1982 Exxon Primer on CO2 Greenhouse Effect

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  • 7/24/2019 1982 Exxon Primer on CO2 Greenhouse Effect

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    I

    E*g1t

    Arrror."

    o*o

    ,*o,*.r*,*o

    .o,tro*"

    -

    I

    e.o.

    Box

    1o1,

    FLoRHAM

    PARK,

    NEwJERSEY 07932

    )

    M.

    8. GLASER

    Manager

    Envi

    ronmenta

    I Affai

    rs Programs

    IIIBG:

    rva

    Attachments

    -

    co^

    Cable:

    ENGREXXON, N.Y.

    November

    L2,

    L982

    "Greenhouse"

    Effect

    I{.

    F,l.

    WEINBERG

    NOV

    1

    5

    i98Z

    82EAP 256

    TO: See

    Distribution

    List

    Attached

    Attached

    for

    your

    information

    and

    guidance

    is

    briefing

    material

    on

    the

    CO2

    "Greenhouse"

    Effect

    which

    is receiving

    increased

    attention

    in

    both

    the

    scientific

    and

    popular press

    as an

    emerging

    environmental

    issue. A brief

    surTnnary

    is

    provided

    along

    with

    a

    more

    detailed

    technical

    review

    prepared

    by CPPD.

    The

    material has

    been

    given

    wide circulation to

    Exxon

    managernent

    and

    is intended to

    familiarize

    Exxon

    personnel

    with the

    subject. ft

    may

    be

    used

    as a

    basis

    for discussing the

    issue with

    outsiders

    as

    may

    be

    appropriate.

    However, it

    should

    be

    restricted

    'to-Exxon

    personnel

    and not

    distributed externally.

    Very

    truly

    yours,

    7ls

    //*

    M. B. GLASER

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    Distribution List:

    R.

    w.

    cohen

    M.

    J.

    Connor,

    ilr.

    E.

    E. David, Jr.

    c. u. Eidt, Jr.

    W. R.

    Epperly

    R.

    L. Hirsch

    T.

    G.

    Kaufmann

    D.

    G. Levine

    G.

    It. I"ong

    J. R.

    Riley

    H. R.

    Savage

    A. Schriesbeim

    iI.

    F

    .

    Taylor

    D.

    T.

    Wade

    H. N. Weinberg

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    -

    NGREENHOUSE

    EFFECTN

    z

    0

    PRC:::-:A.RY

    SUilUARI

    Atuospherlc

    toonltorlng

    prograEs

    shon

    thc

    leve1 of carbon

    dlorlde

    1n the

    attrospbere

    has

    lncreased about

    8l

    ovcr

    thc

    last

    tHenty-flve

    years

    and

    not,

    stands

    at ebout

    3q0

    ppn.

    lttls

    observed

    lncreasc ls

    bclleved

    to

    bc

    tirc con-

    tluuatlo

    of a

    trcnd rblcb

    began ln

    thc

    olddlc of thr

    last

    century sl

    th

    thc

    start of thc

    Industrfal

    Revolutlon.

    Fossll

    fue1

    coobustlon

    and the clcaring

    of vlrgln

    forests

    (

    deforcstatlon)

    arc

    belleved

    to b thc

    prlnary

    anthropogcnlc

    contrl.butors

    althougb the

    rclatlvc contributlon

    of

    cach 1

    uoc.rtaln.

    Thc

    carbon

    dloxlde

    conteDt of tbc

    atDosphere ls of concern

    1Dce

    t

    caD

    affect

    gl,obal

    cllnate. Carbon

    dtoxldc

    and

    otbcr

    trace

    gases-

    eontalned

    ln

    the

    atDosphere such as

    sater

    vepor,

    ozoncr

    r0ethaDe, carbon

    Eonoxldc,

    oxldcs

    -

    of nltrogen,

    etc. absorb

    part

    of the

    lnfrared rays.reradlated

    by

    the earlh.

    Tbls

    lncrease

    tn

    absorbed energy

    uaros

    the atnosphere

    inductng HarBlng

    at the

    earthrs

    surfacc.

    lbls

    phenooenon

    1s

    referred

    to

    ss the

    ngreenhousc

    effcctn.

