Annual Groundwater Monitoring Report Mason County Landfill(Parametrix 1991) and the 1988 monitoring...
Transcript of Annual Groundwater Monitoring Report Mason County Landfill(Parametrix 1991) and the 1988 monitoring...
2015 Annual Groundwater Monitoring ReportMason County Landfill
Prepared for Mason County Department of Utilities
and Waste Management
November 2015
Prepared by
November 2015 │ 555‐1682‐042 (04/03)
2015 Annual Groundwater Monitoring Report Mason County Landfill
Prepared for
Mason County Department of Utilities and Waste Management 410 N. 4th Street P.O. Box 578 Shelton, Washington 98584
Prepared by
Parametrix 719 2nd Avenue, Suite 200 Seattle, WA 98104 T. 206.394.3700 F. 1.855.542.6353 www.parametrix.com
CITATION
.
Parametrix. 2015. 2015 Annual Groundwater Monitoring Report Mason County Landfill. Prepared by Parametrix, Seattle,
Washington. November 2015.
2015 Annual Groundwater Monitoring Report Mason County Landfill
Mason County Department of Utilities and Waste Management
November 2015 │ 555‐1682‐042 (04/03) i
TABLE OF CONTENTS 1. INTRODUCTION .......................................................................................................................... 1‐1
1.1 BACKGROUND ............................................................................................................................... 1‐1
1.2 GEOLOGY AND HYDROGEOLOGY .................................................................................................. 1‐2
2. MONITORING PROGRAM ............................................................................................................ 2‐1
2.1 SAMPLING LOCATIONS AND FREQUENCY .................................................................................... 2‐1
2.2 ANALYTICAL PARAMETERS ............................................................................................................ 2‐1
3. GROUNDWATER FLOW DIRECTION ............................................................................................. 3‐1
3.1 GROUNDWATER LEVELS ............................................................................................................... 3‐1
3.2 GROUNDWATER FLOW DIRECTION AND RATE ............................................................................. 3‐1
4. ANALYTICAL RESULTS.................................................................................................................. 4‐1
4.1 DATA VALIDATION ........................................................................................................................ 4‐1
4.2 COMPARISON TO GROUNDWATER QUALITY STANDARDS ........................................................... 4‐1 4.2.1 On‐Site Wells .................................................................................................................... 4‐1 4.2.2 Off‐Site Well ..................................................................................................................... 4‐1
4.3 GROUNDWATER QUALITY TRENDS ............................................................................................... 4‐2 4.3.1 Time Series Plots .............................................................................................................. 4‐3 4.3.2 Statistical Analysis of Trends ............................................................................................ 4‐3
5. CONCLUSIONS AND RECOMMENDATIONS .................................................................................. 5‐1
5.1 CONCLUSIONS ............................................................................................................................... 5‐1
5.2 RECOMMENDATIONS ................................................................................................................... 5‐1
6. REFERENCES ............................................................................................................................... 6‐1
APPENDICES
A Tabulated 2015 Groundwater Monitoring Results, Inorganic and Field Parameters
B Tabulated 2015 Groundwater Monitoring Results, Volatile Organic Compounds
C July 2015 Laboratory Report and Chain‐of‐Custody Form
D Laboratory Results for Well MW‐6
E Groundwater Quality Trends
2015 Annual Groundwater Monitoring Report Mason County Landfill Mason County Department of Utilities and Waste Management
TABLE OF CONTENTS (CONTINUED)
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LIST OF FIGURES
1 Mason County Landfill, Site Vicinity Map with Monitoring Well Locations .............................. 1‐3
2 Mason County Landfill, Groundwater Potentiometric Surface Map, July 8, 2015 .................... 3‐2
LIST OF TABLES
1 Summary of Analytical Parameters — Mason County Landfill 2015 Groundwater Monitoring ................................................................................................................................. 2‐2
2 Summary of 2015 Groundwater Elevations, Mason County Landfill ......................................... 3‐1
3 Summary of Groundwater and Drinking Water Quality Criteria Exceedances, Mason County Landfill 2015 Groundwater Monitoring ........................................................................ 4‐2
2015 Annual Groundwater Monitoring Report Mason County Landfill
Mason County Department of Utilities and Waste Management
November 2015 │ 555‐1682‐042 (04/03) iii
ACRONYMS AND ABBREVIATIONS ARI Analytical Resources, Inc.
GWQS Groundwater quality standards
MCDHS Mason County Department of Health Services
MCL Maximum Contaminant Level
MSL mean sea level
QA/QC Quality Assurance/Quality Control
RPDs relative percent differences
TOC total organic carbon
WDOC Washington State Department of Corrections
WAC Washington Administrative Code
2015 Annual Groundwater Monitoring Report Mason County Landfill
Mason County Department of Utilities and Waste Management
November 2015 │ 555‐1682‐042 (04/03) 1‐1
1. INTRODUCTION This report presents data from the July 2015 event at the Mason County Landfill, and presents recommendations for future groundwater monitoring. Annual reporting of groundwater monitoring data is required under the General Facility Requirements of Chapter 173‐304 WAC, Minimum Functional Standards for Solid Waste Handling, and the Solid Waste Handling Facility Closure/Post‐Closure Permit issued by the Mason County Department of Health Services (MCDHS).
1.1 Background The Mason County Landfill is located near Shelton in Mason County, Washington (Section 4, Township 20 North, Range 4 West). The site address is 501 West Eells Hill Road, Shelton, Washington. The facility is located in a sparsely populated area used primarily for tree farming. Two private properties, the Culver (formerly Ruggle) residence and the Shelton Auto Yard, are located within 1 mile of the facility.
The 8‐acre landfill is situated within a 77‐acre property and was the primary municipal solid waste disposal facility for Mason County from the early 1970s until the summer of 1993, when closure construction began. A solid waste transfer station is currently operating at the facility. Other features shown on the vicinity map (Figure 1) include two former septage disposal areas and two older landfill areas where waste was placed historically. Material from the septage disposal areas was excavated and stockpiled at the facility in 1990. Closure activities were completed in 1993 and consisted of capping, implementing surface water controls, and constructing a gas extraction system.
The Washington State Department of Corrections (WDOC) has operated a wastewater spray field on the property south of the landfill since 1999. The WDOC conducts quarterly groundwater monitoring at four wells including landfill wells MW‐6 and MW‐9, and sampling is currently conducted by Shelton Wastewater Treatment Plant personnel. Well MW‐6 is upgradient from the spray field, and well MW‐9 is downgradient from the spray field. Sampling of well MW‐6 by the County has been discontinued as recommended in the 2005 Annual Report (Parametrix 2005).
Groundwater monitoring wells MW‐1B, MW‐2B, MW‐3B, MW‐4, and MW‐5B were installed in 1986 and 1987, and wells MW‐6 through MW‐10 were installed in 1991. The “B” suffix is applied to wells where previous test borings were drilled at the same location. Routine groundwater monitoring was first conducted at the landfill during 1988 by Hart Crowser, and has continued to the present.
The Culver (formerly Ruggle) and Auto Yard domestic wells were sampled periodically during the 1980s, and were part of the routine monitoring program beginning in November 1989 (Ruggle) and February 1990 (Auto Yard). On‐site water supply wells TH‐1S and TH‐1D were first monitored in 1975; monitoring of these wells was discontinued after the first quarter of 1995 per approval of the MCDHS (1996).
As a result of recommendations made in the 2002 annual report (Parametrix 2003), several changes were made to the monitoring program with the approval of the Mason County Department of Health Services (MCDHS 2003), including discontinuation of sampling at well MW‐9 and the Auto Yard well. In addition, sampling of well MW‐2B was discontinued beginning in 2008 per recommendations presented in the 2006 Annual Report (Parametrix 2006) with approval of the MCDHS (MCDHS 2007).
Information pertaining to samples collected prior to 1988 is included in the landfill closure plan (Parametrix 1991) and the 1988 monitoring summary report by Hart Crowser (1989). Annual groundwater monitoring reports have been prepared by Parametrix since 1991.
2015 Annual Groundwater Monitoring Report Mason County Landfill Mason County Department of Utilities and Waste Management
1‐2 November 2015 │ 555‐1682‐042 (04/03)
The 2013 Annual Monitoring Report (Parametrix 2015) recommended reducing the sampling locations to include upgradient well MW‐4 and downgradient wells located at the point of compliance (MW‐3B, MW‐8, and MW‐10), and reducing the sampling frequency with the next sampling event to be conducted in Spring 2015.
1.2 Geology and Hydrogeology The region is underlain by a thick sequence of unconsolidated glacial and non‐glacial Pleistocene deposits. The deposits typically consist of interbedded layers of glacial outwash sands and gravels, till, and occasional interglacial fluvial and lacustrine deposits.
The site is underlain by outwash sands and gravels to a depth of approximately 70 ft. A fine‐grained deposit consisting of silt with some fine sand and clay is present beneath the outwash to depths of up to 116 ft below ground surface. These units have been referred to as Unit A and Unit B, respectively, in previous site reports (Parametrix 1991). An unconsolidated sandy gravel deposit (Unit C) underlies Unit B and extends to at least 180 ft below ground surface at the landfill. Bedrock conditions are unknown, but not considered significant to the hydrogeologic conditions at the site.
The Unit A outwash deposits form the uppermost hydrostratigraphic unit at the site. Groundwater is present in Unit A under unconfined conditions at a depth of less than 50 ft below ground surface; groundwater is also present in Unit C under confined conditions. Regional groundwater flow generally follows the topography toward surface water discharge points. In the vicinity of the landfill, the groundwater flow direction in Unit A is to the south‐southeast toward Goldsborough Creek (Parametrix 1991). No information regarding the groundwater flow direction in Unit C is available.
Monitoring wells MW‐1B through MW‐10 and supply well TH‐1S are screened in the uppermost aquifer (Unit A); supply well TH‐1D is screened in an underlying aquifer (Unit C). The depths and screened intervals of the off‐site water supply wells (Culver wells and Auto Yard well) are unknown, but these wells are assumed to be completed in Unit A.
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2015 Annual Groundwater Monitoring Report Mason County Landfill
Mason County Department of Utilities and Waste Management
November 2015 │ 555‐1682‐042 (04/03) 2‐1
2. MONITORING PROGRAM
2.1 Sampling Locations and Frequency The 2015 groundwater monitoring at the Mason County Landfill was conducted in accordance with the recommendations made in the 2013 Annual Report (Parametrix 2015) that included sampling of upgradient well MW‐4, downgradient wells located at the point of compliance (MW‐3B, MW‐8, and MW‐10), and the domestic Culver well.
The locations of the on‐site and off‐site wells used for groundwater monitoring and water level measurements at the Mason County Landfill are shown on Figure 1. MW‐4 is the upgradient monitoring well, and MW‐2B and MW‐6 are located downgradient from the former septage lagoon. Other on‐site monitoring wells are located downgradient from the closed landfill and/or older landfilling locations. Wells MW‐1B, MW‐2B, MW‐3B, MW‐5B, MW‐8, and MW‐10 are located at the perimeter of the landfill property, and wells MW‐1B, MW‐3B, MW‐8, and MW‐10 are located downgradient of the closed landfill area at the point of compliance.
Sampling of well MW‐6 by the County has been discontinued as recommended in the 2005 Annual Report (Parametrix 2005). Instead, available monitoring data collected as part of the WDOC wastewater spray field monitoring program are attached to this report (Appendix D). The annual event that includes testing for metals is conducted in March.
The 2015 sampling event was conducted on July 8 by Parametrix staff. Samples were collected from monitoring wells MW‐3B, MW‐8, and MW‐10 and at the Culver well. Sampling at upgradient well MW‐4 was attempted but was not successful due to a broken pump assembly. Duplicate samples (designated MW‐11) were collected from well MW‐3B for quality control purposes.
Monitoring wells were purged and sampled using dedicated Hydrostar® pumps. The domestic well (Culver new well) was sampled from an outdoor spigot. Groundwater sampling locations and procedures are described further in the Mason County Sanitary Landfill Final Closure Plan (Parametrix 1991).
2.2 Analytical Parameters Groundwater samples were analyzed for the Chapter 173‐304 WAC parameters required by the current Solid Waste Handling Facility Closure/Post‐Closure Permit. In addition, groundwater samples were analyzed for dissolved arsenic and volatile organic compounds, which have been detected historically in groundwater at the facility. Analytical parameters analyzed in all wells are summarized in Table 1. Samples were submitted to Analytical Resources, Inc. (ARI) in Seattle, Washington for chemical analysis.
2015 Annual Groundwater Monitoring Report Mason County Landfill Mason County Department of Utilities and Waste Management
2‐2 November 2015 │ 555‐1682‐042 (04/03)
Table 1. Summary of Analytical Parameters — Mason County Landfill 2015 Groundwater Monitoring
Chapter 173‐304 WAC Parameters (Solid Waste Handling Facility Permit):
Field Parameters:
Temperature pH Specific Conductivity
Conventionals:
Chemical Oxygen Demand Nitrate as Nitrogen Chloride
Ammonia as Nitrogen Total Organic Carbon Sulfate
Nitrite as Nitrogen
Metals (dissolved):
Iron Manganese Zinc
Other Parameters
Metals (dissolved):
Arsenic
Organics:
Volatile Organic Compounds
2015 Annual Groundwater Monitoring Report Mason County Landfill
Mason County Department of Utilities and Waste Management
November 2015 │ 555‐1682‐042 (04/03) 3‐1
3. GROUNDWATER FLOW DIRECTION
3.1 Groundwater Levels Water level data were collected at all wells (measurements at the Culver well are collected from the older well because the new well cannot be accessed for water level measurements) and are summarized in Table 2.
Table 2. Summary of July 2015 Groundwater Elevations, Mason County Landfill
Well Number
Reference Elevation Top of PVC (ft MSL)
Groundwater Elevation (feet MSL)
July 8, 2015
MW‐1B 290.82 266.93
MW‐2B 307.10 267.11
MW‐3B 306.37 266.82
MW‐4 312.01 268.41
MW‐5B 305.54 267.03
MW‐6 311.21 267.94
MW‐7 309.77 267.42
MW‐8 306.23 266.97
MW‐9 306.43 266.76
MW‐10 306.74 266.81
Culver (old well) 283.00 265.11
3.2 Groundwater Flow Direction and Rate Potentiometric surface contour maps were prepared using data collected during the July 2015 monitoring event and are presented in Figure 2. As previously observed, the groundwater flow direction was to the east‐southeast. The groundwater gradient (between MW‐4 and MW‐8) was approximately 0.0008 ft/ft. Using the observed gradient, the rate of groundwater flow is estimated at between 5 and 10 ft per day. This estimate was calculated using measured hydraulic conductivity values ranging from about 2,100 ft/day to 2,400 ft/day (Parametrix 1991) and estimated effective porosities for sand and gravel ranging from 20 to 35 percent (Freeze and Cherry 1979).
2015 Annual Groundwater Monitoring Report Mason County Landfill
Mason County Department of Utilities and Waste Management
November 2015 │ 555‐1682‐042 (04/03) 4‐1
4. ANALYTICAL RESULTS Analytical results for the 2015 groundwater monitoring are summarized in Appendix A (inorganic and field parameters) and Appendix B (volatile organic compounds). The laboratory report and chain‐of‐custody form for the July sampling event are presented in Appendix C. Appendix D presents monitoring data available beginning in 2014 for well MW‐6 provided by the Shelton Wastewater Treatment Plant.
4.1 Data Validation Parametrix conducted a Quality Assurance/Quality Control (QA/QC) review of the laboratory data. The QA/QC review included a complete check of holding times, field duplicate results, and blank results. The laboratory QC internal standard data were also reviewed, including matrix spikes, matrix spike duplicates, surrogate recoveries, and laboratory control samples. No qualifiers were added to the data as a result of this review.
4.2 Comparison to Groundwater Quality Standards Analytical results were evaluated by comparison to the Washington State groundwater standards (GWQSs; WAC 173‐200) and to the state Maximum Contaminant Levels for drinking water (MCLs; WAC 246‐290). Concentrations that were above water quality standards are summarized in Table 3 and discussed in the following sections. Those standards designated primary and carcinogen are potential risks to human health. Secondary standards are based on other factors including odor, taste, and color.
4.2.1 On‐Site Wells The secondary standards for manganese were exceeded in wells MW‐3B and MW‐8, but were below the standards in further downgradient well MW‐10. pH concentrations were below the range of the GWQS, as typically observed, and are believed to reflect naturally occurring conditions (Parametrix 1991). No volatile organic compounds were detected.
4.2.2 Off‐Site Well In the Culver domestic well, the results with the exception of pH met the primary and secondary GWQSs and MCLs. No volatile organic compounds were detected.
2015 Annual Groundwater Monitoring Report Mason County Landfill Mason County Department of Utilities and Waste Management
4‐2 November 2015 │ 555‐1682‐042 (04/03)
Table 3. Summary of Groundwater and Drinking Water Quality Criteria Exceedances, Mason County Landfill 2015 Groundwater Monitoring
Secondary Contaminants Carcinogens
pH
(units) Dissolved Iron
(mg/L) Dissolved Manganese
(mg/L) Dissolved Arsenic
(mg/L)
GWQS 6.5‐8.5 0.3 0.05 0.00005
MCL 0.3 0.05 0.01
ON‐SITE WELLS Upgradient Well MW‐4 NS NS NS NS Landfill Monitoring Wells
MW‐3B 5.47 ‐‐ 0.543 ‐‐ MW‐8 5.50 ‐‐ 0.214 ‐‐ MW‐10 5.58 ‐‐ ‐‐ ‐‐ OFF‐SITE WELLS
Culver (new well) 5.85 ‐‐ ‐‐ ‐‐
GWQS = Groundwater quality standards (Chapter 173‐200 WAC)
MCL = Maximum contaminant level for drinking water (Chapter 246‐290 WAC) ‐‐ Criteria not exceeded NS = well not sampled due to pump malfunction
4.3 Groundwater Quality Trends The effect of landfill closure on groundwater quality was evaluated using time‐series plots and the Mann‐Kendall and Sen’s slope statistical tests. This evaluation was previously presented in the Annual Report for 2013 (Parametrix 2015), and has been updated to incorporate the results of the July 2015 sampling event.
The evaluation was conducted for indicator parameters (dissolved arsenic, chloride, COD, specific conductivity, dissolved iron, dissolved manganese, ammonia, nitrate, nitrite, pH, sulfate, TOC, and dissolved zinc), and volatile organic compounds (vinyl chloride and tetrachloroethene) in the upgradient monitoring well (MW‐4) and seven downgradient monitoring wells (wells MW‐1B, MW‐3B, MW‐5B, MW‐7, MW‐8, MW‐10, and Culver). A time‐series plot is also presented for the volatile organic compound carbon tetrachloride for upgradient well MW‐4 and downgradient wells MW‐1B, MW‐2B, and MW‐6. Carbon tetrachloride has not been detected in any other wells at the site and was believed historically to be related to impacts from former septage application areas of the site (see Figure 1).
4.3.1 Time Series Plots Time‐series plots and trend analyses are presented in Appendix E and summarized in the following sections.
4.3.1.1 Indicator Parameters Overall decreasing trends in the concentrations of indicator parameters continued to be observed since landfill closure in 1993. Concentrations remained generally highest directly downgradient of the landfill at well MW‐7 and decreased with distance from the landfill in further downgradient monitoring wells on the landfill property (wells MW‐3B, MW‐8 and MW‐10). Concentrations of zinc in the Culver well show
2015 Annual Groundwater Monitoring Report Mason County Landfill
Mason County Department of Utilities and Waste Management
November 2015 │ 555‐1682‐042 (04/03) 4‐3
more variability and are typically slightly higher than the concentrations in the landfill monitoring wells. It is likely that the zinc concentrations observed in the Culver well are related to factors other than landfill impacts. Actual concentrations of zinc in the Culver well (all below 0.1 mg/L) are substantially below the secondary MCL and GWQS criterion of 5 mg/L.
4.3.1.2 Volatile Organic Compounds Vinyl chloride has not been detected in well MW‐7 since the second quarter of 2001, in wells MW‐3B and MW‐8 since 1998, and in well MW‐10 since 1995. Carbon tetrachloride has not been detected in any well since 2005.
4.3.2 Statistical Analysis of Trends Potential trends in the groundwater data were evaluated using the Mann‐Kendall test for trend and Sen’s nonparametric estimator of slope (Gibbons 1994; Gilbert 1987, USEPA 2009). These tests are well suited to environmental data because there are no distributional assumptions, and missing data (non‐detects) or irregularly spaced measurement periods are permitted. The Mann‐Kendall test was used to identify whether or not a trend exists, and then the Sen’s slope test was used to determine how steeply the concentration levels are changing.
Trend analyses were conducted using all data measured at the Mason County Landfill monitoring wells between November 1991 and July 2015. In addition, trend analyses were conducted using data from the latest eight consecutive sampling events for each well as recommended in Ecology’s guidance document “Preparing for Termination of Post‐Closure Activities at Landfills Closed Under Chapter 173‐304 WAC.” (Ecology 2011, 2015). The latest eight events for wells, except MW‐4, MW‐1B, and MW‐5B started with September 2010 and ended with July 2015. MW‐4 started with March 2010 because no data were collected in July 2015 due to pump malfunction, and MW‐1B and MW‐5B started with February 2006 because those wells were only sampled during the spring event through 2013.
All non‐detected values were given a value equal to one half the reporting limit (Gilbert 1987, Gibbons 1994). The results of the trend analyses are presented in Appendix E.
4.3.2.1 Mann‐Kendall Tests The nonparametric Mann‐Kendall test evaluates the significance of temporal trends at the 95 percent confidence level. A negative value for the Mann Kendall S statistic implies that a majority of the differences between earlier and later values are negative, suggestive of a decreasing trend. An S value near zero indicates a roughly equal number of positive and negative differences. This would be expected if the measurements were randomly fluctuating about a constant mean with no apparent trend.
4.3.2.2 Sen’s Slope Tests The Sen’s slope test is a nonparametric procedure used to estimate the true slope of the data. The advantage of the Sen’s slope test over linear regression methods is that it is not greatly affected by gross data errors or outliers, and can be computed when data are missing.
2015 Annual Groundwater Monitoring Report Mason County Landfill Mason County Department of Utilities and Waste Management
4‐4 November 2015 │ 555‐1682‐042 (04/03)
4.3.2.3 Summary of Statistical Results For all data collected since November 1991, the results of the combined Mann‐Kendall tests and Sen’s slope tests (see Appendix E) indicate statistically significant downward trends or no trend for all parameters in both upgradient and downgradient wells, except for the following cases:
Upward trends in dissolved iron and dissolved zinc in upgradient well MW‐4 and several of the downgradient wells. It is likely that the upward trends calculated for these parameters are due to historical increases in reporting limits since there are mostly non‐detected values in the wells with upward trends.
Upward trend in sulfate in downgradient well MW‐7. The sulfate trends is not believed to represent landfill impacts since there is a high degree of variability in sulfate concentrations across the site and there was no trend in the MW‐7 sulfate data over the latest eight events (see subsequent section). Actual concentrations in MW‐7 (all below 15 mg/L) are substantially below the secondary criterion of 250 mg/L.
Upward trend in nitrate in upgradient well MW‐4.
Downward trend in pH in all wells, both upgradient and downgradient. Since the trend also occurred in the upgradient well, the downward trend in pH appears to indicate a site‐wide or regional trend.
For the latest eight consecutive sampling events, the results of the combined Mann‐Kendall and Sen’s slope tests indicate no trend or statistically significant downward trends for all parameters in both upgradient and downgradient wells, except for the following cases:
Upward trend for nitrate in upgradient well MW‐4 and downgradient well MW‐3B. Nitrate also showed a significant upward trend in upgradient well MW‐4 using all data, likely reflecting a site‐wide or regional trend. Actual concentrations in both these wells (all below 0.4 mg/L) are substantially below the criterion of 10 mg/L.
Downward trend for pH in downgradient well MW‐3B and Culver well. The downward trend in pH likely indicates a site‐wide or regional trend since there were significant downward trends in all site wells including upgradient well MW‐4 when all data were considered.
The results of trend analyses indicate there were no statistically significant upward trends in downgradient monitoring wells over the most recent eight events, or in any well located downgradient from the closed landfill at the point of compliance for all data measured during the post‐closure period between November 1991 and July 2015. The only exceptions were cases where there was also a significant upward trend (or downgradient trend in the case of pH) in the upgradient monitoring well indicating either the presence of a site‐wide or regional trend, or increasing reporting limits over time.
2015 Annual Groundwater Monitoring Report Mason County Landfill
Mason County Department of Utilities and Waste Management
November 2015 │ 555‐1682‐042 (04/03) 5‐1
5. CONCLUSIONS AND RECOMMENDATIONS
5.1 Conclusions The 1993 closure of the waste disposal areas was designed to reduce leachate generation and, therefore, reduce groundwater impacts. The 2015 monitoring results indicate these reductions continue to occur since groundwater quality impacts from the former landfill are generally decreasing over time.
The extent of groundwater impacts is largely confined to the area immediately downgradient from the landfill at well MW‐7, and to a lesser extent at further downgradient wells MW‐3B and MW‐8. Vinyl chloride has not been detected in any well since 2001.
In monitoring wells located downgradient from the closed landfill at the point of compliance (MW‐1B, MW‐3B, MW‐8, and MW‐10), the only parameter that exceeds the MCL or GWQS criteria (other than pH which is believed to be naturally occurring) is dissolved manganese in wells MW‐3B and MW‐8. The GWQS criterion for manganese is the same as the MCL which is not based on human health but is established as a guidance to assist public water systems to manage drinking water for aesthetic considerations such as taste, color, and odor. Manganese concentrations were below the GWQS criteria in further downgradient monitoring well MW‐10 and the Culver domestic well. Over the last five years of monitoring, none of the landfill monitoring wells have exceeded the Model Toxics Control Act Method B criteria for manganese (2.2 mg/L) that is based on human health criteria.
There were no exceedances of GWQS criteria in the domestic Culver well located approximately 1,400 ft from the landfill property boundary. No volatile organic compounds were detected in the Culver well in 2015.
The information presented in this report documents that a clear reduction in concentrations of landfill indicator parameters has occurred since landfill closure in 1993. The trend analyses indicate either no trend or a statistically significant downward trend for all parameters in wells located at the point of compliance, both since landfill closure and over the last eight sampling events. The only exceptions were cases where there was also a significant upward trend (or downgradient trend in the case of pH) in the upgradient monitoring well indicating either the presence of a site‐wide or regional trend, or increasing reporting limits over time.
5.2 Recommendations The Mason County Landfill closed in 1993, and the 20‐year post‐closure period was completed with the fall 2013 monitoring event. A post‐closure care summary report will be prepared summarizing relevant environmental information and evaluating the stability of the landfill in accordance with the Ecology guidance document “Preparing for Termination of Post‐Closure Activities at Landfills Closed Under Chapter 173‐304 WAC.” In addition to summarizing the status of the groundwater monitoring as presented in this report, the post‐closure care summary report will provide an evaluation of and recommendations for other environmental systems that prevent or monitor releases to the environment including the cover system and the gas collection and monitoring system.
Continued groundwater monitoring of selected monitoring wells at a reduced frequency is recommended to verify that post‐closure groundwater quality continues to be stable or improving, and to meet Ecology and MCDHS requirements.
2015 Annual Groundwater Monitoring Report Mason County Landfill Mason County Department of Utilities and Waste Management
5‐2 November 2015 │ 555‐1682‐042 (04/03)
The following are recommendations for the Mason County Landfill groundwater monitoring system:
Inspect monitoring wells annually to ensure they are covered and locked.
Collect samples of groundwater in two years (spring 2017) from upgradient well MW‐4, wells downgradient from the closed landfill located at the point of compliance (MW‐3B, MW‐8, and MW‐10) and from the domestic Culver well. Analyze the samples for the parameters listed in Table 1.
Based on the results of the spring 2017 groundwater sampling, make recommendations regarding future groundwater monitoring.
2015 Annual Groundwater Monitoring Report Mason County Landfill
Mason County Department of Utilities and Waste Management
November 2015 │ 555‐1682‐042 (04/03) 6‐1
6. REFERENCES
Freeze, R.A. and J.L. Cherry. 1979. Prentice‐Hall, Inc. Englewood Cliffs, New Jersey, 604p.
Gibbons, R.D. 1994. Statistical Methods for Groundwater Monitoring. John Wiley and Sons, Inc. New York
Gilbert, R.O. 1987. Statistical Methods for Environmental Pollution Monitoring. Van Nostrand Reinhold. New York
Hart Crowser. 1989. Groundwater Monitoring Summary Report for 1988, Mason County Landfill, Mason County, Washington. Prepared for Mason County Department of General services. March 24, 1989. Seattle, Washington.
Mason County Department of Health Services (MCDHS). 1996. Letter from Mason County Department of Health Services to Parametrix, Inc. May 7, 1996.
Mason County Department of Health Services (MCDHS). 2003. Letter from Mason County Department of Health Services to Mason County Department of Utilities and Waste Management. April 8, 2003.
Mason County Department of Health Services (MCDHS). 2007. Email from Rose Swier, Environmental Health Specialist III, to David Baker, Mason County Department of Utilities and Waste Management, May 23, 2007.
Parametrix, Inc. 1991. Mason County Sanitary Landfill Final Closure Plan. Prepared for Mason County Department of General Services. April 1991. Seattle, Washington.
Parametrix, Inc. 2003. 2002 Groundwater Monitoring Annual Report, Mason County Landfill. Prepared for Mason County Department of Utilities and Waste Management. February 2003.
Parametrix, Inc. 2005. 2005 Groundwater Monitoring Annual Report, Mason County Landfill. Prepared for Mason County Department of Utilities and Waste Management. December 2005.
Parametrix, Inc. 2006. 2006 Groundwater Monitoring Annual Report, Mason County Landfill. Prepared for Mason County Department of Utilities and Waste Management. December 2006.
Parametrix, Inc. 2015. 2013 Groundwater Monitoring Annual Report, Mason County Landfill. Prepared for Mason County Department of Utilities and Waste Management. June 2015.
U.S. Environmental Protection Agency (USEPA). 2009. Statistical Analysis of Groundwater Monitoring Data at RCRA Facilities – Unified Guidance. March.
Washington State Department of Ecology (Ecology). 2011. Preparing for Termination of Post‐Closure Activities at Landfills Closed Under Chapter 173‐304 WAC. Publication 11‐07‐006.
Washington State Department of Ecology (Ecology). 2015. Addendum to Preparing for Termination of Post‐Closure Activities at Landfills Closed Under Chapter 173‐304 WAC.
Appendix A Tabulated 2015 Groundwater Monitoring Results,
Inorganic and Field Parameters
Tab
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, 201
5, M
aso
n C
ou
nty
Lan
dfi
ll
MW
-3B
MW
-11
MW
-4M
W-8
MW
-10
Cu
lver
An
alyt
eU
nit
sM
CL
(MW
-3B
Du
p)
(fo
rmer
ly R
ug
gle
)
FIE
LD
PA
RA
ME
TE
RS
Tem
pera
ture
Cen
tigra
de10
.33
- -- -
10.4
010
.15
10.4
1pH
units
6.5-
8.5
**5.
47- -
- -5.
505.
585.
85S
peci
fic C
ondu
ctiv
ityµm
hos/
cm@
25C
700
**73
- -- -
8271
112
CO
NV
EN
TIO
NA
LS
Chl
orid
em
g/L
250
**25
0**
2.0
2.0
- -2.
32.
12.
2N
-Am
mon
iam
g-N
/L0.
027
0.02
9- -
0.08
00.
018
0.01
4N
-Nitr
ate
mg-
N/L
10*
10*
0.16
40.
188
- -0.
319
0.35
50.
330
N-N
itrite
mg-
N/L
1*
<0.0
10<0
.010
- -<0
.010
<0.0
10<0
.010
Nitr
ate
+ N
itrite
mg-
N/L
0.16
40.
188
- -0.
319
0.35
50.
330
Sul
fate
mg/
L25
0**
250
**2.
22.
6- -
2.8
2.6
2.9
Che
mic
al O
xyge
n D
eman
dm
g/L
<10.
0<1
0.0
- -<1
0.0
<10.
0<1
0.0
Tota
l Org
anic
Car
bon
mg/
L<0
.50
0.53
- -<0
.50
0.58
<0.5
0
ME
TA
LS
Ars
enic
(Dis
solv
ed)
mg/
L0.
01*
0.00
005
***
<0.0
002
<0.0
002
- -<0
.000
2<0
.000
2<0
.000
2Iro
n (D
isso
lved
)m
g/L
0.3
**0.
3**
<0.0
50<0
.050
- -<0
.050
<0.0
50<0
.05
Man
gane
se(D
isso
lved
)m
g/L
0.05
**0.
05**
0.54
30.
561
- -0.
214
<0.0
01<0
.001
Zinc
(Dis
solv
ed)
mg/
L5
**5
**<0
.010
<0.0
10- -
<0.0
10<0
.010
0.02
0
No
tes: - -
= N
ot M
easu
red
MC
L=
Max
imum
Con
tam
inan
t Lev
el fo
r drin
king
wat
er (W
AC
246
-290
)G
WQ
S=
Was
hing
ton
Sta
te G
roun
dwat
er S
tand
ards
(WA
C 1
73-2
00)
= D
oes
not m
eet s
tand
ard
*=
Prim
ary
Con
tam
inan
t Crit
eria
**=
Sec
onda
ry C
onta
min
ant C
riter
ia**
*=
Car
cino
gen
Con
tam
inan
t Crit
eria
Cul
ver:
Wat
er le
vel m
easu
red
in o
ld w
ell,
sam
ple
colle
cted
from
new
wel
l.
GW
QS
Mas
on C
ount
y La
ndfil
l55
5-16
82-0
428/
5/20
15Ju
ly 2
015
GW
Dat
a.xl
sx
Appendix B Tabulated 2015 Groundwater Monitoring Results,
Volatile Organic Compounds
Table B-1. Groundwater Monitoring Results for Organic Parameters, July 8, 2015, Mason County Landfill
MW-3B MW-11 MW-8 MW-10 Culver Trip Blank
Analyte Units MCL (MW-3B Dup)(formerly Ruggle)
VOLATILE ORGANICSChloromethane µg/L <0.50 <0.50 <0.50 <0.50 <0.50 <0.50Bromomethane µg/L <1.0 <1.0 <1.0 <1.0 <1.0 <1.0Vinyl Chloride µg/L 2 * 0.02 *** <0.020 <0.020 <0.020 <0.020 <0.020 <0.020Chloroethane µg/L <0.20 <0.20 <0.20 <0.20 <0.20 <0.20Methylene Chloride µg/L 5 * 5 *** <1.0 <1.0 <1.0 <1.0 <1.0 <1.0Acetone µg/L <5.0 <5.0 <5.0 <5.0 <5.0 <5.0Carbon Disulfide µg/L <0.20 <0.20 <0.20 <0.20 <0.20 <0.201,1-Dichloroethene µg/L 7 * <0.20 <0.20 <0.20 <0.20 <0.20 <0.201,1-Dichloroethane µg/L 1 *** <0.20 <0.20 <0.20 <0.20 <0.20 <0.20trans-1,2-Dichloroethene µg/L 100 * <0.20 <0.20 <0.20 <0.20 <0.20 <0.20cis-1,2-Dichloroethene µg/L 70 * <0.20 <0.20 <0.20 <0.20 <0.20 <0.20Chloroform µg/L 100 *THM 7 *** <0.20 <0.20 <0.20 <0.20 <0.20 <0.201,2-Dichloroethane µg/L 5 * 0.5 *** <0.20 <0.20 <0.20 <0.20 <0.20 <0.202-Butanone µg/L <5.0 <5.0 <5.0 <5.0 <5.0 <5.01,1,1-Trichloroethane µg/L 200 * 200 * <0.20 <0.20 <0.20 <0.20 <0.20 <0.20Carbon Tetrachloride µg/L 5 * 0.3 *** <0.20 <0.20 <0.20 <0.20 <0.20 <0.20Vinyl Acetate µg/L <0.20 <0.20 <0.20 <0.20 <0.20 <0.20Bromodichloromethane µg/L 100 *THM 0.3 *** <0.20 <0.20 <0.20 <0.20 <0.20 <0.201,2-Dichloropropane µg/L 5 * 0.6 *** <0.20 <0.20 <0.20 <0.20 <0.20 <0.20cis-1,3-Dichloropropene µg/L <0.20 <0.20 <0.20 <0.20 <0.20 <0.20Trichloroethene µg/L 5 * 3 *** <0.20 <0.20 <0.20 <0.20 <0.20 <0.20Dibromochloromethane µg/L 100 *THM <0.20 <0.20 <0.20 <0.20 <0.20 <0.201,1,2-Trichloroethane µg/L 5 * <0.20 <0.20 <0.20 <0.20 <0.20 <0.20Benzene µg/L 5 * 1 *** <0.20 <0.20 <0.20 <0.20 <0.20 <0.20trans-1,3-Dichloropropene µg/L <0.20 <0.20 <0.20 <0.20 <0.20 <0.202-Chloroethylvinylether µg/L <1.0 <1.0 <1.0 <1.0 <1.0 <1.0Bromoform µg/L 100 *THM 5 *** <0.20 <0.20 <0.20 <0.20 <0.20 <0.204-Methyl-2-Pentanone µg/L <5.0 <5.0 <5.0 <5.0 <5.0 <5.02-Hexanone µg/L <5.0 <5.0 <5.0 <5.0 <5.0 <5.0Tetrachloroethene µg/L 5 * 0.8 *** <0.20 <0.20 <0.20 <0.20 <0.20 <0.201,1,2,2-Tetrachloroethane µg/L <0.20 <0.20 <0.20 <0.20 <0.20 <0.20Toluene µg/L 1,000 * <0.20 <0.20 <0.20 <0.20 <0.20 <0.20Chlorobenzene µg/L 100 * <0.20 <0.20 <0.20 <0.20 <0.20 <0.20Ethylbenzene µg/L 700 * <0.20 <0.20 <0.20 <0.20 <0.20 <0.20Styrene µg/L 100 * <0.20 <0.20 <0.20 <0.20 <0.20 <0.20Trichlorofluoromethane µg/L <0.20 <0.20 <0.20 <0.20 <0.20 <0.201,1,2-Trichlorotrifluoroethane µg/L <0.20 <0.20 <0.20 <0.20 <0.20 <0.20m,p-Xylene µg/L 10,000 *XYL <0.40 <0.40 <0.40 <0.40 <0.40 <0.40o-Xylene µg/L 10,000 *XYL <0.20 <0.20 <0.20 <0.20 <0.20 <0.20
NOTES: - - = Not MeasuredMCL = Maximum Contaminant Level for drinking water (WAC 246-290)
GWQS = Washington State Groundwater Standards (WAC 173 - 200)= Does not meet standard
* = Primary Contaminant Criteria** = Secondary Contaminant Criteria
*** = Carcinogen Contaminant CriteriaTHM = Total trihalomethanes cannot exceed 100 µg/LXYL = Total xylenes cannot exceed 10,000 µg/L
VOC detections shown in bold
GWQS
Mason County Landfill 555-1682-042
8/5/2015July 2015 GW Data.xlsx
Appendix C July 2015 Laboratory Report and
Chain‐of‐Custody Form
@l*?J#:f si' ffff i II?; 1 n cot P o rated
21 July 2015
Lisa GilbertParametrix, lnc.719 2nd Avenue, Suite 200Seattle, WA 98104
RE: Project: 555-1582-042, Mason County LFARlJob No. AlXl
Dear Lisa:
Please find enclosed the original Chain of Custody (COC) records and the final results forthe samples for the project referenced above. Analytical Resources, lnc. accepted fivewater samples and one trip blank in good condition on July 8, 2015. lt was noted uponsample receipt that the trip blank was not listed on the COC. The samples were analyzedfor VOAs, vinyl chloride by GC/MS-SIM, selected general chemistry parameters anddissolved metals as requested.
The percent recoveries for the surrogate, d4-1,2-dichlorothane, were high following the8260-VOC analyses of several of these samples. Since no target compounds weredetected in any of these samples, the high bias does not compromise and LOQ. Nocorrective actions were taken.
Matrix spikes (MSs) and matrix spike duplicates (MSDs) were prepared and analyzed for8260-VOCs in conjunction with sample MW-38 and MW-1 1. The percent recoveries forseveral compounds were high following the analyses of both MS/MSD pairs. Since notarget compounds were detected in any sample associated with these MSIMSD, the highbias does not compromise and LOQ. No corrective actions were taken.
There were no further problems with these analyses.
A copy of these reports and all raw data will remain on file at ARl. lf you have questions,or require further information, please contact me at your convenience.
Sincerely,
ANALYTICAL RESOURCES, INC.
')1 , -\- -'./ / (-b '-( /)rt;,/ --- \ tv-vMArk D. HarrisProject Manager206/695-6210<[email protected]>
Enclosures
cc: File AlXl
MDH/mdh
Poge I of 1i4611 South 134th Place, Suite 100 , TukwilaWAgBl68 r 206-695-6200. 206-695-6201 fax
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ARI Client:
COC No(s):
@ ff : i[i::l ff :ffir:#'."itff il::l, Cooler Receipt Form
YES
/vE9
G
Project Name:
tu- Deliverad by: Fed-Ex UPS Courier
Assigned ARI Job No:
@NO
NO
remp Gun w, C)/) ?fi??9?,.-----/_-rime: l1S I
H€{ Deji}ered other:
Tracklng No:
-
,,{APreliminary Examination Phase:
Were intacl, properly signed and dated custody seals attached to the outside of to cooler?
Were custody papers included with the cooler?
Werecustodypapersproperlyfilledout(ink,signed,etc.).........-.......TemperatutgEcoole(s) ("C) (recommended 2-06-0 'C for chemistry)
1 .V q.BIf cooler temperature is out of compliance fill out fom 00070F
Cooler Accepted by:
Was a temperature blank included in the cooler?
\lVhat kind of packing materiatwas used? fubble W]?p d;tg cet Packs eaggies ffi BroLk paper\ -..Was sufficient ice used (if appropriate)? ..................:................... NA
Were all bottles sealed in individual plastic bags?
Did all bottles anive in good condition (unbroken)? ......--...........-..
documents
Were all bottle labels complete and legible?
Did the number of containers listed on COC match with the number of containers received?
Did all bottle labels and tags agree with custody papers? ...... -.. ... ..
Were all bottles used correct for the requested analyses?
Do any of the analyses (bottles) fequire preservation? (attach preservation sheet, excluding VOCs)...
Were all VOC vials free of air bubbles? ....................
Was sufficient amount of sample sent in each bottle? ...... ........
Date VOC Trip BIank was made at AR|.....................
was Sample sptit by ARt , 64r YES DatelTtme: Equipment:
Samples Logged by: Aw
{NA)0qNO
NO
6-ENO
YES
Other:-YES
YES
Ggrfes,YES
Gi,(-ii(isNA
NA
NO
NO
NO
NO
Split by:
oate =t /q I ( S- t^", ?.)5'* Notify Project Manager of discrepancies or concems *
Sample lD on Bottle Sample lD on COC Sample lD on Bottle Sample lD on COC
Additi onal N otes, Ascrepan cies, I Reso/ufions.'
ii,;,1.4 *i/l t/i4l y'rcrir,rr( ctr#rcitt ti /abel'Cu\w.r haS I br:\plr! b vlc\\s, t-$t'5, t-+si)rn\hG,1-So.rrt\HDP*-
By: +v Date: 7/rilrc'.$mgJl Ajt &rbbles fi i,".-rrl6t,
-Itnrn ll t< nt. ; ll -'-"'r' : ll .o.*Small)"sm'(<2mm)Peabubbles ) *pb" (2to <4 mm )
Largc+*lg"(4to<6mm)
Headspace ) "hs" (>6mm)
0016F3tzt10
Revision 014
f-: ii 5 :E- : 1i3"i=+:3&-;=
Cooler Receipt Form
@Analytrcal Resources,IncorporatedAnalytrcal Coemists andConsu.l,tants
Gooler TemperatureCompliance Form
Bottle Count
Sample lD
Completed by:
Version 0003/3/09*-*E ;, _E- :1, - gE!g!rI{F:*!,,-g
00070F Cooler Temperature Compliance Form
SaDpIe ID
sampre rD Cross Reference Report i!35ffS*@
ARI Job No: AIX1Client: Parametrix, fnc.
Pro;ect Event: 5551682042Project Name: Mason County Landfill
ARI ARIL,ab ID LIMS ID l,Iatrix Sarnp].e Date/Tine VTSR
1. MW-102. MW-83. MW-384. MW-115. Culver6. TRIP BLANKS
AIXIA 15-L2262 WaLer O7/a8/!5 Lt:a1 01 /08/15 l7t5LAIX1B 15-12263 Water 07 /A8/L5 L2:05 01 /OB/L5 L7 l5LAIXIC \5-\2264 water 01 /OB/15 73:24 O1 /O8/75 l.'7:51AIXID 15-L2265 Water 01 /aB/l5 1,3:24 O7/08/L5 11 :51ATX1E L5-I2266 Water 07 /08/t5 L4:.34 O1 /a8/15 11 :5LATX1F 15-1226? Water O'7 /O8/15 01 /a8/tb 17:.sl
Printed 01/09/1-5 Page 1 of 1
zr, i i 5 'ii - t{, aF:;r= rs- ;.
Analytical Resources,IncorporatedAnal,yticaf Chemists andConsultant s
Data Reporting QualifiersEffective 12131113
lnorganic Data
U lndicates that the target analyte was not detected at the reportedconcentration
* Duplicate RPD is not within established control limits
B Reported value is less than the CRDL but > the Reporting Limit
N Matrix Spike recovery not within established control limits
NA Not Applicable, analyte not spiked
H The natural concentration of the spiked element is so much greaterthan the concentration spiked that an accurate determination ofspike recovery is not possible
L Analyte concentration is s5 times the Reporting Limit and thereplicate control limit defaults to t1 RL instead of the normal 20%RPD
Organic Data
U lndicates that the target analyte was not detected at the reportedconcentration
* Flagged value is not within established control limits
B Analyte detected in an associated Method Blank at a concentrationgreater than one-half of ARI's Reporting Limit or 5% of theregulatory limit or 5% of the analyte concentration in the sample.
J Estimated concentration when the value is less than ARI'sestablished reporting limits
D The spiked compound was not detected due to sample extractdilution
E Estimated concentration calculated for an analyte response abovethe valid instrument calibration range. A dilution is required toobtain an accurate quantification of the analyte.
Version 14-00312131t13
Laboratory Quality Assurance Plan Page 1 of 3
:r. ,1 ii 'n 1"-q4r-! a-"u:.;,: i-+
Analytical Resources,Incorporat edAnalytical Chemlsts andConsultant s
lndicates a detected analyte withthat does not meet established<2Oo/oDrift or minimum RRF).
an initial or continuing calibrationacceptance criteria (<20%RSD,
o
S
NA
NR
lndicates an analyte response that has saturated the detector. Thecalculated concentration is not valid; a dilution is required to obtainvalid quantification of the analyte
The flagged analyte was not analyzed for
Spiked compound recovery is not reported due to chromatographicinterference
NS The flagged analyte was not spiked into the sample
M Estimated value for an analyte detected and confirmed by ananalyst but with low spectral match parameters. This flag is usedonly for GC-MS analyses
N The analysis indicates the presence of an analyte for which there ispresumptive evidence to make a "tentative identification"
Y The analyte is not detected at or above the reported concentration.The reporting limit is raised due to chromatographic interference.The Y flag is equivalent to the U flag with a raised reporting limit.
EMPC Estimated Maximum Possible Concentration (EMPC) defined inEPA Statement of Work DLM02.2 as a value "calculated for2,3,7,8-substituted isomers for which the quantitation and /orconfirmation ion(s) has signal to noise in excess ol 2.5, but doesnot meet identification criteria" (Dioxin/Furan analysis only)
C The analyte was positively identified on only one of twochromatographic columns. Chromatographic interferenceprevented a positive identification on the second column
P The analyte was detected on both chromatographic columns butthe quantified values differ by >40% RPD with no obviousch romatog raph ic interference
X Analyte signal includes interference from polychlorinated diphenylethers. (Dioxin/Furan analysis only)
Z Analyte signal includes interference from the sample matrix orperfluorokerosene ions. (Dioxin/Furan analysis only)
Laboratory Quality Assurance Plan Page 2 of 3 Version 14-00312t31113
JiE n ,!j _i " +3! {.?E #tnnl. ,4'
Analytical Resources,Incorpo ratedAnalytical Chemists andConsultants
Geotechnical Data
A The total of all fines fractions. This flag is used to report total fineswhen only sieve analysis is requested and balances total grain sizewith sample weight.
F Samples were frozen prior to particle size determination
SM Sample matrix was not appropriate for the requested analysis. Thisnormally refers to samples contaminated with an organic productthat interferes with the sieving process and/or moisture content,porosity and saturation calculations
SS Sample did not contain the proportion of "fines" required to performthe pipette portion of the grain size analysis
W Weight of sample in some pipette aliquots was below the levelrequired for accurate weighting
Version 14-00312t31t13
Laboratory Quality Assurance Plan Page 3 of 3
9".-: .;" ,=* a s,iT =:I i# _._*1i {i
ixssusrb@INCORPORATED
CJ.ient Project ID: 5551682042, tfason County Laadfill
ARI ifob No: Arxl
Param.eter: Vo]-ati].es -SW82 60C
I'Iatrix : 'I{ater
Ho].ding Time: 14 Days Preserved, 1 Days Unpreserved
Date Reported'- 07 /2t/!5
C].ientSamp1e ID
ARISamp1e ID
DateSampJ.ed
DateReceived
DateExtracted
DateAnalyzed
MW-10MW- B
MW_3BMW- 11Cuf ve rTRIP BLANKSMethod BlankLab ControlLab ControfMW- 3BMW-11MW-38MW_11
AIX 14AIX 1BAfXI C
AIX 1DAIXl EAIXl FMBO710l-5LCS 0 71015
Dup LCS D0 7 1015AIXlCMSAIX l DMSAfX l CMS D
AIX 1 DMS D
01 /a8/150'7 /08/t50'/ lo8/).501 /08/L50'7 /08/7501 /08/15
N/AN/AN,/A
at /08/L5a] /08/L50't /08/tsa] /08/15
a] /a8/t5at /0e/L507 /ae/1501 /a8/15o7 /a8/15o1 /08/t5
N/AN/AN/A
01 /08/1501 /08/L5o'7 /08/L5o-t /08 /ts
a] /LO/T501 /L0/L5al lto/L5a] /10/15a] /to/L501 /10/t507 /to/L501 /1,O/1,507 /10/L501 /1.0/1.501 /t0/L507 /L0/t501 /1A/ls
a7 /10/150t /L0/t50't /L0 /t5o7 /1.O/L501 /1,O/15o1 /10/L5o7 /1"O/1501 /LO/150'7 /L0/t5o1 /10/1501 /1A/150'7 /1A /1501 /ta/Ls
Preparation Sunrflary Tablef..t E ,s- 11 Eii! * t# g::?
rrstHs*@INCORPORATED
CJ.ient Project ID: 5551682042, l"Iason County Landfill
ARI Job No: AIX1
ParaEreter : Volatiles-SlM 3!{82608
I'Iatrin : Itlater
Ho1ding Eime: 14 Days Preserved
Date Repolt ed: O7 /21/Ls
CIientSampJ-e ID
ARISanple ID
DateSampled
DateReceiwed
DateExtlacted
DateAnalyzed
MW_ 1OMW- 8MW-38MW_11Culve rTRIP BLANKSMethod Bl-ankLab ControlLab Control DupMW-38MW_ 11MW- 3BMW- 1l-
AIX 1AAIX 1. BAIX ]- C
AIXlDAIX 1EAfX]-FMB071415LCS071415LCSDO71415A]X l CMSAIX l DMSAIX I CMS D
AIX ]. DMS D
a7 /08/L5a] /08/L5a] /08/L50'7 /o8/L5a1 /o8/L501 /08/L5
N,/AN/AN,/A
a7 /08/L5a] /08/15a] /08/L5a7 /08/L5
01 /08/L501 /08/t501 /08/L50'7 /08/t501 /08/L50'7 /08/L5
N/AN/AN/A
0'7 /08/L5o'7 /08 /1501 /o8/L501 /08/L5
01 /1"4/1501 /14/150"7 /14/7501 /14/1501 /1,4/1,5o'7 /1,4/7501 /14/\501 /14/1501 /14/15o1 /14/Is01 /14/1501 /14/t5o'7 /14/15
o't /L4/1,501 /14/15o'7 /14 /ls01 /14/1,50'7 /14/!5o1 /14/1501 /14/1s01 /L4/Ls0't /14/150'1 /1,4/L501 /14/150'7 /14/ls01 /14/ls
Preparation Summary Tab]efic! : i; '\ l. {rr!@ir- ^ft 6"{-i
erssHs*@INGORPORATED
C]-ient Project ID: 5551682042, I'lason County Landfi1].
ARI Job No: AfX].
C]-ientSample ID
ARISamlrle ID
DateExtracted
DateArraJ-yzed
Palamete!: Chloride-EPA 325.2
tlatrix: lYater
Ho]-ding Time: 28 Days
Date Repolted: O7 /2L/L5
Date DateSampJ.ed Receiwed
MW_10MW- 8MW_ 3BMW-11Cu lve rMethod BlankStandard Ref.MW- 3BMW- I1MW_ 3BMW-',] 1
AIX 1AAIX 1BAIX 1CAIXlDAIX 1EMBO 71515SRMO71515AIX 1C DPAIX l DDPAIX ]. CMSAfX l DMS
a1 /08/15a] /08/1501 /o8/1501 /08/L5a] /08/L5
N/AN,/A
a'7 /08/L5a] /08/1501 /08/1507 /08/15
01 /a8/1501 /08/1,50'7 /08/1.501 /08/L50't /08 /15
N/AN/A
01 /08/L507 /08/t50't /08/L501 /08/L5
01 /15/1507 /15/1507 /t5/L501 /rs/L501 /L5/L501 /L5/15o't /15/\so1 /L5/1,50'7 /t5/L501 /t5/1501 /L5/L5
N/A
N,/AN,/AN,/AN/AN,/AN,/AN,/AN/AN,/A
Preparation Summary Tablef-}l a JI. ': E!i!gi=6!'r _:r ':
f,rstfisft@INCORPOHATED
Client Project ID: 5551582042, l{ason County Landfill
ARI 'rob No: AIX1
Palametet: N-Arnmonia-EPA 350 . 1M
Matrix: water
CIientSaq)Ie ID
ARISample ID
DateExtrac.ted
DateAnalyzed
HoJ-ding Time: 28 Days
Date Reported: 01 /2L/L5
Date DateSarpled Reeeived
MW_10MW_ 8MW-38MW- 11CuIve rMethod BlankStandard Ref.MW-38t4w- 1 1MW- 3BMW- 11
AIX 1AAIX 1BAIX 1CAIXIDAIX IEMB07 10 15sRM07 10 15AIX l CDPAlX l DDPAIXl CMSAIX l DMS
a] /0e/L501 /08/L5a7 /08/1507 /a8/tso-t /a8/L5
N,/AN,/A
o7 /a8/1501 /aB/L5o1 /08/1501 /08/15
01 /08/L501 /08/L501 /08/150'7 /oB/t501 /08/L5
N/AN,/A
a1 /08/1501 /a8/L5a1 /aB/t5a] /a8/75
0"7 /10/75o'7 /rc/7so't /t0 /1507 /L0/L507 /L0/1501 /LA/1501 /1A/150'7 /7A /15o7 /LO/15al /to/1,5
N,/AN/AN,/AN,/AN/AN,/AN,/AN,/AN/AN/AN/A
Preparation Surunary Table9+ I -:E ',g th:EL-i!.,'i.fi -.+-
irs5HSft@INCORPORATEO
Client Project ID: 5551682042, l{ason County Landfill
ARI .Iob No: AIX1
Paranreter : Ll-Nitrate-Calcu1ated
t'latrix : Water
Holding Time: 48 Hours
Date Repott ed. o7 /27/!5
C].ient ARI Date Date Date DateSafiip].e ID Sanp1e ID Sarll)].ed Received Extracted Analyzed
MW- 1OMW_ 8MW- 3BIvtW- 1 1
Culver AIXIE 0'7 /08/L5 07 /AB/LS N/A A7 /09/15
ArxlA 01 /AB/3.5 A1 /08/1-5 N/A 0'7 /09/1,5ArxlB 07 /08/15 A1 /AB/L5 N/a A7 /09/15Arxlc A-t /A8/15 07/08/15 N/A A1 /09/15ArxlD 01 /aB/15 01 /08/15 N/A 0'7 /09/1.5
Preparatj-on Summary Tab.leFqr ! F, 'i --- ii,:;"rli "3 ',-
arsffi:l5@INCORFORATED
CJ-ient Pfoject ID: 5551682042, I'Iason County LandfiJ.J.
ARI ,rob No: AIX1
Parameter: N-Nitrite-EPA 353.2
l'ratrix : Vlater
C].ientSample ID
ARISarll)]-e ID
DateExtracted
DateAnalyzed
Holding fime: 48 Hours
Date Reported': 07 /21/L5
Date DateSaq>J.ed R€ceived
MW_ 1OMW-8MW_38MW_11CuIve rMethod Bl-ankMethod BlankStandard Ref.Standard Ref.MW- 3BMW- 11MW- 3BMW_11
AIX 1AAIX 1BAIX 1CAIX 1DAIX ], EMBO7 0 915MBO70915SRMO7 0 915SRMO 7 0 915AIXl CD PAIXl DDPAIX l CMSAIX 1 DMS
c.)1 /08/L5a] /08/Ls01 /08/L5a] /aB/L5o't /08/15
N/AN,/AN/aN/A
01 /08/Ls01 /08/t501 /08/1507 /08/Ls
01 /08/t5a1 / 0B /L501 /08 /t5a] /a8/Ls07/a8/L5
N,/AN,/AN/AN,/A
01 /08/1501 /08/1.501 /08/L5a] /08/t5
a] /09/1,501 /09/L507 /a9/1507 /09/15a7/09/t501 /a9/150'7 /09 /L501 /09/7501 /09/1,5a7 /09/t5a7 /o9/15a1 /09/15a7 /09/1,5
N,/AN,/AN/AN/AN/AN/AN/AN,/AN,i AN/A
N/AN,/A
Preparation Sum'nary Table!.r! 1 E '6 :r- :+= ar! .E :-E
ixssflsrb@INCORPORATED
Client Project ID: 5551682Q42, Masorr County L,andfi11
ARI Job No: AIX1
Pa:aam.eter: Nitaate + Nitrite-EPA 353.2
t{atrix : Iilater
HoJ-ding Time: 48 Hours (unpreserved)28 Days (preserved)
Date Reportedt O7 /27/Ls
c].ientSamp].e ID
ARISamp1e ID
DateSamp1ed
DateReceived
DateExtracted
DateAna]-yzed
MW_10MW- 8MW_ 3BMW_11Cu fve rMethod BlankMethod BlankStandard Ref .
