ug/kg
3.70
Acceptance
Criteria
Column
30-150
A
30-150 A
30-150 B
30-150
B
8/11/2019 Brimbal Ave. - Environmental Notification Form - 9.2.14 - Volume 2 of 2
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Project Name:
Not Specified
Project
Number:
12700960
Lab ID: L0706797 01
Client ID: RIZ-1 (5'-7')
Sample Location: BEVERLY, MA
Matrix: Soil
Anaytical Method: 64,8081A
Analytical Date: 05/15/07 19:47
Analyst:
JB
Percent Solids:
90%
Delta-BHC
Lindane
Alpha-BHC
Beta-BHC
Heptachlor
Aldrin
Heptachlor epoxide
Endrin
Endrin ketone
Dieldrin
4,4'-DDE
4,4'-DDT
Endosulfan I
Endosulfan sulfate
Methoxychlor
Chlordane
Hexachlorobenzene
Surrogate
2,4,5,6-Tetrachloro-m-xylene
Decachlorobiphenyl
2,4,5,6-T etrachloro-m-xylene
Decachlorobiphenyl
Page 49 of
83
SAMPLE
RESULTS
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Recovery
Qualifier
60
81
56
84
Lab Number:
Report
Date:
Date Collected:
Date Received:
Field Prep:
05180713:48
L0706797
05/18/07
05/09/07 08:30
05/10/07
Not Specified
Extraction Method:
EPA3545
Extraction Date:
05/11/07 14:45
Cleanup Method1:
EPA 36208
Cleanup Date1:
05/15/07
ug/kg 3.70
ug/kg
2.96
ug/kg
3.70
ug/kg
3.70
ug/kg
3.70
ug/kg 3.70
ug/kg
3.70
ug/kg 3.70
ug/kg 3.70
ug/kg 3.70
ug/kg
3.70
ug/kg 3.70
ug/kg 3.70
ug/kg 3.70
ug/kg 14.8
ug/kg
14.8
ug/kg 3.70
Acceptance
Criteria
Column
30-150
A
30-150
A
30-150
B
30-150
B
8/11/2019 Brimbal Ave. - Environmental Notification Form - 9.2.14 - Volume 2 of 2
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Project Name:
Project
Number:
Lab ID:
Client ID:
Sample Location:
Matrix:
Anaytical Method:
Analytical Date:
Analyst:
Percent Solids:
Delta-BHC
Lindane
Alpha-BHC
Beta-BHC
Heptachlor
Aldrin
Heptachlor epoxide
Endrin
Endrin ketone
Dieldrin
4,4'-DDE
Endosulfan I
Endosulfan sulfate
Methoxychlor
Chlordane
Hexachlorobenzene
Not Specified
12700960
L0706797 02
RIZ-2 (5'-7')
BEVERLY,MA
Soil
64,8081A
05/15/07 22:11
JB
80%
Surrogate
Page
50 of
83
2,4,5,6-Tetrachloro-m-xytene
Decachlorobiphenyf
2,4,5,6-Tetrachloro-m-xylene
Decachlorobiphenyl
SAMPLE RESULTS
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
602
ND
ND
ND
ND
ND
%Recovery
0
0
0
0
Qualifier
05180713:48
Lab Number: L0706797
Report Date:
05/18/07
Date Collected:
05/09/07 10:50
Date Received:
05/10/07
Field Prep:
Not
Specified
Extraction Method:
EPA3545
Extraction Date:
05/11/0714:45
Cleanup Method1:
EPA3620B
Cleanup Date1:
05/15/07
ug/kg 83.3
20
ug/kg
66.7
20
ug/kg 83.3
20
ug/kg 83.3
20
ug/kg
83.3
20
ug/kg 83.3
20
ug/kg
83.3
20
ug/kg 83.3
20
ug/kg
83.3
20
ug/kg 83.3 20
ug/kg 83.3 20
ug/kg
83.3
20
ug/kg
83.3
20
ug/kg 333 20
ug/kg
333
20
ug/kg
83.3 20
Acceptance
Criteria
Column
30·150
A
30·150
A
30·150
B
30·150
B
8/11/2019 Brimbal Ave. - Environmental Notification Form - 9.2.14 - Volume 2 of 2
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Project Name:
Project
Number:
Lab ID:
Client ID:
Sample Location:
Matrix:
Anaytical Method:
Analytical Date:
Analyst:
Percent Solids:
4,4'-DDO
4,4'-DDT
Endosulfan
II
Not Specified
12700960
L0706797 02
RIZ-2 (5'-7')
BEVERLY,
MA
Soil
64,8081A
05/15/07 22:11
JB
80%
2,4,5,6-Tetrachloro-m-xylene
Decachlorobiphenyl
2,4,5,6-Tetrachloro-m-xylene
Decachlorobiphenyl
Page
51
of
83
SAMPLE
RESULTS
>853
875
ND
%Recovery
Qualifier
0
0
0
0
Lab
Number:
Report
Date:
Date Collected:
Date Received:
Field Prep:
05180713:48
L0706797
05/18/07
05/09/07 10:50
05/10/07
Not Specified
Extraction Method:
EPA3545
Extraction Date:
05/11/07 14:45
Cleanup Method1: EPA3620B
Cleanup Date1: 05/15/07
ug/kg
83.3
20
ug/kg
83.3 20
ug/kg 83.3 20
Acceptance
Criteria
Column
30-150 A
30-150
A
30-150 B
30-150
B
8/11/2019 Brimbal Ave. - Environmental Notification Form - 9.2.14 - Volume 2 of 2
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Project Name:
Not Specified
Project Number:
12700960
Lab ID:
L0706797 02
R
Client ID:
RIZ-2 (5'-7')
Sample Location: BEVERLY, MA
Matrix: Soil
Anaytical Method: 64,8081A
Analytical Date:
05/15/07 20:15
Analyst: JB
Percent
Solids:
80%
4,4'-000
Page
52
of83
SAMPLE RESULTS
2610 ug/kg
Lab Number:
Report Date:
Date Collected:
Date Received:
Field Prep:
05180713:48
L0706797
05/18/07
05/09/07 10:50
05/10/07
Not Specified
Extraction Method:
EPA3545
Extraction
Date:
05/11/07 14:45
Cleanup Method1:
EPA3620B
Cleanup Date1: 05/15/07
417 100
8/11/2019 Brimbal Ave. - Environmental Notification Form - 9.2.14 - Volume 2 of 2
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Project Name:
Not Specified
Project
Number:
12700960
SAMPLE
RESULTS
Lab ID:
L0706797-03
Client ID:
RIZ-3 (10'-12')
Sample Location:
BEVERLY, MA
Matrix: Soil
Anaytical Method:
64,8081A
Analytical Date: 05/15/07 22:39
Analyst: JB
Percent Solids: 73%
Delta-BHC
NO
Lindane
NO
Alpha-BHC
NO
Beta-BHC
NO
Heptachlor
NO
Aldrin
NO
Heptachlor epoxide
NO
Endrin
NO
Endrin ketone
NO
Dieldrin
NO
4,4'-DDE
NO
4,4'-0DT
NO
Endosulfan I
NO
Endosulfan sulfate
NO
Methoxychlor NO
Chlordane
NO
Hexachlorobenzene
NO
Surrogate
%Recovery
Qualifier
---- --
--·····-
2,4,5,6-Tetrachloro-m-xylene
0
Decachlorobiphenyl
0
2,4,5,6-T etrach o ro-m-xylene
0
Decachlorobiphenyl
0
Page
53 of83
Lab Number:
Report
Date:
Date Collected:
Date Received:
Field Prep:
05180713:48
L0706797
05/18/07
05/09/07 13:00
05/10/07
Not Specified
Extraction Method:
EPA3545
Extraction Date:
05/11/0714:45
Cleanup Method1: EPA 36208
Cleanup Date1: 05/15/07
ug/kg
91.3
20
ug/kg
73.0
20
ug/kg 91.3 20
ug/kg 91.3 20
ug/kg 91.3 20
ug/kg 91.3 20
ug/kg
91.3
20
ug/kg 91.3 20
ug/kg 91.3
20
ug/kg 91.3
20
ug/kg 91.3 20
ug/kg
91.3
20
ug/kg
91.3
20
ug/kg 91.3
20
ug/kg
365
20
ug/kg 365
20
ug/kg 91.3
20
Acceptance
Criteria
Column
..
30-150 A
30-150
A
30-150
B
30-150
B
8/11/2019 Brimbal Ave. - Environmental Notification Form - 9.2.14 - Volume 2 of 2
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Project Name:
Not Specified
Project Number:
12700960
Lab ID:
L0706797-03
Client
ID:
RIZ-3 (10'-12')
Sample Location:
BEVERLY, MA
Matrix:
Soil
Anaytical Method: 64,8081A
Analytical Date: 05/15/07 22:39
Analyst:
JB
Percent Solids:
73%
4,4'-DDD
Endosulfan
II
Surrogate
Page
54 of83
2,4,5,6-Tetrachloro-m-xylene
Decachtorobiphenyl
2,4,5,6-Tetrachloro-m-xylene
Decachlorobiphenyl
Lab Number:
Report
Date:
SAMPLE
RESULTS
Date Collected:
Date Received:
Field Prep:
05180713:48
L0706797
05/18/07
05/09/07 13:00
05/10/07
Not Specified
Extraction Method: EPA3545
ND
ND
%Recovery
0
0
0
0
ug/kg
ug/kg
Extraction Date:
Cleanup Method1:
Cleanup Date1:
91.3
91.3
Acceptance
Qualifier
Criteria
30-150
30-150
30-150
30-150
Column
A
A
8
8
05/11/07 14:45
EPA3620B
05/15/07
20
20
8/11/2019 Brimbal Ave. - Environmental Notification Form - 9.2.14 - Volume 2 of 2
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Project Name:
Not Specified
Project Number:
12700960
Lab ID:
L0706797
04
Client ID: RIZ-4 (5'-7')
Sample Location:
BEVERLY, MA
Matrix: Soil
Anaytical Method: 64,8081A
Analytical Date:
05/15/07 23:08
Analyst:
JB
Percent Solids:
77%
4,4'-DDD
Endosulfan
II
Surrogate
Page 55 of83
2,4,5,6-Tetrachloro-m-xytene
Decachlorobiphenyl
2,4,5,6-Tetrachloro-m-xytene
Decachlorobiphenyl
SAMPLE RESULTS
ND
ND
%Recovery
Qualifier
43
67
34
41
05180713:48
Lab Number:
L0706797
Report
Date:
05/18/07
Date Collected:
05/09/07 14:45
Date Received: 05/10/07
Field Prep: Not Specified
Extraction Method:
EPA3545
Extraction Date:
05/11/07 14:45
Cleanup Method :
EPA3620B
Cleanup
Date :
05/15/07
ug/kg 21.6
5
ug/kg
21.6
5
Acceptance
Criteria
Column
30-150
A
30-150
A
30-150
B
30-150
B
8/11/2019 Brimbal Ave. - Environmental Notification Form - 9.2.14 - Volume 2 of 2
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Project
Name:
Not Specified
Project
Number:
12700960
Lab ID: L0706797 04
Client ID:
RIZ-4 (5'-7')
Sample Location: BEVERLY, MA
Matrix: Soil
Anaytical Method: 64,8081A
Analytical Date: 05/15/07 23:08
Analyst: JB
Percent Solids:
77%
Delta-BHC
Lindane
Alpha-BHC
Beta-BHC
Heptachlor
Aldrin
Heptachlor epoxide
Endrin
Endrin ketone
Dieldrin
4,4'-DDE
4,4'-DDT
Endosulfan I
Endosulfan sulfate
Methoxychlor
Chlordane
Hexachlorobenzene
Surrogate
2,4,5,6-Tetrachloro-m-xylene
Decachlorobiphenyl
2,4,5,6-Tetrachforo-m-xylene
Decachlorobiphenyl
Page
56 of 83
SAMPLE
RESULTS
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Recovery
Qualifier
43
67
34
41
Lab Number:
Report
Date:
Date Collected:
Date Received:
Field Prep:
05180713:48
L0706797
05/18/07
05/09/07 14:45
05/10/07
Not Specified
Extraction Method:
EPA3545
Extraction Date: 05/11/07 14:45
Cleanup Method :
EPA 36208
Cleanup Date1:
05/15/07
ug/kg
21.6
5
ugfkg 17.3 5
ug/kg 21.6
5
ug/kg 21.6
5
ug/kg 21.6
5
ug/kg 21.6
5
ug/kg 21.6
5
ug/kg 21.6
5
ug/kg 21.6
5
ug/kg 21.6
5
ug/kg 21.6
5
ug/kg 21.6
5
ug/kg
21.6
5
ug/kg 21.6
5
ug/kg
86.6 5
ug/kg
86.6 5
ug/kg 21.6
5
Acceptance
Criteria
Column
- - - - - - - - - - - - -
30-150
A
30-150
A
30-150
B
30-150
B
8/11/2019 Brimbal Ave. - Environmental Notification Form - 9.2.14 - Volume 2 of 2
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Project Name: Not Specified
Project Number: 12700960
Analytical Method: 64,8081A
05/15/07 18:21
JB
Analytical Date:
Analyst:
D e l t a ~ B H C
Lindane
Alpha-BHC
Beta-BHC
Heptachlor
Aldrin
Heptachlor epoxide
Endrin
Endrin ketone
Dieldrin
4,4'-DDE
4.4'-DDT
Endosulfan I
Endosulfan sulfate
Methoxychlor
Chlordane
Hexachlorobenzene
Surrogate
2,4,5,6-Tetrachloro-m-xylene
Oecachlorobiphenyl
2,4,5,6-Tetrachloro-m-xylene
Decachlorobiphenyl
Page 57 of 83
Method
Blank Analysis
Batch
Quality Control
ND
ug/kg
ND
ug/kg
ND
ug/kg
ND
ug/kg
ND
ug/kg
ND ug/kg
ND
ug/kg
ND
ug/kg
ND
ug/kg
ND ug/kg
ND
ug/kg
ND
ug/kg
ND
ug/kg
ND
ug/kg
ND
ug/kg
ND
ug/kg
ND
ug/kg
Lab Number:
Report
Date:
Extraction Method:
Extraction Date:
Cleanup Method1:
Cleanup Date1:
3.33
2.67
3.33
3.33
3.33
3.33
3.33
3.33
3.33
3.33
3.33
3.33
3.33
3.33
13.3
13.3
3.33
Acceptance
%Recovery
Qualifier
Criteria
Column
56 30-150 A
75 30-150
A
50
30-150
8
78
30-150 8
05180713:48
L0706797
05/18/07
EPA3545
05/11/07 14:45
EPA3620B
05/15/07
8/11/2019 Brimbal Ave. - Environmental Notification Form - 9.2.14 - Volume 2 of 2
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Project Name: Not Specified
Project Number: 12700960
Analytical Method: 64,8081A
05/15/07 18:21
JB
Analytical Date:
Analyst:
4,4'-000
Endosulfan II
Surrogate
2,4,5,6-Tetrachloro-m-xylene
Decachlorobiphenyl
2,4 5,6-T
etrachloro-m-xylene
Decachlorobiphenyl
Page 58 of 83
Method
Blank Analysis
Batch Quality Control
NO
NO
ug/kg
ug/kg
Lab Number:
Report Date:
Extraction Method:
Extraction Date:
Cleanup Method1:
Cleanup Date1:
3.33
3.33
Acceptance
%Recovery
Qualifier
Criteria
Column
56
30-150 A
75
30-150
A
50 30-150
B
78
30-150
B
05180713:48
L0706797
05/18/07
EPA 3545
05/11/07 14:45
EPA3620B
05/15/07
8/11/2019 Brimbal Ave. - Environmental Notification Form - 9.2.14 - Volume 2 of 2
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Project Name:
Not Specified
Project Number: 12700960
Parameter
Oelta-BHC
Lindane
Alpha-BHC
Beta-BHC
Heptachlor
Aldrin
Heptachlor epoxide
Endrin
Endrin ketone
Dieldrin
4,4'-DDE
4,4'-DDT
Endosulfan I
Endosulfan sulfate
Methoxychlor
Hexachlorobenzene
Page 59 of 83
LCS
Lab Control Sample
Analysis
Batch Quality Control
LCSD
%Recovery %Recovery
%Recovery
Limits
40-140
40-140
40-140
40-140
40-140
40-140
40-140
40-140
40-140
40-140
40-140
40-140
40-140
40-140
40-140
40-140
Lab
Repo
R
B l t i i i l i l
8/11/2019 Brimbal Ave. - Environmental Notification Form - 9.2.14 - Volume 2 of 2
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Pro ject Name: Not Specified
Project Number: 12700960
Parameter
4,4'-DDO
Endosulfan
II
Page 60 of
83
Surrogate
2 4 , 5 , 6 ~ Tetrachforo-m-xylene
Decachlorobiphenyl
2,4 5 ,6-Tetrachloro-m-xylene
Decachlorobiphenyl
Surrogate
2 4,5,6-Tetrachloro-m-xylene
Oecachlorobiphenyl
2,4 ,5, 6-T etrachloro-m-xylene
Decachlorobiphenyl
LCS
Lab Control Sample Analysis
Batch Quality Control
LCSD
%Recovery %Recovery
%Recovery
Limits
LCS
%Recovery Qualifier
41
56
37
57
LCS
%Recovery Qualifier
41
56
37
57
LCSD
%Recovery Qualifier
65
82
61
86
LCSD
40-140
40-140
%Recovery Qualifier
65
82
61
86
Lab
Repo
RP
Acceptance
Criteria
30-150
30-150
30-150
30-150
Acceptance
Criteria
30-150
30-150
30-150
30-150
8/11/2019 Brimbal Ave. - Environmental Notification Form - 9.2.14 - Volume 2 of 2
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05180713:48
METALS
Page
61 of
83
8/11/2019 Brimbal Ave. - Environmental Notification Form - 9.2.14 - Volume 2 of 2
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05180713:48
Project
Name: Not Specified Lab Number: L0706797
Project Number:
12700960
Report Date: 05/18/07
SAMPLE RESULTS
Lab
ID: L0706797-01 Date Collected: 05/09/07 08:30
Client
ID:
RIZ-1 (5'-7') Date Received: 05/10/07
Sample Location: BEVERLY, MA Field Prep: Not Specified
Matrix: Soil
Percent Solids: 90%
Dilution
Date
Date
Prep Analytical
Parameter Result
Qualifier Units
RDL
Factor Prepared
Analyzed Method
Method
Analyst
Antimony, Total
ND
mg/kg
2.2
05/15/0716:10 05/17/07 16:22
EPA
30508
60,60108
MG
Arsenic, Total 7.8 mg/kg
0.44
05/15/0716:10
05/17/0716:22
EPA3050B
60,60108
MG
Barium, Total
55
mg/kg
0.44
05/15/0716:10
05/17/0716:22 EPA 30508
60,60108
MG
Beryllium, Total
0.85
mg/kg
0.22
05/15/0716:10
05/17/0716:22 EPA 30508
60,60108
MG
Cadmium, Total ND mg/kg
0.44
05/15/07 16:10
05/17/07 16:22 EPA 30508
60,60108
MG
Chromium, Total
16
mg/kg
0.44
05/15/0716:10
05/17/07 16:22
EPA
30508
60,60108
MG
Copper, Total
11
mg/kg
0.44
05/15/0716:10
05/17/07 16:22
EPA3050B
60,60108
MG
Iron, Total
16000
mg/kg
2.2
05/15/0716:10
05/17/0716:22 EPA
30508
60,60108
MG
Lead, Total
6.8
mg/kg
2.2
05/15/0716:10
05/17/0716:22 EPA
30508
60,60108
MG
Manganese, Total
170
mg/kg
0.44
05/15/0716:10
05/17/0716:22 EPA
30508
60,60108
MG
Mercury, Total
ND
mg/kg
0.08
05/14/07 18:30
05/15/0714:45 EPA 7471A
64,7471A
DM
Nickel, Total 12
mg/kg
1.1
05/15/07 16:10
05/17/07 16:22 EPA
30508
60,60108
MG
Selenium, Total
ND
mg/kg
2.2
05/15/0716:10
05/17/07 16:22 EPA30508
60,60108
MG
Silver, Total ND mg/kg 0.44
05/15/0716:10
05/17/07 16:22 EPA 30508
60,60108
MG
Thallium, Total
ND
mg/kg
2.2
05/15/0716:10
05/17/07 16:22
EPA
30508
60,60108
MG
Zinc, Total 39 mg/kg
2.2
05/15/0716:10
05/17/0716:22
EPA
30508
60,60108
MG
Page 62 o f 83
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05180713:48
Project Name: Not Specified Lab Number: L0706797
Project Number:
12700960
Report Date: 05/18/07
SAMPLE RESULTS
Lab ID: L0706797 02 Date Collected: 05/09/07 10:50
Client ID:
RIZ-2 (5'-7') Date Received: 05/10/07
Sample Location: BEVERLY, MA Field Prep: Not Specified
Matrix: Soil
Percent Solids: 80%
Dilution
Date
Date
Prep Analytical
Parameter Result
Qualifier
Units
RDL
Factor Prepared Analyzed Method
Method
Analyst
Antimony, Total NO mg/kg
12
5
05/15/0716:10
05/17/07 16:29 EPA 30508
60,60108
MG
Arsenic, Total 21 mg/kg
2.5
5 05/15/07 16:10
05/17/0716:29
EPA 30508
60,60108
MG
Barium, Total
96
mg/kg
2.5 5
05/15/07 16:10
05/17/0716:29
EPA3050B
60,60108
MG
Beryllium, Total NO mg/kg
1.2
5
05/15/07 16:10
05/17/0716:29
EPA 30508
60,60108
MG
Cadmium, Ta al NO mg/kg
2.5
5
05/15/0716:10
05/17/0716:29 EPA 30508
60,60108
MG
Chromium, Total
49
mg/kg
2.5
5
05/15/0716:10
05/17/07 16:29
EPA
30508
60,60108
MG
Copper, Total
210
mg/kg
2.5
5
05/15/0716:10
05/17/07 16:29 EPA 30508
60,60108
MG
Iron, Total
75000 mg/kg
12
5
05/15/0716:10
05/17/0716:29
EPA 30508
60,60108
MG
Lead, Total
590
mg/kg
12
5
05/15/07 16:10
05/17/0716:29 EPA 30508
60,60108
MG
Manganese, Total
530
mgfkg
2.5
5 05/15/07 16:10 05/17/0716:29 EPA 30508
60,60108
MG
Mercury, Total
0.57
mg/kg
0.10
05/14/0718:30
05/15/0714:47
EPA 7471A
64,7471A
OM
Nickel, Total
45
mg/kg
6.2 5
05/15/0716:10
05/17/07 16:29 EPA 30508
60,60108
MG
Selenium, Total
ND mg/kg
12 5
05/15/0716:10
05/17/07 16:29
EPA30508
60,60108
MG
Silver, Total
NO
mg/kg
2.5 5
05/15/0716:10
05/17/07 16:29 EPA 30508
60,60108
MG
Thallium, Total NO mg/kg
12
5
05/15/0716:10
05117/0716:29 EPA 30508
60,60108
MG
Zinc, Total 380 mg/kg
12
5
05/15/07 16:10
05/17/0716:29
EPA 30508
60,60108
MG
Page 63 of 83
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05180713:48
Project Name: Not Specified Lab Number:
L0706797
Project Number:
12700960
Report Date:
05/18/07
SAMPLE RESULTS
Lab
ID:
L0706797 03
Date Collected:
05/09/07 13:00
Client ID: RIZ-3 (10'-12') Date Received:
05/10/07
Sample Location: BEVERLY, MA Field Prep: Not Specified
Matrix: Soil
Percent Solids: 73%
Dilution
Date
Date
Prep Analytical
Parameter
Result
Qualifier Units RDL
Factor Prepared Analyzed Method
Method
Analyst
------------------
Antimony, Total 3.5
mg/kg
2.7
05/15/0716:10
05/17/0716:24 EPA 30508
60,60108
MG
Arsenic, Total
13
mg/kg
0.54
05/15/0716:10
05/17/0716:24
EPA 30508
60,60108
MG
Barium, Total
230
mg/kg 0.54
05/15/0716:10
05/17/0716:24 EPA30508
60,60108
MG
Beryllium, Total 0.74
mg/kg
0.27
05/15/0716:10
05/17/0716:24 EPA 30508
60,60108
MG
Cadmium, Total 2.6
mg/kg
0.54 05/15/07 16:10
05/17/0716:24
EPA 30508
60,60108
MG
Chromium, Total
56
mg/kg 0.54
05/15/07 16:10
05/17/07 16:24
EPA 30508
60,60108
MG
Copper, Total
400
mg/kg 0.54
05/15/07 16:10
05/17/07 16:24 EPA 30508
60,60108
MG
Iron, Total
36000
mg/kg 5.4 2
05/15/0716:10
05/17/07 17:08 EPA 30508
60,60108
MG
Lead, Total 610 mg/kg 2.7
05/15/0716:10
05/17/0716:24 EPA 30508
60,60108
MG
Manganese, Total
380
mg/kg 0.54
05/15/0716:10
05/17/07 16:24
EPA 30508
60,60108
MG
Mercury, Total
0.33
mg/kg 0.11
05/14/0718:30
05/15/07 14:49 EPA 7471A
64,7471A
OM
Nickel, Total
38
mg/kg 1.3
05/15/0716:10
05/17/0716:24 EPA 30508
60,60108
MG
Selenium, Total
NO
mg/kg 2.7
05/15/0716:10
05/17/0716:24 EPA 30508
60,60108
MG
Silver, Total NO mg/kg 0.54
05/15/0716:10
05/17/0716:24 EPA30508
60,60108
MG
Thallium, Total
NO
mg/kg
2.7
05/15/0716:10
05/17/0716:24
EPA 30508
60,60108
MG
Zinc, Total 360
mg/kg
2.7 05/15/0716:10
05/17/0716:24
EPA
30508
60,60108
MG
Page 64 of 83
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05180713:48
Project Name:
Not Specified
Lab Number: L0706797
Project Number:
12700960
Report Date: 05/18/07
SAMPLE RESULTS
Lab ID: L0706797 -04 Date Collected: 05/09/07 14:45
Client ID: RIZ-4 (5'-7')
Date Received: 05/10/07
Sample Location: BEVERLY, MA Field Prep: Not Specified
Matrix: Soil
Percent Solids: 77%
Dilution Date Date Prep
Analytical
Parameter Result
Qualifier
Units
RDL
Factor Prepared Analyzed Method
Method
Analyst
- - - - ~ - - - - - · ·
Antimony, Total NO mg/kg
2.6
05115/07 16:10 05/17/0716:27 EPA 30508
60,60108
MG
Arsenic, Total 8.6
mg/kg
0.52
05/15/0716:10 05/17/07 16:27 EPA 30508
60,60108
MG
Barium, Total 100
rna/kg
0.52
05/15/0716:10
05117/07 16:27 EPA 30508
60,60108
MG
Beryllium, Total 0.66 mg/kg 0.26
05/15/0716:10
05/17/0716:27
EPA 30508
60,60108
MG
Cadmium, Total NO mg/kg 0.52
05/15/0716:10
05/17/0716:27 EPA
30508
60,60108
MG
Chromium, Total 16
mg/kg
0.52
05/15/07 16:10
05/17/07 16:27 EPA 30508
60,60108
MG
Copper, Total
9.0
mg/kg
0.52
05/15/07 16:10
05/17/07 16:27
EPA 30508
60,60108
MG
Iron, Total
13000
mg/kg 2.6
05/15/0716:10
05/17/07 16:27 EPA 30508
60,60108
MG
Lead, Total 100
mg/kg
2.6
05/15/0716:10
05/17/07 16:27 EPA 30508
60,60108
MG
Manganese,
Total 110
mg/kg
0.52
05/15/0716:10 05/17/0716:27
EPA 30508
60,60108
MG
Mercury, Total
NO
mg/kg
0.11
05/14/07 18:30 05/15/07 14:50
EPA 7471A
64,7471A
OM
Nickel, Total 9.8 mg/kg
1.3
05/15/0716:10
05/17/0716:27 EPA 30508
60,60108
MG
Selenium, Total
ND
mg/kg
2.6
05/15/07 16:10
05/17/0716 :27 EPA 30508
60,60108
MG
Silver, Total ND
mg/kg
0.52
05/15/0716:10
05/17/07 16:27
EPA30508
60,60108
MG
Thallium, Total NO mg/kg
2.6
0511510716:10
05/17/07 16:27 EPA 30508
60,60108
MG
Zinc, Total 70 mg/kg
2.6
05/15/0716:10
05/17/0716 :27 EPA 30508
60,60108
MG
Page 65
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Project Name: Not Specified
Project Number: 12700960
Parameter
Mercury, Total NO
Method
Blank Analysis
Batch Quality Control
Lab Number:
Report Date:
05180713:48
L0706797
05/18/07
Dilution
Factor
Date
Prepared
Date Analytical
Analyzed Method
Analyst
R ~ ~ j , ~ i i i j l
mg/kg
0.08 05/14/0718:30 05/15/0714:16 64,7471A
OM
Prep
l n f o r m a t i ~ n _
__
Digestion Method: EPA 7471A
Dilution
Date
Date
Analytical
Parameter
Result Qualifier
Units RDL
Factor
Prepared
Analyzed Method
Analyst
Antimony,
Total
NO
mg/kg 2.0
05/15/07 16:10
05/17/07 16:07 60,60108 MG
Arsenic, Total NO mg/kg
0.40
05/15/0716:10
05/17/0716:07 60,60108
MG
Barium, Total
NO mg/kg
0.40
05/15/0716:10
05/17/07 16:07 60,6010B
MG
Beryllium, Total
NO
mg/kg 0.20
05/15/0716:10
05/17/0716:07 60,60108
MG
Cadmium,
Total
NO
mg/kg
0.40
05/15/0716:10
05/17/0716:07 60,60108 MG
Chromium, Total NO mg/kg
0.40
05/15/0716:10
05117/0716:07 60,60108
MG
Copper, Total NO
mg/kg
0.40
05/15/0716:10
05/17/0716:07
60,60108
MG
Iron, Total
NO
mg/kg
2.0
05/15/07 16:10
05/17/07 16:07
60,6010B
MG
lead, Total NO mg/kg
2.0
05/15/07 16:10
05/17/07 16:07
60,60108
MG
Manganese, Total
NO
mg/kg
0.40
05/15/07 16:10
05/17/07 16:07 60,60108
MG
Nickel, Total
NO
mg/kg
1.0
05/15/0716:10
05/17/07 16:07
60,6010B
MG
Selenium, Total
NO
mg/kg
2.0
05/15/0716:10
05/17/07 16:07
60,60108
MG
Silver, Total
NO
mg/kg 0.40
05/15/0716:10
05/17/0716:07 60,60108
MG
Thallium, Total NO mg/kg
2.0
05/15/0716:10
05/17/0716:07
60,6010B
MG
Zinc, Total
NO
mg/kg
2.0
05/15/0716:10
05/17/0716:07 60,60108
MG
Prep Information
~
- - - - - - -
Digestion Method:
EPA3050B
Page 66 of 83
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Project Name:
Not Specified
Project Number: 12700960
Parameter
Mercury, Total
Antimony, Total
Arsenic, Total
Barium, Total
Beryllium, Total
Cadmium, Total
Chromium, Total
Copper, Total
Iron, Total
Lead, Total
Manganese, Total
Nickel, Total
Selenium, Total
Silver, Total
Thallium, Total
Zinc, Total
Page
67
of
83
LCS
Lab Control Sample Analysis
Batch Quality Control
LCSD
%Recovery %Recovery
%Recovery
Limits
75-125
75-125
75-125
75-125
75-125
75-125
75-125
75-125
75-125
75-125
75-125
75-125
75-125
75-125
75-125
75-125
Lab N
Repo
RP
8/11/2019 Brimbal Ave. - Environmental Notification Form - 9.2.14 - Volume 2 of 2
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Page 68 of 83
INORGANICS
&
MISCELLANEOUS
05180713:48
8/11/2019 Brimbal Ave. - Environmental Notification Form - 9.2.14 - Volume 2 of 2
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Project Name: Not Specified
Lab Number:
Project Number:
12700960
Report Date:
SAMPLE
RESULTS
Lab
ID:
L0706797-01
Date Collected:
Client
ID: RIZ-1
(5'-7')
Date Received:
Sample Location:
BEVERLY, MA
Field Prep:
Matrix: Soil
Dilution Date Date
Parameter
RDL Factor Prepared Analyzed
- -------
Cyanide, Total ND mg/kg
1.0
05/16/07 16:30 05/16/07 21:39
Solids, Total 90 %
0.10 05111/0715:00
Page 69
of
83
05180713:48
L0706797
05/18/07
05/09/07 08:30
05/10/07
Not Specified
Analytical
Method
64,9014
30,2540G
1lJ.:?MA
• ~ ~ ~
••
'."dl-' ••••
DD
LR
8/11/2019 Brimbal Ave. - Environmental Notification Form - 9.2.14 - Volume 2 of 2
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Project Name:
Not Specified
Lab
Number:
Project Number: 12700960
Report Date:
SAMPLE RESULTS
Lab 10: L0706797-02 Date Collected:
Client ID: RIZ-2 (5'-7')
Date Received:
Sample Location: BEVERLY,
MA
Field Prep:
Matrix:
Soil
Dilution Date Date
Parameter
Result Qualifier Units
RDL Factor Prepared Analyzed
------ ----
Cyanide, Total
ND
mg/kg
1.2
05/16/07 16:30 05/16/07 21:39
Solids, Total % 0.10 05/11/07 15:00
Page 70 of83
05180713:48
L0706797
05/18/07
05/09/07 10:50
05/10/07
Not Specified
Analytical
Method
Analys
64,9014 DD
30,2540G LR
zi\;?1-iA
;;
. . •• « ........
8/11/2019 Brimbal Ave. - Environmental Notification Form - 9.2.14 - Volume 2 of 2
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05180713:48
Project Name:
Not Specified
Lab Number:
L0706797
Project Number:
12700960
Report Date: 05/18/07
SAMPLE RESULTS
Lab ID:
L0706797-03
Date Collected: 05/09/07 13:00
ClientiD:
RIZ-3 (10'-12')
Date Received: 05/10/07
Sample Location:
BEVERLY,
MA
Field Prep:
Not Specified
Matrix: Soil
Dilution Date
Date Analytical
Parameter
Result Qualifier
Units
RDL
Factor Prepared
Analyzed Method
Analyst
Cyanide, Total ND
mg/kg
1.2
05/16/0716:30
05/16/07 21:40 64,9014
DD
Solids, Total 73 %
0.10
05111/07 15:00 30,2 540G LR
Page 71
of
83
8/11/2019 Brimbal Ave. - Environmental Notification Form - 9.2.14 - Volume 2 of 2
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Project Name:
Not Specified
Lab Number:
Project Number:
12700960
Report
Date:
SAMPLE RESULTS
Lab ID: L0706797-04 Date Collected:
ClientiD: RIZ-4 (5'-7')
Date Received:
Sample Location:
BEVERLY,
MA
Field Prep:
Matrix:
Soil
Dilution Date
Result Qualifier Units
RDL
Factor Prepared
Date
Analyzed
Cyanide, Total ND mg/kg 1.2 05/16/0716:30 05/16/07 21:41
Solids, Total
77
%
0.10
05/11/0715:00
Page 72
of83
05180713:48
L0706797
05/18/07
05/09/07 14:45
05/10/07
Not Specified
Analytical
Method
Analyst
··
64,9014
DD
30,2540G
LR
. ,&c?t;A
. ~ · · - ~ , ~
.. · ....
8/11/2019 Brimbal Ave. - Environmental Notification Form - 9.2.14 - Volume 2 of 2
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Project
Name:
Project Number: 12700960
Parameter
Cyanide, Total
ND
Page 73 of 83
Method Blank Analysis
Batch Quality Control
Units
Dilution
RDL Factor
Lab Number:
Report Date:
Date
Prepared
Date
Analyzed
mg/kg
0.97
05/16/07 16:30 05/16/07 21:35
05180713:48
L0706797
05/18/07
Analytical
Method
64,9014
DD
8/11/2019 Brimbal Ave. - Environmental Notification Form - 9.2.14 - Volume 2 of 2
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Project Name:
Not Specified
Project Number: 12700960
Parameter
Cyanide, Total
Page
74
of
83
LCS
Lab Control Sample Analysis
Batch Quality Control
LCSD
%Recovery %Recovery
%Recovery
Limits
80-120
Lab
Repo
RP
8/11/2019 Brimbal Ave. - Environmental Notification Form - 9.2.14 - Volume 2 of 2
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Pro ject Name: Not Specified
Project Number: 12700960
Parameter
Solids, Total
Page
75
of
83
Lab Duplicate
Analysis
Batch Quality Control
Native Sample Duplicate Sample Units
77
76
%
R
8/11/2019 Brimbal Ave. - Environmental Notification Form - 9.2.14 - Volume 2 of 2
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05180713:48
Project Name: Not Specified
Lab Number:
L0706797
Project Number:
12700960
Report Date: 05/18/07
Sample Receipt and Container Information
Were project specific reporting limits specified?
YES
Cooler Information
Cooler Custody
Seal
A
Absent
Container Information
Container
10
Container Type
Cooler
pH
Temp
Pres Seal Analysis
L0706797-01A
Vial
MeOH
preserved A
NA
4.1C
y
Absent VPH-04
L0706797-01B Vial water preserved A
NA
4.1C
y
Absent VPH-04
L0706797-01C Vial water preserved A
NA
4.1C
y
Absent VPH-04
l0706797-01D
Amber
250ml unpreserved
A
NA 4.1C
y
Absent EPH-04,MCP-8081-04,MCP-
8082-04,TPH-DRO-D
L0706797-01E Amber 250ml unpreserved A
NA
4.1C
y
Absent MCP-7471 T MCP-AG-
6010T,MCP-AS-6010T,MCP-BA-
6010T,MCP-BE-6010T,MCP-CD-
6010T,MCP-CR-6010T,MCP-CU-
60
1OT,MCP-FE-60 1OT, MCP-MN-
60
1OT,MCP-N1-601 OT MCP-PB-
60 1OT,MCP-SB-601OT MCP-SE-
6010T,MCP-TL-6010T,MCP-ZN-
6010T
L0706797-01F Amber
250m unpreserved A
NA
4.1C
y
Absent MCP-TCN9014-04,TS
L0706797-02A
Vial
MeOH
preserved A
NA
4.1C
y
Absent VPH-04
l0706797..02B
Vial water preserved A NA 4.1C
y
Absent
VPH-04
L0706797-02C
Vial
water
preserved
A
NA
4.1C
y
Absent
VPH-04
L0706797-02D
Amber 250ml unpreserved A
NA
4.1C
y
Absent EPH-04,MCP-8081..04,MCP-
8082-04,TPH-DRO-D
L0706797-02E
Amber 250ml unpreserved
A
NA 4.1C
y
Absent
MCP-7471T,MCP-AG-
60
1
OT
,MCP-AS-60
1
OT,
MCP-BA-
6010T,MCP-BE-6010T,MCP-CD-
6010T,MCP-CR-6010T,MCP-CU-
6010T,MCP-FE-6010T,MCP-MN-
601 OT,MCP-NI-601 OT ,MCP-PB-
601 OT,MCP-SB-601 OT MCP-SE-
601 OT,MCP-TL-601 OT,MCP-ZN-
6010T
L0706797-02F
Amber 250ml unpreserved
A
NA 4.1C
y
Absent
MCP-TCN9014-04,TS
L0706797 -03A Vial MeOH preserved A
NA
4.1C
y
Absent VPH-04
L0706797-03B Vial water preserved
A
NA 4.1C
y
Absent
VPH-04
L0706797..03C Vial water preserved
A
NA 4.1C
y
Absent
VPH-04
L0706797-030 Amber
250m1 unpreserved A
NA
4.1C
y
Absent EPH-04,MCP-8081-04,MCP-
8082..Q4,TPH-DRO-D
Page 76 of83
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Project Name:
Project Number:
Not Specified
12700960
Container
Information
Container
10
Container Type
L0706797-03E Amber 250ml unpreserved
L0706797-03F Amber 250ml unpreserved
L0706797-04A Vial MeOH preserved
L0706797-04B Vial water preserved
L0706797-04C Vial water preserved
L0706797-04D Amber 250ml unpreserved
L0706797-04E Amber 250ml unpreserved
L0706797-04F Amber 250ml unpreserved
L0706797-0SA Vial MeOH preserved
L0706797-0SB
Vial water preserved
L0706797-0SC
Vial water preserved
Page 77 of 83
Cooler pH Temp
A
NA 4.1C
A
NA
4.1C
A
NA
4.1C
A
NA 4.1C
A
NA 4.1C
A
NA 4.1C
A
NA
4.1C
A NA 4.1C
NA NA NA
NA
NA
NA
NA
NA
NA
Pres Seal
y
Absent
y
Absent
y
Absent
y
Absent
y
Absent
y
Absent
y
Absent
y
Absent
y
Absent
y
Absent
y
Absent
05180713:48
Lab Number: L0706797
Report Date: 05/18/07
Analysis
MCP-7471T,MCP-AG-
6010T,MCP-AS.6010T,MCP-BA-
60
1OT, MCP-8
E-60
1OT,MCP-CD-
6010T,MCP-CR-6010T,MCP-CU-
6010T,MCP-FE-6010T,MCP-MN-
601 OT,
MCP-NI-601
OT
MCP-PB-
6010T,MCP-SB-6010T,MCP-SE-
6010T,MCP-Tl-6010T,MCP-ZN-
6010T
MCP-TCN9014-04,TS
VPH-04
VPH-04
VPH-04
EPH-04,MCP-8081-04,MCP-
8082-04, TPH-DRO-D
MCP-7471T,MCP-AG-
6010T,MCP-AS-6010T,MCP-BA-
601
OT
,MCP-BE-601 OT,MCP-CD-
601
OT
,MCP-CR-601 OT,MCP-CU-
60
1OT,MCP-FE-601
OT
MCP-M N-
60 1OT, MCP-N 1-601 OT MCP-PB-
6010T,MCP-SB-6010T,MCP-SE-
6010T,MCP-TL-6010T,MCP-ZN-
6010T
MCP-TCN9014-04,TS
HOLD
HOLD
HOLD
8/11/2019 Brimbal Ave. - Environmental Notification Form - 9.2.14 - Volume 2 of 2
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Project Name:
Not Specified
Project Number:
12700960
GLOSSARY
Acronyms
EPA
- Environmental Protection Agency.
Lab Number:
Report Date:
05180713:48
L0706797
05/18/07
LCS - Laboratory Control Sample: A sample matrix, free from the analytes of
interest, spiked with verified
known amounts
of
analytes or a material containing known and verified amounts
of
analytes.
LCSD-
Laboratory Control Sample Duplicate: Refer to LCS.
MS - Matrix Spike Sample: A sample prepared by adding a known mass
of
target analyte to a specified
amount
of
matrix sample for which an independent estimate
of
target analyte concentration is available.
Matrix Spike Sample Duplicate: Refer to MS.
SD
NA
NC
- Not Applicable.
- Not Calculated: Term is utilized when one or more
of
the results utilized in the calculation are
non-detect at the parameter's reporting unit.
NO - Not detected at the reported detection limit for the sample.
RDL - Reported Detection Limit: The value at which an instrument can accurately measure an analyte at a
specific concentration. The RDL includes any adjustments from dilutions, concentrations or moisture
content, where applicable.
RPD - Relative Percent Difference: The results from matrix and/or matrix spike duplicates are primarily
designed to assess the precision of analytical results in a given matrix and are expressed as
relative percent difference (RPD). Values which are less than five times the reporting limit for any
individual parameter are evaluated by utilizing the absolute difference between the values; although
the RPD value will be provided in the report.
Terms
Analytical Method: Both the document from which the method originates and the analytical reference method.
(Example: EPA
82608
is shown as 1
82608.)
The codes for the reference method documents are provided in the
References section
of
the Addendum.
Data Qualifiers
The following data qualifiers have been identified for use under the
CT
DEP Reasonable Confidence Protocols.
A- Spectra identified as "Aldol Condensation Product".
B - The analyte
was
detected above the reporting limit in the associated method blank. Flag
only
applies to
associated field samples that have detectable concentrations
of
the analyte.
E - Concentration
of
analyte exceeds the range
of
the calibration curve and/or linear range
of
the instrument.
J
-Estimated
value. The analyte
was
tentatively identified; the quantitation
is
an estimation. (Tentatively
identified compounds only.)
Report
Format Not
Specified
Page 78 of
83
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05180713:48
Project Name: Not Specified
Project Number: 12700960
Lab Number:
Report Date:
L0706797
05/18/07
REFERENCES
1 Test Methods for Evaluating Solid Waste: Physical/Chemical Methods. EPA SW-846. Third
Edition. Updates
1-
lilA, 1997.
30
Standard Methods for the Examination of Water and Wastewater. APHA-AWWA-WPCF.
18th Edition. 1992.
59 Method for the Determination of Volatile Petroleum Hydrocarbons (VPH). Massachusetts
Department of Environmental Protection, DENORS/BWSC. May 2004, Revision 1.1.
60 Quality Assurance and Quality Control Requirements and Performance Standards for SW-
846 Methods. MADEP BWSC. WSC-CAM-IIA (Revision 4 , WSC-CAM-V C (Revision 2),
WSC-CAM-IIIA (Revision 5). May 2004.
61
Method for the Determination of Extractable Petroleum Hydrocarbons (EPH). Massachusetts
Department of Environmental Protection, DENORS/BWSC. May 2004, Revision 1.1.
64
Quality Assurance and Quality Control Requirements and Performance Standards for SW-
846 Methods. MADEP BWSC. WSC-CAM-IIA (Revision 4), WSC-CAM-V C (Revision 2),
WSC-CAM-IIIA (Revision 5). August 2004.
LIMITATION OF LIABILITIES
Alpha Woods Hole Labs performs services with reasonable care and diligence normal to the analytical testing
laboratory industry. In the event
of
an error, the sole and exclusive responsibility
of
Alpha Woods Hole Labs
shall be to re-perform the work at it's own expense.
In
no event shall Alpha Woods Hole Labs be held liable
for any incidental, consequential
or
special damages, including but not limited to, damages
in
any way
connected with the use of, interpretation of, information or analysis provided by Alpha Woods Hole Labs.
We strongly urge our clients to comply with EPA protocol regarding sample volume, preservation, cooling,
containers, sampling procedures, holding time and splitting of samples in the field .
.
· · - · · · · · - · - - - - - -
Page 79
of83
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CHAIN OF CUSTODY PAGE__l__o,_l__
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8/11/2019 Brimbal Ave. - Environmental Notification Form - 9.2.14 - Volume 2 of 2
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Data
f i le :
\\Drgserv1\ee\chem\GCEXT\Petro10,t\070514arolist,b\0514B029.D
Inject ion Date:
1 4 - ~ A Y - 2 0 0 7
23:11
Instrument:
Petro10,i L-
..: ) '40
lo1Ci..i·
£1\
co
Cl1ent
Sample
ID:
..,.
(.j
t-iP6890 GC Data. FID2B.CH: 9.-s-f6 to 13.5i5
Min
1 -
0
co
'
;;
'
x
,.
6 . 1 ~
6.o-i
5.91
5 . 8 ~
5 . 7 ~
5 . ~
5 . 5 ~
5. 4
5 . 3 ~
5 . 2 ~
5 . 1 ~
5 . ~
4 . 9 ~
4 . 8 ~
4.
4 . 6 ~
4 . 5 ~
4 . 4 ~
4 . ~
4.2-:
4 . 1 ~
4.0-;
3 . 9 ~
3.8..:
3 . 7 ~
3 . 6 - ~
3 . 5 ~
3.4.;
3 , 3 ~
3 . 2 ~
3.1·=
3 . ~
2.
2 , 8 ~
2.71
2 . 6 ~
2 . 5 ~
2 . 4 ~
2 . 3 ~
2 . 2 ~
2.1:
2 .o-1
1 . ~
1 . 8 ~
1 . 7 ~
1 . 6 ~
1 . 5 ~
1 . 4 ~ .
I\
'
9.6
' '
11.6
'
1.8
'
12.0
1
1
.0
11
1
.2
'
11.4
Min.
'
0.6
to'.a
0.2 to'.4
:8
tO.o
t2.2
~
s
J
)
..
"
1-
-,
'
12.4
t2
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~
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Data
File:
\ \ O ~ g s e r v 1 \ e e \ ~ h e m \ G C E X T \ P e t r o 1 0 , i \ 0 7 0 5 1 4 a r o l i s t . b \ 0 5 1 4 8 0 2 B . D
Injection Date: 14-MAY-2007 22:37
Instrument: Petroto, i
L ~ - , · . . 0 ~ ~ . . 0 . . ' \ -.o-,
Cl.lent
Sample
ID: T ·
4.6;
4,S:
4 , 4 ~
4 . ~
4 . 2 ~
4 . 1 ~
4 . 0 ~
3 . 9 ~
3.8
3 . 7 ~
3.6-:
3 . ~
3 . 4 ~
3 . ~
3 . 2 ~
3 . 1 ~
3 . 0 ~
2 . 9 ~
2 , 8 ~
2 . 7 ~
2 . 6 ~
2 . 5 ~
2 . 4 ~
2 . 3 ~
2 . 2 ~
,_
2 . 1 ~
2.01
1.
1 . 8 ~
1.
1 . 6 ~
1 . 5 ~
1 . 4 ~
1 . 3 ~
1 . 2 ~
1.1-:
t.O.:
0 . 9 ~
0 . 8 ~
0 . 7 ~
0 . 6 ~
0 . 5 ~
0,4...;
0 . 3 ~
0.2..:
0.1-
JUlllll})jWlJ
-
'
.1
5
..
'
I
0
HP6890 GC
Oata.
tiD28.CH:
9.109 to 20.024
Min
~ ~ ~ · ~ W
o . o ~
1'o
t'z ·
' '
'
. . '
' ' ..
' ' .. '
.
' '
. '
' '
13
14
15
16
17
Min
11
8/11/2019 Brimbal Ave. - Environmental Notification Form - 9.2.14 - Volume 2 of 2
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Client ID:
CREME SS-1
Phoenix
.D.: AJ36104
Parameter Result
RL
Units
Date Time
By
Reference
PCB-1242
ND 360 ug/Kg 07/30/07
JH
SW8082
PCB-1248
ND
360
ug/Kg
07/30/07
JH
SW8082
PCB-1254
ND 360 ug/Kg 07/30/07
JH
SW8082
PCB-1260
ND
360
ug/Kg
07/30/07
JH
SW8082
PCB-1262
ND
360 ug/Kg
07/30/07
JH
sw
8082
PCB-1268
ND
360 ug/Kg 07/30/07
JH
sw 8082
QAlQC
Surrogates
% DCBP (Surrogate Rec)
95 % 07/30/07
JH
SW8082
% TCMX (Surrogate Rec)
116 %
07/30/07
JH
SW8082
Comments:
*Asbestos analyzed by MA certified lab M-NJ337. No Asbestos was detected in this sample.
If
there are
any questions regarding this data, p lease call Phoenix Client Services a t extension 200.
ND=Not detected BDL=Below Detection
Limit RL=Reporting Limit
. @ ~
...
-
u g u t o : ~
2007
Page 2 of34
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Environmen tal Laboratories,
Inc.
587 East Middle Turnpike
P.O.Box
370, Manchester CT 06040
Analysis Report
A u g u s t
08, 2007
Sample In format ion
Matrix: SOIL
Locat ion Code:
VHB-MA
Rush Request :
P.O.#:
10231
Tel.
(860) 645·1 102 Fax (860)
645-0823
FOR:
Attn:
Mr.
Mike Bastoni
Vanasse Hangen Brustlin,
Inc.
101
Walnut Stree t
P.O.
Box
9151
Watertown,
MA 02471-9151
Custody
In fo rmat ion
Collec ted by:
Received by: LB
Analyzed by: see
"By"
be low
D ate
07/25/07
07/27/07
Time
9:45
16:30
Laboratorx Data
SDG
J.D.:
GAJ36104
Phoenix J.D.: AJ36105
Clien t ID:
CREME
SS-2
P a r a m e t e r R e s u l t
R L
U n i t s
D a t e
T i m e
By R e f e r e n c e
Silver
< 0.33
0.33
mg/Kg
07/31107
EKT
SW6010
Arsenic 4.68
0.66
mg/Kg
07/31107
EKT
SW6010
Barium 43 0.33 mg/Kg 07/31107
EKT
SW6010
Beryllium < 0.27
0.27
mg/Kg
07/31107
EKT
SW6010
Cadmium
< 0.33 0.33 mg/Kg
07/31107
EKT
SW6010
Chromium
10.6 0.33 mg/Kg
07/31/07
EKT
SW6010
Mercury
- Soil
< 0.10 0.10 mg/kg 07/31/07
RS
SW-7471
Nickel 8.68
0.33
mg/Kg
07/31107
EKT
SW6010
Lead
52.3
0.33 mg/Kg 07/31107
EKT
SW6010
Antimony
< 3.32
3.32 mg/Kg 07/31107
EKT
SW6010
Selenium
< 1.66
1.66
mg/Kg
07/31107
EKT
SW6010
Thallium
<
3.32
3.32 mg/Kg 07/31/07
EKT
SW6010
Vanadium 21.1 0.33 mg/Kg 07/31/07
EKT
6010
Zinc 51.3
0.33 mg/Kg 07/31107
EKT
SW6010
Percent Solid 94 %
07/27/07
PU/IDB
E160.3
Mercury Digestion
Completed
07/31/07
D
SW7471
EPH Extraction
Completed
07/27/07
SUP/K
3545
Ext. Petroleum Hydrocarbons
Completed
08/03/07
JH
MADEP EPH-04
Soil Extraction for PCB
Completed
07/30/07
JCIE
SW3545
Total Metals Digest
Completed
07/27/07
AGP
SW846- 3050
P o l y c h l o r i n a t e d Bi32henyls
PCB-1016
ND
380
ug/Kg
08/01107
JH
SW8082
PCB-1221
ND
380
ug/Kg
08/01107
JH
SW8082
PCB-1232
ND
380 ug/Kg 08/01/07
JH
SW8082
PCB-1242
ND
380 ug/Kg 08/01107
JH
SW8082
Page 3 of34
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Client
ID:
CREME SS-2
Phoenix .D.:
AJ36105
Parameter
Result RL
Units
Date Time By Reference
PCB-1248
ND
380
ug/Kg
08/01107
JH
sw 8082
PCB-1254
ND
380
ug/Kg
08/01107
JH
SW8082
PCB-1260
ND
380
ug Kg
08/01/07
JH
SW8082
PCB-1262 ND 380 ug Kg 08/01107
JH
SW8082
PCB-1268
ND
380 ug/Kg
08/01/07
JH
SW8082
QA/QC Surrogates
%
DCBP (Surrogate Rec) 82
%
08/01107
JH
sw
8082
% TCMX (Surrogate
Rec)
88
%
08/01107
JH
sw
8082
Comments:
If there are
any
questions regarding
this data.
please call
Phoenix
Client Services a t
extension
200.
ND=Not detected
BDL=Below
Detection
Limit
RL=Reporting Limit
Page 4 of34
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E n v i r o n m e n t a l L a b o r a to r i e s . I n c .
587
East
Middle Turnpike
P.O.Box
370, Manchester CT 06040
Tel. (860) 645-1102 Fax (860) 645-0823
Analysis Report
FOR: Attn: Mr. Mike Bastoni
Vanasse Hangen
Brustlin,
Inc.
101 Walnut Stree t
ugus t
08, 2007
Samp le
In fo rmat ion
Matrix: SOIL
Locat ion Code: VHB-MA
Ru s h Request :
P.O.#: 10231
P.O. Box 9151
Watertown,
MA 02471-9151
Custody In fo rmat ion
Collected by:
Received
by:
LB
Analyzed
by:
see "By" below
Date
07/25/07
07/27/07
Time
10:15
16:30
Laboratory
Data
SDG
.D.:
GAJ36104
Clien t ID: CREME
SS-3
P a r a m e t e r R e s u l t
Silver
< 0.36
Arsenic
5.89
Barium 28.5
Beryllium
<
0.29
Cadmium
<
0.36
Chromium 10.7
Mercury -Soil 0.11
Nickel 10.6
Lead 53.2
Antimony
< 3.63
Selenium
<
1.82
Thallium
<
3.63
Vanadium 22.4
Zinc 53.2
Percent Solid 97
Mercury Digestion
Completed
EPH Extraction Completed
Ext. Petroleum Hydrocarbons
Total Metals Digest
Asbestos
Completed
Completed
ND
R L
Uni t s
D a t e
0.36 mg/Kg
07/31107
0.73
mg/Kg
07/31/07
0.36
mg/Kg
07/31107
0.29 mg/Kg 07/31107
0.36 mg/Kg 07/31107
0.36 mg/Kg 07/31107
0.10
mg/kg
07/31107
0.36 mg/Kg 07/31107
0.36
mg/Kg
07/31107
3.63 mg/Kg
07/31107
1.82
mg/Kg
07/31107
3.63
mg/Kg
07/31107
0.36
mg/Kg
07/31107
0.36 mg/Kg
07/31107
%
07/27/07
07/31107
07/27/07
08/03/07
07/27/07
%
08/03/07
Page
5 of34
Phoenix .D.: AJ36106
T i m e
B y
R e f e r e n c e
EKT
SW6010
EKT
SW6010
EKT
SW6010
EKT
SW6010
EKT
SW6010
EKT
SW6010
RS
SW-7471
EKT
SW6010
EKT
SW6010
EKT
SW6010
EKT
SW6010
EKT
SW6010
EKT
6010
EKT
SW6010
PU/IDB
£160.3
D
SW7471
SUP/K
3545
JH
MADEP EPH-04
AGP
SW846- 3050
•
E600/M482020
8/11/2019 Brimbal Ave. - Environmental Notification Form - 9.2.14 - Volume 2 of 2
http://slidepdf.com/reader/full/brimbal-ave-environmental-notification-form-9214-volume-2-of-2 345/798
Comments:
*Asbestos analyzed by MA certified lab #M-NJ337. No Asbestos was detected in this sample.
If there are
any
questions
regarding
this
data, please call
Phoenix
Client
Services
at extension
200.
ND=Not
detected
BDL=Below Detection Limit
RL=Reporting
Limit
?#
..
~
ugust 08, 2007
Page 6 of34
8/11/2019 Brimbal Ave. - Environmental Notification Form - 9.2.14 - Volume 2 of 2
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Environmenta l Laborator ies , Inc.
587
East
Middle Turnpike P.O.Box 370, Manchester
CT 06040
Analysis Report
August
08, 2007
Sample Information
Matrix: SOIL
Location
Code: VHB-MA
Rush
Request:
P.O.#:
10231
Client ID:
Parameter
Silver
Arsenic
Barium
Beryllium
Cadmium
Chromium
Mercury - Soil
Nickel
Lead
Antimony
Selenium
Thallium
Vanadium
Zinc
Percent Solid
Mercury Digestion
Total
Metals
Digest
Asbestos
CREME
SS-4
TeL (860) 645·1
102
Fax (860) 645-0823
FOR:
Attn:
Mr.
Mike Bastoni
Vanasse
Hangen Brustlin.
Inc.
101
Walnut Street
P.O. Box
9151
Watertown, MA 02471-9151
Custody Information
Collected by:
Received by: LB
Analyzed
by:
see
"By" below
Date
07/25/07
07/27/07
Time
9:35
16:30
Laboratory Data
s·Dc
J.D.: GAJ36104
Phoenix
J.D.: AJ36107
Result
<
0.37
6.49
45
<
0.29
< 0.37
14.5
0.11
14
85.1
<
3.67
<
1.84
<
3.67
47.5
95.8
92
Completed
Completed
ND
RL
Units
Date
0.37 mg/Kg 07/31107
0.73 mg/Kg 07/31107
0.37 mg/Kg
07/31/07
0.29
mg Kg
07/31107
0.37
mg Kg
07/31107
0.37
mg/Kg
07/31107
0.10 mglkg
07/31107
0.37
mg/Kg
07/31107
0.37 mg/Kg 07/31107
3.67
mg/Kg
07/31107
1.84
mg/Kg
07/31/07
3.67
mg/Kg
07/31107
0.37
mg/Kg
07/31107
0.37 mg/Kg
07/31/07
%
07/27/07
07/31107
07/27/07
%
08/03/07
Page 7
of34
Time
By
Reference
EKT
SW6010
EKT
SW6010
EKT
SW6010
EKT
SW6010
EKT
SW60l0
EKT
SW60l0
RS SW-7471
EKT
SW6010
EKT
SW6010
EKT
SW6010
EKT
SW6010
EKT
SW6010
EKT
6010
EKT
SW6010
PU/IDB
E160.3
D
SW7471
AGP
SW846-
3050
•
E600/M482020
8/11/2019 Brimbal Ave. - Environmental Notification Form - 9.2.14 - Volume 2 of 2
http://slidepdf.com/reader/full/brimbal-ave-environmental-notification-form-9214-volume-2-of-2 347/798
Comments:
*Asbest os analyzed by MA certified lab #M-NJ337. No Asbestos was detected
in
this sample.
If
there are any questions regarding
this
data.
please
call Phoenix
Client
Services
at extension
200.
ND=Not detected
BDL=Below Detectio n
Limit RL=Reporting Limit
~ : . . , . ~ t & ~
August 08, 2007
Page 8 of34
8/11/2019 Brimbal Ave. - Environmental Notification Form - 9.2.14 - Volume 2 of 2
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E n v i r o n m e n t a l L a b o r a t o ri e s , I n c .
587 East Middle Turnpike
P.O.Box
370, Manchester
CT 06040
Tel.
(860) 645-1102
Fax
(860) 645-0823
Analysis Report
FOR: Attn: Mr. Mike Bastoni
Vanasse Hangen Brustlin, Inc.
101 Walnut Stree t
ugus t 08,
2007
P.O. Box 9151
Watertown, MA
02471-9151
SamQle
In fo rmat ion Custody In fo rmat ion
Date
Time
Matrix: SOIL
Collected by: 07/25/07 15:00
Locat ion
Code: VHB-MA
Received
by:
LB 07/27/07 16:30
Ru s h Request :
Analyzed
by:
see "By" below
P.O.#:
10231
Laboratory Data
SOC
J.D.:
GAJ36104
Phoenix J.D.: AJ36108
Clien t ID:
CREME
LGP-1
(0-1)
P a r a m e t e r R e s u l t
R L
Uni t s
D a t e T i m e
By
R e f e r e n c e
Silver < 0.37
0.37
mg/Kg
07/31107
EKT
SW6010
Arsenic 4.67
0.74
mg/Kg
07/31/07
EKT
SW6010
Barium 25.4
0.37
mg/Kg
07/31107
EKT
SW6010
Beryllium 0.594 0.3 mg/Kg 07/31107
EKT
SW6010
Cadmium
< 0.37
0.37 mg/Kg 07/31107
EKT
SW6010
Chromium
6.36
0.37 mg/Kg 07/31107
EKT
SW6010
Mercury - Soil
<
0.10 0.10 mg/kg 07/31/07
RS
SW-7471
Nickel 7.86
0.37
mg/Kg 07/31107
EKT
SW6010
Lead 58.7
0.37
mg/Kg
07/31/07
EKT
SW6010
Antimony
< 3.71
3.71
mg/Kg
07/31107
EKT
SW6010
Selenium
<
1.85
1.85
mg/Kg
07/31/07
EKT
SW6010
Thallium
<
3.71
3.71
mg Kg
07/31/07
EKT
SW6010
Vanadium
40.2
0.37
mg/Kg
07/31107
EKT
6010
Zinc 66.5
0.37
mg/Kg
07/31107
EKT
SW6010
Percent Solid
95
% 07/27/07
PU/IDB
El60.3
Mercury Digestion
Completed
07/31107
D
SW7471
EPH Extraction
Completed 07/27/07
SUP/K
3545
Ext. Petroleum Hydrocarbons
Completed 08/03/07
JH
MADEP EPH-04
Total Metals Digest
Completed
07/27/07
AGP
SW846- 3050
Page 9
of34
8/11/2019 Brimbal Ave. - Environmental Notification Form - 9.2.14 - Volume 2 of 2
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Comments:
If there are
any questions regarding
this
data, please call
Phoenix
Client Services
at
extension
200.
ND=Not
detected BDL=Below Detection
Limit
RL=Reporting
Limit
f?f f;
' " '
ugust 08, 2007
Page 10 of34
8/11/2019 Brimbal Ave. - Environmental Notification Form - 9.2.14 - Volume 2 of 2
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Environmental
Laboratories, Inc.
587
East Middle Turnpike. P.O.Box
370,
Manchester
CT
06040
Tel. (860) 645-1102 Fax (860) 645-0823
Analysis Report
FOR: Attn: Mr. Mike Bastoni
Vanasse Hangen Brustlin. Inc.