    Predlctlons

    of the

    cltratologlcal

    ltopec of

    a

    carbon

    dloxlde

    lnduced

    -

    ngreenhouse

    effectn draH upon

    varlous

    DEtheDetl,cal

    Dodels

    to

    gauge

    lhe eo-

    perature

    lncrease. The sclentlflc cooDunlty

    geocrall.y

    dtscusscs

    the bpact

    ln terDs

    of

    doubllng

    of

    the current

    carbon dlortde

    content

    lD

    order to

    get

    beyond

    the

    nolse

    leve1

    of

    thc

    det8.

    lle cstlnate

    doubllng

    could

    occur

    arormd

    the

    year

    2090

    based upoa

    .fossll

    .fuel

    requlrencnts

    projected

    1r

    Erronrs

    long

    range energy

    outlook.

    thc

    questlon

    of

    rbl.ch

    predlcttons

    and

    nhlch

    oodcls

    best

    sLEu:.atc

    a

    carboa

    dloride

    lnduced elLroate

    cbaage

    ts

    stlU

    bclng

    debated by

    thc

    sclentlflc [email protected].

    Orr

    best

    estlnate

    ls

    tbat

    doublhg

    of the^currcnt

    congeDtrarion could

    lncrrasr

    average

    global

    tcBperatur

    by

    about

    l.Je

    to

    3.1oC.

    lbc

    lDcreasb

    so-uld

    not

    Ua

    nn

    t.ior.n

    over

    tbe earthts

    surfacq

    nlth

    tbe

    polar

    caps llkcly

    to

    sce

    terprature

    lncreases oa

    thc

    order

    of

    lO'C and

    thc

    eguator llttle,

    lf

    any,

    lncrcase.

    Consldcr'able uniertalnty

    elso surrounds

    the

    posslble

    lnpact

    on

    soc ,ety

    of

    such

    a

    rirnlng trend, should

    lt

    occur.

    A

    the Lor cnd

    of.

    tbe

    prcdlcted

    teoperature

    rangc

    there

    eould

    be sooe. Lupact

    on

    agrl.crrltural

    groyth

    and

    ralnfall

    patterus

    rrhlch

    could

    be

    beneflcl.al

    in

    soEa

    reglons

    and delrl^nental

    ln othcrs. At

    tbe

    hlgh

    end,

    sone sctentlsts suggest

    there

    could

    be conslderable

    adverse lnpact

    lncludlng

    lhe

    floodtng

    of soe

    coaslal

    laDd Easses as

    a

    result of a

    rlse

    ln

    sea

    level due

    to

    DeItlDg

    of

    the

    AntarctlQ lce sheet.

    Such

    an cffect

    nould

    not

    lakc

    placc

    untll

    centurlc

    afler

    a

    3lC

    gtoUat

    averege tDperaturc

    Lncreas

    actually

    occurred.

    there

    ls

    currently no unanblguous

    sclcntlflc cvldence

    that

    the

    earth

    ls

    warolng.

    If

    the

    earth ls

    on

    a

    warrlng

    trend,

    uerre not

    11kely

    to detect

    1t

    before

    1995- llrls is about

    thc earllest

    proJectlon

    of

    utten

    the teoperaturc

    EC-11-5/

    A3

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    i.

    trlght rlse

    the

    O.5o

    needed

    fluctuatlons.

    On

    the

    other

    exaggerated

    the

    tenperature

    trgreenhouse

    effectn

    oay not

    -2-

    to

    get

    beyond

    the

    range

    of

    noraal

    tenperature

    hand,

    lf clfunate

    oodellng

    uncertalntles

    have'

    rlse,

    lt ls

    posslble

    ttrat.a

    carbon

    dloxlde

    lnduced

    be detected

    untll

    ?O?O

    at'the

    earllest.

    Tbe

    ngreenhouse

    effectn

    ls

    not

    1lkely

    to

    cause

    substaqtlal

    cllnatlc

    cbanges

    untll

    the

    average

    global

    tenperature

    rlses

    at

    least

    log

    above

    todayrs

    levels.