Standard Ref.MW_ 3BMW-11MW- 3BMVit- 1 1
AIXlAA]X1BAIX 1CAIXl D
ATX 1EMBO 7 0 915MBo 7 0 915sRMo 7 0 915SRMO 7 0 915AIXICDPAIX 1DD PAIX l CMSAIX l DMS
01 /o8/1501 /08/1501 /08/750rl08/150'7 /08/L5
N/AN/AN/AN/A
a] /a8/t50t /0e/1501 /aB/L5ot /a8/15
07 /a8/15o7 /aB/150'7 /08/75u t / a6 / ra01 /08/1.5
N/AN/AN/AN/A
0'7 /08/75a] /08/1,5a'7 /08/L50'7 /08/L5
o'7 /09/L501 /a9/1501 /a9/1501 109/L501 /09/1501 /a9/1501 /a9/1507 /a9/15o't /09/\501 /09/150-t /09/15o7 /o9/1,sa] /09/t5
N,/AN/AN/ANIAN,/AN/AN/AN,/AN/AN,/AN/AN/AN/A
Preparatj-on Summary Table.f*n'i fi :€ 'f : 4:!l!a€i-ait'F ?+t
aHbils*@INCORP,oRAIED
C1ient Project ID: 5551682042, t'Iason County LandfiJ.J-
ARI Job No: AIX1
PararEeter: Su.I.fate-EPA 375.2
I'lataix: I,ilater
C]-ientSaml)].e ID
ARISa.urple ID
DateExtracted
DateAnalyzed
HoJ.ding Time: 28 Days
Date Reportedt 07 /2L/Ls
Date DateSampled Received
MW.1OMW- 8
MW-38MW_11Cu 1ve rMethod BlankStandard Ref.MW_ 3BMW-1IMW- 38MW- l- L
AIX 1AAIX 1BAIX 1CAIX ]. D
AIX 1EM8071715sRMO717l-5AIXICDPAIX I DDPAIXlCMSAIX l DMS
o't /08/1.501 /08/t5a] /08/L5a] / 0e 1150t /08/15
N/AN/A
a] /08/t5a] /08/150'7 /oB/t501 /08/L5
01 /a8/L501 /08/1501 /08/1501 108/150'7 /08/t5
N,/AN/A
0'7 /08/15a7 /08/15a1 /08/15a7 /08/L5
a] /L] /1501 /L'7 /L50't /1"7 /75o7 /L7 /L5c)] /11 /L50"7 /t'7 /1501 /L7 /Ls01 /t] /1501 /L7 /L5o1 /1'1 /1,5o'7 /11 /t5
N/AN/AN,/AN/AN,/AN/AN/AN/AN/AN/AN/A
Preparation Surunary Tabl-eLGja : :F- -i l.rn !J"!:,!: .i r,---
fiIsrfis?b@INCORPORATED
Client Project fD: 5551682042, tr[ason County Landfil].
ARI .,ob No: AIX1
Paramete!: Chemical Oxygen Demand-EPA {10.4
Matrix : lilater
C].ientsatBp]'e ID
ARISa$p].e ID
DateExtracted
DateAnalyzed
Holding Eime: 28 Days
Date Reportedt 07 /27/15
Date Dategalltr)Ied Receiwed
MW-10MW- 8MW-3BMW- 11Culve rMethod BlankStandard Ref.MW- 3BMW-11MW_ 3BMW-11
AIX 1BAIXlCAIX 1DAIX ]. EMB071615SRMO71615AIX 1C DPAIX l DDPAIX l CMSla _L 2l -t lJLvl )
07 /08/75ot /a8/1501 /08/1,501 /08/1.5o'7 /0e/15
N,/A
a] /o8/t501 /08/15o1 /08/15a1 /oB /L5
01 /ae/15a] /aB/1501 /a8/1501 /a8/1507 /08/L5
N/aN/A
01 /08/L501 /08/T507 /o8 /L50't /D8/L5
0'7 /76/L5o7 /16/15o't /16/L507 /r6/1-5o1 /L6/L501 /1,6/15o'7 /76/L501 /L6/L50'7 /1,6/1,50'7 /76/1,5o't /16/15
N/AN/A
N/AN/AN/flN,/AN,/AN,/AN/A
Preparation Summary Tabl-eir: ff :, ': :-ft-..!;i- -! f
AHbnst:@INCORPORATED
Client Project ID: 5551682042, tlason County L,andfilJ-
ARI Job No: AIX1
Paranneter: Total Organic carbon-EPA 9060
![atri:.: Water
CLientSaBpIe ID
ARISamtr>le ID
DateExtraeted
DateArralyzed
Ho1ding fime: 28 Days
Date Report ed,; 07 /2L/L5
Date Datesampled Received
MW_ 1OMVf-8MW-38MI',r-11Cr:f verMethod BlankStandard Ref.MW- 3BMW_ 11MW- 3BMW-11
AIX 1AATX 1BAIX 1CArxLDAIX 1EMBO71015SRMO 7 101sATX l CDPATX 1DD PAIX lCMSATX l DMS
a] /0e/1507 /a8/1501 /aB/t501 /a8/15o1 /08/15
N/AN/A
a] /08/L50'7 /08/15a] /08/t5o"t /a8/15
01 /08/1,5a7 /08/L501 /08/t5a] /08/L507 /aB/15
N/AN,/A
01 /08/7501 /08/7501 /08/15a7/08/L5
01 /r0/L501 /LA/lsa1 /10/1501 /LO/1507 /ro/15a] 110 / 150t /10/L507 /10/1,507 /1"0/t501 /1A/150'7 /L0/L5
NT /aN,/AN/AN,/AN/AN/AN/AN,/AN,/AN,/AN/A
Preparation Summary Tablear.a ii si "r! .. iJtrE5:l-s*f!.:i .s'E
ir3ifi:*@INCORPORATED
Client Project ID: 5551682042, Mason County Landfill
ARI ilob No: AIX1
Parameter: ICP Dissolved MetalE-60X0C
I'Iataix : Wate!
C]-ientSample ID
AB,ISa.ErpIe ID
DateExtracted
DateAna1yzed
Holding Tigre: 6 MoDths
Date Reported: 07 /2!/Ls
Date DateSamp1ed Received
MW-LOMW_BMW- 3BMW_11Culve rMethod Bl-ankLab ControlMW-3BMW- l" 1MW- 3BMW_11
ATYl A
ATX 1B
A-L)( -L U
AIX 1EMBo 71015LCS071015l{-T,(.L LUTAIX l DDPAIX l CMSAIXl DMS
o7 /08/L501 /08/1501 /08/L5a] /08/Lsot /ae/15
N,/AN,/A
01 / a8 11501 /a8/1501 /oB/15o'7 /08/L5
o'7 /08/L507/oB/1,501 /0e/L5a7 /08/150'1 /08/t5
N/e01 /0e17507 /aB/150t /ae/150t /08/15
o1 / to /1-501 /L0/1501 /L0/1501 /L0 / L501 /LO/150'7 /t0/L5a7 /70/L5A-t / Lo l1-501 /LO/15a] /10/L501 /10/L5
01 /L5/15o1 /L5/1501 /L5/1501 /L5/15a] /15/1501 /t5/L5a] /L5/L5a1 /L5/15o7 /ts/ts01 /L5/t5o't /t5/L5
Preparation Summary Tablecz-a E 5_ 'E it=4-?r*-l': +n!
irssfis*@!NCOHPORATED
Lab Samp1e ID: MB- O 71015ALTMS ID: L5-t2262Mat-r:ix: WaterData Release Authori zed:Reported: A1 /14/L5
ORGA}iIICS ANALYS IS DATA SHEETvo]-atiles by Purgre E Trap GC/l"trSi-Method Sw82 60cPage 1 of 1
Sa:nple ID: MB-071015AlIE THOD BI.ANK
QC Report No: AIX1 -Parametrix, Inc.Proj ect: I4ason County Landfill
5551682042Date Sampled: NA
Date Received: NA
Sample Amount: 10.0 mLPurge Volume: 10.0 mL
LOQ Result A
VDIns t rument /Ana.lyst : NT15,zPABDate Analyz edz 0'7 / t0 / L5 1,3 : 27
CAS Nunber Analyte
'1 4-87 -37 4-83 9
75-00 37 5-09-261-64-L7 s- 15-075-35 4
1s6-60-5L56 59-267 - 66-3L07 -06-278-93-37l-55-656 23-5108-05-475-21-418-81 5100 61-01-579-01 6L24-48-179-00-51 7,43-2ra06'1,-42- 6110-7s-815-25-2108-10-1597-18-6tz't -L8 - 4'7 9-3 4-5108-88-3108-90-7700- 4L- 4700- 42-57 5-69- 416-13-!108-38-395*41-6
< 0.50 u< 1.0 u
< 0.20 u<. a.2a u< 1.0 u< 5.0 u
< 0.20 u< 0.20 u< 0.20 u< 0.20 u< 0.20 u< 0.20 u< 0.20 u< 5.0 u
< 0.20 u<. a.2a u< 4.20 u< 0.20 u< 0.20 u< 0.20 u< 0.20 u< 0.20 u< 0.20 u< 0.20 u< 0.20 u< 1.0 u
< 0.20 u< 5.0 u< 5.0 u
< 0.20 u< 0.20 u< 0.20 u< 0.20 u< 0,20 u< 4.20 u< 0.20 u< a.2a u< a.4a u< a.za u
ChloromethaneBromomethanevinyl ChlorideChloroethaneMethylene Chloride
Carbon Di sul f ide1,1-Dichloroethene1, 1- Di chloroe thanetrans-1, 2-Dichloroetheneei c-T ?-ni ^h l
^r^6fhanaChforoform1, 2 -Di chloroethane2-Butanone1, 1. 1-TrichloroethaneCarbon Tetrach.IorideV.inyl AcetateBromodi chl oromethane1. 2 -Di chl oropropanecis-1,, 3-DichloropropeneTrichloroetheneDibromochl-o rome thane1,, 1, 2 -T ri chloroe thaneBenzenetrans- l, 3-D j-chloropropene2 -Chl o roethylwinylethe rBromoform4 -MethyI-2 -Pentanone (Mf BK)2 -HexanoneTet rachloroethenel, 1, 2, 2-T etliachloroethaneTolueneChlorobenzeneEthylbenzene
T r ichlorof Iuo r ome ha ne
0.501.0
0.200 .241.05.0
0.200 .200 .200.200.200.200.205.0
0.200.20a .240 .24o .24a .20a .200 .200 .200 .200 .201.0
0 .245.0s.0
0.200.200.200.200.200.240 .20
L, 7, 2-T r Lch:.oro-L, 2, 2-trif luoroethane0. 200.40a .24
m, p-Xyleneo-Xylene
Reported in frqlL (ppb)
Vo].ati].e Surrogate Recovery
d4 -1, 2-DichloroethanedB-TolueneBromo fluorobenz ened4 -1, 2 -Dichl-orobenzene
1L4Z1018
96.531022
FORM I rli4 n -7i. '9 g,l:{ il.* :=:n ::!r +-
ilsbrrs*@INCORPOHATEDORGANICS AI{AIYS I S DATA SHEET
Vo].atiles by Purge & Irap GC/MS-MethodPage 1 of 1
Lab Sample -D: AIX1ALIMS ID: 15-72262MaLrix: Water 4lfi\Data Release AuLhor i=ea: \,l 'l )Reported: 01 /14 / 15
Instrument,/Anal-yst; NT 15 / PABDate Analyzed: 01 /70/15 16:59
CAS Nun rer Analyte
sw8260c Sanp1e ID: MW-10SAI'TPIJ
QC Report No: AIXI- Parametrix, Inc.Proj ect: Mason County Landfil-I
555r682442Date Sampfed: 01 /08/t5
Date Received: 0ll08/15
Samp.le Amount: 10.0 mLPurqe Vo.Iume: 10.0 mL
LOQ Resu]-t a
7 4-81-3,, oi al
7 5-0L- 4
75-00-37 5-09-26'7 - 64-t75-15-0
156-60-5t56-59-26'7 - 66-3LA1-46-27 B-93-317-5s-656-23-s108-0s-415-21 418-81-510061 01 5'7 9 Al-6124-48-L79-00-s11"-43-2L006L-02-6110-75-815-25-2108-10-l591 7B 6727 LB-479-34-5108-88-3108-90-7100 41-4to1 42-515 69 416-L3-L108-38-395-47-6
< 0.50 u< 1,0 U
< 0.20 u< 0.20 u< 1.0 u< 5.0 u
< 0.20 u< 0.20 u< 0,20 u< o.20 u< 0.20 u< 0.20 u< 0.20 u< 5.0 u
< 0.20 u< 0.20 u< 0.24 u< 0.24 u< 0.24 u< 0.24 u< 0.20 u< o.20 u< Q.20 U< 0.20 u< 0.20 u< 1.0 u
< 0.20 u< 5.0 u< 5.0 u
< 0.20 u< 0.20 u< 0.20 u< 0.20 u< 0.20 u< 0.20 u< 0.20 u< 0.20 u< 0.40 u< 0.20 u
ChloromethaneBromomethaneVinyl ChlorideChIor:oethaneMethylene ChlorideAcetoneCarbon Dl sul fide1, 1- Dl chl oroethene1, 1- Di chl oroethanetrans-1, 2-DichloroethenecLs-L,2- D j chl or oe LheneChloroform1 , 2 -Di chloroel-hane2 -Butanone1, 1, 1-Tri chlo roethaneCarbon TetrachlorideVinyl AcetateB romodi chl o rome thane1. 2 -Di chlo ropropanecis-1, 3-DichloropropeneTrichloroetheneDibromochl oromethaneI , I ,2-TrtchloroeLhaneBenzenetrans-1, 3 Dichloropropene2 Chl o roethylvinyl ethe r:Bromoform4-Methyl-2-Pentanone (MIBK)2 -HexanoneTet rachl oroethene7, 1, 2 t 2-TetTachloroethaneTolueneChlorobenzeneEthylbenzene
T r'i chl oro fluoromethane
0.501.0
0.200.201.05.0
o .200.200.20i )io .20o .20o .205.0
0 .200.200.200.200.200.200.200.200.20
0.201.0
0.20
0 .20
0.20
0.200.20o -20
1, 1, 2 Trichloro-L, 2, 2-trifluoroethane0. 200.400 .20
m,p xyleneo-xylene
Reported ln pg/L (ppb)
volatile gurf,ogate Recoverl.
2 - Chloroe thylvinyl ethe racid preserved sample .
d4-1,2-Dichloroethane 118 B
d8-Toluene 101?Bromo fluorobenz ene 95.8?d4-1,2-Dichtorobenzene 7022
.is an acid labiLe compound and may not be
EPA SW-846 indicates that vinyl chtoride and styrene may degradeacid preservative.
recovered from an
in the presence of
E'ORM I j:5i : ;7- -; .. a:'5!nEs9E:i? "!
*rsbfisr!@INCORPORATEDORGANICS ANAIYS TS DATA SHEET
Volati].es by Purge & Trap GC/MS-IIethod SI{82 60CPage I of 1
Lab Sample ID: AIXIBLIMS ID: L5-1.2263Mal rix: WaterData Re-lease Auchor-zea, \ l\\\Reported: 01 /74/15 V \ -
Instrument/Anafyst: NT l5 / PABDate Analyzed: a'l /t0/15 L'l:26
Sample ID: tfl-8SAI'IPI.E
QC Report No: AIX1 - Paramet rix, Tnc,Proj ect: Mason County Landfill
5557682042Date Sampled: a] /a8/15
Date Received: 07l08/L5
Samp]e Anount: 10.0 mLPurge Volume: 10.0 mL
I,oQ B,esul t OCAS Nurrber Analyte
7 4-81 -37 4-83-9
75-00-37 5-09-26"7 - 64-t75-1s-0?6-?q-115-34-3155-60-sL56-59-26-1 - 66-3LA1-06-278-93-37t-55 656-23 5108 05-4
78 87-510061-01-5?9-01-6124- 48-I79-00-51L-43 210061-02-6110-75-815-25-2108 10-1591-78-6721-78-419-34-5108 B 8-3108 90-7100 41-4100 42-575-69-476-73 7108-38-395-41-6
< 0.50 U< 1.0 u
< 0.20 u< 0.20 u< 1.0 u< 5.0 u
< 0.20 u< 0.20 u< 0.20 u< 0.20 u< 0.20 u< 0.20 u< 0.20 u< 5.0 u
< 0.20 u< a.Za u< a.za u< 4.20 u< 0.20 u< 0.20 u< a.2a u< a.2a u< a.2a u< 0.20 u< a.2a u< 1.0 u
< 0.20 u< 5.0 u< 5.0 u
< 4.20 u< 0.20 u< 0.20 u< 0.20 u< 0.20 u< 0.20 u< 0.20 u< 0.20 u< 0.40 U< 0.20 u
ChloromethaneBromomethaneViny1 ChlorldeChloroethaneMethylene ChlorideAcetoneCarbon Dl sr-rl f ide1,1-Dlchloroethene1,1-Dichloroethanetrans l, 2 -Di chloroethenecis 1,2-DichloroetheneChloroform1,2-Dichloroethane2 -ButanoDe1 , 1, 1-Trichlo roethaneCarbon Tet rachlorideVinyl AcetateBromodichfo romethane1. 2 -DichI oropropanecis-1, 3-DlchloropropeneTrichloroetheneDibromochl o romethane1, 1, 2-TrichloroethaneBenzenetrans -1l 3 - Di chI oropropene2 - Chforoethylvinyl ethe rBromoform4 -Methyl - 2 -Pent anone (MIBK)2-HexanoneTet rachloroethene1-, L | 2, 2-T eLrachloroethaneTolueneChlorobenzeneEthylbenzene
Trichlor:of Iuoromethane
0.501.0
0.200.201.05.0
0 .200 -200 .200 .200 .200 .200 -205.0
0.200.200.200.20o.200.200.200.200.200.200.201.0
0.205.05.0
0 .2aa .20a .20a .2a0.200.20a - 2.a
1, 1, 2-Trichl oro-L, 2, 2-trif luoroethaneo. 200.400.20
m h-\1r rl ^r^
o-xylene
Reported in pqll (ppb)
Volatile surrogate Recovery
d4 I ,2-Dicltlo roethane L20Zd8-Toluene :-038Bromo fluorobenz ene 91 .42d4-1,2-Dichlorobenzene 104S
2 -Chloroethylvinyl ethe r is an acid labile compound and may not beacid preserved sample .
EPA SW-846 indicates that vinyl chloride and styrene may degradeacid preservative.
recowered from an
in the presence of
EORM I ;-; : 11 'I gE er'l i*- r. -!-
rrssfisr!@INCORPOHATEDORGANICS ANAI,YS I S DATA SHEET
vo].atiles by Purge & Trap Gclr"G-tlethod sw8260cPage 1 of 1
Lab Samp1e TD: AfXICLIMS ID: 75-12264Matrix: WaterData Release Authori zeReported: A1 /14/15
Samp].e ID: l"1r{- 38SAMPTE
QC Report No: AlXI--Parametrix, Inc.Proj ect: Mason County Landfi-LI
5551-682442Date Sampled: O1 /08/15
Date Received: a] /OB /15
Sample Amount : 10Purge Vofume: 10
LOQ Result a
", u\)Irrstrument /Ana1yst : NT 15 / PABDate Analyzed: al /TO/1"5 17:53
CAS Nurtber Analyte
0mL0mL
'7 4-87-3 Chloromethane 0.5014 83-9 Bromomethane 1.075-01-4 Vinyl Chloride 0.2075-00-3 Chloroethane 0.2075-09-2 Methylene Chloride 1.067 -64-l Acetone 5. 015-L5-0 Carbon Dlsulfide 0.2A75-35-4 1/ L- D i chl or:oethene 4.207 5-34-3 1,l-Dichloroethane 4.20156-60-5 trans-L. 2 - D j.ch:.Ioroethene 0.20156-59-2 cis-L,2-Dichloroethene O.2061-66-3 Chloroform 0.20141-06-2 1,2-Dichloroethane 0 .20'7 8-93-3 2-Butanone 5.011-55-6 1,1,l-Trichloroethane 0.2056-23-5 Carbon Tetrachloride 0.20108-05-4 Vinyl Acetate 0.2015-2'l - 4 Bromodichloromethane 0.2078-87-5 L,2-DLchlot:opropane 0.24100 61-01--5 cis-1,3-Dichloropropene 0.2019-0L-6 Trichloroethene 0. 20724-48-I Dibromochlo romethane A.2A79-00-5 1,1,2-TrtchLoroethane A.2A7L-43-2 Benzene A.2AL006L-02-6 trans-1.3-Dichloropropene 4.20110-75-8 2 -Chloroethylvinylethe r 1.015-25-2 Bromoform A.2AL08-10-1 4-Methyl-2 Pentanone (MIBK) 5.05 91-7 8- 6 2-Hexanone 5.0L27-L8-4 Tet rachloroe thene 0.2019-34-5 L, L,2,2-TeLrachforoethane 0.20108-88-3 Toluene A.2Ol-08-90-7 ChLorobenzene 0.20:-00-41-4 Ethylbenzene 0.20!-0 0- 42 -5 Styrene 0.2O15-69-4 T ri chlo ro fluoromethane 0.2O1 6-13-7 1 , t,2-Tr\chloro-1 , 2 , 2-Lri fluoroethaneo . 2 0108-38-3 m, p-Xylene 0.4095-41-6 o-Xylene 0.20
< 0.50 u< 1.0 u
<. A .20 u< a.2a u< l-.0 u< 5,0 U
<. a.20 u<. 0 .20 u< 0.20 u-- 0.20 u< 0.20 u< 0.20 U< 0.20 U< 5.0 U
< 0.20 u< 0.20 u< 0.20 u< a.2a u< a.za u< 0.20 u< a.za u< 0.20 u< a.2a U< 0.20 u< a.za u< 1.0 U
< 0.20 u< 5.0 U< 5.0 U
< 0.20 u< 0.20 u< 0.20 u< 0.20 u< o.20 u< 0.20 u< 0.20 u< 0.20 u< 0.40 u< 0-20 u
Reported in pg,/L (ppb)
vo].ati].e Surrogate Recovery
d4-1,2-Dichloroethane LZAZd8-Toluene LozZB romo fluo robenzene 95,3Ed4-1.2-Dichlorobenzene 105?
2 -Chl o roethylvinylethe r is an acid Iabile compor,rnd and may not beacid preserved sample.
EPA SW-846 indicates that vinyl chloride and styrene may degradeacid preservative.
recovered from an
in the presence of
FORM I l?.: E :4:.a : ;j:*n!PE:1+r !f j:r.,€
AXssHSr!@!NCORPORATEDORGA}ITCS ANAI.YS TS DATA SHEET
Vo].atiles by Purge & Tratr) Gc/Ms-t"lethod SI.I82 60CPage 1 of 1
Samp].e ID: IWI-3BI\4ATRIX SPIKE
QC Report No: AIXl - Paramet rix, Inc.Project: Mason County Landf il-f
555t682042Date Sampled: Ol /A8/L5
Date Received: O1 /08/15
Sample Amount : 10.0 mLPurq'e Volume: 10.0 mL
LOQ Result A
Lab Sample ID: AIX1CLIMS ID: l5-L2264MaLrix: Wdler 1i(NData Release AuLhorireA: \u/ \)Reported: 0'1 /14 /15
f nstrument /Analys t : NT15/PABDat.e Analyzed: O7 /la/I5 19:39
CAS t\Iurober Ana].yte
?/4 01_O
75-01-475-00-37 5-09-267 - 64-775-1s 075-3s-475-34-3156-60 5L55-59 261-65 3t 0l 06-27 8-93 371-55- 6s6 23-5108-05-47 5-2'7 - 4
78-87-510061-01-s7 9-0)-- 6124- A8-r79,00 57t 43-2t0a61 02-6110 75-875 25-2108-10-1591-78-6t2'1-t8-419 34-5108-88-3108-90-7loa-41-4L0a- 42-57 5-69-416 73-l108-38-395-41-6
ChloromethaneBromomethaneVinyl ChlorideChLoroethaneMethylene ChlorideAcetoneCarbon Disulfide1, 1- Di chl oroethene1,1-Dichloroethanet:rans-1, 2 - Dichl oroethenecis-1. 2 - Di chloroetheneChloroform1,2 Dichloroeth'ane2 -Butanone1,1,1 frichloroethaneCarbon Tet rachl orldeVinyl AcetateB romodi chforome thaneI , 2 -Dichloropropanecis-1, 3-Dichf oropropeneTrichloroetheneDrbromochlo romethaneL , ! ,2-TYich,r.oroethane
trans-1, 3 -Di chl-o rop ropene2 -Ch.I o roethylvj-nyl etherBromoform4 -Methyl - 2 - Pentanone (MIBK)
Tet rachLoroetheneL, 7, 2, 2-TetrachloroethaneTolueneChlorobenzeneEthylbenzene
T ri chl o rofluo romethane
0.501.0
a .200.201.05.0
0 .2Q0.200.200.200.200.200.205.0
0 .200.200.24n 2n0 .240 .240 .240 .24a.2ai )a0 .2a1.0
0.205.05.0
a .24a .20a .20a .2aa .2aa .24a .24
7, 7, 2 -'I r ic]n).aro- L, 2, 2-tri f luoroethaneo . 2 00.40a .20
m, p-xyleneo-xylene
Reported in pgll. (ppb)
volatile Surlogate Recovely
d4-1,2-Dichloroethane 120?d8-Toluene 1042Bromo fluoroben z ene 98.78d4 - 1, 2-DichLorobenzene 1038
EORM I a+ t :a "t : !.Enari4ie i-_ e.;
ORGA}IICS A}IALYS IS DATA SITEETVolati]-es by Purge & TraI) cC,/1.1S -Method SW82 60CPage 1 of I
fi$snst:@sample rD: D4w-3B
INCoRPoRATED
}{ATRIX SPIKE DUP
Lab Sample lD: AIX1CLIMS ID; 75-t2264Matr-x: Wdter , C:.Dara Re Lease AuLhori=ea: 1/\\Reported: Al /74/75 V t)
T ns t rument,/Analyst : NT 15,i PABDate Analyzedl 01 /LO/L5 20:06
CAS Nuniber Analyte
QC Report No: AIX 1- Parametrix, Inc.Proj ect: Mason County Landfilf
5551682442Date Sampled:' O'7 /08/15
Date Received: O'7 /08/1.5
Sample tunount: 10.0Purge Volume: 10.0
LOQ
MLML
Resu].t a
1A A1 a
1n_41 0
75-00-37 5-09-267-64-L75-15-0
156-60-sL56-59-26"7 - 66-3101-46-278-93-37 t- 5s-656-23-s108-05 4
78-8 7 510061 01-s19-At-6t2 4- 48- L79-00-5'7 1,- 43-21406L-O2-6110-75-B
108-10-1591-78-6121 -IB- 419-34-5108-88 3108- 90 ?100-41-4104-42 515-69 4
7 6-13-t108-38-395- 41 -6
ChloromethaneBromomethaneVinyl ChlorideChloroethaneMethylene ChlorideAcetoneCarbon Disul fide1,1-Dichloroethene1, 1- D.i chloroethanetrans 1, 2-Dichloroethenecis-1. 2 -Di chloroe theneChloroform1.2 Dichtoroethane2 -Butanone1, 1, 1-Tri chl oroethaneCarbon TetrachlorideVinyl AcetateBromodichl o romethane1, 2 - Di chl oropropanecis-1, 3 - Di chl of,opropeneTrichloroetheneDibromochloromethane1, 1. 2-Trichl-oroethaneBenzenetrans-1, 3-Dichloropropene2-ChloroethylvinyletherBromoform4-Methyl--2 - Pentanone (MIBK)2-HexanoneTet rachloroe theneL, 7, 2, 2-I etrachf oroethaneTolueneChforobenzeneEthylbenzene
T ri chI orofluo romethane
1.00.200.201.05.0
0 .2aa .2aa .2ai )na .2aa .240.205.0
a .200 .200.200 .200 .200.200 .20o.200.200.20o.201.0
0.205.05.0
0.200.200.200.240.240 .240 .2a
1, 1, 2-Trichl-oro-L, 2, 2-trif luoroethane0, 200.40a .24
m, p-XyIeneo-xyfene
Reported in pqll (ppb)
Volatile surrogate Recovery
d4-"1.2-Dichloroethane L2LZd8-Toluene 1038Bromo f luorobenz ene 97,52d4--1,2-Dlchlorobenzene 1,022
EORM I
rrsbfis*@INCORPORATED
Lab Sample ID; AIX1 D
LTMS ID: 15-12265Matrix: WaterData Re.l-ease Authori zed:Reported: a] /t4/L5
ORGANICS ANAIYS I S DATA SHEETvolaeiLes by Purge & Trap GClMS-Method Sw8260CPage 1 of I
Sample ID: ltlll- 11SAMPT.E:
QC Report No: AIXl-Parametrix, Inc,Project: Mason Courrty Landfill
555L682A 42Date Sampled: 01 /aB/L5
Date Receivedl. 01 /a8/15
Sample Amount : 10.0 mLPurge Volume: 10. O mL
I,OQ Resu].t A
!\)Tns trument,/Analyst : NT 15 / PABDate Analyzed: 01 /La/15 18:19
CAS Nulnber Ana].yte
7 4-81-314-83-975-01-475-00-3'15-09-2
75-34-3
67-66-3L01-06-2?8-93-37I-55-6s6-23-5108-05-47 5-2'7 - 478-87-510 0 61- 01- 57 9-0L- 61,24-48-t7 9-00- 5
10061,-02-61!-0-75-87 5-25-2108-10-1591-78-6
79-34-s108-88-3108-90-7100-41-4100-42-s7 5- 69- 4
7 6-L3-L108-38-3
ChloromethaneBromomethaneVinyl ChlorideChloroethaneMethylene Chlor.ideAcetoneCarbon Disuffide1,1-Dichloroethene1, 1- Di chloroethanetrans-1, 2-Dichloroethenecis-1, 2-DichloroetheneChLoroform1. 2 -Di chlo roethane2 -Butanone1,1, L -T richl o roethaneCarbon TetrachlorideVlny] AcetateBromodi chlo romethane1- , 2 -Dichloropropanecis-1, 3 - Dl chloropropeneTrichloroetheneD ib r: omo ch 1o rome t hane1, 1, 2-TrichloroethaneBenzenetrans 1.3 Dichloropropene2 -Chloroethylvinyl ethe rBromoform4 -Methyl - 2 -Pentanone (MIBK)2-HexanoneTe t rachloroetheneL | 1, 2, 2-T eLTachloroethaneTolueneChlorobenzeneEt'hylbenzeneSt'yreneTr:ichlo:rof lrlorometh ane
1.00.200 .201.05.0
0.200.200.200 .200 .200.200.205.0
0.20o.20o .24a .24a .24a .24a .24a.2a0.20a .24a .241.0
a .245.0
o .20a .24a .24a .20o .20o .24
< 0.50
< o.20
< 1.0
< 0.20< 0.20< o.20< o.20< 0.20
< o.20< 5.0
< 0.20< 0.24< 0.20< 0.24< 0 ,2a< 0.24< 0.20< 0.20
< 0 .24< 0.20< 1.0
< 0 ,24< 5.0< 5.0
.- 0 .2a< 0,2a< 0.20< 0.20< 0.20< 0.20< 0.20< 0,20< 0,40< 0,20
UUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUU
1, 1, 2 Trichloro-L,2,2 trifluoroethane0.200.40a .24
m, p-xyleneo-xylene
Reported in pgl]- (ppb)
vo].ati].a Suffogate Recovery
d4-1,, 2-Dichloroethaned8 -ToLueneBromo ffuorobenz ened4-1, 2-Dichlorobenzene
ta2294.02
103s
2 - Chloroethylvinylethe r is an acid labile compound and may not beacid preserved sample .
EPA SW-846 indicates that vinyl chloride and styrene may degradeacid preservative.
recovered from an
ln the presence of
E'ORM I
ixs:Hsrb@INCORPORATED
Lab Sampfe ID: AIX 1DLfMS ID: t5-I2265Matrix: WaterData Release Authori zed:Reported: 01 /14/15
ORGANTCS ANATYS I S DATA SHEEIvo].ati].es by Purge & Trap cc/Ms-Method Sw8260CPage 1 of 1
SampJ-e ID: t{VI-11MATRIX SPTKE
QC Report No: AIX1 - Paramet rix, Inc,Proj ect: Mason County Landfiff
555L682A 42Date Samp-Ied: al /08 /75
Date Received: a7 /08/1,5
Sample Amount: 10.0 mLPurge Vofume: 10,0 mL
LOQ Result a
TID
Inst rument /Analyst : NT15/PABDate Analyzed: 07 /I0/15 2a:32
CAS Nutriber Analyte
14-81-3 Chforomethane 0.5014-83-9 Bromonethane 1.015-At4 Vinyl Chloride 0 .2A75-00-3 Chloroethane 0.2415-49-2 Methylene ChLoride 1.061-64-1 Acetone 5.075-15-0 Carbon Disuffide A -2475-35-4 1, 1-Dichforoethene 0.2075-34-3 1, 1-Dichloroethane 4.20156-60-5 t rans - 1, 2 -Dj- chloroethene 0.20L56 59-2 cis-1,2-Dich.Loroethene 4.2061-66-3 Chloroform 0.20LA1-A6-2 1,2-Dichloroethane 0.2078-93-3 2-Butanone 5,071 55-6 1,1,1-Trichloroethane 0.2056 23-5 Carbon Tetrachloride 0.20108-05 4 vinyl Acetate 0.207 5-21-4 Bromodichloromethane 0 .2O7 8-87-5 1 . 2 - D ichloropropane 0.2O10061-01-5 cis-1, 3 -Di chl oropropene 0 . 20-19-AL-6 Trichloroethene 0 .2Q124-48-I Dibromochl o romethane 0,2Q79 00=5 L I L,z-IrLchloroethane 0,247L-43-2 Benzene 0,2410061-02-6 trans-1,3-Dichloropropene 0,20110-75-8 2 -Chl oroethylvinyl ether 1,075-25-2 Bromoform O.2A108-10-1 4 -Methyl- 2 -Pentanone (MrBK) 5.0591-18-6 2-Hexanone 5.0t21-\8-4 Tetrachlo roethene A.2O19-34-5 ! , I,2,Z-Tetxachloroethane 0,20108-88-3 Toluene 0.2A108-90-7 Chlorobenzene Q.2O100-41-4 Ethylbenzene A.2O100-42-5 Styrene 0.207 5-69-4 T ri chl-oro fluorome thane A.2O76-13-L 1,1,2-Trichl or:a-l,2,2-tri fluoroethane 0 . 2 0108-38-3 m,p-xylene 0.4095- 41-6 o-xylene 4.20
Reported in pgll (ppb)
Volatile Surrogate Recovery
d4 1.2-Dichloroethane 12 0?d8-Toluene 1038Bromofluo robenzene 91 .82d4-1.2-Dichlorobenzene 1039
FORM I
ORGAI{ICS ANAJ,YS T S DATA SHEETVolatiles by Purgre & TraI) GC,/MS -Me thodDr^6 1 a€ 1! qYv
Lab Sample ID: AIX1DLIMS ID: 15-12265Matrix: WaterData Release Author -rua, \ lF\Reporced: O7/I4/15 vt-)
Inst rument,/Ana Iyst : NT15,/PABDate Analyzed:. a7 /).0/15 20:59
CAS Nunber Ana].yte
ixss#se:@sample rD: MW-11
INGoRPoRATED
MATRIX SPIKE DUPsw82 50c
QC Report No: AIX1 -Paramet rix / Inc.Pllo j ect: Mason County Landfill
5551682042Date Sampled:. A1 /08/15
Date Received:. 07 / a8 /15
Sampfe Amount: 10.0 mLPurg'e Vo.Lume: 10.0 mL
I.OQ Result O
7 4-8'7 -314-83-97 5-07-4?5-00-3't 5-a9-261-64-I75-15-0'7 5-35- 4
1s6-60-5t56-59-267 - 66-3L07 -05-218-93-377-55-656-23-5108-05-4
78-87-s10061-01-s'7 9-0L- 6124-48-17 9-00-5'11 /1 n
10061-02-6110-l s I108-10-159L 7 8-6
108-88-3108 90-?100-41-4LA1 42-5?5-69-476-13 1108-38-395-41-6
0.501.0
0 .200 .201.05.0
0.200 .240.20o .20a .240 .20a .205.0
0 .200 .20o )i0.200.200.za0.200.200.20a.2a0.20
1.0a.2a5.05,0
4.200 .200 .200.200.200.200.20
ChloromethaneBromomethaneVinyl ChlorideChloroethaneMethylene ChlorldeAcetoneCarbon Disulfide1,1-Dichloroethene1, L- D Lchto roethanetrans 1, 2-Dichloroethenecis-1, 2 -Di chLoroetheneChloroform1, 2 -Di chfo roethane2 -Rlrtanone1, 1, 1-Tri chl oroe thaneCarbon TetfachlorideVinyl AcetateBromodi chlo romethane1, 2 -DichIo rop ropanecis-1, 3-DichloropropeneTrichloroetheneDibromochl oromethane1, 1, 2 -T rl chloroethaneBenzenetrans-1, 3-Dichloropropene2 -ChloroethylvinyletherBromoform4 -Methyl- 2 - Pentanone (MIBK)2 -HexanoneTet rachlo roethene7, L, 2, 2-"1 e-LrachloroethaneTolueneChlof,obenzeneEthyLbenzene
T r ichlorof luoromethane1, 1, 2-?richl-oLo- L, 2, 2-trif luoroethane0. 20m, p-Xyleneo-xyfene
Reported in Lrgll (ppb)
Volatile surrogate Recovery
0.400.24
d4 -1,2-Dichforoethane 1232d8-Toluene 10 32Bromofluorobenz ene 96 .52d4-1,2-Dichlorobenzene 103?
EORM I G!+ : ilt 't _ 1;-E4./g.iF! ++ iiiri
firsbfJ&!@INCORFOHATEDORGANTCS ANAIYSTS DATA SHEET
vo]-atiles by Purge & Trap GClMS-Method SW825OCPage 1 of I
sanp].e ID: CulverSA}4PI-,E
QC Report No: AIXl-Parametrj-x, Inc.Project: Mason County Landf il-l
55516824 42Date Sampled: O1 /08/75
Date Received; a] /08/L5
Sample tunount: 10.0 mLPurqe Vofume: 10.0 mL
t,oQ Result O
Lab Sample TD: AIX1ELIPIS ID: 15-12266Ma.r f -X: !,later t f,\R:":.1:]:';1,?\iiz"
zea: !\ ,)
Instrument/Analyst: NT 15 / PABDate Analyzed: 01 /1,0/15 1B:46
CAS Nulnber Analyte
14-8'/ -3 Chloromethane 0, 5014 B3-9 Bromomethane 1.075 01,-4 Vinyl Chloride A.2A75 00-3 Chloroethane O.2A15-09-2 Methylene Chloride 1.05'7 -64-L Acetone 5. 075-15-0 Carbon Disulflde 0.2075 35-4 1.1-Dlchloroethene 0.2015-34-3 1. 1-Dichloroethane 0. 20156-60-5 trans-1,2-Dichloroethene 0,2O756-59-2 cis-1,2-Dichloroethene 0 ,2067-66-3 Chloroform O.2A101-06-2 1,2-Dichloroethane A.2A78-93-3 2-Butanone 5.071-55-6 l-,1,l-Trichloroethane A.2O56-23-5 Carbon Tetrachloride 0.20108-05-4 Vinyl Acetate 0.2015-27 -4 Bromodichloromethane O.2078-87-5 1,, 2-Dichloropropane 0.2010 0 61- 01- 5 cis-1,3-Dichloropropene 0.207 9-01-6 Trichloroethene 0 .20L24-48-7 Dibromochlo romethane 0.2079-00-5 1,1,2-Trichloroethane 0.201L-43-2 Benzene 0.207006L-02-6 trans-1,3-Dichl-oropropene 0.20110-15-8 2 - Chl o roethylvinyle the r 1.015-25-2 Bromoform 0,20108-10-l- 4-Methyl-2-Pentanone (MIBK) 5.0591-78-6 2-Hexanone 5.0127-L8-4 Tetra chloroethene O.2a19-34-5 7, 7,2,2-Tetrachloroethane 0.20108-88-3 Toluene 4.20108-90-7 Chlorobenzene 0.20LAO-41-4 Ethylbenzene O.20100-42-5 Styrene O.20I5-69-4 Tr i chlorofluoromethane 0.20'16-73-t 1,1,2 Trichlora-l,2,2-trifluoroethaneO.20108-38-3 m.p-Xylene 0.409 5- 4"7 -6 o-Xylene 0.20
< 0.50 u
< 0.20 u< 0.20 u< 1.0 U< 5.0 U
< 0.20 u< 0.20 u< 0.20 u< 0.20 u< 0.20 u< 0.20 u< 0.20 u< 5.0 U
< a.za u< a.2a u< a.2a u<_ 0 .20 u<_ o.20 u<. 0 .20 u< 0.20 u< 0.20 u< 0.20 u< o.20 u< 0.20 u< 1.0 u
< o.20 u< 5.0 U< 5,0 U
< a.Za u< a.2a u< a.2a u< a.2a u< a.2a u< 0.20 u< 0.20 u< o.20 u< 0.40 u< 0.20 u
Reported in UqlL (ppb)
volatile Sutrogate Recovery
2 - Ch I o ro e t hylwi nyl e t he racid preserwed sample.
d4-1,Z-Drchloroethane 122d8-Toluene ta2"zBromo fluorobenzene 95.42d4-1,2-Dichlorobenzene :-03d
is an acid 1abile compound and may not be
EPA SW-846 indicates that vinyt chloride and styrene may degradeacid preservative.
recovered from an
in the presence of
EORM I
rxs5fist:@INCORPOHATEDORGA}IICS AI{AI,YSIS DATA SHEET
Vola.tiles by Purge & Trap ccn4s-Method SW8260CPage 1 of 1
Sample ID: TRIP BLANKSSAMPLE
QC Report Nor AIX1 - Parametrix, Inc.Proj ect: Mason County Landfiff
555L682042Date Sampled: a] /08/15
Date Received: O7l08/15
Sample Amount: 10Purge Vofume: 10
LOQ Result O
Lab Sample ID: AIX 1FLIMS ID: 15-L2267Matrix: WaterData Release Authori zeReported: A1 /14/t5
Ins trument /Analyst : NT15/PABDate Analyzed:' O1 /LO/15 19:13
CAS Number Arta].yte
"'\J\)0mL0 mT,
14-81-3 Chforomethane 0.5014 83-9 Bromonethane 1.015 0L-4 vinyl Chloride 0.2075 00-3 Chloroethane A.20'7 5-09-2 Methylene Chloride 1.067-64-7 Acetone 5.075-15-0 Carbon Disulfide 4.2075-35-4 1,1-Dichl-oroethene 0.2075-34-3 1, 1- Di chl-oroethane 0.20156-60-5 trans- 1, 2-Dichloroethene 0.20L56-59 2 cis-1,2-Dichloroethene 0.2061-66 3 Chloroform 0.20141-A6-2 1,2-Dichloroethane 0.2078-93 3 2-Butanone 5.0?1-55 6 1,1,1-Trichloroethane 0.2056-23-5 Carbon Tetrachloride 0.20108-05-4 Vinyl Acetate 0.201 5-2'/ - 4 Bromodich.Loromethane O.2Q78 87-5 L, 2-Dichloropropane 0.2010 0 61- 01- 5 cis-1,3-Dichloropropene 0.20'7 9-AL- 6 Trichloroethene 0.20L24-48-l Dibromochl oromethane 0.207 9-00-5 l, L,2-T richLoroethane 0.201L-43-2 Benzene 0.2010061-02-6 t.rans-1,3-Dichloropropene 0.20110-75-8 2 -Chl oroethylvinylethe r 1.015-25-2 Bromoform a -24108-10-1 4-Methyl-2 Pentanone (MIBK) 5.0591-78-6 2-Hexanone 5.072'7 -L8- 4 Tetrachl oroethene 4.2019-34-5 ! t L, 2,2-Tetrachloroethane 0.20108-88-3 To.Iuene 4.20108-90-7 Chlorobenzene 0.20100-41-4 Ethylbenzene 0.20LO0-42-5 Styrene 0.2015-69-4 T r i chl o ro fluoromethane 0.207 6-13-1 1, L,2-Trichlora-L / 2,2-trifluoroethane0.2 0108-38-3 m, p-xylene 0.4095-47-6 o-XyLene 0.20
< 0.50 u< 1.0 U
< 0.20 u< 0.20 u< L.0 u< 5.0 U
< a.20 u< 0.20 u< 0.20 u< 0.20 u<- 0.20 u< 0.20 u< 0.20 u< 5.0 U
< 0.20 u< 0.20 u< 0.20 u< 0.20 u< 0.20 u< 0.20 u< 0.20 u< 0.20 U< a.za U< a.20 u< 0.20 U< 1.0 U
< a.2a u< 5.0 u
< 0.20 u< 0.20 u< 0.20 u< 0.20 u< 0.20 u< 0.20 u< 0.20 u< 0.20 u< 0.40 U< 0.20 u
Reported in pql], (ppb)
vo1ati]-e Suffogate Recovery
d4-1. 2 -Dichloroethaned8-TolueneBromofluo robenz ened4-1, 2-Dichlorobenzene
1A2Z94.L
1033
and may not be2 - Chl or:oethylv.inyl ethe r is an acid IabiJ-e compoundacid preserved sample.
EPA SW-846 indicates that vinyl chloride and styrene may degradeacid preservative.
recovered from an
in the presence of
EORM I E,a 5 3i 'i : qgla+-!i=fir..,€g*:*
ORGANICS ANALYS TS DATA SI{EETvolatiles by Purge & Trap Gc,/lds-Method SW825OCPage 7 of 2
Lab Sample ID: LCS-071015ALIMS ID: L5-L2262lVa I r ix: Wacer NData Release AuLhorir"a, !\)Reported: 01 /14 /L5
I nstrument /Analyst LCS: NT15/PABLCSD: NT15 / PAB
Date Analyzed LCS,. a7 /La/15 !0:51LCSD: 07,r10 /15 L2:.55
Analyte LCS
Sample ID: LCS-071015AI,AB CONTROL
QC Report No: ATX 1- Parametrix, fnc.Project: Mason County Landfilf
5551682042Date Sampled: NA
Date Received: NA
rr$ils*@INCORPORATED
SAMPLE
Sample Amount LCS:LCSD:
Purge Volume LCS:I,CSD:
Sl,ike LCSAdded-LCS RecoveEy
10.0 mL10.0 mL10. O mL10.0 mL
St>ikeLCSD Added-LCSD
LCSDRecovery RPD
Chlor:omethaneBromomethaneVinyl ChlorideChloroethaneMethylene ChlorideAcetoneCarbon Disul fide1. 1-lichl o roethene1,1 nichloroethanetrans-1, 2-Dichloroethenecis-1, 2 - D i chloroetheneChloroform1, 2-Dichloroethane2-Butanone1, 1, 1-T ri chl oroethaneCarbon TetrachlorideVinyl AcetateBromodi chlo romethane1, 2-Dichloropropanecis 1, 3-DichloropropeneTrichloroetheneD i b romo ch.I o rome thane1, 1, 2-TrichloroethaneBenzenetrans-1, 3-Dichloroplopene2 - Chl o roethylvinyf etherBromoform4 -Methy.I - 2 - Pentanone (MIBK)2 -HexanoneTet rachloroethene7, L, 2, 2-'I etrachl"oroethaneTo LueneChlorobenzeneEthylbenzeneStyreneTr' cl- [orof luorometnane7, l, 2-'I r Lch,lor.-o-l, 2, 2-trifluoroetham, p-xylene
1,0.27.3010.414.3 Q
38.69.359.921,0.18. 1-5
1-0.1:_0.18.3045.1ra.49.8s9.01
8.709 .248.789.L2t1 . z\)8.79o ?o9.059.53?q n
39.s8.948.808.618. 688.799.0910.1a 1a7'7.6
10.010.010.010.010.050.010.010.010.010.0
10.010. 050.010.010.010.010.010.010.010.010.010.010.010.010.010.0s0.050.010.010.010.010.010.010.010.010.02A .0
73.0e;L04ea143e;
88.9?
o? 69
99 .22101%
81.58101?101 t
83.0ts90 .22
7A 4Z98.5890.1t89.1287.0?a') n,87.88
82.0887.98
90.59
78.0t79.0E89.4288.0E86.1286.88B7.98
10189'7 . 4ZB8. OE
a ua1 .369.4113.5 Q8.8541 .18.238.199.651.679 .1t9.848. 6948.89.418.619 .119.008.669.01I .02
8. 648.399.'70o ?o
9.864L .743.07.909 .1,68.11I .238.088.538.75
L6 .2
10.010.010.010. 010.050.010.01-0.010. 010. 010.0l-0.010.0s0.010.010.010.0r-0.01n n
t-0.010.0l-0.010.010.010.010.010.050.050.010.010.010.010.010.010.010.010.020 .0
92.42 9 -9%73.62 0.8C90.7C L3.7Z135? 5.8ts
88.5? 0. 5ts01 n.+ I 14
82.32 L2.1287.9? L2.LZ96.52 4 .65'76.L2 6.929'1 .L% 3.9s98.4',2 2.6X86.98 4.6297.62 1 .9294.12 10.0886.72 12.'729't .12 8.1890.0s 0.3886.62 0 . 5890.11 2.52ao.2z 9.0392.52 L.4Z86.48 5.2X83.98 4.'7297,aea 0.9?93,92 3.'7298 .62 3 .4283.4A 6.'7286.08 8.5?19,02 72.4'49t,62 4.At81.18 6.7t82.32 5.3280.8t 8.4?85. 3? 6.4"687.52 L4.3"684,22 14.sts81.0? B.3a
FORM III
ANALYTICALRESOURCES
ORGANICS AIIAIYS I S DATA SHEET TNCORPORATEDvolatites by Purge & Trap GclMs-Method Sw8260C sample ID: LCS-071015APage 2 of 2 LAB CONTROI SAS{PLE
Lab Sample ID: LCS-071015A QC Report No: AIXI- Parametrix, Tnc.LIMS fD: 75'1-2262 Project: Mason County Landfil.LMatrix: Water 5557682A42
Spike LCS Spike LCSDAnalyte LCS Added-LCS Recowery LCSD Added-LCSD Recovery RPD
o-Xylene L 61 10.0 86.'lea 8.19 10.0 81. 92 5.72
Reported in pq,/L (ppb )
RPD calcufated using samp-Ie concentrations per SW846.
Vo]-ati.Ie Surrogate Recovery
LCS TCSDdA-l ,2-Dtchforoethane 113 * 1133dB -To.l-uene 1032 1038Bromo fl-uorobenz ene 96. BA 96.32d4-1,2-Dichlorobenzene 99.92 100%
EORM III:f; : .3t -r- I :lrsii 1i.: g?E:ir!i f3e
tx*#:t!@INCORPORATEDORGANICS A},IALYSIS DATA SHEET
volatiles by Purge & Trap GC/MS-Method SW8260CPage 1 of 1
SanpJ-e ID: I.$I-3BI'IATRIX SPrKE
QC Report No: AIX 1- Paramet rix, Inc.Project: Mason County Landfiff
5551682042Date Sampled: O1 /aB/15
Date Received: 01 /OB/15
Sample Amount MS: 10.0 mLMSD: 10.0 mL
Purge Volume MS: 10.0 mLMSD: 10.0 mL
Lab Sample ID: ATX1CLIMS ID: L5-L2264Matrix: WaterData Release Authori zed:Reported: 01 /1,4/L5
f nstrument,/AnaIyst
Date Analyzed MS:MSD:
Analyte
\QMS: NT 15 / PAB
MSD: NT 15 / PAB07 /1,0/15 19:.390'7 /La/15 20:06
Samp1eSpike MS
MS Added-MS RecoverySpike
MSD Added-MSDMSD
Recovery RPD
Chloromethane < 0.50Brcnomethane < 1.0Vinyl Chloride < 0 .24Chloroethane < A.2AMethyl-ene Chlor.ide < L.0Acetone < 5.0Carbon Dlsulfide < A .20!,.1-Dlchloroethene < 4.201 , 1- Di chloroethane < 0.20trans-1,2-Dichloroethene < 0.20cis-L,2-Dichloroethene < 0 .20Chloroform < 0 .201, 2 -Di chloroethane < 0.20Z-Butanone < 5.01,1.1-Trichloroethane < 0 .2ACarbon Tetrachloride < 0.20Vj-nyl Acetate < 4.20Bromodl chlo romethane < A.2A1.2-Dichloropropane < A.2Acis-1,3-D.i(]hloropropene < A.2ATrichloroethene < A.2ODibromochlo romethane < A.201.1,2-Trichloroethane < 0.20Benzene < 0.2Otrans-1,3-Dichloropropene < 0.202 - Chlo roethylvinylether < 1.0Bromoform < 0.204-Methyl 2-Pentanone (MIBK) < 5.02-Hexanone < 5.0Tet rachlo roethene < 0.201,7,2,2 Tetrachloroethane < 0.20To.luene < 0.20Chlorobenzene < 0.20Ethylbenzene < 0.20Styrene < A.2AT ri chlo ro fluoromethane < A.20l-, 1, 2-Trichl oro-!,2 ,2-lrifl < 0.20m,p xylene < 0.40o-Xylene < 0.20
UUUUUUUUUUUUUUUUUUIJ
UUU
UUUUUUUUUUUUUUUUU
concentrations per
11 .9 10.09.10 10.012.4 10. 0L6 .3 Q 10.010. 6 10.055.7 50.011.1 10.072.4 10.0t2.l 10.09.14 10.012.3 10.012.1 10. 070.3 10.064 .6 s0 . 012.2 10.010.9 :,0.0L2 .2 10.0L0.7 10.010.3 10.010. 6 10.0LO.2 10.010.9 10.010.5 10.070.4 10.011.5 10.01'r E 1n n
11.3 10.054.3 50. 05s.3 50.010.2 10.011.0 10.010.3 l-0. 010.2 10.010. 1 10. 010. 6 L0.0L2.! :-0.011.3 !-0.020.4 20.010.1 10.0
Reported in
119 C
91 .0?1242L63Z106ts1LL2LL1%
12791 .4*
727*103*729%
109*
1078103s106s]-025109210531t_t 4 5
1153115%1133109?1 11?702+7L0e.1038102%101 ?
L06Z7272113 ?L02%101 ?
pqlL (ppb)
sw846.
1232 3 .3299.22 8.6?1304 4.12173? 6.02111A 4 . 62L7'tZ 4.92Lt'72 5.3?I24ea 3.3?1262 4 .4"61018 3.6'tt2't z 3 .22L21Z 4. Bt1A1Z 3. 881312 5. 981,282 4.887142 4.521252 2 , 4e"
111E 3.1e"101B 3 .8%110 ? 3 .12LO]Z 4.89tL4Z 4.521108 4.'72L01Z 2.82L19Z 3.42lrrc E qz11BC 4.32LL4Z 4 .521t6Z 4.621079 4.8?1L6t 5.381068 2.92106U 3.8?106t 4 .82111? 4.62126ei 4 .02119ts 5.22106ts 3.4?1078 5.8t
9 .92J-3.0.r,7.3 Q11.1
L7 .7'1,2 . 412.610.1L2 .1L2 .110.758.512 .8LL.4
:_1.110.711.0t0 .717.411.010.7
11.856.851 .910.7rt.61"0.610.610.611.112.6Lt.92t.tLO .'7
1-0.010.010.0l-0.010.0s0.010.010.010.010.010. 010. 010.050. 010. 010.0Tn n
:-0.010.010.0:_0.010.010.010.010.010.010.050. 050. 010.010.010. 010.010.010.010.0t_0.024.010.0
RPD calculated using sample
FORM IIT
ixsbHsr!@INCOHPOHATEDORGANICS ANAIYS IS DATA SHEET
Volati]-es by Purge & Trap Gc/l'4^S-MethodPage 1 of 1
Lab Sample fD: AIX1DLIMS ID: 1"5'12265Marrix: Water r\Dara Re-Lease Authorize"rU)Reported: 07 /14 / L5
sw8250c Samp1e ID: lttll-11I\4ATR] X SPrKE
QC Report No: AIXl- Parametrix, Inc.Proj ect: Mason County Landfil-f
555r6824 42Date Sampfed: 01 /08/75
Date Received: O'7 /a8/15
f ns t rument ,/Anal ys t
Date Ana]yzed MS:MSD:
Ana].yte
MS: NT 15 / PABMSD: NT 15 / PAB07 /lO/75 2a:3207 /la/75 2a:59
SampIe
Sample Amount MS:MSD:
Purge Volume MS:MSD:
Spike MS
MS Added-MS Recovery
10.0 mL10.0 mL1O. O mLlO.0 mL
SpikeMSD Added-MSD
MSDRecovery RPD
Chloromethane < 0.50Bromomethane < 1.0Vinyl Chloride < A.2AChloroethane < 0.20MethyJ,ene Chloride < l-. 0Acetone < 5.0Carbon Disulfide < A.201,1-Dichloroethene < 4.201,l-Dichloroethane < 4.20trans'-1,2-Dichloroethene < 4.20cis-1,2-Dichloroethene < 0.20Chloroform < 0.201,2-Dichloroethane < 0.202-Buranone < 5. 01,1,l-Trichloroethane < 0.20Carbon Tetrachloride < 0.20Vinyl Acetate < 0.20Bromodi chl o romethane < 0.201, 2 -Di chlo ropropane < 0.20cis-1.3-Dichloropropene < 0.20Trichloroethene < 0.20Dib romochl o romethane < 0.201,1,2-Trichloroethane < 0.20Benzene < 0.20trans- 1, 3- Di chloropropene < 0.202 -Chlo roethylvinylethe r < 1.0Bromoform < 0.204 -Methyl -2 - Pentanone (MIBK) < 5,02-Hexanone < 5,0Tet rachl oroethene < 0.20L, L,2,z-TeLrachloroethane < 0.20Toluene < 0.20Chlorobenzene < 0.20Ethylbenzene < 0.20c+!'v^^^ < 0.20T r i chloro fluo rome thane < 0.20L, t, 2-TrLchLoro-7, 2, z-tt)-fl < 0. 20m,p-xylene < 0.40.r-Y./-a"rF < 0.20
UUUUUUUUUUU
UUUUUUUUUUUUUUUUUUUUUUUUU
UU
sample concentrations per
L2.2 10.010.3 10.0L3.2 10.016 Q o tn o
LL.2 10.060.4 s0.0LL .9 10.0L2.1 10.0L2.B 10.010.3 10.072.9 10.013.0 10.011.0 10.0'74.1 50.0L3.2 10.011.5 10.0L2.9 10.011.3 10.010.9 10.011.3 10.011.0 10.0L7.6 10.0I1 .2 10.010. 9 10.0L2.2 10.0t2.2 10.0L2.3 10.058.5 50.064.2 50.011.0 10.012.a 10.010.8 10.010.8 10.010. 9 10.0L1 .4 10.0L2 -9 10.012.0 10.021 .'7 2A.A10.9 10.0
Reported in
L22"a103?
1683t72ZLZLZl79ea
103?129Z
110274Oee
732ea
7292
T n oq
113 E
1102LI6Z
109E
L22e.L23ZL71 e"
L20Z110 ?L20Z108?10Bg109E114EL29Z1209108U1092
pslL (ppb)
sw8 4 6.
L44Z L6.52113? 9.381458 9.427102 L.221222 B.5t135? 11.19130% 8. 881388 8. 3t140t 9.081148 10.18L4LZ 8. 98L42Z 8.8%1199 1 .9%155t 10.3s7422 7 . 3e"
7262 9. 1E1458 LL.7e"1222 7 .7 e.
119t 8.8?
119% '7.927262 8.337232 9.43119t 8.8C133C 8.62135% l-0. lC133? 7.8?t28Z 8.8C1?T9 e AC
!L1Z 6 .221292 'l .22118? 8.8C116? '7.L2!L1Z '7.L2!222 6.8C
o og
t32Z 9.5Ct16Z 6.12L16Z 6.22
L4.411.3
17.0 Q
61 .513.013.874.471,.474.71A 2
7I.97'7 .'114.272.614.5
11. 972 .2
72.672.3
13.363. 965. s1,L .1
1t_.81,L.67L .'1
14. L
11.6
10.010.010.010.010.050.010.010.010.010.010.010.010.0s0.010.010.010.010.0
r-0 .010. o10.010.010.010.010.0s0.0s0.010.010.010.010.010.010.010.010.0lt -u10.0
RPD calculated us inq
FORM III
VOA SURROGATE RECOVERY SUMNfARYa}s:ff:t!@INCORPORATED
Matrix: Water QC Report No: AIXl-Parametrix, Inc.Project: Mason County Landfill
555L6824 42
TOL DCB TOT OUTARI ID C]-ient ID
MB-071015A Method BlankLCS-o?1015A LabControlLCSD-O71015A Lab Control Dup
MVi- 1 0MW-8MW- 3BMW_ 3BMW_ 3BMW-I1MW-1IMW- 11Cul verTR]P BLANKS
d4-L , 2-Dichl oroe!hanedB -ToIueneB romo f luo robenz ened4 - l, 2 - D rchf oroben zene
A]X 1AAIXlBAIX 1CAI X ICMSAIX l CMS D
AIXlDATX l DMSAIXl DMS D
A]X1EAIXl F'
sw82 60c
(ro],) :(BEB) =(DCB) =
10
10101010l0101010101010
LCS,/MB ITMITS
aFO-t ?nl(80-t20)/oo_'T rn\\vw t-w I
(80-120)
L02%
100%1^)9104?I05?103?1n)9
103?1038103%1n?9
QC LIMITS
(80-120)(80-120)(80-120)(80-120)
\7 4ea
11381lB?L204l20zt20zL2tZ*
1202
L22Z*L23Z*
10 1A103?103?101?103?70221042103%1A)q
103?1033r02z7022
96.5%o6 09
96.3295.8U91 .4295.3e"oa -72
o? tr.z
94.0%,9'7 .8ea96 .5295 .4294 .72
00000001
10111
Prep Method: SW5O30BLog Number Range: 1-5-L2262 La L5-7226'l
*.!: i :'-.E _ La= ri++E?i!i:-.li 1! .l
Data Fife : / chemL /nt1,5 . i/201s0710.b/icvo71-015.dReport Date: 10-.fu1-201-5 10:32
Page 1
0029-JUN-201s18:11
Analytical Resources, Inc.