101
Walnut
Stree t
ugust
08, 2007
Samp le
In fo rmat ion
Matrix:
SOIL
Locat ion Code: VHB-MA
Rush
Request :
P.O.#: 10231
P.O. Box 9151
Watertown. MA
02471-9151
Custody In fo rmat ion
Collec ted
by:
Received
by:
LB
Analyzed
by:
see "By"
be low
D at e
07/25/07
07/27/07
Time
15:00
16:30
Laboratory
Data
CREME
LGP-2 {0-1)
SDG
J.D.:
GAJ36104
Clien t ID:
P a r a m e t e r
Silver
Arsenic
Barium
Beryllium
Cadmium
Chromium
Mercury
- Soil
Nickel
Lead
Antimony
Selenium
Thallium
Vanadium
Zinc
Percent Solid
Mercury Digestion
EPH Extraction
Ext. Petroleum Hydrocarbons
R e s u l t
<
0.42
7.16
32.1
0.434
< 0.42
13.6
<
0.13
14.6
386
< 4.22
< 2.11
< 4.22
29.4
74.4
78
Completed
Completed
Completed
Soil Extraction
for PCB
Completed
Total Metals Digest
Completed
P o l y c h l o r i n a t e d B i p h e n y l s
PCB-1016
ND
PCB-1221
ND
PCB-1232
ND
PCB-1242
ND
R L Uni t s
0.42
mg/Kg
0.84
mg/Kg
0.42 mg/Kg
0.34 mg/Kg
0.42 mg/Kg
0.42 mg/Kg
0.13
mg/kg
0.42
mg/Kg
0.42 mg/Kg
4.22 mg/Kg
2.11
mg/Kg
4.22 mg/Kg
0.42 mg/Kg
0.42 mg/Kg
%
310
ug/Kg
310
ug/Kg
310 ug/Kg
310 ug/Kg
Page 11 of34
Phoenix J.D.: AJ36109
D a t e T i m e
B y
R e f e r e n c e
07/31107
EKT
SW6010
07/31107
EKT
SW6010
07/31/07
EKT
SW6010
07/31/07
EKT
SW6010
07/31107
EKT
SW6010
07/31107
EKT
SW6010
07/31107
RS
SW-7471
07/31107
EKT
SW6010
07/31107
EKT
SW6010
07/31107
EKT
SW6010
07/31107
EKT
SW6010
07/31107
EKT
SW6010
07/31107
EKT
6010
07/31107
EKT
SW6010
07/27/07
PU/IDB El60.3
07/31107
D
SW7471
07/27/07
SUP/K
3545
08/03/07
JH
MADEP EPH-04
07/27/07
SJC/E
SW3545
07/27/07
AGP
SW846- 3050
07/30/07
JH
sw 8082
07/30/07
JH
sw
8082
07/30/07
JH
SW8082
07/30/07
JH
SW8082
8/11/2019 Brimbal Ave. - Environmental Notification Form - 9.2.14 - Volume 2 of 2
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Client
ID:
CREME LGP-2 {0-1)
Phoenix
.D.: AJ36109
Parameter Result RL
Units
Date
Time By
Reference
PCB-1248
ND
310 ug/Kg
07/30/07
JH
SW8082
PCB-1254
ND 310
ug/Kg
07/30/07
JH
SW8082
PCB-1260
ND 310
ug Kg
07/30/07
JH
sw 8082
PCB-1262
ND
310 ug Kg 07/30/07
JH
sw 8082
PCB-1268
ND
310
ug Kg 07/30/07
JH
sw
8082
QNQC Surrogates
%
DCBP (Surrogate Rec)
106
%
07/30/07
JH
SW8082
% TCMX (Surrogate
Rec)
123
%
07/30/07
JH
SW8082
Comments:
I f
there are
any questions regarding this data. p lease call Phoenix Client Services
at
extension 200.
ND=Not
detected BDL=Below Detection Limit RL=Reporting Limit
£ ? ] ~ , , ~ . _
August 08, 2007
Page
12 of
34
8/11/2019 Brimbal Ave. - Environmental Notification Form - 9.2.14 - Volume 2 of 2
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E n v i r o n m e n t a l L a b o r a t o r i e s , Inc .
587 East Middle Turnpike P.O.Box 370, Manchester CT
06040
Tel.
(860)
645-1102 Fax
(860)
645-0823
Analysis Report
FOR: Attn: Mr. Mike Bastoni
Vanasse
Hangen Brustlin,
Inc.
101 Walnut Street
ugus t 08, 2007
P.O.
Box
9151
Watertown,
MA 02471-9151
Samgle Informat ion
Custod:,:
Informat ion Date
Time
Matrix : SOIL
Collected by:
07/25/07
10:00
Location
Code:
VHB-MA
Received by:
LB
07/27/07
16:30
Rush Request:
Analyzed by:
see
"By"
below
P.O.#:
10231
Laborator_y
Data
SDG
.D.:
GAJ36104
Phoenix .D.:
AJ36110
Client ID:
CREME
VHB-101 (0-2)
P a r a m e t e r
Resu l t
R L
Uni t s
D a t e
T i m e
B y
Reference
Silver
<
0.33
0.33
mg/Kg 07131107
EKT
SW6010
Arsenic 7.04 0.66 mg/Kg 07/3 /07
EKT
SW6010
Barium
33.9
0.33
mg/Kg
07/31107
EKT
SW6010
Beryllium
<
0.27 0.27
mg/Kg
07/31107
EKT
SW6010
Cadmium
<
0.33 0.33 mg/Kg 07131107
EKT
SW6010
Chromium
15.6 0.33 mg/Kg 07131107
EKT
SW6010
Mercury
-
Soil
0.84 0.10
mglkg
07/3 107
RS
SW-7471
Nickel 11.8 0.33
mg Kg
07/31107
EKT
SW6010
Lead 81.6
0.33
mg/Kg 07/3 107
EKT
SW6010
Antimony <
3.32
3.32
mg Kg
07/3 107
EKT
SW6010
Selenium
<
1.66
1.66
mg Kg
07/3 /07
EKT
SW6010
Thallium
<
3.32
3.32
mg Kg
07/31107
EKT
SW6010
Vanadium
23.2
0.33
mg/Kg
07/31107
EKT
6010
Zinc 73.4
0.33
mg/Kg
07/3 107
EKT
SW6010
Percent Solid
93 %
07/27/07
PU/IDB
E160.3
Mercury Digestion Completed 07131107
D
SW7471
EPH Extraction
Completed
07/27/07
SUP/K
3545
Ext. Petroleum Hydrocarbons
Completed
08/03/07
JH
MADEP EPH-04
Total Metals Digest
Completed 07/27/07
AGP
SW846- 3050
Page 13
of34
8/11/2019 Brimbal Ave. - Environmental Notification Form - 9.2.14 - Volume 2 of 2
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Comments:
If
there are any questions regarding
this data, please
call Phoenix
Client
Services
at extension
200.
ND=Not
detected BDL=Below Detection Limit
RL=Reporting
Limit
Page
14 of34
8/11/2019 Brimbal Ave. - Environmental Notification Form - 9.2.14 - Volume 2 of 2
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Environmental Laboratories, Inc.
587 East Middle Turnpike P.O.Box 370, Manchester CT
06040
Tel.
(860) 645-1102 Fax (860)
645-0823
Analysis Report
FOR: Attn: Mr. Mike
Bastoni
Vanasse
Hangen
Brustlin.
Inc.
101
Walnut
Street
ugus t
08, 2007
P.O. Box
9151
Watertown,
MA 02471-9151
Samg le
Informat ion
Custodx In fo rmat ion Date
Matrix : SOIL
Col lec ted
by: 07/25/07
Locat ion Code: VHB-MA Received
by:
LB
07/27107
Rush
Request :
Analyzed
by:
see
"By"
below
P.O.#:
10231
Time
14:00
16:30
Laboratory Data
SDG
I.D.:
GAJ36104
Phoenix I.D.:
AJ36111
Clien t ID:
CREME
VHB-102 (0-2)
P a r a m e t e r
R e s u l t
R L
Uni t s
D a t e T i m e
B y
R e f e r e n c e
Silver
3.24
0.35 mg/Kg
07/31107
EKT
SW6010
Arsenic
8.71
0.71 mg/Kg
07/31107
EKT
SW6010
Barium
187 0.35
mg/Kg
07/31107
EKT
SW6010
Beryllium <
0.28
0.28 mg/Kg 07/31/07
EKT
SW6010
Cadmium
0.996 0.35 mg/Kg 07/31/07
EKT
SW6010
Chromium Ill
0.35 mg/Kg 07/31/07
EKT
SW6010
Mercury - Soil
0.42 0.10
mgikg
07/31107
RS
SW-7471
Nickel
177
0.35 mg/Kg
07/31/07
EKT
SW6010
Lead
26600
355 mg/Kg
08/06/07
EK
SW6010
Antimony
14
3.55 mg/Kg
07/31107
EKT
SW6010
Selenium
< 1.77
1.77 mg/Kg
07/31107
EKT
SW6010
Thallium
< 3.55 3.55
mg/Kg
07/31107
EKT
SW6010
Vanadium
26.3 0.35
mg Kg
07/31107
EKT
6010
Zinc
551
3.55 mg Kg
08/01107
EK
SW60 0
Percent Solid
94
%
07/27/07
PU/IDB
E160.3
Mercury Digestion
Completed 07/31/07
D
SW7471
EPH Extraction Completed
07/27/07
SUP/K
3545
Ext. Petroleum Hydrocarbons
Completed 08/03/07
JH
MADEP EPH-04
Soil Extraction for PCB
Completed 07/27/07
SJC/E
SW3545
Total Metals Digest
Completed 07/27/07
AGP
SW846- 3050
P o l y c h l o r i n a t e d B i g h e n y l s
PCB-1016
ND
3800 ug Kg
08/01/07
JH
sw
8082
PCB-1221
ND
3800 ug Kg
08/01/07
JH
sw 8082
PCB-1232
ND
3800 ug/Kg
08/01107
JH
SW8082
PCB-1242
ND 3800
ug/Kg
08/01/07
JH
SW8082
Page 15
of34
8/11/2019 Brimbal Ave. - Environmental Notification Form - 9.2.14 - Volume 2 of 2
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8/11/2019 Brimbal Ave. - Environmental Notification Form - 9.2.14 - Volume 2 of 2
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Environmen tal Laboratories, Inc.
587
East
Middle Turnpike P.O.Box 370, Manchester CT
06040
Tel. (860) 645-1102
Fax
(860) 645-0823
Analysis Report
FOR: Attn: Mr. Mike Bastoni
Vanasse
Hangen
Brustlin.
Inc.
A u g u s t 08, 2007
101 Walnut Stree t
P.O.
Box
9151
Watertown.
MA 02471-9151
Samg le I n f o rma t io n
Custody In fo rmat ion D ate
Time
Matr ix:
SOIL
Collec ted by: 07/25/07 10:30
Locat ion Code: VHB-MA
Received by:
LB 07/27/07 16:30
Rush Request :
Analyzed by:
s ee
"By"
be low
P.O.#:
10231
Laboratorx Data
SDG
J.D.:
GAJ36104
Phoenix J.D.: AJ36112
Clien t ID:
CREME VHB-1 01 (15-17)
P a r a m e t e r R e s u l t R L
U n i t s
D a t e T i m e
By
R e f e r e n c e
Silver
< 0.36
0.36
mg/Kg
07/31107
EKT
SW6010
Arsenic 6.42 0.72
mg/Kg
07/31107
EKT
SW6010
Barium 30.4 0.36 mg/Kg 07/31107
EKT
SW6010
Beryllium
0.499
0.29
mg/Kg 07/31/07
EKT
SW6010
Cadmium
< 0.36
0.36
mg/Kg 07/31107
EKT
SW6010
Chromium
18.8
0.36
mg/Kg 07/31/07
EKT
SW6010
Mercury Soil
< 0.10 0.10 mg/kg 07/31107
RS
SW-7471
Nickel
15.2
0.36
mg/Kg
07/31107
EKT
SW6010
Lead 2.28 0.36
mg/Kg
07/31107
EKT
SW6010
Antimony
< 3.58
3.58
mg/Kg
07/31107
EKT
SW6010
Selenium
< 1.79
1.79
mg/Kg
07/31107
EKT
SW6010
Thallium
< 3.58 3.58 mg/Kg 07/31107
EKT
SW6010
Vanadium
24.1 0.36 mg/Kg 07/31107
EKT
6010
Zinc 35.4 0.36 mg/Kg 07/31107
EKT
SW6010
Percent Solid
93 % 07/27/07
PU/IDB
E160.3
Field Extraction
Completed
07/25/07
BP
SW5035
Mercury Digestion
Completed
07/31/07
D
SW7471
EPH
Extraction
Completed
07/27/07
SUP/K
3545
Ext. Petroleum Hydrocarbons
Completed
08/03/07
JH
MADEP EPH-04
Total Metals Digest
Completed
07/27/07
AGP
SW846- 3050
Vola t i l e s
1,1,1,2-Tetrachloroethane
ND
220
ug/Kg
07/28/07
RIJ
SW8260
1,1, 1-Trichloroethane
ND
220
ug Kg
07/28/07
RIJ
SW8260
1,1 ,2,2-
Tetrachloroethane
ND 220
ug/Kg
07/28/07
R/J
SW8260
1,
1,2-Trichloroethane
ND 220 ug/Kg 07/28/07
R/J
SW8260
Page
17
of34
8/11/2019 Brimbal Ave. - Environmental Notification Form - 9.2.14 - Volume 2 of 2
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Client
ID:
CREME
VHB-101 (15-17)
Parameter Result
1, 1-Dichloroethane
1,1-Dichloroethene
1, 1-Dichloropropene
1,2,3-Trichlorobenzene
1 2,3-Trichloropropane
1,2,4-Trichlorobenzene
1 2,4-Trimethylbenzene
1,2-Dibrorno-3-chloropropane
1,2-Dichlorobenzene
1,2-
Dichloroethane
1,2-Dichloropropane
1,3,5-Trimethylbenzene
1,3-Dichlorobenzene
1 , 3 - D i c h l o r ~ p r o p a n e
1,4-Dichlorobenzene
2,2-Dichloropropane
2-Chlorotoluene
2-HeXanone
2-Isopropyl oluene
4-Chlorotoluene
4-Methyl-2-pentanone
Acetone
Acrylonitrile
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
Carbon
Disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
cis-1
,2-
Dichloroethene
cis-1
,3-
Dichloropropene
Dibromochloromethane
Dibromoethane
Dibromomethane
Dichlorodifluoromethane
Ethylbenzene
Hexachlorobutadiene
Isopropylbenzene
m&p-Xylene
Methyl Ethyl Ketone
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
RL
220
220
220
220
220
220
220
220
220
220
220
220
220
220
220
220
220
1100
220
220
1100
4400
440
220
220
220
220
220
220
220
220
220
220
220
220
220
220
220
220
220
220
220
220
220
220
2600
Units
ug/Kg
ug/Kg
ug/Kg
ug/Kg
ug Kg
ug Kg
ug Kg
ug/Kg
ug/Kg
ug/Kg
ug/Kg
ug/Kg
ug/Kg
ug Kg
ug/Kg
ug/Kg
ug Kg
ug/Kg
ug/Kg
ug/Kg
ug/Kg
ug/Kg
ug/Kg
ug/Kg
ug/Kg
ug/Kg
ug/Kg
ug/Kg
ug/Kg
ug/Kg
ug/Kg
ug Kg
ug/Kg
ug/Kg
ug/Kg
ug Kg
ug/Kg
ug/Kg
ug Kg
ug Kg
ug/Kg
ug/Kg
ug/Kg
ug/Kg
ug/Kg
ug/Kg
Page 18 of 34
Phoenix
.D.:
AJ36112
Date Time
By
Reference
07/28/07
07/28/07
07/28/07
07/28/07
07/28/07
07/28/07
07/28/07
07/28/07
07/28/07
07/28/07
07/28/07
07/28/07
07/28/07
07/28/07
07/28/07
07/28/07
07/28/07
07/28/07
07/28/07
07/28/07
07/28/07
07/28/07
07/28/07
07/28/07
07/28/07
07/28/07
07/28/07
07/28/07
07/28/07
07/28/07
07/28/07
07/28/07
07/28/07
07/28/07
07/28/07
07/28/07
07/28/07
07/28/07
07/28/07
07/28/07
07/28/07
07/28/07.
07/28/07
07/28/07
07/28/07
07/28/07
RIJ SW8260
RIJ SW8260
R/J SW8260
RIJ SW8260
RIJ SW8260
RIJ SW8260
R/J
SW8260
RIJ SW8260
RIJ SW8260
RIJ SW8260
RIJ SW8260
RIJ SW8260
RIJ
SW8260
RIJ SW8260
RIJ SW8260
R/J SW8260
RIJ SW8260
RIJ SW8260
RIJ SW8260
RIJ SW8260
RIJ SW8260
RIJ SW8260
RIJ SW8260
RIJ SW8260
RIJ SW8260
RIJ SW8260
RIJ SW8260
RIJ SW8260
RIJ SW8260
RIJ SW8260
RIJ SW8260
RIJ SW8260
RIJ SW8260
RIJ SW8260
RIJ SW8260
RIJ SW8260
RIJ SW8260
RIJ SW8260
RIJ SW8260
RIJ SW8260
RIJ SW8260
RIJ SW8260
RIJ SW8260
RIJ SW8260
RIJ SW8260
RIJ SW8260
8/11/2019 Brimbal Ave. - Environmental Notification Form - 9.2.14 - Volume 2 of 2
http://slidepdf.com/reader/full/brimbal-ave-environmental-notification-form-9214-volume-2-of-2 358/798
Client ID: CREME VHB-101 (15-17) Phoenix .D.: AJ36112
Parameter Result
RL
Units
Date
Time
By
Reference
Methyl t-butyl ether (MTBE) ND
220
ug/Kg
07/28/07
R/J
SW8260
Methylene chloride ND
440
ug/Kg
07/28/07
R J
SW8260
n-Butylbenzene
ND
220
ug Kg
07/28/07
R J
SW8260
n-Propylbenzene
ND
220
ug/Kg
07/28/07
R/J
SW8260
Naphthalene ND
220
ug/Kg
07/28/07
R/J
SW8260
o-Xylene
ND 220 ug/Kg 07/28/07
R/J
SW8260
p- Isopropyltoluene
ND
220
ug Kg
07/28/07
R J
SW8260
sec-Butylbenzene
ND
220 ug/Kg 07/28/07
R J
SW8260
Styrene ND
220
ug/Kg
07/28/07
R/J
SW8260
tert-Butylbenzene ND
220
ug/Kg
07/28/07
R/J
SW8260
Tetrachloroethene
ND
220
ug Kg
07/28/07
R/J
SW8260
Tetrahydrofuran (1HF)
ND
440
ug/Kg
07/28/07
R/J
SW8260
Toluene ND
220
ug/Kg
07/28/07
R/J
SW8260
Total Xylenes ND 220 ug/Kg 07/28/07
R/J
SW8260
trans-1 ,2-Dichloroethene
ND
220
ug/Kg
07/28/07
R/J
SW8260
trans-1,3-Dichloropropene ND
220
ug Kg
07/28/07
R/J
SW8260
trans-1 ,4-dichloro-2-butene
ND
440
ug/Kg
07/28/07
R J
SW8260
Trichloroethene
ND
220
ug/Kg
07/28/07
R J
SW8260
Trichlorofluoromethane
ND
220
ug/Kg
07/28/07
R J
SW8260
Trichlorotrifluoroethane ND 220 ug/Kg
07/28/07
R J
SW8260
Vinyl chloride ND 220 ug/Kg
07/28/07
R J
SW8260
QA/OC Surrogates
% 1,2-dichlorobenzene-d4
99
%
07/28/07
R/J
SW8260
%
Bromofluorobenzene
91 %
07/28/07
R/J
SW8260
% Dibromofluoromethane 93 %
07/28/07
R J
SW8260
% Toluene-dS 96 %
07/28/07
R/J
SW8260
Comments:
If there are
any questions
regarding this
data, please call Phoenix Client Services at extension
200.
ND=No t detected BDL=Below Detection
Limit RL=Reporting Limit
Page 19
of34
8/11/2019 Brimbal Ave. - Environmental Notification Form - 9.2.14 - Volume 2 of 2
http://slidepdf.com/reader/full/brimbal-ave-environmental-notification-form-9214-volume-2-of-2 359/798
8/11/2019 Brimbal Ave. - Environmental Notification Form - 9.2.14 - Volume 2 of 2
http://slidepdf.com/reader/full/brimbal-ave-environmental-notification-form-9214-volume-2-of-2 360/798
Client
ID: CREME VHB-102 (10-12)
Parameter
Result
1,1-Dichloroethane
1, 1-Dichloroethene
1, 1-Dichloropropene
1 2,3-Trichlorobenzene
1 2,3-Trichloropropane
1 2,4-Trichlorobenzene
1,2,
4-Trimethylbenzene
1,2-Dibromo-3-chloropropane
1,2-Dichlorobenzene
1,2-Dichloroethane
1,2-Dichloropropane
1 3,5-Trimethylbenzene
1
3-
Dichlorobenzene
1,3-Dichloropropane
1,4-Dichlorobenzene
2.2-Dichloropropane
2-Chlorotoluene
2-Hexanone
2-Isopropyltoluene
4-Chlorotoluene
4-Methyl-2-pentanone
Acetone
Acrylonitrile
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
Carbon Disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
cis-1 ,2-Dichloroethene
cis-1 ,3-Dichloropropene
Dibromochloromethane
Dibromoethane
Dibromomethane
Dichlorodifluoromethane
Ethylbenzene
Hexachlorobutadiene
lsopropylbenzene
m&p-Xylene
Methyl Ethyl Ketone
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
ND
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
RL
250
250
250
250
250
250
250
250
250
250
250
250
250
250
250
250
250
1200
250
250
1200
4900
490
250
250
250
250
250
250
250
250
250
250
250
250
250
250
250
250
250
250
250
250
250
250
2900
Units
ug Kg
ug/Kg
ug Kg
ug Kg
ug Kg
ug/Kg
ug Kg
ug/Kg
ug/Kg
ug Kg
ug Kg
ug Kg
ug/Kg
ug/Kg
ug/Kg
ug Kg
ug/Kg
ug Kg
ug Kg
ug/Kg
ug/Kg
ug/Kg
ug/Kg
ug Kg
ug Kg
ug/Kg
ug/Kg
ug/Kg
ug/Kg
ug/Kg
ug/Kg
ug/Kg
ug/Kg
ug/Kg
ug/Kg
ug Kg
ug Kg
ug/Kg
ug/Kg
ug/Kg
ug/Kg
ug/Kg
ug/Kg
ug Kg
ug Kg
ug Kg
Page 21 of 34
Phoenix 1.0.:
AJ36113
Date Time
By
Reference
07/28/07
07/28/07
07/28/07
07/28/07
07/28/07
07/28/07
07/28/07
07/28/07
07/28/07
07/28/07
07/28/07
07/28/07
07/28/07
07/28/07
07/28/07
07/28/07
07/28107
07/28/07
07/28/07
07/28/07
07/28/07
07/28/07
07/28/07
07/28/07
07/28/07
07/28/07
07/28/07
07/28/07
07/28/07
07/28/07
07/28/07
07/28/07
07/28/07
07/28/07
07/28107
07/28/07
07/28/07
07/28/07
07/28/07
07/28/07
07/28/07
07/28/07
07/28/07
07/28/07
07/28/07
07/28/07
RIJ SW8260
RIJ
SW8260
R/J SW8260
RIJ SW8260
RIJ
SW8260
RIJ SW8260
RIJ
SW8260
RIJ SW8260
RIJ SW8260
RIJ SW8260
R/J SW8260
RIJ SW8260
RIJ
SW8260
RIJ SW8260
RIJ SW8260
R/J SW8260
RIJ SW8260
RIJ SW8260
RIJ SW8260
RIJ SW8260
RIJ SW8260
RIJ SW8260
RIJ SW8260
RIJ SW8260
RIJ SW8260
RIJ SW8260
RIJ SW8260
RIJ
SW8260
RIJ
SW8260
RIJ SW8260
RIJ SW8260
RIJ SW8260
RIJ SW8260
RIJ SW8260
RIJ SW8260
RIJ SW8260
RIJ
SW8260
RIJ SW8260
RIJ
SW8260
R/J SW8260
RIJ SW8260
RIJ SW8260
RIJ SW8260
RIJ
SW8260
RIJ
SW8260
RIJ SW8260
8/11/2019 Brimbal Ave. - Environmental Notification Form - 9.2.14 - Volume 2 of 2
http://slidepdf.com/reader/full/brimbal-ave-environmental-notification-form-9214-volume-2-of-2 361/798
Client
ID:
CREME VHB-102 (10-12)
Phoenix J.D.:
AJ36113
Parameter Result
RL
Units
Date Time
By Reference
Methyl t-butyl ether (MTBE)
ND
250
ug/Kg
07/28/07
R/J
SW8260
Methylene chloride
ND
490
ug/Kg
07/28/07
R/J
SW8260
n-Butylbenzene
ND
250
ug/Kg
07/28/07
R/J
SW8260
n-Propylbenzene
ND 250 ug/Kg 07/28/07
R/J
SW8260
Naphthalene ND
250
ug Kg
07/28/07
R/J
SW8260
a-Xylene ND 250 ug Kg
07/28/07
R/J
SW8260
p-Isopropyltoluene
ND
250
ug/Kg
07/28/07
R/J
SW8260
sec-Butylbenzene
ND 250 ug/Kg
07/28/07
R/J
SW8260
Styrene ND
250
ug/Kg
07/28/07
R/J
SW8260
tert-Butylbenzene
ND
250
ug/Kg
07/28/07
R/J
SW8260
Tetrachloroethene
ND
250
ug/Kg
07/28/07
R/J
SW8260
Tetrahydrofuran (THF)
ND
490
ug Kg
07/28/07
RIJ
SW8260
Toluene ND 250 ug/Kg 07/28/07
R/J
SW8260
Total Xylenes
ND
250
ug/Kg 07/28/07
R/J
SW8260
trans-
I
,2-Dichloroethene
ND
250
ug/Kg
07/28/07
R/J
SW8260
trans-1 ,3-Dichloropropene
ND
250
ug/Kg
07/28/07
R/J
SW8260
trans- I, 4-dichloro-2-butene
ND
490
ug Kg
07/28/07
R/J
SW8260
Trichloroethene
ND 250 ug/Kg 07/28/07
R/J
SW8260
Trichlorofluoromethane
ND
250
ug Kg 07/28/07
R/J
SW8260
Trichlorotrifluoroethane
ND
250
ug Kg 07/28/07
R/J
SW8260
Vinyl chloride
ND
250
ug/Kg 07/28/07
R/J
SW8260
QAJQC
Surrogates
%
1,2-dichlorobenzene-d4
99 % 07/28/07
R/J
SW8260
%
Bromofluorobenzene
92 % 07/28/07
R/J
SW8260
%
Dibromofluoromethane
104 %
07/28/07
R/J
SW8260
% Toluene-d8
95 %
07/28/07
R/J
SW8260
Comments:
If there are any
questions regarding
this data, please
call Phoenix
Client Services a t extension 200.
ND=Not
detected BDL=Below
Detection
Limit RL=Reporting
Limit
~ # . ~ j & - _ ,
August 08, 2007
Page 22
of34
8/11/2019 Brimbal Ave. - Environmental Notification Form - 9.2.14 - Volume 2 of 2
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DEP REQUIRED EPH DATA REPORTING FORMAT/INFORMATION
SAMPLE INFORMATION
Matrix
Aqueous XX
Soil
Sediment
Other:
Containers
XX
Satisfuctory
Broken
Leaking
Aqueous Preservatives
XXN/A pH<2 _pH>2
Comment:
Temperature
Received on Ice
Received at 4 degrees C XX
Other: See
Chain
Of Custody
Extraction Method
Water: 3510
EPH ANALYTICAL RESULTS
Method for Ranges: MADEP EPH-04
Client ID
Method for Target Analytes: MADEP-EPH-04
I Lab ID
EPH Surrogate Standards
Aromatic: o-terphenyl
Aliphatic: 1-chlorooctadecane
EPH Fractionation Surrogates
Aromatic: 2-Fluorobiphenyl
Aromatic: 2-Bromonaphthalene
Range/Target Analyte
Total TPH
(*I)
Diesel PAH
Target
Analytes
Naphthalene
2-Methyl Naphthalene
Phenanthrene
Acenaphthene
Other PAH Target
Analytes
Acenapthvlene
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(k)fluoranthene
Chrvsene
Dibenzo(a,h )anthracene
Fluoranthene
Fluorene
lndeno(l ,2,3-cd)pyrene
Pyrene
Benzo(ghi)pervlene
C9-C18 Aliphatic Hydrocarbons *1
Cl9-C36
Aliphatic Hydrocarbons *1
Cll-C22 Aromatic Hydrocarbons *1,2
Aliphatic
Surrogate%
Recovery
Aromatic Surrogate % Recovery
Sample Surrogate Acceptance Range
Fractionation Surrogate %Recovery
Fractionation Surrogate %Recovery
ractionation Surr. Acceptance Range
Date Collected
Date Received
Date Extracted:
Date Analyzed
Dilution Factor
%Moisture (soil)
RL
Units
3.30 mg/kg
0.33 mg/kg
0.33 mg/kg
0.33 mg/kg
0.33
mg/kg
0.33
mg/kg
0.33 mg/kg
0.33 mg/kg
0.33 mg/kg
0.33
mg/kg
0.33
mg/kg
0.33
mg/kg
0.33
mg/kg
0.33 mg/kg
0.33 mg/kg
0.33 mg/kg
0.33 m ~ k g
0.33
m ~ k g
3.30
ml')kg
3.30
3.30 mglkg
Soil: 3545
SS-1
SS-2
AJ36104 AJ36105
07/25/07 07125/07
07/27/07 07/27/07
07/27/07 07/27/07
08/01/07 08/01/07
9.0
6.0
51
16
<0.36 <0.34
<0.36
<0.34
2.9
1.3
<0.36 <0.34
1.3 0.45
1.2
0.87
2.6 1.4
2.9
1.4
3.9
2.4
0.7 0.41
3.8 1.9
2.2
1.1
6.4 3.2
0.4 <0.34
0.95 <0.34
5.9 2.7
2
1.1
<3.59
<3.43
<3.59
<3.43
51
16
53
61
76
80
40-140 40-140
94 92
79 63
40-140 40-140
*I Hydrocarbon range data exclude concentrations of any surrogate(s) and/or internal standards eluting in that range.
*2 C
ll-C22
Aromatic Hydrocarbons exclude the concentration
ofTarget
PAH Analytes eluting in that range.
SS-3
AJ36106
07/25/07
07/27/07
07/27/07
08/01/07
3.0
89
0.39
<0.33
4
<0.33
3.2
3.1
5.6
5.5
8.5
2.4
7
3.4
12
0.7
1.6
I I
4.9
<3.29
<3.29
89
44
80
40-140
92
63
40-140
Were all QA/QC procedures REQUIRED by the EPH method followed? XX Yes No
Were all performance/acceptance standards for the required QAIQC procedures achieved? XX Yes
Were any significant modifications made to the EPH method, as specified
in
Section 11.3?
~ * Y e s
*If above question was checked yes, samples were run via GC/MS, otherwise run by G C ~ F I D .
LGP-1 (0-1)
AJ36108
07/25/07
07/27/07
07/27/07
08/01/07
5.0
40
<0.35
<0.35
3.7
<0.35
0.93
1.6
3.1
3.1
5
1.1
4.4
1.9
7.5
0.45
0.41
5.6
1.6
<3.47
<3.47
40
58
81
40-140
79
76
40-140
No
XX No
I attest under the pains andpenalties o perju ry that, based upon my inquiry o hose individuals immediately responsiblefor obtaining the information,
the material contained in this report
is,
to thebel'st,__fmv knowledrze
and
belief, accurate
and
complete.
-ffif.. ...·r
Signature: - . ; - , - - = ~ - , - - - - - -
Printed Name: Johanna Harrington
Position:
Chemist
Date: 8/8/2007
LGP-2 (0-1)
AJ36109
07/25/07
07/27/07
07/27/07
08/01/07
22.0
27
<0.42
<0.42
2
<0.42
0.68
1.2
1.2
1.7
2.5
0.89
2.6
1.3
4
0.5
0.62
3.8
<4.23
<4.23
27
58
94
40-140
88
68
40-140
8/11/2019 Brimbal Ave. - Environmental Notification Form - 9.2.14 - Volume 2 of 2
http://slidepdf.com/reader/full/brimbal-ave-environmental-notification-form-9214-volume-2-of-2 363/798
DEP REQUIRED EPH DATA
REPORTING
FORMAT/INFORMATION
SAMPLE
INFORMATION
Matrix
Aqueous
XX
Soil
Sediment
Other:
Containers
XX
Satisfactory
Broken Leaking
Aqueous Preservatives
XXNIA
___pH<2
___pH>2
Comment:
Temperature
Received on Ice Received at 4 degrees C
XX
Other: See
Chain Of
Custody
Extraction Method
Water: 3510
EPH ANALYTICAL RESULTS
Method for Ranges: MADEP EPH-04 Client lD
Method for Target Analytes: MADEP-EPH-04 LablD
EPH Surrogate Standards
Aromatic: o-terphenyl
Aliphatic: 1-chlorooctadecane
EPH Fractionation Surrogates
Aromatic: 2-Fluorobiphenyl
Aromatic: 2-Bromonaphthalene
Range/Target Analyte
Total TPH
(*I)
Diesel PAH
Target
Analytes
Naphthalene
2-Methyl Naphthalene
Phenanthrene
Acenaphthene
Other
PAH T a r ~ e t
Analytes
Acenapthvlene
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)tluoranthene
Benzo(k)fluoranthene
Chrysene
Dibenzo( a,h )anthracene
Fluoranthene
Fluorene
lndeno(
I
,2.3-cd)pyrene
Pyrene
Benzo(ghi)perylene
C9-C18 Aliphatic Hydrocarbons
*1
C19-C36 Aliphatic Hydrocarbons
*
Cll-C22 Aromatic Hydrocarbons *1,2
Aliphatic Surrogate
%Recovery
Aromatic Surrogate % Recovery
Sample Surrogate Acceptance Range
Fractionation Surrogate% Recovery
Fractionation Surrogate% Recovery
ractionation Surr. Acceptance Range
Date Collected
Date Received
Date Extracted:
Date Analyzed
Dilution Factor
%Moisture
(soil)
RL
Units
3.30 mg/kg
0.33
mg/kg
0.33
mglkg
0.33 mg/kg
0.33
mg/kg
0.33
mg/kg
0.33
mg/kg
0.33 mg/kg
0.33 mg/kg
0.33
mg/kg
0.33
mg/kg
0.33
mg/kg
0.33
mg,kg
0.33 mglkg
0.33
mglkg
0.33 mg/kg
0.33 mg/kg
0.33
mg/kg
3.30
mg/kg
3.30
mg/kg
3.30 mg/kg
Soil: 3545
VHB-101 (0-2) VHB-102 (0-2)
AJ36110 AJ36111
07/25/07 07/25/07
07/27/07
07/27/07
07/27/07 07/27/07
08/01/07
08/01/07
7.0 6.0
27
50
<0.35
0.64
<0.35 <0.34
2.8 1.2
<0.35 <0.34
0.8 0.61
1.4
0.89
2.4 1.4
2.5 1.5
3
2.1
1.7 1.2
3.5 1.7
1.7
1.1
5.1
2.2
0.49
<0.34
1.3
0.82
4.5 1.9
2.2 1.5
<3.52 9.5
<3.52 120
27 .
18
54
71
77
86
40-140
40-140
92 94
50
69
40-140
40-140
*1 Hydrocarbon range data exclude concentrations of any surrogate(s) and/ or internal standards eluti ng in that range.
*2 C 11-C22 Aromatic Hydrocarbons exclude the concentration
of
Target PAH Analytes eluting in that range.
l.:EKTIJ<
Were all QA/QC procedures REQUIRED by the EPH method followed?
XX
Yes _ N o
VHB-101 (15-17) VHB-102 (10-12
AJ36112 AJ36113
07/25/07 07/25/07
07/27/07 07/27/07
07/27/07 07/27/07
08/01/07 08/01/07
I I
7.0
9.0
4.1
5.5
<0.34
<0.35
<0.34
<0.35
<0.34 <0.35
<0.34
<0.35
<0.34
<0.35
<0.34 <0.35
<0.34 <0.35
<0.34
<0.35
<0.34 <0.35
<0.34
<0.35
<0.34
<0.35
<0.34 <0.35
<0.34
<0.35
<0.34 <0.35
<0.34 <0.35
<0.34
<0.35
<0.34 <0.35
<3.42 <3.54
<3.42
<3.54
4.1 5.5
58 66
88 82
40-140
40-140
78
89
65
66
40-140
40-140
Were all performance/acceptance standards for the required QA QC procedures achieved?
XX
Yes
_ N o
Were any significant modifications made to the EPH method, as specified in Section 11.3?
_ * Y e s XX
No
*If above question was checked yes, samples were run via GCIMS, otherwise run
by
GC-FID.
I attest under the pains and penalties o fperjury that, based upon my inquiry o f hose individuals immediately responsiblefor obtaining the information,
the material contained in this report is, to the best o fmv
knowled'i .e
and belief accurate and complete.
,,,..._ " I i i · - · ~
Signature: - ' : , . J - , - - - . . , . . , - ~ - - , - - - - - - -
Printed Name: Johanna Harrington
Position:
Chemist
Date: s ';s= t2 'o 'o7=---
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Environmenta l
Laboratories,
Inc.
NY#11301
587 East Middle Turnpike P.O.Box 370, Manchester CT
06040
Tel. (860) 645-1102
Fax (860) 645-0823
QA/QC
Report
August
08, 2007
OA/OC
Data
SDG J.D.:
GAJ36104
Dup LCS
LCSD LCS
MS
MSDup
Parameter
Blank RPD
%
% RPD Rec%
Rec%
RPD
QAIQC
Batch
80966, Sample No: AJ35832 (AJ36114, AJ36115. AJ36 16)
Mercury BDL
NC 101
92.4 8.9
95.7
96.1 0.4
QA QC
Batch 80906. Sample
No: AJ35880 (AJ36114, AJ36115,
AJ36116)
ICP
Metals-
Dissolved
Aluminum
BDL NC
86.6
92.2 6.3 94.8
98.7 4.0
Antimony
0.005 NC 86.4 90.8 5.0 90.6 93.8 3.5
Arsenic BDL
NC 84.4
89.3 5.6
87.8 91.2
3.8
Barium
BDL BDL
88.5
94.6 6.7 94.0
97.5 3.7
Beryllium
BDL NC 88.3 93.0
5.2
89.7 93.1
3.7
Boron
BDL 1.00 87.7
92.3 5.1
90.3 93.5
3.5
Cadmium
BDL NC
87.1
93.6 7.2 91.9
95.1 3.4
Calcium
BDL BDL
88.9
95.7 7.4 NC
NC NC
Chromium
BDL
NC
86.7
92.7 6.7 88.6
91.2 2.9
Cobalt
BDL
NC 86.6
92.5 6.6 90.2
94.8 5.0
Copper
0.001 3.00 87.2 95.1 8.7 94.9 97.9
3.1
Iron
BDL 3.20 87.3
93.1
6.4 90.0 92.4 2.6
Lead
BDL
NC 88.3 93.1 5.3 91.6 95.1 3.7
Magnesium BDL 2.20
90.2
95.4 5.6
NC
NC NC
Manganese
BDL NC 87.8 94.6 7.5 91.2 93.6 2.6
Molybdenum
BDL 3.70 88.1 93.5 5.9 89.6 92.9 3.6
Nickel
0.004
NC
86.7
93.0 7.0
90.5
94.1
3.9
Phosphorus
BDL BDL
85.8
89.8 4.6 83.3 84.7
1.7
Potassium
BDL BDL
96.4
96.5 0.1 92.4 97.2 5.1
Selenium
BDL
NC
76.6
79.9 4.2 81.6 86.2
5.5
Silver BDL
NC
87.7
93.6 6.5 100
98.0 2.0
Sodium BDL
1.20 94.1
96.2 2.2
NC NC NC
Thallium BDL
NC
86.5
92.0 6.2 94.9
99.0 4.2
Tin BDL
NC 86.4
92.5 6.8
90.8 94.1 3.6
Vanadium
BDL
NC 85.9
93.5 8.5 89.0 92.5
3.9
Zinc
0.002
BDL
85.2 91.7 7.3 89.8 93.0 3.5
QA QC
Batch 80930, Sample
No: AJ36089 (AJ36 04, AJ36105,
AJ36106,
AJ36107, AJ36108,
AJ36 09.
AJ36110,
AJ36 11,
AJ36112, AJ36113)
ICP Metals-
Soil
Aluminum
BDL NC NC NC
NC
NC
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I
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OA/OC Data
SDG I. D.: GAJ36104
Dup
LCS
LCSD LCS
MS
MSDup
Parameter
Blan k RPD
%
% RPD
Rec%
Rec% RPD
Antimony BDL
NC 80.4 88.7 9.8 64.1
66.6
3.8
Arsenic BDL 18.8
78.6
86.8 9.9
65.3 66.8 2.3
Barium
BDL 23.7 85.7 95.8 11.1 75.0 76.9 2.5
Beryllium BDL
NC
85.3 96.5 12.3 69.7 71.9 3.1
Boron
BDL NC 83.3 91.0 8.8 69.5
71.1 2.3
Cadmium
BDL
NC
88.0
94.7
7.3 74.0 75.3
1.7
Calcium
BDL 14.8 NC
NC
NC
NC
Chromium BDL
8.90 82.3 94.4 13.7 69.1
70.9 2.6
Cobalt
BDL 4.30
83.9
95.8 13.2
71.8 74.2
3.3
Copper
BDL NC
88.4
99.6 11.9
85.3 88.1 3.2
Iron
BDL
14.3
NC NC
NC NC
Lead
BDL
NC
85.4
92.5 8.0
80.6 81.6 1.2
Magnesium BDL
NC 116 107 8.1 NC
NC NC
Manganese BDL
4.60 86.9 98.5 12.5 83.0 98.1 16.7
Molybdenum
BDL
NC 82.6
92.6 11.4
69.6 71.1
2.1
Nickel
BDL 5.20 86.1 97.5 12.4 70.6
72.0 2.0
Phosphorus
0.7
3.40 81.8 90.1 9.7 62.0 72.9 16.2
Potassium BDL
NC 76.2 85.2 11.2 103 NC
NC
Selenium
BDL
NC
68.9 75.3 8.9 57.0
58.4 2.4
Silver
BDL
NC
91.4
95.1
4.0 87.0 76.9 12.3
Sodium
BDL 28.4
86.9
97.2 11.2 NC
NC NC
Thallium
BDL NC
90.8
96.5 6.1 77.4
79.1
2.2
Tin 2.54
NC 86.4 96.9 11.5 72.9 76.8 5.2
Vanadium
BDL
15.5
83.5
94.1 11.9
70.9 72.8 2.6
Zinc
BDL
18.5
88.2
96.0 8.5 34.4
>130 NC
QNQC
Batch 81079,
Sample No: AJ36104 (AJ36104, AJ36105, AJ36106, AJ36107, AJ36108, AJ36109, AJ36110, AJ36111,
AJ36112,
AJ36113)
Mercury - Soil
BDL NC
91.6
86.7 5.5 111 106 4.6
If
there are
any quest ions regarding this data , please call Phoenix Client Services a t extension 200.
RPD
- Relative
Percent
Difference
?#;
-
CS
-
Laboratory Control Sample
LCSD - Laboratory Control Sample Duplicate
MS - Matrix
Spike
MS
Dup
-
Matrix Spike
Duplicate
NC
-
No
Criteria
August 08, 2007
Page 2 of8
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Environmental Laboratories, Inc.
NY#11301
87 East Middle Turnpike P.O.Box 370, Manchester CT
06040
Tel. (860) 645-1102
Fax (860) 645-0823
QA/QC
Report
August 08,
2007
OA/OC Data
SDG I.D.:
GAJ36104
LCS LCSD LCS MS
MSDup
Parameter
Blank
% % RPD
Rec%
Rec% RPD
QA QC
Batch
79895, Sample No: AJ31870 (AJ36104, AJ36105. AJ36106. AJ36108, AJ36109, AJ36110, AJ36111. AJ36112,
AJ36113)
MAEPH
Acenaphthene
ND
87 94 7.7 84
85
1.2
Anthracene
ND 74
74 0.0 89 90
1.1
Chrysene
ND 113 123
8.5 76 84
10.0
n-Eicosane (CZO)
ND
81 95 15.9 83
76 8.8
n-Nonadecane (C19)
ND
81 95 15.9 83
76 8.8
n-Octacosane (C28)
ND
81
95 15.9
83 76 8.8
n-Tetradecane (C14)
ND
71 69 2.9 52
54 3.8
Naphthalene
ND 48
48 0.0 53 55
3.7
Pyrehe
ND 81 91
11.6 103 91 12.4
%2-Bromonaphthalene (surr)
97
79 75 5.2 85 85
0.0
%2-Flurobiphenyl (surr)
111
110 111 0.9 110 107 2.8
%a-COD (surr)
58 45 51 12.5
66
62
6.3
%o-Terphenyl (surr)
86 44 48 8.7 81
86
6.0
QAIQC
Batch
81000,
Sample
No:
AJ35858
(AJ36112.
AJ36113)
Volatiles
1,
1,1,2-Tetrachloroethane
ND 116
118 1.7 85 88 3.5
1, 1,1-Trichloroethane
ND
116 120 3.4
96
96 0.0
1.1.2.2-Tetrachloroethane ND
108 109 0.9
79 80 1.3
1,
1,2-Trichloroethane
ND
112 116 3.5
89
90 1.1
1,
1-Dichloroethane
ND 112
115 2.6 90 89 1.1
1.1-Dichloroethene
ND 107
95
11.9
95
94
1.1
1, 1-Dichloropropene
ND 103 110
6.6 99 101 2.0
1,2,3-Trichlorobenzene
ND
106 113 6.4 67 75 11.3
1 2,3-Trichloropropane
ND 113 128 12.4
76 87 13.5
1,2,4-Trichlorobenzene
ND
96 99 3.1 64 69 7.5
1,2,4-Trimethylbenzene
ND
102 105 2.9 84 87 3.5
1,2-Dibromo-3-chloropropane
ND 126
129 2.4
77
83 7.5
1,2-Dichlorobenzene
ND
103
103
0.0
73
76 4.0
1,2-Dichloroethane
ND
113 117 3.5 84 85
1.2
1,2-Dichloropropane
ND
109 115 5.4 89 90
1.1
1,3,5-Trimethylbenzene
ND 102 106 3.8 84
88
4.7
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Parameter
1 3-Dichlorobenzene
1 3-Dichloropropane
1,4-Dichlorobenzene
2,2-Dichloropropane
2-Chlorotoluene
4-Chlorotoluene
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
cis-1,2-Dichloroethene
cis-1,3-Dichloropropene
Dibromochloromethane
Dibromoethane
Dibromomethane
Dichlorodifluoromethane
Ethylbenzene
Hexachlorobutadiene
Isopropylbenzene
m&p-Xylene
Methyl Ethyl Ketone
Methyl t-Butyl Ether (MTBE)
Methylene chloride
n-Butylbenzene
n-Propylbenzene
Naphthalene
o-Xylene
p-Isopropyltoluene
sec-Butylbenzene
Styrene
tert-Butylbenzene
Tetrachloroethene
Toluene
Tota l Xylenes
trans-1 ,2-Dichloroethene
QA/QC
Data
Blank
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
LCS LCSD LCS
% % RPD
102 04 1.9
113 116 2.6
103
05
1.9
109
92
16.9
102 06 3.8
104 107 2.8
I l l 116 4.4
105
07
1.9
117 118 0.9
116 120 3.4
125
26
0.8
87 75 14.8
115 20 4.3
107 112 4.6
104 132 23.7
115 118 2.6
115 113 1.8
114
20
5.1
109 08 0.9
120
23
2.5
118 23 4.1
115 121 5.1
149 51 1.3
110 113 2.7
108 112 3.6
112 118 5.2
110 114 3.6
108 115 6.3
110 118 7.0
105 09 3.7
102
06
3.8
110
99
10.5
109 13 3.6
105 112 6.5
98 102 4.0
113 116 2.6
106 111 4.6
104 110 5.6
108 115 6.3
102 110 7.5
Page 4
of8
SDG
1.0.: GAJ36104
MS MSDup
Rec% Rec%
73
78
86 88
75 79
90 71
83
87
80 82
91 95
79 82
93 91
84 88
74 77
75
50
93
99
85
87
82 98
89
89
84 81
95 94
84 82
82 85
93
94
88 92
119 114
92 95
84
90
89 91
92 95
87 87
81 82
85 85
86
85
70
63
89
93
86 92
86 89
87 88
90
95
94
97
92
96
84
88
RPD
6.6
2.3
5.2
23.6
4.7
2.5
4.3
3.7
2.2
4.7
4.0
40.0
6.3
2.3
17.8
0.0
3.6
1.1
2.4
3.6
1.1
4.4
4.3
3.2
6.9
2.2
3.2
0.0
1.2
0.0
1.2
10.5
4.4
6.7
3.4
1.1
5.4
3.1
4.3
4.7
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Parameter
trans-1 ,3-Dichloropropene
Trichloroethene
Trichlorofluoromethane
Vinyl chloride
% 1,2-dichlorobenzene-d4
% Bromofluorobenzene
% Dibromofluoromethane
QA/QC Data
Blank
ND
ND
ND
ND
99
93
106
LCS LCSD LCS
% %
RPD
113 00 12.2
106 i l3 6.4
120 126 4.9
124 20 3.3
104 102 1.9
104
02
1.9
106
%Toluene-dB 100 100
104
00
1.9
0.0
QAJQC
Batch
81073, Sample
No:
AJ35916
(AJ36114,
AJ36115, AJ36116)
Volatiles
Organics
1, 1, 1,2-Tetrachloroethane
I, ,1-Trichloroethane
1,1 ,2,2-
Tetrachloroethane
1,1 ,2-Trichloroethane
1, 1-Dichloroethane
1, 1-Dichloroethene
1,1-Dichloropropene
1,2,3-Trichlorobenzene
1,2,3-Trichloropropane
1,2.4-Trichlorobenzene
1 2 4-Trimethylbenzene
1,2-Dibromo-3-chloropropane
1,2-Dichlorobenzene
1 2-Dichloroethane
I
,2-Dichloropropane
1 3,5-Trimethylbenzene
1,3-Dichlorobenzene
1,3-Dichloropropane
1,4-Dichlorobenzene
2,2-Dichloropropane
2-Chlorotoluene
4-Chlorotoluene
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
Carbon tetrachloride
Chlorobenzene
Chloroethane
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
109
114
102
109
>130
122
113
95
<70
102
i l2
96
106
i l2
113
113
ilO
ilO
105
93
ilO
i l2
i l6
107
105
i l l
104
85
i l3
112
104
Page
5 of8
101
07
88
85
02
107
i l2
89
<70
93
i l6
80
97
89
98
123
106
94
102
90
i l7
i l6
i l l
103
83
92
82
06
119
108
131
7.6
6.3
14.7
24.7
NC
13.1
0.9
6.5
NC
9.2
3.5
18.2
8.9
22.9
14.2
8.5
3.7
15.7
2.9
3.3
6.2
3.5
4.4
3.8
23.4
18.7
23.7
22.0
5.2
3.6
23.0
SDG J.D.: GAJ36104
MS
MSDup
Rec% Rec%
82 67
97 101
99
94
98
88
101 101
100 101
103
98
109
113
106
114
>130
126
114
93
<70
99
110
98
105
112
115
109
107
108
104
73
110
106
114
106
107
i l2
101
77
129
110
101
100
99
104
110
95
95
107
114
117
89
<70
93
116
76
99
96
101
120
105
98
105
74
i l4
113
112
103
85
97
87
85
119
110
i l7
RPD
20.1
4.0
5.2
10.8
0.0
1.0
3.0
1.0
4.7
2.7
10.9
18.2
NC
10.0
2.6
4.4
NC
6.3
5.3
25.3
5.9
15.4
13.0
9.6
1.9
9.7
1.0
1.4
3.6
6.4
1.8
2.9
22.9
14.4
14.9
9.9
8.1
0.0
14.7
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Parameter
Chloroform
Chloromethane
cis-1.2-Dichloroethene
cis-1
,3-Dichloropropene
Dibromochloromethane
Dibromoethane
Dibromomethane
Dichlorodifluoromethane
Ethylbenzene
Hexachlorobutadiene
Isopropylbenzene
m&p-Xylene
Methyl t-butyl ether
(MTBE)
Methylene chloride
n-Butylbenzene
n-Propylbenzene
Naphthalene
a-Xylene
p-lsopropyltoluene
sec-Butylbenzene
Styrene
tert-Butylbenzene
Tetrachloroethene
Toluene
trans-1 ,2-Dichloroethene
trans-1 ,3-Dichloropropene
Trichloroethene
Trichlorofluoromethane
Vinyl chloride
%
1,2-dichlorobenzene-d4
%
Bromofluorobenzene
%
Dibromofluoromethane
Toluene-dB
QA/QC Data
Blank
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
102
93
97
101
LCS
%
Ill
>130
112
105
108
107
107
>130
116
107
123
117
115
124
115
114
100
114
119
109
110
116
113
114
119
103
112
117
>130
98
103
93
100
Comment:
LFB
was
analyzed with this batch instead
of
MS/MSD.
QAJQC
Batch
80919,
Sample
No:
AJ35959
(AJ36114, AJ36115, AJ36116)
Polynuclear Aromatic HC
2-Methylnaphthalene
Acenaphthene
Acenaphthylene
Anthracene
Benz(a)anthracene
ND
ND
ND
ND
ND
96
102
101
101
110
Page 6 of8
LCSD
LCS
% RPD
99
11.4
118
NC
95 16.4
85 21.1
92 16.0
84 24.1
86
21.8
>130
NC
122 5.0
07
0.0
>130 NC
120 2.5
94 20.1
94
27.5
23 6.7
26
10.0
85 16.2
112 1.8
30 8.8
119 8.8
04 5.6
127 9.1
120 6.0
i l l 2.7
03
14.4
81
23.9
110 1.8
115 1.7
125
NC
95 3.1
99 4.0
82 12.6
100 0.0
94
95
99
97
09
2.1
7.1
2.0
4.0
0.9
SDG J.D.: GAJ36104
MS MSDup
Rec%
Rec%
109
101
96
98
110 102
99
85
104 90
110
90
110 92
92
89
114 122
106 102
111 124
115 120
117 103
124 103
110 118
110 122
96
87
111 114
112 123
113 124
110 108
113 124
112 121
115 113
119 107
97 81
115 113
117 118
108 105
100 95
104 99
94 87
101 99
RPD
7.6
2.1
7.5
15.2
14.4
20.0
17.8
3.3
6.8
3.8
11.1
4.3
12.7
18.5
7.0
10.3
9.8
2.7
9.4
9.3
1.8
9.3
7.7
1.8
10.6
18.0
1.8
0.9
2.8
5.1
4.9
7.7
2.0
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QA/QC
Data
SDG
I. D.:
GAJ36104
LCS LCSD LCS
MS
MSDup
Parameter
Blank
% % RPD
Rec% Rec%
RPD
Benw(a)pyrene
NO 100 99 1.0
Benzo(b)fluoranthene NO
I l l
108 2.7
Benzo(ghi)perylene
NO
112 108 3.6
Benzo(k)fluoranthene
NO
109
107 1.9
Chrysene
NO
I l l
109
1.8
Dibenz(a,h)anthracene
NO
120 116 3.4
Fluoranthene NO
117
111
5.3
Fluorene
NO
105
102 2.9
lndeno(1.2.3-cd)pyrene
NO
115 111 3.5
Naphthalene
NO
92
92 0.0
Phenanthrene
NO
105 00 4.9
Pyrene
NO 114 09 4.5
% 2-Fluorobiphenyl
93
96
94 2.1
% Nitrobenzene-d5
97
90
114 23.5
%
Terphenyl-d14
119 110 106 3.7
Comment: A LCS and LCS Duplicate were performed instead of a matrix spike and matrix spike duplicate.
QAJQC
Batch 80927,
Sample
No: AJ36111
(AJ36104,
AJ36105,
AJ36109, AJ36111)
Polxchlorinated Bighenxls
PCB-1016
NO
96
95 1.0 115
90
24.4
PCB-1221
NO
PCB-1232
NO
PCB-1242
NO
PCB-1248
ND
PCB-1254
ND
PCB-1260
ND
87
84 3.5
• • NC
PCB-1262
ND
PCB-1268
ND
%
DCBP (Surrogate
Rec)
41
71
74 4.1
50 73 37.4
%
TCMX (Surrogate
Rec)
50
63
60 4.9
63
58 8.3
Comment:
*Due to the presence of PCBs in the sample, aroclor 1260 is not reported for the MS/MSD.
QAJQC
Batch
81407, Sample
No:
AJ37148
(aj36114,
aj36115,
aj36116)
MA-VPH
1,2,4-trimethylbenzene
ND
100
98
2.0
100 102 2.0
2-methylpentane
ND
100
102 2.0
74
92
21.7
Benzene ND
100 94 6.2 102 98 4.0
Ethylbenzene
NO
106
92
14.1 108 102
5.7
Iso-octane
NO
100
04 3.9 112 117 4.4
m&p-xylene ND
103
102
1.0 107 104 2.8
n-butylcyclohexane
130
120 8.0
n-nonane
(C9)
ND
84
80
4.9 126 122 3.2
n-pentane
(C5)
ND
112 114 1.8
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OA/QC Data
SDG .D.: GAJ36104
LCS
LCSD
LCS MS MSDup
Parameter
Blank
% %
RPD Rec% Rec%
naphthalene
NO
114
108
5.4 88
92
a-xylene
NO
102 98 4.0 102 100
tert-butylmethyl
ether
(MTBE)
NO
96 94 2.1 84 80
Toluene NO
102
96
6.1
106
102
% 2,5-dibromotoluefle
93 94 90 4.3
121
123
If there
are
any questions
regarding
this data, please call Phoenix C lient Services at extension 200.
RPD
- Relative Percent Difference
LCS - Laboratory Control
Sample
LCSD -
Laboratory Control Sample Duplicate
MS -
Matrix
Spike
MS
Dup
-
Matrix Spike Duplicate
NC - No
Criteria
~ ~ , ~ ~ -
ugust 08, 2007
Page 8
of8
RPD
4.4
2.0
4.9
3.8
1.6
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Title:
MADEP MCPResponse Action Analytical Report Certification Form
Laboratory
Name: Phoenix Environmental laboratories, Inc.
Project#:
Project Location:
CREME
MADEP RTN1:
This
Form
provides certifications for he following
data
set: [l ist laboratory Sample
ID
Number(s))
AJ36104,AJ36105,AJ36106,AJ36107,AJ36108,AJ36109,AJ36110,AJ36111,AJ36112,AJ36113,AJ36114,AJ36115,
AJ36116
Sample Matrices:
0
Groundwater
[0' Soil/Sediment
0
Drinking Water
DOther:
MCPSW-846
0s260B D 8151A
D
8330
[ 3"60108
[i2(7470Al1A
Methods
Used
i:its27oc D
8061A
DVPH
D 6020
D 9014M2
1
As specified
in MADEP
Compendium of
10
8082
D 80218
i1 EPH
D 7000S3
D 7196A
Analytical
Methods.
1 List Release Tracking Number (RTN}, i f
known
(check
all
that apply)
2M- SW-846 Method 9014 or
MADEP
Physiologically Available Cyanide (PAC) Metho
3 S - SW-846 Methods 7000 Series List
indiVidual
method
and
analyte
An affirmative response to questions A,
B,
C and D is required for "Presumptive Certainty" status
A Were all samples received by the laboratory
in
a condition consistent
~ Y e s
hat described on the Chain-of-Custody documentation for the data set?
D No
B Were all
QNQC
procedures required for the specified analytical method(s)
r;:;r'Yes
D No
included in this report followed, including the requirement to note and
.
discuss in a narrative QC data that did not meet appropriate performance
standards or guidelines?
c
Does the analytical data included in this report meet all the requirements for
"Presumptive Certainty", as described in Section 2.0 (a), (b), (c) and (d) of
l i tves
DNa
the MADEP document CAM VII
A,
"Quality Assurance and Quality Control
Guidelines for the c q u i s ~ i o n and Reporting
of
Analytical Data"?
D VPH and EPH Methods only:
Was
the VPH
or
EPH Method conducted
without significant modifications (see Section 11.3
of
respective Methods)
DYes ila'No
A
response to questions E and F below is required for "Presumptive Certainty" status
E Were all QC performance standards and recommendations for the specffied
methods achieved?
DYes
lB No
F Were results for all analyte-list compounds/elements for the specified
l 'fYes DNa
method(s) reported?
All
negative responses
must
be
addressed
in an
attached
Environmentaf
Laboratory
case
naffative.
I, the undersigned, attest under the pains and penalties ofperjury that, based upon my personal
inquiry of hose responsible
for
obtaining the information, the material contained in this analytical
report s, to the best
of my
knowledge and belief, accurate and complete.
1 Authorized
lf ..11+LfJ
.v
J < . . . / ~ IJM.PfJ
Date: Wednesday, August
as:
2007
ignature:
Printed Name: Kathleen Cressia
Position: QNQC Officer
Printed Name: Phyllis Shiller Position: laborato ry Director
CAM VII A, rev. 3.2
April2004
Page 1 of 1
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Environmental
Laboratories, Inc.
587
East Middle Turnpike,
P.O.Box 370,
Manchester, CT
06040
Tel.
(860) 645-1102
Fax
(860) 645·0823
MCP Certification
Report
August
08, 2007
EPH Narration
Were all QA/QC perfor mance criteria specified in the MADEP document CAM achieved? Yes.
Instrument: Au-fid2 08/03/07-1 IAJ36114. AJ36115. AJ36116l
A six level calibrati on was performed. All RSDs were within limits.
The
continuing
calibration standards
were
within control limits.
SDG
I.D.: GAJ36104
SampleS 36114-36122 we re
not extracted using the
EPH
method. Only
one liter
of
sample was provided for
the
analysis
of
semi
volatiles and EPH.
The
semi-volatile SIM extract was exchanged, concentrated, and fractionated to yield extracts suitable for EPH
analysis. For samples 36114-36116, only the fractionation surrogate was added to this sample, therefore,
o-terphenyl
and o-COD
are not reported.
Printed Name
Position:
Date:
Johanna Harrington
Chemist
8/3/2007
All LCS recoveries were within 40- 140
with
the following exceptions: None .
All LCSD
recoveries were within
40
-140
with
the following exceptions: None.
All MS recoveries were within
40.
140 with the following exceptions: None.
All MSD recoveries were within 40 - 140 with the following exceptions: None.
A matrix effect is suspected when a MS/MSD recovery is outside of criteria. No further action is required if 80% ofLCS LCSD
compounds are within criteria.
I attest under the pains
and
penalties of
peljury
that, based
upon
my inquiry of those individuals immediately responsible for
obtaining the information,. the material contained
in
this report is, to the
best
of
my
knowledge and belief, accurate and complete.
Mercury
Narration
Were all QNQC performance criteria specified in the
MADEP
document
CAM
achieved? Yes.
Instrument:
Merlin 07131107-1 IAJ36104, AJ36105 AJ36106, AJ36107,
AJ36 08
AJ36109,
AJ36110 AJ36111 AJ36112 AJ36113, AJ36198, AJ36199)
The
method preparation blank contains all of the acids and reagents as the samples; the instrument blanks do not.
The initial calibration
met
all
criteria
includinga standard
run
at or below
the
reporting level.
All calibration verification standards (ICV, CCV) met criteria.
All calibrati on blankverification standards (ICB, CCB) met criteria.
The matrix
spike sample
is
used
to
identify spectral
interfernce
for
each batch
of
samples,
i f
within
85-115%.
no interference
is
observed and no furtheraction
is
taken.
Printed Name
RJck
Schweitzer
Position: Chemist
Date: 7/3112007
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Environmental Laboratories,
Inc.
587
East
Middle Turnpike, P.O.Box 370
1
Manchester, CT 06040
Tel.
(860) 645-1102
Fax
(860) 645-0823
MCP Certification Report
August 08, 2007
All LCS recoveries were within 80 - 120 with the following exceptions: None.
All
LCSD recoveries were within 80 R 120
with
the fol_lowing exceptions: None.
All MS recoveries were
within
80 - 120 with the following ex-ceptions: None.
All MSD recoveries were within 80 - 120 with
the
following exceptions: None.
SDG J.D.: GAJ36104
A
matrix
effect
is
suspected
when
a MSJMSD recovery
is
outside
of
criteria. No
further
action
is required
if
80%
of
LCS LCSD
compounds
are
within criteria.
I attestunder the pains
and
penalties ofpetjury that. based
upon my
inquiry of those individua1s imme diately responsible for
obtaining the information, the material contained in this
report
is, to the best of my knowledge and belief, accurate and complete.
ICP N arration
Wr;rre
all
QAIQC performance
criteria
specified in the MADEP document CAM achieved? Yes.
Instrument:
lcp7 08/06/07-1 (AJ3611ll
The initial calibration
met
criteria.
The continuing calibration standards met criteria for all the elements reported. The linear range is defmed daily by the calibration
range.
The
continuing calibration blanks were less than the reporting level for the elements reported.
The ICSA and ICSAB were analyz ed at the
beginning and end
of
the
run
and
were within criteria.
Printed Name Emily Kolominskaya
Position: Chemist
Date: 8/6/2007
Instrument:
IeoS 07/27/07-1
CAJ36114.
AJ36115. AJ361 6\
The initial calibration
met
criteria.
The continuing calibration standards met criteria for all the elements reported. The linear range is def"med daily
by
the calibration
range.
The continuing calibration blanks were less than the reporting level for the elements reported.
The ICSA and ICSAB were analyzed
at
the
beginning
and end of the run
and
were within criteria.
Printed Name Emily Kolominskaya
Position: Chemist
Date: 7/27/2007
Instrument:
Iw8 07/31107-1 (AJ36104. AJ36 05. AJ36106. AJ36 07. AJ36 08. AJ36 09
AJ36110. AJ36lll. AJ361 2. AJ361 3. AJ36 98. AJ36 99)
The
initial
calibration met criteria.
The continuing calibration standards met criteria for all the elements reported. The linear range is def"med daily by the calibration
range.
The continuing calibration blanks were less than the reporting level for the elements reported.
The
ICSA
and
ICSAB were analyzed at
the
beginning
and
end of the
run and
were within criteria.
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Environmental
Laboratories, Inc.
587 East Middle Turnpike. P.O.Box 370,
Manchester,
CT 06040
TeL (860) 645·1102
Fax
(860) 645-0828
MCP Certification Report
August
08, 2007
Printed Name
Position:
Date:
Instrument:
Emily Kolominskaya
Chemist
7/31/2007
cpS 08/01/07-1 fAJ3611
ll
The initial calibration met criteria.
SDG
I.D.: GAJ36104
The continuing
calibration
standards
met
criteria
for all
the
elements
reported.
The linear range
is defmed
daily
by the
calibration
range.
The continuing calibration blanks were less than the reporting level for
the
elements reported.
The ICSA and ICSAB were analyzed at the
beginning
and
end
of the run and were
within criteria
Printed Name Emily Kolominskaya
Position: Chemist
Date: 8/1/2007
Instrument:
IeoS 08/03/07-1 (AJ3611 L AJ37997l
The
initial
ca1ibration
met
criteria.
The continuing calibration standards
met
criteria for all
the
elements reported. The
linear range
is def'med
daily by the
calibration
range.
The
continuing calibrationblanks were less
than the
reporting level for the elements reported.
The
ICSAand ICSAB were analyzed at the begimring
and end
of
the
run
and
were within criteria.