    Thls

    eould occur

    ln

    the

    second

    to

    thlrd

    guarter

    of

    tbe

    nert

    century.

    goreyer,

    there

    ts concern

    atrong

    sone

    sclentlfle

    groups

    thab

    once

    ttre

    effecti

    are

    neasurable,

    they

    nlght

    not

    be

    reverslble

    and

    llttle could

    be

    done

    to

    correct

    the

    sltuatlon

    tn

    tUe

    short tero.

    Therefore,

    a

    nrnber

    of

    envlronnental

    groups

    are

    calllng

    for actton

    now

    to

    prevent

    an

    undeslrable

    future

    sltuatloo

    fioo

    developlng.

    Hitlgatlon

    of

    the

    ngreenhouse

    effectn nould

    regulre

    naJor

    re?uitlons

    1o

    fosstJ

    fuel conbustlon.

    Shlfting

    between

    fossll

    fuels

    1s.not

    a

    feaslble

    alternatlve

    because

    of

    ltnlted

    long-teno

    supply

    avallablllty for

    cArtaln

    fuels

    although.

    o11 does produee

    about

    18i less

    carbon

    dloxlde per Btu

    of

    heat

    released

    thau

    coal,

    and

    gas

    about

    321

    less than

    o11.

    The

    energy

    outlook

    suggests

    synthetlc

    fuels

    will

    have.a

    negllglble

    Lnpact

    at

    least

    through

    the

    old

    21st

    eentury

    lcontrlbutlng

    less

    than

    fil

    of

    the

    total

    carbon

    dloxlde

    released

    frm

    fossll

    fuel

    conbustlon

    by

    the

    year

    2050.

    Thls

    low

    1evel

    lneludes

    the

    expecled

    eontrlbutlon

    froo

    carbonaLe

    deconposltlon

    rhlcb

    occurs

    durlng

    shale

    o11

    recovery

    and

    assuues

    essenttally

    no

    efftelency

    lmprovenents

    in

    synthettc.

    fuels

    processes

    above tbose

    currently'achlevable.

    Overall,

    the current

    outlook

    suggests

    potentlally

    serlous

    cllnate problens

    are

    not

    llkeIy

    to

    occur

    untlI the

    late

    21st cenlury

    or

    perhaps

    beyond

    at

    proJected

    energy

    denand'rates.

    Tlrls

    sbould

    provlde

    tlne to

    resolve uncertaln-

    tles

    regardlng'the'overall

    earboo

    cycle

    and

    the

    contrlbutlon

    of

    fossll

    fuel

    conbustton

    as

    rell

    as the

    role

    of

    tbe

    oceans

    as a

    reservolr

    for

    both

    heat

    and

    carbon

    d1oxlde.

    It

    should

    also

    allon

    tlne

    to

    better

    deflne

    the effect

    of

    carbon

    dloxlde

    and

    other

    lnfrared

    absorblng

    gases

    on

    surface

    cltoate.

    ldaklng

    slgnlflcant

    changes

    1n energy

    consr.uptlon

    patterDs

    nor

    to

    deal

    rlth

    thls

    potenttal

    probleo

    anld

    a1I the

    sclentlflc

    uncerlalntles

    would

    be

    prenature

    1a

    vlew.of

    tbe

    severe

    lnpact such

    noves

    could

    have on

    the

    norldrs

    econonles

    and

    soctetles.

    EC-1

    1-5lA4

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    -."

    PROPnIETANT

    I}IFOR}IATION

    FON

    AUTHONIZED

    COI{PANI

    USE

    OTILT

    CO^

    GNEENHOUSE

    EFFECT

    I

    .

    A

    TECHNICAL

    REVIETI

    PREPANED

    BT THE

    :

    COORDIIIATIOil

    A}TD

    PI.ANNING

    DIVISIOI{

    EiCIOII

    RESEANCH

    AIID

    ENGII{EEBIIIG CO{PAI{I

    APnrL

    1,

    1982

    EC:11-5/A2

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    -1-

    CO^ GREENHOUSE

    EFFECT

    z

    A

    TECHNICAL

    REVIEW

    TABLE

    OF

    CONTENTS

    BaCkgfOUnda

    ..