CONTINUING CAI-,IBRATION COMPOUNDS
Injection Date: 10-JUL-201-5 10:rnit. cal . Date (s) : 29-.luN-2015
Instrument TD: ntl-S . iLab File ID: icv07l-015.dAnalysj-s Tlpe: WATERI-,ab Sample ID: ICV07I-0
Init. CaI . Times:Quant. T]T)e: ISTD
L5 .1,2
Method : / cheml-/n:LLs . i/20150710 .b/ B26oo6L2L.m
I
I coMPouND
I
RRF / AMorrNT I
lMrNlI RRF l*D /
CCA],
RRFl O
LMAX I I
TDRIFT gD / ,6DRIFT ICI]RIE TYPEI
| 1 Dichtorodif luoromeEtlane
l2 chLoromethane
l3 Viryl Chtoride
l4 Bromomethaie
l5 cEIOrOeEnAre
| 5 Trichlorof luoromeLhane
l? 1,1-Dichloroethene
l8 Carbon Disulfide
| 9 I12Trich1oro122Tr.if luoroeth
110 Iodomethane
111 Bromoethane
112 Acrolein
113 Methylene chloride
114 Acetone
115 Trans - 1.2 -Dichloroethene
117 Methyl tert buLy1 ether
| 1a 1, 1-Dichloroethane
[19 Acrylonitrile
120 vioyl Aeetate
122 ci B - 1 , 2 -Dichloroethenelz3 z, z - riehloropropane
| 24 Bromochlorometha!1e
125 chloroform
126 carbon Telrachlolide$ 2? Dibromofluorometha:re
128 1,1, 1-Trtchloroetshane
129 2-Butanone
30 1, 1-DLchloropropene
131 aenzene
l$ 33 d4- 1,2 -Dichloroethane1 34 1, 2-DichLoroethane
136 ?richlaroethe4e
138 Dibromonethane
lJy r,r ur-cnroropropane
| 4o Blomodichloromethane
1173 2-Pentanone
0.439391
o ,5'? 97 41
o .5sa8s I
o .50616 |
14.8553e I
o . e2529 |
L - 03229 |
2,1't6931
0,595?11
9. 96646 |
o -4447a1
o.o'7'?2tlo.7654? I
o.12388 |
o.701661
1 .42883 |
1.o7497 |
0.1s1631
0.83810
0 .628?3 I
a.'7649tl|0.2s318l1.00089
o .322e7 |
0. s2173 I
o. es2 os I
o.1zs9s I
0.4580? |
r.345881
0.66688 I
o.4i-9791
o .1o62i I
0.15?46 |
o - 32e38 |
0.38417 |
a.o2a2al
o .558?3 I
o -6422a1
o -7 4s62 |
o - so7a2 |
1o. o oooo I
1 .0143s I
1.11s08 |
2.223311
0,531s8 I
10. ooooo I
0.450?91
o - 0? 920 I
o-?39581
o .10465 |
o -62s261
t -48'166 |
i, .L7 t4 |
o.!46srlo. B4 B2s I
o.G8s2s I
o .91665
0.26113 I
1.0935? |
o.3so47lo .6229s I
0.9G139 |
o. L?880 |
o.44Gso I
t -3a27o I
o .7506s I
0.3889o I
a -2e7a2 |
o. 14488 I
o .313sa I
o .38253 |
0,02895 |
o. ss873 lo.o1o I
o. s4228 lo.1oo l
o . zas62 lo.1oo I
o. so102 lo - 1oo l
o.ag89s lo. o1o l
1- 0143s lo. o10 I
1.11sos lo. roo I
2.223331o -otoo.631sBlo.o1oIo.ss217lo.o1olo .4so 79 I o .10o
I
o.oTe2olo.ooolo.73gs8lo.o1olo. 1o4Gs I o. oo1 I
o.E2s26lo.o1ol1.4e756 lo.10o l
1. 1?3 34 | o.20 o I
o.146s1lo.oo1lo.84s2slo.ololo. 6ss2E I o. o10 |
o.916dslo.o1olo.26113 l o. oso
!-o93G7 o -2oo I
o.3so47 lo. r-oo I
o.5229e lo.1oo l
o.96139lo.1oo L
o.r78Bolo.oo1lo.aa550lo.o1ol1.3o2zolo.soolo,7so6slo.o10lo.38890 Io.10o I
o .2 9102 lo.10o I
o.144BBlo.o1ol0.31354 lo.1oo I
0.38263lo.1oo I
o. ozBgE ]o.10o I
21 .tsa94l10.?8548
|
13 .12105 I
- 1'7 3aa61,l
4B.6G3B7l
9.624501
a.02032 |
2.13r.691
s . 84313 I
-0.33s441
1. 36s23 |
2. se 116 |
-3.3s110I-1s. s2a8a I
-Lr.64462|4.11?211
9.1s083 l
-3.37s43 L
L-2LL24ls.989G5l
19.8383? I
3 - 140?11
9 -27a551
e.s152e I
19 .4o513 |
12 -a2a24l
-0.09?ool-2.52s24l-3.1e370 |
12 .56182 I
-7.35844 |
-4.97858l-7 -9a92t1
-4.51931
-o.4oo 5o I
2.6684s 1
20. oo ooo I
2o - Doooo I
20.ooooo I
2o.ooooo I
20. oooo o I
20. ooooo I
20. ooooo I
2o.oooool2o.ooooo l
2o. ooooo I
2o. ooooo I
2o. ooooo I
20. ooo oo I
20. ooooo J
20. ooooo I
20. ooo oo I
20. ooooo
20. ooooo I
2o. oo ooo I
20. ooo oo I
20. ooooo I
20. ooooo I
20.oooool2o.oooool2o . ooooo
I
2o. ooooo I
20. ooooo I
20. ooo oo I
2o. ooooo l
20. oooo o L
2o - oooo o l
2o. oooo o l
20. o000 0
2o.ooooo I
2o. oo ooo I
2o. oo ooo I
Aweraged | < -Averaged
I
Averaged I
Aweraged I
Lj-near | <-Aweraged
I
Averaged I
Averaged I
Averaged I
ouadratic I
Averaged I
Averaged I
Averaged 1
AveragedAveraged
I
Aweraged I
A.,.eraged ]
Aweraged
Averaged I
Aweraged I
Averaged I
aweraged I
Averaged I
Averaged I
Averaged I
Averaged I
AveragedlAveraged
I
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Data File : / chemaftLl-s. i/ 20150710.b/icw071015.dReport Date I 10-,.fu1-2015 10:32
Page 2
0029-,rUN-201_s18:11
Analytical Resources, Ine.
CONTINUING CAIIBRATION COMPOUNDS
Injection Date: 10-.fUL-201-5 10:rnit. Cal . Date (s) : 29-JuN-2015
Instrument fD: ntl-s . iLab File ID: icv071015.dAnalysis T)pe: WATERL,,ab Sample ID: ICV0710
Init. Cal . Times:Quant Tlpe: ISTD
L5 |L2
Method t / chemL /nLts . i / 201,50710 .b / 826oo61,2L.m
COMPOU}iID
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164
lds
166
J6i58
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175
1'17
2-Chloroethymnyl EtherCis 1, 3-dj-chloropropene43 d8 -TolueneToluene
4-Methyl-2 Pentaaone
Tetrachlo!oetheneTran6 1,3 Dichloropropene1, 1, 2-TrichloroethaneChlorodibromomeLhane
1 , 3 -Dichloropropane1 ,2 -Dibromoethane
2-Hexanone
Chlorobenzene
Ethyl Eenzene
1, 1, 1, 2 -Tetrachloraoethanem,p-xyleneo-xylenestyreneBromoform
lsopropyl Benzene
62 4 -B ron'|of LuorobenzeBe
Blomobenzene
N-Propyl Eenzene
1, 1, 2, 2 -Tet.rachloroethare2-Chloro Toluene
1,3,5 Trimethyl Benzene
1, 2, 3 -TrichloropropaneTrans- 1, 4 -Dichloro 2 Butene
4-Chloro Toluene
T-BuLy1 Benzene
1, 2 ,4 -TrinethylbenzeneS-Buty1 Benzene
4-Isopropyl Toluene
1, 3 -Di chloroberlzene1, 4 -Dichlorobenzene
o .1s157 |
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Data File : /chem1-/nLLs.i/20L50710.b/icv071015. dReport Date: 10-,1u1-2015 10:32
Page 3
29-,JUN-201s18:11
Instrument fD: nt15.i
Analytical Resources, Tnc.
CONTINUING CALIBRATION COMPOUNDS
Injection Date: 10-JUL-2015 10:00Lab File ID: icw071015.d fnit. Ca1 . Date(s): 29-JUN-2OL5Analysis Tlpe: I^IATER Init. CaI. Times; L5:L2Lab Sample fD: ICV0710 Quant Tlpe: ISTDMethod: / c};eml-/ntas - i/2oL50710. b/ 826oo6L2L.m
I
I coMPoulrD
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CCAI
RRFl O
MIN
i RRF
llItD / BDRIP! ltD
MAx I l
/ tDRTFT lcL'RtiE T].pE I
lza t-sutyr renzene
li't9 d4-L.2-DLchlorobeDzene80 1,2-Dichlorobenzene
181 1,2-Dibromo 3 - Chloropropane
183 Herachloro 1,3-Butadiene84 7,2 t 4-'frie:r.]orobenzene
185 Naphthalene
186 1, 2, 3 -TrichlorobenzeneI
2.962a21 3.178671
o . 9o3e5l o .91323 |
1-3osa6l 1.326601
o. o es14I o.o9d31lo - 2s730 | o.23soolo.61Gs6l o,s91g?li,,49757 | 1.430611
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1.43o61lo.o10lo.4Be6elo-01ol
7 .2e522 |
7.02646
r - 67948 |
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-6.98a60[
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E4 LE - ; E4'Y Lt/rE ltj-r -f J_,
ORGANfCS ANAIYS IS DATA SHEETvolatiles by Purge t Trap Gc/Ms-Method sw8250c-slM sanple ID: MB-071415rdgu r rrr -L
Lab Samp1e ID: MB-071415LIMS ID: T5-12262Matrix: WaterData Release Authori zed:Reported: 01 /1,6/L5 \D
METHOD EIANK
QC Report No: AIX1-Parametrix, Inc.Proj ect : Mason County Landfill
5551682042Date Sampled: NA
Date Received: NA
Sample Amount : 10.0 mLPurge Volume: 10.0 mL
Tnstrument/AnaIyst : NT7 /MMHDate Ana-Iyzedl. a] /a4/L5 O9:14
CAS NulDber Analyte RL Result A
'75-0L-4 Vinyl Chloride 0.020 < 0.020 U
Reported in pglL (ppb)
Vo]-atile Surrogate Recoverl'
d4-1,2-Dichforoethane 105%
EORM I
axsbHs*@INCORPORATEDORGANTCS ANAIYSI g DATA SHEET
Volati].es by Purge & Trap GC/MS-Method SW8260C-SIM Samp].e ID: Ivl!,I- 1OPage 1 of 1
Lab Sample ID: AIX1ALIMS ID: l5-L2262Matrix: WaterData Release Authori zed:Reported: 01 /L6/15 vs)
SAMPI,E
QC Report No: AlXl-Parametrix, Inc.Project: Mason County Landf i-If
55516820 42Date Sampled- 01 /08/15
Date Receivedt 01 /08/15
Sample Amount: 10.0 mLPurge Volume: 10.0 mL
Inslrument,/Analyst : NT7 /MMHDate Anal-yzed:. 07 /L4/15 10:21
CAS Num.ber Analyte RL Result a
75-01-4 Vinyl Chlorlde 0.020 < 0.020 U
Reported in pg,zL (PPb)
Volatile Surog'ate Recovery
d4-1,2-Dichforoethane 106?
FORM I i'l * ;'-:. .-1= E= 93!* e4 -:=
ORGA}iITCS AI'IAIYS TS DATA SHEETvolatiles by Purge & Trap GC/MS-I4ethod sw8250C-sIM Sample ID: MW-8Page 1 of 1
Lab Sample ID: AIX1BLrMS ID: 1"5-1-2263
d4-l-,2-Dichloroethane 110 ?
X3i:'i;.3::3'o,.ho,i,"", V q\Reporred : a] /16/ 15
Instrument/Anal-yst: NT 7 /MMHDate Analyzed:. 07 /14/15 l-0:49
CAS Number Analyte RL Result A
15-0T-4 Vinyl Chloride O.O2a < 0.020 U
Reported in pg,/L (ppb)
Volatile Suffogate Recovery
SAMPT.E
QC Report No: AIX1 - Paramet r.ix, Tnc.Proj ect : Mason County Landfill
55516820 42Date Sampled: a'7 /08/75
Date Received: a7 /08/L5
Sample tunount: 1"0.0 mLPu r ge Vofume: 10. O mL
EORM I f,q ! ii 'i rgisJ€:.lrl tr;a =
txssilsn@INCORPORATEDORGANTCS ANA],YS IS DATA SHEET
vo]-atj.les by Purge & Trap GC/MS-Method sI{8260c-sIM saeple rD: }49f-3BP^-e 1 of 1
Lab Sample ID: AIXICLIMS ID: 15-L2264
d4-1,2-DichLoroethane TL1Z
H3i:'i;.1::E'o,,.ho.i,.", \DReported: A1 /16/1-5
Ins trument,/Ana.Iyst : NT7 /MMHDate Analyzedt 01 /14/75 11:18
CAS Nud>er Anal-yte RL Result A
75-01-4 Vinyl Chloride 0 , 020 < 0 .024 U
Reported in pg,/L (ppb )
Volatile Sumogate Recovery
SA}IPI,E
QC Report No: AIX1 - Paramet rix, Inc.Proj ect: Mason County Landfill
5551682042Date Samp-Ie d: a] / OB / L5
Date Received: a'l /OB/L5
Sample Amount : 10.0 mLPurg'e Volume: 10.0 mL
FORM I ii-ri! i :€ 'g .: 4'-qL:-*= L! .f
ORGANTCS AI{ALYS T S DATA SHEETvoJ.atiles by Purge & TEap GC,/MS-Method SW8250C-SIM SampJ.e ID: MW-38Page 1 of 1
Lab Sample ID: AIX1CLIMS ID: 75-72264Matr' x: Wa I er I IData Re I ea se AL - hor i zed: \JReported: a] /16/15
Instrument/Anaf yst : NT7,/MMHDate Analyzed: a] /L4/15 L3:41
T4ATRIX SPIKE
QC Report No: ATxl-Parametrix, fnc.Proj ect: Mason County Landfill
555L6820 42Date Sampled: a7 /08/L5
Date Received: a1 /08/L5
Sample Anount: 10.0 mLPurge Volume: 10.0 mL
CAS Number Anal.yte RL Result O
75-01-4 Vinyl Chloride a.020
Reported in pql], (ppb)
Volati].e Surrogate Recovery
d4-1,2-Dichloroethane 99.0?
FORM I
AIs5[J:rb@INCORPC}HATEDORGAI{TICS ANAI.,YSIS DATA SHEET
VoJ.atiles by Purge t Trap GC/MS-Method SW8260C-SIM Sample rD: W{-3BPage 1 of 1
Lab Sample fD: AIX1CLIMS rD: 15-1"2264
}IATRIX SPIKE DUP
QC Report No: AIX1 -Paramet rix, Inc.Proj ect: Mason County Landfill
55s1682042Date Sampfed:. a] /08/15
Date Received:. 01 /a8/15
Sample tunount: l-0.0 mLPurge Vo lume: 10. O mL
RL Results I
Macrix: Water f\DdLa Rel-ease Aurhor tr"Or
$i\Reported: O'7 /76/15
Instrument/Analyst : NT7/MMHDate Anafyzedt a1 /74/15 14:10
CAS Nurober Ana]-yte
75-01-4 Vinyl- Chl-oride 0.020
Reported in pgll- {ppb)
Volatile Surrogate Recovery
d4-1-, 2-Dichloroethane 98. 0%
EORM I
irsbfJsr@INCORPORATEDORGANTCS AI.IAIYSTS DATA SHEET
volatiles by Purgre & Trap Gc/Ms-Method SW8260C-SIM Samp]-e ID: l.fiI- 11r q9L
Lab Sample ID: ATX1DLIMS ID: 75-L2265Matrix: WaterData Release Authorized:Reported: O7 /16/15 V\
SA}4PLE
QC Report No: AIXl-Parametrix, Inc.Proj ect: Mason County Landfif l-
555L682042Date Samp.Ie d: O1 /aB/15
Date Received: 01 / aB /15
Sample Amount : 10.0 mLPurge Volume: 10.0 mL
Instrument,/Analyst : NT 7 /MMHDale Analyzed: 01 /14/75 11:4'7
CAS Nurnber Analyte RL Result O
15-Ol-4 Vinyl Chloride 0.024 < a.A2O U
Reported in pg,/L (ppb)
Volatil-e Surogate Recovery
d4 - 1 , 2-Dichloroethane 113%
FORM I _;F!f! n .:t'i, !:r.:sax5trE:i'a
ixsHs*@INCORPOFATEDORGAI,IICS ANAT,TS I S DATA SHEET
Volatiles by Purge & TlaI) Gc/Ms-Method sw8260c-SIM Sample ID: I'&I-11P:6e 1 nf 1
Lab Sample ID; AIX1DLIMS ID: 15-1.2265Matrix: WaterData Release Authori zed;Repo rt ed : O-l / t6 / 1,5 \[bIns t rument,/Analys t i NT7/MMHDate Analyzed: a1 /14175 1-22 44
MATRIX SPIKE
QC Report No: AIX1-Parametrix, Inc.Proj ect: Mason County Landfill
5551682042Date Sampfed: a] /08/L5
Date Received: 07lOB/15
Sample Alrrount: 10.0 mLPuroe Vol-ume: 10. 0 mL
CAS Nunbe, Analyte RL Resu].t a
15-A1-4 Vinyl Chloride A .420
Reported in pgl]- (ppb)
vo1atiJ.e Surrogate Recovery
d4-1,2*Dichloroethane L0 42
EORM I
arsffisrb@INCORPOHATED
},IATRIX SPTKE DUP
QC Report No: AIX1 -Parametrix, Inc.Proj ect: Mason County Landfill
55576820 42Date Sampled:. A7 /O8/75
Date Received: 01 /08/75
Sample Amount: 10.0 mLPurge Volume: 10.0 mL
ORGATiIICS ANAIYS I S DATA SHEETvolatiles by Purge & Trap GC,/MS -Method sw8260C-sIM sample ID: l'49I- 11Page 1 of 1
Lab Sarnple f D: AIX1D
d4-1, 2-Dich.Ioroethane 100U
LIMS ID: 1"5-\2265
r:i:t;,::i s io,.no,,,.",
\ft)Reported: A1 /16 /L5
I ns trument,/Anal yst : NT7,/MMHDate Analyzedt O'7 /14/15 13:13
CAS Numl:er Analyte RL Result a
15-OL-4 Vinyl Chloride 0.020
Reported in pqll, (ppb)
Volatile Surrogate Recovery
EORM 1
fixs5fi#b@INGORPORATEDORGANICS ANAI,YS I S DATA SFIEET
Volatiles by Purge & lPrap GC /MS -Me thod S}I8260C-SIM Sample fD: CulverPage 1 of 1
Lab Sample ID: AIX1ELIMS ID: L5-L2266Matrix: WaterData Rel-ease Authori zed:Reported: A1 /1.6/T5 \N)
SA},,IPLE
QC Report No: AIXl-Parametrix, fnc.Proj ect: Mason County LandfiII
555t682042Date Sampled: O7 /08/t5
Date Received: 07l08115
Sample Amount : l-0.0 mLPurge Volume: 10.0 mL
Ins trument /Analyst : NT7/MMHDate Analyzed: 01 /L4/15 L2:15
CAS Number Analyte RL Result A
75-OL-4 Vinyl Ch.J-oride 0.020 < a .020 U
Reported in US/L (ppb)
Vo1atile Surrogate Recovery
d4-1,2-Dich.Loroethane 113 ?
EORM I
"Tbfi8e."@oReANIcs ANALYSIS DATA sHEEr ft1o""oror=oVo].atiles by Purg'e & Tlap Gc/Ms-f'{ethod SI,{82 60C-SIM Samp1e ID : TRIP BLANKSPa cr€. 1 of 'l
Lab Sample ID: AIX1ELIMS ID: 15-72261Matrix: WaterData Release Authorized:Repor:ted: A'7 /L6/15 $I nst runLent /Analyst : NT7/MMHDate Analyzed: 01 /L4/1,5 09:52
SAMPIJE
QC Report No: AIX1 - Parametrix, Tnc.Proj ect: Mason County Landfifl
555L682a42Date Sampled: 01 /08/75
Date Receivedl 01 /08/L5
Sampfe Amount: 10,0 mLPurqe Volume: 10.0 mL
CAS Number Analyte RL Resu1t O
75-01-4 Vlnyl Chloride 0. 020 < 0. 020 U
Reporled j-n }iq,/L (ppb)
Volatil-e Surrogate Recovery
d4-L,2-Drchloroethane 10 6?
FORM I i!,E: =' :gi ': i. +:iE af! E ,e L! =,,,11
SW825O-SIM SURROGATE RECOVERY SUM}4ARY
Matri x: Water QC Report No: A1x1-Parametrix, Inc.Pro j ect : Ma s on Count y Landf i -I I
55516820 42
C1ient ID TOT OUT
MB-071415LCS-071415LCSD-071415MW- 1OMW_ B
MW_ 3BMW_ 3 B _MS
MW- 3B_MSD1".1W - L -L
MW- I 1-MSMW_ 11_MS D
Cul ve rTRIP BLANKS
105?LUIZ
qq ?+
10 6%
110*111?
99 . aea
98.02IIJS104?t-00tL73Z10 6%
ICS/MB I,IM] TS
tAa-129\
0000000000000
9C LIMITS
(80-129)(DCE) = d4-1, 2-Dichloroethane
Prep Method: SW5030Log Number Ranqre: 15-12262 Lo 75-L2267
Pade 1 for AIX1FORM-I I SI.T825O-SIM
*;:r t ::i ': I E!:n cr!: iIE -'r 54.8
ORGAI.ITCS ANAI,YS I S DATA SI{EETVolatiles by Purge & TraI) GClMS-Method SI,{82 60C-SIM Sample ID: LCS-071415Page 1 of 1
Lab Sample ID: LCS-O71415LIMS ID: T5-12262Matrix: WaterData Release Authorized:Reported: 01 /L6/75
LCSD: NT7 /MMH
Analyte
ANALYTICALRESOURCES
LAB CONTROL SA]"IPLE
QC Report No: Alxl-Parametrix, Inc.Proj ect: Mason County LandfiII
s5516820 42Date Sampfed: NA
Date Received: NA
LCSD: 10.0 nL
Spike I,cs sl)ike LcsDLCS Added-Lcs Recovery LcsD Added-LCSD Recowery RPD
INCORPORATED
\\-)
lnstrument /Analyst LCS: NT7/MMH Sample Amount LCS: 10.0 mLLCSD: 10.0 mL
Date Analyzed LCS:. 01 /L4/15 OB,LI Purge Vo]-ume LCS: 10.0 mLLCSD: 07l14 /15 0B:46
Vinyl Chtoride 0.907 1.00 90.12 A.926 1.00 92.62 2.LZ
Reported in pg,rL (ppb)
RPD calculated using sample concentrations per SWBA6.
volatile gurrogate Rec.overy
LCS LCSDd4 -1, , Z-Didnl oroethane 101U 99.22
EORM III
ers5ffs::@INCORPORATEDORGANICS ANALYS I S DATA SHEET
Volatiles by Purge & Trap Gc,nLs-Method SW8250C-SIM Sample ID: MW-38Page 1 of 1
Lab Sample ID: AIX1CLIMS ID: L5-12264Matrix: WaterData Release Aulhorized:Reported: A7 /\6/L5
!'ATRIX SPIKE
QC Report No: AIX1 - Parametrix, Inc.Proj ect : Mason County Landfilf
555r6820 42Date Sampled: 01 /OB /L5
Date Received: 07l08/15
I ns t rument,/Anaf yst MS: NT7/MMH Sample l\mount MS: 10.0 mLMSD: NT7/MMH MSD: 1"0.0 mL
Date Analyzed MS: 01 /!4/15 l3:4t Purge Volume MS: 10.0 mLMsD:. 07/14/ 15 14:10 MSD: 10.0 mL
Spike Ms Spike MsDAnalyte sample MS Added-MS B.ecovery MSD Added-MSD Recovery RPD
Vinyl Chloride < 0.020 U 0. 895 1.00 89.5? 0.831 1.00 83. l% 1 .42
Reported in lrqlL (ppb)
RPD ca.Lcuf ated usinq sample concentrations per SWB46.
FORM III
ixSbHEi:@INCOHPORATEDORGANICS AIiIALYS I S DATA SHEET
VoJ.atiles by Purge & Trap GC/MS-I4ethod SW8260C-SIM Sample ID: MltI-11Page 1 of 1
Lab Sample ID: AIXIDLIMS ID: L5-12265
X3::'i;.:::E'o.,.ho.i,.o,'\ \)
I'IATRIX SPIKE
QC Report No: ATX1-Parametrix, Inc,Proj ecl: Mason County Landfill
5551682042Date Sample d: 0'7 / 08 / L5
Reported: O'l /I6/L5 Date Received: a7 /08/1"5
Instrument/Analyst MS: NT7/MMH Sample Arnount MS: 10.0 mLMSD: NT7/MMH MSD: 10.0 mL
Date Analyzed MS: 0'7 /I4/L5 1,2:44 Purge Volume MS: LO.O mLMSD: a7 /L4/ 15 13:13 MSD: L0.0 mL
Spike l.(S Spike MsDAnalyte Samp].e MS Added-MS Recovery MSD Added-MSD Recovery RPD
Vinyl Chloride < 0.020 U 0.869 1.00 86.92 0.873 1.00 87.33 0.5?
Reporred ln pSlr. (ppb)
RPD cafculated using sample concentrations per SWB46.
FORM III +:q 5 fi; -..r _ {"aE E;Fl!"4:-., :i-+
Mat rix : Water i il
Data Release Authorized: I {' 'Reported: al / 20 /15
SEMPLE REST'LES-CONVEI{TTIONAI,S ANALYTICAL AAlxl-Parametlix, Inc. RESOUHGESV
INCORPORATED
Proj ect: Mason County LandfiflEvent : 555!6820 42
Date Sampled:. A7 /08/15Date Receivedl a] /OB/1,5
Analyte
Client ID I MIi[-10ARI ID: L5-L2262 AIX1A
DateBatch Method Units RL Sample
chforide 01 /L5/L5 EPA 325.2 mg/t' 1-0 2.1071s15+I
N-Amnonia 0-l /t0/15 EPA 350.1-M mg-N/L 0,010 0.0180 7 1015+ 1
N-Nitrate 0'1 /09/15 Calculated mg-N/L 0.010 0.355
N-Nirrite o"l /09/15 EPA 353.2 mg-N/L 0.010 < 0.010 U
070915#1
Nitrate + Nitrite 0'7 /09/15 trPA 353.2 mg-N/L 0'010 0.355070915#t
Sulfate O'l /L'1 /15 EPA 375.2 mg/L 2-O 2.601 t]L5*1-
Chemical oxygen Demand 01 /16/L5 EPA 410.4 mg/L 10.0 < 10.0 U
071615#1
Total Organic Carbon 0'l /L1/Lb EPA 9060 mg/L 0.50 0.58071015+ 1
RL Analytical reporting IimitU Undetected at reported detection limit
Water Sampfe Report-Alx1.:-:: , .E 'E : *- g'E lsE :*! i-4
Matrix: WaterData Release Authorized: i '.'Reported: 01 /20/1,5
INCORPORATED
Proj ect: Mason County LandfillEvent : 5551-6824 42
Date Sampled: 0l /08/15Date Received:. 01 /OB/L5
!4ethod Units RL Samp1eAna]-yte
SAI{PI.,E RESI'LTS -CON\IENTIONAISAlXl-Pararaetrix, Inc.
CLient ID: tdlf-8ARI ID: 15-12263 AIX1B
DateBatch
ers5fisr!@
Ch l ori de
N-Ammonia fi /1A/15 EPA 350.1M mg-N/L 0.010 0.080071015+1
N-Nitrale fi /A9/15 Calculated mg-N/L 0.010 0.319
N-Nitrite 01 /A9/L5 EPA 353.2 mg-N/L 0.010 < 0.010 U
070915+1
Nitrate + Nitrite w /a9/15 EPA 353.2 mg-N/L 0.010 0.3190709L5+1
01 /15/15 EPA 325.2 mg/L0 7 1515+ 1
0'7 /L7 /t5 EPA 3'75.2 mg/t'ol L-t 15+L
Suf fate ao2.9 L.t)
10.0 < 10-0 u
0.50 < 0.50 u
Chemicaf oxygen Demand 01 /16/LS EPA 410.4 mg/L
Total Organic Carbon
071-615+1
01 /rc/15 trPA 9060 mg/L071015+1
RL Analytical reporting limitU Undetected at reported detection limit
Water Sample Report-AIX1
Matrix: Wate.rData Release Authori zed :
Reported: 0'7 /2A /75
SAIIIPLE RESULTS-CONVENTTONAJ.S ANALYTICALAAlxl-Palametrix, Inc. RESOURCESV
INCORPOHATED
Proj ect: Mason County LandfiflEvent: 555L682042
Date Sampf e d: 0'1 / 08 / 15Date B.eceived: 0l /08 /15
Analyte
Client ID: MI1I-3BARI ID: 15-12264 AIXIC
DateBatch litethod unitg RL Samp].e
chforide 0-l /75 lLs EPA 325.2 mg/r 1- 0 2.4071515#1
N-turunonia 01 /1,0/15 EPA 350.1M mg-N/L 0 - 010 0 -021071015+L
N-Nitrate 07 /A9/75 Calculated mg-N/L 0-010 0.L64
N-Nitrite 01 /09/15 EPA 353.2 mg-N/L 0.010 < 0.010 u070915+1
Nitrate + Nj-trite 01 /09/\5 EPA 353.2 mg-N/L 0.010 4.L64070915+1
01 /t'7/t5 EPA 375.2 mg/t 2-a 2-2ru I LdLe 07r 715+1
Chemical oxygen Demand 01 /16/15 EPA 410 ' 4 mq/r' 10.0 < 10.0 U
071615+1
Total organic Carbon 01 /L0/15 EPA 9060 mg/t 0.50 < 0.50 u07:-015#1
RL Analytical reporting IimitU Undetected at reported detection limit
Water Sample Report-AIX1
Matrix: WaterData Re.Iease Authori zed:Reported: 01 /2a/15
Analyte
SA!'PLE REST'LTS -CONVENIIONALSAlXl-Parametrix, Inc.
, , " ,r: '-' "t;+:;:;Date Sampled:
Date Received:
Client ID: t{lV-11ARI ID: 15-12265 AIXID
DateBatch Method Units
ixsbff:tb@INCORPOHATED
Iandf i 1IMason County5551682a4201 /08/t501 /08/15
RL SampJ'e
Chl ori de
N -L'tu'noni a
N-Nitrate
N-Nitrite
Nitrate + Nitrite
Sul- f ate
Chemical oxygen Demand
Totaf Orgtanic Carbon
a] /15/t5071515#1
01 /10/L50 7 1015+ 1
01 /09/15
a7 /a9/L5070915#r
0'7 /09/t5070915#1
o1 /11 /ls071715+1
01 /16/L5071615+1
0-7 /rc/t5071015+1
EPA 325.2
EPA 350. IM
Ca.l-cufated
EPA 353.2
EPA 353.2
EDA ??q ?
EPA 410.4
EPA 9O60
ng/L
mg-N,/ l,
mg-N / L
mg-N/L
mg-N,/L
mg/L
mg/L
mg/t
1.0
0.010
0.010
n nT n
0.0r 0
2.0
10.0
0.50
2.0
n n?q
0.188
n nl n
0.188
2.6
< 10.0 u
0.53
RLU
Analytical reporting limitUndetected at reported detection limit
Water Sample Report-Alxl
SAMPLE RESITLES-CONVENTIONATS ANALV1CALAAlxl-Parametrix, Inc. RESOURCESV
INCORPORATED
Matrix: Water r Project: Mason County LandfillData Release Authorized: , 'r -'l.L' " Event: 5551682042Reported: 0'7 /20/L5 Date Sampledt 01 /08/15
Date Received: 07l08/15
Client ID: CulwerARI ID: 15-12266 AIXIE
AnalyteDateBatch l4ethod Units RI, Sary>le
Chloride 07 /L5/15 EPA 325.2 mg/L 1.0 2.2071515#1
N-tuunonia 0'l /1A/\5 EPA 350.1M mg-N/L 0.010 0.0140l 1015 + 1
N-Nitrate 0', /09/1.5 Calculated mg-N/L 0.010 0.330
N-Nitrite 01 /09/15 EPA 353.2 mg-N/L 0.010 < 0.010 U
070915#1
Nitrate + Nitrite 01 /09/15 EPA 353.2 mg-N/I 0.010 0.330070915#1
Sul fate
ToLaI Organic Carbon
a] /L] /15 EPA 375.2 mg/r071715#1
Chemical- oxygen Demand A1 /16/LS EPA 410.4 mg/t071615#1
A1 /L0/L5 EPA 9060 ms/r071015#1
RL Analytical reporting limitU Undetected at reported detection limit
a^)d
10.0 < 10.0 u
0.-50 < 0.50 u
Water Sample Report-Alxl
Matrix: WaterData Release Authorized:Reported: 0'7 /20/15
Analyte
METHOD BLA!{K RESI'LtrS - CON1ZENTIONALSAIxl-Parametlix, Inc.
Method Date Units
1 r: ,r" Proiect:Event:
Date Sampled:Date Received:
txs:u:*@INCORPORATED
Mason County Landfill5551682042NA
B].ank ID
ChI ori de
N-turunon i a
N-Nitrite
N j-trate + Nitrite
Suf fate
Chemicaf Oxygen Demand
Total Organic Carbon
FB Filtration Blank
EP}. 325.2
EPA 350.lM
FDA ?E? ,
EPA 353.2
FDA ?-I( '
EPA 410.4
EPA 9O5O
01 /15/t5
a] /to/L5
0'1 /09/150'7 /09/t5
a] /09/15a] /09/15
01 /11 /L5
0'7 /16/t5
07 /ra/15
mq/L
mg-N/L
mg-N / L
mg-N / L
mg/t
mq/L
mg/ L
< 1.0 u
< 0.010 u
< 0.010 u< 0.010 u
< 0.010 u< 0.010 u
<)n11
< 10.0 u
< 0.50 u
EB
FB
EBFB
FBTb
FB
Water Method Bfank Repor t -AIx l-
STAT{DARD REFERENCE REST'I.,TS-CONVENTIOTiIAIISAlXl-Parametrix, Iuc. axsbfl:r!@
INCORPORATED
landtrl-LMason County555t682042NANA
Trueva.1ue
Matrix: WaterData Release Authori zed:Reported: 01 /2a /15
Analyte/ sRM ID
- - ,:....3Proj ect :
Event iDate Sampled:
Date Received:
t'!ethod Date units SRM Recovery
ChI orideERA #260115
N -Ar,mon i aERA #360114
N-Ni tr-i t eERA +141113
Nitrate + NitriteERA +320614
SulfateERA 131013
Chemical Oxygen DemandOrion *RP1
Total Organic CarbonERA #0408-13-02
EPA 325.2 a] /15/L5
01 /a9/L501 /a9/t5
01 /09/),501 /a9/15
o'1 /11 /L5
o1 /L6/15
o1 /LA/15
mg/r,
mg-N/L
mg-N/r
mg-N/L
mq/L
mg/L
mq/t
5.0
0.495
0.5180.514
0.5300.525
9t .6
20.8
5.0
0.5000.500
0. s000. s00
15.0
100
20.0
100.0%
ocr n9
103. 5?L02 .?ea
106.0?105.0%
98.0%
9t.62
104 .0?
EPA
EPA
EPA
EPA
EPA
EPA
2Ea 1M
16? 2
353.2
4)"0 .4
9060
Water Standard Reference Report -AIX 1
Matrix: WaterData Release Authori zed:Reported: 01 /20/15
Ana].yte
REPL,ICABE RESI L,TS-CON\TENTIONAIS ANALYflCAL AAlXl-Paaaeetrix, Inc. RESOURCES\/
INCORPORATED
Proj ect: Mason County LandfiLl-L . I .-i.: ri Event: 555L6B2042
Date Sampled: 0'7 /08/!5Date Rece j-ved: 01 / aB / t5
Method Date Units Saurtrrle RePlicate (s) RPD,/RSD
ARI ID: AIX1C Client
Chforide
N-Ammonia
N-Nitrite
Nitrate + Nitrite
Sulfate
Chemical oxygen Demand
Totaf organic Carbon
ARI ID: AIX1D Client
Ch 1o ri de
N-Arnmoni a
N-Nitrite
Nitrate + Nitrite
Sul f ate
Chemical Oxyqen Demand
Tota1 Organic Carbon
rD: MW- 3Et
EPA 325.2
EPA 350.lM
EPA 353.2
EPA 353.2
EPA 31 5.2
EPA 410.4
EPA 9O60
ID: I{9I-11
EPA 325-2
EPA 350. lM
EPA 353.2
EPA 353.2
EPA 375.2
EPA 410.4
EPA 906O
L.9
n nr?
< 0. 010
0.184
2.6
< 10.0
< 0.50
1..9
0.025
< 0.010
0.173
,q
< 10.0
< 0.50
01 /t5/15
o7 /L0/t5
01 /09/15
01 /09/L5
01 /1,1 /L5
01 /t6/t501 /L0/L5
01 /L5/L5
0'1 /L0/L5
07 /09/L5
o'7 /09/15
01 /t1 /15
0-t /16/15
01 /fi/t5
mg/L
mg-N/L
mg-N / L
mg-N / L
mq/t
mg/L
mq/L
mq/L
mg-N/1,
mg-N/I
mg-N/L
mqlL
mq/L
mg/L
)0
0.021
< 0.010
0.164
11
< 10.0
< 0.50
2.0
0.029
< 0.010
u. loo
< 10.0
0. s3
5. 1%
1-6.0?
NA
1:,.5%
1-6.1%
NA
I\A
1_4.82
NA
a ?9
1n 09
NA
NA
Water Repficate Repo rt -AI X 1gi. i "nh A += l+Ef --:.:r -r1
Matrix: WaterData Release Authori zed:Reported: 07 /20/L5
Ana].yte
MS /MSD RESUT.,TS-COtnrENrrONAr.,sAIX1 -Parametlix, Inc.
-1 -lL. "
Method
Proj e ct :
Event :Date Sampfed:
Date Received:
Date Units Sample Spihe
f,r3bfist!@!I{CORPORATED
Mason County Landfifl555t 68204201 /08/L50'7 /08/L5
SpikeAdded Recovery
ARI ID: AIXIC C]'ient
Ch 1or i de
N-Ammon i a
N-Nitrite
Nitrate + Nitrite
Sul fate
Chemicaf Oxygen Demand
Total Organic Carbon
ARI ID: AIX1D C].ient
Chloride
N-Ammon i a
N-Nit ri t e
Nitrate + Nitrite
Chemical Oxygen Demand
?otal Organic Carbon
fD: M9I-3B
EPA 325.2
EPA 350.:-M
EPA 353.2
EPA 353.2
E-D7\ ??q ,
EPA 410.4
EPA 9060
ID: Mfil-1t.
rnn ,aE: aLETI )ZJ , '
EPA 350.1M
EPA 353.2
r,DA ?(? ,
EPA 375,2
EPA 410 . 4
EPA 9060
a] /15/L5
a] /L0/L5
a7 /09/15
01 /09/15
0'7 /1,1 /t5a1 /16/ts
a] /10/Ls
01 /15/15
o7 /ta/Ls
01 /a9/L5
01 /49/15
01 /11 /15
01 /16/15
01 /1,0/15
mg/L
mg-N / L
mg-N/L <
mg-N /L
mq/t
mg/L
mg/L
mq/L
mq-N/L
mg-N/L
mg-N/!
mq/L
mg/L
mq/L
2.0
0.02 ,1
0.010
0.T64
2.2
< :-0.0
< 0.50
z-u
o .029
< 0.010
O.1BB
2.6
< 10.0
0 - 53
1.L
0.555
0.508
0.695
L1 .6
o, o
20.'7
1.1
n q,4 0
0.506
0.61 4
L6 .9
oq (
20 .1
5.0
0.500
0.500
0.500
15.0
100
20 .0
5.0
0. s00
0.500
0.500
15.0
100
20 -0
L02 . OZ
10s. 6*
101.6%
t06.22
to2 .12
q? q*
103.5%
102.0?
104.0?
t0L.2z
91 .22
9s.3?
o( q9
100.8?
lYater MS/MSD Report-Alxle',4, IA'9 - a!.dqr'iEir-+* ;r
ixsbfistb@INCORPOHATED
INORGATiITC S ADIAI,YS I S DATA SHEETDf SSOI,VED META].,SPage 1 of 1
Lab Sample TD: AIX1ALIMS ID:15-12262Matrix: WaterData Refease Authorized:Reported: 01 /L6/L5
Sample ID: MW-10SAI4PLE
QC Report No: AIX L -Parametrix, Inc.Pro; ect i Mason County Landfill
555r682042Date Sampled,' a7 /O8/75
Date Received:. O1 /08/L5
Pre1> Prep Analysis AnalysieMeth Date Method Date CAS Nuober Analyte I,oQ VS/L O
200.8 01 /I0/75 20A.8 01 /13/L5 1440-38-2 Arsenic6010C 01 /LO/15 6010C O1 /15/75 1439-89-6 Iron6010C al /tO/15 6010C 01 /L5/15 1439-96-5 Manganese6010C t)7 l70/15 5010C 0"7 /75/15 1440-66-6 Zinc
U-Analyte undetected at given LOQLOQ-L-Lmi L of Quant ication
0.250
1
10
0.2 u50 u1U
10 u
EORM-I
,ri!;! I L'! r altrll tlJ.E aii'li +ri r-{
#3:H:*@INCORPORATED
INORGANICS AI{AIYS I S DATADISSOI,VED ME TAJ.SPage I of 1
Lab Sample TD: AIX1BLIMS ID: T5-12263Matrix: WaterData Release Authori zed:Reported: a7 /16/15
SHEET
PrepMeth
PrepDate
Analysis AnalysisMethod Date CAS Number Analyte
Samp1e ID: WI-8SAI.''PI.,E
QC Report No: AIX1 - Parametrix, Inc.Proj ect: Mason County Landfil-l-
5551682442Date Sampfed:. O1 /08/15
Date Received: a] /08/15
LOQ rs/L
200 .86010c6010c6 010c
a1 /70/15a7 /70/L5at /to/1501 /to/L5
200.86010c6010c6010c
Arseni-cIronI,Ianganesezinc
o'7 /L3/1-5 7440-38-20'7 /1,5 /15 7 439-89-601 /15/15 7439-96-5a] /t5/15 1440-66-6
0.250
1
10
o.250
2]-410
U
U
U-Analyte undetected at glvenLOQ-Limit of Quant itation
LOQ
EORM-I
r9.& q GE'S - gr:E *n= 6o!E tila :-g
irsbHsr!@INGORPIORATED
INORGANICS ANAJ,YS IS DAIA SHEETDISSOI.VED METAISPage 1 of 1
Lab Sample ID: AIX1CLIMS IDr L5-1,2264Matrix: WaterData ReLease Aurhorized:Reported: 01 /16/L5
Sample fD: MW-38SAI'IPLE
QC Report No: AIX 1- Parametrix, Inc.Project: Mason County Landf iI-I
5551-682042Date Sampled: 01 /08/L5
Date Received: O1 /aB/L5
Prep Prep Analysis Ana].ysieI.,feth Date lrlethod Date CAS Nuolrer Anal-yte L.,OQ ]trS/L A
200.8 07 /7A/\5 2a0.8 01 /t3/15 1440-38-2 Arsenic6010C 01 /70/15 6010c A1 /15/L5 7439-89-6 Iron6010C 01 /LA/15 6010C 07 /15/15 1439-96-5 I'tanganese6010C 01 /LO/t5 6010C 01 /t5/tz 7440-56-6 Zinc
U-Analyte undetected at given LOQLOQ-Limit of Quantitation
0.250
1
4.2 u50 u
54310 r)
EORM-I
"E4 i ]E 'E :l i:r! !++! lrrE er.a!,:i_!
INORGANTCS AI.IALYS I S DArA SHEETDTSSOI,VED ME TAI,SPage 1 of I
Lab Sample TD: AIX1C i|IMS ID: 15-12264 ;'lf.Maurix: warer hikDara Rel ease Author ized: litlReported : O1 /16/15 vJ
Sample ID : t"l!{-3BDUPI,ICATE
QC Report No: AIxl - Paramet rix, Inc.Proj ect: Mason County Landfill
5557692a 42Date Sampled: O1 /O8/\5
Date Received:. a] /O8/15
I',ATRIX DUPLICATE QUAIJITY CONTROL REPORT
AnaLysis ControlAnaLyte Method Sample Duplicate RPD Limit O
Arsenic 240 .5 0.2 u 0.0? +/- o.2 L50 u 0.0a +/- 5a L
548 o.9B +/- 20210 u 0.0? +/- 10 LZinc
6 010c
5010c
0.2 us0 u
E/a
10 U
I ronManganese 6 010C
Repofted in pglT,
* -Control- Limit Not MetL-RPD Invafid, Limit : Detection Limit
EORM-VI
*xs5ilsrb@INCORPOHATED
INOBGAI{ICS ANALYA IS DATADISSOIVED METALSPage I of 1
Lab SampLe ID: AIXICLIMS TD:15-1,2264Matrix: WaterData Release Authori zed:Reported: 01 /16/L5
SHEET
Analysisltlethod Sauple
tl
Saup]-e ID: tllltf-3E}I'TATRIX SPIKE
QC Report No: AIXI- Paramet rix, Tnc.Proj ect: Mason County Landfil]
555L6820 42Date Sampl-e d: 0"7 /08/L5
Date Received: 0'l /OB/15
I{AERIX SPIKE QUAIITY CON1TROL RE PORT
Analyte SpikeSpikeAdded
tRecovery o
ArsenicI ronMangane s e
Zinc
200. B
6010c6010c6 010c
0.2 u50U
54310u
21 ,62,090T, O20
500
"( n
2,004500500
110 tTO4Z
Oq .,1 q
100?
Reported in pqll,
N-Control Limit Not MetH-% Recovery Not Applicable, Sample Concentration Too HighNA-Not Applicable, Anafyte Not SpikedNR-Not Recovered
Percent Recove.ry Limits t l5-L252
EORM-V
ixsbffHb@INCORPOHATED
INORGANTCS ANALYSTS DATADISSOLVED METAI,SPage 1 of 1
Lab Sar,ple ID: AIXIDLIMS ID: L5-L2265Matrix: WaterData Re.Iease Authori zed:Reported: A1 /L6/15
Saople ID: MVII-11SAMPLE
QC Report No: AIX1 -Parametrix, fnc.Proj ect: Mason County Landfill
t,551682442Date Samp-led: O1 /O8/15
Date Received: O1 /08/15
I.oo
SHEET
dPrepMeth
PrepDate
Analysis AnalyeisMethod Date CAS Nuober Ana!-yte VS/L
2AA .86010c6 010Coutur-
200.86010cOU.LUU
6010c
^,50
1
10
50551
10
U-Analyte undetected at given LOQLOQ-Limit of Quantitation
07 /L3/L5 7 440-38-207/15/15 7439-89-601 /15/L5 7439-96-5o'7 /1.5115 1440-66-6
01 /LA/1501 /10/15a] /10/15a"7 /70 /15
Arsenicf ronl{anganeseZinc
U
II
FORM-I
@!:F--E : E fl lr.! Einfl fe -P€
INORGANICS A}IAIYSIS DATADISSOLVED METAISPage 1 of 1
Lab Sample ID: AIX1DLIMS ID: l5-L2265Matrix: WaterData Release Authorized:Reported: C.)1 /L6/15
SI{EET
Anal.ysist'lethod SampLe
SamPle ID : l"fii- 11DUPTICATE
QC Report No: AIXI- -Paramet rix, Inc.Proj ect: Mason County Landfill
555r682442Date Sampled: 0ll08/15
Date Receivedt O'l /08/15
DuplicateControlLinit
aT{ATRIX DUPLICATE QUATITY CONTROI, RE PORT
Ana]-yte
Ars eni cI ronMangane s eZ inc
200.86010c6 010c6 010c
4.2 u50u
5 (51
10 u
4.2 u50u
562
0.0c0. 0?
+/- o.2+/- 50+/- 20%
+/- t0
LL
Reported in pg/t*-Controf Limit Not MetL-RPD Invalld, Limil = Detection Limit
FORM-VT
rrsbflsr!@!NCORFORATED
INORGANICS A}iTAIYSTS DATA SHEETDISSOLVED METAISPage L of 1
Lab Sample ID: AIX1DLrMS ID: 15-12265Matrix: WaterData Release Authori zed:Reported: a] /L6/15
SamP].e ID: t'fl-11MATRIX SPIKE
QC Report Nor Alxl-Parametrix, Inc.Proj ect: Mason County Landfill
555L682a 42Date Samp.le d: 01 / a8 / 15
Date Received: O'7 /A8/15
!.4ATRIX SPIKE OUATITY CONTROL REPORT
Analysis Spike *Anal-yte Method Sanple Spike Added Recovery O
Arsenic 2A0,8 4.2 u 21 .250 u 2tAl06 010c
60l_0c56L
LO U
1,030500
2,400500qan
L09Z104 ?
93. B?
100%
T ronManoanese 6 0l0CZinc
Reported in p,q /L
N-Control Limit Not MetH-% Recovery Not Applicable, Sample Concentration Too HighNA-Not Applicable, Analyte Not SpikedNR-Not Recovered
Percent Recovery Limits z '75-1,25%
FORM-\/
,i:*( i jg "5 i E!a; 4:f5 tii! c' !+'E
ArssHSr!@!NCORPORATED
INORGA}ITCS AI{AIYSIS DATA SHEEEDTSSOL\IED METAI.Sna^^ 1 ^f 1r ovE
Lab Samp1e ID: AIX1ELIMS ID: t5-t2266Matrix: WaterData Refease Authorized:Reported: O-t 116 / 15
SaupJ"e ID: CuJ-verBAI{PIE
QC Report No: AIXl-Parametrix, Inc.Proj ect: Mason County Landfil-l
555t682A 42Date Sampled: O1 /a8/\5
Date Recelvedt 01 /a8/L5
Plep Prep Analysis AnalysisMeth Date Method Date CAS Nunber Anal-yte LoQ lrS/L O
2AA.8 o1 /La/15 20A.8 01 /73/L5 '7440-38-2 Arsenic6010C 01 /la/15 6010C 01 /15/15 1439-89-6 lron60I0C 0'7 /L0/15 6010C 07 /15/t5 1439-96-5 Manganese6010C 01 /LO/L5 6010C 01 /75/t5 1440-66-6 Zj-r:c
U-Anafyte undetected at given LOQLOQ-Limit of Quantitation
o.250
L
10
o.2 u50 u1U
20
E'ORM-I
fiIsb#:*@INCORPORATED
INORGANICS ANAI.,,YS I S DATADISSOI,VED METALSrdge r ()! r
Lab Sample ID: AIX1MBLIMS ID: L5-L2266Matrix: WaterData Release Authorized:Reported: A'1 /tC /15
Sample ID: METHOD BI.ANK
QC Report No: AfXl-Parametrix, fnc.Proj ect: Mason County Landfill
555L682042Date Samp.l-ed: NA
Date Received: NA
SHEET
tuPreptleth
PrepDate
Analyais i{nalysisMethod Date CAS Nunber Analyte I.,OQ t:.s/L
2AA .86 010c6 010c6010c
a.250
1
10
4.250
1
10
01 /r0/1501 /La/1501 /La/ls0'7 /10/t5
200.8 07 /13/156010c a1 /L5/T56010c a7 /L5/L56010c 07 /15/15
'7 444-38-21439-89-61439-96-57 A40-66-6
ArsenicI ronMangane s eZj-nc
U
U
U
U
U-Analyte undetected at given LOQLOQ-Limit of Quantitation
FORM-I
ili;B d !{'t :: ni=4fl4 tr .t:d'
arss[#r!@INCORPORATED
TNORGATiII C S ATiIALYS IS DATADTSSOI,VED METAISPage 1 of 1
Lab Sample ID: AIX1LCSLIMS ID: 1-5-12266Matrix: WaterData Release Authorized:Reported: 01 /16/1,5
Analyte
SHEET
Anal-ysisMethod
Sp5.keFound
SpikeAdded
tRecov€ry
saEple rD3 LAB CoNTRoL
Report No: ATxl-Parametrixf Inc.Project: Mason County Landfill
555L682A 42Date Sampfed: NA
Date Received: NA
BI,A}IK SPIKE OUAII TY CONTROL REPORT
ArsenicI ronMangane s eZinc
Reported i. t-.9 / t
N-Control limitControl- Limits:
200. B
6010c6010c6010C
28.82100
498510
25 .02000
500500
1058qo Aq
to2z
not met80-1242
EORM-VII
€a: 5 iI.: .g ' gjm P,.4q?_E r+ -.r.rq
Appendix D Laboratory Results for Well MW‐6
City o
f S
helton W
WT
PP
roje
ct
Nam
e:
Spra
y F
ield
Annual/Q
rtly
1000 W
est
Pin
e S
treet
Pro
ject
No.:
n/a
Shelton,
WA
98584
P.O
. N
o.:
n/a
Date
Colle
cte
d:
3/1
1/2
014;
08:0
0
Sam
ple
d B
y:
John O
zga
Date
Receiv
ed:
3/1
1/2
014;
13:0
5
Te
mpera
ture
Receiv
ed (
°C):
8 t
o 9
DA
L P
roje
ct
No
.: 1
40311-0
7R
eport
Date
: 3/2
8/2
014
Data
Revie
wed b
y:
Pre
para
tio
n M
eth
od:
US
EP
A 3
010A
Units:
ug/L
Analy
tical M
eth
od:
US
EP
A 2
00.8
Matr
ix:
Non-P
ota
ble
Wate
r
Date
Pre
pare
d:
3/1
8/2
014
Report
ing L
imits:
Sta
ndard
Date
Analy
zed:
3/1
9/2
014
Instr
um
ent
ID:
Agile
nt
7500
Analy
st:
TM
Lab D
ata
File
:14C
19l0
0
Analy
teC
AS
No.
MR
L
Meth
od
Bla
nk
WC
C-1
WC
C-2
MW
-6M
W-9
Ars
enic
(A
s)
7440-3
8-2
5.0
nd
nd
nd
nd
nd
Cadm
ium
(C
d)
7440-4
3-9
5.0
nd
nd
nd
nd
nd
Calc
ium
(C
a)
7440-7
0-2
500
nd
5,3
20
9,8
00
5,4
30
4,0
10
Chro
miu
m (
Cr)
7440-4
7-3
5.0
nd
nd
nd
nd
nd
Copper
(Cu)
7440-5
0-8
5.0
nd
nd
nd
nd
nd
Lead (
Pb)
7439-9
2-1
1.0
nd
1.1
8nd
1.3
7nd
Magnesiu
m (
Mg)
7439-9
5-4
250
nd
1,6
90
3,4
70
1,7
80
1,5
90
Manganese (
Mn)
7439-9
6-5
5.0
nd
30.2
nd
nd
12.0
Merc
ury
(H
g)
7439-9
7-6
1.0
nd
nd
nd
nd
nd
Nic
kel (N
i)7440-0
2-0
5.0
nd
nd
nd
nd
nd
Pota
ssiu
m (
K)
7440-0
9-7
1000
nd
nd
nd
nd
nd
Silv
er
(Ag)
7440-2
2-4
10.0
nd
nd
nd
nd
nd
Sodiu
m (
Na)
7440-2
3-5
1000
nd
2,4
50
8,6
40
2,1
60
2,6
50
Zin
c (
Zn
)7440-6
6-6
10.0
1.2
010.2
nd
nd
12.1
Dilu
tio
n F
acto
r1.0
10
10
10
10
TO
TA
L H
EA
VY
ME
TA
LS
AN
AL
YT
ICA
L R
ES
UL
TS
page 1
of
2
City o
f S
helton W
WT
PP
roje
ct
Nam
e:
Spra
y F
ield
Annual/Q
rtly
DA
L P
roje
ct
No
.: 1
40311-0
7P
roje
ct
No.:
n/a
Analy
te
MS
/MS
D
Level (u
g/L
)
Sam
ple
Conc.
(ug/L
)
MS
Recovery
(ug/L
)
MS
Perc
ent
Recovery
MS
D
Recovery
(ug/L
)
MS
D
Perc
ent
Recovery
MS
/MS
D
Lim
its
(%)
RP
D
MS
/MS
D
RP
D
Lim
its
LC
S
Level
(ug/L
)
LC
S
Recovery
(ug/L
)
LC
S
Perc
ent
Recovery
LC
S
Lim
its
(%)
Ars
enic
(A
s)
50
0.7
60
47.1
92.7
%46.2
90.9
%80-1
20
1.0
0≤ 2
0%
50
48.4
96.8
%80-1
20
Cadm
ium
(C
d)
50
0.0
20
48.8
97.5
%51.3
103%
80-1
20
2.5
3≤ 2
0%
50
51.7
103%
80-1
20
Calc
ium
(C
a)
5000
12680
18150
109%
15780
62.0
%80-1
20
27.7
≤ 2
0%
5000
4894
97.9
%80-1
20
Chro
miu
m (
Cr)
50
1.0
051.2
100%
48.0
93.9
%80-1
20
3.2
8≤ 2
0%
50
48.6
97.1
%80-1
20
Copper
(Cu)
50
7.7
956.9
98.2
%53.3
91.0
%80-1
20
3.8
1≤ 2
0%
50
49.0
98.0
%80-1
20
Lead (
Pb)
50
0.5
30
44.0
87.0
%51.0
101%
80-1
20
7.4
2≤ 2
0%
50
50.4
101%
80-1
20
Magnesiu
m (
Mg)
5000
3461
8556
102%
7926
89.3
%80-1
20
6.5
9≤ 2
0%
5000
4989
99.8
%80-1
20
Manganese (
Mn)
50
285
350
130%
329
87.6
%80-1
20
19.6
≤ 2
0%
50
49.6
99.2
%80-1
20
Merc
ury
(H
g)
2.5
0.0
10
2.3
894.8
%2.7
9111%
80-1
20
7.9
6≤ 2
0%
2.0
2.0
7104%
80-1
20
Nic
kel (N
i)50
2.1
451.0
97.7
%48.2
92.1
%80-1
20
2.9
1≤ 2
0%
50
47.7
95.4
%80-1
20
Pota
ssiu
m (
K)
5000
5332
8320
59.8
%7794
49.2
%80-1
20
9.6
5≤ 2
0%
5000
5449
109%
80-1
20
Silv
er
(Ag)
50
0.0
80
47.6
95.1
%50.2
100%
80-1
20
2.6
2≤ 2
0%
50
51.3
103%
80-1
20
Sodiu
m (
Na)
5000
12760
18490
115%
17250
89.8
%80-1
20
12.1
≤ 2
0%
5000
5062
101%
80-1
20
Zin
c (
Zn
)50
21.4
68.9
95.1
%66.7
90.8
%80-1
20
2.3
4≤ 2
0%
50
51.0
102%
80-1
20
WA
-DO
E-L
abora
tory
Cert
ific
atio
n N
o.:
C890
"nd"
indic
ate
s t
he a
naly
te w
as n
ot
dete
cte
d a
t or
above t
he lis
ted M
eth
od R
eport
ing L
imit.
n/a
in
dic
ate
s n
ot
applic
able
TO
TA
L H
EA
VY
ME
TA
LS
QC
Batc
h I
D:
140319-M
eta
lsLC
S S
am
ple
ID
: 140319-M
eta
ls L
CS
QU
AL
ITY
CO
NT
RO
L R
ES
UL
TS
page 2
of
2
Com
ments
and E
xpla
natio
ns:
None.