Printed Name Emily Kolominskaya
Position: Chemist
Date: 8/3/2007
All LCS recoveries were
within
75 • 125 with
the
following exceptions: Selenium
All LCSD recoveries were within 75 • 125 with
the
following exceptions: None.
All MS recoveries were within 75 • 125 with the following exceptions: Antimony, Arsenic, Beryllium, Boron, Cadmium, Ch romium,
Cobalt, Molybdenum, Nickel, Phosphorus, Selenium, Tin,
VanadiUm,
Zinc
All MSD recoveries were within 75 - 125 with the following exceptions: Antimony, Arsenic, Beryllium, Boron, Chromium, Cobalt,
Molybdenum, Nickel, Phosphorus, Selenium, Vanadium, Zinc
A
matrix
effect is suspected when a MS/MSD recovery is outside of criteria. No further action is required if 80% ofLCS LCSD
compounds
are
within
criteria.
I attest under the pains
and
penalties of perjury
that,
based upon my inquiry of those individuals immedi ately responsible for
obtaining
the
information, the material contained
in this
report
is, to
the best of my knowledge
and
belief, accurate
and
complete.
PAHSIM
Narration
Were all QA/QC performance criteria .specified in the MADEP document
CAM
achieved? Yes.
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Environmental
Laboratories, Inc.
587 East Middle Turnpike, P.O.Box 370, Manchester, CT 06040
Tel.
{860} 645-1102
Fax
{860} 645·0623
MCP
Certification Report
August 08, 2007
Instrument: Chem04 07131/07-1 CAJ36114 AJ36115 AJ36116l
SDG
J.D.: GAJ36104
The client requested
P
AH/base
neutral
compou nds only. Phoeni x utilized a method
that
contained a shortened list of base
neutral
only compounds, CCCs, SPCCs
and
surrogates.
In order
to
achieve the the requested detection levels, the samples were analyzed by selective
ion
monitoring (SIM) mode.
The DDT breakdown
and
pentachlorophenol
&
benzidine peak tailing were not evaluated in
the
DFTPP tune.
Initial Calibration(Chem04/SIM_0731}:
All
base
neutra1 SPCCs, CCCs
and >90%
of
arget
compounds
met criteria The
following
base
neutral
compounds
had
%RSDs
>SO%: none
Continuing Calibration:
All SPCCs, CCCs
and
>90% of
target
compounds met criteria. The following compoun ds
had
%Ds >20%:
Printed Name
Position:
Date:
Keith Aloisa
Chemist
7/31/2007
QC Comments: QC Batch 80919 07/27/07 CAJ36114. AJ36115. AJ361 16l
A LCS
and
LCS Duplicate were
performed
instead of a matrix spike
and
matrix spike duplicate.
All LCS recoveries were within 20 130
with
the following exceptions: None .
All LCSD recoveries were
within
20 - 130
with
the
following exceptions: None.
All MS recoveries were within 20 - 130 with the following exceptions: Non e.
All MSD recoveries were within 20 - 130 with the following exceptions: Non e.
A matrix effect is suspected when a MS/MSD recovery is outside of criteria. No further action is required
if
80% ofLCSJLCSD
compounds
are
within criteria.
I attest
under
the pains
and
penalties of
perjury
that, based upon my inquiry of those individuals immediately responsible for
obtaining
the information, the
material contained in this report
is, to the best
of my
knowledge
and
belief, accurate and complete.
PCB Narration
Were all QA/QC performan ce criteria specified in the MADEP document CAM achieved? Yes.
Instrument:
Au-ecd8 OWJ/07-1 CAJ36105l
8082 Narration:
The initial calibration RSD for the
compound list
was less than 20%.
The continuing calibration standards were within acceptance criteria.
Printed Name Johanna Harrington
Position: Chemist
Date: 7/31/2007
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Environmental Laboratories, Inc.
587 East
Middle
Turnpike, P.O.Box
370,
Manchester, CT
06040
Tel.
(860) 645-1102
Fax
(860)
645-0828
MCP Certification Report
August
08, 2007
SDG
I.D.:
GAJ36104
Instrument:
Au-ecd8 08/01107-1 IAJ36 11 AJ36784l
8082 NBITation:
The initial calibrati on RSD for the compound list was less than 20%.
The continuing calibration standards were within acceptance criteria.
Printed Name Johanna Harrington
Position: Chemist
Date:
8/1/2007
QC Comments: QC Batch 80927 07127107 (AJ36104. AJ36105. AJ36109. AJ36111l
*Due to the presence of PCBs in the sample, aroclor 1260 is
not
reported for the MS MSD.
All LCS recoveries were within 30 - 130 with the following exceptions: None.
All LCSD recoveries were within 30 - 130
with
the
following exceptions: None.
All MS recoveries were within 30 - 130 with the foJlowing exceptions: None.
All MSD recoveries were with in
30-
130 with the following exceptions: None.
A
matrix
effect is suspected when a MSJMSD recovery is outside of criteria.
No further
action is
required if
80% ofLCS/LCSD
compounds
are
within criteria.
I atte13t under the pains
and
penalties of perjury that, based
upon
my inquiry of those individuals immediately responsible for
obtaining the information, the material contained in this report
is,
to the best ?f my knowledge
and
belief, accurate arid complete.
SVOASIM Narration
Were all QNQC performance criteria specified in the MADEP document CAM achieved? Yes.
QC Comments:
OC Batch 80919 07/27107 (AJ36114 AJ361 5. AJ36116)
A LCS and LCS Duplicate were performed
instead of
a
matrix
spike
and matrix
spike duplicate.
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Environmental
Laboratories,
Inc.
587
East
Middle
Turnpike, P.O.Box 370,
Manchester,
CT 06040
Tel.
(860) 645-1102
Fax
(860) 645-0823
MCP Certification Report
August
08, 2007
SDG J.D.: GAJ36104
All LCS recoveries were within 20 - 130 with the following exceptions: None.
All LCSD recoveries were within 20 -130 with
the
following exceptions: None.
All
MS recoveries were
within
20 - 130 with
the
following exceptions:
None.
All MSD recoveries were
within
20 - 180
with
the following exceptions: None.
A
matrix effect
is
suspected
when
a MS MSD recovery is
outside o f criteria.
No
further action
is
required
if
80%
of
LCS/LCSD
compounds are
within
criteria.
I attest under the pains and penalties
of
perjury that, based upon.my inquiry
of
those individuals immediately responsible for
obtaining the information, the material contained in this report is, to the best of my knowledge and belief, accurate and complete.
VOA Narration
Were all QNQC performance
criteria
specified in the MADEP
document
CAM achieved? Yes.
Instrument:
Chem03 07127/07-1 IAJ3 6112. AJ36113. AJ36198. AJ36199l
Initial Calibration
Verificati on (chem03/1110):
All SPCCs, CCCs and >80%
of
target compounds met criteria.
The fo11owing compounds
had
%RSDs >30%: None
Continuing Calibration Verification:
All SPCCs, CCCs
and >80%
of target compounds met criteria. Internal
standards
were within the 50%-200% deviation
from the
initial
calibration.
The following compounds had% Deviations >30%:
Printed Name
Positio.n:
Date:
Johanna Harrington
Chemist
7/27/2007
Instrument:
ChemOS 07127/07-1 IAJ36114. AJ36115.
AJ361 6)
This instrument is
set
up
with
a dual auto sampler Gabe1ed R and 8)
R
.Side
Initial CalibratiDn (062007)
' All SPCCs, CCCs
and
>80% of target compounds met criteria.
Continuing
Calibration Verification:
All
SPCCs, CCCs
and
>80%
of
target
compounds
met
criteria.
Internal standards
were
within
the
50%-200%
deviation from
the
initial calibration.
The
following compounds had % Deviations >30%:
S-Side
Initial Calibration (062007)
All SPCCs, CCCs and >80%
of
target compounds met criteria.
Page6of8
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Environmental
Laboratories, Inc.
587 East
Middle Tum.pike,
P.O.Box 370,
Manchester,
CT 06040
Tel.
(860) 645-1102
Fax
(860) 645-0823
MCP Certification Report
August 08, 2007
SDG J.D.:
GAJ36104
Continuing Calibration Verification:
All SPCCs, CCCs ap_d >80%
of target
compounds
met
criteria. Internal standards were within
the
50%-200% deviation from
the
initial
calibration.
The following compounds had% Deviations >30%: Chloroethane, Acetone, Acrylonitrile, Tetrahydrofuran (THF) Bromomethane,
Naphthalene, 1,2,3-Tricblorobenzene
Printed Name Raman Makol
Position: Chemist
Date:
7/27/2007
All LCS recoveries were within 70-130
with the
following exceptions: l,l-Dichlo roethane,l,2,3 -Trichloropropane, Chloromethane,
Dichlorodifluoromethane, Vmy1 chloride
All LCSD recoveries were
within
70 - 130 with
the
following exceptions: 1,2,3-Trichloropropane, Chloroethane,
Dichlorodifluoromethane, Isopropylbenzene
All
MS
recoveries were with in 70 w 130 with the following exceptions: 1,1-Dichloroethane, 1,2,3-Trichlorobenzene, 1,2,3-
Trichloropropane, 1,2,4-Trichlorobenzene
All MSD recoveries were within 70 - 130 with
the
following exceptions: 1,1-Dichloroethane, 1,2,3-Trichloropropane , 1,2,4-
Trichlorobenzene, Bromo methane, Naphthalene, trans-1,3-Dichloropropene
A
matr ix effect is suspected when a MS/MSD recovery is outs ide of
criteria
No
further
action is
required i f
80%
of
LCS/LCSD
compounds
are
within
criteria.
I attest
under the
pains and penalties
of
perjury
that,
based upon my inquiry
of
those individuals immediately responsible for
obtaining the information, the material contained
in
this report is, to the best of my knowledge and belief, accurat e and complete.
VPH Narration
Were all
QNQC
performance c riteria specified
in
the MADEP document
CAM
achieved? Yes.
Instrument:
Pid-fid 08/03/07-1 (AJ361l4,
AJ36ll5,
AJ36ll6l
A five level calibra tion was performed. All RSDs were within limits.
The continu ing calibration standards were within control limits.
Printed Name Raman Makol
Position:
Date:
Chemist
8/3/2007
Page 7of8
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Environmental
Laboratories,
Inc.
587 East Middle Turnpike, P.O.Box 370, Manchester, CT 06040
Tel.
(860) 645-1102
Fax
(860) 645-0823
MCP
Certification Report
August 08, 2007
SDG I.D.: GAJ36104
All LCS
recoveries were
within 70 - 130 with the following exceptions: None.
All LCSD recoveries were within 70 - 130 with the following exceptions: None.
All MS recoveries were within 70 - 130 with the following exceptions: None.
All MSD recoveries wer e
within
70 - 130
with
the following exceptions: None.
A
matrix
effect
is
suspected
when
a MS/MSD recovery
is
outside
of
criteria.
No
further
action is
required
if
80%
of
LCS/LCSD
compounds are within criteria.
I attest
under the
pains and penalties
ofpetjury
that, based upon my inquiry
of
those individuals immediately responsible for
obtaining the information, the material contained in this report is, to the best of my knowledge and belief, ac_curate and o m p l e t e ~
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•,:'.
D L J f l l J l \ T T V ~
CHAIN OF CUSTODY RECORD
-£
1 1V Dl \ ' . lA
587
East Middle Turnpike, P.O.
Box 370,
Manchester,
CT
06040
Environmental L a b o r a t o r i e s ~ Inc. E m a i l : s e ~ i c e @ p h o e n i x l a b s . c a m
Fax (860)
64S..Qa
23
Chen Services (860) 645·8726
Customer:
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Matrix Code:
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GW=groundwater
Phoenix
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WW=wastewater S=soil/solid O=other
SL=sludge
A=air
Customer Sample
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Matrix
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Request
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\ J ~ P l O E N I X .
CHAIN OF CUSTODY RECORD
587 East Middle Turnpike, P.O. Box 370, Manchester, CT 06040
Environmental
Laboratories, Inc.
Email: [email protected] Fax (860) 645-0823
Client.Services (860) 645-8726
c ~ _ . . . , _
Customer: V \J.J?
Address:
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Matrix Code:
ALAR. _
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Date "ii/.1?/o
Analysis
Request
u v v ~ a r i n k i n g water WW=wastewater S=soll/solid O=other
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Report Date:
12-Nov-0714:16
Tetra Tech Rizzo
One Grant
Street - P.O.
Box 9005
Framingham, MA
01701
Attn:
Paula Rotenberg
Laboratoa ID
Client Samule ID
SA70267-0l
VHB-1 02-1 (0-10")
SA70267-02 VHB-1 02-2 (0-7")
SA70267-03 VHB-102-3 (0-10")
SA70267-04
VHB-1 02-4 (0-9")
SA70267-05 VHB-102-5 (0-12")
SA70267-06 VHB-102-6 (0-5")
SA70267-07 VHB-102-7 (0-7")
SA70267-08 VHB-1 02-8 (0-11 ")
SA70267-09 Dup-102607
SPECTRUM ANAL
'TICAL,
INC
Featuring
HANIBAL TECHNOLOGY
Laboratory Report
Ill
Final Report
D
Re-Issued Report
D
Revised Report
Project:
CEA
Beverly-
Beverly, MA
Project 12700961
Matrix Date Samnled
Date Received
Soil
26-0ct-07 11:55
29-0ct-07 14:10
Soil 26-0ct-07 12:10
29-0ct-07 14:10
Soil
26-0ct-07 12:25
29-0ct-07 14:10
Soil
26-0ct-07 12:35
29-0ct-07 14:10
Soil
26-0ct-07 12:55
29-0ct-0714:10
Soil
26-0ct-07
13:25
29-0ct-07
14:10
Soil
26-0ct-0713:15
29-0ct-07 14:10
Soil
26-0ct-07 13:05 29-0ct-0714:10
Soil
26-0ct-07 08:00
29-0ct-07
14:10
I attest that the information contained within the report has been reviewed for accuracy and checked agains t the quality control
requirements for each method. These results relate only to the sample(s) as received.
All applicable NELAC requirements have been met.
Please note that this report contains 11 pages
of
analytical dat a plus Chain
of
Custody document(s).
This report may not be reproduced, except in full, without written approval from Spectrum Analytical, Inc.
Massachusetts Certifi cation# M-MA
138/MAlllO
Connecticut# PH-0777
Florida# E87600/E87936
Maine#
MA
138
Authorized by:
New
Hampshire#
2538/2972
New
Jersey#
MA0111MA012
New
York#
11393/11840
Rhode Island # 98
Hanibal C. Tayeh, Ph.D.
President/Laboratory Director
USDA# S-51435
Vermont# VT-11393
Technical Reviewer's Initial:
.e
Spectrum Analytical, Inc. is a NELAC accredit ed laboratory organi:=ation and meets NELA C testing standards. Use of he NELAC
logo however does not insure that Spectrum is currently accredited or the specific method
or
analyte indicated. Please refer to our
"Quality" web page at www.spectrum-analytical.comfor a foil listing ofour current certificaUons and ields o faccreditation. States in
which Spectrum Analytical, Inc. holds NELAC certification are New York, New Hampshire, New Jersey and Florida.
All
analytical
work for Volatile Organic and Air analysis are transferred to and conducted at our 830 Silver Street location (NH-2972, NY-11840,
FL-£87936 and NJ-MAOJ2).
Headquarters:
II Almgren D r i ~ · c & 830 Silver Street • Agawam, MA 01001 • 1-800-789-9115 • 413-789-9018 • FAX 413-789-4076
FL Dil•ision:
8180 Woodland Center Boulevard • Tampa, FL 33614 • 1-888-497-5270 • 813-888-9507 • FAX 800-480-6435
www.spectrum-analytical.com
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CASE
NARRATIVE:
The samples were received@ 14.8 degrees Celsius, please refer to the Chain of Custody for details specific to temperature upon
receipt. An infrared thennometer with a tolerance o f + / ~ 2.0 degrees Celsius was used immediately upon receipt of the samples.
MADEP has published a list of analytical methods (CAM) whic h provides a series of recommended protocols for the acquisition,
analysis and reporting of analytical data in support ofMCP decisions. "Presumptive Certainty" can be established only for those
methods published by the MADEP in the MCP CAM. The compounds and/or elements reported were specifically requested by the
client on the Chain
of
Custody and in some cases
may
not
include the full analyte list as defmed
in
the method.
According to WSC-CAM 5/2004 Rev.4, Table I I A-1, recovery for some VOC analytes have been deemed potentially difficult.
Although they
may
still be within the recommended 70% -130% recovery range, a range has been set based
on
historical control limits.
See below for
any
non-conformances
and
issues relating to quality control samples
and/or
sample analysis/matrix.
SW846 60108
Spikes:
7110417-MS1 Source: SA70267-05
The spike recovery was outside ofQC acceptance limits for the MS,
MSD
and/or PS due to analyte concentration at 4 times or
greater the spike concentration. The QC batch was accepted based on LCS and/or LCSD recoveries within the acceptance limits.
Lead
7110417-MSDI Source: SA70267-05
The spike recovery was outside of QC acceptance limits for the MS,
MSD
and/or PS due to analyte concentration at 4 times
or
greater the spike concentration. The QC batch was accepted based on LCS and/or LCSD recoveries within the acceptance limits.
Lead
71 10417-PS1 Source: SA70267-05
The spike recovery was outside
ofQC
acceptance limits for the MS, MSD and/or PS due to analyte concentration at 4 times
or
greater the spike concentration. The QC batch was accepted based
on
LCS and/or LCSD recoveries within the acceptance limits.
Lead
This laboratory report is not valid without an a uthorized signature on the cover page.
* Reportable Detection Limit BRL = Below Reporting Limit
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Samgle Identification
Client Project # Collection Dateff ime
VHB-102-1 (0-10")
Matrix
Received
SA70267-0I
12700961 Soil 26-0ct-07 11:55
29-0ct-07
CAS No.
Analyte(s)
Result Flag Units *RDL
Dilution
Method Ref. Prepared
Analyzed Batch Analyst
Semivolatile Organic Compounds by
GC
Polychlorinated BiQhenyls
by
SW846 8082
Prepared by method SW846 3545A
12674-11-2
PCB 1016
BRL
IJQ/kg dry 36.3 SW846 8082 02-Nov-07 07-Nov-07 7110256 SM
11104-28-2
PCB 1221
BRL
IJQ/kg
dry 36.3
11141-16-5
PCB 1232
BRL
IJQ/kg
dry 36.3
53469-21-9
PCB 1242
BRL
IJQ/kg dry 36.3
12672-29-6 PCB 1248 BRL
IJQ/kg dry
36.3
11097-69-1 PCB
1254
170
IJQ/kg dry 36.3
11096-82-5 PCB
1260
48.9
IJQ/kg dry 36.3
37324-23-5 PCB
1262
BRL
IJQ/kg
dry 36.3
111Q0-14-4
PCB
1268
BRL
IJQ/kg
dry
36.3
Surrogate recoveries:
10386-84-2
4,4-DB-Octafluorobipheny/ (Sr)
35
30-150%
2051-24-3
Decachforobiphenyl (Sr) 120
30-150%
Total Metals by EPA 6000nooo Series Methods
7439-92-1
Lead
297
mg/kgdry
1.82
SW846 60108
06-Nov-07 08-Nov-07 7110417
TBG
General Chemistry Parameters
%Solids
76.9
% SM2540 G Mod. 05-Nov-07 05-Nov-07 7110310
DBM
Samule Identification
Client Project #
Matrix Collection Datef f ime
VHB-102-2 (0-7")
Received
SA70267-02
12700961
Soil
26-0ct-07 12:10
29-0ct-()7
CAS No.
Analyte(s) Result Flag Units *RDL
Dilution
Metho d Ref. Prepared
Analyzed Batch Analyst
Semivolatile Organic Compounds by GC
Polychlorinated
BiQhenyls
by SW846 8082
Prepared by method SW846 3545A
12674-"11-2
PCB 1016
BRL
IJQ/kg dry
34.7 SW846 8082 02-Nov-07
07-Nov-07 7110256
SM
11104-28-2
PCB
1221
BRL
IJQ/kg
dry
34.7
11141-16-5
PCB 1232
BRL IJQ/kg dry 34.7
53469-21-9
PCB 1242
BRL
IJQ/kg
dry
34.7
12672-29-6
PCB
1248
BRL IJQ/kg
dry
34.7
11097-69-1 PCB
1254
BRL IJQ/kg dry
34.7
11096-82-5 PCB 1260 BRL IJQ/kg dry
34.7
37324-23-5
PCB 1262 BRL
IJQ/kg
dry 34.7
11100-14-4 PCB
1268
BRL
IJQ/kg
dry 34.7
Surrogate recoveries:
10386-84-2
4,4-DB-Octafluorobiphenyl (Sr) 35
30-150%
2051-24-3
Decachlorobiphenyl (Sr) 70
30-150%
Total Metals by EPA 60oonooo Series Methods
7439-92-1
Lead
113
mg/kg dry
1.53
SW846 60108 0 6 - N o v ~ 0 7 0 8 ~ N o v - 0 7 7110417 TBG
General Chemistry
Parameters
%Solids
88.7
% SM2540 G Mod. 05-Nov-07 05-Nov-07 7110310
DBM
This laboratory report is not valid without an authorized signature on the cover page.
*
Reportable Detection Limit BRL
=Below
Reporting Limit
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Samgle Identification
Client Project#
Matrix Collection Dateffi me
VHB-102-3 (0-10")
Received
SA70267-03
12700961 Soil
26-0ct-07
12:25
29-0ct-07
CAS
No. Analyte(s) Result Flag Units *RDL
Dilution
Meth od Ref. Prepared
Analyzed Batch Analyst
Semivolatile
Organic
Compounds by
GC
P o l ~ c h l o r i n a t e d
B i r ; h e n ~ l s
SW846 8082
Prepared by method SW846 3545A
12674-11-2
PCB 1016
BRL
IJQ/kg dry 31.0
SW846 8082 02-Nov-07 07-Nov-07 7110256
SM
11104-28-2
PCB
1221 BRL
IJQ/kg dry 31.0
11141-16-5 PCB 1232
BRL
)JQ/kg dry 31.0
53469-21-9 PCB 1242 BRL
jJQ/kg
dry 31.0
12672-29-6
PCB
1248
BRL
jJQ/kg dry 31.0
11097-69-1
PCB 1254
94.4
)Jg/kg dry 31.0
11096-82-5
PCB 1260
BRL
)Jg/kg dry 31.0
37324-23-5
PCB 1262
BRL
)JQ/kg dry 31.0
11100-14-4
PCB 1268
BRL
)Jg/kg dry 31.0
Surrogate recoveries:
10386-84-2
4,4-DB-Octafluorobipheny/ (Sr) 35
30-150%
2051-24-3
Decach/orobiphenyl (Sr) 60
30-150%
Total Metals by EPA
60oonooo
Series Methods
7439-92-1
Lead
56.9
mg/kg dry 1.60
SW846 60108 06-Nov-07 08-Nov-07 7110417
TBG
General
Chemistry
Parameters
%Solids
89.0
%
SM2540 G Mod.
05-Nov-07
05-Nov-07 7110310
DBM
Samole Identification
Client Project #
Matrix Collection Dateffi me Received
VHB-102-4 (0-9")
12700961 Soil
26-0ct-07 12:35
29-0ct-07
SA70267-04
CAS
No. Analyte(s) Result Flag
Units
*RDL
Dilution
Meth od Ref. Prepared
Analyzed Batch
Analyst
Semivolatile Organic Compounds by GC
P o l ~ c h l o r i n a t e d BiQhenyls
SW846
8082
Prepared by method SW846 3545A
12674-11-2
PCB 1016
BRL
)Jglkg dry
34.5
SW846 8082
02-Nov-07
07-Nov-07 7110256
SM
11104-28-2
PCB 1221 BRL
jJQ/kg
dry 34.5
11141-16-5
PCB 1232
BRL IJQ/kg dry
34.5
53469-21-9
PCB 1242
BRL IJQ/kg dry
34.5
12672-29-6
PCB 1248
BRL IJQ/kg dry
34.5
11097-69-1
PCB 1254
60.2 IJQ/kg
dry
34.5
11096-82-5
PCB 1260
41.3
IJQ/kg dry
34.5
37324-23-5
PCB 1262
BRL
IJQ/kg dry 34.5
11100-14-4
PCB 1268
BRL
IJQ/kg
dry 34.5
· · · ~ ~ ~ ~ ~
Surrogate recoveries:
10386-84-2 4,
4-DB-Octaf/uorobipheny/ (Sr) 30
30-150%
2051-24-3
Decach/orobiphenyl (Sr)
70 30-150%
Total Metals by EPA
6000/7000
Series Methods
7439-92-1
Lead
501
mg/kg dry 1.64
SWB46 60108 06-Nov-07 08-Nov-07 7110417 TBG
General
Chemistry
Parameters
%Solids
83.7
% SM2540 G Mod.
05-Nov-07 05-Nov-07 7110310
DBM
This laboratory report is not valid without an authorized signature on the cover page.
* Reportable Detection Limit
BRL
=
Below Reporting Limit
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Samg:le Identification
Client Project#
VHB"102-5 (0-12")
Matrix
Collection
Dateffime
Received
SA70267-05
12700961
Soil
26-0ct-07 12:55
29-0ct-07
CAS
No. Analyte(s)
Result Flag
Units
•RDL
Dilution
Method Ref. Prepared
Analyzed Batch Analyst
Semivolatile Organic Co mpounds by GC
Polychlorinated BiQhenyls by
SW846 8082
Prepared by method SW846 3545A
12674-11-2
PCB 1016
BRL
IJQ/kg
dry
35.3 SWB46 8082 02-Nov-07 07-Nov-07 7110256
SM
11104-28-2 PCB 1221
BRL
JQ/kg dry 35.3
11141-16-5 PCB 1232
BRL
j.Jg/kg dry 35.3
53469-21-9
PCB
1242
BRL
Jg/kg dry 35.3
12672-29-6 PCB 1248
BRL
Jg/kg dry 35.3
11097-69-1
PCB
1254
256
JQ/kg
dry
35.3
11096-82-5
PCB 1260
101
Jg/kg dry 35.3
37324-23-5
PCB 1262
BRL
Jglk.g dry 35.3
11100-14-4
PCB 1268
BRL
Jglkg dry
35.3
Surrogate recoveries:
10386-84-2
4,4:.08-0ctafluorobipheny/ (Sr)
40
30-150%
2051-24-3
Decachforobiphenyl (Sr) 125
30-150%
Total Metals by EPA
6000nooo
Series Methods
7439-92-1
Lead
929
mglkg dry 7.97
5
SWB46 60108
06-Nov-07 09-Nov-07 7110417
LR
General Chemistry
Parameters
%Solids
79.0
% SM2540 G Mod. 05-Nov-07 05-Nov-07 7110310 DBM
Samgle Identification
Client Project #
VHB-102-6 (0-5")
Matrix Collection Dateffime Received
SA70267-06
12700961 Soil
26-0ct-()7 13:25 29-0ct-()7
CAS No. Analyte(s) Resul t Flag Units
•RDL
Dilution
Method Ref. Prepared
Analyzed Batch
Analyst
Semivolatile Organic Compounds by GC
Polychlorinated BiQheny:ls
by: SW846 8082
Prepared by method
SW846
3545A
12674-11-2
PCB 1016
BRL
JQ/kg
dry 35.0
SW846 8082 02-Nov-07
07-Nov-07 7110256
SM
11104-28-2
PCB
1221
BRL
Jg/kg dry 35.0
11141-16-5
PCB 1232
BRL
Jg/kg dry 35.0
53469-21-9
PCB 1242
BRL
Jg/kg dry 35.0
12672-29-6
PCB 1248
BRL
Jg/kg dry 35.0
11097-69-1
PCB
1254
161
Jg/kg dry 35.0
11096-82-5
PCB 1260
BRL
Jg/kg dry 35.0
37324-23-5
PCB 1262
BRL JQ/kg dry
35.0
11100-14-4
PCB 1268
BRL
Jg/kg dry 35.0
Surrogate recoveries:
10386-84-2
4,4-DB-Octaf/uorobipheny/ (Sr)
35
30-150%
2051-24-3
Decachlorobiphenyl (Sr) 60
30-150%
Total Metals by EPA
600017000
Series Methods
7439-92-1
Lead
66.2
mglkg dry 1.66
SWB46 60108
06-Nov-07 09-Nov-07 7110417
TBG
General Chemistry Parameters
%Solids
83.9
% SM2540 G Mod. 05-Nov-07 05-Nov-07 7110310
DBM
This laboratory report is not valid without an authorized signature on the cover page.
* Reportable Detection Limit BRL =Below Reporting Limit
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Samgle Identification
Client Project#
VHB-102-7 (0-7")
SA70267-07
12700961
CAS
No. Analyte(s) Result Flag Units "RDL
Semivolatile Organic Compounds by GC
P o l ~ c h l o r i n a t e d B i g h e n ~ l s SW846 8082
Prepared by method SW846 3545A
12674·11-2
PCB
1016
BRL
Jg/kg dry 34.0
11104-28-2 PCB 1221
BRL
Jg/kg
dry 34.0
11141-16-5 PCB 1232
BRL
Jg/kg
dry 34.0
53469-21-9 PCB
1242
BRL -19/kg dry
34.0
12672-29-6
PCB 1248
BRL
IJg/kg
dry 34.0
11097-69-1
PCB
1254
47.5
IJg/kg
dry 34.0
11096-82-5
PCB 1260
BRL
IJg/kg dry
34.0
37324-23-5
PCB 1262
BRL
IJg/kg
dry
34.0
11100-14-4
PCB
1268
BRL IJQ/kg dry 34.0
- - - - - - - - - - - - -
Surrogate recoveries:
10386--84-2
4,4-DB-Octaf/uorobiphenyl (Sr)
40
2051-24-3 Decachlorobiphenyl (Sr) 80
Total Metals by EPA 6000/7000 Series Methods
7439-92-1
Lead
Gi neral Chemistry Parameters
%Solids
Samgle Identification
VHB-102-8 (0-11")
SA70267-08
CAS No. Analyte(s)
Semivolatile Organic Compounds by GC
P o l ~ c h l o r i n a t e d
B i g h e n ~ l s
by SW846 8082
Prepared by
method
SW846 3545A
12674-11-2 PCB 1016
11104-28-2
PCB
1221
11141-16-5 PCB
1232
53469-21-9
PCB
1242
12672-29-6 PCB
1248
11097-69-1
PCB 1254
11096-82-5 PCB 1260
37324-23-5
PCB 1262
11100-14-4 PCB 1268
Surrogate recoveries:
108
85.1
Result
BRL
BRL
BRL
BRL
BRL
BRL
BRL
BRL
BRL
10386-84-2
4,4-DB-Octafluorobipheny/ (Sr) 35
2051-24-3
Decachlorobiphenyl (Sr) 85
Total Metals by EPA 6000/7000 Series Methods
7439-92-1
Lead 72.4
General Chemistry
Parameters
%Solids
84.6
30-150%
30-150%
mg/kg dry 1.67
%
Client Project #
12700961
Flag Units
*RDL
IJQ/kg dry
34.5
IJg/kg
dry 34.5
IJg/kg dry 34.5
IJg/kg
dry 34.5
IJQ/kg dry 34.5
IJQ/kg dry 34.5
IJQ/kg dry 34.5
IJg/kg dry
34.5
IJg/kg
dry 34.5
30-150%
30-150%
mg/kg dry 1.55
%
Matrix
Collection DatefTime
Received
Soil
26-0ct-07 13:15
29-0ct-07
Dilution
Method Ref.
Prepared Analyzed Batch Analyst
SW846 8082 02-Nov-07 07-Nov-07 7110256
SM
SW846
60108
06-Nov-07 09-Nov-07 7110417 TBG
SM2540 G Mod. 05-Nov-07 05-Nov-07 7110310 DBM
Matrix
Collection Datef fime Received
Soil
26-0cHl7 13:05
29-0ct-07
Dilution Method Ref.
Prepared
Analyzed Batch Analyst
SW846 8082 02-Nov-07 07-Nov-07 7110256 SM
SW846 601 OB 06-Nov-07 09-Nov-07 7110417 TBG
SM2540 G Mod. 05-Nov-07 0 5 - N o v ~ 0 7 7110310 DBM
This laboratory report is not valid without an authorized signature on the cover page.
* Reportable Detection Limit BRL = Below Reporting Limit
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Sample Identification
Dup-102607
SA70267-09
CAS
No.
Analyte(s)
Semivolatile Organic Compounds by GC
Polychlorinated Biphenyls by SW846 8082
Prepared by method SW846 3545A
12674-11-2
PCB
1016
11104-28-2
PCB 1221
11141-16-5
PCB
1232
53469-21-9
PCB
1242
12672-29-6
PCB
1248
11097-69-1 PCB 1254
11096-82-5
PCB
1260
37324·23-5
PCB
1262
11100·14-4 PCB 1268
- - - - - - -
Su Togate recoveries:
10386-84-2
4,4-DB-Octaf/uorobiphenyl
(Sr)
2051-24-3
Decachlorobiphenyl (Sr)
Result
BRL
BRL
BRL
BRL
BRL
63.8
53.2
BRL
BRL
30
85
Total Metals
by
EPA
60oonooo
Series Methods
7439-92-1 Lead
723
General Chemistry Parameters
%Solids
82.4
Client Project #
12700961
Matrix
Soil
Flag
Units
*RDL
Dilution
f.Ig/kg
dry
35.5
IJg/kg
dry 35.5
f.Ig/kg
dry
35.5
f.Ig/kg dry
35.5
f.Ig/kg dry
35.5
j.Jg/kg dry 35.5
j.Jg/kg dry 35.5
IJg/kg dry
35.5
j.Jg/kg dry
35.5
30-150%
30-150%
mg/kg dry 1.71
%
Collection Dateffime
26-0ct-07 08:00
Received
29-0ct-07
Method Ref.
Prepared Analyzed Batch Analyst
SW846 8082 02-Nov-07 07-Nov-07 7110256 SM
SW846
60108
06-Nov-07 09-Nov-07 7110417 TBG
SM2540 G Mod. 05-Nov-07 05-Nov-07 7110310 OBM
This laboratory report is not valid without an authorized signature on the cover page.
* Reportable Detection Limit BRL = Below Reporting Limit
Page 7
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Semivolatile Organic Compounds
by
GC- Quality Control
Spike Source
o/oREC
RPD
Analyte(s) Result Flag
Units
'RDL
Level Result
%REC
Limits
RPD
Limit
Batch
7110256-
SW846 3545A
Blank (7110256-BLK1)
Prepared: 02-Nov-07 Analyzed: 06-Nov-07
PCB 1016
BRL J.Jg/kg wet 28.6
PCB 1221
BRL
tJg/kg wet 28.6
PCB 1232
BRL
tJQ/kg wet 28.6
PCB 1242 BRL JJQ/kg wet 28.6
PCB 1248 BRL JJQ/kg wet 28.6
PCB 1254 BRL
tJg/kg wet
28.6
PCB 1260 BRL
tJg/kg wet
28.6
PCB 1262 BRL ]Jglkg
wet
28.6
PCB 1268 BRL ]Jg/kg
wet
28.6
- - - - - - - - - - - - - - - -
Surrogate: 4,4-DB-Octafluorobipheny/ (Sr) 11.4 ]Jg/kg
wet
28.6
40
30-150
Surrogate: Decach/orobiphenyl (Sr)
31.4 ]JQ/kg
wet
28.6
110
30-150
LCS (7110256-8511
Prepared: 02-Nov-07 Analyzed: 06-Nov-07
PCB 1016 414 ]lg/kg wet 28.6 357 116 40-140
PCB 1260
441
]lg/kg wet 28.6 357 124 40-140
Surrogate: , 4 - D B ~ O c t a f l u o r o b i p h e n y l (Sr)
10.0
]lg/kg wet
28.6
35
30-150
Surrogate: Decachlorobiphenyl (Sr)
31.4 ]lg/kg
wet
28.6
110
30-150
LCS Du( (7110256-8501)
Prepared: 02-Nov-07 Analyzed: 06-Nov-07
PCB 1016 419 JJQ/kg wet 28.6
357 117
40-140
30
PCB 1260
447 J.Jg/kg
wet 28.6
357 125
40-140
30
Surrogate: 4,4-DB-Octanuorobipheny/ (Sr) 10.0 JJQ/kg wet
28.6 35
30-150
Surrogate: Decachlorobiphenyl (Sr) 28.6
]lQ/kg wet
28.6 .
100
30-150
DU( IiCate f7110256-DUP1) Sourc e: SA70476-01
Prepared: 02-Nov-07 Analyzed: 06-Nov-07
PCB 1016
BRL
)Jg/kg dry 34.7
BRL 40
PCB 1221
BRL
j.Jg/kg dry 34.7
BRL 40
PCB 1232
BRL
j.JQ/kg
dry 34.7
BRL
40
PCB 1242
BRL
)Jg/kg dry 34.7
BRL
40
PCB 1248
BRL j.Jg/kg
dry 34.7
BRL 40
PCB 1254
BRL
j.JQ/kg dry
34.7
BRL
40
PCB 1260
BRL
j.JQ/kg dry 34.7
BRL
40
PCB 1262
BRL IJQ/kg
dry 34.7
BRL
40
PCB 1268
BRL
IJQ/kg dry
34.7
BRL 40
Surrogate: 4,4-DB-Octanuorobiphenyl (Sr) 15.6
IJQ/kg dry
34.7
45
30-150
Surrogate: Decachlorobiphenyl (Sr)
31.2
IJQ/kg
dry
34.7 90 30-150
Matrix S( ike (7110256-MS11
Source: SA70476-01
Prepared: 02-Nov-07 Analyzed: 06-Nov-07
PCB 1016
511
IJQ/kg dry
33.5 418 BRL 122 40-140
PCB 1260
527
tJQ/kg dry 33.5
418 BRL
126
40-140
Surrogate: 4,4-DB-Octanuorobipheny/ (Sr) 13.4
tJg/kg
dry 33.5
40
30-150
Surrogate: Decachforobiphenyl (Sr) 38.5
IJQ/kg dry
33.5
115
30-150
Matrix S ; ike Due f7110256-MSD11 Sourc e: SA70476-01
Prepared: 02-Nov-07 Analyzed: 06-Nov-07
PCB 1016
449
]Jg/kg dry 31.0
387 BRL 116
40-140
5
50
PCB 126Q
426
]Jg/kg dry 31.0
387
BRL 110
40-140 14 50
Surrogate: 4,4-DB-Octafluorobiphenyl (Sr)
10.8 ]Jg/kg dry
30.9
35
30-150
Surrogate: Decach/orobiphenyl (Sr)
29.4 JJglkg dry 30.9 95 30-150
This laboratory report is not valid without an authorized signature on
the
cover page.
* Reportable Detection Limit
BRL =Below
Reporting
Limit
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Total Metals by EPA 6000/7000 Series Methods - Quality Control
Spike Source %REC
RPD
Analyte(s) Result
Flag
Units
'RDL
Level Result
%REC Limits
RPD
Limit
Batch
7110417-
SW846
30508
Blank (7110417-BLK1}
Prepared: 06-Nov-07 Analyzed: 08-Nov-07
Lead BRL mg/kg wet 1.44
Ou( licate (7110417-DUP1J Source:
SA70267-01
Prepared:
06-Nov-07 Analyzed:
08-Nov-07
Lead
342
mglkg dry 1.78
297
14
20
Matrix S( ike (7110417-M$1} Source: SA70267-05
Prepared:
06-Nov-07 Analyzed: 08-Nov-07
lead
933
QM4X
mg/kg dry 1.82 151 929 3
75-125
Matrix
S ; ike Du( (7110417 -M$01}
Source:
SA70267-05
Prepared:
06-Nov-07 Analyzed: 08-Nov-07
Lead
769
QM4X
mg/kg dry
1.74
145 929
-110
75-125
19
35
PostSeike
(7110417-PS1}
Source:
SA70267-05
Prepared: 06-Nov-07 Analyzed: 09-Nov-07
Lead
3670
QM4X
mglkg
dry
1.77
146 929 1860 80-120
Refer ence (7110417-SRM1)
Prepared: 06-Nov-07 Analyzed: 09-Nov-07
Lead 42.0 mg/kg wet 1.50 45.4
92
81.8-118.1
Reference f7110417-5RM2}
Prepared: 06-Nov-07 Analyzed: 09-Nov-07
Lead
41.0 mglkg wet
1.50
44.6
92
81.8-118.1
General Chemistry Parameters - Quality Control
Spike Source o/oREC
RPD
Analyte(s) Result Flag
Units 'RDL
Level Result %REC Limits
RPD
Limit
Batch 7110310- General Preparation
Duelicate f7110310-DUP1) Sourc e: SA70267-01
Prepared
&
Analyzed: 05-Nov-07
%Solids 76.0 % 76.9 20
This laboratory report is not valid without an authorized signature on the cover page.
*
Reportable Detection Limit
BRL = Below Reporting Limit
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Notes
and
Definitions
QM4X
The spike recovery was outside ofQC acceptance limits for the MS, MSD and/or PS due to analyte concentration at 4
times
or
greater the spike concentration. The
QC
batch was accepted based on LCS and/or
LCSD
recoveries within the
acceptance limits.
BRL Below Reporting Limit- Analyte NOT DETECTED at or above the reporting limit
dry Sample results reported
on
a dry weight basis
NR Not Reported
RPD Relative Percent Difference
A plus sign(+) in the Method Reference colwnn indicates the method is not accredited
by
NELAC.
Labora tory Control Sample (LCS1: A known matrix spiked with compound(s) representative of he target analytes, which is used to
document laboratory performance.
Matrix Duplicate: An intra-laboratory split sample
which
is used to document the precision
of
a
method in
a given sample matrix.
Matrix Spike: An aliquot of a sample spiked with a known concentration of arget analyte(s). The spiking occurs prior to sample
preparation and analysis. A matrix spike
is
used to document the bias
of
a method in a given sample matrix.
Method Blank:
An
analyte-free matrix to which all reagents are added in the same volumes
or
proportions as
used
in sample
processing. The method blank should be carried through the complete sample preparation and analytical procedure. The method
blank is used to document contamination resulting from the analytical process.
Method Detectio n Limit (MDL): The minimum concentration of a substance that can be measured and reported with 99%
confidence that the analyte concentration is greater than zero and is determined from analysis
of
a sample in a given matrix type
containing the analyte.
Reportable Detection Limit <RDU: The lowest concentration that can be reliably achieved within specified limits
of
precision and
accuracy during routine laboratory operating conditions. For many analytes the RDL analyte concentration
is
selected as the lowest
non-zero standard in the calibration curve. While the RDL is approximately 5 to 10 times the MDL, the RDL for each sample takes
into account the sample volume/weight, extract/digestate volume, cleanup procedures and,
if
applicable, dry weight correction.
Sample RDLs are highly matrix-dependent.
Surrogate:
An
organic compound
which
is similar
to
the target analyte(s) in chemical composition
and
behavior in the analytical
process, but which is not normally found in environmental samples. These compounds are spiked into all blanks, standards, and
samples prior to analysis. Percent recoveries are calculated for each surrogate.
Validated by:
Hanibal
C.
Tayeh, Ph.D.
Nicole
Brown
This laboratory report is not valid without an authorized signature on the cover page.
*
Reportable Detection Limit
BRL = Below Reporting Limit
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MADEP MCP ANALYTICAL METHOD REPORT CERTIFICATION
FORM
Laboratory Name: Spectrum Ana1ytical, Inc. -Agawam, MA Project#: 12700961
Project Location: CEA Beverly- Beverly, MA
MADEPRTN':
This form provides certifications for the following data set:
SA70267-0l
through
SA70267-09
Sample matrices:
Soil
0
82608
0
8151A
0
8330 fi1l
60108 0
7470A/IA
MCPSW-846
0
8270C
0
8081A
Methods Used
0
VPH
0
6020
0
9014M'
fi1l
8082
0
80218
0
EPH
0
70005'
0
7196A
I List
Release Tracking Number (RTN),
ifknown
2 M SW-846 Method 9014 or MADEP
Physiologically Available
Cyanide (PAC) Method
3 S- SW-846 Methods 7000 Series List
individual method
and analyte
An
affirmative response to questions A, B, C
and
Dis required or "Presumptive Certainty" status
A
Were all samples received by the laboratory
in
a condition consistent with that described
on
the
fi1l Yes
0
No
Chain
of
Custody documentation for the data set?
Were all QA/QC procedures required for the specified analytica1 method(s) included in this report
B
followed, including the requirement to note and discuss in a narrative QC data that did not meet
fi1l Yes
0
No
appropriate performance standards or guidelines?
Does the data included in this report
meet
all the analytical requirements for "Presumptive
c
Certainty", as described in Section 2.0 (a), (b), (c) and (d) of the MADEP document CAM VII A,
"Quality Assurance and Quality Control Guidelines for the Acquisition and Reporting of
fi1l
Yes
0
No
Analytical Data"?
D
VPH and
EPH
methods only: Was the VPH or EPH method conducted without significant
DYes
0
No
modifications (see Section 11.3 ofrespective methods)?
A
response to questions E
and F
below is required or "Presumptive Certainty" status
E
Were
a11
analytical QC performance standards and recommendations for the specified methods
fi1l
Yes
0
No
achieved?
F
Were results for all analyte-Iist compounds/elements for the specified method(s) reported?
0
Yes
fi1l
No
All
negative responses are addressed in a case narrative on the cover page
of
his report.
I,
the undersigned, attest
under
the
pains
and
penalties of perjury
that,
based upon my personal
inquiry
of
those
responsible for
obtaining
the information, the material
contained
in this analytical report is, to the best of my
knowledge
and
belief,
accurate
and
complete.
t}Vtdzj__
Hanibal C. Tayeh, Ph.D.
President/Laboratory Dir ector
Date:
11/12/2007 2:16:53PM
This laboratory report is not valid without an authorizedsignature on the cover page.
* Reportable Detection
Limit
BRL =
Below
Reporting Limit
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Appendix F
Human Health
Risk Assessment
of
Potentia/Indoor and Outdoor
Inhalation Exposure to Landfill
Gas
Emissions From
the
Former
Brimbat
A venue
Landfill
Relative
to Future Development of
the
Site
prepared by Tetra Tech EC, Inc. September 2008
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HUMAN HEALTH RISK ASSESSMENT
OF POTENTIAL INDOOR AND OUTDOOR
INHALATION EXPOSURE TO
LANDFILL GAS EMISSIONS FROM
THE FORMER BRIMBAL AVENUE LANDFILL
RELATIVE
TO
FUTURE DEVELOPMENT
OF
THE SITE
September 2008
Prepared
for
Tetra Tech Rizzo
CEA
Group, Inc.
Prepared by
Tetra Tech EC, Inc.
133 Federal St., Gth
Floor
Boston,
MA
0211 0
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HUMAN
HEALTH RISK
ASSESSMENT
OF
POTENTIAL INDOOR AND OUTDOOR
INHALATION EXPOSURE TO
LANDFILL GAS EMISSIONS
FROM
THE FORMER BRIMBAL A VENUE LANDFILL
RELATIVE TO FUTURE DEVELOPMENT OF THE SITE
Revision
I
September
2008
Prepared for
Tetra Tech Rizzo
CEA
Group,
Inc.
Prepared by
Tetra
Tech
EC
133
Federal
St., 6
1
h Floor
Boston,
MA
02110
Date
09/30/08
Prepared By
T. Ambrose/
M. Newton Lima
Approved By
R. Marnicio
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TABLE OF CONTENTS
1.0 INTRODUCTION AND GENERAL APPROACH ....................................................................
1-1
2.0 RISK ASSESSMENT .................................................................................................................. 2-1
2.1
Hazard Identification ................. : ....................................................................................
2-1
2.1.1 Nature of the Site and the Proposed Development Activity ............................... 2-1
2.1.2 Description of the Areas oflnterest at the Site .................................................. 2-2
2.1.3 Evaluation of the Available LFG Composition Data ......................................... 2-2
2.2 Exposure Assessment ......................................................................................................
2-4
2.2.1 Inhalation Exposure Areas (lEAs) ...................................................................... 2-4
2.2.2 Conceptual Site Model for Air Exposure ........................................................... 2-4
2.2.3 Characterization
of
the Potentially Exposed Populations .................................. 2-5
2.3
Dose-Response Assessment ............................................................................................ 2-6
2.4 Risk Characterization ...................................................................................................... 2-7
2.4.1 Indoor Air Risk Assessment.. .............................................................................
2-7
2.4.2 Outdoor Air Risk Assessment .......................................................................... 2-10
2.4.3 Quantitative Cumulative Inhalation Pathway Risk Assessment ...................... 2-17
2.4.4 Qualitative Cumulative Inhalation Pathway Assessments for the Off-Site
Residents and the Commercial I Retail Customers .......................................... 2-18
2.4.5 Qualitative Odor Threshold Evaluation for Hydrogen Sulfide (H
2
S) .............. 2-19
2.5 Uncertainty Analysis ..................................................................................................... 2-19
2.5.1 LFG Composition ............................................................................................ 2-19
2.5.2 LFG Generation and Emission Rate ................................................................. 2-20
2.5.3 Atmospheric Mixing and Dispersion Modeling Using a Box Model... ............ 2-20
2.5.4 Exposure Frequency and Exposure Duration, and Daily Exposure Time ........ 2-21
2.5.5 Vapor Intrusion Modeling Input Parameters .................................................... 2-21
2.5.6 Exposure Parameters ........................................................................................ 2-22
2.5.7 Toxicity Criteria ............................................................................................... 2-22
3.0 SUMMARY AND FINDINGS ....................................................................................................
3-1
4.0 REFERENCES ............................................................................................................................. 4-l
FIGURES
Figure 1. Site Location Map
Figure
2.
Proposed Layout for Site Development
Figure 3. Soil Gas Sampling Locations
Figure 4. Sizes and Orientations
of
the Boxes Assumed for the Outdoor Air Mixing and Dispersion
Analysis
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TABLES
Table
l.
Summary of Landfill Gas Sampling Results for 2008
Table 2. Calculation of the Average Soil Gas Concentrations for the Detected LFG Constituents by
Inhalation Exposure Area
Table 3. Conceptual Site Model for the Potential Inhalation Exposures Associated with Development
at the North Shore Commons Site
Table 4. Inhalation Toxicity Values for the Detected Landfill Gas Constituents Associated with
Cancer and Non-Cancer Health Effect Endpoints
Table 5. Site-Specific Subsurface Soil and Site Parameters that Were Used to Project Vapor Diffusion
and Intrusion Into Indoor Air for the Cumulative Inhalation Pathway Risk Calculations (Same
for All Scenarios)
Table 6. Scenario-Specific Building Dimensions and Receptor Exposure Parameters Used in the
Cumulative Inhalation Pathway Risk Calculations
Table.7. Summary of the Results of he Indoor Air Risk Assessment for the North Shore Commons
Site
Table 8. Summary of the Results of he Indoor Air Risk Assessment for the Receptors Associated with
Future Development
Table 9. Summary of the LandGEM Modeling Results for LFG and Hydrogen Sulfide Generation
Rates Over Time for the Former Brimbal Avenue Landfill
Table
10.
Average Annual Wind Speed and Direction Data for the Beverly Cove Meteorological
Station, Beverly, MA (2000-2007)
Table II. Airborne Mixing and Dispersion Calculations for the Concentrations of Landfill Gas
Constituents in the Outdoor Air at the Eastern Inhalation Exposure Area
Table 12. Airborne Mixing and Dispersion Calculations for the Concentrations of Landfill Gas
Constituents
in
the Outdoor Air at the Western Inhalation Exposure Area
Table 13. Airborne Mixing and Dispersion Calculations for the Concentrations of Landfill Gas
Constituents in
the Outdoor Air at the Site-Wide Inhalation Exposure Area
Table 14. Calculation of the Cancer and Non-Cancer Inhalation Risk Estimates Relative to Outdoor
Exposure for Each Inhalation Exposure Area
Table 15.
Summary of the Results
of
he Outdoor Air Risk Assessment for Each Inhalation Exposure
Area (Applicable to All Receptors Exposed to Outdoor Air)
Table 16. Combined Results of the Indoor and Outdoor Air Inhalation Risk Assessments for the North
Shore Commons Site for Each Inhalation Exposure Area
Table
17.
Summary of the Hydrogen Sulfide Sampling Results and Relevant Odor Thresholds and
Occupational Safety Criteria for Hydrogen Sulfide
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APPENDICES
Appendix A Site Visit Photographic Log (August 15, 2008)
Appendix B Test America Laboratory Report for the Soil Gas Probe Samples (August
18,
2008)
Appendix C LandGEM Output for the Modeling of Landfill Gas Generation at the Former Brimbal
Avenue Landfilll in Beverly, MA
Appendix D Selected Illustrative Johnson and Ettinger Model Calculation Worksheets for Potential
Landfill Gas Vapor Intrusion and Inhalation Risk Assessment
Appendix E Compilation ofthe Indoor Air Vapor Intrusion Risk Calculation Results by Inhalation
Exposure Area
iii
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ATe
ATN
ATSDR
bgs
c
CAA
CalEPA
em
CMR
coc
CSM
DL
DTSC
ED
EF
ELCR
foe
g
Griffin Engineering
H
2
S
HEAST
m
hr
HHRA
HVAC
lEA
m
IRIS
IUR
J&E
L
LandGEM
LEL
LFG
m
m'
m'
mg
MassDEP
MCP
Mg
MH
NMOC
NSPS
ACRONYMS AND ABBREVIATIONS
averaging time for carcinogenic risk
averaging time for non-carcinogenic risk
Agency for Toxic Substance and Disease Registry
below ground surface
Centigrade degrees
Clean Air Act
California EPA
centimeter
Code of Massachusetts Regulations
chemicals of concern
conceptual site model
detection limit
Department of Toxic Substances Control
exposure duration
exposure frequency
Excess Lifetime Cancer Risk
fraction of organic carbon
gram
Griffin Engineering Group, LLC
Hydrogen sulfide
Health Effects Assessment Summary Tables
Hazard Index
hour
Human Health Risk Assessment
heating, ventilating, and air conditioning
Inhalation Exposure Area
inch
Integrated Risk Information System
Inhalation Unit Risk
Johnson and Ettinger
liter
Landfill Gas Emissions Model
Lower Explosive Limit
landfill gas
meter
square meters
cubic meters
milligram
Massachusetts Department of
Environmental Protection
Massachusetts Contingency Plan
Megagram
mixing height
Non-Methane Organic Compound
New Source Performance Standards
IV
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OHM
ORNL
PEL
ppb
ppm
PPRTV
RfC
RL
s
ug
USEPA
URF
uses
voc
yr
ACRONYMS AND ABBREVIATIONS- Cont'd
Oil or Hazardous Material
Oak Ridge National Laboratory
Permissible Exposure Limit
parts per billion
parts per million
Provisional Peer Reviewed Toxicity Value
reference concentration
reporting limit
second
microgram
U.S. Environmental Protection Agency
Unit
Risk Factor
Unified Soil Classification System
volatile organic compound
year
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1.0 INTRODUCTION AND GENERAL APPROACH
CEA Group, Inc., located in Cambridge, Massachusetts, is considering the development of the Former
Brimbal Avenue Landfill
in
Beverly, Massachusetts, which
is
referred to
in
this assessment as the North
Shore Commons Site. This Human Health Risk Assessment (HHRA) was conducted to evaluate the
potential risks to receptors that could be exposed to landfill gas (LFG) emissions by inhaling its
constituents either outdoors or indoors within the buildings associated with future development
of
the site.
Two primary inhalation exposure possibilities exist with respect to development at the site: l) as the
result
of
vapor migration from the subsurface soil or waste up into the indoor air
of
structures that may be
built as part
of
the development; and 2) in the outdoor air following the release ofLFG and its mixing and
dispersion
in
the air at the site.
The potential exposures and risks due to the inhalation
of
volatile vapors emitted from the inactive landfill
were evaluated by first developing a conservative estimate of the generation and emission rate of the
LFG. This LFG emission rate was then combined with measurements of
on-site soil gas collected
in
the
area that is currently being considered for development. Together, this information provides a reasonable
estimate
of
the amount and composition
of
the LFG emissions that may lead to potential future exposures.
The LFG releases could migrate and enter into the indoor spaces
of
the new structures that may be
constructed on-site. The general design and construction characteristics
of the potential structures were
projected based on knowledge of the site and the features of similar structures in this area. The
dimensions
of
the indoor air spaces most likely to be impacted by vapor intrusion were estimated from
typical building sizes depicted in one of the proposed development plans. A vapor intrusion model was
applied to estimate the concentrations of the LFG contaminants that may be created in the indoor air of
the future structures.
The LFG emissions at other locations at the site would be released and mixed with the ambient air that
blows across the surface of the property. This mixing and dispersion process would dilute the
concentration of any LFG constituents emitted. The conceptual mixing and dispersion and the dimensions
of
the air volume into which the LFG emissions would
be
released were established based on the
proposed development plans and the detected soil gas constituent distributions. A mixing and dispersion
model was applied to estimate the outdoor concentrations of the released LFG contaminants within the
potential breathing zone
of
the people that are likely to be present on-site given the proposed
development. The level
of
risk associated with breathing this outdoor air was also estimated using
exposure parameters tailored to the future site users.
The representative concentrations
of
each constituent found to be present in the soil gas were entered into
the models for calculating the indoor and outdoor air exposure point concentrations. These concentrations
were combined with exposure parameters associated with the potential site future users and with
chemical-specific toxicity values for the constituents detected in the soil gas to develop estimates
of
the
potential inhalation risks posed to the people associated with the future development. These estimates of
the inhalation cancer and non-cancer risk were compared to the established Massachusetts Contingency
Plan (MCP) target risk thresholds to determine whether or not the proposed development poses a
"significant risk" to human health.
This risk assessment also includes qualitative assessments of the potential on-site exposure to hydrogen
sulfide (H
2
S) gas and the potential for exposure to released LFG constituents in the soil gas or ambient air
that may have migrated off-site.
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2.0 RISK ASSESSMENT
This risk assessment of the potential inhalation exposures to a set
of
site-specific receptors was performed
in accordance with the risk characterization protocols established by the Massachusetts Department of
Environmental Protection (MassDEP) for the MCP program. Human health risk characterizations
performed under the MCP are conducted to determine whether conditions at a site pose a risk of harm to
health. The MCP provides three options for defining a level
of
"no significant risk":
• Method l uses published numeric standards for more than l 00 common chemicals in soil and
groundwater;
• Method 2 allows for some adjustments in these standards to reflect site-specific conditions; and
• Method 3 allows for the potential risks to be estimated on the basis of a site-specific exposure
parameters and site conditions.
A MassDEP Method
3
risk characterization is a cumulative risk assessment that considers all
of
the
exposure pathways associated with a receptor and a land use with respect to the chemicals
of
concern
(COCs). A Method 3 risk characterization consists of five steps (MassDEP 1996):
l.
Hazard Identification
2. Exposure Assessment
3. Dose-Response Assessment
4. Risk Characterization
5. Uncertainty Analysis
The subsections that follow present each of these components of the focused assessment of the potential
inhalation risks to a set of potential future groups expected to access or use the site or facilities of the
proposed development at the North Shore Commons Site.
2.1 Hazard Identification
The hazard identification step describes the chemical constituents that may be present in an area or
associated with the location
of
an exposure scenario.
It
identifies those chemicals that may be
of
concern
from a human health risk perspective given the concentration in which they are present and the nature of
the adverse effects that may be associated with exposures. To identifY these constituents, an
understanding
of
the current land use and the proposed future development was established. Thereafter,
the area of the site where the proposed development is to occur was defined. Finally, the composition of
the LFG that may be generated and migrate into the indoor air via diffusion through the foundations of
future buildings or into the ambient outdoor air where this development may be performed was identified.
These aspects
of
the assessment are discussed further below.
2.1.1 Nature of the Site and the Proposed Development Activity
The North Shore Commons Site
is
comprised
of
just over 6 acres and
is
located off
of
Route 128 on
Brimbal Avenue, next to the Northridge Homes Cooperative, Inc. in Beverly,
MA.
The general location
of the site is presented in Figure
l.
The landfill material is covered by soil, but there is no cap
or
landfill
gas vents installed at this time. The proposed future activities to take place at the site would be expected
to result in some level
of
exposure to the LFG released from the soil and waste beneath and within the site
boundary.
Historical activities performed at the North Shore Commons Site included the installation of
a 24-inch
drainage culvert through the site in 1946. Prior to this date, the site was undeveloped and contained a free-
2-l
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flowing stream. The Town of Beverly began using the site as a landfill between 1946 and 1947, and
continued dumping at the site until approximately 1961. During that time, the landfill accepted primarily
municipal household waste and some construction debris. The site has been inactive as a landfill since
1961, and the there are no municipal records of any other development
or
activities since that time.
2.1.2 Description of the Areas
of
Interest at the Site
Figure 2 depicts one proposed plan for the development
of
the site. The northwestern portion
of
the site is
the area designated for the development of a Day Care Center under this proposal. The remaining
southeastern portion of the site
is
the area designated for the development of commercial, retail, and/or
residential facilities under the proposal shown. The overall site has an approximate length (northwest
southeast) of 650 feet (or 198.1 meters [m]) and an approximate width (northeast-southwest) of 400 feet
(or 121.9
m).
The site
is
relatively flat, ranging in elevation from
78
feet to 86 feet across the area with
changes in grade near the outer boundaries adjacent to the roads and a few low-lying areas near the
drain line.
In
order to obtain the site-specific information needed to conduct the risk assessment, a site walk and
reconnaissance of the property were conducted on August 15, 2008. The site visit and reconnaissance was
performed by Ron Marnicio
of
Tetra Tech EC, Inc. on August
15,
2008. The entire site was examined and
also the surrounding properties and usages. Twenty-nine photographs taken during the site visit are
presented in Appendix A. The photographs identified below highlight the following specific features of
the site:
I. Photograph l:
2. Photograph
17:
3. Photograph
9:
4. Photograph
13:
5.
Photograph
2:
6. Photograph 7:
General Location of the Proposed Development Area
View to the South across the Western Portion of the Site
View to the South across the Eastern Portion of
he Site
View to the South showing the Nearest Off-Site Residence
View showing the Property Advertisement Sign Posted On-Site
View across Brimbal Avenue showing the existing Commercial/Retail
Establishments
Soil borings made on-site show the soil to be coarse to medium sand, with some fine sand and surficial
organic soil and traces of silt, gravel, clay and debris at depth. The site
is
generally flat and vegetated with
scrub brush and small trees except where the vegetation was removed to provide access for well
placement or the soil borings, or the groundwater or soil gas sampling. Along the eastern edge
of
the site,
near Brimbal A venue, there is a section of exposed pavement that
is
a remnant of a former building
foundation slab. A drain line runs under the site and through a culvert under the Route 128 Access Road
on the northwestern edge of the site.
2.1.3 Evaluation of the Available LFG Composition Data
Soil gas samples were collected at a depth of between 3 and 8 feet below the ground surface by Griffin
Engineering Group, LLC (Griffin Engineering) on December 19, 2007 and August 4, 2008. The 2007
sampling occurred within three sample locations (GP-5, GP-6, and GP-14) and the 2008 sampling
occurred at eight additional locations (GP-6R, GP-11, GP-12, GP-14, GP-20, GP-21, GP-25, and GP-26)
(see Figure
3).
A natural gas leak was detected under the street in the vicinity of sample GP-14 as the
result of uncharacteristically high levels of methane being detected in the soil gas being sampled at this
end of the site. Consequently, the LFG toxic constituent results for this sample were highly suspect and
the results of this sample were eliminated from further consideration and use in this risk assessment.
In
addition, the sample extraction structures at GP-5 and GP-6 were both destroyed subsequent to the 2007
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sampling event, so additional data collection at these locations was not possible in 2008. For these
reasons, only the 2008 sampling data (with the exception
of
sample GP-14) were used to establish the
characteristics
of
the LFG emissions for the risk assessment. The results for H
2
S from the 2007 sample
collected at GP-6 were, however, used in the qualitative assessment
of
this constituent. Table I presents
the soil gas sample data. The locations of these seven sampling points that were spread across the site are
shown
in
Figure
3.
It is
common that the composition
of
the waste disposed in various parts
of
a landfill varies, and that the
composition
of
the LFG generated at a location depends a great deal on the nature
of
the waste disposed
there (among other factors like age and moisture content). For this risk assessment, a characterization
of
the composition of the LFG that would be released from the site during completion of the proposed
development was necessary. However, this gas does not now exist and cannot, therefore, be measured
directly.
In
addition, the LFG is likely to change over time as soil gas migration shifts in response to
ongoing waste decay, landfill settlement, and the overlying disturbances associated with the new
development and its construction.
The concentrations of a total of 49 volatile organic compounds (VOCs) were quantified by Test America
in
each soil gas sample using Method T0-15 (see -Appendix B for the full data reports).
Of
these
49 VOCs, only 17 were detected
in
at least one
of
the seven samples. In addition, samples were also
analyzed for a set
of
common sulfide compounds.
Of
these, only one common sulfide (H
2
S) was detected
in any of the seven samples.
After evaluating the concentration patterns detected in the soil gas samples, it was seen that the samples in
the western portion
of
the site were somewhat distinct
in
composition from the eastern side. This was
especially true for the soil gas constituents
of
tetrachloroethene, trichloroethene, chloroform,
chlorobenzene, and dichlorodifluoromethane as they were only detected on the western side of the site.
Similarly, methylene chloride and 1,2,4-trimethylbenzene were only detected on the eastern side
of
the
site see Table I), As such, the data from GP-6R, GP-20 and GP-26 were considered collectively to
characterize a Western Inhalation Exposure Area (lEA), and the data from GP-11, GP-12, GP-21 and GP-
25
were grouped together to characterize
an
Eastern lEA. Figure 4 shows the line dividing the site into
these two lEAs. Separate risk calculations were performed for the Western and Eastern lEAs, as well as
for a Site-Wide lEA, whose soil gas characteristics were based on the analytical results for all seven
of
the 2008 samples.
Average concentrations for each detected VOC in the soil gas samples from each lEA were calculated for
use in the risk assessments. When a particular compound was not detected in a particular sample in the
set, one half
of
the maximum detection limit (DL) indicated for that compound by the laboratory was used
as the concentration for the purpose of calculating the average LFG constituent concentration. This
process is in accordance with the MassDEP
Guidance
for
Disposal Site Risk Characterization
(MassDEP
1996). Table 2 summarizes these analytical results for the three exposure areas. It should be noted that
bolded entries
in
the sample results columns indicate a detected concentration
of
that constituent
in
that
sample. The maximum measured concentrations were not considered to
be
characteristic of the LFG
constituent concentrations
in
the soil gas across the entire site or across an lEA. Use
of
all the maximum
detected concentrations
in
the risk assessment would be overly conservative with respect to the risks
posed by actual conditions that might be expected at the site.