    ..

    .

    ...

    . ...

    .. ...

    o t.

    ... . o.

    . .. ...

    o.. ...

    . o. o.. ...

    . .. . o. ..

    o

    Sources

    and

    Dispositlon

    of

    Atnospherlc

    Carbon

    Dtoxide

    -

    Thil

    CanbOn

    Cyele..

    o

    ...

    o..

    ... ...

    .

    ..

    ... ... ... ...

    .

    .. ...

    .

    .

    o

    .

    ..

    ..

    o

    ...

    .

    Desorlptlon

    of.Potential

    Inpact

    on

    lleather,

    Cllnate'

    and

    Land AVa1lablllty.

    .

    .

    . .

    .

    . ..

    . ..

    .

    ..

    .

    ....

    .

    .

    .

    .

    o

    r .. ..

    .

    . ..

    o .. .

    ..

    .

    .. . .

    o

    . . o

    MaJor

    Rgsgarch

    Prograns

    Underway.

    .

    . .

    .

    . . . .

    . . . .

    . . . . . .

    . .

    .

    .

    . .

    .

    .

    .

    . .

    .

    .

    . . .

    Future

    Energy

    Scenarlos

    and

    Ttrefr

    Potentlal

    Impact

    on

    AtnosPherlc

    CafbOn

    DlOXldg...

    .

    . o .

    ..

    .

    ..

    . .

    . . . ...

    . .. ...

    . ..

    .

    o. . .. ..

    . .

    ..

    .

    ..'.

    .. ...

    Forecagt

    Based

    on

    Fossll

    FueI

    ProJected

    n

    Exxon

    Long

    Range

    Enefgy

    O,ttIOOk.....

    ... r...........

    .........

    ....

    o.............

    o...

    o

    Detgctlon

    of

    -a

    COo

    Induced

    Greenhouse

    Effect..............

    r........

    z

    PAGE

    NO.

    2

    17

    6

    15

    1g

    26

    30

    EC-l1-5/A5

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    -2-

    c02

    cREEllnousE

    EFFECT

    Background

    the

    butldup

    of

    co. ln the

    atoosphere

    has

    been

    Eonltored

    contlnuously'

    af

    the Natlona1

    Oceaflc

    and

    Atuospherlc

    AdDtnlstratloo

    I

    s

    (llOM)

    Observatory

    8t

    Hauna

    Loe,

    Hanall,

    and

    perlodtcally

    1n

    other

    places

    since

    1957.

    In

    addltlon

    to

    observlng

    a

    trend

    between

    1957

    -1979

    that

    strowed atEospherlc

    co2

    lncreaslng

    fron

    315

    to

    33?

    ppn,

    Keellng

    and others

    a13o

    observed

    a

    seasonal

    ?arlablllty

    ranglng

    froo

    6

    lo 10

    pp

    betreen

    a

    lox

    at

    the

    end

    of

    ttre

    suDDer

    growing

    season

    (aui

    to

    phoeosynthesls) and

    a

    h .gh

    at the

    end

    of

    ntnter

    (due

    to fossll

    f\rel.

    burnlng

    for

    heat,

    aDd

    bloDass

    decay).

    rhere

    ls 11 t1e doubt

    that

    these

    obser-

    vatlons

    tndleate

    a

    SroFlh

    of stEosPherle

    CO"

    (see

    F 'gure 1). It

    ls

    also

    belleved

    that

    the

    Srowth

    of

    atEospherlc

    Cor-has

    beeD

    occurrtng

    since the

    niddle

    of

    the

    past

    cenbury,

    1.e.,

    coincldefit

    r{'ltb the start of

    the

    Industrlal.

    Bevolutlon.

    I?rere

    ls,

    however,

    Sreat

    uncertainty as

    to

    wbether

    the

    at[os-

    Dherlc

    co^

    concentration

    prlor

    to the

    Industrlal

    Revol.utlon

    (ca.