LA
BO
RA
TO
RY
CO
NT
RO
L S
AM
PLE
AN
D M
AT
RIX
SP
IKE
MS
/MS
D S
am
ple
ID
: 140319-M
eta
ls M
S/M
SD
City o
f S
helton W
WT
PP
roje
ct
Nam
e:
Spra
y F
ield
Annual/Q
rtly
1000 W
est
Pin
e S
treet
Pro
ject
No.:
n/a
Shelton,
WA
98584
P.O
. N
o.:
n/a
Matr
ix:
Non-P
ota
ble
Wate
r
Sam
ple
d b
y:
John O
zga
Te
mpera
ture
Receiv
ed (
°C):
8 t
o 9
DA
L P
roje
ct
No
.: 1
40311-0
7R
eport
Date
: 3/2
8/2
014
SA
MP
LE
NA
ME
RE
SU
LT
S
SA
MP
LE
VO
LU
ME
(mL
)
FIL
TE
R
CO
UN
TM
RL
UN
ITS
ME
TH
OD
AN
AL
YS
IS
DA
TE
AN
AL
YS
TD
AT
A
FL
AG
S
WC
C-1
3100
3<
1C
FU
/100 m
LS
M 9
222 B
2,5
,63/1
1/2
014;
08:0
03/1
1/2
014;
13:0
53/1
1/2
014;
15:1
33/1
2/2
014
BW
J
WC
C-2
1100
1<
1C
FU
/100 m
LS
M 9
222 B
2,5
,63/1
1/2
014;
08:1
03/1
1/2
014;
13:0
53/1
1/2
014;
15:1
53/1
2/2
014
BW
J
MW
-6<
1100
0<
1C
FU
/100 m
LS
M 9
222 B
2,5
,63/1
1/2
014;
08:3
03/1
1/2
014;
13:0
53/1
1/2
014;
15:1
83/1
2/2
014
BW
J
MW
-9<
1100
0<
1C
FU
/100 m
LS
M 9
222 B
2,5
,63/1
1/2
014;
08:4
53/1
1/2
014;
13:0
53/1
1/2
014;
15:1
93/1
2/2
014
BW
J
SA
MP
LE
NA
ME
RE
SU
LT
S
SA
MP
LE
VO
LU
ME
(mL
)
FIL
TE
R
CO
UN
TM
RL
UN
ITS
ME
TH
OD
AN
AL
YS
IS
DA
TE
AN
AL
YS
TD
AT
A
FL
AG
S
Meth
od B
lank -
Open
<1
100
0<
1C
FU
/100 m
LS
M 9
222 B
2,5
,63/1
2/2
014
BW
Meth
od B
lank -
Clo
se
<1
100
0<
1C
FU
/100 m
LS
M 9
222 B
2,5
,63/1
2/2
014
BW
Fe
cal and/o
r T
ota
l C
olif
orm
s m
ust
be d
eliv
ere
d t
o t
he la
bora
tory
within
6 h
ours
of
sam
ple
colle
ctio
n.
Sam
ple
s m
ust
be f
iltere
d b
y t
he la
bora
tory
within
2 h
ours
of
recie
pt.
WA
-DO
E-L
abora
tory
Cert
ific
atio
n N
o.:
C890
"MR
L"
indic
ate
s M
eth
od R
eport
ing L
imit
Com
ments
and E
xpla
natio
ns:
A "
J"
fla
g in
dic
ate
s a
n e
stim
ate
d v
alu
e b
ecause t
he c
olo
ny c
ount
was o
uts
ide t
he o
ptim
um
range o
f colo
nie
s p
er
filter.
Data
revie
wed b
y:
TO
TA
L C
OL
IFO
RM
S A
NA
LY
TIC
AL
RE
SU
LT
S
page 1
of
1
CO
LIF
OR
M Q
UA
LIT
Y C
ON
TR
OL
R
ES
UL
TS
Meth
od
B
lan
k
DA
TE
/TIM
E
SA
MP
LE
FIL
TE
RE
D
DA
TE
/TIM
E
SA
MP
LE
RE
CE
IVE
D
DA
TE
/TIM
E
SA
MP
LE
CO
LL
EC
TE
D
City o
f S
helton W
WT
PP
roje
ct
Nam
e:
Spra
y F
ield
Annual/Q
rtly
1000 W
est
Pin
e S
treet
Pro
ject
No.:
n/a
Shelton,
WA
98584
P.O
. N
o.:
n/a
Sam
ple
Nam
e:
WC
C-1
Sam
ple
d b
y:
John O
zga
Matr
ix:
Non-P
ota
ble
Wate
r
Te
mpera
ture
Receiv
ed (
°C):
8 t
o 9
Colle
cte
d:
3/1
1/2
014;
08:0
0
Receiv
ed:
3/1
1/2
014;
13:0
5
DA
L P
roje
ct
No
.: 1
40311-0
7R
eport
Date
: 3/2
8/2
014
Alk
alin
ity (
CaC
O3)
20.8
n/a
5.0
mg/L
SM
2320 B
1
3/2
4/2
014
3/2
4/2
014
n/a
CH
BiC
arb
onate
20.8
n/a
1.0
mg/L
SM
2320
13/2
4/2
014
3/2
4/2
014
n/a
CH
Carb
onate
nd
n/a
3.0
mg/L
SM
2320
13/2
4/2
014
3/2
4/2
014
n/a
CH
Chlo
rid
e1.7
90.0
22
0.1
0m
g/L
EP
A 3
00.0
13/1
2/2
014
3/1
2/2
014
n/a
FW
Flu
orid
e0.0
40.0
37
0.1
0m
g/L
EP
A 3
00.0
13/1
2/2
014
3/1
2/2
014
n/a
FW
J
Nitro
gen,
Nitra
te
0.0
40.0
26
0.1
0m
g/L
EP
A 3
00.0
13/1
2/2
014
3/1
2/2
014
n/a
FW
J
Nitro
gen,
Nitrite
nd
0.0
34
0.1
0m
g/L
EP
A 3
00.0
13/1
2/2
014
3/1
2/2
014
n/a
FW
Nitro
gen,
(TK
N)
0.6
0.3
62.0
mg/L
SM
4500-N
org
B1
3/2
1/2
014
3/2
1/2
014
n/a
RP
J
pH
6.3
6n/a
n/a
SU
SM
4500-H
+1
3/1
1/2
014
3/1
1/2
014
14:3
2R
P(1
)
Specific
Conducta
nce
57.6
n/a
10.0
um
ho/c
mS
M 2
510 B
13/1
4/2
014
3/1
4/2
014
n/a
GD
Solid
s,
To
tal D
issolv
ed
54.0
n/a
20.0
mg/L
SM
2540 C
13/1
2/2
014
3/1
2/2
014
n/a
BW
Sulfate
1.1
30.0
15
0.1
0m
g/L
EP
A 3
00.0
13/1
2/2
014
3/1
2/2
014
n/a
FW
WA
-DO
E-L
abora
tory
Cert
ific
atio
n N
o.:
C890
"MD
L"
indic
ate
s M
eth
od D
ete
ctio
n L
imit
"MR
L"
indic
ate
s M
eth
od R
eport
ing L
imit
"DF
" in
dic
ate
s D
ilutio
n F
acto
r
"nd"
indic
ate
s t
he a
naly
te w
as n
ot
dete
cte
d a
t or
above t
he lis
ted M
eth
od R
eport
ing L
imit.
"n/a
" in
dic
ate
s n
ot
applic
able
Data
revie
wed b
y:
Report
Pre
pare
d B
y:
FW
AN
AL
YS
TD
AT
A
FL
AG
SU
NIT
SM
ET
HO
DD
FP
RE
PA
RA
TIO
N
DA
TE
AN
AL
YS
IS
DA
TE
AN
AL
YS
IS
TIM
E
AN
AL
YT
ICA
L R
ES
UL
TS
page 1
of
8
PA
RA
ME
TE
RR
ES
UL
TS
MD
LM
RL
Com
ments
and E
xpla
natio
ns:
A "
J"
fla
g in
dic
ate
s a
n e
stim
ate
d v
alu
e t
hat
is g
reate
r th
an t
he M
DL b
ut
less t
han t
he M
RL.
A (
1)
fla
g I
ndic
ate
s a
n e
stim
ate
d v
alu
e,
because t
he s
am
ple
was r
eceiv
ed a
nd
there
fore
analy
zed o
uts
ide o
f th
e r
ecom
mended a
nd r
egula
tory
hold
tim
e o
f 15 m
inute
s.
City o
f S
helton W
WT
PP
roje
ct
Nam
e:
Spra
y F
ield
Annual/Q
rtly
1000 W
est
Pin
e S
treet
Pro
ject
No.:
n/a
Shelton,
WA
98584
P.O
. N
o.:
n/a
Sam
ple
Nam
e:
WC
C-2
Sam
ple
d b
y:
John O
zga
Matr
ix:
Non-P
ota
ble
Wate
r
Te
mpera
ture
Receiv
ed (
°C):
8 t
o 9
Colle
cte
d:
3/1
1/2
014;
08:1
0
Receiv
ed:
3/1
1/2
014;
13:0
5
DA
L P
roje
ct
No
.: 1
40311-0
7R
eport
Date
: 3/2
8/2
014
Alk
alin
ity (
CaC
O3)
32.4
n/a
5.0
mg/L
SM
2320 B
1
3/2
4/2
014
3/2
4/2
014
n/a
CH
BiC
arb
onate
32.4
n/a
1.0
mg/L
SM
2320
13/2
4/2
014
3/2
4/2
014
n/a
CH
Carb
onate
nd
n/a
3.0
mg/L
SM
2320
13/2
4/2
014
3/2
4/2
014
n/a
CH
Chlo
rid
e14.2
0.0
22
0.1
0m
g/L
EP
A 3
00.0
13/1
2/2
014
3/1
2/2
014
n/a
FW
Flu
orid
e0.0
40.0
37
0.1
0m
g/L
EP
A 3
00.0
13/1
2/2
014
3/1
2/2
014
n/a
FW
J
Nitro
gen,
Nitra
te
0.6
90.0
26
0.1
0m
g/L
EP
A 3
00.0
13/1
2/2
014
3/1
2/2
014
n/a
FW
Nitro
gen,
Nitrite
nd
0.0
34
0.1
0m
g/L
EP
A 3
00.0
13/1
2/2
014
3/1
2/2
014
n/a
FW
Nitro
gen,
(TK
N)
1.1
0.3
62.0
mg/L
SM
4500-N
org
B1
3/2
1/2
014
3/2
1/2
014
n/a
RP
J
pH
6.5
1n/a
n/a
SU
SM
4500-H
+1
3/1
1/2
014
3/1
1/2
014
14:3
3R
P(1
)
Specific
Conducta
nce
134
n/a
10.0
um
ho/c
mS
M 2
510 B
13/1
4/2
014
3/1
4/2
014
n/a
GD
Solid
s,
To
tal D
issolv
ed
122
n/a
20.0
mg/L
SM
2540 C
13/1
2/2
014
3/1
2/2
014
n/a
BW
Sulfate
5.0
00.0
15
0.1
0m
g/L
EP
A 3
00.0
13/1
2/2
014
3/1
2/2
014
n/a
FW
WA
-DO
E-L
abora
tory
Cert
ific
atio
n N
o.:
C890
"MD
L"
indic
ate
s M
eth
od D
ete
ctio
n L
imit
"MR
L"
indic
ate
s M
eth
od R
eport
ing L
imit
"DF
" in
dic
ate
s D
ilutio
n F
acto
r
"nd"
indic
ate
s t
he a
naly
te w
as n
ot
dete
cte
d a
t or
above t
he lis
ted M
eth
od R
eport
ing L
imit.
"n/a
" in
dic
ate
s n
ot
applic
able
Data
revie
wed b
y:
Report
Pre
pare
d B
y:
FW
AN
AL
YS
IS
TIM
E
DA
TA
FL
AG
SP
AR
AM
ET
ER
RE
SU
LT
SM
DL
MR
LU
NIT
SM
ET
HO
DD
FP
RE
PA
RA
TIO
N
DA
TE
AN
AL
YT
ICA
L R
ES
UL
TS
page 2
of
8
Com
ments
and E
xpla
natio
ns:
A "
J"
fla
g in
dic
ate
s a
n e
stim
ate
d v
alu
e t
hat
is g
reate
r th
an t
he M
DL b
ut
less t
han t
he M
RL.
A (
1)
fla
g I
ndic
ate
s a
n e
stim
ate
d v
alu
e,
because t
he s
am
ple
was r
eceiv
ed a
nd
there
fore
analy
zed o
uts
ide o
f th
e r
ecom
mended a
nd r
egula
tory
hold
tim
e o
f 15 m
inute
s.
AN
AL
YS
IS
DA
TE
AN
AL
YS
T
City o
f S
helton W
WT
PP
roje
ct
Nam
e:
Spra
y F
ield
Annual/Q
rtly
1000 W
est
Pin
e S
treet
Pro
ject
No.:
n/a
Shelton,
WA
98584
P.O
. N
o.:
n/a
Sam
ple
Nam
e:
MW
-6
Sam
ple
d b
y:
John O
zga
Matr
ix:
Non-P
ota
ble
Wate
r
Te
mpera
ture
Receiv
ed (
°C):
8 t
o 9
Colle
cte
d:
3/1
1/2
014;
08:3
0
Receiv
ed:
3/1
1/2
014;
13:0
5
DA
L P
roje
ct
No
.: 1
40311-0
7R
eport
Date
: 3/2
8/2
014
Alk
alin
ity (
CaC
O3)
17.6
n/a
5.0
mg/L
SM
2320 B
1
3/2
4/2
014
3/2
4/2
014
n/a
CH
BiC
arb
onate
17.6
n/a
1.0
mg/L
SM
2320
13/2
4/2
014
3/2
4/2
014
n/a
CH
Carb
onate
nd
n/a
3.0
mg/L
SM
2320
13/2
4/2
014
3/2
4/2
014
n/a
CH
Chlo
rid
e2.1
10.0
22
0.1
0m
g/L
EP
A 3
00.0
13/1
2/2
014
3/1
2/2
014
n/a
FW
Flu
orid
e0.0
30.0
37
0.1
0m
g/L
EP
A 3
00.0
13/1
2/2
014
3/1
2/2
014
n/a
FW
J
Nitro
gen,
Nitra
te
0.0
70.0
26
0.1
0m
g/L
EP
A 3
00.0
13/1
2/2
014
3/1
2/2
014
n/a
FW
J
Nitro
gen,
Nitrite
nd
0.0
34
0.1
0m
g/L
EP
A 3
00.0
13/1
2/2
014
3/1
2/2
014
n/a
FW
Nitro
gen,
(TK
N)
1.1
0.3
62.0
mg/L
SM
4500-N
org
B1
3/2
1/2
014
3/2
1/2
014
n/a
RP
J
pH
6.3
1n/a
n/a
SU
SM
4500-H
+1
3/1
1/2
014
3/1
1/2
014
14:3
4R
P(1
)
Specific
Conducta
nce
54.8
n/a
10.0
um
ho/c
mS
M 2
510 B
13/1
4/2
014
3/1
4/2
014
n/a
GD
Solid
s,
To
tal D
issolv
ed
nd
n/a
20.0
mg/L
SM
2540 C
13/1
2/2
014
3/1
2/2
014
n/a
BW
Sulfate
1.1
70.0
15
0.1
0m
g/L
EP
A 3
00.0
13/1
2/2
014
3/1
2/2
014
n/a
FW
WA
-DO
E-L
abora
tory
Cert
ific
atio
n N
o.:
C890
"MD
L"
indic
ate
s M
eth
od D
ete
ctio
n L
imit
"MR
L"
indic
ate
s M
eth
od R
eport
ing L
imit
"DF
" in
dic
ate
s D
ilutio
n F
acto
r
"nd"
indic
ate
s t
he a
naly
te w
as n
ot
dete
cte
d a
t or
above t
he lis
ted M
eth
od R
eport
ing L
imit.
"n/a
" in
dic
ate
s n
ot
applic
able
Data
revie
wed b
y:
Report
Pre
pare
d B
y:
FW
PR
EP
AR
AT
ION
DA
TE
AN
AL
YS
IS
DA
TE
AN
AL
YS
IS
TIM
EA
NA
LY
ST
DA
TA
FL
AG
S
page 3
of
8
PA
RA
ME
TE
RR
ES
UL
TS
MD
LM
RL
UN
ITS
ME
TH
OD
DF
AN
AL
YT
ICA
L R
ES
UL
TS
Com
ments
and E
xpla
natio
ns:
A "
J"
fla
g in
dic
ate
s a
n e
stim
ate
d v
alu
e t
hat
is g
reate
r th
an t
he M
DL b
ut
less t
han t
he M
RL.
A (
1)
fla
g I
ndic
ate
s a
n e
stim
ate
d v
alu
e,
because t
he s
am
ple
was r
eceiv
ed a
nd
there
fore
analy
zed o
uts
ide o
f th
e r
ecom
mended a
nd r
egula
tory
hold
tim
e o
f 15 m
inute
s.
City o
f S
helton W
WT
PP
roje
ct
Nam
e:
Spra
y F
ield
Annual/Q
rtly
1000 W
est
Pin
e S
treet
Pro
ject
No.:
n/a
Shelton,
WA
98584
P.O
. N
o.:
n/a
Sam
ple
Nam
e:
MW
-9
Sam
ple
d b
y:
John O
zga
Matr
ix:
Non-P
ota
ble
Wate
r
Te
mpera
ture
Receiv
ed (
°C):
8 t
o 9
Colle
cte
d:
3/1
1/2
014;
08:4
5
Receiv
ed:
3/1
1/2
014;
13:0
5
DA
L P
roje
ct
No
.: 1
40311-0
7R
eport
Date
: 3/2
8/2
014
Alk
alin
ity (
CaC
O3)
15.6
n/a
5.0
mg/L
SM
2320 B
1
3/2
4/2
014
3/2
4/2
014
n/a
CH
BiC
arb
onate
15.6
n/a
1.0
mg/L
SM
2320
13/2
4/2
014
3/2
4/2
014
n/a
CH
Carb
onate
nd
n/a
3.0
mg/L
SM
2320
13/2
4/2
014
3/2
4/2
014
n/a
CH
Chlo
rid
e2.0
50.0
22
0.1
0m
g/L
EP
A 3
00.0
13/1
2/2
014
3/1
2/2
014
n/a
FW
Flu
orid
e0.0
30.0
37
0.1
0m
g/L
EP
A 3
00.0
13/1
2/2
014
3/1
2/2
014
n/a
FW
J
Nitro
gen,
Nitra
te
0.1
40.0
26
0.1
0m
g/L
EP
A 3
00.0
13/1
2/2
014
3/1
2/2
014
n/a
FW
Nitro
gen,
Nitrite
nd
0.0
34
0.1
0m
g/L
EP
A 3
00.0
13/1
2/2
014
3/1
2/2
014
n/a
FW
Nitro
gen,
(TK
N)
1.4
0.3
62.0
mg/L
SM
4500-N
org
B1
3/2
1/2
014
3/2
1/2
014
n/a
RP
J
pH
6.1
4n/a
n/a
SU
SM
4500-H
+1
3/1
1/2
014
3/1
1/2
014
14:3
5R
P(1
)
Specific
Conducta
nce
51.1
n/a
10.0
um
ho/c
mS
M 2
510 B
13/1
4/2
014
3/1
4/2
014
n/a
GD
Solid
s,
To
tal D
issolv
ed
40.0
n/a
20.0
mg/L
SM
2540 C
13/1
2/2
014
3/1
2/2
014
n/a
BW
Sulfate
1.4
20.0
15
0.1
0m
g/L
EP
A 3
00.0
13/1
2/2
014
3/1
2/2
014
n/a
FW
WA
-DO
E-L
abora
tory
Cert
ific
atio
n N
o.:
C890
"MD
L"
indic
ate
s M
eth
od D
ete
ctio
n L
imit
"MR
L"
indic
ate
s M
eth
od R
eport
ing L
imit
"DF
" in
dic
ate
s D
ilutio
n F
acto
r
"nd"
indic
ate
s t
he a
naly
te w
as n
ot
dete
cte
d a
t or
above t
he lis
ted M
eth
od R
eport
ing L
imit.
"n/a
" in
dic
ate
s n
ot
applic
able
Data
revie
wed b
y:
Report
Pre
pare
d B
y:
FW
AN
AL
YS
TD
AT
A
FL
AG
SM
DL
MR
LU
NIT
SM
ET
HO
DD
FP
RE
PA
RA
TIO
N
DA
TE
AN
AL
YS
IS
DA
TE
AN
AL
YS
IS
TIM
E
page 4
of
8
AN
AL
YT
ICA
L R
ES
UL
TS
PA
RA
ME
TE
RR
ES
UL
TS
Com
ments
and E
xpla
natio
ns:
A "
J"
fla
g in
dic
ate
s a
n e
stim
ate
d v
alu
e t
hat
is g
reate
r th
an t
he M
DL b
ut
less t
han t
he M
RL.
A (
1)
fla
g I
ndic
ate
s a
n e
stim
ate
d v
alu
e,
because t
he s
am
ple
was r
eceiv
ed a
nd
there
fore
analy
zed o
uts
ide o
f th
e r
ecom
mended a
nd r
egula
tory
hold
tim
e o
f 15 m
inute
s.
City o
f S
helton W
WT
PP
roje
ct
Nam
e:
Spra
y F
ield
Annual/Q
rtly
DA
L P
roje
ct
No
.: 1
40311-0
7P
roje
ct
No.:
n/a
140324-A
lkalin
ity (
CaC
O3)
Alk
alin
ity (
CaC
O3)
nd
5.0
mg/L
SM
2320 B
3/2
4/2
014
CH
140324-B
iCarb
BiC
arb
onate
n/a
n/a
mg/L
SM
2320
3/2
4/2
014
CH
140324-C
arb
Carb
onate
n/a
n/a
mg/L
SM
2320
3/2
4/2
014
CH
140312-C
hlo
ride
Chlo
rid
end
0.1
0m
g/L
EP
A 3
00.0
3/1
2/2
014
FW
140312-F
louride
Flu
orid
end
0.1
0m
g/L
EP
A 3
00.0
3/1
2/2
014
FW
140312-N
O
₃
Nitro
gen,
Nitra
te
nd
0.1
0m
g/L
EP
A 3
00.0
3/1
2/2
014
FW
140312-N
O
₂
Nitro
gen,
Nitrite
nd
0.1
0m
g/L
EP
A 3
00.0
3/1
2/2
014
FW
140321-T
KN
Nitro
gen,
(TK
N)
nd
2.0
mg/L
SM
4500-N
org
B3/2
1/2
014
RP
140311-p
HpH
n/a
n/a
SU
SM
4500-H
+n/a
n/a
140314-S
CS
pecific
Conducta
nce
nd
10.0
um
ho/c
mS
M 2
510 B
3/1
4/2
014
GD
140312-T
DS
Solid
s,
To
tal D
issolv
ed
nd
20.0
mg/L
SM
2540 C
3/1
2/2
014
BW
140312-S
ulfate
Sulfate
nd
0.1
0m
g/L
EP
A 3
00.0
3/1
2/2
014
FW
WA
-DO
E-L
abora
tory
Cert
ific
atio
n N
o.:
C890
"MR
L"
indic
ate
s M
eth
od R
eport
ing L
imit
"RP
D"
indic
ate
s R
ela
tive P
erc
ent
Diffe
rence
"nd"
indic
ate
s t
he a
naly
te w
as n
ot
dete
cte
d a
t or
above t
he lis
ted M
eth
od R
eport
ing L
imit.
"n/a
" in
dic
ate
s n
ot
applic
able
Com
ments
and E
xpla
natio
ns:
None
Data
revie
wed b
y:
A
NA
LY
SIS
DA
TE
AN
AL
YS
TD
AT
A
FL
AG
S
page 5
of
8
QU
AL
ITY
C
ON
TR
OL
R
ES
UL
TS
Meth
od
B
lan
k
SA
MP
LE
BA
TC
HP
AR
AM
ET
ER
RE
SU
LT
MR
LU
NIT
SA
NA
LY
TIC
AL
ME
TH
OD
City o
f S
helton W
WT
PP
roje
ct
Nam
e:
Spra
y F
ield
Annual/Q
rtly
DA
L P
roje
ct
No
.: 1
40311-0
7P
roje
ct
No.:
n/a
140324-A
lkalin
ity (
CaC
O3)
Alk
alin
ity (
CaC
O3)
20.8
20.4
mg/L
SM
2320 B
1.9
4±35
3/2
4/2
014
CH
140324-B
iCarb
BiC
arb
onate
20.8
20.4
mg/L
SM
2321
1.9
4±35
3/2
4/2
014
CH
140324-C
arb
Carb
onate
nd
nd
mg/L
SM
2320
0.0
0±35
3/2
4/2
014
CH
140312-C
hlo
ride
Chlo
rid
e0.7
66
0.7
65
mg/L
EP
A 3
00.0
0.1
31
±35
3/1
2/2
014
FW
140312-F
louride
Flu
orid
e0.0
44
0.0
48
mg/L
EP
A 3
00.0
8.7
0±35
3/1
2/2
014
FW
140312-N
O
₃
Nitro
gen,
Nitra
te
0.0
87
0.0
83
mg/L
EP
A 3
00.0
4.7
1±35
3/1
2/2
014
FW
140312-N
O
₂
Nitro
gen,
Nitrite
0.0
08
0.0
1m
g/L
EP
A 3
00.0
22.2
±35
3/1
2/2
014
FW
140321-T
KN
Nitro
gen,
(TK
N)
nd
nd
mg/L
SM
4500-N
org
B0.0
0±35
3/2
1/2
014
RP
140311-p
HpH
n/a
n/a
SU
SM
4500-H
+n/a
n/a
n/a
n/a
140314-S
CS
pecific
Conducta
nce
184
194
um
ho/c
mS
M 2
510 B
5.4
5±35
3/1
4/2
014
GD
140312-T
DS
Solid
s,
To
tal D
issolv
ed
258
246
mg/L
SM
2540 C
4.7
6±35
3/1
2/2
014
BW
140312-S
ulfate
Sulfate
0.7
25
0.7
52
mg/L
EP
A 3
00.0
3.6
6±35
3/1
2/2
014
FW
WA
-DO
E-L
abora
tory
Cert
ific
atio
n N
o.:
C890
"MR
L"
indic
ate
s M
eth
od R
eport
ing L
imit
"RP
D"
indic
ate
s R
ela
tive P
erc
ent
Diffe
rence
"nd"
indic
ate
s t
he a
naly
te w
as n
ot
dete
cte
d a
t or
above t
he lis
ted M
eth
od R
eport
ing L
imit.
"n/a
" in
dic
ate
s n
ot
applic
able
Data
revie
wed b
y:
AN
AL
YS
IS
DA
TE
AN
AL
YS
TD
AT
A
FL
AG
SS
AM
PL
E B
AT
CH
PA
RA
ME
TE
RR
ES
UL
TD
UP
.
RE
SU
LT
UN
ITS
AN
AL
YT
ICA
L
ME
TH
OD
RP
D
(%)
LIM
ITS
(%)
Com
ments
and E
xpla
natio
ns:
None
page 6
of
8
QU
AL
ITY
C
ON
TR
OL
R
ES
UL
TS
Du
plicate
Sam
ple
City o
f S
helton W
WT
PP
roje
ct
Nam
e:
Spra
y F
ield
Annual/Q
rtly
DA
L P
roje
ct
No
.: 1
40311-0
7P
roje
ct
No.:
n/a
140324-A
lkalin
ity (
CaC
O3)
Alk
alin
ity (
CaC
O3)
n/a
n/a
mg/L
SM
2320 B
n/a
n/a
n/a
n/a
140324-B
iCarb
BiC
arb
onate
n/a
40
mg/L
SM
2320
n/a
n/a
n/a
n/a
140324-C
arb
Carb
onate
n/a
n/a
mg/L
SM
2320
n/a
n/a
n/a
n/a
140312-C
hlo
ride
Chlo
rid
e0.5
40
0.5
mg/L
EP
A 3
00.0
108
65.0
-135
3/1
2/2
014
FW
140312-F
louride
Flu
orid
e0.5
35
0.5
mg/L
EP
A 3
00.0
107
65.0
-135
3/1
2/2
014
FW
140312-N
O
₃
Nitro
gen,
Nitra
te
0.5
16
0.5
mg/L
EP
A 3
00.0
103
65.0
-135
3/1
2/2
014
FW
140312-N
O
₂
Nitro
gen,
Nitrite
0.5
55
0.5
mg/L
EP
A 3
00.0
111
65.0
-135
3/1
2/2
014
FW
140321-T
KN
Nitro
gen,
(TK
N)
21.6
20.0
mg/L
SM
4500-N
org
B108
65.0
-135
3/2
1/2
014
RP
140311-p
HpH
6.9
97.0
SU
SM
4500-H
+99.9
65.0
-135
3/1
1/2
014
RP
140314-S
CS
pecific
Conducta
nce
1434
1415
um
ho/c
mS
M 2
510 B
101
65.0
-135
3/1
4/2
014
GD
140312-T
DS
Solid
s,
To
tal D
issolv
ed
498
500
mg/L
SM
2540 C
99.6
65.0
-135
3/1
2/2
014
n/a
140312-S
ulfate
Sulfate
0.5
72
0.5
mg/L
EP
A 3
00.0
114
65.0
-135
3/1
2/2
014
FW
WA
-DO
E-L
abora
tory
Cert
ific
atio
n N
o.:
C890
"RP
D"
indic
ate
s R
ela
tive P
erc
ent
Diffe
rence
"nd"
indic
ate
s t
he a
naly
te w
as n
ot
dete
cte
d a
t or
above t
he lis
ted M
eth
od R
eport
ing L
imit.
"n/a
" in
dic
ate
s n
ot
applic
able
Com
ments
and E
xpla
natio
ns:
None
Data
revie
wed b
y:
AN
AL
YS
TT
RU
E
VA
LU
E
AN
AL
YT
ICA
L
ME
TH
OD
RE
CO
VE
RY
(%)
LIM
ITS
(%)
AN
AL
YS
IS
DA
TE
UN
ITS
DA
TA
FL
AG
S
page 7
of
8
QU
AL
ITY
CO
NT
RO
L R
ES
UL
TS
Lab
ora
tory
Fo
rtif
ied
Bla
nk
SA
MP
LE
BA
TC
HP
AR
AM
ET
ER
LF
B
RE
SU
LT
City o
f S
helton W
WT
PP
roje
ct
Nam
e:
Spra
y F
ield
Annual/Q
rtly
DA
L P
roje
ct
No
.: 1
40311-0
7P
roje
ct
No.:
n/a
140324-A
lkalin
ity (
CaC
O3)
Alk
alin
ity (
CaC
O3)
n/a
n/a
n/a
mg/L
SM
2320 B
n/a
n/a
n/a
n/a
140324-B
iCarb
BiC
arb
onate
n/a
n/a
n/a
mg/L
SM
2320
n/a
n/a
n/a
n/a
140324-C
arb
Carb
onate
n/a
n/a
n/a
mg/L
SM
2320
n/a
n/a
n/a
n/a
140312-C
hlo
ride
Chlo
rid
e0.5
94
0.5
86
0.5
mg/L
EP
A 3
00.0
0.9
02
±35
3/1
2/2
014
FW
140312-F
louride
Flu
orid
e0.5
62
0.5
83
0.5
mg/L
EP
A 3
00.0
2.4
6±35
3/1
2/2
014
FW
140312-N
O
₃
Nitro
gen,
Nitra
te
0.5
43
0.5
63
0.5
mg/L
EP
A 3
00.0
2.4
3±35
3/1
2/2
014
FW
140312-N
O
₂
Nitro
gen,
Nitrite
0.4
99
0.4
98
0.5
mg/L
EP
A 3
00.0
0.1
34
±35
3/1
2/2
014
FW
140321-T
KN
Nitro
gen,
(TK
N)
20.4
21.3
20.0
mg/L
SM
4500-N
org
B2.7
0±35
3/2
1/2
014
RP
140311-p
HpH
n/a
n/a
n/a
SU
SM
4500-H
+n/a
n/a
n/a
n/a
140314-S
CS
pecific
Conducta
nce
n/a
n/a
n/a
um
ho/c
mS
M 2
510 B
n/a
n/a
n/a
n/a
140312-T
DS
Solid
s,
To
tal D
issolv
ed
n/a
n/a
n/a
mg/L
SM
2540 C
n/a
n/a
n/a
n/a
140312-S
ulfate
Sulfate
0.8
75
0.9
13
0.5
mg/L
EP
A 3
00.0
2.8
5±35
3/1
2/2
014
FW
WA
-DO
E-L
abora
tory
Cert
ific
atio
n N
o.:
C890
"RP
D"
indic
ate
s R
ela
tive P
erc
ent
Diffe
rence
"nd"
indic
ate
s t
he a
naly
te w
as n
ot
dete
cte
d a
t or
above t
he lis
ted M
eth
od R
eport
ing L
imit.
"n/a
" in
dic
ate
s n
ot
applic
able
Com
ments
and E
xpla
natio
ns:
None
Data
revie
wed b
y:
AN
AL
YS
IS
DA
TE
AN
AL
YS
TS
AM
PL
E B
AT
CH
PA
RA
ME
TE
RM
S R
ES
UL
TM
SD
RE
SU
LT
TR
UE
VA
LU
E
DA
TA
FL
AG
SU
NIT
SA
NA
LY
TIC
AL
ME
TH
OD
RP
D
(%)
LIM
ITS
(%)
QU
AL
ITY
CO
NT
RO
L R
ES
UL
TS
Matr
ix S
pik
e/M
atr
ix S
pik
e D
up
licate
page 8
of
8
City o
f S
helton W
WT
PP
roje
ct
Nam
e:
Spra
y F
ield
Annual/Q
rtly
1000 W
est
Pin
e S
treet
Pro
ject
No.:
n/a
Shelton,
WA
98584
P.O
. N
o.:
n/a
Date
Colle
cte
d:
3/1
1/2
014;
08:0
0
Sam
ple
d B
y:
Date
Receiv
ed:
3/1
1/2
014;
13:0
5
Te
mpera
ture
Receiv
ed (
°C):
8 t
o 9
DA
L P
roje
ct
No
.: J
oh
n O
zg
aR
eport
Date
:
Pre
para
tio
n M
eth
od:
US
EP
A 5
030B
Units:
ug/L
Analy
tical M
eth
od:
US
EP
A 8
260B
Matr
ix:
Non-P
ota
ble
Wate
r
Date
Pre
pare
d:
3/2
0/2
014
Report
ing L
imits:
Sta
ndard
Date
Analy
zed:
3/2
0/2
014
Purg
e V
olu
me:
10 m
L
Analy
st:
TM
Instr
um
ent
ID:
Agile
nt
3026
Data
Revie
wed B
y:
Lab D
ata
File
:14032001
Sam
ple
Identificatio
nC
AS
No.
MR
L
Meth
od
Bla
nk
WC
C-1
WC
C-1
Dup.
WC
C-2
MW
-6M
W-9
Bro
modic
hlo
rom
eth
ane
75-2
7-4
1.0
nd
nd
nd
nd
nd
nd
Bro
mofo
rm75-2
5-2
1.0
nd
nd
nd
nd
nd
nd
Chlo
rofo
rm67-6
6-3
1.0
nd
nd
nd
4.6
0nd
nd
Dib
rom
ochlo
rom
eth
ane
124-4
8-1
1.0
nd
nd
nd
nd
nd
nd
Dilu
tio
n F
acto
r1.0
1.0
1.0
1.0
1.0
Data
Fla
gs
page 1
of
2
3/2
8/2
014
VO
LA
TIL
E O
RG
AN
IC C
OM
PO
UN
DS
AN
AL
YT
ICA
L R
ES
UL
TS
City o
f S
helton W
WT
PP
roje
ct
Nam
e:
Spra
y F
ield
Annual/Q
rtly
DA
L P
roje
ct
No
.: 1
40311-0
7P
roje
ct
No.:
n/a
Surr
ogate
Lim
its (
%)
Meth
od
Bla
nk
WC
C-1
WC
C-1
Dup.
WC
C-2
MW
-6M
W-9
Dib
rom
oflu
oro
meth
ane
86-1
18
104
100
101
104
102
102
To
luene-d
888-1
10
104
104
109
104
101
103
4-B
rom
oflu
oro
benzene
86-1
15
96.4
95.2
95.8
96.0
94.8
95.2
Analy
te
MS
Lim
its
(%)
MS
Level
(ug/L
)
Sam
ple
Conc.
(ug/L
)
MS
Recovery
(ug/L
)
MS
Perc
ent
Recovery
MS
D
Recovery
(ug/L
)
MS
D
Perc
ent
Recovery
MS
/MS
D
RP
D
Lim
its
RP
D
LC
S
Lim
its
(%)
LC
S
Level
(ug/L
)
LC
S
Recovery
(ug/L
)
LC
S
Perc
ent
Recovery
Benzene
76-1
27
10.0
nd
9.4
094.0
%9.1
991.9
%≤ 1
1%
1.1
380-1
20
10.0
10.3
103%
Chlo
robenzene
75-1
30
10.0
nd
8.6
086.0
%8.6
786.7
%≤ 1
3%
0.4
05
80-1
20
10.0
8.0
380.3
%
1,1
-Dic
hlo
roeth
ene
61-1
45
10.0
nd
8.0
480.4
%8.0
880.8
%≤ 1
4%
0.2
48
75-1
35
10.0
8.4
384.3
%
To
luene
76-1
25
10.0
nd
9.4
094.0
%10.2
102%
≤ 1
3%
4.2
380-1
20
10.0
10.7
107%
Trichlo
roeth
ene
71-1
20
10.0
nd
10.8
108%
10.8
108%
≤ 1
4%
0.0
46
80-1
20
10.0
9.9
499.4
%
WA
-DO
E-L
abora
tory
Cert
ific
atio
n N
o.:
C890
"nd"
indic
ate
s t
he a
naly
te w
as n
ot
dete
cte
d a
t or
above t
he lis
ted M
eth
od R
eport
ing L
imit.
"n/a
" in
dic
ate
s n
ot
applic
able
VO
LA
TIL
E O
RG
AN
IC C
OM
PO
UN
DS
page 2
of
2
Com
ments
and E
xpla
natio
ns:
None.
LA
BO
RA
TO
RY
CO
NT
RO
L S
AM
PLE
AN
D M
AT
RIX
SP
IKE
SU
RR
OG
AT
E R
EC
OV
ER
Y
QU
AL
ITY
CO
NT
RO
L R
ES
UL
TS
QC
Batc
h I
D:
140320-V
OC
LC
S S
am
ple
ID
: 140320-V
OC
LC
SM
S/M
SD
Sam
ple
ID
: 140320-V
OC
MS
/MS
D
City o
f S
helton
Pro
ject
Nam
e:
Quart
erly S
pra
yfie
ld
1000 W
est
Pin
e S
treet
Pro
ject
No.:
n/a
Shelton,
WA
98584
P.O
. N
o.:
n/a
Matr
ix:
Non-P
ota
ble
Wate
r
Sam
ple
d b
y:
John O
zga
Te
mpera
ture
Receiv
ed (
°C):
10
DA
L P
roje
ct
No
.: 1
40610-0
6R
eport
Date
: 6/3
0/2
014
SA
MP
LE
NA
ME
RE
SU
LT
S
SA
MP
LE
VO
LU
ME
(mL
)
FIL
TE
R
CO
UN
TM
RL
UN
ITS
ME
TH
OD
AN
AL
YS
IS
DA
TE
AN
AL
YS
TD
AT
A
FL
AG
S
WC
C-1
<1
100
0<
1C
FU
/100 m
LS
M 9
222 D
6/1
0/2
014;
08:0
06/1
0/2
014;
14:1
06/1
0/2
014;
16:0
46/1
1/2
014
CH
WC
C-2
<1
100
0<
1C
FU
/100 m
LS
M 9
222 D
6/1
0/2
014;
08:1
56/1
0/2
014;
14:1
06/1
0/2
014;
16:0
66/1
1/2
014
CH
MW
-6<
1100
0<
1C
FU
/100 m
LS
M 9
222 D
6/1
0/2
014;
08:3
06/1
0/2
014;
14:1
06/1
0/2
014;
16:0
76/1
1/2
014
CH
MW
-9<
1100
0<
1C
FU
/100 m
LS
M 9
222 D
6/1
0/2
014;
09:0
06/1
0/2
014;
14:1
06/1
0/2
014;
16:0
86/1
1/2
014
CH
SA
MP
LE
NA
ME
RE
SU
LT
S
SA
MP
LE
VO
LU
ME
(mL
)
FIL
TE
R
CO
UN
TM
RL
UN
ITS
ME
TH
OD
AN
AL
YS
IS
DA
TE
AN
AL
YS
TD
AT
A
FL
AG
S
Meth
od B
lank -
Open
<1
100
0<
1C
FU
/100 m
LS
M 9
222 D
6/1
1/2
014
CH
Meth
od B
lank -
Clo
se
<1
100
0<
1C
FU
/100 m
LS
M 9
222 D
6/1
1/2
014
CH
Fe
cal and/o
r T
ota
l C
olif
orm
s m
ust
be d
eliv
ere
d t
o t
he la
bora
tory
within
6 h
ours
of
sam
ple
colle
ctio
n.
Sam
ple
s m
ust
be f
iltere
d b
y t
he la
bora
tory
within
2 h
ours
of
recie
pt.
WA
-DO
E-L
abora
tory
Cert
ific
atio
n N
o.:
C890
"MR
L"
indic
ate
s M
eth
od R
eport
ing L
imit
Com
ments
and E
xpla
natio
ns:
None
Data
revie
wed b
y:
FE
CA
L C
OL
IFO
RM
S A
NA
LY
TIC
AL
RE
SU
LT
S
page 1
of
1
CO
LIF
OR
M Q
UA
LIT
Y C
ON
TR
OL
R
ES
UL
TS
Meth
od
B
lan
k
DA
TE
/TIM
E
SA
MP
LE
FIL
TE
RE
D
DA
TE
/TIM
E
SA
MP
LE
RE
CE
IVE
D
DA
TE
/TIM
E
SA
MP
LE
CO
LL
EC
TE
D
City o
f S
helton
Pro
ject
Nam
e:
Quart
erly S
pra
yfie
ld
1000 W
est
Pin
e S
treet
Pro
ject
No.:
n/a
Shelton,
WA
98584
P.O
. N
o.:
n/a
Sam
ple
Nam
e:
WC
C-1
Sam
ple
d b
y:
John O
zga
Matr
ix:
Non-P
ota
ble
Wate
r
Te
mpera
ture
Receiv
ed (
°C):
10
Colle
cte
d:
6/1
0/2
014;
08:0
0
Receiv
ed:
6/1
0/2
014;
14:1
0
DA
L P
roje
ct
No
.: 1
40610-0
6R
eport
Date
: 6/3
0/2
014
Chlo
rid
e1.8
70.0
22
0.1
0m
g/L
EP
A 3
00.0
16/1
1/2
014
6/1
1/2
014
n/a
FW
Nitro
gen,
Nitra
te
0.0
60.0
26
0.1
0m
g/L
EP
A 3
00.0
16/1
1/2
014
6/1
1/2
014
n/a
FW
Nitro
gen,
Nitrite
0.0
00.0
34
0.1
0m
g/L
EP
A 3
00.0
16/1
1/2
014
6/1
1/2
014
n/a
FW
Nitro
gen,
(TK
N)
0.0
00.3
62.0
mg/L
SM
4500-N
org
B1
6/1
7/2
014
6/1
7/2
014
n/a
NH
pH
6.6
0n/a
n/a
SU
SM
4500-H
+1
6/1
0/2
014
6/1
0/2
014
17:5
1G
D(1
)
Specific
Conducta
nce
65.2
n/a
10.0
um
ho/c
mS
M 2
510 B
16/1
1/2
014
6/1
1/2
014
n/a
GD
Solid
s,
To
tal D
issolv
ed
54.0
n/a
20.0
mg/L
SM
2540 C
16/1
4/2
014
6/1
4/2
014
n/a
SV
WA
-DO
E-L
abora
tory
Cert
ific
atio
n N
o.:
C890
"MD
L"
indic
ate
s M
eth
od D
ete
ctio
n L
imit
"MR
L"
indic
ate
s M
eth
od R
eport
ing L
imit
"DF
" in
dic
ate
s D
ilutio
n F
acto
r
"nd"
indic
ate
s t
he a
naly
te w
as n
ot
dete
cte
d a
t or
above t
he lis
ted M
eth
od R
eport
ing L
imit.
"n/a
" in
dic
ate
s n
ot
applic
able
Data
revie
wed b
y:
Report
Pre
pare
d B
y:
FW
Com
ments
and E
xpla
natio
ns:
A (
1)
fla
g I
ndic
ate
s a
n e
stim
ate
d v
alu
e,
because t
he s
am
ple
was r
eceiv
ed a
nd t
here
fore
analy
zed o
uts
ide o
f th
e r
ecom
mended a
nd r
egula
tory
hold
tim
e o
f 15 m
inute
s.
AN
AL
YS
TD
AT
A
FL
AG
SP
AR
AM
ET
ER
RE
SU
LT
SM
DL
MR
LU
NIT
SM
ET
HO
DD
FP
RE
PA
RA
TIO
N
DA
TE
AN
AL
YS
IS
DA
TE
AN
AL
YT
ICA
L R
ES
UL
TS
page 1
of
6
AN
AL
YS
IS
TIM
E
City o
f S
helton
Pro
ject
Nam
e:
Quart
erly S
pra
yfie
ld
1000 W
est
Pin
e S
treet
Pro
ject
No.:
n/a
Shelton,
WA
98584
P.O
. N
o.:
n/a
Sam
ple
Nam
e:
WC
C-2
Sam
ple
d b
y:
John O
zga
Matr
ix:
Non-P
ota
ble
Wate
r
Te
mpera
ture
Receiv
ed (
°C):
10
Colle
cte
d:
6/1
0/2
014;
08:1
5
Receiv
ed:
6/1
0/2
014;
14:1
0
DA
L P
roje
ct
No
.: 1
40610-0
6R
eport
Date
: 6/3
0/2
014
Chlo
rid
e3.6
00.0
22
0.1
0m
g/L
EP
A 3
00.0
16/1
1/2
014
6/1
1/2
014
n/a
FW
Nitro
gen,
Nitra
te
0.1
80.0
26
0.1
0m
g/L
EP
A 3
00.0
16/1
1/2
014
6/1
1/2
014
n/a
FW
Nitro
gen,
Nitrite
0.0
00.0
34
0.1
0m
g/L
EP
A 3
00.0
16/1
1/2
014
6/1
1/2
014
n/a
FW
Nitro
gen,
(TK
N)
0.3
0.3
62.0
mg/L
SM
4500-N
org
B1
6/1
7/2
014
6/1
7/2
014
n/a
NH
pH
6.7
1n/a
n/a
SU
SM
4500-H
+1
6/1
0/2
014
6/1
0/2
014
17:5
6G
D(1
)
Specific
Conducta
nce
77.8
n/a
10.0
um
ho/c
mS
M 2
510 B
16/1
1/2
014
6/1
1/2
014
n/a
GD
Solid
s,
To
tal D
issolv
ed
22.0
n/a
20.0
mg/L
SM
2540 C
16/1
4/2
014
6/1
4/2
014
n/a
SV
WA
-DO
E-L
abora
tory
Cert
ific
atio
n N
o.:
C890
"MD
L"
indic
ate
s M
eth
od D
ete
ctio
n L
imit
"MR
L"
indic
ate
s M
eth
od R
eport
ing L
imit
"DF
" in
dic
ate
s D
ilutio
n F
acto
r
"nd"
indic
ate
s t
he a
naly
te w
as n
ot
dete
cte
d a
t or
above t
he lis
ted M
eth
od R
eport
ing L
imit.
"n/a
" in
dic
ate
s n
ot
applic
able
Data
revie
wed b
y:
Report
Pre
pare
d B
y:
FW
Com
ments
and E
xpla
natio
ns:
A (
1)
fla
g I
ndic
ate
s a
n e
stim
ate
d v
alu
e,
because t
he s
am
ple
was r
eceiv
ed a
nd t
here
fore
analy
zed o
uts
ide o
f th
e r
ecom
mended a
nd r
egula
tory
hold
tim
e o
f 15 m
inute
s.
AN
AL
YS
IS
DA
TE
AN
AL
YS
IS
TIM
EA
NA
LY
ST
DA
TA
FL
AG
SP
AR
AM
ET
ER
RE
SU
LT
SM
DL
MR
LU
NIT
SM
ET
HO
DD
FP
RE
PA
RA
TIO
N
DA
TE
AN
AL
YT
ICA
L R
ES
UL
TS
page 2
of
6
City o
f S
helton
Pro
ject
Nam
e:
Quart
erly S
pra
yfie
ld
1000 W
est
Pin
e S
treet
Pro
ject
No.:
n/a
Shelton,
WA
98584
P.O
. N
o.:
n/a
Sam
ple
Nam
e:
MW
-6
Sam
ple
d b
y:
John O
zga
Matr
ix:
Non-P
ota
ble
Wate
r
Te
mpera
ture
Receiv
ed (
°C):
10
Colle
cte
d:
6/1
0/2
014;
08:3
0
Receiv
ed:
6/1
0/2
014;
14:1
0
DA
L P
roje
ct
No
.: 1
40610-0
6R
eport
Date
: 6/3
0/2
014
Chlo
rid
e1.9
00.0
22
0.1
0m
g/L
EP
A 3
00.0
16/1
1/2
014
6/1
1/2
014
n/a
FW
Nitro
gen,
Nitra
te
0.1
00.0
26
0.1
0m
g/L
EP
A 3
00.0
16/1
1/2
014
6/1
1/2
014
n/a
FW
Nitro
gen,
Nitrite
0.0
00.0
34
0.1
0m
g/L
EP
A 3
00.0
16/1
1/2
014
6/1
1/2
014
n/a
FW
Nitro
gen,
(TK
N)
0.3
0.3
62.0
mg/L
SM
4500-N
org
B1
6/1
7/2
014
6/1
7/2
014
n/a
NH
pH
6.4
8n/a
n/a
SU
SM
4500-H
+1
6/1
0/2
014
6/1
0/2
014
17:5
8G
D(1
)
Specific
Conducta
nce
56.6
n/a
10.0
um
ho/c
mS
M 2
510 B
16/1
1/2
014
6/1
1/2
014
n/a
GD
Solid
s,
To
tal D
issolv
ed
28.0
n/a
20.0
mg/L
SM
2540 C
16/1
4/2
014
6/1
4/2
014
n/a
SV
WA
-DO
E-L
abora
tory
Cert
ific
atio
n N
o.:
C890
"MD
L"
indic
ate
s M
eth
od D
ete
ctio
n L
imit
"MR
L"
indic
ate
s M
eth
od R
eport
ing L
imit
"DF
" in
dic
ate
s D
ilutio
n F
acto
r
"nd"
indic
ate
s t
he a
naly
te w
as n
ot
dete
cte
d a
t or
above t
he lis
ted M
eth
od R
eport
ing L
imit.
"n/a
" in
dic
ate
s n
ot
applic
able
Data
revie
wed b
y:
Report
Pre
pare
d B
y:
FW
Com
ments
and E
xpla
natio
ns:
A (
1)
fla
g I
ndic
ate
s a
n e
stim
ate
d v
alu
e,
because t
he s
am
ple
was r
eceiv
ed a
nd t
here
fore
analy
zed o
uts
ide o
f th
e r
ecom
mended a
nd r
egula
tory
hold
tim
e o
f 15 m
inute
s.
DF
PR
EP
AR
AT
ION
DA
TE
page 3
of
6
AN
AL
YS
IS
DA
TE
AN
AL
YS
IS
TIM
EA
NA
LY
ST
DA
TA
FL
AG
SP
AR
AM
ET
ER
RE
SU
LT
SM
DL
MR
LU
NIT
SM
ET
HO
D
AN
AL
YT
ICA
L R
ES
UL
TS
City o
f S
helton
Pro
ject
Nam
e:
Quart
erly S
pra
yfie
ld
1000 W
est
Pin
e S
treet
Pro
ject
No.:
n/a
Shelton,
WA
98584
P.O
. N
o.:
n/a
Sam
ple
Nam
e:
MW
-9
Sam
ple
d b
y:
John O
zga
Matr
ix:
Non-P
ota
ble
Wate
r
Te
mpera
ture
Receiv
ed (
°C):
10
Colle
cte
d:
6/1
0/2
014;
09:0
0
Receiv
ed:
6/1
0/2
014;
14:1
0
DA
L P
roje
ct
No
.: 1
40610-0
6R
eport
Date
: 6/3
0/2
014
Chlo
rid
e1.9
90.0
22
0.1
0m
g/L
EP
A 3
00.0
16/1
1/2
014
6/1
1/2
014
n/a
FW
Nitro
gen,
Nitra
te
0.1
30.0
26
0.1
0m
g/L
EP
A 3
00.0
16/1
1/2
014
6/1
1/2
014
n/a
FW
Nitro
gen,
Nitrite
0.0
00.0
34
0.1
0m
g/L
EP
A 3
00.0
16/1
1/2
014
6/1
1/2
014
n/a
FW
Nitro
gen,
(TK
N)
0.3
0.3
62.0
mg/L
SM
4500-N
org
B1
6/1
7/2
014
6/1
7/2
014
n/a
NH
pH
6.2
9n/a
n/a
SU
SM
4500-H
+1
6/1
0/2
014
6/1
0/2
014
17:5
9G
D(1
)
Specific
Conducta
nce
50.7
n/a
10.0
um
ho/c
mS
M 2
510 B
16/1
1/2
014
6/1
1/2
014
n/a
GD
Solid
s,
To
tal D
issolv
ed
30.0
n/a
20.0
mg/L
SM
2540 C
16/1
4/2
014
6/1
4/2
014
n/a
SV
WA
-DO
E-L
abora
tory
Cert
ific
atio
n N
o.:
C890
"MD
L"
indic
ate
s M
eth
od D
ete
ctio
n L
imit
"MR
L"
indic
ate
s M
eth
od R
eport
ing L
imit
"DF
" in
dic
ate
s D
ilutio
n F
acto
r
"nd"
indic
ate
s t
he a
naly
te w
as n
ot
dete
cte
d a
t or
above t
he lis
ted M
eth
od R
eport
ing L
imit.
"n/a
" in
dic
ate
s n
ot
applic
able
Data
revie
wed b
y:
Report
Pre
pare
d B
y:
FW
Com
ments
and E
xpla
natio
ns:
A (
1)
fla
g I
ndic
ate
s a
n e
stim
ate
d v
alu
e,
because t
he s
am
ple
was r
eceiv
ed a
nd t
here
fore
analy
zed o
uts
ide o
f th
e r
ecom
mended a
nd r
egula
tory
hold
tim
e o
f 15 m
inute
s.
AN
AL
YS
IS
DA
TE
AN
AL
YS
IS
TIM
EA
NA
LY
ST
DA
TA
FL
AG
SM
DL
MR
LU
NIT
SM
ET
HO
DD
FP
RE
PA
RA
TIO
N
DA
TE
page 4
of
6
AN
AL
YT
ICA
L R
ES
UL
TS
PA
RA
ME
TE
RR
ES
UL
TS
City o
f S
helton
Pro
ject
Nam
e:
Quart
erly S
pra
yfie
ld
DA
L P
roje
ct
No
.: 1
40610-0
6P
roje
ct
No.:
n/a
140611-C
hlo
ride
Chlo
rid
end
0.1
0m
g/L
EP
A 3
00.0
6/1
1/2
014
FW
140611-N
O
₃
Nitro
gen,
Nitra
te
nd
0.1
0m
g/L
EP
A 3
00.0
6/1
1/2
014
FW
140611-N
O
₂
Nitro
gen,
Nitrite
nd
0.1
0m
g/L
EP
A 3
00.0
6/1
1/2
014
FW
140617-T
KN
Nitro
gen,
(TK
N)
nd
2.0
mg/L
SM
4500-N
org
B6/1
7/2
014
NH
140610-p
HpH
n/a
n/a
SU
SM
4500-H
+n/a
n/a
140611-S
CS
pecific
Conducta
nce
nd
10.0
um
ho/c
mS
M 2
510 B
6/1
1/2
014
GD
140614-T
DS
Solid
s,
To
tal D
issolv
ed
nd
20.0
mg/L
SM
2540 C
6/1
4/2
014
SV
140611-C
hlo
ride
Chlo
rid
e4.3
94.3
9m
g/L
EP
A 3
00.0
0.0
23
±35
6/1
1/2
014
FW
140611-N
O
₃
Nitro
gen,
Nitra
te
1.5
31.5
4m
g/L
EP
A 3
00.0
0.5
22
±35
6/1
1/2
014
FW
140611-N
O
₂
Nitro
gen,
Nitrite
nd
nd
mg/L
EP
A 3
00.0
0.0
0±35
6/1
1/2
014
FW
140617-T
KN
Nitro
gen,
(TK
N)
nd
nd
mg/L
SM
4500-N
org
B0.0
0±35
6/1
7/2
014
NH
140610-p
HpH
6.6
6.6
3S
US
M 4
500-H
+0.4
54
±35
6/1
0/2
014
GD
(1)
140611-S
CS
pecific
Conducta
nce
n/a
n/a
um
ho/c
mS
M 2
510 B
n/a
n/a
n/a
n/a
140614-T
DS
Solid
s,
To
tal D
issolv
ed
2184
2230
mg/L
SM
2540 C
2.0
8±35
6/1
4/2
014
SV
WA
-DO
E-L
abora
tory
Cert
ific
atio
n N
o.:
C890
"MR
L"
indic
ate
s M
eth
od R
eport
ing L
imit
"RP
D"
indic
ate
s R
ela
tive P
erc
ent
Diffe
rence
"nd"
indic
ate
s t
he a
naly
te w
as n
ot
dete
cte
d a
t or
above t
he lis
ted M
eth
od R
eport
ing L
imit.
"n/a
" in
dic
ate
s n
ot
applic
able
Data
revie
wed b
y:
Com
ments
and E
xpla
natio
ns:
A (
1)
fla
g I
ndic
ate
s a
n e
stim
ate
d v
alu
e,
because t
he s
am
ple
was r
eceiv
ed a
nd t
here
fore
analy
zed o
uts
ide o
f th
e r
ecom
mended a
nd r
egula
tory
hold
tim
e o
f 15 m
inute
s.
RP
D
(%)
LIM
ITS
(%)
AN
AL
YS
IS
DA
TE
AN
AL
YS
TD
AT
A
FL
AG
S
A
NA
LY
SIS
DA
TE
AN
AL
YS
TD
AT
A
FL
AG
S
SA
MP
LE
BA
TC
HP
AR
AM
ET
ER
RE
SU
LT
DU
P.