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2.2
Exposure Assessment
This exposure assessment identifies the potential exposure areas, the potentially exposed populations and
the potential routes
of
inhalation exposure for the people associated with the proposed development at the
North Shore Commons Site.
2.2.1 Inhalation Exposure Areas (lEAs)
As described above, the site displayed some soil gas contamination patterns that justified evaluating
potential exposures to soil gas separately
in
the western and eastern portions
of
the site. The proposed
development plan depicted
in
Figure 2 shows a possible Day Care facility
in
the Western lEA and
possible CommerciaVRetail and Residential use in the Eastern lEA. However, this risk assessment
evaluated all
of
these potential uses relative to each
of
the identified lEAs. As such, it
is
not predicated on
any particular development proposal.
2.2.2 Conceptual Site Model for Air Exposure
A conceptual site model (CSM) illustrates the exposure pathway relationships between the potential
sources
of
the VOCs associated with the subsurface conditions at the site and the potential inhalation
exposures
of
these compounds to future users or occupants
of
the site. A complete exposure pathway
is
comprised
of
the following elements:
• A source and mechanism of chemical release to the environment (i.e., releases of LFG from the
subsurface waste material);
• An environmental transport medium for the released chemical (i.e., the ambient air where mixing
and dispersion
of
the released LFG constituents would occur or the indoor air where migrating
soil gas vapors penetrating through cracks
in
the floor
of
the proposed new
s t r u ~ t u r e s
would mix
with ventilated air within the buildings);
• A point
of
potential coritact by people with the contaminated medium (i.e., the breathing zones
within the lEAs); and
• A route of intake or exposure (i.e., inhalation of the dispersed LFG constituents by a person at
the site).
Table 3 presents a simplified tabular CSM for the North Shore Commons Site assummg a future
development scenario.
It
should be noted that the site is currently inactive.
The LFG that is generated within the emplaced waste could migrate up and into the indoor air
of
the
future buildings as well as into the ambient air. The processes of diffusion and convection could result in
the subsurface contaminants being transported into the ground level indoor air spaces of a potential new
slab-on-grade commerciaVretail or residential structure. The concentration
of
the
LFG
contaminants
in
the indoor air also is shown to be affected by the ventilation and mixing
of
the intruding soil gas with
relatively fresh ambient (outside) air. Any future occupants
of
these structures also would be exposed to
this indoor air. Soil gas also could migrate into the indoor air spaces through preferential migration
pathways, such as storm water or sewer lines, underground utility corridors or building foundations. Soil
gas can also be released into the open air and naturally dispersed. A future site user would be exposed to
these contaminants at some level in the ambient outdoor air.
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2.2.3 Characterization of the Potentially Exposed Populations
The proposed development of the North Shore Commons Site creates the opportunity for a variety of
receptors to be exposed to the LFG emissions via the inhalation route of exposure. These receptors are
described below.
• Commercial/Retail Worker - This individual would work on-site inside a new slab-on-grade
building to be constructed as part of the proposed development. The Commercial/Retail Worker
is assumed to be an adult from 18 to 45 years of age who would work
at
the site 5 days per week
for 8 hours per day over 50 weeks
of
the year. This receptor is expected to be exposed to indoor
air for 7 hours per day and outdoor ambient air for I hour per day (e.g., during breaks).
• Day Care Worker/Toddler- These individuals would be present on-site spending time both inside
and outside a Day Care facility to be constructed as part
of
the proposed development. The Day
Care Worker would be an adult from 18
to
45 years of age and the Toddler enrolled at the Day
Care would be between l and 5 years of age. Both the Day Care Worker and Toddler are
expected to be present
at
the site 5 days per week for 8 hours per day over 50 weeks
of
the year.
Both of these receptors are expected
to
be exposed
to
indoor air for 6 hours per day and outdoor
air
for 2 hours per day.
• Maintenance Worker - This individual would work on-site primarily inside a building to be
constructed as part of the proposed development. The Maintenance Worker is assumed to be an
adult from
18
to 45 years of age who is present at the site 5 days per week for 8 hours per day
over 50 weeks
of
the year, This receptor is expected to be exposed to indoor
air
for 7 hours per
day and outdoor ambient air for
I
hour per day.
• Landscape Worker - This individual would work on-site primarily outdoors. The Landscape
Worker is assumed to be an adult from 18 to 45 years of age who is present at the site 5 days per
week for 8 hours per day over 50 weeks of the year. This receptor is expected to be exposed to
indoor air for only I hour per day and outdoor ambient
air
for 7 hours per day.
• Construction Worker- This individual would work on-site and outdoors on projects related to the
proposed development. The Construction Worker is assumed to be an adult
at
22 years of age
who accesses the site 5 days per week for 8 hours per day over 26 weeks
of
the year. This
receptor is expected to be exposed to outdoor air for the entire 8-hour workday.
• Utility Worker - This individual would work on-site and outdoors on facilities related
to
the
proposed development. The Utility Worker is assumed to be an adult at 22 years of age who
accesses the site 5 days per week for 8 hours per day for I week of the year. This receptor is
expected to be exposed to outdoor air for the entire 8-hour workday.
• On-Site Adult/Child Resident - These individuals would be present on-site both inside and
outside of a new slab-on-grade residential building constructed as part of the proposed
development. The On-Site Resident could be an Adult from
15
to 30 years of age
or
a Child from
I to 8 years of age. Both the Adult and the Child Resident are expected to be present on-site
7 days per week for 24 hours per day over 52 weeks
of
the year. These receptors are expected to
be exposed to indoor air for 20 hours per day and outdoor air for 4 hours per day.
• Off-Site Adult/Child Resident - These individuals would not be present on-site, but would be
residing adjacent to the site. The Off-Site Resident would be an Adult from 15 to 30 years of age
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or a Child from I to 8 years
of
age. Both the Adult and the Child Resident are expected to be
present at the off-site location 7 days per week for 24 hours per day over 52 weeks
of
the year.
These receptors are expected to be exposed to outdoor air for only 4 hours per day.
• Commercial/Retail Customer - This receptor would temporarily be present at a new slab-on
grade retail structure to be constructed as part
of
the proposed development. The Customer could
be either
an
Adult or a Child. The Commercial/Retail Customer
is
assumed to access the site once
per day 5 days per week for
0.5
hour per day over 50 weeks
of
the year. These receptors are
expected to be exposed to indoor air for 1/4 hour per day and outdoor air for 1/4 hour per day.
• Trespasser - This member
of
the public may enter the site now or after development despite
physical barriers or prohibitions to not
do
so.
An
On-Site Trespasser
is
likely to be "passing
through" to a surrounding area adjacent to the site. The Trespasser
is
assumed to
be
an adolescent
teenager from 8 to 15 years of age who may be present at the site about once a day (during the
seven warmer months
of
the year) for about two hours per incursion. The trespasser
is
expected to
be outdoors and would, therefore, only be exposed to the outdoor air encountered at the site.
2.3 Dose-Response Assessment
The relationship between the level
of
exposure and the likelihood and/or severity
of
an adverse health
effect can be determined
by
analyzing the toxicity
of
a LFG constituent. Section 7
2.1 of
the
Guidance for
Disposal Site Risk Characterization
(MassDEP 1996) indicates:
"A Reference Concentration
(RfC,
in units
of
mg/m
3
) is the inhalation exposure concentration
(with uncertainty spanning perhaps an order
of
magnitude or greater) to which daily exposure
of
a
human population, including sensitive populations,
is
likely to be free
of
appreciable effects. The
Massachusetts Contingency Plan requires that primary consideration be given to information
developed by the U.S. Environmental Protection Agency (31 0 CMR 40.0993(5)(a))."
Similarly, Section 7.2.2
of
the
Guidance
for
Disposal Site Risk Characterization
(MassDEP 1996)
indicates:
"The ability of a chemical to increase the incidence of cancer in a target population is described by
one
of
two measures: the cancer slope factor or the unit risk. The Unit Risk is the upper 95%
Confidence Limit
of
the mean incremental lifetime cancer risk estimated to result from lifetime
exposure to
an
agent
if it
is in the air at a concentration of I J.Lg/m
3
.
The inhalation toxicity values applied in this risk assessment are presented in Table
4.
The following is a
list
of
sources for both
RfC
and Inhalation Unit Risk (IUR) values
in
the order
of
preference for use
in
this risk assessment:
I. MassDEP' s Shortforms for Human Health Risk Assessment default v0207 workbook,
February 2007;
2. U.S. Environmental Protection Agency's (USEP A 2008) Integrated Risk Information System
(IRIS);
3. USEPA's Provisional Peer Reviewed Toxicity Values (PPRTVs); and
4. Other Toxicity Values. When information is not available in IRIS or PPRTV, the following
sources were reviewed to determine whether comparable values exist that are appropriate for
quantitative risk assessment:
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a.
Agency for Toxic Substance and Disease Registry (ATSDR 2008) - ATSDR has produced
Toxicological Profiles for over 275 hazardous substances.
b. California EPA (CaiEPA 2008)- These values are reviewed by toxicologists for the State of
California, and address both cancer and non-cancer health effects.
c. Oak Ridge National Laboratory (ORNL) National Regional Database of Preliminary
Remediation Goals - This database was developed under an interagency agreement with the
USEPA and includes toxicity information use utilized by USEPA Regions III, VI, and IX.
d. Other USEPA source documents and USEPA Technical Support.
2.4 Risk Characterization
The risk characterization step combines the hazard identification, exposure assessment, and dose-response
assessment components to develop a quantitative estimate of the chronic risk of harm to human health.
For this risk assessment, cancer and/or non-cancer risks were estimated separately for the potential
inhalation exposures of the identified receptors. Incremental chemical-specific contributions to risk were
then summed to generate cumulative Excess Lifetime Cancer Risk (ELCR) estimates and/or cumulative
non-cancer Hazard Indices (HI) estimates for exposure to indoor and outdoor air. These results for indoor
air exposure and for outdoor air exposure were then added together (when the receptor was assumed
"to
be
exposed to both media) and the sums were compared to the MassDEP Cumulative Receptor Risk Limits
(31 0 CMR 40.0933(6)) to assess whether a condition of "no significant risk" would exist for the proposed
development. A condition of "no significant risk" of harm to human health exists for a potentially
exposed individual if:
• the Cumulative Receptor Non-Cancer Risk calculated for that individual (i.e., the HI)
is
less than
or
equal to the Cumulative Receptor Non-Cancer Risk Limit of 1.0; and
• the Cumulative Receptor Cancer Risk calculated for that individual (i.e., the ELCR)
is
less than
or equal to the Cumulative Cancer Risk Limit of I x Io·'.
Section 7 4.1 of the MassDEP
Guidance
for
Disposal Site
Risk
Characterization
states that the potential
for non-cancer health effects
is
measured by the HI. The HI ratio compares the exposure concentration
of
the "Oil or Hazardous Material" (OHM) within the air to the allowable level or the RfC (Reference
Concentration toxicity value). This ratio
is
calculated using the following equation:
HI; =OHM I RfC, =CAMEAt I RfC,
Section 7.4.2 of the MassDEP
Guidance
for
Disposal Site Risk Characterization
states that the potential
for cancer health effects is measured by the ELCR. The ELCR value represents the probability of
developing cancer over a lifetime due to a specified exposure concentration of OHM within the air. The
IUR toxicity value is a measure of cancer potency and
is
used to estimate the ELCR by the following
equation:
ELCR,
=
OHM x IUR;
=
CAidEAi
x IUR;
The following sections discuss the indoor and outdoor air risk characterizations, as well as the models
used to perform the assessments.
2.4.1 Indoor Air Risk Assessment
The LFG generated in the subsurface may potentially migrate up into the indoor air of a new structure that
may be constructed as part of the proposed development. An assessment of the potential inhalation risks
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associated with the volatile constituents measured in the soil gas vapor was conducted with respect to
their potential migration into such buildings. The indoor air risk assessment included the performance of a
series of area-specific cumulative risk calculations that were performed using the average soil gas
concentrations measured in each
lEA
and other site-specific and default parameters applicable to the site
and the potential receptors that may use the site in the future. Projections were made of the level
of
inhalation risk associated with vapor intrusion into a hypothetical future Day Care facility, a Commercial/
Retail establishment, or a Residential structure that may be constructed within each lEA.
The site-specific evaluation was a cumulative multi-constituent inhalation pathway risk assessment that
included the following components:
• Using the average calculated soil gas concentrations for each detected VOC within the three
defined lEAs (i.e., the Eastern, Western and Site-Wide lEAs);
• Modeling the upward migration of each detected VOC (accounting for diffusion and convection)
into a hypothetical slab-on-grade Day Care, CommerciaVRetail, or Residential building (using the
vapor intrusion model and the default soil parameters used by MassDEP to calculated the MCP
GW-2 Method I Groundwater Standards);
• Using the projected indoor
air
VOC concentrations as the exposure point concentratio-ns for the
receptors associated with the hypothetical development scenarios (i.e., an Adult and Child
Resident, a Day Care Worker, a Day Care Toddler, and a Commercial/Retail Worker) by
considering indoor air mixing and ventilation with fresh outdoor air
at
each structure;
• Calculating the inhalation-related exposure to each detected/modeled VOC;
• Applying the appropriate inhalation toxicity values for cancer and/or non-cancer health effect
endpoints for each
VOC
detected in each lEA;
• Summing the constituent-specific contributions to the cumulative
ELCR
and/or the cumulative
non-cancer
HI
for each receptor
to
calculate the corresponding cumulative risk estimates for each
lEA; and
• Comparing these estimates
to
threshold limits for cancer risk (i.e., an ELCR of l.OE-5) and/or
non-cancer risk (i.e., a HI of I) to assess the suitability of the current conditions in each lEA for
potential development
of
the types identified with respect to possible vapor intrusion.
The USEPA Johnson and Ettinger (J&E) Vapor Intrusion Model (USEPA 2004) was used to calculate the
projected indoor air concentrations associated with the average soil gas VOC concentrations for each
lEA. The vapor intrusion and inhalation risk calculations were performed for each of the f0ur hypothetical
receptors (i.e., a resident, an adult worker at a day care, a toddler at a daycare, and a commerciallretail
worker). The calculations were performed using a combination
of
site-specific information, default
MassDEP parameters used for the determination of the MCP GW-2 Method I Standards and default J&E
model assumptions. Table 5 presents the site-specific input parameters that were assumed for the vapor
intrusion analysis.
Other input parameters to the vapor intrusion modeling
or
receptor-specific exposure parameters used in
the risk calculations varied across the four hypothetical future use scenarios. These scenario-specific
assumptions were used to more accurately reflect the conditions and lengths of times that each receptor
associated with that scenario could be exposed to LFG emissions. The length and width of the potential
future Day Care and Commerciai Retail buildings were estimated based on the potential site configuration
shown in Figure
2.
The length and width of the potential future Residential building was taken as the
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default assumption used in the calculation of the MCP GW-2 Method I Standards. Table 6 presents the
input parameters whose values differed for the various scenarios to account for variations in the possible
building dimensions, the people likely to use or occupy the buildings, and the amount of time the person
would potentially be exposed to soil gas contaminants intruding into the indoor air.
Using the site-specific soil gas concentrations, soil properties, and building characteristics, the vapor
intrusion modeling was performed using the J&E Model for each
of
the three lEAs for:
I. each of the VOCs detected in the soil gas in that lEA (i.e., for 10 VOCs in the Eastern lEA, 13
VOCs in the Western lEA, and 15 VOCs in the Site-Wide lEA); and
2. the residential, commercial/retail, and day care exposure scenarios.
These combinations represent 570 different J&E modeling runs (i.e., 3 lEAs x 5 future use scenarios x I 0,
13, or 15 VOCs per lEA, respectively). Appendix D presents a selection of these J&E Model calculation
worksheets [SG-ADV Version 3.1; 02/04] that were used to calculate the chemical-specific indoor air
inhalation risks. For illustration, the worksheets for the following cases are presented in Appendix
D:
• Set D-1: Residential (Adult) Scenario for tetrachloroethene for the Site-Wide lEA
• Set D-2: Residential (Child) Scenario for tetrachloroethene for the Site-Wide lEA
• Set D-3: Commercial/Retail Scenario for tetrachloroethene for the Site-Wide lEA
• Set D-4: Day Care (Adult) Scenario for tetrachloroethene for the Site-Wide lEA
• Set D-5: Day Care (Toddler) Scenario for tetrachloroethene for the Site-Wide lEA
• Set D-6: Day Care (Toddler) Scenario for tetrachloroethene for the Western lEA
Results of the Indoor Air Risk Assessment
The MCP requires cumulative cancer and non-cancer risks to be calculated for a receptor
for
the full set
of chemicals and exposure routes associated with each complete exposure pathway. A cumulative ELCR
.of I.OE-05 or less indicates a condition of "no significant risk" of harm to human health based
on
the
projected cancer health effect endpoint. A cumulative HI of 1.0 or less indicates a condition of "no
significant risk"
of
harm to human health based
on
projected non-cancer health effect endpoints.
Accordingly, cumulative ELCRs and/or His were calculated for the hypothetical On-Site Resident (Adult and
Child), Commercial/Retail Worker, Adult Day Care Worker, and the Day Care Toddler by summing the
individual risks contributions projected for each LFG constituent detected in each lEA.
Appendix E contains the tabulated J&E vapor intrusion modeling results for each soil gas constituent in
each lEA and the resulting location-, chemical-, and receptor-specific contributions to the cumulative
ELCR and cumulative non-cancer
HI
for each evaluated receptor. Table 7 presents the cumulative ELCRs
and His that were calculated for each lEA and receptor by summing the constituent-specific contributions
to risk. The results are summarized in Table 8.
As indicated in Table 8, there were no potential non-cancer health risks relative to indoor air exposure for
any receptor within any lEA exceeding the MCP-specified cumulative HI
of
I. However, the on-site
Lifetime (Adult and Child) Resident exceeds the MCP cancer risk threshold of I.OE-5 in the Site-Wide and
Western lEAs, but not in the . Eastern lEA. These exceedances are primarily due to exposure to
tetrachloroethene, which was detected at one location in the Western lEA (and hence
is
also a part of he Site
Wide lEA), but was not detected in the Eastern lEA.
The cumulative cancer and non-cancer results indicate that commercial/retail and day care redevelopment
would not be of concern in any of the lEAs given the results of the cumulative inhalation pathway risk
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assessment. In addition, the results of the cumulative inhalation pathway risk assessment indicate that
residential development also would not be
of
concern
in
the Eastern lEA, but may not be suitable for the
Western lEA given the current conditions at the site. It is important to note that there is no residential
development proposed for the Western lEA under the plan depicted in Figure
2.
2.4.2 Outdoor Air Risk Assessment
The sections that follow consider the following aspects
of
the exposure and risk assessment with respect
to the outdoor air at the site: the emission rate of LFG; the spatial distribution of the LFG constituents; the
dilution of the emitted LFG constituents as they mix and disperse in the ambient air, and an estimate of
the concentration
of
the LFG constituents
in
the outdoor air
of
the exposure area.
LFG Emission Rate - LandGEM
The mass flux or volumetric flow of the LFG generated within the material disposed in a landfill is site
specific and varies both spatially and temporally. The amount
of
LFG produced depends on the
characteristics
of
both the waste and the site, including the waste type, age, temperature, moisture,
avenues for gas migration, and the local barometric pressure.
For this analysis, direct measurement (e.g., by using flux box measurements)
of
the amount or flux
of
LFG generated at the site may not yield quantitative results that would be representative of the proposed
development scenario. As was noted, the landfill has been inactive for some time and has a layer
of
soil
over the emplaced waste material and, as such, LFG flow rates and subsurface pressure gradients may
change when the proposed development occurs. In addition, site conditions affecting LFG generation
rates are not the same now as they will be in the future, such as moisture content, compaction and
channels for gas collection and preferential migration.
In light of these factors, LFG generation and emission rates were estimated by Griffin Engineering using
LandGEM (Landfill Gas Emissions Model). LandGEM is a USEPA screening model, routinely used to
quantij'y emissions from the anaerobic decomposition of landfilled waste in municipal solid waste
landfills
.
The model estimates gas generation based on a first-order decomposition rate equation. The
modeling defaults in LandGEM are based on empirical data from a large number of U.S. landfills. A
modeling run was performed using LandGEM Version 3.02 (the most recent version) incorporating both
site-specific data and inputs supplemented with reasonable default values. Due to its relatively small size
and age, the landfill
is
neither subject to the Clean Air Act (CAA) nor the
New
Source Performance
Standards (NSPSs) for municipal solid waste landfills. As such, the modeling performed for this
assessment used the USEPA inventory default values for certain primary ·modeling inputs, in accordance
with LandGEM protocol, as these values were appropriate with respect to the characteristics
of
this
landfill. For these reasons, the LandGEM output is expected to provide a conservative estimate (i.e.,
reflecting greater LFG emissions than may actually occur) of the LFG generation rate for use in this risk
assessment.
The following site-specific inputs were applied in the LandGEM modeling performed by Griffin
Engineering.
• Year Landfill Started Accepting Waste
• Year Landfill Stopped Accepting Waste
• Current quantity of Waste-In-Place (as of 1962)
• Annual Waste Acceptance Quantities 1948-1961
• Cumulative Waste-In-Place
2-10
1948
1961
155,909 Mg
(see Results in Appendix C)
12,250 short tons/year or 11,136 Mg/year
155,909 Mg 2008
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In addition, the following set of default inputs were applied in the modeling in consideration to the overall
characteristics of the Former Brimbal Avenue Landfill:
• Methane Generation Rate Parameter (k)
• Potential Methane Generation Capacity (L
0
)
• Non-Methane Organic Compound (NMOC) Concentration
• Methane Content
0.040 year·
1
100 m
3
/Mg
600 ppm (as hexane)
50% by volume
Chemical-specific properties were used for the default gas/pollutant in the model. The projected pollutant
concentrations in the LFG estimated by LandGEM were developed using USEPA's AP-42 emission
factor specifications and were corrected for air infiltration. The summary input, output, and all results of
the LandGEM modeling run are presented in Appendix C. The results estimated Total LFG, Methane,
NMOC, and H
2
S quantities. The primary results that are most applicable
to
this risk assessment are
summarized in Table 9. The LFG generation rate for 2008 was used for this risk assessment. This was a
conservative selection as the generation rates are projected to continue to decrease over time.
Representative Exposure Point Concentration for Chronic Outdoor Air Exposure
The emissions from the LFG are expected to be released into and through the soil gas and potentially on
and into the ambient air above the site. Once in the ambient air, the constituents will experience some
degree of dilution as they mix with the outdoor air and disperse due to wind and other forces.
A conservative estimate
of
this degree
of
mixing and dispersion may be obtained by applying a "box
model" approach to the evaluation of the LFG emissions. The box model approach considers the LFG
emissions being released into and mixing within a box-shaped volume of air, which is also ventilated by
wind carrying generally cleaner air into the box. The height
of
the box
is
estimated to be the minimum
height
of
the layer
of
air that would be naturally mixed. This mixing
is
generally caused by the wind
interacting with the roughness of the surface of he ground and protrusions that extend up from the ground
into the air. In this case, these protrusions include the new structures, vegetation, and the receptors. As
such, this height was based on the shorter
of
these protrusions and was conservatively taken to be the
breathing zone height
ofthe
site users.
Application of a box model to a slightly contoured surface adds some uncertainty to the conceptual
analysis of air mixing and dispersion relative to the case
of
a hypothetical flat "box." However, a number
of considerations and factors supported the justification to use the box model approach for this
assessment.
• Winds blowing over a grassy landscaped area or parking are (i.e., the approximate conditions
of
the flat portions of the site following development) tend to be in a laminar flow regime near the
surface
of
the ground. This flow regime is characterized by air flow lines that run approximately
parallel to the surface
of
the ground. When the undulations or changes in elevation of the ground
are not large in a relative sense, the flow lines rise or dip in response to the change in topography
while maintaining the laminar flow regime. When the topographic changes are more abrupt, a
deviation from the laminar flow regime can occur (i.e., separation) and vertical or turbulent
eddies of air flow can result. Separation would be expected to occur somewhat more readily for a
given change in topography when the elevation is falling off. In this situation, the momentum of
the air tends to make the streamline continue
on
a path that takes it farther fron{ the surface of the
ground. This spreading
of
the flow lines results in a widening mixing zone or "box" on the
downhill side
of
a hump. This occurrence would result in a "box" that was shorter at its inlet (or
upwind side) and taller at its outlet (or downwind side). If the separation gets even greater,
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turbulent eddy flow can result. Conversely, if the wind is blowing up a slight grade, the "box"
could be shorter
on
the downwind side. A flat
"box"
approach typically provides a conservative
estimate
of
the near-ground air concentrations for sites that are not steeply sloped and relatively
flat. The layout of the proposed development reflect a fairly flat topography which slants slightly
to the south with relatively continuous contours.
• As one assumption
of
the
box
model is that the air is well mixed within the
box
(by small scale
eddies near the ground or turbulent flow around solid features in the box (e.g., vehicles, buildings
and trees), some vertical mixing due to separation at topographic changes would make this
complete mixing assumption more representative
of
actual conditions.
In consideration of these factors, application of a flat-bottomed "box" with a conservatively specified
constant height was expected to provide a suitable estimate
of
the ambient air concentration near the
ground at the site.
Weather Underground publishes detailed information on historical wind speed and direction for
established weather stations on its website (www.weatherunderground.com). The nearest weather station
listed on this website to the Town of Beverly is the Beverly Cove Station. Table I 0 presents a summary
of
the annual wind speed and direction data reported for
the
period 2000 through 2007. Data pre-dating
2000 were not available. Table 10 indicates that wind over a long-term average blow across the site from
the southeast toward the northwest. The average annual wind speed was calculated to be 0.54 m/s (see
Table I 0). These wind speeds were used as inputs for the
lEA box
modeling (see below).
The following three factors are most significant with regard to impacting the estimated concentrations of
the LFG constituents in the air within the
box
(and, accordingly,
at
the location
of
potential inhalation
exposures):
I.
The dimensions of the box.
2. LFG emissions into the box via the soil gas.
3. The dilution of the air in the box by the wind bringing generally cleaner air into the box.
These factors can be related to the concentration of any particular LFG constituent mathematically using
the principal of conservation of mass. For this assessment, a steady-state evaluation that assumed that
there is no further build-up
of
LFG constituent concentrations in the air within the box over time was
appropriate, as this assumption provides an estimate of the highest concentration that would be generated
at the point of exposure. Assuming steady-state conditions, the influx of a LFG constituent must equal the
outflow of that LFG constituent from the box. Mathematically, this development is written
in
terms of a
"box" located in the proposed development area and coinciding with the footprint of one of the lEAs, as
defined in Figure 4 and described below.
Influx Contributions (from the south and east given the annual average wind is out of the southeast)
LFG Constituent Influx with the Wind from the South (INws):
Where:
INwsi
Vs
WIEA
Influx ofLFG constituent
"i"
in the wind blowing from the south [ug/s];
Average speed
of
the wind blowing from
the
south [m/s];
Width
of the lEA
perpendicular to the flow
of
wind from
the
south [m];
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MHIEA
CINWSi
Mixing Height of
the
air within
the
lEA [m];
and
Concentration ofLFG constituent "i" in the wind blowing from
the
south [ug/m
3
] .
LFG Constituent Influx with the Wind from the East (INWE):
Where:
INWEi
VE
LIEA
MHIEA
CINWEi
Influx ofLFG constituent
"i"
in the wind blowing from the east [ug/s];
Average speed of
the
wind blowing from
the
east [m/s];
Length
of the lEA
perpendicular to the flow
of
wind from the east [m];
Mixing
Height
of
the
air within
the
lEA [m];
and
Concentration of LFG constituent "i" in
the
wind blowing from
the
east [ ug/m
3
] .
LFG Constituent Influx from the LFG influx from
the
subsurface
of
the
lEA ( Nv):
Where:
IN
vi
Q
CINVi
Influx
of
LFG constituent
"i"
from
the
LFG influx from the subsurface
of
the
lEA
[ ug/s];
Flux ofLFG released per
unit
area within the
lEA
[m
3
/m
2
-s];
Concentration
of
LFG constituent
"i"
in the LFG emissions being released into the
lEA
[ug/m
3
] ;
Length of the lEA [m];
and
Width of
the
lEA
[m].
Outflow Contributions (to
the
north
and
west given the observed annual average wind direction
LFG Constituent Outflow
with the Wind
to
the
North (OUTWN):
Where:
OUTWNi
VN
WIEA
MHIEA
CBOXi
Outflow
ofLFG constituent "i" in
the
wind blowing to
the
north [ug/s];
Average speed of the wind blowing
to
the north [m/s];
Width
of
the
lEA
perpendicular to the flow
of
wind to the north [m];
Mixing Height of the air within the lEA [m]; and
Concentration
of
LFG constituent
"i"
in the box representing the
lEA
[ ug/m
3
] .
LFG Constituent Outflow with the Wind
to the
West (OUTww):
Where:
OUTwwi
Vw
=
LIEA
MHIEA
Csoxi
Outflow
ofLFG
constituent
"i"
in the wind blowing to the west [ug/s];
Average speed
of
the
wind blowing to the
west
[m/s];
Length of
the
lEA perpendicular to the flow of wind to the
west
[m];
Mixing
Height
of
the
air within
the
lEA [ m];
and
Concentration of LFG constituent "i" in the box representing
the
lEA [ ug/m
3
] .
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Setting the sum of the inflow terms to the sum of the outflow terms yields the following expression:
Solving this expression for CBox;, the concentration of LFG constituent "i" in the box representing the
lEA, results in the following relationship:
[v, X W EA X C lNWSi
l
r ] [ Q X C lNVi X L EA
+ t .VE
X LIHA X
c NWEi +
MH lEA
CBOXi
The concentration of the air in the box is indicated to be affected by contributions of the LFG constituents
from the soil gas below the site and potentially by the influx
of
LFG constituents into the box from
upwind areas. Initial applications of the box model indicated that given the size of the lEA, the speed of
the wind, and the relatively low projected LFG emission rate, both sources of constituent contributions
could be important.
As presented previously in Table 9, the LandGEM model estimated a Total LFG quantity of6.29 m
3
/m
2
-
year (or 2.0 E-07 m
3
/m
2
-s) for the year 2008.
As
noted earlier, this value was used for this conservative
assessment as the generation rate in
any future year
is
projected to be lower and, accordingly, associated
with less potential inhalation risk. This value
is
the input parameter
"Q"
in the box model relationships. It
was assumed that the LFG emission rate or flux (Q) was the same across all locations on the landfill.
The three lEAs were assessed separately and in a certain sequence due to differences in the soil gas
concentrations, model inputs (such as the length and width
of
the box), and the potential contributions
of
LFG constituents from upwind areas. The Eastern lEA was evaluated first, as the outputs from that
analysis (CBoXIEAi) were then used as an input to the analysis performed for the Western lEA (i.e., the
concentration of LFG constituent "i" in the wind blowing out of the box of the Eastern lEA was assumed
to blow into the box of the Western lEA). The three analyses are presented in the sequence in which they
were performed.
The Box Model for the Eastern Inhalation Exposure Area
This "box" includes the southeastern portion of the site. As shown in Figure 4, this box has an
approximate length (the dimension in the southeast to northwest wind direction) of 565 feet (or 172.2 m)
and an approximate width (the dimension in the southwest to northeast direction) of325 feet (or 99.1 m).
The maximum mixing layer height was conservatively assumed to be 6 feet (1.83
m)
to represent the
height of the breathing zone of the on-site receptors. As the actual mixing zone would be expected to be
taller· (due to the influences of the taller buildings and trees associated with the development protruding
higher above the ground and increasing the turbulence and circulation), this assumption should not lead to
an underestimate of risk. The Eastern lEA box model dimensions were:
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EASTERN
lEA
LIEA =
172.2
·m
Since this box extends to the southeastern boundary
of
the site (i.e., the upwind side),
no
contribution
of
LFG constituents was assumed to come with the wind inflow from the upwind directions.
Mathematically, this translates into the following:
c Nws; = c NWEi = o
Calculating the concentration
of
the LFG constituents
in
the lEA was then accomplished using the
following simplified relationship:
Csox; = ((Q X
CrNV;
X w,EA X Luu;)
+
MH Jid_
(VNx
W1EA)
+ (Vwx L1EA)
The calculated LFG constituent concentrations within the lEA
(CBoxi)
are presented in Table
II
for the
Eastern lEA. CBoxi was then used as the estimate
of
CJNWsi and
CINWEi
for the Western lEA analysis, since
the Western lEA is located conceptually downwind
of
the Eastern lEA and would, therefore,
be
influenced by the LFG concentrations coming out of the box for the Eastern lEA.
The Box Model for the Western Inhalation Exposure Area
This box includes the northwestern portion
of
the site. As shown
in
Figure
4,
the Western lEA has
an
approximate length (in the southeast to northwest wind direction) of 325 feet (99.1
m)
and an
approximate width (in the southwest to northeast direction)
of 235
feet (71.6
m).
The maximum mixing
layer height was again conservatively assumed to be 6 feet (1.8 m) to represent the height
of
the breathing
zone of the on-site receptors. As discussed above, the actual mixing height is likely to
be
greater than 6
feet, which would cause the resulting outdoor air concentration to be lower that what was projected for
this assessment. The Western lEA box model dimensions were:
WESTERN
lEA
WIEA =
71.6 m
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Results of the Outdoor Air Risk Assessment
The MCP requires cumulative cancer and non-cancer risks to be calculated due to multiple chemicals and
exposure routes. A cumulative HI and ELCR were calculated for each EA. The development of he results
is
shown in Table 14, and the results are summarized in Table 15. No risk estimates for exposure to the outdoor
air exceeded the MassDEP cumulative risk thresholds.
2.4.3 Quantitative Cumulative Inhalation Pathway Risk Assessment
This section summarizes the quantitative aggregation of the indoor and outdoor risk results for each
receptor that was quantitatively evaluated in this assessment (a qualitative assessment of the potential
inhalation risks to Off-Site Residents and potential future CommerciaVRetail Customers
is
discussed in
Section 2.4.4 below). Each receptor associated with the potential site development (with the exception of
the Construction Worker, the Utility Worker, and the Trespasser who are assumed to spend all of their
time outdoors) was assumed to spend some portion of their time at the site exposed to both indoor air and
the outdoor air. Therefore, the total exposure for each receptor was quantified by:
• calculating the fraction of time that each receptor spends indoors and multiplying that fraction by
the projected ELCR and/or HI calculated for that receptor for each lEA in the indoor air risk
assessment (which implicitly assumes a full day of inhalation exposure according to that specific
exposure scenario);
• calculating the fraction of time that each receptor spends outdoors and multiplying that fraction
by the projected ELCR and/or
HI
calculated for that receptor for each lEA in the outdoor air risk
assessment; and
• summing the two components of the inhalation risk to develop a combined cumulative ELCR
and/or
HI
for each receptor for each EA.
The ELCRs for the Adult and Child On-Site Residents were combined to estimate an ELCR for potential
Lifetime exposure. These steps were completed for each receptor for which a quantitative evaluation was
to performed, and the results are presented
in
Table
16.
A cumulative ELCR of l.OE-05
or
less indicates that a condition of "no significant risk" of harm to
human health exists based on the projected level of cancer health effects. The combined cumulative
ELCRs for all but the Lifetime On-Site Resident were below this threshold. The combined cumulative
ELCR for the Lifetime On-Site Resident exceeded this threshold in the Site-Wide lEA (ELCR of 1.26E-
05) and the Western lEA (ELCR of 2.77E-05). These ELCRs were driven by the LFG constituent
tetrachloroethene, which was not detected
in
the samples collected in the Eastern EA.
It
should be
recalled that the Site-Wide lEA includes both the Western and Eastern lEAs. The risk associated with the
Site-Wide lEA
is
primarily associated with the projected exposure to LFG in the Western IgA, since the
combined cumulative ELCR for the Eastern lEA (ELCR of 5.50E-07)
is
well below the risk threshold of
l.OE-05.
A cumulative
HI
of 1.0 or less indicates that a condition of "no significant risk" of harm to human health
exists based on the projected level non-cancer health effects. The highest HI calculated for this assessment
(1.26E-02 for the Child On-Site Resident in the Site-Wide lEA) is almost two orders of magnitude lower
than the threshold value. Therefore, it can be concluded that there
is
"no significant risk" to any of the
assessed receptors with respect to non-cancer health effect endpoints relative to proposed development.
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2.4.4 Qualitative Cumulative Inhalation Pathway Assessments for the Off-Site Residents
and the Commercial/ Retail Customers
Supplementing the quantitative assessment discussed above, qualitative assessments of the human health
risks attributable to inhalation exposure to hypothetical Off-Site Adult and Child Residents and a
potential Commercial/Retail Customer also were performed.
On July 15, 2008, methane was detected at sampling location GP-20 at a concentration of 17.4% of the
Lower Explosive Limit (LEL) (Griffin Engineering 2008). This location was approximately 30 feet from
a residential structure on the northern edge of the Northridge Homes Cooperative property (located
adjacent to the southwestern corner of the site). This 2.5 story structure is Building K of that complex.
A crushed stone trench exists along the property line between GP-20 and Building
K.
It is believed that
the trench may have been installed
in
the past for gas venting purposes. On July 22, 2008 (at the request
of
the MassDEP Solid Waste Section), Griffin Engineering conducted additional methane sampling
within and around Building
K.
Soil gas samples were collected on both sides of the crushed stone trench
to determine if it was acting as an effective barrier to gas migration toward the off-site residential
complex. Thirteen soil gas samples were collected
in
the vicinity
of
the crushed stone trench. Eight
of
the
samples were collected on the Northridge Homes Cooperative side ofthe trench and five were collected
on the side toward the site and the former landfill. Field screening of the soil gas detected methane in the
subsurface at concentrations exceeding 25%
of
the LEL at two locations on the landfill side
of
the trench.
Methane was detected at a maximum concentration of only 0.2% of the LEL on the residential side of the
trench. These results indicate that the crushed stone trench was effectively venting the LFG to the ambient
air at this time. Additional sampling in the basement laundry room
of
Building K revealed
no
methane.
Utility penetrations into Building K also were examined by Griffin Engineering. Natural gas, electricity
and telephone services were all found to be installed on the outside of the building foundation wall and to
penetrate the building wall above grade. As such, these services cannot provide a preferential pathway for
potential LFG migration into the building. The water and sewer services for Building K enter the building
through the lowest slab level. Air quality testing near the sewer cleanout, the water main shut-offvalve, in
the hallway in the lowest level of the building, and in the laundry room of Building K provided no
evidence of LFG intrusion into Building
K.
Based on these observations, there was no evidence that LFG
is migrating into Building K.
While the sampling on either side
of
the crushed stone trench,
in
the basement
of
Building K, and near the
utility penetrations of the walls of Building K did not quantifY the levels of specific toxic VOCs (i.e., the
samples were field screened and only analyzed for methane), the lack
of
methane at any significant level
on the residential side
of
the trench and no indication
of
methane
in
Building K (the residence closest to
the former landfill) supports the position that other toxic LFG constituents also are not migrating to and
into this building. As such, a condition
of
"no significant risk"
is
indicated to exist relative to the potential
inhalation
of
LFG constituents in indoor air by an Off-Site Resident. As the projected outdoor air
inhalation risks for the On-Site Resident were well below the MassDEP threshold levels, the outdoor air
inhalation risks at an off-site residence (like Building
K)
should be even less. While the Off-Site Resident
would have the same exposure parameters as the On-Site Resident, the outdoor air concentrations
of
the
LFG constituents should be less than are projected for the on-site locations due to the fact that the existing
off-site residential locations are generally upwind of the site or farther from the landfill source material
(which allows for greater mixing and dispersion of the LFG emissions). Taken together, the inhalation
risks to the Off-Site Resident resulting from indoor and outdoor exposures are indicated to be very small
and pose "no significant risk" to the Off-Site Residents (adult or child).
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Because the human health risks relative to both cancer and non-cancer health effects were found to not be
significant for the Commercial/Retail Worker, it can be inferred that LFG constituents at the site would
also not pose a significant risk to the Commercial/Retail Customer (who will spend less time on-site, both
indoors and outdoors, than the Commercial/Retail Worker).
2.4.5 Qualitative Odor Threshold Evaluation for Hydrogen Sulfide (H
2
S)
H
2
S is a colorless, flammable gas that is easily identified by a "rotten egg" odor. H
2
S can cause eye, nose
and throat irritation at concentrations less than I 0 ppm, with higher concentrations causing significant
health issues and even death. Olfactory fatigue (which is when a person looses the ability to smell a
particular compound) occurs at high concentrations and/or with continuous exposure to lower
concentrations of H
2
S in air. This can lead individuals to believe that there is no danger present, even as
concentrations increase to potentially more toxic levels. Table
17
summarizes the soil gas H
2
S data
collected at the site and the odor thresholds and occupational health limits for airborne H
2
S
from several
pertinent sources.
H
2
S was detected at GP-6
in
December, 2007 and at GP-6R
in
August, 2008. There were also detections
at two locations on the landfill side of a gravel trench along the western boundary of the site during the
same sampling event near Building
K
discussed above, although was
no
H
2
S
detected inside Building
K.
The detected concentrations were above all three odor thresholds listed
in
Table 17, but below the lowest
occupational health limit
of
I0 ppm. These detections confirm the presence
of
H
2
S in the Western lEA at
levels that should be easily smelled by the average person. No sampling for H
2
S was performed
in
the
Eastern lEA. As such, it cannot be determined whether H
2
S may pose an odor problem or a potential
health concern in that part
of
the site. It has been shown that H
2
S may have detrimental health effects on
children at levels as low as 0.6 ppm (Simonton and Spears 2007).
2.5 Uncertainty Analysis
Risk assessments are subject to a number
of
uncertainties which necessitate the making
of
assumptions
for quantitative analysis. For risk assessments, these assumptions are typically based on "best estimate"
values
of
the uncertain parameters or, more typically, on conservative assumptions selected specifically
so
that the estimated exposures or risks will not be underestimated. The following discussion examines
the primary uncertainties associated with this risk assessment and their implications relative to this risk
assessment.
2.5.1 LFG
Composition
The composition of the LFG that may be emitted in the future was estimated based on a set of
measurements
of
the soil gas at seven locations throughout the site. As noted previously, the analytical
results from a couple
of
samples had to be discounted and not used
in
the risk assessment (e.g., due to
natural gas infiltration from a pipeline leak and destruction of the sampling port). Consequently, the LFG
composition was based on a relatively small number
of
measurements.
An
analysis
of
this data was
performed and
it
was seen that the soil gas appeared to
be
characteristically different
in
the eastern and
western portions of the site with respect to the set
of
constituents that was detected and their
concentrations. This finding supported the decision to establish separate exposure areas for the risk
assessment. However, splitting the relatively small data set left each
of
the two lEAs with only three or
four samples on which to base the LFG constituent compositions. While the calculated average LFG
constituent concentrations for each lEA are considered to be representative for use
in
this risk assessment,
some uncertainty associated with this characterization exists. For example, tetrachloroethene (the risk
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driver for the indoor air risk assessments for the Western lEA) was only detected at one
of
three locations
in the Western lEA and was not detected at all
in
the Eastern lEA.
No soil gas samples from the Eastern lEA were analyzed for H
2
S.
Based on the sampling performed
in
the Western lEA, possible odor concerns might
be
anticipated for the entire site if no mitigation steps are
taken.
2.5.2 LFG Generation and Emission Rate
The LFG generation and assumed emission rates were estimated by Griffin Engineering using the
industry standard LandGEM model that was developed by USEPA. This model was selected for use due
to its demonstrated applicability to municipal landfills of the size and age of the Former Brimbal Avenue
Landfill. The default modeling inputs
in
LandGEM were based on empirical data from a large number
of
similar U.S. landfills. While there is variability
in
the exact nature
of
municipal wastes and the amount
of
LFG they can generate, the LandGEM model is reported to provide an accurate prediction of the LFG
generation. Site-specific waste-in-place histories were used
in
the modeling, and other input parameters
were tailored to site-specific values whenever the site documentation allowed. LandGEM
is
expected to
provide a conservative estimate
of
the LFG generation and emission rate (i.e., reflecting greater LFG
emissions than may actually occur). The LandGEM predictions
of
LFG generation were seen to be
decreasing with time due to the fact that waste placement ended some time ago. As a conservative
measure, the current LFG emission rate (i.e., the highest value projected with respect to the future
composting scenario) was used in the risk assessment. Over the next 20 years the LFG generation rate is
projected to drop by approximately 55% (see Table 9) which would result
in
a commensurate drop
in
the
projected exposure point concentrations and inhalation risks.
2.5.3 Atmospheric Mixing and Dispersion Modeling Using a Box Model
The mixing and wind-borne dispersion of LFG emissions in the outdoor air at a future developed site will
be influenced by a number
of
site-specific aspects
of
the proposed development, the local meteorology,
and the type and exact location of the activities associated with the development. Many of these factors
have not been specified at this time. As such, a detailed modeling
of
the potential mixing and dispersion
of
released LFG constituents at the landfill could not be supported.
For this assessment, a conservative steady-state evaluation was conducted which assumed
no
build-up
of
LFG constituent concentrations in the air within the box over time (i.e., established the maximum
concentration expected within the box). The mixing height parameter limits the amount of air into which
the LFG emissions can mix and dilute by placing a top on the box. The smaller the mixing height, the
more conservative the analysis will be in terms
of
not providing too much dilution volume for the LFG
constituents to mix within. As such, the smallest representative and plausible mixing height
of
6 feet
(1.83 m) was selected for each
of
the lEA box model simulations. This value
is
reflective
of
the minimal
height
of
the potential future intrusions into the box by structures, landscaping, vegetation, and vehicles
that would serve to divert and mix the air flow within the box. This height also is consistent with the
thickness
of
the breathing zone
of
a typical adult. Increasing the height
of
the box to account for the
proposed buildings would increase the dilution
of
the LFG constituents within the air, thus lowering the
exposure point concentrations and the corresponding ELCR and HI projections. A reduction in height
(especially for the Western lEA to account for the presence of children) would decrease the dilution, and
increase the ELCR and HI projections somewhat. The assumed mixing height value
is
reasonably
conservative and appropriate given the uncertainties associated with the nature and details
of
the future
development that have been considered at this time.
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Wind speed inputs into the box model calculations were selected based on long term average
meteorological data from the Weather Underground website. This data was selected because it was
collected at a nearby analogous location and had the required published meteorological information. The
seacoast areas along the north shore
of
Boston experience similar local wind and meteorological patterns.
Observing that the predominant wind directions annually for this area are from the southeast, applications
of the box models were set-up to account for the inflow influence of the "upwind" portions of the site.
This approach assumes the greatest inflow of LFG constituents into the lEA, as winds blowing from the
northwest would pass over little or no emplaced waste and pick up minimal LFG emissions. As such, the
wind data was used to set-up the box models in a conservative fashion such that an underestimate
of
the
resulting risks was very unlikely.
The portions
of
the site that were defined as the Eastern and Western lEAs (and also the Site-Wide lEA)
are not perfectly rectangular, as is assumed in the box modeling. The lengths and widths assumed for the
boxes used
in
the mixing and dispersion analyses for each lEA were selected to maintain an equivalent
overall area for that lEA and
in
consideration
of
the relative amount
of
emplaced waste that was indicated
to
be
beneath the rectangular lEA and the actual lEA boundary. This approximation is not expected to
introduce significant uncertainty into the results
of
the outdoor air risk assessment.
2.5.4 Exposure Frequency and Exposure Duration, and Daily Exposure Time
The ELCR and HI values calculated using the MCP exposure relationship do not explicitly account for a
receptor-specific Exposure Frequency (EF), Exposure Duration (ED), or exposure during only a portion
of
a given day. This exposure relationship implicitly reflects a scenario
of
continuous exposure through
the underlying development
of
the toxicity values and the averaging times associated with the inhalation
exposure relationship. The anticipated exposures
of the identified site receptors under the proposed future
development scenario will not be exposed to the released LFG constituents continuously. For most
of
the
groups that would be expected to access the future site, the exposure scenarios reflect less than
24 hour/day exposure. Alternate formulations of the ELCR and HI relationships allow these exposure
factors to be explicitly considered through the multiplicative reduction factors (i.e., EF /365 for the HI
and
EFxED 125,550
for the ELCR). These exposure-related adjustments for the non-residential receptors
would only serve to reduce the projected risks for the various on-site workers, the Day Care Toddlers, and
the Trespasser.
As
the risks to these receptors were already less than the MassDEP thresholds, the
exposure-related adjustments would only lead to even lower projected risks that would also reflect "no
significant risk."
The fractions
of
time each receptor was assumed to
be
indoors (and exposed to the indoor air) and
outdoors (and exposed to the ambient air) were explicitly accounted for in the combined cumulative risk
projections for each receptor.
2.5.5 Vapor Intrusion Modeling Input Parameters
The assumed building characteristics and soil properties used
in
the J&E Modeling for the indoor air risk
assessment were conservative MassDEP defaults (i.e., the values used to establish the MCP Method I
GW-2 Standards) or characteristics established by site-specific measurement or observation. Site-specific
commerciaVretail and day care building dimensions reflective of the proposed development plan depicted
in Figure
2.
As such, the projected risks are likely to be higher than would actually result from
development
of
the site.
Actual future structures may have larger footprints, taller internal spaces, or thicker slabs and foundations
than were assumed for this assessment. All
of
these differences would lead to lower projected indoor air
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concentrations and lower projected inhalation risks. In addition, many modern commerciaVretail
buildings are designed to maintain a positive pressure differential with respect to tbe outside air.
An
effective positive pressure design would essentially eliminate vapor intrusion concerns.
2.5.6 Exposure Parameters
The assumed exposure parameters used
in
this inhalation risk assessment were either based on site
specific considerations or were the conservative regulatory defaults.
As
such, risks are not likely to have
been underestimated.
2.5.7 Toxicity Criteria
This risk assessment incorporated the currently published MassDEP ShortForm and federal toxicity
values in accordance with the hierarchy of preferred sources established by MassDEP. No published, peer
reviewed chronic inhalation toxicity criteria or chemical parameters were identified for 4-ethyltoluene or
1,2-dichloro-1, 1 2,2-tetrafluoroethane, and no appropriate surrogates were identified. The lack
of
suitable
inhalation toxicity values for these two constituents would lead to a slight underestimation of the
inhalation risk. Given the level of conservatism included in the other toxicity values and throughout the
assessment, tbis underestimation
is
not significant with respect to the results
of
tbe risk assessment.
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3.0 SUMMARY AND FINDINGS
The Town of Beverly is considering a proposal to allow development on a portion of the Former Brimbal
Avenue Landfill in Beverly, MA known as the North Shore Commons Site following the closure of the
former landfill. This human health risk assessment was conducted to evaluate the inhalation risks to
potential future commercial/retail, day care, residential, and other users
of
the site assuming the site
is
developed. The risk assessment focused on potential inhalation exposures to LFG constituents that could
be encountered either inside the proposed new buildings or outside the buildings in the near-field
ambient air.
Analytical data from on-site and off-site sampling performed in 2007 and 2008 were compiled and
evaluated with regard to spatial trends. Based on differences in the detected sets
of
soil gas contaminants,
the overall site was broken down into a Western Inhalation Exposure Area (where a Day Care facility
is
proposed to be built), an Eastern Inhalation Exposure Area (where Commercial/Retail and Residential
facilities are proposed to be built), and a Site-Wide Inhalation Exposure Area (i.e., the whole site). The
soil gas characteristics for each Inhalation Exposure Area were used in
combination with conservative
indoor air vapor intrusion modeling and outdoor air atmospheric mixing and dispersion modeling to
estimate the concentrations
of
the LFG constituents that may be present
in
the air at potential future
exposure points associated with site development. These concentrations were then combined with current
peer-reviewed inhalation toxicity values to project the potential cancer and non-cancer risks for the
persons that may access and use this area in the future (as the site is currently vacant).
The findings
of
the risk assessment were as follows:
• The analyses indicated that there
is
"no significant risk"
of
harm to human health for any
of
the
evaluated receptors
in
any portion of the site with the exception of a potential future resident with
lifelong exposure to the released LFGs in the western portion of the site. The projected ELCR for
this scenario exceeded the MassDEP threshold of 1.0 E-5, due to potential vapor intrusion into
the indoor air
of
a hypothetical new slab-on-grade residence in this area. The LFG constituent
tetrachloroethene was the principal risk driver. No inhalation risk concerns were identified for the
other receptors in the Western Inhalation Exposure Area, or for any of the evaluated receptors in
the Eastern Inhalation Exposure Area. The tetrachloroethene in the western portion
of
the site
also caused the projected cancer risk for a potential future resident with lifelong Site-Wide
exposure to exceed the MassDEP threshold. The tetrachloroethene was only detected in the soil
gas at one location in the Western Inhalation Exposure Area. No inhalation risk issues were
identified relative to exposure to the outdoor air under any
of
the evaluated scenarios.
• Regarding the potential significance
of
H
2
S relative to development, no sampling was performed
for H
2
S
in
the Eastern Inhalation Exposure Area, and only 2
of
3 samples collected in the Western
Inhalation Exposure Area were analyzed for H
2
S. The detection ofH
2
S in the Western Inhalation
Exposure Area (at a maximum concentration
of
4.2 ppm) exceeded a number
of
published odor
thresholds (which ranged between 0.13 ppm and
8.1
ppm). As such, it is likely that people would
be able to smell H
2
S in the Western Inhalation Exposure Area if no mitigative steps are taken. It
could not be determined whether H
2
S may pose an odor problem or a potential health concern in
the eastern part
of
the site since the H
2
S levels
in
the soil gas
in
this area have not been
quantified.
• While the off-site sampling associated with Building K
of
the neighboring residential complex
did not quantifY the levels of specific toxic VOCs, the lack of methane at any significant level on
3-1
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the residential side
of
the off-site interceptor trench and no indication
of
methane in Building K
(the residence closest to the former landfill) supports the position that other toxic LFG
constituents also are not migrating to and into this building. As such, a condition of "no
significant risk" is indicated to exist relative to the potential inhalation of LFG constituents by an
Off-Site Resident.
The uncertainty analysis indicated that there
is
a moderate to high level
of
confidence
in
these findings.
3-2
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4.0 REFERENCES
ATSDR (Agency for Toxic Substances and Disease Registry). 2008. Available online at http://www.
atsdr.cdc.gov/mrls.html
CaiEPA (California EPA). 2008. Office
of
Environmental Health Hazard Assessment. Available online at
http:l/www.oehha.ca.gov/risklchemicalDBI/index.asp.
Griffin Engineering (Griffin Engineering Group, LLC). 2008. Letter from Robert
H.
Griffin,
P.E.
to Mr.
John Carrigan, Solid Waste Section. MassDEP, "Notification
of
Exceedance
of
25% LEL at Property
Line", Brimbal Avenue Property, Beverly, MA. July 23.
MassDEP (Massachusetts Department
of
Environmental Protection). 1996 Guidance for Disposal Site
Risk Characterization. Interim Final Policy #WSC/ORS-95-141, March.
Simonton, Scott and Morgan Spears. 2007. Human Health Effects from Exposure to Low
Level Concentrations
of
Hydrogen Sulfide. Occupational Health and Safety. Available online at
http:l/www.ohsonline.com/articles/50654/.
USEPA (U.S. Environmental Protection Agency). 2004. Johnson and Ettinger Model Spreadsheets for
Estimating Subsurface Vapor Intrusion into Buildings, Version 3.1, February. USEPA Version.
USEP
A.
2008. Integrated Risk Information System. Available online at http:l/cfpub.epa.gov/
ncealiris/index.cfm.
4-1
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FIGURES
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I
)
Fi
Site Lo
North Shore
Beve
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' - 'V I_AUV MJ ·Beverly, MA
~
Figure
2
Proposed Layout for
Site Development
North Shore Commons Site
Beverly,
MA
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TABLES
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Table 1. Summary of Landfill Gas Sampling Results for 2008
>In
I
·Area
Date
GP-20
1RI GP-12
I ~
I GP-
........ " uo"
Western
Inhalation Eastern Inhalation
Detection
Exposure Area Exposure Area
Limit
Gases- ASTM D1946-% (v/v)
Carbon Dioxide 13 3.8 16
11
7.4 9.7 9.6
2.1
.....
...... . - . 2 ___
2.1
....1? ..
12
13
N i " _ ' : ' ~ c "
74 72 77
72 75 70 75
Methane 8.4 7.6 0.027
13 NO 6.0 0.2
Carbon Monoxide
NO
ND
NO NO NO NO
NO
T0-15- ppb (v/v)
Acetone 10
16 .••
19
NO NO
20 27
19
..3.0
.28
.. 1.4
I No
.
__ 7._6_ 3.1
.. .. - - ~ 2
.
.....
··_.4.8
Benzyl C l , . ~ ; . ~ ~ · ·
25
NO NO
NO
NO NO NO NO
Bromodichloromethane
2.0
NO NO NO NO NO NO
NO
Bromoform 2.0 NO NO NO NO
NO NO NO
Bromomethane
4.0
NO NO NO
NO NO
NO NO
2-Butanone (MEK) 10
NO NO NO
NO NO
NO NO
...
q ? ~ h ' : n
i 10
NO NO NO NO
NO NO NO
Carbon Tetrachloride
2.0
NO
.... ~ ~ .
NO
NO NO NO NO
Chlorobenzene 2.0 2.2 : ND
NO NO
NO
NO
. ...... 2Q
.....
N.D
...
N[)
NO NO
NO
NO
.....
.. Nb
\.Alouo ucu oao oc
4.0
NO NO NO
NO NO
Chloroform 2.0 8.1
:, .......
·• 1\11'1
NO NO NO
NO
Chloromethane
. 4.q ..
NO
_ND_
_N[)_.
NO
ND_
........
\10
NO
..
1 2 ~ b i t i r c i m o m e t h a n e (EDB)
2.0
NO NO NO
NO NO NO NO
1 2-Dichlorobenzene
2.0
NO NO NO NO NO NO
NO
1,3-L
2.0
ND NO NO NO
NO
NO NO
1A-Dichlorobenzene
6.0
NO
NO
NO NO NO NO NO
Dichlorodifluoromethane
2.0 4;0•
I ~ L I (
•.
.-.;-21
NO NO NO
ND
1,1·
2.0
NO
ND
NO NO
NO NO NO
1 2-Dichloroethane
2.0
NO NO NO NO
~ ~ i
NO
Nb
cis-1
,2-Dichloroethene
2.0 7.2
. - } _ ~
ND ·,
•·••·
5.1
NO
'
••
< ? .
2.0
NO NO
.NO
NO NO NO NO
1
1-
•ucuoc"c
2.0 NO NO NO NO NO NO
NO
1 2-Dichloropropane
3.0
NO NO NO NO
NO NO NO
cis-1
... P e ~ e
....
3.0
NO NO
.. _ND
__
. ND_
NO NO
u a . .
o
:>-Uivo
2.0
~ ; ~ .. -.
•• • ~ g
...... ~ - - -
NO
ND
NO NO
1 2-Dichloro-1,1 2,2-tetrafluoroethane
2.0
·-··· 21
..
4.6
2.0
7.t_ .
iNo ·.
.. _7;8
6.8.< .
•
',:::6 .·
3;1
4-Ethyltoluene
2.0
1 ~ ~ · · ·
\is>···
'f'ib
. 6.3
2.3
·-··
. NO ·
No
Hexachlorobutadiene
4.0
NO NO
NO NO NO NO
2-Hexanone ' . ' ' '
10 NO
NO NO NO NO NO
NO
Methylene Chloride
2.0
ND NO NO
... Nb
2;5
. .
NO NO
4-Methyi-2-Pentanone (MIBK)
10
NO
~ - ~ , - - , •
1 .• ~
NO NO NO NO
2.0
1_ _
- ~ ' 2
'
, - JP
~ p
.2.7>
. 3 , ~
......
_ 2 , ~
1,1
,2,2-T cuavo uuo ucu oao
'
2.0
NO NO NO NO
NO NO NO
Tetrachloroethene
2.0
NO· .
.••..... ~ ~ - )
: .280··<
NO NO
NO
NO
Tolue111l
...
. ..
. ..... 2
9.
1 . . . . 1.9_·
_
1 1 2 ','
_1_5_
..... ·:
r 21 ___ ·-.
13
1 2,4-To ovo nuo
uuco
"c '
"
5.0
NO NO NO NO
NO
flib
1,1, 1-Trichloroethane
2.0
NO NO NO
NO ND NO NO
1,1
,2-Trichloroethane
2.0
NO
NO NO ND
NO NO
. f\1[)
I
.. .. . . ; iTCE)
2.0
ND
··ND
-0
ND
NO
NO NO
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Table 1. Summary of
Landfill
Gas Sampling Results for 2008
Site-Wide Inhalation Exposure Area
Sample Date
8/4/2008
Sample Location
GP-6R I GP-20 I GP-26 GP-11RI GP-12 I GP-21 GP-
Minimum
Detection
Limit
Western Inhalation
Exposure Area
Eastern Inhalation
Exposure Area
Trichlorofluoromethane 2.0 ND ND ND ND ND ND ND
· - - ~ - • - ~ . , ? : . T E i . ' e ~ < : > r . < : > : ~ . , ? . , ? . : f i f i J . < : > r . < : > ' - ~ ? . ~ . ' - .................. .:_9______ ND ND ND ND ND ....
:J. ?....
.
.ti ?
1,2,4-Trimethylbenzene 3.0
····No-··- ---·-No····
·····Ni5"-- ·-··g-;g·•·-
···s:a····
NO ND
1,3,5-Trimethylbenzene 3.0
ND ND ND ND ND ND ND
· - - ~ l ~ t t ~ ~ ~ ~ - ; ; -
····-······-·-··-··--······-········
·· · · · · · · J ~ · - · · · - · 1 · · - - ~ ~ - - - -
· · · - - ~ - - - ·
· · · · N ~ - : - - - - - ~ 5 · · · · · · - - ~ K - · - · · - - - ~ f - - · - · · · - - - ~ ,
Xvlenes (total) 4.0 I< H .· 12 6,2 · 17 13 <. 9.7 7.6
Sulfides- EPA
15/16- ppm
(v/v)
NS
NS NS NS NS
Hydrogen
sulfide
0.05
4;2
· · ND
... ~ E ~ . < : l ~ Y . I ~ _ U . f 9 . < ; . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ...Q,Q?. ....... _f':I_Q
____
................. ':1.1?. ...........................................
···-··-·
Methyl mercaptan 0.05 ND ND
Ethyl mercaptan 0.05 ND
ND
___ i ' I . ~ . ~ Y . I
~ J . I f i _ c j _ t ; _ . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
.. . ..
_9
•.Q?.
..........
:J. ?.... ·--·-·-··-··- .... ':l.i?.
.... ······-···-· ......................... ·······-·
Carbon disulfide 0.025 ND
ND
Dimethyl disulfide 0.025 ND ND
Notes:
Bold indicates a
detection
NO Not Detected
NS Not Sampled
ppm parts per
million
ppb parts per billion
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Table 3. Conceptual Site Model for the Potential Inhalation Exposures Associated with Development at th
Receptor Age Exposure Medium Exposure Route
Commercial/ Retail
Worker
Adult Indoor Air Inhalation
18-45 years Outdoor Air
Inhalation
Day Care
Worker
Adult Indoor Air Inhalation
18-45 years Outdoor Air Inhalation
Day Care Toddler
Child
Indoor Air
Inhalation
1-5 years
Outdoor Air Inhalation
Maintenance
Worker Adult Indoor Air Inhalation
18-45 years Outdoor Air
Inhalation
Landscape Worker Adult Indoor Air Inhalation
18-45 years Outdoor Air Inhalation
Construction Worker Adult
Outdoor Air
Inhalation
22 years
Utility
Worker
Adult
Outdoor Air Inhalation
22 years
On-Site Resident Adult Indoor Air Inhalation
_ 1 8 ~ 4 5 _ y e a r s
Outdoor Air Inhalation
-----------------
-- - - - - -------------------
--
-- - - - - - - - - - - - - --
Child
Indoor Air
Inhalation
1-8 years
Outdoor Air Inhalation
Off-Site Resident Adult Indoor Air Inhalation
18-45
y e ~ ~ s _
_
Outdoor Air Inhalation
- - - - - - - - - - - - - - - - -
-----
-- -
. ---·---·--·--------- ------ - - - -
Child
Indoor Air
Inhalation
1-8 years Outdoor Air Inhalation
Commercial/ Retail Customer
Adult
Indoor Air
Inhalation
_ 1 _ ~ - : i 5 _ } ' E ' C i r 1 J
Outdoor Air Inhalation
. -
---
--
-- -
-----
-- -- - ---------
----------
Child
Indoor Air
Inhalation
1-8 vears
Outdoor Air
Inhalation
Trespasser
Adolescent Outdoor Air Inhalation
8-15 years
Notes.
Quantitative analysis means
that
cancer and non-cancer risk levels were projected for this receptor.
Qualitative analysis means that. the risk to this
receptor
was evaluated in comparison to the risks of
another
receptor for which
quantitatively assessed that
was similarly exposed to higher levels of contamination for a longer
frequency
or duration of expos
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Table
4. Inhalation
Toxicity Values
for
the
Detected Landfill Gas Constituents Associated with
Cancer and No
CAS
Inhalation
Detected LFG Constituent
Number
Unit Risk
(f g/mar'
Acetone 67-64-1 NA
Benzene 71-43-2 7.8E-06
Chlorobenzene 108-90-7 NA
Chloroform 67-66-3 2.3E-05
Dichlorodifluoromethane 75-71-8 NTV
cis-1 ,2-Dichloroethene 156-59-2
NA
1 2-Dichloro-1, 1 2,2-tetrafluoroethane
76-14-2 NTV
Ethyl benzene 100-41-4 NA
4-Ethyltoluene 622-96-8
NTV
Methylene Chloride 75-09-2
4.7E-07
Styrene
100-42-5 5.7E-07
Tetrachloroethene (PCE) 127-18-4 5.5E-05
Toluene 108-88-3
INAD
Trichloroethene (TCE)
79-01-6 1.7E-06
1 2,4-Trimethylbenzene 95-63-6
NA
Vinyl chloride 75-01-4
8.8E-06
Xylenes (total)
1330-20-7
INAD
Hydrogen Sulfide
7783-06-4 INAD
NOTES.