    '

    1850)

    ras

    )go-goo

    pfin

    uhlch one

    would

    arrlve

    at

    by

    assuulng

    atoospherlc

    C0"

    Srowth

    ls

    :

    due to

    fossl1

    fuel

    burnlng

    and

    ceoent

    Danufacturlng,

    ot

    260-270

    lpu

    based

    on

    -

    c'arbon

    Lsotope

    EeasureEents

    ln

    tree rlngs.

    The lnfortatlol-

    9n.

    c9z

    concentra-

    tlon

    prlor

    to

    1850

    i3

    lnportant

    because

    lt

    rroul d helP

    establish

    the valld1ty

    of cliroatlc

    predlctlons nlth respeet

    to

    the tnceptlon

    of a

    CO2

    I'nduced

    tgreenhouse

    effectn.

    ?he

    ngreenhouse

    effecti

    refers

    o the

    absorbtlon

    by

    CO2

    and

    otber

    trace

    gases-conlained in

    the

    al66sphere

    (such

    as rater

    vapori ozone,

    carbo6

    Donottdel

    6rldes

    of

    nltrogen,

    freons,

    and

    netlrane) of

    part

    of tbe lnfrared

    radlation

    $hlih

    ls

    riradlated

    by

    the

    earth.

    An

    lncrease

    ln

    absorbed energy

    vla thls

    route

    nould iarn

    the

    earthts

    surface

    csuslng

    cbaages 1n

    cllEate affectlng

    .

    atDospherlc

    and ocean

    teEperatures,

    ralnfall

    Patteins,

    solI

    uolsture' and

    over

    cenbuiles

    potentially ueltlng

    the

    polar

    tce

    caps.

    Tbe

    relatlve

    contrlbutlons

    of

    bioloass

    oxldation

    (nalnly

    due

    to deforestatlon)

    and

    fossll

    fuel

    cornbustton

    go

    the observed

    atsospherlc

    COr

    increase

    are

    not

    loom. Ttrere

    are

    falrly

    good

    lndlcatlons

    that

    tbe

    anfiual

    gronth

    of

    ataospherlc

    CO;

    ls oo

    lhe order

    ot

    2.5

    Lo

    3.0

    Gtlar

    of carbon

    and

    the

    net

    quantlty

    of

    caFbon

    absorbed

    by

    the

    ocean.ls

    siu11ar1y

    2.5

    lo

    3

    Gtla.

    1bu3,

    these

    tuo

    slnks

    (atDosphere

    and

    ocean)

    can account

    for the

    total fosslI

    carbon

    burned

    (lncludlng

    0.3

    GIC/art

    frm

    ceuent

    nanufaeturlng)

    which ls on the

    order

    of

    5-6

    Gl/a

    and

    does

    not

    alJow

    nuch rooo for a

    net

    contrlbutlon

    of

    bloness

    r

    Gt/a

    =

    glgatons

    per

    annun

    =

    10'

    Detrl8

    tons

    per year.

    tt

    GtC/a

    =

    glgatons

    carbon

    per

    annun

    =

    10'

    netrlc toDs

    of carbon

    Per

    year.

    EC-11-5/

    A6

  • 7/24/2019 1982 Exxon Primer on CO2 Greenhouse Effect

    10/46

    Eii

    o

    :9

    az

    :3

    -_a

    EE

    EP

    9.9

    =-5

    c;

    -9

    Zg

    c3

    il

    :

    9;.

    -iE

    =a

    B

    cl=

    a=

    >E

    Ec

    oo

    EI

    gc

    oa

    t-u

    o8

    (J5

    cE

    BI

    *s

    Eg

    ac

    r

    EE

    EE

    i ::'a

    E;'

    c

    i

    a

    I

    aio

    t

    :t

    c

    I

    t

    t

    B

    IT

    t

  • 7/24/2019 1982 Exxon Primer on CO2 Greenhouse Effect

    11/46

    -4-

    carbon. Yet, highly

    respcted

    sclentlsts

    such as

    Hcodwe11,

    Bolln

    and

    others

    have

    postulaled

    a

    net

    blonass

    contrlbutlon

    to

    atDospherlc

    C0.

    that

    ranges

    froo 1

    to

    perhaps

    8

    GL/a

    ot

    earbon. Drrlng

    1980,

    a nrnber

    of

    dlfferent

    groups

    Produced

    ner estloates

    of

    the contrlbutlon

    of

    organlo.