RE
SU
LT
UN
ITS
AN
AL
YT
ICA
L
ME
TH
OD
page 5
of
6
QU
AL
ITY
C
ON
TR
OL
R
ES
UL
TS
Meth
od
B
lan
k
QU
AL
ITY
C
ON
TR
OL
R
ES
UL
TS
Du
plicate
Sam
ple
SA
MP
LE
BA
TC
HP
AR
AM
ET
ER
RE
SU
LT
MR
LU
NIT
SA
NA
LY
TIC
AL
ME
TH
OD
City o
f S
helton
Pro
ject
Nam
e:
Quart
erly S
pra
yfie
ld
DA
L P
roje
ct
No
.: 1
40610-0
6P
roje
ct
No.:
n/a
140611-C
hlo
ride
Chlo
rid
e0.5
37
0.5
mg/L
EP
A 3
00.0
107
65.0
-135
6/1
1/2
014
FW
140611-N
O
₃
Nitro
gen,
Nitra
te
0.5
20
0.5
mg/L
EP
A 3
00.0
104
65.0
-135
6/1
1/2
014
FW
140611-N
O
₂
Nitro
gen,
Nitrite
0.5
45
0.5
mg/L
EP
A 3
00.0
109
65.0
-135
6/1
1/2
014
FW
140617-T
KN
Nitro
gen,
(TK
N)
19.6
20.0
mg/L
SM
4500-N
org
B98.0
65.0
-135
6/1
7/2
014
NH
140610-p
HpH
6.9
97.0
SU
SM
4500-H
+99.9
65.0
-135
6/1
0/2
014
GD
140611-S
CS
pecific
Conducta
nce
1391
1415
um
ho/c
mS
M 2
510 B
98.3
65.0
-135
6/1
1/2
014
GD
140614-T
DS
Solid
s,
To
tal D
issolv
ed
496
500
mg/L
SM
2540 C
99.2
65.0
-135
6/1
4/2
014
n/a
140611-C
hlo
ride
Chlo
rid
e0.4
76
0.4
98
0.5
mg/L
EP
A 3
00.0
3.0
3±35
6/1
1/2
014
FW
140611-N
O
₃
Nitro
gen,
Nitra
te
0.4
96
0.5
28
0.5
mg/L
EP
A 3
00.0
4.2
1±35
6/1
1/2
014
FW
140611-N
O
₂
Nitro
gen,
Nitrite
0.5
41
0.5
35
0.5
mg/L
EP
A 3
00.0
0.7
42
±35
6/1
1/2
014
FW
140617-T
KN
Nitro
gen,
(TK
N)
20.4
20.4
20.0
mg/L
SM
4500-N
org
B0.0
0±35
6/1
7/2
014
NH
140610-p
HpH
n/a
n/a
n/a
SU
SM
4500-H
+n/a
n/a
n/a
n/a
140611-S
CS
pecific
Conducta
nce
n/a
n/a
n/a
um
ho/c
mS
M 2
510 B
n/a
n/a
n/a
n/a
140614-T
DS
Solid
s,
To
tal D
issolv
ed
n/a
n/a
n/a
mg/L
SM
2540 C
n/a
n/a
n/a
n/a
WA
-DO
E-L
abora
tory
Cert
ific
atio
n N
o.:
C890
"RP
D"
indic
ate
s R
ela
tive P
erc
ent
Diffe
rence
"nd"
indic
ate
s t
he a
naly
te w
as n
ot
dete
cte
d a
t or
above t
he lis
ted M
eth
od R
eport
ing L
imit.
"n/a
" in
dic
ate
s n
ot
applic
able
Com
ments
and E
xpla
natio
ns:
None
Data
revie
wed b
y:
DA
TA
FL
AG
SU
NIT
SA
NA
LY
TIC
AL
ME
TH
OD
RP
D
(%)
LIM
ITS
(%)
AN
AL
YS
IS
DA
TE
AN
AL
YS
T
RE
CO
VE
RY
(%)
LIM
ITS
(%)
AN
AL
YS
IS
DA
TE
AN
AL
YS
TD
AT
A
FL
AG
S
SA
MP
LE
BA
TC
HP
AR
AM
ET
ER
MS
RE
SU
LT
MS
D
RE
SU
LT
TR
UE
VA
LU
E
QU
AL
ITY
CO
NT
RO
L R
ES
UL
TS
Lab
ora
tory
Fo
rtif
ied
Bla
nk
QU
AL
ITY
CO
NT
RO
L R
ES
UL
TS
Matr
ix S
pik
e/M
atr
ix S
pik
e D
up
licate
page 6
of
6
SA
MP
LE
BA
TC
HP
AR
AM
ET
ER
LF
B
RE
SU
LT
T
RU
E
VA
LU
EU
NIT
SA
NA
LY
TIC
AL
ME
TH
OD
City o
f S
helton
Pro
ject
Nam
e:
Quart
erly S
pra
yfie
ld
1000 W
est
Pin
e S
treet
Pro
ject
No.:
n/a
Shelton,
WA
98584
P.O
. N
o.:
n/a
Date
Colle
cte
d:
6/1
0/2
014;
08:0
0
Sam
ple
d B
y:
Date
Receiv
ed:
6/1
0/2
014;
14:1
0
Te
mpera
ture
Receiv
ed (
°C):
10
DA
L P
roje
ct
No
.: J
oh
n O
zg
aR
eport
Date
:
Pre
para
tio
n M
eth
od:
US
EP
A 5
030B
Units:
ug/L
Analy
tical M
eth
od:
US
EP
A 8
260B
Matr
ix:
Non-P
ota
ble
Wate
r
Date
Pre
pare
d:
6/1
2/2
014
Report
ing L
imits:
Sta
ndard
Date
Analy
zed:
6/1
2/2
014
Purg
e V
olu
me:
15 m
L
Analy
st:
TM
Instr
um
ent
ID:
Agile
nt
3026
Data
Revie
wed B
y:
Lab D
ata
File
:14061201
Sam
ple
Identificatio
nC
AS
No.
MR
L
Meth
od
Bla
nk
WC
C-1
WC
C-2
MW
-6M
W-9
Bro
modic
hlo
rom
eth
ane
75-2
7-4
1.0
nd
nd
nd
nd
nd
Bro
mofo
rm75-2
5-2
1.0
nd
nd
nd
nd
nd
Chlo
rofo
rm67-6
6-3
1.0
nd
nd
1.3
1nd
nd
Dib
rom
ochlo
rom
eth
ane
124-4
8-1
1.0
nd
nd
nd
nd
nd
Dilu
tio
n F
acto
r1.0
1.0
1.0
1.0
Data
Fla
gs
6/3
0/2
014
TO
TA
L T
RIH
AL
OM
ET
HA
NE
S
AN
AL
YT
ICA
L R
ES
UL
TS
page 1
of
2
City o
f S
helton
Pro
ject
Nam
e:
Quart
erly S
pra
yfie
ld
DA
L P
roje
ct
No
.: 1
40610-0
6P
roje
ct
No.:
n/a
Surr
ogate
Lim
its (
%)
Meth
od
Bla
nk
WC
C-1
WC
C-2
MW
-6M
W-9
Dib
rom
oflu
oro
meth
ane
86-1
18
99.6
97.8
95.0
92.8
97.0
To
luene-d
888-1
10
94.4
97.6
92.0
94.2
91.4
4-B
rom
oflu
oro
benzene
86-1
15
98.4
102
105
106
102
Analy
te
MS
Lim
its
(%)
MS
Level
(ug/L
)
Sam
ple
Conc.
(ug/L
)
MS
Recovery
(ug/L
)
MS
Perc
ent
Recovery
MS
D
Recovery
(ug/L
)
MS
D
Perc
ent
Recovery
MS
/MS
D
RP
D
Lim
its
RP
D
LC
S
Lim
its
(%)
LC
S
Level
(ug/L
)
LC
S
Recovery
(ug/L
)
LC
S
Perc
ent
Recovery
Benzene
76-1
27
20.0
nd
21.0
105%
n/a
n/a
n/a
n/a
80-1
20
10.0
10.8
108%
Chlo
robenzene
75-1
30
20.0
nd
21.2
106%
n/a
n/a
n/a
n/a
80-1
20
10.0
11.9
119%
1,1
-Dic
hlo
roeth
ene
61-1
45
20.0
0.5
30
20.0
97.5
%n/a
n/a
n/a
n/a
75-1
35
10.0
8.7
587.5
%
To
luene
76-1
25
20.0
nd
23.5
118%
n/a
n/a
n/a
n/a
80-1
20
10.0
11.5
115%
Trichlo
roeth
ene
71-1
20
20.0
nd
23.5
117%
n/a
n/a
n/a
n/a
80-1
20
10.0
9.0
190.1
%
WA
-DO
E-L
abora
tory
Cert
ific
atio
n N
o.:
C890
"nd"
indic
ate
s t
he a
naly
te w
as n
ot
dete
cte
d a
t or
above t
he lis
ted M
eth
od R
eport
ing L
imit.
"n/a
" in
dic
ate
s n
ot
applic
able
VO
LA
TIL
E O
RG
AN
IC C
OM
PO
UN
DS
page 2
of
2
Com
ments
and E
xpla
natio
ns:
None.
LA
BO
RA
TO
RY
CO
NT
RO
L S
AM
PLE
AN
D M
AT
RIX
SP
IKE
SU
RR
OG
AT
E R
EC
OV
ER
Y
QU
AL
ITY
CO
NT
RO
L R
ES
UL
TS
QC
Batc
h I
D:
140613-V
OC
LC
S S
am
ple
ID
: 140613-V
OC
LC
SM
S/M
SD
Sam
ple
ID
: 140613-V
OC
MS
/MS
D
City o
f S
helton
Pro
ject
Nam
e:
QR
T R
ecaim
ed S
pra
yfie
ld
1000 W
est
Pin
e S
treet
Pro
ject
No.:
n/a
Shelton,
WA
98584
P.O
. N
o.:
n/a
Matr
ix:
Non-P
ota
ble
Wate
r
Sam
ple
d b
y:
John O
zga
Te
mpera
ture
Receiv
ed (
°C):
8-1
0 C
°
DA
L P
roje
ct
No
.: 1
40917-1
3R
eport
Date
: 10/6
/2014
SA
MP
LE
NA
ME
RE
SU
LT
S
SA
MP
LE
VO
LU
ME
(mL
)
FIL
TE
R
CO
UN
TM
RL
UN
ITS
ME
TH
OD
AN
AL
YS
IS
DA
TE
AN
AL
YS
TD
AT
A
FL
AG
S
MW
-6<
10
10
0<
10
CF
U/1
00 m
LS
M 9
222 B
2,5
,6U
nknow
nU
nknow
n9/1
7/2
014;
15:3
89/1
7/2
014;
16:2
69/1
8/2
014
CH
MW
-9<
10
10
0<
10
CF
U/1
00 m
LS
M 9
222 B
2,5
,6U
nknow
nU
nknow
n9/1
7/2
014;
15:3
89/1
7/2
014;
16:3
09/1
8/2
014
CH
WC
C-1
<10
10
0<
10
CF
U/1
00 m
LS
M 9
222 B
2,5
,6U
nknow
nU
nknow
n9/1
7/2
014;
15:3
89/1
7/2
014;
16:2
09/1
8/2
014
CH
WC
C-2
<2
50
0<
2C
FU
/100 m
LS
M 9
222 B
2,5
,6U
nknow
nU
nknow
n9/1
7/2
014;
15:3
89/1
7/2
014;
16:2
49/1
8/2
014
CH
Fe
cal and/o
r T
ota
l C
olif
orm
s m
ust
be d
eliv
ere
d t
o t
he la
bora
tory
within
6 h
ours
of
sam
ple
colle
ctio
n.
Sam
ple
s m
ust
be f
iltere
d b
y t
he la
bora
tory
within
2 h
ours
of
recie
pt.
WA
-DO
E-L
abora
tory
Cert
ific
atio
n N
o.:
C890
"MR
L"
indic
ate
s M
eth
od R
eport
ing L
imit
Com
ments
and E
xpla
natio
ns:
None
Data
revie
wed b
y:
TO
TA
L C
OL
IFO
RM
S A
NA
LY
TIC
AL
RE
SU
LT
S
page 1
of
2
DA
TE
/TIM
E
SA
MP
LE
FIL
TE
RE
D
DA
TE
/TIM
E
SA
MP
LE
RE
CE
IVE
D
DA
TE
/TIM
E S
AM
PL
E
CO
LL
EC
TE
D
City o
f S
helton
Pro
ject
Nam
e:
QR
T R
ecaim
ed S
pra
yfie
ld
DA
L P
roje
ct
No
.: 1
40917-1
3P
roje
ct
No.:
n/a
SA
MP
LE
NA
ME
RE
SU
LT
S
SA
MP
LE
VO
LU
ME
(mL
)
FIL
TE
R
CO
UN
TM
RL
UN
ITS
ME
TH
OD
AN
AL
YS
IS
DA
TE
AN
AL
YS
TD
AT
A
FL
AG
S
Meth
od B
lank -
Open
<1
100
0<
1C
FU
/100 m
LS
M 9
222 B
2,5
,69/1
8/2
014
CH
Meth
od B
lank -
Clo
se
<1
100
0<
1C
FU
/100 m
LS
M 9
222 B
2,5
,69/1
8/2
014
CH
Fe
cal and/o
r T
ota
l C
olif
orm
s m
ust
be d
eliv
ere
d t
o t
he la
bora
tory
within
6 h
ours
of
sam
ple
colle
ctio
n.
Sam
ple
s m
ust
be f
iltere
d b
y t
he la
bora
tory
within
2 h
ours
of
recie
pt.
WA
-DO
E-L
abora
tory
Cert
ific
atio
n N
o.:
C890
"MR
L"
indic
ate
s M
eth
od R
eport
ing L
imit
Com
ments
and E
xpla
natio
ns:
None
Data
revie
wed b
y:
page 2
of
2
CO
LIF
OR
M Q
UA
LIT
Y C
ON
TR
OL
R
ES
UL
TS
Meth
od
B
lan
k
City o
f S
helton
Pro
ject
Nam
e:
QR
T R
ecaim
ed S
pra
yfie
ld
1000 W
est
Pin
e S
treet
Pro
ject
No.:
n/a
Shelton,
WA
98584
P.O
. N
o.:
n/a
Sam
ple
Nam
e:
MW
-6
Sam
ple
d b
y:
John O
zga
Matr
ix:
Non-P
ota
ble
Wate
r
Te
mpera
ture
Receiv
ed (
°C):
8-1
0 C
°
Colle
cte
d:
Un
kn
ow
n;
Un
kn
ow
n
Receiv
ed:
9/1
7/2
014;
15:3
8
DA
L P
roje
ct
No
.: 1
40917-1
3R
eport
Date
: 10/6
/2014
Chlo
rid
e2.4
60.0
22
0.1
0m
g/L
EP
A 3
00.0
19/1
8/2
014
9/1
8/2
014
n/a
FW
Nitro
gen,
Nitra
te
0.1
10.0
26
0.1
0m
g/L
EP
A 3
00.0
19/1
8/2
014
9/1
8/2
014
n/a
FW
Nitro
gen,
Nitrite
nd
0.0
34
0.1
0m
g/L
EP
A 3
00.0
19/1
8/2
014
9/1
8/2
014
n/a
FW
Nitro
gen,
(TK
N)
0.4
20.3
62.0
mg/L
SM
4500-N
org
B1
9/2
9/2
014
9/2
9/2
014
n/a
GM
DJ
pH
6.5
6n/a
n/a
SU
SM
4500-H
+1
9/1
7/2
014
9/1
7/2
014
15:5
4M
S(1
)
Specific
Conducta
nce
55.5
n/a
10.0
um
ho/c
mS
M 2
510 B
19/1
8/2
014
9/1
8/2
014
n/a
CH
Solid
s,
To
tal D
issolv
ed
48.0
n/a
20.0
mg/L
SM
2540 C
19/1
8/2
014
9/1
8/2
014
n/a
GM
D
WA
-DO
E-L
abora
tory
Cert
ific
atio
n N
o.:
C890
"MD
L"
indic
ate
s M
eth
od D
ete
ctio
n L
imit
"MR
L"
indic
ate
s M
eth
od R
eport
ing L
imit
"DF
" in
dic
ate
s D
ilutio
n F
acto
r
"nd"
indic
ate
s t
he a
naly
te w
as n
ot
dete
cte
d a
t or
above t
he lis
ted M
eth
od R
eport
ing L
imit.
"n/a
" in
dic
ate
s n
ot
applic
able
Com
ments
and E
xpla
natio
ns:
A
(1)
fla
g I
ndic
ate
s a
n e
stim
ate
d v
alu
e,
because t
he s
am
ple
was r
eceiv
ed a
nd t
here
fore
analy
zed o
uts
ide o
f th
e r
ecom
mended a
nd r
egula
tory
hold
tim
e o
f 15 m
inute
s.
A "
J"
fla
g in
dic
ate
s a
n e
stim
ate
d v
alu
e t
hat
is g
reate
r th
an t
he M
DL b
ut
less t
han t
he M
RL.
Data
revie
wed b
y:
Report
Pre
pare
d B
y:
ND
H
AN
AL
YT
ICA
L R
ES
UL
TS
page 1
of
6
PA
RA
ME
TE
RR
ES
UL
TS
MD
LM
RL
UN
ITS
ME
TH
OD
DF
PR
EP
AR
AT
ION
DA
TE
AN
AL
YS
IS
DA
TE
AN
AL
YS
IS
TIM
EA
NA
LY
ST
DA
TA
FL
AG
S
City o
f S
helton
Pro
ject
Nam
e:
QR
T R
ecaim
ed S
pra
yfie
ld
1000 W
est
Pin
e S
treet
Pro
ject
No.:
n/a
Shelton,
WA
98584
P.O
. N
o.:
n/a
Sam
ple
Nam
e:
MW
-9
Sam
ple
d b
y:
John O
zga
Matr
ix:
Non-P
ota
ble
Wate
r
Te
mpera
ture
Receiv
ed (
°C):
8-1
0 C
°
Colle
cte
d:
Un
kn
ow
n;
Un
kn
ow
n
Receiv
ed:
9/1
7/2
014;
15:3
8
DA
L P
roje
ct
No
.: 1
40917-1
3R
eport
Date
: 10/6
/2014
Chlo
rid
e1.9
80.0
22
0.1
0m
g/L
EP
A 3
00.0
19/1
8/2
014
9/1
8/2
014
n/a
FW
Nitro
gen,
Nitra
te
0.1
20.0
26
0.1
0m
g/L
EP
A 3
00.0
19/1
8/2
014
9/1
8/2
014
n/a
FW
Nitro
gen,
Nitrite
nd
0.0
34
0.1
0m
g/L
EP
A 3
00.0
19/1
8/2
014
9/1
8/2
014
n/a
FW
Nitro
gen,
(TK
N)
nd
0.3
62.0
mg/L
SM
4500-N
org
B1
9/2
9/2
014
9/2
9/2
014
n/a
GM
D
pH
6.4
9n/a
n/a
SU
SM
4500-H
+1
9/1
7/2
014
9/1
7/2
014
15:5
3M
S(1
)
Specific
Conducta
nce
46.2
n/a
10.0
um
ho/c
mS
M 2
510 B
19/1
8/2
014
9/1
8/2
014
n/a
CH
Solid
s,
To
tal D
issolv
ed
36.0
n/a
20.0
mg/L
SM
2540 C
19/1
8/2
014
9/1
8/2
014
n/a
GM
D
WA
-DO
E-L
abora
tory
Cert
ific
atio
n N
o.:
C890
"MD
L"
indic
ate
s M
eth
od D
ete
ctio
n L
imit
"MR
L"
indic
ate
s M
eth
od R
eport
ing L
imit
"DF
" in
dic
ate
s D
ilutio
n F
acto
r
"nd"
indic
ate
s t
he a
naly
te w
as n
ot
dete
cte
d a
t or
above t
he lis
ted M
eth
od R
eport
ing L
imit.
"n/a
" in
dic
ate
s n
ot
applic
able
Com
ments
and E
xpla
natio
ns:
A (
1)
fla
g I
ndic
ate
s a
n e
stim
ate
d v
alu
e,
because t
he s
am
ple
was r
eceiv
ed a
nd t
here
fore
analy
zed o
uts
ide o
f th
e r
ecom
mended a
nd r
egula
tory
hold
tim
e o
f 15 m
inute
s.
Data
revie
wed b
y:
Report
Pre
pare
d B
y:
ND
H
AN
AL
YT
ICA
L R
ES
UL
TS
page 2
of
6
PA
RA
ME
TE
RR
ES
UL
TS
MD
LM
RL
UN
ITS
ME
TH
OD
DF
PR
EP
AR
AT
ION
DA
TE
AN
AL
YS
IS
DA
TE
AN
AL
YS
IS
TIM
EA
NA
LY
ST
DA
TA
FL
AG
S
City o
f S
helton
Pro
ject
Nam
e:
QR
T R
ecaim
ed S
pra
yfie
ld
1000 W
est
Pin
e S
treet
Pro
ject
No.:
n/a
Shelton,
WA
98584
P.O
. N
o.:
n/a
Sam
ple
Nam
e:
WC
C-1
Sam
ple
d b
y:
John O
zga
Matr
ix:
Non-P
ota
ble
Wate
r
Te
mpera
ture
Receiv
ed (
°C):
8-1
0 C
°
Colle
cte
d:
Un
kn
ow
n;
Un
kn
ow
n
Receiv
ed:
9/1
7/2
014;
15:3
8
DA
L P
roje
ct
No
.: 1
40917-1
3R
eport
Date
: 10/6
/2014
Chlo
rid
e1.8
40.0
22
0.1
0m
g/L
EP
A 3
00.0
19/1
8/2
014
9/1
8/2
014
n/a
FW
Nitro
gen,
Nitra
te
0.0
80.0
26
0.1
0m
g/L
EP
A 3
00.0
19/1
8/2
014
9/1
8/2
014
n/a
FW
J
Nitro
gen,
Nitrite
nd
0.0
34
0.1
0m
g/L
EP
A 3
00.0
19/1
8/2
014
9/1
8/2
014
n/a
FW
Nitro
gen,
(TK
N)
0.4
20.3
62.0
mg/L
SM
4500-N
org
B1
9/2
9/2
014
9/2
9/2
014
n/a
GM
DJ
pH
7.1
1n/a
n/a
SU
SM
4500-H
+1
9/1
7/2
014
9/1
7/2
014
15:4
8M
S(1
)
Specific
Conducta
nce
59.9
n/a
10.0
um
ho/c
mS
M 2
510 B
19/1
8/2
014
9/1
8/2
014
n/a
CH
Solid
s,
To
tal D
issolv
ed
40.0
n/a
20.0
mg/L
SM
2540 C
19/1
8/2
014
9/1
8/2
014
n/a
GM
D
WA
-DO
E-L
abora
tory
Cert
ific
atio
n N
o.:
C890
"MD
L"
indic
ate
s M
eth
od D
ete
ctio
n L
imit
"MR
L"
indic
ate
s M
eth
od R
eport
ing L
imit
"DF
" in
dic
ate
s D
ilutio
n F
acto
r
"nd"
indic
ate
s t
he a
naly
te w
as n
ot
dete
cte
d a
t or
above t
he lis
ted M
eth
od R
eport
ing L
imit.
"n/a
" in
dic
ate
s n
ot
applic
able
Com
ments
and E
xpla
natio
ns:
A (
1)
fla
g I
ndic
ate
s a
n e
stim
ate
d v
alu
e,
because t
he s
am
ple
was r
eceiv
ed a
nd t
here
fore
analy
zed o
uts
ide o
f th
e r
ecom
mended a
nd r
egula
tory
hold
tim
e o
f 15 m
inute
s.
Data
revie
wed b
y:
Report
Pre
pare
d B
y:
ND
H
AN
AL
YT
ICA
L R
ES
UL
TS
PA
RA
ME
TE
RR
ES
UL
TS
MD
LM
RL
UN
ITS
ME
TH
OD
DF
PR
EP
AR
AT
ION
DA
TE
AN
AL
YS
IS
DA
TE
AN
AL
YS
IS
TIM
EA
NA
LY
ST
page 3
of
6
DA
TA
FL
AG
S
City o
f S
helton
Pro
ject
Nam
e:
QR
T R
ecaim
ed S
pra
yfie
ld
1000 W
est
Pin
e S
treet
Pro
ject
No.:
n/a
Shelton,
WA
98584
P.O
. N
o.:
n/a
Sam
ple
Nam
e:
WC
C-2
Sam
ple
d b
y:
John O
zga
Matr
ix:
Non-P
ota
ble
Wate
r
Te
mpera
ture
Receiv
ed (
°C):
8-1
0 C
°
Colle
cte
d:
Un
kn
ow
n;
Un
kn
ow
n
Receiv
ed:
9/1
7/2
014;
15:3
8
DA
L P
roje
ct
No
.: 1
40917-1
3R
eport
Date
: 10/6
/2014
Chlo
rid
e6.5
60.0
22
0.1
0m
g/L
EP
A 3
00.0
19/1
8/2
014
9/1
8/2
014
n/a
FW
Nitro
gen,
Nitra
te
0.3
30.0
26
0.1
0m
g/L
EP
A 3
00.0
19/1
8/2
014
9/1
8/2
014
n/a
FW
Nitro
gen,
Nitrite
nd
0.0
34
0.1
0m
g/L
EP
A 3
00.0
19/1
8/2
014
9/1
8/2
014
n/a
FW
Nitro
gen,
(TK
N)
nd
0.3
62.0
mg/L
SM
4500-N
org
B1
9/2
9/2
014
9/2
9/2
014
n/a
GM
D
pH
6.8
4n/a
n/a
SU
SM
4500-H
+1
9/1
7/2
014
9/1
7/2
014
15:5
1M
S(1
)
Specific
Conducta
nce
87.5
n/a
10.0
um
ho/c
mS
M 2
510 B
19/1
8/2
014
9/1
8/2
014
n/a
CH
Solid
s,
To
tal D
issolv
ed
66.0
n/a
20.0
mg/L
SM
2540 C
19/1
8/2
014
9/1
8/2
014
n/a
GM
D
WA
-DO
E-L
abora
tory
Cert
ific
atio
n N
o.:
C890
"MD
L"
indic
ate
s M
eth
od D
ete
ctio
n L
imit
"MR
L"
indic
ate
s M
eth
od R
eport
ing L
imit
"DF
" in
dic
ate
s D
ilutio
n F
acto
r
"nd"
indic
ate
s t
he a
naly
te w
as n
ot
dete
cte
d a
t or
above t
he lis
ted M
eth
od R
eport
ing L
imit.
"n/a
" in
dic
ate
s n
ot
applic
able
Com
ments
and E
xpla
natio
ns:
A (
1)
fla
g I
ndic
ate
s a
n e
stim
ate
d v
alu
e,
because t
he s
am
ple
was r
eceiv
ed a
nd t
here
fore
analy
zed o
uts
ide o
f th
e r
ecom
mended a
nd r
egula
tory
hold
tim
e o
f 15 m
inute
s.
Data
revie
wed b
y:
Report
Pre
pare
d B
y:
ND
H
page 4
of
6
AN
AL
YT
ICA
L R
ES
UL
TS
PA
RA
ME
TE
RR
ES
UL
TS
AN
AL
YS
TD
AT
A
FL
AG
SM
DL
MR
LU
NIT
SM
ET
HO
DD
FP
RE
PA
RA
TIO
N
DA
TE
AN
AL
YS
IS
DA
TE
AN
AL
YS
IS
TIM
E
City o
f S
helton
Pro
ject
Nam
e:
QR
T R
ecaim
ed S
pra
yfie
ld
DA
L P
roje
ct
No
.: 1
40917-1
3P
roje
ct
No.:
n/a
140918-C
hlo
ride
Chlo
rid
end
0.1
0m
g/L
EP
A 3
00.0
9/1
8/2
014
FW
140918-N
O
₃
Nitro
gen,
Nitra
te
nd
0.1
0m
g/L
EP
A 3
00.0
9/1
8/2
014
FW
140918-N
O
₂
Nitro
gen,
Nitrite
nd
0.1
0m
g/L
EP
A 3
00.0
9/1
8/2
014
FW
140929-T
KN
Nitro
gen,
(TK
N)
nd
2.0
mg/L
SM
4500-N
org
B9/2
9/2
014
GM
D
140917-p
HpH
n/a
n/a
SU
SM
4500-H
+n/a
n/a
140918-S
CS
pecific
Conducta
nce
nd
10.0
um
ho/c
mS
M 2
510 B
9/1
8/2
014
CH
140918-T
DS
Solid
s,
To
tal D
issolv
ed
nd
20.0
mg/L
SM
2540 C
9/1
8/2
014
GM
D
140918-C
hlo
ride
Chlo
rid
e1.3
61.3
6m
g/L
EP
A 3
00.0
0.2
±35
9/1
8/2
014
FW
140918-N
O
₃
Nitro
gen,
Nitra
te
nd
nd
mg/L
EP
A 3
00.0
0.0
0±35
9/1
8/2
014
FW
140918-N
O
₂
Nitro
gen,
Nitrite
nd
nd
mg/L
EP
A 3
00.0
0.0
0±35
9/1
8/2
014
FW
140929-T
KN
Nitro
gen,
(TK
N)
nd
nd
mg/L
SM
4500-N
org
B0.0
0±35
9/2
9/2
014
GM
D
140917-p
HpH
7.1
16.8
6S
US
M 4
500-H
+3.6
±35
9/1
7/2
014
MS
(1)
140918-S
CS
pecific
Conducta
nce
n/a
n/a
um
ho/c
mS
M 2
510 B
n/a
n/a
n/a
n/a
140918-T
DS
Solid
s,
To
tal D
issolv
ed
200
180
mg/L
SM
2540 C
10.5
±35
9/1
8/2
014
GM
D
WA
-DO
E-L
abora
tory
Cert
ific
atio
n N
o.:
C890
"MR
L"
indic
ate
s M
eth
od R
eport
ing L
imit
"RP
D"
indic
ate
s R
ela
tive P
erc
ent
Diffe
rence
"nd"
indic
ate
s t
he a
naly
te w
as n
ot
dete
cte
d a
t or
above t
he lis
ted M
eth
od R
eport
ing L
imit.
"n/a
" in
dic
ate
s n
ot
applic
able
Com
ments
and E
xpla
natio
ns:
A (
1)
fla
g I
ndic
ate
s a
n e
stim
ate
d v
alu
e,
because t
he s
am
ple
was r
eceiv
ed a
nd t
here
fore
analy
zed o
uts
ide o
f th
e r
ecom
mended a
nd r
egula
tory
hold
tim
e o
f 15 m
inute
s.
Data
revie
wed b
y:
page 5
of
6
QU
AL
ITY
C
ON
TR
OL
R
ES
UL
TS
Meth
od
B
lan
k
QU
AL
ITY
C
ON
TR
OL
R
ES
UL
TS
Du
plicate
Sam
ple
SA
MP
LE
BA
TC
HP
AR
AM
ET
ER
RE
SU
LT
MR
LU
NIT
SA
NA
LY
TIC
AL
ME
TH
OD
SA
MP
LE
BA
TC
HP
AR
AM
ET
ER
RE
SU
LT
DU
P.
RE
SU
LT
UN
ITS
AN
AL
YT
ICA
L
ME
TH
OD
RP
D
(%)
LIM
ITS
(%)
AN
AL
YS
IS
DA
TE
AN
AL
YS
TD
AT
A
FL
AG
S
A
NA
LY
SIS
DA
TE
AN
AL
YS
TD
AT
A
FL
AG
S
City o
f S
helton
Pro
ject
Nam
e:
QR
T R
ecaim
ed S
pra
yfie
ld
DA
L P
roje
ct
No
.: 1
40917-1
3P
roje
ct
No.:
n/a
140918-C
hlo
ride
Chlo
rid
e0.5
0.5
mg/L
EP
A 3
00.0
100
65.0
-135
9/1
8/2
014
FW
140918-N
O
₃
Nitro
gen,
Nitra
te
0.5
40.5
mg/L
EP
A 3
00.0
107
65.0
-135
9/1
8/2
014
FW
140918-N
O
₂
Nitro
gen,
Nitrite
0.5
30.5
mg/L
EP
A 3
00.0
106
65.0
-135
9/1
8/2
014
FW
140929-T
KN
Nitro
gen,
(TK
N)
17.7
20.0
mg/L
SM
4500-N
org
B88.5
65.0
-135
9/2
9/2
014
GM
D
140917-p
HpH
7.0
27.0
SU
SM
4500-H
+100
65.0
-135
9/1
7/2
014
MS
140918-S
CS
pecific
Conducta
nce
1423
1415
um
ho/c
mS
M 2
510 B
101
65.0
-135
9/1
8/2
014
CH
140918-T
DS
Solid
s,
To
tal D
issolv
ed
530
500
mg/L
SM
2540 C
106
65.0
-135
9/1
8/2
014
n/a
140918-C
hlo
ride
Chlo
rid
e0.5
00.4
80.5
mg/L
EP
A 3
00.0
2.5
8±35
9/1
8/2
014
FW
140918-N
O
₃
Nitro
gen,
Nitra
te
0.5
20.5
40.5
mg/L
EP
A 3
00.0
2.6
8±35
9/1
8/2
014
FW
140918-N
O
₂
Nitro
gen,
Nitrite
0.5
40.5
50.5
mg/L
EP
A 3
00.0
0.4
9±35
9/1
8/2
014
FW
140929-T
KN
Nitro
gen,
(TK
N)
16.4
16.7
20.0
mg/L
SM
4500-N
org
B1.1
3±35
9/2
9/2
014
GM
D
140917-p
HpH
n/a
n/a
n/a
SU
SM
4500-H
+n/a
n/a
n/a
n/a
140918-S
CS
pecific
Conducta
nce
n/a
n/a
n/a
um
ho/c
mS
M 2
510 B
n/a
n/a
n/a
n/a
140918-T
DS
Solid
s,
To
tal D
issolv
ed
n/a
n/a
n/a
mg/L
SM
2540 C
n/a
n/a
n/a
n/a
WA
-DO
E-L
abora
tory
Cert
ific
atio
n N
o.:
C890
"RP
D"
indic
ate
s R
ela
tive P
erc
ent
Diffe
rence
"nd"
indic
ate
s t
he a
naly
te w
as n
ot
dete
cte
d a
t or
above t
he lis
ted M
eth
od R
eport
ing L
imit.
"n/a
" in
dic
ate
s n
ot
applic
able
Com
ments
and E
xpla
natio
ns:
None
Data
revie
wed b
y:
QU
AL
ITY
CO
NT
RO
L R
ES
UL
TS
Lab
ora
tory
Fo
rtif
ied
Bla
nk
QU
AL
ITY
CO
NT
RO
L R
ES
UL
TS
Matr
ix S
pik
e/M
atr
ix S
pik
e D
up
licate
page 6
of
6
SA
MP
LE
BA
TC
HP
AR
AM
ET
ER
LF
B
RE
SU
LT
T
RU
E
VA
LU
EU
NIT
SA
NA
LY
TIC
AL
ME
TH
OD
RE
CO
VE
RY
(%)
LIM
ITS
(%)
AN
AL
YS
IS
DA
TE
AN
AL
YS
TD
AT
A
FL
AG
S
SA
MP
LE
BA
TC
HP
AR
AM
ET
ER
MS
RE
SU
LT
MS
D
RE
SU
LT
TR
UE
VA
LU
E
DA
TA
FL
AG
SU
NIT
SA
NA
LY
TIC
AL
ME
TH
OD
RP
D
(%)
LIM
ITS
(%)
AN
AL
YS
IS
DA
TE
AN
AL
YS
T
City o
f S
helton
Pro
ject
Nam
e:
QR
T R
ecaim
ed S
pra
yfie
ld
1000 W
est
Pin
e S
treet
Pro
ject
No.:
n/a
Shelton,
WA
98584
P.O
. N
o.:
n/a
Date
Colle
cte
d:
Unknow
n;
Unknow
n
Sam
ple
d B
y:
John O
zga
Date
Receiv
ed:
9/1
7/2
014;
15:3
8
Te
mpera
ture
Receiv
ed (
°C):
8-1
0 C
°
DA
L P
roje
ct
No
.: 1
40917-1
3R
eport
Date
:
Pre
para
tio
n M
eth
od:
US
EP
A 5
030B
Units:
ug/L
Analy
tical M
eth
od:
US
EP
A 8
260B
Matr
ix:
Non-P
ota
ble
Wate
r
Date
Pre
pare
d:
9/3
0/2
014
Report
ing L
imits:
Sta
ndard
Date
Analy
zed:
9/3
0/2
014
Purg
e V
olu
me:
15 m
L
Analy
st:
TM
Instr
um
ent
ID:
Agile
nt
3026
Data
Revie
wed B
y:
Lab D
ata
File
:14093002
Sam
ple
Identificatio
nC
AS
No.
MR
L
Meth
od
Bla
nk
MW
-6M
W-9
WC
C-1
WC
C-2
Bro
modic
hlo
rom
eth
ane
75-2
7-4
1.0
nd
nd
nd
nd
nd
Bro
mofo
rm75-2
5-2
1.0
nd
nd
nd
nd
nd
Chlo
rofo
rm67-6
6-3
1.0
nd
0.2
5 J
nd
nd
2.0
3
Dib
rom
ochlo
rom
eth
ane
124-4
8-1
1.0
nd
nd
nd
nd
nd
Dilu
tio
n F
acto
r1.0
1.0
1.0
1.0
Data
Fla
gs:
A (
J)
Fla
g in
dic
ate
s t
hat
the r
esult w
as b
etw
een t
he M
DL a
nd M
RL a
nd t
here
fore
estiim
ate
d.
10/6
/2014
VO
LA
TIL
E O
RG
AN
IC C
OM
PO
UN
DS
AN
AL
YT
ICA
L R
ES
UL
TS
page 1
of
2
City o
f S
helton
Pro
ject
Nam
e:
QR
T R
ecaim
ed S
pra
yfie
ld
DA
L P
roje
ct
No
.: 1
40917-1
3P
roje
ct
No.:
n/a
Surr
ogate
Lim
its (
%)
Meth
od
Bla
nk
MW
-6M
W-9
WC
C-1
WC
C-2
Dib
rom
oflu
oro
meth
ane
86-1
18
97.0
100
102
103
101
To
luene-d
888-1
10
100
103
103
101
101
4-B
rom
oflu
oro
benzene
86-1
15
101
99.8
98.4
96.2
98.4
Analy
te
MS
Lim
its
(%)
MS
Level
(ug/L
)
Sam
ple
Conc.
(ug/L
)
MS
Recovery
(ug/L
)
MS
Perc
ent
Recovery
MS
D
Recovery
(ug/L
)
MS
D
Perc
ent
Recovery
MS
/MS
D
RP
D
Lim
its
RP
D
LC
S
Lim
its
(%)
LC
S
Level
(ug/L
)
LC
S
Recovery
(ug/L
)
LC
S
Perc
ent
Recovery
Benzene
76-1
27
10.0
nd
9.4
794.7
%9.3
593.5
0%
≤ 1
1%
0.6
480-1
20
10.0
9.8
198.1
%
Chlo
robenzene
75-1
30
10.0
nd
10.6
106%
10.3
103.2
0%
≤ 1
3%
1.3
980-1
20
10.0
10.7
107%
1,1
-Dic
hlo
roeth
ene
61-1
45
10.0
nd
9.2
992.9
%8.8
588.5
0%
≤ 1
4%
2.4
375-1
35
10.0
9.0
990.9
%
To
luene
76-1
25
10.0
nd
10.5
105%
10.3
102.6
0%
≤ 1
3%
1.0
680-1
20
10.0
10.6
106%
Trichlo
roeth
ene
71-1
20
10.0
nd
11.8
118%
11.8
117.5
0%
≤ 1
4%
0.3
080-1
20
10.0
11.9
119%
WA
-DO
E-L
abora
tory
Cert
ific
atio
n N
o.:
C890
"nd"
indic
ate
s t
he a
naly
te w
as n
ot
dete
cte
d a
t or
above t
he lis
ted M
eth
od R
eport
ing L
imit.
"n/a
" in
dic
ate
s n
ot
applic
able
QC
Batc
h I
D:
140930-V
OC
LC
S S
am
ple
ID
: 140930-V
OC
LC
SM
S/M
SD
Sam
ple
ID
: 140930-V
OC
MS
/MS
D
page 2
of
2
Com
ments
and E
xpla
natio
ns:
None.
LA
BO
RA
TO
RY
CO
NT
RO
L S
AM
PLE
AN
D M
AT
RIX
SP
IKE
SU
RR
OG
AT
E R
EC
OV
ER
Y
QU
AL
ITY
CO
NT
RO
L R
ES
UL
TS
VO
LA
TIL
E O
RG
AN
IC C
OM
PO
UN
DS
City o
f S
helton
Pro
ject
Nam
e:
Monitorin
g W
ells
1000 W
est
Pin
e S
treet
Pro
ject
No.:
na
Shelton,
WA
98584
P.O
. N
o.:
na
Matr
ix:
Non-P
ota
ble
Wate
r
Sam
ple
d b
y:
John O
zga
Te
mpera
ture
Receiv
ed (
°C):
11
DA
L P
roje
ct
No
.: 1
41202-1
9R
eport
Date
: 12/1
9/2
014
SA
MP
LE
NA
ME
RE
SU
LT
S
SA
MP
LE
VO
LU
ME
(mL
)
FIL
TE
R
CO
UN
TM
RL
UN
ITS
ME
TH
OD
AN
AL
YS
IS
DA
TE
AN
AL
YS
TD
AT
A
FL
AG
S
WC
C-1
10
10
1<
10
CF
U/1
00 m
LS
M 9
222 B
2,5
,612/2
/2014;
08:0
012/2
/2014;
14:0
512/2
/2014;
17:3
412/3
/2014
MM
J
WC
C-2
60
10
6<
10
CF
U/1
00 m
LS
M 9
222 B
2,5
,612/2
/2014;
08:1
512/2
/2014;
14:0
512/2
/2014;
17:3
612/3
/2014
MM
J
MW
-620
10
2<
10
CF
U/1
00 m
LS
M 9
222 B
2,5
,612/2
/2014;
08:3
012/2
/2014;
14:0
512/2
/2014;
17:3
812/3
/2014
MM
J
MW
-9<
10
10
0<
10
CF
U/1
00 m
LS
M 9
222 B
2,5
,612/2
/2014;
08:4
512/2
/2014;
14:0
512/2
/2014;
17:4
012/3
/2014
MM
SA
MP
LE
NA
ME
RE
SU
LT
S
SA
MP
LE
VO
LU
ME
(mL
)
FIL
TE
R
CO
UN
TM
RL
UN
ITS
ME
TH
OD
AN
AL
YS
IS
DA
TE
AN
AL
YS
TD
AT
A
FL
AG
S
Meth
od B
lank -
Open
<1
100
0<
1C
FU
/100 m
LS
M 9
222 B
2,5
,612/3
/2014
MM
Meth
od B
lank -
Clo
se
<1
100
0<
1C
FU
/100 m
LS
M 9
222 B
2,5
,612/3
/2014
MM
Fe
cal and/o
r T
ota
l C
olif
orm
s m
ust
be d
eliv
ere
d t
o t
he la
bora
tory
within
6 h
ours
of
sam
ple
colle
ctio
n.
Sam
ple
s m
ust
be f
iltere
d b
y t
he la
bora
tory
within
2 h
ours
of
recie
pt.
WA
-DO
E-L
abora
tory
Cert
ific
atio
n N
o.:
C890
"MR
L"
indic
ate
s M
eth
od R
eport
ing L
imit
Com
ments
and E
xpla
natio
ns:
A "
J"
fla
g in
dic
ate
s a
n e
stim
ate
d v
alu
e b
ecause t
he c
olo
ny c
ount
was o
uts
ide t
he o
ptim
um
range o
f colo
nie
s p
er
filter.
Data
revie
wed b
y:
TO
TA
L C
OL
IFO
RM
S A
NA
LY
TIC
AL
RE
SU
LT
S
page 1
of
1
CO
LIF
OR
M Q
UA
LIT
Y C
ON
TR
OL
R
ES
UL
TS
Meth
od
B
lan
k
DA
TE
/TIM
E
SA
MP
LE
FIL
TE
RE
D
DA
TE
/TIM
E
SA
MP
LE
RE
CE
IVE
D
DA
TE
/TIM
E
SA
MP
LE
CO
LL
EC
TE
D
City o
f S
helton
Pro
ject
Nam
e:
Monitorin
g W
ells
1000 W
est
Pin
e S
treet
Pro
ject
No.:
na
Shelton,
WA
98584
P.O
. N
o.:
na
Sam
ple
Nam
e:
WC
C-1
Sam
ple
d b
y:
John O
zga
Matr
ix:
Non-P
ota
ble
Wate
r
Te
mpera
ture
Receiv
ed (
°C):
11
Colle
cte
d:
12/2
/2014;
08:0
0
Receiv
ed:
12/2
/2014;
14:0
5
DA
L P
roje
ct
No
.: 1
41202-1
9R
eport
Date
: 12/1
9/2
014
Chlo
rid
e1.9
0.0
22
0.1
0m
g/L
EP
A 3
00.0
112/3
/2014
12/3
/2014
n/a
FW
Dis
solv
ed O
xygen
10.9
n/a
0.0
1m
g/L
SM
4500-O
G1
12/2
/2014
12/2
/2014
18:1
2M
M(1
)
Nitro
gen,
Nitra
te
0.0
46
0.0
26
0.1
0m
g/L
EP
A 3
00.0
112/3
/2014
12/3
/2014
n/a
FW
J
Nitro
gen,
Nitrite
nd
0.0
34
0.1
0m
g/L
EP
A 3
00.0
112/3
/2014
12/3
/2014
n/a
FW
Nitro
gen,
(TK
N)
0.2
80.3
62.0
mg/L
SM
4500-N
org
B1
12/1
0/2
014
12/1
0/2
014
n/a
MS
J
pH
6.5
n/a
n/a
SU
SM
4500-H
+1
12/3
/2014
12/3
/2014
17:5
0JB
(1)
Specific
Conducta
nce
50.6
n/a
10.0
um
ho/c
mS
M 2
510 B
112/9
/2014
12/9
/2014
n/a
JB
Solid
s,
To
tal D
issolv
ed
40.0
n/a
20.0
mg/L
SM
2540 C
112/2
/2014
12/2
/2014
n/a
GM
D
WA
-DO
E-L
abora
tory
Cert
ific
atio
n N
o.:
C890
"MD
L"
indic
ate
s M
eth
od D
ete
ctio
n L
imit
"MR
L"
indic
ate
s M
eth
od R
eport
ing L
imit
"DF
" in
dic
ate
s D
ilutio
n F
acto
r
"nd"
indic
ate
s t
he a
naly
te w
as n
ot
dete
cte
d a
t or
above t
he lis
ted M
eth
od R
eport
ing L
imit.
"n/a
" in
dic
ate
s n
ot
applic
able
Data
revie
wed b
y:
Report
Pre
pare
d B
y:
GM
D
Com
ments
and E
xpla
natio
ns:
A (
1)
fla
g I
ndic
ate
s a
n e
stim
ate
d v
alu
e,
because t
he s
am
ple
was r
eceiv
ed a
nd t
here
fore
analy
zed o
uts
ide o
f th
e r
ecom
mended a
nd r
egula
tory
hold
tim
e o
f 15 m
inute
s.
A
"J"
fla
g in
dic
ate
s a
n e
stim
ate
d v
alu
e t
hat
is g
reate
r th
an t
he M
DL b
ut
less t
han t
he M
RL.
PA
RA
ME
TE
RR
ES
UL
TS
MD
LM
RL
UN
ITS
ME
TH
OD
DF
PR
EP
AR
AT
ION
DA
TE
AN
AL
YS
IS
DA
TE
AN
AL
YS
IS
TIM
EA
NA
LY
ST
DA
TA
FL
AG
S
AN
AL
YT
ICA
L R
ES
UL
TS
page 1
of
6
City o
f S
helton
Pro
ject
Nam
e:
Monitorin
g W
ells
1000 W
est
Pin
e S
treet
Pro
ject
No.:
na
Shelton,
WA
98584
P.O
. N
o.:
na
Sam
ple
Nam
e:
WC
C-2
Sam
ple
d b
y:
John O
zga
Matr
ix:
Non-P
ota
ble
Wate
r
Te
mpera
ture
Receiv
ed (
°C):
11
Colle
cte
d:
12/2
/2014;
08:1
5
Receiv
ed:
12/2
/2014;
14:0
5
DA
L P
roje
ct
No
.: 1
41202-1
9R
eport
Date
: 12/1
9/2
014
Chlo
rid
e8.8
0.0
22
0.1
0m
g/L
EP
A 3
00.0
112/3
/2014
12/3
/2014
n/a
FW
Dis
solv
ed O
xygen
10.3
n/a
0.0
1m
g/L
SM
4500-O
G1
12/2
/2014
12/2
/2014
18:1
3M
M(1
)
Nitro
gen,
Nitra
te
0.8
00.0
26
0.1
0m
g/L
EP
A 3
00.0
112/3
/2014
12/3
/2014
n/a
FW
Nitro
gen,
Nitrite
nd
0.0
34
0.1
0m
g/L
EP
A 3
00.0
112/3
/2014
12/3
/2014
n/a
FW
Nitro
gen,
(TK
N)
0.8
40.3
62.0
mg/L
SM
4500-N
org
B1
12/1
0/2
014
12/1
0/2
014
n/a
MS
J
pH
6.6
n/a
n/a
SU
SM
4500-H
+1
12/3
/2014
12/3
/2014
17:5
6JB
(1)
Specific
Conducta
nce
101
n/a
10.0
um
ho/c
mS
M 2
510 B
112/9
/2014
12/9
/2014
n/a
JB
Solid
s,
To
tal D
issolv
ed
42.0
n/a
20.0
mg/L
SM
2540 C
112/2
/2014
12/2
/2014
n/a
GM
D
WA
-DO
E-L
abora
tory
Cert
ific
atio
n N
o.:
C890
"MD
L"
indic
ate
s M
eth
od D
ete
ctio
n L
imit
"MR
L"
indic
ate
s M
eth
od R
eport
ing L
imit
"DF
" in
dic
ate
s D
ilutio
n F
acto
r
"nd"
indic
ate
s t
he a
naly
te w
as n
ot
dete
cte
d a
t or
above t
he lis
ted M
eth
od R
eport
ing L
imit.
"n/a
" in
dic
ate
s n
ot
applic
able
Data
revie
wed b
y:
Report
Pre
pare
d B
y:
GM
D
Com
ments
and E
xpla
natio
ns:
A (
1)
fla
g I
ndic
ate
s a
n e
stim
ate
d v
alu
e,
because t
he s
am
ple
was r
eceiv
ed a
nd t
here
fore
analy
zed o
uts
ide o
f th
e r
ecom
mended a
nd r
egula
tory
hold
tim
e o
f 15 m
inute
s.
A
"J"
fla
g in
dic
ate
s a
n e
stim
ate
d v
alu
e t
hat
is g
reate
r th
an t
he M
DL b
ut
less t
han t
he M
RL.
DA
TA
FL
AG
S
AN
AL
YT
ICA
L R
ES
UL
TS
page 2
of
6
PA
RA
ME
TE
RR
ES
UL
TS
MD
LM
RL
UN
ITS
ME
TH
OD
DF
PR
EP
AR
AT
ION
DA
TE
AN
AL
YS
IS
DA
TE
AN
AL
YS
IS
TIM
EA
NA
LY
ST
City o
f S
helton
Pro
ject
Nam
e:
Monitorin
g W
ells
1000 W
est
Pin
e S
treet
Pro
ject
No.:
na
Shelton,
WA
98584
P.O
. N
o.:
na
Sam
ple
Nam
e:
MW
-6
Sam
ple
d b
y:
John O
zga
Matr
ix:
Non-P
ota
ble
Wate
r
Te
mpera
ture
Receiv
ed (
°C):
11
Colle
cte
d:
12/2
/2014;
08:3
0
Receiv
ed:
12/2
/2014;
14:0
5
DA
L P
roje
ct
No
.: 1
41202-1
9R
eport
Date
: 12/1
9/2
014
Chlo
rid
e3.3
0.0
22
0.1
0m
g/L
EP
A 3
00.0
112/3
/2014
12/3
/2014
n/a
FW
Dis
solv
ed O
xygen
10.3
n/a
0.0
1m
g/L
SM
4500-O
G1
12/2
/2014
12/2
/2014
18:1
4M
M(1
)
Nitro
gen,
Nitra
te
0.1
60.0
26
0.1
0m
g/L
EP
A 3
00.0
112/3
/2014
12/3
/2014
n/a
FW
Nitro
gen,
Nitrite
nd
0.0
34
0.1
0m
g/L
EP
A 3
00.0
112/3
/2014
12/3
/2014
n/a
FW
Nitro
gen,
(TK
N)
nd
0.3
62.0
mg/L
SM
4500-N
org
B1
12/1
0/2
014
12/1
0/2
014
n/a
MS
pH
6.5
n/a
n/a
SU
SM
4500-H
+1
12/3
/2014
12/3
/2014
17:5
7JB
(1)
Specific
Conducta
nce
58.5
n/a
10.0
um
ho/c
mS
M 2
510 B
112/9
/2014
12/9
/2014
n/a
JB
Solid
s,
To
tal D
issolv
ed
44.0
n/a
20.0
mg/L
SM
2540 C
112/2
/2014
12/2
/2014
n/a
GM
D
WA
-DO
E-L
abora
tory
Cert
ific
atio
n N
o.:
C890
"MD
L"
indic
ate
s M
eth
od D
ete
ctio
n L
imit
"MR
L"
indic
ate
s M
eth
od R
eport
ing L
imit
"DF
" in
dic
ate
s D
ilutio
n F
acto
r
"nd"
indic
ate
s t
he a
naly
te w
as n
ot
dete
cte
d a
t or
above t
he lis
ted M
eth
od R
eport
ing L
imit.
"n/a
" in
dic
ate
s n
ot
applic
able
Data
revie
wed b
y:
Report
Pre
pare
d B
y:
GM
D
Com
ments
and E
xpla
natio
ns:
A (
1)
fla
g I
ndic
ate
s a
n e
stim
ate
d v
alu
e,
because t
he s
am
ple
was r
eceiv
ed a
nd t
here
fore
analy
zed o
uts
ide o
f th
e r
ecom
mended a
nd r
egula
tory
hold
tim
e o
f 15 m
inute
s.
page 3
of
6
AN
AL
YT
ICA
L R
ES
UL
TS
PA
RA
ME
TE
RR
ES
UL
TS
MD
LM
RL
UN
ITS
AN
AL
YS
TD
AT
A
FL
AG
SM
ET
HO
DD
FP
RE
PA
RA
TIO
N
DA
TE
AN
AL
YS
IS
DA
TE
AN
AL
YS
IS
TIM
E
City o
f S
helton
Pro
ject
Nam
e:
Monitorin
g W
ells
1000 W
est
Pin
e S
treet
Pro
ject
No.:
na
Shelton,
WA
98584
P.O
. N
o.:
na
Sam
ple
Nam
e:
MW
-9
Sam
ple
d b
y:
John O
zga
Matr
ix:
Non-P
ota
ble
Wate
r
Te
mpera
ture
Receiv
ed (
°C):
11
Colle
cte
d:
12/2
/2014;
08:4
5
Receiv
ed:
12/2
/2014;
14:0
5
DA
L P
roje
ct
No
.: 1
41202-1
9R
eport
Date
: 12/1
9/2
014
Chlo
rid
e2.0
0.0
22
0.1
0m
g/L
EP
A 3
00.0
112/3
/2014
12/3
/2014
n/a
FW
Dis
solv
ed O
xygen
9.2
n/a
0.0
1m
g/L
SM
4500-O
G1
12/2
/2014
12/2
/2014
18:1
5M
M(1
)
Nitro
gen,
Nitra
te
0.1
00.0
26
0.1
0m
g/L
EP
A 3
00.0
112/3
/2014
12/3
/2014
n/a
FW
Nitro
gen,
Nitrite
nd
0.0
34
0.1
0m
g/L
EP
A 3
00.0
112/3
/2014
12/3
/2014
n/a
FW
Nitro
gen,
(TK
N)
0.2
80.3
62.0
mg/L
SM
4500-N
org
B1
12/1
0/2
014
12/1
0/2
014
n/a
MS
J
pH
6.0
n/a
n/a
SU
SM
4500-H
+1
12/2
/2014
12/2
/2014
17:5
9JB
(1)
Specific
Conducta
nce
97.4
n/a
10.0
um
ho/c
mS
M 2
510 B
112/9
/2014
12/9
/2014
n/a
JB
Solid
s,
To
tal D
issolv
ed
84.0
n/a
20.0
mg/L
SM
2540 C
112/2
/2014
12/2
/2014
n/a
GM
D
WA
-DO
E-L
abora
tory
Cert
ific
atio
n N
o.:
C890
"MD
L"
indic
ate
s M
eth
od D
ete
ctio
n L
imit
"MR
L"
indic
ate
s M
eth
od R
eport
ing L
imit
"DF
" in
dic
ate
s D
ilutio
n F
acto
r
"nd"
indic
ate
s t
he a
naly
te w
as n
ot
dete
cte
d a
t or
above t
he lis
ted M
eth
od R
eport
ing L
imit.
"n/a
" in
dic
ate
s n
ot
applic
able
Data
revie
wed b
y:
Report
Pre
pare
d B
y:
GM
D
page 4
of
6
AN
AL
YT
ICA
L R
ES
UL
TS
PA
RA
ME
TE
RR
ES
UL
TS
MD
LM
RL
UN
ITS
ME
TH
OD
DF
PR
EP
AR
AT
ION
DA
TE
AN
AL
YS
IS
DA
TE
AN
AL
YS
IS
TIM
EA
NA
LY
ST
DA
TA
FL
AG
S
Com
ments
and E
xpla
natio
ns:
A (
1)
fla
g I
ndic
ate
s a
n e
stim
ate
d v
alu
e,
because t
he s
am
ple
was r
eceiv
ed a
nd t
here
fore
analy
zed o
uts
ide o
f th
e r
ecom
mended a
nd r
egula
tory
hold
tim
e o
f 15 m
inute
s.
A
"J"
fla
g in
dic
ate
s a
n e
stim
ate
d v
alu
e t
hat
is g
reate
r th
an t
he M
DL b
ut
less t
han t
he M
RL.
City o
f S
helton
Pro
ject
Nam
e:
Monitorin
g W
ells
DA
L P
roje
ct
No
.: 1
41202-1
9P
roje
ct
No.:
na
141203-C
hlo
ride
Chlo
rid
end
0.1
0m
g/L
EP
A 3
00.0
12/3
/2014
FW
141202-D
OD
issolv
ed O
xygen
8.6
0.0
1m
g/L
SM
4500-O
G12/2
/2014
MM
141203-N
O
₃
Nitro
gen,
Nitra
te
nd
0.1
0m
g/L
EP
A 3
00.0
12/3
/2014
FW
141203-N
O
₂
Nitro
gen,
Nitrite
nd
0.1
0m
g/L
EP
A 3
00.0
12/3
/2014
FW
141210-T
KN
Nitro
gen,
(TK
N)
nd
2.0
mg/L
SM
4500-N
org
B12/1
0/2
014
MS
141203-p
HpH
n/a
n/a
SU
SM
4500-H
+n/a
n/a
141209-S
CS
pecific
Conducta
nce
nd
10.0
um
ho/c
mS
M 2
510 B
12/9
/2014
JB
141202-T
DS
Solid
s,
To
tal D
issolv
ed
nd
20.0
mg/L
SM
2540 C
12/2
/2014
GM
D
141203-C
hlo
ride
Chlo
rid
e1.9
1.9
mg/L
EP
A 3
00.0
0.6
3±35
12/3
/2014
FW
141202-D
OD
issolv
ed O
xygen
n/a
n/a
mg/L
SM
4500-O
G0.0
0±35
12/2
/2014
MM
(1)
141203-N
O
₃
Nitro
gen,
Nitra
te
nd
nd
mg/L
EP
A 3
00.0
0.0
0±35
12/3
/2014
FW
141203-N
O
₂
Nitro
gen,
Nitrite
nd
nd
mg/L
EP
A 3
00.0
0.0
0±35
12/3
/2014
FW
141210-T
KN
Nitro
gen,
(TK
N)
0.8
40.8
4m
g/L
SM
4500-N
org
B0.0
0±35
12/1
0/2
014
MS
141203-p
HpH
6.5
6.5
SU
SM
4500-H
+0.6
1±35
12/3
/2014
JB
(1)
141209-S
CS
pecific
Conducta
nce
97.4
97.3
um
ho/c
mS
M 2
510 B
0.0
1.0
112/9
/2014
JB
141202-T
DS
Solid
s,
To
tal D
issolv
ed
112
134
mg/L
SM
2540 C
17.9
±35
12/2
/2014
GM
D
WA
-DO
E-L
abora
tory
Cert
ific
atio
n N
o.:
C890
"MR
L"
indic
ate
s M
eth
od R
eport
ing L
imit
"RP
D"
indic
ate
s R
ela
tive P
erc
ent
Diffe
rence
"nd"
indic
ate
s t
he a
naly
te w
as n
ot
dete
cte
d a
t or
above t
he lis
ted M
eth
od R
eport
ing L
imit.