ATSDR
IRIS
Agency for Toxic Substances and Disease Registry (minimal risk levels).
U.S.
EPA
Integrated Risk Information System. Accessed August 22, 2008.
http://cfpub.epa.gov/ncea/iris/index.cfm
Reference.
SOURCE Concentration
(mg/m•)
IRIS 8.00E-01
MassDEP 3.00E-02
IRIS 2.00E-02
MassDEP 6.60E-01
NTV 2.00E-01
IRIS 3.50E-02
NTV NTV
IRIS 1.00E+OO
NTV NTV
IRIS 1.06E+OO
MassDEP 1.00E+OO
MassDEP 4.60E+OO
IRIS
5.00E+OO
MassDEP 1.80E-01
IRIS
6.00E-03
MassDEP 1.00E-01
IRIS
1.00E-01
IRIS 2.00E-03
MassDEP
MassDEP
Shortfonms for Human Health Risk
Assessment
Under the MCP. Updated February 2007.
http://www.mass.gov/dep/service/compliance/riskasmt.htm
INAD
NA
NTV
ORNL
PPRTV
Per the U.S. EPA, data are inadequate for an assessment of human carcinogenic potential.
This compound is not considered a carcinogen by the U.S
EPA
No
Inhalation RfC and/or
IUR
available.
Oak Ridge National Laboratory National Regional Database of Preliminary Remediation Goals.
http://epa-prgs.ornl.gov/chemicals/index.shtml
USEPA
Provisional Peer Reviewed Toxicity Value. February 28, 2008.
SOURC
MassD
MassD
MassD
MassD
ORNL
MassD
NTV
MassD
NTV
ATSD
MassD
MassD
MassD
MassD
PPRT
MassD
MassD
IRIS
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Table 5.
Site-Specific Subsurface Soil and Site Parameters that Were Used to
Project Vapor Diffusion and Intrusion Into Indoor Air for the Cumulative
Inhalation Pathway Risk Calculations
(Same for All Scenarios)
Input Parameter
Default Value
Depth Below Grade to Bottom of Enclosed Space Floor
111
15
em (5.9 inches)
Soil Gas Depth Below Grade
1
'1
133.5 em (52.6 inches)
Average Soil Temperature
131
JO"C
Thickness of Soil Stratum A
1
'1
133.5 em (52.6 inches)
Stratum A SCS Soil Type 1'
1
S (Sand)
Stratum A Soil Dry Bulk Density 1
3
1
1.5
g/cm
3
Stratum A Soil Total Porosity 1
3
1
0.43 (unitless)
Stratum A Soil Water-Filled Porosity 1
3
1
0.06 cm
3
I cm
3
Soil Stratum for Estimating Soil Vapor Permeabilityl'l
Stratum A
Enclosed Space Floor Thickness
111
15 em (5.9 inches)
Soil-Building Pressure Differential [J]
40 g/cm,s
Enclosed Space Floor Height
13
1
244 em (96.1 inches)
Floor-Wall Seam Crack Width
[JJ
0.1 em (0.039 inches)
Average Vapor Flow Rate into Building
131
5 Llmin
NOTES:
[I] Consistent with a future slab-on-grade structure.
[2] Consistent with the depth
of
the soil gas samples collected at the site.
[3] Soil parameter values used
in
the vapor intrusion modeling for the MassDEP MCP
GW-2 Method I Standards.
[4] Site-specific assumption.
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Table
6.
Scenario-Specific Building Dimensions and Receptor Exposure Parameters
Used in the
Cumulative Inhalation Pathway Risk Calculations
Receptor
Input Parameter
Adult Child Commercial Day Care
Day Care
Resident Resident
I
Retail Worker
Toddler
Enclosed Space
961
em
961 em
2724.9 em
3773.4 em 3773.4 em
Floor Length (32 ft) (32 ft) (89 ft) (124ft)
(124ft)
Enclosed Space
961
em 961 em 1886.7 em 2305.1 em 2305.1 em
Floor Width
(32 ft)
(32 ft) (62 ft) (76ft) (76 ft)
Averaging Time
70 yrs
70 yrs
70yrs
70 yrs 70 yrs
(Cancer)
Averaging Time 30yrs
7 yrs
25 yrs 25 yrs
4 yrs
(Non-Cancer)
Indoor Air Exchange 0.45 I hr 0.45 I hr 1.0 I hr 0.45 I
hr
0.45 I hr
Rate
Exposure Duration 30 yrs
7 yrs
25
yrs
25 yrs
4yrs
Exposure Frequency 365 dayslyr 365 dayslyr
250 dayslyr
250 dayslyr 250 dayslyr
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Table
7.
Summary of the Results of the Indoor Air Risk Assessment for the North Shore Commons Site
Site-Wide Inhalation Exposure Area Eastern Inhalat ion Exposure Area W
Projected Projected Cumulative Projected Projected
Cumulative Non-Cancer Hazard Cumulative Cumulative Non- C
Receptors
Excess Lifetime Index Excess Lifet ime Cancer Hazard Ex
Cancer Risk Cancer Risk
Index
C
Commercial/ Retail Worker 8.66E-07 1.29E-03 3.52E-08 1.21E-03
Adult
Day
Care Worker 1.19E-06 1.79E-03 4.82E-08 1.68E-03
Day
Care Toddler
1.91 E-07
1.79E-03
7.70E-09
1.68E-03
On-Site Resident- Adult
1.51E-05
1.50E-02
6.57E-07
1.40E-02
On-Site Resident - Child 1.50E-02 1.40E-02
On-Site Resident - Lifetime
1.74E-05
3.49E-02 7.48E-07 3.26E-02
Notes.
Bold
indicates an exceedance of the MassDEP excess lifetime cancer risk threshold of 1.0 E-05.
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Table 8.
Summary
of
the Results
of
the
Indoor Air
Risk Assessment for the Receptors Associated with Future
Development
No.
of
Risk lEA Where Risk Receptor
for
Whom
Calculated
Health Effect Type
Threshold Thresholds Were Risk Thresholds Cumulative
Exceedances Exceeded Were Exceeded
Risk
{#)
Cancer 2 Site-Wide On-Site Lifetime
1.51 E-05
Resident
Western On-Site Lifetime 3.31 E-05
Resident
Non-Cancer
0 None None
None
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Table 9.
Summary
of
the LandGEM Modeling Results for LFG and Hydrogen Sulfide
Generation Rates over Time for the Former Brimbal Avenue Landfill
Year Total LFG Generation Hydrogen Sulfide Generation
(m /year)
(m' m"-
year)
1
(m /year)
(m'/m -yearf
1
2008 152,000 6.29 0.1368 5.66E-06
2018 101,900 4.22 0.09169 3.80E-06
2028
68,290
2.83
0.06146 2.54E-06
2038
45,780.
1.90 0.0412 1.71E-06
2048
30,680
1.27
0.02762 1.14E-06
2058 20,570
0.85
0.01851 7.66E-07
2068 13,790 0.57
0.01241
5.14E-07
2078 9,242 0.38 0.008318 3.44E-07
NOTE:
[I]
The value
of
cubic meters
ofthe
Total LFG
or
Hydrogen Sulfide generated per
square meter
of
emplaced waste is based on a waste footprint of24,156 square meters
or 6 acres (i.e., the estimated footprint
of
the emplaced waste at the site).
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Table 10. Average
Annual Wind
Speed and
Direction
Data
for the
Beverly Cove
Meteorological
Station, Bever
Monitoring
Year
2000 2001 2002 2003 2004 2005 2006 2007 8
Year
Averag
(mph) (mph)
(mph) (mph) (mph)
(mp.h) (mph) (mph)
(mph)
~ ~ n n u a l
Average Wind
Speed
2.0
1.9
0.5
1.4
1.1
0.8 0.8
1.1
1.2
Predominant Wind
Direction .
SE
SE ESE ESE E
ENE SSE ssw
SE
- - - -
-----
SOURCE: Weather Underground, Historical Weather for the Beverly Cove Weather Station, Beverly, MA. Accessed August 20, 2008
(http://www. wunderground .com/weatherstation/WXDailyH story.asp?l D=KMASTONE 1&day=20&year=2008&month=8&graphspan=ye
[1)
CONVERSION FACTOR:
1 mph = 0.44704 m/s
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Table 11. Airborne Mixing and Dispersion Calculations for the Concentrations of Landfill Gas Constituents in
Inhalation Exposure Area
Influx with wind from the South
Influx with wind from the East
Influx from the Vents
Outflow with wind to North
Outflow with wind to East
Cone of LFG in the lEA or UA
DEFINITIONS
INwsi
IN
wEi
IN vi
OUTwNi=
OUTwwi=
CBOXi
Vs and
VN
VE
and Vw
WIEA
LIEA
MHIEA
Q
CINWSi
CINWEi
CINVi
ll'{ys;
=
Vs x"Tf;EAXMJ-kAJCCINws.
Il'{yEi = v;,x4EAXMJ-kAJCCINwE
IN V; = Q
X
CINVi
X
LIEA
X
WIEA
OUJ;N;
=v;;xw;dM fEAxCsox
OUJ:'w, = ~ x 4 E J C M I - f E A X C e o x ,
[
l
[
l
[
QxCINViXL
1
EAXWm
Vs XWIEA X c NWSi + VEX
LIEA
XCINWEi + = - - - - ' = . c . ~ = - ~
MHIE4
CBOX i = [( L )]
Vsx
WIEA) + (VEx IliA
Influx ofLFG constituent
"i"
in the wind blowing from the south [ug/s]
Influx ofLFG constituent "i" in the wind blowing from the east [ug/s]
Influx ofLFG constituent "i" from the LFG influx from within the footprint area of the bo
Outflow
ofLFG
constituent
"i"
in the wind blowing to the north [ug/s]
Outflow
ofLFG
constituent "i"
in
the wind blowing to the west [ug/s]
Concentration ofLFG constituent
"i"
in the box [ug/m
3
]
Average speed
of
the wind blowing from the south or to the north [rnls]
Average speed
of
the wind blowing from the east or to the west [rnls]
Width
of
he box [m]
Length of he box [m]
Mixing Height
of
the air
in
the box [m]
Flux ofLFG released per unit area within the footprint of he box [ m 3 / m 2 ~ s ]
Concentration of LFG constituent
"i"
in the clean wind blowing from the south into the b
Concentration
of
LFG constituent "i" in the clean wind blowing from the east into the box
Concentration
ofLFG
constituent
"i"
in the LFG emissions entering into the box [ug/m
3
]
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Table 11. Airborne Mixing and
Dispersion Calculations
for
the
Concentrations of
Landfill
Gas Constituents in
Inhalation Exposure Area
V
8
and VN
VE and
Vw
WIEA
.
LIEA
MHIEA
(m/s) (m/s)
(m)
(m) (m)
IEastern lEA
Box Model
Parameters 0.54 0.54
-99.1
172.2 1.83
Eastern lEA
Cuoxi
CINWSi
CtNWEi CINVi
Detected
Volatile
Organic
Compounds
(uglm )
(ug/m ) (uglm )
(ug/m)
Acetone 5.74E-04
0.00 0.00
45.2
Benzene 7.64E-04
0.00
0.00
60.1
Chlorobenzene 1.17E-04 0.00
0.00
9.2
Chloroform 1.24E-04
0.00 0.00 9.8
Dichlorodifluoromethane
1.26E-04
0.00 0.00
9.9
cis-1 ,2-Dichloroethene
1.40E-04
0.00 0.00 11.0
1 2-Dichloro-1, 1 2,2-tetrafluoroethane 9.23E-04 0.00
0.00
72.7
Ethyl benzene 3.07E-04 0.00
0.00
24.2
4-Ethyltoluene
2.15E-04
0.00 0.00
16.9
Methylene Chloride 9.36E-05 0.00 0.00 7.4
Styrene 1.43E-04 0.00 0.00 11.3
Tetrachloroethene (PCE)
1.72E-04 0.00
0.00
13.6
Toluene
7.66E-04
0.00 0.00
60.3
Trichloroethene (TCE) 1.36E-04 0.00 0.00 10.7
1 2,4-Trimethylbenzene
4.01E-04 0.00
0.00
31.6
Vinyl chloride
2.70E-04
0.00 0.00
21.2
Xylenes (total)
6.55E-04 0.00
0.00
51.6
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Table
12.
Airborne Mixing and Dispersion Calculations for the Concentrations of Landfill Gas Constituents in
Inhalation Exposure Area
Influx with wind from the South
Influx with wind from the East
Influx from
the Vents
Outflow with wind to North
Outflow with wind to East
Cone of LFG in the lEA or UA
DEFINITIONS
INwsi
IN wEi
IN vi
OUTwNi=
OUTwwi=
CBOXi
V
5
and
VN
VE
and
Vw
WIEA
LIE A
MHIEA
Q
CINWSi
CINWEi
CtNVi
- - - - -
--- · -----
l. Vws;
=V,xw;EAxMfk;xGNws.
IJ¥ve; ="V;,x4eAxlVllfeAxGNwE.
INv; = QxCINVi xLIEA xWIEA
OU'f,Ni
= J i ; y x w ; E ) C M ~ E A x C B O X
OUTww; = VExLIEAxMHIEAxCsox;;
[v:
W C
l
[
C
l
[
QxCINviXLIEAxWIE
s X lEA X
INWSi +
VEX LJEA X
INWEi +
C
- MHIEA
BOX/i -
[(V
8
xW
11
') + (VEXL
1
EA )]
Influx ofLFG constituent
"i"
in the wind blow ing from the south [ug/s]
Influx ofLFG constituent "i" in the wind blow ing from the east [ug/s]
Influx
ofLFG
constituent "i" from the LFG influx from within the footprint area of he bo
Outflow ofLFG constituent ' 'i" in the wind blowing to the north [ug/s]
Outflow
ofLFG
constituent "i" in the wind blowi ng to the west [ug/s]
Concentration
ofLFG
constituent "i" in the box [ug/m
3
]
Average speed of he wind blowing from the south or to the north [m/s]
Average speed of the wind blowing from the east or to the west [m/s]
Width of the box [m1
Length of the box [m1
Mixing Height of the air in the box [m1
Flux
ofLFG
released per unit area within the footprint of he box [m3/m2-s1
Concentration
ofLFG
constituent "i" in the clean wind blowing from the south into the b
( A s s u m e d ~ output of the Eastern lEA) [ug/m31
Concentration
of
LFG c:onstituent
"i"
in the clean wind blowing from the east into the box
( A s s u m e d ~ output of the Eastern lEA) [ug/m31
Concentration of LFG constituent "i" in the LFG emissions entering into the box [ ug/m
3
]
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Table 12. Airborne Mixing and Dispersion Calculations for the Concentrations
of
Landfill Gas Constituents in
Inhalation Exposure Area
Vs and VN
VEand
Vw
WIEA
LIEA MHn:A
(m/s)
(m/s) (m) (m) (m)
Western lEA Box Model Parameters
0.54 0.54 71.6 99.1 1.83
Western lEA
Caoxi
CINWSi
CINWEi
CINVi
Detected Volatile Organic Compounds
(ug/m ) (ug/m )
(ug/m)
(ug/m )
Acetone
8.74E-04 5.74E-04 5.74E-04 35.7
Benzene
1.17E-03 7.64E-04 7.64E-04 47.9
Chlorobenzene 1.97E-04 1.17E-04
1.17E-04 9.5
Chloroform 2.95E-04
1.24E-04 1.24E-04 20.3
Dichlorodifluoromethane 5.00E-04 1.26E-04 1.26E-04
44.6
cis-1 ,2-Dichloroethene 3.64E-04 1.40E-04 1.40E-04 26.7
1 2-Dichloro-1, 1 2,2-tetrafluoroethane 1.85E-03 9.23E-04
9.23E-04 .110.7
Ethyl benzene 4.97E-04
3.07E-04 3.07E-04 22.6
4-Ethyltoluene 3.17E-04 2.15E-04 2.15E-04
12.2
Methylene Chloride 1.52E-04 9.36E-05 9.36E-05 6.9
Styrene 2.65E-04 1.43E-04 1.43E-04 14.5
Tetrachloroethene (PCE)
5.56E-03
1.72E-04 1.72E-04 641.8
Toluene 1.24E-03 7.66E-04 7.66E-04
56.6
Trichloroethene (TCE)
3.32E-04
1.36E-04 1.36E-04 23.3
1 2,4-Trimethylbenzene 6.08E-04 4.01E-04 4.01 E-04
24.6
Vinyl chloride 9.50E-04 2.70E-04
2.70E-04 81.1
Xylenes (total)
1.08E-03 6.55E-04 6.55E-04
51.2
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Table 13. Airborne Mixing and Dispersion Calculations for the Concentrations of Landfill Gas Constituents in
Inhalation Exposure Area
Influx with wind from the South
Influx with wind from the East
Influx from the Vents
Outflow with wind to North
Outlaw with wind to East
Cone
of
LFG in the lEA or UA
DEFINITIONS
INwsi
IN wEi
INvi
OUTwNi=
OUTwwi=
Cooxi
Vs
and VN
VEand Vw
WIEA
LIEA
MHIEA
Q
CINWSi
CINWEi
CINVi
ll¥¥s;
="Vs,x'if;EAxMfkrGNws.
Il¥¥E;
= ~ x 4 E A x M f - k , ; c G N w E .
IN Vi =
Q
X CJNVi X
LIEA
X WIEA
OUJ;Ni = ~ X ~ E ) C M l f E A x C s o x
OU;l;v;
=
x 4 E J C M I - k r C s o x ,
[
l
[
l
[
QxCINVixL,EAxW,EA]
~ , x W , E A
xC Nwst
+ VExL,EA xC,NwEt + MH,EA
CBOX/i =
(V L
)]
[
V,x WlliA)
+ EX
lEA
Influx
ofLFG
constituent
"i"
in the wind blowing from the south [ug/s]
Influx ofLFG constituent "i" in the wind blowing from the east [ug/s]
Influx ofLFG constituent "i" from the LFG influx from within the footprint area
of
the box [ug/
Outflow ofLFG constituent
"'i"
in the wind blowing to the north [ug/s]
Outflow ofLFG constituent
"i"
in the wind blowing to the west [ug/s]
Concentration
of
LFG constituent "i" in the box [ug/m
3
]
Average speed of he wind blowing from the south or to the north [rn/s]
Average speed
of
he wind blowing from the east or
to
the west [rn/s]
Width
of
he box [m]
Length
of
the box [m]
Mixing Height
of
the air in the box [m]
Flux ofLFG released per unit area within the footprint
of
the box [rn3/rn2-s]
Concentration ofLFG constituent "i" in
the
clean wind blowing from
the
south into the box (As
Concentration ofLFG constituent "i" in the clean wind bloWing from the east into the box(= 0)
Concentration ofLFG constituent "i" in the LPG emissions entering into the box [ug/m
3
]
Page 1
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Table 13. Airborne Mixing and Dispersion Calculations for the Concentrations
of
Landfill Gas Constituents
in
Inhalation Exposure Area
Vs and
VN
VEand
Vw
WIEA LIEA
MHIEA
(m/s)
(m/s) (m) (m) (m)
Site-Wide lEA Box Model Parameters 0.54 0.54
121.9
198.1 1.83
Site-Wide lEA
Cnoxi
CINWSi
CINWEi
CINVi
Detected Volatile Organic Compounds
(ug/m ) (ug/m') (ug/m ') (ug/m )
Acetone 6.27E-04 0.00
0.00
41.1
Benzene 8.37E-04
0.00 0.00 54.9
Chlorobenzene 1.43E-04
0.00 0.00 9.4
Chloroform 2.18E-04 0.00
0.00
14.3
Dichlorodifluoromethane
3.77E-04 0.00
0.00
24.8
cis-1 ,2-Dichloroethene
2.71E-04
0.00 0.00 17.8
1 2-Dichloro-1, 1 2,2-tetrafluoroethane
1.36E'03
0.00
0.00
89.0
Ethyl benzene 3.58E-04 0.00
0.00
23.5
4-Ethyltoluene
2.27E-04
0.00 0.00 14.9
Methylene Chloride 1.10E-04 0.00
0.00
7.2
Styrene
1.93E-04
0.00 0.00 12.7
Tetrachloroethene (PCE)
4.31 E-03 0.00
0.00
282.8
Toluene 8.95E-04 0.00
0.00 58.7
Trichloroethene (TCE)
2.46E-04
0.00
0.00
16.1
1 2,4-Trimethylbenzene 4.36E-04
0.00 0.00 28.6
Vinyl chloride 7.15E-04 0.00
0.00
46.9
Xylenes (total)
7.84E-04
0.00
0.00
51.4
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Table 14.
Calculation
of
the Cancer and Non-Cancer
Inhalation Risk
Estimates
Relative to Outdoor Exposure f
Exposure Point
Non-Cancer
Health Effect Endpoint
Detected Volatile Organic Compounds
Concentration
Incremental Non
-CBOXi
RfC
RfC Cancer Hazard
Index
(ug/m3) (ug/m3)
Source
Site-Wide Inhalation Exposure Area
Acetone 6.27E-04
Benzene 8.37E-04
Chlorobenzene 1.43E-04
Chloroform 2.18E-04
Dichlorodifluoromethane 3.77E-04
cis-1 ,2-Dichloroethene
2.71E-04
1 2-Dichloro-1, 1 2,2-tetrafluoroethane 1.36E-03
Ethyl benzene
3.58E-04
4-Ethyltoluene 2.27E-04
Methylene Chloride
1.10E-04
Styrene 1.93E-04
Tetrachloroethene (PCE) 4.31E-03
Toluene
8.95E-04
Trichloroethene (TCE) 2.46E-04
1 2,4-Trimethylbenzene
4.36E-04
Vinyl chloride 7.15E-04
Xvlenes (total)
7.84E-04
Hvdroqen sulfide
4.51E-05
TOTAL
NOTES:
All values
are based on
chronic exposure.
X-
Signifies inadequate or unavailable inhalation toxicity value
RfC - Reference Concentration
IUR-
Inhalation Unit Risk
IRIS= Integrated Risk Information System
8.00E+02
3.00E+01
2.00E+01
6.60E+02
2.00E+02
3.50E+01
X
1.00E+03
X
1.06E+03
1.00E+03
4.60E+03
5.00E+03
1.80E+02
6.00E+OO
1.00E+02
1.00E+02
2.00E+OO
ATSDR =Agency for Toxic Substances and Disease Registry (Minimal Risk Levels)
PPRTV
=
Provisional
Peer Reviewed
Toxicity Value
MassDEP
MassDEP
MassDEP
MassDEP
ORNL
MassDEP
X
MassDEP
X
ATSDR
MassDEP
MassDEP
MassDEP
MassDEP
PPRTV
MassDEP
MassDEP
IRIS
MassDEP = MassDEP Shortforms for
Human
Health Risk Assessment Under the
MCP.
Updated February
2007.
ORNL
= Oak
Ridge National Laboratory National Regional Database of Preliminary Remediation
Goals.
7.84E-07
2.79E-05
7.13E-06
3.30E-07
X
X
X
3.58E-07
X
1.04E-07
1.93E-07
X
1.79E-07
1.37E-06
7.27E-05
7.15E-06
7.84E-06
2.26E-05
1.49E-04
Ca
IUR
(ug/m3)
X
7.80E-0
X
2.30E-0
X
X
X
X
X
4.70E-0
5.70E-0
5.50E-0
X
1.70E-0
X
8.80E,0
X
X
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.
Table 14.
Calculation of the Cancer and Non-Cancer Inhalation
Risk
Estimates
Relative to
Outdoor
Exposure f
Exposure Point
Non-Cancer
Health
Effect
Endpoint
Detected Volatile Organic Compounds
Concentration
Incremental Non
-CBOXi
RfC RfC
Cancer
Hazard
Index
(ug/m3) (ug/m3)
Source
Eastern Inhalation Exposure Area
Acetone 5.74E-04
Benzene 7.64E-04
Chlorobenzene
1.17E-04
Chloroform 1.24E-04
Dichlorodifluoromethane 1.26E-04
cis-1 ,2-Dichloroethene
1.40E-04
1 2-Dichloro-1, 1 2,2-tetrafluoroethane 9.23E-04
Ethyl benzene 3.07E-04
4-Ethyltoluene 2.15E-04
Methylene Chloride
9.36E-05
Styrene
1.43E-04
Tetrachloroethene (PCE) 1.72E-04
Toluene 7.66E-04
Trichloroethene (TCE)
1.36E-04
1 2,4-Trimethylbenzene
4.01E-04
Vinyl chloride 2.70E-04
Xylenes (total)
6.55E-04
Hydrogen sulfide
-
TOTAL
NOTES.
All values are based on chronic exposure.
X-
Signifies inadequate
or
unavailable inhalation toxicity value
RfC - Reference Concentration
IUR-
Inhalation Unit Risk
IRIS=
Integrated Risk Information System
8.00E+02
3.00E+01
2.00E+01
6.60E+02
2.00E+02
3.50E+01
X
1.00E+03
X
1.06E+03
1.00E+03
4.60E+03
5.00E+03
1.80E+02
6.00E+OO
1.00E+02
1.00E+02
2.00E+OO
ATSDR
=Agency
for Toxic Substances
and
Disease Registry (Minimal Risk Levels)
PPRTV =Prov isiona l Peer Reviewed Toxicity Value
MassDEP
MassDEP
MassDEP
MassDEP
ORNL
MassDEP
X
MassDEP
X
ATSDR
MassDEP
MassDEP
MassDEP
MassDEP
PPRTV
MassDEP
MassDEP
IRIS
MassDEP = MassDEP Shortforms for Human Health Risk Assessment Under the MCP. Updated February 2007.
ORNL = Oak Ridge National Laboratory National Regional Database of Preliminary Remediation Goals.
7.18E-07
2.55E-05
5.85E-06
1.88E-07
X
X
X
3.07E-07
X
8.84E-08
1.43E-07
X
1.53E-07
7.58E-07
6.69E-05
2.70E-06
6.55E-06
-
1.10E-04
Ca
IUR
(ug/m3)
X
7.80E-0
X
2.30E-0
X
X
X
X
X
4.70E-0
5.70E-0
5.50E-0
X
1.70E-0
X
B.BOE-0
.
X
X
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Table 14.
Calculation
of the Cancer and Non-Cancer
Inhalation Risk
Estimates Relative to
Outdoor
Exposure
f
Exposure Point
Non-Cancer
Health Effect Endpoint
Detected Volatile Organic Compounds
Concentration
Incremental Non
-CBOXi
RfC
RfC Cancer Hazard
Index
(ug/m3) (ug/m3)
Source
Western Inhalation Exposure Area
Acetone 8.74E-04
Benzene 1.17E-03
Chlorobenzene 1.97E-04
Chloroform
2.95E-04
Dichlorodifluoromethane 5.00E-04
cis-1 ,2-Dichloroethene
3.64E-04
1 2-Dichloro-1, 1 2,2-tetrafluoroethane 1.85E-03
Ethyl benzene
4.97E-04
4-Ethyltoluene
3. 17E-04
Methylene Chloride
1.52E-04
Styrene
2.65E-04
Tetrachloroethene (PCE)
5.56E-03
Toluene
1.24E-03
Trichloroethene (TCE) 3.32E-04
1 2,4-Trimethylbenzene
6.08E-04
Vinyl chloride
9.50E-04
Xylenes (total)
1.08E-03
HvdroQen sulfide
2.48E-05
TOTAL
NOTES.
All
values
are
based
on
chronic exposure.
X.- Signifies inadequate or unavailable inhalation toxicity value
RfC - Reference Concentration
IUR-
Inhalation Unit Risk
IRIS = Integrated Risk Information System
8.00E+02
3.00E+01
2.00E+01
6.60E+02
2.00E+02
3.50E+01
X
1.00E+03
X
1.06E+03
1.00E+03
4.60E+03
5.00E+03
1.80E+02
6.00E+OO
1.00E+02
1.00E+02
2.00E+OO
ATSDR
=Agency
for Toxic Substances and Disease Registry (Minimal Risk Levels)
PPRTV
=
Provisional Peer Reviewed Toxicity Value
MassDEP
MassDEP
MassDEP
MassDEP
ORNL
MassDEP
X
MassDEP
X
ATSDR
MassDEP
MassDEP
MassDEP
MassDEP
PPRTV
MassDEP
MassDEP
IRIS
MassDEP = MassDEP Shortforms for Human Health Risk Assessment Under the MCP. Updated February 2007.
ORNL
=
Oak Ridge National Laboratory National Regional Database of Preliminary Remediation Goals.
1.09E-06
3.88E-05
9.85E-06
4.46E-07
X
X
X
4.97E-07
X
1.43E-07
2.65E-07
X
2.48E-07
1.84E-06
1.01 E-04
9.50E-06
1
OBE-05
-
1.75E-04
Ca
IUR
(ug/m3)
X
7.80E-0
X
2.30E-0
X
X
X
X
X
4.70E-0
5.70E-0
5.50E-0
X
1.70E-0
X
8.80E-0
X
X
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Table 15.
Summary
of
the Results
of
the Outdoor
Air
Risk Assessment
for
Each Inhalation Exposure Area
(ApJ licable to All Receptors Exposed to
Outdoor
Air)
Inhalation Exposure Area
Site-Wide
Eastern
Western
Cumulative HI
1.49E-04 l.IOE-4 1.75E-04
Cumulative ELCR 2.49E-07 1.86E-08 3.22E-07
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Table 17. Summary
of the
Hydrogen
Sulfide
Sampling Results
and Relevant Odor
Thresholds
and
Occupational Safety Criteria for Hydrogen Sulfide
Data Summary
CAS Number
7783-06-4
Minimum Detected Concentration (ppm)
0.9
Maximum Detected Concentration (ppm)
4.2 ppm
Location
of
Maximum Detected Concentration GP-6R
Frequency
of
Detection
2/5
Odor
Thresholds
ERDC Odor Threshold [1]
0.13 ppm
ATSDR Odor Threshold [2]
0.5 ppb
CaiEPNOEHHA Odor Threshold [3]
8.1
ppb
Relevant
Occupational
Safety Criteria
NIOSH REL [4]
10 ppm
OSHA PEL - Construction Industry [5]
10 ppm
ACGIH TLV (8-hr Time Weighted Average) [1]
10 ppm
ACGIH STEL [1]
15 ppm
OSHA PEL- General Industry [5]
20ppm
OSHA Maximum Peak (10 min exposure) [4]
50 ppm
NIOSH IDLH Level [4]
100 ppm
NOTES:
ACGIH =American Conference
of
Government Industrial Hygenists
IDLH = Immediately Dangerous to Life and Health
PEL= Permissible Exposure Limit (10 minute maximum peak)
REL = Reasonable Exposure Limit
STEL
=Short
Term Exposure Limit (above TLV)
TLV = Threshold Limit Value
[1] Source: Economic Research and Development Center (ERDC), USAGE
[2] Source: ATSDR Website (http://www.atsdr.cdc.gov/mhmi/mmg114.html)
[3] CaiEPA OEHHA.
[4] Source: NIOSH Pocket Guide to Chemical Hazards (online).
[5] Source: OSHA Website (www.osha.gov)
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APPENDIX A
Site Visit
Photographic
Log
August 15, 2008
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Location Key to the Photographic Log
Site: North Shore Commons Site, Brimbal Avenue, Beverly, MA
Numbers correspond to photograph numbers
in
the photographic log . Arrows denote direction
in
which the ph
taken. Created 9/2/2008 .
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-- - - - - - - -
-
Photograph 1:
View to the west from Brimbal Avenue across
the site,
w1th
the temporary access road into the site visible
on
the left.
t 'P ·ro
6.5
i
\CRES
-----
\/ILL B l
- I I O rrO
SlJirf
Photograph
2:
View to the south at the northeastern edge of
the site along Brimbal Avenue, showing the property
advertisement sign.
SITE VISIT PHOTOGRAPHIC LOG
Solid Waste Assessment
Risk
Assessment
North Shore Commons Site, Brimbal Avenue, Beverly, MA
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Photograph 3: View to the southwest from Brimbal Avenue
across the site toward the Northridge Homes Cooperative, with the
section of exposed pavement to the left.
Photograph
4:
Close-up view of the section of exposed
pavement along Brimbal Avenue on the eastern edge of the
site.
SITE VISIT PHOTOGRAPHIC LOG
Solid Waste Assessment
Risk
Assessment
North Shore Commons Site, Brimbal Avenue, Beverly,
MA
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Photograph 5: View to the south across the site, showing
the topography and ground cover and the northeastern
portion of the Northndge Homes Cooperative.
Photograph
6: View to the east across Brimbal Avenue
from the eastern edge of the site, toward the North Shore
Regional Dialysis Center.
SITE VISIT PHOTOGRAPHIC LOG
Solid Waste Assessment Risk Assessment
North Shore Commons Site, Brimbal Avenue, Beverly, MA
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Photograph
7:
View to the southeast across Brimbal Avenue
from the eastern edge
of
the site, toward the gas stations across
from the southeast corner
of
the site.
Photograph
8:
View
of
the ground surface
in
the
northeastern portion
of
the
s1te
that was cleared and that
had accumulated rainwater.
SITE VISIT PHOTOGRAPHIC LOG
Solid Waste Assessment Risk Assessment
North Shore Commons Site, Brimbal Avenue, Beverly, MA
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Photograph
9:
View to the south across the eastern half
of
the site, snowing the current ground cover and the open
area
of
the Northridge Homes Cooperative in the
b-aGkQFOH-nfi-. -
Photograph
10:
View to the southwest across the site,
showing the current ground cover and the unit
of
the Northridge
Homes Cooperative closest to the site.
SITE VISIT PHOTOGRAPHIC LOG
Solid
Waste Assessment Risk Assessment
North Shore Commons Site, Brimbal Avenue, Beverly, MA
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Photograph 11:
View to the northwest across Sohier Road,
at the ous1ness across the street.
Photograph
12:
View to the west across Sohier Road, at the
business across the street.
SITE VISIT PHOTOGRAPHIC LOG
Solid Waste Assessment Risk Assessment
North Shore Commons Site, Brimbal Avenue, Beverly, MA
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Photograph 13:
View to the south from the southwestern
corner of the site, showing the unit of the Northridge
Homes Cooperative closest to the site.
Photograph 14: View to the northeast from the center of the
site, toward the Italian American Club
on
Brimbal Avenue.
SITE VISIT PHOTOGRAPHIC LOG
Solid Waste Assessment
Risk
Assessment
North Shore Commons Site, Brimbal Avenue, Beverly, MA
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- - -
---- -- -
-
Photograph
15: View to the west from the northeastern corner
of the site along the Sohier Road
I
Brimbal Avenue access road
that borders the site
on
the north, showing the change in
elevation and fence.
Photograph 16: View to the south from the northeastern corner
of the site along Brimbal Avenue that borders the site on the east,
showing the fence that blocks portions of the site.
SITE VISIT PHOTOGRAPHIC LOG
Solid Waste Assessment Risk Assessment
North Shore Commons Site, Brimbal Avenue, Beverly, MA
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Photograph 17: View to the south from the Schier Road I
Brimbal Avenue access road across the central portion of
the site, showing the topography and current ground cover.
Photograph 18:
View to the southeast from the Schier Road
I
Brimbal Avenue access road across the central portion of the
site, showing the fence and the current ground cover.
SITE VISIT PHOTOGRAPHIC LOG
Solid Waste Assessment
Risk
Assessment
North Shore Commons Site, Brimbal Avenue, Beverly, MA
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Photograph 19: View to the northeast from the northwestern
corner of the site, showing the fencing above the drainage
culvert running beneath the Sohier Road I Brimbal Avenue
access road.
Photograph 20: View to the east from the northwestern
corner of the site, showing the property advertisement sign.
SITE VISIT PHOTOGRAPHIC LOG
Solid
Waste Assessment Risk Assessment
North Shore Commons Site, Brimbal Avenue, Beverly, MA
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Photograph
21: View to the southeast from the northwestern
corner of the site across the central portion of the site,
showing the topography and current ground cover.
Photograph 22: View to the southeast from the western edge
of the site, showing the unit of the Northridge Homes
Cooperative closest to the site.
SITE VISIT PHOTOGRAPHIC LOG
Solid Waste Assessment Risk Assessment
North Shore Commons Site, Brimbal Avenue, Beverly, MA
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Photograph 23: View toward the northeast from the
southwestern corner of the site, showing the topography and
current ground cover
in
this area.
Photograph 24: View toward the east from just south of the
southwestern corner of the site, showing the trench next to
the
unit of the Northridge Homes Cooperative.
SITE VISIT PHOTOGRAPHIC LOG
Solid Waste Assessment
Risk
Assessment
North Shore Commons Site, Brimbal Avenue, Beverly, MA
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Photograph
25: View toward the southeast across Sohier
Road, showing the sign for the Northridge Homes Cooperative.
Photograph 26: View toward the northwest from the
southwestern corner of the site, showing the CPI facility across
Sohier Road.
SITE VISIT PHOTOGRAPHIC LOG
Solid Waste Assessment
Risk
Assessment
North Shore Commons Site, Brimbal Avenue, Beverly, MA
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Photograph
27: View toward the northwest from the
northwestern corner
of
the site, looking across the grass island
in the traffic intersection.
Photograph
28:
View toward the northeast from the
northeastern corner of the site, looking across the grass island in
the traffic intersection with the Italian American Club in the
background.
SITE VISIT PHOTOGRAPHIC LOG
Solid
Waste Assessment Risk Assessment
North Shore Commons Site, Brimbal Avenue, Beverly, MA
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Photograph 29:
View toward the north along Brimbal Avenue
from the southeastern corner of the site.
SITE VISIT PHOTOGRAPHIC LOG
Solid
Waste Assessment Risk Assessment
North Shore Commons Site, Brimbal Avenue, Beverly, MA
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APPENDIXB
Test America Laboratory
Report
for the Soil Gas Probe Samples
August 18, 2008
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TestAmerica
THE LEADER IN
ENVIRONMENTAL
TESTING
August 18, 2008
Client:
Griffin Engineering Group Beverly
100 Cummings Center Suite 222G
Beverly, MA 01915
Attn: Peter Flink
1721 South Grand Avenue Santa Ana, CA 92705 • 714-25 8-861 0• Fax 714-258-0921
LABORATORY REPORT
Work Order:
Project Name:
Project Number:
Date Received:
LRH0043
Brimbal Ave
[none]
08/05/08
The results listed within this Laboratory Report pertain on ly to the samples tested in the laboratory. The analyses contained in this report were
performed
in
accordance with the applicable certifications as
noted
This Laboratory Report is confidential
and
is intended or the sole use
o f
TestAmerica
and
its client. This report shafl not be reproduced, e xcept in full, without written permission rom TestAmerica.
TestAmerica Laboratories, Inc. certifies that the analytical results contai ned herein apply on ly to the specific samp/e(s) analyzed.
The Chain(s) ofCziStody, 2 pages, are included
and
are an integral part of his report. This entire report was reviewed
and
approved or
release.
If
you have any questions relating to this analytical report, please contact your Laboratory Project Manager at 714-258-8610.
Analyses included in this report were performed by the laboratory shown at the top
of
this report unless otherwise indicated.
Approved By:
Marisol Tabirara
Project Manager
NELAP Certification # E87652
1
of
53
LRH
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Test
America
Tfii;: LEADE:R IN ENVIRONME:NTAL TESTING
Griffin Engineering Group Beverly
100 Cummings Center Suite 2220
Beverly,
MA
01915
Peter Flink
SAMPLE
IDENTIFICATION
GP-21
GP-25
GP-14
GP-26
GP-20
GP-6R
GP-IIR
GP-12
1721 South Grand Avenue Santa Ana, CA 92705 • 714-258-8610 • Fax 714-258-0921
Work Order:
LRH0043
Project:
Brimbal Ave
Project Number:
[none]
LAB
NUMBER COLLECTION
LRH0043-0I
08/04/08 09: 16
LRH0043-02 08/04/08 09:35
LRH0043-03 08/04/08 09:30
LRH0043-04 08/04/08 10:00
LRH0043-05
08/04/08 10:05
LRH0043-06 08/04/08 10:38
LRH0043-07 08/04/08 I 0:25
LRH0043-08
08/04/08 I0: 18
2
o f
53
MATRIX
Air
Air
Air
Air
Air
Air
Air
Air
Received: 08/05/08 10:00
Reported: 08/18/0817:18
CONTAINER TYPE
Passivated Canister
Passivated Canister
Passivated Canister
Passivated Canister
Passivated Canister
Passivated Canister
Passivated Canister
Passivated Canister
LRH
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TestAmerica
THE
LE:ADE:R IN
ENVIRONMENTAl TESTING
721
South Grand Avenue Santa Ana, CA 92705
*
714-258-8610 • Fax 714-258-0921
Griffin Engineering Group Beverly
100 Cummings Center Suite 222G
Beverly, MA 01915
Peter Flink
Department: , Sample Control
Method:
QC Batch:
Identification and Definition of Problem:
Work Order: LRH0043
Project: Brimbal Ave
Project Number: [none]
CORRECTIVE ACTION
REPORT
Date: 08/05/2008
Matrix:
Sample
#01
was not analyzed for EPA
1,5/16.
Determination of the Cause of the Problem:
The Tedlar bag that contained the sample was flat when received at the laboratory.
Corrective Action Taken:
Client was notitied of he anomaly on August 5, 2008.
3
of
53
Received: 08/05/08 10:00
Reported: 08/18/08
17:
18
LRH
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TestAmerica
THE LEADER
IN ENVIRONMENTAL TESTING
1721 South Grand Avenue Santa Ana, CA 92705 • 714-258-8610 • Fax_714-258-0921
Griffin Engineering Group Beverly
100 Cummings Center Suite 222G
Beverly,
MA
01915
Peter Flink
Work Order:
Project
Project Number:
LRH0043
Brimbal Ave
{none]
Received: 08/05/08 I 0:00
Reported: 08/18/08 17:18
ANALYTICAL REPORT
Analyte
Sample ID: LRH0043-0I (GP-21
-Air)
Data
Result Qualifiers
EPA TOIS (Med-level)- Volatile Organic Compounds by GC/MS
Acetone
Benzene
Benzyl chloride
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone
(MEK)
Carbon disulfide
Carbon tetrachloride
Chi oro benzene
Dibromochloromethane
Chloroethane
Chloroform
Chloromethane
1,2-Dibromoethane (EDB)
1,2-Dichlorobcnzene
1,3-Dichlorobenzene
I, 4-Dichlorobenzene
Dichlorodifluoromethane
I,
1-Dichloroethane
1,2-Dichloroethane
cis-1,2-Dichloroethene
trans-I ,2-Dich\oroethene
I, I- Dichloroethene
I 2-Dich\oropropane
cis-I 3-Dichloropropene
trans-1,3-Dichloropropene
J
2-Dichloro-1,1,2,2-tetraftuoroethane
Ethyl benzene
4-Ethy\to\uene
Hexachlorobutadiene
2-Hexanone
Methylene chloride
4-Methy\-2-pentanone (MIBK)
Styrene
I, I 2,2-Tetrachloroethane
Tetrachloroethene
Toluene
I 2,4-Trichlorobenzene
1,1, -Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
27
32
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
5,1
ND
ND
ND
ND
ND
14
4.6
ND
ND
ND
ND
ND
3.3 JA
ND
ND
21
ND
ND
ND
ND
Units
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
RL
10
3.0
10
2.0
2.0
4.0
10
10
2.0
2.0
2.0
4.0
2.0
4.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
3.0
2.0
2.0
2.0
2.0
2.0
4.0
10
2.0
10
2.0
2.0
2.0
2.0
5.0
2.0
2.0
2.0
4
o f 53
Date
Dilution Analyzed
Instrument
QC
Analyst Batch
Sampled: 08/04/08 09:16
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
08/06/08 13:34
08/06/08 13:34
08/06/08 13:34
08/06/08 13 :34
08/06/08 13:34
08/06/08 13:34
08/06/08 13:34
08/06/08 13:34
08/06/08 13:34
08/06/08 13:34
08/06/08 13:34
08/06/08 13:34
08/06/08 13:34
08/06/08 13:34
08/06/08 13:34
08/06/08 13:34
08/06/08 13:34
08/06/08 13:34
08/06/08 13:34
08/06/08 13:34
08/06/08 13
:34
08/06/08 13:34
08/06/08 13:34
08/06/08 13:34
08/06/08 13:34
08/06/08 13:34
08/06/08 13:34
08/06/08 13:34
08/06/08 13:34
08/06/08 13:34
08/06/08 13:34
08/06/08 13:34
08/06/08 13:34
08/06/08 13:34
08/06/08 13:34
08/06/08 13:34
08/06/08 13:34
08/06/08 13:34
08/06/08 13:34
08/06/08 13:34
08/06/08 13 :34
08/06/08 13:34
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
8H07011
8H070ll
8H07011
8H0701l
8H07011
8H07011
8H070\l
8H07011
8H07011
8H07011
8H07011
8H07011
8H07011
8H07011
8H070ll
8H07011
8H070ll
8H07011
8H070ll
8H07011
8H07011
8H07011
8H07011
8H07011
8H07011
8H07011
8H07011
8H07011
8H0701l
8H07011
8H07011
8H07011
8H07011
8H07011
8H07011
8H070\l
8H07011
8H07011
8H07011
8H07011
8H07011
8H070ll
LR I0
8/11/2019 Brimbal Ave. - Environmental Notification Form - 9.2.14 - Volume 2 of 2
http://slidepdf.com/reader/full/brimbal-ave-environmental-notification-form-9214-volume-2-of-2 480/798
TestAmerica
THE LEADE:R
IN
ENVIRONMENTAl TE'STING
1721 South Grand Avenue Santa Ana, CA 92705 * 714-258-8610 • Fax 714-258-0921
Griffin Engineering Group Beverly
l 00 Cummings Center Suite
2220
Beverly, MA 01915
Peter Flink
Analyte
Result
Sample ID: LRH0043-0l (GP-21
-Air)-
cont.
Work Order: LRH0043
Project: Brimbal Ave
Project Number: [none]
ANALYTICAL REPORT
Data
Qualifiers Units
RL
Dilution
EPA T015 (Med-level)- Volatile
Organic
Compounds
by GC/MS-
coot
Trichlorofluoromethane NO ppbv 2.0
1.0
I, 1,2-Trichloro-1 ,2,2-trifluoroethane
NO
ppbv 2.0
1.0
I 2, 4-T rimethylbenzene NO
ppbv
3.0
1.0
1,3,5-Trimethylbenzene
NO ppbv
3.0
1.0
Vinyl acetate NO
ppbv
10
1.0
Vinyl chloride 21 ppbv 3.0
1.0
Xylenes, total 9.7 ppbv
2.0
1.0
5
o f 53
Received: 08/05/08 I 0:00
Reported: 08/18/08 17:18
Date
QC
Analyzed
Instrument Analyst
Batch
Sampled: 08/04/08 09:16
08106/08 13:34 MSA
AA
8H07011
08/06/08 13:34
MSA
AA
&H07011
08106/08 13:34 MSA AA
8H07011
08/06/08 13:34
MSA AA
8H07011
08/06/08 13;34
MSA
AA
8H07011
08/06/08 13:34
MSA
AA
8H07011
08/06/08 13:34
MSA
AA 8H07011
LRH
8/11/2019 Brimbal Ave. - Environmental Notification Form - 9.2.14 - Volume 2 of 2
http://slidepdf.com/reader/full/brimbal-ave-environmental-notification-form-9214-volume-2-of-2 481/798
Test
America
THE: Lf:ADE:R IN ENVIRONMf:NTAL TE:STING
Griffin Engineering Group Beverly
100
Cummings Center Suite
2220
Beverly,
MA
01915
Peter Flink
1721 South Grand Avenue Santa Ana, CA 92705 * 714-258-8610 • Fax 714-258-0921
Work Order:
Project:
Project Number:
LRH0043
BrimbalAve
[none]
ANALYTICAL REPORT
Received: 08/05/08 10:00
Reported: 08/18/0817:18
Analytc
Data
Result Qualifiers Units
RL
Date
Dilution Analyzed
Instrument
QC
Analyst Batch
Sample ID: LRH0043-02 (GP-25- Air)
EPA TOtS (Med-level)- Volatile Organic Compounds by GC/MS
Acetone
Benzene
Benzyl chloride
Bromodich\oromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon disulfide
Carbon tetrachloride
Chioro benzene
Dibromochloromethane
Chloroethane
Chlorofonn
Chloromethane
1,2-Dibromoethane (EDB)
1,2-Dichlorobenzene
I 3-Dichlorobenzene
1,4-Dich\orobenzene
Dichlorodifluoromethane
1,1-Dich\oroethane.
I 2-Dich\oroethane
cis- ,2-Dichloroethene
trans- ,2-Dichloi-oethene
I, 1-Dichloroethene
1,2-Dichloropropane
cis-1,3-Dichloropropene
trans- ,3-Dichloropropene
1,2-Dichloro-1, 1,2,2-tetrafluoroetbane
Ethyl
benzene
4-Ethyltoluene
Hexachlorobutadiene
2-Hexanone
Methylene chloride
4-Methyl-2-pentanone (MIBK)
Styrene
I, 1,2,2-Tetrachloroethane
T etrach1oroethene
Toluene
1,2,4-Trichlorobenzene
1,1, 1-Trichloroethane
I,
1,2-Trichloroethane
Trich1oroethene
19
4.8
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
4.6
3.1
NO
NO
NO
NO
NO
2.6 JA
NO
NO
13
NO
NO
NO
NO
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
10
3.0
10
2.0
2.0
4.0
10
10
2.0
2.0
2.0
4.0
2.0
4.0
2.0
2.0
2.0
2.0
2.0
_2.0
2.0
2.0
2.0
2.0
3.0
2.0
2.0
2.0
2.0
2.0
4.0
10
2.0
lO
2.0
2.0
2.0
2.0
5.0
2.0
2.0
2.0
6
o f
53
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
Sampled: 08/04/08 09:35
08/06/08 14:14
08/06/08 14:14
08/06/08 14:14
08/06/08 14:14
08/06/08 14:14
08/06/0814:14
08/06/0814:14
08/06/0814:14
08/06/08 14:14
08/06/08 14:14
08/06/08 14:14
08/06/08 14:14
08/06/08 14:14
08/06/08 14:14
08/06/ 08 14: 14
08/06/08 14:14
08/06/08 14:14
08/06/ 08 14: 14
08/06/08 14:14
08/06/ 08 14: 14
08/06/08 14:
14
08/06/08 14: 14
08/06/08 14: 14
08/06/08 14: 14
08/06/08 14:14
08/06/08
14:
14
08/06/08
14:
14
08/06/08 14:
14
08/06/08 14: 14
08/06/08 14:14
08/06/08 14:14
08/06/08
14: 14
08/06/08 14:14
08/06/08 14:14
08/06/08 14:14
08/06/08 14:14
08/06/08 14:14
08/06/08 14:14
08/06/0814:14
08/06/0814:14
08/06/0814:14
08/06/08 14:14
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
8H07011
8H07011
8H07011
8H07011
8H07011
8H07011
8H07011
8H07011
8H07011
8H07011
8H07011
8H07011
8H070ll
8H07011
8H07011
8H07011
8H07011
8H0701l
8H07011
8H07011
8H07011
8H07011
8H07011
8H07011
8H07011
8H07011
8H07011
8H07011
8H07011
8H070ll
8H07011
8H07011
8H07011
8H07011
8H07011
8H07011
8H07011
8H07011
8H0701l
8H0701 I
8H07011
8H07011
LRH
8/11/2019 Brimbal Ave. - Environmental Notification Form - 9.2.14 - Volume 2 of 2
http://slidepdf.com/reader/full/brimbal-ave-environmental-notification-form-9214-volume-2-of-2 482/798
TestAmerica
THE LEADER IN EONVIRONMENTAL TESTING
1721 South Grand Avenue Santa Ana, CA 92705 * 714-258-8610 • Fax 714-258-0921
Griffin Engineering Group Beverly
100 Cummings_
e n t e r
Suite
2220
Beverly, MA 01915
Peter Flink
Analyte
Result
Sample ID: LRH0043-02
(GP-25- Air)-
cont.
Work Order: LRH0043
Project
Brimhal Ave
Project Number: [noneJ
ANALYTICAL REPORT
Data
Qualifiers
Units
RL
Dilution
EPA TOtS (Med-level)- Volatile Organi c Compounds by GC/MS- cont.
Trichlorofluoromethane NO
ppbv 2.0
1.0
I, I 2-Trichloro-1,2,2-trifluoroethane NO ppbv
2.0 1.0
1,2,4-Trimethylbenzene
NO
ppbv 3.0 1.0
l , 3 , 5 ~ T r i m e t h y l b e n z e n e
ND
ppbv
3.0 1.0
Vinyl acetate
NO
ppbv 10 1.0
Vinyl chloride 6.2 ppbv 3.0
1.0
Xylenes, total 7.6
ppbv 2.0 1.0
7
o f 53
Date
Analyzed
Received: 08/05/08 10:00
Reported: 08/18/0817:18
QC
Instrument
Analyst
Batch
Sampled: 08/04/08 09:35
08/06/08 14:
14
MSA AA
8H0701l
08/06/08 14:
14 MSA
AA 8H07011
08/06/08 14:
14
MSA
AA 8H07011
08/06/08 14:14
MSA
AA
8H07011
08/06/08 14:14
MSA
AA 8H07011
08/06/08 14:14
MSA
AA
8H07011
08/06/0814:14
MSA AA 8H07011
LRH
8/11/2019 Brimbal Ave. - Environmental Notification Form - 9.2.14 - Volume 2 of 2
http://slidepdf.com/reader/full/brimbal-ave-environmental-notification-form-9214-volume-2-of-2 483/798
TestAmerica
THE LEADER
IN ENVIRONMENTAL
HoSTING
1721 South Grand Avenue Santa Ana, CA 92705 • 714-258-8610" Fax 714-258-0921
Griffin Engineering Group Beverly
100 Cummings Center Suite 2220
Beverly, MA
01915
Peter Flink
Work Order:
Project:
Project Number:
LRH0043
Brimbal Ave
[none]
Received:
08/05/08 10:00
Reported:
08/18/08 17:18
ANALYTICAL
REPORT
Analyte
Sample
10:
LRH0043-03
(GP-14-
Air)
Data
Result Qualifiers
EPA TO IS (Med-level)- Volatile Organic Compounds by GC/MS
Acetone
Benzene
Benzyl chloride
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone
(MEK)
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Dibromocbloromethane
Chloroethane
Chloroform
Chloromethane
1,2-Dibromoethane (EDB)
1,2-Dichlorobenzene
I 3-Dich\orobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
I 2-Dichloroethane
cis-1,2-Dich\oroethene
trans-1,2-Dichloroethene
I, 1-Dich\oroethene
1,2-Dich\oropropane
cis- 3-Dich\oropropene
trans-\ 3-Dich\oropropene
I 2-Dich\oro-1, 1 2,2-tetrafluoroethane
Ethylbenzene
4-Etbyltoluene
Hexachlorobutadiene
2-Hexanone
Methylene chloride
4-Methy\-2-pentanone
(MIBK)
Styrene
1,
I 2,2-Tetrachloroethane
T etrachloroethene
Toluene
1,2,4-Trich\orobenzene
I, I, 1-Trichloroethane
I, 1,2-Trich\oroethane
Trichloroethene
NO
250
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
..
2.0
NO
NO
NO
NO
4.2 JA
NO
NO
30
NO
NO
NO
NO
Units
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
Jlpbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
RL
0
3.0
10
2.0
2.0
4.0
10
10
2.0
2.0
2.0
4.0
2.0
4.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
3.0
2.0
2.0
2.0
2.0
2.0
4.0
10
2.0
10
2.0
2.0
2.0
2.0
5.0
2.0
2.0
2.0
8
o f
53
Date
Dilution Analyzed
Instrument
QC
Analyst Batch
Sampled: 08/04/08 09:30
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
10
1.0
10
1.0
10
1.0
10
10
1.0
10
1.0
1.0
1.0
1.0
1.0
1.0
10
1.0
1.0
1.0
1.0
10
1.0
10
1.0
1.0
1.0
1.0
1.0
1.0
10
1.0
10
08/06/08 15:04
08/06/08 15:04
08/06/08 15:04
08/06/08 15:04
08/06/08 15:04
08/06/08 15:04
08/06/08 15:04
08/06/08 IS :04
08/06/08 15:04
08/06/08 15:04
08/06/08 15:04
08/06/08 15:04
08/06/08 15:04
08/06/08 15:04
08/06/08 15:04
08/06/08 15:04
08/06/08 15:04
08/06/08 15:04
08/06/08 15:04
08/06/08 15:04
08/06/08 15:04
08/06/08 15:04
08/06/08 15:04
08/06/08 15:04
08/06/08 15:04
08/06/08 15:04
08/06/0815:04
08/06/08 15:04
08/06/08 15:04
08/06/08 15:04
08/06/08 15:04
08/06/08 15:04
08/06/08 15:04
08/06/08 15:04
08/06/08 15:04
08/06/08 15:04
08/06/08 15:04
08/06/08 15:04
08/06/08 15:04
08/06/08 15:04
08/06/08 15:04
08/06/08 15:04
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
8H07011
8H07011
8H07011
8H07011
8H07011
8H07011
8H070ll
8H070.11
8H07011
8H0701 I
8H07011
8H0701 I
8H0701l
8H07011
8H07011
8H07011
8H07011
8H070ll
8H07011
8H07011
8H0701\
8H07011
8H07011
8H07011
8H0701l
8H0701 I
8H07011
8H0701l
8H070ll
8H07011
8H07011
8H070ll
8H0701\
8H07011
8H0701\
8H07011
8H07011
8H07011
8H07011
8H07011
8H07011
8H07011
LRH0
8/11/2019 Brimbal Ave. - Environmental Notification Form - 9.2.14 - Volume 2 of 2
http://slidepdf.com/reader/full/brimbal-ave-environmental-notification-form-9214-volume-2-of-2 484/798
TestAmerica
THI': LI':ADI':R IN
ENVIRONMENTAL
TESTING
1721
South Grand Avenue Santa Ana, CA 92705 • 714-258-8610 • Fax 714-258-0921
Griffin Engineering Group Beverly
100 Cummings Center Suite 222G
Beverly, MA 01915
Peter Flink
.
Analyte
Result
Sample ID: LRH0043-03 (GP-14- Air)- cont.
Work Order:
Project:
Project Number:
LRH0043
Brimbal Ave
[none]
ANALYTICAL REPORT
Data
Qualifiers
Units
RL
Dilution
EPA T015 (Med-level)- Volatile Organic Compounds by GC/MS- cont.
T richlorofluoromethane ND ppbv 2.0 1.0
I, 1 2·Tricbloro-1 ,2,2-trifluoroethane
ND ppbv
2.0
1.0
1,2,4-Trimethy\benzene
ND
ppbv 3.0 1.0
1,3,5-Trimethy\benzene
ND
ppbv
3.0
1.0
Vinyl acetate
ND
ppbv 10
1.0
Vinyl chloride
NO
ppbv 3.0
1.0
Xylenes, total 14 ppbv
2.0
1.0
9
o f 53
.
Received: 08/05/08 10:00
Reported: 08118/08 17:18
Date QC
Analyzed
Instrument
Anaiyst
Batch
Sampled: 08/04/08 09:30
08/06/08 15:04 MSA
AA
8H07011
08/06/08
15
:04
MSA
AA
8H0701\
08/06/08 15:04 MSA
AA
8H07011
08106/08 15:04
MSA
AA
8H07011
08/06/08 15:04 MSA AA 8H07011
08/06/08 15:04
MSA AA
8H07011
08/06/08 15:04
MSA AA
8H07011
LRH
8/11/2019 Brimbal Ave. - Environmental Notification Form - 9.2.14 - Volume 2 of 2
http://slidepdf.com/reader/full/brimbal-ave-environmental-notification-form-9214-volume-2-of-2 485/798
TestAmerica
THE LEADER IN ENVJRONMEN'fAL
TESTING
1721 South Grand Avenue Santa Ana, CA 92705 • 714-258-8610 • F ax 714-258-0921
Griffin Engineering Group Beverly
100 Cummings Center Suite
2220
Beverly, MA 01915
Peter Flink
Work Order:
Project:
Project Number:
LRH0043
Brimbal Ave
[none]
Received: 08105108 I 0:00
Reported: 08118108 17:18
ANALYTICAL REPORT
Analyte
Sample
ID: LRH0043-04 (GP-26-
Air)
Data
Result Qualifiers
EPA T015 (Med-level)- Volatile
Organic
Compounds by GC/MS
Acetone
Benzene
Benzyl chloride
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone
(MEK)
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Dibromochloromethane
Chloroethane
Chloroform
Chloromethane
1,2-Dibromoethane (EDB)
I 2-Dichlorobenzene
1,3-Dichlorobenzene
I 4-Dichlorobenzene
Dichlorodiftuoromethane
I,
1-Dichloroethane
1,2-Dichloroethane
ds-1,2-Dichloroethene
trans-1,2-Dichloroethene
I,
1-Dichloroethene
1,2-Dichloropropane
cis-1,3-Dichloropropene
trans- ,3-Dichloropropene
1,2-Dichloro-1,1,2,2-tetrafluoroetbane
Ethylbenzene
4-Ethyltoluene
Hexachlorobutadiene
2-Hexanone
Methylene chloride
4-Methyl-2-pentanone (MIBK)
Styrene
I, I 2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,2,4-Trichlorobenzene
I, I, -Trichloroethane
I, 1,2-Trichloroethane
Trichloroetbene
NO
NO
NO
NO
NO
ND
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
21
NO
NO
11
NO
NO
NO
NO
NO
42
NO
NO
NO
NO
NO
NO
NO
NO
280
12
NO
NO
NO
9,0
Units
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
pphv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
"""
pbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
RL
20
5.9
20
3.9
3.9
7.8
20
20
3.9
3.9
3.9
7.8
3.9
7.8
3.9
3.9
3.9
3.9
3.9
3.9
3.9
3.9
3.9
3.9
5.9
3.9
3.9
3.9
3.9
3.9
7.8
20
3.9
20
3.9
3.9
3.9
3.9
9.8
3.9
3.9
3.9
10
o f
53
Date
Dilution Analyzed
Instrument
QC
Analyst Batch
Sampled:
0810410810:00
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
08106/08 15:39
08/06/08 15;39
08/06/08 15:39
08/06/08 15:39
08/06/08 15:39
08/06/08 15:39
08/06/0815:39
08/06/08 15:39
08/06/0815:39
08/06/08 15:39
08/06/08 15:39
08/06/08 15:39
08106/08 15:39
08/06/08 15;39
08/06/08 15:39
08/06/08 15:39
08/06/08 15:39
08/06/08 15:39
08/06/08 15:39
08/06/08 15:39
08/06/08 15:39
08/06/08 15:39
08/06/0815:39
08/06/08 15:39
08/06/08 15:39
08/06/08 15:39
08/06/08 15:39
08/06/08 15:39
08106/08 15:39
08/06/08 15:39
08/06/08 15:39
08/06/08 15:39
08/06/08 15:39
08/06/08 15:39
08/06/08 15:39
08/06/08 15:39
08/06/0815:39
08/06/08 15:39
08/06/0815:39
08/06/08 15:39
08/06/08 15:39
08/06/08 15:39
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
8H07011
8H07011
8H070ll
8H07011
8H070ll
8H070ll
8H07011
8H070ll
8H07011
8H07011
8H07011
8H07011
8H07011
8H07011
8H07011
8H07011
8H07011
8H07011
8H07011
8H07011
8H07011
8H07011
8H07011
8H07011
8H07011
8H07011
8H07011
8H070ll
8H07011
8H07011
8H07011
8H07011
8H07011
8H07011
8H07011
8H070ll
8H07011
8H070ll
8H07011
8H07011
8H07011
8H07011
LRH
8/11/2019 Brimbal Ave. - Environmental Notification Form - 9.2.14 - Volume 2 of 2
http://slidepdf.com/reader/full/brimbal-ave-environmental-notification-form-9214-volume-2-of-2 486/798
TestAmerica
THE LEADER
IN
ENVIRONMENTAL
TESTING
1721 South Grand Avenue Santa Ana, CA 92705 • 714-258-8610 *Fax 714-258..-0921
Griffin E n g ~ e e r i n g Group Beverly
100 Cummings Center Suite 2220
Beverly,
MA
01915
Peter Flink
Analyte
Result
Sample ID: LRH0043-04
(GP-26-
Air)- cont.