    terrestlal

    fl|[es

    to

    atoosphertc

    C0r. A

    consensus

    has

    not been

    reached,

    but esttsates

    of

    the

    net

    annual

    terFestlal

    blosphere

    eolsslons

    to

    the

    at&osphere

    noH

    range

    betueen

    a

    4

    GtC/a

    source

    and

    a

    2

    GtCla

    slnk. Flgure

    2 al@Earizes

    the

    Cluxes

    and

    reservoLrs for the

    carbon

    cycle.

    rt should

    be noted that

    the

    net

    blosphere

    contrlbutlon

    nas assuued

    to be 0-2 Cte/a.

    The rate

    of

    forest

    clearlng

    has been

    estfuoatqd

    4f

    0.5/ Eo

    1.51

    per

    yeaE

    of

    the

    exlstlng

    area. Forests

    occupy

    about

    50

    x 10-h'

    out

    of about

    150

    x lOekn

    /

    p,fat

    ,r'l:1,"":':l

    1l

    /

    ttuctu.aiions

    /

    I

    ./

    -'/a"tt

    rC

    /

    including

    co2

    effec.

    t\L-

    /

    .\\--

    .

    /P"rt

    ctranges

    without

    Range

    of

    \

    natural

    fluctuations

    (climatic

    noise)

    Lo,

    effect

    (?l

    -

    ---

    v

  • 7/24/2019 1982 Exxon Primer on CO2 Greenhouse Effect

    36/46

    _29

    _

    the

    behavtor

    of

    the

    nean

    global

    tenperature

    froo 1850

    to

    the

    present,

    contalned

    rdthln

    an

    envelop

    scaled

    to

    lnclude

    the

    randgn

    tenpe5ature

    fluctuatlons,

    and

    proJected

    lnto

    the t\rture

    to

    lnclude

    the

    1.3-

    to

    3.1'C

    range of

    uncertalnty

    noted

    above

    for

    the

    CO,

    effect.

    Dependtng

    on

    the

    actual global

    energy

    denand

    and

    supplY,

    1t1-"

    po""fble

    tbat

    sone of

    the

    eoncerns

    about

    CO,

    Erowtb

    due

    to fossll

    fuel

    conbustlon nay

    be

    reduced

    lf foss1l

    fuel

    use lstdecreaseS

    due

    to

    hlgh

    prlee,

    scarclty,'and

    unavallabll1ty.

    The

    above

    dlscusslon

    assunes

    that

    an

    lnstantaneous

    cllnatlc

    resPonse

    results

    froa

    an

    lncrease

    ln

    atrnosptrerlc

    GOo

    concentratlon.

    In

    actuallty'

    the

    tenperabure

    effect

    nould llke1y

    Ia

    the

    C0,

    change

    by about 20

    years

    beeause

    the

    oceans

    would

    tend

    to

    danp

    out

    tenperat[re

    changes"

    Gtven

    the

    long

    tern

    nafure

    of

    the

    potentlal

    problen

    and

    the ulcertalntles

    lnvo1ved,

    tt

    rould

    appear

    that

    there ls

    tlne

    for

    firther

    study and

    nonl'tortng

    before

    speclflc

    acllons

    need

    be

    taken.

    At

    the

    present

    tl.ne,

    that

    actlon

    would

    Itkely

    be curtallnent

    of fossll

    fuel

    consunptlon

    uhlch

    rculd

    undoubtedly

    serlously

    inpact

    tlre

    worldts

    economles

    and

    socleties.

    Key

    Polnts

    needlng

    .better deflnition

    lnclude

    the

    lnpact

    of

    fossll

    fuel

    conbuslon and

    the role

    of

    -ttre

    oceans

    ln

    the

    carbon

    cycle

    and

    the lnteractlve

    effect

    of

    carbon dl'oxlde

    and

    other

    trace

    atnospherlc

    gases

    on

    clluate-

    EC-l1-5/A18

  • 7/24/2019 1982 Exxon Primer on CO2 Greenhouse Effect

    37/46

    -30-

    BIBLIOGNAPHT

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