"n/a
" in
dic
ate
s n
ot
applic
able
Data
revie
wed b
y:
page 5
of
6
QU
AL
ITY
C
ON
TR
OL
R
ES
UL
TS
Meth
od
B
lan
k
QU
AL
ITY
C
ON
TR
OL
R
ES
UL
TS
Du
plicate
Sam
ple
SA
MP
LE
BA
TC
HP
AR
AM
ET
ER
RE
SU
LT
MR
LU
NIT
SA
NA
LY
TIC
AL
ME
TH
OD
SA
MP
LE
BA
TC
HP
AR
AM
ET
ER
RE
SU
LT
DU
P.
RE
SU
LT
UN
ITS
AN
AL
YT
ICA
L
ME
TH
OD
Com
ments
and E
xpla
natio
ns:
A (
1)
fla
g I
ndic
ate
s a
n e
stim
ate
d v
alu
e,
because t
he s
am
ple
was r
eceiv
ed a
nd t
here
fore
analy
zed o
uts
ide o
f th
e r
ecom
mended a
nd r
egula
tory
hold
tim
e o
f 15 m
inute
s.
A
NA
LY
SIS
DA
TE
AN
AL
YS
TD
AT
A
FL
AG
S
RP
D
(%)
LIM
ITS
(%)
AN
AL
YS
IS
DA
TE
AN
AL
YS
TD
AT
A
FL
AG
S
City o
f S
helton
Pro
ject
Nam
e:
Monitorin
g W
ells
DA
L P
roje
ct
No
.: 1
41202-1
9P
roje
ct
No.:
na
141203-C
hlo
ride
Chlo
rid
e0.4
90.5
0m
g/L
EP
A 3
00.0
98.2
65.0
-135
12/3
/2014
FW
141202-D
OD
issolv
ed O
xygen
n/a
n/a
mg/L
SM
4500-O
Gn/a
n/a
n/a
n/a
141203-N
O
₃
Nitro
gen,
Nitra
te
0.5
00.5
0m
g/L
EP
A 3
00.0
100
65.0
-135
12/3
/2014
FW
141203-N
O
₂
Nitro
gen,
Nitrite
0.5
10.5
0m
g/L
EP
A 3
00.0
102
65.0
-135
12/3
/2014
FW
141210-T
KN
Nitro
gen,
(TK
N)
19.6
20.0
mg/L
SM
4500-N
org
B98.0
65.0
-135
12/1
0/2
014
MS
141203-p
HpH
7.0
7.0
SU
SM
4500-H
+100
65.0
-135
12/3
/2014
JB
141209-S
CS
pecific
Conducta
nce
1420
1415
um
ho/c
mS
M 2
510 B
100
65.0
-135
12/9
/2014
JB
141202-T
DS
Solid
s,
To
tal D
issolv
ed
568
500
mg/L
SM
2540 C
114
65.0
-135
12/2
/2014
n/a
141203-C
hlo
ride
Chlo
rid
e0.4
70.4
90.5
0m
g/L
EP
A 3
00.0
2.7
±35
12/3
/2014
FW
141202-D
OD
issolv
ed O
xygen
n/a
n/a
n/a
mg/L
SM
4500-O
Gn/a
n/a
n/a
n/a
141203-N
O
₃
Nitro
gen,
Nitra
te
0.5
10.6
00.5
0m
g/L
EP
A 3
00.0
10.9
±35
12/3
/2014
FW
141203-N
O
₂
Nitro
gen,
Nitrite
0.5
40.5
30.5
0m
g/L
EP
A 3
00.0
1.1
±35
12/3
/2014
FW
141210-T
KN
Nitro
gen,
(TK
N)
18.8
19.4
20.0
mg/L
SM
4500-N
org
B2.1
±35
12/1
0/2
014
MS
141203-p
HpH
n/a
n/a
n/a
SU
SM
4500-H
+n/a
n/a
n/a
n/a
141209-S
CS
pecific
Conducta
nce
n/a
n/a
n/a
um
ho/c
mS
M 2
510 B
n/a
n/a
n/a
n/a
141202-T
DS
Solid
s,
To
tal D
issolv
ed
n/a
n/a
n/a
mg/L
SM
2540 C
n/a
n/a
n/a
n/a
WA
-DO
E-L
abora
tory
Cert
ific
atio
n N
o.:
C890
"RP
D"
indic
ate
s R
ela
tive P
erc
ent
Diffe
rence
"nd"
indic
ate
s t
he a
naly
te w
as n
ot
dete
cte
d a
t or
above t
he lis
ted M
eth
od R
eport
ing L
imit.
"n/a
" in
dic
ate
s n
ot
applic
able
Com
ments
and E
xpla
natio
ns:
None
Data
revie
wed b
y:
QU
AL
ITY
CO
NT
RO
L R
ES
UL
TS
Lab
ora
tory
Fo
rtif
ied
Bla
nk
QU
AL
ITY
CO
NT
RO
L R
ES
UL
TS
Matr
ix S
pik
e/M
atr
ix S
pik
e D
up
licate
page 6
of
6
SA
MP
LE
BA
TC
HP
AR
AM
ET
ER
LF
B
RE
SU
LT
T
RU
E
VA
LU
EU
NIT
SA
NA
LY
TIC
AL
ME
TH
OD
RE
CO
VE
RY
(%)
LIM
ITS
(%)
AN
AL
YS
IS
DA
TE
AN
AL
YS
TD
AT
A
FL
AG
S
SA
MP
LE
BA
TC
HP
AR
AM
ET
ER
MS
RE
SU
LT
MS
D
RE
SU
LT
TR
UE
VA
LU
E
DA
TA
FL
AG
SU
NIT
SA
NA
LY
TIC
AL
ME
TH
OD
RP
D
(%)
LIM
ITS
(%)
AN
AL
YS
IS
DA
TE
AN
AL
YS
T
City o
f S
helton
Pro
ject
Nam
e:
Monitorin
g W
ells
1000 W
est
Pin
e S
treet
Pro
ject
No.:
na
Shelton,
WA
98584
P.O
. N
o.:
na
Date
Colle
cte
d:
12/2
/2014;
08:0
0-0
8:4
5
Sam
ple
d B
y:
John O
zga
Date
Receiv
ed:
12/2
/2014;
14:0
5
Te
mpera
ture
Receiv
ed (
°C):
11
DA
L P
roje
ct
No
.: 1
41202-1
9R
eport
Date
:
Pre
para
tio
n M
eth
od:
US
EP
A 5
030B
Units:
ug/L
Analy
tical M
eth
od:
US
EP
A 8
260B
Matr
ix:
Non-P
ota
ble
Wate
r
Date
Pre
pare
d:
12/1
1/2
014
Report
ing L
imits:
Sta
ndard
Date
Analy
zed:
12/1
1/2
014
Purg
e V
olu
me:
15 m
L
Analy
st:
TM
Instr
um
ent
ID:
Agile
nt
3026
Data
Revie
wed B
y:
Lab D
ata
File
:14121014.
D
Sam
ple
Identificatio
nC
AS
No.
MR
L
Meth
od
Bla
nk
Trip
Bla
nk
WC
C-1
WC
C-2
MW
-6M
W-9
Bro
modic
hlo
rom
eth
ane
75-2
7-4
1.0
nd
nd
nd
0.1
1 J
nd
nd
Bro
mofo
rm75-2
5-2
1.0
nd
nd
nd
nd
nd
nd
Chlo
rofo
rm67-6
6-3
1.0
nd
nd
nd
3.9
0.3
6 J
nd
Dib
rom
ochlo
rom
eth
ane
124-4
8-1
1.0
nd
nd
nd
nd
nd
nd
Dilu
tio
n F
acto
r1.0
1.0
1.0
1.0
1.0
Data
Fla
gs
Com
ments
and E
xpla
natio
ns:
A "
J"
fla
g in
dic
ate
s a
n e
stim
ate
d v
alu
e t
hat
is g
reate
r th
an t
he M
DL b
ut
less t
han t
he M
RL.
12/1
9/2
014
TO
TA
L T
RIH
AL
OM
ET
HA
NE
S
AN
AL
YT
ICA
L R
ES
UL
TS
page 1
of
2
City o
f S
helton
Pro
ject
Nam
e:
Monitorin
g W
ells
DA
L P
roje
ct
No
.: 1
41202-1
9P
roje
ct
No.:
na
Surr
ogate
Lim
its (
%)
Meth
od
Bla
nk
Trip
Bla
nk
WC
C-1
WC
C-2
MW
-6M
W-9
Dib
rom
oflu
oro
meth
ane
86-1
18
102
104
101
103
102
100
To
luene-d
888-1
10
98.2
103
101
98.2
101
101
4-B
rom
oflu
oro
benzene
86-1
15
105
104
103
102
104
101
Analy
te
LC
S
Lim
its
(%)
LC
S
Level
(ug/L
)
LC
S
Recovery
(ug/L
)
LC
S
Perc
ent
Recovery
LC
SD
Recovery
(ug/L
)
LC
SD
Perc
ent
Recovery
Benzene
80-1
20
10.0
10.9
109%
10.9
109%
Chlo
robenzene
80-1
20
10.0
8.3
283.2
%11.5
115%
1,1
-Dic
hlo
roeth
ene
75-1
35
10.0
11.1
111%
10.0
100%
To
luene
80-1
20
10.0
12.0
120%
11.2
112%
Trichlo
roeth
ene
80-1
20
10.0
13.5
135%
11.7
117%
WA
-DO
E-L
abora
tory
Cert
ific
atio
n N
o.:
C890
"nd"
indic
ate
s t
he a
naly
te w
as n
ot
dete
cte
d a
t or
above t
he lis
ted M
eth
od R
eport
ing L
imit.
"n/a
" in
dic
ate
s n
ot
applic
able
page 2
of
2
QC
Batc
h I
D:
141211-V
OC
LC
S S
am
ple
ID
: 141211-V
OC
LC
SM
S/M
SD
Sam
ple
ID
: 141211-V
OC
MS
/MS
D
SU
RR
OG
AT
E R
EC
OV
ER
Y
VO
LA
TIL
E O
RG
AN
IC C
OM
PO
UN
DS
Com
ments
and E
xpla
natio
ns:
None.
LA
BO
RA
TO
RY
CO
NT
RO
L S
AM
PLE
AN
D M
AT
RIX
SP
IKE
QU
AL
ITY
CO
NT
RO
L R
ES
UL
TS
City o
f S
helton
Pro
ject
Nam
e:
Recla
imed S
pra
y F
ield
1000 W
est
Pin
e S
treet
Pro
ject
No.:
n/a
Shelton,
WA
98584
P.O
. N
o.:
n/a
Matr
ix:
Non-P
ota
ble
Wate
r
Sam
ple
d b
y:
John O
zga
Te
mpera
ture
Receiv
ed (
°C):
10 t
o 1
2
DA
L P
roje
ct
No
.: 1
41230-0
2R
eport
Date
: 12/3
1/2
014
SA
MP
LE
NA
ME
RE
SU
LT
S
SA
MP
LE
VO
LU
ME
(mL
)
FIL
TE
R
CO
UN
TM
RL
UN
ITS
ME
TH
OD
AN
AL
YS
IS
DA
TE
AN
AL
YS
TD
AT
A
FL
AG
S
WC
C 1
<10
10
0<
10
CF
U/1
00 m
LS
M 9
222 B
2,5
,612/3
0/2
014;
08:0
012/3
0/2
014;
09:4
012/3
0/2
014;
11:0
612/3
1/2
014
MM
WC
C 2
<10
10
0<
10
CF
U/1
00 m
LS
M 9
222 B
2,5
,612/3
0/2
014;
08:1
512/3
0/2
014;
09:4
012/3
0/2
014;
11:0
812/3
1/2
014
MM
MW
6<
10
10
0<
10
CF
U/1
00 m
LS
M 9
222 B
2,5
,612/3
0/2
014;
08:3
012/3
0/2
014;
09:4
012/3
0/2
014;
11:0
912/3
1/2
014
MM
MW
9<
10
10
0<
10
CF
U/1
00 m
LS
M 9
222 B
2,5
,612/3
0/2
014;
08:4
512/3
0/2
014;
09:4
012/3
0/2
014;
11:1
112/3
1/2
014
MM
SA
MP
LE
NA
ME
RE
SU
LT
S
SA
MP
LE
VO
LU
ME
(mL
)
FIL
TE
R
CO
UN
TM
RL
UN
ITS
ME
TH
OD
AN
AL
YS
IS
DA
TE
AN
AL
YS
TD
AT
A
FL
AG
S
Meth
od B
lank -
Open
<1
100
0<
1C
FU
/100 m
LS
M 9
222 B
2,5
,612/3
1/2
014
MM
Meth
od B
lank -
Clo
se
<1
100
0<
1C
FU
/100 m
LS
M 9
222 B
2,5
,612/3
1/2
014
MM
Fe
cal and/o
r T
ota
l C
olif
orm
s m
ust
be d
eliv
ere
d t
o t
he la
bora
tory
within
6 h
ours
of
sam
ple
colle
ctio
n.
Sam
ple
s m
ust
be f
iltere
d b
y t
he la
bora
tory
within
2 h
ours
of
recie
pt.
WA
-DO
E-L
abora
tory
Cert
ific
atio
n N
o.:
C890
"MR
L"
indic
ate
s M
eth
od R
eport
ing L
imit
Com
ments
and E
xpla
natio
ns:
None
Data
revie
wed b
y:
TO
TA
L C
OL
IFO
RM
S A
NA
LY
TIC
AL
RE
SU
LT
S
page 1
of
1
CO
LIF
OR
M Q
UA
LIT
Y C
ON
TR
OL
R
ES
UL
TS
Meth
od
B
lan
k
DA
TE
/TIM
E
SA
MP
LE
FIL
TE
RE
D
DA
TE
/TIM
E
SA
MP
LE
RE
CE
IVE
D
DA
TE
/TIM
E
SA
MP
LE
CO
LL
EC
TE
D
City o
f S
helton
Pro
ject
Nam
e:
Recla
imed S
pra
yfe
ild Q
uart
erly
1000 W
est
Pin
e S
treet
Pro
ject
No.:
n/a
Shelton,
WA
98584
P.O
. N
o.:
n/a
Date
Colle
cte
d:
3/2
/2015;
08:0
0-0
9:3
0
Sam
ple
d B
y:
John O
zga
Date
Receiv
ed:
3/2
/2015;
14:0
0
Te
mpera
ture
Receiv
ed (
°C):
9 t
o 1
0
DA
L P
roje
ct
No
.: 1
50302-0
7R
eport
Date
:
Data
Revie
wed b
y:
Pre
para
tio
n M
eth
od:
US
EP
A 3
010A
Units:
ug/L
Analy
tical M
eth
od:
US
EP
A 2
00.8
Matr
ix:
Non-P
ota
ble
Wate
r
Date
Pre
pare
d:
3/5
/2015
Report
ing L
imits:
Sta
ndard
Date
Analy
zed:
3/6
/2015
Instr
um
ent
ID:
Agile
nt
7500
Analy
st:
TM
Lab D
ata
File
:15C
06k00.B
Analy
teC
AS
No.
MR
L
Meth
od
Bla
nk
WC
C1
WC
C2
MW
6M
W9
Ars
enic
(A
s)
7440-3
8-2
5.0
nd
0.1
7 J
0.2
2 J
nd
nd
Cadm
ium
(C
d)
7440-4
3-9
5.0
nd
0.0
70 J
nd
0.1
2 J
0.0
45 J
Calc
ium
(C
a)
7440-7
0-2
500
nd
6,7
20
5,9
40
5,3
50
5,7
20
Chro
miu
m (
Cr)
7440-4
7-3
5.0
nd
4.6
J2.4
J2.1
J2.3
J
Copper
(Cu)
7440-5
0-8
5.0
nd
nd
nd
nd
nd
Lead (
Pb)
7439-9
2-1
1.0
nd
1.6
0.2
8 J
0.5
3 J
0.3
9 J
Magnesiu
m (
Mg)
7439-9
5-4
250
nd
2,5
70
1,7
90
1,6
30
1,9
10
Manganese (
Mn)
7439-9
6-5
5.0
nd
84.5
6.9
11.1
13.2
Merc
ury
(H
g)
7439-9
7-6
1.0
nd
nd
0.0
48 J
0.0
29 J
0.0
13 J
Nic
kel (N
i)7440-0
2-0
5.0
nd
nd
nd
nd
nd
Pota
ssiu
m (
K)
7440-0
9-7
1000
nd
23.4
Jnd
nd
nd
Silv
er
(Ag)
7440-2
2-4
10.0
nd
0.0
50 J
0.0
64 J
0.0
49 J
0.0
40 J
Sodiu
m (
Na)
7440-2
3-5
1000
nd
2,4
70
9,1
60
2,1
80
9,0
50
Zin
c (
Zn
)7440-6
6-6
10.0
nd
18.3
6.3
J6.4
J9.4
J
Dilu
tio
n F
acto
r10
10
10
10
10
Com
ments
and E
xpla
natio
ns:
A "
J"
fla
g in
dic
ate
s a
n e
stim
ate
d v
alu
e t
hat
is g
reate
r th
an t
he M
DL b
ut
less t
han t
he M
RL.
page 1
of
2
3/1
2/2
015
TO
TA
L H
EA
VY
ME
TA
LS
AN
AL
YT
ICA
L R
ES
UL
TS
City o
f S
helton
Pro
ject
Nam
e:
Recla
imed S
pra
yfe
ild Q
uart
erly
DA
L P
roje
ct
No
.: 1
50302-0
7P
roje
ct
No.:
n/a
Analy
te
MS
/MS
D
Level (u
g/L
)
Sam
ple
Conc.
(ug/L
)
MS
Recovery
(ug/L
)
MS
Perc
ent
Recovery
MS
D
Recovery
(ug/L
)
MS
D
Perc
ent
Recovery
MS
/MS
D
Lim
its
(%)
RP
D
MS
/MS
D
RP
D
Lim
its
LC
S
Level
(ug/L
)
LC
S
Recovery
(ug/L
)
LC
S
Perc
ent
Recovery
LC
S
Lim
its
(%)
Ars
enic
(A
s)
50
0.0
17
48.4
96.8
%49.2
98.3
%80-1
20
0.8
0≤ 2
0%
50
50.5
101%
80-1
20
Cadm
ium
(C
d)
50
0.0
070
49.2
98.3
%50.5
101%
80-1
20
1.4
≤ 2
0%
50
50.7
101%
80-1
20
Calc
ium
(C
a)
5000
672
5740
101%
5690
100%
80-1
20
0.5
0≤ 2
0%
5000
5240
105%
80-1
20
Chro
miu
m (
Cr)
50
0.4
650.2
99.5
%48.9
96.9
%80-1
20
1.3
≤ 2
0%
50
47.9
95.8
%80-1
20
Copper
(Cu)
50
nd
47.4
94.8
%45.6
91.2
%80-1
20
1.9
≤ 2
0%
50
44.3
88.6
%80-1
20
Lead (
Pb)
50
0.1
649.9
99.4
%51.6
103%
80-1
20
1.7
≤ 2
0%
50
50.0
100%
80-1
20
Magnesiu
m (
Mg)
5000
257
5160
98.1
%5000
94.9
%80-1
20
1.7
≤ 2
0%
5000
4872
97.4
%80-1
20
Manganese (
Mn)
50
8.4
58.2
99.5
%56.6
96.4
%80-1
20
1.6
≤ 2
0%
50
58.6
117%
80-1
20
Merc
ury
(H
g)
3.0
nd
2.6
85.7
%2.7
88.7
%80-1
20
1.7
≤ 2
0%
3.0
3.0
101%
80-1
20
Nic
kel (N
i)50
nd
48.0
96.1
%46.3
92.6
%80-1
20
1.8
≤ 2
0%
50
45.0
90.0
%80-1
20
Pota
ssiu
m (
K)
5000
2.3
4180
83.6
%4010
80.2
%80-1
20
2.1
≤ 2
0%
5000
5034
101%
80-1
20
Silv
er
(Ag)
50
0.0
050
48.4
96.8
%49.6
99.1
%80-1
20
1.2
≤ 2
0%
50
50.2
100%
80-1
20
Sodiu
m (
Na)
5000
247
5240
99.9
%5110
97.3
%80-1
20
1.3
≤ 2
0%
5000
4965
99.3
%80-1
20
Zin
c (
Zn
)50
1.8
50.8
97.9
%50.6
97.5
%80-1
20
0.1
8≤ 2
0%
50
49.8
99.5
%80-1
20
WA
-DO
E-L
abora
tory
Cert
ific
atio
n N
o.:
C890
"nd"
indic
ate
s t
he a
naly
te w
as n
ot
dete
cte
d a
t or
above t
he lis
ted M
eth
od R
eport
ing L
imit.
n/a
in
dic
ate
s n
ot
applic
able
page 2
of
2
Com
ments
and E
xpla
natio
ns:
None.
LA
BO
RA
TO
RY
CO
NT
RO
L S
AM
PLE
AN
D M
AT
RIX
SP
IKE
MS
/MS
D S
am
ple
ID
: 150306-M
eta
ls M
S/M
SD
TO
TA
L H
EA
VY
ME
TA
LS
QC
Batc
h I
D:
150306-M
eta
lsLC
S S
am
ple
ID
: 150306-M
eta
ls L
CS
QU
AL
ITY
CO
NT
RO
L R
ES
UL
TS
City o
f S
helton
Pro
ject
Nam
e:
Recla
imed S
pra
yfe
ild Q
uart
erly
1000 W
est
Pin
e S
treet
Pro
ject
No.:
n/a
Shelton,
WA
98584
P.O
. N
o.:
n/a
Date
Colle
cte
d:
3/2
/2015;
08:0
0-0
9:3
0
Sam
ple
d B
y:
John O
zga
Date
Receiv
ed:
3/2
/2015;
14:0
0
Te
mpera
ture
Receiv
ed (
°C):
9 t
o 1
0
DA
L P
roje
ct
No
.: 1
50302-0
7R
eport
Date
: 3/1
2/2
015
Pre
para
tio
n M
eth
od:
US
EP
A 5
030B
Units:
ug/L
Analy
tical M
eth
od:
US
EP
A 8
260B
Matr
ix:
Non-P
ota
ble
Wate
r
Date
Pre
pare
d:
3/4
/2015
Report
ing L
imits:
Sta
ndard
Date
Analy
zed:
3/5
/2015
Purg
e V
olu
me:
15 m
L
Analy
st:
TM
Instr
um
ent
ID:
Agile
nt
3026
Data
Revie
wed B
y:
GM
DLab D
ata
File
:15030401
Sam
ple
Identificatio
nC
AS
No.
MR
L
Meth
od
Bla
nk
WC
C1
WC
C2
MW
6M
W9
Bro
modic
hlo
rom
eth
ane
75-2
7-4
1.0
nd
nd
nd
nd
nd
Bro
mofo
rm75-2
5-2
1.0
nd
nd
nd
nd
nd
Chlo
rofo
rm67-6
6-3
1.0
nd
nd
2.1
nd
nd
Dib
rom
ochlo
rom
eth
ane
124-4
8-1
1.0
nd
nd
nd
nd
nd
Dilu
tio
n F
acto
r1.0
1.0
1.0
1.0
Data
Fla
gs
TO
TA
L T
RIH
AL
OM
ET
HA
NE
S
AN
AL
YT
ICA
L R
ES
UL
TS
page 1
of
2
City o
f S
helton
Pro
ject
Nam
e:
Recla
imed S
pra
yfe
ild Q
uart
erly
DA
L P
roje
ct
No
.: 1
50302-0
7P
roje
ct
No.:
n/a
Dic
hlo
robenzene
Surr
ogate
Lim
its (
%)
Meth
od
Bla
nk
WC
C1
WC
C2
MW
6M
W9
Dib
rom
oflu
oro
meth
ane
86-1
18
106
108
107
108
102
To
luene-d
888-1
10
95.6
97.6
94.8
96.4
96.2
4-B
rom
oflu
oro
benzene
86-1
15
89.8
99.0
100
97.0
97.6
1,2
-Dic
hlo
robenzene-d
480-1
20
102
103
103
104
104
Analy
te
LC
S L
imits
(%)
LC
S
Level
(ug/L
)
LC
S
Recovery
(ug/L
)
LC
S
Perc
ent
Recovery
LC
SD
Recovery
(ug/L
)
LC
SD
Perc
ent
Recovery
Benzene
80-1
20
10
10.1
101%
10.0
99.6
%
Chlo
robenzene
80-1
20
10
10.9
109%
10.5
105%
1,1
-Dic
hlo
roeth
ene
75-1
35
10
10.3
103%
10.0
99.5
%
To
luene
80-1
20
10
11.3
113%
11.7
117%
Trichlo
roeth
ene
80-1
20
10
11.9
119%
10.8
108%
WA
-DO
E-L
abora
tory
Cert
ific
atio
n N
o.:
C890
"nd"
indic
ate
s t
he a
naly
te w
as n
ot
dete
cte
d a
t or
above t
he lis
ted M
eth
od R
eport
ing L
imit.
"n/a
" in
dic
ate
s n
ot
applic
able
SU
RR
OG
AT
E R
EC
OV
ER
Y
TO
TA
L T
RIH
AL
OM
ET
HA
NE
S
QU
AL
ITY
CO
NT
RO
L R
ES
UL
TS
LA
BO
RA
TO
RY
CO
NT
RO
L S
AM
PLE
AN
D M
AT
RIX
SP
IKE
page 2
of
2
Com
ments
and E
xpla
natio
ns:
None.
QC
Batc
h I
D:
150305-V
OC
MS
/MS
D S
am
ple
ID
: 150305-V
OC
MS
/MS
D
LC
S S
am
ple
ID
: 150305-V
OC
LC
S
City o
f S
helton
Pro
ject
Nam
e:
Recla
imed S
pra
yfe
ild Q
uart
erly
1000 W
est
Pin
e S
treet
Pro
ject
No.:
n/a
Shelton,
WA
98584
P.O
. N
o.:
n/a
Matr
ix:
Non-P
ota
ble
Wate
r
Sam
ple
d b
y:
John O
zga
Te
mpera
ture
Receiv
ed (
°C):
9 t
o 1
0
DA
L P
roje
ct
No
.: 1
50302-0
7R
eport
Date
: 3/1
2/2
015
SA
MP
LE
NA
ME
RE
SU
LT
S
SA
MP
LE
VO
LU
ME
(mL
)
FIL
TE
R
CO
UN
TM
RL
UN
ITS
ME
TH
OD
AN
AL
YS
IS
DA
TE
AN
AL
YS
TD
AT
A
FL
AG
S
WC
C1
11
100
11
<1
CF
U/1
00 m
LS
M 9
222 B
2,5
,63/2
/2015;
08:0
03/2
/2015;
14:0
03/2
/2015;
15:4
63/3
/2015
MM
J
WC
C2
9100
9<
1C
FU
/100 m
LS
M 9
222 B
2,5
,63/2
/2015;
08:3
03/2
/2015;
14:0
03/2
/2015;
15:4
83/3
/2015
MM
J
MW
68
100
8<
1C
FU
/100 m
LS
M 9
222 B
2,5
,63/2
/2015;
09:0
03/2
/2015;
14:0
03/2
/2015;
15:5
03/3
/2015
MM
J
MW
910
100
10
<1
CF
U/1
00 m
LS
M 9
222 B
2,5
,63/2
/2015;
09:3
03/2
/2015;
14:0
03/2
/2015;
15:5
13/3
/2015
MM
J
Fe
cal and/o
r T
ota
l C
olif
orm
s m
ust
be d
eliv
ere
d t
o t
he la
bora
tory
within
6 h
ours
of
sam
ple
colle
ctio
n.
Sam
ple
s m
ust
be f
iltere
d b
y t
he la
bora
tory
within
2 h
ours
of
recie
pt.
WA
-DO
E-L
abora
tory
Cert
ific
atio
n N
o.:
C890
"MR
L"
indic
ate
s M
eth
od R
eport
ing L
imit
Com
ments
and E
xpla
natio
ns:
A "
J"
fla
g in
dic
ate
s a
n e
stim
ate
d v
alu
e b
ecause t
he c
olo
ny c
ount
was o
uts
ide t
he o
ptim
um
range o
f colo
nie
s p
er
filter.
Data
revie
wed b
y:
TO
TA
L C
OL
IFO
RM
S A
NA
LY
TIC
AL
RE
SU
LT
S
page 1
of
2
DA
TE
/TIM
E
SA
MP
LE
FIL
TE
RE
D
DA
TE
/TIM
E
SA
MP
LE
RE
CE
IVE
D
DA
TE
/TIM
E
SA
MP
LE
CO
LL
EC
TE
D
City o
f S
helton
Pro
ject
Nam
e:
Recla
imed S
pra
yfe
ild Q
uart
erly
DA
L P
roje
ct
No
.: 1
50302-0
7P
roje
ct
No.:
n/a
SA
MP
LE
NA
ME
RE
SU
LT
S
SA
MP
LE
VO
LU
ME
(mL
)
FIL
TE
R
CO
UN
TM
RL
UN
ITS
ME
TH
OD
AN
AL
YS
IS
DA
TE
AN
AL
YS
TD
AT
A
FL
AG
S
Meth
od B
lank -
Open
<1
100
0<
1C
FU
/100 m
LS
M 9
222 B
2,5
,63/3
/2015
MM
Meth
od B
lank -
Clo
se
<1
100
0<
1C
FU
/100 m
LS
M 9
222 B
2,5
,63/3
/2015
MM
Fe
cal and/o
r T
ota
l C
olif
orm
s m
ust
be d
eliv
ere
d t
o t
he la
bora
tory
within
6 h
ours
of
sam
ple
colle
ctio
n.
Sam
ple
s m
ust
be f
iltere
d b
y t
he la
bora
tory
within
2 h
ours
of
recie
pt.
WA
-DO
E-L
abora
tory
Cert
ific
atio
n N
o.:
C890
"MR
L"
indic
ate
s M
eth
od R
eport
ing L
imit
Com
ments
and E
xpla
natio
ns:
None
Data
revie
wed b
y:
page 2
of
2
CO
LIF
OR
M Q
UA
LIT
Y C
ON
TR
OL
R
ES
UL
TS
Meth
od
B
lan
k
City o
f S
helton
Pro
ject
Nam
e:
Recla
imed S
pra
yfe
ild Q
uart
erly
1000 W
est
Pin
e S
treet
Pro
ject
No.:
n/a
Shelton,
WA
98584
P.O
. N
o.:
n/a
Sam
ple
Nam
e:
WC
C1
Sam
ple
d b
y:
John O
zga
Matr
ix:
Non-P
ota
ble
Wate
r
Te
mpera
ture
Receiv
ed (
°C):
9 t
o 1
0
Colle
cte
d:
3/2
/2015;
08:0
0
Receiv
ed:
3/2
/2015;
14:0
0
DA
L P
roje
ct
No
.: 1
50302-0
7R
eport
Date
: 3/1
2/2
015
BiC
arb
onate
25.9
n/a
1.0
mg/L
SM
2320
13/4
/2015
3/4
/2015
n/a
JC
/CH
Carb
onate
nd
n/a
3.0
mg/L
SM
2320
13/4
/2015
3/4
/2015
n/a
JC
/CH
Chlo
rid
e1.8
0.0
22
0.1
0m
g/L
EP
A 3
00.0
13/2
/2015
3/2
/2015
n/a
FW
Dis
solv
ed O
xygen
6.7
n/a
0.0
1m
g/L
SM
4500-O
G1
3/2
/2015
3/2
/2015
16:4
1N
J(1
)
Flu
orid
e0.0
76
0.0
37
0.1
0m
g/L
EP
A 3
00.0
13/2
/2015
3/2
/2015
n/a
FW
J
Nitro
gen,
Nitra
te
0.0
84
0.0
26
0.1
0m
g/L
EP
A 3
00.0
13/2
/2015
3/2
/2015
n/a
FW
J
Nitro
gen,
Nitrite
nd
0.0
34
0.1
0m
g/L
EP
A 3
00.0
13/2
/2015
3/2
/2015
n/a
FW
Nitro
gen,
(TK
N)
nd
0.3
62.0
mg/L
SM
4500-N
org
B1
3/1
1/2
015
3/1
1/2
0015
n/a
MS
pH
6.6
n/a
n/a
SU
SM
4500-H
+1
3/2
/2015
3/2
/2015
17:1
4JC
(1)
Specific
Conducta
nce
57.3
n/a
10.0
um
ho/c
mS
M 2
510 B
13/2
/2015
3/2
/2015
n/a
NJ
Solid
s,
To
tal D
issolv
ed
62.0
n/a
20.0
mg/L
SM
2540 C
13/4
/2015
3/4
/2015
n/a
JB
Sulfate
1.0
0.0
15
0.1
0m
g/L
EP
A 3
00.0
13/2
/2015
3/2
/2015
n/a
FW
WA
-DO
E-L
abora
tory
Cert
ific
atio
n N
o.:
C890
"MD
L"
indic
ate
s M
eth
od D
ete
ctio
n L
imit
"MR
L"
indic
ate
s M
eth
od R
eport
ing L
imit
"DF
" in
dic
ate
s D
ilutio
n F
acto
r
"nd"
indic
ate
s t
he a
naly
te w
as n
ot
dete
cte
d a
t or
above t
he lis
ted M
eth
od R
eport
ing L
imit.
"n/a
" in
dic
ate
s n
ot
applic
able
Data
revie
wed b
y:
Report
Pre
pare
d B
y:
NJ
AN
AL
YT
ICA
L R
ES
UL
TS
page 1
of
8
PA
RA
ME
TE
RR
ES
UL
TS
MD
LM
RL
UN
ITS
ME
TH
OD
DF
PR
EP
AR
AT
ION
DA
TE
AN
AL
YS
IS
DA
TE
AN
AL
YS
IS
TIM
EA
NA
LY
ST
DA
TA
FL
AG
S
Com
ments
and E
xpla
natio
ns:
A (
1)
fla
g I
ndic
ate
s a
n e
stim
ate
d v
alu
e,
because t
he s
am
ple
was r
eceiv
ed a
nd t
here
fore
analy
zed o
uts
ide o
f th
e r
ecom
mended a
nd r
egula
tory
hold
tim
e o
f 15 m
inute
s.
A
"J"
fla
g in
dic
ate
s a
n e
stim
ate
d v
alu
e t
hat
is g
reate
r th
an t
he M
DL b
ut
less t
han t
he M
RL.
City o
f S
helton
Pro
ject
Nam
e:
Recla
imed S
pra
yfe
ild Q
uart
erly
1000 W
est
Pin
e S
treet
Pro
ject
No.:
n/a
Shelton,
WA
98584
P.O
. N
o.:
n/a
Sam
ple
Nam
e:
WC
C2
Sam
ple
d b
y:
John O
zga
Matr
ix:
Non-P
ota
ble
Wate
r
Te
mpera
ture
Receiv
ed (
°C):
9 t
o 1
0
Colle
cte
d:
3/2
/2015;
08:3
0
Receiv
ed:
3/2
/2015;
14:0
0
DA
L P
roje
ct
No
.: 1
50302-0
7R
eport
Date
: 3/1
2/2
015
BiC
arb
onate
30.3
n/a
1.0
mg/L
SM
2320
13/4
/2015
3/4
/2015
n/a
JC
/CH
Carb
onate
nd
n/a
3.0
mg/L
SM
2320
13/4
/2015
3/4
/2015
n/a
JC
/CH
Chlo
rid
e3.6
0.0
22
0.1
0m
g/L
EP
A 3
00.0
13/2
/2015
3/2
/2015
n/a
FW
Dis
solv
ed O
xygen
7.0
n/a
0.0
1m
g/L
SM
4500-O
G1
3/2
/2015
3/2
/2015
16:4
3N
J(1
)
Flu
orid
e0.0
69
0.0
37
0.1
0m
g/L
EP
A 3
00.0
13/2
/2015
3/2
/2015
n/a
FW
J
Nitro
gen,
Nitra
te
0.2
90.0
26
0.1
0m
g/L
EP
A 3
00.0
13/2
/2015
3/2
/2015
n/a
FW
Nitro
gen,
Nitrite
nd
0.0
34
0.1
0m
g/L
EP
A 3
00.0
13/2
/2015
3/2
/2015
n/a
FW
Nitro
gen,
(TK
N)
nd
0.3
62.0
mg/L
SM
4500-N
org
B1
3/1
1/2
0015
3/1
1/2
0015
n/a
MS
pH
6.7
n/a
n/a
SU
SM
4500-H
+1
3/2
/2015
3/2
/2015
17:1
9JC
(1)
Specific
Conducta
nce
76.2
n/a
10.0
um
ho/c
mS
M 2
510 B
13/2
/2015
3/2
/2015
n/a
NJ
Solid
s,
To
tal D
issolv
ed
66.0
n/a
20.0
mg/L
SM
2540 C
13/4
/2015
3/4
/2015
n/a
JB
Sulfate
2.2
0.0
15
0.1
0m
g/L
EP
A 3
00.0
13/2
/2015
3/2
/2015
n/a
FW
WA
-DO
E-L
abora
tory
Cert
ific
atio
n N
o.:
C890
"MD
L"
indic
ate
s M
eth
od D
ete
ctio
n L
imit
"MR
L"
indic
ate
s M
eth
od R
eport
ing L
imit
"DF
" in
dic
ate
s D
ilutio
n F
acto
r
"nd"
indic
ate
s t
he a
naly
te w
as n
ot
dete
cte
d a
t or
above t
he lis
ted M
eth
od R
eport
ing L
imit.
"n/a
" in
dic
ate
s n
ot
applic
able
Data
revie
wed b
y:
Report
Pre
pare
d B
y:
NJ
AN
AL
YT
ICA
L R
ES
UL
TS
page 2
of
8
PA
RA
ME
TE
RR
ES
UL
TS
MD
LM
RL
UN
ITS
ME
TH
OD
DF
PR
EP
AR
AT
ION
DA
TE
AN
AL
YS
IS
DA
TE
AN
AL
YS
IS
TIM
EA
NA
LY
ST
DA
TA
FL
AG
S
Com
ments
and E
xpla
natio
ns:
A (
1)
fla
g I
ndic
ate
s a
n e
stim
ate
d v
alu
e,
because t
he s
am
ple
was r
eceiv
ed a
nd t
here
fore
analy
zed o
uts
ide o
f th
e r
ecom
mended a
nd r
egula
tory
hold
tim
e o
f 15 m
inute
s.
A
"J"
fla
g in
dic
ate
s a
n e
stim
ate
d v
alu
e t
hat
is g
reate
r th
an t
he M
DL b
ut
less t
han t
he M
RL.
City o
f S
helton
Pro
ject
Nam
e:
Recla
imed S
pra
yfe
ild Q
uart
erly
1000 W
est
Pin
e S
treet
Pro
ject
No.:
n/a
Shelton,
WA
98584
P.O
. N
o.:
n/a
Sam
ple
Nam
e:
MW
6
Sam
ple
d b
y:
John O
zga
Matr
ix:
Non-P
ota
ble
Wate
r
Te
mpera
ture
Receiv
ed (
°C):
9 t
o 1
0
Colle
cte
d:
3/2
/2015;
09:0
0
Receiv
ed:
3/2
/2015;
14:0
0
DA
L P
roje
ct
No
.: 1
50302-0
7R
eport
Date
: 3/1
2/2
015
BiC
arb
onate
19.8
n/a
1.0
mg/L
SM
2320
13/4
/2015
3/4
/2015
n/a
JC
/CH
Carb
onate
nd
n/a
3.0
mg/L
SM
2320
13/4
/2015
3/4
/2015
n/a
JC
/CH
Chlo
rid
e1.7
0.0
22
0.1
0m
g/L
EP
A 3
00.0
13/2
/2015
3/2
/2015
n/a
FW
Dis
solv
ed O
xygen
6.7
n/a
0.0
1m
g/L
SM
4500-O
G1
3/2
/2015
3/2
/2015
16:4
4N
J(1
)
Flu
orid
e0.0
69
0.0
37
0.1
0m
g/L
EP
A 3
00.0
13/2
/2015
3/2
/2015
n/a
FW
J
Nitro
gen,
Nitra
te
0.1
20.0
26
0.1
0m
g/L
EP
A 3
00.0
13/2
/2015
3/2
/2015
n/a
FW
Nitro
gen,
Nitrite
nd
0.0
34
0.1
0m
g/L
EP
A 3
00.0
13/2
/2015
3/2
/2015
n/a
FW
Nitro
gen,
(TK
N)
nd
0.3
62.0
mg/L
SM
4500-N
org
B1
3/1
1/2
0015
3/1
1/2
0015
n/a
MS
pH
6.3
n/a
n/a
SU
SM
4500-H
+1
3/2
/2015
3/2
/2015
17:3
0JC
(1)
Specific
Conducta
nce
46.0
n/a
10.0
um
ho/c
mS
M 2
510 B
13/2
/2015
3/2
/2015
n/a
NJ
Solid
s,
To
tal D
issolv
ed
52.0
n/a
20.0
mg/L
SM
2540 C
13/4
/2015
3/4
/2015
n/a
JB
Sulfate
1.1
0.0
15
0.1
0m
g/L
EP
A 3
00.0
13/2
/2015
3/2
/2015
n/a
FW
WA
-DO
E-L
abora
tory
Cert
ific
atio
n N
o.:
C890
"MD
L"
indic
ate
s M
eth
od D
ete
ctio
n L
imit
"MR
L"
indic
ate
s M
eth
od R
eport
ing L
imit
"DF
" in
dic
ate
s D
ilutio
n F
acto
r
"nd"
indic
ate
s t
he a
naly
te w
as n
ot
dete
cte
d a
t or
above t
he lis
ted M
eth
od R
eport
ing L
imit.
"n/a
" in
dic
ate
s n
ot
applic
able
Data
revie
wed b
y:
Report
Pre
pare
d B
y:
NJ
page 3
of
8
AN
AL
YT
ICA
L R
ES
UL
TS
PA
RA
ME
TE
RR
ES
UL
TS
MD
LM
RL
UN
ITS
ME
TH
OD
DF
PR
EP
AR
AT
ION
DA
TE
AN
AL
YS
IS
DA
TE
AN
AL
YS
IS
TIM
EA
NA
LY
ST
DA
TA
FL
AG
S
Com
ments
and E
xpla
natio
ns:
A (
1)
fla
g I
ndic
ate
s a
n e
stim
ate
d v
alu
e,
because t
he s
am
ple
was r
eceiv
ed a
nd t
here
fore
analy
zed o
uts
ide o
f th
e r
ecom
mended a
nd r
egula
tory
hold
tim
e o
f 15 m
inute
s.
A
"J"
fla
g in
dic
ate
s a
n e
stim
ate
d v
alu
e t
hat
is g
reate
r th
an t
he M
DL b
ut
less t
han t
he M
RL.
City o
f S
helton
Pro
ject
Nam
e:
Recla
imed S
pra
yfe
ild Q
uart
erly
1000 W
est
Pin
e S
treet
Pro
ject
No.:
n/a
Shelton,
WA
98584
P.O
. N
o.:
n/a
Sam
ple
Nam
e:
MW
9
Sam
ple
d b
y:
John O
zga
Matr
ix:
Non-P
ota
ble
Wate
r
Te
mpera
ture
Receiv
ed (
°C):
9 t
o 1
0
Colle
cte
d:
3/2
/2015;
09:3
0
Receiv
ed:
3/2
/2015;
14:0
0
DA
L P
roje
ct
No
.: 1
50302-0
7R
eport
Date
: 3/1
2/2
015
BiC
arb
onate
30.8
n/a
1.0
mg/L
SM
2320
13/4
/2015
3/4
/2015
n/a
JC
/CH
Carb
onate
nd
n/a
3.0
mg/L
SM
2320
13/4
/2015
3/4
/2015
n/a
JC
/CH
Chlo
rid
e3.6
0.0
22
0.1
0m
g/L
EP
A 3
00.0
13/2
/2015
3/2
/2015
n/a
FW
Dis
solv
ed O
xygen
6.7
n/a
0.0
1m
g/L
SM
4500-O
G1
3/2
/2015
3/2
/2015
16:4
5N
J(1
)
Flu
orid
e0.0
64
0.0
37
0.1
0m
g/L
EP
A 3
00.0
13/2
/2015
3/2
/2015
n/a
FW
J
Nitro
gen,
Nitra
te
0.2
90.0
26
0.1
0m
g/L
EP
A 3
00.0
13/2
/2015
3/2
/2015
n/a
FW
Nitro
gen,
Nitrite
nd
0.0
34
0.1
0m
g/L
EP
A 3
00.0
13/2
/2015
3/2
/2015
n/a
FW
Nitro
gen,
(TK
N)
nd
0.3
62.0
mg/L
SM
4500-N
org
B1
3/1
1/2
0015
3/1
1/2
0015
n/a
MS
pH
6.3
n/a
n/a
SU
SM
4500-H
+1
3/2
/2015
3/2
/2015
17:3
0JC
(1)
Specific
Conducta
nce
45.9
n/a
10.0
um
ho/c
mS
M 2
510 B
13/2
/2015
3/2
/2015
n/a
NJ
Solid
s,
To
tal D
issolv
ed
56.0
n/a
20.0
mg/L
SM
2540 C
13/4
/2015
3/4
/2015
n/a
JB
Sulfate
2.2
0.0
15
0.1
0m
g/L
EP
A 3
00.0
13/2
/2015
3/2
/2015
n/a
FW
WA
-DO
E-L
abora
tory
Cert
ific
atio
n N
o.:
C890
"MD
L"
indic
ate
s M
eth
od D
ete
ctio
n L
imit
"MR
L"
indic
ate
s M
eth
od R
eport
ing L
imit
"DF
" in
dic
ate
s D
ilutio
n F
acto
r
"nd"
indic
ate
s t
he a
naly
te w
as n
ot
dete
cte
d a
t or
above t
he lis
ted M
eth
od R
eport
ing L
imit.
"n/a
" in
dic
ate
s n
ot
applic
able
Data
revie
wed b
y:
Report
Pre
pare
d B
y:
NJ
page 4
of
8
AN
AL
YT
ICA
L R
ES
UL
TS
PA
RA
ME
TE
RR
ES
UL
TS
MD
LM
RL
UN
ITS
ME
TH
OD
DF
PR
EP
AR
AT
ION
DA
TE
AN
AL
YS
IS
DA
TE
AN
AL
YS
IS
TIM
EA
NA
LY
ST
DA
TA
FL
AG
S
Com
ments
and E
xpla
natio
ns:
A (
1)
fla
g I
ndic
ate
s a
n e
stim
ate
d v
alu
e,
because t
he s
am
ple
was r
eceiv
ed a
nd t
here
fore
analy
zed o
uts
ide o
f th
e r
ecom
mended a
nd r
egula
tory
hold
tim
e o
f 15 m
inute
s.
A
"J"
fla
g in
dic
ate
s a
n e
stim
ate
d v
alu
e t
hat
is g
reate
r th
an t
he M
DL b
ut
less t
han t
he M
RL.
City o
f S
helton
Pro
ject
Nam
e:
Recla
imed S
pra
yfe
ild Q
uart
erly
DA
L P
roje
ct
No
.: 1
50302-0
7P
roje
ct
No.:
n/a
150304-B
iCarb
BiC
arb
onate
nd
n/a
mg/L
SM
2320
3/4
/2015
n/a
150304-C
arb
Carb
onate
nd
n/a
mg/L
SM
2320
3/4
/2015
n/a
150302-C
hlo
ride
Chlo
rid
end
0.1
0m
g/L
EP
A 3
00.0
3/2
/2015
FW
150302-D
OD
issolv
ed O
xygen
n/a
n/a
mg/L
SM
4500-O
Gn/a
n/a
150302-F
louride
Flu
orid
end
0.1
0m
g/L
EP
A 3
00.0
3/2
/2015
FW
150302-N
O
₃
Nitro
gen,
Nitra
te
nd
0.1
0m
g/L
EP
A 3
00.0
3/2
/2015
FW
150302-N
O
₂
Nitro
gen,
Nitrite
nd
0.1
0m
g/L
EP
A 3
00.0
3/2
/2015
FW
150311-T
KN
Nitro
gen,
(TK
N)
nd
2.0
mg/L
SM
4500-N
org
B3/1
1/2
0015
MS
150302-p
HpH
n/a
n/a
SU
SM
4500-H
+n/a
n/a
150302-S
CS
pecific
Conducta
nce
nd
10.0
um
ho/c
mS
M 2
510 B
3/2
/2015
NJ
150304-T
DS
Solid
s,
To
tal D
issolv
ed
nd
20.0
mg/L
SM
2540 C
3/4
/2015
JB
150302-S
ulfate
Sulfate
nd
0.1
0m
g/L
EP
A 3
00.0
3/2
/2015
FW
WA
-DO
E-L
abora
tory
Cert
ific
atio
n N
o.:
C890
"MR
L"
indic
ate
s M
eth
od R
eport
ing L
imit
"RP
D"
indic
ate
s R
ela
tive P
erc
ent
Diffe
rence
"nd"
indic
ate
s t
he a
naly
te w
as n
ot
dete
cte
d a
t or
above t
he lis
ted M
eth
od R
eport
ing L
imit.
"n/a
" in
dic
ate
s n
ot
applic
able
Com
ments
and E
xpla
natio
ns:
None
Data
revie
wed b
y:
QU
AL
ITY
C
ON
TR
OL
R
ES
UL
TS
Meth
od
B
lan
k
SA
MP
LE
BA
TC
HP
AR
AM
ET
ER
RE
SU
LT
MR
LU
NIT
SA
NA
LY
TIC
AL
ME
TH
OD
AN
AL
YS
IS
DA
TE
AN
AL
YS
TD
AT
A
FL
AG
S
page 5
of
8
City o
f S
helton
Pro
ject
Nam
e:
Recla
imed S
pra
yfe
ild Q
uart
erly
DA
L P
roje
ct
No
.: 1
50302-0
7P
roje
ct
No.:
n/a
150304-B
iCarb
BiC
arb
onate
25.9
25.3
mg/L
SM
2321
2.3
±35
3/4
/2015
JC
/CH
150304-C
arb
Carb
onate
nd
nd
mg/L
SM
2320
0.0
0±35
3/4
/2015
JC
/CH
150302-C
hlo
ride
Chlo
rid
e1.7
1.7
mg/L
EP
A 3
00.0
0.4
1±35
3/2
/2015
FW
150302-D
OD
issolv
ed O
xygen
6.7
6.9
mg/L
SM
4500-O
G2.7
±35
3/2
/2015
NJ
(1)
150302-F
louride
Flu
orid
end
nd
mg/L
EP
A 3
00.0
0.0
0±35
3/2
/2015
FW
150302-N
O
₃
Nitro
gen,
Nitra
te
0.1
20.1
1m
g/L
EP
A 3
00.0
0.8
7±35
3/2
/2015
FW
150302-N
O
₂
Nitro
gen,
Nitrite
nd
nd
mg/L
EP
A 3
00.0
0.0
0±35
3/2
/2015
FW
150311-T
KN
Nitro
gen,
(TK
N)
nd
nd
mg/L
SM
4500-N
org
B0.0
0±35
3/1
1/2
0015
MS
150302-p
HpH
6.9
6.9
SU
SM
4500-H
+0.5
8±35
3/2
/2015
JC
(1)
150302-S
CS
pecific
Conducta
nce
n/a
n/a
um
ho/c
mS
M 2
510 B
n/a
n/a
n/a
n/a
150304-T
DS
Solid
s,
To
tal D
issolv
ed
190
182
mg/L
SM
2540 C
4.3
±35
3/4
/2015
JB
150302-S
ulfate
Sulfate
1.1
1.1
mg/L
EP
A 3
00.0
2.1
±35
3/2
/2015
FW
WA
-DO
E-L
abora
tory
Cert
ific
atio
n N
o.:
C890
"MR
L"
indic
ate
s M
eth
od R
eport
ing L
imit
"RP
D"
indic
ate
s R
ela
tive P
erc
ent
Diffe
rence
"nd"
indic
ate
s t
he a
naly
te w
as n
ot
dete
cte
d a
t or
above t
he lis
ted M
eth
od R
eport
ing L
imit.
"n/a
" in
dic
ate
s n
ot
applic
able
Data
revie
wed b
y:
page 6
of
8
QU
AL
ITY
C
ON
TR
OL
R
ES
UL
TS
Du
plicate
Sam
ple
SA
MP
LE
BA
TC
HP
AR
AM
ET
ER
RE
SU
LT
DU
P.
RE
SU
LT
UN
ITS
AN
AL
YT
ICA
L
ME
TH
OD
Com
ments
and E
xpla
natio
ns:
A (
1)
fla
g I
ndic
ate
s a
n e
stim
ate
d v
alu
e,
because t
he s
am
ple
was r
eceiv
ed a
nd t
here
fore
analy
zed o
uts
ide o
f th
e r
ecom
mended a
nd r
egula
tory
hold
tim
e o
f 15 m
inute
s.
RP
D
(%)
LIM
ITS
(%)
AN
AL
YS
IS
DA
TE
AN
AL
YS
TD
AT
A
FL
AG
S
City o
f S
helton
Pro
ject
Nam
e:
Recla
imed S
pra
yfe
ild Q
uart
erly
DA
L P
roje
ct
No
.: 1
50302-0
7P
roje
ct
No.:
n/a
150304-B
iCarb
BiC
arb
onate
n/a
n/a
mg/L
SM
2320
n/a
n/a
n/a
n/a
150304-C
arb
Carb
onate
n/a
n/a
mg/L
SM
2320
n/a
n/a
n/a
n/a
150302-C
hlo
ride
Chlo
rid
e0.5
30.5
mg/L
EP
A 3
00.0
105
65.0
-135
3/2
/2015
FW
150302-D
OD
issolv
ed O
xygen
n/a
n/a
mg/L
SM
4500-O
Gn/a
n/a
n/a
n/a
150302-F
louride
Flu
orid
e0.5
00.5
mg/L
EP
A 3
00.0
100
65.0
-135
3/2
/2015
FW
150302-N
O
₃
Nitro
gen,
Nitra
te
0.4
60.5
mg/L
EP
A 3
00.0
91.4
65.0
-135
3/2
/2015
FW
150302-N
O
₂
Nitro
gen,
Nitrite
0.5
20.5
mg/L
EP
A 3
00.0
104
65.0
-135
3/2
/2015
FW
150311-T
KN
Nitro
gen,
(TK
N)
18.2
20.0
mg/L
SM
4500-N
org
B91.0
65.0
-135
3/1
1/2
0015
MS
150302-p
HpH
7.0
7.0
SU
SM
4500-H
+100
65.0
-135
3/2
/2015
JC
150302-S
CS
pecific
Conducta
nce
1414
1415
um
ho/c
mS
M 2
510 B
100
65.0
-135
3/2
/2015
NJ
150304-T
DS
Solid
s,
To
tal D
issolv
ed
488
500
mg/L
SM
2540 C
97.6
65.0
-135
3/4
/2015
n/a
150302-S
ulfate
Sulfate
0.5
40.5
mg/L
EP
A 3
00.0
107
65.0
-135
3/2
/2015
FW
WA
-DO
E-L
abora
tory
Cert
ific
atio
n N
o.:
C890
"RP
D"
indic
ate
s R
ela
tive P
erc
ent
Diffe
rence
"nd"
indic
ate
s t
he a
naly
te w
as n
ot
dete
cte
d a
t or
above t
he lis
ted M
eth
od R
eport
ing L
imit.
"n/a
" in
dic
ate
s n
ot
applic
able
Com
ments
and E
xpla
natio
ns:
None
Data
revie
wed b
y:
QU
AL
ITY
CO
NT
RO
L R
ES
UL
TS
Lab
ora
tory
Fo
rtif
ied
Bla
nk
SA
MP
LE
BA
TC
HP
AR
AM
ET
ER
LF
B
RE
SU
LT
T
RU
E
VA
LU
EU
NIT
SA
NA
LY
TIC
AL
ME
TH
OD
RE
CO
VE
RY
(%)
LIM
ITS
(%)
AN
AL
YS
IS
DA
TE
AN
AL
YS
TD
AT
A
FL
AG
S
page 7
of
8
City o
f S
helton
Pro
ject
Nam
e:
Recla
imed S
pra
yfe
ild Q
uart
erly
DA
L P
roje
ct
No
.: 1
50302-0
7P
roje
ct
No.:
n/a
150304-B
iCarb
BiC
arb
onate
n/a
n/a
n/a
mg/L
SM
2320
n/a
n/a
n/a
n/a
150304-C
arb
Carb
onate
n/a
n/a
n/a
mg/L
SM
2320
n/a
n/a
n/a
n/a
150302-C
hlo
ride
Chlo
rid
e0.4
90.5
00.5
mg/L
EP
A 3
00.0
1.2
±35
3/2
/2015
FW
150302-D
OD
issolv
ed O
xygen
n/a
n/a
n/a
mg/L
SM
4500-O
Gn/a
n/a
n/a
n/a
150302-F
louride
Flu
orid
e0.4
90.4
80.5
mg/L
EP
A 3
00.0
0.9
7±35
3/2
/2015
FW
150302-N
O
₃
Nitro
gen,
Nitra
te
0.4
40.4
60.5
mg/L
EP
A 3
00.0
2.6
±35
3/2
/2015
FW
150302-N
O
₂
Nitro
gen,
Nitrite
0.5
40.5
40.5
mg/L
EP
A 3
00.0
0.1
2±35
3/2
/2015
FW
150311-T
KN
Nitro
gen,
(TK
N)
18.2
18.2
20.0
mg/L
SM
4500-N
org
B0.0
0±35
3/1
1/2
0015
MS
150302-p
HpH
n/a
n/a
n/a
SU
SM
4500-H
+n/a
n/a
n/a
n/a
150302-S
CS
pecific
Conducta
nce
n/a
n/a
n/a
um
ho/c
mS
M 2
510 B
n/a
n/a
n/a
n/a
150304-T
DS
Solid
s,
To
tal D
issolv
ed
n/a
n/a
n/a
mg/L
SM
2540 C
n/a
n/a
n/a
n/a
150302-S
ulfate
Sulfate
0.5
80.6
20.5
mg/L
EP
A 3
00.0
4.4
±35
3/2
/2015
FW
WA
-DO
E-L
abora
tory
Cert
ific
atio
n N
o.:
C890
"RP
D"
indic
ate
s R
ela
tive P
erc
ent
Diffe
rence
"nd"
indic
ate
s t
he a
naly
te w
as n
ot
dete
cte
d a
t or
above t
he lis
ted M
eth
od R
eport
ing L
imit.