Work Order: LRH0043
Project: Brimbal Ave
Project Number: [none]
ANALYTICAL
REPORT
Data
Qualifiers Units
RL
Dilution
EPA
TOtS
(Med-level)- Volatile Organic Compounds by GC/MS- cont
Trichlorofluoromethane NO ppbv 3.9
2.0
I,
1,2-T richloro-1,2,2-trifluoroethane
NO
ppbv
3.9 2.0
I ,2,4-Trimethylbenzene NO
pplw 5.9 2.0
1,3,5-T
rimethylbenzene NO
ppbv
5.9 2.0
Vinyl acetate NO
ppbv 20 2.0
Vinyl chloride
NO
ppbv
5.9 2.0
Xylenes, total 6.2
ppbv
3.9
2.0
11 o f 53
Received: 08105108 I 0:00
Reported: 0811810817: 8
Date QC
Analyzed Instrument Analyst
Batch
Sampled: 08104108 10:00
08106/08 15:39
MSA AA
8H07011
08/06/08 15:39 MSA AA
8H07011
08/06/0815:39
MSA AA
8H07011
08/06/08 15:39
MSA
AA
8H07011
08/06/08 15:39 MSA AA
8H07011
08/06/08 15:39
MSA AA
8H07011
08/06/08 15:39
MSA
AA 8H0701l
LRH
8/11/2019 Brimbal Ave. - Environmental Notification Form - 9.2.14 - Volume 2 of 2
http://slidepdf.com/reader/full/brimbal-ave-environmental-notification-form-9214-volume-2-of-2 487/798
TestAmerica
THE LEADER IN E N V I R O N M ~ N T A L TESTING
1721 South Grand Avenue Santa Ana, CA 92705 • 714-258-8610 • Fax 714-258-0921
Griffin Engineering Group Beverly
100 Cummings Center Suite
2220
Beverly, MA 01915
Peter Flink
Work Order:
Project:
Project Number:
LRH0043
Brimbal Ave
[none]
Received: 08/05/08 10:00
Reported: 08/18/08 17:18
ANALYTICAL REPORT
Analyte
Sample ID: LRH0043-05
(GP-20-
Air)
Data
Result Qualifiers
EPA
TOIS
(Med-level)- Volatile Organic Compounds by GC/MS
Acetone
Benzene
Benzyl chloride
Bromodichloromethane
Bromofonn
Bromomethane
2-Butanone (MEK)
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Dibromochloromethane
Chloroethane
Chloroform
Chloromethane
1 2-Dibromoethane (EDB )
1,2-Dichlorobenzene
1 , 3 ~ D i c h l o r o b e n z e n e
I, ~ D i c h l o r o b e n z e n e
Dichlorodifluoromethanc
1,1-Dichloroethane
1,2-Dichloroethane
cis- 2-Dichloroethene
trans- ,2-Dichloroethene
I, 1-Dichloroethene
1,2-Dichloropropane
cis- I 3-Dich\oropropene
trans- 3-Dichloropropene
I 2-Dichloro-1, 1,2,2-tetrafluoroethane
Ethylbenzeoe
4-Ethy\toluene
Hexach1orobutadiene
2-Hexanone
Methylene
chloride
4-Methyl-2-pentanone (MIBK)
Styrene
I, I 2,2-Tetrachloroethane
T etrachloroethene
Toluene
1,2,4-Trich\orobenzene
I, l,l-Trichloroethane
1, 1,2-Trichloroethane
Trichloroethene
19
14
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
2.4
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
65
2.6
NO
NO
NO
NO
4.0 JA
NO
NO
14
NO
NO
NO
NO
Units
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
·
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
RL
10
3.0
10
2.0
2.0
4.0
10
10
2.0
2.0
2.0
4.0
2.0
4.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
3.0
2.0
2.0
2.0
2.0
2.0
4.0
10
2.0
10
2.0
2.0
2.0
2.0
5.0
2.0
2.0
2.0
12
o f
53
Date
Dilution Analyzed
Instrument
QC
Analyst Batch
Sampled: 08/04/08 10:05
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
08/07/08
05:28
08/07/08 05:28
08/07/08
05:28
08/07/08 05:28
08107/08 05:28
08/07/08 05:28
08/07/08 05:28
08/07/08 05:28
08/07/08 05:28
08/07/08 05:28
08/07/08 05:28
08/07/08 05:28
08/07/08
05:28
08/07/08 05:28
08/07/08 05:28
08107/08 05:28
08107/08 05:28
08/07/08'05:28
08/07/08 05:28
08/07/08 05:28
08/07/08
05:28
08/07/08 05:28
08/07/08
05:28
08/07/08
05:28
08/07/08 05:28
08107/08
05:28
08/07/08 05:28
08107/08 05:28
08107/08 05:28
08/07/08 05:28
08107/08
05:28
08/07/08 05:28
08/07/08 05:28
08/07/08 05:28
08/07/08 05:28
08107/08
05:28
08/07/08 05:28
08107/08
05:28
08107/08 05:28
08/07/08 05:28
08107/08 05:28
08107/08 05:28
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
8H07012
8H07012
8H07012
8H07012
8H07012
8H07012
8H07012
8H07012
8H07012
8H07012
8H07012
8H07012
8H07012
8H07012
8H07012
8H07012
8H07012
8H07012
8H07012
8H07012
8H07012
8H07012
8H070l2
8H07012
8H07012
8H07012
8H07012
8H07012
8H07012
8H07012
8H07012
8H07012
8H07012
8H07012
8H07012
8H07012
8H07012
8H07012
8H07012
8H07012
8H07012
8H07012
LRH
8/11/2019 Brimbal Ave. - Environmental Notification Form - 9.2.14 - Volume 2 of 2
http://slidepdf.com/reader/full/brimbal-ave-environmental-notification-form-9214-volume-2-of-2 488/798
TestAmerica
THE LEADER
IN ENVIRONMENTAL
TESTING
1721 South Grand Avenue Santa Ana, CA 92705 • 714-258-8610 • Fax 714-258-0921
Griffin Engineering Group Beverly
100 Cummings Center Suite
2220
Beverly, MA 01915
Peter Flink
Analyte
Result
Sample ID: LRH0043-05
(GP-20- A;r)-
cont.
Work Order: LRH0043
Project: Brimbal Ave
Project Number: [none]
ANALYTICAL REPORT
Data
Qualifiers
Units
RL
Dilution
EPA
T015
(Med-level)- Volatile Organic Compounds by GC/MS- cont.
Trichlorofluoromethane
NO
ppbv 2.0
1.0
I, 1,2-T richloro-1,2,2-trifluoroethane
NO
ppbv 2.0
1.0
1,2,4-Trimethy\benzcne NO ppbv
3.0
1.0
1,3,5-Trimethylbenzene NO
ppbv 3.0
1.0
Vinyl acetate NO
ppbv
10
1.0
Vinyl chloride
44
ppbv
3.0 1.0
Xylenes, to tal 12
ppbv
2.0
1.0
13
o f
53
Received: 08/05/08 10:00
Reported: 08/18/08 17:18
Date QC
Analyzed
Instrument
Analyst
Batch
Sampled: 08/04/08 I 0:05
08/07/08 05:28 MSA
AA
8H07012
08/07/08 05:28
MSA
AA
8H07012
08107/08 05:28 MSA
AA
8H07012
08/07/08 05:28
MSA
AA
8H07012
08107/08 05:2 8 MSA
AA
8H07012
08107/08 05:2 8
MSA AA
8H07012
08/07/08 05:28
MSA AA
8H07012
LRH0
8/11/2019 Brimbal Ave. - Environmental Notification Form - 9.2.14 - Volume 2 of 2
http://slidepdf.com/reader/full/brimbal-ave-environmental-notification-form-9214-volume-2-of-2 489/798
TestAmerica
Tf-<E LE:ADER IN ENVIRONMENTAL T£STING
1721 South Grand Avenue Santa Ana, CA 92705 • 714-258-8610 • Fax 714-258-0921
Griffin Engineering Group Beverly
IOO
Cummings Center Suite 2220
Beverly, MA 01915
Peter Flink
Work Order:
Project
Project Number:
LRH0043
BrimbalAve
[none]
Received: 08/05108 I 0:00
Reported: 08/1810817:18
ANALYTICAL REPORT
Analyte
Sample ID: LRH0043-06 (GP-6R- Air)
Data
Result Qualifiers
EPA TOtS (Med-level)- Volatile Organi c Compounds by GC/MS
Acetone
Benzene
Benzyl chloride
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Dibromoch\oromethane
Chloroethane
Chloroform
Chloromethane
1,2-Dibromoethane (EDB)
1,2-Dichlorobenzene
1 3-Dichlorobenzene
1 4-Dichlorobenzene
DichlorodiOuoromethane
I,
1-Dichloroethane
1,2-Dichloroethane
cis-1,2-Dichloroethenc
trans-I 2-Dichloroethene
I, 1-Dichloroethene
1,2-Dichloropropane
cis-1,3-Dichloropropene
trans- ,3-Dichloropropene
I ,2-Dichloro-1,1,2,2-tetrafluoroethane
Ethylbenzene
4-IUhyltoluene
Hexachlorobutadiene
2-Hexanone
Methylene chloride
4-Methyl-2-pentanone (MIBK)
Styrene
I, 1,2,2-Tetrachloroet hane
T etrachloroethene
Toluene
1,2,4-Trichlorobenzene
I, 1,1-Trichloroethane
I, 1 2-Trichloroethane
Trichloroethene
16
28
NO
NO
NO
NO
NO
NO
NO
2.2
NO
NO
8.1
NO
NO
NO
NO
NO
4.0
NO
NO
7.2
NO
NO
NO
NO
NO
3.5
7.1
2.2
NO
NO
NO
NO
4.2 JA
NO
NO
19
NO
NO
NO
NO
Units
ppbv
ppbv
ppb'
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
RL
10
3.0
10
2.0
2.0
4.0
10
10
2.0
2.0
2.0
4.0
2.0
4.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
3.0
2.0
2.0
2.0
2.0
2.0
4.0
10
2.0
10
2.0
2.0
2.0
2.0
5.0
2.0
2.0
2.0
14
o f 53
Date
Dilution Analyzed
Instrument
QC
Analyst Batch
Sampled: 08/04/08 0:38
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
08/07/0806:11
08/07/0806:11
08/07/08 06: II
08/07/0806:11
08/07/08 06: I I
08/07/08 06:
II
08/07/08 06:
II
08/07/08 06: II
08/07/08 06: II
08/07/0806:11
08/07/08 06:11
08/07/08 06:11
08/07/0806:11
08/07/08 06:11
08/07/08 06:11
08/07/0806:11
08/07/0806:11
08/07/0806:11
08/07/08 06:
II
08/07/0806:11
08/07/08 06: II
08/07/08 06: II
08/07/0806:11
08/07/0806:11
08/07/0806:11
08/07/0806:11
08/07/08 06:ll
08/07/08 06:11
08/07/0806:11
08/07/0806:11
08/07/08 06:11
08/07/08 06:11
08/07/0806:11
08/07/0806:11
08/07/08 06:11
08/07/0806:11
08/07/08 06: II
08/07/08 06: II
08/07/0806:11
08/07/08 06: II
08/07/0806:11
08/07/0806:11
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
'MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
8H07012
8H07012
8H07012
8H07012
8H07012
8H07012
8H07012
8H07012
8H07012
8H07012
8H07012
8H07012
8H07012
8H07012
8H07012
8H07012
8H07012
8H07012
8H07012
8H07012
8H07012
8H07012
8H07012
8H07012
8H07012
8H07012
8H07012
8H07012
8H070l2
8H07012
8H07012
8H07012
8H07012
8H07012
8H07012
8H07012
8H07012
8H07012
8H07012
8H07012
8H07012
8H07012
LRH
8/11/2019 Brimbal Ave. - Environmental Notification Form - 9.2.14 - Volume 2 of 2
http://slidepdf.com/reader/full/brimbal-ave-environmental-notification-form-9214-volume-2-of-2 490/798
Test
America
THE
LEADE'fl N
ENVIRONME'NTAL
tESTING
1721 South Grand Avenue Santa Ana, CA 92705 • 714-258-8610 • Fax 714-258-0921
Griffin Engineering Group Beverly
I00 Cummings Center Suite 222G
Beverly, MA 01915
Peter Flink
Analyte
Result
Sample ID: LRH0043-06 (GP-6R-
Ak)-
cont.
Work Order:
LRH0043
Project:
Brimbal Ave
Project Number; [none]
ANALYTICAL
REPORT
Data
Qualifiers
Units
RL
Dilution
EPA
T015 (Med-Jevel)- Volatile
Organic
Compounds
by
GC/MS- cont.
Trichlorofluoromethane ND
ppbv 2.0
1.0
I, I 2-Trichloro-1 ,2,2-trifluoroethane
ND ppbv
2.0
1.0
1,2,4-Trimelhylbenzene ND
ppbv 3.0
1.0
1,3,5-Trimethylbenzene
ND
ppbv 3.0 1.0
Vinyl acetate ND
ppbv 10
1.0
Vinyl chloride
48
ppbv
3.0
1.0
Xylenes, total 17
ppbv 2.0 1.0
15
of
53
Received: 08/05/08 10:00
Reported: 08/18/08 17:18
Date
QC
Analyzed
Instrument
Analyst
Batch
Sampled: 08/04/08 10:38
08/07/0806:11 MSA
AA
8H07012
08/07/0806:11
MSA
AA
8H07012
08/07/0806:11
MSA
AA
8H07012
08/07/08 06:11
MSA AA
8H07012
08/07/08 06:11
MSA AA
8H07012
08/07/08 06:11
MSA AA
8H07012
08/07/08 06:11 MSA
AA
8H07012
LRH
8/11/2019 Brimbal Ave. - Environmental Notification Form - 9.2.14 - Volume 2 of 2
http://slidepdf.com/reader/full/brimbal-ave-environmental-notification-form-9214-volume-2-of-2 491/798
Test
America
THE: LE:ADE:R IN
ENVIRONMENTAl TESTING
Griffin Engineering Group Beverly
I00 Cwnmings Center Suite 2220
Beverly,
MA
01915
Peter Flink
1721 South Grand Avenue Santa Ana, CA 92705 * 714-258-8610 • Fax 714-258-0921
Work Order:
Project:
Project Number:
LRH0043
Brimbal Ave
[none]
ANALYTICAL REPORT
Received: 08/05/08
IO:Oo'
Reported: 08/18/08 17:18
Analyte
Data
Result Qualifiers Units
RL
Date
Dilution Analyzed
Instrument
QC
Analyst Batch
Sample ID: LRH0043-07 (GP-llR- Air)
EPA
T O t ~
(Med-level)- Volatile
Organic
Compounds by GC/MS
Acetone
Benzene
Benzyl chloride
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Dibromochloromethane
Chloroethane
Chloroform
Chloromethane
1,2-Dibromoethane (EDB)
1,2-J:: ichlorobenzene
1,3-Dichlorobenzene
I 4-Dichloroberu:ene
Dichlorodifluoromethane
1,1-Dichloroethane
I 2-Dichloroethane
cis- 2-Dichloroethene
trans-1,2-Dichloroethene
I, 1-Dichloroethene
1,2-Dichloropropane
cis- ,3-Dichloropropene
trans- ,3-Dich oropropene
1.2-Diehloro-1,1,2,2-tetrafluoroethane
Ethyl benzene
4-Ethyltoluene
Hexachlorobutadiene
2-Hexanone
Methylene chloride
4-Methyl-2-pentanone(MIBK)
Styrene
I, I 2,2-Tetrachloroethane
T etrachloroeth ene
Toluene
1,2,4-Trichloroben;zene
I, 1,1-Trichloroethane
I, 1,2-TrichloroethMe
Trichloroethene
ND RL2
7,6 RL2
ND
RL2
ND RL2
ND
RL2
ND
RL2
ND RL2
NO RL2
NO RL2
ND RL2
NO RL2
ND RL2
ND RL2
ND ·RL2
ND RL2
ND RL2
ND RL2
ND
RL2
ND RL2
ND
RL2
ND RL2
ND RL2
ND
RL2
NO
RL2
ND RL2
ND RL2
NO RL2
21 RL2
7.8 RL2
6.3 RL2
ND
RL2
ND RL2
ND RL2
ND RL2
ND RL2
ND RL2
ND RL2
15 RL2
ND
RL2
ND RL2
ND
RL2
ND RL2
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
20
6.0
20
4.0
4.0
8.0
20
20
4.0
4.0
4.0
8.0
4.0
8.0
4.0
4.0
4.0
4.0
4.0
4.0
4.0
4.0
4.0
4.0
6.0
4.0
4.0
4.0
4.0
4.0
8.0
20
4.0
20
4.0
4.0
4.0
4.0
10
4.0
4.0
4.0
16
o f 53
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
Sampled: 08/04/08 I 0:25
08/0.7/08 06:56
08/07/08
06:56
08/07/08
06:56
08107/08 Q6:56
08/07/08
06:56
08/07/08 06:56
08107/08 06:56
08/07/08 06:56
08/07/08 06:56
08/07/08 06:56
08/07/08 06:56
08/07/08 06:56
08/07/08 06:56
08/07/08 06:56
08/07/08 06:56
08/07/08 06:56
08/07/08 06:56
08/07/08 06:56
08/07/08 06:56
08/07/08
06:56
08/07/08
06:56
08107/08
06:56
08/07/08
06:56
08107/08 06:56
08/07/08 06:56
08107/08
06:56
08107/08 06:5 6
08/07/08 06:56
08/07/08 06:56
08/07/08 06:56
08/07/08 06:56
08/07/08 06:56
08/07/08 06:56
08/07/08 06:56
08/07/08 06:56
08/07/08 06:56
08/07/08 06:56
08/07/08 06:56
08/07/08 06:56
08/07/08 06:56
08/07/08 06:56
08/07/08 06:56
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
8H07012
8H07012
8H07012
8H07012
8H07012
8H07012
8H07012
8H07012
8H07012
8H07012
8H07012
8H07012
8H07012
8H07012
8H07012
8H07012
8H07012
8H07012
8H07012
8H07012
8H07012
8H07012
8H07012
8H07012
8H07012
8H07012
8H07012
8H07012
8H07012
8H07012
8H07012
8H07012
8H07012
8H07012
8H07012
8H07012
8H07012
8H07012
8H07012
8H07012
8H07012
8H07012
LRH0
8/11/2019 Brimbal Ave. - Environmental Notification Form - 9.2.14 - Volume 2 of 2
http://slidepdf.com/reader/full/brimbal-ave-environmental-notification-form-9214-volume-2-of-2 492/798
TestAmerica
THE LEADER
IN ENVIRONMENTAL T ~ S T I N G
1721 South Grand Avenue Santa Ana, CA 92705 • 714-258-8610 • Fax 714-258-0921
Work Order: LRH0043
Received:
08105108
10:00
Reported: 08118108 17:18
Griffin Engineering Group Beverly
100 Cummings Center Suite 222G
Beverly, MA 01915
Project: Brimbal Ave
Peter Flink
Project Ntunber: [none]
ANALYTICAL
REPORT
Data
Analyte
Result Qualifiers Units
RL
Sample ID: LRH0043-07 (GP-IIR-
Air)-
cont.
EPA
T015 M e d ~ l e v e l )
~ V o l a t i l e Organic
Compounds
by GC/MS- cont.
Trichlorofluoromethane
ND
RL2
ppbv
4.0
1,1 ,2-Trichloro-1 ,2,2-trifluoroethane ND
RL2
ppbv 4.0
1,2,4-
Trimethylbenzene
9.9
RL2
ppbv
6.0
1,3,5-Trimethy\benzene ND RL2
ppbv
6.0
Vinyl acetate
ND
RL2
ppbv
20
Vinyl chloride NO RL2
ppbv 6.0
Xylenes, total 17 RL2
ppbv 4.0
17
o f 53
Date
Dilution Analyzed
Instrument
QC
Analyst Batch
Sampled: 08/04/08 10:25
2.0 08/07/08 06:56
MSA AA
8H07012
2.0 08/07/08 06:56
MSA AA
8H070l2
2.0 08/07/08 06:56
MSA
AA
8H07012
2.0 08/07/08 06:56
MSA AA
8H07012
2.0 08/07/0 8 06:56
MSA
AA
8H07012
2.0 08/07/08 06:56
MSA
AA
8H07012
2.0
08/07/08 06:56
MSA
AA
8H07012
LRH
8/11/2019 Brimbal Ave. - Environmental Notification Form - 9.2.14 - Volume 2 of 2
http://slidepdf.com/reader/full/brimbal-ave-environmental-notification-form-9214-volume-2-of-2 493/798
Test
America
THE LEADER
IN ENVIRONMENoAL
TE:SOING
1721 South Grand Aven ue Santa Ana, CA 92705 • 714-258-8610 • Fa x 714-258-0921
Griffin Engineering Group Beverly
100 Cummings Center Suite 222G
Beverly, MA 01915
Peter Flink
Work Order:
Project:
Project Number:
LRH0043
Brimbal Ave
[none]
Received: 08/05/08 10:00
Reported: 08/18108 17:18
ANALYTICAL
REPORT
Analyte
Sample
10:
LRH0043-08
(GP-12-
Air)
Data
Result Qualifiers
EPA TO IS (Med-level)- Volatile Organic Compounds by GC/MS
Acetone
Benzene
Benzyl chloride
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone
(MEK)
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Dibromochloromethane
Cbloroethane
Chloroform
Chloromethane
1,2-Dibromoethane (EDB)
1,2-Dich\orobenzene
I 3-Dicblorobenzene
I 4 ~ D i c h l o r o b e n z e n e
Dichlorodi fluoromethane
I,
1-Dichloroethane
1 . 2 ~ D i c h l o r o e t h a n e
cis- 2-Dichloroethene
trans-1,2-Dichloroethene
I, 1- Dichloroethene
1,2-Dichloropropane
cis- ,3-Dichloropropene
trans-1,3-Dichloropropene
I 2-Dichloro-1, I 2,2-tetrafluoroethane
Ethylbenzene
4-Ethyltoluene,
Hexachlorobutadiene
2-Hexanone
Methylene chloride
4-Methy1-2-pentanone (MIBK)
Styrene
I, 1,2,2-Tetrachloroethane
T etrachloroethene
Toluene
1,2,4-Trichlorobenzene
I, 1, 1-Trichloroethane
I, 1,2-Trichloroethane
Trichloroethene
20
31
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
63
23
ND
ND
2.5
ND
2.7
ND
ND
15
ND
ND
ND
ND
Units
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
pplw
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
RL
10
3.0
10
2.0
2.0
4.0
10
10
2.0
2.0
2.0
4.0
2.0
4.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
3.0
2.0
2.0
2.0
2.0
2.0
4.0
10
2.0
10
2.0
2.0
2.0
2.0
5.0
2.0
2.0
2.0
18
o f 53
Date
Dilution Analyzed
Instrument
QC
Analyst Batch
Sampled: 08104/08 10:18
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
08/07/08 15:46
08/07/08 15:46
08/07/08 15:46
08107/08 15:46
08107/08 15:46
08/07/08 15:46
08107/0815:46
08/07/08 15:46
08/07/08 15:46
08/07/08 15:46
08/07/08 15:46
08/07/08 15:46
08/07/08 15:46
08/07/08 15:46
08/07/08 15:46
08/07/08 15:46
08/07/08 15:46
08/07/08 15:46
08/07/08 15:46
08/07/08 15:46
08/07/08 15:46
08/07/08 15:46
08/07/08 15:46
08/07/08 15:46
08/07/08 15:46
08/07/08 15:46
08107/08 15:46
08/07/08 15:46
08107/08 15:46
08/07/08 15:46
08107/08 15:46
08107/0815:46
08/07/08 15:46
08/07/0815:46
08/07/08 15:46
08/07/08 15:46
08/07/08 15:46
08/07/08 15:46
08/07/08 15:46
08/07/08 15:46
08107/08 15:46
08/07/08 15:46
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
. MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
8H08008
8H08008
8H08008
8H08008
8H08008
8H08008
8H08008
8H08008
8H08008
8H08008
8H08008
8H08008
8H08008
8H08008
8H08008
8H08008
8H08008
8H08008
8H08008
8H08008
8H08008
8H08008
8H08008
8H08008
8H08008
8H08008
8H08008
8H08008
8H08008
8H08008
8H08008
8H08008
8H08008
8H08008
8H08008
8H08008
8H08008
8H08008
8H08008
8H08008
8H08008
8H08008
LRH
8/11/2019 Brimbal Ave. - Environmental Notification Form - 9.2.14 - Volume 2 of 2
http://slidepdf.com/reader/full/brimbal-ave-environmental-notification-form-9214-volume-2-of-2 494/798
TestAmerica
THE
LEADER IN ENVIRONMENTAL
TE:STING
1721 South Grand Avenue Santa Ana, CA 92705 • 714-258-8610
·Fax
714-258-0921
Griffin Engineering Group Beverly
100 Cummings Center Suite
2220
Beverly, MA 01915
Peter Flink
Analyte
Result
SampleiD:
LRH0043-08
(GP-12- Air)- cont.
Work Order: LRH0043
Project Brimbal Ave
Project Number: [none]
ANALYTICAL REPORT
Data
Qualifiers
Units
RL
Dilution
EPA
TOlS
(Med-level)- Volatile Organic Compounds by GC/MS- cont.
Trichlorofluoromethane NO ppbv
2.0 1.0
I, I 2-Trichloro-1 ,2,2-trifluoroethane
NO ppbv
2.0 1.0
I ,2,4-Trimethylbenzene
5.8 ppbv 3.0
1.0
1,3,5-Trimethylbenzene
NO ppbv 3.0 1.0
Vinyl acetate NO ppbv
10 1.0
Vinyl chloride
NO
ppbv
3.0 1.0
Xylenes, total 13
ppbv
2.0 1.0
19
o f
53
Received: 08/05/08 10:00
Reported: 08/18/08 17:18
Date
QC
Analyzed
Instrument Analyst Batch
Sampled: 08/04/08 10:18
08/07/08 15:46
MSA
AA
8H08008
08/07/08 15:46
MSA AA 8H08008
08/07/08 15:46 MSA
AA
8H08008
08107/08 15:46
MSA
AA 8H08008
08/07/08 15:46 MSA AA 8H08008
08107/08 15:46
MSA AA
8H08008
08/07/08 15:46
MSA
AA
8H08008
LRH
8/11/2019 Brimbal Ave. - Environmental Notification Form - 9.2.14 - Volume 2 of 2
http://slidepdf.com/reader/full/brimbal-ave-environmental-notification-form-9214-volume-2-of-2 495/798
TestAmerica
Tfl O
LEADf:R IN ENVIRONMENTAL
TESTING
Griffin Engineering Group Beverly
100
Cummings Center Suite 2220
Beverly, MA 01915
Peter Flink
Data
1721 South Grand Avenue Santa Ana, CA 92705 • 714-258-8610 • Fax 714-258-0921
Work Order:
Project:
Project Number:
LRH0043
BrimbalAve
[none]
ANALYTICAL REPORT
Received:
Reported:
08/05/08 10:00
08118/0817:18
Analyte
Result Qualifiers Units
RL
Date
Dilution Analyzed
Instrument
QC
Analyst Batch
Sample
ID: LRH0043-0l (GP-21 - Ak)
ASTM 01946
F i x e d
Gases
Carlron d i o ~ i d e
Carbon monoxide
Methane
Oxygen
Nitrogen
9.7
NO
6.0
l2
70
o/o(v/v) 0.020
%(v/v)
0.0020
o/<>(v/v) 0.00040
o/o(v/v)
0.40
%(v/v) 2.0
20 o f 53
Sampled:
08/04/08 09:16
2.0
08/06/08 10:24 GC8 El 8H07006
2.0 08/06/08 I 0:24
GC8 El
8H07006
2.0 08106/08 10:24
GC8 EI
8H07006
2.0 08106/08 10:24
GC8 El 8H07006
2.0
08/06/08 10:24
GC8
El
8H07006
LRH0
8/11/2019 Brimbal Ave. - Environmental Notification Form - 9.2.14 - Volume 2 of 2
http://slidepdf.com/reader/full/brimbal-ave-environmental-notification-form-9214-volume-2-of-2 496/798
TestAmerica
THE LEADER IN
ENVIRONMENTAL TESTING
Griffin Engineering Group Beverly
100 Cummings Center Suite 2220
Beverly, MA 01915
Peter Flink
1721 South Grand Avenue Santa Ana, CA 92705 • 714-256-8610 *Fax 714-258-0921
Work Order: LRH0043 Received: 08/05/08 10:00
Reported: 08/18/08 17:18
Project Brimbal Ave
Project Number: [none]
ANALYTICAL REPORT
Data Date
Analyte
Result Qualifiers Units
RL
Dilution Analyzed
Instrument
QC
Analyst Batch
Sample ID: LRH0043-02
(GP-25-
Air)
ASTM 01946- Fixed Gases
Carbon dioxide
Carbon monoxide
Methane
Oxygen
Nitrogen
9,6
o/o(v/v)
NO o/o(v/v)
0.23
%(v/v)
13
o/o(v/v)
75
%(v/v)
Sampled: 08/04/08 09:35
0.021 2.1 08/06/08 10:37 GC8
El
8H07006
0.0021
2.1 08/06/08 10:37
GC8
El
8H07006
0.00041 2.1 08/06/08 10:37
GC8
El 8H07006
0.41
2.1 08/06/08 10:37 GC8 El
8H07006
2.1
2.1 08/06/08 10:37
GC8
El
8H07006
21
o f 53 LRH
8/11/2019 Brimbal Ave. - Environmental Notification Form - 9.2.14 - Volume 2 of 2
http://slidepdf.com/reader/full/brimbal-ave-environmental-notification-form-9214-volume-2-of-2 497/798
TestAmerica
THE LEADER
IN
E'NVIRONMENTAL TESTING
Griffin Engineering Group Beverly
100
Cummings Center Suite 222G
Beverly, MA 01915
Peter Flink
Data
1721 South Gr and Avenue Santa Ana, CA 92705 • 714-258 -8610 • Fax 714-258-0921
Work Order: LRH0043 Received: 08/05/08 10:00
Reported: 08/18/0817:18
Project Brimbal Ave
Project Number: [none]
ANALYTICAL REPORT
Date
Analyte
Result Qualifiers Units
RL
Dilution Analyzed
Instrument
QC
Analyst Batch
Sample ID: LRH0043-03 (GP-14- Air)
ASTM D1946- Fixed Gases
Carbon dioxide
Carbon monoxide
Methane
Oxygen
Nitrogen
II
NO
25
1.3
60
%(v/v)
0.021
%(v/v)
0.0021
%(v/v)
0.00041
o/<>(v/v)
0.41
o/<>(v/v)
2.1
22
o f
53
Sampled: 08/04/08 09:30
2.1 08/06/08 10:50
GC8
El 8H07006
2.1 08/06 /08 10:50
GC8
El
8H07006
2.1
08/06/08 10:50 GCS
El 8H07006
2.1 08106/08 10:50 GC8 El
8H07006
2.1 08106/08 10:50
GC8
El
8H07006
LRH
8/11/2019 Brimbal Ave. - Environmental Notification Form - 9.2.14 - Volume 2 of 2
http://slidepdf.com/reader/full/brimbal-ave-environmental-notification-form-9214-volume-2-of-2 498/798
TestAmerica
THE
LEADER
IN
ENVIRONMENTAL
TESTING
Griffin Engineering Group Beverly
100 Cwnmings Center Suite 2220
Beverly, MA 01915
Peter Flink
1721 South Grand Avenue Santa Ana, CA 9270 5 * 714-258-8610 • Fax 714-258-0921
Work Order:
LRH0043 Received: 08/05/08 10:00
Reported: 0811810817:18
Project:
Brimbal Ave
Project Number: [none]
ANALYTICAL REPORT
Data
Date
Analyte
Result Qualifie rs Units
RL
Dilution Analyzed
Instrument
QC
Analyst Batch
Sample ID:
LRH0043-04 (GP-26-
Air)
ASTM Dl946- Fixed Gases
Carbon
dioxide
Carbon monoxide
Methane
Oxygen
Nitrogen
EPA 15/16- Sulfur Compounds
Carbon disulfide
Carbonyl sulfide
Dimethyl disulfide
Dimethyl sulfide
Hydrogen sulfide
Ethyl mercaptan
Methyl mercaptan
16
NO
0.027
77
NO
NO
NO
NO
NO
NO
NO
o/o(v/v)
0.020
%(v/v)
0.0020
%(v/v) 0.00039
'Yo(v/v)
0.39
%(v/v)
2.0
ppmv 0.025
ppmv 0.050
ppmv 0.025
PP'"'
0.050
ppmv
0.050
ppmv
0.050
ppmv 0.050
23 o f 53
Sampled:
08104108
10:00
2.0 08/06/08 II :04
GCS
EI
8H07006
2.0 08/06/08 II :04 GCS
EI
8H07006
2.0 08/06/08 II :04
GCS EI
8H07006
2.0 08/06/08 II :04 GCS
EI
8H07006
2.0 08/06/08
II
04 GCS EI
8H07006
1.0 08/06/08 07:44 GC1 TO 8H06002
1.0
08106/08 07:4 4 GC7
TO
8H06002
1.0 08106/08 07: 44
GC1
TO
8H06002
1.0
08106/08 07:44 GC7
TO
8H06002
1.0 08/06/08 07:44 GC1
TO
8H06002
1.0 08/06/08 07:44 GC7 TO
81-106002
1.0 08/06/08 07:44
GC7
TO
8H06002
LRH
8/11/2019 Brimbal Ave. - Environmental Notification Form - 9.2.14 - Volume 2 of 2
http://slidepdf.com/reader/full/brimbal-ave-environmental-notification-form-9214-volume-2-of-2 499/798
TestAmerica
THE LEADER
IN ENVIRONMENTAL
TE'STING
Griffin Engineering Group Beverly
100 Cummings Center Suite 2220
Beverly,
MA
01915
Peter Flink
1721 South Grand Avenue Santa Ana, CA 92705 714-258-8610 • Fax 714-258-0921
Data
Work Order:
Project:
Project Number:
LRH0043
Brimbal Ave
[none]
ANALYTICAL REPORT
Received:
Reported:
Date
08/05/08 10:00
08118/0817:18
Analyte
Result Qualifiers Units
RL
Dilution Analyzed
Instrument
QC
Analyst Batch
Sample
ID: LRH0043-05 (GP-20- Air)
ASTM 01946- Fixed Gases
Carbon dioxide
Carbon monoxide
Methane
Oxygen
Nitrogen
3.8 o/o(v/v)
NO o/o(v/v)
7.6 %(v/v)
14
%(v/v)
72
%(v/v)
Sampled:
08/04/08 10:05
0.020
2.0 08106/08 II: 17 GC8 EI
8H07006
0.0020 2.0 08106/08 II: 17
GC8
EI
8H07006
0.00041 2.0
08/06/0811:17
GC8 EI 8H07006
0.41 2.0 08/06/08 II: 17
GC8 EI 8H07006
2.0 2.0
08/06/08 11:17
GC8
EI 8H07006
24
o f 53
LRH0
8/11/2019 Brimbal Ave. - Environmental Notification Form - 9.2.14 - Volume 2 of 2
http://slidepdf.com/reader/full/brimbal-ave-environmental-notification-form-9214-volume-2-of-2 500/798
TestAmerica
THE:
LE:ADE:R
IN ENVIRONMENTAL TESTING
1721 South Grand Avenue Santa Ana, CA 92705 * 714-258-8610 • Fax 714-258-0921
Griffin Engineering Group Beverly
I
00
Cwnmings Center Suite
2220
Beverly, MA 01915
Peter Flink
Analyte
Sample ID: LRH0043-06
(GP-6R-
Air)
ASTM D1946- Fixed Gases
Carbon dioxide
Carbon monoxide
Methane
Oxygen
Nitrogen
EPA
15/16-Sulfur
Compounds
Carbon disulfide
Carbonyl sulfide
Dimethyl disulfide
Dimethyl sulfide
Hydrogen sulfide
Ethyl mercaptan
Methyl mercaptan
Work Order:
Project:
Project Number:
LRH0043
Brimbal Ave
[none]
ANALYTICAL REPORT
Data
Result Qualifiers
Units
RL
Date
Dilution Analyzed
Received: 08/05/08 10:00
Reported: 08/18/0817:18
Instrument
QC
Analyst Batch
Sampled: 08/04/08 10:38
13
%(v/v) 0.020
2.0
08/06/08
II
:34
GCS El
8H07006
ND o/o(v/v) 0.0020 2.0 08106/08 II :34 GC8
El
8H07006
8.4 %(v/v)
0.00040
2.0 08/06/08 II :34
GCS El
8H07006
2.1
o/n(v/v)
0.40 2.0 08/06/08 II :34
GC&
El
8H07006
74
o/o{v/v)
2.0 2.0 08/06/08 11:34
GCS
El 8H07006
ND
ppm'
0.025 1.0 08/06/08 08:09
GC7
TD
8H06002
ND
ppmv 0.050
1.0 08/06/08 08:09
GC7
TD
8H06002
ND
ppm'
0.025
1.0
08/06/08 08:09
GC7
TD
8H06002
ND
ppmv 0.050
1.0 08/06/08 08:09 GC7
TD
8H06002
4.2
ppmv 0.25 5.0 08/06/08 08:32 GC7
TD
8H06002
ND
ppmv 0.050
1.0 08/06/08 08:09
GC7
TD
8H06002
ND
ppmv
0.050
1.0 08/06/08 08:09
GC?
TD
8H06002
25
of
53
LRH
8/11/2019 Brimbal Ave. - Environmental Notification Form - 9.2.14 - Volume 2 of 2
http://slidepdf.com/reader/full/brimbal-ave-environmental-notification-form-9214-volume-2-of-2 501/798
TestAmerica
THE tEADEiliN ENVIRONMENTAl TESTING
Griffin Engineering Group Beverly
100 Cummings Center Suite 2220
Beverly, MA 01915
Peter Flink
1721 South Grand Ave,nue Santa Ana, CA 92705 714-258-8610* Fax 714-258-0921
Data
Work Order:
Project:
Project
Number:
LRH0043
Brimbal Ave
[none}
ANALYTICAL REPORT
Received: 08/05/08 10:00
Reported:
08/18/08 17:18
Analyte
Result Qualifiers Units
RL
Date
Dilution Analyzed
Instrument
QC
Analyst Batch
Sample ID: LRH0043-07
(GP-IIR-
Air)
ASTM 01946- Fixed Gases
Carbon dioxide
Carbon monoxide
Methane
Oxygen
Nitrogen
11 %(v/v)
NO
%(v/v)
13 %(v/v)
2.1
%(v/v)
72
"%(v/v)
Sampled: 08/04/08 10:25
0.020 2.0 08/06/08 II :50 GCS
EI
8H07006
0.0020
2.0
08/06/08 11:50
GC8
EI
8H07006
0.00040 2.0 08/06/08 ll:SO GC8
EI
8H07006
0.40
2.0 08106/08 II
:50
GC8 El
SH07006
2.0 2.0 08106/08
II
:50 GC8
El
8H07006
26
o f 53
LRH
8/11/2019 Brimbal Ave. - Environmental Notification Form - 9.2.14 - Volume 2 of 2
http://slidepdf.com/reader/full/brimbal-ave-environmental-notification-form-9214-volume-2-of-2 502/798
TestAmerica
THE LEAOE:R
IN
ENVIRONMENTAL TESTING
Griffin Engineering Group Beverly
I 00 Cummings Center Suite
2220
Beverly,
MA
0 915
Peter Flink
1721 South Grand Avenue Santa Ana, CA 92705 • 714-258-8610
*Fax
714-258-0921
Work Order: LRH0043
Received: 08/05/08 I 0:00
Reported: 08/18/08 17: 18
Project Brimbal Ave
Project Number: [none]
ANALYTICAL REPORT
Data
Date
Analyte
Result Qualifiers Units
RL
Dilution Analyzed
Instrument
QC
Analyst Batch
Sample
ID: LRH0043-08
(GP-12-
Air)
ASTM
01946- Fixed Gases
Carbon
dioxide
Carbon monoxide
Methane
Oxygen
Nitrogen
7,4
%(v/v)
NO %(v/v)
NO o/o(v/v)
15
o/o(v/v)
75
o/o(v/v)
Sampled: 08/04/0810:18
0.022
2.2 08106/08 12:03
GC8 EI 8H07006
0.0022
2.2
08106/08 12:03
GC8
EI 8H07006
0.00044
2.2 08/06/08 12:03
GC8
EI 8H07006
0.44 2.2 08106/08 12:03
GC8
EI 8H07006
2.2 2.2
08/06/08 12:03
GC8
EI
SH07006
27
o f
53
LRH
8/11/2019 Brimbal Ave. - Environmental Notification Form - 9.2.14 - Volume 2 of 2
http://slidepdf.com/reader/full/brimbal-ave-environmental-notification-form-9214-volume-2-of-2 503/798
TestAmerica
THE:
UocADE:R
IN E:NVIRONM ;NTAL
TESTING
1721 South Grand Avenue Santa Ana, CA 92705 714-258-8610* Fax 714-258-0921
Griffin Engineering Group Beverly
100 Cummings Center Suite 2220
Beverly, MA 01915
Peter Flink
Analyte Result
Sample 10: 8H07011-BLKI (Blank- Air)
Work Order:
Project:
Project Number:
LRH0043
Brimbal Ave
[none]
PROJECT QUALITY CONTROL DATA
Data
Qualifier
Units
Blank
Date
RL
Dilution Analyzed
EPA TOtS (Med-level)- Volatile Organic Compounds by GC/MS
Acetone
Benzene
Benzyl chloride
Bromodichloromethane
Bromofonn
Bromomethane
2-Butanone (MEK)
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Dibromochloromethane
Chloroethane
Chlorofom1
Chloromethane
1,2-Dibromoethane (EDB)
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
I,
1-Dichloroethane
1,2-Dichloroethane
cis-1,2-Dichloroethene
trans-\ ,2-Dichloroethene
1,
1-Dichloroethene
I 2-Dichloropropane
cis- ,3-Dichloropropene
trans- ,3-Dichloropropene
I 2-Dichloro-1, 1,2,2 -tetrafluoroethane
Ethyl benzene
4-Ethyltoluene
Hexachlorobutadiene
2-Hexanone
Methylene chloride
4-Methyl-2-pentanone (MIBK)
Styrene
l, 1,2,2-Tetrachloroethane
T etrachloroethene
NO
ND
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
lO
3.0
lO
2.0
2.0
4.0
lO
lO
2.0
2.0
2.0
4.0
2.0
4.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
3.0
2.0
2.0
2.0
2.0
2.0
4.0
lO
2.0
lO
2.0
2.0
2.0
28
o f 53
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
LOO
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
08/06/08 II :47
08/06/08 ll:47
08/06/08
11
:4 7
08/06/08 I I 4 7
08/06/08 II :4 7
08/06/08 II :4 7
08/06/08 11:47
08/06/08
ll:47
08/06/08 11:47
08/06/08 11:47
08/06/08 11:47
08/06/08 11:47
08/06/08 11:47
08/06/08 11:47
08/06/08 11:47
08/06/08 11:47
08/06/08 11:47
08/06/08 11:47
08/06/08 11:47
08/06/08 11:47
08/06/08 11:47
08/06/08 11:47
08/06/08 11:47
08/06/08 II 4 7
08/06/08 I I 47
08/06/08 11:47
08/06/08 11:47
08/06/08 11:47
08/06/08 ll:47
08/06/08 11:47
08/06/08 11:47
08/06/08 11:47
08/06/08 11:47
08/06/08 11:47
08/06/08 11:47
08/06/08 11:47
08/06/08 11:47
Received:
08105108
10:00
Reported: 08118108 17:18
Instrument Analyst
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
QC
Batch
8H070ll
8H07011
8H07011
8H07011
8H07011
8H070ll
8H07011
8H07011
8H070ll
8H07011
8H070ll
8H07011
8H0701\
8H070ll
8H07011
8H07011
8H07011
8H07011
8H07011
8H07011
8H070ll
8H07011
8H07011
8H070ll
8H07011
8H07011
8H07011
8H07011
8H07011
8H07011
8H07011
8H07011
8H07011
8H07011
8H07011
8H07011
8H070ll
LRH0
8/11/2019 Brimbal Ave. - Environmental Notification Form - 9.2.14 - Volume 2 of 2
http://slidepdf.com/reader/full/brimbal-ave-environmental-notification-form-9214-volume-2-of-2 504/798
Test
America
TH : L ':AOE:R IN ENVIRONMENTAL T ':ST NG
1721 South Grand Avenue Santa Ana, CA 92705 • 714-258-8610 ~ F a x 714-258-0921
Griffin Engineering Group Beverly
100 Cummings Center Suite 222G
Beverly,
MA
01915_
Peter Flink
Work Order:
Project:
Project Number:
LRH0043
Brimba Ave
[none]
PROJECT
QUALITY CONTROL DATA
Blank- Cont.
Date
Analyte Result
Data
Qualifier
Units RL
Dilution Analyzed
Sample ID: 8H07011-BLK1
(Blank- Air)-
cont.
EPA
TO
IS (Med-level)- Volatile Organic Compounds by GC/MS
Toluene
I 2,4-Trich\orobenzene
l, I, 1-Trichloroethane
I, 1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
I, I 2-T richloro-1 ,2,2-trifluoroethane
I ,2,4-Trimethylb enzene
1,3,5-Trimethylbenzene
Vinyl acetate
Vinyl chloride
Xylenes, total
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Sample ID: 8H07012-BLK1
(Blank-
Air)
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
EPA
T015
(Med-level)- Volatile Organic
Compounds
by
GC/MS
Acetone
Benzene
Benzyl chloride
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon disulfide
Carbon tetrachloride
Chi oro benzene
Dibromochloromethane
Chloroethane
Chloroform
Chloromethane
1,2-Dibromoethane (E DB)
I 2-Dichlorobenzene
I ,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
2.0
5.0
2.0
2.0
2.0
2.0
2.0
3.0
3.0
10
3.0
2.0
10
3.0
10
2.0
2.0
4.0
10
10
2.0
2.0
2.0
4.0
2.0
4.0
2.0
2.0
2.0
2.0
2.0
2.0
29
o f 53
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
08/06/08 II :47
08/06/08 I I 47
08/06/08 II :4 7
08/06/08 11:47
08/06/08 11:47
08106/08 11:47
08106/08 11:47
08106/08
I I
4 7
08106/08 11:47
08106/08 l1:47
08106/08 11:47
08106/08 I I 47
08/07/08 2:53
08/07/08 2:53
08/07/08 2:53
08/07/08 2:53
08/07/08 2:53
08107/08 2:53
08.(07/08 2:53
08107/08 2:53
08107/08 2:53
08107/08 2:53
08/07/08 2:53
08/07/08 2:53
08/07/08 2:53
08/07/08 2:53
08/07/08 2:53
08107/08 2:53
08107/08 2:53
08107/08 2:53
08107/08 2:53
08/07/08 2:53
Received: 08/05/08 10:00
Reported: 08/18/08 17:18
Instrument
Analyst
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
QC
Batch
8H07011
8H07011
8H07011
8H07011
8H070ll
8H07011
8H07011
8H070ll
8H07011
8H07011
8H07011
8H07011
8H07012
8H07012
8H07012
8H07012
8H07012
8H070\2
8H07012
8H07012
8H07012
8H07012
8H07012
8H07012
8H07012
8H07012
8H07012
8H07012
8H07012
8H07012
8H07012
8H07012
LRH0
8/11/2019 Brimbal Ave. - Environmental Notification Form - 9.2.14 - Volume 2 of 2
http://slidepdf.com/reader/full/brimbal-ave-environmental-notification-form-9214-volume-2-of-2 505/798
Test
America
Tf.lE lEADER IN ENVIRONMENTAL tESTING
1721 South Grand Avenue Santa Ana, CA 92705 • 714-258-8610 • Fax 714-258-0921
Griffin Engineering Group Beverly
I 00 Cummi ngs Center Suite 2220
Beverly,
MA
01915
Peter Flink
Analyte
.
Result
Sample ID: 8H07012-BLKI
(Blank- Air)-
cont.
Work Order:
Project:
Project Number:
LRH0043
BrimbalAve
[none]
PROJECT QUALITY CONTROL DATA
Data
Qualifier
Blank-
Cont.
Units
RL
Date
Dilution Analyzed
EPA
TO
IS (Med-level)- Volatile Organic Compounds
by
GC/MS
1,2-Dichloroethane
cis-\ 2-Dich\oroethene
trans-1,2-Dichloroethene
I, 1-Dichloroethene
1,2-Dich\oropropane
cis- 3-Dichloropropene
trans- I
3-Dichloropropene
I 2-Dichloro-1, I 2,2-tetrafluoroethane
Ethyl
benzene
4-Ethy\toluene
Hexachlorobutadiene
2-Hexanone
Methylene
chloride
4-Methyl-2-pentanone (MIBK)
Styrene
I,
1,2,2-
Tetrachloroethane
T etrachloroethene
Toluene
1,2,4-
Trichlorobenzene
I, I, -Trichloroethane
I, 1,2-Trichloroethane
Trich1oroethene
Trichlorofluoromethane
1,
1 2-T richloro-1 ,2,2-trifluoroethane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Vinyl
acetate
Vinyl chloride
Xylenes, total
Sample ID: 8H08008-BLKI
(Blank-
Air)
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
EPA
T015
(Med-level)- Volatile Organic Compounds by GC/MS
Acetone
Benzene
Benzyl chloride
NO
NO
NO
ppbv
ppbv
ppbv
2.0
2.0
2.0
2.0
3.0
2.0
2.0
2.0
2.0
2.0
4.0
10
2.0
10
2.0
2.0
2.0
2.0
5.0
2.0
2.0
2.0
2.0
2.0
3.0
3.0
10
3.0
2.0
10
3.0
10
30
o f
53
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
08/07/08 2:53
08/07/08 2:53
08/07/08 2:53
08/07/08 2:53
08/07/08 2:53
08/07/08 2:53
08/07/08 2:53
08/07/08 2:53
08/07/08 2:53
08/07/08 2:53
08/07/08 2:53
08/07/08 2:53
08/07/08 2:53
08/07/08 2:53
08/07/08 2:53
08/07/08 2:53
08/07/08 2:53
08/07/08 2:53
08/07/08 2:53
08/07/08 2:53
08/07/08 2:53
08/07/08 2:53
08/07/08 2:53
08/07/08 2:53
08/07/08 2:53
08/07/08 2:53
08/07/08 2:53
08/07/08 2:53
08/07/08 2:53
08/07/08 14:16
08/07/08 14:16
08/07/08 14:16
Received:
Reported:
08/05/08 10:00
08/18/08 17: 18
Instrument
Analyst
QC
Batch
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
8H07012
8H07012
8H07012
8H07012
8H07012
8H07012
8H07012
8H07012
8H07012
8H07012
8H07012
8H07012
8H07012
8H07012
8H07012
8H07012
8H07012
8H07012
8H07012
8H07012
8H07012
8H07012
8H07012
8H07012
8H07012
8H07012
8H07012
8H07012
8H07012
8H08008
8H08008
8H08008
LRH0
8/11/2019 Brimbal Ave. - Environmental Notification Form - 9.2.14 - Volume 2 of 2
http://slidepdf.com/reader/full/brimbal-ave-environmental-notification-form-9214-volume-2-of-2 506/798
TestAmerica
THE
LEADER
IN ENVIRONMENTAL
IE'ST NG
1721 South Grand Avenue Santa Ana, CA 92705 • 714-258-8610 ~ F a x 714-258-0921
Griffin Engineering Group Beverly
100 Cummings Center Suite 2220
Beverly, MA
01915
Peter Flink
Analyte Result
Sample ID: 8H08008-BLK1 (Blank- Air)- cont.
Work Order:
Project:
Project Number:
LRH0043
Brimbal Ave
[none]
PROJECT QUALITY CONTROL DATA
Blank- Cont.
Date
ata
Qualifier
Units
RL
Dilution Analyzed
EPA TO
IS
(Med-level)-
Volatile Organic Compounds by
GC/MS
Bromodicbloromethane
Bromoform
Bromometbane
2-Butanone (MEK)
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Dibromochtoromethane
Chloroethane
Chloroform
Chloromethane
1,2-Dibromoethane (EDB)
I ,2-Dichlorobenzene
1 3·Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1, 1-Dichloroethane
1,2-Dich\oroethane
cis- 2-Dichloroethene
trans-
I
,2-Dich\oroethene
I,
1-Dichloroethene
1,2-Dich\oropropane
cis- 3-Dichloropropene
trans-1,3-Dichloropropene
I
2-Dich
oro-\, I
2,2-tetrafluoroethane
Ethyl benzene
4-Ethyltolucne
HexaChiorobutadiene
2-Hexanone
Methylene chloride
4-Methyl-2-pentanone
(MIBK)
Styrene
l, 1 2,2-Tetrachloroethane
T etrach\oroethene
Toluene
I 2,4-T rich oro benzene
I, I, - Trichloroethan e
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
2.0
2.0
4.0
10
10
2.0
2.0
2.0
4.0
2.0
4.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
3.0
2.0
2.0
2.0
2.0
2.0
4.0
10
2.0
10
2.0
2.0
2.0
2.0
5.0
2.0
31
o f 53
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
08/07/08 14:16
08/07/08 14:16
08/07/08 14:16
08/07/08 14:16
08/07/08 14:16
08/07/08 14:16
08/07/08 14:16
08/07/08 14:16
08/07/08 14:16
08/07/08 14:16
08/07/08 14:16
08/07/08 14:16
08/07/08 14:16
08/07108 14:16
08/07/08 14:16
08107108
14:16
08/07/08 14:16
08/07/08 14:16
08/07/08 14:16
08107108
14:16
08/07/08 14:16
08/07/08 14:16
08107108
14:16
08/07108 14:16
08/07/08 14:16
08107108
14:16
08/07/08 14:16
08/07108 14:16
08/07/08 14:16
08/07/08 14:16
08/07/08 14:16
08/07/08 14:16
08/07/08 14:16
08/07108 14:16
08/07/08 14:16
08/07/08 14:16
08/07/08 14:16
Received: 08/05/08 10:00
Reported: 08/18/08 17:18
Instrument Analyst
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
AA
QC
Batch
8H08008
8H08008
8H08008
8H08008
8H08008
8H08008
8H08008
8H08008
8H08008
8H08008
8H08008
8H08008
8H08008
8H08008
8H08008
8H08008
8H08008
8H08008
8H08008
8H08008
8H08008
8H08008
8H08008
8H08008
8H08008
8H08008
8H08008
8H08008
8H08008
8H08008
8H08008
8H08008
8H08008
8H08008
8H08008
8H08008
8H08008
LRH
8/11/2019 Brimbal Ave. - Environmental Notification Form - 9.2.14 - Volume 2 of 2
http://slidepdf.com/reader/full/brimbal-ave-environmental-notification-form-9214-volume-2-of-2 507/798
Test
America
THE LEADER IN ENVIRONMENTAl TESTING
1721 South Grand Avenue Santa Ana, CA 92705 • 714-258-8610 • Fax 714-258-0921
Griffin Engineering Group Beverly
100 Cummings Center Suite 2220
Beverly, MA 01915
Peter Flink
Analyte
Result
Sample ID: 8H08008-BLK1 (Blank-
Air)-
cont.
Work Order:
Project:
Project Number:
LRH0043
Brimbal Ave
[none]
PROJECT QUALITY CONTROL DATA
Blank-
Cont.
Dateata
Qualifier
Units RL Dilution Analyzed
EPA
T015
(Med-level)- Volatile
Organic
Compounds by GC/MS
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
I, 1,2-Trichloro-1,2,2-trifluoroethane
1,2,4-T imethylbenzene
1,3,5-Trimethylbenzene
Vinyl acetate
Vinyl chloride
Xylenes, total
Analyte
ND
ND
ND
ND
ND
ND
ND
ND
ND
Result
Sample ID: 8H06002-BLKI (Blank- Air)
EPA
15/16- Sulfur
Compounds
Carbon disulfide
Carbonyl sulfide
Dimethyl disulfide
Dimethyl sulfide
Hydrogen sulfide
Ethyl mercaptan
Methyl mercaptan
ND
ND
ND
ND
ND
ND
ND
Sample ID: 8H07006-BLKI
(Blank-
Air)
ASTM
D1946-
Fixed Gases
Carbon dioxide
Carbon monoxide
Methane
Oxygen
Nitrogen
ND
ND
ND
ND
ND
Data
Qualifier
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
2.0
2.0
2.0
2.0
3.0
3.0
10
3.0
2.0
Blank - Cont.
Units
ppmv
ppmv
ppmv
ppmv
ppmv
ppmv
ppmv
o/o(v/v)
o/o(v/v)
o/o(v/v)
o/o(v/v)
o/o(v/v)
RL
0.025
0.050
0.025
0.050
0.050
0.050
0.050
0.010
0.0010
0.00020
0.20
1.0
32
of
53
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
08/07/08 14:16
08107/08 14:16
08107/08 14:16
08/07/08 14:16
08107/08 14:16
08107/08 14:16
08/07/08 14:16
08/07/08 14:16
08/07/08 14:16
Date
Dilution Analyzed
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
08/06/08 7:20
08/06/08 7:20
08/06/08 7:20
08/06/08 7:20
08/06/08 7:20
08/06/08 7:20
08/06/08 7:20
08/06/08 7:30
08/06/08 7:30
08/06/08 7:30
08/06/08 7:30
08/06/08 7:30
Received: 08/05/08 I 0:00
Repor ted: 08118/08 17:
18
Instrument
Analyst
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
AA
AA
AA
AA
AA
AA
AA
AA
AA
Instrument
Analyst
GC7
GC7
GC7
GC7
GC7
GC7
GC7
GCS
GCS
GC8
GC8
GCS
TD
TD
TD
TD
TD
TD
TD
El
El
El
El
El
QC
Batch
8H08008
8H08008
8H08008
8H08008
8H08008
8H08008
8H08008
8H08008
8H08008
QC
Batch
8H06002
8H06002
8H06002
8H06002
8H06002
8H06002
8H06002
8H07006
8H07006
8H07006
8H07006
8H07006
LRH
8/11/2019 Brimbal Ave. - Environmental Notification Form - 9.2.14 - Volume 2 of 2
http://slidepdf.com/reader/full/brimbal-ave-environmental-notification-form-9214-volume-2-of-2 508/798
TestAmerica
THE LEADER
IN ENVIRONMENTAL
TE'STING
Griffin Engineering Group Beverly
I 00 Cummings Center Suite 222G
Beverly, MA 01915
Peter Flink
1721 South Grand Avenue Santa Ana, CA 9270 5 * 714-258-8610 • Fax 714-258-0921
Work Order: LRH0043 Received: 08/05/08 10:00
Reported: 08/18/0817:18
Project: Brimbal Ave
Project Nwnber: [none]
PROJECT QUALITY CONTROL DATA
Analyte Result
Sample ID: 8H07006-BLK1 (B lank- Air)- cont.
ASTM
01946- Fixed
Gases
Blank - Cont.
Data
Qualifier Units
RL
33
of
53
Date QC
Dilution Analyzed Instrument Analyst Batch
LRH
8/11/2019 Brimbal Ave. - Environmental Notification Form - 9.2.14 - Volume 2 of 2
http://slidepdf.com/reader/full/brimbal-ave-environmental-notification-form-9214-volume-2-of-2 509/798
8/11/2019 Brimbal Ave. - Environmental Notification Form - 9.2.14 - Volume 2 of 2
http://slidepdf.com/reader/full/brimbal-ave-environmental-notification-form-9214-volume-2-of-2 510/798
TestAmerica
THE LE:ADEfl IN ENVIRONMENTAL
TESTING
1721 South Grand Avenue Santa Ana, CA 92705 * 714-258-861 0 • Fax 714-258-0921
Griffin Engineering Group Beverly
100 Cununings Center Suite 2220
Beverly, MA 01915
Peter Flink
Analyte
Sample ID: 8H08008-BSI (LCS- Air)
Result
Work Order:
Project:
Project Number:
LRH0043
BrimbalAve
[none]
PROJECT QUALITY CONTROL DATA
Data
Qualifiers Units
LCS
-Cont.
RL
Spike
Dilution Cone
%
Rec
EPA
TO
IS {Med-level)- Volatile Organic Compounds by GC/MS
Acetone
Bromodichloromethane
Bromomethane
Carbon
disulfide
Chlorofonn
1,3-Dichlorobenzene
1,2-Dich\oroethane
trans-1,2-Dichloroethene
cis-1,3-Dichloropropene
Ethylbenzene
4-Ethyltoluene
Styrene
1,
1,2-Trichloroethane
Trichlorofluoromethane
I, I 2-Trichloro-1 ,2,2-trifluoroetbane
Vinyl chloride
Analyte
Sample ID: 8H06002-BSI
(LCS-
Air)
EPA 15/16-
Sulfur Compounds
Carbon disulfide
Carbonyl
sulfide
Dimethyl
disulfide
Dimethyl
sulfide
Hydrogen sulfide
Ethyl mercaptan
Methyl mercaptan
62.6
su
66.1
51.4
50.3
51.8
47.8
50.1
47.7
56.1
57.9
54.8
40.8
44.7
53.9
53.3
Result
0.912
1.04
0.258
0.976
0.802
0.797
0.817
ME
Data
Qualifiers
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
Units
ppm'
ppmv
ppmv
ppmv
ppmv
ppmv
ppmv
10
2.0
4.0
10
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
3.0
LCS- Cont.
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
53.0
50.0
118%
102%
50.0 132%
50.0 103%
50.0
53.0
53.0
52.5
50.0
52.5
54.5
50.0
50.0
53.0
50.0
50.0
101%
98%
90%
95%
95%
107%
106%
110%
82%
84%
108%
107%
RL
Spike
Dilution Cone % Rec
0.025
0.050
0.025
0.050
0.050
0.050
0.050
1.00
1.00
1.00
1.00
1.00
1.00
1.00
35 o f
53
0.950 96%
1.03
101%
0.300 86%
0.985 99%
0.980 82%
0.890 90%
0.930 88%
Target
Range
70 - 130
70-
130
70-130
70-
130
70-
130
70- 130
70- 130
70- 130
70- 130
70- 130
70-130
70- 130
70-130
70-
130
70-
130
70-
130
Target
Range
70- 120
75- 140
70-
130
70- 130
60 - 130
70- 130
75-
130
Received: 08/05/08 10:00
Reported: 08118/08 17:18
Instrument
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
MSA
Instrument
GC7
GC7
GC7
GC7
GC7
GC7
GC7
Date
Analyzed
QC
Batch
08/07/08 12:38 8H08008
08/07/08 12:38 8H08008
08107/08 12:38 8H08008
08/07/08 12:38 8H08008
08/07/08 12:38 8H08008
08/07/08 12:38 8H08008
08/07/08 12:38 8H08008
08/07/08 12:38 8H08008
08/07/08 12:38 8H08008
08/07/08 12:38 8H08008
08/07/08 12:38 8H08008
08/07/08 12:38 8H08008
08/07/0812:38 8H08008
08/07/08 12:38 8H08008
08/07/08 12:38 8H08008
08/07/08 12:38 8H08008
Date
Analyzed
QC
Batch
08/06/08 06:21 8H06002
08/06/08 06:21 8H06002
08/06/08 06:21 8H06002
08/06/08 06:21 8H06002
08/06/08 06:21 8H06002
08/06/08 06:21 8H06002
08/06/08 06:21 8H06002
LRH
8/11/2019 Brimbal Ave. - Environmental Notification Form - 9.2.14 - Volume 2 of 2
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Test
America
THE lEAOE:R IN ENVIRONME:NTAL
TESTING
1721 South Grand Avenue Santa Ana, CA 92705 * 714-258-8610 • Fax 714-258-0921
Griffin Engineering Group Beverly
100 Cummings Center Suite
2220
Beverly, MA 01915
Peter Flink
Analyte
Sample ID: 8H07006-BSI (LCS- Air)
ASTM
01946-
Fixed Gases
Carbon dioxide
Carbon monoxide
Methane
Oxygen
Nitrogen
Result
1.05
0.0483
0.0293
5.17
20.6
Work Order: LRH0043
Project Brimbal Ave
Project Number; [none]
PROJECT
QUALITY CONTROL DATA
LCS-
Cont.
Data
Spike Target
Qualifiers Units RL
Dilution Cone
%
Rec
Range
o/o(v/v)
0.010
1.00
0.998 105% 75 -
125
%(v/v)
0.0010 1.00
0.0455 106%
70 -
130
%(v/v)
0.00020 1.00 0.0280 105% 75- 135
%(v/v)
0.20
1.00 4.98
104%
70 -
130
o/o(v/v)
1.0
1.00 20.0
103% 70-130
36 o f 53
Received: 08/05/08 10:00
Reported: 08118/08
17:18
Instrument
GC8
ocs
GC8
GC8
GC8
Date
Analyzed
08/06/08 06;57
08/06/08 06:57
08106/08 06:5 7
08/06/08 06:57
08/06/08 06:57
QC
Batch
8H07006
SH07006
8H07006
8H07006
8H07006
LRH
8/11/2019 Brimbal Ave. - Environmental Notification Form - 9.2.14 - Volume 2 of 2
http://slidepdf.com/reader/full/brimbal-ave-environmental-notification-form-9214-volume-2-of-2 512/798
Test
America
THE LEADER IN ENVIRONMENTAL
rESTING
1721 South Grand Avenue Santa Ana, CA 92705 • 714-258-8610 Fax-714-258-0921
Griffin Engineering Group Beverly
I 00 Cummings Center Suite 222G
Beverly,
MA
01915
Peter Flink
Work Order:
Project:
Project Number:
LRH0043
Brimbal Ave
[none]
PROJECT
QUALITY CONTROL DATA
LCS Dup
Spike
Received: 08/05/08 10:00
Reported: 08118/08 17:18
Target
Analyte Result
Data
Qualifiers
Units
RL
Dilution Cone % Rec Range RPD Limit
Date
Analyzed
QC
Batch
Sample ID: 8H07011-BSDI (LCS Dup- Air)
EPA TOlS (Med-level)- Volatile
Organic Compounds
by GC/MS
Acetone
Bromodichloromethane
Bromomethane
Carbon disulfide
Chloroform
1 3-Dichlorobenzene
I 2-Dichloroethane
troos-1 ,2-Dicliloroethene
cis-1,3-Dichloropropene
Ethyl benzene
4-Ethyltoluene
Styrene
I, I 2-Trichloroethane
Trichlorofluoromethane
I, 1,2-T richloro-1 ,2,2-trifluoroethane
Vinyl chloride
60.8
50.6
57.1
55.3
50.5
49.0
46.0
52.2
47.8
51.6
57.4
49.0
40.5
49.2
56.5
51.2
Sample ID: 8H07012-BSDI (LCS
Dup-
Air)
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
pP,v
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
EPA
TOtS
(Med-level)- Volatile Organic
Compounds by
GC/MS
Acetone
Bromodichloromethane
Bromomethane
Carbon disulfide
Chlorofonn
1,3-Dichlorobenzene
I 2-Dichloroethane
trans-
2 ~ D i c h l o r o e t h e n e
cis-1,3-Dichloropropene
Ethylbenzene
4-Ethyltoluene
Styrene
I, 1,2-Trichloroethane
Trichlorofluoromethane
1, I 2-T richloro-1 ,2,2-trifluoroethane
Vinyl chloride
59.8
52.3
55.5
52.3
48.2
47.1
47.8
50.7
48.2
52.7
58.7
49.9
39.8
47.7
53.7
49.9
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
10
2.0
4.0
10
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
3.0
10
2.0
4.0
10
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
3.0
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
37 o f
53
53_0
50.0
50.0
50.0
50.0
53.0
53.0
52.5
50.0
52.5
54.5
50.0
50.0
53.0
50.0
50.0
53.0
50.0
50.0
50.0
50.0
53.0
53.0
52.5
50.0
52.5
54.5
50.0
50.0
53.0
50.0
50.0
115%
70-130
101% 70- 130
114% 70-
130
111%
70-130
101% 70-130
92% 70- 130
87%
99%
96%
98%
70- 130
70-130
70-
130
70-
130
105% 70- 130
98% 70- 130
81%
70-130
93%
70-130
113% 70- 130
102%
70-
130
5
3
II
0.2
0.6
0.8
4
7
3
7
113% 70- 130 4
105% 70- 130 0.09
I l l% 70-130 24
105%
70- 130
0.2
96%
70
- 130 0.8
89%
70-130
2
90%
70-130
4
97% 70- 130
96%
70-
130
100% 70- 130
108% 70- 130
100% 70- 130
80% 70- 130
90%
70-
130
107% 70- 130
100% 70- 130
0.2
0.6
2
2
0.7
0.9
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
08/06/08 10:53 8H07011
08106/08 10:53 8H07011
08/06/08 10:53 8H070 II
08/06/08 10:53 8H070 I I
08/06/08 10:53 8H07011
08/06/08 10:53 8H07011
08106/08 10:53 8H070
11
08/06/08 10:53 8H070ll
08/06/0810:53 8H07011
08/06/08 10:53 8H07011
08/06/08 10:53 8H07011
08/06/08 10:53 8H07011
08/06/08 10:53 8H07011
08/06/08 10:53 8H07011
08106/08 10:53 8H07011
08106/08 10:53 8H07011
08/07/08 02:14 8H07012
08/07/0802:14 8H07012
08/07/08 02:14 8H07012
08/07/08 02:14 8H07012
08/07/08 02:14 8H07012
08107/0802:14 8H07012
08/07/0802:14 8H07012
08/07/0802:14 8H07012
08107/0802:14 8H07012
08/07/08 02:14 8H07012
08/07/08 02:14 8H07012
08/07/0802:14 8H07012
08/07/08 02:14 8H07012
08/07/0802:14 8H07012
08/07/08 02:14 8H070 \2
08/07/08 02:14 8H07012
LRH
8/11/2019 Brimbal Ave. - Environmental Notification Form - 9.2.14 - Volume 2 of 2
http://slidepdf.com/reader/full/brimbal-ave-environmental-notification-form-9214-volume-2-of-2 513/798
Test
America
THE LEADER
IN ENVIRONMENTAL
TE:$TING
Griffin Engineering Group Beverly
100
Cummings Center Suite 2220
Beverly, MA 01915
Peter Flink
1721 South Grand Avenue Santa Ana, CA 92705 • 714-258-8610 • Fax 714-258-0921
Work
Order:
Project:
Project Number:
LRH0043
Brimbal Ave
[none]
Received: 08/05/08 10:00
Reported: 08118/08 17:18
PROJECT
QUALITY CONTROL DATA
Analyte Result
Sample
ID:
8H08008-BSDI (LCS
Dup- Ak)
Data
Qualifiers
Units
EPA TOtS (Med-level)- Volatile Organic Compounds by GC/MS
Acetone
Bromodichloromethane
Bromomethane
Carbon disulfide
Chloroform
1,3-Dichlorobenzene
1,2-Dich\oroethane
trans-1,2-Dichloroethene
cis-1,3-Dichloropropene
Ethylbenzene
4-Ethyltoluene
Styrene
I, 1,2-Trichloroethane
Trichlorofluoromethane
I, I ,2-Trichloro-1,2,2-trifluoroethane
Vinyl chloride
Analyte
52.1
50.9
63.7
53.6
48.7
49.3
46.1
Sl.l
47.3
52.5
55.5
49.6
39.5
47.7
55.0
50.6
Result
Sample ID: 8H06002-BSDI (LCS
Dup-
Air)
EPA 15/16- Sulfur Compounds
Carbon
disulfide
Carbonyl sulfide
Dimethyl disulfide
Dimethyl sulfide
Hydrogen sulfide
Ethyl mercaptan
Methyl mercaptan
0.905
1.01
0.256
0.966
0.757
0.737
0.797
Data
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppb\'
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
Qualifiers Units
ppmv
ppmv
ppmv
ppmv
ppmv
ppmv
ppmv
LCS Dup- Cont.
Spike
Target
RL
Dilution Cone
%
Rec Range RPD Limit
Date
Analyzed
QC
Batch
10
2.0
4.0
10
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
3.0
1.00
1.00
l.OO
1.00
1.00
l.OO
1.00
1.00
l.OO
1.00
1.00
1.00
1.00
1.00
1.00
1.00
LCS Dup - Cont.
53.0
50.0
50.0
50.0
50.0
53.0
53.0
52.5
50.0
52.5
54.5
50.0
50.0
53.0
50.0
50.0
Spike
98%
70.
130
102%
70- 130
127%
70-
130
107%
70-130
97% 70- 130
93%
87%
97%
95%
70- 130
70-
130
70 -
130
70 -
130
100% 70 - 130
102% 70 - 130
99%
70-
130
79% 70- 130
90% 70-130
110%
70-130
101%
70-
130
Target
18
0.4
4
4
3
4
2
7
4
10
3
6
2
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
08/07/08 13:14 8H08008
08/07/08 13:14 8H08008
08107/08 13:14 8H08008
08107/08 13:14 8H08008
08/07/08 13:14 8H08008
08/07/08 13:14 8H08008
08107/0813:14 8H08008
08107/08 13:14 8H08008
08107/08 13:14 8H08008
08107/08 13:14 8H08008
08107/08 13:14 8H08008
08107/08 13:14 8H08008
08/07/08 13:14 8H08008
08/07/0813:14 8H08008
08/07/08 13:14 8H08008
08/07/08 13:14 8H08008
RL
Dilution Cone
%
Rec Range RPD Limit
Date
Analyzed
QC
Batch
0.025
0.050
0.025
0.050
0.050
0.050
0.050
l.OO
1.00
1.00
l.OO
1.00
l.OO
1.00
38 o f 53
0.950 95%
1.03 98%
0.300 85%
0.985 98%
0.980 77%
0.890 83%
0.930 86%
70- 120
75-
140
70 - 130
70 - 130
60 -
130
70- 130
75- 130
0.7
3
6
8
2
25
08106/08 07:00 8H06002
25
· 08/06/08 07:00 8H06002
30
30
25
30
25
08/06/08 07:00 8H06002
08/06/08 07:00 8H06002
08/06/08 07:00 8H06002
08/06/08 07:00 8H06002
08/06/08 07:00 8H06002
LRHQ
8/11/2019 Brimbal Ave. - Environmental Notification Form - 9.2.14 - Volume 2 of 2
http://slidepdf.com/reader/full/brimbal-ave-environmental-notification-form-9214-volume-2-of-2 514/798
Test
America
THE LEADER IN ENVIRONMENTAL TESTING
1721 South Grand Avenue Santa Ana, CA 92705 • 714-258-8610 • Fax 714-258-0921
Griffin Engineering Group Beverly
I 00 Cummings Center Suite 222G
Beverly,
MA
0 915
Peter Flink
Work Order: LRH0043
Project: Brimhal Ave
Project Number: [none]
PROJECT QUALITY CONTROL DATA
LCS Dup - Cont.
Data
Spike
Target
Received: 08/05/08 10:00
Reported: 08/18/0817:18
Date
Analyte Result Qualifiers Units RL Dilution . Cone
%
Rec Range RPD Limit Analyzed
QC
Batch
Sample ID: 8H07006-BSDI (LCS Dup- Air)
ASTM
01946-
Fixed Gases
Carbon dioxide
LOS
%(v/v) 0.010 1.00
0.998
105%
75 -
125 03
20
08/06/08 07:10 8H07006
Carbon
monoxide 0.0483
%{v/v)
0.0010 1.00 0.0455
106% 70- 130
0.003
30
08/06/08 07:
10
8H07006
Methane 0.0293
o/o{v/v)
0.00020 1.00 0.0280
105%
75 - 135
0.06
20 08106/08
07:10
8H07006
Oxygen
5.17
o/o(v/v)
0.20
1.00
4.98
104% 70 - \30
0.04
30 08106/08 07:
to
8H07006
Nitrogen 20.6 o/o(v/v)
1.0
1.00
20.0
103% 70 - 130
0 30 08106/08 07:
to
8H07006
39
o f 53 LRH0
8/11/2019 Brimbal Ave. - Environmental Notification Form - 9.2.14 - Volume 2 of 2
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TestAmerica
THE LEADER IN ENVIRONMENTAL TE:STINO
1721 South Grand Avenue Santa Ana, CA 92705 • 714-258-8610
~ F a x
714-258-0921
Griffin Engineering Group Beverly
100 Cummings Center Suite 2220
Beverly, MA01915
Peter Flink
Work Order: LRH0043
Project: Brimbal Ave
Project Number: [none]
DATA QUALIFIERS AND DEFINITIONS
Internal Standard recovery
was
outside ofmethod limits. Matrix interference was conftrmed
by
reanalysis.
JA The analyte was positively identified but the quantitation
is
an estimate.
Received: 08/05/08 I 0:00
Reported: 08/18/0817:18
ME The percent recovery of he analyte is outside the control limits but within marginal exceedance limits, per NELAC
requirements.
RL2 Reporting limit raised due to high concentrations of hydrocarbons.
ND Not detected. at the reporting limit (or method detection limit i f hown)
40 o f
53
LRH
8/11/2019 Brimbal Ave. - Environmental Notification Form - 9.2.14 - Volume 2 of 2
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http://slidepdf.com/reader/full/brimbal-ave-environmental-notification-form-9214-volume-2-of-2 518/798
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LRH
8/11/2019 Brimbal Ave. - Environmental Notification Form - 9.2.14 - Volume 2 of 2
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44 o f 53
LRH
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-
VFR ID:
t tF\
L\
0
CANISTER
SERIAL #:
--'0""-'-\_,_,\_'-\__,_,.(o,__--,-
DATE CLEANED: --;OO"i· - l - ' - : - ' : ' Z . . ~ L _ , l " ' 0 " - ' 1 5 - " " " F____
CLIENT SAMPLE#: - - - - 3 1 ( 9 ' 7 ~ ' - - - ' 1 _ , ' - { f - - - - - - - -
SITE LOCATION: _flJ '(l.;ul l " - _ _ : : u f , " - ' f A L = - l ( T i - - 1 / ( _ _ " " " - - - - ~ ~
Duration of camp. :
L-
Hrs. I mins.
Flow setting: ~ " . ( . , -:-LfJ.7mllmin
Initials: ~
READING
INITIAL VACUUM CHECK
I
NITIAL FIELD
VACUUM
I
INAL FIELD READING
<?
,,
LABORATORY CANISTER PRESSURIZATION
INITIAL VACUUM (Inches f - f g r ~ ~ ( c i r c l e untl used))
\.__/,(
Pressurization Gas:
~
COMMENTS:
I , .
"c
I
I Z(.Cj( I
I
COMPOSITE
TIME
IHOURS\
15 Min.
30Min.
1
2
4
6
8
10
12
24
1/1
I
FLOW RATE RANGE
(mVmin)
316-333
158-166.7
79.2-83.3
.
39.6-41.7
19.8-20.8
13.2-13.9
9.9
11l.4
7.92 8.3
6.6
6.9
3.5 4.0
N:\001\DOCS\TestAmerica
DOCs\TestAmeric-a
~ C A N I S T E R FIELD DATA R E C O R D ~ 20080201,doc I
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CANISTER FIELD
DATA RECORD
CLIENT:
--'-"6'--'',
- - - - - - ' - - ' = I = ·
_,_f_F-"I"--N
_
_N_G_.
-
CANISTER
SERIAL#: A . _ , _ - _ 3 - ' - - L . _ c - = - = - - - - - -
DATE
CLEANED: _ _ _ , 0 " " - - / _ , _ , Z . . ~ L - ' l " " 0 " - - ' 1 $ ' = . : . F
____
CLIENT
SAMPLE #: _ _,G"-'f_-_,'Z.,_(p=-------:------
SITELOCATION: ilJC"\Mf#-G k
READING
INITIAL VACUUM CHECK
I
NITIAL FIELD
VACUUM
tooo
VFR ID:
tfF
0
8;'=\
Duration of comp. : ?-- Hrs./ mins.
Flow setting: 7>"L(, -:-L(f.7ml/min
Initials: ~
I
INAL FIELD
READING
B
•
LABORATORY CANISTER PRESSURIZATION
1
INITIAL VACUUM (Inches
Hg / f s ~
(circle
untt
used))
I
I L
I
t
.r ~ ' l
I
M
. FINAL PRESSURE
<{siAl) ~
I
z.:Z.1'/- I
J
I
.(;
' - - .1\
Pressurization Gas:
~
COMPOSITE
FLOW RATE RANGE
TIME
COMMENTS:
(HOURS)
(m lmln)
15
Min.
316-333
30Min.
158-166.7
1
79.2-83.3
2
39.6-41.7
4
19.8-20.8
6
13.2-13.9
8
9.9-10.4
10
7.92
8.3
12
6.6-6.9
.
24
3.5
4.0
N:\COI\DOCS\TestAmerica DOCs\TestAmerica- CANISTER FIELD
DATA
RECORD - 20080201.doc t
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5
CANISTER FIELD
DATA
RECORD
CLIENT:
--'-"6"--''
' - - - - - ' - - ' = I = - - ' - - f - - ' - - - F _ : : I ~ t v
_ _
_N_G_.
-
CANISTER
SERIAL
#:
_(\-"--{o=-£_-"--'{_=-.@,=-----::=-----
DATE
CLEANED: ~ - - ' 0 " " - - - / _ , _ , L ~ ' - - _ , l ' - " 0 " - - ' 1 5 - = . : F
____
VFR ID:
ttf=O
\0
Duration of comp. :
{ ._
Hrs. I mins.
Flow
setting:
7,"{.(.,
>Lf/.7ml/min
CLIENT SAMPLE#:
- - - , , G _ I ' _ ~ _ ' L O - - - : : - - : - - - - - - -
SITE
LOCATION: _
_ , _ f " ' - " \ M J b - ' - - " " ' - ' j \ 0 - ' - - _ ~ : _ _ _ _ . : _
___
Initials:
~
READING
INITIAL VACUUM CHECK
I
NITIAL FIELD VACUUM
({)6)'
I
INAL FIELD READING
I
i}ct[o(
LABORATORY CANISTER PRESSURIZATION
INITIAL VACUUM (Inches
Hg/e
circle unit used))
2(. ~
COMPOSITE
FLOW RATE RANGE
TIME
COMMENTS:
(HOURS)
(mllmin)
15
Min.
316-333
.
30Min.
158-166.7
1
79.2-83.3
2
39.6-41.7
4
19.8-20.8
6
13.2-13.9
8
9.9 10.4
10 7.92 8.3
12
6.6 6.9
24 3.5-4.0
N:\COI\DOCS\TestAmetica DOCs\TestAmerica ~ C A N I S T E R FIELD
DATA
RECORD- 20080201.doc
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G
T ~ A m e r l c q
CANISTER FIElD DATA RECORD
CLIENT:
- " " " 6 " - - ' ~
' - - - - - ' - " I = . . - F - ' - F - = I = ' - - - - N
__
E_N_G_.
-
VFR ID:
t iF0 :S'"]
CANISTER
SERIAL
#: _q--'""5-"-'L.=-3.....,_"3,,__---:::=----
DATECLEANED: 0 t
Z . . L l Q ~ F
Duration of camp. : ' - Hrs. I mins.
Flow setting: ~ " . ( . -:-L(f.7mllmin
CLIENT
SAMPLE
#:
. ~ C 9 l l f . . : : : - _ , ( o " - ' f ( _ _ = - : - - c - : - - - - - -
SITE LOCATION:
6i:..IN\.
A A . .
A J'f
READING
INITIAL VACUUM CHECK
I
NITIAL FIELD
VACUUM
IO'S¥
I
INAL FIELD
READING
1 2 ~ 1 '
Initials: ~
I
30
I
1"/Lf
/o
'6
Co
I
'F}
4\ {) <(
LABORATORY CANISTER PRESSURIZATION
INITIAL VACUUM (Inches
H g / f s l ~ ( c i r c l e
unit used))
I
f/.o<>
~
's
. FINAL PRESSURE 1¥s1A0
I
2 f-77
:
.J;
-
Pressurization Gas:
1
COMPOSITE
COMMENTS:
(f
TIMES\
HOURS
15Min.
30Min.
1
2
4
6
8
10
12
24
I
~ \ ( V \ .
I
~ j ) j
I
M
I
&
FLOW RATE RANGE
(mVmin)
316-333
158
166.7
79.2 83.3
39.6 41.7
19.8 20.8
13.2 13.9
9.9 10.4
7.92-8.3
6.6-6.9
3.5-4.0
N:\COI\DOCS\Tes America DOCs\TestAmerica ~ C A N I S T E R
FIELD DATA
R ;CORD - 20080201.doc
I
48
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CANISTER
FIELD DATA
RECORD
CLIENT: _
_,_,6"-''
- - - - ' - " ' I " " - ' - F _ : _ F _ : : : : I = : ; _ N
__
__N_G_.
-
CANISTER
SERIAL #:
_ _ , 0 : : . _ _ ' : \ _ . _ \ - ' - ' { . , " " - = L j + - - - ~ - - - - -
DATE
CLEANED: _ ___,0="· I-:--'-2__7-L.-\li"0"--'15"-'='-'F
___
CLIENT
SAMPLE
#: -J..,42rf-- f _ t ~ - - ' \ - " \
rf._.'------::-:--.---
SITE LOCATION: _ _ , j b . l l l ( t _ e : : : l ' l l / t l l c : . . : J . f z a # G L ~ _ , f ± _ : _ _ U ( _ = - - ~ -
READING
INITIAL VACUUM CHECK
I
NITIAL FIELD
VACUUM
\02\
I
FINAL FIELD
READING
VFR ID:
t tF
l \
' l ._
Duration of comp. : ( ._ Hrs./ mins.
Flow setting: 7> Df,.(p -:-L(/.7mVmin
Initials: ~
LABORATORY CANISTER PRESSURIZATION
J
.INITIAL VACUUM (Inches Hg ~ ~ (circle unit used))
I
I
I
I 'b
I
Pressurization Gas:
~
COMPOSITE
FLOW RATE RANGE
TIME
COMMENTS: IHOURS\
{mVmln)
15
Min.
316-333
30Min.
158-166.7
1 79.2-83.3
2
39.6-41.7
4
19.8-20.8
6 13.2-13.9
8 9.9 10.4
10
7.92
8.3
12
6.6 6.9
24
3.5
4.0
I
N;\COI\DOCS\TestAmerlca OOGs\TestAmerica- CANISTER FlELO
DATA
RECORD- 20080201.doc j
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CANISTER FIELD DATA RECORD
CLIENT:
--'-6"-'' -.'--'-"I=-'-f-'-F_:::I=.:._N
_ _
__f\)_G_.
-
CANISTER SERIAL #: _ __,l__,lw3,_'-t--"--'2_=--==-----
DATECLEANED:
0/Z.:LlO"b"F
CLIENT SAMPLE#:
___,(b ;.)"-(J_----'\'-'1.,...'------------
SITE O C A T I O N : - - - - - - - - - - - - ~ -
READING
INITIAL VACUUM CHECK
I
NITIAL FIELD VACUUM
JD r'f
I INAL FIELD READING
VFR ID:
t iF
\
0 \
Duration of comp. : £ _ Hrs. I mins.
Flow setting: 2,0f,.(., -:-'-{f.7mVmin
Initials: ~
LABORATORY CANISTER PRESSURIZATION
INITIAL VACUUM (Inches
Hg
~ ~ (circle unfi used))
. FINAL PRESSURE fs0>
I Z(, D? I .f; I
Pressurization Gas:
__My
COMPOSITE
FLOW
RATE RANGE
TIME
COMMENTS:
(HOURS)
(ml/min)
15 Min.
316-333
30
Min.
158-166.7
1
79.2-83.3
2 39.6 41.7
4
19.8-20.8
6
13.2-13.9
8
9.9-10.4
10
7.92-8.3
12
6.6 6.9
24
3.5 4.0
I
N;\001\00CS\TestAmerit:a DOCs\TestAmerlca- CANISTER FIELD
DATA
RECORD- 20080201.doc j
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CANISTER QC
CERTIFICATION
TestAmerioo
1[' .
:::--
·-··
r- P T
If"
.
' f ' : ~ l l l i . t . . S . ~ ~ k ~ ~
Certification Type: J l w O ~ -
\ L ' b " - ~ · . L I ' Y \ ~ .
. c : L ~. - - - - - - - ~
'
ate Cleaned/Batch
Date
of
QC
Data File Number
vls
q3D-33
.......--
Dl.\ I -\l.a
\/'""
1\34
d.
6Co3d.49
l·2ti-0'3 f
CANISTER ID NUMBERS
v- q·3oso
v OLl\lpY
g · ~ d - - L \ 0
¥ 9ted-:J
B
Cf31S5
The above canisters w ~ r e cleaned as.a batch. This certifies this batch containsno
target analyte concentratiO.n·greater than or equal to the method criteria for the
· ~ c e r t i f i c a t i o n Tvofi'
indicate'd above.
*
"INDICATES THE CAN OR CANS WHICH WERE SCREENED.
Reviewed By:
N:\CQI\DOCS\TestAmerica009S\Can QC Cert 20Ci70712.doc
Date:
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Data
Fi le : \\LAPC046\MSA CC\chem\MSA.i\080730.B\MB07301.D
Report Date:
30-Jul-2008-10:25
Data f i l e
:
Lab
Smp Id:
Inj Date
Operator
Smp In fo
Mise
In fo
Comment
TestAmerica Los Angeles
AIR TOXICS - T0-14AIT0-15 MEDIUM LEVEL
\\LAPC046\MSA
CC\chem\MSA.i\080730.B\MB0730l.D
BLANK
- Client Smp
ID: 93233
30-JUL-2008 09:58
DLK Ins t
ID:
MSA.i
. BLANK,93233,,SCREEN BLANK
1,1,500,500,3,,BLANK,BLANK.SUB,O,
Method
\\LAPC046\MSA
CC\CHEM\MSA.I\080730.B\T014A.m
Meth Date
30-Jul-2008
OB:39 kammererd
Quant
Type: ISTD
Cal Date 30-JUL-2008 03:53 Cal
Fi le :
IC07295.D
Als bo t t l e : 15
QC Sample:
BLANK
Dil
Factor :
1.00000
Page
1
In teg ra to r :
HP
RTE
Subt ract ion
Fi le : \\LAPC046\MSA CC
Target
Version: 4.04
Compound
Subl i s t :
BLANK.SUB
Process ing
Host:
LAPC046
Concent ra t ion Formula: Amt * DF * (FinalPres
I
In i tPres)*(CalVol
I
SmpVol)
Name
DF
Final Pres
In i tP re s
Cal
Vol
SmpVol
Compounds
= = = = = ~ ~ = ~ = = = = ~ = ~ = = = = = = = = = =
•
64 Bromochloromethane
$
70
1,2-Dichloroethane-d4
•
77
1,4-Difluoroben%ene
$
89
Toluene-de
.
02
Chlorobenzene-dS
$
122
4-Bromo.fluorobenzene
Value
1.000
1 . 000
1.000
500.000
500.000
Descr ip t ion
Dilut ion Factor
Final Pres
In i tPres
CalVol
SmpVol
QUANT
SIG
MASS RT EXP RT
REt. RT
49
10.311
10.353
(1.000)
65
1 1 . 3 3 ~
11 .363
(0.937)
114 12 087 12 112
{1.000)
100
14 685
14.709
(1.215)
117
17 346 .17.361
1.000)
95 1.9.582 19.598
{1.129)
52
o f
53
CONCENTRATIONS
ON-COLUMN
FINAL
RESPONSE
( ppbv)_
{
ppbv)
"'""'"'"'"'"'"'
1743374 50.0000
801869 53 7201 53 72
2513688
50.0000
1350319
51 5680
51 57
2006782
50 0000
1774461 52 4509 52 45
LRH
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0
0
;.,
t.
m-
+
,_
-
-
-
,...
-
-
>-<
-
-
-
-
-
-
,_
-
-
-
0 0
.r
:"
?
- B r o ~ o c h l o r o M e t h a n e
-1,2-Diohloroethane-d4
<11
..330)
1,4-Ditluorobenzene
Toruene-d8
Chlorobenzene-d5
4-Bromofluorobenzene
53 o f 53
(10 . 311)
(12
.079)
0 0
<144686)
0
,
c
•
3
.,
,
<
0 3
..
;;
3
;·
::-
"
;;
"'
t
"'
;
' '
-
>
l J
(17.337>
(19.583)
LRH0
8/11/2019 Brimbal Ave. - Environmental Notification Form - 9.2.14 - Volume 2 of 2
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APPENDIXC
Land GEM
Output
for
the
Modeling of Landfill Gas Generation
at
the Former Brimbal
Avenue Landfill
in Beverly,
MA
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Appendix C.xls
10/2/2008
USER
INPUTS
Landfill
Name or Identifier:
~ - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - ~
1:
PROVIDE LANDFILL CHARACTERISTICS
Clear ALL
Non-Parameter
I
Inputs/Selections
Landfill
Open Year 1948
Landfill
Closure Year 1961
Have
Model
Calculate
Closure
Year?
CYes
.ENo
Waste Design Capacity
short tons
...,
Restore Default Model
2: DETERMINE MODEL PARAMETERS
Parameters
Methane Generation Rate, k
(year·
1
)
I Inventory Conventional - 0.04
... J
Potential
Methane Generation Capacity, L
0
(m
3
/Mg)
I
Inventory Conventional - 100
3
NMOC
Concentration
(ppmv as
hexane)
I Inventory No or Unknown Co-disposal - 600
...
j
Methane Content(%
by volume)
I
CAA
- 50% by \,{)lume ...
3:
SELECT GASES/POLLUTANTS
Gas
I Pollutant
#1
User-specified pollutant parameters are
currently
being used by model.
I Total landfill gas
...I
Edit Existing or
Add
Gas
I
Pollutant
#2
New
Pollutant
I Methane
...
]
Parameters
Gas
I
Pollutant
#3
I NMOC
...
I
Restore
Default
Pollutant
Gas
I
Pollutant #4
Parameters
I
Hydrogen sulfide
_
..
I
Description/Comments:
USER
INPUTS-
1
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Appendix C.xls
4: ENTER WASTE ACCEPTANCE RATES
Input Units:
I short tons/year
..-I
Input Units Calculated Units
Year
(short tons/year) (Mg/year)
1948
12,250 11,136
1949
12,250
11,136
1950
12,250
11 ,136
1951
12,250 11,136
1952 12 ,250 11,136
1953 12,250 11,136
1954
12,250
11,136
1955
12,250
11 ,136
1956 12,250 11,136
1957 12,250
11 ,136
1958
12,250
11,136
1959 12,250 11,136
1960
12,250
11,136
1961
12,250
11,136
1962
1963
1964
1965
1966
1967
1968
1969
1970
1971
1972
1973
1974
1975
1976
1977
1978
1979
1980
1981
1982
1983
1984
1985
1986
1987
USER INPUTS - 2
10/2/2008
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Appendix C.xls
4:
ENTER WASTE ACCEPTANCE RATES
Input Units:
j short tons/year .. j
Input Units Calculated Units
Year
(short tons/year) (Mglyear)
1988
1989
1990
1991
1992
1993
1994
1995
1996
1997
1998
1999
2000
2001
2002
2003
2004
2005
2006
2007
2008
2009
2010
2011
2012
2013
2014
2015
2016
2017
2018
2019
2020
2021
2022
2023
2024
2025
2026
2027
USER
INPUTS - 3
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Appendix C.xls
I
Enter New Com ound
A.
Hazardous air pollutants (HAP) listed
in
Title Ill of the 1990 Clean Air Act Amendments.
B. Considered volatile organic compounds (VOC}, as defined by U.S. EPA
in
40 CFR 51 .100(s).
C. Source tests did not indicate whether this compound was the para- or ortho- isomer. The
para- isomer
is
a Title Ill-listed HAP.
Source: Tables 2.
4-1
and 2.4-2 of Compilation of Air Pollutant Emission Factors, AP-42, Volume
1: Stationary Point and Area Sources, 5th ed. , Chapter 2.4 Municipal Solid Waste Landfills . U.S.
EPA, Office of Air Quality Planning and Standards . Research Triangle Park, NC. November
1998. http ://www.epa.gov/ttn/chief/ap42/ch02/final/c02s04 .p
df
POLLUTANTS- 2
Return to
USER INPUTS
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Appendix C.xls
10/2/2008
INPUT REVIEW
Landfill
Name or Identifier:
LANDFILL CHARACTERISTICS
Landfill Open Year
Landfill Closure Year (with 80-year limit)
Actual Closure Year (without limit)
Have Model Calculate Closure Year?
Waste Design Capacity
MODEL PARAMETERS
Methane Generation Rate, k
Potential Methane Generation Capacity,
La
NMOC Concentration
Methane Content
GASES I POLLUTANTS SELECTED
Gas I Pollutant #1:
Gas I
Pollutant #2:
Gas I Pollutant #3:
Gas
I
Pollutant #4:
Total landfill gas
Methane
NMOC
Hydrogen sulfide
Description/Comments:
1948
1961
1961
No
0.040
100
600
50
-------------------------------------
short tons
year-
1
m
3
/Mg
ppmv as hexane
%by volume
INPUT
REVIEW-
1
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Appendix C.xls
10/2/2008
WASTE ACCEPTANCE RATES
Year (Mg/year)
(short tons/year)
1948
11 '136
12,250
1949
11 '136
12,250
1950
11
'136
12,250
1951
11 '136
12,250
1952
11
' 136
12,250
1953
11
'136 12,250
1954
11
'136
12,250
1955
11 '136
12,250
1956
11 ' 136
12,250
1957
11 '136
12,250
1958
11 '136
12,250
1959
11 '136
12,250
1960
11 '136
12,250
1961
11 '136
12,250
1962
0
0
1963
0
0
1964
0
0
1965 0
0
1966
0
0
1967
0
0
1968 0
0
1969
0
0
1970 0
0
1971
0
0
1972 0 0
1973 0
0
1974
0
0
1975
0
0
1976
0
0
1977
0
0
1978
0
0
1979
0
0
1980
0
0
1981
0
0
1982 0 0
1983
0
0
1984
0
0
1985
0
0
1986
0
0
1987
0
0
1988
0
0
1989
0
0
1990 0
0
INPUT
REVIEW-
2
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Appendix C.xls
10/2/2008
WASTE ACCEPTANCE RATES
Year
(Mg year)
(short tons/year)
1991
0
0
1992
0
0
1993
0
0
1994
0
0
1995
0
0
1996 0 0
1997
0
0
1998
0
0
1999
0
0
2000 0
0
2001
0
0
2002 0
0
2003
0
0
2004
0
0
2005
0
0
2006 0
0
2007 0
0
2008
0
0
2009
0
0
2010
0
0
2011
0
0
2012
0
0
2013
0
0
2014
0
0
2015 0 0
2016
0
0
2017
0
0
2018
0
0
2019
0
0
2020
0
0
2021
0
0
2022
0
0
2023
0
0
2024
0
0
2025 0 0
2026
0
0
2027
0
0
INPUT
REVIEW-
3
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Appendix C.xls
10/2/2008
METHANE
Landfill Name or Identifier:
First-Order Decomposition Rate Equation :
Where,
n 1 M)
cH4
=
L L kLo i
e lctsj
i=l j=O.l
} Q
Mi = mass of waste accepted in the i th year
(Mg)cH
4
= annual methane generation
in
the year of the calculation (m
3
year)
i = 1-year time increment
n =(year
of
the calculation) - (initial year o f waste acceptance)
j = 0.1-year time increment
tii = age of the jthsection of waste mass M accepted in the ith year
(decimal years , e.g ., 3.2 years)
k =methane generation rate (year ·
1
)
L
0
=potential methane generation capacity (m
3
/Mg)
When Model Calculates Closure Year ..
Final Non-Zero Acceptance Entered =
Waste Design Capacity =
Closure Year (with 80-year limit) =
Actual Closure Year (without limit)=
Model Waste Acceptance Limit =
Model Parameters from User Inputs :
11,136 megagrams in
1961
megagrams
1961
1961
80 years
METHANE-
1
k
= 0.040 year·
1
Lo
= 100 m
3
/Mg
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Appendix C.xls
10 /2/2008
User Waste
User Waste-In
Waste Waste-In-
Year
Acceptance
Place Acceptance
Place
Inputs
(Mg year) (Mg)
(Mg year)
(Mg)
1948
11 ' 136
0
11 '136
0
1949
11 ' 136 11 '136
11
' 136
11 '136
1950
11 ' 136
22,273
11 ' 136
22,273
1951
11 ' 136
33,409
11 ' 136
33,409
1952
11 ' 136
44,545
11 ' 136
44,545
1953
11
' 136
55,682
11 ' 136
55,682
1954
11 ' 136
66 ,818
11
' 136
66,818
1955
11
' 136 77,955
11
' 136 77,955
1956
11
' 136
89,
091
11 ' 136
89,
091
1957
11
' 136
100,227
11
' 136
100,227
1958
11 ' 136
111
,364
11
' 136
111
,364
1959
11
'136
122,500
11
'136
122,500
1960
11 '136
133,636
11 '136
133,636
1961
11 '136
144,773
11 ' 136
144,773
1962 0 155,909
0
155,909
1963
0
155,909
0
155,909
1964
0
155,909
0
155,909
1965
0
155,909
0
155,909
1966
0
155,909
0 155,909
1967
0
155,909
0
155,909
1968
0
155,909
0
155,909
1969 0 155,909 0 155,909
1970
0
155,909
0
155,909
1971
0
155,909
0
155,909
1972
0
155,909
0
155,909
1973 0 155,909
0
155,909
1974
0
155,909
0
155,909
1975
0
155,909
0
155,909
1976 0 155,909
0
155,909
1977
0
155,909
0
155,909
1978
0
155,909
0
155,909
1979
0
155,909
0
155,909
1980
0 155,909
0
155,909
1981
0
155,909
0
155,909
1982
0
155,909
0
155,909
1983 0 155,909 0 155,909
1984
0
155,909
0
155,909
1985
0
155,909
0
155,909
1986
0
155,909
0
155,909
1987
0
155,909
0
155,909
1988
0 155,909
0
155,909
1989
0
155,909
0
155,909
1990
0 155,909
0
155,909
1991
0 155,909
0
155,909
1992
0
155,909
0
155,909
1993
0
155,909
0
155,909
1994
0
155,909
0
155,909
1995
0
155,909
0
155,909
1996
0 155,909
0
155,909
1997
0
155,909
0
155,909
1998 0 155,909 0 155,909
1999
0
155,909
0
155,909
2000
0 155,909
0
155,909
2001
0
155,909
0
155,909
2002
0
155,909
0
155,909
2003
0 155,909
0
155,909
2004
0
155,909
0
155,909
2005
0
155,909
0
155,909
2006 0 155,909
0
155,909
2007
0
155,909
0
155,909
METHANE - 2
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Append ix C.xls 10/2/2008
User Waste
User Waste-In Waste
Waste-In-
Year
Acceptance
Place Acceptance
Place
Inputs
(Mg year) (Mg) (Mg year) (Mg)
2008 0
155,909
0
155,909
2009 0
155,909
0
155,909
2010 0
155,909
0
155,909
2011 0
155,909
0
155,909
2012
0
155,909
0
155,909
2013 0
155,909
0
155,909
2014 0
155,909
0
155,909
2015 0 155,909 0 155,909
2016 0
155,909
0
155,909
2017 0
155,909
0 155,909
2018 0
155,909
0
155,909
2019
0
155,909
0
155,909
2020
0
155,909
0
155,909
2021
0
155,909
0 155,909
2022
0
155,909
0
155,909
2023 0
155,909
0
155,909
2024
0
155,909
0
155,909
2025
0
155,909
0
155,909
2026 0
155,909
0
155,909
2027
0
155,909
0
155,909
ME
TH
ANE
- 3
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Appendix C.xls
GRAPHS
Landfill Name or Identifier:
(/)
c
0
·;;;
(/)
·e
w
---------------------------------------
Megagrams Per Year
1 400E+03
.,--
------------------------------------------------------,
1.200E+03 +------- ...-- 1
1.000E+03
8.000E+02
6.000E+02
4.000E+02
2.000E+02
O.OOOE+OO ~ ~ ' f i ' f f l ' ~ " f i ' f " ' ' t ' l ' l ' ' l " ' ' ' ~
; ; ; ; ; ; ; : ; ; ; ; ; ; ; r ~ m ; ; ; ; ; ; ; ; ; ~ ~ ~ ~ i i T i i i i i T i i i ~
~ ~ ~
~
~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~
~ ~ ~ ~ ~ ~ ~ ~
~
~ ~ ~ ~ ~
~
Year
-Total andfill gas
- Methane
- NMOC
- Hydrogen sulfide
(/)
c
0
·;;;
(/)
·e
w
Cubic Meters Per Year
8.000E+05
6.000E+05
4.000E+05
O.OOOE+OO
~
m " I " M " T m ' m m m T T ' I ~ T m T m m T T ' I ' i " ' m " T T T ~ ; : ; ; ; ; : ; : ; ; = ~ = ~ ~ ~ ~ ~ F F i i i ' ' l ' i ' i i i ' i ~
~
~
~
~
~ ~
~ ~ ~ ~ ~
~ ~
~ ~
~ ~ ~ ~
~
~
~ ~ ~ ~ ~ ~ ~ ~ ~
Year
-Total andfill gas
- Methane
- NMOC
- Hydrogen sulfide
(/)
c
0
·;;;
(/)
·e
w
User-specified Unit (units shown
in
legend below)
7.000E+01
6.000E+01
5.000E+01
4.000E+01
3.000E+01
2.000E+01
1.000E+01
O.OOOE+OO
' ' i ' m " ' i ' " " ' " l " " ' ' ' ' ' " ' " ' ' " " ' ' l ' l ' ' l " ' ' ' ' ' " m , . , . , . , . , ' m ' I ' I ' ' I " ' " ' ' ' T ~ ; ; ; : : : ;
= = ~ ~ ~ = ~ ~ T r m i m i ' i i ' ~
~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~
~ ~ ~
~
~
~ ~ ~ ~ ~
~ ~ ~
~
~
Year
-Total andfill gas (av ftA3/min)
- Methane (av ft"3/min)
- NMOC (av ft"3/min)
- Hydrogen sulfide (av ft"3/min)
GRAPHS-
1
10/2/2008
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Appendix C.xls
10/2/2008
INVENTORY Landfill Name or Identifier:
---------------------------------------
Enter year of emissions inventory:
Gas I Pollutant
Emission Rate
(Mg year) (m
3
/year)
(av
ft
3
min) (ft
3
year)
(short tons/yea
T ( ) t C ) I I ? . f 1 9 . ~ U 9(3S
Methane
Carbon dioxide
NMOC
O.OOOE+OO
O.OOOE+OO
O.OOOE+OO
O.
OOOE+OO
O.OOOE+OO
O.OOOE+OO
O.OOOE+OO
O.OOOE+OO
O.
OOOE+OO
O.OOOE+OO
O.OOOE+OO
O.OOOE+OO
O.OOOE+OO
......
.
.
OOOOE+OO
. ....
O.
OOOE+OO
O.OOOE+OO
...........•.....•...•.......•....•...•.•....••..•......
O.
OOOE+OO
O.OOOE+OO
O.OOOE+OO
O.
OOOE+OO
O.OOOE+OO
.
..................................................
1,1,1-Trichloroethane (methyl chloroform)-
HAP
1,1 2,2-Tetrachloroethane- HAPNOC
1,1-Dichloroethane (ethylidene dichloride)- HAPNOC
P i < : : b l ( ) r ( ) ~
b ~ r 1 ~ ( y i f 1 y l i 9 . ~ r 1 ~
< : : h l s > ~ i q ~ ) t i / \ P Y 9 g
1 P i < : : h l s > ~ ( ) ~ h < I r 1 ~ ( ~ t h . y l ~ l l ~ q i < : ; b l g ~ i g ~ ) ~ .ljJ.\F JYOg .....
1 2-Dichloropropane (propylene dichloride) - HAPNOC
2-Propanol (isopropyl alcoho l)- VOC
Acetone
Acrylonitrile - HAP/VOC
~ e n z e n e - No or Unknown 9 . i ~ p ( ) ~ C ) I - HAPNOC
Benzer1e C ( ) - q i ~ p ( ) ~ a l Hf\P.fY()(:
Bromodichloromethane - VOC
.....
····· ...........
Butane-
VOC
Carbon disulfide - HAP/VOC
Carbon monoxide
Carbon tetrachloride - HAP/VOC
9 < = . t
f 1 y l
? ~ l ~ g
ti.
f.\f.'./Y.'Qg ..........................................
Chlorobenzene - HAPNOC
Chlorodifluoromethane
Chloroethane (ethyl chloride) - HAPNOC
Chloroform - HAPNOC
Chloromethane -
VOC
p i g b l < ? ~ c : > ~ ~ r 1 ? ~ r 1 ~ ( 1 j , £ 1 , p f()rpar?. s o ~ ~ r t y Q C )
Dichlorodifluoromethane
Dichlorofluoromethane - VOC
Q i < : ; h i < ? E ( ) ~
( ~ ~ h Y I ~ f 1 ~ < : : h l s > r i g ~
O.OOOE+OO
O.
OOOE+OO
O.OOOE+OO
OOOOE+OO
O.OOOE+OO
O
OOOE+OO
O.OOOE+OO
O.OOOE+OO
O.
OOOE+OO
O.OOOE+OO
O.OOOE+OO
.......... ···· I·····
O.OOOE+OO
O.
OOOE+OO
O.OOOE+OO
O.
OOOE+OO
O.OOOE+OO
O.OOOE+OO
O.OOOE+OO
O.OOOE+OO
O.OOOE+OO
O.OOOE+OO
. • ..
i ····
.
O.OOOE+OO
O.OOOE+OO
O.OOOE+OO
O.
OOOE+OO
O.
OOOE+OO
O.OOOE+OO
O.OOOE+OO
O.OOOE+OO
O.OOOE+OO
O.
OOOE+OO
O.OOOE+OO
O.OOOE+OO
O.OOOE+OO
O.OOOE+OO
O.OOOE+OO
O.
OOOE+OO
O.OOOE+OO
O.OOOE+OO
O.OOOE+OO
O.OOOE+OO
O.OOOE+OO
O.
OOOE+OO
O.OOOE+OO
O.OOOE+OO
O.OOOE+OO
O.OOOE+OO
.......... - ······- ·--·
O.OOOE+OO
O.OOOE+OO
O.OOOE+OO
O.OOOE+OO
O.OOOE+OO
O.OOOE+OO
O.OOOE+OO
O.OOOE+OO
O.OOOE+OO
O.OOOE+OO
O.OOOE+OO
O.OOOE+OO
O.
OOOE+OO
O.OOOE+OO
O.
OOOE+OO
O.OOOE+OO
O.OOOE+OO
O.OOOE+OO
O.OOOE+OO
O.OOOE+OO
O.OOOE+OO
O.OOOE+OO
O.OOOE+OO
O.OOOE+OO
O.OOOE+OO
O.OOOE+OO
O.OOOE+OO
OOOOE+OO
O
OOOE+OO
O
OOOE+OO
O.OOOE+OO
OOOOE+OO
O
OOOE+OO
O.OOOE+OO
O.OOOE+OO
O.OOOE+OO
O.
OOOE+OO
O.OOOE+OO
O.OOOE+OO
O
OOOE+OO
O.OOOE+OO O
OOOE+OO
O.OOOE+OO O.OOOE+OO O.OOOE+OO
O.OOOE+OO
O.OOOE+OO
O.OOOE+OO
O.OOOE+OO O.OOOE+OO
O.OOOE+OO O.
OOOE+OO
O.OOOE+OO O.OOOE+OO
O.OOOE+OO O.OOOE+OO O.OOOE+OO
O.OOOE+OO
~ - - - - - - - - - - - - - - - - - - - - ~ ~ - - - - - - - - -
O.OOOE+OO
O.OOOE+OO
O.OOOE+OO
OOOOE+OO
....
O.OOOE+OO O.
OOOE+OO
O.OOOE+OO O.
OOOE+OO
.. .. . . . .
O.OOOE+OO O.OOOE+OO O.OOOE+OO O.OOOE+OO
........
O.OOOE+OO
O.OOOE+OO O.OOOE+OO OOOOE+OO
Dimethyl sulfide (methyl sul fide)- VOC O.OOOE+OO
O.OOOE+OO
O.OOOE+OO
O.OOOE+OO O.OOOE+OO
Ethane
O.OOOE+OO
O.OOOE+OO O.OOOE+OO O.OOOE+OO O
OOOE+OO
Ethanol - VOC O.OOOE+OO O.OOOE+OO O.OOOE+OO O.OOOE+OO O
OOOE+OO
Ethyl mercapt_.f1 _eth.anethiol)-
VOC
... .. ........... ........................ ..... . .9.:900E+OO
O.
OOOE+OO
O.OOOE+OO O.
OOOE+OO
OOOOE+OO
§ h . Y ~ ~ r 1 ~ ~ r 1 ~ l j \ P . / Y O g
.
Ethylene dibromide- HAP/VOC
Fluorotrichloromethane - VOC
Hexane - HAPNOC
Hydrogen sulfide
t \ - 1 ~ ~ < : ; u r y ( ()t<ll) -
HAP
_
M e t h . y l ~ t h . y l ~ ~ t ( ) f 1 ~ HAPNOC
Methyl
i S < : ) ~ l j t y l ~ ~ t ( ) l l ~
- HAP/VOC
~ h . Y I
. ~ < : : C 1 P C 1 r 1 ....=
\ Q9
Pentane
- VOC
Perchloroethylene (tetrachloroethylene)- HAP
Propane - VOC
l ? l < : : b l c : > ~ c : > ~ t h . ... \ Qg
T c : > l l j ~ r 1 ~ c : >
..
...
l:l
1 ~ r 1 c : > ' ' l l ... < : l i ~ p c : > ~ =ti \P.JY9C: ...
Toluene - Co-disposal - HAP/VOC
Trichloroethylene (trichloroethene)- HAP/VOC
Vinyl
chloride - HAPNOC
Xylenes - HAPNOC
O.OOOE+OO
O.OOOE+OO
O.
OOOE+OO
O.OOOE+OO
O.OOOE+OO
O.OOOE+OO
-----------
-----------
O.OOOE+OO
O.OOOE+OO
O.OOOE+OO
O.OOOE+OO
O.
OOOE+OO
O.OOOE+OO
O.OOOE+OO
O.OOOE+OO
O.OOOE+OO
O.OOOE+OO
O.
OOOE+OO
O.OOOE+OO
O.OOOE+OO
...... -----------------
O.
OOOE+OO
O.OOOE+OO
O.OOOE+OO
O.
OOOE+OO
O.OOOE+OO
O.OOOE+OO
O.OOOE+OO
O.OOOE+OO
O.OOOE+OO
O.
OOOE+OO
O.OOOE+OO
O.OOOE+OO
O.OOOE+OO
O.OOOE+OO
O.OOOE+OO
O.OOOE+OO
O.
OOOE+OO
O.OOOE+OO
O.OOOE+OO
O.OOOE+OO
O.OOOE+OO O.OOOE+OO O.OOOE+OO
••·•• •· ••· • · • · ••n•- ••••••••••••••••- •••••••••••- •••••••
O.
OOOE+OO
O.OOOE+OO O.OOOE+OO
O.OOOE+OO O.
OOOE+OO
O.
OOOE+OO
O.OOOE+OO O.OOOE+OO O.
OOOE+OO
O.
OOOE+OO
O.OOOE+OO O.OOOE+OO
O.OOOE+OO O.
OOOE+OO
O.OOOE+OO
O.OOOE+OO O.OOOE+OO O.OOOE+OO
0.888:::::
88 O.
OOOE+OO
O.OOOE+OO
•
········································································································································································································-················································
+
···················
·
····
·
········································
, ............................................... . . . . . . . . . . . . . . . . . . ............. .
O.OOOE+OO O.
OOOE+OO
O.OOOE+OO
O.OOOE+OO O.OOOE+OO O.OOOE+OO
O.OOOE+OO O.OOOE+OO
O.OOOE+OO
O.OOOE+OO O.OOOE+OO O.
OOOE+OO
O.
OOOE+OO O.OOOE+OO
O.OOOE+OO
O.OOOE+OO O.
OOOE+OO
O.
OOOE+OO
O.OOOE+OO O.OOOE+OO . O.
OOOE+OO
INVENTORY- 1
·········-··········-··-····
O.OOOE+OO O.OOOE+OO
O.OOOE+OO O.OOOE+OO
O.OOOE+OO OOOOE+OO
O.OOOE+OO
O
OOOE+OO
O.OOOE+OO OOOOE+OO
O.OOOE+OO OOOOE+OO
O.OOOE+OO
O
OOOE+OO
. . . . . . .
O.OOOE+OO
OOOOE+OO
O.OOOE+OO
O.OOOE+OO
O.OOOE+OO
O.
OOOE+OO
O.OOOE+OO
O.OOOE+OO
O
OOOE+OO
O.OOOE+OO
O.OOOE+OO
O.OOOE+OO
O.OOOE+OO
O.OOOE+OO
O.OOOE+OO
O.OOOE+OO
O.
OOOE+OO
O.OOOE+OO
O.OOOE+OO
O.OOOE+OO
O.
OOOE+OO
O.
OOOE+OO
···
I ··········
O.OOOE+OO
O.OOOE+OO
O.OOOE+OO
O.
OOOE+OO
O.OOOE+OO
O.
OOOE+OO
------------------------------------·····
...
O.OOOE+OO
O
OOOE+OO
O
OOOE+OO
O.OOOE+OO
OOOOE+OO
OOOOE+OO
O.OOOE+OO
O.OOOE+OO
OOOOE+OO
O
OOOE+OO
O.OOOE+OO
O.OOOE+OO
O.OOOE+OO
O.
OOOE+OO
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Appendix C.xls
&EPA
LandGEM
Landfill Gas Emissions Model
Version 3.02
U.S. Enviromnental Protection Agency
Office ofResearch and Development
National Risk Management Research Laboratory (NRMRL)
and
Clean Air Technology Center (CATC)
Research Triangle Park, North Carolina
Summary Report
Landfill Name or Identifier:
Date: Thursday, October 02, 2008
Description/Comments:
About LandGEM:
First-Order Decomposition Rate Equation :
n
1
[M
·J
cH4 =
L L
kLa
l
e -ktjj
i=l
j=O.l
1
Q
Where,
O
cH
4
=annual
methane generation
in
the year of the calculation (m
3
/year)
i = 1-year time increment
Mi =mass
of
waste accepted in the i
1
h year (Mg)
10/2/2008
n = (year
of
the calculation)- (initial year of waste acceptance)
j = 0.1-year time increment
tii = age of the
j
1
h section of waste mass Mi accepted in the i
1
h year
(decimal years, e.g ., 3.2 years)
k = methane qeneration rate (vear -
1
)
La = potential methane generation capacity (m
3
/Mg)
LandGEM is based on a first-order decomposition rate equation for quantifying emissions from the decomposition of landfilled waste in
municipal solid waste (MSW) landfills. The software provides a relatively simple approach to estimating landfill gas emissions. Model defaults
are based on empirical data from U.S. landfills. Field test data can also be used in place of model defaults when available. Further guidance on
EPA test methods, Clean Air Act (CAA) regulations, and other guidance regarding landfill gas emissions and control technology requirements
can
be
found at http://www.epa.gov/ttnatw01/landfill/landflpg.html.
LandGEM is considered a screening too l - the better the input data, the better the estimates. Often , there are limitations with the available data
regarding waste quantity and composition, variation in design and operating practices over time, and changes occurring over time that impact
the emissions potential. Changes to landfill operation , such as operating under wet conditions through leachate recirculation or other liquid
additions, will result
in
generating more gas at a faster rate . Defaults for estimating emissions for this type
of
operation are being developed to
include
in
LandGEM along with defaults for conventiallandfills (no leachate or liquid additions) for developing emission inventories and
determining CAA applicability. Refer to the Web site identified above for future updates.
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Appendix C.xls
Input Review
LANDFILL CHARACTERISTICS
Landfill Open Year
Landfill Closure Year (with 80-year limit)
Actual Closure Year (without limit)
Have Model Calculate Closure Year?
Waste Design Capacity
MODEL PARAMETERS
Methane Generation Rate, k
Potential Methane Generation Capacity, La
NMOC Concentration
Methane Content
GASES I POLLUTANTS SELECTED
Gas I Pollutant #1:
Gas I Pollutant #2:
Total landfill gas
Methane
Gas I Pollutant #3: NMOC
Gas
I
Pollutant #4: Hydrogen sulfide
WASTE ACCEPTANCE RATES
Year
Waste Accepted
(Mglyear) (short tons/year)
1948
11 I 136 12,250
1949
11
1136 12,250
1950 111136 12,250
1951
111136 12 ,250
1952 11 1136 12 ,250
1953
111136
12,250
1954
111136 12,250
1955 11 I 136 12,250
1956
11 1136
12
,250
1957
111136
12
,250
1958 11 I 136
12
,250
1959
11 1136
12
,250
1960
111136 12 ,250
1961
111136 12 ,250
1962
0 0
1963
0
0
1964 0
0
1965 0
0
1966 0
0
1967
0 0
1968
0 0
1969
0 0
1970
0
0
1971
0
0
1972 0
0
1973 0
0
1974 0
0
1975 0
0
1976
0
0
1977 0
0
1978 0
0
1979 0
0
1980 0 0
1981
0
0
1982 0
0
1983
0 0
1984
0 0
1985
0
0
1986 0
0
1987
0
0
1948
1961
1961
No
0.040
100
600
50
short tons
year
-
1
m
3
/Mg
ppmv as hexane
%by
volume
Waste-In-Place
(Mg) (short tons)
0
0
111136
12,250
22,273
24,500
33,409
36,750
44,545
49,000
55,682
61,250
66,818
73,500
77,955
85,750
89,091
98,000
100,227
110,250
111,364
122,500
122,500 134,750
133,636 147,000
144,773
159,250
155,909
171,500
155,909
171,500
155,909
171,500
155,909 171,500
155,909 171,500
155,909 171,500
155,909 171 ,500
155,909
171
,500
155,909
171
,500
155,909
171
,500
155,909
171
,500
155,909
171,500
155,909 171,500
155,909 171 ,500
155,909
171
,500
155,909
171,500
155,909 171,500
155,909 171,500
155,909
171
,500
155,909
171
,500
155,909 171,500
155,909 171,500
155,909
171,500
155,909
171
,500
155,909 171,500
155,909
171 ,500
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Appendix C.xls 10/2/2008
WASTE ACCEPTANCE RATES (Continued)
Year
Waste Accepted
Waste-In-Place
(Mg year)
(short tons/year)
(Mg)
(short tons)
1988 0 0
155,909
171 ,500
1989 0 0 155,909 171,500
1990
0 0
155,909
171,500
1991
0 0
155,909
171
,500
1992 0
0
155,909 171,500
1993
0 0
155,909
171,500
1994
0 0
155,909
171,500
1995
0 0
155,909
171
,500
1996 0 0 155,909 171,500
1997 0
0
155,909
171,500
1998 0 0
155,909
171,500
1999 0
0
155,909
171,500
2000
0 0
155,909
171,500
2001
0
0
155,909 171,500
2002
0 0
155,909
171,500
2003
0 0
155,909
171
,500
2004 0 0
155,909
171,500
2005
0 0
155,909
171 ,500
2006 0
0
155,909 171,500
2007
0 0
155,909
171,500
2008 0
0
155,909 171,500
2009 0 0
155,909
171,500
2010
0 0
155,909
171,500
2011
0 0 155,909 171,500
2012 0
0
155,909
171,500
2013
0 0
155,909
171,500
2014 0
0
155,909
171
,500
2015 0 0
155,909
171
,500
2016 0
0
155,909 171,500
2017
0 0
155,909
171,500
2018 0 0
155,909
171,500
2019 0
0
155,909
171
,500
2020 0
0
155,909
171,500
2021
0 0 155,909
171
,500
2022 0 0 155,909 171,500
2023 0
0
155,909
171
,500
2024 0
0
155,909 171 ,500
2025 0
0
155,909
171
,500
2026 0 0 155,909 171,500
2027 0 0 155,909 171,500
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Appendix C.xls
10/2/2008
Pollutant Parameters
G
I P II t t D
f
It P
s
o
u an
e au
arame ers:
User-specified Pollutant Parameters:
Concentration Concentration
Compound
(ppmv)
Molecular Weight
(ppmv) Molecular Weight
Total landfill gas 0.00
1/)
Methane
)
16 .04
1/)
co
Carbon dioxide
44.01
( )
NMOC
4,000
86 .18
1,1,
1-
Trichloroethane
(methyl chloroform)-
HAP 0.48 133.41 0.00
1,1,2,2-
Tetrachloroethane -
HAPNOC
1.1
167.85
0.00
1, 1-Dichloroethane
(ethylidene dichloride)-
HAPNOC
2.4 98.97 0.00
1, 1-Dichloroethene
(vinylidene chloride)-
HAPNOC
0.20 96 .94 0.00
1 2-Dichloroethane
(ethylene dichloride)-
HAPNOC
0.41 98 .96
0.00
1 2-Dichloropropane
(propylene dichloride)-
HAPNOC
0.18 112.99 0.02
2-Propanol (isopropyl
alcohol) - VOC
50
60.11
Acetone
7.0 58.08
0.
01
Acrylonitrile -
HAPNOC
6.3 53.06
Benzene - No or
Unknown Co-disposal-
HAPNOC
1.9
78.11
0.09
Benzene - Co-disposal -
1/)
HAPNOC
11
78.
11
1:
Bromodichloromethane -
co
:§
voc
3.1 163.83 0.00
0
Butane-
VOC
5.0 58.12
a.
Carbon disulfide -
HAPNOC
0.58 76.13
0.
01
Carbon monoxide
140 28.01
0.00
Carbon tetrachloride -
HAPNOC
4.0E-03
153.84 0.00
Carbonyl sulfide -
HAPNOC
0.49 60 .07 0.90
Chlorobenzene -
HAPNOC
0.25 112.56
0.00
Chlorodifluoromethane 1.3 86.47
Chloroethane (ethyl
chloride) -
HAPNOC
1.3
64 .52 0.00
Chloroform -
HAPNOC
0.03 119.39 0.00
Chloromethane - VOC 1.2 50.49 0.00
Dichlorobenzene - (HAP
for para isomerNOC)
0.
21
147 0.
01
Dichlorodifluoromethane
16 120.91 0.02
.........
..
.....
..........
...
.. ..
.
..
.........
.. ..
.......
..
Dichlorofluoromethane -
voc
2.6
102.92
Dichloromethane
(methylene chloride) -
HAP 14 84.94 0.00
Dimethyl sulfide (methyl
sulfide) - VOC
7.8
62.13 0.05
Ethane 890 30.07
Ethanol - VOC
27
46.08
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Appendix C.xls 10/2/2008
Pollutant Parameters (Continued)
G I P II t t D f It P
s
o u an
e
au
arame ers:
User-specified Pollutant Parameters:
Concentration
Concentration
Compound (ppmv) Molecular Weight
(ppmv)
Molecular Weight
Ethyl mercaptan
(ethanethiol)- VOC 2.3
62.13 0.03
Ethylbenzene -
HAPNOC
4.6
106.16 0.08
Ethylene dibromide-
HAPNOC
1.0E-03 187.88
Fluorotrichloromethane -
voc
0.76 137.38 0.00
Hexane - HAPNOC 6.6
86.18
Hydrogen sulfide 36
34.08 0.90
Mercury (total)- HAP
2.9E-04 200.61
Methyl ethyl ketone -
HAPNOC 7.1
72.11 0.01
Methyl isobutyl ketone -
HAPNOC
1.9 100.16
Methyl mercaptan - VOC
2.5 48.11 0.05
Pentane - VOC 3.3 72.15
Perchloroethylene
(tetrachloroethylene) -
HAP
3.7 165.83 0.00
Propane - VOC
11
44.09
t-1 ,2-Dichloroethene-
voc
2.8 96 .94 0.00
Toluene - No or
Unknown Co-disposal -
HAPNOC
39
92.13 0.07
Toluene- Co-disposal -
HAPNOC
170 92.13 0.07
Trichloroethylene
1/)
(trichloroethene)-
E
HAPNOC
ctS
2.8 131.40 0.00
:;
Vinyl chloride -
0
HAPNOC
7.3 62 .50 0.19
ll..
Xylenes -
HAPNOC
12
106.16 0.24
REPORT-
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Appendix C.xls
10/2/2008
REPORT-
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Appendix C.xls
Graphs
VI
1::
0
·u;
VI
.E
w
VI
1::
0
·u;
VI
.E
w
VI
1::
0
·u;
VI
.E
w
Megagrams Per Year
1.400E+03
1.200E+03
1
OOOE+03
8 OOOE+02
6.000E+02
4.000E+02
2.000E+02
OOOOE+OO
~
~
~ ~ ~ ~
~
~ ~
~ ~ w
* ~ ~ ~
~
~ ~
~ ~
~
~
~ ~
~
~
~ ~ ~ ~ ~ ~ ~ ~ ~
~
~
Year
- - T o t a l
landfill gas
Methane
NMOC
Hydrogen sulfide
Cubic Meters Per Year
1.200E+06
1.000E+06
8.000E+05
6 OOOE+05
4.000E+05
2
OOOE+05
O.OOOE+OO
~ $ $ ~ ~ ~ ~ ~
~ ~ ~ ~ ~ ~ ~
Year
- - T o t a l
landfill gas Methane NMOC
Hydrogen sulfide
User-specified Unit (units shown in legend below)
7.000E+01
6 OOOE+01
5.000E+01
4 OOOE+01
3.000E+01
2.000E+01
1.000E+01
O.OOOE+OO
~ ~ ~ ~ ~ ~
~
~ ~
~
~ w * ~ ~ ~ ~ ~ ~
~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~
Year
- -T o ta l landfill gas (av ft"3/min) Methane (av ft"3 /min)
NMOC (av ft"3/m in) Hydrogen sulfide (av ft"3/min)
REPORT- 7
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Append ix C .xls
10/2/2008
Results
Year
Total landfill gas
Methane
(Mg year) (m
3
/year) (av ft"31min) (Mg year) (m
3
/year)
(av ft"31min)
1948
0 0 0 0
0 0
1949
1.093E+02
8.751 E+04
5.880E+OO 2.919E+01
4.375E+04 2.
940E+OO
1950 2.143E+02 1.716E+05 1.153E+01 5.724E+01
8.579E+04 5.764E+OO
1951
3.152E+02 2.524E+05 1.696E+01 8.418E+01
1.262E+05 8.478E+OO
1952
4.121 E+02
3.300E+05
2.217E+01
1.101E+02
1.650E+05 1.109E+01
1953 5.052E+02 4.045E+05 2.718E+01 1.349E+02
2.023E+05 1.359E+01
1954 5.947E+02 4.762E+05 3.200E+01 1.588E+02 2.381E+05 1.600E+01
1955 6.806E+02 5.450E+05 3.662E+01 1.818E+02
2.725E+05 1.831 E+01
1956
7.632E+02
6.112E+05
4.106E+01
2.039E+02
3.056E+05 2.053E+01
1957 8.426E+02 6.747E+05 4.533E+01 2.251 E+02
3.374E+05 2.267E+01
1958
9.188E+02 7.358E+05 4.944E+01 2.454E+02
3.679E+05
2.472E+01
1959 9.921 E+02 7.944E+05 5.338E+01 2.650E+02
3.972E+05 2.669E+01
1960
1.062E+03 8.508E+05 5.716E+01
2.838E+02
4.254E+05
2.858E+01
1961 1.130E+03 9.049E+05 6.080E+01 3.019E+02
4.525E+05 3.040E+01
1962
1.195E+03 9.569E+05 6.430E+01
3.192E+02
4.785E+05
3.215E+01
1963
1.148E+03 9.194E+05 6.178E+01 3.067E+02
4.597E+05 3.089E+01
1964 1.103E+03 8.834E+05
5.935E+01
2.947E+02
4.417E+05
2.968E+01
1965
1.060E+03 8.487E+05 5.703E+01 2.831 E+02
4.244E+05 2.851 E+01
1966 1.018E+03 8.155E+05 5.479E+01 2.720E+02
4.077E+05
2.740E+01
1967
9.784E+02 7.835E+05 5.264E+01
2.613E+02
3.917E+05
2.632E+01
1968
9.401 E+02 7.528E+05 5.058E+01 2.
511
E+02
3.764E+05 2.529E+01
1969 9.032E+02 7.232E+05 4.859E+01 2.413E+02 3.616E+05 2.430E+01
1970 8.678E+02 6.949E+05 4.669E+01 2.318E+02
3.474E+05 2.334E+01
1971
8.338E+02 6.676E+05 4.486E+01
2.227E+02
3.338E+05
2.243E+01
1972 8.011 E+02 6.415E+05 4.310E+01 2.140E+02
3.207E+05 2.155E+01
1973
7.697E+02 6.163E+05 4.141E+01 2.056E+02
3.082E+05
2.070E+01
1974 7.395E+02 5.921 E+05 3.979E+01 1.975E+02
2.961E+05
1.989E+01
1975 7.105E+02 5.689E+05 3.823E+01 1.898E+02
2.845E+05 1.911 E+01
1976
6.826E+02
5.466E+05
3.673E+01
1.823E+02
2.733E+05
1.836E+01
1977 6.559E+02 5.252E+05 3.529E+01 1.752E+02
2.626E+05
1.764E+01
1978 6.301 E+02 5.046E+05 3.390E+01 1.683E+02
2.523E+05 1.695E+01
1979
6.054E+02 4.848E+05 3.257E+01 1.617E+02
2.424E+05 1.629E+01
1980
5.817E+02
4.658E+05
3.130E+01
1.554E+02
2.329E+05
1.565E+01
1981 5.589E+02 4.475E+05 3.007E+01 1.493E+02
2.238E+05
1.503E+01
1982 5.370E+02 4.300E+05 2.889E+01 1.434E+02
2.150E+05 1.445E+01
1983 5.159E+02 4.131 E+05 2.776E+01 1.378E+02
2.066E+05 1.388E+01
1984
4.957E+02 3.969E+05 2.667E+01 1.324E+02
1.985E+05 1.333E+01
1985 4.763E+02 3.814E+05 2.562E+01 1.272E+02 1.907E+05 1.281 E+01
1986
4.576E+02 3.664E+05 2.462E+01 1.222E+02
1.832E+05
1.231 E+01
1987
4.396E+02 3.520E+05 2.365E+01
1.174E+02 1.760E+05 1.183E+01
1988
4.224E+02
3.382E+05
2.273E+01
1.128E+02
1.691 E+05
1.136E+01
1989
4.058E+02
3.250E+05
2.183E+01
1.084E+02
1.625E+05
1.092E+01
1990
3.899E+02
3.122E+05 2.098E+01 1.042E+02
1.561 E+05 1.049E+01
1991 3.746E+02 3.000E+05 2.016E+01 1.001 E+02
1.500E+05 1.008E+01
1992
3.599E+02 2.882E+05 1.937E+01 9.614E+01
1.441 E+05 9.
683E+OO
1993 3.458E+02 2.769E+05 1.861 E+01 9.238E+01
1.385E+05 9.303E+OO
1994
3.323E+02 2.661 E+05 1.788E+01 8.875E+01
1.330E+05 8.