"n/a
" in
dic
ate
s n
ot
applic
able
Com
ments
and E
xpla
natio
ns:
None
Data
revie
wed b
y:
QU
AL
ITY
CO
NT
RO
L R
ES
UL
TS
Matr
ix S
pik
e/M
atr
ix S
pik
e D
up
licate
page 8
of
8
SA
MP
LE
BA
TC
HP
AR
AM
ET
ER
MS
RE
SU
LT
MS
D
RE
SU
LT
TR
UE
VA
LU
E
DA
TA
FL
AG
SU
NIT
SA
NA
LY
TIC
AL
ME
TH
OD
RP
D
(%)
LIM
ITS
(%)
AN
AL
YS
IS
DA
TE
AN
AL
YS
T
City o
f S
helton
Pro
ject
Nam
e:
WC
C S
pra
yfie
ld
1000 W
est
Pin
e S
treet
Pro
ject
No.:
n/a
Shelton,
WA
98584
P.O
. N
o.:
n/a
Matr
ix:
Non-P
ota
ble
Wate
r
Sam
ple
d b
y:
J.
Ozga
Te
mpera
ture
Receiv
ed (
°C):
n
/a
DA
L P
roje
ct
No
.: 1
50609-0
6R
eport
Date
: 6/2
3/2
015
SA
MP
LE
NA
ME
RE
SU
LT
S
SA
MP
LE
VO
LU
ME
(mL
)
FIL
TE
R
CO
UN
TM
RL
UN
ITS
ME
TH
OD
AN
AL
YS
IS
DA
TE
AN
AL
YS
TD
AT
A
FL
AG
S
WC
C 1
<1
100
0<
1C
FU
/100 m
LS
M 9
222 B
2,5
,66/9
/2015;
08:1
56/9
/2015;
13:4
56/9
/2015;
15:1
26/1
0/2
015
MM
WC
C 2
3100
3<
1C
FU
/100 m
LS
M 9
222 B
2,5
,66/9
/2015;
08:1
56/9
/2015;
13:4
56/9
/2015;
15:1
46/1
0/2
015
MM
J
MW
6<
1100
0<
1C
FU
/100 m
LS
M 9
222 B
2,5
,66/9
/2015;
08:1
56/9
/2015;
13:4
56/9
/2015;
15:1
56/1
0/2
015
MM
MW
9<
1100
0<
1C
FU
/100 m
LS
M 9
222 B
2,5
,66/9
/2015;
08:1
56/9
/2015;
13:4
56/9
/2015;
15:1
76/1
0/2
015
MM
SA
MP
LE
NA
ME
RE
SU
LT
S
SA
MP
LE
VO
LU
ME
(mL
)
FIL
TE
R
CO
UN
TM
RL
UN
ITS
ME
TH
OD
AN
AL
YS
IS
DA
TE
AN
AL
YS
TD
AT
A
FL
AG
S
Meth
od B
lank -
Open
<1
100
0<
1C
FU
/100 m
LS
M 9
222 B
2,5
,66/1
0/2
015
MM
Meth
od B
lank -
Clo
se
<1
100
0<
1C
FU
/100 m
LS
M 9
222 B
2,5
,66/1
0/2
015
MM
Fe
cal and/o
r T
ota
l C
olif
orm
s m
ust
be d
eliv
ere
d t
o t
he la
bora
tory
within
6 h
ours
of
sam
ple
colle
ctio
n.
Sam
ple
s m
ust
be f
iltere
d b
y t
he la
bora
tory
within
2 h
ours
of
recie
pt.
WA
-DO
E-L
abora
tory
Cert
ific
atio
n N
o.:
C890
"MR
L"
indic
ate
s M
eth
od R
eport
ing L
imit
Com
ments
and E
xpla
natio
ns:
A "
J"
fla
g in
dic
ate
s a
n e
stim
ate
d v
alu
e b
ecause t
he c
olo
ny c
ount
was o
uts
ide t
he o
ptim
um
range o
f colo
nie
s p
er
filter.
Data
revie
wed b
y:
TO
TA
L C
OL
IFO
RM
S A
NA
LY
TIC
AL
RE
SU
LT
S
page 1
of
1
CO
LIF
OR
M Q
UA
LIT
Y C
ON
TR
OL
R
ES
UL
TS
Meth
od
B
lan
k
DA
TE
/TIM
E
SA
MP
LE
FIL
TE
RE
D
DA
TE
/TIM
E
SA
MP
LE
RE
CE
IVE
D
DA
TE
/TIM
E
SA
MP
LE
CO
LL
EC
TE
D
City o
f S
helton
Pro
ject
Nam
e:
WC
C S
pra
yfie
ld
1000 W
est
Pin
e S
treet
Pro
ject
No.:
n/a
Shelton,
WA
98584
P.O
. N
o.:
n/a
Sam
ple
Nam
e:
WC
C 1
Sam
ple
d b
y:
J.
Ozga
Matr
ix:
Non-P
ota
ble
Wate
r
Te
mpera
ture
Receiv
ed (
°C):
n
/a
Colle
cte
d:
6/9
/2015;
08:1
5
Receiv
ed:
6/9
/2015;
13:4
5
DA
L P
roje
ct
No
.: 1
50609-0
6R
eport
Date
: 6/2
3/2
015
Chlo
rid
e1.6
0.0
22
0.1
0m
g/L
EP
A 3
00.0
16/1
0/2
015
6/1
0/2
015
n/a
FW
Nitro
gen,
Nitra
te
0.0
58
0.0
26
0.1
0m
g/L
EP
A 3
00.0
16/1
0/2
015
6/1
0/2
015
n/a
FW
J
Nitro
gen,
Nitrite
nd
0.0
34
0.1
0m
g/L
EP
A 3
00.0
16/1
0/2
015
6/1
0/2
015
n/a
FW
Nitro
gen,
(TK
N)
0.2
80.3
62.0
mg/L
SM
4500-N
org
B1
6/1
7/2
015
6/1
7/2
015
n/a
MS
N
pH
6.4
n/a
n/a
SU
SM
4500-H
+1
6/9
/2015
6/9
/2015
15:0
3M
S(1
)
Specific
Conducta
nce
56.0
n/a
10.0
um
ho/c
mS
M 2
510 B
16/1
1/2
015
6/1
1/2
015
n/a
JC
Solid
s,
To
tal D
issolv
ed
10.0
n/a
20.0
mg/L
SM
2540 C
16/1
6/2
015
6/1
5/2
015
n/a
JB
J
WA
-DO
E-L
abora
tory
Cert
ific
atio
n N
o.:
C890
"MD
L"
indic
ate
s M
eth
od D
ete
ctio
n L
imit
"MR
L"
indic
ate
s M
eth
od R
eport
ing L
imit
"DF
" in
dic
ate
s D
ilutio
n F
acto
r
"nd"
indic
ate
s t
he a
naly
te w
as n
ot
dete
cte
d a
t or
above t
he lis
ted M
eth
od R
eport
ing L
imit.
"n/a
" in
dic
ate
s n
ot
applic
able
Com
ments
and E
xpla
natio
ns:
A "
J"
fla
g in
dic
ate
s a
n e
stim
ate
d v
alu
e t
hat
is g
reate
r th
an t
he M
DL b
ut
less t
han t
he M
RL.
A (
1)
fla
g I
ndic
ate
s a
n e
stim
ate
d v
alu
e,
because t
he s
am
ple
was r
eceiv
ed a
nd t
here
fore
analy
zed o
uts
ide o
f th
e r
ecom
mended a
nd r
egula
tory
hold
tim
e o
f 15 m
inute
s.
A "
N"
fla
g I
ndic
ate
s a
naly
te w
as t
enta
tively
id
entifie
d b
elo
w t
he M
DL a
nd a
n e
stim
ate
d v
alu
e is p
rovid
ed.
Data
revie
wed b
y:
Report
Pre
pare
d B
y:
NJ
AN
AL
YT
ICA
L R
ES
UL
TS
page 1
of
6
PA
RA
ME
TE
RR
ES
UL
TS
MD
LM
RL
AN
AL
YS
TD
AT
A
FL
AG
SU
NIT
SM
ET
HO
DD
FP
RE
PA
RA
TIO
N
DA
TE
AN
AL
YS
IS
DA
TE
AN
AL
YS
IS
TIM
E
City o
f S
helton
Pro
ject
Nam
e:
WC
C S
pra
yfie
ld
1000 W
est
Pin
e S
treet
Pro
ject
No.:
n/a
Shelton,
WA
98584
P.O
. N
o.:
n/a
Sam
ple
Nam
e:
WC
C 2
Sam
ple
d b
y:
J.
Ozga
Matr
ix:
Non-P
ota
ble
Wate
r
Te
mpera
ture
Receiv
ed (
°C):
n
/a
Colle
cte
d:
6/9
/2015;
08:1
5
Receiv
ed:
6/9
/2015;
13:4
5
DA
L P
roje
ct
No
.: 1
50609-0
6R
eport
Date
: 6/2
3/2
015
Chlo
rid
e4.4
0.0
22
0.1
0m
g/L
EP
A 3
00.0
16/1
0/2
015
6/1
0/2
015
n/a
FW
Nitro
gen,
Nitra
te
0.3
60.0
26
0.1
0m
g/L
EP
A 3
00.0
16/1
0/2
015
6/1
0/2
015
n/a
FW
Nitro
gen,
Nitrite
nd
0.0
34
0.1
0m
g/L
EP
A 3
00.0
16/1
0/2
015
6/1
0/2
015
n/a
FW
Nitro
gen,
(TK
N)
0.2
80.3
62.0
mg/L
SM
4500-N
org
B1
6/1
7/2
015
6/1
7/2
015
n/a
MS
N
pH
6.6
n/a
n/a
SU
SM
4500-H
+1
6/9
/2015
6/9
/2015
15:0
4M
S(1
)
Specific
Conducta
nce
78.5
n/a
10.0
um
ho/c
mS
M 2
510 B
16/1
1/2
015
6/1
1/2
015
n/a
JC
Solid
s,
To
tal D
issolv
ed
24.0
n/a
20.0
mg/L
SM
2540 C
16/1
5/2
015
6/1
5/2
015
n/a
JB
WA
-DO
E-L
abora
tory
Cert
ific
atio
n N
o.:
C890
"MD
L"
indic
ate
s M
eth
od D
ete
ctio
n L
imit
"MR
L"
indic
ate
s M
eth
od R
eport
ing L
imit
"DF
" in
dic
ate
s D
ilutio
n F
acto
r
"nd"
indic
ate
s t
he a
naly
te w
as n
ot
dete
cte
d a
t or
above t
he lis
ted M
eth
od R
eport
ing L
imit.
"n/a
" in
dic
ate
s n
ot
applic
able
Com
ments
and E
xpla
natio
ns:
A (
1)
fla
g I
ndic
ate
s a
n e
stim
ate
d v
alu
e,
because t
he s
am
ple
was r
eceiv
ed a
nd t
here
fore
analy
zed o
uts
ide o
f th
e r
ecom
mended a
nd r
egula
tory
hold
tim
e o
f 15 m
inute
s.
A "
N"
fla
g I
ndic
ate
s a
naly
te w
as t
enta
tively
id
entifie
d b
elo
w t
he M
DL a
nd a
n e
stim
ate
d v
alu
e is p
rovid
ed.
Data
revie
wed b
y:
Report
Pre
pare
d B
y:
NJ
AN
AL
YT
ICA
L R
ES
UL
TS
page 2
of
6
PA
RA
ME
TE
RR
ES
UL
TS
MD
LM
RL
UN
ITS
ME
TH
OD
DF
PR
EP
AR
AT
ION
DA
TE
AN
AL
YS
IS
DA
TE
AN
AL
YS
IS
TIM
EA
NA
LY
ST
DA
TA
FL
AG
S
City o
f S
helton
Pro
ject
Nam
e:
WC
C S
pra
yfie
ld
1000 W
est
Pin
e S
treet
Pro
ject
No.:
n/a
Shelton,
WA
98584
P.O
. N
o.:
n/a
Sam
ple
Nam
e:
MW
6
Sam
ple
d b
y:
J.
Ozga
Matr
ix:
Non-P
ota
ble
Wate
r
Te
mpera
ture
Receiv
ed (
°C):
n
/a
Colle
cte
d:
6/9
/2015;
08:1
5
Receiv
ed:
6/9
/2015;
13:4
5
DA
L P
roje
ct
No
.: 1
50609-0
6R
eport
Date
: 6/2
3/2
015
Chlo
rid
e1.6
0.0
22
0.1
0m
g/L
EP
A 3
00.0
16/1
0/2
015
6/1
0/2
015
n/a
FW
Nitro
gen,
Nitra
te
0.0
91
0.0
26
0.1
0m
g/L
EP
A 3
00.0
16/1
0/2
015
6/1
0/2
015
n/a
FW
J
Nitro
gen,
Nitrite
nd
0.0
34
0.1
0m
g/L
EP
A 3
00.0
16/1
0/2
015
6/1
0/2
015
n/a
FW
Nitro
gen,
(TK
N)
nd
0.3
62.0
mg/L
SM
4500-N
org
B1
6/1
7/2
015
6/1
7/2
015
n/a
MS
pH
6.4
n/a
n/a
SU
SM
4500-H
+1
6/9
/2015
6/9
/2015
15:0
6M
S(1
)
Specific
Conducta
nce
49.7
n/a
10.0
um
ho/c
mS
M 2
510 B
16/1
1/2
015
6/1
1/2
015
n/a
JC
Solid
s,
To
tal D
issolv
ed
26.0
n/a
20.0
mg/L
SM
2540 C
16/1
5/2
015
6/1
5/2
015
n/a
JB
WA
-DO
E-L
abora
tory
Cert
ific
atio
n N
o.:
C890
"MD
L"
indic
ate
s M
eth
od D
ete
ctio
n L
imit
"MR
L"
indic
ate
s M
eth
od R
eport
ing L
imit
"DF
" in
dic
ate
s D
ilutio
n F
acto
r
"nd"
indic
ate
s t
he a
naly
te w
as n
ot
dete
cte
d a
t or
above t
he lis
ted M
eth
od R
eport
ing L
imit.
"n/a
" in
dic
ate
s n
ot
applic
able
Com
ments
and E
xpla
natio
ns:
A "
J"
fla
g in
dic
ate
s a
n e
stim
ate
d v
alu
e t
hat
is g
reate
r th
an t
he M
DL b
ut
less t
han t
he M
RL.
A (
1)
fla
g I
ndic
ate
s a
n e
stim
ate
d v
alu
e,
because t
he s
am
ple
was r
eceiv
ed a
nd t
here
fore
analy
zed o
uts
ide o
f th
e r
ecom
mended a
nd r
egula
tory
hold
tim
e o
f 15 m
inute
s.
Data
revie
wed b
y:
Report
Pre
pare
d B
y:
NJ
page 3
of
6
AN
AL
YT
ICA
L R
ES
UL
TS
PA
RA
ME
TE
RR
ES
UL
TS
MD
LM
RL
UN
ITS
ME
TH
OD
DF
PR
EP
AR
AT
ION
DA
TE
AN
AL
YS
IS
DA
TE
AN
AL
YS
IS
TIM
EA
NA
LY
ST
DA
TA
FL
AG
S
City o
f S
helton
Pro
ject
Nam
e:
WC
C S
pra
yfie
ld
1000 W
est
Pin
e S
treet
Pro
ject
No.:
n/a
Shelton,
WA
98584
P.O
. N
o.:
n/a
Sam
ple
Nam
e:
MW
9
Sam
ple
d b
y:
J.
Ozga
Matr
ix:
Non-P
ota
ble
Wate
r
Te
mpera
ture
Receiv
ed (
°C):
n
/a
Colle
cte
d:
6/9
/2015;
08:1
5
Receiv
ed:
6/9
/2015;
13:4
5
DA
L P
roje
ct
No
.: 1
50609-0
6R
eport
Date
: 6/2
3/2
015
Chlo
rid
e1.6
0.0
22
0.1
0m
g/L
EP
A 3
00.0
16/1
0/2
015
6/1
0/2
015
n/a
FW
Nitro
gen,
Nitra
te
0.1
40.0
26
0.1
0m
g/L
EP
A 3
00.0
16/1
0/2
015
6/1
0/2
015
n/a
FW
Nitro
gen,
Nitrite
nd
0.0
34
0.1
0m
g/L
EP
A 3
00.0
16/1
0/2
015
6/1
0/2
015
n/a
FW
Nitro
gen,
(TK
N)
nd
0.3
62.0
mg/L
SM
4500-N
org
B1
6/1
7/2
015
6/1
7/2
015
n/a
MS
N
pH
6.2
n/a
n/a
SU
SM
4500-H
+1
6/9
/2015
6/9
/2015
15:0
7M
S(1
)
Specific
Conducta
nce
41.1
n/a
10.0
um
ho/c
mS
M 2
510 B
16/1
1/2
015
6/1
1/2
015
n/a
JC
Solid
s,
To
tal D
issolv
ed
10.0
n/a
20.0
mg/L
SM
2540 C
16/1
5/2
015
6/1
5/2
015
n/a
JB
J
WA
-DO
E-L
abora
tory
Cert
ific
atio
n N
o.:
C890
"MD
L"
indic
ate
s M
eth
od D
ete
ctio
n L
imit
"MR
L"
indic
ate
s M
eth
od R
eport
ing L
imit
"DF
" in
dic
ate
s D
ilutio
n F
acto
r
"nd"
indic
ate
s t
he a
naly
te w
as n
ot
dete
cte
d a
t or
above t
he lis
ted M
eth
od R
eport
ing L
imit.
"n/a
" in
dic
ate
s n
ot
applic
able
Com
ments
and E
xpla
natio
ns:
A (
1)
fla
g I
ndic
ate
s a
n e
stim
ate
d v
alu
e,
because t
he s
am
ple
was r
eceiv
ed a
nd t
here
fore
analy
zed o
uts
ide o
f th
e r
ecom
mended a
nd r
egula
tory
hold
tim
e o
f 15 m
inute
s.
A "
N"
fla
g I
ndic
ate
s a
naly
te w
as t
enta
tively
id
entifie
d b
elo
w t
he M
DL a
nd a
n e
stim
ate
d v
alu
e is p
rovid
ed.
Data
revie
wed b
y:
Report
Pre
pare
d B
y:
NJ
page 4
of
6
AN
AL
YT
ICA
L R
ES
UL
TS
PA
RA
ME
TE
RR
ES
UL
TS
AN
AL
YS
IS
DA
TE
AN
AL
YS
IS
TIM
EA
NA
LY
ST
DA
TA
FL
AG
SD
FP
RE
PA
RA
TIO
N
DA
TE
MD
LM
RL
UN
ITS
ME
TH
OD
City o
f S
helton
Pro
ject
Nam
e:
WC
C S
pra
yfie
ld
DA
L P
roje
ct
No
.: 1
50609-0
6P
roje
ct
No.:
n/a
150610-C
hlo
ride
Chlo
rid
end
0.1
0m
g/L
EP
A 3
00.0
6/1
0/2
015
FW
150610-N
O
₃
Nitro
gen,
Nitra
te
nd
0.1
0m
g/L
EP
A 3
00.0
6/1
0/2
015
FW
150610-N
O
₂
Nitro
gen,
Nitrite
nd
0.1
0m
g/L
EP
A 3
00.0
6/1
0/2
015
FW
150617-T
KN
Nitro
gen,
(TK
N)
nd
2.0
mg/L
SM
4500-N
org
B6/1
7/2
015
MS
150609-p
HpH
n/a
n/a
SU
SM
4500-H
+n/a
n/a
150611-S
CS
pecific
Conducta
nce
nd
10.0
um
ho/c
mS
M 2
510 B
6/1
1/2
015
JC
150615-T
DS
Solid
s,
To
tal D
issolv
ed
nd
20.0
mg/L
SM
2540 C
6/1
5/2
015
JB
150610-C
hlo
ride
Chlo
rid
e5.0
5.0
mg/L
EP
A 3
00.0
0.0
80
±35
6/1
0/2
015
FW
150610-N
O
₃
Nitro
gen,
Nitra
te
1.3
1.3
mg/L
EP
A 3
00.0
0.1
5±35
6/1
0/2
015
FW
150610-N
O
₂
Nitro
gen,
Nitrite
nd
nd
mg/L
EP
A 3
00.0
0.0
0±35
6/1
0/2
015
FW
150617-T
KN
Nitro
gen,
(TK
N)
nd
nd
mg/L
SM
4500-N
org
B0.0
0±35
6/1
7/2
015
MS
150609-p
HpH
6.1
6.0
SU
SM
4500-H
+2.1
±35
6/9
/2015
MS
(1)
150611-S
CS
pecific
Conducta
nce
88.3
88.4
um
ho/c
mS
M 2
510 B
0.1
1±35
6/1
1/2
015
n/a
150615-T
DS
Solid
s,
To
tal D
issolv
ed
70.0
74.0
mg/L
SM
2540 C
5.6
±35
6/1
5/2
015
JB
WA
-DO
E-L
abora
tory
Cert
ific
atio
n N
o.:
C890
"MR
L"
indic
ate
s M
eth
od R
eport
ing L
imit
"RP
D"
indic
ate
s R
ela
tive P
erc
ent
Diffe
rence
"nd"
indic
ate
s t
he a
naly
te w
as n
ot
dete
cte
d a
t or
above t
he lis
ted M
eth
od R
eport
ing L
imit.
"n/a
" in
dic
ate
s n
ot
applic
able
Com
ments
and E
xpla
natio
ns:
None
Data
revie
wed b
y:
page 5
of
6
QU
AL
ITY
C
ON
TR
OL
R
ES
UL
TS
Meth
od
B
lan
k
QU
AL
ITY
C
ON
TR
OL
R
ES
UL
TS
Du
plicate
Sam
ple
SA
MP
LE
BA
TC
HP
AR
AM
ET
ER
RE
SU
LT
MR
LU
NIT
SA
NA
LY
TIC
AL
ME
TH
OD
AN
AL
YS
IS
DA
TE
AN
AL
YS
TD
AT
A
FL
AG
S
SA
MP
LE
BA
TC
HP
AR
AM
ET
ER
LIM
ITS
(%)
AN
AL
YS
IS
DA
TE
AN
AL
YS
TD
AT
A
FL
AG
SR
ES
UL
TD
UP
.
RE
SU
LT
UN
ITS
AN
AL
YT
ICA
L
ME
TH
OD
RP
D
(%)
City o
f S
helton
Pro
ject
Nam
e:
WC
C S
pra
yfie
ld
DA
L P
roje
ct
No
.: 1
50609-0
6P
roje
ct
No.:
n/a
150610-C
hlo
ride
Chlo
rid
e0.4
80.5
mg/L
EP
A 3
00.0
96.6
65.0
-135
6/1
0/2
015
FW
150610-N
O
₃
Nitro
gen,
Nitra
te
0.4
50.5
mg/L
EP
A 3
00.0
90.4
65.0
-135
6/1
0/2
015
FW
150610-N
O
₂
Nitro
gen,
Nitrite
0.5
20.5
mg/L
EP
A 3
00.0
103
65.0
-135
6/1
0/2
015
FW
150617-T
KN
Nitro
gen,
(TK
N)
19.0
20.0
mg/L
SM
4500-N
org
B95.2
65.0
-135
6/1
7/2
015
MS
150609-p
HpH
7.0
7.0
SU
SM
4500-H
+100
65.0
-135
6/9
/2015
MS
150611-S
CS
pecific
Conducta
nce
1436
1415
um
ho/c
mS
M 2
510 B
101
65.0
-135
6/1
1/2
015
JC
150615-T
DS
Solid
s,
To
tal D
issolv
ed
470
500
mg/L
SM
2540 C
94.0
65.0
-135
6/1
5/2
015
n/a
150610-C
hlo
ride
Chlo
rid
e0.4
80.4
80.5
mg/L
EP
A 3
00.0
0.2
1±35
6/1
0/2
015
FW
150610-N
O
₃
Nitro
gen,
Nitra
te
0.4
70.4
60.5
mg/L
EP
A 3
00.0
1.3
±35
6/1
0/2
015
FW
150610-N
O
₂
Nitro
gen,
Nitrite
0.5
40.5
30.5
mg/L
EP
A 3
00.0
2.0
±35
6/1
0/2
015
FW
150617-T
KN
Nitro
gen,
(TK
N)
17.4
18.2
20.0
mg/L
SM
4500-N
org
B4.7
±35
6/1
7/2
015
MS
150609-p
HpH
n/a
n/a
n/a
SU
SM
4500-H
+n/a
n/a
n/a
n/a
150611-S
CS
pecific
Conducta
nce
n/a
n/a
n/a
um
ho/c
mS
M 2
510 B
n/a
n/a
n/a
n/a
150615-T
DS
Solid
s,
To
tal D
issolv
ed
n/a
n/a
n/a
mg/L
SM
2540 C
n/a
n/a
n/a
n/a
WA
-DO
E-L
abora
tory
Cert
ific
atio
n N
o.:
C890
"RP
D"
indic
ate
s R
ela
tive P
erc
ent
Diffe
rence
"nd"
indic
ate
s t
he a
naly
te w
as n
ot
dete
cte
d a
t or
above t
he lis
ted M
eth
od R
eport
ing L
imit.
"n/a
" in
dic
ate
s n
ot
applic
able
Com
ments
and E
xpla
natio
ns:
None
Data
revie
wed b
y:
QU
AL
ITY
CO
NT
RO
L R
ES
UL
TS
Lab
ora
tory
Fo
rtif
ied
Bla
nk
QU
AL
ITY
CO
NT
RO
L R
ES
UL
TS
Matr
ix S
pik
e/M
atr
ix S
pik
e D
up
licate
page 6
of
6
SA
MP
LE
BA
TC
HP
AR
AM
ET
ER
LF
B
RE
SU
LT
T
RU
E
VA
LU
EU
NIT
SA
NA
LY
TIC
AL
ME
TH
OD
SA
MP
LE
BA
TC
HP
AR
AM
ET
ER
MS
RE
SU
LT
MS
D
RE
SU
LT
TR
UE
VA
LU
E
RE
CO
VE
RY
(%)
LIM
ITS
(%)
AN
AL
YS
IS
DA
TE
AN
AL
YS
TD
AT
A
FL
AG
S
DA
TA
FL
AG
SA
NA
LY
ST
UN
ITS
AN
AL
YT
ICA
L
ME
TH
OD
RP
D
(%)
LIM
ITS
(%)
AN
AL
YS
IS
DA
TE
City o
f S
helton
Pro
ject
Nam
e:
WC
C S
pra
yfie
ld
1000 W
est
Pin
e S
treet
Pro
ject
No.:
n/a
Shelton,
WA
98584
P.O
. N
o.:
n/a
Date
Colle
cte
d:
6/9
/2015;
08:1
5
Sam
ple
d B
y:
J.
Ozga
Date
Receiv
ed:
6/9
/2015;
13:4
5
Te
mpera
ture
Receiv
ed (
°C):
n/a
DA
L P
roje
ct
No
.: 1
50609-0
6R
eport
Date
:
Pre
para
tio
n M
eth
od:
US
EP
A 5
030B
Units:
ug/L
Analy
tical M
eth
od:
US
EP
A 8
260B
Matr
ix:
Non-P
ota
ble
Wate
r
Date
Pre
pare
d:
6/1
1/2
015
Report
ing L
imits:
Sta
ndard
Date
Analy
zed:
6/1
1/2
015
Purg
e V
olu
me:
15 m
L
Analy
st:
TM
Instr
um
ent
ID:
Agile
nt
3026
Data
Revie
wed B
y:
Lab D
ata
File
:15060902
Sam
ple
Identificatio
nC
AS
No.
MR
L
Meth
od
Bla
nk
WC
C 1
WC
C 2
MW
6M
W 9
MW
9
Dup.
Bro
modic
hlo
rom
eth
ane
75-2
7-4
1.0
nd
nd
nd
nd
nd
nd
Bro
mofo
rm75-2
5-2
1.0
nd
nd
nd
nd
nd
nd
Chlo
rofo
rm67-6
6-3
1.0
nd
nd
3.9
nd
nd
nd
Dib
rom
ochlo
rom
eth
ane
124-4
8-1
1.0
nd
nd
nd
nd
nd
nd
Dilu
tio
n F
acto
r1.0
1.0
1.0
1.0
1.0
Data
Fla
gs
AN
AL
YT
ICA
L R
ES
UL
TS
6/2
3/2
015
VO
LA
TIL
E O
RG
AN
IC C
OM
PO
UN
DS
page 1
of
2
City o
f S
helton
Pro
ject
Nam
e:
WC
C S
pra
yfie
ld
DA
L P
roje
ct
No
.: 1
50609-0
6P
roje
ct
No.:
n/a
Surr
ogate
Lim
its (
%)
Meth
od
Bla
nk
WC
C 1
WC
C 2
MW
6M
W 9
MW
9
Dup.
Dib
rom
oflu
oro
meth
ane
86-1
18
90.6
112
112
114
112
117
To
luene-d
888-1
10
106
102
107
106
104
105
4-B
rom
oflu
oro
benzene
86-1
15
102
98.8
105
99.4
107
97.2
1,2
-Dic
hlo
robenzene-d
480-1
20
109
102
109
108
104
101
Analy
te
LC
S
Lim
its
(%)
LC
S
Level
(ug/L
)
LC
S
Recovery
(ug/L
)
LC
S
Perc
ent
Recovery
LC
SD
Recovery
(ug/L
)
LC
SD
Perc
ent
Recovery
Benzene
76-1
27
10.0
10.0
99.9
%9.8
97.7
%
Chlo
robenzene
75-1
30
10.0
10.5
105%
10.0
99.7
%
1,1
-Dic
hlo
roeth
ene
61-1
45
10.0
8.6
86.0
%8.1
81.4
%
To
luene
76-1
25
10.0
9.7
96.9
%10.0
99.5
%
Trichlo
roeth
ene
71-1
20
10.0
10.3
103%
10.1
101%
WA
-DO
E-L
abora
tory
Cert
ific
atio
n N
o.:
C890
"nd"
indic
ate
s t
he a
naly
te w
as n
ot
dete
cte
d a
t or
above t
he lis
ted M
eth
od R
eport
ing L
imit.
"n/a
" in
dic
ate
s n
ot
applic
able
QC
Batc
h I
D:
150611-V
OC
LC
S S
am
ple
ID
: 150611-V
OC
LC
SM
S/M
SD
Sam
ple
ID
: 150611-V
OC
MS
/MS
D
page 2
of
2
Com
ments
and E
xpla
natio
ns:
None.
LA
BO
RA
TO
RY
CO
NT
RO
L S
AM
PLE
AN
D M
AT
RIX
SP
IKE
SU
RR
OG
AT
E R
EC
OV
ER
Y
QU
AL
ITY
CO
NT
RO
L R
ES
UL
TS
VO
LA
TIL
E O
RG
AN
IC C
OM
PO
UN
DS
City o
f S
helton
Pro
ject
Nam
e:
Qrt
ly S
pra
y F
ield
1000 W
est
Pin
e S
treet
Pro
ject
No.:
n/a
Shelton,
WA
98584
P.O
. N
o.:
n/a
Matr
ix:
Non-P
ota
ble
Wate
r
Sam
ple
d b
y:
Bre
nt
Arm
str
ong
Te
mpera
ture
Receiv
ed (
°C):
U
nk
no
wn
DA
L P
roje
ct
No
.: 1
50917-0
7R
eport
Date
: 10/1
/2015
SA
MP
LE
NA
ME
RE
SU
LT
S
SA
MP
LE
VO
LU
ME
(mL
)
FIL
TE
R
CO
UN
TM
RL
UN
ITS
ME
TH
OD
AN
AL
YS
IS
DA
TE
AN
AL
YS
TD
AT
A
FL
AG
S
WC
C-1
<1
100
0<
1C
FU
/100 m
LS
M 9
222 B
2,5
,69/1
7/2
015;
11:0
89/1
7/2
015;
15:0
09/1
7/2
015;
17:2
59/1
8/2
015
CH
/EK
WC
C-2
<1
100
0<
1C
FU
/100 m
LS
M 9
222 B
2,5
,69/1
7/2
015;
10:3
09/1
7/2
015;
15:0
09/1
7/2
015;
17:2
39/1
8/2
015
CH
/EK
MW
-6<
1100
0<
1C
FU
/100 m
LS
M 9
222 B
2,5
,69/1
7/2
015;
12:4
09/1
7/2
015;
15:0
09/1
7/2
015;
17:2
69/1
8/2
015
CH
/EK
MW
-9<
1100
0<
1C
FU
/100 m
LS
M 9
222 B
2,5
,69/1
7/2
015;
12:5
59/1
7/2
015;
15:0
09/1
7/2
015;
17:2
79/1
8/2
015
CH
/EK
SA
MP
LE
NA
ME
RE
SU
LT
S
SA
MP
LE
VO
LU
ME
(mL
)
FIL
TE
R
CO
UN
TM
RL
UN
ITS
ME
TH
OD
AN
AL
YS
IS
DA
TE
AN
AL
YS
TD
AT
A
FL
AG
S
Meth
od B
lank -
Open
<1
100
0<
1C
FU
/100 m
LS
M 9
222 B
2,5
,69/1
8/2
015
CH
/EK
Meth
od B
lank -
Clo
se
<1
100
0<
1C
FU
/100 m
LS
M 9
222 B
2,5
,69/1
8/2
015
CH
/EK
Fe
cal and/o
r T
ota
l C
olif
orm
s m
ust
be d
eliv
ere
d t
o t
he la
bora
tory
within
6 h
ours
of
sam
ple
colle
ctio
n.
Sam
ple
s m
ust
be f
iltere
d b
y t
he la
bora
tory
within
2 h
ours
of
recie
pt.
WA
-DO
E-L
abora
tory
Cert
ific
atio
n N
o.:
C890
"MR
L"
indic
ate
s M
eth
od R
eport
ing L
imit
Com
ments
and E
xpla
natio
ns:
None
Data
revie
wed b
y:
page 1
of
1
CO
LIF
OR
M Q
UA
LIT
Y C
ON
TR
OL
R
ES
UL
TS
Meth
od
B
lan
k
DA
TE
/TIM
E
SA
MP
LE
FIL
TE
RE
D
DA
TE
/TIM
E
SA
MP
LE
RE
CE
IVE
D
DA
TE
/TIM
E
SA
MP
LE
CO
LL
EC
TE
D
TO
TA
L C
OL
IFO
RM
S A
NA
LY
TIC
AL
RE
SU
LT
S
City o
f S
helton
Pro
ject
Nam
e:
Qrt
ly S
pra
y F
ield
1000 W
est
Pin
e S
treet
Pro
ject
No.:
n/a
Shelton,
WA
98584
P.O
. N
o.:
n/a
Sam
ple
Nam
e:
WC
C-1
Sam
ple
d b
y:
Bre
nt
Arm
str
ong
Matr
ix:
Non-P
ota
ble
Wate
r
Te
mpera
ture
Receiv
ed (
°C):
U
nk
no
wn
Colle
cte
d:
9/1
7/2
015;
11:0
8
Receiv
ed:
9/1
7/2
015;
15:0
0
DA
L P
roje
ct
No
.: 1
50917-0
7R
eport
Date
: 10/1
/2015
Chlo
rid
e2.0
0.0
22
0.1
0m
g/L
EP
A 3
00.0
19/1
7/2
015
9/1
7/2
015
n/a
NJ
Dis
solv
ed O
xygen
10.3
n/a
0.0
1m
g/L
SM
4500-O
G1
9/1
7/2
015
9/1
7/2
015
15:4
9N
J(1
)
Nitro
gen,
Nitra
te
0.0
60
0.0
26
0.1
0m
g/L
EP
A 3
00.0
19/1
7/2
015
9/1
7/2
015
n/a
NJ
J
Nitro
gen,
Nitrite
nd
0.0
34
0.1
0m
g/L
EP
A 3
00.0
19/1
7/2
015
9/1
7/2
015
n/a
NJ
Nitro
gen,
(TK
N)
1.7
0.3
62.0
mg/L
SM
4500-N
org
B1
9/3
0/2
015
9/3
0/2
015
n/a
MS
J
pH
5.8
n/a
n/a
SU
SM
4500-H
+1
9/1
7/2
015
9/1
7/2
015
17:1
5N
J(1
)
Specific
Conducta
nce
57.2
n/a
10.0
um
ho/c
mS
M 2
510 B
19/1
7/2
015
9/1
7/2
015
n/a
NJ
Solid
s,
To
tal D
issolv
ed
44.0
n/a
20.0
mg/L
SM
2540 C
19/2
3/2
015
9/2
3/2
015
n/a
JB
WA
-DO
E-L
abora
tory
Cert
ific
atio
n N
o.:
C890
"MD
L"
indic
ate
s M
eth
od D
ete
ctio
n L
imit
"MR
L"
indic
ate
s M
eth
od R
eport
ing L
imit
"DF
" in
dic
ate
s D
ilutio
n F
acto
r
"nd"
indic
ate
s t
he a
naly
te w
as n
ot
dete
cte
d a
t or
above t
he lis
ted M
eth
od R
eport
ing L
imit.
"n/a
" in
dic
ate
s n
ot
applic
able
Data
revie
wed b
y:
Report
Pre
pare
d B
y:
FW
AN
AL
YS
TD
AT
A
FL
AG
SP
AR
AM
ET
ER
RE
SU
LT
SM
DL
MR
LU
NIT
SM
ET
HO
DD
FP
RE
PA
RA
TIO
N
DA
TE
AN
AL
YT
ICA
L R
ES
UL
TS
page 1
of
6
AN
AL
YS
IS
DA
TE
AN
AL
YS
IS
TIM
E
Com
ments
and E
xpla
natio
ns:
A (
1)
fla
g I
ndic
ate
s a
n e
stim
ate
d v
alu
e,
because t
he s
am
ple
was r
eceiv
ed a
nd t
here
fore
analy
zed o
uts
ide o
f th
e r
ecom
mended a
nd r
egula
tory
hold
tim
e o
f 15 m
inute
s.
A
"J"
fla
g in
dic
ate
s a
n e
stim
ate
d v
alu
e t
hat
is g
reate
r th
an t
he M
DL b
ut
less t
han t
he M
RL.
City o
f S
helton
Pro
ject
Nam
e:
Qrt
ly S
pra
y F
ield
1000 W
est
Pin
e S
treet
Pro
ject
No.:
n/a
Shelton,
WA
98584
P.O
. N
o.:
n/a
Sam
ple
Nam
e:
WC
C-2
Sam
ple
d b
y:
Bre
nt
Arm
str
ong
Matr
ix:
Non-P
ota
ble
Wate
r
Te
mpera
ture
Receiv
ed (
°C):
U
nk
no
wn
Colle
cte
d:
9/1
7/2
015;
10:3
0
Receiv
ed:
9/1
7/2
015;
15:0
0
DA
L P
roje
ct
No
.: 1
50917-0
7R
eport
Date
: 10/1
/2015
Chlo
rid
e8.8
0.0
22
0.1
0m
g/L
EP
A 3
00.0
19/1
7/2
015
9/1
7/2
015
n/a
NJ
Dis
solv
ed O
xygen
10.1
n/a
0.0
1m
g/L
SM
4500-O
G1
9/1
7/2
015
9/1
7/2
015
15:5
0N
J(1
)
Nitro
gen,
Nitra
te
0.8
30.0
26
0.1
0m
g/L
EP
A 3
00.0
19/1
7/2
015
9/1
7/2
015
n/a
NJ
Nitro
gen,
Nitrite
nd
0.0
34
0.1
0m
g/L
EP
A 3
00.0
19/1
7/2
015
9/1
7/2
015
n/a
NJ
Nitro
gen,
(TK
N)
2.2
0.3
62.0
mg/L
SM
4500-N
org
B1
9/3
0/2
015
9/3
0/2
015
n/a
MS
pH
5.9
n/a
n/a
SU
SM
4500-H
+1
9/1
7/2
015
9/1
7/2
015
17:1
7N
J(1
)
Specific
Conducta
nce
95.8
n/a
10.0
um
ho/c
mS
M 2
510 B
19/1
7/2
015
9/1
7/2
015
n/a
NJ
Solid
s,
To
tal D
issolv
ed
68.0
n/a
20.0
mg/L
SM
2540 C
19/2
3/2
015
9/2
3/2
015
n/a
JB
WA
-DO
E-L
abora
tory
Cert
ific
atio
n N
o.:
C890
"MD
L"
indic
ate
s M
eth
od D
ete
ctio
n L
imit
"MR
L"
indic
ate
s M
eth
od R
eport
ing L
imit
"DF
" in
dic
ate
s D
ilutio
n F
acto
r
"nd"
indic
ate
s t
he a
naly
te w
as n
ot
dete
cte
d a
t or
above t
he lis
ted M
eth
od R
eport
ing L
imit.
"n/a
" in
dic
ate
s n
ot
applic
able
Com
ments
and E
xpla
natio
ns:
A (
1)
fla
g I
ndic
ate
s a
n e
stim
ate
d v
alu
e,
because t
he s
am
ple
was r
eceiv
ed a
nd t
here
fore
analy
zed o
uts
ide o
f th
e r
ecom
mended a
nd r
egula
tory
hold
tim
e o
f 15 m
inute
s.
Data
revie
wed b
y:
Report
Pre
pare
d B
y:
FW
AN
AL
YS
IS
DA
TE
AN
AL
YS
IS
TIM
EA
NA
LY
ST
DA
TA
FL
AG
SP
AR
AM
ET
ER
RE
SU
LT
SM
DL
MR
LU
NIT
SM
ET
HO
DD
FP
RE
PA
RA
TIO
N
DA
TE
AN
AL
YT
ICA
L R
ES
UL
TS
page 2
of
6
City o
f S
helton
Pro
ject
Nam
e:
Qrt
ly S
pra
y F
ield
1000 W
est
Pin
e S
treet
Pro
ject
No.:
n/a
Shelton,
WA
98584
P.O
. N
o.:
n/a
Sam
ple
Nam
e:
MW
-6
Sam
ple
d b
y:
Bre
nt
Arm
str
ong
Matr
ix:
Non-P
ota
ble
Wate
r
Te
mpera
ture
Receiv
ed (
°C):
U
nk
no
wn
Colle
cte
d:
9/1
7/2
015;
12:4
0
Receiv
ed:
9/1
7/2
015;
15:0
0
DA
L P
roje
ct
No
.: 1
50917-0
7R
eport
Date
: 10/1
/2015
Chlo
rid
e1.9
0.0
22
0.1
0m
g/L
EP
A 3
00.0
19/1
7/2
015
9/1
7/2
015
n/a
NJ
Dis
solv
ed O
xygen
10.6
n/a
0.0
1m
g/L
SM
4500-O
G1
9/1
7/2
015
9/1
7/2
015
15:5
1N
J(1
)
Nitro
gen,
Nitra
te
0.1
70.0
26
0.1
0m
g/L
EP
A 3
00.0
19/1
7/2
015
9/1
7/2
015
n/a
NJ
Nitro
gen,
Nitrite
nd
0.0
34
0.1
0m
g/L
EP
A 3
00.0
19/1
7/2
015
9/1
7/2
015
n/a
NJ
Nitro
gen,
(TK
N)
1.4
0.3
62.0
mg/L
SM
4500-N
org
B1
9/3
0/2
015
9/3
0/2
015
n/a
MS
J
pH
5.9
n/a
n/a
SU
SM
4500-H
+1
9/1
7/2
015
9/1
7/2
015
17:1
8N
J(1
)
Specific
Conducta
nce
52.8
n/a
10.0
um
ho/c
mS
M 2
510 B
19/1
7/2
015
9/1
7/2
015
n/a
NJ
Solid
s,
To
tal D
issolv
ed
32.0
n/a
20.0
mg/L
SM
2540 C
19/2
3/2
015
9/2
3/2
015
n/a
JB
WA
-DO
E-L
abora
tory
Cert
ific
atio
n N
o.:
C890
"MD
L"
indic
ate
s M
eth
od D
ete
ctio
n L
imit
"MR
L"
indic
ate
s M
eth
od R
eport
ing L
imit
"DF
" in
dic
ate
s D
ilutio
n F
acto
r
"nd"
indic
ate
s t
he a
naly
te w
as n
ot
dete
cte
d a
t or
above t
he lis
ted M
eth
od R
eport
ing L
imit.
"n/a
" in
dic
ate
s n
ot
applic
able
Data
revie
wed b
y:
Report
Pre
pare
d B
y:
FW
DF
PR
EP
AR
AT
ION
DA
TE
AN
AL
YS
IS
DA
TE
AN
AL
YS
IS
TIM
EA
NA
LY
ST
DA
TA
FL
AG
SP
AR
AM
ET
ER
RE
SU
LT
SM
DL
MR
LU
NIT
SM
ET
HO
D
AN
AL
YT
ICA
L R
ES
UL
TS
Com
ments
and E
xpla
natio
ns:
A (
1)
fla
g I
ndic
ate
s a
n e
stim
ate
d v
alu
e,
because t
he s
am
ple
was r
eceiv
ed a
nd t
here
fore
analy
zed o
uts
ide o
f th
e r
ecom
mended a
nd r
egula
tory
hold
tim
e o
f 15 m
inute
s.
A
"J"
fla
g in
dic
ate
s a
n e
stim
ate
d v
alu
e t
hat
is g
reate
r th
an t
he M
DL b
ut
less t
han t
he M
RL.
page 3
of
6
City o
f S
helton
Pro
ject
Nam
e:
Qrt
ly S
pra
y F
ield
1000 W
est
Pin
e S
treet
Pro
ject
No.:
n/a
Shelton,
WA
98584
P.O
. N
o.:
n/a
Sam
ple
Nam
e:
MW
-9
Sam
ple
d b
y:
Bre
nt
Arm
str
ong
Matr
ix:
Non-P
ota
ble
Wate
r
Te
mpera
ture
Receiv
ed (
°C):
U
nk
no
wn
Colle
cte
d:
9/1
7/2
015;
12:5
5
Receiv
ed:
9/1
7/2
015;
15:0
0
DA
L P
roje
ct
No
.: 1
50917-0
7R
eport
Date
: 10/1
/2015
Chlo
rid
e2.2
0.0
22
0.1
0m
g/L
EP
A 3
00.0
19/1
7/2
015
9/1
7/2
015
n/a
NJ
Dis
solv
ed O
xygen
10.3
n/a
0.0
1m
g/L
SM
4500-O
G1
9/1
7/2
015
9/1
7/2
015
15:5
3N
J(1
)
Nitro
gen,
Nitra
te
0.1
30.0
26
0.1
0m
g/L
EP
A 3
00.0
19/1
7/2
015
9/1
7/2
015
n/a
NJ
Nitro
gen,
Nitrite
nd
0.0
34
0.1
0m
g/L
EP
A 3
00.0
19/1
7/2
015
9/1
7/2
015
n/a
NJ
Nitro
gen,
(TK
N)
0.2
80.3
62.0
mg/L
SM
4500-N
org
B1
9/3
0/2
015
9/3
0/2
015
n/a
MS
J
pH
5.6
n/a
n/a
SU
SM
4500-H
+1
9/1
7/2
015
9/1
7/2
015
17:2
1N
J(1
)
Specific
Conducta
nce
49.3
n/a
10.0
um
ho/c
mS
M 2
510 B
19/1
7/2
015
9/1
7/2
015
n/a
NJ
Solid
s,
To
tal D
issolv
ed
30.0
n/a
20.0
mg/L
SM
2540 C
19/2
3/2
015
9/2
3/2
015
n/a
JB
WA
-DO
E-L
abora
tory
Cert
ific
atio
n N
o.:
C890
"MD
L"
indic
ate
s M
eth
od D
ete
ctio
n L
imit
"MR
L"
indic
ate
s M
eth
od R
eport
ing L
imit
"DF
" in
dic
ate
s D
ilutio
n F
acto
r
"nd"
indic
ate
s t
he a
naly
te w
as n
ot
dete
cte
d a
t or
above t
he lis
ted M
eth
od R
eport
ing L
imit.
"n/a
" in
dic
ate
s n
ot
applic
able
Data
revie
wed b
y:
Report
Pre
pare
d B
y:
FW
AN
AL
YS
IS
DA
TE
AN
AL
YS
IS
TIM
EA
NA
LY
ST
DA
TA
FL
AG
SM
DL
MR
LU
NIT
SM
ET
HO
DD
FP
RE
PA
RA
TIO
N
DA
TE
AN
AL
YT
ICA
L R
ES
UL
TS
PA
RA
ME
TE
RR
ES
UL
TS
Com
ments
and E
xpla
natio
ns:
A (
1)
fla
g I
ndic
ate
s a
n e
stim
ate
d v
alu
e,
because t
he s
am
ple
was r
eceiv
ed a
nd t
here
fore
analy
zed o
uts
ide o
f th
e r
ecom
mended a
nd r
egula
tory
hold
tim
e o
f 15 m
inute
s.
A
"J"
fla
g in
dic
ate
s a
n e
stim
ate
d v
alu
e t
hat
is le
ss t
han t
he M
RL.
page 4
of
6
City o
f S
helton
Pro
ject
Nam
e:
Qrt
ly S
pra
y F
ield
DA
L P
roje
ct
No
.: 1
50917-0
7P
roje
ct
No.:
n/a
150917-C
hlo
ride
Chlo
rid
end
0.1
0m
g/L
EP
A 3
00.0
9/1
7/2
015
NJ
150917-D
OD
issolv
ed O
xygen
8.9
0.0
1m
g/L
SM
4500-O
G9/1
7/2
015
NJ
150917-N
O
₃
Nitro
gen,
Nitra
te
nd
0.1
0m
g/L
EP
A 3
00.0
9/1
7/2
015
NJ
150917-N
O
₂
Nitro
gen,
Nitrite
nd
0.1
0m
g/L
EP
A 3
00.0
9/1
7/2
015
NJ
150930-T
KN
Nitro
gen,
(TK
N)
nd
2.0
mg/L
SM
4500-N
org
B9/3
0/2
015
MS
150917-p
HpH
n/a
n/a
SU
SM
4500-H
+n/a
n/a
150917-S
CS
pecific
Conducta
nce
nd
10.0
um
ho/c
mS
M 2
510 B
9/1
7/2
015
NJ
150923-T
DS
Solid
s,
To
tal D
issolv
ed
nd
20.0
mg/L
SM
2540 C
9/2
3/2
015
JB
150917-C
hlo
ride
Chlo
rid
e92.1
92.2
mg/L
EP
A 3
00.0
0.1
1±35
9/1
7/2
015
NJ
150917-D
OD
issolv
ed O
xygen
10.6
10.7
mg/L
SM
4500-O
G1.5
±35
9/1
7/2
015
NJ
(1)
150917-N
O
₃
Nitro
gen,
Nitra
te
nd
nd
mg/L
EP
A 3
00.0
0.0
0±35
9/1
7/2
015
NJ
150917-N
O
₂
Nitro
gen,
Nitrite
nd
nd
mg/L
EP
A 3
00.0
0.0
0±35
9/1
7/2
015
NJ
150930-T
KN
Nitro
gen,
(TK
N)
nd
nd
mg/L
SM
4500-N
org
B0.0
0±35
9/3
0/2
015
MS
150917-p
HpH
5.6
5.7
SU
SM
4500-H
+0.7
1±35
9/1
7/2
015
NJ
(1)
150917-S
CS
pecific
Conducta
nce
49.3
49.4
um
ho/c
mS
M 2
510 B
0.2
0±35
9/1
7/2
015
NJ
150923-T
DS
Solid
s,
To
tal D
issolv
ed
1730
1664
mg/L
SM
2540 C
3.9
±35
9/2
3/2
015
JB
WA
-DO
E-L
abora
tory
Cert
ific
atio
n N
o.:
C890
"MR
L"
indic
ate
s M
eth
od R
eport
ing L
imit
"RP
D"
indic
ate
s R
ela
tive P
erc
ent
Diffe
rence
"nd"
indic
ate
s t
he a
naly
te w
as n
ot
dete
cte
d a
t or
above t
he lis
ted M
eth
od R
eport
ing L
imit.
"n/a
" in
dic
ate
s n
ot
applic
able
Com
ments
and E
xpla
natio
ns:
None
Data
revie
wed b
y:
RP
D
(%)
LIM
ITS
(%)
AN
AL
YS
IS
DA
TE
AN
AL
YS
TD
AT
A
FL
AG
S
A
NA
LY
SIS
DA
TE
AN
AL
YS
TD
AT
A
FL
AG
S
SA
MP
LE
BA
TC
HP
AR
AM
ET
ER
RE
SU
LT
DU
P.
RE
SU
LT
UN
ITS
AN
AL
YT
ICA
L
ME
TH
OD
page 5
of
6
QU
AL
ITY
C
ON
TR
OL
R
ES
UL
TS
Meth
od
B
lan
k
QU
AL
ITY
C
ON
TR
OL
R
ES
UL
TS
Du
plicate
Sam
ple
SA
MP
LE
BA
TC
HP
AR
AM
ET
ER
RE
SU
LT
MR
LU
NIT
SA
NA
LY
TIC
AL
ME
TH
OD
City o
f S
helton
Pro
ject
Nam
e:
Qrt
ly S
pra
y F
ield
DA
L P
roje
ct
No
.: 1
50917-0
7P
roje
ct
No.:
n/a
150917-C
hlo
ride
Chlo
rid
e0.5
30.5
mg/L
EP
A 3
00.0
105
65.0
-135
9/1
7/2
015
NJ
150917-D
OD
issolv
ed O
xygen
n/a
n/a
mg/L
SM
4500-O
Gn/a
n/a
n/a
n/a
150917-N
O
₃
Nitro
gen,
Nitra
te
0.5
00.5
mg/L
EP
A 3
00.0
99.0
65.0
-135
9/1
7/2
015
NJ
150917-N
O
₂
Nitro
gen,
Nitrite
0.5
90.5
mg/L
EP
A 3
00.0
118
65.0
-135
9/1
7/2
015
NJ
150930-T
KN
Nitro
gen,
(TK
N)
19.3
20.0
mg/L
SM
4500-N
org
B96.5
65.0
-135
9/3
0/2
015
MS
150917-p
HpH
7.0
7.0
SU
SM
4500-H
+100
65.0
-135
9/1
7/2
015
NJ
150917-S
CS
pecific
Conducta
nce
1448
1415
um
ho/c
mS
M 2
510 B
102
65.0
-135
9/1
7/2
015
NJ
150923-T
DS
Solid
s,
To
tal D
issolv
ed
506
500
mg/L
SM
2540 C
101
65.0
-135
9/2
3/2
015
JB
150917-C
hlo
ride
Chlo
rid
eD
OD
OD
Om
g/L
EP
A 3
00.0
DO
DO
DO
DO
150917-D
OD
issolv
ed O
xygen
n/a
n/a
n/a
mg/L
SM
4500-O
Gn/a
n/a
n/a
n/a
150917-N
O
₃
Nitro
gen,
Nitra
te
0.4
70.4
70.5
mg/L
EP
A 3
00.0
0.4
3±35
9/1
7/2
015
NJ
150917-N
O
₂
Nitro
gen,
Nitrite
0.5
70.5
60.5
mg/L
EP
A 3
00.0
0.3
5±35
9/1
7/2
015
NJ
150930-T
KN
Nitro
gen,
(TK
N)
18.8
17.9
20.0
mg/L
SM
4500-N
org
B4.6
±35
9/3
0/2
015
MS
150917-p
HpH
n/a
n/a
n/a
SU
SM
4500-H
+n/a
n/a
n/a
n/a
150917-S
CS
pecific
Conducta
nce
n/a
n/a
n/a
um
ho/c
mS
M 2
510 B
n/a
n/a
n/a
n/a
150923-T
DS
Solid
s,
To
tal D
issolv
ed
n/a
n/a
n/a
mg/L
SM
2540 C
n/a
n/a
n/a
n/a
WA
-DO
E-L
abora
tory
Cert
ific
atio
n N
o.:
C890
"RP
D"
indic
ate
s R
ela
tive P
erc
ent
Diffe
rence
"nd"
indic
ate
s t
he a
naly
te w
as n
ot
dete
cte
d a
t or
above t
he lis
ted M
eth
od R
eport
ing L
imit.
"n/a
" in
dic
ate
s n
ot
applic
able
Com
ments
and E
xpla
natio
ns:
None
Data
revie
wed b
y:
DA
TA
FL
AG
SU
NIT
SA
NA
LY
TIC
AL
ME
TH
OD
RP
D
(%)
LIM
ITS
(%)
AN
AL
YS
IS
DA
TE
AN
AL
YS
T
RE
CO
VE
RY
(%)
LIM
ITS
(%)
AN
AL
YS
IS
DA
TE
AN
AL
YS
TD
AT
A
FL
AG
S
SA
MP
LE
BA
TC
HP
AR
AM
ET
ER
MS
RE
SU
LT
MS
D
RE
SU
LT
TR
UE
VA
LU
E
QU
AL
ITY
CO
NT
RO
L R
ES
UL
TS
Lab
ora
tory
Fo
rtif
ied
Bla
nk
QU
AL
ITY
CO
NT
RO
L R
ES
UL
TS
Matr
ix S
pik
e/M
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Appendix E Groundwater Quality Trends
719 2ND AVENUE, SUITE 200 | SEATTLE, WA 98104 | P 206.394.3700
TECHNICAL MEMORANDUM
DATE: September 9, 2015
TO: Brian Matthews
FROM: Lisa Gilbert
SUBJECT: Statistical Analysis of Trends in Groundwater Quality Data
PROJECT NUMBER: 555-1682-042 (04/03)
PROJECT NAME: Mason County Landfill
This Memorandum presents the results of statistical analyses of trends in groundwater monitoring data measured at the Mason County Landfill during the post-closure period. The landfill closed in 1993. The statistical analyses were originally prepared following the September 2013 monitoring event, and have been updated to incorporate additional data collected in July 2015 (wells MW-3B, MW-8, MW-10, and Culver).
STATISTICAL APPROACH Potential trends in the groundwater data were evaluated using the Mann-Kendall test for trend and Sen’s nonparametric estimator of slope (Gibbons 1994; Gilbert 1987, USEPA 2009). These tests are well suited to environmental data because there are no distributional assumptions, and missing data (non-detects) or irregularly spaced measurement periods are permitted. The Mann-Kendall test was used to identify whether or not a trend exists, and then the Sen’s slope test was used to determine how steeply the concentration levels are changing.
Trend analyses were conducted using all data collected from the Mason County Landfill monitoring wells between November 1991 and July 2015. The analyses were conducted for indicator parameters (dissolved arsenic, chloride, COD, specific conductivity, dissolved iron, dissolved manganese, ammonia, nitrate, nitrite, pH, sulfate, TOC, and dissolved zinc), and volatile organic compounds that have historically been detected at the site (carbon tetrachloride, tetrachloroethene, and vinyl chloride). The wells analyzed include upgradient well MW-4, downgradient monitoring wells MW-1B, MW-3B, MW-5B, MW-7, MW-8, and MW-10, and a domestic well at the Culver home located approximately 1,400 ft from the landfill property boundary in a downgradient direction. Wells MW-1B, MW-3B, MW-8, and MW-10 are located downgradient from the closed landfill at the point of compliance. Data for previously monitored wells MW-2B and MW-6 were not considered because these wells have not been sampled by the County since 2007 and 2005, respectively. Time-series plots showing all data collected during this period are presented in Attachment A.
In addition, trend analyses were conducted on data from the latest eight consecutive sampling events for each well as recommended in Ecology’s guidance document “Preparing for Termination of Post-Closure Activities at Landfills Closed Under Chapter 173-304 WAC.” (Ecology 2011, 2013). The latest eight events for wells except MW-4, MW-1B, and MW-5B started with September 2010 and ended with July 2015. MW-4 started with March 2010 because no data were collected in July 2015 due to pump malfunction, and MW-1B and MW-5B started with February 2006 because those wells were only sampled during the spring event through 2013.
All non-detected values were given a value equal to one half the reporting limit (Gilbert 1987, Gibbons 1994).
TECHNICAL MEMORANDUM (CONTINUED)
MANN-KENDALL TESTS The nonparametric Mann-Kendall test evaluates the significance of temporal trends at the 95 percent confidence level. This test uses only the relative magnitudes of the data instead of their measured values and can be considered a non-parametric test for zero slope of the linear regression of time-ordered data versus time (Gilbert, 1987). As such, it can be greatly influenced by gross data errors, a few extreme data values, and/or outliers and the estimated slope can deviate greatly from the true slope of the trend. A negative value for the Mann Kendall S statistic implies that a majority of the differences between earlier and later values are negative, suggestive of a decreasing trend. An S value near zero indicates a roughly equal number of positive and negative differences. This would be expected if the measurements were randomly fluctuating about a constant mean with no apparent trend. A positive value for the S statistic suggests an increasing trend.