938E+OO
1995
3.192E+02
2.556E+05
1.718E+01
8.527E+01
1.278E+05
8.588E+OO
1996
3.067E+02
2.456E+05 1.650E+01 8.193E+01
1.228E+05
8.251E+OO
1997 2.947E+02 2.360E+05 1.586E+01 7.872E+01
1.180E+05 7.928E+OO
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Append ix C.xls
10/2/2008
Results (Continued)
Year
Total landfill gas
Methane
(Mg year)
m
3
year)
(av
ft11.3fmin)
(Mglyear)
m
3
/year)
(av
ft11.3fmin)
1998
2.
831
E+02
2.267E+05
1.523E+01
7.563E+01
1.134E+05
7.617E+OO
1999
2.720E+02
2.178E+05 1.464E+01 7.266E+01
1.089E+05 7.318E+OO
2000 2.614E+02 2.093E+05 1.406E+01 6.982E+01
1.046E+05 7.031E+OO
2001 2.
511
E+02
2.011 E+05 1.351 E+01 6.708E+01
1.005E+05 6.
756E+OO
2002 2.413E+02 1.932E+05 1.298E+01 6.445E+01
9.660E+04
6.491 E+OO
2003 2.318E+02
1.856E+05
1.247E+01
6.192E+01
9.281E+04 6.236E+OO
2004 2.227E+02 1.783E+05 1.198E+01 5.949E+01 8.917E+04 5.992E+OO
2005 2.140E+02 1.714E+05 1.151 E+01
5.716E+01
8.568E+04 5.
757E+OO
2006
2.056E+02
1.646E+05 1.106E+01 5.492E+01
8.232E+04 5.531E+OO
2007 1.975E+02 1.582E+05 1.063E+01
5.277E+01
7.909E+04
5.314E+OO
2008
1.898E+02
1.520E+05 1.021 E+01 5.070E+01
7.599E+04 5.106E+OO
2009 1.824E+02 1.460E+05 9.811 E+OO
4.871 E+01
7.301 E+04
4.906E+OO
2010
1.752E+02
1.403E+05 9.426E+OO 4.680E+01
7.015E+04 4.713E+OO
2011 1.683E+02 1.348E+05 9.057E+OO
4.496E+01
6.740E+04
4.528E+OO
2012
1.617E+02
1.295E+05 8.702E+OO 4.320E+01
6.475E+04 4.351 E+OO
2013 1.554E+02 1.244E+05
8.360E+OO 4.151E+01
6.222E+04
4.
180E+OO
2014 1.493E+02 1.196E+05 8.033E+OO
3.988E+01 5.978E+04 4.
016E+OO
2015
1.434E+02
1.149E+05 7.718E+OO 3.832E+01
5.743E+04 3.859E+OO
2016 1.378E+02
1.1
04E+05 7.415E+OO
3.681 E+01
5.518E+04
3.708E+OO
2017
1.324E+02
1.060E+05 7.124E+OO 3.537E+01
5.302E+04 3.562E+OO
2018 1.272E+02 1.019E+05
6.845E+OO 3.398E+01
5.094E+04
3.422E+OO
2019 1.222E+02 9.788E+04 6.577E+OO 3.265E+01 4.894E+04 3.288E+OO
2020 1.174E+02 9.404E+04
6.319E+OO 3.137E+01
4.702E+04 3.159E+OO
2021
1.128E+02
9.036E+04 6.071E+OO 3.014E+01
4.518E+04 3.
035E+OO
2022 1.084E +02 8.681 E+04 5.833E+OO
2.896E+01
4.341E+04
2.
916E+OO
2023
1.042E+02
8.
341
E+04 5.604E+OO 2.782E+01
4.170E+04 2.802E+OO
2024
1.001 E+02
8.014E+04 5.384E+OO
2.673E+01
4.007E+04
2.692E+OO
2025 9.615E+01 7.700E+04
5.173E+OO 2.568E+01
3.850E+04 2.587E+OO
2026
9.238E+01
7.398E+04 4.970E+OO 2.468E+01
3.699E+04 2.485E+OO
2027 8.876E+01 7.108E+04 4.776E+OO
2.
371
E+01
3.554E+04
2.388E+OO
2028 8.528E+01
6.829E+04 4.588E+OO 2.278E+01
3.414E+04
2.294E+OO
2029
8.194E+01
6.561 E+04 4.408E+OO 2.189E+01
3.281E+04 2.204E+OO
2030
7.872E+01
6.304E+04 4.236E+OO 2.103E+01
3.152E+04 2.118E+OO
2031 7.564E+01 6.057E+04 4.069E+OO
2.020E+01
3.028E+04
2.035E+OO
2032 7.267E+01 5.819E+04 3.910E+OO
1.941E+01
2.910E+04
1.955E+OO
2033 6.982E+01 5.591 E+04
3.757E+OO 1.865E+01
2.796E+04
1.878E+OO
2034 6.708E+01
5.372E+04 3.609E+OO 1.792E+01
2.686E+04
1.805E+OO
2035 6.445E+01 5.161 E+04 3.468E+OO 1.722E+01 2.581 E+04 1.734E+OO
2036
6.193E+01
4.959E+04 3.332E+OO 1.654E+01
2.479E+04 1.
666E+OO
2037
5.950E+01
4.764E+04 3.201 E+OO 1.589E+01
2.382E+04 1.601 E+OO
2038
5.717E+01
4.578E+04 3.076E+OO 1.527E+01
2.289E+04 1.538E+OO
2039
5.492E+01
4.398E+04 2.955E+OO 1.467E+01
2.199E+04 1.478E+OO
2040
5.277E+01
4.226E+04 2.839E+OO
1.410E+01
2.113E+04
1.420E+OO
2041 5.070E+01 4.060E+04 2.728E+OO
1.354E+01
2.030E+04
1.364E+OO
2042 4.871 E+01 3.901 E+04
2.621E+OO 1.301 E+01
1.950E+04 1.
310E+OO
2043 4.680E+01
3.748E+04 2.518E+OO 1.250E+01
1.874E+04 1.259E+OO
2044 4.497E+01
3.601 E+04 2.419E+OO 1.201 E+01
1.800E+04 1.210E+OO
2045
4.320E+01
3.460E+04 2.325E+OO
1.154E+01
1.730E+04
1.
162E+OO
2046
4.151 E+01
3.324E+04
2.233E+OO 1.109E+01
1.662E+04 1.117E+OO
2047 3.988E+01 3.194E+04
2.146E+OO 1.065E+01
1.597E+04
1.073E+OO
2048 3.832E+01
3.068E+04 2.062E+OO 1.024E+01
1.534E+04 1.031 E+OO
REPORT-9
8/11/2019 Brimbal Ave. - Environmental Notification Form - 9.2.14 - Volume 2 of 2
http://slidepdf.com/reader/full/brimbal-ave-environmental-notification-form-9214-volume-2-of-2 555/798
Appendix C.xls
10/2/2008
Results (Continued)
Year
Total landfill gas
Methane
(Mg year)
m
3
/year)
(av ftA3fmin)
(Mg/year)
(m
3
year)
j v ftA3fmin)
2049 3.682E+01 2.948E+04 1.981 E+OO 9.834E+OO
1.474E+04
9.904E-01
2050 3.537E+01
2.833E+04
1.903E+OO
9.449E+OO
1.416E+04 9.516E-01
2051 3.399E+01 2.721 E+04
1.829E+OO
9.078E+OO
1.361 E+04 9.143E-01
2052 3.265E+01 2.615E+04 1.757E+OO
8.722E+OO
1.307E+04 8.784E-01
2053 3.137E+01
2.512E+04
1.688E+OO
8.380E+OO
1.256E+04 8.440E-01
2054 3.014E+01 2.414E+04 1.622E+OO
8.051 E+OO 1.207E+04
8.109E-01
2055 2.896E+01 2.319E+04 1.558E+OO 7.736E+OO 1.160E+04 7.791 E-01
2056
2.783E+01
2.228E+04 1.497E+OO
7.432E+OO 1.114E+04
7.485E-01
2057 2.673E+01 2.141E+04 1.438E+OO
7.141
E+OO
1.070E+04 7.192E-01
2058
2.569E+01
2.057E+04 1.382E+OO 6.861E+OO
1.028E+04
6.910E-01
2059 2.468E+01 1.976E+04 1.328E+OO
6.592E+OO
9.881E+03 6.639E-01
2060
2.371 E+01
1.899E+04 1.276E+OO 6.334E+OO
9.493E+03 6.379E-01
2061 2.278E+01 1.824E+04 1.226E+OO
6.085E+OO
9.121E+03 6.129E-01
2062
2.189E+01
1.753E+04 1.178E+OO 5.847E+OO
8.764E+03 5.888E-01
2063
2.103E+01 1.684E+04 1.131E+OO
5.617E+OO
8.420E+03 5.657E-01
2064 2.021 E+01 1.618E+04 1.087E+OO 5.397E+OO
8.090E+03 5.436E-01
2065
1.941 E+01 1.555E+04
1.044E+OO 5.185E+OO
7.773E+03 5.222E-01
2066 1.865E+01 1.494E+04 1.004E+OO 4 .982E+OO
7.468E+03
5.018E-01
2067
1.792E+01
1.435E+04 9.642E-01 4.787E+OO
7.175E+03 4.821 E-01
2068 1.722E+01 1.379E+04 9.264E-01
4.599E+OO
6.894E+03 4.632E-01
2069 1.654E+01 1.325E+04 8.900E-01 4.419E+OO
6.623E+03 4.450E-01
2070 1.589E+01 1.273E+04 8.551 E-01
4.245E+OO
6.364E+03 4.276E-01
2071 1.527E+01 1.223E+04 8.216E-01 4.079E+OO
6.114E+03 4.108E-01
2072
1.467E+01 1.175E+04 7.894E-01
3.919E+OO
5.874E+03 3.947E-01
2073 1.410E+01 1.129E+04 7.584E-01 3.765E+OO
5.644E+03 3.792E-01
2074 1.354E+01 1.085E+04 7.287E-01
3.618E+OO
5.423E+03 3.644E-01
2075
1.301 E+01
1.042E+04 7.001 E-01 3.476E+OO
5.210E+03 3.501 E-01
2076 1.250E+01 1.001 E+04 6.727E-01
3.340E+OO 5.006E+03
3.363E-01
2077 1.201 E+01 9.619 E+03 6.463E-01
3.209E+OO
4.810E+03 3.232E-01
2078
1.154E+01
9.242E+03 6.210E-01 3.083E+OO
4.621E+03 3.105E-01
2079 1.109E+01 8.880E+03 5.966E-01
2.962E+OO
4.440E+03
2.983E-01
2080
1.065E+01 8.531 E+03 5.732E-01
2.846E+OO
4.266E+03 2.866E-01
2081
1.024E+01
8.197E+03 5.507E-01 2.734E+OO
4.098E+03 2.754E-01
2082 9.835E+OO 7.875 E+03 5.
291
E-01 2.627E+OO
3.938E+03 2.646E-01
2083
9.449E+OO
7.567E+03 5.084E-01 2.524E+OO
3.783E+03 2.542E-01
2084 9.079E+OO 7.270E+03 4.885E-01 2.425E+OO
3.635E+03 2.442E-01
2085 8.723E+OO 6.985 E+03 4.693E-01
2.330E+OO 3.492E+03 2.347E-01
2086 8.381
E+OO
6.711 E+03 4.509E-
01
2.239E+OO 3.355E+03 2.255E-
01
2087 8.052E+OO 6.448 E+03
4.332E-01 2.151 E+OO
3.224E+03 2.166E-01
2088 7.736E+OO 6.195E+03 4.162E-01 2.067E+OO
3.098E+03 2.081 E-01
REPORT-
10
8/11/2019 Brimbal Ave. - Environmental Notification Form - 9.2.14 - Volume 2 of 2
http://slidepdf.com/reader/full/brimbal-ave-environmental-notification-form-9214-volume-2-of-2 556/798
Appendix C.xls 10/2/2008
Results (Continued)
Year
NMOC
Hydrogen sulfide
(Mg/year)
m
3
year)
(av ft/\3/min)
(Mg year)
m
3
/year)
(av ft/\3/min)
1948
0
0
0
0
0
0
1949 1.882E-
01
5.250E+01 3.528E-03
1.116E-04 7.876E-02 5.292E-06
1950 3.690E-
01
1.030E+02 6.917E-03
2.189E-04
1.544E-01
1.038E-05
1951 5.428E-01 1.514E+02 1.017E-02 3.219E-04
2.271 E-01 1.526E-05
1952 7.097E-01 1.980E+02 1.330E-02
4.210E-04
2.970E-01
1.995E-05
1953
8.700E-01
2.427E+02
1.631 E-02
5.161 E-04
3.641 E-01 2.446E-05
1954 1.
024E+OO
2.857E+02 1.920E-02 6.075E-04 4.286E-01 2.880E-05
1955 1.172E+OO 3.270E+02
2.197E-02 6.953E-04
4.905E-01 3.296E-05
1956 1.314E+OO 3.667E+02 2.464E-02
7.797E-04
5.500E-01
3.696E-05
1957 1.451 E+OO 4.048E+02 2.720E-02
8.607E-04
6.072E-01 4.080E-05
1958
1.582E+OO
4.415E+02 2.966E-02 9.386E-04
6.622E-01 4.449E-05
1959 1.709E+OO 4.766E+02
3.203E-02 1.013E-03
7.150E-01 4.804E-05
1960 1.
830E+OO
5.105E+02 3.430E-02
1.085E-03 7.657E-01 5.145E-05
1961 1.946E+OO 5.430E+02
3.648E-02 1.154E-03
8.144E-01
5.472E-05
1962
2.058E+OO
5.742E+02 3.858E-02
1.221 E-03 8.613E-01 5.787E-05
1963
1.977E+OO 5.517E+02
3.707E-02 1.173E-03
8.275E-01 5.560E-05
1964 1.900E+OO 5.300E+02 3.561 E-02
1.127E-03
7.950E-01
5.342E-05
1965
1.825E+OO
5.092E+02 3.422E-02 1.083E-03
7.639E-01 5.132E-05
1966 1.754E+OO 4.893E+02
3.287E-02 1.040E-03
7.339E-01
4.931 E-05
1967
1.685E+OO
4.701 E+02 3.159E-02
9.995E-04 7.051 E-01 4.738E-05
1968
1.619E+OO 4.517E+02
3.035E-02 9.603E-04
6.775E-01
4.552E-05
1969
1.
555E+OO
4.339E+02 2.916E-02 9.227E-04 6.509E-01 4.374E-05
1970 1.494E+OO 4.169E+02
2.801E-02 8.865E-04
6.254E-01 4.202E-05
1971
1.436E+OO
4.006E+02 2.692E-02
8.517E-04
6.009E-01
4.037E-05
1972
1.380E+OO 3.849E+02
2.586E-02 8.183E-04
5.773E-01
3.879E-05
1973
1.325E+OO
3.698E+02 2.485E-02 7.862E-04
5.547E-01 3.727E-05
1974 1.
274E+OO
3.553E+02 2.387E-02
7.554E-04
5.329E-01
3.581 E-05
1975
1.224E+OO
3.414E+02 2.294E-02 7.258E-04
5.120E-01 3.440E-05
1976
1.
176E+OO
3.280E+02 2.204E-02
6.973E-04 4.920E-01 3.305E-05
1977 1.130E+OO 3.151 E+02
2.117E-02 6.700E-04
4.727E-01
3.176E-05
1978
1.085E+OO 3.028E+02
2.034E-02 6.437E-04
4.541 E-01 3.051 E-05
1979
1.043E+OO
2.909E+02 1.954E-02 6.185E-04
4.363E-01 2.932E-05
1980 1.002E+OO 2.795E+02 1.878E-02
5.942E-04
4.192E-01
2.817E-05
1981 9.625E-01 2.685E+02 1.804E-02
5.709E-04
4.028E-01
2.706E-05
1982 9.248E-01 2.580E+02
1.733E-02 5.485E-04
3.870E-01
2.600E-05
1983 8.885E-01 2.479E+02
1.665E-02 5.270E-04
3.718E-01
2.498E-05
1984
8.537E-01 2.382E+02
1.600E-02 5.064E-04
3.572E-01
2.400E-05
1985 8.202E-01 2.288E+02 1.537E-02 4.865E-04 3.432E-01 2.306E-05
1986
7.880E-01
2.198E+02 1.477E-02 4.674E-04
3.298E-01 2.216E-05
1987
7.571 E-01
2.112E+02 1.419E-02
4.491 E-04 3.168E-01 2.129E-05
1988 7.274E-01 2.029E+02 1.364E-02
4.315E-04
3.044E-01
2.045E-05
1989 6.989E-01 1.950E+02 1.310E-02
4.146E-04
2.925E-01
1.965E-05
1990 6.715E-01 1.873E+02
1.259E-02 3.983E-04
2.810E-01
1.888E-05
1991 6.452E-01 1.800E+02
1.209E-02 3.827E-04
2.700E-01
1.814E-05
1992 6.199E-01 1.729E+02
1.162E-02 3.677E-04
2.594E-01 1.743E-05
1993
5.956E-01
1.662E+02 1.116E-02 3.533E-04
2.492E-01 1.675E-05
1994
5.722E-01
1.596E+02 1.073E-02 3.394E-04
2.395E-01
1.609E-05
1995 5.498E-01 1.534E+02
1.031 E-02 3.261E-04
2.
301
E-01
1.546E-05
1996 5.282E-01 1.474E+02
9.902E-03 3.133E-04
2.210E-01
1.485E-05
1997 5.075E-01 1.416E+02
9.513E-03 3.010E-04
2.124E-01
1.427E-05
REPORT-
11
8/11/2019 Brimbal Ave. - Environmental Notification Form - 9.2.14 - Volume 2 of 2
http://slidepdf.com/reader/full/brimbal-ave-environmental-notification-form-9214-volume-2-of-2 557/798
Appendix C.xls
10/2/2008
Results (Continued)
Year
NMOC
Hydrogen sulfide
(Mg year)
(m
3
/year)
(av ftAJfmin)
(Mg year)
(m
3
year)
(av
ftAJfmin)
1998 4.876E-01 1.360E+02 9.140E-03
2.892E-04 2.041 E-01 1.371 E-05
1999
4.685E-01 1.307E+02
8.782E-03
2.779E-04
1.961
E-01
1.317E-05
2000 4.501 E-01 1.256E+02 8.438E-03 2.670E-04
1.884E-01 1.266E-05
2001 4.325E-01
1.207E+02
8.107E-03
2.565E-04
1.810E-01 1.216E-05
2002 4.155E-01 1.159E+02 7.789E-03 2.465E-04
1.739E-01 1.168E-05
2003 3.992E-01 1.114E+02 7.483E-03
2.368E-04
1.671 E-01 1.123E-05
2004 3.836E-01 1.070E+02 7.190E-03 2.275E-04 1.605E-
01
1.078E-05
2005 3.685E-01 1.028E+02 6.908E-03
2.186E-04
1.542E-01
1.036E-05
2006 3.541
E-01
9.878E+01
6.637E-03
2.100E-04
1.482E-01 9.956E-06
2007 3.402E-01 9.491 E+01 6.377E-03 2.018E-04
1.424E-01 9.565E-06
2008 3.269E-01
9.119E+01
6.127E-03
1.939E-04
1.368E-01
9.190E-06
2009 3.140E-01 8.761 E+01 5.887E-03 1.863E-04
1.314E-01 8.830E-06
2010 3.017E-01
8.418E+01
5.656E-03
1.790E-04
1.263E-01
8.484E-06
2011 2.899E-01 8.088E+01 5.434E-03 1.720E-04
1.213E-01 8.151 E-06
2012
2.785E-01
7.
771 E+01
5.221 E-03
1.652E-04
1.166E-01
7.
831
E-06
2013 2.676E-01 7.466E+01 5.016E-03
1.587E-04 1.120E-01 7.524E-06
2014
2.
571 E-01
7.173E+01 4.820E-03 1.525E-04
1.076E-01 7.229E-06
2015 2.470E-01 6.892E+01 4.631 E-03
1.465E-04
1.034E-01
6.946E-06
2016 2.373E-01 6.622E+01 4.449E-03 1.408E-04
9.932E-02 6.674E-06
2017 2.280E-01 6.362E+01 4.275E-03
1.353E-04
9.543E-02 6.412E-06
2018 2.191 E-01 6.113E+01 4.107E-03 1.300E-04
9.169E-02 6.160E-06
2019 2.105E-01
5.873E+01 3.946E-03 1.249E-04
8.809E-02 5.919E-06
2020 2.023E-01 5.643E+01 3.791 E-03 1.200E-04
8.464E-02
5.687E-06
2021 1.943E-01
5.421 E+01 3.643E-03 1.153E-04
8.132E-02 5.464E-06
2022
1.867E-01
5.209E+01 3.500E-03 1.107E-04
7.813E-02 5.250E-06
2023 1.794E-01 5.004E+01 3.363E-03
1.064E-04
7.507E-02 5.044E-06
2024
1.724E-01
4.808E+01 3.231 E-03 1.022E-04
7.212E-02 4.846E-06
2025 1.656E-01 4.620E+01 3.1 04E-03
9.823E-05 6.930E-02 4.656E-06
2026 1.
591
E-01 4.439E+01
2.982E-03 9.437E-05
6.658E-02
4.473E-06
2027
1.529E-01
4.265E+01 2.865E-03 9.067E-05
6.397E-02 4.298E-06
2028 1.469E-01 4.097E+01 2.753E-03
8.712E-05 6.146E-02 4.129E-06
2029 1.411 E-01 3.937E+01 2.645E-03
8.370E-05
5.905E-02
3.968E-06
2030 1.356E-01
3.782E+01
2.541 E-03
8.042E-05
5.673E-02
3.812E-06
2031
1.303E-01
3.634E+01 2.442E-03 7.727E-05
5.451 E-02 3.663E-06
2032
1.252E-01
3.492E+01 2.346E-03 7.424E-05
5.237E-02 3.519E-06
2033 1.202E-01 3.355E+01 2.254E-03 7.133E-05
5.032E-02 3.381 E-06
2034 1.155E-01 3.223E+01 2.166E-03 6.853E-05
4.835E-02 3.248E-06
2035 1.110E-01 3.097E+01 2.081 E-03 6.584E-05 4.645E-02 3.121E-06
2036 1.066E-01 2.975E+01 1.999E-03
6.326E-05 4.463E-02 2.999E-06
2037 1.025E-01 2.859E+01 1.921 E-03
6.078E-05
4.288E-02
2.881 E-06
2038
9.845E-02 2.747E+01
1.845E-03 5.840E-05
4.120E-02
2.768E-06
2039 9.459E-02
2.639E+01 1.773E-03 5.611 E-05
3.958E-02
2.660E-06
2040 9.088E-02
2.535E+01 1.704E-03 5.391E-05
3.803E-02 2.555E-06
2041 8.732E-02
2.436E+01 1.637E-03 5.179E-05
3.654E-02 2.455E-06
2042
8.389E-02
2.340E+01 1.573E-03 4.976E-05
3.511 E-02 2.359E-06
2043 8.060E-02 2.249E+01 1.511 E-03 4.781E-05
3.373E-02 2.266E-06
2044 7.744E-02 2.160E+01 1.452E-03
4.594E-05
3.241 E-02
2.177E-06
2045 7.441E-02 2.076E+01
1.395E-03 4.414E-05
3.114E-02
2.092E-06
2046 7.149E-02 1.994E+01
1.340E-03 4.
241 E-05
2.992E-02 2.010E-06
2047 6.868E-02
1.916E+01 1.287E-03 4.074E-05
2.874E-02 1.
931
E-06
2048
6.599E-02
1.841 E+01 1.237E-03 3.914E-05
2.762E-02 1.855E-06
REPORT - 12
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Appendix C.xls
10 /2/2008
Results (Continued)
Year
NMOC
Hydrogen sulfide
(Mglyear)
m
3
/year) (av ft"31min) (Mglyear) m
3
/year) (av ft"31min)
2049
6.340E-02
1.769E+01 1.188E-03 3.761E-05 2.653E-02
1.783E-06
2050
6.092E-02 1.700E+01
1.142E-03 3.614E-05 2.549E-02
1.713E-06
2051 5.853E-02
1.633E+01
1.097E-03 3.472E-05
2.449E-02
1.646E-06
2052
5.623E-02
1.569E+01 1.054E-03 3.336E-05 2.353E-02
1.581 E-06
2053
5.403E-02 1.507E+01
1.013E-03 3.205E-05
2.
261
E-02
1.519E-06
2054 5.
191
E-02
1.448E+01 9.731 E-04 3.079E-05 2.172E-02
1.460E-06
2055 4.988E-02 1.
391
E+01 9.349E-04 2.959E-05 2.087E-02 1.402E-06
2056 4.792E-02
1.337E+01 8.982E-04 2.842E-05 2.005E-02
1.347E-06
2057
4.604E-02 1.284E+01
8.630E-04 2.731 E-05 1.927E-02 1.295E-06
2058
4.424E-02 1.234E+01
8.292E-04 2.624E-05
1.851 E-02
1.244E-06
2059
4.250E-02 1.186E+01
7.967E-04 2.
521
E-05 1.779E-02
1.195E-06
2060
4.083E-02 1.139E+01
7.654E-04 2.422E-05
1.709E-02
1.148E-06
2061
3.923E-02 1.095E+01
7.354E-04 2.327E-05 1.642E-02
1.103E-06
2062 3.770E-02
1.052E+01 7.066E-04 2.236E-05 1.577E-02
1.060E-06
2063
3.622E-02 1.010E+01
6.789E-04 2.148E-05 1.516E-02
1.018E-06
2064 3.480E-02
9.708E+OO 6.523E-04 2.064E-05 1.456E-02
9.784E-07
2065
3.343E-02 9.327E+OO
6.267E-04 1.983E-05 1.399E-02
9.400E-07
2066
3.212E-02
8.961
E+OO
6.021 E-04 1.905E-05 1.344E-02
9.032E-07
2067
3.086E-02 8.610E+OO
5.785E-04 1.
831
E-05 1.291 E-02
8.678E-07
2068
2.965E-02 8.272E+OO
5.558E-04 1.759E-05 1.241 E-02
8.337E-07
2069 2.849E-02
7.948E+OO 5.340E-04 1.690E-05 1.192E-02
8.010E-07
2070
2.737E-02 7.636E+OO
5.131 E-04 1.624E-05 1.145E-02
7.696E-07
2071 2.630E-02
7.337E+OO 4.930E-04 1.560E-05 1.101E-02
7.395E-07
2072
2.527E-02 7.049E+OO
4.736E-04 1.499E-05 1.057E-02
7.105E-07
2073
2.428E-02 6.773E+OO 4.
551
E-04 1.440E-05 1.016E-02
6.826E-07
2074
2.333E-02
6.
507E+OO
4.372E-04 1.384E-05 9.
761
E-03
6.558E-07
2075
2.
241
E-02 6.252E+OO
4.
201
E-04 1.329E-05
9.378E-03
6.301 E-07
2076 2.153E-02
6.007E+OO 4.036E-04 1.277E-05 9.010E-03
6.054E-07
2077
2.069E-02 5.771
E+OO 3.878E-04 1.227E-05 8.657E-03
5.817E-07
2078
1.988E-02 5.545E+OO
3.726E-04 1.179E-05
8.318E-03
5.589E-07
2079 1.910E-02
5.328E+OO 3.580E-04 1.133E-05 7.992E-03
5.370E-07
2080
1.835E-02 5.119E+OO
3.439E-04 1.088E-05 7.678E-03
5.159E-07
2081
1.763E-02 4.918E+OO
3.304E-04 1.046E-05 7.377E-03
4.957E-07
2082
1.694E-02 4.725E+OO
3.175E-04 1.005E-05
7.088E-03
4.762E-07
2083
1.627E-02 4.540E+OO 3.050E-04 9.653E-06 6.81 OE-03
4.576E-07
2084
1.564E-02 4.362E+OO 2.
931
E-04 9.274E-06 6.543E-03
4.396E-07
2085
1.502E-02
4.
191 E+OO
2.816E-04 8.
911
E-06 6.286E-03
4.224E-07
2086 1.443E-02 4.027E+OO 2.705E-04 8.561 E-06 6.040E-03 4.058E-07
2087
1.387E-02
3.869E+OO 2.599E-04 8.226E-06 5.803E-03
3.899E-07
2088
1.332E-02 3.717E+OO
2.497E-04 7.903E-06
5.576E-03
3.746E-07
REPORT - 13
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APPENDIXD
Selected Illustrative Johnson and Ettinger Model Calculation
Worksheets for
Potential Landfill Gas
Vapor
Intrusion and Inhalation Risk Assessment
• Set D-1: Residential (Adult) Scenario for Tetrachloroethene
for the
Site-Wide lEA
• Set D-2: Residential (Child) Scenario for Tetrachloroethene for the Site-Wide lEA
• Set D-3: Commercial/Retail Scenario
for
Tetrachloroethene
for the
Site-Wide
lEA
• Set D-4: Day Care (Adult) Scenario for Tetrachloroethene for the Site-Wide lEA
• Set D-5: Day Care (Toddler) Scenario
for
Tetrachloroethene for
the
Site-Wide lEA
• Set D-6: Day Care (Toddler) Scenario
for
Tetrachloroethene for the Western lEA
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SG-ADV
Version
3.1;
02/0
r Reset to l
l_ Defaults _;
I
~ R E
I
I
~ R E
I
I
~ R E
I
I END I
DATA ENTRY SHEET
SoiiG
c,
Data
trati
. ,uu ' - ' v u o o ~ u o n o u . u o o ...,.,..,..
ENTER
ENTER
ENTER
Soil
Soil
Chemical
'"
'"
AS No.
cone., OR cone.,
(numbers only,
c.
c,
no dashesl
( ~ - t g / m 3 )
room•J
Chemical
127184 2.83E+02
I
Tetrachloroethylene
ENTER ENTER
ENTER
ENTER
ENTER
ENTER ENTER
Depth
Totals must
add
uo to value of
Ls
(cell
F24)
Soil
below grade
Soil
gas
Thickness Thickness stratum A U
to bottom
sampling
Average Thickness of soil of soil
scs
of enclosed
depth
soil of soil stratum B, stratum C,
soil type
space floor, below grade, temperature, stratum A, (Enter value or 0)
(Enter value or 0) (used to estimate
OR p
'•
L,
T,
h,
ho ho
soil vapor
(om) (om)
("C)
(em) (om) (em) permeability)
15
133.5
10
133.5
'
ENTER
ENTER
ENTER
ENTER
ENTER
ENTER ENTER
ENTER
Stratum A Stratum A
Stratum A Stratum A Stratum B Stratum B
Stratum
8 Stratum 8
scs
soil
dry
soil
total
soil water-filled
scs
soil
dry
soil
total
soil water-filled
soil
type
bulk
density,
porosity, porosity,
soil type
bulk density, porosity, porosity,
C_L-;;-.;kup Soil\,
'
o'
' '
LookuPSoi J
'
o'
'
'
~
Po
Po
- ~ · a - ~ " : ~ ~ e - ~ _ _ )
(g/em3)
(tJnitless)
(cm
3
/cm
3
)
l._ Parameters
(g/cm_'_)
__
. . u . ~ j t l e s s )
(cm
3
/cm
3
)
, _ _
o,06 - - ~ ~ ~
ENTER
Enclosed
ENTER ENTER
Enclosed
ENTER
Enclosed
ENTER ENTER ENTER
space Soil-bldg. space space Enclosed Floor-wall Indoor
floor pressure floor floor space
seam
crack air exchange
thickness, differential, length,
width,
height,
width, rate,
l.:raei<.
AP le We He w ER
(em) (g/cm-s
2
) (em) (em) {em) {em) (1/h)
I 15 I .. ·- 40 I
961
I
961
I
244
I
0.1
I
0.45
I
ENTER ENTER ENTER ENTER
Averaging
Averaging
time for time for
Exposure
Exposure
carcinogens, noncarclnogens, duration, frequency,
ATe
ATNc
ED EF
(yrs) (yrs) (yrs) (daystyr)
I
1o ·-·
-·T-
3o
- ~ C l · - - · ·
I
365
I
1 of 4
Av
flow
Leave b
I
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CHEMICAL
PROPERTIES SHEET
Henry's
Henry's
Enthalpy of
law constant law constant vaporization at Normal Unit
Diffusivity DiffuSivity at reference reference
the
normal
boiling Critical Molecular risk
in
air,
in
water,
temperature, temperature,
boiling
point,
point, temperature, weight,
factor,
D,
Dw
H T,
t..Hv.b Ta
Tc
MW URF
(cm
2
/s) (cm
2
/s) (atm-m
3
/mol)
tc>
(cal/mol)
(K)
(oK)
(g/mol)
( lg/m3r1
1
1.2oE-o2
1
8 . 2 o E ' ~ o s l 1.84E-o2
1
2s
1
8.288
1
394.40
1
62o.2o
1
165.83
1
s.sE-os
2 of4
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INTERMEDIATE CALCULATIONS SHEET
Stratum A Stratum 8 Stratum C Stratum A Stratum A Stratum A Stratum A
Source-
soil
soil
soil
effective
soil soil soil
Exposure building air-filled air-filled air-filled total fluid intrinsic relative air effective vapor
duration,
separation, porosity, porosity, porosity, saturation,
permeability, permeability, permeability,
pe
'C Lr
9aA
8a
8
Sac
Ste k1 k,ll kv
(sec) (Qm)
_____ (cm
3
/cm
3
)_
(cm
3
/cm
3
) _ ( ~ _ m (cm
3
/cm
3
) _(cm
2
) (cm
2
)
(cm
2
)
I 9.46E+08 I 118.5_ I 0.370 I ERROR I__ _ERROR I 0.019 I 9.92E-08 I 0.987 I 9.79E-08 I
Area of
enclosed
space
below
grade,
A,
(cm
2
)
Stratum Stratum S
Crack- Crack Enthalpy of Henry's law Henry's law Vapor A B
to-total depth vaporization at constant at constant at viscosity at effective effective e
area below ave. soil ave. soil ave. soil ave. soil diffusion diffusion d
ratio, grade, temperature, temperature, temperature, temperature, coefficient, coefficient, co
11 Z c r a c ~ D.Hv.TS
Hrs H'rs
J..ITS
DeltA
DeUS
(unitless) (em) (cal/mQ.IL_ (atm-m
3
/mol) (unitless) (g/cm-s) (cm
2
/s) (cm
2
/s)
U ~ 4 ~ + 0 5 I 4.16E-04 I 15----,--- j l , § _ ; ~ _ I 7.81E-03 ----1 3.36E-01 I 1.75E-04 I 1.42E-02 I O.OOE+OO I O
Exponent of Infinite
Average Crack equivalent source
Infinite
Convection Source vapor effective foundation indoor
source
path vapor Crack flow rate diffusion Area
of
Peclet attenuation
bldg.
length, cone., radius, into bldg., coefficient,
crack,
number, coefficient,
cone.,
L, Csource
f e r a e ~
Osoil
Dcrack
Acrack
exp(Pe
1
)
a
Cbuildin l
(em)
(J..Ig/m3)
(em)
_ ( ~ 1 1 ) 3 / s )
(cm
2
/s) (cm
2
)
(unitless) (unitless)
(J..Ig/m3)
{J
1
1s
1
2.a3E+o2
r
o.1o
1
a.33E+o1 t
1 . 4 2 E ~ 0 2 _ _ _
t 3.84E+o2
1
2.53E+99 t 1.est::-cr:f t 4.77E-o1
1
s
I END I
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Appendix D-1
RESULTS SHEET
INCREMENTAL RISK CALCULATIONS:
Incremental
risk from
vapor
intrusion to
indoor
air,
Hazard
quotient
from vapor
intrusion to
indoor
air,
carcinogen noncarcinogen
{unitless) (unitless)
I 1.1E-05 I 1.0E-04 -1
MESSAGE AND ERROR SUMMARY BELOW: (DO NOT USE RESULTS lF ERRORS ARE PRESENT)
I E N b := l
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SG-ADV
version
3.1; 0210·
l _ ~ : ~ : ~ ~ : f ]
I ~ R E I
I
~ R E
I
I
~ R E
I
I
END
I
DATA
ENTRY SHEET
Soil Gas G
1lration·
Data
' " ~ ~ · ·
ENTER ENTER ENTER
Soil Soil
Chemical
'"
'"
AS No.
cone., OR
cone.,
(numbers only,
c,
c,
no dashes)
( lgfm
3
)
IPPm' I
Chemical
127184 2.83E+02
I I
T
t r a c h l o r o ~ t ~ y l e n e
ENTER ENTER ENTER
ENTER
ENTER
ENTER
ENTER
Depth
Totals must add up to value of
Ls
{cell F24l Soil
below grade Soil
gas
Thickness
Thickness
stratum A
Us
to bottom
sampling
Average Thickness of
soil
of so'i
scs
of enclosed
depth
soil of soil stratum
B,
stratum C, soil type s
space floor,
below grade,
temperature, stratum A, (Enter value or 0) {Enter value or 0) (used
to
estimate OR pe
L,
L.
T,
h,
h,
h,
soil vapor
(om) (om)
(OC)
)em) (em) (em)
I . permeability)
15
133.5
10
133.5
'
ENTER
ENTER
ENTER
ENTER
ENTER ENTER ENTER ENTER
Stratum A Stratum A
Stratum A
Stratum A
Stratum B
Stratum
B Stratum B Stratum B
S
scs
soil
dry
soil
total
soil
water-filled scs
soil dry
soil
total
soil water-filled
soil type
bulk density, porosity,
porosity, soil
type
bulk density,
porosity,
porosity,
c
ookup Soil
' I
'
o'
' '
1
~ . ~ ~ ~ s - ~ ~ ~ - ,
1
'
o'
' '
c- -
•
Po
Parameters j
(g/cm3)
(unitless)
(cm
3
/cm
3
)
~ , _ Parameters
1
(g/cm
3
)
(unitless)
(cm
3
/cm
3
)
_
0.06
ENTER
Enclosed
ENTER ENTER
Enclosed
ENTER
Enclosed
ENTER ENTER ENTER
space Soil-bldg.
space space Enclosed
Floor-wall
Indoor
floor pressure floor floor space seam crack air exchange
thickness, differential,
length,
width, height, width,
rate,
lorack 6.P
La Wa Hs
w
ER
(em) (g/cm-s
2
) (em) (em) (em) (em)___
(1/h)
.---=--,----;u;----,---961
t 961 t
244
t
0.1
t
~ ~
ENTER
ENTER
ENTER ENTER
Averaging Averaging
time for time for Exposure Exposure
carcinogens, noncarcinogens, duration, frequency,
ATe ATNc
ED
EF
(yrs) (yrs)
_(yr§)
(days/yr)
1 7 0 1 t 365 I
1 of4
Av
flow
Leave b
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CHEMICAL PROPERTIES SHEET
Henry's Henry's
Enthalpy of
law constant law
constant
vaporization at
Normal
Unit
Diffusivity
Oiffusivity at reference
reference
the normal
boiling Critical
Molecular
risk
in
air,
in water,
temperature,
temperature,
boiling point,
point,
temperature,
weight,
factor,
D,
Dw
H
T,
D.Hv,b
T,
To
MW
URF
(cm
2
/s)
{cm
2
/s) {atm-m
3
/mo1)
('C)
(cal/mol)
('K)
i'K)
(g/mol)
(J.tg/m3r,
I 7.20E-02 . n•-1 8.20E-0§_[_1.84E-02 I 25
r·
8,288 I 394.40 I 620.20 I 165.83 r · s ~ S E - 0 5
2
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INTERMEDIATE CALCULATIONS SHEET
Stratum
A Stratum B
Stratum
C
Stratum
A
Stratum
A
Stratum
A
Stratum
A
Source- soil soil soil effective soil soil soil
Exposure building air-filled air-filled air-filled total fluid intrinsic relative air effective vapor
duration, separation, porosity, porosity, porosity, saturation, permeability, permeability,
permeability, pe
t Lr 9aA
9a
8
Sac Ste
k; k'R kv
(sec)
(em)
(cm
3
/cm
3
) (cm
3
/cm
3
) (cm
3
/cm
3
) (cm
3
/cm
3
) (cm
2
) (cm
2
) (cm
2
)
I
2.21E+08
I
118.5
[ --6.370 I ERROR I ERROR I 0.019 I 9.92E-08 I 0.987 I 9.79E-08 I
Area of
enclosed
space
below
grade,
A,
(cm
2
)
Stratum
Stratum S
Crack- Crack Enthalpy
of
Henry's law Henry's law
Vapor
A B
to-total depth vaporization at constant at constant at viscosity at effective effective e
area below ave. soil ave. soil ave. soil ave. soil diffusion diffusion d
ratio, grade, temperature, temperature, temperature, temperature, coefficient, coefficient, co
i1 Zcrack 6.Hv.TS Hrs H'rs
J.l.TS
DeliA
De
11
a
(unitless) (em) {cal/mol) (atm-m
3
/mol) (unitless) (g/cm-s) (cm
2
/s) {cm
2
/s)
1 9.24E•os 1
••
1sE-o• 1 15
r
9,553 1 7.s1E-o3 1 3.3sE-o1 1 1.75E-o4 1 1.42E-02 1
o.ooE•oo 1· o
Exponent of Infinite
Average
Crack
equivalent source
Infinite
Convection Source
vapor
effective
foundation indoor
source
path vapor Crack
flow rate
diffusion Area of
Peclet
attenuation bldg.
length, cone., radius, into bldg., coefficient, crack, number, coefficient, cone.,
L,
Csource
rcrack
Osoil
ocrack
Acrack
exp(Pe
1
)
a
Cbuildin l
(em)
(J.Lg/m3)
(em)
(cm
3
/s) (cm
2
/s) (cm
2
)
(unitless) (unitless)
(J.Lg/m3) (J
I 15 I 2.83E+02 I 0.10 I 8.33E+01 I 1.42E-02 I 3.84E+02 I 2.53E+9g I 1.69E-03 I 4.77E-01 I 5
I END I
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Appendix D-2
RESULTS SHEET
INCREMENTAL RISK CALCULATIONS:
Incremental
risk from
vapor
intrusion
to
indoor air,
Hazard
quotient
from vapor
intrusion
to
indoor air,
carcinogen noncarcinogen
(unitless) (unitless)
I 2.6E-06 I 1.0E-04 I
MESSAGE
AND ERROR SUMMARY BELOW:
(DO
NOT
USE RESULTS F ERRORS
ARE PRESENT
I END I
4
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CHEMICAL PROPERTIES SHEET
Henry's
Henry's
Enthalpy
of
law constant
law constant
vaporization at
Normal
Unit
Diffusivity Diffusivity at reference
reference the normal boiling Critical Molecular
risk
in
air,
in
water,
temperature,
temperature, boiling point, point,
temperature,
weight,
factor,
D,
Dw
H
T, L\Hv,b T,
To
MW URF
(cm
2
/s) (cm
2
/s)
(atm-m
3
/mol)
("C)
(ca lmol)
tK)
(oK)
(g/mol)
{J.Ig/m3)",
I 7.20E-02 ___ L8.20E-06 I 1.84E-02 I 25. I 8,288 I 394.40 I 620.20 I 165.83 I 5.5E-05
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Stratum A
source- soil
Exposure building air-filled
duration, separation, porosity,
Stratum 8
soil
air-filled
porosity,
Stratum C
soil
air-filled
porosity,
INTERMEDIATE CALCULATIONS SHEET
Stratum A
Stratum A
Stratum A
Stratum A
effective soil soil soil
total fluid
intrinsic relative air effective vapor
saturation, permeability, permeability,
permeability,
pe
t Lr
SaA
9.,
8
Sac Ste k; km kv
{sec) {em)
(cm
3
/cm
3
) (cm
3
/cm
3
) (cm
3
/cm
3
)
{cm
3
/cm
3
)
J ~ f l ~ )
(cm
2
) {cm
2
)
I 7.BBE+OB I 118.5 I 0.370 I ERROR I ERROR I 0.019 I 9.92E ,Q8. I 0.987 I 9.79E-08 I _9
Area of
enclosed
space
below
grade,
A,
{cm
2
)
Stratum Stratum S
Crack- Crack Enthalpy of Henry's law Henry's law Vapor A 8
to-total depth vaporization at constant at constant at viscosity at effective effective e
area below ave. soil ave. soil ave. soil ave. soil diffusion diffusion d
ratio, grade, temperature, temperature. temperature, temperature, coefficierit, coefficient, coe
f]
Z c r a c ~
ll.Hv.TS Hrs H'rs J.lTS D"
11
A o"rrs
(unitless) (em) {cal/mol) {atm-m
3
/mo1L___
(unitless) (gfcm-s)___ (cm
2
/s) (cm
2
/s)
___
I 5.14E+06 I 1.79E-04 I
15
I 9,553 I 7.81E-03 I 3.36E-01 I 1.75E-04 I 1.42E-02 I _ O ~ O O E + O O I O.
Exponent of
Infinite
Average Crack
equivalent
source
Infinite
Convection
Source vapor effective foundation indoor source
path
vapor
Crack
flow rate
diffusion
Area of Peclet attenuation bldg.
length,
cone.,
radius,
into bldg.,
coefficient,
crack, number, coefficient,
cone.,
L,
Csource
f e r a e ~
Osorr
o c r a c ~
A c r a c ~
exp(Pe
1
)
a
Cbuildinl
(em)
{J.lg m3)
(em)
{em%)
(cm
2
/s)
(cm
2
)
{unitless) {unilless)
("glm')
( ~
1· 15 1
2.a3E+o2
1
o.1o
1
s _ . _ ~ ~ E + o 1
1 1.42E-o2 L _9.22E+o2 1
2.69E+41-
1
2 . 1 1 _ ~ ; - o 4
1
5.ssE-o2 --r
5
I END I
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RESULTS SHEET
INCREMENTAL RISK CALCULATIONS:
Incremental Hazard
risk from
quotient
vapor from
vapor
intrusion
to
intrusion
to
indoor air,
indoor
air,
carcinogen noncarcinogen
(unitless) {unitless)
I B.OE-07 I 8.9E-06 I
MESSAGE AND ERROR SUMMARY BELOW: (DO NOT
USE
RESULTS IF ERRORS ARE PRESEND
I END I
Appendix D-3
4
of
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SG-ADV
Version
3.1;
0210·
Reset to
l
-,
D e f a ~ ~ : _ _ j
I ~ R E I
I
~ R E
I
I
~ R E
I
I END I
DATA ENTRY SHEET
Soil
Gas
Concentration
Data
-·· -- -
.-
.. - · · ~
---
ENTER
ENTER ENTER
Soil
Soil
Chemical
'"
'"
AS No.
cone.,
OR
cone.,
(numbers only,
c.
c.
no dashes)
().tgfm
3
)
..iEE_m_y)_ Chemical
127184
2.83E+02
I I
Tetrachloroethylene
ENTER ENTER
ENTER
ENTER
ENTER
ENTER
ENTER
Depth Totals must add up to value of ls (cEi l F24) Soil
below grade
Soil
gas Thickness Thickness stratum A Us
to bottom sampling
Average
Thickness of
so'i
of soil
scs
s
of enclosed
depth
soil of soil
stratum B,
stratum C,
soil
type
s
space floor,
below grade,
temperature, stratum A,
(Enter value or 0)
(Enter value or 0) (used
to
estimate
OR pe
L, L,
T,
h, h, h,
soil vapor
(om)
<oml
("C)
(om)
<oml <oml
oermeabilitvl
15
133.5
10
133.5 s
ENTER ENTER ENTER ENTER ENTER ENTER ENTER ENTER
Stratum A Stratum A Stratum A Stratum A Stratum 8 Stratum 8 Stratum 8 Stratum 8 S
SCS soil dry soil total soil water-filled SCS soil dry soil total soil water-filled
soil type bulk density, porosity, porosity, bulk density, porosity, porosity,
- - L ~ - ; ; k - u P S o i t
.. \ PbA nA
ewA
Pbs n
8
ew
8
L
Parameters ) (g/cm
3
) (unitless) (cm
3
/cm
3
) (g/cm
3
) (unitless) (cm
3
/cm
3
) P
I I
1.5
I
.ML __ _I
o.oo I
~ - - - -
I I . -1
ENTER
Enclosed
ENTER ENTER
Enclosed
ENTER
Enclosed
ENTER ENTER ENTER
space Soil-bldg. space space Enclosed Floor-wall Indoor
floor pressure floor floor space seam crack air exchange
thickness, differential, length, width, height, width. rate,
lcra<tc boP La Wa Ha w ER
(em)
(g/cm-s
2
) (em) (em) (em)
(em)
(1/h)
I_ 15 I 40 I --3773A___ I 2305.1 I 244
o.t
I 0.45 I
ENTER ENTER ENTER
ENTER
Averaging Averaging
time for
time
for Exposure Exposure
carcinogens, noncarcinogens, duration, frequency,
ATe
ATNc ED EF
(yrs) (yrs) (yrs) (days/yr)
I
10
I -2 5 I
25
I
250 --1
1 of 4
Ave
flow
Leave b
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CHEMICAL PROPERTIES SHEET
Henry's Henry's Enthalpy of
law
constant
law constant
vaporization at
Normal
Unit
Diffusivity Diffusivity
at
reference reference
the normal
boiling Critical
Molecular
risk
in air,
in water,
temperature,
temperature, boiling
point, point, temperature,
weight, factor,
o. Ow
H
Te D.Hv,b
T,
Tc
MW
URF
(cm
2
/s)
(cm
2
/s) (atm-m
3
/mol)
('C)
(cal/mol)
(oK)
('K)
{g/mol)
( lg/m3r1
t 7.20E-02 I 8 . 2 0 E ~ b 6 - J 1.84E-02 I 25 I 8.288 I 394.40 I 620.20 I 165.83 I 5.5E-05
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INTERMEDIATE CALCULATIONS SHEET
Stratum
A Stratum B
Stratum
C
Stratum
A
Stratum
A
Stratum
A
Stratum
A
Source- soil
soil soil
effective
soil soil
soil
Exposure building . air-filled air-filled air-filled total fluid intrinsic relative air effective vapor
duration,
separation,
porosity, porosity, porosity,
saturation, permeability, permeability, permeability,
pe
t
Lr
GaA
9a
9
Gac Ste
k;
. krQ kv
~ ___
q[l)__ _ i ~ l ~ ~ . r J " l ~ ) .
(cm
3
/cm
3
)
(cm
3
/cm
3
)
(cm
3
/cm
3
)
(em') {cm
2
)
(cm
2
)
1 7.88E•o8 l_m.L_I __ o,37o 1 ERRoR 1 ERROR
r·--
o.o19 1 9.92E-o8 1 o.987 1 9.79E-o8 1
Area of
enclosed
space
below
grade,
As
(cm
2
)
Stratum Stratum S
Crack- Crack
Enthalpy
of
Henry's law Henry's law
Vapor A B
to-total depth vaporization at constant at constant at viscosity at effective effective e
area
below ave. soil ave.
soil
ave.
soil
ave. soil
diffusion diffusion d
ratio, grade, temperature, temperature, temperature, temperature, coefficient, coefficient, co
'1 Zcrack t..Hv.TS
Hrs H'rs f.l.TS DeffA
Deft8
(unitless) (em) (99 lllJ.OI)__ {atm-m
3
/mol) {unitless) (gfcm-s) (cm
2
/s) (cm
2
/s)
1
8.7oE•os
1 1.40E-o4 1
15
1 9 553 1 7.81E-o3 r 3.36E-01 1 1.16E-o1 1 1.42E-o2 1 o.ooE•oo 1 o
Exponent of Infinite
Average Crack equivalent source
Infinite
Convection Source vapor effective foundation indoor
source
path vapor Crack
flow
rate diffusion Area of
Peclet
attenuation
bldg.
length, cone.,
radius, into bldg., coefficient,
crack, number,
coefficient,
cone.,
Lp
Csource
rcrack
Osoit Dcrack Acrack
exp{Pe
1
)
a
CbuildinSI
(em) (llg/m
3
)
(em)
(cm
3
/s) (cm
2
/s) (cm
2
) (unitless) (unitless)
(llg/m
3
)
{f
I 15 I 2.83E+02 I 0.10 I 8.33E+Q.1 ___ I 1.42E-02 I 1.22E+o3' ·1 2.70E+31 I 2.91E-04 I 8.23E-02 I 5
I END I
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RESULTS
SHEET
INCREMENTAL RISK CALCULATIONS:
Incremental Hazard
risk from quotient
vapor from vapor
intrusion to intrusion to
indoor air, indoor
air,
carcinogen noncarcinogen
(unitless) (unitless)
I
1.1E-06
I
1.2E-05
I
MESSAGE AND ERROR
SUMMARY
BELOW: (DO NOT USE RESULTS
IF
ERRORS ARE
PRESENT
I END I
Appendix D-4
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SG-ADV
Version 3.1; 0210
o = ~ ~ ~ : ~
I ~ R E I
I ~ R E I
I
~ R E
I
I END I
DATA ENTRY SHEET
Soil Gas Concentration
Dati
ENTER ENTER
ENTER
Soil
Soil
Chemical
'"
'"
AS No. cone.,
OR
cone.,
(numbers only,
c,
c.
no dashes)
(1-l-g/mJ)
loomv Chemical
127184 2.83E+02
I
Tetrachloroethylene
ENTER ENTER
ENTER
ENTER
ENTER
ENTER
ENTER
Depth Totals must add
up to
value of
Ls
(cell F24)
Soil
below grade Soil gas
Thickness Thickness stratum
A
U
to bottom sampling
Average Thickness
of s o ~
of
soil
scs
of enclosed depth
soil of soil stratum 8, stratum C, soil type
space floor, below grade,
temperature, stratum A, (Enter value or 0) (Enter value or 0) (used
to
estimate OR
p
L,
'·
T,
h, h, h,
soil vapor
<em>
loml
(oC)
(om\
lcml loml
oermeabilitvl
15
133.5
10
133.5
s
ENTER ENTER
ENTER
ENTER
ENTER
ENTER ENTER
ENTER
Stratum A Stratum A
Stratum A
Stratum
A Stratum 8
Stratum
8 Stratum 8 Stratum B
scs
soil
dry
soil total soil water-filled
scs
soil
dry
soil
total
soil water-filled
soil type
bulk
density,
porosity,
porosity, soil type bulk density, porosity, porosity,
C } ; ~ ~ ~ ~ J
'
o'
e.'
(-lookupsoli---,
'
o'
e."
1,-
o
Po
(g/cm
3
)
(unitless)
(cm
3
/cm
3
)
Parameters
(g/cm
3
)
(unitless)
(cm
3
/cm
3
)
, ~
,---------
o.4a
1
o.os--
ENTER
Enclosed
ENTER
ENTER
Enclosed
ENTER
Enclosed
ENTER
ENTER ENTER
space Soil-bldg. space space Enclosed Floor-wall Indoor
floor pressure floor floor space seam crack air exchange
thickness, differential, length, width, height, width, rate,
l o r o c ~ < . AP Le
Ws He w ER
{em)
(g/cm-s
2
) (em) (em) (em) (em) (1/h)
15
40 3773.4 I 2305.1 I 244 I o.1 - - - - - ~ o.45 I
ENTER ENTER
ENTER ENTER
Averaging Averaging
lime for time for Exposure Exposure
carcinogens, noncarcinogens, duration, frequency,
ATe
ATNc ED EF
(yrs) (yrs) (yrs) (dayslyr)
I 10 I 4 ___4 I 250 I
1 of4
Av
flow
Leave b
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CHEMICAL PROPERTIES SHEET
Henry's Henry's Enthalpy
of
law constant
law constant vaporization at Normal
Unit
Diffusivity
Diffusivity
at
reference
reference
the normal boiling Critical Molecular
risk
in
air,
in
water, temperature,
temperature, boiling point,
point,
temperature,
weight,
factor,
D,
Dw
H
T,
t..Hv.b
T,
To
MW
URF
(cm
2
/s)
(cm
2
/s)
(atm-m
3
/mol) ('C)
(cal/mol)
{oK)
('K)
(g/mol)
(Jlg/m3r1
1
7.2oE-o2
-
r
s.2o O_,_Qa_L 1.s•E-o2 1 25 1 s.2ss 1 394.4o 1
52o.2o
1
165.ao·r 5.5E-os
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INTERMEDIATE CALCULATIONS SHEET
Stratum A
Stratum
B
Stratum C Stratum A Stratum A Stratum A Stratum A
Source- soil
soil soil
effective soil soil soil
Exposure
building
air-filled air-filled air-filled total fluid intrinsic
relative
air effective vapor
duration,
separation,
porosity, porosity, porosity, saturation,
permeability, permeability,
permeability, pe
't l r 9/ 9a
8
Sac
Ste k1 kJ]:l kv
(sec} (em)
_(cm
3
icm
3
)
{cm
3
/cm
3
)
(cmJcm
3
) (cm
3
/cm
3
) (cm
2
)___
(cm
2
) (cm
2
)
I 1.26E+08 "I 118.5 I 0.370 I
ERROR
I ERR,DR I 0.019 I
9 . 9 2 E - O ~ _ L _ _
0.987 I 9.79E-08 I 1
Area of
enclosed
space
below
grade,
Crack-
to-total
area
ratio,
Crack
Enthalpy of
depth
vaporization at
below
ave. soil
grade,
temperature,
Henry's law
Henry's law
Vapor
constant
at constant at viscosity at
ave. soil ave. soil ave. soil
temperature, temperature, temperature,
Stratum Stratum
S
A B
effective effective
e
diffusion diffusion d
coefficient, coefficient, co
As 11 Zcrack
LI.Hv,Ts
Hrs H'rs lrs DenA De
11
s
(cm
2
) (unitless) (em) (cal/mol) (atm-m
3
/mol) (unitless) (g/cm-s) (cm
2
/s) (cm
2
/s) (
1
a.?OE+oa
1 1.4oE-o4 1
15-
] 9.553 1 7.81E-o3 1 3.3aE-o1 1 1.75E-o4 1 1.42E-o2 1 o.ooE+oo -r-o.o
Exponent of Infinite
Average Crack equivalent source
Infinite
Convection Source
vapor
effective foundation indoor
source
path vapor Crack flow rate diffusion Area of Peclet attenuation
bldg.
length, cone.. radius, into bldg., coefficient. crack, number, coefficient, cone.,
Lp
Csource rcrack
·
Osoil ocrack Acrack
exp(Pe
1
)
a
CbulldinQ
(em)
(J.Lg/m
3
)
(em) 3 ~ r T 1 _
/ s ) (cm
2
/s) (cm
2
)
{u(1itless)
{unitless)
( lg/m3)
(J
1 15 1 2.a3E+o2
r--
o.1o 1 a.33E+o1 1 1.42E-o2 - - - - ~ 1 22E+o3 1 2.7oE+31 1 2.91 E ~ D 4 1 a.23E-o2 1 5
I
END
I
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Appendix
D-5
RESULTS SHEET
INCREMENTAL RISK CALCULATIONS:
Incremental
risk from
vapor
intrusion to
indoor
air,
Hazard
quotient
from vapor
intrusion
to
indoor
air,
carcinogen noncarcinogen
(unitless) (unitless)
I 1.8E-07 I 1.2E-05 I
MESSAGE AND ERROR SUMMARY BELOW:
(00
NOT USE RESULTS
IF
ERRORS ARE PRESENT
I END I
4
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SG-ADV
version 3.1;
0210·
[
.
-- Reset to
l
Defaults
I
~ R E
I
I ~ R E I
I ~ R E I
r<-NDl
ENTER
Chemical
CAS No.
(numbers
only,
no dashes)
127184
ENTER
Depth
below grade
to bottom
of enclosed
space floor,
L,
(em)
15
ENTER
Stratum A
scs
soil type
( Lookup Soil -J
l
Parameters _
DATA ENTRY SHEET
Soil Gas Co
, ......,
tration
Oat;
'
ENTER
ENTER
Soil
Soil
'"
'"
one.,
OR cone.,
c,
c,
(J.Iglm3)
(ppm')
Chemical
6.42E+02
I
I
Tetrachloroethylene
ENTER
ENTER ENTER ENTER ENTER ENTER
Totals must add up to value of Ls {cell F24l Soil
Soil
gas
Thickness Thickness stratum A U
sampling
Average Thickness of soil
of
soil scs
depth
soil
of
soil
stratum B, stratum C,
soil type
below grade,
temperature, stratum A, (Enter value or 0) (Enter value or 0)
(used
to estimate OR pe
L,
T,
h,
h, h,
soil vapor
om)
("C)
(om) (om) (om)
permeability)
133.5
10 133.5 s
ENTER
ENTER ENTER ENTER ENTER ENTER ENTER
Stratum A
Stratum A Stratum A Stratum B Stratum B Stratum B Stratum B S
soil
dry
soil total soil
water-filled SCS
soil
dry
soil total soil
water-filled
bulk density,
porosity, porosity, soil type bulk density, porosity, porosity,
'
o
(g/cm
3
)
nA
e./ (
.
L - - ; ; ; ~ p s ; l -
Pbs n
8
Gw
8
,--
(unitless) (cm3/cm3) '- __
: ~ ~ m e t e r s
___)
(g/cm3)
{unitless) (cm3/cm3)
, ----,-----«----.-o.43 I o.oe
----r·
I I I
-
ENTER
Enclosed
ENTER
ENTER
Enclosed
ENTER
Enclosed
ENTER
ENTER ENTER
space Soil-bldg. space space Enclosed Floor-wall Indoor
floor pressure floor floor space seam crack air excllange
thickness, differential,
length,
width, height, width,
rate,
Lorack 6.P
Ls
We Hs w
ER
(em) (gtcm-s
2
) (em) (em) (em)
{em
_{_1fb)
15 40 3ii3A--- - - - ~ - - - - - - - 2305.1 I 244 0.1 I o.4s I
ENTER ENTER
ENTER ENTER
Averaging Averaging
time for time for Exposure Exposure
carcinogens, noncarcinogens, duration, frequency,
ATe
ATNc ED EF
(yrs) (yrs)
{yrs)
(days/yr)
l7o
4
41 zso
I
1 of4
Av
flow
Leave b
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CHEMICAL PROPERTIES SHEET
Henry's
Henry's
Enthalpy of
raw constant
law constant vaporization at Normal
·unit
Diffusivity
Diffusivity
at
reference reference
the
normal
boiling
Critical
Molecular
risk
in
air,
in water,
temperature, temperature,
boiling
point, point, temperature,
weight, factor,
o,
Ow
H
T,
.6.Hv.b
Ta
Tc
MW
URF
(cm
2
/s)
(cm
2
/s)
(atm-m
3
/mol)
('C)
(cal/mol)
CKJ
(oK)
{g/mol)
( lglm3r1
I 7.20E-02 I 8.20E-06 T--1.84E-02 I 25 I 8.288 I 394.40 I 620.20 I 165.83 I S.SE-05 I
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INTERMEDIATE CALCULATIONS SHEET
Stratum A Stratum B Stratum C Stratum A Stratum A Stratum A Stratum A F
Source-
soil
soil soil effective
soil soil soil
Exposure building air-filled air-filled air-filled total fluid intrinsic
relative
air effective vapor
duration,
separation, porosity, porosity, porosity,
saturation, permeability, permeability, permeability,
pe
• Lr
e,.A 8aB 8a
c
Ste k;
k,Q
kv
(sec)
(em) (cm
3
/cm
3
) (cm
3
/cm
3
) (cm
3
/cm
3
) (cm
3
/cm
3
) (cm
2
) (cm
2
) (cm
2
)
1
1.26E+os ·c 11a.s
1 o.37o 1
ERRoR r ERRoR
1
o.o1s
1 9 . 9 2 E ~ o - a - · - ] o.aa7 1
9.7sE-oa
1 1
Area of
enclosed
space
below
grade,
Aa
(cm
2
)
Stratum Stratum S
Crack- Crack Enthalpy
of
Henry's
Jaw
Henry's
Jaw
Vapor A B
to-total depth vaporization at constant at constant at viscosity at effective effective ef
area below ave. soil ave. soil ave. soil ave. soil diffusion diffusion di
ratio, grade, temperature, temperature, temperature, temperature, coefficient. coefficient, coe
T[ Zcrack ll.Hv,TS
Hrs H'rs Prs oefiA
oeffB
(unitless)
(em)
(cat/mol) . (atm-m
3
/mol) (unitless) (g/cm-s) (cm
2
/s) (cm
2
/s) (c
I 8.70E+06 I 1.40E-04 I
15
I 9.553 I 7.81E·03 I 3.36E-01 I 1.75E-04 I 1.42E-02 I O.OOE+OO
t
O.O
Exponent of Infinite
Average Crack equivalent
source Infinite
Convection Source vapor effective foundation
indoor source
path vapor
Crack
flow rate diffusion
Area of
Peclet
attenuation bldg.
length, cone.,
radius,
into bldg.,
coefficient, crack, number, coefficient, cone.,
f
L,
Csource
r c r a c ~
Osoil
oorack
Acrack
exp{Pe
1
)
a
C b u i l d l ~
(em) ( ) l g l ~ ~ ) _
___
(em)
(cm
3
/s)
(cm
2
/s) (cm
2
)
(unitless) (unitless)
{J.tg/m3) (p
15 t 6.42E+02 t 0.10 I a.33E+01 .t 1.42E-02 t 1.22E+03 t 2.70E+31 t 2.91E-04 t 1.87E-01 I 5
I END I
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Appendix E
Compilation
of
the Indoor Air Vapor Intrusion
Risk Calculation
Results
by Inhalation Exposure
Area
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Corporate Headquarters
One Grant Street
Framingham, MA 01701 -9005
www.tetratechrizzo.com
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Phase I Environmental Site Assessment and Limited
Subsurface Investigation Report
579 G. A. R. Highway (Route 6)
Swansea, Massachusetts
Submitted to:
R. K. Associactes, Inc.
September 6, 2007
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