SEN’S SLOPE TESTS The Sen’s slope test is a nonparametric procedure used to estimate the true slope of the data. The advantage of the Sen’s slope test over linear regression methods is that it is not greatly affected by gross data errors, a few extreme data values, or outliers, and can be computed when data are missing. The Sen's Slope/Trend Estimator Test used was a two-tailed test with the null hypothesis of zero slope. Therefore the slope (S = median Q) can be less than zero (< 0), not different than zero (ND 0), or greater than zero (> 0). The upper and lower confidence limits for the true slope are calculated based on the variance of S and Z (normal theory approximation). The probability and significance of the calculated slope S depend on the position of the upper and lower limits with reference to zero (the null hypothesis of zero slope). If both limits are greater than zero, a significant upward trend in slope exists, if both limits are less than zero, a significant downward trend exists, and if both limits are equal to zero or if zero lies between the lower and upper limits, no significant trends exists.
RESULTS OF TREND TESTS
In several cases where there are a few relatively high detected values and the majority of the data are low or non-detected, the Mann-Kendall and Sen’s slope test results did not agree. In these cases, the Sen’s slope test is a more accurate depiction of whether a trend actually exists because the test estimates the magnitude of the linear slope of the overall data, relative to zero. The Mann-Kendall, instead, estimates or tests for the presence of a linear trend using the relative magnitudes of the data. Therefore, an overall significant trend was considered to occur only when both the Mann-Kendall test and the Sen’s slope test showed significant trends.
Trends Using All Data For all data collected since November 1991, the results of the combined Mann-Kendall tests and Sen’s slope tests are presented in the tables in Attachment B, and summarized in Table 1. The results indicate statistically significant downward trends or no trend for all parameters in both upgradient and downgradient wells, except for the following cases:
• Upward trends in dissolved iron and dissolved zinc in upgradient well MW-4 and several of the downgradient wells. It is likely that the upward trends calculated for these parameters are due to historical increases in reporting limits since there are mostly non-detected values in the wells with upward trends. Time-series plots for these parameters with an expanded vertical scale to show the changes in reporting limits are presented in Attachment C.
• Upward trend in sulfate in downgradient well MW-7. The sulfate trends is not believed to represent landfill impacts since there is a high degree of variability in sulfate concentrations across the site and there was no trend in the MW-7 sulfate data over the latest eight events (see subsequent section). Actual concentrations in MW-7 (all below 15 mg/L) are substantially below the secondary criterion of 250 mg/L.
• Upward trend in nitrate in upgradient well MW-4.
• Downward trend in pH in all wells, both upgradient and downgradient. Since the trend also occurred in the upgradient well, the downward trend in pH appears to indicate a site-wide or regional trend.
TECHNICAL MEMORANDUM (CONTINUED)
Table 1. Summary of Combined Mann-Kendall and Sen's Slope Test Results for All Data (November 1991 through July 2015)
MW-4
(Upgradient well) MW-1B MW-3B MW-5B MW-7 MW-8 MW-10 CULVER
Arsenic -- -- -- -- -- -- -- -- Carbon Tetrachloride -- -- NA NA NA NA NA NA Chloride -- -- D -- D D -- -- COD -- -- -- -- -- -- -- -- Conductivity -- D D -- D D D D Iron1 U U -- U -- U U -- Manganese -- -- D -- D D D -- Ammonia -- -- D -- D -- -- -- Nitrate U D -- -- -- -- D -- Nitrite -- -- -- -- -- -- -- -- pH D D D D D D D D Sulfate -- -- D -- U -- -- -- Tetrachloroethene -- -- -- D -- -- -- D TOC -- -- -- -- -- -- -- -- Vinyl Chloride -- -- -- -- -- -- -- -- Zinc1 U -- U U -- U U U
U = Statistically Significant Upward Trend 1 Upgradient trends reflect historical increases in reporting limits D = Statistically Significant Downward Trend -- indicates no statistical trend NA = Not analyzed. All data non-detected
TrendS Using Latest Eight Sampling Events
The results of the combined Mann-Kendall tests and Sen’s slope tests for the latest eight consecutive sampling events are presented in the tables in Attachment D, and summarized in Table 2. The results indicate no trend or statistically significant downward trends for all parameters in both upgradient and downgradient wells, except for the following cases:
• Upward trend for nitrate in upgradient well MW-4 and downgradient well MW-3B. Nitrate also showed a significant upward trend in upgradient well MW-4 using all data, likely reflecting a site-wide or regional trend. Actual concentrations in both these wells (all below 0.4 mg/L) are substantially below the criterion of 10 mg/L.
• Downward trend for pH in downgradient well MW-3B and Culver well. The downward trend in pH likely indicates a site-wide or regional trend since there were significant downward trends in all site wells including the upgradient well when all data were considered.
TECHNICAL MEMORANDUM (CONTINUED)
Table 2. Summary of Mann-Kendall Test Results for Latest Eight Sampling Events
MW-4
(upgradient well) MW-1B MW-3B MW-5B MW-7 MW-8 MW-10 CULVER
Arsenic -- D -- D -- -- -- -- Carbon Tetrachloride -- -- NA NA NA NA NA NA Chloride -- -- -- -- -- -- -- -- COD -- -- -- -- -- -- -- -- Conductivity -- -- -- -- -- D -- -- Iron -- -- -- -- -- -- -- -- Manganese -- -- -- -- -- -- -- -- Ammonia -- -- D -- -- -- -- -- Nitrate U -- U -- -- -- -- -- Nitrite -- -- -- -- -- -- -- -- pH -- -- D -- -- -- -- D Sulfate -- -- D -- -- -- -- -- Tetrachloroethene -- -- -- -- -- -- -- -- TOC -- -- -- -- -- -- -- -- Vinyl Chloride -- -- -- -- -- -- -- -- Zinc -- -- -- -- -- -- -- --
U = Statistically Significant Upward Trend D = Statistically Significant Downward Trend -- indicates no statistical trend, or all data were non-detected NA = not analyzed. All data non-detected
CONCLUSIONS
The results of trend analyses indicate there were no statistically significant upward trends in downgradient monitoring wells over the most recent eight events, or in any well located downgradient from the closed landfill at the point of compliance for all data measured during the post-closure period between November 1991 and July 2015. The only exceptions were cases where there was also an upward trend (or downgradient trend in the case of pH) in the upgradient monitoring well indicating the presence of a site-wide or regional trend. Some of the upward trends in the data for the entire post-closure period reflect increasing reporting limits over time.
REFERENCES
Gibbons, R.D. 1994. Statistical Methods for Groundwater Monitoring. John Wiley and Sons, Inc. New York
Gilbert, R.O. 1987. Statistical Methods for Environmental Pollution Monitoring. Van Nostrand Reinhold. New York
U.S. Environmental Protection Agency (USEPA). 2009. Statistical Analysis of Groundwater Monitoring Data at RCRA Facilities – Unified Guidance. March.
Washington State Department of Ecology (Ecology). 2011. Preparing for Termination of Post-Closure Activities at Landfills Closed Under Chapter 173-304 WAC. Publication 11-07-006.
Washington State Department of Ecology (Ecology). 2013. Addendum to Preparing for Termination of Post-Closure Activities at Landfills Closed Under Chapter 173-304 WAC.
TECHNICAL MEMORANDUM (CONTINUED)
ATTACHMENTS A Time-Series Plots
B Results of Mann-Kendall Test for Trend and Sen’s Slope Analysis – All Data
C Time-Series Plots for Selected Parameters Illustrating Changing Reporting Limits
D Results of Mann-Kendall Test for Trend and Sen’s Slope Analysis – Most Recent Eight Events
Attachment A Time-Series Plots
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-1B
MW
-3B
MW
-4M
W-5
BM
W-7
MW
-8M
W-1
0C
ulve
r
Mas
on
Co
un
ty L
and
fill
201
5 G
roun
dwat
er M
onito
ring
Ann
ual R
epor
tM
ason
plo
ts th
ru 2
015.
xlsx
555
-168
2-04
29/
9/20
15
0
0.00
05
0.00
1
0.00
15
0.00
2
0.00
25
0.00
3
0.00
35
0.00
4
0.00
45Nov-91May-92Nov-92May-93Nov-93May-94Nov-94May-95Nov-95May-96Nov-96May-97Nov-97May-98Nov-98May-99Nov-99May-00Nov-00May-01Nov-01May-02Nov-02May-03Nov-03May-04Nov-04May-05Nov-05May-06Nov-06May-07Nov-07May-08Nov-08May-09Nov-09May-10Nov-10May-11Nov-11May-12Nov-12May-13Nov-13May-14Nov-14May-15
mg/LD
isso
lved
Ars
enic
MW
-1B
MW
-3B
MW
-4M
W-5
BM
W-7
MW
-8M
W-1
0C
ulve
r
Mas
on
Co
un
ty L
and
fill
201
5 G
roun
dwat
er M
onito
ring
Ann
ual R
epor
tM
ason
plo
ts th
ru 2
015.
xlsx
555
-168
2-04
29/
9/20
15
012345678910Nov-91May-92Nov-92May-93Nov-93May-94Nov-94May-95Nov-95May-96Nov-96May-97Nov-97May-98Nov-98May-99Nov-99May-00Nov-00May-01Nov-01May-02Nov-02May-03Nov-03May-04Nov-04May-05Nov-05May-06Nov-06May-07Nov-07May-08Nov-08May-09Nov-09May-10Nov-10May-11Nov-11May-12Nov-12May-13Nov-13May-14Nov-14May-15
mg/LD
isso
lved
Iro
n
MW
-1B
MW
-3B
MW
-4M
W-5
BM
W-7
MW
-8M
W-1
0C
ulve
r
Mas
on
Co
un
ty L
and
fill
201
5 G
roun
dwat
er M
onito
ring
Ann
ual R
epor
tM
ason
plo
ts th
ru 2
015.
xlsx
555
-168
2-04
29/
9/20
15
0123456Nov-91May-92Nov-92May-93Nov-93May-94Nov-94May-95Nov-95May-96Nov-96May-97Nov-97May-98Nov-98May-99Nov-99May-00Nov-00May-01Nov-01May-02Nov-02May-03Nov-03May-04Nov-04May-05Nov-05May-06Nov-06May-07Nov-07May-08Nov-08May-09Nov-09May-10Nov-10May-11Nov-11May-12Nov-12May-13Nov-13May-14Nov-14May-15
mg/LD
isso
lved
Man
gan
ese
MW
-1B
MW
-3B
MW
-4M
W-5
BM
W-7
MW
-8M
W-1
0C
ulve
r
Mas
on
Co
un
ty L
and
fill
201
5 G
roun
dwat
er M
onito
ring
Ann
ual R
epor
tM
ason
plo
ts th
ru 2
015.
xlsx
555
-168
2-04
29/
9/20
15
0
0.01
0.02
0.03
0.04
0.05
0.06
0.07
Nov-91May-92Nov-92May-93Nov-93May-94Nov-94May-95Nov-95May-96Nov-96May-97Nov-97May-98Nov-98May-99Nov-99May-00Nov-00May-01Nov-01May-02Nov-02May-03Nov-03May-04Nov-04May-05Nov-05May-06Nov-06May-07Nov-07May-08Nov-08May-09Nov-09May-10Nov-10May-11Nov-11May-12Nov-12May-13Nov-13May-14Nov-14May-15
mg/LD
isso
lved
Zin
c
MW
-1B
MW
-3B
MW
-4M
W-5
BM
W-7
MW
-8M
W-1
0C
ulve
r
Mas
on
Co
un
ty L
and
fill
201
5 G
roun
dwat
er M
onito
ring
Ann
ual R
epor
tM
ason
plo
ts th
ru 2
015.
xlsx
555
-168
2-04
29/
9/20
15
0
0.2
0.4
0.6
0.81
1.2
Nov-91May-92Nov-92May-93Nov-93May-94Nov-94May-95Nov-95May-96Nov-96May-97Nov-97May-98Nov-98May-99Nov-99May-00Nov-00May-01Nov-01May-02Nov-02May-03Nov-03May-04Nov-04May-05Nov-05May-06Nov-06May-07Nov-07May-08Nov-08May-09Nov-09May-10Nov-10May-11Nov-11May-12Nov-12May-13Nov-13May-14Nov-14May-15
µg/LV
inyl
Ch
lori
de
MW
-1B
MW
-3B
MW
-4M
W-5
BM
W-7
MW
-8M
W-1
0C
ulve
r
Mas
on
Co
un
ty L
and
fill
201
5 G
roun
dwat
er M
onito
ring
Ann
ual R
epor
tM
ason
plo
ts th
ru 2
015.
xlsx
555
-168
2-04
29/
9/20
15
0123456789Nov-91May-92Nov-92May-93Nov-93May-94Nov-94May-95Nov-95May-96Nov-96May-97Nov-97May-98Nov-98May-99Nov-99May-00Nov-00May-01Nov-01May-02Nov-02May-03Nov-03May-04Nov-04May-05Nov-05May-06Nov-06May-07Nov-07May-08Nov-08May-09Nov-09May-10Nov-10May-11Nov-11May-12Nov-12May-13Nov-13May-14Nov-14May-15
µg/LC
arb
on
Tet
rach
lori
de
MW
-1B
MW
-2B
MW
-4M
W-6
Mas
on
Co
un
ty L
and
fill
201
5 G
roun
dwat
er M
onito
ring
Ann
ual R
epor
tM
ason
plo
ts th
ru 2
015.
xlsx
555
-168
2-04
29/
9/20
15
0
0.51
1.52
2.5
Nov-91May-92Nov-92May-93Nov-93May-94Nov-94May-95Nov-95May-96Nov-96May-97Nov-97May-98Nov-98May-99Nov-99May-00Nov-00May-01Nov-01May-02Nov-02May-03Nov-03May-04Nov-04May-05Nov-05May-06Nov-06May-07Nov-07May-08Nov-08May-09Nov-09May-10Nov-10May-11Nov-11May-12Nov-12May-13Nov-13May-14Nov-14May-15
µg/LT
etra
chlo
roet
hen
e
MW
-1B
MW
-3B
MW
-4M
W-5
BM
W-7
MW
-8M
W-1
0C
ulve
r
Attachment B Results of Mann-Kendall Test for Trend and
Sen’s Slope Analysis – All Data
Mas
on
Co
un
ty L
and
fill
MW
-3B
Res
ult
s o
f M
ann
-Ken
dal
l/Sen
's S
lop
e A
nal
yses
fo
r T
ren
d
Man
n-K
enda
ll Tr
end
Ana
lysi
sS
en's
Slo
pe A
naly
sis
Wel
l ID
Ana
lyte
n S
Var
ianc
eZ
Tren
dS
lope
(Med
ian
Q)
Low
er L
imit
Upp
er L
imit
Tren
d
MW
-3B
Ars
enic
, Dis
solv
ed53
-421
8389
.0-4
.59
Dow
nwar
d0.
000.
000.
00N
o Tr
end
MW
-3B
Ch
lori
de
63-9
0028
339.
3-5
.34
Do
wn
war
d-0
.05
-0.0
8843
14-0
.025
5814
Do
wn
war
dM
W-3
BC
OD
63-2
2117
972.
3-1
.64
No
Tren
d0.
000.
000.
00N
o Tr
end
MW
-3B
Sp
ecif
ic C
on
du
ctiv
ity
63-1
090
2842
6.0
-6.4
6D
ow
nw
ard
-2.7
75-3
.614
04-2
.025
Do
wn
war
dM
W-3
BIro
n, D
isso
lved
6329
325
765.
71.
82U
pwar
d0.
000.
000.
0001
5625
No
Tren
dM
W-3
BM
ang
anes
e, D
isso
lved
63-1
243
2842
5.0
-7.3
7D
ow
nw
ard
-0.0
291
-0.0
3701
75-0
.022
3462
Do
wn
war
dM
W-3
BA
mm
on
ia63
-163
628
414.
0-9
.70
Do
wn
war
d-0
.015
6563
-0.0
1685
29-0
.014
5833
Do
wn
war
dM
W-3
BN
itrat
e63
-101
2612
2.3
-0.6
2N
o Tr
end
0.00
-0.0
0024
242
0.00
No
Tren
dM
W-3
BN
itrite
63-3
126
03.7
-0.5
9N
o Tr
end
0.00
0.00
0.00
No
Tren
dM
W-3
Bp
H62
-885
2709
6.3
-5.3
7D
ow
nw
ard
-0.0
1529
41-0
.02
-0.0
1D
ow
nw
ard
MW
-3B
Su
lfat
e63
-518
2835
9.3
-3.0
7D
ow
nw
ard
-0.0
2619
05-0
.045
4545
-0.0
0975
61D
ow
nw
ard
MW
-3B
Tetra
chlo
roet
hene
63-6
7722
099.
7-4
.55
Dow
nwar
d0.
00-0
.005
8823
50.
00N
o Tr
end
MW
-3B
TOC
6325
1797
2.3
0.18
No
Tren
d0.
000.
000.
00N
o Tr
end
MW
-3B
Vin
yl C
hlor
ide
63-7
0623
396.
7-4
.61
Dow
nwar
d-0
.000
1351
35-0
.000
50.
00N
o Tr
end
MW
-3B
Zin
c, D
isso
lved
6111
1122
491.
77.
40U
pw
ard
0.00
0043
478
0.00
0031
250.
0000
5882
Up
war
d
n =
Sam
ple
size
S =
Man
n-K
enda
ll te
st s
tatis
tic.
Pos
itive
num
bers
impl
y in
crea
sing
tren
ds; n
egat
ive
num
bers
impl
y de
crea
sing
tren
ds.
Z =
App
roxi
mat
e no
rmal
test
sta
tistic
; cal
cula
ted
base
d on
S a
nd th
e es
timat
ed v
aria
nce
whe
n th
e sa
mpl
e si
ze is
gre
ater
than
10.
The
com
paris
on le
vel (
criti
cal v
alue
of Z
) at 1
.0 -
(α/ 2
) = (0
.05
/ 2) =
97.
5% c
onfid
ence
leve
l = 1
.977
37 f
or a
two-
taile
d M
ann-
Ken
dall
test
and
at
1.0
- (a
) = (0
.05)
= 9
5% c
onfid
ence
leve
l = 1
.654
63 f
or a
one
-taile
d M
ann-
Ken
dall
test
A s
igni
fican
t tre
nd is
pre
sent
in th
e da
ta if
the
abso
lute
val
ue o
f the
cal
cula
ted
Z st
atis
tic (|
Z|) >
1.9
7737
and
a s
igni
fican
t upw
ard
or d
ownw
ard
trend
is p
rese
nt in
the
data
if th
e ab
solu
te v
alue
of t
he c
alcu
late
d Z
stat
istic
(|Z|
) > 1
.654
63.
Ther
e is
no
trend
in th
e da
ta w
hen
|Z| <
1.9
7737
and
no
sign
ifica
nt u
pwar
d or
dow
nwar
d tre
nd w
hen
|Z| <
1.6
5463
The
Sen
's S
lope
/Tre
nd E
stim
ator
Tes
t is
a t
wo-
taile
d te
st w
ith a
nul
l hyp
othe
sis
of z
ero
slop
e. T
here
fore
Q (S
lope
Est
imat
or=
Med
ian
Q) c
an b
e le
ss th
an z
ero
(< 0
), no
t diff
eren
t tha
n ze
ro (N
D 0
), or
gre
ater
than
zer
o (>
0).
If ze
ro li
es b
etw
een
the
uppe
r and
low
er 9
5% C
onfid
ence
Lim
its a
roun
d th
e m
edia
n Q
, the
re is
no
trend
.If
zero
lies
abo
ve th
e up
per l
imit
(UL
< 0)
, the
re is
a d
ownw
ard
trend
in th
e da
ta.
If ze
ro li
es b
elow
the
low
er li
mit
(0 <
LL)
, the
re is
a u
pwar
d tre
nd in
the
data
.
The
resu
lts o
f bot
h th
e M
ann-
Ken
dall
and
the
Sen
's S
lope
ana
lyse
s m
ust b
e si
gnifi
cant
for a
tren
d to
be
cons
ider
ed s
igni
fican
t.
Tren
ds s
igni
fican
t at c
onfid
ence
leve
l of 9
5% o
r 97.
5% a
re s
how
n in
bol
d ty
pe.
9/9/
2015
Pag
e 1
of 4
Mas
on
Co
un
ty L
and
fill
MW
-8R
esu
lts
of
Man
n-K
end
all/S
en's
Slo
pe
An
alys
es f
or
Tre
nd
Man
n-K
enda
ll Tr
end
Ana
lysi
sS
en's
Slo
pe A
naly
sis
Wel
l ID
Ana
lyte
n S
Var
ianc
eZ
Tren
dS
lope
(Med
ian
Q)
Low
er L
imit
Upp
er L
imit
Tren
d
MW
-8A
rsen
ic, D
isso
lved
55-3
8184
33.0
-4.1
4D
ownw
ard
0.00
0.00
0.00
No
Tren
dM
W-8
Ch
lori
de
65-7
0931
116.
3-4
.01
Do
wn
war
d-0
.03
-0.0
5-0
.014
2857
Do
wn
war
dM
W-8
CO
D65
-30
2074
8.0
-0.2
0N
o Tr
end
0.00
0.00
0.00
No
Tren
dM
W-8
Sp
ecif
ic C
on
du
ctiv
ity
65-1
183
3119
9.0
-6.6
9D
ow
nw
ard
-2.7
8018
-3.5
-2.1
0217
Do
wn
war
dM
W-8
Iro
n, D
isso
lved
6511
2927
887.
06.
75U
pw
ard
0.00
0357
143
0.00
025
0.00
0425
53U
pw
ard
MW
-8M
ang
anes
e, D
isso
lved
65-3
9731
191.
7-2
.24
Do
wn
war
d-0
.004
9636
4-0
.014
-0.0
0035
714
Do
wn
war
dM
W-8
Am
mon
ia65
3730
977.
70.
20N
o Tr
end
0.00
-0.0
0205
882
0.00
2925
93N
o Tr
end
MW
-8N
itrat
e65
-394
3070
4.7
-2.2
4D
ownw
ard
-0.0
0528
099
-0.0
1714
290.
00N
o Tr
end
MW
-8N
itrite
65-1
9389
76.3
-2.0
3D
ownw
ard
0.00
0.00
0.00
No
Tren
dM
W-8
pH
65-1
068
3118
2.0
-6.0
4D
ow
nw
ard
-0.0
1607
14-0
.019
7222
-0.0
125
Do
wn
war
dM
W-8
Sul
fate
65-1
5231
155.
3-0
.86
No
Tren
d-0
.007
6923
1-0
.027
0833
0.01
1111
1N
o Tr
end
MW
-8Te
trach
loro
ethe
ne65
-644
2602
8.7
-3.9
9D
ownw
ard
0.00
-0.0
050.
00N
o Tr
end
MW
-8TO
C65
125
1930
9.0
0.89
No
Tren
d0.
000.
000.
00N
o Tr
end
MW
-8V
inyl
Chl
orid
e65
-388
2320
6.0
-2.5
4D
ownw
ard
0.00
0.00
0.00
No
Tren
dM
W-8
Zin
c, D
isso
lved
6312
1724
714.
37.
73U
pw
ard
0.00
0043
478
0.00
0031
250.
0000
566
Up
war
d
n =
Sam
ple
size
S =
Man
n-K
enda
ll te
st s
tatis
tic.
Pos
itive
num
bers
impl
y in
crea
sing
tren
ds; n
egat
ive
num
bers
impl
y de
crea
sing
tren
ds.
Z =
App
roxi
mat
e no
rmal
test
sta
tistic
; cal
cula
ted
base
d on
S a
nd th
e es
timat
ed v
aria
nce
whe
n th
e sa
mpl
e si
ze is
gre
ater
t
han
10.
The
com
paris
on le
vel (
criti
cal v
alue
of Z
) at 1
.0 -
(α/ 2
) = (0
.05
/ 2) =
97.
5% c
onfid
ence
leve
l = 1
.977
37 f
or a
two-
taile
d M
ann-
Ken
dall
test
and
at
1.0
- (a
) = (0
.05)
= 9
5% c
onfid
ence
leve
l = 1
.654
63 f
or a
one
-taile
d M
ann-
Ken
dall
test
A s
igni
fican
t tre
nd is
pre
sent
in th
e da
ta if
the
abso
lute
val
ue o
f the
cal
cula
ted
Z st
atis
tic (|
Z|) >
1.9
7737
and
a s
igni
fican
t upw
ard
or d
ownw
ard
trend
is p
rese
nt in
the
data
if th
e ab
solu
te v
alue
of t
he c
alcu
late
d Z
stat
istic
(|Z|
) > 1
.654
63.
Ther
e is
no
trend
in th
e da
ta w
hen
|Z| <
1.9
7737
and
no
sign
ifica
nt u
pwar
d or
dow
nwar
d tre
nd w
hen
|Z| <
1.6
5463
The
Sen
's S
lope
/Tre
nd E
stim
ator
Tes
t is
a t
wo-
taile
d te
st w
ith a
nul
l hyp
othe
sis
of z
ero
slop
e. T
here
fore
Q (S
lope
Est
imat
or=
Med
ian
Q) c
an b
e le
ss th
an z
ero
(< 0
), no
t diff
eren
t tha
n ze
ro (N
D 0
), or
gre
ater
than
zer
o (>
0).
If ze
ro li
es b
etw
een
the
uppe
r and
low
er 9
5% C
onfid
ence
Lim
its a
roun
d th
e m
edia
n Q
, the
re is
no
trend
.If
zero
lies
abo
ve th
e up
per l
imit
(UL
< 0)
, the
re is
a d
ownw
ard
trend
in th
e da
ta.
If ze
ro li
es b
elow
the
low
er li
mit
(0 <
LL)
, the
re is
a u
pwar
d tre
nd in
the
data
.
The
resu
lts o
f bot
h th
e M
ann-
Ken
dall
and
the
Sen
's S
lope
ana
lyse
s m
ust b
e si
gnifi
cant
for a
tren
d to
be
cons
ider
ed s
igni
fican
t.
Tren
ds s
igni
fican
t at c
onfid
ence
leve
l of 9
5% o
r 97.
5% a
re s
how
n in
bol
d ty
pe.
9/9/
2015
Pag
e 2
of 4
Mas
on
Co
un
ty L
and
fill
MW
-10
Res
ult
s o
f M
ann
-Ken
dal
l/Sen
's S
lop
e A
nal
yses
fo
r T
ren
d
Man
n-K
enda
ll Tr
end
Ana
lysi
sS
en's
Slo
pe A
naly
sis
Wel
l ID
Ana
lyte
n S
Var
ianc
eZ
Tren
dS
lope
(Med
ian
Q)
Low
er L
imit
Upp
er L
imit
Tren
d
MW
-10
Ars
enic
, Dis
solv
ed42
-277
4619
.7-4
.06
Dow
nwar
d0.
000.
000.
00N
o Tr
end
MW
-10
Chl
orid
e52
-202
1597
5.3
-1.5
9N
o Tr
end
-0.0
1490
74-0
.036
0.00
No
Tren
dM
W-1
0C
OD
5211
156
08.3
1.47
No
Tren
d0.
000.
000.
00N
o Tr
end
MW
-10
Sp
ecif
ic C
on
du
ctiv
ity
52-6
8116
047.
7-5
.37
Do
wn
war
d-1
.547
5-1
.954
55-1
.059
26D
ow
nw
ard
MW
-10
Iro
n, D
isso
lved
5287
614
127.
37.
36U
pw
ard
0.00
0535
714
0.00
0421
050.
0006
0606
Up
war
dM
W-1
0M
ang
anes
e, D
isso
lved
52-7
5613
995.
3-6
.38
Do
wn
war
d-0
.003
8786
8-0
.009
9078
9-0
.000
3448
3D
ow
nw
ard
MW
-10
Am
mon
ia52
337
1421
1.0
2.82
Upw
ard
0.00
0069
048
0.00
0.00
0326
531
No
Tren
dM
W-1
0N
itra
te52
-295
1605
8.3
-2.3
2D
ow
nw
ard
-0.0
0916
818
-0.0
1862
5-0
.001
3877
6D
ow
nw
ard
MW
-10
Nitr
ite52
00.
00.
00N
o Tr
end
0.00
0.00
0.00
No
Tren
dM
W-1
0p
H52
-759
1604
5.0
-5.9
8D
ow
nw
ard
-0.0
2-0
.025
-0.0
1413
79D
ow
nw
ard
MW
-10
Sul
fate
52-5
615
936.
0-0
.44
No
Tren
d0.
00-0
.028
5714
0.01
9047
6N
o Tr
end
MW
-10
Tetra
chlo
roet
hene
51-5
8610
031.
3-5
.84
Dow
nwar
d0.
00-0
.008
3333
30.
00N
o Tr
end
MW
-10
TOC
5244
810
211.
34.
42U
pwar
d0.
000.
000.
00N
o Tr
end
MW
-10
Vin
yl C
hlor
ide
514
9219
.30.
03N
o Tr
end
0.00
0.00
0.00
No
Tren
dM
W-1
0Z
inc,
Dis
solv
ed50
768
1251
4.7
6.86
Up
war
d0.
0000
625
0.00
0041
670.
0000
7895
Up
war
d
n =
Sam
ple
size
S =
Man
n-K
enda
ll te
st s
tatis
tic.
Pos
itive
num
bers
impl
y in
crea
sing
tren
ds; n
egat
ive
num
bers
impl
y de
crea
sing
tren
ds.
Z =
App
roxi
mat
e no
rmal
test
sta
tistic
; cal
cula
ted
base
d on
S a
nd th
e es
timat
ed v
aria
nce
whe
n th
e sa
mpl
e si
ze is
gre
ater
t
han
10.
The
com
paris
on le
vel (
criti
cal v
alue
of Z
) at 1
.0 -
(α/ 2
) = (0
.05
/ 2) =
97.
5% c
onfid
ence
leve
l = 1
.977
37 f
or a
two-
taile
d M
ann-
Ken
dall
test
and
at
1.0
- (a
) = (0
.05)
= 9
5% c
onfid
ence
leve
l = 1
.654
63 f
or a
one
-taile
d M
ann-
Ken
dall
test
A s
igni
fican
t tre
nd is
pre
sent
in th
e da
ta if
the
abso
lute
val
ue o
f the
cal
cula
ted
Z st
atis
tic (|
Z|) >
1.9
7737
and
a s
igni
fican
t upw
ard
or d
ownw
ard
trend
is p
rese
nt in
the
data
if th
e ab
solu
te v
alue
of t
he c
alcu
late
d Z
stat
istic
(|Z|
) > 1
.654
63.
Ther
e is
no
trend
in th
e da
ta w
hen
|Z| <
1.9
7737
and
no
sign
ifica
nt u
pwar
d or
dow
nwar
d tre
nd w
hen
|Z| <
1.6
5463
The
Sen
's S
lope
/Tre
nd E
stim
ator
Tes
t is
a t
wo-
taile
d te
st w
ith a
nul
l hyp
othe
sis
of z
ero
slop
e. T
here
fore
Q (S
lope
Est
imat
or=
Med
ian
Q) c
an b
e le
ss th
an z
ero
(< 0
), no
t diff
eren
t tha
n ze
ro (N
D 0
), or
gre
ater
than
zer
o (>
0).
If ze
ro li
es b
etw
een
the
uppe
r and
low
er 9
5% C
onfid
ence
Lim
its a
roun
d th
e m
edia
n Q
, the
re is
no
trend
.If
zero
lies
abo
ve th
e up
per l
imit
(UL
< 0)
, the
re is
a d
ownw
ard
trend
in th
e da
ta.
If ze
ro li
es b
elow
the
low
er li
mit
(0 <
LL)
, the
re is
a u
pwar
d tre
nd in
the
data
.
The
resu
lts o
f bot
h th
e M
ann-
Ken
dall
and
the
Sen
's S
lope
ana
lyse
s m
ust b
e si
gnifi
cant
for a
tren
d to
be
cons
ider
ed s
igni
fican
t.
Tren
ds s
igni
fican
t at c
onfid
ence
leve
l of 9
5% o
r 97.
5% a
re s
how
n in
bol
d ty
pe.
9/9/
2015
Pag
e 3
of 4
Mas
on
Co
un
ty L
and
fill
Cu
lver
Wel
lR
esu
lts
of
Man
n-K
end
all/S
en's
Slo
pe
An
alys
es f
or
Tre
nd
Man
n-K
enda
ll Tr
end
Ana
lysi
sS
en's
Slo
pe A
naly
sis
Wel
l ID
Ana
lyte
n S
Var
ianc
eZ
Tren
dS
lope
(Med
ian
Q)
Low
er L
imit
Upp
er L
imit
Tren
d
Cul
ver
Ars
enic
, Dis
solv
ed53
-336
8412
.0-3
.65
Dow
nwar
d0.
000.
000.
00N
o Tr
end
Cul
ver
Chl
orid
e58
-133
2185
5.0
-0.8
9N
o Tr
end
-0.0
0227
273
-0.0
20.
0032
2581
No
Tren
dC
ulve
rC
OD
5810
1106
6.7
0.09
No
Tren
d0.
000.
000.
00N
o Tr
end
Cul
ver
Sp
ecif
ic C
on
du
ctiv
ity
57-3
8121
099.
7-2
.62
Do
wn
war
d-1
.036
62-1
.7-0
.246
667
Do
wn
war
dC
ulve
rIro
n, D
isso
lved
58-2
3320
291.
0-1
.63
No
Tren
d0.
00-0
.000
5555
60.
00N
o Tr
end
Cul
ver
Man
gane
se, D
isso
lved
58-6
1818
387.
3-4
.55
Dow
nwar
d-0
.000
0416
67-0
.000
0882
40.
00N
o Tr
end
Cul
ver
Am
mon
ia58
146
1726
1.3
1.10
No
Tren
d0.
000.
000.
00N
o Tr
end
Cul
ver
Nitr
ate
5810
222
198.
00.
68N
o Tr
end
0.00
0555
556
-0.0
0136
170.
0021
1111
No
Tren
dC
ulve
rN
itrite
58-3
632
48.7
-0.6
1N
o Tr
end
0.00
0.00
0.00
No
Tren
dC
ulve
rp
H56
-789
2000
5.7
-5.5
7D
ow
nw
ard
-0.0
1416
67-0
.018
0645
-0.0
0979
167
Do
wn
war
dC
ulve
rS
ulfa
te58
125
2201
3.0
0.84
No
Tren
d0.
0044
4444
-0.0
0740
741
0.02
3913
No
Tren
dC
ulve
rT
etra
chlo
roet
hen
e59
-112
922
055.
7-7
.60
Do
wn
war
d-0
.006
5217
4-0
.007
5471
7-0
.005
4054
1D
ow
nw
ard
Cul
ver
TOC
5825
411
068.
72.
40U
pwar
d0.
000.
000.
00N
o Tr
end
Cul
ver
Vin
yl C
hlor
ide
5939
013
200.
03.
39U
pwar
d0.
000.
000.
00N
o Tr
end
Cul
ver
Zin
c, D
isso
lved
5846
522
091.
03.
12U
pw
ard
0.00
0230
769
0.00
0052
632
0.00
04U
pw
ard
n =
Sam
ple
size
S =
Man
n-K
enda
ll te
st s
tatis
tic.
Pos
itive
num
bers
impl
y in
crea
sing
tren
ds; n
egat
ive
num
bers
impl
y de
crea
sing
tren
ds.
Z =
App
roxi
mat
e no
rmal
test
sta
tistic
; cal
cula
ted
base
d on
S a
nd th
e es
timat
ed v
aria
nce
whe
n th
e sa
mpl
e si
ze is
gre
ater
t
han
10.
The
com
paris
on le
vel (
criti
cal v
alue
of Z
) at 1
.0 -
(α/ 2
) = (0
.05
/ 2) =
97.
5% c
onfid
ence
leve
l = 1
.977
37 f
or a
two-
taile
d M
ann-
Ken
dall
test
and
at
1.0
- (a
) = (0
.05)
= 9
5% c
onfid
ence
leve
l = 1
.654
63 f
or a
one
-taile
d M
ann-
Ken
dall
test
A s
igni
fican
t tre
nd is
pre
sent
in th
e da
ta if
the
abso
lute
val
ue o
f the
cal
cula
ted
Z st
atis
tic (|
Z|) >
1.9
7737
and
a s
igni
fican
t upw
ard
or d
ownw
ard
trend
is p
rese
nt in
the
data
if th
e ab
solu
te v
alue
of t
he c
alcu
late
d Z
stat
istic
(|Z|
) > 1
.654
63.
Ther
e is
no
trend
in th
e da
ta w
hen
|Z| <
1.9
7737
and
no
sign
ifica
nt u
pwar
d or
dow
nwar
d tre
nd w
hen
|Z| <
1.6
5463
The
Sen
's S
lope
/Tre
nd E
stim
ator
Tes
t is
a t
wo-
taile
d te
st w
ith a
nul
l hyp
othe
sis
of z
ero
slop
e. T
here
fore
Q (S
lope
Est
imat
or=
Med
ian
Q) c
an b
e le
ss th
an z
ero
(< 0
), no
t diff
eren
t tha
n ze
ro (N
D 0
), or
gre
ater
than
zer
o (>
0).
If ze
ro li
es b
etw
een
the
uppe
r and
low
er 9
5% C
onfid
ence
Lim
its a
roun
d th
e m
edia
n Q
, the
re is
no
trend
.If
zero
lies
abo
ve th
e up
per l
imit
(UL
< 0)
, the
re is
a d
ownw
ard
trend
in th
e da
ta.
If ze
ro li
es b
elow
the
low
er li
mit
(0 <
LL)
, the
re is
a u
pwar
d tre
nd in
the
data
.
The
resu
lts o
f bot
h th
e M
ann-
Ken
dall
and
the
Sen
's S
lope
ana
lyse
s m
ust b
e si
gnifi
cant
for a
tren
d to
be
cons
ider
ed s
igni
fican
t.
Tren
ds s
igni
fican
t at c
onfid
ence
leve
l of 9
5% o
r 97.
5% a
re s
how
n in
bol
d ty
pe.
9/9/
2015
Pag
e 4
of 4
Attachment C Time-Series Plots for Selected Parameters Illustrating
Changing Reporting Limits
Attachment D Results of Mann-Kendall Test for Trend and Sen’s
Slope Analysis– Most Recent Eight Events
Mas
on
Co
un
ty L
and
fill
MW
-3B
Res
ult
s o
f M
ann
-Ken
dal
l/Sen
's S
lop
e A
nal
yses
fo
r T
ren
d (
n=
8)
Man
n-K
enda
ll A
naly
sis
Sen
's S
lope
Ana
lysi
sP
rob.
Pro
b.S
lope
Low
erU
pper
Wel
l ID
Ana
lyte
1n
S(n≤1
0)(S
igni
f.)Tr
end
(Med
ian
Q)
Lim
itLi
mit
Tren
d
MW
-3B
Chl
orid
e8
-30.
025/
0.05
0.81
2/0.
406
No
Tren
d-0
.025
-0.2
750.
15N
o Tr
end
MW
-3B
Spe
cific
Con
duct
ivity
8-8
0.02
5/0.
050.
398/
0.19
9N
o Tr
end
-3.0
2857
-6.4
6667
0.75
No
Tren
dM
W-3
BM
anga
nese
, Dis
solv
ed8
-16
0.02
5/0.
050.
062/
0.03
1D
ownw
ard
-0.0
255
-0.0
705
0.00
25N
o Tr
end
MW
-3B
Am
mo
nia
8-2
40.
025/
0.05
0.00
174/
0.00
087
Do
wn
war
d-0
.016
-0.0
22-0
.011
5D
ow
nw
ard
MW
-3B
Nit
rate
821
0.02
5/0.
050.
0099
/0.0
0495
Up
war
d0.
0203
333
0.00
80.
0333
333
Up
war
dM
W-3
Bp
H8
-18
0.02
5/0.
05 0
.032
/0.0
16D
ow
nw
ard
-0.0
345
-0.1
05-0
.006
Do
wn
war
dM
W-3
BS
ulf
ate
8-1
80.
025/
0.05
0.0
32/0
.016
Do
wn
war
d-0
.321
429
-0.5
5-0
.05
Do
wn
war
d
1 Tre
nd a
naly
ses
wer
e no
t run
for A
rsen
ic, C
OD
, Iro
n, N
itrite
, Tet
rach
loro
ethe
ne, T
OC
, Vin
yl C
hlor
ide
and
Zinc
bec
ause
the
data
for t
hese
ana
lyte
s ar
e al
l ND
s
n =
Sam
ple
size
S =
Man
n-K
enda
ll te
st s
tatis
tic.
Pos
itive
num
ber i
mpl
ies
an in
crea
sing
tren
d; a
neg
ativ
e nu
mbe
r im
plie
s a
decr
easi
ng tr
end.
P(n≤1
0) =
Pro
babi
lity
of o
btai
ning
a s
peci
fic |S
| val
ue (a
bsol
ute
valu
e of
S) w
hen
the
sam
ple
size
is le
ss th
an o
r equ
al to
10
(Tab
le 9
.4, G
ibbo
ns, 1
994)
.P
(Sig
nif))
≤ 0
.025
for a
two-
taile
d M
ann-
Ken
dall
test
(i.e
. at 1
.0 -
(α/ 2
) = 9
7.5%
con
fiden
ce le
vel)
P(S
igni
f)) ≤
0.0
5 fo
r a o
ne-ta
iled
Man
n-K
enda
ll te
st (i
.e. a
t 1.0
- (α
) = 9
5% c
onfid
ence
leve
l)If
the
prob
abili
ty o
f obt
aini
ng th
e ab
solu
te v
alue
of t
he c
alcu
late
d S
sta
tistic
(|S
|) ≤
0.02
5, a
sig
nific
ant t
rend
is p
rese
nt in
the
data
.If
the
prob
abili
ty o
f obt
aini
ng th
e ab
solu
te v
alue
of t
he c
alcu
late
d S
sta
tistic
(|S
|) ≤
0.05
, a s
igni
fican
t upw
ard
or d
ownw
ard
trend
is p
rese
nt in
the
data
.
Ther
e is
no
trend
in th
e da
ta w
hen
|S| >
0.0
25 a
nd n
o si
gnifi
cant
upw
ard
or d
ownw
ard
trend
whe
n |S
| > 0
.05
The
Sen
's S
lope
/Tre
nd E
stim
ator
Tes
t is
a t
wo-
taile
d te
st w
ith a
nul
l hyp
othe
sis
of z
ero
slop
e. T
here
fore
Q (S
lope
Est
imat
or=
Med
ian
Q) c
an b
e le
ss th
an z
ero
(< 0
), no
t diff
eren
t tha
n ze
ro (N
D 0
), or
gre
ater
than
zer
o (>
0).
If ze
ro li
es b
etw
een
the
uppe
r and
low
er 9
5% C
onfid
ence
Lim
its a
roun
d th
e m
edia
n Q
, the
re is
no
trend
.If
zero
lies
abo
ve th
e up
per l
imit
(UL
< 0)
, the
re is
a d
ownw
ard
trend
in th
e da
ta.
If ze
ro li
es b
elow
the
low
er li
mit
(0 <
LL)
, the
re is
a u
pwar
d tre
nd in
the
data
.
The
resu
lts o
f bot
h th
e M
ann-
Ken
dall
and
the
Sen
's S
lope
ana
lyse
s m
ust b
e si
gnifi
cant
for a
tren
d to
be
cons
ider
ed s
igni
fican
t.
Tren
ds s
igni
fican
t at a
con
fiden
ce le
vel o
f 97.
5% O
R 9
5% a
re s
how
n in
bol
d ty
pe.
9/9/
2015
Pag
e 1
of 4
Mas
on
Co
un
ty L
and
fill
MW
-8R
esu
lts
of
Man
n-K
end
all/S
en's
Slo
pe
An
alys
es f
or
Tre
nd
(n
=8)
Man
n-K
enda
ll A
naly
sis
Sen
's S
lope
Ana
lysi
sP
rob.
Pro
b.S
lope
Low
erU
pper
Wel
l ID
Ana
lyte
1n
S(n≤1
0)(S
igni
f.)Tr
end
(Med
ian
Q)
Lim
itLi
mit
Tren
d
MW
-8C
hlor
ide
8-1
10.
025/
0.05
0.22
7/0.
1135
No
Tren
d-0
.066
6667
-0.1
50.
05N
o Tr
end
MW
-8C
OD
813
0.02
5/0.
050.
143/
0.07
15N
o Tr
end
0.38
6905
00.
7475
No
Tren
dM
W-8
Sp
ecif
ic C
on
du
ctiv
ity
8-1
80.
025/
0.05
0.0
32/0
.016
Do
wn
war
d-3
.994
29-6
.9-0
.4D
ow
nw
ard
MW
-8M
anga
nese
, Dis
solv
ed8
00.
025/
0.05
1.09
6/0.
548
No
Tren
d0.
0102
5-0
.263
0.19
35N
o Tr
end
MW
-8A
mm
onia
8-2
0.02
5/0.
050.
904/
0.45
2N
o Tr
end
-0.0
12-0
.094
0.12
1N
o Tr
end
MW
-8N
itrat
e8
-30.
025/
0.05
0.81
2/0.
406
No
Tren
d-0
.001
875
-0.1
150.
0785
No
Tren
dM
W-8
pH8
-13
0.02
5/0.
050.
143/
0.07
15N
o Tr
end
-0.0
175
-0.0
880.
02N
o Tr
end
MW
-8S
ulfa
te8
-12
0.02
5/0.
050.
178/
0.08
9N
o Tr
end
-0.2
3333
3-0
.60.
22N
o Tr
end
1 Tre
nd a
naly
ses
wer
e no
t run
for A
rsen
ic, I
ron,
Nitr
ite, T
etra
chlo
roet
hene
, TO
C, V
inyl
Chl
orid
e an
d Zi
nc b
ecau
se th
e da
ta fo
r the
se a
naly
tes
are
all N
Ds
n =
Sam
ple
size
S =
Man
n-K
enda
ll te
st s
tatis
tic.
Pos
itive
num
ber i
mpl
ies
an in
crea
sing
tren
d; a
neg
ativ
e nu
mbe
r im
plie
s a
decr
easi
ng tr
end.
P(n≤1
0) =
Pro
babi
lity
of o
btai
ning
a s
peci
fic |S
| val
ue (a
bsol
ute
valu
e of
S) w
hen
the
sam
ple
size
is le
ss th
an o
r equ
al to
10
(Tab
le 9
.4, G
ibbo
ns, 1
994)
.P
(Sig
nif))
≤ 0
.025
for a
two-
taile
d M
ann-
Ken
dall
test
(i.e
. at 1
.0 -
(α/ 2
) = 9
7.5%
con
fiden
ce le
vel)
P(S
igni
f)) ≤
0.0
5 fo
r a o
ne-ta
iled
Man
n-K
enda
ll te
st (i
.e. a
t 1.0
- (α
) = 9
5% c
onfid
ence
leve
l)If
the
prob
abili
ty o
f obt
aini
ng th
e ab
solu
te v
alue
of t
he c
alcu
late
d S
sta
tistic
(|S
|) ≤
0.02
5, a
sig
nific
ant t
rend
is p
rese
nt in
the
data
.If
the
prob
abili
ty o
f obt
aini
ng th
e ab
solu
te v
alue
of t
he c
alcu
late
d S
sta
tistic
(|S
|) ≤
0.05
, a s
igni
fican
t upw
ard
or d
ownw
ard
trend
is p
rese
nt in
the
data
.
Ther
e is
no
trend
in th
e da
ta w
hen
|S| >
0.0
25 a
nd n
o si
gnifi
cant
upw
ard
or d
ownw
ard
trend
whe
n |S
| > 0
.05
The
Sen
's S
lope
/Tre
nd E
stim
ator
Tes
t is
a t
wo-
taile
d te
st w
ith a
nul
l hyp
othe
sis
of z
ero
slop
e. T
here
fore
Q (S
lope
Est
imat
or=
Med
ian
Q) c
an b
e le
ss th
an z
ero
(< 0
), no
t diff
eren
t tha
n ze
ro (N
D 0
), or
gre
ater
than
zer
o (>
0).
If ze
ro li
es b
etw
een
the
uppe
r and
low
er 9
5% C
onfid
ence
Lim
its a
roun
d th
e m
edia
n Q
, the
re is
no
trend
.If
zero
lies
abo
ve th
e up
per l
imit
(UL
< 0)
, the
re is
a d
ownw
ard
trend
in th
e da
ta.
If ze
ro li
es b
elow
the
low
er li
mit
(0 <
LL)
, the
re is
a u
pwar
d tre
nd in
the
data
.
The
resu
lts o
f bot
h th
e M
ann-
Ken
dall
and
the
Sen
's S
lope
ana
lyse
s m
ust b
e si
gnifi
cant
for a
tren
d to
be
cons
ider
ed s
igni
fican
t.
Tren
ds s
igni
fican
t at a
con
fiden
ce le
vel o
f 97.
5% O
R 9
5% a
re s
how
n in
bol
d ty
pe.
9/9/
2015
Pag
e 2
of2
4
Mas
on
Co
un
ty L
and
fill
MW
-10
Res
ult
s o
f M
ann
-Ken
dal
l/Sen
's S
lop
e A
nal
yses
fo
r T
ren
d (
n=
8)
Man
n-K
enda
ll A
naly
sis
Sen
's S
lope
Ana
lysi
sP
rob.
Pro
b.S
lope
Low
erU
pper
Wel
l ID
Ana
lyte
1n
S(n≤1
0)(S
igni
f.)Tr
end
(Med
ian
Q)
Lim
itLi
mit
Tren
d
MW
-10
Chl
orid
e8
-40.
025/
0.05
0.72
/0.3
6N
o Tr
end
-0.0
1666
67-0
.225
0.06
6666
7N
o Tr
end
MW
-10
Spe
cific
Con
duct
ivity
8-6
0.02
5/0.
050.
548/
0.27
4N
o Tr
end
-2.0
0833
-8.6
3333
2.56
667
No
Tren
dM
W-1
0M
anga
nese
, Dis
solv
ed8
10.
025/
0.05
1.0/
0.5
No
Tren
d0.
000.
000.
00N
o Tr
end
MW
-10
Am
mon
ia8
50.
025/
0.05
0.63
4/0.
317
No
Tren
d0.
0004
5833
3-0
.007
0.00
5666
67N
o Tr
end
MW
-10
Nitr
ate
88
0.02
5/0.
050.
398/
0.19
9N
o Tr
end
0.01
9025
-0.0
50.
0636
667
No
Tren
dM
W-1
0pH
8-1
60.
025/
0.05
0.06
2/0.
031
Dow
nwar
d-0
.036
6667
-0.0
70.
00N
o Tr
end
MW
-10
Sul
fate
8-1
30.
025/
0.05
0.14
3/0.
0715
No
Tren
d-0
.291
071
-0.6
0.12
No
Tren
dM
W-1
0TO
C8
-70.
025/
0.05
0.47
3/0.
2365
No
Tren
d0.
000.
000.
00N
o Tr
end
1 Tre
nd a
naly
ses
wer
e no
t run
for A
rsen
ic, C
OD
, Iro
n, N
itrite
, Tet
rach
loro
ethe
ne, V
inyl
Chl
orid
e an
d Zi
nc b
ecau
se th
e da
ta fo
r the
se a
naly
tes
are
all N
Ds
n =
Sam
ple
size
S =
Man
n-K
enda
ll te
st s
tatis
tic.
Pos
itive
num
ber i
mpl
ies
an in
crea
sing
tren
d; a
neg
ativ
e nu
mbe
r im
plie
s a
decr
easi
ng tr
end.
P(n≤1
0) =
Pro
babi
lity
of o
btai
ning
a s
peci
fic |S
| val
ue (a
bsol
ute
valu
e of
S) w
hen
the
sam
ple
size
is le
ss th
an o
r equ
al to
10
(Tab
le 9
.4, G
ibbo
ns, 1
994)
.P
(Sig
nif))
≤ 0
.025
for a
two-
taile
d M
ann-
Ken
dall
test
(i.e
. at 1
.0 -
(α/ 2
) = 9
7.5%
con
fiden
ce le
vel)
P(S
igni
f)) ≤
0.0
5 fo
r a o
ne-ta
iled
Man
n-K
enda
ll te
st (i
.e. a
t 1.0
- (α
) = 9
5% c
onfid
ence
leve
l)If
the
prob
abili
ty o
f obt
aini
ng th
e ab
solu
te v
alue
of t
he c
alcu
late
d S
sta
tistic
(|S
|) ≤
0.02
5, a
sig
nific
ant t
rend
is p
rese
nt in
the
data
.If
the
prob
abili
ty o
f obt
aini
ng th
e ab
solu
te v
alue
of t
he c
alcu
late
d S
sta
tistic
(|S
|) ≤
0.05
, a s
igni
fican
t upw
ard
or d
ownw
ard
trend
is p
rese
nt in
the
data
.
Ther
e is
no
trend
in th
e da
ta w
hen
|S| >
0.0
25 a
nd n
o si
gnifi
cant
upw
ard
or d
ownw
ard
trend
whe
n |S
| > 0
.05
The
Sen
's S
lope
/Tre
nd E
stim
ator
Tes
t is
a t
wo-
taile
d te
st w
ith a
nul
l hyp
othe
sis
of z
ero
slop
e. T
here
fore
Q (S
lope
Est
imat
or=
Med
ian
Q) c
an b
e le
ss th
an z
ero
(< 0
), no
t diff
eren
t tha
n ze
ro (N
D 0
), or
gre
ater
than
zer
o (>
0).
If ze
ro li
es b
etw
een
the
uppe
r and
low
er 9
5% C
onfid
ence
Lim
its a
roun
d th
e m
edia
n Q
, the
re is
no
trend
.If
zero
lies
abo
ve th
e up
per l
imit
(UL
< 0)
, the
re is
a d
ownw
ard
trend
in th
e da
ta.
If ze
ro li
es b
elow
the
low
er li
mit
(0 <
LL)
, the
re is
a u
pwar
d tre
nd in
the
data
.
The
resu
lts o
f bot
h th
e M
ann-
Ken
dall
and
the
Sen
's S
lope
ana
lyse
s m
ust b
e si
gnifi
cant
for a
tren
d to
be
cons
ider
ed s
igni
fican
t.
Tren
ds s
igni
fican
t at a
con
fiden
ce le
vel o
f 97.
5% O
R 9
5% a
re s
how
n in
bol
d ty
pe.
9/9/
2015
Mas
on
Co
un
ty L
and
fill
Cu
lver
Wel
lR
esu
lts
of
Man
n-K
end
all/S
en's
Slo
pe
An
alys
es f
or
Tre
nd
(n
=8)
Man
n-K
enda
ll A
naly
sis
Sen
's S
lope
Ana
lysi
sP
rob.
Pro
b.S
lope
Low
erU
pper
Wel
l ID
Ana
lyte
1n
S(S
igni
f.)(n≤1
0)Tr
end
(Med
ian
Q)
Lim
itLi
mit
Tren
d
Cul
ver
Chl
orid
e8
-80.
025/
0.05
0.39
8/0.
199
No
Tren
d-0
.045
-0.1
50.
0333
333
No
Tren
dC
ulve
rS
peci
fic C
ondu
ctiv
ity8
00.
025/
0.05
1.09
6/0.
548
No
Tren
d-0
.391
667
-11.
175
7.12
5N
o Tr
end
Cul
ver
Iron,
Dis
solv
ed8
-50.
025/
0.05
0.63
4/0.
317
No
Tren
d0.
000.
000.
00N
o Tr
end
Cul
ver
Man
gane
se, D
isso
lved
8-2
0.02
5/0.
050.
904/
0.45
2N
o Tr
end
0.00
0.00
0.00
No
Tren
dC
ulve
rA
mm
onia
80
0.02
5/0.
051.
096/
0.54
8N
o Tr
end
0.00
-0.0
055
0.00
475
No
Tren
dC
ulve
rN
itrat
e8
160.
025/
0.05
0.06
2/0.
031
Upw
ard
0.00
8666
67-0
.002
0.02
5N
o Tr
end
Cu
lver
pH
8-1
90.
025/
0.05
0.02
31/0
.011
6D
ow
nw
ard
-0.0
6333
33-0
.085
-0.0
22D
ow
nw
ard
Cul
ver
Sul
fate
8-1
30.
025/
0.05
0.14
3/0.
0715
No
Tren
d-0
.338
571
-0.7
3333
30.
2N
o Tr
end
Cul
ver
Tetra
chlo
roet
hene
8-1
0.02
5/0.
051.
0/0.
5N
o Tr
end
0.00
0.00
0.00
No
Tren
dC
ulve
rZi
nc, D
isso
lved
8-3
0.02
5/0.
050.
812/
0.40
6N
o Tr
end
0.00
-0.0
10.
01N
o Tr
end
1 Tre
nd a
naly
ses
wer
e no
t run
for A
rsen
ic, C
OD
, Nitr
ite, T
OC
, and
Vin
yl C
hlor
ide
beca
use
the
data
for t
hese
ana
lyte
s ar
e al
l ND
s
n =
Sam
ple
size
S =
Man
n-K
enda
ll te
st s
tatis
tic.
Pos
itive
num
ber i
mpl
ies
an in
crea
sing
tren
d; a
neg
ativ
e nu
mbe
r im
plie
s a
decr
easi
ng tr
end.
P(n≤1
0) =
Pro
babi
lity
of o
btai
ning
a s
peci
fic |S
| val
ue (a
bsol
ute
valu
e of
S) w
hen
the
sam
ple
size
is le
ss th
an o
r equ
al to
10
(Tab
le 9
.4, G
ibbo
ns, 1
994)
.P
(Sig
nif))
≤ 0
.025
for a
two-
taile
d M
ann-
Ken
dall
test
(i.e
. at 1
.0 -
(α/ 2
) = 9
7.5%
con
fiden
ce le
vel)
P(S
igni
f)) ≤
0.0
5 fo
r a o
ne-ta
iled
Man
n-K
enda
ll te
st (i
.e. a
t 1.0
- (α
) = 9
5% c
onfid
ence
leve
l)If
the
prob
abili
ty o
f obt
aini
ng th
e ab
solu
te v
alue
of t
he c
alcu
late
d S
sta
tistic
(|S
|) ≤
0.02
5, a
sig
nific
ant t
rend
is p
rese
nt in
the
data
.If
the
prob
abili
ty o
f obt
aini
ng th
e ab
solu
te v
alue
of t
he c
alcu
late
d S
sta
tistic
(|S
|) ≤
0.05
, a s
igni
fican
t upw
ard
or d
ownw
ard
trend
is p
rese
nt in
the
data
.
Ther
e is
no
trend
in th
e da
ta w
hen
|S| >
0.0
25 a
nd n
o si
gnifi
cant
upw
ard
or d
ownw
ard
trend
whe
n |S
| > 0
.05
The
Sen
's S
lope
/Tre
nd E
stim
ator
Tes
t is
a t
wo-
taile
d te
st w
ith a
nul
l hyp
othe
sis
of z
ero
slop
e. T
here
fore
Q (S
lope
Est
imat
or=
Med
ian
Q) c
an b
e le
ss th
an z
ero
(< 0
), no
t diff
eren
t tha
n ze
ro (N
D 0
), or
gre
ater
than
zer
o (>
0).
If ze
ro li
es b
etw
een
the
uppe
r and
low
er 9
5% C
onfid
ence
Lim
its a
roun
d th
e m
edia
n Q
, the
re is
no
trend
.If
zero
lies
abo
ve th
e up
per l
imit
(UL
< 0)
, the
re is
a d
ownw
ard
trend
in th
e da
ta.
If ze
ro li
es b
elow
the
low
er li
mit
(0 <
LL)
, the
re is
a u
pwar
d tre
nd in
the
data
.
The
resu
lts o
f bot
h th
e M
ann-
Ken
dall
and
the
Sen
's S
lope
ana
lyse
s m
ust b
e si
gnifi
cant
for a
tren
d to
be
cons
ider
ed s
igni
fican
t.
Tren
ds s
igni
fican
t at a
con
fiden
ce le
vel o
f 95%
OR
97.
5% a
re s
how
n in
bol
d ty
pe.
9/9/
2015